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HomeMy WebLinkAboutWater Chemistry Date Package 06/2007Analytical Data Package For TOWN OF SOUTHOLD PART 360 ROUTINE :SDG NO: TSLO10 is Water Samples .Received: 6/14/07 & 6/15/07 WET CHEMISTRY DATA PACKAGE JUNE 2007 I AA 1_/Ztusq� Is U40 Environmental Testing Laboratories 575 Broad Hollow Road, Melville, N.Y. 11747 H2M LABS, INC. WET CHEMISTRY TABLE OF CONTENTS I. SAMPLE REPORTS II. Q.C. SUMMARY 111. RAW DATA H2M LABS, INC. SAMPLE REPORTS 1-1 U%s INC, 575 Broad Hdlow Road, Mdv7e W 11747 (631) 6943040.FAX- (631)420.8436 WSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-001 A Attn To Original Collected 6/14/07 11:50:00 AM Received 6114/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Alkalinity, Total (As CaCO3) Chloride Sulfate Bromide Biochemical Oxygen Demand Total Dissolved Solids Client ID. : MW -BD Results Qualifier D.F.. Units 31.0 1 mg/L 42.2 1 mg/L 108 5 mg/L 0.5 1 mg/L < 2 1 mg/L 305. 1 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported: Page 1 of 40 Sample Information... Type: Aqueous Origin: Method Number Analyzed E310.1 06/20/2007 2:35. PM E300.0 06/22/2007 4:52 PM E300.0 06/22/2007 8:59 PM E300.0 06/22/2007 4:52 PM E405.1 06/15/2007 9:05 AM E160.1 06/19/2007 12:04 PM Laboratory Manager 1H U%9 INC. 575 Broad Hollow Road, Meld le NY 11747 (631)6943040. FAX- (631)42GZ436 NYSDOH ID# 10478 LABORATORY RESULTS Town of Southold, Landfill Lab No. : 0706952-001 B Attn To : Original Client ID. MW -BD Collected 6114107 11:50:OQ AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Chemical Oxygen Demand Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Nitrogen, Kjeldahl, Total Results Qualifier D.F.. Units <10 1 mg/L 0.13 1 mg/L 8.48 10 mg/L < 5.0 1 pg/L 1.01 1 mg/L 'Qualifiers: E . Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 2 of 40 Sample Information... Type: Aqueous Origin: Method Number Analyzed E410.4 06/26/2007 1:02 PM E350.1 06/28/2007 1:20 PM E353.2 06/25/2007 11:55 AM E420.1 06/27/2007 9:20 AM E351.2 06/26/2007 1:30 PM Laboratory Manager US9 'NCO 575 Broad Hollow Road, Mdde NY 11747 (631) 6943040.FAX (631)42OZ436 NYSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952 -OO I C Attn To : Original Client ID. MW -BD Collected 6/14/07 11:50:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Hardness (As CaCO3) 210 10 mg/L Qualifiers: E -Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 3 of 40 Sample Information... Type: Aqueous Origin: Method Number Analyzed E130.2 06/28/2007 1:06 PM Laboratory Manager IH US, INC. 575 Brad Hollow Road, Melville NY 11747 (631)694,9040. FAX (631)42(}8436 WSDOH ID# 10478 Town of Southold Landfill 1 Attn To Original Collected 6/14/07 11:50:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC LABORATORY RESULTS Sample Information... Lab No. : 0706952-001 E Type: Aqueous Client ID. : MW -BD Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Total Organic Carbon 1.3 1 mg/L SW9060 06/21/2007 6:05 PM INC O Ol Qualifiers: E - Value above quantitation range D - Results for Dilution w:w• > D.F. = Dilution Factor Date Reported : Laboratory Manager Page 4 of 40 575 Broad FUm Road, Melfie W 11747 (631)6943040.FAX (631)42M436 WSDOH ID# 10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-002A Type Aqueous AttnTo Original Origin: Client ID. : MW -4D Collected 6/14/07 10:30:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original. CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 10 1 mg/L E310.1 06/20/2007 2:40 PM Chloride 35.2 1 mg/L E300.0 06/22/2007 5:05 PM Sulfate 96.5 5 mg/L E300.0 06/22/2007 9:14 PM Bromide < 0.5 1 mg/L E300.0 06/22/2007 5:05 PM Biochemical Oxygen Demand <2 1 mg/L E405.1 06/15/2007 9:10 AM Total Dissolved Solids 445 1 mg/L E160.1 06/19/2007 12:06 PM Qualifiers: E -Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : . Laboratory Manager Page 5 of 40 1-I US9 INC® 575 Broad Hdbw Road, McWe W 11747 (631)6943 .FAX(631)4205436 NYSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-0028 Type: Aqueous Attn To Original Origin: Client ID. MW -4D Collected 6/14/07 1.0:30:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy :.Original Cc Parameter(s) Results Qualifier DD=F. Units Method Number Analyzed Chemical Oxygen Demand 40.9 1 mg/L E410.4 06/26/2007 1:03 PM Nitrogen, Ammonia (As.N) 0.78 1 mg/L E350.1 06/28/2007 1:22 PM Nitrate as N 8.55 10 mg/L E353.2 06/25/2007 11:57 AM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 06/27/2007 9:30 AM Nitrogen, Kjeldahl, Total 2.50 10 mg/L E351.2 06/26/2007 1:31 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Repotted: Page 6 of 40 Laboratory Manager 00 O r --- i O 575 Broad Holloav Road, Mdvile NY 11747 (631)6943040. FAX: (631)4W8436 NYSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-002C Type: Aqueous Origin:. Attn To Original Client ID. : MW -4D Collected 6/14/07 10:30:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Hardness (As CaCO3) 250 10 mg/L E130.2 06/28/2007 1:09 PM O O Qualifiers: • E -Value above quantitation range D - Results for Dilution, w!!!•�''•ti" ' - D.F. = Dilution Factor Date Reported : Laboratory Manager Page 7 of 40 U2AA "U%s INC. 515 Broad FUm Road, Mdde NY 11747 (631)6943040.FAK(631)42064.96 NYSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-002E Attn To : Original Client ID. : MW -4D Collected 6/14/07 10:30:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy Original CC Sample Information... Type: Aqueous Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Total Organic Carbon 11.7 1 mg/L SW9060 06/21/2007 6:35 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 8 of 40 Laboratory Manager U M� INCO 575 Broad Hdlow Road, MdWa W 11747 (631) 6943040.FAX (631,)4W-84.36 NYSDOHID#10478 Town of Southold Landfill Attn To Original Collected 6114/07 10:00:00 AM Received 6114107 3:15:00 PM Collected By: VG Copy : Original CC mg/L LABORATORY RESULTS Lab No. : 0706952-003A Client ID. : MW -4S Sample Information... Type: Aqueous Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 876 20 mg/L E310.1 06/20/2007 2:45 PM Chloride 352 20 mg/L E300.0 06/27/2007 7:20 PM Sulfate 91.0 5 mg/L E300.0 06/22/2007 9:29 PM Bromide 2.0 1 mg/L E300.0 06/22/2007 5:19 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 - 06/15/2007 9:15 AM Total Dissolved Solids 1300 4 mg/L E160.1 06/19/2007 12:08 PM - Qualifiers: E -Value above quantitation range D - Results for Dilution D.F. = Dilution Factor / // _® s rA Date Reported: Laboratory Manager Page 9 of 40 575 Broad Hollow Road, Mdvie W 11747 (631)694.3040.FAX(631)42&8436 WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-003B Type: Aqueous Qualifiers: E - Value above quantitation range D - Results for -Dilution D.F. = Dilution Factor Date Reported Laboratory Manager Page 10 of 40 Origin:' Attn To Original Client ID. : MW -4S Collected 6/14/07 10:00:00 AM Received 6114/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Chemical Oxygen Demand 107 1 mg/L E410.4 06/26/2007 1:04 PM Nitrogen, Ammonia (As N) 19.6 10 mg/L E350.1 06/28/2007 1:23 PM Nitrate as N < 0.10 1 mg/L E353.2 06/25/2007 11:58 AM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 06/27/2007 9:40 AM Nitrogen, Kjeldahl, Total 32.9 50 mg/L E351.2 06/26/2007 1:32 PM Qualifiers: E - Value above quantitation range D - Results for -Dilution D.F. = Dilution Factor Date Reported Laboratory Manager Page 10 of 40 575 Broad Hollow Road, Mdvk W 11747 (631)694.9040.FAX(631)420&136 WSDOH ID# 10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-003C Attn To Original Client ID. : MW -4S Collected 6114/07 10:00:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Sample Information... Type: Aqueous Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Hardness (As CaCO3) 780 20 mg/L E130.2 06/28/2007 1:12 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported: Page 11 of 40 'Laboratory Manager U%9 Isco 575 Broad Hollow Road, Melvlle W 11747 (631)094--oAO. FAX (631) 42MW WSDOH ID # 10478 'LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-003E I Attn To Original Client ID. : MW -4S Collected 6/14/07 10:00:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Sample Information... Type: Aqueous Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Total Organic Carbon 28.9 1 mg/L SW9060 06/21/2007 7:05 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported Page 12 of 40 Laboratory Manager U2AA "U%s ING 575 Broad Hollow Road, Meyie NY 11747 (631)6943040.FAX- (631)42M436 WSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-004A Attn To : Original Client ID. : MW -5D Collected 6/14/07 9:15:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original cc Sample Information... Type: Aqueous Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 312 10 mg/L E310.1 06/20/2007 2:50 PM Chloride 376 10 mg/L E300.0 06/27/2007 7:34 PM Sulfate 53.9 10 mg/L E300.0 06/27/2007 7:34 PM Bromide 0.7 1 mg/L E300.0 06/22/2007 5:32 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/15/2007 9:20 AM Total Dissolved Solids 1220 4 mg/L E160.1 06/19/2007 12:10 PM Qualifiers: E - Value above quantitation range f D - Results for Dilution D.F. = Dilution Factor Date Reported : Laboratory Manager Page 13 of 40 575Broadl-loUaw Road, Mdvile W 11747 (631)694.3040.FAX (631)4agAW WSDO-IID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-0048 Attn To : Original Collected 6/14107 9:15:00 AM Received 6/14107 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Chemical Oxygen Demand Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Nitrogen, Kjeldahl, Total Client ID. : MW -5D Results Qualifier D.F.. Units 102 1 mg/L 50.6 10 mg/L < 0.10 1 mg/L < 5.0 1 pg/L 58.4 20 mg/L Qualifiers: E - Value above quantitation range i D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 14 of 40 Sample Information... Type: Aqueous Origin: Method Number Analyzed E410.4 06/26/2007 1:05 PM E350.1 06/28/20071:24 PM E353.2 06/25/200712:01 PM E420.1 06/27/2007 9:50 AM E351.2 06/26/2007 4:20 PM &KII . Laboratory Manager 11.0 r O �-i O 1H2A "U%s INCo 575 Broad Hollow Road, MdJe N1' 11747 (631) 694,3040. FAY, (631)4208436WSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-0040 Attn To : Original Client ID. : MW -5D Collected 6/14/07 9:15:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy Original cc Sample Information... Type: Aqueous Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Hardness (As CaCO3) 560 20 mg/L E130.2 06/28/2007 1:15 PM Qualifiers: E - Value abovequantitation range D -.Results for Dilution D.F_ = Dilution Factor Date Reported Page 15 of 40 Laboratory Manager Usg INC® 575 Brad Hdbw Road; McMb NY 11747 (631) 694-WM. FAX (631)42M436 WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-004E Type: Aqueous Attn To Original Origin: Client ID. MW -5D Collected 6/14/07 9:15:00 AM Received 6/14107 3:15:00 PM Collected By: VG Copy : Original cc Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Total Organic Carbon 26.7 1 mg/L SW9060 06/21/2007 7:35 PM Qualifiers: E - Value above quantitation range y/y D - Results for Dilution D.F_ = Dilution Factor Daze Reported : Laboratory Manager Page -16 of 40 575 Broad Hollow Road, Mdvae NY 11747 (631)6943M.FAY, (631)420-84W NYSDOHID#10478 Town of Southold Landfill Attn To : Original Collected 6/14107 9:45:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC LABORATORY RESULTS Lab No. : 0706952-005A Client ID. : MW -5S Sample Information... Type: Aqueous Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 41.0 2 mg/L E310.1 06/22/2007 2:45 PM Chloride 23.5 1 mg/L E300.0 06/22/2007 6:13 PM Sulfate 34.8 1 mg/L E300.0 06/22/2007 6:13 PM Bromide < 0.5 1 mg/L E300.0 06/22/2007 6:13 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/15/2007 9:30 AM Total Dissolved Solids 185 1 mg/L E160.1 06/19/2007 12:16 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D -F. = Dilution Factor -® s VA Date Reported: Laboratory Manager Page 17 of 40 CT O O �LL l� 1HUS' INCe 575 Broad Hollow Road, Melvie NY 11747 (631)6943040.FAX(631)420S436 NYSDOHID#10478 Town of Southold Landfill Attn To : Original Collected 6/14/07 9:45:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC LABORATORY RESULTS Sample Information... Lab No. : 0706962-0058 Type: Aqueous Client ID. : MW -5S Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Chemical Oxygen Demand <10 1 mg/L E410.4 06/26/2007 1:08 PM Nitrogen, Ammonia (As N) 0.53 1 mg/L E350.1 06/28/2007 1:28 PM Nitrate as N 7.16 10 mg/L E353.2 06/25/2007 12:05 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 06/27/2007 10:20 AM Nitrogen, Kjeldahl, Total 1.60 10 mg/L E351.2 06/26/2007 1:36 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Laboratory Manager Page 18 of 40 12A %9 ING 575 Broad Hollow Road, MEtvie NY 11747 (631)694-XA0.FAX (631)420&t36 NYSD0HID#10478 Town of Southold Landfill Attn To Original Collected 6/14/07 9:45:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC LABORATORY RESULTS Sample Information... Lab No. : 0706952-005C Type: Aqueous Client ID. : MW -55 Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Hardness (As CaCO3) 110 10 mg/L E130.2 06/28/2007 1:24 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor /7 WEE -B l Date Reported: Laboratory Manager Page 19 of 40 PS-9 INCO 575 Broad Hdlavv Road, Melville W 11747 (631)a43040_FAX (631)4208436 NYSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-005E Attn To Original Sample Information... Type: Aqueous Origin: Client ID. : MW -5S Collected 6/14/07 9:45:00 AM Received 6/14107 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Total Organic Carbon 5.2 1 mg/L SW9060 06/21/2007 9:06 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Laboratory Manager Page 20 of 40 U U%9 I c® 575 Broad Hollow Road, Made W 11747 (631)694.3040.FAX- (631)420-84%WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-006A Type: Aqueous Qualif ers: E -Value above quantitation range I � D -Results for Dilution D.F. = Dilution Factor Date Reported : Page 21 of 40 db Laboratory Manager E Origin:Attn To : Original Client ID. : MW -6D Collected ' 6/14/07 11:50:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 28.0 1 mg/L E310.1 06/22/2007 2:50 PM Chloride 42.3 1 mg/L E300.0 06/22/2007 6:26 PM Sulfate 109 5 mg/L E300.0 06/22/200710:56 PM Bromide < 0.5 1 mg/L E300.0 06/22/2007 6:26 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/15/2007 9:35 AM Total Dissolved Solids 290 1 mg/L E160.1 06/19/2007 12:18 PM Qualif ers: E -Value above quantitation range I � D -Results for Dilution D.F. = Dilution Factor Date Reported : Page 21 of 40 db Laboratory Manager E 1 I2A "US, IMC® 575 Broad Follow Road, Mdvie W 11747 (631) 694.3040. FAX- (631)4W8435 WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. 0706952-0068 Type: Aqueous Atfn To Original Origin: Client ID. : MW -613 Collected 6/14/07 11:50:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Chemical Oxygen Demand 18.1 1 mg/L E410.4 06/26/2007 1:09 PM Nitrogen, Ammonia (As N) 0.24 1 mg/L E350.1 06/28/2007 1:29 PM Nitrate as N 7.76 10 mg/L E353.2 06/25/2007 12:06 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 06/27/2007 10:30 AM Nitrogen, Kjeldahl, Total 0.71 1 mg/L E351.2 06/27/2007 12:23 PM Qualifiers: E - Value above quanlilation range D - Results for Dilution D.F. = Dilution Factor 9 Date Reported : Laboratory Manager Page 22 of 40 1-I "US9INC• 575 &ued Hdlow Road, Melville NY 11747 (631) 40. FAX (631)4208436WSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952^0060 Attn To : Original Client ID. : MW -613 Collected 6/14/07 11:50:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Sample Information... Type: Aqueous Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Hardness (As CaCO3) 190 10 mg/L E130.2 06/28/2007 1:27 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F- = Dilution Factor Date Reported : Page 23 of 40 -e s Laboratory Manager 1HIMUS, INCe 575 Broad Hdbw Road, Melvle NY 11747 (631)694:040.FAX:(631)4205436 NYSDOHID#10478 Town of Southold Landfill Attn To Original Collected 6/14/07 11:50:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC LABORATORY RESULTS Sample Information... Lab No. : 0706952-006E Type: Aqueous Client ID. : MW -613 Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Total Organic Carbon 2.0 1 mg/L SW9060 06/21/2007 9:37 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. =Dilution Factor Date Reported : Laboratory Manager Page 24 of 40 575 Broad Hollow Road, Melville NY 11747 (631) 6943040. FAX(631)4205436 NYSDOH ID# 10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-007A Type: Aqueous Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor 6 // r Date Reported: Laboratory Manager Page 25 of 40 Origin: Attn To Original Client ID. : MW -6S Collected 6/14/07 11:10:00 AM Received 6/14107 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units i Method Number Analyzed Alkalinity, Total (As CaCO3) 41.0 2 mg/L E310.1 06/22/2007 2:55 PM Chloride 5.7 1 mg/L E300.0 06/22/2007 6:40 PM Sulfate 12.4 1 mg/L E300.0 06/22/2007 6:40 PM. Bromide < 0.5 1 mg/L E300.0 06/22/2007 6:40 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/15/2007 9:40 AM Total Dissolved Solids 103 1 mg/L E160.1 06/19/2007 12:20 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor 6 // r Date Reported: Laboratory Manager Page 25 of 40 I-1 "U%s INC 575 Broad Wow Road, Mdvie NY 11747 (631)6943040. FAK(631)4204436 NYSD0HID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 07069527007B Attn To : Original Collected 6/14/07 11:10:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Chemical Oxygen Demand Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Nitrogen, Kjeldahl, Total Client ID. : MW -6S Results Qualifier D.F.. Units 23.1 1 mg/L < 0.10 1 mg/L 0.49 1 mg/L < 5.0 1 pg/L 1.08 1 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F_ = Dilution Factor Date Reported: Page 26 of 40 Sample Information... Type: Aqueous Origin: Method Number Analyzed E410.4 06/26/2007 1:10 PM E350.1 06/28/2007 1:30 PM E353.2 06/25/2007 12:07 PM E420.1 06/27/2007 10:40 AM E351.2 06/27/2007 12:24 PM Laboratory Manager 00 N O O L IWO 575 Broad Hollow Road, Melville NY 11747 (631)6943040.FAX (631)4205436 NYSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-007C Attn To Original Collected 6/14/07 11 A 0:00 AM Received 6/14/07 3:15:00 PIN Collected By: VG Copy : Original CC Parameter(s) Hardness (As CaCO3) Client ID. : MW -6S Sample Information... Type: Aqueous Origin: Results Qualifier D.F. Units Method Number Analyzed 55.0 5 mg/L