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Home My WebLink AboutSample Data Summary Package 06/2007I_ Analytical Data Package For TOWN OF SOUTHOLD PART 360 ROUTINE SDG NO: TSLO10 Water Samples - Received: 6/14/07 & 6/15/07 SAMPLE DATA SUMMARY PACKAGE . JUNE 2007 J C Onvironmental Testing Laboratories I 575 Broad Hollow Road, Melville, N.Y. 11747 SAMPLE DATA SUMMARY PACKAGE TABLE OF CONTENTS TOWN OF SOUTHOLD PART 360 ROUTINE WATER SAMPLES SAMPLES RECEIVED: 6/14/07 & 6/15/07 SDG NO.: TSLO10 1. NYS DEC SUMMARY FORMS 2. CHAIN OF CUSTODY DOCUMENTATION 3. SDG NARRATIVES 4. SAMPLE REPORTS ' 4.1 METALS 4.2 WET CHEMISTRY 5. DUPLICATE SUMMARY RESULTS 5.1 METALS 5.2 WET CHEMISTRY 6. SPIKE SAMPLE RESULTS 6.1 METALS 6.2 WET CHEMISTRY 7. BLANK SUMMARY DATA AND RESULTS 7.1 METALS 7.2 WET CHEMISTRY U2M "US, INC, 1. NYS DEC SUMMARY FORMS NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE IDENTIFICATION AND ANALYTICAL REQUIREMENT SUMMARY SDG: TSLO10 Anal tical Requirements Customer Sample Code Laboratory Sample Code ME we MW -BD 0706952-001 X X h1W-4D 0706952-002 X X MW -4S 0706952-003 X X MW -5D 0706952-004 X X Mw -5s 0706952-005 X X MW -6D 0706952-006 X X MW -6S 0706952-007 X, X MW -8D 0706952-008 X X MW -8S 0706952-009 X X FB 061407 0706952-010 X X MW -1D 0706986-001 X X MW -1s 0706986-002 X X MW -3D 0706986-003 X X Mw -3S 0706986-004 X X CLP(on-CLP Piease indicate year of AW v 10hs NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG: TSLO10 INORGANIC ANALYSIS Laboratory Samp ID Client Sample ID Matrix Metals Requested DateRecd at Lab Date Analyzed 0706952-001 MW -BD WATER CA,CD,FE,K,MG,MN,NA,PB, 14 -Jun -07 06/07 0706952-002 MW -4D WATER CA,CD,FE,K,MG,MN,NA,PB, 14 -Jun -07 06/07 0706952-003 IMW-4S I WATER CA,CD,FE,K,MG,MN,NA,PB, 14 -Jun -07 06/07 0706952-004 MW -5D WATER CA,CD,FE,K,MG,MN,NA,PB, 14 -Jun -07 06/07 0706952-004DUA MW-5DD WATER CA,CD,FE,K,MG,MN,NA,PB, 14 -Jun -07 06/07 0706952-004MS MW-5DS WATER I CA,CD,FE,K,MG,MN,NA,PB, 14 -Jun -07 06/07 0706952-005 MW -5S I WATER CA,CD,FE,K,MG,MN,NA,PB, 14 -Jun -07 06/07 0706952-006 ivJW-6D WATER CA,CD,FE,K,MG,MN,NA,PB, 14 -Jun -07 06/07 0706952-007 MW -6S WATER I CA,CD,FE,K,MG,MN,NA,PB, 14 -Jun -07 06/07 0706952-008 MW -8D WATER I CA,CD,FE,K,MG,MN,NA,PB, 14 -Jun -07 06/07 0706952-009 MW -8S WATER CA,CD,FE,K,MG,MN,NA,PB, 14 -Jun -07 06/07 0706952-01.0 IFB 061407 WATER CA,CD,FE,K,MG,MN,NA,PB, 14 -Jun -07 06/07 0706986-001 MW -ID I WATER CA,CD,FE,K,MG,MN,NA,PB, 115 -Jun -07 06/07 0706986-002 MW -IS WATER CA,CD,FE,K,MG,MN,NA,PB, 15 -Jun -07 06/07 0706986-003 MW -3D WATER CA,CD,FE,K,MG,MN,NA,PB, 115 -Jun -07 06/07 0706986-004 MW -3S WATER CA,CD,FE,K,MG,MN,NA,PB, 15 -Jun -07 06/07 TSLO10 S4 NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG: TSLO10 INORGANIC ANALYSIS Laboratory Samp ID Client Sample ID Matrix I Tests DateRec I d at Lab Date Analyze 0706952-001 MW -BD Aqueous SELECT WET CHEMISTRY ** 06/14/07 06/07 0706952-002 MW -4D I Aqueous I SELECT WET CHEMISTRY * 06/14/07 06/07 0706952-003 MW -4S I Aqueous SELECT WET CHEMISTRY** 06/14/07 06/07 0706952-004 MW -5D Aqueous SELECT WET CHEMISTRY'* 06/14/07 06/07 070b952-004DUP I MW-5DDUP Aqueous I SELECT WET CHEMISTRY ** I 06/14/07 ( 06/07 0706952-004MS I MW-5DMS Aqueous SELECT WET CHEMISTRY "* 06/14/07 I 06/07 0706952-005 MW -5S I Aqueous I SELECT WET CHEMISTRY ** I 06/14/07 I 06/07 0706952-006 MW -6D I Aqueous SELECT WET CHEMISTRY ** 06/14/07 06/07 0706952-007 MW -6S Aqueous SELECT WET CHEMISTRY ** I 06/14/07 I 06/07 .0706952-008 I MW -8D Aqueous I SELECT WET CHEMISTRY ** 06/14/07 06/07 0706952-009 MW -8S Aqueous SELECT WET CHEMISTRY ** 06/14/07 06/07 0706952-010 I FB 061407 Field Blank SELECT WET CHEMISTRY ** 06/14/07 06/07 0706986-001 I MW -ID ( Aqueous SELECT WET CHEMISTRY `* 06/15/07 06/07 0706986-002 I Mw -IS I Aqueous SELECT WET CHEMISTRY ** 06/15/07 06/07 0706986-003 MW -3D I Aqueous I SELECT WET CHEMISTRY ** 06/15/07 06/07 0706986-004 MW -3S Aqueous SELECT WET CHEMISTRY * 06/15/07 06/07 ** Alkalinity, Total (As CaCO3) ; Biochemical Oxygen Demand; Bromide; Chemical. Oxygen Demand ; Chloride ; Hardness (As CaCO3) ; Nitrate as N ; Nitrogen, Ammonia (As N) ; Nitrogen, Kjeldahl, Total ; Phenolics; Total Recoverable; Sulfate ; Total Dissolved Solids; Total Organic Carbon; 2. CHAIN OF CUSTODY DOCUMENTATION 575 Broad Hollow Rd, Melville, NY 11747--5076 14r, Ot NCO [U4ll� STERNAL CHAIN OF CUSTODY • Tel. (631) 694-3040 Fax: (631) 420-8436 CLIENT: H2M SDG NO: -FS L, 0t0 PROJECT NAME/NUMBER SO v7d-r 0 Ld 4,+IiJ p F/ LL X 007 0, N �P_ o Ll o ° o JE,9 1 NOTES: Protect Contact: P�aTC.7J� 3 o Phone Number: 0 U 77NE PIS/Quote # >�N ✓ Pv SO�L7-o7D( SAMPLERS: (signatureyClient vCr DELIVERABLES: j S — 7 T ,0 o _� 3 9 a .V j► ANALYSIS REQUESTED TURNAROUND TIME:✓ 7 ORGANIC INORG. . DATE TIME MATRI FIELD I.D. �I/ `Z/ L3� i Z V 'LAB I.D. NO. REMARKS: a V'/ 0 :l� NI tN - .- 5 Q le, :3 0 M (IV - .D ll=! D /w W— (� 5 6 C� 0 — L 1/r-601 M W - (V -b ILL,MW— 8S Cf--M�Q9 Sa— /2 '3,5 M IBJ - S b o --� 0 CQ `1 &-.-:- c� 12-106e, flan lit 671 //: rol h a /11 W - Opal)a ' c, b IBI h a D rJ /icat F;Wi*i (s ) Date Time Received by. (Sw4hxe) Date lei (3"i' Time ��' I S LABORATORY USE ONLY Discrepancies Between Sample Labels and COC Record? Y or N Explain: Sampies were:�{ t. Shipped_ or Hand Delivered_ Alrbili 2 Ambient or chilied, Temp 3. P.eceived in good condition: Y or 4. Property preserved: Y or N COC Taoo was: I. Present on outer package: Y or N 2. Lh*mken on outer package: Y or N 3. COC record present b complete upon sample receipt: YorN Relinquished by: (Signature) Dat Time Received by: (Signature) Date Time Relinquished by: (Signature) Date Tlme Received by: (Signature) Date Time Relinquished by: (Signature) Date Time Received by (Slpnature) Date Time WHITE COPY - ORIGINAL YELLOW COPY -- CLIENT PINK COPY - LABORATORY TSL010 S7 ",,12M LABS, INC. N Sample Receipt Checklist Client Name PCTSL Contacted by: Regarding Date and Time Receive 6/14/2007 3:15:00 PM Work Order Numbe 0706952 Corrective Action Received by CAM Checklist completed by ) �_-. `� �� Reviewed by , - -- - -- Signalure ; 4-�_ Dale __- Initials ate Matrix: Carrier name Hand Delivered i Shipping, container/cooler in good condition? Yes VI No ❑ Not Applicable ❑ Custody seals intact on shippping container/cooler? Yes ❑ No ❑ Not Applicable Custody seals intact on sample bottles? Yes ❑ No ❑ Not Applicable Chain of custody present? Yes R No ❑ Chain of custody signed when relinquished and received? Yes R No ❑ Chain of custody agrees with sample labels? Yes (!�] No Samples in proper container/bottle? Yes W No Sample containers intact? Yes 0 No ❑ Sufficient sample volume for indicated test? Yes No ❑ I samples received within holding time? Yes 0 No ❑ Container/Temp Blank temperature in compliance? Yes IV] No ❑ Water - VOA vials have zero headspace? No VOA vials submitted ❑ Yes n No U Water - pH acceptable upon receipt? Yes C No 0 Adjusted? Checked b Any No and/or NA (not applicable) response must be detailed in the comments section be Client contacted Date contacted: Person contacted Contacted by: Regarding Comments: Corrective Action 00 -.---- ---- --- — --- — C/) O r� i ------------ INTERNAL CHAIN OF CUSTODY CLIENTTTURN AROUND . ME: DELIVERABLES SDG it, 5LQ C) CASE #:_ MATRIX: Py CHECK Y a N REMARKS: - RECEIVEDgY:- SIGNATURE: CLIENT ID H2M LAB S DATE BOTTLE # OF TFTS COLLECTED TYPE BOTTLES REQUESTED Q) IT -D) S cz —5-0 co -(Y-)G- Q opb D (-6 -c 13 rl METALS P 0247 Isce CLIENT:R:,I�L SDG INTERNAL CHAIN OF CUSTODY DATE SAMPLE RELINQUISHED SAMPLE TD4E BY. -ECEIVED BY BOTTLE TYPE PURPOSE OF CHOF CU INIT U A C HI 31 1SyT}STOODY ( - SIGs s Zaj 1et.•S S slog SION ._ slog SIGN sIOp SION - sION SIGN SIow SIGH . SION SIGN SION .SIGN SION SIGN SION SIGN - SIGN. SIGN SION SIGN SION SION , Slily SIGN SIGN - SIGH SIGN - SION Sl cm SION SION SION - slow SIGN SIGN SIGN SION SIGN. SIGN - SIGN -_ - METALS -' 0249 INTERNAL CHAIN OF CUSTODY CLIENT�- TURN AROUND TME: DELIVERABLES - S MATRIX:�jLj J pH CHECK Y of N ' SDG #: ` f�CASE 9:_— �— -- REMARKS: } RECErVED BY: � " 1 SIGNATURE: 5 WET CHEMISTRY Z)� p 0193 112M LAB DATE BOTTLE BOF TESTS CLIENT ID COLLECTED TYPE BOTTLES REQUESTED P•ScoK3c 07" — COl —01) l A Ws - lig � qo —COS 5 WET CHEMISTRY Z)� p 0193 71�lc CL "I" SDG INTERNAL CHAIN OF CUSTODY WET CHEMISTRY P 0194 LINQUISHED I BY ...... ..... gg'I'l-iiiii Ip IrAn WA . . . . . . . . . . IAN - WET CHEMISTRY P 0194 INC - CLIENT:. SDO 1: STODY CHAIN OF. CTJ WET CHEMISTRY p 0195 _NC 1JAIIAW PH 1NAMlla_ NY 11747--5076 20�� EXTERNAL CHAIN OF CUSTODY • Tel: (631) 694-3040 Fax. (631) 420-8436 CLIENT: Ts, (._ H2M SDG NO: (, PROJECT NAMEINUMBER .S o (/774 C c 0 1-4 /YO F I LL, ODS Z 4 a -� ? ' J 1 ° N� <Z) 2 ,` _ NOTES: Project Contact F)/4r c s F 3 Phone Number o Lr77N F— X l $ �}- �� M E, PfS/Quote# 6N V, S o k76761� EA SAMPLERS: (signetureyCllent V M2M DELIVERABLES: 65— —70D Z 0 ► ANALYSIS REQUESTED TURNAROUND TIME: a I DAY–,; ORGANIC INORG. , DATE- TIME MATRIX LAB I.D. (l) C2-) I.D. NO. REMARKS: *qigFIELD M w -. 8 I I 3 1 – z o MK— IS bfo�c _ 60 I (�I S M, ►N — 1 D �-0 (0 �1 f3 � -(� l Reihrqui by. IS lure) Date I S o Time 13:53 Received W. (swi.attxe) Data IS�i Time 13 .', LA . BORATORYUSEONLY Discrepancies Betv.w Sample Labels and COC -Record? Y or N Explain: 68"'0'w -l' 1. Shipped_ or Hand Deihrered_Alrbilt 2 Ambient orchfUed, Temp 3. Received in good condwon: Y or N 4. Property preserved: Y or N COC Tsps was: 7. Present on outer padwge: Y or N 2. Unbroken on outer package: Y or N) 3. COC record present b Complete upon Semple receipt: YorN Relinquished by. (Signature) Da Time Received by: (Signature) Date Time RellNuished by: (Signature) Date Time Received try: (Signature) Date Time Relinquished by (Signature) Date Time Received by (Signature) Date Time Wfylyl RT - ORIGINAL YELLOW COPY - CLIENT PINK COPY - LABORATORY ,2M LABS, INC. Sample Receipt Checklist Client Name PCTSL Date and Time Receive 6/15/2007 1:53:00 PM Work Order Numbe 0706986 Received by CAM Checklist completed by ` 6 Reviewed by .J (.