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Home My WebLink AboutWet Chemistry Data Package 12/2007Analytical Data Package For TOWN OF SOUTHOLD PART 360 ROUTINE SDG NO: TSLO12 Water Samples Received: 12/5/07 & 12/6/07 WET CHEMISTRY DATA PACKAGE DECEMBER 2007 V I *t I -AUS, Environmental Testing Laboratories 575 Broad Hollow Road, Melville, N.Y. 11747 WET CHEMISTRY TABLE OF CONTENTS 1. SAMPLE REPORTS 11. Q.C. SUMMARY III. RAW DATA SAMPLE REPORTS U2A "US. INCo 575 Broad Hollow Road, Meese NY 11747 LABORATORY RESULTS (631)6M-3040. FAX(631)420-8436 NYSDOHID#10478 Sample Information... Town of Southold Landfill Lab No. : 0713771-001 Type : Groundwater Qualifiers: E -Value above quantitalion range -- D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 1 of 9 Laboratory Manager Origin: Attn To Original Client ID. : MWAD Collected :12/5/2007 2:00:00 PM Received :12/5/2007 3:40:00 PM Collected By VG Copies To :Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 33.2 2 mg/L E310.1 12/13/2007 9:46 AM Chloride 19.0 2 mg/L E300.0 12/19/2007 4:11 PM Sulfate 52-1 2 mg/L E300.0 12/19/2007 4:11 PM Bromide < 0.5 1 mg/L E300.0 12/14/2007 4:37 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 12/06/2007 1:20 PM Chemical Oxygen Demand <10 1 mg/L E410.4 12/20/2007 1:47 PM Hardness (As CaCO3) 105 5 mg/L E130.2 12/11/2007 2:34 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 12/28/2007 11:29 AM Nitrate as N 2.28 5 mg/L E353.2 12/17/2007 12:05 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2007 11:20 AM Total Dissolved Solids 176 1 mg/L E160.1 12/10/2007 3:11 PM Nitrogen, Kjeldahl, Total 0.19 1 mg/L E351.2 12/20/2007 10:18 AM Total Organic Carbon 2.3 1 mg/L SW9060 12/07/2007 8:27 PM Qualifiers: E -Value above quantitalion range -- D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 1 of 9 Laboratory Manager U2A® "US.. INC* 575 Broad Hdlow Road, Mdville W 11747 (631)694-3040. FAX (631)420$436 WSDOH ID# 10478 Town of Southold Landfill Attn To : Original Collected :12/5/2007 1:30:00 PM Received :12/5/2007 3:40:00 PM Collected By VG Copies To :Original CC LABORATORY RESULTS I Lab No. : 0713771-002 Client ID. : MWAS Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 9.3 1 mg/L E310.1 12/13/2007 9:54 AM Chloride 59.2 2 mg/L E300.0 12/19/2007 4:25 PM Sulfate 22.6 2 mg/L E300.0 12/19/2007 4:25 PM Bromide < 0.5 1 mg/L E300.0 12/14/2007 4:51 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 12/06/20071:25 PM Chemical Oxygen Demand <10 1 mg/L E410.4 12/20/20071:48 PM Hardness (As CaCO3) 52.0 4 mg/L El 30.2 12/11/2007 2:36 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 12/28/2007 11:30 AM Nitrate as N 3.24 5 mg/L E353.2 12/17/2007 12:06 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2007 11:30 AM Total Dissolved Solids 179 1 mg/L E160.1 12/10/2007 3:13 PM Nitrogen, Kjeldahl, Total 0.18 1 mg/L E351.2 12/20/2007 10:19 AM Total Organic Carbon < 1.0 1 mg/L SW9060 12/07/2007 8:58 PM Qualifiers: E -Value above quantitalion range D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 2 of 9 Laboratory Manager U2/4 "US. INC® 575 Broad Hollow Road, MaMille NY 11747 (631)694,3040. FAX (631)4205436 NYSDOH ID# 10478 Town of Southold Landfill Attn To Original Collected :12/5/2007 12:00:00 PM Received :12/5/2007 3:40:00 PM Collected By VG Copies To :Original CC LABORATORY RESULTS Lab No.: 0713771-003 Client ID.: MW -413 Sample Information... Type: Groundwater Origin: Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 766 20 mg/L E310.1 12/13/2007 10:02 AM Chloride 339 10 mg/L E300.0 12/19/2007 4:38 PM Sulfate 87.5 10 mg/L E300.0 12/19/2007 4:38 PM Bromide 2.5 1 mg/L E300.0 12/14/2007 5:05 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 12/06/2007 1:30 PM Chemical Oxygen Demand 53.5 1 mg/L E410.4 12/20/2007 1:49 PM Hardness (As CaCO3) 760 20 mg/L E130.2 12/11/2007 2:38 PM Nitrogen, Ammonia (As N) 25.0 20 mg/L E350.1 12/28/2007 11:31 AM Nitrate as N < 0.10 1 mg/L E353.2 12/17/2007 12:07 PM Phenolics, Total Recoverable < 5.0 1 Ng/L E420.1 121201200711:40 AM Total Dissolved Solids 1280 4 mg/L E160.1 12/10/20013:15 PM Nitrogen, Kjeldahl, Total 37.9 20 mg/L E351.2 12/20/200711:49 AM Total Organic Carbon 27.4 1 mg/L SW9060 12/07/2007 9:30 PM Qualifiers: E - Value above quanlitation range D - Results for Dilution D.F. = Dilution Factor Date Reported: Page 3 of 9 alwl Laboratory Manager 575 Broad Hdbw Road, Melville NY 11747 (631)694-3040.FAX(631)4205436 WSDOHID#10478 Town of Southold Landfill I Attn To Original Collected :12/5/2007 11:30:00 AM Received :12/5/2007 3:40:00 PM Collected By VG Copies To :Original CC LABORATORY RESULTS Lab No. : 0713771-004 Client ID.: MW -4S Sample Information... Type: Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 203 10 mg/L E310.1 12/13/2007 10:10 AM Chloride 26.0 2 mg/L E300.0 12/19/2007 4:52 PM Sulfate 50.3 2 mg/L E300.0 12/19/2007 4:52 PM Bromide < 0.5 1 mg/L E300.0 12/14/2007 5:18 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 12/06/2007 1:35 PM Chemical Oxygen Demand 13.0 1 mg/L E410.4 12/20/2007 1:50 PM Hardness (As CaCO3) 240 20 mg/L E130.2 12/11/2007 2:40 PM Nitrogen, Ammonia (As N) 0.31 1 mg/L E350.1 12/28/2007 11:32 AM Nitrate as N 9.34 10 mg/L E353.2 12/17/2007 12:08 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2007 11:50 AM Total Dissolved Solids 401 1 mg/L E160.1 12/10/2007 3:17 PM Nitrogen, Kjeldahl, Total 3.78 20 mg/L E351.2 12/20/200710:20 AM Total Organic Carbon 13.2 1 mg/L SW9060 12/07/200710:01 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 4 of 9 Laboratory Manager UW "U ss ss NCO 575 Broad Hollow Road, Mdvbe NY 11747 (631)6943040.FAX (631)42H436 NYSDOHID#10478 Town of Southold Landfill Attn To Original Collected :12/5/2007 1:00:00 PM Received :12/5/20073:40:00 PM Collected By VG Copies To :Original CC LABORATORY RESULTS Lab No. : 0713771-005 Client ID.: MW -5D Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 715 20 mg/L E310.1 12/13/2007 10:18 AM Chloride 340 10 mg/L E300.0 12/19/2007 5:19 PM Sulfate 46.4 5 mg/L E300.0 12/19/2007 5:05 PM Bromide 1.4 1 mg/L E300.0 12/14/2007 5:32 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 12/06/20071:40 PM Chemical Oxygen Demand 71.3 1 mg/L E410.4 12/20/20071:51 PM Hardness (As CaCO3) 480 20 mg/L E130.2 12/11/2007 2:42 PM Nitrogen, Ammonia (As N) 39.7 50 mg/L E350.1 12/28/2007 11:33 AM Nitrate as N < 0.10 1 mg/L E353.2 12/17/2007 12:09 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2007 12:00 PM Total Dissolved Solids 1090 4 mg/L E160.1 12/10/2007 3:19 PM Nitrogen, Kjeldahl, Total 62.9 50 mg/L E351.2 12/20/200710:21 AM Total Organic Carbon 25.5 1 mg/L SW9060 12/07/200710:33 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported :. Page 5 of 9 Laboratory Manager 575 Broad Hdkw Road, Melville NY 11747 LABORATORY RESULTS (631)6943040.FAX (631)42OZ435 WSDOHID#10478 Landfill Lab No. Sample Information... Town of Southold Land 0713771-006 Type : Groundwater Attn To Original Origin: Client ID. : MW -5S Collected :12/5/2007 12:30:00 PM Received :12/5/2007 3:40:00 PM Collected By VG Copies To :Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 38.5 1 mg/L E310.1 12/13/2007 10:26 AM Chloride 15.6 1 mg/L E300.0 12/19/2007 5:32 PM Sulfate 37.0 1 mg/L E300.0 12/19/2007 5:32 PM Bromide < 0.5 1 mg/L E300.0 12/14/2007 5:45 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 12/06/2007 1:45 PM Chemical Oxygen Demand 13.0 1 mg/L E410.4 12/20/2007 1:52 PM Hardness (As CaCO3) 96.0 4 mg/L E130.2 12/11/2007 2:44 PM Nitrogen, Ammonia (As N) 0.18 1 mg/L E350.1 12/28/2007 11:35 AM Nitrate as N 1.76 5 mg/L E353.2 12/17/2007 12:11 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2007 12:10 PM Total Dissolved Solids 147 1 mg/L E160.1 12/10/2007 3:21 PM Nitrogen, Kjeldahl, Total 0.40 1 mg/L E351.2 12/20/2007 10:22 AM Total Organic Carbon 3.8 1 mg/L SW9060 12/07/2007 11:04 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported Page 6 of 9 00 awl, A . O 1--i Laboratory Manager 575 Broad Hollow Road, Melville NY 11747 LABORATORY RESULTS (631)6943040.FAX:(631)420$436 WSDOHID#10478 Town of Southold Landfill Lab No. : 0713771-007 I Attn To Original Client ID.: MW -8D Collected :12/5/2007 11:00:00 AM Received :12/5/2007 3:40:00 PM Collected By VG Copies To :Original CC Sample Information... Type: Groundwater Origin: Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 438 20 mg/L E310.1 12/13/2007 10:34 AM Chloride 126 5 mg/L E300.0 12/19/2007 5:46 PM Sulfate 81.8 5 mg/L E300.0 12/19/2007 5:46 PM Bromide 0.9 1 mg/L E300.0 12/14/2007 5:59 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 12/06/2007 1:50 PM Chemical Oxygen Demand 58.6 1 mg/L E410.4 12/20/2007 1:53 PM Hardness (As CaCO3) 380 20 mg/L E130.2 12/11/2007 2:46 PM Nitrogen, Ammonia (As N) 30.0 50 mg/L E350.1 12/28/2007 11:36 AM Nitrate as N < 0.10 1 mg/L E353.2 12/17/2007 12:12 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2007 12:20 PM Total Dissolved Solids 678 2 mg/L E160.1 12/10/2007 3:23 PM Nitrogen, Kjeldahl, Total 43.0 50 mg/L E351.2 12/20/2007 10:22 AM Total Organic Carbon 18.7 1 mg/L SW9060 12/07/2007 11:36 PM N Qualifiers: E -Value above quantilalion range l 1 0 Wry' _ D - Results for Dilution 1 D.F. = Dilution Factor DO Date Reported : Laboratory Manager Page 7 of 9 575 Broad Hdlow Road, Mile NY 11747 LABORATORY RESULTS (631)6943040. FAX (631)42M436 NYSDOHID#10478 Sample Information... Town of Southold Landfill Lab No. : 0713771-008 Type; Groundwater Attn To Original Origin: Client ID. : MW -8S Collected :12/5/2007 10:30:00 AM Received :12/5/2007 3:40:00 PM Collected By VG Copies To :Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 253 20 mg/L E310.1 12/13/2007 10:58 AM Chloride 43.6 5 mg/L E300.0 12/19/2007 6:54 PM Sulfate 66.8 5 mg/L E300.0 12/19/2007 6:54 PM Bromide < 0.5 1 mg/L E300.0 12/14/2007 6:39 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 12/06/2007 2:00 PM Chemical Oxygen Demand 38.3 1 mg/L E410.4 12/20/2007 1:56 PM Hardness (As CaCO3) 176 4 mg/L E1302 12/11/2007 2:52 PM Nitrogen, Ammonia (As N) 25.0 10 mg/L E350-1 12/28/2007 11:39 AM Nitrate as N < 0.10 1 mg/L E353-2 12/17/2007 12:15 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2007 12:50 PM Total Dissolved Solids 378 2 mg/L E160.1 12/10/2007 3:29 PM Nitrogen, Kjeldahl, Total 40.2 20 mg/L E351.2 12/20/2007 10:24 AM Total Organic Carbon 11.1 1 mg/L SW9060 12/08/2007 1:11 AM Qualifiers: E -Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported Laboratory Manager : ' Page 8 of 9 575 Broad Hollow Road, Me141e NY 11747 LABORATORY RESULTS (631) 6943040. FAX(631)4205436 NYSDOHID#10478 Town of Southold Landfill Lab No. : 0713771-009 Attn To : Original Collected :12/5/2007 12:00:00 PM Received :1215/2007 3:40:00 PM Collected By VG Copies To :Original CC Parameter(s) Alkalinity, Total (As CaCO3) Chloride Sulfate Bromide Biochemical Oxygen Demand Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID.: FS 120507 Sample Information... Type; Field Blank Origin: Results Qualifier D.F.. Units Method Number Analyzed < 1.0 1 mg/L E310.1 12/13/200711:22 AM < 2.0 1 mg/L E300.0 12/19/2007 7:07 PM < 5.0 1 mg/L E300.0 12/19/2007 7:07 PM < 0.5 1 mg/L E300.0 12/14/2007 7:20 PM < 2 1 mg/L E405.1 12/06/2007 2:05 PM <10 1 mg/L E410.4 12/20/2007 1:57 PM < 5.0 1 mg/L El 30.2 12/11/2007 2:54 PM < 0.10 1 mg/L E350.1 12/28/2007 11:58 AM < 0.10 1 mg/L E353.2 12/17/2007 12:19 PM < 5.0 1 pg/L E420.1 12/20/2007 1:00 PM <10 1 mg/L E160.1 12/10/2007 3:31 PM < 0.10 1 mg/L E351.2 12/20/2007 10:26 AM < 1.0 1 mg/L SW9060 12/08/2007 2:45 AM Qualifiers: E - Value above quantitation range - , D - Results for Dilution D.F. = Dilution Factor Date Reported Page 9 of 9 Qnv►,, Laboratory Manager U2A "U%9 INNS 575 Broad Hollow Road, Meese W 11747 (631)6943040. FAY: (631)42"436 WSDOHID#10478 Town of Southold Landfill Attn To : Original Collected :12/6/2007 9:30:00 AM Received :12/6/2007 1:16:00 PM Collected By VG Copies To :Original CC LABORATORY RESULTS Lab No. : 0713$17-001 Client ID.: MW -313 Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 