E130.2 06/28/2007 1:30 PM Qualifiers: E -Value above quantitation range J D - Results for Dilution D.F. = Dilution Factor Date Reported: Page 27 of 40 -Laboratory Manager N O O L�L U2144 "U%s INCe 575 Brom Hollow Road, Mdvie NY 11747 (631)6943040. FAX (631)420.84W NYSDOH ID# 10478 Town of Southold Landfill Attn To : Original LABORATORY RESULTS Lab No. : 0706952-007E Client ID. MW -6S Collected 6/14/07 11:10:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Sample Information... Type: Aqueous Origin: Parameter(s) Results Qualifier D_F_ Units Method Number Analyzed Total Organic Carbon 9.4 1 mg/L SW9060 06/21/200710:07 PM O cM O O Qualifiers:. E - Value above quantitation range KAA- /y D -.Results for Dilution -= W•—•3"' - .. D.F. = Dilution Factor Date Reported : Laboratory Manager Page 28 of 40 575 Broad'HdlawRoad, Md'& NY 11747 (631)aKZG40.FAX(631)4205436 NYSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 07069552-008A Type: Aqueous Attn To Original Origin: Client ID. : MW -8D Collected 6/14/07 12:35:00 PM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 434 10 mg/L E310.1 06/22/2007 3:00 PM Chloride 139 5 mg/L E300.0 06/22/200711:11 PM Sulfate 89.4 5 mg/L E300.0 06/22/2007 11:11 PM Bromide 0.7 1 mg/L E300.0 06/2212007 6:54 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/15/2007 9:45 AM Total Dissolved Solids 674 1 mg/L E160.1 06/19/2007 12:22 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Laboratory Manager Page 29 of 40 U US9 INCO 575 Broad Hollow Road, Melvie NY 11747 (631)6943040.FAX (631)42MW NYSDOH10#10478 Town of Southold Landfill Attn To : Original Collected 6/14/07 12:35:00 PM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Chemical Oxygen Demand Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Nitrogen, Kjeldahl, Total LABORATORY RESULTS Sample Information... Lab No. : 0706952-008B Type: Aqueous Origin: Client ID. : MW -8D Results Qualifier D.F.. Units 61.1 1 mg/L 38.7 10 mg/L < 0.10 1 mg/L 12.7 1 pg/L 47.0 20 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 30 of 40 Method Number Analyzed E410.4 06/26/2007 1:11 PM E350.1 06/28/2007 1:31 PM E353.2 06/25/2007 12:09 PM E420.1 06/27/2007 10:50 AM E351.2 06/26/2007 3:29 PM Laboratory Manager 1-I "US, INC, 575 Broad Hollow Road, Melville W 11747 (631)694-3040.FAK(631) 4208136 WSDOH ID # 10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-008C Type: Aqueous Attn To Original Origin: Client ID. : MW -8D Collected 6/14/07 12:35:00 PM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Hardness (As CaCO3) 340 10 mg/L E130.2 06/28/2007 1:33 PM Qualifiers: E -Value above quantitation range I D - Results for Dilution D.F. = Dilution Factor Date Reported: Laboratory Manager Page 31 of 40 U "U%s NCo 575 Broad Hollow Road, Melville NY 11747 (631)6N4 040. FAX- (631)42(}8436NYSDOHID#10478 Town of Southold Landfill Attn To Original Collected 6/14/07 12:35:00 PM Received 6/14107 3:15:00 PM Collected By: VG Copy : Original CC LABORATORY RESULTS Sample Information... Lab No. : 0706952-008E Type: Aqueous Client ID. : MW -8D Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Total Organic Carbon 23.0 1 mg/L SW9060 06/21/2007 10:37 PM Qualifiers: E- Value above quantitation range D - Results for Dilution_ D.F. = Dilution Factor Date Reported: Laboratory Manager Page 32 of 40 M O O LC/) L 1 2A "US, INC® 575 BroadFiollow Road, Mdvie W 11747 (631)6943040. FAX(631)420-84W WSDOH ID# 10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-009A Type: Aqueous Origin: AttnTo Original Client ID. : MW -8S Collected 6/14/07 12:10:00 PM Received 6/14/07 3:15:00 PM Collected By: VG' Copy : Original CC Parameter(s) Results Qualifier DD=F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 290 10 mg/L E310.1 06122/2007 3:05 PM Chloride 58.9 5 mg/L E300.0 06/22/2007 11:26 PM Sulfate 33.7 1 mg/L E300.0 06/22/2007 7:34 PM Bromide < 0.5 1 mg/L E300.0 06/22/2007 7:34 PM Biochemical Oxygen Demand 3 1 mg/L E405.1 06/15/2007 9:50 AM Total Dissolved Solids 414 2 mg/L E160.1 06/19/2007 12:24 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 33 of 40 Laboratory Manager 575 Broad Hdlow Road, Mdvie NY 11747 (631)6943040. FAX (631)420&136 NYSD0HID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-009B Type: Aqueous . Origin: Attn To Original Client ID. MW -8S Collected 6/14/07 12:10:00 PM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Chemical Oxygen Demand 61.1 1 mg/L E410.4 06/26/2007 1:12 PM Nitrogen, Ammonia (As N) 28.2 10 mg/L E350.1 06/28/2007 1:37 PM Nitrate as N < 0.10 1 mg/L E353.2 06/25/200712:10 PM Phenolics, Total Recoverable < 5.0 1 pg/L . E420.1 06/27/200711:00 AM Nitrogen, Kjeldahl, Total 35.4 20 mg/L E351.2 06/26/2007 3:29 PM Qualifiers: E -Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported.: Page 34 of 40 Laboratory Manager US, INCe 575 Broad Holbw Road, Melvie NY 11747 (631)694.3040. FAX-(631)42DZ436 WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952=0090 Type: Aqueous Origin: Attn To Original Client ID. MW -8S Collected 6/14/07 12:10:00 PM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Hardness (As CaCO3) 290 10 mg/L E130.2 06/28/2007 1:36 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported: Laboratory Manager Page 35 of 40 U2A 1 U%3 INCo 575 Broad Follow Road, Mdvie W 11747 (631)694WM.FAX(631)4W8436 WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-009E Type: Aqueous ' Origin: Attn To Original Client ID. MW -8S Collected 6/14/07 12:10:00 PM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original cc Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Total Organic Carbon 23.0 1 mg/L SW9060 06/22/2007 12:09 AM 00 M O O Qualifiers: E - Value above quantitation range D - Results for Dilution J D.F. = Dilution Factor Date Reported: Laboratory Manager Page 36 of 40 575 Broad Hdkwv Road, Melville W 11747 (631)6943040.FAX:(631)4M8436 WSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab.No. -: 0706952-01 OA Attn To : Original Collected 6114107 12:00:00 PM Received 6114/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s1 Alkalinity, Total (As CaCO3) Chloride Sulfate Bromide Biochemical Oxygen Demand Total Dissolved Solids Client ID. : FB 061407 Results Qualifier D.F.. Units < 1.0 1 mg/L < 2.0 1 mg/L < 5.0 1 mg/L < 0.5 1 mg/L < 2 1 mg/L <10 1 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported: Page 37 of 40 Sample Information... Type: Field Blank Origin: Method Number Analyzed E310.1 06/22/2007 3:10 PM E300.0 06/22/2007 7:48 PM E300.0 06/22/2007 7:48 PM E300.0 06/22/2007 7:48 PM E405.1 06/15/2007 9:55 AM E160.1 06/19/2007 12:26 PM Laboratory Manager 575 Broad Hollow Road, Md✓le NY 11747 (631)6943040. FAX(631)420Z436 NYSDDHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-01 OB Type: Field Blank Attn To Original Origin: Client ID. : FB 061407 Collected 6/14/07 12:00:00 PM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Chemical Oxygen Demand <10 1 mg/L E410.4 06/26/2007 1:13 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 06/28/2007 1:38 PM Nitrate as N < 0.10 1 mg/L E353.2 06/25/2007 12:11 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 06/27/2007 11:10 AM Nitrogen, Kjeldahl, Total < 0.10 1 mg/L E351.2 06/28/2007 1:47 PM Qualifiers: E -Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 38 of 40 Laboratory Manager 1H"Ug 'IVIG. 575 Broad Hollow Road, Melville NY 11747 (631)694,9040.FAK(631)4208436 WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-01 OC Type : Field Blank Attn To Original Origin: Client ID. : FB 061407 Collected 6/14/07 12:00:00 PM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Hardness (As CaCO3) < 5.0 1 mg/L E130.2 1 06/28/2007 1:39 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilufion Factor Date Reported: Page 39 of 40 Laboratory Manager 1--12M "USS IMC® 575 Broad Fldbw Road, Metvie W 11747 (631)6943W.FAX(631)4W8436 WSDOHID#10478 Town of Southold Landfill Attn To Original Collected 6/14/07 12:00:00 PM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original cc LABORATORY RESULTS Sample Information... Lab No. : 0706952-010E Type: Field Blank Client ID. : FB 061407 Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Total Organic Carbon < 1.0 1 mg/L SW9060 06/22/2007 12:40 AM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reporied Page 40 of 40 Laboratory Manager II2A U%s INV© 575 Broad Hd1ow Road, Mdvile NY 11747 (631) 694,3040. FAX -(631)420-8436 WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. 0706986-001 A Type: Aqueous Origin: Attn To Original Client ID. : MWAD Collected 6/15/0711:15:00 AM Received 6/15/07 1:53:00 PM Collected By: Client Copy : Original cc Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 31.3 2 mg/L E310.1 06/22/2007 3:25 PM Chloride 23.0 1 mg/L E300.0 06/22/2007 8:01 PM Sulfate 62.7 5 mg/L E300.0 06/22/2007 11:41 PM Bromide < 0.5 1 ` mg/L E300.0 06/22/2007 8:01 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/15/2007 4:00 PM Total Dissolved Solids 176 1 mg/L E160.1 06/19/2007 12:28 PM Qualifiers: E -Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 6/29/07 Page 1 of 16 Laboratory Manager M d' O O 575 Broad Hdlwu Road, MdAle NY 11747 (631) 6943040.FAX (631)420$4W NYSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706986-001 B Attn To : Original Collected 6/15/07 11:15:00 AM Received 6/15/07 1:53:00 PM Collected By: Client COPY : Original CC Parameter(s) Chemical Oxygen Demand Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Nitrogen, Kjeldahl, Total Client ID. : MW -1D Results Qualifier D.F.. Units <10 1 mg/L 0.21 1 mg/L 2.88 5 mg/L < 5.0 1 pg/L 0.76 1 mg/L Qualifiers: E - Value above quantitation range 0 - Results for Dilution D.F. = Dilution Factor Date Reported: 6/29/07 Page 2 of 16 Sample Information... Type: Aqueous Origin: Method Number Analyzed E410.4 06/26/2007 1:14 PM E350.1 06/28/20071:39 PM E353.2 06/25/2007 12:12 PM E420.1 06/27/2007 11:20 AM E351.2 06/26/2007 1:40 PM Laboratory Manager 575 Broad How Road, Mdrle W 11747 (631)694-3040.FAX(631)4M6436 WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706986-001 C Type: Aqueous Attn To Original Origin: Client ID. : MW -1D Collected 6115/07 11:15:00 AM Received 6/15107 1:53:00 PM Collected By : Client Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Hardness (As CaCO3) 85.0 5 mg/L E130.2 06/28/2007 1:42 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 6/29/07 Page 3 of 16 Laboratory Manager 575 Broad Mow Road, Mdv7e IVY 11747 (631) 6943040.FAX- (631)4208436 WSDOH ID # 10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706986-001 E Type: Aqueous Origin: Attn To Original Client ID. : MW -1D Collected 6115/07 11:15:00 AM Received 6115107 1:53:00 PM Collected By: Client Copy : Original cc Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Total Organic Carbon 1.2 1 mg/L SW9060 06/22/2007 1:11 AM Qualifiers: E - Value above quantitation range - D - Results for Dilution D.F. = Dilution Factor Date Reported: .6/29/07 Page 4 of 16 Laboratory Manager 575 Broad Hollow Road, Mdvile NY 11747 (631)6943040. FAX -(631)4205436 NYSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706986-002A Type: Aqueous Origin: Attn To : Original Client ID. : MWAS Collected 6/15/07 12:00:00 PM Received 6/15/07 1:53:00 PM Collected By: Client Copy : Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 9.6 1 mg/L E310.1 06/22/2007 3:30 PM Chloride 86.0 5 mg/L E300.0' 06/22/200711:56 PM Sulfate 27.5 1 mg/L E300,0 06/22/2007 8:15 PM Bromide < 0.5 1 mg/L E300.0 06/22/2007 8:15 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/15/2007 4:10 PM Total Dissolved Solids 202 1 mg/L E160.1 06/19/200712:30 PM Qualifiers: E - Value above quantitation range I D - Results for Dilution D.F. = Dilution Factor Date Reported 6/29/07 Page 5 of 16 Laboratory Manager INCe o 575 Broad Wow Road, Melville NY 11747 (631)694-3M.FAX (631)42OZ436 NYSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold' Landfill Lab No. 0706986-0028 Type: Aqueous Origin: Attn To : Original Client ID. : MW -1S Collected 6/15/07 12:00:00 PM Received 6/15/07 1:53:00 PM Collected By: Client Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Chemical Oxygen Demand <10 1 mg/L E410.4 06/26/2007 1:15 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L- E350.1 06/28/2007 1:40 PM Nitrate as N 5.20 10 mg/L E353.2 06/25/2007 12:16 PM Phenolics, Total Recoverable < 5.0 1 lig/L E420.1 06/27/2007 11:30 AM Nitrogen, Kjeldahl, Total 0.53 1 mg/L E351.2 06/26/2007 1:40 PM Qualifiers: E - Value above quantitation. range D - Results for Dilution D.F. = Dilution Factor Date Reported : 6/29/07 Page 6 of 16 Laboratory Manager 575 Broad Hollow Road, Melvile W 11747 (631)694.9040. FAX -(631)420$436 WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706986-002C Type: Aqueous ' Attn To Original Origin: Client ID. MWAS Collected 6115/07 12:00:00 PM Received 6/15/07 1:53:00 PM Collected By: Client Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Hardness (As CaCO3) 50.0 5 mg/L E130.2 06/28/2007 1:45 PM Qualifiers: E- Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported: 6/29/07 Page 7of16 Laboratory Manager U2A tAu%y INCO 575 Broad Hollow Road, Mdvie W 11747 (631) 6943040. FAX (631)420$435WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706986-002E Type: Aqueous Origin: Attn To Original Client ID. : MW -1S Collected 6115/07 12:00:00 PM Received 6115/07 1:53:00 PM Collected By: Client Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Total Organic Carbon 1.4 1 mg/L SW9060 06/22/20071:42 AM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 6/29/07 Page 8 of 16 Laboratory Manager ® 2AA USs ,NCe 575 Broad Hallow Road, Mdvie NY 11747 (631)6943040. FAX (631)420&136 WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706986-003A Type: Aqueous I Origin: Attn To Original Client ID. : MW -3D Collected 6/15/07 9:00:00 AM Received 6/15/07 1:53:00 PM Collected By: Client copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 948 20 mg/L E310.1 06/22/2007 3:35 PM Chloride 241 20 mg/L E300.0 06/27/2007 8:55 PM Sulfate 39.0 1 mg/L E300.0 06/22/2007 8:28 PM Bromide 0.7 1 mg/L E300.0 06/22/2007 8:28 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/15/2007 4:15 PM Total Dissolved Solids 1020 4 mg/L E160.1 06/19/2007 12:32 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 6/29/07 Page 9 of 16 Laboratory Manager U -i 0__/ US43 INC, 575 Broad Hdiory Road, Mtdvile NY 11747 (631)694,0 .FAX(631)4208436WSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706986-003B Attn To Original Collected 6/15/07 9:00:00 AM Received 6/15/07 1:53:00 PM Collected By: Client Copy : Original CC Parameter(s) Chemical Oxygen Demand Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Nitrogen, Kjeldahl, Total Client ID. : MW -3D Results Qualifier D.F.. Units 119 1 mg/L 110 20 mg/L < 0.10 1 mg/L 9.5 1 pg/L 128 50 mg/L Qualifiers: E -Value above quantitation range D -Results for Dilution D.F. = Dilution Factor Date Reported: 6/29/07 Page 10 of 16 Sample Information... Type: Aqueous Origin: Method Number Analyzed E410.4 06/26/2007 1:16 PM E350.1 06/28/2007 1:41 PM E353.2 06/25/2007 12:17 PM E420.1 06/27/2007 11:40 AM E351.2 06/26/2007 1:41 PM Laboratory Manager U2A TAUS, INC, 575 Goad Hollow Road, Mdvk NY 11747 (631)694.3040. FAX(631)4205436 NYSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706986-003C Type: Aqueous Origin: Attn To Original Client ID. : MW -31) Collected 6/15/07 9:00:00 AM Received 6115/07 1:53:00 PM Collected By: Client copy : Original cc Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Hardness (As CaCO3) 170 10 mg/L E130.2 06/28/2007 1:48 PM Qualifiers: E -Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 6/29/07 Page 11 of 16 Laboratory Manager 1-I "U%s INC, 575 Broad Hollow Road, Mdvie NY 11747 (631) 6943040.FAX (631)42OZ436 NYSDOH ID # 10478 Town of Southold Landfill Attn To Original LABORATORY RESULTS Lab No. : 0706986-003E Client ID. : MW -3D Sample Information... Type: Aqueous Origin: Collected 6/15/07 9:00:00 AM Received 6115107 1:53:00 PM Collected By : Client Copy : Original cc Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Total Organic Carbon 37.6 1 mg/L SW9060 06/22/2007 2:12 AM Nt O O Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor e O sA Date Reported : 6/29/07 Laboratory Manager Page 12 of 16 U2/4 US, INCe 575 Broad Hollow Road, Mdvile NY 11747 (631)6943040. FAX:(631)42M436 NYSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706986-004A Attn To Original Collected 6115/07 9:45:00 AM Received 6/15107 1:53:00 PM Collected By: Client Copy : Original cc Parameter(s) Alkalinity, Total (As CaCO3) Chloride Sulfate Bromide Biochemical Oxygen Demand Total Dissolved Solids Client ID. : MW -3S Results Qualifier D.F.. Units 316 10 mg/L 82.2 5 mg/L 43.2 1 mg/L < 0.5 1 mg/L < 4 1 mg/L 458 2 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F_ = Dilution Factor Date Reported: 6/29/07 Page 13 of 16 Sample Information... Type: Aqueous Origin: Method Number Analyzed E310.1 06/22/2007 3:40 PM E300.0 06/23/2007 12:11 AM E300.0 06/22/2007 8:42 PM E300.0 06/22/2007 8:42 PM E405.1 06/15/2007 4:17 PM E160.1 06/19/2007 12:34 PM Q/ JR �t�i�rsi+ Laboratory Manager 575 Broad Hollow Road, Mdvile NY 11747 (631) 694,3040. FAX -(631)420Z436 NYSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706986-004B Type: Aqueous Origin: Attn To : Original Client ID. MW -3S Collected 6/15/07 9:45:00 AM Received 6/15/07 1:53:00 PM Collected By : Client Copy : Original cc Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Chemical Oxygen Demand 68.7 1 mg/L E410.4 06/26/20071:17 PM Nitrogen, Ammonia (As N) 17.4 10 mg/L E350.1 06/28/2007 1:43 PM Nitrate as N < 0.10 1 mg1L E353.2 06/25/2007 12:18 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 06/27/2007 11:50 AM Nitrogen, Kjeldahl, Total 21.0 10 mg/L E351.2 06/26/2007 1:43 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 6/29/07 Page 14 of 16 910 /i Laboratory Manager 575 Broad How Road, Mdvile NY 11747 (631)694.3040. FAX(631)42GB436 NYSDOH ID# 10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706986-0040 Type: Aqueous Origin: Attn To Original Client ID. : MW -3S Collected 6/15107 9:45:00 AM Received 6115/07 1:53:00 PM Collected By: Client Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Hardness (As CaCO3) 280 10 mg/L E130.2 06/28/2007 1:51 PM Qualifiers: E - Value above quantitation range 0 - Results for Dilution D -F. = Dilution Factor Date Reported: 6/29/07 Page 15 of 16 Laboratory Manager 1HU%s INCe 575 Broad Follow Road, Mdvie NY 11747 (631)694,' .FAX(631)4268436 NYSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706986-004E Attn To Original Client ID. : MW -3S Collected 6/15/07 9:45:00 AM Received 6/15/07 1:53:00 PM Collected By: Client Copy : Original CC Sample Information... Type: Aqueous Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Total Organic Carbon 14.6 1 mg/L SW9060 06/22/2007 2:42 AM Qualifiers: E - Value above quantitation range D -Results for Dilution D.F. = Dilution Factor Date Reported: 6/29/07 Laboratory Manager Page 16 of 16 00 O O I4 H2M LABS, INC. II. Q.C. SUMMARY H2M LABS, INC. SDG: TSLO10 Date: 29 -Ju» -07 QC SUMMARY REPORT Spike Sample Recovery RPDRef %RPD Sample-ID_Client Sample ID:Analvte Result _ ^ Units Amount Result %REC Limits Value %RPD UCL MB -062207 -_ MB -062207--- Alkalinity, Total (As CaCO3) < 1 _ _ �- LCS-062207 LCS-062207 Alkalinity, Total (As CaCO3) 25.8 mg/L 25 < 1 103 80 120 I�- MB-062007 - ---- -- LCS-062007 MB -062007 -- -- LCS-062007 Alkalinity, Total (As CaCO3) < I mg1L- i jAlkalinity, Total (As CaCO3) 22.0—_I mglL 25 < 1 + 88 80 120 3-- 12 r 101 75 125 ----r-•. -_- 0706952-004ams TV=25 0706952l004adu - --BMW-51DDUP MW-501VIS Alkalinity, Total (As CaCO3) 563 mg1L Alkalinity, Total (As CaCO3) 250 I 312 1.1 20 MB -061507 LCS-0_61507 0706952-004ADUP MB -061507 LCS-061507 MWy5DDUP Biochemical Oxygen Demand <2 mglL Biochemical Oxygen Demand 216 mg/L 200 _<_2 108 80 120 Biochemical Oxygen Demand <2 mglL < 2 20 --- - - --- - - (MB -062707 MB -062707< Bromide 0.5 mg1L --- - -- - -- - -T -- -i ILCS-062707 ILCS-062707 Bromide 2.5 - mg1L 2.5 ,-< 0_5 L 100 90 110 ---� - - MB -062607 MB -062607 `L_CS-062607 - ILCS-062607 ._------- MB -062207-- --- Bromide -- --- <0.5 _mg1L - 1000 <10 LCS-062207_ TLCS-062207 -- - Bromide 2.7 mg1L 2.5 < 0.5 108 90 110 I 07069----..