` l� signaturei Dale Initials i Date Matrix: Carrier name Hand Delivered Shipping container/cooler in good condition? Yes No ❑ Custody seals intact on shippping container/cooler? Yes Not Applicable ❑� Custody seals intact on sample bottles? Yes ❑ Chain of custody present? Yes Chain of custody signed when relinquished and received? Yes No ❑ Chain of custody agrees with sample labels? Yes (] Samples in proper container/bottle? Yes 0 Sample containers intact? Yes U —Sufficient sample volume for indicated test? Yes 0 I samples received within holding time? Yes E Container/Temp Blank temperature in compliance? Yes Rl Water - VOA vials have zero headspace? No VOA vials submitted RJ Water - pH acceptable upon receipt? Yes RI Adjusted? No ❑ Not Applicable ❑ No ❑ Not Applicable u No ❑ Not Applicable ❑� No ❑ No ❑ No ❑ No ❑ No ❑ No ❑ No ❑ No ❑ Yes ❑ No ❑ No ❑ Checked b Any No and/or NA (not applicable) response must be detailed in the comments section be Client contacted Date contacted: Contacted by: Regarding Comments: Corrective Action Person contacted O O V) H 912A LA", INC. INTERNAL CHAIN OF CUSTODY CLIENT: C DELIVERABLES: u > Tl" AROUND TIME: 1 SDG #--V CASE #: MATRIX: �Q- — pH CHECK Y or N REMARKS: lJ c( D PCITS RECEIVEDBY: G 1- SIGNATURE: DATE: Y �4� TIME: 13 ` -V'3 CLIENT ID H2M LAB k DATEBOTTLE COLLECTED N OF TESTS TYPE BOTTLES REQUESTED ,.zi o i n METALS P 4253 -1H2A LAOS, INC. CLIEW:'pc�-(� L SDG #: -Fs Lc) I C) INTERNAL CHAIN OF CUSTODY DATE T124H SAMPLE RELINQUISHED BY SAMPLE BOTTLE AECHIVED BY TYPR PURPOSE OF. CHANGE OF CUSTODY INIT SIGN CA (.kAd:p- wou SION v slow SIGN slow SION 5IO?f SIGN SZOV SIGN slow SIGN Siam SIGN sroN SIGN SION SIGN slum SIGN SION SIGN SIGN SION SIGN SION SIGN SIC" SION SION • slow SION SION SION SION SIGN SIGN 31 ON SIGN SIGN IGN -MET-A-L-S----, I INC INTERNAL CHAIN OF CUSTODY '2 DELIVERABLES-tS�'L__l'oD TURN AROUND TRvfE:c SDG 4!5150Q(D CASE 9- MATRIX: pH CHECK Y or N REMARKS: RECEIVED BY: SIGNATURE: DATE:_6'tV&T"VIE_t _,__ - - MET CHEMISTRY IP 0205 IHIAA LAUSs ISCo -Ni CLIENT-RCSL, SDG j p T-mm-wRNAIi CHAIN OF CUSTODY -WET-CHEMISTRY -- P WET--C---BEMISTRY---- IP 0206 U2A4 LAOS, INC. 3. SDG NARRATIVES SDG NARRATIVE FOR METALS SAMPLE RECEIVED: 6/14/07 & 6/15/07 SDG#: TSLO10 For Sample: MW -BD MNAI-61) MWAD MW -41) MW -6S MW-iS MW -4S MW -81) MW -31) MW -51) MS/MSD MW -8S MW -3S MW -5S FB 061407 Fourteen water samples were received by 112M Labs, Inc. for analysis of a select list of metals. Samples were prepared and analyzed using EPA methods 6010B with a TJA 61E Trace ICP Instrument. Sample MW -513 was utilized for QC analysis and reporting. • The sample spike recovery for manganese was above 125%. Since the sample result exceeded the spike concentration by more than four times, post spike analysis and data qualifiers were not required. • In the serial dilution analysis of the sample, %D for potassium exceeded the acceptance range, and all results for this analyte were flagged with the qualifier "E" on Forms 1 and 9. All other QC data and calibrations met the requirements of the method and no problems were encountered with sample analysis. Sample MW -3S was reanalyzed for manganese at a dilution to keep the concentration within the calibration range. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above.. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: June 21, 2007 Ursula Middel Technical Manager 1-124 NABS, IMC. For Samples: SDG NARRATIVE FOR WET CHEMISTRY SAMPLES RECEIVED: 6/15/07 SDG#: TSLO10 MW -BD MW -8D MW -4D MW -8S MW -4S FB 061407 MW -5D MW -1D MW -5S MW -1S MW -6D MW -3D MW -6S MW -3S Fourteen water samples were received by H2M Labs, Inc. on 6/15/07 for select wet chemistry analysis. Samples were prepared and analyzed using the following methods: Alkalinity Anions- chloride/sulfate/bromide Biochemical Oxygen Demand Chemical Oxygen Demand Hardness Ammonia Nitrate Phenols Total Dissolved Solids Total Kjeldahl Nitrogen Total Organic Carbon Sample was utilized for QC analysis and reporting. EPA 310.1 EPA 300.0 EPA 405.1 EPA 410.4 EPA 130.2 EPA 3501 EPA 353.2 EPA 420.1 EPA 160.1 EPA 351.2 EPA SW846 9060 Samples were diluted and reanalyzed as required to keep instrument readings within calibration ranges. No problems were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: June 29, 2007 Vincent Stancampiano Vice President N N O E- U2AA "US' INC. 4. SAMPLE REPORTS 4.1 METALS 4.2 WET CHEMISTRY O U2i4 "Uss Isce QUALIFIERS FOR METALS ANALYSIS Q (Quality Control) Qualifiers E - The reported value is estimated because of the presence of interference. An explanatory note is included in the SDG narrative. M - Duplicate injection precision not met. N - Matrix spike sample recovery not within control limits. S- The reported value was determined -by the Method of Standard Additions (MSA). + - Correlation coefficient for the MSA is less than 0.995 W - Post digestion spike for Furnace AA analysis is out of control limits (85- 115%), while sample absorbance is less than 50% of spike absorbance. * - Duplicate analysis is not within control limits. C (Concentration) Qualifiers S - Entered if the reported value is less than the Contract Required Detection Limit (CRDL) but greater than the Instrument Detection Limit (IDL). U - Entered if the analyte was analyzed for but not detected, i.e., less than the IDL. - M (Method) Qualifiers P - Analyzed by ICP. M - Analyzed by ICP -MS A - Analyzed by Flame AA. F - Analyzed by Furnace AA.. CV - Analyzed by Manual Cold Vapor techniques. AV - Analyzed by Automated Cold Vapor techniques. C - Analyzed by Manual Spectrophotometric Method. CA- Analyzed by Midi -distillation Spectrophotometric Method. NR- Analyte not Required. U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET ; MW -BD Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSLO10 Matrix (soil/water): WATER Lab Sample ID: 0706952-001 Level (low/med): LOW Date Received: 6/14/2007 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte ConcentrationI C Q + M i 7440-43-9 Cadmium 1.1 B P 7440-70-2 Calcium 39500 P 7439-89-6 Iron 1234 P- 7439-92-1 Lead 1.1 U P 7439-95-4 Magnesium 17300 P 7439-96-5 Manganese 4580 P 7440-09-7 Potassium 4520 B E P 7440-23-5 Sodium_ 15600 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments DATE REPORTED: JUNE 21, 2007 FORM I - IN ILM04.1 1 2j4 "US, INC. 575 Broad Hollow Road, Movie W 11747 (631)6943040. FAX (631)42G8436 WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-001A Type: Aqueous Origin: Attn To Original Client ID. : MW -BD Collected 6/14/07 11:50:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 31.0 1 mg/L E310.1 06/20/2007 2:35 PM Chloride 42.2 1 mg/L E300.0 06/22/2007 4:52 PM Sulfate 108 5 mg/L E300.0 06/22/2007 8:59 PM Bromide < 0.5 1 mg/L E300.0 06/22/2007 4:52 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/15/2007 9:05 AM Total Dissolved Solids 305 1 mg/L E160.1 06/19/2007 12:04 PM -'QUalifl2rs: E --Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Laboratory Manager Page 1 of 40 U "U%4, IMC. 575BroadFdlow Road, Md g-- W 11747 (631)69A-3040.FAX(631)4205436 WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. :-0706952-001B Type : Aqueous ' Origin: Attn To Original Client ID. MW -BD Collected 6/14/07 11:50:00 AM Received 6/14/07 3:15`.00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Chemical Oxygen Demand <10 1 mg/L E410.4 06/26/2007 1:02 PM Nitrogen, Ammonia (As N) 0.13 1 mg/L E350.1 06/28/2007 1:20 PM Nitrate as N 8.48 10 mg/L E353.2 06/25/2007 11:55 AM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 06/27/2007 9:20 AM Nitrogen, Kjeldahl,. Total 1.01 1 mg/L E351.2 06/26/2007 1:30 PM —� Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 2 of 40 Laboratory Manager E_ U2AA IAU%4, INC* 575 Broad Hollow Road, Me1Ze NY 11747 (631)6943040. FAX (631)4205436 NYSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No.: 0706952-001C Type: Aqueous Attn To Original Origin: Client ID. MW -BD Collected 6/14/07 11:50:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Hardness (As CaCO3) 210 10 mg/L E130.2 06/28/2007 1:06 PM t Qualifiers: E - Value above quantitation range D - Results for Dilution-- &KI1t D.F. = Dilution Factor Date Reported : Laboratory Manager Page 3 of 40 575 Broad hollow Road, Metyle W 11747 (631)6943040.FAX(631)42U436 WSDOHID#10478 LABORATORY RESULTS - Town of Southold Landfill Lab No. : 0706952-001 E Attn To Original Collected 6/14/07 11:50:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Total Organic Carbon Client ID. : MW -BD Results Qualifier D.F. Units 1.3 1 mg/L - QU811fi&r—s.'