839 20 mg/L E310.1 12/13/2007 12:34 PM Chloride 233 10 mg/L E300.0 12/19/2007 7:34 PM Sulfate 34.3 1 mg/L E300.0 12/19/2007 7:21 PM Bromide 1.1 1 mg/L E300.0 12/14/2007 7:33 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 12/07/2007 10:00 AM Chemical Oxygen Demand 124 1 mg/L E410.4 12/20/2007 1:58 PM Hardness (As CaCO3) 460 20 mg/L E130.2 12/11/2007 2:56 PM Nitrogen, Ammonia (As N) 81.0 50 mg/L E350.1 12/28/2007 11:47 AM Nitrate as N < 0.10 1 mg/L E353.2 12/17/2007 12:20 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2007 1:10 PM Total Dissolved Solids 928 4 mg/L E160.1 12/10/2007 3:33 PM Nitrogen, Kjeldahl, Total 122 100 mg/L E351.2 12/20/200710:27 AM Total Organic Carbon 30.8 1 mg/L SW9060 12/08/2007 3:17 AM N ,—t j Qualifiers: E -Value above quantitation range D - Results for Dilution 4V •"• _ D.F. = Dilution Factor Laboratory Manager Date Reported : Page 1 of 5 U2A "US, INCe 575 Broad Hdlow Road, Melville W 11747 (631)6943040. FAX (631)42M436 WSDOH ID# 10478 Town of Southold Landfill Attn To Original Collected :12/612007 9:00:00 AM Received :12/6/2007 1:16:00 PM Collected By VG Copies To :Original CC LABORATORY RESULTS Lab.No. : 0713817-002 Client ID.: MW -3S Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 313 20 mg/L E310.1 12/13/2007 12:58 PM Chloride 74.9 2 mg/L E300.0 12/19/2007 7:48 PM Sulfate 37.9 2 mg/L E300.0 12/19/2007 7:48 PM Bromide < 0.5 1 mg/L E300.0 12/14/2007 7:47 PM Biochemical Oxygen Demand 3 1 mg/L E405.1 12/07/2007 10:05 AM Chemical Oxygen Demand 66.2 1 mg/L E410.4 12/20/2007 1:59 PM Hardness (As CaCO3) 260 20 mg/L E130.2 12/11/2007 2:58 PM Nitrogen, Ammonia (As N) 17.0 10 mg/L E350.1 12/28/2007 11:48 AM Nitrate as N < 0.10 1 mg/L E353.2 12/171200712:22 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2007 1:20 PM Total Dissolved Solids 452 2 mg/L E160.1 12/10/2007 3:35 PM Nitrogen, Kjeldahl, Total 26.0 20 mg/L E351.2 12/20/2007 10:28 AM Total Organic Carbon 1.1 1 mg/L SW9060 12/08/2007 3:48 AM Qualifiers: E - Value above quantilalion range D - Results for Dilution D.F. = Dilution Factor Date Reported Page 2 of 5 ao Laboratory Manager U2M "FS., INC® 575BmadHdlow Road, M4j3e NY 11747 LABORATORY RESULTS (631)6943040.FAX(631)42U436 NYSDOHID#10478 Sample Information... Town of Southold Landfill Lab No. : 0713817-003 Type : Groundwater Attn To Original Origin: Client ID.: MW -6D Collected :12/6/2007 10:30:00 AM Received :121612007 1:16:00 PM Collected By VG Copies To :Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 22.8 1 mg/L E310.1 12/13/2007 1:06 PM Chloride 34.3 5 mg/L E300.0 12/19/2007 8:01 PM Sulfate 101 5 mg/L E300.0 12/19/2007 8:01 PM Bromide < 0.5 1 mg/L E300.0 12/14/2007 8:00 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 12/07/2007 10:10 AM Chemical Oxygen Demand <10 1 mg/L E410.4 12/20/2007 2:00 PM Hardness (As CaCO3) 184 4 mg/L E130.2 12/11/2007 3:00 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 12/28/2007 12:00 PM Nitrate as N 9.78 10 mg/L E353.2 12/17/2007 12:23 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2007 1:30 PM Total Dissolved Solids 319 1 mg/L E160.1 12/10/2007 3:37 PM Nitrogen, Kjeldahl, Total 0.14 1 mg/L E351.2 12/20/200710:28 AM Total Organic Carbon 12.2 1 mg/L SW9060 12/08/2007 4:20 AM Qualifiers: E - Value above quantilation range D - Results for Dilution D.F. = Dilution Factor Date Reported . Page 3 of 5 Laboratory Manager 575 Broad Hollow Road, MdA;e NY 11747 LABORATORY RESULTS (631)694,3040. FAX(631)4205436 NYSDOHID#10478 Sample Information... Town of Southold Landfill Lab No. : 0713817-004 Type: Groundwater Attn To Original Origin: Client ID.: MW -6S Collected :12/6/2007 10:00:00 AM Received :12/6/2007 1:16:00 PM Collected By VG Copies To :Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 58.2 4 mg/L E310.1 12/13/2007 1:14 PM Chloride 5.6 1 mg/L E300.0 12/19/2007 8:15 PM Sulfate 7.1 1 mg/L E300.0 12/19/2007 8:15 PM Bromide < 0.5 1 mg/L E300.0 12/14/2007 8:14 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 12/07/2007 10:15 AM Chemical Oxygen Demand 23.1 1 mg/L E410.4 12/20/2007 2:01 PM Hardness (As CaCO3) 72.0 4 mg/L El 30.2 12/11/2007 3:02 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 12/28/2007 11:51 AM Nitrate as N 1.20 5 mg/L E353.2 12/17/200712:24 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2007 1:40 PM Total Dissolved Solids 117 1 mg/L E160.1 12/10/2007 3:39 PM Nitrogen, Kjeldahl, Total 0.63 1 mg/L E351.2 12/20/200710:29 AM Total Organic Carbon 7.2 1 mg/L SW9060 12/08/2007 4:51 AM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : Page 4 of 5 Laboratory Manager 575 BroadHdlaw Road, MdvL- NY 11747 LABORATORY RESULTS (631)6943040.FAX-(631)42M436 NYSDOH ID# 10478 Sample Information... Town of Southold Landfill Lab No. 0713817-0055' Type : Groundwater Origin: Attn To Original Client ID.: MB -BD Collected :12/6/2007 11:00:00 AM Received :12/6/2007 1:16:00 PM Collected By VG Copies To :Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 23.4 1 mg/L E310.1 12/13/2007 1:22 PM Chloride 34.0 5 mg/L E300.0 12/19/2007 8:28 PM Sulfate 99.4 5 mg/L E300.0 12/19/2007 8:28 PM Bromide < 0.5 1 mg/L E300.0 12/14/2007 8:27 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 12/07/2007 10:20 AM Chemical Oxygen Demand <10 1 mg/L E410.4 12/20/2007 2:02 PM Hardness (As CaCO3) 176 4 mg/L E130.2 12/11/2007 3:04 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 12/28/2007 11:52 AM Nitrate as N 9.21 10 mg/L E353.2 12/17/2007 12:25 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2007 1:50 PM Total Dissolved Solids 309 1 mg/L E160.1 12/10/2007 3:41 PM Nitrogen, Kjeldahl, Total 0.14 1 mg/L E351.2 12/20/2007 10:30 AM Total Organic Carbon _ _ 1.5 1 mg/L SW9060 12/08/2007 5:22 AM E I i. i Qualifiers: E - Value above quantitation range D -Results for Dilution i D.F. = Dilution Factor L/) Laboratory Manager Date Reported i Page 5 of 5 i i 11. Q.C. SUMMARY H2M LABS, INC. Date: 31 -Dec -07 - QC SUMMARY REPORT SDG: TSL012 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample I.D: Analvte Result Units Amount Result %REC Limits Value %RPD UCL mb-121307 mb-121307 Alkalinity, Total (As CaCO3) < 1 mg/L Ics-121307 Ics-121307 Alkalinity, Total (As CaCO3) 21.7 mg/L 25 < 1 87 80 120 0713771-007aMS MW-8DMS Alkalinity, Total (As CaCO3) 919 mglL 500 438 96 75 125 0713771-007aDUP MW-8DDUP Alkalinity, Total (As CaCO3) 445 mg/L 1438 1.6 20 IMB-120707 IMB-120707i jBiochemical Oxygen Demand <2 mg/L LCS-120707 LCS-120707 Biochemical Oxvaen Demand 174 mg/L 1 200 1 < 2 1 87 1 80 1120 1 1 11 9B-120607 MB -120607 Biochemical Oxygen Demand < 2 mglL CS -120607 LCS-120607 Biochemical Oxygen Demand 184 mg/L 200 < 2 92 80 120 713771-007ADUP MW-8DDUP Biochemical Oxygen Demand <2 mg/L <2 20 MB -121407 MB -121407 Bromide < 0.5 mg/L LCS-121407 LCS-121407 Bromide 2.4 mg/L 2.5 < 0.5 96 90 110 0713771-007AMS MW-8DMS Bromide 1.9 mg/L 1 0.9 102 75 125 0713771-007ADUP MW-8DDUP Bromide 0.9 mg/L 0.9 0 20 MB -122007 MB -122007 Chemical Oxygen Demand <10 mg/L LCS122007 LCS122007 Chemical Oxygen Demand 973 mg/L 1000 <10 97 80 120 0713771-007BMS MW-8DMS Chemical Oxygen Demand 1050 mg/L 1000 58,6 99 75 125 0713771-007BDUP MW-8DDUP Chemical Oxygen Demand 56.1 mg/L 58.6 4.4 20 MB -121907 MB -121907 Chloride < 2 mg/L LCS-121907 LCS-121907 Chloride 9.2 mg/L 10 < 2 92 90 110 0713771-007Ams MW-8DMS Chloride 171 mg/L 50 126 89 75 125 0713771-007Adup MW-8DDUP Chloride 126 mg/L 126 0 20 1 TSLO12 W18 QC SUMMARY REPORT SDG: TSL012 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -121107 MB -121107 Hardness (As CaCO3) < 5 mg/L LCS-121107 LCS-121107 Hardness (As CaCO3) 1020 mg/l. 1000 < 5 102 80 120 0713771-007Cms MW-8DMS Hardness (As CaCO3) 2440 mg/L 2000 380 103 75 125 0713771-007Cdup MW-8DDUP Hardness (As CaCO3) 420 mg/L 380 10 20 MB -121707 MB -121707 Nitrate as N < 0,1 mg/L LCS-121707 LCS-121707 Nitrate as N 1.14 mg/L 1.13 < 0.1 101 80 120 0713771-007BMS_ MW-81DMS Nitrate as N 0.52 mg/L 0.5 < 0.1 104 75 125 0713771-007BDUP MW-8DDUP Nitrate as N < 0.1 mg/L < 0.1 20 mb-24238 mb-24238 Nitrogen, Ammonia (As N) < 0.1 mg/L LCS-24238 LCS-24238 Nitrogen, Ammonia (As N) 1.12 mg/L 1 < 0.1 112 80 120 0713771-007BMS MW-8DMS Nitrogen, Ammonia (As N) 35.8 mg/L 5 30.0 117 75 125 0713771-007BDUP MW-8DDUP Nitrogen, Ammonia (As N) 30.0 mg/L 30.0 0 20 MBl-24152 MBI -24152 Nitrogen, Kjeldahl, Total < 0.1 mg/L MB -24152 MB -24152 Nitrogen, Kjeldahl, Total < 0.1 mg/L LCS1-24152 LCS1-24152 Nitrogen, Kjeldahl, Total 3.91 mg/L 4 <0.1 98 80 120 LCS-24152 LCS-24152 Nitrogen, Kjeldahl, Total 3.87 mg/L 4 < 0.1 97 80 120 0713771-007BMS MW-81DMS Nitrogen, Kjeldahl, Total 46.8 mg/L 4 43.0 95 75 125 0713771-007BDUP MW-8DDUP Nitrogen, Kjeldahl, Total 43.0 mg/L 43.0 0 20 MB -24205 MB -24205 Phenolics, Total Recoverable < 5 ug/L LCS-24205 LCS-24205 Phenolics, Total Recoverable 29.2 uglL 30 < 5 97 80 120 0713771-007BMS MW-81DMS Phenolics, Total Recoverable 19.2 ug/L 20 < 5 96 75 125 0713771-007Bdup MW-8DDUP Phenolics, Total Recoverable < 5 ug/L < 5 20 TSLO12 W19 QC SUMMARY REPORT SDG: TSLO12 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value °/ RPD UCL MB -121907 MB -121907 Sulfate < 5 mglL LCS-121907 LCS-121907 Sulfate 9.0 mg/L 10 < 5 90 90 110 0713771-007Ams MW-8DMS Sulfate 129 mg/L 50 81.8 94 75 125 0713771-007Adup MW-8DDUP Sulfate 81.9 mg/L 81.8 0.12 20 MB -121007 MB -121007 Total Dissolved Solids <10 mg/L LCS-121007 LCS-121007 Total Dissolved Solids 292 mg/L 300 <10 97 80 120 0713771-007AMS MW=801VIS Total Dissolved Solids 1270 mg/L 600 678 99 75 125 0713771-007ADUP MW-8DDUP Total Dissolved Solids 674 mg/L 678 0.59 20 MB -120707 MB -120707 Total Organic Carbon < 1 mglL LCS-120707 LCS-120707 Total Organic Carbon 27.6 mg/L 25 < 1 110 80 120 0713771-007EMS MW-8DMS Total Organic Carbon 28.5 mglL 10 18.7 98 75 125 0713771-007EDUP MW-8DDUP Total Organic Carbon 19.0 mg/L 18.7 1.1 20 TSLO12 W20 u2AA U9 INC® III. RAW DATA CODES FOR MANUAL CORRECTIONS T: Transcription error. CE: Calculation error CC: Changed per client request SC: Sample cancelled LB: Wrong spot in logbook- The ogbookThe following codes are specific to chromatography GC I IC: MS (Match standard): The integration of the continuous calibration or the sample was different from that used for the initial calibration, e.g. more or less of the tail was - —inc iude3- BL (Baseline): Incorrect integration due to changing baseline (rise or fall). NP (Negative peak): Due to a negative displacement in the baseline, wrong areas were integrated, which usually are too high. FP (Fused peak): A contamination is not resolved from the peak that is eluting in the retention time window and is included in the area. Areas are allocated for. the two (or more) unresolved peaks in the manual integration. 