-.._____.- II 52 004BMS MW-5DMS - 0706952-004AMS MW-5DMS Bromide - 1.6 mgll 1 0.7 88 75 125 102 -99 0706952-004ADUP MW-5DDUP - Bromide - -_ ---- -0_6 - mglL 0.7 13.7 20 --- - - --- - - (MB -062707 MB -062707< Bromide 0.5 mg1L --- - -- - -- - -T -- -i ILCS-062707 ILCS-062707 Bromide 2.5 - mg1L 2.5 ,-< 0_5 L 100 90 110 ---� - - MB -062607 MB -062607 `L_CS-062607 - ILCS-062607 ._------- Chemical Oxygen Demand <10 ;g/L Chemical Oxygen Demand - 1010 mg1L -- - -- 1000 <10 -101 80 75 1120 125 I 07069----..-.._____.- II 52 004BMS MW-5DMS - Chemical Oxygen Demand - -- 1090 -�- mg/L 1000 102 -99 _^ -_ 102 2.9-� 20 `0706952-004BDUP ---�MW-5DDUP - - Chemical Oxygen Demand- 99.1 mglL -- I TSLO10 W60 QC SUMMAR17 REPORT SDG: TSLO10 Spike Sample Recovery RPDRef %RPD _Sample.IDSClient_Samnle ID: Anal Result Units Amount Result %REG Limits Value %RPD UCL MB -062107 _ MB -062107 Total Organic Carbon �I <1 mg/L _-i— — LCS-062107 LCS-062107 _ Total Organic Carbon ; 28.6 mg1L 25 < 1 j 114 180 120 _ 0706952-004EMS _ MW-5DMS Total Organic Carbon ; 38.8 mgIL 10 26.7 121 75 125 0706952-004EDUP MW-5DDUP Total Organic Carbon _ 27.5 _ mg/L 1 —_I 26.7 3.0 20 TSLO10 W61 H2M LABS, INC.. III. RAW DATA CODES FOR MANUAL CORRECTIONS T: Transcription error. CC: Calculation error CC: Changed per client request SC. Sample cancelled LB: Wrong spot in logbook The following codes are specific to chrorratography: GC / XC: MS (Match standard): The integration of the continuous calibration or the sample was different from that used for the initial calibration, e.g. more or less of the tail was included: BL (Baseline): Incorrect integration due to changing baseline (rise or fall)_ NP (Negative peak): Due to a negative displacement in the baseline, wrong areas were integrated, which usually are too high_ FP (Fused peak): A contamination is not resolved from the peak that is eluting in the retenr,en time window and is included :^ dhe'area. Areas are allocated for. the Wro (or more) unresolved peaks in the manual integration. WB (Wrong basepoint).: The start or finish of the peak (" basepoinC) was put too high or too low, and the basepoint is corrected to match to projected baseline. R'(Rider): The peak is riding on a larger.contamination, and is reintegrated as a rider. GC -MS: MT: Missed peak MR'- Misintegrated peak WI• Wrong isomer TI: Total of isomers O ez - iq-- �{c� - OV hsA00 Pos Analysts Ident Amount Date initial pN mis at 4.5 End ymis at ' TALK °� �tlo (m1) value 4 2 low recovery n FI 1 TALK low LCS-062007 100 6/20/2007 9.31 229 4.15 0.10 21.95 87.8 IV- M 12:32:26 PM 2 TALK low M 6200 100 6/20/2007 5.34 0.09 4.18 0.06 0.30 12:46:14 PM 3 TALK low 0706913-001f 10 6/20/2007 5.67 1.31 4.18 0.12 119.00 W , l 12:49:43 PM 4 TALK low 0706913-002f 10 6/20/2007 5.98 1.96 4.17 0.15 181.00 -1, 12:56:13 PM 5 TALK low 0706913-003f 10 6/20/2007 5.92 1.23 4.15 0.15 108.00 79- 1:03:12 PM 6 TALK low 0706913-004f 10 6/20/2007 5.91 1.24 4.17 0.13 111.50 aX 1:10:19 PM 7 TALK low 0706913-005f 100 6/20/2007 6;54 5.80 4.15 0.23 55.70 1:17:50 PM 8 TALK low 0706913-005fMS 100 6/20/2007 8:,59 8.20 4.18 0.23 79.75 95.2 TV=25PPM fFW 31i 1:27:03 PM 9 TALK low 0706913-005fDUP 100 6/20/2007 6:83 5.82 4.14 023 55.95 RPD=0.4 1:39:21 PM 10 TALK low 0706913-006f 20 6/20/2007 636 1.75 4.17 0.17 79,25 1:49:07 PM 11 TALK low 0 13-00 25 6/20/2007 6.39 2.32 4.17 0.18 85.60 1:57:06 PM 12 TALK low0 913-0� wf7� 5 6/20/2007 6.16 1.26 4.17 0.17 218.00 l YI> 2:05:08 PM I 13 TALK !ow ccv 100 6/20/2007 9.61 2.55 4.17 0.15 24.05 96.2 �l ✓ 2:11:46 PM 14 TALK low ccb 100 6/20/2007 5.454.17 0.12 -0.05 2:24:16 PM 15 TALK low 070 913-009f pfW -q-5 1 6/20/2007 8.77 0.58 4.15 0.15 435.00 2:28:15 PM 16 TALK low 07 13-010f 5 6/20/2007 6.26 4.23 4.16 0.22 802.00 S 2:36:07 PM 17 TALK low 0706913-0111' , 25 6/20/2007 7.53 2.05 4.19 0.32 69.40 r. 2:43:12 PM 18 TALK low 0 06 3-012f 10 6/20/2007 6.1;3 1.59 0.21 138.60- 3:02:07 PM 10. 19 TALK low 0 13-013f -�3 10 6/20/2007 6.19 1.71 E4.16 1 150.00 3:09:07 PM 20 TALK low 0706913-014f 5 6/20/2007 6.37 1.92 4.18 0.18 349.00 3:16:11 PM 21 TALK low 0706913-017f _ 25 6/20/2007 6.33 2.400.19 88.40 3:23:57 PM 22 TALK low 070 91 01� 10 6/20/2007 6.23 1.54 4.16 0.19 135.00 j 3:31:29 PM 23 TALK low 0706913-019f 10 6/20/2007 6.22 1.27 4.18 0.15 112.00 � - 3:39:03 PM 24 TALK low 0706913-020f 10 6/20/2007 6.26 1.30 4.19 0.17 113.00 �!J 4 3:46:10 PM 25 TALK low 070691,3-021f 100 6/20/2007 5.71, 0.15 4.16 0.16 -0.10 3:53:18 PM 26 TALK low 0706913-022f, 100 6/20/2007 5.54 0.17 4.16 0.18 -0.10 �- 3:57:38 PM 27 TALK low ccv ✓- 2rr 100 6/20/2007 9.63 2.60 4.17 0.17 24.30 97.2 ✓b 4:02:01 PM 28 TALK low ccb 100 6/20/2007 5.75 0.15 4.160.05 4:13:53 PM 29 TALK tow 07069`52- 01a 100 - 6/20/2007 6.33 3.34 4.14 0.25 30.95 VV 4:18:18 PM 30 TALK I low 06952-Q0 a t 6/20/2007 1.22 14.18 9.95 0.23 1100 4:26:05 15.57 PM 31 TALK L9 low 07O952-OQ 5 6/20/2007 6.65 4.62 `4.17 0.24 4:31:10 PM I (876.00 O UO 32 TALK low 070695,2-0�a 10 6/20/2007 6.24 3.33 4.18 0.22 311.50 �� 4:38:34 PM 33 TALK low 0706952-004ams TV=250 10 6/20/2007 6.61 5.86 4.17 0.23 563.00 92.6 PPM 4:45:20 PM 34 TALK low 0706952-004adup 10 6/20/2007 6.27 3.40 4.14 0.25 315.00 RPD=1.0 AAW 4:53:39 PM 35 TALK low reference sample TV=64.3 100 6/20/2007 7.93 6.40 4.16 0.27 61.35 5:00:44 PM 36 TALK low 0706803-004a 100 6/20/2007 7.33 8.41 4.18 0.25 81.65 5:11:50 PM 37 TALK low 0706803-004aMS 100 6/20/2007 8.76 11.00 4.16 0.32 106.85 100.8 TV=25PPM 5:21:52 PM 38 TALK low 0706803-004aDUP 100 6/20/2007 7.35 8.57 4.16 0.30 82.70 RPD--I.3 5:34:59 PM 39 TALK low ccv 100 6/20/2007 9.77 2.62 4.13 0.21 24.10 96.4 �Si1F�r>1 5:45:34 PM 40 TALK low ccb 100 6/20/2007 5.48 0.15 4.17 0.17 -020 5:57:58 PM 99AkOTOISI TALK low is LG 062207 1`OQ k 6/22/2007 9 85 2.73-1 .3 0.15 25.80 1,03.2 AM ll ffilti , Lw GOQrf Y "s? IN 4 "W", ON R ""R"i M-� TALK ow*:' 0.1 -6.00-7 6/22/90OT" 1.50 0.18 13.2 AM 2. P m elg m 6 2 tilt, 5 . TALK low 69-001:a a -.Ifo01.;,.,,-. - W22/2 -007. 7,03: 6.64 411� 0.21 64.30 8 Ww" "MIN N 0707069 7 M 'R 1 612-21200V': '0 :orf r TALKW 6.3'1 4:15 0.23 60.85 4, RUN m % OEM$0 23k !7, RON 0707069'4 05 7 '15:- 5.63 tl 4:1:6" 0*..20 54.30 P *DJ W700 MRX� W ,ryii u� 69x !1aP',2410' "M , 100 5/22/2007 720 5.63 4:16 0.21 11 T;A, E K, 16W'�- �,., ��, . ." �; 64.20 w 02:AM� -T54 mop- - 13 C IoW cev TV=25MG 2.60 1.20..' 3, -.10: 25.00 100 57 4'd tixz .2,1 .4, �ggg gl� q n 'GG3a 100 '0.1-9 53.60 Q�212007: -7.27 5.55 1, 2.,� 29 41 'PM RMW 51M 0' N `2 -3,51 4" 1T TALC<!nw 0707075 QG5i 5:31 4.1'5.- 0.20 51.10 Km -77, llyN IM "MIN gy 'go u gugg, 'Aw t, 6 .6 L9MA 4. 1'7 0 2 .. . . . . . . . . . . SAL Oo 7 'l 0ti INIO 97 P- 1,00 M2212GOT 6 45'... 4.99= 4 18 0:20 47M rpd-2.86 �-,rdw f mg 02a' '612. . I '20'OT"�':­ 2Y 8 �QMJOZ 4 -NN', 8Q375g 2'V' 017 29,45 'Ic'M Tv�25MWL I ,25 TALK 63` 4.l 7" 0.13 25.05 0.2 Ile i A A "o MR. o"', .22 2007, '21 02, — 92 4.18—.%* 0.14 10.65 211 18 PM t R %w9d "AR P,11- W.,, 'ol 1 o 6/2,2/2007- 7;42 8:32 419 0.23 80.95 2 29 50 PM Ar' TALEC ibw 0706952 00'5a 5016/2212607 31 ` 5 57 2 4116 3.23 41.00 OUR# 300, 11,11 IS P,214 M 18 F MYN 07()OM OQ7a' 50 6122/2007 :6Tl `07 33 TALK low 2.24 4.17 0.19 11.00 P Ab 1W 'A' apzp� 4 MW. f TALK-towTq-1, 17069'5Z' ,: 3'09 4.1 .5 320 289.50 38t .6 22=07 . 8: 44 : d-IMVF -5 Z R pq- 36 IYAN �gq III 'EO4 ggp'� owgvm Rg gg imp - Q17, ,--I� vim 89A A, 0 10-1 37,{ TALiCwlo°w 0.5 27.85 111.4 oz " Tv 'KI m 1.72 6,.,39 4.' 0.16 31.30 N U6�, —10� ',W,ON aOw4 0700986 003a 5 612210 7' 7; 4.19'.. . 0.17 948.00 5MG/L. 4.18 oi 15 29.00 116 YA ldll,,�� g morm kuy",-UND R& 14 WON '10 0?v m "" It MiAl 4 001""t "M KW- GU #Aw Aq OAW-u$ W dti MW -SS F& 611K1�-, t-.tw - IS LLA,w ^3*0 JAW -35 KW- Slo hw-yA ,mow-ys P11a-�t� s Author: cmo Vey-..- 1-12M Labs. Inc. TTS L,oI,o Original Run Filename: OM_6-22-2007_03-51-28PM.OMN created 6/22/2007 3:51:28 PM Original Run Author's Signature: [cmo] Current Run Filename: anions062207.omn last modified 6/23/2007 7:17:01 AM Current Run Author's Signature: [cmo] Description: Default New Run Run: anions062207 TSL010 W69 -1 - Date : 6/23/2007 P_„n nsu"Sc�,l werC� t. � ,x !7.7`1 p,/.c!'Ce:. t.� 4-(. ktzp 2u•�ti Gl '� f�`� � �t MT P 1u�ti e1 + .R.�.,- Soy c�,cr �(• . rs & r l wu- C- k. M P ✓n. <1• 1-.v' G.1- 4enl L( lu-& C.\ wv- C,1. IC Channell Sample p Cup No. Bromide Chloride Sulfate Conc. Area Conc. Area Conc. Area ADF MDF m /L Vs m /L Vs m /L s "LCS-062207:LCS:Anion300 WW" 1 2.738 0.218 10.640 3.006 •9.9891 2.073 Known Conc: 2.500 [_109/. 10.000 /ot.Y. 10.000 0)"t "ICB-062207:ICB:anion300 ww" T 2 0.007 0.000 0.139 0.023 -0.016 0.002 Known Conc: 0.000 e.5, 0.000 0.000 LS.� "Ifb-062207:Ifb:anion300 ww" 3 1.038 0.082 10.913 -1-1L10 3.087 10.313 2.142 Known Conc: 1.000 WLA1. 10.000 oq•( 10.000 10'r. "MB-062207:MBLK:anion300 ww" 4 0.007 0.000 0.132 0.020 -0.027 -0.000 Known Conc: 0.000 1,0. 5, 0.000 L2.11 0.000 L .0 "0706952-001A.-SAMP:ANION300 WW" 5 0.132 0.010 42.198 13.707 89.539 28.747 "0106952-002A.SAMP-ANION300 WW" 6 0.166 0.0131 35.151 11.013 84.411 25.302 "0706952-003A:SAMP:ANION300 WW" 7 2.012 0.160 -54.758 -13.081 80.933 23.404 "0706952-004A:SAMP:ANION300 WW" 8 : Go 0.717 0.057 14 (� -56.81--3--13.513 1 N l0 57.723 14.272 "0706952-004AMS:MS:ANION300 WW" 9 ( '1.1.575 0.125 43.777 14.345 C 65.470 16.888 _ "0706952-004ADUP:DUP:ANION300 W" 10 W DYi'0.625 0.049 42.093 13.665 57.742 14.278 Calibration: Table/ i . 1 Table/F!2 "0706952-005A:SAMP:ANION300 WW 11 0.277 0.022. 23.506 6.991 34.805 7.806 Calibration: Table/Fig. 3 "0706952-006A:SAMP:ANION300 WW 12 0.127 0.010 42.296 13.746 89.535 28.744 "0706952-007A:SAMP:ANION300 WW" 13 0.007 0.0001 5.663 1.566 12.398 2.590 "0706952-008A:SAMP:ANION300 WIM' 14 0.709 0.0561 2.009 0.539 80.238 23.053 "CCV:CCV:anion300 ww" I S4 1.029 0.082 10.996 3.111 10.374 2.155 Known Conc: 1.000 Io -Sy. 1 10,000 11•7Y• 10.000 toy( "CCB:CCB:anion300 ww" S8 0.007 0.000 0.028 -0.008 0.001 0.006 Known Conc: 0.000 ocb 0.000 LZ•� 0.000 0 "0706952-009A:SAMP:ANION300 WW" 15 0.262 0.020 ----:1'40 082 -28.897 33.746 7.540 __ "0706952-010A:SAM P:ANION300 WW" 16 0.007 0.000 0.024 -0.009 -0.004 0.005 "0706986-001A:SAMP:ANION300 WW" 17 0.074 0.005 22.974 6.817 62.259 15.767 "0706986-002A:SAMP:ANION300 WW" 18 0.110 0.008 71.518 --f9 6-51 27.497 6.013 "0706986-003A:SAMP:ANION300 WW" 19 0.703 0.056 20.345 5.973 39.026 8.891 "0706986-004A:SAMP:ANION300 WW" 20 0.316 0.025 -151.361 -30.737 43.217 10.009 "0706952-001A:SAMP:ANION300 WW" 5 0.140 0.002 39.547 2.2101 108.035 4.637 5.00 "0706952-002A:SAMP:ANION300 WW" 6 0.188 0.002 36.136 2.013 96.462 4.111 5.00. ...:0706952-003A:SAMP:ANION300 WW" 7 2.480 0.039 333.509 26.019 91.026 3.866 5.00 "0706952-004A:SAMP.-ANION300 WW" 8 1.285 0.020J-- a 344.353 27.553 -60 57.493 2.396 5.00 "CCV:CCV.anion300 ww" S4 1.067 0.085 11.072 3.134 10.374 2.156 Known Conc: 1.000 (071. 10.000 iit11, 10.000 (, "CCB:CCB:anion300 ww" S8 0.007 -0.000 0.028 -0.008 -0.027 0.000 Known Conc: 0.000 Go.S 0.000 �• a 0.000 "0706952-004AMS:MS:ANION300 WW" 9 2.155 0.034 < 348.7121 28.2131 67.240 1 ,o 2.817 5.00 Run: anions062207 TSL010 W69 -1 - Date : 6/23/2007 P_„n nsu"Sc�,l werC� t. � ,x !7.7`1 p,/.c!'Ce:. t.� 4-(. ktzp 2u•�ti Gl '� f�`� � �t MT P 1u�ti e1 + .R.�.,- Soy c�,cr �(• . rs & r l wu- C- k. M P ✓n. <1• 1-.v' G.1- 4enl L( lu-& C.\ wv- C,1. IC �tw-6D taw -0 a�w-$5 Mw-c� dt'1W-�S +tc�-3S Author: cmo H2M Labs. Inc. "0706952-004ADUP:DUP:ANION300 WW 10 1.306 0.020 1 342.452 27.274 57.404 2.392 5.00 First Order "0706952-006A:SAMP:ANION300 WW' 7'0706952-008A:SAMP:ANION300 12 0.173 0.002 39.996 2.236 109.352 4.697 5.00 False WW' 14 0.822 0.013 138.586 8.392 89.357 3.792 5.00 110 "0706952-009A:SAMP:ANION300 WW' 15 0.379 0.005 58.859 3.341 31.644 1.302 5.00 Direct/Bi olar "0706986-001 A:SANIP:ANION300 WW' 17 0.085 0.001 20.351 1.115 62.709 2.621 5.00 31 "0706986-002A:SAMP:ANION300 WW' 18 0.113 0.001 86.000 4.987 25.489 1.047 5.00 "0706986-004A:SAMP:ANION300 WW" 20 0.349 0.005 82.217 4.753 41.562 1.718 5.00 "CCV:CCV:anion300 ww" S4 1.019 0.081 11.090 3.139 10.313 2.142 Known Conc: 1.000 (02•(. 10.000 iwt 10.000 LST(, "CCB:CCB:anion300 ww" S8 0.010 0.000 0.020 -0.010 0.001 0.006 Known Conc: 0.000 Lo.S 1 0.000 ft.o .0.000 Analyte Properties Table for anions062207.omn Property Channel Bromide Chloride Sulfate Concentration Units m /L mg/L m /L Callibration Fit Type First Order Second Order Second Order Clear Calibration True True True Force Throu h Zero False False False Calibration Weighting 1& 1/x 1/x Auto Dilution Trigger True True True % of Hi2h Standard 110 110 110 Quik Chem Method - lD-510-00-1-A 10-510-00-1-A 10-51.0-00-1-A Chemistry DirectlBi olar Direct/Bipolar Direct/Bi olar Calibration b Height False False. False Inject to Peak Start 260 146 450 Peak Base Width 31 45 187 Run: anions062207 TSLO10 W70 -2- Date : 6/23/2007 Ic Author: cmo H2M Labs. Inc. Date : 6/23/2007 Force Through Zero Falser False False Calibration Weighting_1/x { 1/x 1/x Auto Dilution Trigger True True V True % of High Standard 110 I 1101 110 Quik Chem Method 10-510-00-1-A 10-510-00-1-A ( 10-510-00 1 A i Chemist Direct/Bipolar Direct/Bi olar, Direct/Bi olar Calibration by Height False False i False Inject to Peak Start 260 1461 450 Peak Base Width 31 451 187 Channel 1 (Anions) : "LCS-062207:LCS:Anion300_WW' [Row 1] 5.724 v o Z Z m L N U - E m N a 0 10.6462 ig/L m z ii in 2.820 mg/L 15.397 mg/L 2.738 - -- -----•------9– 9-8-9 _m_..g._/.._Lmc2 =70 mg/L 2.708 m /L 0.189 -_ _ _. ............ 1.7 1.7 Time (min) 12.2 Run: anions062207 -2- is Author: cmo H2M Labs. Inc. Channel 1 (Anions) : "ICB-062207:ICB:anion300_ww" [Row 2] 5.724 (1) Q) z -p D O `o `o _ E 2 UL U Z m 0.118 mg/ 0.139 0.020 mg/L0.007 mg/L 0.189__.._.-__._._...__.,.._. .... .._._.._.._....__._.-.............. .....__.____..___._._... ... ..... ______...._-__..__..__.... —. 15.2 Time (min) Channel 1 (Anions) : "lfb-062207:lfb:anion300 ww" [Row 3] 5.724- 0.189 .724- 0.189= v 28.8 Date : 6/23/2007 a z m � a m ro o .° z a CO 01-0.069 mg/L -0.016 mg/L 25.7 -o m N O Z z IU •O (i w E � to 10.91EZig/L 2 M z a_ 1.121 mg/L J5.497 mg/L 1,038 mg1.074 mg/L 1.077 mg/L 10.313 mg/L Time (min) 39,2 Run: anions062207 - 3 - IC Author: cmo H2M Labs. Inc. Channel 1 (Anions) : "MB-062207:MBLK:anion300_ww" [Row 4] 5.724 0 0.189 42.3 m m z m v -o p o .o E =3t — 2 FL U 2 m 0.00. 132 r0.021 mg/1-0.007 mg/L Time (min) Channel 1 (Anions) : "0706952-001A:SAMP:ANION300_WW" [Row 5] 5.724 -< Date : 6/23/2007 o_ a� Z io l r- _ a) CO o m 4- z 0- fn 0.(-0.067 mg/L -0.027 52.8 N O N 'D O t N U m 42.198 mg/L z o u� 89.539 mg/L v Z -o is s a� a. o _ o Z m U- z m` 5.526 mg/L n=. g/L00.074 mg/L 0.209 mg/L 0.132 mg/L.-0.089 mg/LA.- 0. 189 .189 --_------------ --------_.-._�--_------ -- 55.8 Time (min) 66.3 Run: anions062207 -4- Ic M O O V) h Author: cmo H2M Labs. Inc. Channel 1 (Anions) : "0706952-002A:SAMP:ANION300 WW" [Row 6] 5.724 0.189 69.4 Channell 5.724 - w 0 Date : 6/23/2007 N .a O r U :? 35.151 mg/L a z a � 16 [14,411 mg/L L-1574 Ezo29.086 mg/LIL 0.166 mg/L_ -0.143 mg/L Time (min) 79.8 (Anions) : "0706952-003A:SAMP:ANION300_W V' [Row 7] a� v o r U -54.758 mg/L 0.189- V 82.9 Run: anions062207 a � Cb z r 80.933 mg/L �o 2 O LL m z Q -0.045 mg/L 2.012 mg/L I -O.t-0.047 mg/Li\\\--- - c]- i Time (min) 93.4 ,3 O O j N -5- Ic Author: cmo 1-12M Labs. Inc. Date : 6/23/2007 Channel 1 (Anions) : "0706952-004A:SAMP:ANION300_WVV' [Row 8] 5.724 -- i r i II . o i t w U -56.813 mg/L I� o_ a� a� m Z _ is COO - o E m w 57.723 mg/L U- Co z a- t \ -0.065 mg/L 0.717 m 0.015 mg/L -0.061 mg/L� 0.189--_._._..._,._._._.__.___..._._._.___..._._......-_--_.....,_..----- .------ ...___....-------- ._..___._.__...._...___---.-.------._----___........._.._ 96.4 Time (min) 106.9 Channell 5.724-- (Anions): .724-- (Anions): "0706952-004AMS:MS:ANION300WW" [Row 9] �I a� v_ `o s U 43.777 mg/L 0.870 mg/L 0.189-1—V 109.9 n. ,m CO C 65.470 mg/L i d .039 mg/L 1.015 mg/L Time (min) 120.4 Run: anions062207 - 6 - IC Author: cmo H2M Labs. Inc. Channel 1 (Anions) : "0706952-004ADUP:DUP:ANION300_WW" [Row 10] 5.724 42 0 0.189 123.5 Time (min) Channel 1 (Anions) : "0706952-005A:SAMP:ANION300 WW" [Row 11] 5.724 137.0 0 v 0 0 Z d? 23.EZi mg/L m `o E z i �I z m` 8.834 mg/L 0.138 mg/L`0.020 mg/L 0.277 mg/L_ Time (min) Date : 6/23/2007 (1) v o U 42.093 mg/L i I / I mg/L 127.5 a CL C 0 o CO ii 34.805 mg/L -0.199 mg/L-- 147.4 Run: anions062207 - 7 - Ic D Author: cmo H2M Labs. Inc. Channel 1 (Anions) : "0706952-006A:SAMP:ANION300_WIM' [Row 12] 5.724 0-189 150.5 Date : 6/23/2007 N 'D .O t O U m 42.296 mg/L a_ U z d, 89.535 mg/L m z m s Z n E 0 o 0 z m` 0.267 mg/L if mg/L,0.200 mg/L 0.127 mg/L`_--0.089 m/L Time (min) 160.9 Channel 1 (Anions) : "0706952-007A:SAMP:ANION300_WW° [Row 13] 5.724 0 a a o Z oo Z t M mCL IU o U _ E `° o L (/� U- 5.663 mg/L z m z ° 12.398 mg/L 0.138 mg/L -0.00.007 mg/L0.510 mg/L -0.047 mg/L—�� 0.189 - ----------- —------- =-- - — ----- --- ------ 164.0 Time (min) 174.5 Run: anions062207 - 8 - IC Author: cmo H2M Labs. Inc. Channel 1 (Anions): "0706952-008A:SAMP:ANION300—WW" (Row 14) 5.724 •+ 0 0.189 177.6 )49 mg/L z �z '8.394 mg/L U 2.009 mg/L Channel 1 (Anions) : "CCV.,CCV:anion300 ww" [Row 15] 5.724 !I Date : 6/23/2007 m CL =3 z co_ 80.238 mg/L :?CL E `° CO o 0 CO Z CL 0.7090.013 mg/L -0.062 mg/L Time (min) 188.0 m CL t7 � N O z Z l9 'DL p L N o Ea m 2 N - LL 10.99Ezig/L 2 s n M Z p 1.146 mg/L J5.552 mg/L 1.029 mc1.082 mg/L 1.096 mg/L 10.374 mg/L 0.189—:-- 191.1 Time (min) 201.5 Run: anions062207 - 9 - IC 00 O ,--a O Author: crno H2M Labs. Inc. Channel I (Anions): "CCB:CCB:anion300_ww" [Row 16] 5.724.. 