—E -Value above quantitation range - -- --- -- D - Results for Dilution D.F. = Dilution Factor Date Reported : Page •4 of 40 Sample Information... Type: Aqueous Origin: Method Number Analyzed SW9060 06/21/2007 6:05 PM MY - Laboratory Manager U.S. EPA - CLP Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 EPA SAMPLE NO. M INORGANIC ANALYSIS DATA SHEET 0.45 B P 7440-70-2 MW -4D Lab Name: H2M LABS, INC. Contract: 7439-89-6 Iron Lab Code: 10478 Case No. SAS No.: SDG No.: TSLO10 Matrix (soil/water): WATER Lab Sample ID: 0706952-002 Level (low/med)• LOW Date Received: 6/14/2007 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C( Q M 7440-43-9 Cadmium 0.45 B P 7440-70-2 Calcium 56500 P 7439-89-6 Iron 94.4 B P 7439-92-1 Lead 1.1 U P 7439-95-4 Magnesium 20200 P 7439-96-5 Manganese 10100 P 7440-09-7 Potassium 48200 E P 7440-23-5 Sodium 25000 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR` Artifacts: Comments: DATE REPORTED: JUNE 21, 2007 FORM I - IN ILM04.1 575 Broad Hdlg v Road, Mdvae W 11747 (631)694MQ.FAx(631)420$4W WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-002A Type: Aqueous Attn To Original Origin: Client ID. : MW -4D - Collected 6/14107 10:30:00 AM Received 6/14107 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 10 1 mg/L E310.1 06/20/2007 2:40 PM Chloride 35.2 1 mg/L E300.0 06/22/2007 5:05 PM Sulfate 96.5 5 mg/L E300.0 06/22/2007 9:14 PM Bromide < 0.5 1 mg/L E300.0 06/22/2007 5:05 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/15/2007 9:10 AM Total Dissolved Solids 445 1 mg/L E160.1 06/19/2007 12:06 PM — Qualifiers: — E - Value above quantitationrarige - — D - Results for Dilution D.F. = Dilution Factor Date Reported Page 5 of 40 Laboratory Manager U2At "US, INC. 575 Broad Hollow Road, MdAe NY 11747 (631)6943M-FAX,(631)420$436 NYSDOHID#10478 Town of Southold Landfill Attn To : Original Collected 6/14/07 10:30:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC LABORATORY RESULTS Sample Information... Lab No. : 0706952-002B Type: Aqueous Client ID. : MW -4D Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Chemical Oxygen Demand 40.9 1 mg/L E410.4 06/26/20071:03 PM Nitrogen, Ammonia (As N) 0.78 1 mg/L E350.1 06/28/2007 1:22 PM Nitrate as N 8.55 10 mg/L E353.2 06/25/2007 11:57 AM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 06/27/2007 9:30 AM Nitrogen, Kjeldahl, Total 2.50 10 mg/L E351.2 06/26/2007 1:31 PM Qualifiers E - Value above quantitation range T D - Results for Dilution D.F. = Dilution Factor Date Reported: Laboratory Manager Page 6 of 40 - 1112% "Uss isce 575 Broad Hollow Road, Melville W 11747 (631)6943040.FAX (631)42M436 NYSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-0020 Type: Aqueous Attn To Original Origin: Client ID. : MW -41) Collected 6/14/07 10:30:00 AM Received 6/14/07 3:15:00 PM Collected By: VG COPY : Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Hardness (As CaCO3) 250 10 mg/L E130.2 06/28/2007 1:09 PM -`? Quallfle S. E - Value afwve quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Laboratory Manager Page 7 of 40 E' -t 575 Broad Hallow Road, Melvile W 11747 - (631)6943040.FAX' (631)420-84W WSDOHID#10478 LABORATORY RESULTS r Sample Information... Town of Southold Landfill Lab No. : 0706952-002E Type: Aqueous Attn To Original Origin: Client ID. MW -4D Collected 6/14107 10:30:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Total Organic Carbon 11.7 1 mg/L SW9060 06/21/2007 6:35 PM ciUellfl@�S: E - V5lue above quantitation range ' D - Results for Dilution D.F. = Dilution Factor Date Reported : Laboratory Manager Page 8 of 40 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -4S Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSLO10 Matrix (soil/water): WATER Lab Sample ID: 0706952-003 Level (low/med): LOW Date Received: 6/14/2007 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 ICadmium 0.16 U P 7440-70-2 iCalcium 182000 P 7439-89-6 jIron 680 7439-92-1 Lead 1.1 U _P P 7439-95-4 Magnesium 79800 P 7439-96-5 Manganese 2920 P 7440-09-7 Potassium 67500 E P 7440-23-5 Sodium 256000 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: JUNE 21, 2007 M C/1 CD CD v� H FORM I - IN ILM04.1 575 Broad Hollow Road, Melv3e NY 11747 (631)6M3040.FAX(631)420-8436 NYSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 07069662-003A Type: Aqueous Origin: Attn To Original Client ID. MW -4S Collected 6/14/07 10:00:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 876 20 mg/L E310.1 06/20/2007 2:.45 PM Chloride 352 20 mg/L E300.0 06/27/2007 7:20 PM Sulfate 91.0 5 mg/L E300.0 06/22/2007 9:29 PM Bromide 2.0 1 mg/L E300.0 06/22!2007 5:19 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/15/2007 9:15 AM Total Dissolved Solids 1300 4 mg/L E160.1 06/19/2007 12:08 PM QUallfler5: E - Value above quantitation range F " D - Results for Dilution D.F. = Dilution Factor Date Reported : Laboratory Manager Page 9 of 40 U2/4 "US, I %C. 575 Broad Hollow Road, Meivile NY 11747 (631)6943 .FAx(631)4208436NYSDDHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 07069552-003B Attn To : Original Collected 6/14/07 10:00:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Chemical Oxygen Demand Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Nitrogen, Kjeldahl, Total Client ID. : MW -4S Results Qualifier D.F.. Units 107 1 mg/L 19.6 10 mg/L < 0.10 1 mg/L < 5.0 1 lig/L 32.9 50 mg/L QUaiifierS-.E-- Vslue above quanthation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 10 of 40 Sample Information... Type: Aqueous Origin: Method Number Analyzed E410.4 06/26/2007 1:04 PM E350.1 06/28/2007 1:23 PM E353.2 06/25/2007 11:58 AM E420.1 06/27/2007 9:40 AM E351.2 06/26/20071:32 PM Laboratory Manager U2/4 "US, INC. 575 Broad Hdlow Road, Melville W 11747 (631)694-3040. FAX(631)4208436 WSDOHID#10478 Town of Southold Landfill Attn To Original Collected 6/14/07 10:00:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC LABORATORY RESULTS Sample Information... Lab No. : 0706952-0O3C Type: Aqueous Client 11). : MW -4S Origin: Parameter(s) • Results Qualifier D.F. Units Method Number Analyzed Hardness (As CaCO3) 780 .20 mg/L E130.2 06/28/2007 1:12 PM 00 M O O Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported: Laboratory Manager Page 11 of 40 U"U%s INC* 575 Broad Hollow Road, Mdvlle W 11747 (631)6943040. FAX (631)4208136 WSDOH ID# 10478 Town of Southold Landfill Attn To : Original LABORATORY RESULTS Lab No. : 0706952-003E Client ID. : MW -4S Sample Information... Type: Aqueous Origin: Collected 6/14/07 10:00:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Total Organic Carbon 28.9 1 mg/L SW9060 06/21/2007 7:05 PM Qualifiers: E-V5Iue above quantitation range - D - Results for Dilution D.F. = Dilution Factor Date Reported : Laboratory Manager Page 12 of 40 U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte ConcentrationlC Q M i 7440-43-9 Cadmium 0.16 U P 7440-70-2 Calcium 99100 P 7439-89-6 Iron 93.4 B P 7439-92-1 Lead 2.3 B P 7439-95-4 Magnesium 58100 P 7439-96-5 Manganese 11800 P 7440-09-7 Potassium 121000 E P Sodium 245000 P ffTf Color Before: COLORLESS Clarity Before Color After: COLORLESS Clarity After: Comments: DATE REPORTED: JUNE 21, 2007 EPA SAMPLE NO MW -5D SDG No.: TSL010 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 CD v� CD CD H 1-I "U%4' INC. 575 Broad Hdlow Road, McNile W 11747 (631)694,3040.FAX: (631)42M436 WSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-004A Attn To : Original Collected 6/14/07 9:15:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Alkalinity, Total (As CaCO3) Chloride Sulfate Bromide Biochemical Oxygen Demand Total Dissolved Solids D - Results for Dilution D.F. = Dilution Factor Date Reported Client ID. : MW -5D Results Qualifier D.F.. Units 312 10 mg/L 376 10 mg/L 53.9 10 mg/L 0.7 1 mg/L < 2 1 mg/L 1220 4 mg/L Page 13 of 40 Sample Information... Type: Aqueous Origin: Method Number Analyzed E310.1 06/20/2007 2:50 PM E300.0 06/27/2007 7:34 PM E300.0 06/27/2007 7:34 PM E300.0 06/22/2007 5:32 PM E405.1 06/15/2007 9:20 AM E160.1 06/19/2007 12:10 PM Laboratory Manager —4 d- O O r� C/) H 1H2 A "US. IMC• 575 Broad Hallow Road, Mdville NY 11747 (631)6943040. FAX (631)42M436 NYSDOHID#117478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-004B Attn To Original Collected 6/14/07 9:15:00 AM Received 6/14107 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Chemical Oxygen Demand Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Nitrogen, Kjeldahl, Total Client ID. : MW -5D Results Qualifier D.F.. Units 102 1 mg/L 50.6 10 mg/L < 0.10 1 mg/L < 5.0 1 pg/L 58.4 20 mg/L 'age 14 of 40 Sample Information... Type: Aqueous Origin: Method Number Analyzed E410.4 06/26/2007 1:05 PM E350.1 06/28/2007 1:24 PM E353.2 06/25/2007 12:01 PM E420.1 06/27/2007 9:50 AM E351.2 06/26/2007 4:20 PM ? &KII-1- *A ; Laboratory Manager 575 Broad Hollow Road, McNae NY 11747 (631)694- 0 .FAX(631)42054% WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. :0706952-0040 Type: Aqueous Attn To Original Origin: Client ID. MW-5D Collected 6/14/07 9:15:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Hardness (As CaCO3) 560 120 mg/L E130.2 06/28/2007 1:15 PM Qtlallfle(S: E- Value'above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Laboratory Manager Page 15 of 40 E- NU -2A "Use IWO 575 Broad Hollow Road, Meluz1e W 11747 (631)6943040. FAX (631) 42(}8436 NYSDOH ID# 10478 Town of Southold Landfill Attn To : Original Collected 6/14/07 9:15:00 AM Received 6/14/07 3:15:00 PM Collected By: VG COPY : Original CC LABORATORY RESULTS Sample Information... Lab No. : 0706952-004E Type: Aqueous Client ID. : MW -5D Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Total Organic Carbon 26.7 1 mg/L SW9060 06/21/2007 7:35 PM Qualifiers: E.- Value above quantitation range .._ - D Results for Dilution D.F. = Dilution Factor ? &W" A 1-d'hA� Date Reported : Laboratory Manager Page 16 of 40 r U.S. EPA - CLP - 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET i MW -5S Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSLO10 Matrix (soil/water): WATER Lab Sample ID: 0706952-005 Level (low/med): LOW Date Received: 6/14/2007 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.36 B P 7440-70-2 Calcium 16800 P 7439-89-6 Iron 231 P 7439-92-1 Lead 1.3 B P 7439-95-4 Magnesium 12400 P j 7439-96-5 Manganese 2540 P 7440-09-7 Potassium 6240 E P 7440-23-5 ISodium 16100 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: JUNE 21, 2007 O O FORM I - IN ILM04.1 I-1 "19%, ING 575 Broad Hollow Road, Melville W 11747 (631)6943 : FAX' (631)42"436 WSDOH'ID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 07069552-0055' A Type: Aqueous Attn To Original Origin: Client ID. MW -5S Collected 6/14/07 9:45:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original. CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 41.0 2 mg/L E310.1 06/22/2007 2:45 PM Chloride 23.5 1 mg/L E300.0 06/22/2007 6:13 PM Sulfate 34.8 1 mg/L E300.0 06/22/20076:13 PM Bromide < 0.5 1 mg/L E300.0 06/22/2007 6:13 PM Biochemical Oxygen Demand <2 1 mg/L E405.1 06/15/2007 9:30 AM Total Dissolved Solids 185 1 mg/L E160.1 06/19/2007 12:16 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported :Laboratory Manager Page 17 of 40 ®-2""M� IMC• 575 Broad Hollow Road, Melville W 11747 (631) 694,9040. FAX: (631) 420$436 WSDOH ID# 10478 Town of Southold Landfill Attn To : Original Collected 6/14/07 