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TSL012 W26 -M Labs Detail Report Start Time: 13:00 Ilnitial Reading Date: 1 2007/12/6 Final Reading Date: 2007/12/11 Seed Correction I I'_'- - 0,19 X 3.162 BAW IWiinkler In: I 8.9 Winkler Out: 8.9 g g,551 / C�CCCA I z1- In: 9.0 Out: 9.0 Sample ID; Client ID Sample Client Name; Test Code Vol Seed Initial DU i -mai uu uepieuon Duu rvy Dvv riaya Type mL mL mg/L mglL mglL mg/L mg/L RINSE RB; BOD5 W 299.00 9.08 8.86 <2.00 <2.01 <2.01 1d 26 MB -120607 MBLK BLANK A; BOD5_W 299.00 8.90 8.96 <2.00 <2.01 <2.01 1d 26 MBLK BLANK B; BOD5_W 299.00 8.88 9.04 <2.00 <2.01 <2.01 1d 26 LCS-120607 LCS STANDARD; BOD5_W 3.00 4,00 8.81 6.57 2.24 166.48 183.85 ds 26 LCS-120607 LCS-120607 LCS LCS STANDARD; BOD5_W STANDARD; BOD5_W 6.00 9.00 4.00 4.00 8.99 8.92 4.55 2.59 4.44 6.33 193.24 191.83 ds ds 26 26 Seed 4.00 8.78 8.48 <2.00 <150.00 42.17 evlXds 26 Seed 6.00 8.80 8.17 <2.00 <100.00 evlXds 26 Seed 15.00 1 8.74 6.68 2.06 41.20 eXds 26 Seed 21.00 8.71 5.69 3.02 43.14 eds 26 0713771-001A - SAMP PCTSL001; BOD5_W 30.00 4.00 8.66 8.07 <2.00 <14.25 <1.43 v1ds 26 0713771-001A SAMP PCTSL001; BOD5_W 60.00 4.00 8.38 7.81 <2.00 <7.12 v1ds 26 0713771-001A SAMP PCTSL001; BOD5_W 150.00 4.00 7.41 6.78 <2.00 <2.85 v1ds 26 0713771-001A SAMP PCTSL001; BOD5-W 299.90 4.00 6.99 6.57 <2.00 <1.43 Ids 26 0713771-002A SAMP PCTSL002; BOD5_W 30.00 4.00 8.73 8.35 <2.00 <14.25 <1.43 vlds 26 0713771-002A 0713771-002A 0713771-002A SAMP SAMP SAMP PCTSL002; BOD5-W PCTSL002; BOD5_W PCTSL002; BOD5 W 60.00 150.00 299.90 4.00 4.00 4.00 8.70 8.67 8.50 8.39 8.28 8.27 <2.00 <2.00 <2.00 <7.12. <2,85 <1.43 v1 v1 1.00 26 26 26 0713771-003A (n _ 0713771-003A SAMP SAMP PCTSL003; BOD5 W PCTSL003; BOD5_W 30.00 60.00 4.00 4.00 8.63 8.32 8.16 7.73 <2.00 <2.00 <14.25 <7.12 <1.43 v1 v1 26 26 0713771-003A SAMP PCTSL003; BOD5_W 150.00 4.00 7.17 6.26 <2.00 <2.85 v1 26 0713771-003A SAMP PCTSL003; BOD5_W 299.90 4.00 6.79 5.67 <2.00 <1.43 1.00 26 0713771-004A jry� US 0713771-004A SAMP SAMP PCTSL004; BOD5_W PCTSL004; BOD5-W 30.00 60.00 4.00 4.00 8.65 8.52 7.85 8.14 <2.00 <2.00 <14.25 <7.12 <1.43 v1 v1 26 26 71 07137-004A SAMP PCTSL004; BOD5 150.00 4.00 7.72 7.36 <2,00 <2.85 v1 40 0713771-004A SAMP PCTSL004; BOD5- W 299.90 4.00 7.39 6.80 <2.00 <1.43 1.00 40 0713771-005A (yl - 0713771-005A SAMP SAMP PCTSL005; BOD5-W PCTSL005; BOD5_W 30.00 60.00 4.00 4.00 8.89 8.71 8.27 8.02 <2.00 <2.00 <14.25 <7.12 <1.43 v1 v1 40 40 0713771-005A SAMP PCTSL005; BOD5_W 150.00 4.00 7.70 7.03 <2.00 <2.85 v1 40 0713771 005A SAMP PCTSL005; BOD5_W 299.90 4.00 7.57 6.84 <2.00 <1.43 1.00 40 0713771-006A i�-SS SAMP PCTSL006; BOD5 W 30.00 4.00 8.83 8.18 <2.00 <14,25 <1.43 v1 40. 0713771-006A SAMP PCTSL006; BOD5_W 60.00 4.00 8.72 8.09 <2.00 <7.12 v1 40 0713771-006A SAMP PCTSL006; BOD5_W 150.00 4.00 7.83 7.39 <2,00 <2.85 v1 40 0713771-006A --<1.43.2 SAMP PCTSL006; BOD5_W 299.90 4.00 7.43 7.01 <2.00 1.00 40 0713771-04,07 n).�hV,�,7 SAMP PCTSL007; BOD5_W 30.00 4.00 8.87 8.15 <2.00 <14.25 <1.43 v1 40 1 1-jL11J1L. yr t.i Sa D; Client ID Samplel Client Name; Test Code Vol I Initial DO I Final DO I Depletionj BOD I Avg BOD Flags Rac - Type mL mgtL mg/L mg/L mg/L mg/L 0713771-007A SAMP PCTSL007; BOD5_W 299.90 4.00 0713771-007A m v _u n ISAMP IPCTSLO07: BOD5 W I 60.00 1 4.00 8.71 7.94 <2.00 I <7.12 I I v1 140 0713771-007A SAMP PCTSL007; BOD5_W 150.00 4.00 8.02 7.18 <2.00 <2.85 vi 40 0713771-007A SAMP PCTSL007; BOD5_W 299.90 4.00 7.69 6.93 <2.00 <1.43 1.00 40 0713771-007ADUP $ t7 DUP PCTSL007DUP; BOD5_W 30.00 4.00 8.93 8.07 <2.00 <14.25 <1.43 vi 40 0713771-007ADUP DUP PCTSL007DUP; BOD5_W 60.00 4.00 8.75 8.00 <2.00 <7.12 V1 40 --._......... ... .....--- --- 0713771-007ADUP DUP PCTSL007DUP; BOD5_W 150.00 4.00 7.87 7.05 <2.00 <2.85 v1 40 0713771-007ADUP DUP PCTSLO07DUP: BOD5_W 299.90 4.00 7.65 6.74 <2.00 <1.43 1.00 40 0713771-008A _q q SAMP PCTSL008; BOD5_W 30.00 4.00 8.72 7.89 <2.00 <14.25 <1.43 v1 40 0713771-008A SAMP PCTSL008; BOD5_W 60.00 4.00 8.40 7.51 <2.00 <7.12 v1 40 0713771-008A SAMP PCTSL008; BOD5_W 150.00 4.00 5.89 4.85 <2.00 <2.85 v1 40 0713771-008A SAMP PCTSL008; BOD5_W 299.90 4.00 4.04 2.50 <2.00 <1.43 1.00 40 0713771-009A l� SAMP PCTS1 09; BOD5_W 30.00 4.00 8.95 8.08 <2.00 <14.25 <1.43 V1 40 0713771-009A SAMP PCTSL009; BOD5_W 60.00 4.00 8.91 8.14 <2.00 <7.12 v1 40 0713771-009A SAMP PCTSL009; BOD5_W 150.00 4.00 8.89 7.91 <2.00 <2.85 V1 42 0713771-009A SAMP PCTSL009; BOD5_W 299.90 4.00 8.78 7.58 <2.00 <1.43 1.00 42 0713784-001C SAMP WES001; BOD5_W 15.00 4.00 8.94 7.51 <2.00 <28.50 13.07 v1 42 0713784-001C SAMP WES001; BODS -VV 30.00 4.00 8.75 7.11 <2.00 <14.25 v1s 42 0713784-001C SAMP WES001; BOD5_W 60.00 4.00 8.34 5.15 3.19 13.07 s 42 0713784-0010 _ SAMP--WES001;- BOD5_W-- -- 150.00 4.00 6.42 <1.00 5.42 >9.69 v2s 42 0713784-001C SAMP WES001; BOD5 W 299.90 4.00 6.99 <1.00 5.99 >5.42 v2s 42 0713784-002C a3 SAMP WES002; BOD5_W 15.00 4.00 9.03 7.36 <2.00 <28.50 14.51 v1s 42 0713784-002C 0713784-002C SAMP SAMP WES002; BOD5 W WES002; BODS W 30.00 60.00 4.00 4.00 8.89 8.35 6.80 5.00 2.09 3.35 15.15 13.87 S. s 42 42 0713784-002C SAMP WES002; BOD5_W 150.00 4.00 7.11 <1.00 6.11 >11.07 v2s 42 0713784-002C SAMP WES002; BOD5_VV 299.90 4.00 6.42 <1.00 5.42 >4.85 v2s 42 0713784-003C -�yj �� ..2b SAMP WES003; BOD5_W 15.00 4.00 8.90 7.41 <2.00 <28.50 20.54 v1s 42 0713784-003C SAMP WES003; BODS W 30.00 4.00 8.62 6.08 2.54 19.65 s 42 0713784-003C SAMP WES003; BOD5_W 60.00 4.00 8.11 3.25 4.86 21.42 s 42 0713784-0030 SAMP WES003; BOD5_W 150.00 4.00 6.06 <1.00 5.06 >8.97 v2s 42 0713784-003C SAMP WES003; BOD5_W 299.90 4.00 5.30 <1.00 4.30 >3.73 v2s 42 0713784-0040 rn �- �o SAMP WES004; BOD5_W 15.00 4.00 8.92 7.03 <2.00 <28.50 17,76 v1s 42 0713784-004C 0713784-004C SAMP SAMP WES004; BOD5_W WES004; BOD5_W 30.00 60.00 4.00 4.00 8.71 7.94 6.30 3.93 2.41 4.01 18.35 17.17 S 5 42 42 0713784-004C SAMP WES004; BOD5_W 150.00 4.00 5.74 <1.00 4.74 >8.33 v2s 42 0713784-004C SAMP WES004; BOD5_W 299.90 4.00 4.93 <1.00 3.93 >3.36 v2s 42 0713784-005C1� SAMP WES005; BOD5_W 15.00 4.00 8.93 5.30 3.63 61.10 61.10 s 42 0713784-005C 0713784-0050 SAMP ISAMP WES005; BOD5_W WES005; BOD5_W 30.00 60.00 4.00 4.00 8.68 8.19 <1.00 j <1.00 j 7.68 7.19 >71.05 j >33.07 v2s v2s 42 139 0713784-005C SAMP WES005; BOD5_W 150.00 4.00 6.49 <1.00 5.49 >9.83 v2s 39 0713784-0050 ISAMP WES005; BODS W 1 299.90 4.00 4.45 <1.00 3.45 1 >2.88 1 1 v2s 139 0713784-006C In w --I 1 e 5 ISAMP IWE5006; BUUb_W TSLO12 W28 I 15.UU I 4.UU I b.W I /.b4 I <L.UU I <Zt5.5U I ;J. Ili I VIS I3y & D; Client ID Samplel Client Name; Test Code Vol Initial DO Final DO Depletion BOD Avg SOD I Flags lRat Type <2.00 mL _ mg/L mg/L mg/L mg/L mg/L SAMP WES006; BOD5_W 150.00 4.00 7.08 0713784-006C m W - Z) 4S ISAMP JWES006; BOD5_W I 30.00 4.00 I 8.84 7.36 <2.00 1 <14.25 1 1 vis 139 0713784-0066 SAMP WES006; BOD5_W 60.00 4.00 8.37 6.75 <2.00 <7,12 v1s 39 0713784-006C SAMP WES006; BOD5_W 150.00 4.00 7.08 4.57 2.51 3.87 s 39 0713784-006C _ SAMP WES006; BOD5_W 299.90 4.00 6.50 2.23 4.27 3.70 s 39 0713784-007C 6j ZO_S07 SAMP WES007; BOD5_W 30.00 4.00 8.88 7.64 <2.00 <14.25 <1.43 v1s 39 0713784-007C SAMP WES007; BOD5_W 60.00 4.00 8.89 7.48 <2.00 <7.12 v1s 39 0713784-007C SAMP WES007; BOD5_W 150.00 4.00 8.69 7.54 <2.00 <2.85 v1s 39 0713784-007C �^ SAMP WES007; BOD5_W 299.90 4.00 8.51 7.44 <2.00 <1.43 1s 39 0713806-001A �Z��l Y1 oS17C SAMP GECO; BOD5_W 30.00 4.00 8.94 7.12 <2.00 <14.25 3.95 vis 39 0713806-001A SAMP GECO; BOD5_W 60.00 4.00 9.00 7.17 <2.00 <7.12 vis 39 0713806-001A SAMP GECO; BOD5_W 150.00 4.00 9.30 6.57 2.73 4.31 s 39 0713806-001A SAMP GECO; BOD5 W 299.90 4.00 9.62 5.45 4.17 3.60 5 39 0713772-001A SAMP GPS INF; BODS-C_W 1.50 9.02 7.21 <2.00 <400.00 238.00 v1 39 0713772-001A SAMP GPS INF; BOD5-C_W 3.00 9.14 6.50 2.64 264.00 39 0713772-001A SAMP GPS INF; BOD5-C_W 6.00 9.05 4.81 4.24 212.00 39 0713772-001A T SAMP GPS INF; BOD5-C_W 15.00 8.80 <1.00 7.80 >156.00 v2 39 (5713772-002A SAMP GPS EFF; BOD5-C_W 30.00 4.00 8.91 6.66 2.25 16.75 15.67 s 39 0713772-002A SAMP GPS EFF; BODS-C_W 60.00 4.00 9.00 5.22 3.78 16.02 s 39 0713772-002A SAMP GPS EFF; BOD5-C_W 150.00 4.00 9.19 1.50 7.69 14.23 s 39 0713772-002A SAMP GPS EFF; BODS -C W 299.90 4.00 9.22 <1.00 8.22 >7.65 v2s 39 0713792-001A L S 1 .-ior SAMP BNLS EFF; BODS W 30.00 4.00 8.89 7.45 <2.00 <14.25 <1.43 vis 28 0713792-001A �! SAMP BNLS EFF; BOD5_W 60.00 4.00 8.96 7.51 <2.00 <7.12 v1s 28 0713792-001A SAMP BNLS EFF; BOD5_W 150.00 4.00 9.16 7.63 <2.00 <2.85 v1s 28 0713792-001A SAMP BNLS EFF; BOD5 W 299.90 4.00 9.24 7.62 <2.00 <1.43 1s 28 0713792-003A Z S) 7 BNLS INF; BOD5_W 3.00 8.88 7.64 <2.00 <200.00 60.95 v1 28 0713792-003A _ _SAMP SAMP BNLS INF; BOD5_W 6.00 8.88 7.32 <2.00 <100.00 v1 28 0713792-003A SAMP BNLS INF; BOD5W 15.00 8.90 4.57 4.33 86.60 28 n7l3749-nnsA SAMP BNLS INF- BOD5_W 1 30.00 1 8.53 5.00 1 3.53 35.30 1 128 TSLO12 W29 Page 1 of 1 BOD Flags r Flag Flaiy Description cN 1 Change in DO is less than 2.0 W 2 Final DO is less than 1.0 O a Sample is a calibration sample (ie `calibrate#') A Sample was voided by the Additional Rules for Reportability D Sample was diluted through the Auto Dilution component of control 1 E Sample is a `Seed' control sample F Sample has failed the EC requirements g `Check' sample has failed the Check Sample initial DO range criteria G `Check' sample has failed the Check Sample final DO range criteria M Sample has exceeded the specified Maximum Variance for the incubation period o Sample reading is unstable — Stabilization Timeout occurred (Initial DO) O Sample reading is unstable — Stabilization Timeout occurred (Final DO) q `Check' Sample has failed the Check Sample Standard Deviation criteria (Initial DO) Q `Check' Sample has failed the Check Sample Standard Deviation criteria (Final DO) R `Check' sample BOD value is out of range S Seed or ATU has been added to the sample t Initial Temperature is out of range T z: Final Temperature is out of range U Sample set is determined to be statistically unreliable(bactericidal effect indicated),by the Additional Rules for Reportability . v Sample has been voided (i.e. failed rule) V Blank Check sample has exceeded the specified maximum value W Sample is suspected of being toxic X Blank, Seed or Spike sample has failed a rule and is not used when calculating the correction factor y Sample has surpassed Supersaturation level specified in setup (Initial DO) Y Sample has surpassed Supersaturation level specified in setup (Final DO) Z A Check sample's BOD Standard Deviation exceeds the Maximum Standard Deviation Page 1 of 1 _-�M Labs Detail Report Start Time: 10:00 Initial Reading Date: 2007/12/7 Final Reading Date: 2007/12/12 Seed Correction % 21 rator: BAW Winkler In 00'= b, -S7 Client Name; Test Code Vol 8.9 Meter In: 8.9 Meter Out: 8.9 w 9.0 TS L 012 - Sample ID: Client ID (Sample Client Name; Test Code Vol Seed Initial DO Final DO Depletion I BOD Avg BOD Flags lRack# Type - mL mL mg/L mg/L mg/L mg/L mglL RINSE RB; BOD5_W 299.00 9.04 9.10 <2.00 <2.01 <2.01 1d 41 MB-- MBLK BLANKA; BOD5-W 299.00 9.09 9.15 <2.00 <2.01 <2.01 1d 41 MBLK BLANK B; BODS -VV 299.00 9.10 9.19 <2.00 <2.01 <2.01 1d 41 LCS LCS STANDARD; BOD5-W 3.00 4.00 8.88 6.48 2.40 182.86 174.36 ds 41 -----..----------- LCS - LCS - STANDARD; BODS -W 6.00 4.00 8.88 4.79 4.09 175.93 �o ds 41 LCS ' 7 LCS STANDARD; BOD5_W 9.00 4.00 8.68 3.18 5.50 164.29 0 v -ds 41 Seed 4.00 9.02 8.72 <2.00 <150.00 42.43 evlXds 41 Seed 6.00 9.03 8.49 <2.00 <100.00 evlXds 41 Seed 15.00 9.01 6.91 2.10 42.00 eXds 41 Seed 21.00 8.99 5.99 3.00 42.86 • eds 41- 0713781-001A SAMP RHS INF; BOD5-W 1.50 9.19 8.14 <2.00 <400.00 259.00 v1d 41 0713781-001A SAMP RHS INF; BOD5 W 3.00 9.10 6.66 2.44 244.00 d 41 0713781-001A SAMP RHS INF; BOD5_W 6.00 9.12 3.64 5.48 274.00 d 41 0713781-001A SAMP RHS INF; BOD5-W 15.00 9.28 <1.00 8.28 >165.60 v2 41 0713781-001A SAMP RHS INF; BOD5-C-W 1.50 9.19 8.36 <2.00 <400.00 - 195.00 v1 41 0713781-001A SAMP RHS INF; BOD5-C-W 3.00 9.11 7.26 <2.00 <200.00 v1 41 0713781-001A SAMP RHS INF; BODS -C W 6.00 9.12 5.22 3.90 195.00 41 0713781-001A SAMP RHS INF; BODS -C -W 15.00 8.96 <1.00 7.96 >159.20 v2 41 0713781-001A SAMP RHS INF; BOD5_W DISS 1.50 9.23 8.72 <2.00 <400.00 97.60 v1 41 0713781-001A _ SAMP RHS INF; BODS-W-DISS 3.00 9.13 8.30 <2.00 <200.00 v1 41 0713781-001A SAMP RHS INF; BOD5 W DISS 6.00 9.06 7.36 <2.00 <100.00 v1 41 0713781-001A SAMP RHS INF; BOD5_W_DISS 15.00 9.15 4.27 4.88 97.60 41 0713781-002A SAMP RHS EFF; BOD5 W 15.00 4.00 9.14 8.52 <2.00 <28.57 <2.86 v1 41 0713781-002A SAMP RHS EFF; BODS_W 30.00 4.00 9.03 8.29 <2.00 <14.29 v1 41 0713781-002A SAMP RHS EFF; BOD5_W 60.00 4.00 9.03 8.23 <2.00 <7.14 v1 30 0713781-002A - SAMP RHS EFF; BOD5_W 150,00 4.00 9.09 8.01 <2.00 <2.86 1.00 30 0713781-002A - SAMP RHS EFF; BODS -C -W 15.00 4.00 9.10 8.76 <2.00 <28.57 <2.86 v1 30 0713781-002A SAMP RHS EFF; BODS -C -W 30.00 4.00 9.14 8.70 <2.00 <14.29 v1 30 0713781-002A _ SAMP RHS EFF; BOD5-C-W 60.00 4.00 9.10 8.57 <2.00 <7.14 v1 30 07 1 378 1-002A SAMP RHS EFF; BODS -C -W 150.00 4.00 9.28 8.19 <2.00 <2.86 1.00 30 0713781-002A SAMP JRHS EFF; BOD5_W_DISS 15.00 4.00 9.10 8.61 <2.00 <28.57 <2.86 v1 30 0713781-002A SAMP RHS EFF; BOD5_W_DISS 30.00 4.00 9.06 8.38 <2.00 <14.29 v1 30 0713781-002A _ SAMP RHS EFF; BOD5_W_DISS 60.00 4.00 9.06 8.18 <2.00 <7.14 v1s 30 0713781-002A SAMP RHS EFF; BOD5_W-DISS 150.00 4.00 8.86 7.95 <2.00 <2.86 1s 30 071377"-09f'b,T Ial ,-) 1XV2 1 SAMP RHS LOC #2; BOD5-C-W 0.30 9.04 1 6.11 2.