1 z W 0.118 0.028 mgt0.020 mg/L0.007 mg/L 0.189-7-1- .......... . L . .. ......... I ... . ........ .. -- .. ........... . ..... 204.6 Time (min) Channel 1 (Anions): "0706952-009A:SAMP:ANION300—WW" [Row 17] 5.724-1 Date : 6/2312007 Z CU 75 0 j_- in 0.00',0.055 mg/L — 0.001 TqLL— ...... .. .. . ...... ..... ... 215.1 o z -140.08 ig/L z .020 mg/L Z E 0 0 FL CL 0.167 mg/L tO.262 mg/L 0.(-0.065 m 0.189 218.2 Time (min) 2 33.746 mg/L 228.6 Run: anions062207 -10- IC Author: cmo H2M Labs. Inc. Channel 1 (Anions) : "0706952-010A:SAMRAN ION 300–VVVV" [Row 18] 5.724 0 0 0.189 231.7 a a� a) a) Z v v_ p a m 0 E En =1 FL U z m Z n cq Date : 6123/2007 0.12M.024 mg/L 0.0:0.007 mg/L_0.040 mg/L_-0.067 mg/L-0.004 mg/L Time (min) 242.2 Channel 1 (Anions) : "0706986-001A:SAMP:ANION300–VVVV" [Row 19] 5.724 --- 0 W v o` a� 0 Z N 7 22.97?ng/L ro _ U) 9i a 2 0 62.259 mg/L z Co Z a U 0.191 mg/L_0.020 mg/L 0.074 m3;160 mg/L 0.061 mg/L� 0.189 - _ __------- --- - — ------------- .._..--------_ __—�-.--------- _—; 245.2 Time (min) 255.7 Run: anions062207 -11- IC O 00 O O Author: cmo H21M Labs. Inc. Channel 1 (Anions): "0706986-002A:SAMP:ANION300_WW" [Row 20] 5.724 0.189 258.8 Date : 6/23/2007 m `o .c U 71.518 mg/L 1 a_ z 2 aD Z C - �, a ` E o LL z m` 4.418 m /L 27.497 mg/L 0.249 mg/L, -2.91'0.110 mgt 9 70.089 Time (min) Channel 1 (Anions) : "0706986-003A:SAMP:ANION300_WW° [Row 21] 5.724 z 399.436 mg/L v N •o O t > U 20.345 mg/L i a a> Z io o E m m U t 39.026 mg/L U_ m z a 0.069 mg/L- 0.703 mg0.176 mg/L -0.117 mg/L--_ 0.189 _ —_�— _-- -- ----- ---- - --- — --- ---- — - -- 272.3 Time (min) 269.2 282.8 Run: anions062207 -12- 1C Author: cmo H2M Labs. Inc. Channel 1 (Anions) : "0706986-004A:SAMP:ANION300_WW" [Row 22] 5.724 w 0 0.189 285.8 Date : 6/23/2007 a� o` r U -151.361 mg/L z a� z -327.830 mg/L a m m m N N z -o p _ E m o CO a 43.217 mg/L LL in z 0.194 mg/L 0.316 mg/L 0.006 mg/L-0.106 mg/L�__ Time (min) Channel 1 (Anions) : "0706952-001A:SAMP:ANION300_WW' [Row 23] 5.724 42 0 0.189 —�- 302.7 a� a v t v d) O 0 - E N u 7.909 iZ L 0 m` z .139 mg/L_0.025 mg/L 0.028 mL1.541 mg/L Time (min) n- m m o t m N = o U) s CL 21.607 mg/L -0.124 mg/L_ 296.3 313.2 Run: anions062207 -13. IC N 00 O O i Author: cmo H2M Labs. Inc. Channel 1 (Anions) : "0706952-002A:SAMP:ANION300_WW" [Row 24] 5.724 m 0 0.189 317.7 0 a) v_ CU N O Z N Zr t oU - E m N O FL 7.227 'zj/L 0.131 mg/L_0.032 mg/L 0.038 mO.689 mg/L -0.075 mg/L Time (min) Channel 1 (Anions) : "0706952-003A:SAMP:ANION300—WW° [Row 25] 5.724._.. 0.189----Y 332.7 66.702 mg/L o_ m Date : 6/23/2007 a) CO 19.292 mg/L 328.2 a� Z m Z s M COo _ o a = Z m z a- 18.205 mg/L 0.159 mglL 0.020 mg/L 0.496 mg/L 0.0-0.055 mg/L___./- Time g/L_fTime (min) 343.2 Run: anjons062207 -14- [C M 00 O O C/1 F- Author: cmo H2M Labs. Inc. Channel 1 (Anions) : "0706952-004A:SAMP:ANION300_V"' [Row 261 5.724 Ui 0 0.189 347.7 Date : 6/23/2007 `o L U , 68.871 mg/L �i i a a� ) Z L N _ n_ O E [2 O 7 O z a 11.499 mg/L 0.160 mg/L 0.020 mg/L 0.257 mg/L O.Ot-0.054 mg/L_� Channel 1 (Anions) : "CCV:CCV:anion300_ww" [Row 271 5.724 0.189 361.2 Time (min) 358.1 Time (min) 371.7 Run: anions062207 -15- Ic Author: cmo H2M Labs. Inc. Channel 1 (Anions) : "CCB:CCB:anion300_ww" [Row 28] 5.724 0.189 V 374.8 Date : 6/23/2007 a m a� z z m a o m a a� 0 0 _ E ro N B O o L = t 7 U z m z a U) 7777_0.1 150M8 mg0.021 mg/L_0.007 mg/L 0.0-0.072 mg/L-0.027 mg/L Time (min) 385.2 Channel 1 (Anions) : "0706952-004AMS:MS:ANION300 WW" [Row 29] 5.724 - i a� v w J-- a U > 69.742 mg/L a a� t a� Z al Z m L O _ E O 7 Y 2 t Z m z Q- 0.322 0.322 mg/L�_0.020 mg/L 0.431 mgA.210 mgt 0.246 0.189-'-- �.._.__-__-•-----------_-------------------..---_-_— 389.7 Time (min) N 7 13.448 mg/L 400.2 Run: anions062207 -16- Ic 00 O O Author: cmo H2M Labs. Inc. Channel 1 (Anions) : "0706952-004ADUP:DUP:ANION300_WW" [Row 301 5.724 -- N 0 0.189 404.7 v `o L U 68.490 mg/L or m z ro z M _ E `` o 0 z m` z a 1 mg/L 0.020 mg/L 0.261 mg/L 0.0-0.056 mg/L_ Time (min) Channel 1 (Anions) : "0706952-006A:SAMP:ANION300_WW' [Row 31] 5.724 -I 0.189 —u 419.6 Run: anions062207 a� c Z m 2 z m U L U — O N tL 7.999 zi/L m z 0.159 mg/L_0.028 mg/L 0.035 mo.686 mg/L Time (min) EL Date : 6/23/2007 m N CO 11.481 mg/L m m a; C (0 Q toO 0 21.870 mg/L -0.117 mq/L, 415.2 Author: cmo H2M Labs. Inc. Channel 1 (Anions) : "0706952-008A:SAMP:ANION300–WW" [Row 32) AMA 2 0 0.189 434.6 .o t U 27.717 mg/L z v �, E o 2 LLL Z M 0.119 mg/L -0.4940.164 mg/L_ Time (min) Channel 1 (Anions) : "0706952-009A:SAMP:ANION300 WW" [Row 331 5.724 -- Date : 6/23/2007 a a� Z CU n ° � to D z a 17.871 mg/L 0.0(-0.047 mg/L__,/—� 445.1 v a `o 0 c Z Z c m U ) n d 0 11.71: -ng/L 2 `� 0 E 11 Z m z a 0.121 mg/L_0.020 mg/L 0.076 mg/L0.024 mg/L_-0.052 mg/L�6,329 mg/L 0.189 449.6 Time (min) 460.1 Run: anions062207 -18 - Ic Author: cmo H2M. Labs. Inc. Date : 6/23/2007 Channel 1 (Anions) : "0706986-001A:SAMP:ANION300-WW" [Row 341 . 5.724 C a a) 0 a� '0- z4) z _. _0 2m N 0 L U tp 4.070 m /1 m z ° 12.542 mg/L 0.139 my«_0.021 mg/L-0.017 mg0.626 mg/L -0.065 mglL_/-- 0.189-=--..__....__........_.. ------- ._.._.....------.._._-__.._...__....-..,_..__..........._.-._.___..........__._._......_........._.--_._....._.-__.._._...._.................................i 464.6 Time (min) 475.1 Channel 1 (Anions) : "0706986-002A:SAMP:ANION300_WW" [Row 35) 5.724 0 CD v - a d U Z m Z m 0 l 17.20.2 ng/L F � u w° 0 M 11 Z m Z a 0.170 mg/L_0.020 mg/L 0.023 mg0.956 mg/L -0.060 mg/L__5.098 mg/L 0.189-.— ---- ----- ----------.-------------- -_ _ _ _ ------ 479.6 Time (min) 490.1 Run: anions062207 -19- IC. 00 00 O O H Author: cmo 1-12M Labs. Inc. Channel 1 (Anions) : "0706986-004A:SAMP:ANION300_WW" [Row 36] 5.724 0.189 494.6 Date : 6/23/2007 `o 16.443 m /L o g E 2 0 — 2 LL z Co z a 0.143 mg/L -0.2410.070 mg/L 0.00.056 mg/L___-8.312 mg/L Time (min) 505.1 Channel 1 (Anions) : "CCV:CCV:anion300_ww" [Row 37] 5.724 0 0.189--�--�- 509.5 v_ m aD `o Z m Z r � � w E 11.09CZig/L 2 M z a 1.147 mg/L J5.532 mg/L 1.019 mg1.084 mg/L 0.685 Time (min) is 10.313 mg/L 520.0 Run: anions062207 = 20 - IC Author: cmo 1-112M Labs. Inc. Channel 1 (Anions) : "CCB:CCB:anion300 ww" [Row 38) 5.724--- 523.1 .724" - 523.1 Table 1: Bromide a a� Z o z L v a o` m E ro N ° _ o c O X- 0 U z CO` z n. cn Date : 6/23/2007 0.020 mg.0.020 mg/1-0.010 mg/L O.G0.062 mg/L_0:001 mg/L Time (min) 533.5 Figure 1: Bromide 0.409 ® Area = 0.080' Conc - 0.001 - Conc = 12.508 ` Area + 0.007 Correlation Coefficient (r) = 0.99991 1/x weighting Y CU N n. Bromide concentration, mg/L 5.000 O O ,--+ O C/1 Run: anions062207 - 21 - IC Conc. (mg/L) Rep Peak Area (Volt -s) Peak Height (Volts) % Residual Detection Date Detection Time 1 5.000 1 0.409 0.029 -2.5 6/20/2007 3:25:28 PM 2 2.500 1 0.198 0.014 0.4 6/20/2007 3:25:28 PM 3 2.000 1 0.156 0.011 1.9 6/20/2007 3:25:28 PM 4 1.000 1 0.076 0.005 4.5 6/20/2007 3:25.28 PM 5 0.500 1 0.036 0.002 8.3 6/20/2007 3:25:28 PM 6 0.1001 1 0.0080.000 -5.8 6/20/2007 3:25:28 PM 7 1 0.0001 1 1 0.0001 0.000 6/20/2007 3:25:28 PM Figure 1: Bromide 0.409 ® Area = 0.080' Conc - 0.001 - Conc = 12.508 ` Area + 0.007 Correlation Coefficient (r) = 0.99991 1/x weighting Y CU N n. Bromide concentration, mg/L 5.000 O O ,--+ O C/1 Run: anions062207 - 21 - IC Author: cmo Table 2: Sulfate H2M Labs. Inc. Date : 6/23/2007 Figure 2: Sulfate 11.884, /� Area = 0.001 * Conc^2 + 0.197 * Conc + 0.009 / Conc = - 0.064 * Area^2 + 4.964 * Area - 0.027 N Correlation Coefficient (r) = 0.99999 m 1/xweighting a� Q � CU N n. Sulfate concentration, mg/L 50.000 Table 3: Chloride i Conc. (mg/L) Rep ( 1 11 Peak Area (Volt -s) i Peak Height (Volts) 1 1 % Residual Detection Date i Detection Time 1 50.000 , 1 11.8841 0.452 ` 0.2 6/20/2007 I 3:25:28 PM 2 25.000 1 5.4821 0.2151. 0.6 6/20/2007 3:25:28 PM 3 , 20.000 1 4.2961 0.168 -0.41 6/20/2007 1 3:25:28 PM 4 1 10.000 1 1 i 2.049 0.0801 0.7 6/20/2007 3:25:28 PM 5 5.0000 5 .981 0.981 0.038 1 3.4 , 6/20/2007 3:25:28 PM 6 1.000 1 l 0.222 0.008 -7.3 1 6/20/2007 i 3:25:28 PM 7 0.000 1 0.000 -0.000 j ;_ 6/20/2007 3:25:28 PM Figure 2: Sulfate 11.884, /� Area = 0.001 * Conc^2 + 0.197 * Conc + 0.009 / Conc = - 0.064 * Area^2 + 4.964 * Area - 0.027 N Correlation Coefficient (r) = 0.99999 m 1/xweighting a� Q � CU N n. Sulfate concentration, mg/L 50.000 Table 3: Chloride Figure 3: Chloride 16.851 Area = 0.002 * Conc^2 + 0.264 * Conc - 0.008 Conc = - 0.042 * Area^2 + 3.646 * Area + 0.057 N Correlation Coefficient (r) = 0.99995 1/x weighting caY a) a� a Chloride concentration, mg/L 50.000 Run: anions062207 -22- IC Conc. (mg/L) Rep Peak Area (Volt -s) Peak Height (Volts) % Residual Detection Date Detection Time 1 50.000 1 16.851 1.558 0.6 6/20/2007 3:25:28 PM 2 25.000 1 7.724 0.775 1 -2.5 6/20/2007 3:25:28 PM 3 20.000 1 1 5.974 0.608 -1.6 6/20/2007 3:25:28 PM 4 10.000 1 1 2.710 0.273 2.7 6/20/2007 3:25:28 PM 5 5.000 1 1.250 0.123 7.5 6/20/2007 3:25:28 PM 6. 1.000 1 0.2581 0.024 0.1 1 3:25:28 PM 7 0.000 1 0.0101 0.000 1 6/20/2007 1 3:25:28 PM Figure 3: Chloride 16.851 Area = 0.002 * Conc^2 + 0.264 * Conc - 0.008 Conc = - 0.042 * Area^2 + 3.646 * Area + 0.057 N Correlation Coefficient (r) = 0.99995 1/x weighting caY a) a� a Chloride concentration, mg/L 50.000 Run: anions062207 -22- IC MU3­4's OLAW .-V> �. Author: bnk />ti,�.� L� H2M Labs. Inc. Date : 6/2812007 Original Run Filename: OM_6-27-2007_04-45-16PM.OMN created 6/2712007 4:45:16 PM Original Run Author's Signature: [bnk] Current Run Filename: anions062707.omn last modified 6/281200.7 8:00:43 AM Current Run Author's Signature: [bnk] Description: Default New Run Sample Cup No. Channell _Channel Bromide - -Chloride _ Bromide I Chloride Sulfate ADF MDF Cone. (m/L Area Conc. Area Cone. Area Vs (mg/L Vs m /L Vs m !L _Concentration _ Callibration Fit Type _First Order I Second Order 5.000 0.546 50.000 19.507 50.000 12.708 CALSTD B - S2 2.500 0.244 25.000 9.196 25.000 5.911 _ CALSTD C _ S3 2.000 0.212 20.000 7.108 20.000 4.527 CALSTD D - - - _ S4 1.000 0.103 3.278 10.000 2.166 CALSTD E _ _ S5 0.500 0.049 _10.000 5.000 1.516 5.000 1.046 _ CALSTD FS6 CALSTD G "LCS-062707:LCS:Anion300 WVV" - LICB-062707Jwww"�_ ----------- - �-..�-._ S8 _ _ 1 Known Conc: -[ 2 0.100 0.000 2.467 2.500 -0.001 0.010 -0.001 0.260 g -0.001 _ 1.000 .0.282 0.000 -0.008 9.510 3.210 10.000 /• 0.218 0.031 1.000 0.000 9.317 --- 10.000 0.018 0.214 0.000 2.047 r3'J. -0.000 _ -- Known Conc: 0.000 5 0.000 ,a 0.000 45) �If_b-062707:lfb_:anion300 ww" -3 - - - - - _Known Conc: _ 0.949 1.000 _0. 0.099 (. _ 9.573 10.000 3.2321 q6.j. 9.544 10.000 2.098 45'/. "MB-062707_:M_BL_K-anion_303_ ww" _--- _ ___ 4_ '0.013 0.000 0.185 0.020 0.021 0.000 Known Conc: 0.000 0.000 LZ•) 0.000 L .J 0706952-003K: §AMP.ANION300 WVU 5 2.547 _�0,5 0:012 352.284 6.126 84.253 0.910 20.00 WVV' _ 6 1.382 0.013 p 376.130 14.050 _ 53.888 1.169 10.00 _"0706952-004A:SAMP:ANION300 " _ 7 _ 11.016 0.115 L463.188 17.927 �[q'. 152.990 3.424 10.00 WV "0706952-004ADUP:DUP:ANION300 W'- V' 8 1.305 0.012 oy.377.343 14.102 53.864 1.166 10.00 "0706952-004A:SAMP:ANION300 WW' 9 1.288 0.026 334.289 28.743 54.797 2.420 5.00 "0706952-004AMS:MS:ANION300_WW'- _ - 10 6.098 0.128 362.472 32.360 105.137 4.794 5.00 "0706952-004ADUP:DUP:ANION300 WW" 11 1.334 0.027 _ 336.454 29.008 54.368 2.400 5.00 "0706986-003A:SAMP:ANION300 WW" 12 1.273 0.005 240.619 4.102 35.636 0.380 20.00 "0707291-003A:SAMP:AN_ION30.0 W_W" _ _ 13 y 0.013 0.000 _ 28.080 10.126 7.319 1.598 _ - _ -Calibration: 0.707351-003A:SAMP:ANION300 WVV 14 0.011 -0.000 28.629 10.344 Table/Fig. 1 7.286 1.590 Table/Fig. 3 - Table/Fig. 2 0707351-007A:SAMP:ANION300 VWV" I 'CCV:CCV:anion300 ww" --- 15 -- S4 109.325 0.968 0.230 0.101 --- 35.178 - 9.807 0.193 3.314 13.700 - 9.908 0.055 2.180 50.00 �- Known Conc: 1,000 (. 10.000 '/. 10.000 " S8 0.002 -0.001 0.093 -0.011 0.018 -0.000 -_'CCB:CCB:anion300^ww" -- _- �-- Known Conc: - 0.000 L�. S - 0.000 L7.• 0.0001 4f. y - Analyte Properties Table for anions062707.omn --Property --- 1--- _Channel Bromide - -Chloride Sulfate _ Units mc,�/L mg/L m !L _Concentration _ Callibration Fit Type _First Order I Second Order Second Order Run: anions062707 TSLO10 W92 -1- IC Author: bnk H2M Labs. Inc. Date : 6/28/2007 CIea CaIibration - 'I True True True Force Through Zero _ False False False Calibration Weighting _ 1/x IN 1/x I__ _ _ _. _ Auto Dilution Tri er True _ _False False 0L. hiigh Standard 110 _ 110 110 Quik Chem Method 10-510-00-1-A 110-510-00-1-A 10-510-00-1-A Chemistry - Direct/Bipolar Direct/Bipolar Direct/Bipolar ( Calibration by Height False False False Inject to Peak Start _ 259 i 151 494 Peak Base Width ^_ _ 64 1 54 133 Channel 1 (Anions) : CALSTD A [Row 1] 2.734 0 0.210 1.5 Run:anions062707 TSLO1O W93 5.000 mg/L Time (min) -2- a� :D o- 50.000 mg/L a� m s CL 0 s a 5.000 mg1L 11.9 L Author:bnk Channel 1(Amions):CALSTDA[Row1] 0.210--' ------- 1.5 Channel 1@oions:CALSTD8(Row 2] � � H2M Labs. Inc. Date: 612812007 � 50.000 mg/L co 2 ') JL 5.000 mgJL a) g/L CL a. 5.000 mg1L ..... --_^_---..... -...... ..... .......... -........ --_-______---_.-__.-__ U210 ' ' 15.0 Time (min) � u 25.000 mg/L z Cb 76 0. 11/9 Time (min) 25.4 RumonionaOG27O7 '2' |c Author: bnk Channel 1 (Anions) : CALSTD C [Row 3] 2.734 0.210.-.-- 28.6 Channel 1 (Anions) : CALSTD D [Row 41 2.734 N O U.21 U .._.. ....:.:...... 42.1 H2M Labs. Inc. .000 mg/L z z o z o 2.000 mg/L m z 2.000 mg L000 mglL Time (min) N L O t U 10.000 Z g/L z II z o z ig/L 1.000 mg1L m 1.000 m !L 1.000 mg, _ mg 1L (min) Date : 6/28/2007 EL CD 2 a CO :3 C3. m r 20.000 mg/L a. 2.000 mg/L 38.9 a a� r v° a o to r o_ 10.000 mg/L 1.000 mg/L---/'\ 52.4 Run: anions062707 - 3- IC Authmr:bnk Channel 1(Aomno):{AuSTos[Ruwn] � � U.z1U-- * I - 55.6 Channel I (Anions): CALSTD F [Row 61 In 0 H2M Labs. Inc. a) z a) 0 �2 .2 E 5.000 , IL ^ Co ig/L 0.500 mg/L -. ___'___ _--__- Time (min) Date : 6/28/2007 � m ca Q. In 5.000 mg/L 66.0 EU j'00 1OOmg/lq�j 00 mg u11.0 . - ' Time (min) Run:uni6nuO627O7 '4' |C Author: bnk Channel 1 (Anions): CALSTD G [Row 7] 2.734-.- 0.210 - -V- 82.7 H2M Labs. Inc. Date : 6128/2007 E m ra z 0- U) ------,,__0.000 mg/L 0.000 mg/L 0.000 mg/L O.00.000 mg/L 0.000 rrO.000 mg/L . .. ... .. ....... I ... . ............... .. ....... .. . ... ... ..... . ... ....... . - Time (min) 93.1 Channel I (Anions): "LCS-062707:LCS:Anion300—VvW'[Row 8] 2.734 - U.z1U - 96.3 z z 510 r -611 - ca z E 2.489 m g,L 2 /\, M 2.368 mg/L �61 Time (min) CL p U) 2 U) L 9.317 mg/L 2.167 106.6 Run: anions062707 - 5 - ic Author: bnk 1-112M Labs. Inc. Date : 6/28/2007 Channel 1 (Anions) : "lCB-062707:ICB:anion300 ww" [Row 9] 2.734 -- 0 n. a� �o a 6 `o ° Z v (1) o. o E m 0 o w U Z m` Z a. 0) i 0.018 mg/L 0.210.014 mg/L -0.00'0.025 mg/L 0.045 mg/L 0.018 0.210......: _._._..........__.._..__. ._ ...._........__...._,- .._.._.............. _.__. ..._...__.._.. -- .._...., 109.8 Time (min) 120.2 Channel 1 (Anions) : "lfb-062707:Ifb:anion300_ww" [Row 101 2.734.- 2 O > ! N 'O O I U ! 9.573 rZ 1L Z ' a aa) u iI Z m Z 0.871 mg/L 0.919 mg/L 0 863 m /L 0.949 mg! __ mg/L 0.210 - 123.3 Time (min) a a� L �@ O O CO nt 9.544 mg/L 133.7 Run: anions062707 - 6 - IC 00 O O H Author:bnk R2MLabs. Inc Channel I (Anions): "MB-062707:MBLK:anion3OO—wW'[Row 11] -Eq FL 0 ZED z umo/L o�1V-r��------�----.... ...... —'---------... ......... .... ....... ....... ....... ---'--'-- 136.9 Time (min) Channel 1 (Anions): "0706952-003A:SAMP:ANION300—WVV'[Row 12] 2J34– B C, "~= 150.4 17.614mg/L 28 mSmg/L Time (min) Date : 6/2812007 n- 0.021 147.2 Q._ CU 4g� _2.wwmg�:213m�� 160.8 Run:oniono062707 -7- |C Author: bnk 1-112M Labs. Inc. Channel 1 (Anions) : "0706952-004A:SAMP:ANION300 WW' [Row 131 2.734 0 0.210 163.9 Date: 6/28/2007 a) `o r U 37.613 mg/L or 77 a� CLLO 9 I o �` r CO i z m z ° 5.389 mg/L 37 mg0.014 mg/L 0.138 m /L _0.01310.045 mg/L Time (min) Channel 1 (Anions) : "0706952-004AMS:MS:ANION300_WW' [Row 14] 2.734 0.210 177.5 a) 8 L U 46.319 mg/L 174.3 Z a) d 0 z 0.014 mg/L Z a N m z d En V@-. 7 CO a 5.299 mg/L ig/U! _ J _ -i 1.102 mgi0.867 mg/L ` -0.015 mg/L Time (min) 187.8 Run: anions062707 - 8 - IC Author: bnk H2M Labs. Inc. Channel 1 (Anions) : "0706952-004ADUP:DUP:ANION300 VWV" [Row 151 2.734 0.210 191.0 Date : 6/28/2007 . a� v `o s U 37.734 mg/L ro a e Ca o Z m` Z a_ 127 mg0.014 mg/L 0.130.019 mg/L -0.032 mg/l: mg/L Time (min) 201.3 Channel 1 (Anions) : "0706952-004A:SAMP:ANION300_WW" [Row 16] 2.734 0.210 204.5 73 a (D Z m m v a w E is o _ o m` 2 a- 10.959 mg/L ----0.250.019 mg/L ---0.045 Time (min) 214.9 Run: anions062707 - 9 - IC O O O C/1 N Autbonbnk H2MLobm Inc Channel 1 (Anions): "0706952-004AMS:MSANION300—WVV'[Row 17] "oi"— .^.~_ 218.0 ig/L Date : 6/28/2007 ' �cc � ` 21.027mg/L ' u 872 mg/L -0.146 Time (min) 228.4 Channel 1ymiono : pRow18] � � -93.878 mg/L 231.5 Time (min) a_ 10.874mg/L -0.n35mg/L\^___ ~ ' 241.9 Run:unionoOG2707 -10- |C Author: bnk H2M Labs. Inc. Channel 1 (Anions): "0706986-003A:SAMP:ANION300—VVW'[Row 19] 2.734 Date : 6/28/2007 0 12.031 mg/L N O 2 U- Z [a Z d U) V-----1__O-QO9 mg0.014 mg/L 0.064 mq/1-0.028 mg/L_0.048 mg/L_1_382mg/L 0.210,-.-- .... .. . . ...... - .......... . ... 245.1 Time (min) 255.4 Channel 1 (Anions): "0707291-003A:SAMP:ANION300—WVV'[Row 20] 2.734 - 0.210 258.6 28.080 mg/L Cj E 2 LL Co 0.021 mg/L f % -0-;0.013 mg/L--.! Time (min) z z L 5 L 1174 267.0 Run: anions062707 -11 - 1C Author: bnk H2M Labs. Inc. Channel 1 (Anions): "0707351-003A:SAMP:ANION300—WW" [Row 21 ] 2.734 Date : 612812007 0 28.629 mg/L z -6 > 21.472 mg/L CD o- 0 CO a. 7.286 mg/L 0.022 mg/1-1 -0Z014 mg/L 0.011 mglL—_0.045 mg/L 0.210--._ -- ------ 272.1 Time (min) 282.5 Channel I (Anions): "0707351-007A:SAMP:ANION300—WVV'[Row 22] 2,734. 2 0 0.210 285.7 z M E raN l9 0 0 C) z m Z EL U) 8 Mg/!-,L706.014'.'Ta/�l_ 2.186 M911-0. 