9:45:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC LABORATORY RESULTS Sample Information... Lab No. : 0706952-005B Type: Aqueous Client ID. : MW -5S Origin: Parameter(s) Results Qualifier D.F.. ,Units Method Number Analyzed Chemical Oxygen Demand. <10 1 mg/L E410.4 06/26/2007 1:08 PM Nitrogen, Ammonia (As N) 0.53 1 mg/L E350.1 06/28/2007 1:28 PM Nitrate as N 7.16 10 mg/L 11353.2 06/25/2007 12:05 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 06/27/2007 10:20 AM Nitrogen, Kjeldahl, Total 1.60 10 mg/L E351.2 06/26/2007 1:36 PM Qualifiers: E - Value above quantitation range D - Results for Dilution , awvl . � .. D.F. = Dilution Factor Date Reported : Laboratory Manager Page 18 of 40 575 Broad Hollow Road, Melvile W 11747 (631)6943040.FAX (631)420-84.36 WSDOHID#10478 Town of Southold Landfill Attn To : Original Collected 6/14107 9:45:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC LABORATORY RESULTS Sample Information... Lab No. : 0706952-005C Type: Aqueous Client ID. : MW -5S Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analvzed Hardness (As CaCO3) 110 10 mg/L E130.2 06/28/2007 1:24 PM Qualifiers: E- Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Laboratory Manager Page 19 of 40 00 It C/1 O O 00 E - IH2/4 "US. INC. 575 Broad Hollow Road, Me\r?e W 11747 (631)6943040.FAX:(631)42M436 WSDOH ID# 10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-005E Type: Aqueous Attn To Original Origin: Client ID. MW -5S Collected 6/14/07 9:45:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original cc Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Total Organic Carbon 5.2 1 mg/L SW9060 06/21/2007 9:06 PM O\ 'Zt C/) O _.l Qualifiers: E -Value above quantitation range ' D - Results for Dilution a/1VP4 - E -i D.F. = Dilution Factor Date Reported : Laboratory Manager Page 20 of 40 U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.20 B P 7440-70-2 Calcium 41400 P 7439-89-6 Iron 114 P 7439-92-1 ILead 1.1 U P 7439-95-4 Magnesium 18000 P 7439-96-5 Manganese j 4760 P 7440-09-7 Potassium 4580 B E P 7440-23-5 sodium 16100 P Color Before: COLORLESS Clarity Before Color After: COLORLESS Clarity After: Comments: DATE REPORTED: JUNE 21, 2007 IJLr t -IL% EPA SAMPLE NO MW -6D SDG No.: TSLO10 6/14/2007 Texture: Artifacts: FORM I - IN ILM04.1 O V1 O O C/] H 575 Broad Hollow Road, MelvL- NY 11747 (631)6943040. FAX:(631)42H436 NYSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-006A Attn To : Original Collected 6/14/07 11:50:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Alkalinity, Total (As CaCO3) Chloride Sulfate Bromide Biochemical Oxygen Demand Total Dissolved Solids Client ID. : MW -6D Results Qualifier D.F.. Units 28.0 1 mg/L 42.3 1 mg/L 109 5 mg/L < 0.5 1 mg/L < 2 1 mg/L 290 1 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 21 of 40 Sample Information... Type: Aqueous Origin: Method Number Analyzed E310.1 06/22/2007 2:50 PM E300.0 06/22/2007 6:26 PM E300.0 06/22/2007 10:56 PM E300.0 06/22/2007 6:26 PM E405.1 06/15/2007 9:35 AM E160.1 06/19/2007 12:18 PM Laboratory Manager 575 Broad Hollow Road, Melville NY 11747 (631)694W40.FAX:(631)420-84% NYSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. 0706952-0068 Type: Aqueous Attn To Original Origin: Client ID. MW -6D Collected 6/14/07 11:50:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Chemical Oxygen Demand 18.1 1 mg/L E410.4 06/26/2007 1:09 PM Nitrogen, Ammonia (As N) 0.24 1 mg/L E350.1 06/28/2007 1:29 PM Nitrate as N 7.76 10 mg/L E353.2 06/25/2007 12:06 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 06/27/2007 10:30 AM Nitrogen, Kjeldahl, Total' 0.71 1 mg/L E351.2 06/27/2007 12:23 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported Laboratory Manager Page 22 of 40 N O O 575 Broad Follow Road, Melville NY 11747 - (631)6943040.FAx(631)4208436 NYSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-006C Type: Aqueous Attn To Original Origin: Client ID. MW -6D Collected 6/14/07 11:50:00 AM Received 6/14/07 3:15:00,PM Collected By 'VG Copy : Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Hardness (As CaCO3) 190 10 mg/L E130.2 06/28/2007 1:27 PM Qualifiers: E - Value above quantitation. range D - Results for Dilution D -F. = Dilution Factor Date Reported : Laboratory Manager Page 23 of 40 575 Broad Hollow Road, Mme W 11747 (631)694,1040-FAK(631)420-8436 WSD0HID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. 0706952-006E Type; Aqueous Attn To Original Origin: Client ID. MW -6D Collected 6/14/07 11:50:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Total Organic Carbon 2.0 1 mg/L SW9060 06/21/2007 9:37 PM' Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 24 of 40 Laboratory Manager U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET t MW -6S j Lab Name:' H2M LABS, INC. Contract: i r Lab Code: 10478 Case No. SAS No.: SDG No.: TSLO10 Matrix (soil/water): WATER Lab Sample ID: 0706952-007 Level (low/med): LOW Date Received: 6/14/2007 % Solid's: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. I Analyte Concentration Q I M 7440-43-9 Cadmium 0.16 U P 7440-70-2 Calcium 14400 P 7439-89-6 Iron 153 P 7439-92-1 bead 1.1 U P 7439-95-4 Magnesium j 3730 B P 7439-96-5 Manganese 1330 P 7440-09-7 IPotassium 6560 E P 7440-23-5 ISodiurn 4610 B' I P Color Before: COLORLESS Clarity Before: CLEAR -_ Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: JUNE 21, 2007 FORM I - IN ILM04.1 112A "US, INC. 575 Broad Holbw Road, Melville- NY 11747 (631)694-3040.FAX(631)420.84W WSDOHID#10478 Town of Southold Landfill I Attn To Original Collected 6/14/07 11:10`00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Alkalinity, Total (As CaCO3) Chloride Sulfate Bromide Biochemical Oxygen Demand Total Dissolved Solids LABORATORY RESULTS Sample Information:.. Lab No. : 0706952-007A Type: Aqueous Origin: Client ID. : MW -6S Results Qualifier D.F.. Units 41.0 2 mg/L 5.7 1 mg/L 12.4 1 mg/L < 0.5 1 mg/L * 2 1 mg/L 103 1 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 25 of 40 Method Number Analyzed E310.1 06/22/2007 2:55 PM E300.0 06/22/2007 6:40 PM E300.0 06/22/2007 6:40 PM E300.0 06/22/2007 6:40 PM E405.1 06/15/2007 9:40 AM E160.1 06/19/2007 12:20 PM Laboratory Manager U2/4 "US, INCo 575 Broad Hollow Road, Melville NY 11747 (631)6943040.FAX:(631)420S436 WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 07069552-0078 Type: Aqueous Attn To Original Origin: Client ID. MW -6S Collected 6/14/07 11:10:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D_F. Units Method Number Analyzed Chemical Oxygen Demand 23.1 1 mg/L E410.4 06/26/2007 1:10 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 06/28/2007 1:30 PM Nitrate as N 0.49 1 mg/L E353.2 06/25/2007 12:07 PM Phenolics, Total Recoverable <.5.0 1 pg/L E420.1 06/27/2007 10:40 AM Nitrogen, Kjeldahl, Total 1.08 1 mg/L E351.2 06/27/2007 12:24.PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 26 of 40 Laboratory Manager U2A USs Co 575 Broad Hollow Road; Melville NY 11747 (631)694W0 .FAK(631)4205436 NYSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-007C Type: Aqueous Attn To Original Origin: Client ID. MW -6S Collected 6/14/07 11:10:00 AM Received 6/14/07 3:15:00 PM Collected By: VG COPY : Original cc Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Hardness (As CaCO3) .55.0 5 mg/L E130.2 06/28/2007 1:30 PM E - Value above quantitation range � Qualifiers: 9 9 D - Results for Dilution D.F. = Dilution Factor Date Reported : Laboratory Manager Page 27 of 40 FZ14 I US, INC* 575 Broad FIdbw Road, Melvile NY 11747 (631) 6943040YAK (631)42084W NYSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-007E Attn To Original Client ID. : MW -6S Collected 6/14/07 11:10:00 AM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F. Units Total Organic Carbon 9.4 1 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 28 of 40 Sample Information... Type: Aqueous Origin: Method Number Analyzed SW9060 06/21/2007 10:07 PM Laboratory Manager U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET ---� [NW -8D Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSLO10 Matrix (soil/water): WATER Lab Sample ID: 0706952-008 Level (low/med): LOW Date Received: 6/14/2007 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.16 U P 7440-70-2 Calcium 72700 P 7439-89-6 Iron 8940 P 7439-92-1 Lead 1.1 U P 7439-95-4 Magnesium 38500 P 7439-96-5 Manganese 1600 P 7440-09-7 Potassium j 84700 E { P 7440-23-5 Sodium 82700 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: JUNE 21, 2007110 FORM I - IN ILM04.1 O Cn O ,--q O H 575 Broad Hollow Road, Metvte W 11747 (631)694- 0 - FAX (631)4M8436 NYSD0HID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No.: 07069552-008A Attn To Original Client ID. : MW -8D Collected 6/14/07 12:35:00 PM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original cc Sample Information... Type: Aqueous Origin: Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 434 10 mg/L E310.1 06/22/2007 3:00 PM Chloride 139 5 mg/L E300.0 06/22/200711:11 PM Sulfate 89.4 5 mg/L E300.0 06/22/2007 11:11 PM Bromide 0.7 1 mg/L E300.0 06/22/2007 6:54 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/15/2007 9:45 AM Total Dissolved Solids 674 1 mg/L E160.1 06/1.9/2007 12:22 PM Qualifiers: E - Value above quantitation range D Results for Dilution D.F. = Dilution Factor ? &'W". A /PAXI� Date Reported : Laboratory Manager Page 29 of 40 - U28i "US. INC. 575 Broad Hollow Road, Melville NY 11747 (631)6943040. FAX -(631)420-84W NYSDOH ID# 10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 07069.52-0088 Parameter(s) Chemical Oxygen Demand Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Nitrogen, Kjeldahl, Total Client ID. : MW -8D Results Qualifier D.F.. Attn To Original Collected 6/14/07 12:35:00 PM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC 1 Parameter(s) Chemical Oxygen Demand Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Nitrogen, Kjeldahl, Total Client ID. : MW -8D Results Qualifier D.F.. Units 61.1 1 mg/L 38.7 