�3 2930.00 3212.50 130 S;. 'D; Client ID Samplel Client Name; Test Code Vol i Initial DO Final DU uepletion buu Hvg avu riags rsa mL mg/L mg/L mg1L mg/L mg/L Type 071379$01A SAMP IRHS LOC #2; BOD5-C W 0.60 9.04 2.05 6.99 3495.00 1 30 - -- ----- 07137-001A -- - ----- --- - SAMP JRHS LOC #2; BODS-C_W -1.50 9.04 <1.00 8.04 >1608.00 v2 30 07137 �J-001 A SAMP RHS LOC #2; BOD5-C_W 3.00 8.83 <1.00 7.83 >783.00 v2 30 0713812-001A SAMP RHS RAY; BOD5-C_W 1.50 9.06 7.46 <2.00 <400.00 244.75 v1 30 0713812-001A SAMP RHS RAY; BOD5-C_W 3.00 9.09 6.55 2.54 254.00 30 0713812-001A SAMP RHS RAY; BOD5-C_W 6.00 9.07 4.36 4.71 235.50 30 0713812-001A SAMP RHS RAY; BOD5-C_W 15.00 8.75 <1.00 7.75 >155.00 v2 30 0713817-001A (� tij.?,(� SAMP PCTSL001; BOD5_W 30.00 4.00 8.91 8.21 <2.00 <14.29 <1.43 v1s 30 0713817-001A -- - ------ ---- -------.._..._..-..----- 0713817-001A SAMP -- SAMP PCTSL001; BOD5_W - -- - PCTSL001; BOD5_W 60.00 150.00 4.00 4.00 8.71 7.75 7.92 6.62 <2.00 <2.00 z7,14 <2.86 v1s v1s 30' 30 0713817 001A SAMP PCTSL001; BOD5_W 299.90 4.00 7.24 5.75 <2.00 <1.43 1s 30 0713817 002A rn SAMP PCTSL002; BO -D-5 30.00 4.00 8.87 8.11 <2.00 <14.29 2.g(� vis 30 0713817-002A SAMP PCTSL002; BOD5_W 60.00 4.00 8.14 6.94 <2.00 <7.14 vis 30 - ---- -- 07711381177-002A - - -- -- -- -- SAMP SAMP- ---- - --- PCTSL002; BOD5_W 150.00 4.00 6 4& 6,a 4-44 2,o<z.9g- •8"b�:BF, r v1s 31 13817-002A, ✓ SAMP PCTSL002; BODS -W 299.90 4.00 4.27 <1.00 3.27 >2.70 v2s 31 ------.._..----------..___.SSSS----_...-___._.:.._-- 0713817-003A M tS, SSSS SAMP PCTSL003; BOD5_W - 30.00 4.00 8.96 8.12 <2.00 <14.29 <1.43 v1s 31 0713817-003A SAMP PCTSL003; BOD5-W 60.00 4.00 8.93 8.32. <2.00 <7.14 v1s 31 _. _ 0713817-003A - - - -- -..._ - .___ -- SAMP 'PCTSL003; BOD5_W 150.00 4.00 8.48 7.78 <2.00 <2.86 v1s 1s 31 31 - --- -- - 0713817-003A -- SAMP IPCTSL003; BOD5_W 299.90 4.00 8.15 7.58 <2.00 <1.43 - --- - 0713817-004A -- - UJ - --- f -- -- -- SAMP PCTSL004; BOD5_W 30.00 4.00 9.10 8.11 <2.00 <14.29 <1.43 v1s 31 0713817-004A SAMP PCTSL004; BOD5W 60.00 4.00 8.91 8.16 <2.00 <7.14 v1s 31 0713817-004A SAMP PCTSL004; BOD5__W 150.00 4.00 8.02 7.23 <2.00 <2.86 v1s 31 __...- - - -- 0713817-004A - - -- --- - SAMP PCTSL004; BODS_W 299.90 4.00 7.61 6.96 <2.00 <1.43 1 s 31 SSSS.. -:.:--..__.-_----- 0713817-005A SAMP PCTSL005; BOD5_W 30.00 4.00 9.04 8.14 <2.00 <14.29 <1.43 v1s 31 ----0-05,A-- 0713817--- SAMP PCTSLO05: BOD5_W 60.00 4.00 8.85 8.37 <2.00 <7.14 v1s 31 0713817-005A SAMP PCTSL005'; BOD5_W 150.00 4.00 8.14 7.30 <2.00 <2.86 v1s 31 0713817-005A SAMP PCTSL005; BOD5_W 299.90 7.51 6.960713832-001C J SAMP WES001; BOD5_W 15.00 00 9.07 8.06 <2.00 <28.57 10.84v1s 31 0713832-001CSAMP WES001; BOD5W 30.00 !4.00 00 8.94 2>11.38 7.67 <2.00 <14.29 v1s 31 SAMP WES001; BOD5 W 60.00 00 8.56 5.82 2.74 10.84 s 31 0713832-001C SAMP WES001; BOD5_W 150.00 4.00 7.26 <1.00 6.26 v2s 31 ------ 0713832-001C - - - -- - SAMP WES001; BOD5_W 299:90 4.00 7.48 <1.00 6.48 >5.91 v2s 31 0713832-002C SAMP WES002; BOD5_W 15.00 4.00 8.90 7.67 <2.00 <28.57 13.19 v1s 31 ..--- -....._.-- 0713832-002C. _ -SSSS b-7-1- - SAMP - --- WES002; BOD5_W 30.00 4A0 8.91 7.19 <2.00 <14.29 v1s 31 --------- -----1-----__SSSS..._-- 0713832-002C - -- - - -- --- --------- 0713832-0020 SAMP SAMP WES002; BODS W WES002; BODSW 60.00 150.00 4.00 4.00 8.03 5.78 4.82 <1.00 3.21 4.78 13.19 >8.42 s v2s 31 31 0713832-002C SAMP WES002; BOD5_W 299.90 4.00 5.80 <1.00 4.80 >4.23 v2s 31 0713832-003C - Mint - Z � SAMP WES003; BOD5_W 15.00 4.00 9.02 8.01 <2.00 <28.57 12.89 v1s 38 _ _ 0713832 003C SAMP WES003; 6005_W 30.00 4.00 8.89 7.32 <2.00 <14.29 v1s 38 0713832 0030 0713832-0030 SAMP SAMP WES003; BOD5_W WES003; BOD5_W 60.00 150.00 4.00 4.00 8.55 7.61 5.40 <1.00 3.15 6.61 12.89 >12.08 s v2s 38 38 TSLO12 W32 S' ID; Client ID Sample Client Name; Test Code Vol !d Initial DO Final DO Depletion I BOD jAvg BOD Flags Ra 'type mL mg/L mg/L mg1L mg/L mg/L 0713832-003C rnW_L12� SAMP IWES003; BOD5_W 299.90 1 4.00 I 7.24 <1.00 6.24 >5.67 1 v2s 38 0713832-003CDUP DUP DUP GW; BOD5_VV 15.00 4.00 9.18 8.06 <2.00 <28.57 11.24 v1s 38 6i13832-003CDUP 0713832-003CDUP DUP DUP DUP GW; BOD5-W DUP GW; BOD5_W 30.00 60.00 4.00 4.00 9.12 8.64 7.86 5.82 <2.00 2.82 <14.29 11.24 v1s s 38 38 0713832 003CDUP DUPDUP GW; BOD5_W 150.00 4.00 7.55 <1.00 6.55 >11.96 v2s 38 0713832 003CDUP DUP +DUP GW; BOD5_W 299.90 4.00 6.76 <1.00 5.76 >5.19 v2s 38 0713832_-0040 0713832-004C 0713632-0040 SAMP SAMP SAMP IWESOO4; WES004; BOD5_W WES004; BOD5_W BOD5_W 15.00 30.00 60.00 4.00 4.00 4.00 8.99 8.78 8.46 8.18 7.92 7.38 <2.00 <2.00 <2.00 <28.57 <14.29 <7.14 2.28 v1s v1s v1s 38 38 38 0713832-004C SAMP WES004; BOD5_W 150.00 4.00 6.88 5.00 <2.00 <2.86 v1s 38 0713832-0040 1SAMP WES004; BOD5-W 299.90 4.00 6.40 3.55 2.85 2.28 s 38 0713832-0050- -�� _� i� s_ - SAMP WES005; BOD5_W - 15.00 4.00 8.78 4.46 4.32 74.97 68.83 s 38 0713832-005C SAMP WES005; BOD5-W 30.00 4.00 8.38 1.54 6.84 62.69 s 38 0713832-0050 SAMP WES005; BOD5-W 60.00 4.00 7.80 <1.00 6.80 >31.14 v2s 38 0713832 0050 SAMP WES005; BOD5_W 150.00 4.00 5.74 <1.00 4.74 >8.34 v2s 38 0713832-005C SAMP WES005; BOD5_W 299.90 4.00 6.01 <1.00 5.01 >4.44 v2s 38 0713832.0060 - SAMP WES006; BOD5_W' 15.00 4.00 8.97 6.86 2.11 30.77 39.78 s 38 0713832-006_ SAMP WES006; BOD5_W 30.00 4.00 8.77 3.32 5.45 48.79 s 38 0713832-006C SAMP WES006; BOD5 W 60.00 4.00 8.18 <1.00 7.18 >33.04 v2s 38 0713832-0060 SAMP WES006; BOD5-W 150.00 4.00 6.03 <1.00 5.03 >8.92 v2s 38 0713832-006C SAMP WES006; BOD5_W 299.90 4.00 5.47 <1.00 4.47 >3.90 v2s 34 0713832-0070 p SAMP WES007; BOD5_W 15.00 4.00 9.02 7.56 <2.00 <28.57 <1.43 v1s. 34 0713832-007C SAMP WES007; BOD5-W 30.00 4.00 8.96 8.03 <2.00 <14.29 v1s 34 0713832-0070 SAMP IWES007; BOD5-W 60.00 4.00 8.68 7.94 <2.00 <7.14 v1s 34 0713832-007C SAMP WES007; BOD5_W 150.00 4.00 6.86 6.72 <2.00 <2.86 v1s 34 0713832 0070 SAMP WES007; 80D5_W 299.90 4.00 7.30 6.82 <2.00 <1.43 is 34 0713832-0080 I�w bbfq2 SAMP WES008; BOD5-W15.00 4.00 8.29 8.04 <2.00 <28.57 8.24 v1s 34 0713832-0080 SAMP WES008; BOD5_W 30:00 4.00 8.06 7.16 <2.00 <14.29 v1s 34 0713832-008C SAMP WES008; BOD5-W 60.00 4.00 7.71 5.49 2.22 8.24 s 34 0713832-0080 SAMP WES008; BOD5-W 150.00 4.00 6.40 <1.00 5.40• >9.66 v2s 34 6i13832-0080 SAMP WES008; BOD5-W 299.90 4.00 5.78 <1.00 4.78 >4.21 v2s 34 0713855-001A SAMP WCS EFF; BOD5_W 30.00 4.00 8.39 8.05 <2.00 <14.29 <1.43 v1s 34 0713855-001A SAMP WCS EFF; BOD5-W 60.00 4.00 8.19 8.07 <2.00 <7.14 v1s 34 0713855-001A SAMP WCS EFF; BOD5_W 150.00 4.00 8.29 8.15 <2.00 <2.86 v1s 34 0713855-001A SAMP WCS EFF; BOD5 W 299.90 4.00 7.62 7.45 <2.00 <1.43 1s 34 0713840-002A SAMP SYC; BOD5_W 15.00 4.00 8.24 7.54 <2.00 <28.57 24.11 v1s 34 0713840-002A - - SAMP SYC; BOD5_W 30.00 4.00 8.54 5.96 2.58 20.09 s 34 0713840-002A - SAMP SYC; BOD5_W 60.00 4.00 8.21 2.01 6.20 28.14 s 34 0713840-002A SAMP SYC; BOD5_W 150.00 4.00 7.96 <1.00 6,96 >12.78 v2s 34 0713833-OO1A - SAMP OBS INF; BOD5-C W 3.00 8.65 7.80 <2.00 <200.00 78.60 v1 34 0713833-001A SAMP OBS INF; BOD5-C-W 6.00 7.70 7.17 <2.00 <100.00 v1 34 TSL012 W33 ID; Client ID Client Name; Test Code I Vol :d I Initial DO I Final DO I Depletion I BOD I Avg BOD I Flags IR1. TSLO12 W34 � Ty mL ML rngrL niyrL InyrL IuyrL 111yI4 ------------------- 0713833-001A SAMP OBS INF; BOD5-C W 15.00 8.02 4.09 3.93 78.60 34 0713833-001A _ _ _ _- SAMP OBS INF; BOD5-C-W 30.00 7.97 <1.00 6.97 >69.70 v2 34 0713-8'- 02A SAMP OBS EFF; BOD5-C_W 30.00 4.00 8.29 8.02 <2.00 <14.29 1.55 v1s 34 0713833-002A SAMP OBS EFF; BOD5-C_W 60.00 4.00 7.56 7.86 <2.00 <7.14 v1s 29 0713833-002A SAMP OBS EFF; BOD5-C_W 150.00 4.00 7.97 7.38 <2.00 <2.86 v1s 29 0713833-002A SAMP OBS EFF; BOD5-C_W 299.90 4.00 7.94 5.82 2.12 1.55 s 29 0713887-001A SAMP HGO INF; BOD5_W 1.50 8.39 5.74 2.65 530.00 532.50 29 0713887-001A SAMP HGO INF; BOD5_W 3.00 7.80 2.45 5.35 535.00 29 0713887-001A - SAMP HGO INF; BODS W 6.00 7.86 <1.00 6.86 >343.00 v2 29 0713887-001A SAMP HGO INF; BOD5_W 15.00 7.75 <1.00 6.75 >135.00 v2 29 d7i-3 3 8 87-002A SAMP HGO EFF; BOD5_W 30.00 4.00 8.35 6.52 <2.00 <14.29 10.84 v1s 29 -_._._::.._ ------._... 0713887-002A ------ -- SAMP HGO EFF; BODS W 60.00 4.00 7.56 4.82 2.74 10.84 s 29 0713887-002A SAMP HGO EFF; BOD5_W 150.00 4.00 7.06 <1.00 6.06 >10.98 v2s 29 0713887-002A SAMP HGO EFF; BOD5_W 299.90 4.00 5.55 <1.00 4.55 >3.98 v2s 29 0713885-001A SAMP RHS RAY2; BOD5-C W 1.50 4.00 8.17 7.17 <2.00 <285.71 146.93 v1s 29 0713885-001A SAMP RHS RAY2; BOD5-C_W 3.00 4.00 7.69 6.28 <2.00 <142.86 v1s 29 0713885-001A SAMP RHS RAY2; BOD5-C-W 6.00 4.00 7.66 4.15 3.51 146.93 s 29 0713885-001A SAMP RHS RAY2; BOD5-C_W 15.00 4.00 8.00 <1.00 7.00 >128.57 v2s 29 0713892-001A --- -1 0 o 1 SAMP BNLS EFF; BOD5 W - 30.00 4.00 8.30 8.10 <2.00 <14.29 <1.43 v1s 29 0713892-001A SAMP BNLS EFF; BOD5_W 60.00 4.00 7.73 8.46 <2.00 <7.14 v1s 29 0713892-001A SAMP BNLS EFF; BOD5 W 150.00 4.00 8.82 8.83 <2.00 <2.86 v1s 29 0713892-001A SAMP BNLS EFF; BOD5-W 299.90 4.00 8.74 8.71 <2.00 <1.43 1s 29 0713892-003A Zj�ctZ G'6S SAMP BNLS INF; BOD5-W 3.00 8.27 7.78 <2.00 1 <200.00 51.15 v1 29 0713892-003A SAMP BNLS INF; BOD5_W 6.00 7.82 7.56 <2.00 <100.00 v1 29 0713892-003A SAMP BNLS INF; BOD5_W 15.00 8.59 5.86 2.73 54.60 29 0713892-003A SAMP BNLS INF; BOD5-W 30.00 8.49 3.72 4.77 47.70 129 SAMP PCNR; BOD5_W 15.00 4.00 8.11 <1.00 7.11 >130,77 2489.29 v2s 29 - .. - ------------3 0 1) �9 Y. U01A - -- _ -- SAMP ---- PCNR; BOD5_W 0.60 4.00 7.48 1.93 5.55 2489.29 s 24 0 6919-001A SAMP PCNR; BODS -W 1.50 4.00 7.94 <1.00 6.94 >1273.71 v2s 24 _.. ._._......._..........------ ,070 19 001A -- - - -- -- ---- SAMP PCNR; BOD5_W 3.00 4.00 8.25 <1.00 7.25 >667.86 v2s 24 070691 001A SAMP PCNR; BOD5_W 6.00 4,00 8.18 <1.00 7.18 >330.43 v2s 24 TSLO12 W34 Page 1 of 1 BOD Flags r NFlag Flag Description 1 Change in DO is less than 2.0 2 Final DO is less than 1.0 a Sample is a calibration sample (ie `calibrate#') A Sample was voided by the Additional Rules for Reportability D Sample was diluted through the Auto Dilution component of control 1 E Sample is a `Seed' control sample F Sample has failed the EC requirements g ` `Check' sample has failed the Check Sample initial DO range criteria G `Check' sample has failed the Check Sample final DOrange criteria M Sample has exceeded the specified Maximum Variance for the incubation period o Sample reading is unstable — Stabilization Timebut occurred (Initial DO) O Sample reading is unstable — Stabilization Timeout occurred (Final DO) q `Check' Sample has failed the Check Sample Standard Deviation criteria (Initial DO) Q `Check' Sample has failed the Check Sample Standard Deviation criteria (Final DO) R `Check' sample BOD value is out of range s Seed or ATU has been added to the sample t . Initial Temperature is out of range T Final Temperature is out of range U Sample set is determined to be statistically unreliable(bactericidal effect indicated),by the Additional Rules for Reportability . v Sample has been voided (i.e. failed rule) V Blank Check sample has exceeded the specified maximum value w Sample is suspected of being toxic X Blank, Seed or Spike sample has failed a rule and is not used when calculating the correction factor Y Sample has surpassed Supersaturation level specified in setup (Initial DO) Y Sample has surpassed Supersaturation level specified in setup (Final DO) Z A Check sample's BOD Standard Deviation exceeds the Maximum Standard Deviation Page 1 of 1 M +410411') , fp.OS17r9 MW- /A NW - i5 Mw-Np Mw -45 OW -5b R w. 55 MN -0 " IZiS% -3 s Hw-bb h.w • 6S M(3-87 ^rS(-o(2 Author: Omnion User H2M Labs. Inc. Date: 12/15/2007 Original Run Filename: OM_12-14-2007_03-40-13PM.OMN created 12/14/2007 3:40:13 PM Original Run Author's Signature: [Omnion User] Current Run Filename: anionsl21407.omn last modified 12/15/2007 7:40:14 AM Current Run Author's Signature: [Omnion User] . Description: Default New Run �2►f �bni 7 14�-V i Sample Channell Bromide Cup No. Channel 1 Bromide Conc. (mg/L I Area .min T� ADF MDF "LCS-121407:LCS:Anion300 WVV" True 1 2.435 0.004 1/x Auto Dilution Td er Known Conc: 2.500 q+TI• 11 "ICB-121407:ICB:anion300 ww" 1 2 0.014 0.000 Known Conc: 0.000 L0. 