105 mg/L 0.045 mg/L_ 0.274 �7 mg/L Time (min) 296.0 Run: anions062707 -12- IC Author: bnk H2M Labs. Inc. Channel 1 (Anions) : "CCV:CCV:anion300 ww" [Row 23] 2.734 y 0 0.210 300.6 a) v `o L U 9.807 r,Z IL Z m a E � z 0 m Z g/L 0.923 mg/L 0.968 mgp•896 mg/L Time (min) Channel 1 (Anions) : "CCB:CCB:anion300_ww" [Row 24] 2.734 0 > 0.210 " 314.2 Date : 6/28/2007 a. m °: CL L w U) tp J-- 0- n- 9.908 mg/L 0.860 mg/L 311.0 4. a� (D Z W 77 CU o -0 p a a� a o `o °) E m CO o io L L :3 U z m z a cn 0.018 mg/L 0.093 m /c/LL 0.013 mg/L_0.002 mg/L_0.019 mg/L�y _0.044 mg/L0.018 Time (min) 324.5 Run: anions062707 -13- IC U Author: bnk Table 1: Sulfate H2M Labs. Inc. Date : 6/28/2007 Figure 1: Sulfate 12.708 Sulfate concentration, mg/L 50.000 Table 2: Chloride Area = 0.001 * ConcA2 + 0.210 * Conc - 0.001 Conc = - 0.058 * Area A2 + 4.662 * Area + 0.019 Correlation Coefficient (r) = 0.99999 1/x weighting T Conc. (mg/L) Rep Peak Area (Volt -s) Peak Height (Volts) % Residual Detection Date Detection Time 1 50.000 1 12.708 0.594 0.3 6/28/2007 7:56:36 AM 2 25.000 1 5.911 0.283 -1.8 6/28/2007 7:56:36 AM 3 20.000 1 4.527 0.219 0.6 6/28/2007 7:56:36 AM 4 10.000 1 2.166 0.104 0.9 6/28/2007 7:56:36 AM 5 5.000 1 1.046 0.049 2.3 6/28/2007 7:56:36 AM i 6 1.0001 1 1 0.2141 0.010 -2.0 6/28/2007 1 7:56:36 AM 7 0.0001 1 1 0.000 -0.000 6/28/2007 1 7:56:36 AM Figure 1: Sulfate 12.708 Sulfate concentration, mg/L 50.000 Table 2: Chloride Area = 0.001 * ConcA2 + 0.210 * Conc - 0.001 Conc = - 0.058 * Area A2 + 4.662 * Area + 0.019 Correlation Coefficient (r) = 0.99999 1/x weighting T Conc. (mg/L) Rep � Peak Area (Volt -s) Peak Height (Volts) %Residual 1 I I Detection Date I Detection Time 1 1 I- -- 2 3 _ 50.000 25.000 I 20.000 1 19.507 1.912 0.7 1 9.196 , 1.136 -2.7 1 7.108 0.926 -1.2 6/28/2007 7:56:36 AM 6/28/2007 1 7:56:36 AM ^ 6/28/2007 7:56:36 AM i 4 10.0001 1 3.2781 0.4601 2.4 6/28/2007 7:56:36 AM 5 4 5.000 _ 1 1 1.516 i _ 0.217 6.8 6/28/2007 7:56:36 AM i 6 1.000 ( 1 0.282 0.038 3.2 -11 6/28/2007 7756736 AM i----0_000 -0.0081 -0.001 1 6/28/2007 1 7:56:36 AM Figure 2: Chloride 19.507. Chloride concentration, mg/L 50.000 Run:anions062707 Area = 0.001 * ConcA2 + 0.326 * Conc - 0.036 Conc = - 0.024 * Area A2 + 2.999 * Area + 0.125 Correlation Coefficient (r) = 0.99995 1/x weighting -14- IC Author: bnk 1-12M Labs. Inc. Date : 6/28/2007 Table 3: Bromide Figure 3: Bromide 0.54 Area = 0.106 ' Cone - 0.001 Cone = 9.447 ' Area + 0.013 in Correlation Coefficient (r) = 0.99981 1/x weighting a(D (6 Bromide concentration, mg/L 5.000 Run: anions062707 -15- IC Cone. (mg/L) Rep Peak Area (Volt -s) Peak Height (Volts) % Residual Detection Date Detection Time 1 5.000 1 0.546 0.046 -3.7 6/28/2007 7:56:36 AM 2 2.500 1 0.244 0.021 7.0 6/28/2007 ( 7:56:36 AM 3 2.000 1 0.212 0.017 -0.9 6/28/2007 7:56:36 AM 4 1.000 1 0.103 0.0081 1.0 6/28/2007 7:56:36 AM 5 0.500 1 0.049 0.0041 4.8 6/28/2007 7:56:36 AM 6 0.100 1 0.010 0.001 1 -6.9 6/28/2007 7756:36 AM 7 0.000 1 -0.001 -0.0001 I 6/28/2007 7:56:36 AM Figure 3: Bromide 0.54 Area = 0.106 ' Cone - 0.001 Cone = 9.447 ' Area + 0.013 in Correlation Coefficient (r) = 0.99981 1/x weighting a(D (6 Bromide concentration, mg/L 5.000 Run: anions062707 -15- IC ..-M Labs_sws Detail Report Seed Correction '�- = 0. f X -2.6'j c 0. Start Time: 07:30 Initial Reading Date: 2007/6/15 Operator: BAW Winkler In: 8.7 Meter In: 9.0 Final Reading Date: 2007/6/20 Winkler Out: 8.5 Meter Out: 8.9 �r OID Sample ID; Client ID Sample Client Name; Test Code Vol Seed Initial DO Final DO Depletion BOD I Avg BODI Flags Rack # Type mL mL mg/L mg/L mg/L mg/L mg/L RINSE RB; BOD5_W 299.00 8.70 8.30 <2.00 <2.01 <2.01 Id 26 MB -061507 MBLK BLANK A; BOD5_W 299.00 8.73 8.40 <2.00 <2.01 <2.01 1d 26 MB -061507 MBLK BLANK B; BOD5_W 299.00 8.71 8.40 <2.00 <2.01 <2.01 ld 26 LCS-061507 LCS STANDARD; BOD5_W 3.00 4.00 8.68 5.81 2.87 232.33 216.48 ds 26 LCS-0_61507 LCS STANDARD; BOD5_W 6.00 4.00 8.67 3.99 4.68 206.67 ds 26 LCS-061507 LCS STANDARD; BOD5_W 9.00 4.00 8.68 1.82 6.86 210.44 ds 26 Seed 4.00 8.68 8.01 <2.00 <150.00 40.70 evlXds 26 Seed 6.00 8.64 7.74 <2.00 <100.00 evlXds 26 Seed 15.00 8.64 6.62 2.02 40.40 eXds 26 Seed 21.00 8.60 5.73 2.87 41.00 eds 26 0706895-001A SAMP RHS INF; BOD5_W 1.50 8.69 7.58 <2.00 <400.00 1 313.00 vid 26 0706895-001A SAMP RHS INF; BOD5_W 3.00 8.68 6.90 <2.00 <200.00 v1d 26 0706895-001A SAMP RHS INF; BOD5_W 6.00 8.61 2.35 6.26 313.00 d 26 0706895-001A SAMP RHS INF; BOD5_W 15.00 8.40 <1.00 7.40 >148.00 v2d 26 0706895-001A SAMP RHS INF; BOD5-C_W 1.50 8.71 7.68 <2.00 <400.00 159.50 v1d 26 0706895-001A SAMP RHS INF; BODS-C_W 3.00 8.66 7.11 <2.00 <200.00 v1d 26 0706895-001A SAMP RHS INF; BODS -C W 6.00 8.59 5.40 3.19 159.50 d 26 0706895-001A SAMP RHS INF; BODS-C_W 15.00 8.41 <1.00 7.41 >148.20 v2d 26 0706895-001A SAMP RHS INF; BOD5_W_DISS 1.50 8.61 8.23 <2.00 <400.00 62.00 vld 26 0706895-001A SAMP RHS INF; BOD5_W_DISS 3.00 8.62 8.02 <2.00 <200.00 v1d 26 0706895-001A SAMP RHS INF; BOD5_W DISS 6.00 8.59 7.35 <2.00 <100.00 v1d 26 0706895-001A SAMP RHS INF; BOD5_W DISS 15.00 8.55 5.45 3.10 62.00 d 26 0706895-002A SAMP RHS EFF; BOD5_W 15.00 4.00 8.61 8.03 <2.00 <29.07 -4.94- v1 ds 26 0706895-002A SAMP RHS EFF; BOD5_W 30.00 4.00 8.60 7.85 <2.00 <14.53 LY v1ds 26 0706895-002A SAMP RHS EFF; BOD5_W 60.00 4.00 8.64 7.67 <2.00 <7.27 v1ds 39 0706895-002A SAMP RHS EFF; BOD5_W 150.00 4.00 8.64 7.08 <2.00 <2.91 Tr G Ids 39 0706895-002A SAMP RHS EFF; BODS-C_W 15.00 4.00 8.52 8.12 <2.00 <29.07 -42.8.1 v1 ds 39 0706895-002A SAMP RHS EFF; BODS -C W 30.00 4.00 8.52 7.97 <2.00 • <14.53 L vlds 39 0706895-002A SAMP RHS EFF; BODS-C_W 60.00 4.00 8.55 7.95 <2.00 <7.27 vids 39 0706895-002A SAMP RHS EFF; BODS-C_W 150.00 4.00 8.75 7.77 <2.00 <2.91 DIL. Ids 39 0706895-002A SAMP RHS EFF; BOD5_W DISS 15.00 4.00 8.55 7.92 <2.00 <29.07 - 2.91- v1ds 39 0706895-002A SAMP RHS EFF; BOD5_W DISS 30.00 4.00 8.52 7.88 <2.00 <14.53 G v1ds 39 0706895-002A SAMP RHS EFF; BOD5_W_DISS 60.00 4.00 8.38 7.55 <2.00 <7.27 vlds 39 0706895-002A SAMP RHS EFF; BOD5_W DISS 150.00 4.00 7.82 6.57 <2.00 <2.91 6 2° Ids 39 0706899-001AfSLO 1 O W 1 O$ ISAMP IRHS LOC #2; BOD5-C_W 1 0.30 1 1 8.55 1 2.75 1 5.80 1 5800.00 1 5800.00 .1 d 139 Sana.- ,_; Client ID Sample Client Name; Test Code Vol Initial DO Final DO Depletion BOD Avg BOD Flags Rack _ Type mL mL mg/L mg/L mg/ L mglL mg/L 0706899-001A SAMP RHS LOC #2; BOD5-C W 0.60 1 8.51 <1.00 7.51 >3755.00 v2d 39 0706899-001A SAMP RHS LOC #2; BOD5-C W 1.50 8.49 <1.00 7.49 >1498.00 v2d 39' 0706899-001A SAMP RHS LOC #2; BOD5-C_W 3.00 8.43 <1.00 7.43 >743.00 v2d 39 0706928-001A SAMP GNK INF; BOD5-C W 1.50 8.57 6.97 <2.00 <400.00 228.25 v1d 39 0706928-001A SAMP GNK INF; BOD5-C W 3.00 8.52 5.96 2.56 256.00 d 39 0706928-OOIA SAMP GNK INF; BOD5-C_W 6.00 8.49 4.48 4.01 200.50 d 39 0706928-001A SAMP GNK INF; BOD5-C W 15.00 8.26 <1.00 7.26 >145.20 v2d 39 0706928-002A SAMP GNK EFF; BOD5-C W 30.00 4.00 8.40 6.23 2.17 16.23 19.62 ds 39 0706928-002A SAMP GNK EFF; BOD5-C_W 60.00 4.00 8.20 3.05 5.15 23.02 ds 39 0706928-002A SAMP GNK EFF; BOD5-C W 150.00 4.00 7.70 <1.00 6.70 >12.31 v2ds 39 0706928-002A SAMP GNK EFF; BOD5-C W 299.90 4.00 6.39 <1.00 5.39 >4.84 v2ds 39 0706942-001A SAMP OBS INF; BOD5-C_W 3.00 8.44 7.82 <2.00 <200.00 59.25 v1d 39 0706942-001A SAMP OBS INF; BODS-C_W 6.00 8.44 7.03 <2.00 <100.00 v1d 39 0706942-001A SAMP OBS INF; BOD5-C W 15.00 8.30 5.55 2.75 55.00 d 30 0706942-001A SAMP OBS INF; BOD5-C_W 30.00 8.05 1.70 6.35 63.50 d 30 0706942-002A SAMP OBS EFF; BOD5-C_W 30.00 4.00 8.45 7.80 <2.00 <14.53 3.52 v1ds 30 0706942-002A SAMP OBS EFF; BOD 5-C W 60.00 4.00 1 8.58 7.60 <2.00 <7.27 v1ds 30 0706942-002A SAMP OBS EFF; BODS -CW 150.00 4.00 1 8.94 7.03 <2.00 <2.91 v1ds 30 0706942-002A SAMP OBS EFF; BOD5-C_W 299.90 4.00 9.19 5.12 4.07 3.52 ds 30 0706894-001A SAMP SIH INF; BODS W 1.50 8.32 6.67 <2.00 <400.00 323.00 v1d 130 0706894-001A SAMP SIH INF; BOD5_W 3.00 8.34 5.33 3.01 301.00 d 30 0706894-001A SAMP SIH INF; BOD5_W 6.00 8.25 1.35 6.90 345.00 d 30 0706894-001A SAMP SIH INF; BOD5_W 15.00 8.03 <1.00 7.03 >140.60 v2d 30 0706894-002A SAMP SIH EFF; BOD5_W 30.00 4.00 8.19 7.70 <2.00 <14.53 3.13 vlds 30 0706894-002A SAMP SIH EFF; BOD5_W 60.00 4.00 8.07 7.07 <2.00 <7.27 v1ds 30 0706894-002A SAMP SIH EFF; BOD5_W 150.00 4.00 7.70 5.80 <2.00 <2.91 v1ds 30 0706894-002A SAMP SIH EFF; BOD5 W i 299.90 4.00 7.58 3.90 3.68 3.13 ds 30 0706934-001A SAMP ASPEC INF; BOD5_W 1.50 8.23 7.45 <2.00 <400.00 197.25 v1d 30 0706934-001A SAMP ASPEC INF; BOD5_W 3.00 8.29 6.15 2.14 214.00 d 30 0706934-001A SAMP ASPEC INF; BOD5_W 6.00 8.26 4.65 3.61 180.50 d 30 0706934-001A SAMP ASPEC IN BOD5_W 15.00 8.09 <1.00 7.09 >141.80 v2d 30 0706934-002A SAMP ASPEC EFF; BOD5_W 30.00 4.00 8.22 7.81 <2.00 <14.53 -44 v1ds 30 0706934-002A SAMP ASPEC EFF; BOD5_W 60.00 4.00 8.24 7.63 <2.00 <7.27 LZ v 30 0706934-002A _ SAMP ASPEC EFF; BOD5_W 150.00 4.00 8.17 7.45 <2.00 <2.91 v1ds 30 0706934-002A SAMP ASPEC EFF; BOD5_W 299.90 4.00 8.27 6.41 <2.00 <1.45 Ids 30 0706952-001A ^ SAMP PCTSL001; BOD5_W 30.00 4.00 8.20 7.94 <2.00 <14.53 X1.4& v1 ds 30 0706952-001A SAMP PCTSL001; BOD5_W 60.00 4.00. 7.94 7.45 <2.00 <7.27 Z v1 ds 30 0706952-001A� SAMP PCTSL001; BOD5_W 150.00 4.00 6.93 6.55 <2.00 <2.91 6 v1ds 32 0706952-001A SAMP PCTSL001; BOD5_W 299.90 4.00. 7.13 6.98 <2.00 <1.45 Ids 32 0706952-002A ��,j �p SAMP PCTSL002;BOD5_W 30.00 4.00 8.19 7.74 <2.00 <14.53 <IAE v1ds 32 132 0706952-002A TSL01b W109 ISAMP PCTSL002; BOD5_W 60.00 4.00 7.87 1 7.45 <2.00 <7.27 LZ vlds Xe Sampic iu, Client ID Sample Client Name; Test Code Vol t Initial DO Final DO Depletion BOD Avg BOD I Flags IRack Type mL mL mg/L mg/L mg/L mg/L mg1L 0706952-002A 1'14J _ y SAMP PCTSL002; BODS_W 150.00 4.00 6.66 6.19 <2.00 <2.91 v1ds 132 0706952-002A 0706952-003A 0706952-003A SAMP SAMP SAMP PCTSL002; BOD5-W PCTSL003; BODS_W PCTSL003; BODS_W 299.90 30.00 60.00 4.00 4.00 4.00 5.78 8.28 8.20 5.28 7.64 7.39 <2.00 <2.00 <2.00 <1.45 <14.53 <7.27 (1-45- Z -c- ids _ v1ds v1 ds 32 32 32 0706952-003A SAMP PCTSL003; BOD5-W 150.00 4.00 7.78 6.58 <2.00 <2.91 v1ds 32 0706952-003A SAMP PCTSL003; BOD5 W 299.90 4.00 7.68 6.11 <2.00 <1.45 p�J 6 Ids 32 0706952-004A yyI&--S SAMP PCTSL004; BODS W 30.00 4.00 8.27 7.90 <2.00 1 <14.53 44?45' v1ds 32 0706952-004A SAMP PCTSL004; BODS_W 60.00 4.00 8.16 7.61 <2.00 <7.27 L vids 32 0706952-004A SAMP PCTSL004; BODS_W 150.00 4.00 7.51 6.85 <2.00 <2.91 v1ds 32 0706952-004A SAMP PCTSL004; BODS_W 299.90 4.00 7.05 6.30 <2.00 <1.45 Ids 32 0706952-004ADUPQ 0706952-004ADUP DUP DUP DUP GW; BOD5 W DUP GW; BODS_W 30.00 60.00 4.00 4.00 8.26 8.14 7.74 7.56 <2.00 <2.00 <14.53 <7.27 41 -ors- LZ v1 ds v1ds 32 32 n 0706952-004ADUP DUP DUP GW; BOD5-W 150.00 4.00 7.36 6.54 <2.00 <2.91 vids 32 0706952-004ADUP DUP DUP GW; BOD5-W 299.90 4.00 6.31 5.39 <2.00 <1.45 W6Jza Ids 32 0706952-005A 0706952-005A SAMP SAMP PCTSL005; BODS_W PCTSL005; BODS_W 30.00 60.00 4.00 4.00 1 8.28 8.22 7.69 7.46 <2.00 <2.00 <14.53 <7.27 c4,48- v1ds vids 32 32 0706952-005A SAMP PCTSL005; BODS_W 150.00 4.00 7.74 6.86 <2.00 <2.91 v1ds 32 0706952-005A SAMP PCTSL005; BODS_W 299.90 4.00 7.49 6.24 <2.00 <1.45 63 GVP Ids 32 0706952-006A SAMP PCTSL006; BOD5 W ' 30.00 4.00 8.21 7.73 <2.00 <14.53 <1,4r v1ds 32 0706952-006A SAMP PCTSL006; BOD5-W 60.00 4.00 8.08 7.61 <2.00 <7.27 Ly v1ds 32 0706952-006A +SAMP PCTSL006; BODS_W 150.00 4.00 7.26 6.77 <2.00 <2.9I v1ds 36 0706952-006A SAMP PCTSL006; BODS_W 299.90 4.00 6.92 6.68 <2.00 <1.45 6 Ids 36 0706952-007ASAMP I PCTSL007; BODS_W 30.00 4.00 8.32 7.80 <2.00 <14.53 51-45- v1ds 36 0706952-007A SAMP PCTSLOOT BODS_W 60.00 4.00 8.10 7.65 <2.00 <7.27 L v1 ds 36 0706952-007A SAMP PCTSL007; BOD5-W 150.00 4.00 7.15 6.56 <2.00 <2.91 vids 36 0706952-007A SAMP PCTSL007; BODS_W 299.90 4.00 6.16 5.75 <2.00 <1.45 4j &p Ids 36 0706952-008A Yhlnl� 0706952-008A SAMP SAMP PCTSL008; BODS_W PCTSL008; BOD5 30.00 60.00 4.00 4.00 8.24 8.14 7.59 7.51 <2.00 <2.00 <14.53 <7.27 --1-.46- Gy v1ds v1 ds 36 36 0706952-008A SAMP PCTSL008; BOD5-W : 150.00 4.00 7.21 6.60 <2.00 <2.91 v1 ds 36 0706952-008A SAMP PCTSL008; BODS_W 299.90 4.00 6.98 6.48 <2.00 <1.45 wjo Ids 36 0706952-009A 0706952-009A SAMP SAMP PCTSL009; BOD5-W PCTSL009; BOD5-'W 30.00 60.00 4.00 4.00 8.17 7.82 7.57 6.60 <2.00 <2.00 <14.53 <7.27 3,32 v1ds v1 ds, 36 36 0706952-009A SAMP PCTSL009; BOD5 W 150.00 4.00 6.15 3.76 2.39 3.69 ds 36 0706952-009A Nv SAMP PCTSL009; BOD5-W 299.90 4.00 4.80 1.30 3.50 2.95 ds 36 0706952-010A t 0706952-010A SAMP SAMP PCTSL010; BODS_W PCTSL010; BODS_W 30.00 60.00 4.00 4.00 8.34 8.35 7.91 7.83 <2.00 <2.00 <14.53 <7.27 s1,$5 L2- vids v1ds 36 36 0706952-010A SAMP PCTSL010; BODS_W 150.00 4.00 8.43 8.09 <2.00 <2.91 v1ds 36 0706952-010A SAMP PCTSL010; BOD5 W 299.90 4.00 8.55 8.48 <2.00 <1,45 Ids 36 0706919-001A SAMP PCNR; BOD5 W 1.50 4.00 8.40 <1.00 7.40 >1370.67 3341.67 v2ds 36 0706919-001A SAMP PCNR; BOD5 W 3.00 4.00 8.43 <1.00 7.43 >688.33 v2ds 36 0706919-001A TSLO10 W110 SAMP PCNR; BODS W 6.00 1 4.00 8.36 <1.00 7.36 >340.67 v2ds 36 1�� Sar,.,.... -j; Client ID Sample Client Name; Test Code Vol Initial DO Final DO Depletion BOD Avg BUU I nags Kaci Type ImL mL mg/L mg/L mg/L mg/L mg/L 0706919-001A SAMP PCNR; BOD5_W 30.00 4.00 8.26 <1.00 7.26 >67.13 v2ds 136 0706919-001A SAMP PCNR; BOD5_W 0.60 4.00 8.39 1.16 7.23 3341.67 ds 36 0706986-001A W- SAMP PCTSL201; BOD5-W 30.00 4.00 8.24 7.88 <2.00 <14.53 v1ds 36 0706986-001A SAMP PCTSL201; BOD5_W 60.00 4.00 8.06 7.69 <2.00 <7.27 Z v1ds 41 0706986-001A SAMP PCTSL201; BOD5 1A 150.00 4.00 7.34 6.90 <2.00 <2.91 vlds 41 0706986-001A SAMP PCTSL201; BOD5-W 299.90 4.00 6.30 5.84 <2.00 <1.45 1P Ids 41 0706986-002A SAMP PCTSL202; BOD5_W 30.00 4.00 1 8.46 7.83 <2.00 <14.53 s1,4&- vlds 41 0706986-002A SAMP PCTSL202; BOD5-W 60.00 4.00 1 8.48 8.01 <2.00 <7.27 /-7 v1ds 41 0706986-002A SAMP PCTSL202; BOD5_W 150.00 4.00 8.54 8.07 <2.00 <2.91 v1ds 41 0706986-002A SAMP PCTSL202; BODS_W 299.90 4.00 8.53 8.36 <2.00 <1.45 o Ids 41 0706986-003A mow_ 0706986-003A SAMP SAMP PCTSL203; BOD5_W PCTSL203; BOD5-W 30.00 60.00 4.00 4.00 8.27 8.00 7.68 7.35 <2.00 <2.00 <14.53 <7.27 Z v1ds v1ds 41 41 0706986-003A SAMP PCTSL203; BOD5_W 150.00 4.00 7.04 6.02 <2.00 <2.91 v1ds 41 0706986-003A SAMP PCTSL203; BOD5_W 299.90 4.00 5.64 4.32 <2.00 <1.45 Ids 41 0706986-004A SAMP PCTSL204; BOD5-W 30.00 4.00 8.11 7.62 <2.00 <14.53 Z-4 v1ds 41 0706986-004A SAMP PCTSL204; BOD5_W 60.00 4.00 7.46 6.88 <2.00 <7.27 OP v1ds 41 0706986-004A SAMP PCTSL204; BOD5_W 150.00 4.00 6.16 4.38 <2.00 <2.91 44!L v1ds 41 0706986-004A SAMP PCTSL204: BOD5_W 299.90 4.00 3.84 <1.00 2.84 >2.29 v2ds 41 0707000-001A SAMP HGO INF; BOD5_W 1.50 8.47 1.56 6.91 1382:00 1382.00 d 41 0707000-001A SAMP HGO INF; BOD5_W 3.00 8.46 <1.00 7.46 >746.00 v2d 41 0707000-001A SAMP HGO INF; BOD5_W 6.00 8.40 <1.00 7.40 >370.00 v2d 41 0707000-001A SAMP HGO INF; BOD5 W 15.00 8.20 <1.00 7.20 >144.00 v2d 41 0707000-002A SAMP HGO EFF; BOD5_W 15.00 4.00 8.19 7.27 <2.00 <29.07 7.91 olds 41 0707000-002A SAMP HGO EFF; BOD5_W 30.00 4.00 8.31 7.33 <2.00 <14.53 v1ds 41 0707000-002A SAMP HGO EFF; BOD5_W 60.00 4.00 8.18 6.21 <2.00 <7.27 v1ds 41 0707000-002A SAMP HGO EFF; BOD5_W 150.00 4.00 7.58 3.08 4.50 7.91 ds 41 0707008-001A 3(�6 �j� SAMP BNLS EFF; BOD5_W 30.00 4.00 8.46 7.66 <2.00 <14.53 .4+q3- v1ds 41 0707008-001A SAMP BNLS EFF; BOD5 W 60.00 4.00 8.50 7.86 <2.00 <7.27 1 2 Ads 42 0707008-001A SAMP BNLS EFF; BOD5 W 150.00 4.00 9.04 8.21 <2.00 <2.91 v1ds 42 0707008-001A SAMP BNLS EFF; BOD5 299.90 4.00 9.34 8.53 <2.00 <1.45 Zo Ids 42 0707008-003A 2 3 ,8D SAMP BNLS INF; BOD5_W 3.00 8.34 7.70 <2.00 <200.00 56.40 v1d 42 0707008-003A SAMP BNLS INF; BOD5-W 6.00 8.42 7.49 <2.00 <100.00 vId 42 0707008-003A SAMP BNLS INF; BOD5_W 15.00 8.39 6.60 <2.00 <40.00 v1d 42 0707008-003A SAMP BNLS INF; BOD5_W 30.00 8.37 2.73 5.64 56.40 d 42 0706998-001A SAMP GPS INF; BOD5-C W 1.50 8.44 6.94 <2.00 <400.00 213.25 v1d 42 0706998-001A SAMP GPS INF; BOD5-C W 3.00 8.39 6.09 2.30 230.00 d 42 0706998-001A SAMP GPS INF; BOD5-C-W 6.00 8.36 4.43 3.93 196.50 d 42 0706998-001A SAMP GPS INF; BOD5-C-W 15.00 8.22 <1.00 7.22 >144.40 v2d 42 0706998-002A SAMP GPS EFF; BOD5-C_W 30.00 4.00 8.35 7.51 <2.00 <14.53 5.26 Ads 42 0706998-002A SAMP GPS EFF; BOD5-C_W 60.00 4.00 8.34 7.06 <2.00 <7.27 vlds 42 0706998-002A TSLO10 W111 SAMP GPS EFF; BODS -C -W 150.00 1 4.00 8.48 5.48 3.00 4.91 ds 42 1 S2 D; Client ID 0706998-002A TSLO10 W112 Client Name; Test Code Type ISAMP IGPS EFF; BODS-C_W Vol I Initial DO Final DO Depletion mL I mL mg/L mg/L mg/L {II 9ss_snsn 4.00 I 8.71 I 2.56 I 6.15 BOD Avg BOD I Flags IRac. mg/L mg/L 5.61 1 ds 142 BOD Flags Fln Flag Description 1 Change in DO is less than 2.0 2 Final DO is less than 1.0 a Sample is a calibration sample (ie `calibrate#') A Sample was voided by the Additional Rules for Reportability D Sample was diluted through the Auto Dilution component of control 1 E Sample is a `Seed' control sample F Sample has failed the EC requirements g `Check' sample has failed the Check Sample initial DO range criteria G `Check' sample has failed the Check Sample final DO range criteria M Sample has exceeded the specified Maximum Variance for the incubation period o Sample reading is unstable - Stabilization Timeout occurred (Initial DO) 0 Sample reading is unstable — Stabilization Timeout occurred (Final DO) q `Check' Sample has failed the Check Sample Standard Deviation criteria (Initial DO) Q `Check' Sample has failed the Check Sample Standard Deviation criteria (Final DO) R `Check' sample BOD value is out of range s Seed or ATU has been added to the'sample t Initial Temperature is out of range T Final Temperature is out of range U Sample set is determined to be statistically unreliable(bactericidal effect indicated),by the Additional Rules for Reportability v Sample has been voided (i.e. failed rule) V Blank Check sample has exceeded the specified maximum value w Sample is suspected of being toxic X Blank, Seed or Spike sample has failed a rule and is not used when calculating the correction factor y Sample has surpassed Supersaturation level specified in setup (Initial DO) Y Sample has surpassed Supersaturation level specified in setup (Final DO) Z A Check sample's BOD Standard Deviation exceeds the Maximum Standard Deviation Page 1 of 1 I lH2M TAUS, INC. COD Anal Lst: Date: Start time: CLIENT SAMPLE ID LAB# MLS USED ABS. DILUTIONS MGIL NOTES ICV (1000 MG/I D, ZQ PX 2- P ICB d, 000 Z/b 2 g 3 —O.Oqq 4 Id 2- 5 ftn 1912-1 YYV X2, V! �7 7 6 MY/ 7 mhl z /d 8 wo t 9 10' Aw4p .0& —CCV(1000MG11) 1603 h,3 CCB Z 0-000 -//0 MIS 0 70,/f <2 M Z 0,02-6 2 661 //0 3 0 4 -2- Doi <iD /0 5 10 ---- ON �—CCV(1000MGIQ CCB 0'roo NO Calibration 12/28/2006 conc abs 0 0 10 0.005 50 0.021 250 0.105 500 0.202 750 0.293 1000 0.398 Intercept (b) -4.715 slope (m) 2532 r 0.9998 TSLO10 W115 COD Calibration 12/28/06 1100 = 532.2x - 4.715 1000 900 800 —� 700 E 600 o conc 500 linear (conc) = 400 v 300 200 100 0 -100 42 Absorbance Page 1 of 1 -32L//S j&iP46 INC. 14ARDNESS DATE: ANALYST: TITRANT 0 I N P i D 02 2 Mw -Bb fn LU _ �{ y'S S S3s:5,- 3 s z M09 Author: cmo Original Run Filename: Original Run Authors Signature: Current Run Filename: Current Run Author's Signature: Description: H21VI Labs. Inc. Date : 6/28/2007 OM_6-28-2007_01-03-33PM.OMN created 6/28/20071:03:33 PM [cmo] nh3062807a.omn last modified 6/28/2007 1:57:08 PM [cmo] Default New Run f r_7SL D lD Sample I Cup No. Channell Conc. (mg/L Area ADF s MDF "CalStd7:ical7:nh3 w" S1 3.000 51.199 True "CalStd6:ical6:nh3 w" S2 1.000 16.049 "CalStd5:ical5:nh3 w" S3 1 0.500 7.863 "CalStd4:ical4:nh3 w" S4 0.200 3.034 _ "CalStd3:ical3:nh3 W' S5 0.100 1.558 _ "CalStd2:ical2:nh3 w" S6 0.050 0.904 "CalStdl:icall:nh3 w" S8 0.000 0.040 "CRA:cra:nh3 w" S5 0.111 1.580 Known Conc: 0.100 Calibration: Table/Fig. 1 "LCS-21521:LCS:nh3 W' 1 2 1.084 18.203 Known Conc: 1.000 "mb-21521:mblk:nh3 W' 1 1 0.010 -0.142 Known Conc: 0.000 "0706952-001B:SAMP:NH3 W' 3 0.134 1.973 "0706952-002B:SAMP:NH3 W' 4 0.785 13.095 "0706952-003B:SAMP:NH3 W' 5 3.933 6.404 10.00 "0706952-004B:SAMP:NH3 W' 6 5.060 8.329 10.00 "0706952-004BMS:MS:NH3_W' i 7 16.507. 