10 mg/L < 0.10 1 mg/L 12.7 1 Ng/L 47.0 20 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported Page 30 of 40 Sample Information... Type: Aqueous Origin: Method Number Analyzed E410.4 06/26/2007 1:11 PM E350.1 06/28/2007 1:31 PM E353.2 06/25/2007 12:09 PM E420.1 06/27/2007 10:50 AM E351.2 06/26/2007 3:29 PM Laboratory Manager U2/44 "US. INCe 575 Broad Hollwv Road, Melville W 11747 (631)694-3040. FAX (631)42H436 WSDOH ID# 10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-OOBC Attn To Original Client ID. : MW -8D Collected 6/14/07 12:35:00 PM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Hardness (As CaCO3) 340 10 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported: Page 31 of 40 Sample Information... Type: Aqueous Origin: Method Number Analyzed E130.2 .06/28/2007 1:33 PM Laboratory Manager 575 Broad Hollow Road, Md!vile W 11747 (631)694-3040.FAX(631)420S436 WSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-008E Attn To : Original Client ID. : MW -8D Collected 6/14/07 12:35:00 PM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Total Organic Carbon 23.0 1 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported Page 32 of 40 Sample Information... Type: Aqueous Origin: Method Number Analyzed SW9060 06/21/2007 10:37 PM Laboratory Manager U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET r-� MW -8S Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSLO10 Matrix (soil/water): WATER Lab Sample ID: 0706952-009 Level (low/med).: LOW Date Received: 6/14/2007 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte !Concentration C Q M 7440-43-9 ICadmiu 0.91 B P 7440-70-2 ICalcium 60300 P 7439-89-6 Iron 49000 P 7439-92-1 Lead 1.1 U. I P 7439-95-4 Magnesium 20400 P 7439-96-5 Manganese 418 P 7440-09-7 Potassium 39600 E I P 7440-23-5 Sodium 37800 P Color Before: COLORLESS Clarity Before: Color After: COLORLESS Clarity After: Comments: DATE REPORTED: JUNE 21, 2007 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.,1 U2/4 "US' INCo 575 Broad Hollow Road, Mdvie W 11747 (631)6943040.FAX{631)4205436 WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 07069552-009A Type: Aqueous Attn To Original Origin: Client ID. MW -8S Collected 6/14/07 12:10:00 PM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original cc Parameter(s) Results Qualifier D.F. 'Units Method Number Analyzed Alkalinity, Total (As CaCO3) 290 10 mg/L E310.1 06/22/2007 3:05 PM Chloride 58.9 5 mg/L E300.0 06/22/2007 11:26 PM Sulfate 33.7 1 mg/L E300.0 06/22/2007 7:34 PM Bromide < 0.5 1 mg/L E300.0 06/22/2007 7:34 PM Biochemical Oxygen Demand 3 1 mg/L E405.1 06/15/2007 9:50 AM Total Dissolved Solids 414 2 mg/L E160.1 06/19/2007 12:24 PM Qualifiers: E - Value above quantitation range ' D - Results for Dilution D.F. = Dilution Factor Date Reported : Laboratory Manager Page 33 of 40 U2/4 LAM, INCe 575 Broad Paw Road, Melville NY 11747 (631)694,3040. FAX- (631)42(}8436 NYSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-009B Attn To Original Client ID. : MW -8S Collected 6/14/07 12:10:00 PM Received" 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Sample Information... Type: Aqueous Origin: Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Chemical Oxygen Demand 61.1 1 mg/L E410.4 06/26/2007 1:12 PM Nitrogen, Ammonia (As N) 28.2 10 mg/L E350.1 06/28/2007 1:37 PM Nitrate as N < 0.10 1. mg/L E353.2 06/25/2007 12:10 PM Phenolics, Total Recoverable < 5.0 1 Ng/L E420.1 06/27/2007 11:00 AM Nitrogen, Kjeldahl, Total 35.4 20 mg/L E351.2 06/26/2007 3:29 PM O - r --i Qualifiers: E - Value above quantitation range 1--i D -Results for Dilution D.F. = Dilution Factor Date Reported : Laboratory Manager Page 34 of 40 U2A WU%9 INCE 575 Broad Hollow Road, Mdvile W 11747 (631)6943040. FAK(631)4208436 WSDOHID#10478 Town of Southold Landfill Attn To Original LABORATORY RESULTS Lab No. : 0706952-009C Client ID. : MW -8S Sample Information... Type: Aqueous Origin: Collected 6/14/07 12:10:00 PM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Hardness (As CaCO3) 290 10 mg/L E130.2 06/28/2007 1:36 PM Qualifiers: E -Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Laboratory Manager Page 35 of 40 575 Broad Hollow Road, MdvZe W 11747 (631)694, LABORATORY NYSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-009E Attn To : Original Client ID. : MW -8S Collected 6114/07 12:10:00 PM Received 6/14107 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F. Units Total Organic Carbon 23.0 1 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 36 of 40 Sample Information... Type: Aqueous Origin: Method Number Analyzed SW9060 06/22/2007 12:09 AM Laboratory Manager U.S. EPA - CLP Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 - EPA SAMPLE NO 17440-43-9 INORGANIC ANALYSIS DATA SHEET P 7440-70-2 Calcium 46.4B P 7439-89-6 FB 061407 Lab Name: H2M LABS, INC. Contract: Lead 1.1 U P 7439-95-4 Lab Code: 10478 Case No. SAS No.: SDG No.: TSLO10 Matrix (soil/water): WATER Lab Sample ID: 0706952-010 Level (low/med): LOW Date Received: 6/14/2007 o Solids: 0_0 P Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentrationj.C! Q i M 17440-43-9 Cadmium 0.16 U P 7440-70-2 Calcium 46.4B P 7439-89-6 Iron 22.4 B P 7439-92-1 Lead 1.1 U P 7439-95-4 Magnesium 7.7 U P 7439-96-5 Manganese 0.79 B P 7440-09-7 Potassium 80.6 B E P 7440-23-5 Sodium 89.71 B.. P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: JUNE 21, 2007 FORM I - IN ILM04.1 1 2j4 "US, INC. 575 Broad Hollow Road, McWe W 11747 (631) 6943040.FAX (631)42M436 WSDOHID#10478 LABORATORY RESULTS j Sample Information... Town of Southold Landfill Lab No. : 0706952-010A Type: Field Blank Attn To Original Origin: Client ID. : FB 061407 Collected 6/14/07 12:00:00 PM Received 6/14/07 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310.1 06/22/2007 3:10 PM Chloride < 2.0 1 mg/L E300.0 06/22/2007 7:48 PM Sulfate < 5.0 1 mg/L E300.0 06/22/2007 7:48 PM Bromide < 0.5 1 mg/L E300.0 06/22/2007 7:48 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/15/2007 9:55 AM Total Dissolved Solids <10 1 mg/L E160.1 06/19/2007 12:26 PM .y Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported Page 37 of 40 4r/ KIV6 Laboratory Manager U2/4 "KAs ING 575 Broad Hollow Road, MelvBe NY 11747 (631)6943040. FAX (631)420-8436 NYSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. 0706952-0106 Type: Field Blank Attn To Original Origin: Client ID. FB 061407 Collected 6/14/07 12:00:00 PM Received 6/14/07 3:15:00 PM Collected By: VG COPY : Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Chemical Oxygen Demand <10 1 mg/L E410.4 06/26/2007 1:13 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 06/28/2007 1:38 PM Nitrate as N < 0.10 1 mg/L E353.2 06/25/2007 12:11 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 06/27/2007 11:10 AM Nitrogen, Kjeldahl, Total < 0.10 1 mg/L E351.2 06/28/2007 1:47 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Laboratory Manager. Page 38 of 40 575 Broad Hollow Road, Melvie W 11747 (631)6943040.FAX(631)4208436 WSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706952-01 OC Attn To : Original Client ID. : FB 061407 Collected 6/14/07 12:00:00 PM Received 6114107 3:15:00 PM Collected By: VG Copy : Original CC Parameter(s) Results Qualifier D.F. Units Hardness (As CaCO3) <5.0 1 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Sample Information... Type: Field Blank Origin: Method Number Analyzed E130.2 06/28/2007 1:39 PM Laboratory Manager Page 39 of 40 575 Broad Hollow Road, McSvile NY 11747 (631)694.30AO.FAX (631)42M436 NYSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706952-OI OE Type: Field Blank Origin: Attn To Original Client ID. : FB 061407 Collected 6/14/07 12:00:00 PM Received 6/14/07 3:15:00 PM Collected By: VG COPY : Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Total Organic Carbon < 1.0 1 mg/L SW9060 06/22/2007 12:40 AM Qualifiers: E -Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Laboratory Manager Page 40 of 40 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET I MW -1D Lab. Name: H2M LABS, INC. Contract: i Lab Code: 10478 Case No. SAS No.: SDG No.: TSLO10 Matrix (soil/water): WATER Lab Sample ID: 0706986-001 Level (low/med): LOW Date Received: 6/15/2007 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration CI Q I M 7440-43-9 Cadmium 0.16 U P 7440-70-2 ICalcium 22700 P 7439-89-6 Iron 222 P 7439-92-1 Lead 1.1 U P 7439-95-4 Magnesium 10400 P 7439-96-5 Manganese 7.1 B P 7440-09-7 Potassium 1360 B E P 7440-23-5 Sodium 20100 P Color Before: COLORLESS Clarity Before: Color After: COLORLESS Clarity After: Comments: DATE REPORTED: JUNE 21, 2007 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 U2At "UJ' Isce 575 &cad Hollow Road, MdvIDe W 11747 (631)694.3040.FAX(631)420-84W WSDDHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706986-OOIA I Attn To Original Collected 6/15/07 11:15:00 AM Received 6/15107 1:53:00 PM Collected By: Client Copy : Original CC Parameter(s) Alkalinity, Total (As CaCO3) Chloride Sulfate Bromide Biochemical Oxygen Demand Total Dissolved Solids Client ID. : MWAD Results Qualifier D.F.. Units 31.3 2 mg/L 23.0 1 mg/L 62.7 5 mg/L < 0.5 1 mg/L < 2 1 mg/L 176 1 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 6/29/07 Page 1 of 16 Sample Information... Type: Aqueous Origin: Method Number Analyzed E310.1 06/22/2007 3:25 PM E300.0 06/22/2007 8:01 PM E300.0 06/22/2007 11:41 PM E300.0 06/22/2007 8:01 PM E405.1 06/15/2007 4:00 PM E160.1 06/19/2007 12:28 PM Laboratory Manager 575 Broad Hollow Road, Mdvile W 11747 (631)694-.3040.FAX-(631)42M436 WSDOH ID# 10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706986-001 B Type: Aqueous ' Origin: Attn To : Original Client ID. MW -1D Collected 6115/07 11:15:00 AM Received 6/15/07 1:53:00 PM Collected By: Client Copy Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Chemical Oxygen Demand <10 1 mg/L E410.4 06/26/2007 1:14 PM Nitrogen, Ammonia (As N) 0.21 1 mg/L E350.1 06/28/2007 1:39 PM Nitrate as N 2.88 5 mg/L E353.2 06/25/2007 