5 "lfb-121407:lfb:anion300 ww" 1 3 1 0.922 0.002 i Known Conc: 1 1.000 cl 7.1• 1 "MB-121407:MBLK:anion300 ww" 1 4 0.020 0.000 1 Known Conc: 0.000 GD.s "0713771 -001 A:SAMP:AN ION 300 WW 5 0.058 0.000 - Calibration: Table/Fi . 1 "0713771-002A:SAMP:ANION300 WVV" 6 0.083 0.000 "0713771-003A:SAMP:ANION300 WW' 7 2.454 0.004 "0713771-004A:SAMP:ANION300 WW' 8 0.165 0.000 "0713771-005A:SAMP:ANION300 WVV" 9 1.401 0.002 "0713771-006A:SAMP:ANION300 WW' 10 0.160 0.000 "0713771-007A:S .-ANION300 WW' H4 11 1.864 0.003 "0713771-007AMS: :ANION300 WVV 12 0.8761 0.002 "0713771-007ADUP:DUP-ANION300 WVV 13 0.8701 0.002 "0713771-008A:SAMP:ANION300 WW' 14 0.3131 0.001 "CCV:CCV:anion300 ww" S4 0.9341 0.002 Known Conc: 1.000 AS-I- "CCB:CCB:anion300 ww S8 0.019 0.000 Known Conc: 0.000 Go.S "0713771-009A:SAMP:ANION300 WW' 15 0.014 0.000 "0713817-001A:SAMP:ANION300 WVW 16 1.053 0.002 "0713817-002A:SAMP:ANION300 WW' 17 0.371 0.001 FO713817-003A:SAMP:ANION300 WW" 18 0.110 0.000 "0713817-004A:SAMP:ANION300 WVV" 19 0.022 0.000 1 "0713817-005A:SAMP:ANION300 WW" 20 0.081 0.000 "0713771-002A:SAMP:ANION300 WW' 6 0.145 0.000 5.00 "0713771-003A:SAMP:ANION300 WVV" 7 2.329 0.001 5.001 "0713771-007A:SAMP:ANION300 VVW' 11 1.790 0.001 5.00 "0713771-007AMS:MS:ANION300 WVV" 12 0.869 0.000 5.00 "CCV:CCV:anion300 ww" I S4 0.940 0.002 Known Conc: 1.000 H•I. "CCB:CCB:anion300 ww" S8 0.0201 0.0001 1 Known Conc: 0.000 1-5 "0713771-007ADUP:DUP:ANION300 WVV' 13 0.883 0.000 5.00 "0713771-008A:SAMP:ANION300 WVV" 14 0.354 0.000 5.00' "0713817-002A:SAMP`.ANION300 WVV" 17 0.386 0.000 5.00 "0713817-003A:SAMP:ANION300 WVV' 18 0.181 0.000 5.00 "0713817-005A:SAMP:ANION300 WVV". 1 20 0.268 0.000 10.00 "CCV:CCV:anion300 ww" I S4 0.933 0.002 Known Conc: 1.000 3 7 "CCB:CCB:anion300 ww S8 0.014 0.000 Known Conc: 0.000 1 GO,j Analyte Properties Table for anions 121407.omn Property Channell Bromide Concentration Units mg/ Callibration Fit Type First Order Clear Calibration True Force Through Zero False Calibration Weighting 1/x Auto Dilution Td er True % of High Standard 1 110 1 Run: anions121407 -1- IC Author: Omnion User H2M Labs. Inc. Quik Method 10-510-00-1-A 10-510-00-1-A I Chemistry Direct/Bi olar Direct/Bi olar Calibration by Height 1 True True I Inject to Peak Start 1 257 145 Peak Base Width 1 56 59 Channel 1 (Anions) : "LCS-121407:LCS:Anion300_WW" [Row 1] 3.005 W O L v U Z Z .0 8.529 i � dL W� FLCO E 2.524 mg/L 2,545 mg/L 2 z CD 2.463 mg/L 2.435 mg/L 0.219 -... ........ .... ._.._..._._._...._..._..__.__..__..._..,....-_----....._....._.... _....... _....._._...._'..._,____..:_.....___._._._...____... 1.5 Time (min) Run: anions121407 - 2 - a d m L a 0 L 2.532 mg/L Date : 12/15/2007 9.427 mg/L 12.0 IC Author: Omnion User H2M Labs. Inc. Channel 1 (Anions): "ICB-121407:ICB:anion300_ww" [Row 2] 3.005--] C m v_ m m a a o t +- r 0.016gg/L z m z a 0 200 mglL0.013 mg/L 0.014 mg/L-0.022 mg/L -0.11 0.219...._.._.__.._.__.........._.._._:...._......._.._:__:.__._.._.:._.._..__._.....__.......__... --------.._....:_..---- ._._......_........._._...._...__....-..._...___— 15.1 Time (min) Channel 1 (Anions) : "Ifb-121407: Ifb:anion300_ww" [Row 31 3.005 -,- I 0.219 28.6 m `o U o_ 3.740 rzi/L z c a E o z 2 z a 0.928 mg/L 0 922 m CO 0.899 mg/L 1.318 mg/L n g- - – Time (min) Date : 12/15/2007 0.065 mg/L 25.6 26.871 mg/L 39.1 Run: an[ons121407 - 3 - IC 00 M N O C/1 Author: OmnionUser H2MLnba Inc. Channel 1 (Anions): "MB-121407:MBLK:anion3OO–wwDRvw4O 3.005 E CO 0.219 Channel 1Kniono : "07 3771-O@1A:SAMP:ANxJN9ou_WVV'yRow51 3.005 Dote : 12M5/2007 mg/L CO 2.400 mg/L Time (min) 66.2 Rbncanionn1214D7 -4- |C Author: Omnion User H2M Labs. Inc. Channel 1 (Anions) : "0713771-002A:SAMP:ANION300_WNP' [Row 61 3.005 -f o j U z CCC 56.4260.013 mg/L 0 0.219 >— ... 69.2 z a� � � m a 0 o Z - 3.422 mg/L 0.1.83 mg/L�— 0.083 mg/L____ Time (min) Channel 1 (Anions) : "0713771-003A:SAMP:ANION300 WW" [Row 7] 3.005 0 0.219 82.7 Date : 12/1512007 a� a m L 26.256 mg/L a a. a. /\ 0.121 mg/Lj �_ 79.7 Time (min) 93.2 Run: anions121407 - 5 - IO Author: Omnion User H2M Labs. Inc. Channel 1 (Anions) "0713771-004A:SAMP:ANION300_WW" [Row 81 3.005 - Date : 12/15/2007 `o U j28.605 mg/L a� z :? cA 12 a 51.011 mg/L z 11.436 mg/L Z , m i v N CLO - z m \ 4_ 0.065 mg/L�_0.109 mg/L 0.165 mg/L� -0.103 mg/L� 0.219 ...__._... _.._. _. _ ......... ... — ..._...... _..--- -..... . ...... _ ....__..._...:..._.......... _... 96.3 Time (min) Channel 1 (Anions) : "0713771-005A:SAMP:ANION300 WIN' [Row 91 3.005 N O 0.219 109.8 i O n 50.021 mg/L N O z L O p O m z a_ 0.045 mg/L '\- 1.401 mg/1-0.021 m /L -9.107mg/L Time (min) 106.8 120.3 Run: anions121407 - 6 - iC Author: Ornnion User F12M Labs. Inc. Date : 12/15/2007 Channel I (Anions): "0713771-006A:SAMP:ANION30C)—WW" [Row 10] 3.005 I rR > 15.677 mg/L 42 z 39.937 mg/L z CO 0- E z h; 0 0 LL 1,742 mg/L 0.106 mg/L 0.013 mg/L.0..160 MgIL -0.088 mg/LI ......... . ... . . ........ .... . . . ..... 0.219 -- — --- --------- - ------ 123.3 Time (min) 133.8 Channel I (Anions): 110713771-007A:SAMP:ANION300—WW" [Row 111 3.005 2 0 0.219 136.8 0 U- 0.972 mg/L z z E 12 2 0.614 mg/L M Q- \_1.864 Mg0.874 mg/L 0.601 mg/L Time (min) CO 77.020 mg/L 147.3 Run- anions121407 - 7 - IC Author: Omnion User H2M Labs. Inc. Channel 1 (Anions) : "0713771-007AMS:MS:ANI6N300 WW" [Row 12] 3.005-1 f' 0 0.219 ; ..._...... 150.3 0.086 mg a a� as a) Q E @ N O t m z a. IL0.876 mg/L-0.022 mg/L= 0.124 mg/I Time (min) Channel 1 (Anions) : "0713771-007ADUP:DUP:ANION300 WW" [Row 13] 3. 0 > Date : 12/15/2007 m m M 72.897 mg/L 160.8 163.9 Time (min) 174.4 Run: anions121407 - - 8 - IC Author: Omnion User H2M Labs. Inc. Channel 1 (Anions) : "0713771-008A:SAMP:ANION300_WW" [Row 14] 3.005 0 0.21 y -- --------- .--- .. 177.4 11 0 .o z o - _ s U z 48.1311013 mg/L Channel 1 (Anions) : "CCV:CCV-.anion300 ww" [Row 15] 3.005 - i n_ a� O Z - :D Q) ❑. E m CO O O t M z a 0.313 mg/ -0.008 mg/L -0.1; Time (min) Date : 12/15/2007 a) m S to 65.350 mg/L m a 0 U o- 9.801 rz1lL z rl o ro o II E o ii LL 2�10 z g/L 0 902 m /L m z g 0.934 mg0.889 mg/L 1.371 mg/L 0.219 -..- -- - -- --... - .._.. -- ------ ---- -: ---------- 190.9 Time (min) 2 w 17.052 mg/L 187.9 201.4 Run: anions121407 - 9 - IC Author: Omnion User H2M Labs. Inc. Channel 1 (Anions) : "CCB:CCB:anion300 ww" [Row 16] 3.005 2 0 0.219 -- 204.5 204.5 W v 72 aD Z (DZ "O 'aw 0.016 L3/L � 2 U Z Co Z 0.211 m0.013 mo.019 mg/L -0.020 mg/L Time (min) Channel 1 (Anions) : "0713771-009A:SAMP:ANION300 WW" [Row 171 3.005 a 0 0.219 218.0 Date : 12/15/2007 a a� io X- 0- 0 O a c'n 0.112 mg/L_0.064 mg/L 215.0 or a� Z 0 Z m L N °? a E 120 ° O _ L i Z Co Z d U) 212 mg/L 0.013 mg/0.014 me -0.016 mg/L -0.111 mg/L_0.060 mg/L Time (min) 228.5 Run: anions121407 -10- IC Author: Omnion User 1-112M Labs. Inc. Channel 1 (Anions) : "0713817-001A:SAMP:ANION300_WW" [Row 181 3.005 + � I v 0 U 7.352]! mg/L 1 I a 0 Date : 12/15/2007 ca or M CD ` n 35.594 mg/L {I ° oc F i m z a 0.061 mg/L � 1.053 mg/ -0.021 mg/L -0.123 mg/L 0.219._..._...._ ......... ....__...__.........._..__.._....__._...._...-._............. .... .......... ._..... ,.__....._................._..._..._..__.....__........_....... ....... ..._..._..._....__....... .... _.............._............ .... ....._.........__._._...._..._............._.__.; 231.6 Time (min) 242.1 Channel 1 (Anions) : "0713817-002A:SAMP:ANION300 WW" [Row 191 3.005 0 > 0.219 245.1 2 m a � 41.694 mg/L E CO z N I _ o M z a / 0.371 mg10.021 mg/L -0.115 mg/L/ Time (min) 255.6 Run: anions121407 -11 - IC Author: Omnion User H2M Labs. Inc. Channel 1 (Anions) : "0713817-003A:SAMP:ANION300W W" [Row 20] 3.005..-[ N 0 J a) v `o LL 0.145 `o r U 38.715 mg/L Z d m z °- 11.299 mg/L CD CO L a a CO o O m a 0.110 mg/L—_-O. 126 m Time (min) Channel 1 (Anions) : "0713817-004A:SAMP:ANION300 WW" [Row 21] 3.005 --1 ED 0 Date: 12/15/2007 (D m 81.561 mg/L 269.1 � a o Z a� 0 5.529 _2 i/L E `� o CO 0 u= z m` Z a 8.701 mg/L 1.360 mg/L -0.104 mg1L�\ 0.020 mg/L 0;016 mglL 0.022 mg/E 0.219 u... --- .. _ ..- -- _ .... ... ...... -.... ._ _............... _... -- ....... _ 272.1 Time (min) 282.6 N - O h Run: anions121407 -12- IC Author: Omnion User 1-112M Labs. Inc. Channel 1 (Anions) : "0713817-005A:SAMP:ANION300 WVV' [Row 221 3.005 42 0 0-219 285.7 a) `o L U 38.518 mg/L Z a� E2 2 9- 11.178 mg/L m Z (� L I` Q E O Z M I \ D_ I/L_0.096 mg/L 0_081 mg/L__-O. 126 rr Time (min) Channel 1 (Anions) : "0713771-002A:SAMP:ANION300 WW" [Row 231 Date : 12/15/2007 (D m CO 81.343 mg/L 296.2 3.005 -- a� v `o LL 0 0.016 mg/L a� I � `o r U 12.274 mg/L 9 a� Z a ? o. m Z L CO a. 0.013 mg/1-0.029 me .601 mg/L 0.122 mg/L4 ' 774 mg/L 0.219 ;....... _._... ..... ..... ....._-.... — - _ _--------- - -- 3 00.6 300.6 Time (min) 311.1 Run: anions121407 -13- IC Author: Omnion User H2M Labs. Inc. Channel 1 (Anions) : "0713771-003A:SAMP:ANION300_WW" [Row 241 3.005.- U z 63.2210.013 mg/L 42 6 Date : 12/15/2007 I� i if f I i a� io a 0 19.290 mg/L !� 0.016 mg/L� 0.466 mg/L 0.022 mg/L= 0.124 mg/Ll 0.219 _._ ....... .......... _......... ...._..___-_-.--_------ _.---------._.._.__._..._................._.__..._...--.--......----...._...__-.._.___......_......------.--_--.__...__...__....---.......__-_-------_._.._._...____-. 315.6 Time (min) 326.1 Channel 1 (Anions) : "0713771-007A:SAMP:ANION300_WW" [Row 251 3.005 a� v 0 28.217 mg/L > !!� I� fl a a� a� CO z CL o E o 2 U- I z m Z a. 0.555 mg/L�0.144 mg/L 0.358 mg,0.148 mg/L 0.134 mg/L 0.219..... ...... ---.. -._.....- -- -- -- ---._..._.----- --- -- - -- -- --- --- ---- - --- 330.6 Time (min) Run: anions121407 -14 - 19.248 mg/L 341.1 IC Author: Omnion User 1-12M Labs. Inc. Channel 1 (Anions) : "0713771-007AMS:MS:ANION300 WW" [Row 261 3.005 Date : 12/1512007 z o - s y U z 26.55310.013 mg/L I - a � z CLm v m E 76 L 17.443 mg/L I m z o 0.025 mg/L 0.174 mg/ I 0.021 mg/L -0.123 mg/L� __ 0:21 -._.__.._...--_.-..----_-.._..__......._.. _._. _. _. _._ ... _ -.�. _..__._... 345.5 Time (min) 356.0 Channel 1 (Anions) : "CCV:CCV.anion300_ww" [Row 27] 3.005 0.219 359.1 d U O U 9.909,21/L z N . L z o z n 17.174 mg/L ig/L 0.885 m /L m 9 0.40 m'0_900 mg/L 1.384 mg/L Time (min) 369.6 Run: anions121407 -15- IC Author: Omnion User H2M Labs. Inc. Channel 1 (Anions) : "CCB:CCB:anion300 ww" [Row 28] 3.005 w 0 0.219 . 372.6 Time (min) Channel 1 (Anions) : "0713771-007ADUP:DUP:ANION300 WW" [Row 29] 3.005-.- 2 .005- w 0 0.219 .__....-.... 387.6 Date : 12/15/2007 0_ m r a� CL O L 7 a cn .022 mg -0.109 mg/L_0.062 mg/L 383.1 � z v `o — t U z 26.536 10.013 mg/L I n. a� CO w N Z n m a <n 15 E `� t 17.678 mg/L U m z o 0.046 mg/L 0.177 mg/L-0.021 mg/L -0.120 mg/L--,/ Time (min) 398.1 N r O r4 C/) N Run: anions121407 -16- IC Author: Omnion User H2M Labs. Inc. Date : 12/15/2007 Channel 1 (Anions) : "0713771-008A:SAMP:ANION300_WW" [Row 30] 3.005 - _I N O i U n. y 9.154mZL W Z r w v � � o E 2 o 0 _ 14.372 mg/L LL I I z CO z a / 0.089 mg/L 0.013 mg/1-0.071 mg/W.018 m Y�crL-0.122 mg/LJ ,_. 0.219 _ -- - ---....--- .............._.. —_ -- ..._....- ..... -- _.._._.....-- -----._....------ 4 ..._ _.....__._.........._._.._._.....__........__._.........._............__...._..........................._........_i 402.6 Time (min) j 413.1 Channel 1 (Anions): "0713817-002A:SAMP:ANION300W W" (Row 311 3.005---,l 0 i '.I 0.219- - .219 - 417.6 0o Z c d o - L U Z 15.648 r0.013 mg/L M Z v m 0 0 E ro 0 LL CO Z 0.041 mg/L 0.077 mg/1-0.012 Time (min) a m m � t �p a o j_ - IL 7.822 mg/L -0.122 mg/L_�"\ 428.1 Run: anions121407 -17- 1 IC N N O Author: Ornnion User H2M Labs. Inc. Date : 12/1512007 Channel I (Anions): "0713817-003A:SAMP:ANION300—WW" [Row 32] 3.005- 9 lq* Z W 7.260 i /L E z 0 CL ME U) 21,206 mg/L U- z ca 1.866 mg/L 0.081 mq/L 0.030 mg/L 0.036 mg/L,_-O. 125 mg/Lj\,--: 0.219-=------•--_..__-__ . ..... I ---- - ------------- -- ---- . ...... . - . ...... . ... . ........... 