10.00 "0706952-004BDUP:DUP:NH3 W' I 8,_ _9.848 4.960 8.159 10.00 "0706952-005B:SAMP:NH3 W' 9 -{ - 0.532 8.778--- "0706952-006B:SAMP:NH3 W' _ 10 - 0.238 3.746 "0706952-007B:SAMP:NH3 W' ! 11 0.088 1.1_ 971 1 "0706952-008B:SAMP:NH3_W' 12 3.871 6.3001 10.00 "CCV:CCV:NH3 W' S2 0.957 16.0371 Known Conc: _ 1.000 _ "CCB:CCB:NH3 W' S8 0.015 -0.061 _ Known Conc: 0.000 "0706952-009B:SAMP:NH3_W' j 13 5.632 9.307 10.00 i "0706952-010B:SAMP:NH3 W' i "0706986-001B:SAMP:NH3_ W' "0706986-002B:SAMP:NH3 W' 14 _ 15 16 _ 0.008 -0.183 _ 0.211 3.2901 i 1 0.065 0.801 "0706986-00313:SAMP:NH3 W' 177 11.011 9.090 20.00 "0706986-004B:SAMP:NH3 W' 18 3.473 5.620 10.00 "LFB-21521:LFB:nh3_W' �+ 19 i 5.174 ^i 8.525 ; 10.00 "LFBD-21521:LFBD:nh3 W' j 20 5.191 8.554 10.00 "CCV:CCV:NH3 W' S2 0.959 116.073 i Known Conc: _ 1.000 i "CCB:CCB:NH3_W' _ i S8 j _ 0.016 -0.043 _ _ Known Conc: , 0.000. Analyte Properties Table for nh3062807a.omn Property Channel 1_' �i i NH3 Concentration Units I r mq% ( Gallibration Fit type ;_t -first Uraer 1 Clear Calibration_ -�_ - True I Force Thro�_Zero _False Calibration Weighting ! None Auto Dilution Tri er ' True _ of High Standard 100 Quik Chem Method _ I Run: nh3062807a -1 - J 0 G / 08, 04 71 Go. 54y 1'?. j�10=Sa.� Xlu P� o°lo << to [ 0 LID, I FIA X c w 0 am N O O 4 w TSLO10 W118 CD CD N _ Volts N w m o CaIStd6:ical6:nh3 w" �o 3 m o "CaIStd5:ical5:nh3 w" 0 0 3 N "CaIStd4:ical4:nh3_w" c) C) —o l.' r "CalStd3:ical3:nh3_W" C:, c:' =o O o "CalStd2:ical2:nh3_w" 0 3 cn o "CalStdl:icall:nh3_w" 0 0 P "CRA:cra:nh3 W r/ W !` O w S P, to co rn w Wo "CalStd7:ical7:nh3_ 0 0 m, r•-- o "LCS-21521:LCS:nh3_W" m 3 I0 r= "mb-21521:mblk:nh3 W" n w 7 m O s u v R -n Volts C.0 co 00 QI P "CCV:CCV:NH3— W, Ln -4 3 o"CCB:CCB:NH3—VV' cn "0706952-009B:SAMP:NH3 7 VT cri 0) 3 C:' "0706952-01OB:SAMP:NH3 VT o co 3- [,,N "0706986-OOIB:SAMP:NH3—W'. 3 . io F:;;0706986 -002B: SAM P: NH3—VV' Cj) Cil cp "0706986-003 B: SAM P: NH3—VV' cp 3 P "0706986-00413:SAMRNI`13 VT c:' "LFB-21521:LFB:nh3 VT "LFBD-21521:LFBD:nh3—V\P' 3 IQ N) rTSLO10 W119 FE 4, w m 0) CD O Volts K) w (0 co co co P "0706952-001B:SAMP:NH3 W' .—B . ...... . ........ c:' "0706952-002B:SAMP:NH3 W' —4 co 3 c:) "0706952-0036:SAMP:NH3 W' tw 1 C w06952-004B:SAMP:NH3 W' 0) __.-.--3.._.._......t P "0706952-0046MS:MS:NH3 W' to co o.. i:A 0706952-0046DU P: DU P: N H3—VV' 10) fn "0706952-005B:SAMP:NH3 W" IN 3 F -L- P "0706952-006B:SAMP:NH3 VT CA 03 C) "0706952-007B:SAMP:NH3 W" 00 "EP "0706952-008B:SAMP:NH3 W' 00 LTI VI co Author: cmo 1-12M Labs. Inc. Date : 6/28/2007 Channel 1: Set 4 of 4 4.963--- .963 -- 3.698-.-- 3.698--- C o = > z U UCO = 2 0.959 mg/L z m U U M i U 0.016 mg/L 1.238 ..; . ; 2438.6 Table 1: NH3 Time (s) 3319.1 I Conc. (mg/L) I Rep Peak Area (Volt -s) iPeak Height (Volts) CO Detection Date Detection Time 1 3.000 1 51.1991 2.450 -0.6 6/28/2007 1:10:26 PM 2 �— 1.000 i 1 0.775 4.3 6/28/2007 1:11:38 PM 3 0.500 _(__ 1 _16.049 I 7.863 _ 0.380 4.4 6/28/2007 1:12:51 PM i 4 0.200 1 -1_ - 3.034 0.14812.4 ; 6/28/2007 1:14:04 PM 5 _ 0.100 j _ 1�— 0.0751 -11.31 6/28/2007 1 1:15:17 PM 6 0.050 10.9041 0.044 -65-.31 6/28/2007 1 1:16:30 PM Table 1: NH3 Time (s) 3319.1 I Conc. (mg/L) I Rep Peak Area (Volt -s) iPeak Height (Volts) % Residual Detection Date Detection Time 1 3.000 1 51.1991 2.450 -0.6 6/28/2007 1:10:26 PM 2 �— 1.000 i 1 0.775 4.3 6/28/2007 1:11:38 PM 3 0.500 _(__ 1 _16.049 I 7.863 _ 0.380 4.4 6/28/2007 1:12:51 PM i 4 0.200 1 -1_ - 3.034 0.14812.4 ; 6/28/2007 1:14:04 PM 5 _ 0.100 j _ 1�— 0.0751 -11.31 6/28/2007 1 1:15:17 PM 6 0.050 10.9041 0.044 -65-.31 6/28/2007 1 1:16:30 PM 7 1 0.000 1 1 0..04 —� 0.0021 1 6/28/2007 1:17:45 PM Figure 1: NH3 51.199, i > I a@i m � I 19 NH3 concentration, mg/L 3.000 Area = 17.071 ' Conc - 0.307 Conc = 0.059 ' Area + 0.018 Correlation. Coefficient (r) = 0.99975 No Weighting Run: nh3062807a - 4 - FIA H AMMONIA DISTILLATION NAME: Al,';,H DATE: 6 -� = - /1Z LAB NO. CLIENT ID SAMPLE WEIGHT GRAMS SAMPLE VOLUME MLS FINAL VOLUME MLS DATE ANALYZED SPIKE SYJfl 1001S- 'o?9P-00(h bo s'o IS2- voth wt - Y(J SO 9s2 - vo3 m �-v — k W2-oay 9Sl-00 Rsz - 9sz- oofh. �s S s10 9.Q- 001 ;4 -dry so 9st - 0 W Ui ` 6.� S0 --yri-09W JAU,tL !tp jgj- 0lob 9b6 -cF°3 ha ►� - 3IJ S X g -0o b ►u 3.5 10 p 003 2 404 � 08-los- Author: fs-Author: bnk H21VI Labs. Inc. Date : 6/25/2007 Original Run Filename: OM_6-25-2007_11-33-40AM.OMN created 6125/200711:33:40 AM Original Run Author's Signature: [bnk] Current Run Filename: no3062507.omn last modified 6/25/2007 12:30:25 PM Current Run Author's Signature: [bnk] Description: Default New Run Sample Cup No. Channel 2 Nitrate as NConc. (mg Area . ADF MDF I NIL s "Cal Std 5:ical5:no3 dw" 31 2.000 21.961 "Cal Std 4:ical4:no3 dw" S2 1.000 11.053 "Cal Std 3:ical3:no3 dw" S3 0.500 5.461 "Cal Std 2:ical2:no3 dw" S4 0.100 1.111 "Cal Std 1:icall:no3 dw" S5 0.050 0.583 "Cal Std O:ical0:no3 dw" S16 0.000 -0.002 "CRa:cra:no3 dw" S4 0.100 1.114 Known Conc: 0.100 Calibration: Table/Fi . 1 "LCS-062507:lcs:no3 dw" 1 S6 1.14812.623 Known Conc: 1.130 "MB-062507:mblk:no3 dw" S16 0.000 0.014 s Known Conc: 0.000 "ref-47859:SAMP:NO3 W" 1 2.849 6.271 5.00 'ref-47859:SAMP:NO3 W' 2 2.844 6.260 5.00 "0706803-005A:SAMP:NO3 W' 3 1.707 3.763 5.00 "0706803-005AMS:MS:NO3 W' 4 4.329 9.523. 5.00 "0706803-005ADUP:DUP:NO3 W' 5 1.712 3.774 5.00 "0706942-001A:SAMP:NO3 W' 6 1.522 3.355 5.00 "0706942-002A:SAMP:NO3 W' 7 5.190 5.713 10.00 "0706952-001B:SAMP:NO3 W' 8 8.480 -9.3261 10.00 "0706952-002B:SAMP:NO3 W' 9 8.555 9.409 10.00 "0706952-003B:SAMP:NO3 W' - 10 0.015 OA74 "CCV:CCV:NO3 W' S2 1.030 11.329 Known Conc: 1.000 "CCB:CCB:NO3 W' I S16 -0.000 0.010 Known Conc: 0.000 "0706952-004B:SAMP:NO3 W' 11 0.008 0.106 ! "0706952-004BMS:MS:NO3 W' 12 0.533 5.871 "0706952-004BDUP:DUP:NO3 W' 13 0.010 0.118 "0706952-005B:SAMP:NO3 W' 14 7.165 7.882 10.00 "0706952-006B:SAMP:NO3 W' 15 7.759 8.535 10.00 "0706952-0078:SAMP:1\103 W' 16 0.487 5.364 7'0706952-008B:SAMP:NO3 W' 1 17 0.011 0.139 "0706952-009B:SAMP:NO3 W' 18 1 0.010 0.125 "0706952-010B:SAMP:NO3 W' 19 0.023 0.269 "0706986-001 B:SAMP:NO3 W' 20 2.887 6.356 5:00 "CCV:CCV:NO3_W' S2 ! 1.040 11.436 Known Conc: 1.000 I "CCB:CCB:NO3 W' 1 S16 -0.000 0.0111 Known Conc: ! 0.000 "0706986-002B: SAM P: NO3 W' 21 5.1991 5.723 i 10.00 "0706986-003B:SAMP:NO3 W' 22 0.0221 0.260 1 "0706986-00413:SAMP:1\103 W' 23 0.0201 0.232 , I "0706998-001A:SAMP:NO3 W' 24 0.04811 0.540 "0706998-002A:SAMP:NO3 W' 25 0.7791 1.724 15.00 i "LFB-062507:lfb:no3 dw" 26 j 0.514 j 5.6631 ! "LFBD-062507:lfbd:no3 dw" 27 ! 0.511 5.631 i t "CCV:CCV:NO3, W' S2 1.031 Known! 1.000 "CCB:CCB:NO3 W' ! S1616 j_ -0.0001 Known Conc: j 0.000 j 11.341 ! 0.0121 � Run:no3062507 -1 - v- i �3 ,L 4-<- /002 r®. I -1= �? • 7.f 0•S 0/� c - ivy% 11 = 2 P9 D`la. 'P,Z-C. 103 1, iv= 0.50 IL °&C i S -CA P"Ob I v/. .7 Re.c.. to S'I , 0 - FIA Author: bnk H2M Labs. Inc. Analyte Properties Table for no3062507.omn Property Channe12 Nitrate as N Concentration Units mg N/L Callibration Fit Type First Order Clear Calibration True Force Through Zero False Calibration Weighting None Auto Dilution Trigger True % of High Standard 100 Quik Chem Method 10-107-04-1-C Chemist Direct/Bipolar Calibration by Height False Inject to Peak Start 14 Peak Base Width 73 Channel 2 (No2/No3) : Set 1 of 4 3.338 3 al M O Ce) 0 i3 C 0 O Cn N O O J UI 1.148 mg OL 3 c U) of E U � LO 2.000 mg CO'L N 2.283 0.100 riq NIL v 3 O > O c I � a 1.000 mg w L o N ml 0 0.500 mgu5L 6 v N =, f0 U W U I 0.100 mrg,0 mg 0.000 mg NIL 0.546-- .546-,78.2 _ 78.2 Time (s) Date : 6/25/2007 0:570 mg0.569 mg NIL NIL 972.4 Run: no3062507 - 2 - FIA 3 al Ce) 0 i3 0 O Cn N O O J UI 1.148 mg OL 3 c of E C 1 LO U N U 0.100 riq NIL Date : 6/25/2007 0:570 mg0.569 mg NIL NIL 972.4 Run: no3062507 - 2 - FIA Author: bnk H2M Labs. Inc. Channel 2 (No2JNo3) Set 2 of 4 3.338 --- 0 0 0 ce) z U) 2.283-- 2i CO CO : 0 0 2 2 U) < < z CQ ti 0 < 0- 0 CO z LO D cnz C) < Coll ce) 9 C) Ce) U) 9 C 0 � C4 <U) C) D < LO U) z CO 0) M q U) 0 (0 L (D < (D C) LO C) 0 CD C14 C) < C) C) U) C) c) 0.866 mg N& C14 0.848 m 0.1355 mg CO C3 CD (0 CO 0) (D p CD C) p /L M Q 0.519 m M CN (D 0.341 m 0.342 mg !304 m� p 1 0.01 0.546 972.4 Time (s) Channel 2 (No2/No3) : Set 3 of 4 3.338-1 Date : 612512007 CO 0 z OI 0 2 1.030 mg < U) 0 Z 6d 9 cli LO M (0 C) Ce)l Ce) 0 0 z CQ L 1 2.283 z 0 0 0 CQ 0 CO z &ja_ Z - z 0 UJ < ie Cl) 156 2 0 m CD < > z CO Ce) q� 0 0 0 CO ca C) C? C\1 Ca z z z 0 O to CA 03 U') C)d a d 0 C� CL 0) (0 9 �5 2 2 (6 LO (0 0 C\1 < < < OD 1.040 mg 0 C) r- LO U) 0) 1 "� M 0 r— p 0) (D CO CD M (0 ca C) CD 'r CO M P— 0 t*- , 1�76 mg e p z C) C) C) C) 0.716 m C) 9 R N C\j 0.577 m L LO to 0.533 mg Ng 0.487 9 t4 L) 0) (0 (0 (D o ` �- 0 0 p 10 q OF.010 mg Nk 0.011. mg WID mm NIL -0- 0.546 1770.3 Time (s) Run: no3062507 -3- 3 mg N/L 1770.8 0O.O.mg N/L 2571.3 O O FIA Author: bnk 1-12M Labs. Inc. - Rep Peak Area (Volt -s) Date: 6/25/2007 Channel 2 (No2/No3) : Set 4 of 4 I Detection Date I - Detection Time 1 2.000 1 3.338 -- 1.736 0.1 1 6/25/2007 ( 11:36:25 AM 2 1.000 1 11.053 0.874 -0.5 6/25/2007 ! 11:37:37 AM 2.283 Oo a. S 1 5.461 0.429 0.8 a.MI 11:38:49 AM Mi Cl)I O Z 1.111 j OMI MOI C.O. 0 � z c � U 0.050 Z z o n n CL o ti � > U 11:41:16 AM O C ¢ Q U LON 0 = 1.031 mg Mki 6/25/2007 Q CO C)r� C) 'ITm O O o o O O m LL --� LL J O Z�. 0.520 mg t 0 0.514 mg t�1511 mg N/L v —j o o o o I m i o o 0.156m NL U 0.546 ...:. ; i i 0.022 mg I0ID20 m IQ/Q48 ,�( `_ �1 ! -0.000 m NIL 9 ...... 2571.7 Time (s) 3372.6 Table 1: Nitrate as N Figure 1: Nitrate as N 21.9611 c� ca Q d I 1-4 moo Nitrate as N concentration, mg NIL 2.000 Area =10.983 * Cone + 0.013 Cone = 0.091 * Area - 0.001 Correlation Coefficient (r) = 0.99999 No Weighting Run: no3062507 - 4 - FIA Conc. (mg NIL) - Rep Peak Area (Volt -s) Peak Height (Volts) % Residual I Detection Date I - Detection Time 1 2.000 1 21.961 1.736 0.1 1 6/25/2007 ( 11:36:25 AM 2 1.000 1 11.053 0.874 -0.5 6/25/2007 ! 11:37:37 AM 3 0.500 1 5.461 0.429 0.8 6/25/2007 11:38:49 AM 4 0.100 1 1.111 0.0871 0.0 6/25/2007 11:40:02 AM 5 0.050 1 0.5831 0.045 -3.8 6/25/2007 11:41:16 AM 6 0.000 1 -0.002 -0.000 6/25/2007 11:42:30 AM Figure 1: Nitrate as N 21.9611 c� ca Q d I 1-4 moo Nitrate as N concentration, mg NIL 2.000 Area =10.983 * Cone + 0.013 Cone = 0.091 * Area - 0.001 Correlation Coefficient (r) = 0.99999 No Weighting Run: no3062507 - 4 - FIA U284 "US, Isco Phenols Method 420.1 Distillation Date: 41 -0 Time; q :90 PClg, 0/o Analyst: t i v Date: -2 -0 'CLIENT ID# ICV (30 UG/L) ICB H2M LAB# ImL SAMPLE GRAMS DISTILLED USED 50 NONE ABS 0.OQry UG/L DILUTION 1s. o UG/L MG/KG %TS NOTES/CALCULATIONS LS O 5 UG/L STD NONE 49-010 Y PREP BLANK 50 p COP zr.0 Zr. 0 1 6 07049S,2- 01 SO 40.49.00 15.,0 • .l " 0 2 0.00 -r. .c S, J 3 -mo , 00 y 15.0. 15.0 4 wyi •4949 � m. Od ' zS`. 5 nti - o.OS .�, 6 7 8 - ,f .. T -Q08 9'Sl-ooh p, o 0 of 0. coy .l^. dS,o L�.D -, S^. o eS'O 0 CCV (30 UG/L) 50 0 06 _ b 2 ` CCB NONE 0.00,0 .LSA., O 6 0 0640x•049 S4 0.00( 2 x - p -ov? 49.0 2. 3 S 9•a - w9h .'0 �S 4 F qD-010A0. 4949,49 CS, o .t S'. -O 5 rt — (m -,00r 8 0. o o5 .IS O 6 Wt V-00ZA00 [g, O 1 Z,! .10 8 0.00S zs",o DUP SPK (20 UG/L) CCV (30 UG/L) 50 CCB NONE p, 000 TSL010 W126 Phenols p 0029 Calibration 6-25-07 conc abs 0 0.000 1 0.002 2 0.003 5 0.01 10 0.02 20 0.050 30 0.072 40 0.098 50 0.123 Intercept (b) 0.6807 slope (m) 401.78 r 0.9994 TSLO1O W127 Phenol Calibration 6/25/07 60 50 =-401.78x + 0.6807 0z40- CD ♦ conc 30 —Linear (conc) 0 V 20- 10- 0 0100 0.000 0.050 0.100 0.150 Absorbance Page 1 of 1 HDried Wt.(q)-Tare Wt. (g)W000W000 Solids(mgil)= mL Sample ANALYST:RAJ, DATE: 6,119AJ-7 START: ,aOLIDS DS)/ SS/ TS r. TEMP. 5L () P 60D011oly LAB # CLIENT ID PAN/ CRUC. SAMPLE (ML) DRIED WT (G) 'TARE WEIGHT (Gy SOLID WEIGHT (G) RESULT MGIL DRIED WT (G) IGNITED '�NrUEJD G VOL. WT (G Vo E 1vo S. (MGIL) % AT-? 61c, MOO X Ll 160 /a./IV /a6 479 01 OYP"', 1;11 -OD AW,q5lb 2S -3 14. �7dZ loVh 2-5- Z. 3027 1,:xM o,o;e:6 y SZ 0Dyhf,7j 2,,( /, I $f* /Lv9 /;Wo e, 0 30,5( o. 01DYM joV OUA /�o tm zyf5" 12V 2/ _ / � 0. 0 �37' /. ;5.�, TSL010.W128 824 CI �— mon LIDS . [{Dried wt fal Tare wt (a)?x10001x10Q0 Solids(mgll)= mL Sample D SSI TS ANALYST: U TEMP. DATE: �J START: HUMIDITY: PAN! SAMPLE DRIED TARE SOLID RESULT DRIED IGNITED VOL. VO E CLIENT ID CRUC. ML WT G WEIGHT G WEIGHT G MGfL WT G WT G WT G S, (MGIC) LAB # , ✓. co 7, 02' 0-02,0 v�45 Ai e2 -57y 7 A /k2 co o �J azo /DSI a o0. of' /05 D.wZ 2y Z -y .2 //,g 2o®.-n3Y 3 TSLO 10 W129 83 ' . JL -4 i =aJ Lu,a"' SOLIUS rfDried Ma) - Tare Wt. (g)WOOM1000 /�/ SS/ TS Solids(mg/l)= mL Sample ANALYST: 1 I / D lei 0'r A 01r. TEMP. ul I"lr%l"rv. LAB #' CLIENT ID PAN/ CRUC. SAMPLE (ML) DRIED WT (G) 'TARE WEIGHT (G) SOLID WEIGHT (G)', RESULT MG/L DRIED WT (G) IGNITED WT (G) VOL. WT (G) VOLATILE RES. (MGIL) Oro 07 ..�� y �l� /0�6� /o�� 3 0 . ��� 2 � -rte 39 /Z 10Y2 IdY, /0 � 37F 0 2-0' om /100 X ,X 1,116� Xo/ AP 4 7 �%44 /4, �- ,7 lwlaTo 0,5,y-- 77 60 V 10-5- 1:0,3 e, X7777 TSLO10 W130 ffDried WUM - Tare Wt. (g))x1000lxl000 Solids(mg/l)= mL Sample ANALYST: c TEMP. - IDS TDS••� SS/ TS LAK Ir_:. i/ LAB # v CLIENT ID �,.,,.,. PAN/ CRUC. SAMPLE ML ......... DRIED . WT G TARE WEIGHT G SOLID WEIGHT G RESULT MG/L DRIED WT G IGNITED WT G VOL. WT G VOLATILE _ RES. MGIL 32iz 5V ��� ae-vi �� y /o,/02 o.0;,& 3P6 ( TSLO10 W131 85 0 _.._..:............_.......-----._._----- . Effective immediately, when analyzing any matrix other than potable water for TDS, l ity of the sample and record it in the last column of the logbook. please take the conductivl Please use the following guide for dilutions based on the conductivity. All potable water samples should be analyzed at 100 mis. For fresh kills total and filtered samples use the same amount of sample volume for both sets -of samples. FKNData Peak SamplelD Concentration listed after Optical Blank Correction. Preparation dilution factor not applied to results. SampTy Cone Units DF Cone x DF AnalDate TS AnalTime TestCod 1 Primer PRIM 3 mg/1 1 L� 6/26/2007 01:18:09 PM tkn_w 2 Drift DRIF 3.01 mg/I 1 3.01' 6/26/2007 01:18:50 PM tkn_w 3 High HIGH 3.03 mg/I 1 3.03 6/26/2007 01:19:30 PM tkn_w 4 Low LOW 0.02 mg/1 1 0.02 6/26/2007 01:20:08 PM tkn w 5 Low LOW 0.02 mg/I 1 0.02 6/26/2007 01:20:38 PM tkn_w 6 Cal. CALB 3.01 mg/I 1 3.01 626/2007 01:21:30 PM tkn_w 7 Cal. CALB 0.97 mg/1 1 0.97 6/26/2007 01:22:01 PM tkn_w 8 Cal. CALB 0.49 mg/I 1 0.49 6/26/2007 01:22:47 PM tkn_w 9 Cal. CALB 0.21 mg/I 1 0.21 6/26/2007 01:23:20 PM tkn_w 10 Cal. CALB 0.11 mg/I 1 0.1 I 6/26/2007 01:24:08 PM tkn_w 11 Cal. CALB 0 mg/I 1 6/26/2007 01:24:51 PM tkn_w 12 OPTICAL BLK QUAL 0.82 mg/1 1 0.82 6/26/2007 01:25:28 PM tkn_w 13 Ics 21468 ICS 0.47 mg/I n 10 4.7 6/26/2007 rn2ct4101:26:08 PM tkn_w 14 mb21468 mblk 0 mg/I 1 6/26/2007 GD' 1 01:26:50 PM tkn_w 15 ref47860 SAMP 1.65 mg/I 10 16.5 6/26/2007 01:27:30 PM tkn_w 16 ref 47860 I�l SAMP 1.676 mg/I 10 16.76 6/26/2007 01:28:08 PM tkn_w 17'0706803-005A SAMP 3.05 mg/I 5 15.25 6/26/2007 01:28:52 PM tkn_w 18 0706803-005AMS ms 1.771 mg/1 20 35.42 6/26/2007 01:29:28 PM tkn_w 19 0706803-005ADUP dup 3.05 mg/1 5 15.25 6/26/2007 01:30:12 PM tkn_w 20 0706952-OOIB Mk%' 1") SAMP 1.01 mg/I 1 1.01 6/26/2007 01:30:48 PM tkn w 21 0706952-002B SAMP 0.25 mg/I 10 2.5 6/26/2007 01:31:28 PM tkn_w 22 0706952-003B q S SAMP 0.6572 mg/1 50E-----32.786 6/26/2007 01:32:09 PM tkn_w 23 0706952-004B `, SAMP 3.145 mg/1 10 31.45 6/26/2007 01:32:52 PM pp ikn_w 4-1,, -z- iC111 24 0706952-004BMS ms 0.445 mg/1 10 4.45 6/26/2007 01:33:28 PM Isva- tkn_1113 I p 25 CCV 1.0 ccv 0.97 mg/I 1 0.97 6/262007 r1� 01:34:08 PM tkn w 26 CCB ccb 0.01 mg/1 1 0.01 6/26/2007 G.0+101:34:52 PM tkn_w 27 0706952-004BDUP dup 3.153 mg/I 10 31.53 6/26/2007 01:35:32 PM tkn_w�'-� ^ _ 28 0706952-005B M u1- = s SAMP 0.16 mg/I 10 1:6 6/26/2007 01:36:08 PM tkn_w 29 0706952-006B tO' SAMP 0.089 mg/I 10 0.89 6/26/2007 01:36:49 PM tkn_w 30 0706952-007B jp S SAMP 0.0515 mg/l 20 1.03 6/26/2007 01.37.28 PM tkn_w ' C/) 762007 5:58:29 PM Pagel of 3 ?eak SampleID SampTy Cone Units DF Cone x DF AnalDate AnalTime TestCod 31,0706952-008B SAMP 3.154 mg/l 10 3 L54 6/26/2007 01:38:12 PM tkn_w �j ez- o IX 32 0706952-009B o SAMP 3.125 mg/l 10 31.25 6/26!2007 01:38:51 PM tkn_w/ 33 0706952 -OI OB SAMP 0.46 mg/l 1 0.46 6/26/2007 01:39:27 PM tkn_w t2a�Vtj Jtr •b�+i fi 34 0706986-00I B 117 U -J -1 SAMP 0.76 mg/l 1 0.76 6/26/2007 01:40:10 PM tkn_w 35 0706986-002B 1 SAMP 0.53 mg/l 1 0.53 6/26/2007 01:40:48 PM tkn_w 36 0706986-003B 3 1) SAMP 2.5546 mg/l 50 127.73 6/26/2007 01:41:30 PM @@LL tkn_w !