12:12 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 06127/2007 11:20 AM Nitrogen, Kjeldahl, Total 0.76 1 mg/L E351.2 06/26/2007 1:40 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor ? awl,' A /P-"� Date Reported : 6/29/07 Laboratory Manager Page 2 of 16 I-II ILA13S9 ING 575 Broad Hdbw Road, MdVae W 11747 (631) 6943040. FAX(631)42084.96 WSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706986-001 C Attn To : Original Client ID. : MW -1 D Collected 6/15/07 11:15:00 AM Received 6/15/07 1:53:00 PM Collected By : Client Copy : Original cc Parameter(s) Results Qualifier D.F.. Units Hardness (As CaCO3) 85.0 5 mg/L Qualifiers: E - Value above quantitation range 'D - Results for Dilution D.F. = Dilution Factor Date Reported: 6/29/07 Page 3 of 16 Sample Information... Type: Aqueous Origin: Method Number Analyzed E130.2 06/28/2007 1:42 PM Laboratory Manager UZ — ��J, INCe 575 Broad Hollow Road, Mdvae W 11747 (631) 6943040. FAX (631)420$436 WSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706986-00'I E Attn To : Original Client ID. : MW -1D Collected 6/15/07 11:15:00 AM Received 6/15/07 1:53:00 PM Collected By: Client Copy Original CC Parameter(s) Results Qualifier D.F.. Units Total Organic Carbon 1.2 1 mg/L Qualifiers: E -Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported: - 6/29/07 Sample Information... Type: Aqueous Origin: Method Number Analyzed SW9060 06/22/2007 1:11 AM Laboratory Manager Page 4 of 16 U.S. EPA - CLP Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 - EPA SAMPLE NO Q M INORGANIC ANALYSIS DATA SHEET 0.50 -�� P 7440-70-2 Calcium 9090 MW -1S Lab Name: H2M LABS, INC. Contract: 2370 P 7439-92-1 Lab Code: 10478 Case No. SAS No.: SDG No.: TSLO10 Matrix (soil/water): WATER Lab Sample ID: 0706986-002 Level (low/med)• LOW Date Received: 6/15/2007 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.50 B1 P 7440-70-2 Calcium 9090 P 7439-89-6 Iron 2370 P 7439-92-1 ILead 2.8 B P 7439-95-4 Magnesium 7150 P 7439-96-5 Manganese 82.3 P 7440-09-7 Potassium 23901B E P 7440-23-5 Sodium 51200 P Color Before: COLORLESS Clarity Before Color After: COLORLESS Clarity After: Comments: DATE REPORTED: JUNE 21, 2007 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 O 00 O r-+ O C/] H 575 Broad Willow Road, Melville NY 11747 (631)6943040.FAX(631)4208436 NYSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706986-002A Type: Aqueous ' Attn To : Original Origin: Client ID. : MWAS Collected 6/15/07 12:00:00 PM Received 6/15/07 1:53:00 PM Collected By: Client Copy : Original cc Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 9.6 1 mg/L E310.1 06/22/2007 3:30 PM Chloride 86.0 5 mg/L E300.0 06/22/2007 11:56 PM Sulfate 27.5 1 mg/L E300.0 06/22/2007 8:15 PM Bromide < 0.5 1 mg/L E300.0 06/22/2007 8:15 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/15/2007 4:10 PM Total Dissolved Solids 202 1 mg/L E160.1 06/19/2007 12:30 PM Qualifiers: --E---value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 6/29/07 Laboratory Manager Page 5 of 16 U2/4 UAU%s INC• 575 Broad How Road, Melville NY 11747 (631) 6943040.FAX (631)4205436 NYSDOH ID# 10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706986-002B Type: Aqueous Attn To Original Origin: Client ID. MWAS Collected 6/15107 12:00:00 PM Received 6/15/07 1:53:00 PM Collected By: Client Copy : Original CC Parameter(s) Results Qualifier DD=F_ Units Method Number Analyzed Chemical Oxygen Demand <10 1 mg/L E410.4 06/26/2007 1:15 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 06/28/2007 1:40 PM Nitrate as N 5.20 10 mg/L E353.2 06/25/2007 12:16 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 06/27/2007 11:30 AM Nitrogen, Kjeldahl, Total 0.53 1 mg/L E351.2 06/26/2007 1:40 PM Qualifiers: E - Value above quantitation range D - Results for Dilution alit", D.F. = Dilution Factor Date Reported : 6/29/07 Page 6 of 16 Laboratory Manager N 00 O O V) E- r WI3S, INC, 575 Broad Hoilow Road, Melva- W 11747 (631) 6943040. FAX(631)420$436 WSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706986-0020 I Attn To Original Client ID. : MW -1S Collected 6/15/07 12:00:00 PM Received - 6/15/07 1:53:00 PM Collected By: Client Copy : Original cc Parameter(s) Results Qualifier D.F.. Units Hardness (As CaCO3) 50.0 5 mg/L QualiflefS: E - Value above quantitation range 0 - Results for Dilution D.F. = Dilution Factor Date Reported : 6/29/07 Sample Information... Type: Aqueous Origin: Method Number Analyzed E130.2 06/28/2007 1:45 PM Laboratory Manager Page 7 of 16 575 Broad W w Road, MdvZe W 11747 (631)6943040.FAX:(631)420-8436 WSDDHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706986-002E Type: Aqueous Attn To Original Origin: Client ID. MW -1S Collected 6/15/07 12:00:00 PM Received 6/15/07 1:53:00 PM Collected By : Client Copy : Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Total Organic Carbon 1.4 1 mg/L SW9060 06/22/2007 1:42 AM Quallfit3r5 E - V61ue above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 6/29/07 It 00 O t?/K Laboratory Manager Page 8 of 16 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -3D I Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSLO10 Matrix_ (soil/water): WATER Lab Sample ID: 0706986-003 Level (low/med): LOW Date Received: 6/15/2007 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.16 U P 7440-70-2 Calcium 62100 P 7439-89-6 Iron 6650 P 7439-92-1 Lead 1.1 U P 7439-95-4 Magnesium 33000 P 7439-96-5 Manganese 3930 P 7440-09-7 Potassium 131000 E P 7440-23-5 Sodium 218000 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: . Comments: DATE REPORTED: JUNE 21, 2007 FORM I - IN ILM04.1 V) 00 O O H U2AA "US, INCo 575 Broad Hollow Road, Mabe W 11747 (631)694.3M.FAX (631)42H436 WSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706986-003A Parameter(s) Alkalinity, Total (As CaCO3) Chloride Sulfate Bromide Biochemical Oxygen Demand Total Dissolved Solids Client ID. MW -3D Results Qualifier D.F. Attn To : Original Collected 6/15/07 9:00:00 AM Received 6/15/07 1:53:00 PM Collected By: Client Copy : Original CC 1 Parameter(s) Alkalinity, Total (As CaCO3) Chloride Sulfate Bromide Biochemical Oxygen Demand Total Dissolved Solids Client ID. MW -3D Results Qualifier D.F. Units 948 20 mg/L 241 20 mg/L 39.0 1 mg/L 0.7 1 mg/L < 2 1 mg/L 1020 4 mg/L Qualifiers: E Value aiwve quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 6/29/07 Page 9 of 16 Sample Information... Type: Aqueous Origin: Method Number Analyzed E310.1 06/22/2007 3:35 PM E300.0 06/27/2007 8:55 PM E300.0 06/22/2007 8:28 PM E300.0 06/22/2007 8:28 PM E405.1 06/15/2007 4:15 PM E160.1 06/19/2007 12:32 PM 00 O Q E - Laboratory Manager 575 Broad Hollow Road, Melville NY 11747 (631)6943040. FAX (631)420$436 NYSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706986-003B Type: Aqueous T Qualifiers: E - Value above quantitation range, D - Results for Dilution D -F. = Dilution Factor Date Reported : 6/29/07 r-- 00 f� O Laboratory Manager Page 10 of 16 Origin: Attn To Original Client ID. : MW -3D Collected 6/15/07 9:00:00 AM Received 6/15/07 1:53:00 PM Collected By: Client Copy : Original cc Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Chemical Oxygen Demand 119 1 mg/L E410.4 06/26/2007 1:16 PM Nitrogen, Ammonia (As N) 110 20 mg/L E350.1 06/28/2007 1:41 PM Nitrate as N < 0.10 1 mg/L E353.2 06/25/2007 12:17 PM Phenolics, Total Recoverable 9.5 1 pg/L E420.1 06/27/2007 11:40 AM Nitrogen, Kjeldahl, Total 128 50 mg/L E351.2 06/26/2007 1:41 PM T Qualifiers: E - Value above quantitation range, D - Results for Dilution D -F. = Dilution Factor Date Reported : 6/29/07 r-- 00 f� O Laboratory Manager Page 10 of 16 t12AA SUS, INCe 575 Broad Hollow Road, Melville W 11747 (631)6943040. FAX(631)4205436 WSDOH ID# 10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706986-003C Attn To : Original Client ID. : MW -313 Collected 6/15/07 9:00:00 AM Received 6/15/07 1:53:00 PM Collected By : Client Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Hardness (As CaCO3) 170 10 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported: 6/29/07 Page 11 of 16 Sample Information... Type: Aqueous Origin: Method Number Analyzed E130.2 06/28/2007 1:48 PM Laboratory Manager 00 00 O O HAt I -AUS., ��. 575 Broad Hollow Road, Melville W 11747 (631)6943040.FAX (631)42oS4W WSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706986-003E Attn To : Original Client ID. : MW -31) Collected 6/15/07 9:00:00 AM Received 6/15/07 1:53:00 PM Collected By : Client Copy : Original CC Parameter(s) Results Qualifier D.F.. Units Total Organic Carbon 37.6 1 mg/L QU8lifi6rs: E -value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 6/29/07 Page 12 of 16 Sample Information... Type: Aqueous Origin: Method Number Analyzed SW9060 06/22/2007 2:12 AM Laboratory Manager U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET ---� MW -3S Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL010 Matrix (soil/water): WATER Lab Sample ID: 0706986-004 Level (low/med): LOW Date Received: 6/15/2007 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L ACAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 1.0 B P 7440-70-2 Calcium 50700 P 7439-89-6 Iron 42200 P 7439-92-1 ILead 1.1 U P 7439-95-9 Magnesium 26300 P 7439-96-5 Manganese 19500 P 7440-09-7 Potassium 38600 E P 7440-23-5 Sodium 55800 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: JUNE 21, 2007 FORM I - IN ILM04.1 575 Broad Hollow Road, Melville W 11747 (631)694-3M.FAX (631)42084W NYSDOHID#10478 LABORATORY RESULTS _. Town of Southold Landfill Lab No. : 0706986-004A Attn To : - Original Collected 6/15107 9:45:00 AM Received 6115/071:53:00'PM Collected By: Client Copy : .Original CC Parameter(s) Alkalinity, Total (As CaCO3) Chloride Sulfate Bromide Biochemical Oxygen Demand Total Dissolved Solids Client ID. : MW -3S Results Qualifier D.F.. Units 316 10 mg/L 82.2 5 mg/L 43.2 1 mg/L < 0.5 1 mg/L < 4 1 mg/L 458 2 mg/L Sample Information... Type- Aqueous Origin: Method Number Analyzed E310.1 06/22/2007 3:40 PM