432.6 Time (min) 443.1 Channel I (Anions): "0713817-005A:SAMP:ANION300—WW' [Row 33] 3.005 0.219 447.5 Run: anions121407 C_ (D EO M O Z 0- 10.010 mg/L 0.027 rn�.871 mg/L -0.125 mg/L—/\— .... . ........ ... Time (min) 458.0 C) IC Author: Omnion User H2M Labs. Inc. Date : 12/1512007 Channel 1 (Anions) : "CCV:CCV:anion300 ww" [Row 34] 3.005 -: 1 1 m -o `o r a U °? 9.853 rZi/L Z @ m CD r `o U LL Z o z a 17.066 mg/L 2.125 mg/L 0.876 m /L m mg/L mg0_901 mg/L 1.379 mg/L 0.219-�-•___.__....--�__._—_._.__..__.------�----_--...----____--------- ------------_--._.__._------...-------------------------...------.._._..___..._____-_---.-----i 461.4 Time (min) 471.9 Channel 1 (Anions) : "CCB:CCB:anion300 ww" [Row 35] 3.005 0.219 475.0 Time (min) . 485.5 Run: anions121407 -19- IC Author: Omnion User 1-12M Labs. Inc. Date : 1211512007 Table 1: Chloride Figure 1: Chloride 2.119 Height = - 0.000 * Cone2 + 0.053 * Cone - 0.007 Cone = 2.391 * Height^2 + 18.025 * Height + 0.160 S Correlation Coefficient (r) = 0.99983 o, 1 /x weighting Y l9 G) a Chloride concentration, mg/L 50.000 Table 2: Bromide Known Cone. (mg/L) I Re I P Peak Area (V.min) Peak Height (V) %RSD I %Residual Det. Cone. (mg/L) Detection Date .Detection Time 1 50 000 { 1 0.341 2.119 ( 0.0 1.2 49.095 12/13/2007 4:49:04 PM �1 1 2 l 25.000 1 1 0.161 1.230 { 0.0 -2.8 25.942 12/13/2007 5:02:35 PM 3 { 20.000 j 1 ( 0.126 { 1.007 0.0 -3.2 20.736 i 12/13/2007 I 5:16:07 PM 4 10.000 1 0.058 0.498 0.0 1.3 9.737 112/13/2007 ( 5:29:39 PM 5 5.000 { 1 0,026 0.228 1 0.0 10.4 4.390 12/13/2007 5:43:11 PM 6 1.000 1 0.005 0.040 0.0 13.9 0.879 12/13/2007 5:56:44 PM 7 0.000 f 1 0.001 0.003 I 0.213 12/13/2007 6:10:17 PM Figure 1: Chloride 2.119 Height = - 0.000 * Cone2 + 0.053 * Cone - 0.007 Cone = 2.391 * Height^2 + 18.025 * Height + 0.160 S Correlation Coefficient (r) = 0.99983 o, 1 /x weighting Y l9 G) a Chloride concentration, mg/L 50.000 Table 2: Bromide Figure 2: Bromide 0.05C Height = 0.009 * Cone - 0.000 / Cone = 105.446 * Height + 0.014 S Correlation Coefficient (r) = 0.99968 m 1/x weighting Y c0 Q7 a Bromide concentration, mg/L 5.000 Run: anions121407 -20- IC Known Conc. (mg/L) Rep Peak Area (V.min) Peak Height (V) %RSD %Residual Det. Cone - (mg/L) Detection Date Detection Time 1 5.000 1 0.010 0.050 0.0 -5.7 5.265 12/13/2007 4:49:04 PM 2 2.500 1 0.004 1 0.023 0.0 3.7 2.401 12113/2007 5:02:35 PM 3 2.000 1 0.003 0.018 0.0 4.1 1.913 12/13/2007 5:16:07 PM 4 1.000 1 0.002 0.009 0.0 1 7.2 0.926 1 12/13/2007 1 5:29:39 PM 5 0.500 1 0.001 0.004 0.0 7.6 0.462 12/13/2007 5:43:11 PM 6 0.100 1 0.000 0.001 0.0 I 2.9 0.098 12/13/2007 5:56:44 PM 7 0.000 1 1 0.000 0.000 0.020 12/13/2007 1 6:10:17 PM Figure 2: Bromide 0.05C Height = 0.009 * Cone - 0.000 / Cone = 105.446 * Height + 0.014 S Correlation Coefficient (r) = 0.99968 m 1/x weighting Y c0 Q7 a Bromide concentration, mg/L 5.000 Run: anions121407 -20- IC r1W-41P Mw -5S Mw- 4D �� s(�tZ Author: Omnion User H21VI Labs. Inc. Date : 12/20/2007 Original Run Filename: OM_12-19-2007_03-13-48PM.OMN created 12/19/2007 3:13:48 PM Original Run Author's Signature: [Omnion User] Current Run Filename: anions121907.omn last modified 12/20/2007 7:30:47 AM Current Run Authors Signature: [Omnion User] - ELS' Description: Default New Run 4;;i ,�o� . ;sE /yo67 [.xa_ 71.9 1-"j. G/v 4 Sample Channell Channell Chloride Concentration Units Chloride I Sulfate ADF MDF Cup No. Conc. Area Conc. Area (mg/L .min (mg/L) (V.min) Clear Calibration Force Through Zero "LCS-121907:LCS:Anion300 WW' 1 9.230 0.056 9.014 0.035 False Known Conc: 10.000 4L'/. 10.000 o' . 10-510-00-1-A 1 10-510-00-1-A "ICB-121907:iCB:anion300 ww" 1 2 0.146 0.001 00.038 0.000 1451 Known Conc: 0.000 Z2.0 0.000 LS.o "lfb-121907:lfb:anion300 ww" 1 3 9.122 0.055 9.302 0.036 Known Conc: 10.000 Cit.)- 10.000 ci3• I. "MB-121907:MBLK:anion300 ww" 1 4 0.141 0.001 0.034 0.000 Known Conc: 0.000 L z •0 0.000 41.0 "0713771-OOIA:SAMP:ANION300 WIN" 5 19.042 0.058 52.134 0.107 2.00 "0713771-002A:SAMP:ANION300 WW' 6 59.224 0.193 22.596 0.044 2.00 "0713771-003A:SAMP:ANION300 WW' 7 339.390 0.225 87.748 0.034 10.00 "0713771-004A:SAMP:ANION300 WW' 8 26.016 0.080 50.345 0.103 2.00 "0713771-005kSAMRANION300 WW' 9 308.767 0.473 46.357 0.036 5.00 Calibration: Table/Fig. 1 Table/Fi . 2 "0713771-005A:SAMP:ANION300 WW" 10 340.2821 0.226 45.500 0.017 10.00 "0713771-006A:SAMP:ANION300 WW' 11 15.6161 0.097 36.988 0.159 "0713771-007A:SAMP:ANION300 WW" 12 'NS0126.481 0.1621v:50 81.846 0.065 5.00 "0713771-007Ams:ms:ANION300 WW' 13 jyj, 170.885 0.227 qs . 129.259 0.106 5.00 "0713771-007Adu :du :ANION300 WW" 14 :0(.126.394 0.162 )!oj81.946 0.065 5.00 "CCV:CCV.anion300 ww" S4 9.191 0.056 9.332 0.036 Known Conc: 10.000 Q -(- 10.000 43' (- "CCB:CCB:anion300 ww" 1 S8 0.147 0.001 0.039 0.000 Known Conc: 0.000 12.3 0.000 LS•o "0713771-008A:SAMP:ANION300 WW' 15 43.615 0.053 66.790 0.052 5.00 "0713771-009A:SAMP:ANION300 WW' 16 0.140 0.001 0.041 0.000 "0713817-001A:SAMP:ANION300 WW" 17 7.821 0.047 34.338 0.146 "0713817-001A:SAMP:ANION300 WW" 18 232.672 0.148 30.927 0.012 10.00 "0713817-002A:SAMP:ANION300 WW" 19 74.932 0.252 37.916 0.076 2.00 "0713817-003A:SAMP:ANION300 WW" 20 34.283 0.041 100.546 0.081 5.00 "0713817-004A:SAMP:ANION300 WW' 21 5.572 0.034 7.069 0.027 "0713817-005A:SAMP:ANION300 WW' 22 33.950 0.041 99.449 0.080 5.00 "CCV:CCV:anion300 ww" S4 9.197 0.056 9.387 0.036 Known Conc: 10.000 r,i 1. 10.000 qy' 1. "CCB:CCB:anion300 ww" S8 0.078 0.001 0.040 0.000 Known Conc: 0.000 L'L.o 0.000 G t O Analyte Properties Table for anions 121907.omn Property Channell Chloride Concentration Units Callibration Fit Type Second Order Second Order , Clear Calibration Force Through Zero TrueI False _ True � False Calibration Wei htin 1!x 1/x Auto Dilution Tri _ger False False % of High Standard 1101 110 Quik Chem Method 10-510-00-1-A 1 10-510-00-1-A Chemist 1 Direct/Bipolar I Direct/Bipolar Calibration by Height r- False i False Inject to Peak Start 1451 473 Peak Base Width ; 591 158 Run: anions121907 -1 - Author: Omnion User H2M Labs. Inc. Channel 1 (Anions):"LCS-121907:LCS:Anion300 WW" [Row 1] 2.230 C t U 9.230 Z I/L OrZ CD `o W �' r LL ZCO uCi 2.162 mg/L 2.430 mg/L o Z ii m 2.347 mg/L 2.386 mg/L 351 mg/L 0.221- _.-_-_ __ _.__—_.-_-----------.----___...._.._..._---__ _ ...__. _. �-----•---....__.._.__._._._. 1.7 Time (min) Channel 1 (Anions) : "ICB-121907:ICB:anion300 ww" [Row 2] 2.230--- 0.221 .230_-- 0.221 15.3 Date : 12/20/2007 c'n 9.014 mg/L 12.2 a� o_ E m U) LL o 0 0 0.015-69/1- z m` z S-- in 0.146 mg0A15 mg/L 0.017 mg/L-0.029 mL -0.085 mg/L_0.038 mg/L____ Time (min) 25.8 Run: anions121907 - 2 - IC t-- C) `O E Author: Omnion User H2M Labs. Inc. Channel 1 (Anions) : "lfb-121907:lfb:anion300_ww" [Row 31 2.230 0 Date: 12/20/2007 v_ `o U 9.122 mg/L a z z U1 d L w CL = E m M 3 0 0.823. ...... mg/L 0.874 mg/L 03 z 9.302 mg/L J� 0.936 m50.849 mg1L 0.899 mg/L 0.221 .....-_...... _._,._.._ ._...._..._...._.-- ._..._._._....---..... _-- ..... ...... .......... _-......... _ T_...... ... _........ ..----- ---------- ._ -...- - 28.8 Time (min) 39.3 Channel 1 (Anions) : "MB-121907:MBLK:anion300 ww" [Row 4] 2.230 0 0 0.221 42.3 z CO ci Z a w a a� E m 0 ° 0 0 U 3/L z m z a con 0.141 mg/L 0.01;.10.013 mg/L -0.026 mg/I-0.058 mg/L ._0.034 mg/L__ Time (min) 52.8 Run: anions121907 - 3 - Ic 00 kn N O F-, Author: Omnion User H2M Labs. Inc. Channel 1 (Anions) : "0713771-001A:SAMP:ANION300 WW" [Row 5] 2.230 - N UI a `o L U 9.521 mg/L i z z LL z CO 1.079 mg/L 0.1 mg/L_0.012 mg/L0.025 mgfL 0.221 •---------..-_.............----___............__...._.._--.._..-----------____._.._....__---_ __ ----.._._.._,.�._.._.. 55.9 Time (min) Channel 1 (Anions) : "0713771-002A:SAMP:ANION300 WIM' [Row 6] 69.4 29.612 mg/L z p a) � o M Z z 1.499 mg/L 0.012 mg/10.035 mg/L Time (min) Date : 12/20/2007 m m n N CO .r- 26.067 mg/L 0. w 0 a -0.073 mg/L 66.4 a d 0 CO .C -- CL U U, a 11.298 mg/L -0.086 mg/Lj\ 79.9 Run: anions121907 - 4 - IC N CD C/1 F-+ Author: Omnion User H2M Labs. Inc. Channel 1 (Anions) : "0713771-003A:SAMP:ANION300 WW" [Row 7] 2.230 0.221 -- 82.9 a) z — ar t 0 z 33.939 r0.012 mg/L or v a� o a� La LL a o 0.015 mg/L 2 z _0.243 M&0.027 mg/L 0.081 Time (min) Channel 1 (Anions) : "0713771-004A:SAMP:ANION300 WW" [Row 8] 2.230 0.221 96.4 Date : 12/20/2007 8.775 mg/L 93.4 N "O O L U 13.008 mg/L - m z m I 2 a CO z a 25.172 mg/L CL o w E 4.896 mg/o z 2 0.015 mg/L�� 96 mg/L 0.072 mg/L 0.075 mg/L&-- - Time (min) 106.9 Run: anions121907 - 5 - Ic Author: Omnion User H2M Labs. Inc. Channel 1 (Anions) : "0713771-005A:SAMP:ANION300 WW" [Row 9] 2.230 0.221 110.0 Date 12/20/2007 Time (min) Channel 1 (Anions) : "0713771-005A:SAMP:ANION300_WW' [Row 101 2.230 0.221 123.5 a� v `o r U 34.028 mg/L 120.5 a a � o z v o 5 w U- _ E 6 o 0 0.015 mg/L z m` z a 4.550 mg/L 0.012 mg/L0.132 mg/I 0.028 mg/L 0.083 mg/L_-,---- ------------- Time (min) 134.0 Run: anions121907 - 6 - IC Author: Ornnion User H2M Labs. Inc. Channel I (Anions): "0713771-006A:SAMP:ANION300—WW"[Row 11] 2.230 ---- 0 > 15.616 mg/L '0 W S CU CL E z 0 1.673 mg/L a- mg/L--___2._012mg/L0L149 mg/L -0.050 mg/L 0.221- ............ ... ... ... ..... -.7 .. ............ 137.0 Time (min) Channel I (Anions): "0713771-007A:SAMP:ANION300—WW" [Row 12] 2.230 -] CD z 25.296 0.012 mg/L 0 U- 0.021 mg/L . . .......... ... 150.5 Date : 1212012007 36.988 mg/L 147.5 ID w E 0 16.369 mg/L 0 -C L 2 CL 0.176 Mgl1-0.027 mg/L-0.087 mg/Li\"--, Time (min) 161.0 Run: anions121907 - 7 - IC Author: Omnion User H2M Labs. Inc. Channel 1 (Anions) : "0713771-007Ams:ms:ANION300_WW" [Row 131 2.230- 2 .230- 0.732 rr 0.221 -=---... 164.0 m v `o r U 34.177 mg/L a z z m o . E (` N z 2 O I/L 0.785 mg/L 00 0. 0 835 m /L . ��1.094 mg. _ g _832 Time (min) Channel 1 (Anions) : "0713771-007Adup:dup:ANION300 WIM' [Row 14] 2.230 0.221 177.6 m z �o L U z 25.279 X0.012 mg/L W a) z O :O N o I E m o L m` z ).022 mg/L_ 0.178 m191W.028 mg/L Time (min) Date : 1212012007 25.852 mg/L Q. N N w 7 L (n 0 16.389 mg/L EL \ -0.083 mg/L 188.1 174.5 Run: anions121907 - 8 - IC M N O C/� Author: Ornnion User 1-112M Labs. Inc. Channel 1 (Anions): "CCV:CCV:anion300—ww" [Row 15] 2.230--,.I FA O O 9.191 mg/L z M LL z 2 0.817 mg/L 0.879 mg/L M 0 849 mg/L 0.221 191.1 Time (min) Channel 1 (Anions): "CCB:CCB:anion300—,AW'[Row 16] 2.230-1 49 0 0.221 204.7 Date : 1212012007 a. .A CO C1. CO 0 9.332 mg/L 3.968 mg/L -/\ 201.6 M .2m CL ;5E CO to 0 :3 03/L :ZM z a- W 0.147 mg0.013 mg/L 0.009 mt-0.024 mg/L__-0.074 mgLL_0.039 mg/L Time (min) 215.2 Run: anions121907 - 9 - IC Author: Omnion User H2M Labs. Inc. Date : 12/20/2007 Channel 1 (Anions) : "0713771-008A:SAMP:ANION300 WW" [Row 17] 2.230 a) z a - d , U_ z 8.723 mi0.012 mg/Lz cc a a� I � 9 a in o 13.358 mg/L LL jm z a / 0.015 mg/L : 0.064 mg 0.026 mg/L -0.084 mgiL/ .... 0.221=-------...._----__....___------.._..--------------...._.._._____—__-----------._......_.__-----------____....._.__..._... _... _...------. 218.2 Time (min) 228.7 Channel 1 (Anions) : "0713771-009A:SAMP:ANION300_V\ , [Row 181 2.230 ---. I 0.221 231.7 Run: anions121907 a a� z N O O 3/1- 0 Z m Z a- CO 0.140 mc0.012 mg/L_ 0.010-0.021 mg/L 0.085 m0/L 0.041 mg/L ------.............. _..__.__-____.._.____ __...----_---- _ •. Time (min) 242.2 I i Author: Omnion User H2MI Labs. Inc. Channel 1 (Anions) : "0713817-001A:SAMP:ANION300_\AW' [Row 191 2.230 Date : 12/20/2007 0.221 - 245.3 Time (min) Channel 1 (Anions) : "0713817-001A:SAMP:ANION300_WW" [Row 20] 2.230 0.221 258.8 3.267 mg1L a m Z N Z L N d CL O lfl L z O m` z a 3.ig/L 0.012Emgt-0.027 mg lL -0.087 mg/L__-- mg/L Time (min) 255.8 269.3 Run: anions121907 - -11 - - IC Author: Omnion User H2M Labs. Inc. Channel 1 (Anions) : "0713817-002A:SAMP:ANION300 VWV' [Row 21] -- v Z 2.230 a� `o - U z' 37.4660.012 mg/L S 0 0.221 -!-........_. 272.3 a- Time (min) Channel 1 (Anions) :"0713817-003A:SAMP:ANION300 WVV' [Row 22] 2.230 ---I N O > 0.221 , 285.8 -0.082 Date: 12/20/2007 m U) 18.958 mg/L 282.8 N 'O O N L Q N Z N 7 6.857 M2 /L o d) m CL 0.109 mg/L 19/1- 0 o Z o Ill z m 1.748 mg/L o 0.027 mg/L 0.024 mg/L -0.089 mg/ Time (min) 296.3 Run: anions121907 -12- IC Author: Ornnion User H2M Labs. Inc. Channel 1 (Anions) : "0713817-004A:SAMP:ANION300_WW" [Row 23) 2.230 Date : 12/20/2007 a� v o d L Z d U Q? 5.572mI2F. CO a IM E z t CO U- zm` 1.318 mglL ° 7.069 mg/L 0.015 mg/L_0.012 mg/L0.014 mg/L -0.069 mg/L--,1/\�—_ 4.221_...