� 37 CCV 1.0 ccv 0.97 mg/l 1 0.97 6/26/2007�r01:42:10 PM tkn_w 38 CCB ccb 0.02 mg/l 1 0.02 6/26/2007" ( 01:42:49 PM tkn_w 39 0706986-004B i"1 W 35 SAMP 2.104 mg/l 10 21.04 6/26/2007 01:43:30 PM tkn-w 40 0706928-OOIA SAMP 1.453 mg/l 10 14.53 6/26/2007 01:44:09 PM tkn-w 41 0706928-002A - SAMP 1.7915 mg/l 20 35.83 6/26/2007 01:44:50 PM. tkn_w ., 42 0706942-OOIA SAMP 0.574 tng/l 10 5.74 6/26/2007 01:45:29 PM tkn_w 43 0706942-002A SAMP 0.403 mg/l 10 4.03 6/26/2007 01:46:05 PM tkn w 44 0706998-OOIA SAMP 1.314 mg/l 10 13.14 6/26/2007 01:46:50 PM tkn-w 45 0706998-002A SAMP 1.9465 mg/l 20 38.93 6/26/2007 01:47:27 PM tkn_w 46 0707084-OOIA SAMP 0.515 mg/l 50 25.75 6/26/2007 01:48:01 PM tkn-w 47 0707158-OOIA SAMP 1.246 mg/l 10 12.46 6/26/2007 01:48:47 PM tkn_w 48 0707158-002A SAMP 1.9125 mg/l 20 38.25 6/26/2007 01:49:27 PM tkn_w 49 CCV 1.0 ccv 0.96 mg/l // 1 0.96 6/26/2007 1446 1:50:07 PM tkn_w 50 CCB ccb 0.02 mg/l I 0.02 6/26/2007 , 1 01:50:53 PM tkn_w 51 0707160-OOIA SAMP 0.346 mg/l 10 3.46 6/26/2007 01:51:25 PM tkn_w 52 0707170-OOIA SAMP 0.788 mg/l l0 7.88 6/26/2007 01:52:06 PM tkn_w 53 0707170-002A SAMP 0.157 mg/l 10 1.57 6/26/2007 01:52:42 PM tkn_w 54 0707210-OOIA SAMP 0.2076 mg/l 50 10.38 6/26/2007 01:53:28 PM tkn_w 55 0707212-OOIA SAMP 1.269 mg/l 10 12.69 6/26/2007 01:54:06 PM tkn_w 56 0707212-002A SAMP 0.196 mg/l 10 1.96 6/26/2007 01:54:48 PM tkn w 57 Ifb21468 Ifb 0.466 mg/l 10 4.66 6/26/2007 t�,_U lgt01:55:26 PM tkn_w 58 lfbd2I468 Ifbd 0.468 mg/l 10 4.68 6/26/2007 401:56:05 PM tkn_w 59 CCV 1.0 ccv 0.96 mg/l 1 0.96 6/26/20071q� 01:56:47 PM tkn_w M 60 CCB ccb 0.02 mg/l 1 0.02 6/26/2007[x. ` 01:57:33 PM tkn_w 61 Drift DR1F 3.01 mg/l 1 3.01 6/26/2007 01:58:07 PM tkn_w O O DO 6/26/2007 5:58:29 PM Page 2 of 3 Peak SampleID SampTy Cone Units DF Cone x DF AnalDate AnalTime TestCod 62 End END 0.01 mg/l 1 0.01 6/26/2007 02:00:29 PM tkn_w 5/26/2007 5:58:29 PM Page 3 of 3 BRAN+LUEBBE AACE 5.48 Post -run Report H2M Labs Inc. Post -run report Name of Run tkn062607aRl Name of Analysis :TKN.ANL Date of Report 6/26/2007 System No. :1 Date of Run 6/26/2007 Type of System :TRAACS Operator bnk Start/Stop time :13:06 - 14:00 Comment Unit 21468 mg/l mg/1 Channel Type Real Data Channel 2 2 Method Method 2 Dilution Unit mg/l mg/1 Calibr. Fit Linear Corr. Coeff. 0.9999 Base 54 Gain 28 Sensitivity 0.4145 Sample Limit 1 Sample Limit 2 A Id Valuea,,1'e" Pk Cup Sample l \J 0 0 B Baseline 0.01 V�� 0 V�� U 1 1 P Primer 3.00 1 2 1 D Drift 3.01 1 3 1 H1 High 3.03 1 4 0 L1 Low 0.02 1 5 0 L1 Low 0.02 1 6 1 C Cal. 3.01 1 7 2 C Cal. 0.97 1 8 3 C Cal. 0.49 1 9 4 C Cal. 0.21 1 10 5 C Cal. 0.11 1 11 0 C Cal. 0.00 1 12 6 QC1 OPTICAL SLK 0.82 1 13 9 QC1 lcs 21468 5.52 10 14 10 QC1 mb21468 0.82 1 15 11 S ref 47860 17.32 10 16 12 S ref 47860 17.58 10 17 13 S 0706803-005A 16.07 5 18 14 S 0706803-005AMS 36.24 20 19 15 S 0706803-005ADUP 16.07 5 TKN.ANL / tkn062607aRl.run Page 1 BRAN+LUEBBE AACE 5.48 Post-run Report 20 16 S 0706952-001B 1.83 1 21 17 S 0706952-002B 3.32 10 22 18 S 0706952-003B 33.68 50 23 19 S 0706952-004B 32.27 10 24 20 S 0706952-004BMS 5.27 10 25 2 QCl CCV 1.0 0.97 1 26 0 QCl CCB 0.01 1 27 21 S 0706952-004BDUP 32.35 10 28 22 S 0706952-OOSB 2.42 10 29 23 S 0706952-006B 1.71 10 30 24 S 0706952-007B 1.85 20 31 25 S 0706952-0088 32.36 10 32 26 S 0706952-009B 32.07 10 33 27 S 0706952-OIOB 1.28 1 34 28 S 0706986-OOIB 1.56 1 35 29 S 0706986-002B 1.35 1 36 30 S 0706986-003B 128.55 50 37 2 QC1 CCV 1.0 0.97 1 38 0 QC1 CCB 0.02 1 39 31 S 0706986-004B 21.86 10 40 32 S 0706928-001A 15.35 10 41 33 S 0706928-002A 36.65 20 42 34 S 0706942-001A 6.56 10 43 35 S 0706942-002A 4.85 10 44 36 S 0706998-OOIA 13.96 10 45 37 S 0706998-002A 39.75 20 46 38 S 0707084-OOIA 26.57 50 47 39 S 0707158-OOIA 13.28 10 48 40 S 0707158-002A 39.07 20 49 2 QC1 CCV 1.0 0.96 1 50 0 QC1 CCB 0.02 1 51 41 .S 0707160-OOIA 4.28 10 52 42 S 0707170-OOIA 8.70 10 53 43 S 0707170-002A 2.39 10 54 44 S 0707210-001A 11.20 50 55 45 S 0707212-001A 13.51 10 56 46 S 0707212-002A 2.78 10 57 47 S 1fb21468 5.48 10 58 48 S lfbd21468 5..50 10 59 2 QC1 CCV 1.0 0.96 1 60 0 QC1 CCB 0.02 1 61 1 D Drift 3.01 1 62 0 B FinalBase 0.01 1 M QC Limits e--1 TKN.ANL / tknO62607aRl.run Page 2 BRAN+LUEBBE AACE S.48 Post -run Report Channel 2 QC 1 Unused QC 2 Unused QC 3 Unused QC 4 Unused QC 5 Unused QC 6 Unused QC 7 Unused QC 8 Unused QC 9 Unused QC10 Unused CORRECTIONS Channel Baseline Drift Carry over ** <END OF REPORTS ** 2 Yes Yes Yes 0.9 TKN.ANL / tkn062607aRl.run Page 3 BR,W. LUEBBE AACE 5.48 H2M Labs Inc. Calibration Curve Name of run :tkn062607aR1.RUN Comment Calibration Curve Name of analysis :TKN.ANL Channel :2 Method :Method 2 Curve fit :linear a= -1.2675E-001 b=5.1133E-005 Corr. coeff. :0.9999 Peak [%] 100 80 60 40 20 0 0.00 0.50 1.00 1.50 2.00 2.50 3.00 3.50 Conc. [ mg/l J Page 1 of 1 BRhN.LUEBBE hACE 5.46 H21VI Labs Inc. Post -run chart . Name of run :tkn062607aRl.RUN Comment Post -sun charc Name of analysis :TKN.ANL min Channel 2 Method Method 2 Unit ma/1 Base 54 Gain 28 Corr. 0.9999 2 4 6 8 10 OB 0.01 iP 3.00 12 2D 3.01 3H 3.03 4L 0.02 14 16 5L 0.02 6C 3.01 7C 0.97 Page 1 of 4 Pos. —n char. BRAN.LUE5EE RACE 5.43 ie of run :tkn062607aR1.RUN Name of analysis :TKN.ANL iment min 8C 0.49i I I 9C 0.21I 10C 0.11 18 11C 0.00 12QC1 0.82 13QC1 5.52 20 140C1 0.82 15S 17.32 16S 17.58 22 7S 16.07* 18S 36.24 S 16.07- 24 20S 1.83 21S 3.32 22S 33.66 26 S 32.27* 24S 5.27 25QC1 0.97 28 26QC1 0.01 7S 32.35- 28S 2.42 30 29S 1.71 30S 1.85 S 32.36* 32 S 32.07* 33S 1.28 34S 1.58 34 35S 1.35 36S 128.55 Page 2 of 4 BP.AN.LUEBBE AACE 5..48 :,me of run :tkn062607aRl.RUN mment Post -run chart Name of analysis :TKN.ANL min 37QC1 0.97 36 38QC1 0.02 39S 21.86 40S 15.35, 30 � - 41S 36.65 42S 6.56 43S 4.85 40 44S 13.96 _ 45S 39.75 46S 26.57 42 47S 13.28 48S 39.07 i 49QC1 0.96 44 50QC1 0.02 51S 4.28 52S 8.70 46 53S 2.39 54S 11.20 55S 13.51 48 56S 2.78 57S 5.48 58S 5.50 50 59QC1 0.96 60QC1 0.02 61D 3.01 52 54 62B 0.01 Page 3 of 4 BMIJ.LUEBBE RACE 5.48 ne of run :tkn062607aRl.RUN nment post -run chart Name of analysis :TKN.ANL min 56 f 58 60 62 64 66 68 70 72 Page 4 of 4 ;/a A �P 7 TKNData Peak SampleID Concentration listed after Optical Blank Correction. 4C- %"SL- 0 / Q Preparation dilution factor not applied to results. SampTy Conc Units DF Cone x DF AnalDate AnalTime TestCod I Primer PRIM 2.99 mg/I 1 2.99 6/26/2007 03:14:32 PM tkn_w 2 Drift DRIF 3.01 mgfl 1 3.01 6/26/2007 03:15:14 PM tkn_w 3 High HIGH 3.02 mg/I 1 3.02 6/26/2007 03:15:53 PM tkn_w 4 Low LOW 0.02 mg/I l 0.02 6/26/2007 03:16:31 PM tkn_w 5 Low LOW 0.02 mg/l 1 0.02 6/26/2007 03:17:12 PM tkn_w 6 Cal. CALB 3.01 mg/I l 3.01 6/26/2007 03:17:53 PM tkn_w 7 Cal. CALB 0.97 mg/I 1 0.97 6/26/2007 03:18:24 PM - tkn w 8 Cal. CALB 0.48 mg/I 1 0.48 6/26/2007 03:19:14 PM tkn_w _ 9 Cal. CALB 0.21 mg/l 1 0.21 6/26/2007 03:19:44 PM tkn_w 10 Cal: CALB 0.1 mg/I 1 O.l 6/26/2007 03:20:31 PM tkn_w 11 Cal. CALB 0.02 mgtl 1 0.02 6/26/2007 03:21:13 PM tkn_w 12 OPTICAL BLK QUAL 0.82 mg/l 1 0.82 6/26/2007 03:21:54 PM tkn_w 13 IJ21468 les 0.466 mg/I 10 4.66 6/26/20071,,43:22:30 PM i tkn_w 14 mb121468 mblk 0 mg/I 1 6/26/2007,eo, j 03:23:14 PM tkn_w 15 ref 47860 SAMP 1.652 mg/I 10 16.52 6/26/2007 03:23:53 PM tkn_w 16 ref47860 SAMP 1.669 mg/I 10 16.69 6/26/2007 03:24:32 PM tkn w 17 0706803-005a SAMP 1.4365 mg/1 20 28.73 6/26/2007 03:25:13 PM tkn w 18 0706803-005a ms Tiy y1"$Z, ms 1.698 mg/I i 20 33.96 6/26/2007 %77/ 03:25:45 PM tkn_w 19 0706803-005a dup DUP 1.4525 mg/I 2029.05 6/26/2007 03:26:33 PM tkn_w 20 0706952-0046 'Mtn.c.J - s 1� SAMP 2.8835 mg/I 20 57.67 6/26/2007 03:27:07 PM tkn_w 21 0706952-004bms ms 3.173 mg/I 20E----63.46 6/26/2007 03:27:54 PM tkn w 22 0706952-004bdup DUP 2.977 mg/I 20 59.54 6/26/2007 03:28:28 PM tkn_w �`• 23 0706952-008b ''`' ul `r6 L-� SAMP 2.3475 mg/I 20 46.95 6/26/2007 03:29:12 PM tkn_w 24 0706952-009b &5 SAMP 1.771 mg/I 20 35.42 6/26/2007 03:29:54 PM tkn w pp -�,� W. 1 25 CCV I.0 ccv 0.96 mg/I 1 0.96 6/26%2007 03:30:32 PM tkn_w D i 26 CCB ccb 0.03 mg/I 1 0.03 6/26/2007 03:31:15 PM tkn_w IV 4. 1 27 M 21468 Ifb 0.45 mg/I 10 4.5 6/26/20071103:31:53 PM tkn_w 28 Md 21468 lfbd 0.446 mg/l 10 4.46 6/26/2007 s P 4� 1 3:32:33 PM tkn_w r -I 29 CCV 1.0 ccv 0.94 mg/I 1 0.94 6/26/2007 � Z3:33:13 PM tkn_w r --•i 30 CCB ccb 0.01 mg/l 1 0.01 6/26/2007 60•1 03:33:51 PM tkn_w 6/27/2007 9:17:53 AM Page i of 2 Peak SampleID SampTy Cone Units DF Cone x DF AnalDate AnalTime TestCod 31 Drift DRIF 3.01 mg/I 32 End END 0.01 mg/I 1 3.01 6/26/2007 1 0.01 6/26/2007 03:34:34 PM tkn_iv 03:36:22 PM tkn w 6/27/2007 9:17:53 AM Page 2 of 2 BRAN+LUEBBE RACE 5.48 Name of Run tkn062607bR1 Date of Report 6/26/2007 Date of Run 6/26/2007 Operator bnk Comment 21468 H2M Labs Inc. Post -run report Name of Analysis :TKN.ANL System No. :1 Type of System :TRAACS Start/Stop time :15:02 - 15:36 Channel Type Real Data Channel 2 2 Method Method 2 Dilution Unit mg/1 mg/l Calibr. Fit Linear Corr. Coeff. 0.9998 Base 54 Gain 28 Sensitivity 0.4138 Sample Limit 1 Sample Limit 2 Pk Cup Sample Id Value Va v / 0 0 B Baseline 0.01 0 1 1 P Primer 2.99 1 2 1 D Drift 3.01 1 3 1 Hl High 3.02 1 4 0 L1 Low 0.02 1 5 0 L1 Low 0.02 1 6 1 C Cal. 3.01 1 7 2 C Cal. 0.97 1 8 3 C Cal. 0.48 1 9 4 C Cal. 0.21 1 10 5 C Cal. 0.10 1 11 0 C Cal. 0.02 1 12 8 QC1 OPTICAL BLK 0.82 1 13 9 QC1 lcs 21468 5.48 10 14 10 QC1 mb 21468 0.82 1 15 11 S ref 47860 17.34 10 16 12 S ref 47860 17.51 10 17 13 S 0706803-005a 29.55 20 18 14 S 0706803-005a ms 34.78 20 19 15 S 0706803-005a dup 29.87 20 TKN.ANL / tkn062607bRl.run Page 1 Post -run Report BRAN+LUEBBE RACE 5.48 2 QC 1 20 16 S 0706952-004b 58.49 20 21 17 S 0706952-004bms 64.28 20 22 18 S 0706952-004bdup 60.36 20 23 19 S 0706952-008b 47.77 20 24 20 S 0706952-009b 36.24 20 25 2 QC1 CCV 1.0 0.96 1 26 0 QC1 CCB 0.03 1 27 21 S lfb 21468 5.32 10 28 22 S lfbd 21468 5.28 10 29 2 QC1 CCV 1.0 0.94 1 30 0 QC1 CCB 0.01 1 31 1 D Drift 3.01 1 32 0 B FinalBase 0.01 1 QC Limits Channel 2 QC 1 Unused QC 2 Unused QC 3 Unused QC 4 Unused QC 5 Unused QC 6 Unused QC 7 Unused QC 8 Unused QC 9 Unused QC10 Unused CORRECTIONS Channel 2 Baseline Yes Drift Yes Carry over Yes $: 1.0 ** <END OF REPORT> ** TKN.ANL / t]rn062607bRl.run Page 2 Post -run Report ERAN.LUBBBE AACE 5.48 H2M Labs Inc. Calibration Curve Name of run :tkn062607bR!.RUN Comment Calibration Curve Name of analysis :TKN_ANL Channel :2 Method :Method 2 Curve fit :linear a= -1.1008E-001 b=5.1105E-005 Corr. coeff. :0.9998 Peak [%) 100 o6040200 so- 60- 40- 20-- OV 0.00 0.50 1.00 1.50 2.00 2.50 3.00 3.50 Conc. [ mg/1 ] Page 1 of 1 SRAN.LUEBEE RACE 5.48 H2M Labs Inc. Post -run chart Past -run chart Name of run :tkn062GO7bRl.RUN Name of analysis :TKN.ANL Comment min Channel 2 Method Method 2 Unit mg/l Base 54 Gain 28 Corr. 0-9998 2 4 6 8 10 12 OB 0.01 1P 2.99 2D 3.01 3H 3.02 4L 0.02 14 SL 0.02 6C 3.01 7C 0.97 16 Page 1 of 2 Foss -:nn cha:c RRM.LUEcEE AACE 5.48 ie of run :tkn062607bRl-RUN Name of analysis :TKN.ANL nment min 8C 0.48 9C 0.21 i0c 0.10 18 11C 0.02 12QC1 0.82 13QC1 5.48 20 14QC1 0.82 15S 17.34 16S 17.51 22 17S 29.55 18S 34 .78 19S 29.87 24 20S 58.49 S 64.28* 22S 60.36 26 23S 47.77 24S 36.24 25QC1 0.96 28 26QC1 0.03 27S 5.32 28S 5.28 30 29QC1 0.94 - 30QC1 0.01 31D 3.01 32 32B 0.01 34 Page 2 of 2 22 S TSL o Concentration listed after Optical Blank Correction. rKN Data Preparation dilution factor not applied to results. Peak SampleID SampTy Cone Units DF Cone x DF AnalDate AnalTime TestCod 1 Primer PRIM 2.99 mg/I 1 2.99 6/26/2007 04:11:30 PM tkn_w 2 Drift DRIF 3 mg/I I 6/26/2007 04:12:11 PM tkn_w 3 High HIGH 3.01 mg/I I 3.01 6/26/2007 04:12:51 PM tkn w 4 Low LOW 0.02 mg/I 1 0.02 6/26/2007 04:13:29 PM tkn_w 5 Low LOW 0.02 mg/I 1 F 0.02 6/26/2007 04:14:10 PM tkn_w 6 Cal. CALB 3.02 mg/1 1 3.02 6/26/2007 04:14:51 PM tkn_w 7 Cal. CALB 0.96 mg/I 1 0.9b 6/26/2007 04:15:31 PM tkn_w 8 Cal. CALB 0.49 mg/1 1 0.49 6/26/2007 04:16:08 PM tkn_w 9 Cal. CALB 0.21 mg/1 1 _ 0.21 6/26/2007 04:16:39 PM tkn_w 10 Cal. CALB 0.1 mg/I 1 0.1 6/26/2007 04:17:19 PM tkn_w 1 I Cal. CALB 0.01 mg/1 1 0.01 6/26/2007 04:18:09 PM tkn_w 12 OPTICAL BLK QUAL 0.82 mg/1 1 0.82 6/26/2007 04:18:48 PM tkn_w z 13 021468 ICS 0.462 mg/I 10 4.62 6/26/2007kc 04:19:26 PM tkn_w 1 a 14 m021468 mblk 0 mg/I 1 6/26/2007.e0. 1 04:20:12 PM tkn_w 15 0706952-004b -m W --S SAMP 1918 mg/1 20 58.36 6/26/2007 04:20:50 PM tkn_w -tv = K-1 16 0706952-004bms ms 2.5288 mg/I 25 63.22 6/26/20071$ ( ItjtD4:21:28PM tkn_w 17 0706952-004bdup DUP 2.94 mg/I 20 58.8 6/26/2007 Q Pu 1% 04:22:02 PM tkn_w 71U -k• 18 lfb 21468 lfb 0.477 mg/I 10 4.77 6/26/20071k- 11 0404:22:48 PM tkn_w 19 Ifbd 21468 lfbd 0.471 mg/I 10 4.71 6/26/20070' 1t04:23:31 PM tkn_w 20 CCV 1.0 ccv 0.96 mg/I 1 0.96 6/26/2007 4CIb104:24:11 PM tkn_w 21 CCB ccb 0.02 mg/1 1 0.02 6/26/2007 -/0.1 04:24:53 PM tkn_w 22 Drift DR1F 3 mg/1 1 6/26/2007 04:25:32 PM tkn_w 23 End END 0.02 mg/1 1 0.02 6/26/2007 04:27:18 PM tkn_w _1/26/2007 4:43:18 PM Page 1 of 1 BRAN+LUEBBE RACE 5.48 Name of Run tkn062607cRl Date of Report 6/26/2007 Date of Run 6/26/2007 Operator bnk Comment 2 21468 H2M Labs Inc. Post -run report Name of Analysis :TKN.ANL System No. :1 Type of System :TRAACS Start/Stop time :15:59 - 16:27 Channel Type Real Data Channel 2 2 Method Method 2 Dilution Unit mg/1 mg/l Calibr. Fit Linear Corr. Coeff. 0.9998 Base 54 Gain 27 Sensitivity 0.4106 Sample Limit 1 Sample Limit 2 Pk Cup Sample Id Value Value 0 0 B Baseline 0.02 0 1 1 P Primer 2.99 1 2 1 D Drift 3.00 1 3 1 Hl High 3.01 1 4 0 L1 Low 0.02 1 5 0 L1 Low 0.02 1 6 1 C Cal. 3.02 1 7 2 C Cal. 0.96 1 8 3 C Cal. 0.49 1 9 4 C Cal. 0.21 1 10 5 C Cal. 0.10 1 it 0 C Cal. 0.01 1 12 8 QC1 OPTICAL BLK 0.82 1 13 9 QC1 lcs 21468 5.44 10 14 10 QC1 mb 21468 0.82 1 15 11 S 0706952-004b 59.18 20 16 12 S 0706952-004bms 64.04 25 17 13 S' 0706952-004bdup 59.62 20 18 14 S lfb 21468 5.59 10 19 15 S lfbd 21468 5.53 10 TKN.ANL / tkn062607CRI.run Page 1 Post -run Report N in r --I C) r--1 0 F4 BRAN+LUEBBE AACE 5.48 2 20 2 QC1 CCV 1.0 0.96 21 0 QC1 CCB 0.02 22 1 D Drift 3.00 23 0 B FinalBase 0.02 QC Limits Channel 2 QC 1 Unused QC 2 Unused QC 3 Unused QC 4 Unused QC 5 Unused QC 6 Unused QC 7 Unused QC 8 Unused QC 9 Unused QC10 Unused CORRECTIONS 2 Channel 2 Baseline Yes Drift Yes Carry over Yes %; 1.2 ** <END OF REPORT> ** 1 1 1 1 TKN.ANL / tkno62607cRl.run Page 2 Post -run Report BRAN.LUEBBE RACE 5.48 H2M Labs Inc. Calibration Curve Name of run :tkn062607cRl.RUN Comment Calibration Curve Name of analysis :TKN.ANL Channel :2 Method :Method 2 Curve fit :linear a= -1.1414E-001 b=5.3120E-005 Corr. coeff. :0.9998 Peak [%] 100 80- 06040200 Go- 40- 20- Oz 0.00 0.50 1.00 1.50 2.00 2.50 3.00 3.50 Conc. [ mg/l ) Page 1 of 1 0 rl 14 � V) E ---q BP.AN.LUEBBE RACE 5.40 H2M Labs Inc. Post -run chart Post -run. chart Name of run :tkn062607cR1.RUN Name of analysis :TKN.ANL Comment min Channel 2 Method Method 2 Unit mg/l Base 54 Gain 27 Corr. : 0.9998 2 4 6 8 10 12 OB 0.02 iP 2-99 2D 3.00 3H 3.01 4L 0.02 14 5L 0.02 6C 3.02 7C 0.96 16 Page 1 of 2 HRhN.LUErSF .ACE 5.4E me of run :tkn062607cRl.RUN mment Post -run chart Name of analysis :TKN.ANL min 8C 0.49 9C 0.21 l0C 0.10 18 11C 0.01 12QC1 0.82 13QC1 5.44 20 22 14QC1 0.82 15S 59.18 16S 64.04 17S 59.62 18S 5.59 19S 5.53 24 26 20QC1 0.96 21QC1 0-02 22D 3.00 23B 0.02 28 30 32 S4 Page 2 of 2 Concentration listed after Optical Blank Correction. PC 7-sZ G) O TKN Data Preparation dilution factor not applied to results. Peak SamplelD SampTy Cone Units DF Cone x DF AnalDate AnalTime TestCod 1 Primer PRIM 3.01 mg/I 1 3.01 6/27/2007 12:14:30 PM tkn_w 2 Drift DRIF 3.01 mg/I 1 3.01 6/27/2007 12:15:10 PM tkn w 3 High HIGH 3.01 mg/I 1 3.01 6/27/2007 12:15:50 PM tkn_w 4 Low LOW 0.02 mg/1 I 0.02 6/27/2007 12:16:28 PM tkn_w 5 Low LOW 0.02 mg/I I 02] 6/27/2007 12:17:10 PM tkn_w 6 Cal. CALB 3.01 mg/I 1 3.01 6/27/2007 12:17:50 PM tkn_w 7 Cal. CALB 0.96 mg/1 1 0.96 6/27/2007 12:18:29 PM tkn w 8 Cal. CALB 0.49 mg/I 1 0.49 6/27/2007 12:19:08 PM tkn_w 9 Cal. CALB 0.22 mg/I 1 0.22 6/27/2007 12:19:49 PM tkn w 10 Cal. CALB 0.11 mg/I 1 0.11 6/27/2007 12:20:30 PM tkn_w I 1 Cal. CALB 0.01 mg/I 1 0.01 6/27/2007 12:21:09 PM tkn_w 12 OPTICAL BLK QUAL 0.81 mg/1 1 0.81 6/27/2007 12:21:44 PM tkn_w 3 �;v 4-1 A'�f ����L 13 0§21468 ICS 0.476 mg/I 10 4.76 6/27/2007�/,L, 2:12:30 PM tkn_w � a 14 mk1468 mblk 0.03 mg/I 10.03 6/27/2007Z -0"t 12:23:10 PM tkn_w 15 0706952-006B 1 W `- 6 SAMP 0.71 mg/I 1 0.71 6/27/2007 12:23:51 PM tkn_w 16 0706952-007B tO S SAMP 1.08 mg/1 1 1.08 6/27/2007 12:24:30 PM tkn_w 17 Ifb21468 Ifb 0.468 mg/I 10 4.68 6/27/2007/,11q°2:25:04 PM tkn_w yy �K b�z7�1 18 Ifbd21468 Ifbd 0.453 mg/1 10 4.53 6/27/200)) ' /d2:25:48 PMotkn_w 19 CCv 1.0 ccv 0.96 mg/1 1 0.96 6/27/2007Re,jb ,12:26:31 PM tkn_w 20 CCB ccb - 0.01 mg/l 1 0.01 6/27/202 0.1 12:27:09 PM tkn w 21 Drift DRIF 3.01 mg/1 1 3.01 6/27/2007 12:27:51 PM tkn_w 22 End END 0 mg/l 1 6/27/2007 12:29:18 PM tkn_w 6/27/2007 12:42:08 PM Page 1 of 1 BRAN+LUEBBE AACE 5.48 Name of Run tkn062707R1 Date of Report 6/27/2007 Date of Run 6/27/2007 Operator bnk Comment Unit 21468 mg/1 H2M Labs Inc. Post -run report Name of Analysis :TKN.ANL System No. :1 Type of System :TRAACS Start/Stop time :12:03 - 12:30 Channel Type Real Data Channel 2 2 Method Method 2 Dilution Unit mg/l mg/1 Calibr. Fit Linear Corr. Coeff. 0.9998 Base 54 Gain 29 Sensitivity 0.4096 Sample Limit 1 Sample Limit 2 Pk Cup Sample Id Value Value 0 0 B Baseline 0.00 0 1 1 P Primer 3.01 1 2 1 D Drift 3.01 1 3 1 H1 High 3.01 1 4 0 - -Ll Low 0.02 .1 5 0 Ll Low 0.02 1 6 1 C Cal. 3.01 1 7 2 C Cal. 0.96 1 8 3 C Cal. 0.49 1 9 4 C Cal- 0.22 1 10 5 C Cal. 0:11 1 11 0 C Cal. 0.01 1 12 8 QC1 OPTICAL BLK 0.81 1 13 9 QC1 lcs21468 5.57 10 14 10 QC1 mb21468 0.84 1 15 11 S 0706952-006B 1.52 1 16 12 S 0706952-007B 1.89 1 17 13 S 1fb21468 5.49 10 18 14 S lfbd21468 5.34 10 19 2 QC1 CCV 1.0 0.96 1 TKN.ANL / tkn062707RI.run Page 1 Post -run Report BRAN+LUEBBE RACE 5.48 Post -run Report 20 0 QC1 CCB 0.01 1 21 1 D Drift 3.01 1 22 0 B FinalBase 0.00 1 QC Limits Channel 2 QC 1 Unused QC 2 Unused QC 3 Unused QC 4 Unused QC 5 Unused QC 6 Unused QC 7 Unused QC 8 Unused QC 9 Unused QC10 Unused CORRECTIONS 2 Channel 2 Baseline Yes Drift Yes Carry over Yes .