E300.0 06/23/2007 12:11 AM E300.0 06/22/2007 8:42 PM E300.0 06/22/2007 8:42 PM E405.1 06/15/2007 4:17 PM E160.1 06/19/2007 12:34 PM ' Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 6/29/07 Page 13 of 16 Laboratory Manager U2j*t "US. INC. 575 Broad Hollow Road, Mddle W 11747 (631)69QW.FAx(631)420&136 WSDOHID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0706986-004B I Attn To Original Client ID. : MW -3S Collected 6115/07 9:45:00 AM Received 6/15/07 1:53:00 PM Collected By: Client Copy : Original CC Sample Information... Type: Aqueous Origin: Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Chemical Oxygen Demand 68.7 1 mg/L E410.4 06/26/2007 1:17 PM Nitrogen, Ammonia (As N) 17.4 10 mg/L E350.1 06/28/2007 1:43 PM Nitrate as N < 0.10 1 mg/L E353.2 06/25/2007 12:18 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 06/27/2007 11:50 AM Nitrogen, Kjeldahl, Total 21.0 10 mg/L E351.2 06/26/2007 1:43 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported: 6/29/07 N O\ O O Laboratory Manager Page 14 of 16 575 Broad Hollow Road, MdWe NY 11747 (631)6943040. FAX (631)420-8336 NYSD0HID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706986-004C Type: Aqueous Attn To Original Origin: Client ID. MW -3S Collected 6/15/07 9:45:00 AM Received 6/15/07 1:53:00 PM Collected By: Client Copy : Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Hardness (As CaCO3) 280 10 mg/L E130.2 06/28/2007 1:51 PM Qualifiers: E --value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 6/29/07 M O Laboratory Manager Page 15 of 16 575 Broad Hollow Road, Mdvile W 11747 (631) 6943040.FAX- (631)42U436 WSDOHID#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0706986-004E Type: Aqueous Attn To Original Origin: Client ID. : MW -3S Collected 6/15107 9:45:00 AM Received 6/15/07 1:53:00 PM Collected By: Client Copy : Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Total Organic Carbon 14.6 1 mg/L SW9060 06/22/2007 2:42 AM QL 61lf18r5' E - Value above quantitation range - D - Results for Dilution D.F. = Dilution Factor Date Reported 6/29/07 Page 16 of 16 1-t D\ L/] O Laboratory Manager u2A "uss ,sc. 5. DUPLICATE SAMPLE RESULTS 5.1 METALS 5.2 WET CHEMISTRY Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER Solids for Sample: 0.0 U.S. EPA - CLP 5A SPIKE SAMPLE RECOVERY Contract: SAS No. EPA SAMPLE NO MW-5DS SDG No.: TSLO10 Level (low/med): LOW Concentration Units (ug/L or mg/kg dry weight): UG/L Analyte Control Limit %R Spiked Sample Result (SSR) C Sample Result (SR) C Spike Added (SA) %R Q M Cadmium 75-125 52.4600 0.1643 U 50.00 104.9 Pf Iron 75-125 1121.4100 93.3700 B 1000.00 102.8 P Lead 75-125 23.2659 2.3294 B 20.00 104.7 P -Manganese 12939.9900 1 11812.4900 500.00 225.5 P Comments: - FORM V (Part 1) - IN CD ILM04.1 H H2M LABS, INC. Date: 29 -Jun -07 QC SUMMARY REPORT SDIG: TSLO10 Spike Sample Recovery RPDRef %RPD Sample' ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL i MB -062207 IMB-062207 jAlkalinity, Total (As CaCO3) < 1 mg/L I_CS-062207 ILCS-062207 lAlkalinity, Total (As CaCC3) 25.8 mg/L I 25 < 1 1 103 180 1120 MB -062007 MB -062007 Alkalinity, Total (As CaCO3) < 1 I mg/L mg/L A13-061507, LCS-062007 LCS-062007 Alkalinity, Total (As CaCO3) 22.0 mg/L 25 < 1 88 80 120 -CS-061507 006952-004ams TV=25 MW-5DMS Alkalinity, Total (As CaCO3) 563 mg/L 250 1 312 101 75 125 )706952-064ADUP 0706952-004adup MW-5DDUP Alkalinity, Total (As CaCO3) 315 mg/L 20 312 1 1.1 20 I MB -062207 Bromide < 0.5 mg/L A13-061507, MB -061507 Biochemical Oxygen Demand < 2 mg/L mg/L 2.6 < 0.5 108 90 110 -CS-061507 LCS-061507 Biochemical Oxygen Demand 216 mg/L 1 200 1 <2 1 108 80 120 mg/L 1 0.7 88 75 125 )706952-064ADUP MW-5DDUP Biochemical Oxygen Demand < 2 mg/L <2 20 MB -062207 MB -062207 Bromide < 0.5 mg/L 1000 < 10 101 80 120 LCS-062207 LCS-062207 Bromide 2.7 mg/L 2.6 < 0.5 108 90 110 1000102 09 75 125 0706952-004AMS MW-5DMS Bromide 1.6 mg/L 1 0.7 88 75 125 102 2.9 20 0706952-004ADUP MW-50DUP Bromide 0.6 mgll 0.7 13.7 20 MB -062707 MS -062707 (Bromide < 0,5 mg/L li cc.nF97n7 LCS-062707 Bromide 2,5 mg/L 2.5 < 0.5 100 90 110 1 i MB -062607 LCS-062607 MB -062607 LCS-062607 Chemical Oxygen Demand Chemical Oxygen Demand < 10 1010 mglL mg/L 1000 < 10 101 80 120 0706952-004BMS MW-5DMS Chemical Oxygen Demand 1090 mg/L 1000102 09 75 125 0706952-004BDUP MW-5DDUP Chemical Oxygen Demand 99.1 mg/L 102 2.9 20 I TSLO10 S97 i QC SUMMARY REPORT SDG: i TSLO10 Spike Sample Recovery RPDRef %RPD Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL Sample ID: MB -062707 : MB -062707 Chloride < 2 mg/L mg/L 10 <2 95 90 110 LCS-062707 LCS-062707 Chloride 9.5 463 mglL 100 376 87 75 125 0706952-004AMS MW-5DMS Chloride 377 mg/L 376 0.32 20 0706952-004ADUP MW-5DDUP Chloride MB -062207 MB -062207 Chloride < 2 10.6 mI mglL 10 < 2 106 90 110.t_HEEB LCS-062207 LCS-062207 Chloride MB -062807 MB -062807 Hardness (As CaCO3) < 5 1020 mglL mg/L 1000 < 5 102480120 LCS-062807 LCS-062807 Hardness (As CaCO3) 2620 mg/L 2000 560 1125 0706952-00;4CMS MW -51D Hardness (As CaCO3) 560 0 20 0706952-00'4CDUP MW-5DMS Hardness As CaCO3 ( ) 560 mg/L MB -062507; MB -062507 Nitrate as N < 0.1 1.15 mglL mg/L 1.13 < 0.1 102 80 120 LCS-062507 LCS 062507 Nitrate as N 0.53 mg/L 0.5 < 0.1 106 75 125 0706952-004BMS MW-5DMS Nitrate as N —<—o —1 --m9—/L < 0.1 20 0706952-00;4BDUP MW-51DDUP Nitrate as N mb-21521 mb 062807 Nitrogen, Ammonia (As N) < 0.1 mg/L < 0.1 108 LCS-21521. LCS-062807 Nitrogen, Ammonia (As N) 1.08 mg/L mg/L 1 50 50.6 96 j75125 Nitrogen, Ammonia (As N) 98.5 0706952-00,4BMS MW 5DMS g 50,6P2.J20 n7naarq-nndRni Ip MW-5DDUP Nitrogen, Ammonia (As N) 49.6 mg/L 2 TSLO10 S98 QC SUMMARY REPORT SDG: TSLO10 i Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REG Limits Value %RPD UCL M84-21468 M94-062807 Nitrogen, Kjeldahl, Total < 0.1 mg/L LCS-062707 LCS-062707 Phenolics, Total Recoverable 27.6 M133 21468 MB3 062707 Nitrogen, Kjeldahl, Total < 0.1 mg/L 21.6 ug/L 20 < 5 108 75 125 MW-5DMS 0706952-004Bdup MW-5DDUP _ MB2 21468 MB2 062607 Nitrogen, Kjeldahl, Total < 0.1 mg/L MW-5DDUP Sulfate 53.9 mg/L 1 1 53.9 M81 21468 MBI 062607 Nitrogen, Kjeldahl, Total < 0.1 mg/L 20 MB 21468; MB 062607 Nitrogen, Kjeldahl, Total < 0.1 mg/L LCS4-21468 LCS4-062807 Nitrogen, Kjeldahl, Total 4.23 mg/L 4.1 < 0.1 103 80 120 LCS3 21468 LCS3 062707 Nitrogen, Kjeldahl, Total 4.76 mg/L 4.1 3.00 116 80 120 LCS2 21468 LC82 062607 Nitrogen, Kjeldahl, Total 4.62 mg/L 4.1 < 0.1 113 80 120 LCS1 21468 LCS1 06260 Nitrogen, Kjeldahl, Total 4.66 mg/L 4.1 < 0.1 114 80 120 LCS 21468 LCS 062607 Nitrogen, Kjeldahl, Total 4.70 mg/L 4.1 < 0.1 115 80 120 0706952-004bms MW-5DMS Nitrogen, Kjeldahl, Total 63.2 mg/L 4.1 58.4 118 75 125 0706952-004bdup MW-5DDUP Nitrogen, Kjeldahl, Total 58.8 mg/L 58.4. 0.75 20 MB -062707 MB -062707 Phenolics, Total Recoverable < 5 ug/L LCS-062707 LCS-062707 Phenolics, Total Recoverable 27.6 ug/L 30 < 5 92 80 120 9.3 0706952-004BMS MW-5DMS Phenolics, Total Recoverable 21.6 ug/L 20 < 5 108 75 125 MW-5DMS 0706952-004Bdup MW-5DDUP Phenolics, Total Recoverable < 5 ug/L < 5 20 K-062201 IMB-062207 ISulfate I <5 1 mg/L 1 11 I r..q-ns22ri7 LCS-062207 ISulfate 1 10 1 mg/L 1 10 1 < 5 1 100 1 90 11101 1 1 1 MB -062707 MB -062707 Sulfate <5 mg/L LCS-06270.7 LCS-062707 Sulfate 9.3 mg/L 10 < 5 93 190 110 mg/L 300 < 10 100 80 120 0706952-004AMS MW-5DMS Sulfate 153 mg/L 100 53.9 99 75 125 2310 mg/L 1200 1220 90 75 125 0706952-004ADUP MW-5DDUP Sulfate 53.9 mg/L 1 1 53.9 0 20 MB -061907 MB -061907 Total Dissolved Solids <10 I mg1L LCS-061907 LCS-061907 Total Dissolved Solids 300 mg/L 300 < 10 100 80 120 0706952-004AMS MW-5DMS Total Dissolved Solids 2310 mg/L 1200 1220 90 75 125 0706952-004ADUP MW-50DUP Total Dissolved Solids 1240 mg/L 1220 1.3 20 3 TSLO1O S99 QC SUMMARY REPORT SDG: TSLO10 i Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -062107 MB -062107 Total Organic Carbon < 1 mg/L LCS-062107 LCS-062107 Total Organic Carbon 28.6 m91L 25 < 1 114 80 120 0706952-004EMS MW-SDMS Total Organic Carbon 38.8 I mg/L 10 26,7 121 75 125 0706952-0,04EDUP MW-SDDUP ITotal Organic Carbon 27.5 mg/L 26.7 1 3.0 120 9 II TSL010 S100 U2M LABS. INC. 6. SPIKE SAMPLE RESULTS 6.1 METALS 6.2 WET CHEMISTRY 0 cn 0 ---- -- - -- ---- - -- Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER % Solids for Sample: 0.0 U.S. EPA - CLP 6 EPA SAMPLE NO DUPLICATES MW -5D Contract: ! SAS No.: SDG No.: TSLO10 Level (low/med): LOW % Solids for Duplicate: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L Analyte Control Limit Sample (S) C Duplicate (D) C RPD !Q M Cadmium 0.1643JU 0.1643 U P Calcium 99051.7100 104737.8600 5.6 P Iron 100.0000 93.3700 B 80.5100 B 14.8 P Lead 3.0000 2.3294 B 1.0807 U 200.0 P magnesium 58059.4300 61230.4800 5.3 P Man anese 11812.4900 12462.5500 5.9 P Potassium Sodium 121080.8900 245273.6300 I 126537.8100 256535.5200 4.4 4.5 1 P P I �-- - --- -, , --- - -- --- — FORM VI - IN - - - -- -- - - --- - - -- ILM04.1 N O Cn O O V) H H2M LABS, INC. Date: 29 -Juin -07 QC SUMMARY REPORT SDG: TSLO10 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID• Analvte Result Units Amount Result %REC Limits Value %RPD UCL MB -062207 MB -062207 Alkalinity, Total (As CaCO3)< 1 mg/L ILLS -062207 ILCS-062207 lAlkalinity, Total (As CaCO3) 1 25,8 1 mg/L 25 <1 1 103 180 11201 MB -062007 MB -062007 Alkalinity, Total (As CaCO3) <1 mg/L LCS-062007 LCS-062007 Alkalinity, Total (As CaCO3) 22.0 mg/L 25 <1 88 80 120 0706952-004ams TV=25 MW-5DMS Alkalinity, Total (As CaCO3) 563 mg/L 250 312 101 75 125 20 0706952-004adup MW-5DDUP Alkalinity, Total (As CaCO3) 315 mg/L 312 1.1 20 MB -061507 MB -061507 Biochemical Oxygen Demand < 2 mg/L —168180- LCS-061507 LCS-061507 Biochemical Oxygen Demand 216 mg/L 200 <2 120 0706952-004ADUP MW-5DDUP jBiochemical Oxygen Demand < 2 mg/L < 2 20 MB -062207 MB -062207 Bromide < 0.5 j mg/L LCS-062207 LCS-062207 Bromide 2.7 mg/L 2.5 < 0.5 108 90 110 1125 0706952-004AMS MW-5DMS Bromide 1.6 mg1L 1 0.7 88 75 0706952-004ADUP MW-5DDUP Bromide 0.6 mgtI 1 0.7 13.7 20 MB -062707 IMB-062707 IBromide -10.5 mg/L I I I I I I I I I It r.G.na9707 LCS-D62707 Bromide 12.5 mg/L 1 2.5 1 < 0.5 1 100 1 90 11101 1 1 1 MB -062607 MB -062607 Chemical Oxygen Demand <10 mg/L LCS-062607 LCS-062607 lChemical Oxygen Demand 1010 mg/L 1000 < 10 101 80 120 0706952-004BMS MW-5DMS (Chemical Oxygen Demand 1090 mg/L 1000 102 99 75 125 0706952-004BDUP MW-5DDUP Chemical Oxygen Demand 99.1 mg1L 102 2.9 20 I TSL:010 S103 I QC SUMMARY REPORT SDG: TSLO10 Spike Sample Recovery RPDRef %RPD Q.