___.-_..-----._ _..__....._...------._..__-.----...- ..._....... __._...__...._.___....._..-- 299.3 Time (min) Channel 1 (Anions) : "0713817-005A:SAMP:ANION300 WVV' [Row 241 2.230 2 0 0.221 —.-._._..-, 312.9 309.8 v `o m L Uz 2 73 v 6.790 mI/L m ro m N LO 19.890 mg/L U- - 0.015 mg/L Z o z m 1.722 mg/L o L o_ x_0.027 mg/L .... 0.024 mg/L -0.089 mg/Li\",-- Time (min) 323.4 Run: anions121907 -13- Ic 00 N O Author: Omnion User H2M Labs. Inc. Date : 12/20/2007 Channel 1 (Anions) : "CCV:CCV:anion300_wW' [Row 25] 2.230-1 N .D O L U 9.197 mg/L z z 6 01 v � m a2 o E `° O to z m z n 9.387 mg/L 0.818 mg/� J\875 mg/L 0.946 mg0.853 mgiL 0.992 mg/L 0.221 326.8 Time (min) 337.3 Channel 1 (Anions) : "CCB:CCB:anion300_wW' [Row 26] 2.230 — N O e. z 03 LL o 2 E m o m 0 0.015 U 3/L z m` z a_ iq 0.078 mp.014 mg/L_0.010 mg/ -0.028 mg/L -0.075 mg/L_0.040 mg/L 0.221 -i....-....._........_._...... _--...._.. _...._............._..--.....-........... ....._:.__....._......_..----._,_._.._._.__..,._.------._�._....--.___..._..__. --___ _ ...:. --..._.-......_._..._.._... .......... _- 340.3 Time (min) , 350.8 Run: anions121907 -14- IC Author: Omnion User Table 1: Chloride 1-12M Labs. Inc. Date: 12/20/2007 Figure 1: Chloride 0.353 Area = 0.000 * Cone2 + 0.006 * Cone + 0.000 Cone = - 81.740 * AreaA2 + 169.314 * Area - 0.016 c Correlation Coefficient (r) = 0.99989 Z 1/x weighting m a� m ar a Chloride concentration, mg/L 50.000 Table 2: Sulfate Known Cone. (mg/L) Rep Peak Area (V.min) Peak Height (V) % RSD % Residual Det. Cone. (mg/L) Detection Date Detection Time 1 50.000 1 0.353 2.194 0.0 0.9 49.562 12/17/2007 3:49:36 PM 2 25.000 1 0.165 1.301 0.0 -2.6 25.683 1 12/17/2007 4:03:07 PM 3 20.000 1 0.131 1.078 0.0 -3.8 20.715 1 12/17/2007 4:16:39 PM 4 10.000 j 1 0.057 0.516. 0.0 5.0 9.412 12/17/2007 ; 4:3011 PM 5 5.000 1 0.027 0.245 0.0 7.3 4.562 12/17/2007 1 4:43:43 PM 6 1.000 1 0.005 0.042 0.0 10.1 0.896 12/17/2007 4:57:16 PM 7 0.000 1 0.001 1 0.003 i 0.196 12/17/2007 5:10:50 PM Figure 1: Chloride 0.353 Area = 0.000 * Cone2 + 0.006 * Cone + 0.000 Cone = - 81.740 * AreaA2 + 169.314 * Area - 0.016 c Correlation Coefficient (r) = 0.99989 Z 1/x weighting m a� m ar a Chloride concentration, mg/L 50.000 Table 2: Sulfate Figure 2: Sulfate 0.227, 0. Sulfate concentration, mg/L 50.000 Area = 0.000 * Con&2 + 0.004 * Cone - 0.000 Cone = - 201.284 * Area ^2 + 264.960 * Area + 0.031 Correlation Coefficient (r) = 0.99996 1/x weighting Run: anions121907 -15- IC Known Conc. (mg/L) Rep Peak Area (V.min) Peak Height M oda RSD % Residual Det. Conc. (mg/L) Detection Date Detection Time 1 50.000 1 0.227 0.691 0.0 0.3 49.798 12/17/2007 3:49:36 PM 2 25.000 1 0.102 0.327 0.0 0.5 25.023 12/17/2007 4:03:07 PM 3 20.000 1 0.083 0.258 0.0 -3.8 20.735 12/17/2007 4:16:39 PM 4 10.000 1 0.038 0.113 0.0 1.8 9.741 12/17/2007 ( 4:30:11 PM 5 5.0001 0.018 0.055 0.0 4.9 4.692 12/1712007 4:43:43 PM 6 1.000 1 0.003 0.011 0.0 5.7 0.941 12/17/2007 4:57:16 PM 7 0.000 1 0.000 0.001 0.113 12/17/2007 1 5:10:50 PM Figure 2: Sulfate 0.227, 0. Sulfate concentration, mg/L 50.000 Area = 0.000 * Con&2 + 0.004 * Cone - 0.000 Cone = - 201.284 * Area ^2 + 264.960 * Area + 0.031 Correlation Coefficient (r) = 0.99996 1/x weighting Run: anions121907 -15- IC IH2A MAUSg INC. Analyst: Date: /& 20 0% Start time: (3 '30 A0 °. W6m —FSL29— CLIENT SAMPLE ID LAB# MLS USED ABS. DILUTIONS MGR NOTES ICV 1000 MG/1)/ 0. l9 6.�f� x X13 apo Ice 2— Z Z _. Ze__ 2; 0,000 1 ix < /yo , 3 3 —03 2 0,000 /Y < /8O ", •� 4 0. l � I' V A3s 3( /6 q�o9 a ✓: /g; 000 5 s co3G'IIty.000 x18/ <Igo im= c, C2- 0.000 /8' < /10 8 C3 I —co &c-, z 0,062- x/�l o 9 P1 0, DOL? VO < 160 10 — r�bS z 0, 00 ?/ If , Sy /0 'aq yq ^. „ AW O CCV 1000 MG/1 ) W T Y90 973 9� 3 CCB Z 0.06 �o 0,006 /0.vt x/ 2 12V o, 00'.5- � ' <Igo /. 3 I __ 0//(, z 0,012- � J_ .� 4 IyIG' — O/Z z . D iz 5 , 1)9LO K- —Gl.3G 0.00c' 6 W-1 127 000 � o 7 mPV-/S 2 0.000 � o 8 AW -YO I _ 0. 02 3 s 9 " pi- ,o m kyS17 0,636 �. 3 A7162 GCV 1000 MG/1 J. A fol 73 43 /X -3,0 CCB N 0 V) E___( i .� lH2M.tAUS-5 INC.' COD -Analyst: A Date: Start time: CLIENT SAMPLE JD LAB# ffL_S USED ABS. DILUTIONS MGlL NOTES ICV G11 CV I MG/1 MW -9 2>72d7? L /Y. 6 2 3�V� 4 k6p A (fio 38;3 60"_ 0,602- z_ /0 12- 8 9 M hl -bo 2- 0,603 CCV (1000 MG/1) 1 0.260 5603 YL 03 Z EGD 3 ccs 10 GCV (1000 MG/1) 73 >l Z 160 2 r7=GCB _/to Calibration 12/28/2006 2onc abs 0 0 10 0.005 50 0.021 250 0.105 500 0.202 750 0.293 1000 0.398 Intercept (b) -4.715 slope (m) 2632 r 0.9998 TSLO12 W73 COD Calibration 12128106 1100- 1000: y = 2532.2x - 4.715 900 - 800 - 706.- E 600- 000- conc 500 - I—Linear (conc)] 400- 0 300 - 200. -- 104 - 0 -100 42 Absorbance Page 1 of I IH2A 1AM2INC® } Ak" Ala HARDNESS = B x N x 100.000 A Aw - rP. HARDNESS DATE: �?J )) 161 1 ANALYST: TITRANT = G N CLIENT ID LABd# MLS USED A MLS. TITRATED B MG NOTES !o 17 VAI ICV(1000 mg/1) 0 _�j, U'LG ICB (� 0-0 (—s . U 1-ooI a s a_ 1 f os - -om as -3 s2 3.—YOL S_ 3- -16o 4. _VS' --oaf- S f .ri.... 2 Q `• 7. Fo -(?� S_� 30 8 s - S ,� a, �M� 0 X3% 9. #' c4c a y, ! CCV(1000 mg/1) l ; t At) CCB �. JZ,OS67 0 -71.7?} -09L 6td olI ► -Cat a. —60 —Cv? 5. _ Gs - a s_ 1_ g 6. - ��))y� -aec aS Q I 7. 8. 9. I0. CCV(1000 mg/1) (o �UL.✓ j �f� CCB /00 040 �s � P 0082 eW jq-. 4 -�- 9�- iSd q � e;,19 yO Y Author: Omnion User Aco-/ IS z4b 5 �T G�fj^k M„J 3.9 3S 6D 6s 6L G6 A26s,9 rnw-6k H2M Labs. Inc. Date : 12/28/2007 Original Run Filename: OM_12-28-2007_11-13-15AM.OMN created 12/28/2007 11:13:15 AM Original Run Authors Signature: [Omnion User] Current Run Filename: nh3122807a.omn last modified 12/28/2007 12:09:52 PM Current Run Authors Signature: [Omnion User] Description: Default New Run -SZ- 0/2- Sample Cup No. Channe12 NH3Area (mg/L .s Detection Time ADF MDF "CalStd7:ical7:nh3 w" S1 3.000 51.872 12/28/2007@11: 16:58 AM Auto Dilution Trigger "CalStd6:ical6:nh3 w" S2 1.000 17.912 12/28/2007 11:18:10 AM "CalStd5:ical5:nh3 w" S3 0.500 8.883 12/28/2007@11:19:23 AM "CalStd4:ical4:nh3 w" S4 0.200 3.310 12/28/2007@11:20:36 AM "CalStd3:ical3:nh3 W" S5 0.100 1.482 12/28/2007@11:21:49 AM "CalStd2:ical2:nh3 w" S6 0.050 0.801 12/28/2007@11:23:02 AM "CalStdl:icall:nh3 w" S8 0.000 -0.004 12/28/2007@11:24:17 AM "CRA:cra:nh3 w" S5 0.086 1.513 12128/2007@11:25:30 AM Known Conc: 0.100 Calibration: Table/Fig. 1 "LCS-24238:LCS:nh3 W" 1 2 1.124 19.522 12128/2007@11:26:43 AM Known Conc: 1.000 "mb-24238:mblk:nh3 W" 1 -0.017 -0.278 12/28/2007@_l 1:27:56 AM Known Conc: 0.000 "0713771-001B:SAMP:NH3 W" 3 -0.015 -0.241 12/28/2007@11:29:10 AM "0713771-002B:SAMP:NH3 W' 4 -0.018 -0.299 112/28/20070_1 -12/28./2007@11:31:34 1:30:22 AM "0713771-003B:SAMP:NH3 W' 5 25.048 21.747 AM 1 120.00 "0713771-0046:SAMP:NH3 W" 6 0.314 5.469 12/28/2007@11:32:46 AM "0713771-005B:SAMP:NH3 W" 7 39.698 13.791 12/28/2007 11:33:59 AM 1 150.00 "0713771-006B:SAMP:NH3 W" 8 0.175 3.053 12/28/2007 11:35:11 AM "0713771-007B:SAMP:NH3 W" 9 29.972 10.415 12/28/2007@11:36:23 AM 50.00 "0713771-007BMS:MS:NH3 W" 10 35.795 12.436 12/28/2007 11:37:35 AM F50.001 "0713771-007BDUP:DUP:NH3 W" 11 30.074 10.451 12/28/2007@11:38:47 -i-2-/-28/2007@1 AM 150.001 "0713771-008B:SAMP:NH3 W" 12 24.997 43.391 1:39:59 AM 10.00 "CCV:CCV:NH3 W" 32 1.056 18.331 12/28/2007 11:41:10 AM Known Conc: 1.000 "CCB:CCB:NH3 W" S8 -0.007 -0.103 112/28/2007@11:46- 15 AM Known Conc: 0.000 "0713771-009B:SAMP:NH3 W' 13 0.335 5.825 12/28/2007911:46:27 AM "0713817-001 B:SAMP:NH3 W" 14 80.945 28.107 12/28/2007 11:47:40 AM 150.00 "0713817-002B:SAMP:NH3 W" 15 16.970 29.462 12/28/2007@11:48:54 AM 10.00 7'0713817-003B:SAMP:NH3 W' 16 0.255 4.432 12/28/2007@11:50:06 AM "0713817-004B:SAMP:NH3 W" 17 0.003 0.066 12/28/2007@11:51:19 AM "0713817-005B:SAMP:NH3 W" 18 0.008 0.156 12/28/2007@11:52:31 AM "0713840-001A:SAMP:NH3 W" 19 1.881 3.278 12/2812007011:53:44 AM 10.00 "0713840-002A:SAMP:NH3 W' 20 10.686 18.557 12128/2007@11:54:56 AM 10.00 "0713771-009B:SAMP:NH3 W" 21 0.001 0.037 12/28/2007@11:58:57 AM "0713817-003B:SAMP:NH3 W" 22 -0.004 -0.049 T2-/28/2007@1 2:00:10 PM "CCV:CCV:NH3 W" S2 1.035 17.972 12/28/2007 12:01:22 PM Known Conc: 1.000 "CCB:CCB:NH3 W" S8 0.003]::0::0::5:7:'[12/28/2007 12:05:26 PM Known Conc: 0,0001 1 Analyte Properties Table for nh3122807a.omn Property Channe12 NH3 Concentration Units m /L Callibration Fit Type i First Order Clear Calibration True Force Throu h Zero False Calibration Weighting None Auto Dilution Trigger True Run:nh3122807a -1- romer 117% to �o r Zeman a:.qs� Zees, ` ?L- (ov ° 1--a FIA Author: Ornnion User H2M Labs. Inc. Date : 12/2812007 % of High Standard 1001 Quik Chem Method Chemistry Direct/Bipolar Calibration by Height False Inject to Peak Start 49, Peak Base Width 75 Channel 2: Set I of 3 4.648--.. C, F; ce) < z ti F U)S7 9C) Sg Ce) Ce) :r < 3.000 mg/L Cl) 3.083-4 CO d6 ce) M z z < 2 IL id U) A d: (L ce) CO ce) CO :E < � < I-- CO U) (0 C c) CO —C) cli 1.252 rr 0 L U3 C-) 9 6 9 1 CO 0 F; ce) ;z CO — -A Cl) Aj 0.614- 63.9 .614 -63.9 Time (s) 1203.6 Run: 03122807a - 2 - FIA Ce) ce) < z F U)S7 9C) Sg Ce) Ce) :r < Cl) CO d6 ce) M z z < 2 IL id U) A d: (L ce) CO ce) CO :E < � < I-- CO U) (0 C co CO —C) cli 1.252 rr 0 L 1.124 n EL 66 9 6 9 1 Fv� NCl) ;z 0.794 mg/L 0.614- 63.9 .614 -63.9 Time (s) 1203.6 Run: 03122807a - 2 - FIA Author: Ornnion User H2M Labs. Inc. Date 1212812007 Channel 2: Set 2 of 3 4.648 --.- rel <II ca a: z w CO C) z C) < CO < r, (5 CO Mml CQ . . N a —- 3.083- z C) § 'M L p 9 C) C) < z U) A 1 2.5 0 W/L CO co 0 CO < z z C� CL >C) < C) 8 < </L (L (L < V- cr, r- q� Q39 U:E 2 CO C) q 4, (0 I> rnm 1.61 7 q m0 9 E6 :C CD LO C) (D 60 0 Z r- 0 C) 6 1.069 mg/L 1.056 mg/L r- C) a 'Kt r- p hr- I . C) MOO 1,� tz. CO C) z 0.71 00 05 in, g 1 �2 p 0.3 9/ C) 0.255 ma = 0,11V = = 1 13.1 i g/L q1 1 1 11 1 11 F77 0.614-v—, ... ... .. ...... 1203.6 Time (s) 2545.8 Channel 2: Set 3 of 3 4.648-.- 3.0n Cl) Cl) z = M z z 0 0 < < UI n CO 0) Cl) C) C) 1.035 mg/L 0 t- CO CO 01-W 3/1- 0.003 mg/L 0.614 ----- ---- - - 2545.8 Time (s) 3888.0 Run: nh3122807a - 3 - FIA Author: Omnion User Table 1: NH3 H2M Labs. Inc. Date : 1212812007 Figure 1: NH3 51.872 Area = 17.349 * Conc + 0.016 Conc = 0.058 * Area - 0.001 Correlation Coefficient (r) = 0.99988 m No Weighting Al a) N a. NH3 concentration, mg/L 3.000 00 N CD C/] Run: nh3122807a -4- FIA i Kno(L)nc. mg Rep� Pe Area Peak M dRSD %Residual Det. g��c' L Detection Date j Detection Time ( 1 3.000 1 51.872 2.451 0.0 0.4 2.988 12/28/2007 I 11:16:58 AM 2 T 1.000 1 17.912 0.855 0.0 -3.2 1.031 12/28/2007 I 11:18:10 AM 3 0.500 1 8.883 0.424 0.0 -2.2 0.511 12/28/2007 11:19:23 AM 4 0.200 1 3.310 0.158 0.0 5.0 _ 0.190 12/28/2007 ( 11:20:36 AM 5 0.100 1 1.482 0.074 0.0 15.4 0.085 12/28/2007 11:21:49 AM 6 0.050 1 0.801 0.037 0.0 9.3 0.045 ( 12/28/2007 11:23:02 AM 7 0.000 1 -0.004 -0.002 -0.001 18/2007 2/2 11:24:17 AM Figure 1: NH3 51.872 Area = 17.349 * Conc + 0.016 Conc = 0.058 * Area - 0.001 Correlation Coefficient (r) = 0.99988 m No Weighting Al a) N a. NH3 concentration, mg/L 3.000 00 N CD C/] Run: nh3122807a -4- FIA # 1109 Pe?sb. O/Z AMMONIA DISTILLATION NAME.. N►,Si F( V 4/ DATE'. :oo 1l: ot? LAB NO. CLIENT ID SAMPLE WEIGHT GRAMS SAMPLE VOLUME MLS FINAL VOLUME M DATESPIRE ANALYZED VLS ' sO SCJ Uri •ril 15dgb _ S p f,Q -002 b - kLV, 15 - 0f3 �,% - '(p _ ops �,� —, —av6 1u � S _4Q WmcrPP - M w L !^O " IDw - po8 6 wx — SS 81 -� kc to -3 fJ 8 —acv gl -Vqb v le - 6.S ?I?