%; 1.5 ** <END OF REPORT> ** TKN.ANL / tkn062707R1.run Page 2 BRAN+LUEBBE AACE 5.48 H2M Labs Inc. Calibration Curve Name of run :tkn062707R1.RUN Comment Calibration Curve Name of analysis :TKN.ANL Channel :2 Method :Method 2 Curve fit :linear a= -8.2199E-002 b=5.0181E-005 Corr. coeff. :0.9998 Peak [%] 100 80- 06040200 60- 40- 20- 0(zj 0.00 0.50 1.00 1.50 2.00 2.50 3.00 3.50 Conc. ( mg/1 ] Page 1 of 1 BRAN.LUEBBE AACE 5.48 H2M Labs Inc. Post -run chart Post -run chart Name of run :tkn062707Rl.RUN Name of analysis :TKN.ANL Comment min Channel 2 Method Method 2 Unit mg/1 Base 54 Gain 29 Corr. 0.9998 2 4 6 8 10 OR 0.00 1P 3.01 12 2D 3.01 3H 3.01 4L 0.02 14 iI 161-� 5L 0.02 6C 3.01 7C 0.96 8C 0.49 Page 1 of 2 BRAN,LUEBBE AACE 5.48 Post -run chart ame of run :tkn062707R1.RUN Name of analysis :TKN.ANL omment min 9C 0.22 10C 0.11 18 11c 0.01 12QC1 0.81 13QC1 5.57 20 14QC1 0.84 15S 1.52 16S 1.89 22 17S 5.49 18S 5.34 19QC1 0.96 24 20QC1 0.01 21D 3.01 26 22B 0.00 28 30 32 34 f Page 2 of 2 S --T �1 Concentration listed after Optical Blank Correction. CKNData Preparation dilution factor not applied to results. Peak SampleTD SampTy Cone Units DF Cone x DF AnalDate AnalTime TestCod 1 Primer PRIM 2.99 mg/I 1 2.99 6/28/2007 01:38:23 PM tkn_w 2 Drift DRIF 3 mg/i 1 6/28/2007 01:39:03 PM tkn_w 3 High HIGH 3.01 mg/I l 3.01 6/28/2007 01:39:44 PM tkn_w 4 Low LOW 0.03 mg/I 1 0.03 6/28/2007 01:40:23 PM tkn_w 5 Low LOW 0.03 mg/I 1 0.03 6/28/2007 01:41:03 PM tkn_w 6 Cal. CALB 3.01 mg/I 1 3.01 6/28/2007 01:41:44 PM tkn_w 7 Cal. CALB 0.97 mg/I I F 0.97 6/28/2007 01:42:21 PM tkn_w 8 Cal. CALB 0.48 mg/I 1 0.48 6/28/2007 01:43:02 PM tkn_w 9 Cal. CALB 0.2 mg/1 1 0.2 6/28/2007_ 01:43:42 PM tkn w 10 Cal. CALB 0.1 mg/I 1 O.l 6/28/2007 01:44:23 PM tkn_w 1 I Cal. CALB 0.02 mg/I 1 0.02 6/28/2007 01:45:03 PM tkn_w 12 OPTICAL BLK QUAL 0.83 mg/I 1 0.83 6/28/2007 01:45:44 PM tkn_w �/ s 13 LCS-21468 � Y (P611 ICS 0.423 mg/I 10 4.23 6/28/2007 io31, 01:46:23 PM tkn_w 14 MB -21468 mblk 0 mg/1 I E::= 6/28/2007 GJ• ( 01:47:03 PM tkn_w F11 15 0706952-OIOB SAMP -0.01 mg/1 1 0.01 6/28/2007 01:47:43 PM tkn_w 16 LFB-21468 lfb 0.426 mg/I 10 4.26 6/28/2007 01:48:23 PM tkn_w 17 LFBD-21468 lfbd 0.426 mg/1 10 4.26 6/28/2007 Atb-`1) 101:49:01 PM tkn w 18 CCv 1.0 ccv 0.96 mg/1 1 0.96 6/28/2007q&'/- 01:49:44 PM tkn_w 19 'CCB ccb 0.01 mg/l 1 0.01 6/28/2007 01:50:23 PM . tkn_w 20 Drift DRIF 3 mg/1 1 6/28/2007 01:51:04 PM tkn_w 21 End END 0.01 mg/1 1 0.01 6/28/2007 01:52:49 PM tkn_w M O O 5/28/2007 2:15:08 PM Page 1 of i BRAN+LUEBBE RACE 5.48 Name of Run tkn062807 Date of Report 6/28/2007 Date of Run 6/28/2007 Operator cmo Comment pctsl H2M Labs Inc. Post -run report Name of Analysis :TKN.ANL System No. :1 Type of System :TRAACS Start/Stop time :13:27 - 13:53 Channel Type Real Data Channel 2 2 Method Method 2 Dilution Unit mg/l mg/1 Calibr. Fit Linear Corr. Coeff. 0.9999 Base 54 Gain 28 Sensitivity 0.4031 Sample Limit 1 Sample Limit 2 Pk Cup Sample Id Value Value 0 0 B Baseline 0.01 0 1 1 P Primer 2.99 1 2 1 D Drift 3.00 1 3 1 H1 High 3.01 1 4 0 L1 Low 0.03 1 5 0 Ll Low 0.03 1 6 1 C Cal_ 3.01 1 7 2 C Cal. 0.97 1 8 3 C Cal. 0.48 1 9 4 C Cal. 0.20 1 10 5 C Cal. 0.10 1 11 0 C Cal. 0.02 1 12 8 QC1 OPTICAL BLK 0.83 1 13 9 QC1 LCS-21468 5.06 10 14 10 QC1 MB -21468 0.83 1 15 11 S 0706952-010B 0.82 1 16 12 S LFB-21468 5.09 10 17 13 S LFBD-21468 5.09 10 18 2 QC1 CCV 1.0 0.96 1 19 0 QC1 CCB 0.01 1 TKN.ANL / tkn062807.run Page 1 Post -run Report BRAN+LUEBBE RACE 5.48 20 1 D Drift 21 0 B FinalBase QC Limits Channel QC 1 Unused QC 2 Unused QC 3 Unused QC 4 Unused QC 5 Unused QC 6 Unused QC 7 Unused QC 8 Unused QC 9 Unused QC10 Unused CORRECTIONS Channel Baseline Drift Carry over ** <END OF REPORT> ** 3.00 0.01 2 2 Yes Yes Yes 1.3 1 1 TKN.ANL / tkn062807.run Page 2 Post -run Report BRAN.LUEBBE AACE 5.48 H2M Labs Inc. Calibration Curve Name of run :tkn062807.RUN Comment Calibration Curve Name of analysis :TKN_ANL Channel :2 Method :Method 2 Curve fit :linear a= -1.5416E-001 b=5.2430E-005 Corr. coeff. :0.9999 Peak [%] 100 80 60 --- 40- 0200 20- OV 0.00 0.50 1.00 1.50 2.00 2.50 3.00 3.50 Conc. [ mg/l ] Page 1 of 1 ERAN•LUEEEE RACE 5.48 H2M Labs Inc. Post -run chart Name of run :tkn062807.RUN Comment Post -run chart Name of analysis :TKN.ANL min Channel 2 Method : Method 2 Unit mg/l Base 54 Gain 28 Corr. 0.9999 2 4 6 8 1 10 } 1P 2.99 12 3.C1 i I4=: 1.0x 14 I 6 16 Page 1 of 2 BRAN.LUEBBE AACE 5.49 .e of run :tkn062B07.RUN ment Post -run chart Name of analysis :TKN.ANL min 9C 0.20 i 10C 0.10 11C 0.02 18 I 12QC1 0.83 13QC1 5.06 140C1 0.83 20 15S 0.82 16S 5.09 17S 5-09 22 18QC1 0.96 19QC1 0.01 20D 3.00 24 21B 0.01 26 28 30 32 34 i Page 2 of 2 00 r—I O e---1 0 F--�I T m- Pwd. (fAk" �JOCGS€Jiv U2A LAU%, INC. PC T5 b 1 _f 1� TOTAL/TKN DIGESTIONS NAME' Al ►SihoRtgrvw DATE- 6 :2S- vr �l: sc cSb& U—— LAB NO. - `v CLIENT ID SAMPLE WEIGHT GRAMS - SAMPLE VOLUME MLS FINAL VOLUME MLS DATE ANALYZED S RE s as loll oc ids 1S.r 2i ��v6 -cam Pry{- s --Ye b lig 3 ?a 0 069s�-oorB-go M -002b ktit- YD 951- 003 zu v-- - `tS IJ2 - vo Yh vtr- ' S� IS'2 - OoYb M IQ-Ooyb kot Isl - oos rx - 5 91'p -00b w�z, 6P ITI -'00?k -G 952- o09 ►�,� �5 9S2-9)o F 986-oor k(W - I 99b- mz t -tit l S -003 htt 918-o0rA C Pic 3� W -,wz �' ti l,--- � P 0008 --1--O h �i 1 IH2A ILA Ss INCo �o TOTAL pS/TKN DIGESTIONS NAMENl �t if hopyrAo l - DATE•_ �-,?,C-D�- LAB NO. CLIENT ID SAMPLE WEIGHT GRAMS SAMPLE VOLUME MLS FINAL VOLUME MLS DATE ANALYZED S ob9 -aBf �8 S/� IS 9Yz-0 ( 92-0o 99�-moz SPS � �S�-oar tiL So I bo-tiol oo, S o f -ov2 SP2 2J bib 7v; l•I vm 1°I J F p 000.E Multiple Analysis Report Print Date/Time: 2007/06/22 9:18:10 Sample ID Result Std. Dev. RSD Mode ALT Method ID Sample Type Vial Timestamp Message ID1 + 0.2350 0.0092 3.91 UTILITY Cleaning Procedure Sample sp 2007/06/21 15:31. LCS`dtPjjN,,rr+v�� IN/1 28.5762 0.1364 0.48 TOC TOC WASTE WATER Sample 1 2007/06/21 15:57 ICB +" -4'0 0.0516 0.1805 350.24 TOC TOC WASTE WATER Sample 2 2007/06/21 16:32 Low Sample > Detected) r CRI![pr. .......... jl�S!t 1.0480... 0.0961.. 9.17 ... TOC TOC WASTE WATER ...Sample 3..2007/06/21 17:03.Low Sample -0 Detected MBLK e).D -0.0468 0.0869 -185.64 TOC TOC WASTE WATER Sample 4 2007/06/21 17:34 Low Sample -D Detected 0706952-OOIE M W - U�J Q 1.3152 0.2006 15.25 TOC TOC WASTE WATER Sample 5 2007/06/21 18:05 Low Sample -o Detected 0706952-002E. ..~��D...... 11.6884... 0.4070., 3.48 ... TOC TOC WASTE WATER Sample 6..2007/06/21 18:35. 0706952-003E 28.8641 1.1338 3.93 TOC TOC WASTE WATER Sample 7 2007/06/21 19:05 0706952-004E ` 50 26.6615 1.4454 5.42 TOC TOC WASTE WATER Sample 8 2007/06/21 19:35 0706952-004EMS T✓.�/00.' JIG' 38.8018... 0.5485.. 1.41.. TOC TOC WASTE WATER ...Sample 9..2007/06/21 20:06. 0706952-004EDUP O) �,0f 27.4845 1.1751 4.28 TOC TOC WASTE WATER Sample 10 2007/06/21 20:36 0706952-005E W- 5.1775 0.3917 7.57 TOC TOC WASTE WATER Sample 11 2007/06/21 21:06 gs- 0706952-006E. ..:C * ...... 1.9643... 0.2628.. 13.38 ... TOC TOC WASTE WATER ...Sample 12..2007/06/21 21:37.Low Sample -0 Detected 0706952-007E 9.4092 0.1745 1.85 TOC TOC WASTE WATER Sample 13 2007/06/21 22:07 07069 -OOPE �,Gs 22.9725 0.6432 2.80 TOC TOC WASTE WATER Sample 14 2007/06/21 22:37 CCV..1.V..;45Vr ......../16% 29.0930... 0.2765.. 0.95 ... TOC TOC WASTE WATER ...Sample 15..2007/06/21 23:07. CCB ,cr:6 0.1700 0.1406 82.70 TOC TOC WASTE WATER Sample 16 2007/06/21 23:38 Low Sample -0 Detected 0706952-009E •M,L�j 23.0074 0.9106 3.96 TOC TOC WASTE WATER Sample 17 2007/06/22 00:09 0706952-OIOE ` glk��(d�..,)0 0.4260... 0.1437.. 33.74 ... TOC TOC WASTE WATER ...Sample 18..2007/06/22 00:40.Low Sample -0 Detected 0706986-001Ejnj,p {� 1.1571 0.0997 8.61 TOC TOC WASTE WATER Sample 19 2007/06/22 01:11 Low Sample -D Detected 0706986-002E 1.4104 0.0948 6.72 TOC TOC WASTE WATER Sample 20 2007/06/22 01:42 Low Sample -u Detected -3u 0706986-003E........... 37.5852... 1.2643.. 3.36 ... TOC TOC WASTE WATER ...Sample 21..2007/06/22 02:12. 0706986-004E r 14.6127 0.6347 4.34 TOC TOC WASTE WATER Sample 22 2007/06/22 02:42 CCV'1J : 28.7301 0.0513 0.18 TOC TOC WASTE WATER Sample 23 2007/06/22 03:13 CCB....................0.4998... 0.1321.. 26.43...TOC TOC WASTE WATER ...Sample 24..2007/06/22 03:40.Low Sample >Detected Printed: 6122107 9:18:10 AM AM TSLO10 W171 Page 1 of 1 -0 > a Detailed Analysis Report Print Date/Time: 2007/06/22 9:18:12 Sample ID: IDI Mode: UTILITY Method: Cleaning Procedure Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/21 15:31 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.2323 0.1162 25520 11.858 12.058 122 2 0.2298 0.1149 25309 11.877 12.077 121 3 0.2487 0.1243 26885 11.858 12.054 121 4 0.2294 0.1147 25277 11.892 12.091 121 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 0.2350 Std Dev: 0.0092 RSD: 3.91 Sample ID: LCS Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/21 15:57 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 28.5533 1.4277 244630 12.001 12.995 110 2 28.7293 1.4365 246100 12.062 13.057 110 3 28.6192 1.4310 245181 12.050 13.034 110 4 28.4030 1.4201 243374 12.035 13.025 110 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 28.5762 Std Dev: 0.1364 RSD: 0.48 Sample ID: ICB Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/21 16:32 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.2121 0.0106 7884 11.978 11.981 120 2 -0.1091 -0.0055 5201 11.963 11.950 120 3 -0.1004 -0.0050 5274 11.936 11.896 120 4 0.2036 0.0102 7813 11.892 11.884 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 0.0516 Std Dev: 0.1805 RSD: 350.24 Sample ID: CRI Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/21 17:03 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 1.1067 0.0553 15357 11.921 11.932 120 2 1.1172 0.0559 15445 11.920 11.932 120 3 0.9090 0.0455 13706 11.926 11.916 120 4 1.0593 0.0530 14961 11.917 11.923 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 1.0480 Std Dev: 0.0961 RSD: 9.17 Sample ID: MBLK Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/21 17:34 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.0792 0.0040 6774 11.935 11.940 120 2 -0.0827 -0.0041 5421 11.914 11.899 120 Printed: 6122107 9:18:13 AM AM Page 1 of 6 3 -0.0651 -0.0033 5569 11.902 11.902 120 4 -0.1187 -0.0059 5121 11.913 11.924 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: -0.0468 Std Dev: 0.0869 RSD: -185.64 Sample ID: 0706952-OOIE Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/21 18:05 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 1.5895 0.0795 19390 12.016 11.999 120 2 1.2533 0.0627 16581 12.000 12.042 120 3 1.3068 0.0653 17029 11.985 11.997 120 4 1.1112 0.0556 15395 11.982 11.981 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 1.3152 Std Dev: 0.2006 RSD: 15.25 Sample ID: 0706952-002E Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC VTW CURVE 040507 Timestamp: 2007/06/21 18:35 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 12.2875 0.6144 108755 11.940 12.936 104 2 11.5846 0.5792 102883 11.927 12.922 104 3 11.3927 0.5696 101281 11.910 12.908 104 4 11.4889 0.5744 102084 11.926 12.923 105 ----------------------------------------------------------------------------- « <Statistics>>> Mean: 11.6884 Std Dev: 0.4070 RSD: 3.48 Sample ID: 0706952-003E Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/21 19:05 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 30.4906 1.5245 260813 12.213 13.201 110 2 28.6748 1.4337 245645 12.170 13.158 110 3 28.4122 1.4206 243451 12.150 13.140 110 4 27.8788 1.3939 238995 12.106 13.098 109 ----------------------------------------------------------------------------- < -Statistics » > Mean: 28.8641 Std Dev: 1.1338 RSD: 3.93 Sample ID: 0706952-004E Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/21 19:35 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 28.7072 1.4354 245916 12.359 13.357 111 2 26.2241 1.3112 225173 12.405 13.396 109 3 26.4997 1.3250 227475 12.399 13.394 111 4 25.2952 1.2648 217414 12.477 13.471 109 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 26.6815 Std Dev: 1.4454 RSD: 5.42 Sample ID: 0706952-004EMS Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/21 20:06 Operator ID: JASON SAMUEL Sample Type: Sample Printed: 6122/07 9:18:13 AM AM Page 2 of 6 Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 39.47.84 1.9739 335892 13.106 14.099 112 2 38.9000 1.9450 331060 13.101 14.087 112 3 38.1547 1.9077 324834 13.126 14.116 112 4 38.6741 1.9337 329173 13.151 14.144 112 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 38.8018 Std Dev: 0.5485 RSD: 1.41 Sample ID: 0706952-004EDUP Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/21 20:36 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 29.1070 1.4553 249255 13.456 14.445 109 2 27.4043 1.3702 235032 13.404 14.390 109 3 26.3172 1.3159 225951 13.444 14.439 109 4 27.1094 1.3555 232568 13.411 14.399 110 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 27.4845 Std Dev: 1.1751 RSD: 4.28 Sample ID: 0706952-005E Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC NiW CURVE 040507 Timestamp: 2007/06/21 21:06 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 5.6576 0.2829 53372 13.757 14.755 100 2 5.3358 0.2668 50685 13.725 14.713 100 3 4.8817 0.2441 46891 13.736 14.723 100 4 4.8350 0.2418 46501 13.738 14.729 100 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 5.1775 Std Dev: 0.3917 RSD: 7.57 Sample ID: 0706952-006E Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/21 21:37 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending integration Baseline Baseline Time 1 2.2213 0.1111 24668 13.782 13.826 120 2 2.1572 0.1079 24132 13.789 13.846 120 3 1.7019 0.0851 20329 13.839 13.837 120 4 1.7768 0.0888 20954 13.828 13.854 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 1.9643 Std Dev: 0.2628 RSD: 13.38 Sample ID: 0706952-007E Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/21 22:07 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 9.4933 0.4747 85414 13.854 14.847 104 2 9.3453 0.4673 84178 13.839 14.827 104 3 9.5991 0.4800 86298 13.827 14.816 105 4 9.1992 0.4600 82957 13.812 14.799 104 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 9.4092 Std Dev: 0.1745 RSD: 1.85 Sample ID: 0706952-008E Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Printed: 6122107 9:18:13 AM AM Page 3 of 6 r C) L Cal_ Curve: TOC WW CURVE 040507 Timestamp: 2007/06/21 22:37 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 23.8562 1.1928 205393 13.845 14.831 109 2 22.4309 1.1215 193487 13.862 14.860 108 3 23.0342 1.1517 198526 13.816 14.810 109 4 22.5688 1.1264 194639 13.822 14.818 109 ----------------------------------------------------------------------------- <<<Statisti.cs>>> Mean: 22.9725 Std Dev: 0.6432 RSD: 2.80 Sample ID: CCV Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/21 23:07 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 28.8429 1.4421 247049 13.783 14.779 111 2 28.8993 1.4450 247520 13.812 14.809 110 3 29.1910 1.4595 249956 13.798 14.796 110 4 29.4390 1.4719 252028 13.802 14.794 110 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 29.0930 Std Dev: 0.2765 RSD: 0.95 Sample ID: CCB Made: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/21 23:38 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.2845 0.0142 8489 13.723 13.713 120 2 -0.0064 -0.0003 6059 13.709 13.687 120 3 0.2819 0.0141 8467 13.687 13.689 120 4 0.1198 0.0060 7113 13.678 13.676 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 0.1700 Std Dev: 0.1406 RSD: 82.70 Sample ID: 0706952-009E Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/22 00:09 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 24.2982 1.2149 209085 13.741 14.726 109 2 22.6419 1.1321 195249 13.712 14.697 110 3 22.1845 1.1092 191428 13.703 14.698 110 4 22.9050 1.1452 197447 13.651 14.635 109 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 23.0074 Std Dev: 0.9106 RSD: 3.96 Sample ID: 0706952-010E Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/22 00:40 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.6264 0.0313 11345 13.464 13.443 120 2 0.4333 0.0217 9732 13.423 13.403 120 3 0.3133 0.0157 8730 13.396 13.390 120 4 0.3309 0.0165 8876 13.373 13.342 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 0.4260 Std Dev: 0.1437 RSD: 33.74 Printed: 6122107 9:18:13 AM AM Page 4 of 6 Sample ID: 0706986-OOIE Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/22 01:11 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 1.2850 0.0642 16846 13.383 13.396 120 2 1.0489 0.0524 14874 13.389 13.371 120 3 1.1196 0.0560 15465 13.377 13.418 120 4 1.1750 0.0587 15927 13.363 13.384 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 1.1571 Std Dev: 0.0997 RSD: 8.61 Sample ID: 0706986-002E Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/22 01:42 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 1.4532 0.0727 18252 13.393 13.393 120 2 1.3327 0.0666 17245 13.374 13.366 120 3 1.3317 0.0666 17237 13.351 13.353 120 4 1.5239 0.0762 18842 13.299 13.313 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 1.4104 Std Dev: 0.0948 RSD: 6.72 Sample ID: 0706986-003E Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/22 02:12 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration . Baseline Baseline Time 1 39.4301 1.9715 335488 13.329 14.324 112 2 37.2320 1.8616 317126 13.238 14.234 112 3 37.1170 1.8558 316166 13.201 14.190 112 4 36.5616 1.8281 311527 13.193 14.187 113 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 37.5852 Std Dev: 1.2643 RSD: 3.36 Sample ID: 0706986-004E Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/22 02:42 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 15.5107 0.7755 135679 13.094 14.085 106 2 14.4799 0.7240 127069 13.053 14.037 107 3 14.0158 0.7008 123192 13.009 13.995 105 4 14.4444 0.7222 126772 12.959 13.949 106 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 14.6127 Std Dev: 0.6347 RSD: 4.34 Sample ID: CCV Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/22 03:13 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 28.6575 1.4329 245500 12.914 13.905 110 2 28.7697 1.4365 246437 12.882 13.875 110 3 28.7625 1.4381 246378 12.873 13.865 110 Printed: 6122107 9:18:13 AM AM Page 5 of 6 4 28.7308 1.4365 246113 12.817 13.802 111 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 28.7301 Std Dev: 0.0513 'RSD: 0.18 Sample ID: CCB Mode: TOC Method: TOC WASTE WATER Filename: 06211506 Cal. Curve: TOC WW CURVE 040507 Timestamp: 2007/06/22 03:40 Operator ID: JASON SAMUEL - Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.6330 0.0317 11400 12.693 12.709 120 2 0.5936 0.0297 11071 12.656 12.643 120 3 0.3929 0.0196 9394 12.647 12.659 120 4 0.3799 0.0190 9286 12.628 12.618 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 0.4998 Std Dev: 0.1321 RSD: 26.43 Printed: 6122/07 9:18:13 AM AM Page 6 of 6 Calibration Report Print Date/Time: 2007/06/22 9:18:17 Cal. Curve ID: TOC WW CURVE 040507 Created: 2007/04/05 16:17 Calibration Factor (m): 1.671e+OS Y Intercept (b): 2610 ' r -squared: 0.99921 Standard ID Y X Expected Measured Message Date & Raw Data ug C ug C Time DI 6813 0.000 0.025 Low Sample De 2007/04/05 13:35 0.5PPM 8736 0.025 0.037 Low Sample De 2007/04/05 13:58 1.OPPM 13782 0.050 0.067 Low Sample De 2007/04/05 14:21 5.OPPM 41913 0.250 0.235 2007/04/05 14:43 10.OPPM 77213 0.500 0.447 2007/04/05 15:06 25.OPPM 207246 1.250 1.225 2007/04/05 15:28 50.OPPM 432042 2.500 2.570 2007/04/05 15:.51 75.OPPM 623979 3.750 3.719 2007/04/05 16:14 Printed: 6122107 9:18:18 AM AM Page 1 of 1 H2M LABS, INC. SDG NO.:�G I V SCAN: This data package was reported by the undersigned. This reporting includes data calculations, manual edits if necessary and compilation of raw data. The information presented is true and correct to the best of my knowledge. Signature:, Date: Date'