—i. Tn• (Tient Satnnle ID Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -062707 MB -062707 Chloride < 2 mg/L Hardness (As CaCO3) LCS-062707 LCS-062707 Chloride 9.5 mg/L 10 < 2 95 90 110 070695?.-0,04AMS MW-5DMS Chloride 463 mg/L 100 376 87 75 125 Nitrate as N 0706952-004ADUP MW-5DDUP Chloride 377 mg/L 376 0.32 20 MB -062207 LOS -062207 MB -062807 LCS-062807 0706952.004CMS 0706952-004CDUP MB -062507 LCS-062507 0706952-004BMS 0706952-004BDUP I mb-21521 LCS-21521 0706952-004BMS 0706952-004BDUP II TSLO 10 S104 Chloride LCS-062207 B-062807 :S-062807 Hardness (As CaCO3) Hardness (As CaCO3) W-5DMS Hardness (As CaCO3) W-51DMS Hardness (As CaCO3) B-062507 Nitrate as N ;S-062507 Nitrate as N W-51DMS Nitrate as N W-51DDUP Nitrate as N mg/L mglL 1000 <5 102 2620 b-062807 Nitrogen, Ammonia (As N) ,S-062807 Nitrogen, Ammonia (As N) W-5DMS W-51DDUP Nitrogen, Ammonia (As N) Nitrogen, Ammonia (As N) < 2 mg/L _ 10.6106 < 5 1020 mg/L mglL 1000 <5 102 2620 mg/L 2000 560 103 560 mg/L < 0.1 mg/L _T- —T —13 1,15 mglL < 0.1 102 0.53 mg/L 0.5 . < 0.1 106 < 0.1 mg/L < 0.1 mg/L 1.08 mg/L I< 0.1 108 98.5 49.6 mg/L mglL 50 50.6 96 560 1 0 < 0.1 50.6 1 2.0 Pa QC SUMMARY REPORT SDG: TSLO10 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB4-21468 MB4-062807 Nitrogen, Kjeldahl, Total < 0.1 mg/L LCS-062707 LCS-062707 Phenolics, Total Recoverable 27.6 ug/L 30 < 5 ' 92 80cc 0706952.004BMS MB3 21468 MB3 062707 Nitrogen, Kjeldahl, Total < 0.1 mg/L EIE] Phenolics, Total Recoverable < 5 ug/L 20 0706952-004ADUP MB2 21468 MB2 062607 Nitrogen, Kjeldahl, Total < 0.1 1 mg/L 20 MB1 21468 MB1 062607 Nitrogen, Kjeldahl, Total < 0.1 1 mg/L MB 21468 MB 062607 Nitrogen, Kjeldahl, Total < 0.1 mg/L LCS4-21468 LCS4-062807 Nitrogen, Kjeldahl, Total 4.23 mg/L 4.1 < 0.1 103 80 120 LCS3 21468 LCS3 062707 Nitrogen, Kjeldahl, Total 4.76. mg/L 4.1 3.00 116 80 120 LCS2 214,68 LC82 062607 Nitrogen, Kjeldahl, Total 4.62 mg/L 4.1 < 0.1 113 80 120 LCS1 21468 LC81 06260 Nitrogen, Kjeldahl, Total 4.66 mg/L 4.1 < 0.1 114 80 120 LCS 21468 LCS 062607 Nitrogen, Kjeldahl, Total 4.70 mg/L 4.1 :T. 115 80 120 0706952-004bms MW-5DMS Nitrogen, Kjeldahl, Total 63.2 mg/L 4.1 58.4 1 118 75 125 0706952-004bdup MW-500UP Nitrogen, Kjeldahl, Total 58.8 mg/L 158.4 0.75 20 MS -062707 MB -062707 Phenolics, Total Recoverable < 5 ug/L LCS-062707 LCS-062707 Phenolics, Total Recoverable 27.6 ug/L 30 < 5 ' 92 80cc 0706952.004BMS MW-5DMS Phenolics, Total Recoverable 21.6 ug/L 20 < 5 108 750706952.004Bdup MW-5Dh4S MW-5DDUP Phenolics, Total Recoverable < 5 ug/L 20 IMB-062207 SMB -062207 ISulfate <5 1 m911- 1 1 1 1I I 1� LCS-062207 LCS-062207 (Sulfate 10 mg/L 10 < 5 100 90 110 MB -062707 MB -062707 Sulfate < 5 mg/L LCS-062707 LCS-062707 Sulfate 9.3 mg/L 10 < 5 93 90 110 0706952-004AMS MW-5Dh4S Sulfate 153 mg/l. 100 53.9 99 75 125 A20 0706952-004ADUP MW-5DDUP Sulfate 53.9 mg/L 53.9 1.3 20 MS -061907 MB -061907 Total Dissolved Solids <10 I mg/L LCS-061907 LCS-061907 Total Dissolved Solids 300 mg/L 300 < 10 100 80 120 0706952-004AMS MW-5DMS Total Dissolved Solids 2310 mg/L 1200 1220 90 75 125 0706952-004ADUP MW-5DDUP Total Dissolved Solids 1240 mg/L 1220 1.3 20 TSLO 10 S105 QC SUMMARY REPORT SDG: TSLO10 Spike Sample Recovery RPDRef %RPD Sample IOD: Client Sample ID: Analvte Result Units Amount Result %REC Limits Value %RPD UCL MB -062107 MB -062107 Total Organic Carbon < 1 mg/L LCS-062107 LCS-062107 Total Organic Carbon 28.6 mg/L 25 < 1 114 180 120 1 0706952-004EMS MW-50MS Total Organic Carbon 38.8 mgrL 10 26.7 121 75 1251 1 0706952-004EDUP MW-50DUP Total Organic Carbon 27.5 mg/L 1 26.7 1 3.0 20 TSLO 10 S106 U2A iL US' INC* 7. BLANK SUMMARY DATA AND RESULTS 7.1 METALS 7.2 WET CHEMISTRY U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSLO10 Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L Analyte Initial Calib. Blank (ug/L) C Continuing Blank 1 C Calibration (ug/L) 2 C 3 C Prepa- ration Blank C M Cadmium 0.2 ul 0.3 B 0.2 U 0.2 U 0.1801 B I P Calcium -59.0B -33.0 B -61.0 B -51.0 B -66.600 B IP Iron -22.0 B -7.1 B -21.0 B -10.0 B -17.900 B P Lead -1.4 B -1.7 BI 1.1 U -1.7 B 1.081 U P Magnesium -58.0 B -31.0 B -59.0 B -57.0 B -52.700 B P Manganese 0.2 B 0.2 B 0.1 U 0.3 B 0.129 U P Potassium 38.3 B 36.9 B 45.2 B 56.5 B 31..700 B P Sodium 7.1 B 10.4 B 20.4 B 33.3 B 4.780 B P O '-- - FORM III - IN IL1,104.1 a H U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSLO10 Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L Analyte Cadmium Initial Calib. Blank (ug/L) C Continuing Calibration Blank (ug/L) 1 C 2 C 3 0.4 B Prepa- ration C Blank C M P Calcium -40.0 B P Iron -15.0 B P Lead 1.1 U P Magnesium -46.0 B P Manganese 0.3 B P Potassium 47.4 B P Sodium 15.9 Bi P FORM III - IN ILM04.1 �-_r H2M LABS, INC. Date: 29 -Jun -07 QC SUMMARY REPORT SIDG: TSLO10 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analvte Result Units Amount. Result %REC Limits Value %RPD UCL IMB-062207 IMB-062207 jAlkallnity, Total (As CaCO3) I< 1 mg/L I I I I I_ I I I I LCS-062207 LCS-062207 Alkalinity, Total (As CaCO3) 25.8 mg/L 25 < 1 103 80 120 MB -062007 MB -062007 Total (As CaCO3) < 1 mg/L LCS-062607 LCS-062007 _Alkalinity, lAlkalinity, Total (As CaCO3) 22.0 mg/L 25 <1 88 80 120 0706952-004ams TV=25 MW-5DMS Alkalinity, Total (As CaCO3) 563 mg/L 250 312 101 75 125 0706952-004adup MW-5DDUP lAlkalinity, Total (As CaCO3) 315 mg/L 312 1.1 20 MB -061507 MB -061507 Biochemical Oxygen Demand <2 mg/L LCS-062207 LCS-061507 LCS-061507 Biochemical Oxygen Demand 216 mg/L 200 < 2 108 180 120 MW-5DMS 0706952-004ADUP MW-5DDUP Biochemical Oxygen Demand < 2 mg/L < 2 20 MB -062207 MB -062207 Bromide < 0.5 mg/L LCS-062207 LCS-062207 Bromide 2.7 mg/L 2.5 < 0,5 108 90 110 0706952-004AMS MW-5DMS Bromide 1.6 mg/L 1 0.7 88 75 125 0706952-004ADUP MW-50DUP Bromide 0.6 mg/L 1 0.7 1.3.7 20 MB -062607 MB -062607 Chemical Oxygen Demand <10 mgiL LCS-062607 LCS-062607 Chemical Oxygen Demand 1010 mglL 1000 < 10 101 80 120 0706952-004BMS MW-5DMS Chemical Oxygen Demand 1090 mg/L 1000 102 99 75 125 1 0706952-004BDUP MW-5DDUP Chemical Oxygen Demand 99.1 mg/L 11102 2.9 20 TSLO10 S110 QC SUMMARY REPORT SDG: TSLO10 Sample ID: Client Sample ID: Analyte Result Units Spike Amount Sample Result %REC Recovery RPDRef Limits Value %RPD %RPD UCL MB -062707 MB -062707 IChloride <2 mg/L LCS-062707 LCS-062707 Chloride 9.5 mg/L 10 < 2 95 90 110 T376O.32 0706952-004AMS 0706952-004ADUP MW 5DMS MW-5DDUP Chloride Chloride 463 377 mg/L mg/L 100 376 87 75 125 20-- 07 MB -062207 ILCS-062207 Chloride IChlorlde <2 10.6 mg/L mg/L 1 10 1 < 2 1 106 190 11101 7 LCS-062207 MB -062807 LCS-062807 MB -062807 LCS-062807 Hardness (As CaCO3) Hardness (As CaCO3) < 5 1020 mg/L mg/L 1000 < 5 102 80 120 d2O 0706952-004CMS n'7naoa0_nndnni Ip MW-55MS MW-5DMS Hardness (As CaCO3) Hardness (As CaCO3) 2620 560 mglL mg/L 2000 560 103 75 125 560 0 mb•21521 mb-062807 Nitrogen, Ammonia (As N) < 0.1 mglL LCS-215211 LCS-062807 Nitrogen, Ammonia (As N) 1.08 mg/L 1 < 0.1 108 80 120 0706952-004SMS MW -5 DMS Nitrogen, Ammonia (As N) 98.5 mg/L 50 50.6 96 75 11251 0706952-004BDUP MW-5DDUP Nitrogen, Ammonia (As N) 49.6 mg/L 50,6 2.0 20 2 TSLO10 S111 QC SUMMARY REPORT SDG: TSL010 Spike Sample Recovery RPDRef %RPD Sampie ID: CIient Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB4-21468 M64-062807 Nitrogen, Kjeldahl, Total < 0.1 mglL LCS-062707 LCS-062707 lPhenolics, Total Recoverable 27.6 ug/L 30 < 5 92 80 120 MB3 21468 MB3 062707 Nitrogen, Kjeldahl, Total < 0.1 mg/L ug/L 20 < 5 108 75 125 0706952-004Bdup MW-5DDUP 110henolics, Total Recoverable < 5 M62 21468, MB2 062607 Nitrogen, Kjeldahl, Total < 0.1 mg/L MBI 21468 MBI 062607 Nitrogen, Kjeldahl, Total < 0.1 mg/L MB 21468 MB 062607 Nitrogen, Kjeldahl, Total < 0.1 mg/L LC84-214,68 LCS4-062807 Nitrogen, Kjeldahl, Total 4.23 mg/L 4.1 < 0.1 103 80 120 j LCS3 21468 LCS3 062707 Nitrogen, Kjeldahl, Total 4.76 I mg/L 4.1 3.00 116 80 120 LCS2 21468 LCS2 062607 Nitrogen, Kjeldahl, Total 4.62 mg/L 4.1 < 0.1 113 80 120 LCS1 21468 LCS1 06260 Nitrogen, Kjeldahl, Total 4,66 mg/l. 4.1 < 0.1 114 80 120 LCS 21468 LCS 062607 Nitrogen, Kjeldahl, Total 4.70 mg/L 4.1 < 0.1 115 80 120 0706952-004bms MW-5DMS Nitrogen, Kjeldahl, Total 63.2 mg/L 4.1 58.4 1 118 75 125 0706952-004bdup MW-5DDUP Nitrogen, Kjeldahl, Total 58.8 mg/L I I58.4 0.75 20 MB -062707 MB -062707 Phenolics, Total Recoverable < 5 ug/L LCS-062707 LCS-062707 lPhenolics, Total Recoverable 27.6 ug/L 30 < 5 92 80 120 0706952-004BMS MW-5DMS IPhenolics. Total Recoverable 21.6 ug/L 20 < 5 108 75 125 0706952-004Bdup MW-5DDUP 110henolics, Total Recoverable < 5 ug/L < 5 20 SMB -062207 SMB -062207 ISulfate 1 <5 1 mg/L 1 LCS-062207 ILCS-062207 ISulfate 1 10 1 mg/L 1 10 1 <5 1 100 190 11101 -- MB -062707 MB -062707 Sulfate < 5 mg/L LCS-062707 LCS-062707 Sulfate 9,3 mg/L 10 < 5 93 90 110 0706952-004AMS MW-5DMS Sulfate 153 mg/L 100 53.9 99 75 125 0706952-004ADUP MW-5DDUP Sulfate 53.9 mg/L 1 1 53.9 1 0 I20 MB -061907 MB -061907 Total Dissolved Solids < 10 1 mg/L LCS-061907 LCS-061907 Total Dissolved Solids 300 mg/L 300 < 10 100 80 120 0706952-004AMS MW-5DMS Total Dissolved Solids 2310 mg/L 1200 1220 90 175 1125 0706952-004ADUP MW-5DDUP Total Dissolved Solids 1240 mg/L1 111220 1 1.3 120 3 TSLO10 S112 QC SUMMARY REPORT BDG: TSLO1O Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -062107 MB -062107 ITotal Organic Carbon < 1 mg/L LCS-0621;07 LCS-062107 Total Organic Carbon 28.6 mg/L 25 < 1 114 80 120 0706952-004EMS MW-SDMS Total Organic Carbon 38.8 mgfL 10 26.7 121 75 11251 0706952-004EDUP MW-50DUP Total Organic Carbon 27.5 mglL 26.7 3.0 20� TSLO10 5113