-Oosb K - bo T D "Cal Std 2:ical2:no3 dw" S4 0.100 0.874 1217/2007@11:55:30A "Cal Std 1:ical1:no3 dw" S5 0.0501 0.451 12/17/2007 11:56:44 AM "rad Gtri Nrnln-nn3 dw" I S16 0.000 1 -0.014 12/17/2007011:57:58 AM "LCS-121707:lcs:no3 dw" Calibration: S6 Table/Fig. 1 1.139 9.756 12/17/2007@12:02:36 Author: Omnion User H2M Labs. Inc. Date: 12/17/2007 Original Run Filename: OM_12-17-2007_11-50-34AM.OMN created 12/17/200711:50:34 AM Original Run Author's Signature: [Omnion User] 1.130 Current Run Filename: no3121707.omn last modified 12/17/2007 12:58:44 PM Current Run Author's Signature: [Omnion User] Description: Default New Run t D /Z -0.003 0.002 Channel 2 PM / Sample Cup No. Nitrate as N Conc. (mg Detection Time ADF MDF Area 0.000 12/17/2007@12:23:14 PM N/L .s bS Mme- 11, "Cal Std 5:ical5:no3 dw" S1 2.000 17.070 12/17/2007 11:51:53 AM 3.911 12/17/2007@12:05:04 "r.A Std Alr-qWnn3 dw" S2 1.000 1 8.633 12/17/2007011:53:04 AM 1 S "Cal Std 2:ical2:no3 dw" S4 0.100 0.874 1217/2007@11:55:30A "Cal Std 1:ical1:no3 dw" S5 0.0501 0.451 12/17/2007 11:56:44 AM "rad Gtri Nrnln-nn3 dw" I S16 0.000 1 -0.014 12/17/2007011:57:58 AM F,61ZQJ`P "LCS-121707:lcs:no3 dw" Calibration: S6 Table/Fig. 1 1.139 9.756 12/17/2007@12:02:36 PM -= I ��/L" % /'70--3'.D "0713817-001B:SAMP:NO3 W' Known Conc: 1.130 0.213 12/1712007@12:20:48 PM 3S "MB-121707:mblk:no3 dw" I S16 -0.003 0.002 12/17/2007@12:03:51 PM / "0713817-003B:SAMP:NO3 W' 14 Known Conc: 0.000 12/17/2007@12:23:14 PM 10.00 bS Mme- 11, "0713771 -001 B:SAMP:NO3 W' 1 2.275 3.911 12/17/2007@12:05:04 PM 5.00 Mg -BD 1 S "0713771-002B:SAMP:NO3 W' 2 3.237 5.554 12/17/2007@12:06:17 PM 5.00 if "0713771-003B:SAMP:NO3 W' 3 0.007 0.087 12/17/2007@12:07:30 PM LAS "0713771-004B:SAMP:NO3 W' 4 9.342 8.003 12117/2007@12:08:43 PM 110.00 SZ "0713771-005B:SAMP:NO3 W' 5 0.008 0.092 12/17/2007@-12:09:55 PM 5S "0713771-006B:SAMP:NO3 W' 6 1.763 3.035 12/17/2007@12:11:08 PM 5.00 Known Conc: ! &Z "0713771-007B:SAMP:NO3 W' 7 0713771-0076MS:MS:NO3 W 8 "0713771-007BDUP:DUP:NO3 W' 9 0.017 0.523 0.014 0.169 4.491 0.142 12/17/2007@12:12.2-1 12/17/2007@12:13:33 12/17/2007@12:14:46 PM PM PM Q gS "0713771-008B:SAMP:NO3 W' 10 0.010 0.114 12/17/2007@12:15:58 PM Known Conc: 0-000 "CCV:CCV:NO3 W' S2 0.976 8.361 12/17/2007 12:17:10 PMRe-C, "0713734-001A:SAMP:N2N3 W' 9 Flo 0 0941 0.829 Known Conc: 1.000 I "0713734-002A:SAMP:N2N3 W' 22 ! 0.8441 "CCB:CCB:NO3 W' I S16 -0.003 -0.003 12117/2007@12:18:24 PM 10, "0714057-001A.:SAMP:N2N3 VY" 23 ! F,61ZQJ`P "0713771-009B:SAMP:NO3 W"11 0.009 0.101 12/17/2007@12:19:36 PM ! /'70--3'.D "0713817-001B:SAMP:NO3 W' 12 0.022 0.213 12/1712007@12:20:48 PM 3S "0713817-002B:SAMP:NO3 W' 13 0.018 0.176 12/17/2007@12:22:01 PM (61. "0713817-003B:SAMP:NO3 W' 14 9.783 8.380 12/17/2007@12:23:14 PM 10.00 bS "0713817-004B:SAMP:NO3 W' 15 1.206 2.084 12/17/2007 12:24:27 PM 5.00 Mg -BD "0713817-0056:SAMP:NO3 W' 16 9.209 7.890 12/17/2007@12:25:40 PM 10.00 "0714044-001A:SAMP:NO3 W' 17 0.252 2.179 12/17/2007@12:26:53 PM "0714044-002A:SAMP:NO3 W" 1 18 0.4661 4.004 12/17/2007@12:28 06 PM "0714148-001A:SAMP:NO3 W' 19 1.901 1.648 12/17/2007@12:29:18 PM 1 10.00 "0714148-002A:SAMP:NO3 W' "CCV:CCV:NO3 W' 203.784 S2 1 0.937 3.257 8.032 12/17/2007@12:30:30 PM110.001 12117/2007�a 12.31:42 PM i "'�C q i k Known Conc: ! 1.000 ! ! "CCB:CCB:NO3 W_' I S16 -0.004 -0.007112/17/2007@12:32:56 PM Known Conc: 0-000 "0713734-001A:SAMP:N2N3 W' 21 0 0941 0.829 12/17/2007 12:34:08 PM I "0713734-002A:SAMP:N2N3 W' 22 ! 0.8441 7.229 12/1712007@12:35:20 PM "0714057-001A.:SAMP:N2N3 VY" 23 ! 0.058! 0.524 12/17/2007@12:36:32 PM "0714057-002A:SAMP:N2N3 W' "LFB-121707:LFB:NO3 DW' 1 24 1 i 25 _ 0.738 ! 0.462 6.325 12/17/2007 3.969 , 12/17/2007@12:38:57 12:37:44 PM ! PM j C1 "LFBD-121707:LFBD:NO3 DW' ! 26 ! 0.466 ! 4.007 12/17/2007@12:40:10 PM! 00 "CCV:CCV:NO3 W' ! S2 ; 0.921 ! 7.894 12/17/2007@12:43:34 PM j Known Conc: ' 1.000_ "CCB:CCB:NO3 W' S16 `- - -Known Conc: ! ----- - - - - Analyte Properties Table for no3121707.omn Run: no3121707 -0.0_03 ; -0.002 ! 12/1712007@12:44:48 0.000 - -1 - PM ; r ----____.i - iL D. N ,--i - O tj FIA Author: Omnion User H2M Labs. Inc. Date : 12/1712007 Property Channe12 Nitrate as N Concentration Units mg N/L Callibration Fit Type First Order Clear Calibration True Force Through Zero False Calibration Weighting None Auto Dilution Trigger True % of High Standard 100 Quik Chem Method 10-107-04-1-C Chemist Direct/Bipolar Calibration by Height False Inject to Peak Start 19 Peak Base Width 69 Channel 2 (No2/No3) : Set 1 of 4 3.039 -_- 0 0 0 O o O a c n < CO -� v1 Q M (q N m o 1.139 v1Y r c NIL o n co CO c 1 'n E M o c� C (D O.E 0.455 rit l 0.102 mil N/ � v CO 0 - 1 2.000 M. 0 J/L 2.176 - � U_ .N. c) C CO ri 3 ` 1 1.000 m1 w111- M N rz Cl) ) �p U c U M C) I I 0.500 m1�l1L ca 05 U) V a 0.100 mD 050 m 000 0.756 _._.. 76.0 NIL Time (s) 3 �I 0 O o O a N n < CO -� v1 Q M (q N m o 1.139 v1Y r c NIL o n co CO c 1 'n E M o Eo C (D O.E 0.455 rit l 0.102 mil N/ � m! Q 1/L n 0 O.OQ7,mg NIL 1100.3 Run: no3121707 - - 2 - FIA Author: Ornnion User H2M Labs. Inc. Date: 1211712007 Channel 2 (No2/No3) Set 2 of 4 3.039—,. 0 ce) 2.176 < 0 cr) CO K Ce) 0 0 C) (Y) ?: 0 0 0 Ce) CY) CQ Ce) M 0 :E 0 0 0 0 < ca Z z z z z CO i CL EL 0 0 (0 z < C) < D <CO < ; 0.976 mg NIL I (0 r- 0 CO 0.934 mg TL 6j �2 CO f6 ca 0 00 C) C) C) OC) C) C) 9 0- 9 M 9 9 9 p 0.523 mg WL iz ce) CO 0.353 mg WL CO CO U11! 0 iz 0 j 0 0 0 p CZ) 8.10 08 /L 0.017 rrpi IL 0.014mgOJ(lJQn-,i L .-0.003o rNOf12?mg(W1JJ8mgN/L 0.756 ...... . ...... ... .. ............ .... 1100.3 Time (s) 1971.2 Channel 2 (No2/No3) Set 3 of 4 3.039-1 Cl) 0 0 Cl) z Ce) z EL < 2.176 < U) 0 ce) ce) 6j a. CO z 0 0 M ce) CO z 0 U') C) 0 C) 0 z cr)I C01 -6 h9 0 z z > < n K 9 C14 <U Z z CO �2 < CO < CL r1- < < L) U) CN zo M 0 C) 0 < < — 4 9 q� o 0.978 g OL co 0.137 m, WL < F 0 0.921 m, 1�1- 'C`t:) — 9 0 c) 0.844 mg §L 00 9 A CO v - CO v o , , U r— i is LO 44 P- 0.466 mg RL 8 m NIL 0.37 66 0.241 IT'A/L 0.252 n i /L 0 90 0.1 !.�71: p I., . i - 0.094 �iq! /L 0.058 mg NIL /A , -I, -0.004mg\N/L, !I 0.756 - Ell 1971.6 Time (s) 2841.7 Run: no3121707 - 3 - FIA N 00 O Author: Omnion User Channel 2 (No2/No3) : Set 4 of 4 1-12M Labs. Inc. Date: 12117/2007 3.039 - Known Conc. (mg N/L) Rep Peak Area (V -s) Peak Height M % RSD % Residual Det. Conc. (mg N/L) Detection Date z N 1 2.000 2.176-- Z a 0I 0.0 0.2 pl O Z MI O N QQ U No Z p m Z U 0.715 o m -0.8 U 12/17/2007 J 0 0 ti U 1 4.308 0.358 0.0 -0.3 N P r '- 0.921 mg N/L o0 4 0.738 mg i�L LL m z 0.073 1 0.5 ! m t 0.462 m 0Jit66 mg N/L j U 1 0.451 0.039 ! m 0.1 0.050 12/17/2007 , 0.756 j 1 I - 3 mg N/L 0.00 ...... ...... _... ....--......._....... _...... 2842.1 Time (s) 3712.2 Table 1: Nitrate as N Figure 1: Nitrate as N 17.07Q Nitrate as'N concentration, mg N/L 2.000 Area = 8.541 Conc + 0.025 Conc = 0.117 ` Area - 0.003 Correlation Coefficient (r) = 0.99998 No Weighting M 00 N O h Run: no3121707 - 4 - FIA Known Conc. (mg N/L) Rep Peak Area (V -s) Peak Height M % RSD % Residual Det. Conc. (mg N/L) Detection Date Detection Time 1 2.000 1 17.070 1.404 0.0 0.2 1.996 12/17/2007 11:51:53 AM 2 1.000 1 8.633 0.715 0.0 -0.8 1.008 12/17/2007 11:53:04 AM 3 0.500 1 4.308 0.358 0.0 -0.3 0.502 12/17/2007 11:54:17 AM 4 0.100 1 0.874 0.073 0.0 0.5 0.099 12/17/2007 11:55:30 AM 5 0.050 1 0.451 0.039 0.0 0.1 0.050 12/17/2007 11:56:44 AM 6 0.000 1 -0.014 -0.002 -0.004 12/17/2007 11:57:58 AM Figure 1: Nitrate as N 17.07Q Nitrate as'N concentration, mg N/L 2.000 Area = 8.541 Conc + 0.025 Conc = 0.117 ` Area - 0.003 Correlation Coefficient (r) = 0.99998 No Weighting M 00 N O h Run: no3121707 - 4 - FIA � - �.�...., Lei: 1 .,�;,�• :,n��+';.' � � �`�I O. vt ,s � • /02 0.000 1S:O ,1s•p Phenols Method 420.1 Distillation Date: l,2-,�v-o Time: 10:ao PC rsL otz v+mO AMi UG/L DILUTION UG/L MG/KG USED %TS NOTES/CALCULATIONS .Z 29.2 O. vt ,s � • /02 0.000 1S:O ,1s•p 0.0,02-- .0020. 0.0 Of 0.00,5- .00 0.001 0.00 ^.0 1S 0 O. 00 0.00.2„ 0.003 4S.0 ts.9 0.0Y_ 12.2- l P&'^ : mo 0.0Fj 2 P? - 2- 9;1. 3 o. 000 O /_x.0 c9.40oZ cS.p �s •o p�Jziq/ 0. 00.E .t .s^.,p .Zs. •D ' 0.00 is'. 0 ��rJ O.00t 4r.10 0.00 AS 10 0.00( ,lS:O "r.o 69. 0 G o.o�-t z9•z •Z 9�• . 0.4000 1S'.0 ,(S 0 Phenols P 0081 TSLO12 W84 I Calibration 6-25-07 conc abs 0 0.000 1 0.002 2 0.003 5 0.01 10 0.02 20 0.050 30 0.072 40 0.098 50 0.123 Intercept (b) slope (m) r TSLO12 W85 0.6807 401.78 0.9994 Phenol Calibration 6/25/07 60 50 — 01.78x + 0.6807 40 J z ♦ conc 30 Linear (conc) c 0 v 20 10 - Z' 0 0.000 0.050 0.100 0.150 Absorbance Page 1 of 1 SOLIDS [{Dried Wt (q) -Tare Wt (g))X10001x1000 (O;S/ TS ©� �— Solids(mg/I)= mL Sample ANALYST; TEMP. 20,8 .— f7U DATE: /� LAB # di CLIENT ID START: % PAN/ CRUC. ' -/,) IIUMIUI SAMPLE ML I T: DRIED WT G TARE WEIGHT G SOLID WEIGHT G RESULT MG/L DRIED WT G IGNITED WT G VOL. WT G - VOLA E . (MGiL) Tip 3� 2 /u /-o Q'.D 63 8� /�yU,�B3 %3. ?2 D02L a,,06 o. ol��' zgv g� >� 73y 7/� -�Il� -Gi)L v PqiL-0/A S -P gym✓ 108 ty6yl lb , p3o3 o•o1/Z � 0 713�3�7-op! �8y Go /06,2.5'/ / 0-)l3 , oo� 6pC, /oy.O.S O 10yoft d .w -7Y - � AL AV /� lis ys�� d 1 0677 T� j06 7 0, 04 0•07 -7 a W TSLO12 W86 Is ENO MWM ``PMM® rl� ..e. ham, f W`3 �t fel �ixh x e.'d . ({Dried Wt (g) - Tare Wt. (g))X1000)X1000 Solids(mg/l)= mL Sample ANALYST: 8 '" TEMP. 4OLIDS D � SS( TS I DATE: k�Ja START: SAMPLE ML HUMIUi I r: DRIED r— G /U TARE WEIGHT G SOLID WEIGHT G OZ70 RESULT MGIL a7f I�G, DRIED WT G bso IGNITED WT G VOL. WT G VOLA rn R (MGIL) LAB # CLIENT ID PAN/ CRUC. ( ail A6,. 271 �z3.32,� figo %2 3 Z �`l�' ®. o far` 17f fey /0/ 3d z 2 S —O A- M �l `�S L 990 �' /6Z.Zt� ��'3, y3 D 9 id y q -5v /Z�'.Zv P2:7-3 �.ol�� 0,033 .o�3� 1o�v /y7 /2�� Tv �D �.�90 2 -Z° 1. 2 � Iv, 50 0 , �2� l'D 6.3 1 6.0337 6?L _ v�P v ►"sv S� TSLO12 W87 IMUM ® _ _ . SOLIDS HDried Wt (4) -Tare Wt. (a))x1000lx1000 TD / SSI TS Solids(mgll)= mL Sample ANALYST: TEMP. DATE: J2 o START: HUMIDITY: DRIED TARE SOLID IGNITED VOL. VO LE PAN! SAMPLE LAB # CLIENT ID CRUC. WT G WEIGHT G WEIGHT GWT EDRIED G WT G WT G S. (MGIL) ml /oy.a3�i` azo ,a /07. o�D Q o7�9 73 p. OL -? C/o 7l�os� w L V (A� � j2bS n� y� /OS, 3 000/ c/a 03.736 ODIC -0)2A ��=� fAA Mc Sa os STl Ion o. o2z� ys� � yo � 67 Oyu /07 � 0,0117 //7 7%12919s6 " ©.030 307 SZ v av s �'M 0703 z . %0 3 p, 02�,� � 2 F �7.6w - 50 TSLO12 W88 Effective immediately, when analyzing any matrix other than potable water for TDS, please take the conductivity of the sample and record it in the last column of the logbook. Please use the following guide for dilutions based on the conductivity. READING ON CONDUCTIVITY METER MLS OF SAMPLE TO USE On C up to 200/ on D under 800 100 mis Over 800 on D/up to 2.00 -on E 50 mis On E from 2.00 to 5.00 25. mis 4n E from 5.00 to 8.00 20 mis Anything past 8.00 on E to F 10 mis On F reading of 20 or higher 5 mis for 25 or lower 1 ml for 25 or higher All potable water samples should be analyzed at 100 mis. For fresh kills total and filtered samples use the same amount of sample volume for both sets of samples. TSLO12 W89 (,j -# Z-70-7 R- TSLoIZ -7 10i . n D _ Liu --4+ �j�� . ,, Q "' " �-o I zb 2 b ego I 269 I'K:N Data Concentration listed after Optical Blank Correction. Preparation dilution factor not applied to results. Peak SampleID SampTy Cone Units DF Cone x DF AnalDate AnalTime TestCod 1 Primer PRIM 3.01 mg/l 1 3.01 12/20/2007 10:09:23 AM tkn_w 2 Drift DRIF 3 mg/l 1 12/20/2007 10:10:02 AM tkn_w 3 High HIGH 3.01 mg/I 1 3.01 12/20/2007 10:10:43 AM tkn_w 4 Low LOW 0.05 mg/I 1 0.05 12/20/2007 10:11:20 AM tkn_w 5 Low LOW 0.05 mg/I 1 0.05 12/20/2007 10:11:51 AM tkn w 6 Cal. CALB 3.02 mg/I 1 3.02 I2/20/2007 10:12:43 AM tkn-w 7 Cal. CALB 0.96 mg/I 1 0.96 12/20/2007 10:13:24 AM tkn w 8 Cal. CALB 0.47 mg/I 1 0.47 12/20/2007 10:14:03 AM tkn-w 9 Cal. CALB 0.19 mg/I 1 0.19 12/20/2007 10:14:41 AM tkn_w 10 Cal. CALB 0.09 mg/I 1 0.09 12/20/2007 10:15:21 AM tkn-w 11 Cal. CALB 0.03 mg/I 1 0.03 12/20/2007 10:15:59 AM tkn_w 12 OPTICAL BLK QUAL 0.7 mg/l 1 0.7 12/20/2007 10:16:44 AM tkn_w 13 LCS-24152 Wz.11 a'16I L Ics 0.387 mg/I 10 3.87 12/20/2007 t7'/. 10:17:23 AM tkn-w 14 MB -24152 mblk 0.01 mg/I 1 0.01 12/20/2007 40.1 10:18:03 AM tkn_w 15 0713771-OOIB hW - lib SAMP 0.19 mg/I 1 0.19 12/20/2007 10:18:43 AM tkn_w 16 0713771-002B M W - 15 SAMP 0.18 mg/I 1 0.18 12/20/2007 10:19:23 AM tkn_w 17 0713771-003B A w _ y -b SAMP 3.43 mg/I 5 17.15 12/20/2007 10:20:04 AM tkn w Q¢n,n pjv-"C%,(, 18 0713771-004B M W - 4$ SAMP 0.189 mg/I 20 3.78 12/20/2007 10:20:40 AM tkn_w 19 0713771-005B kw " 5 � SAMP 1.2584 mg/I 50 62.92 12/20/2007 10:21:23 AM tkn_w 20 0713771-006B h W - 5S SAMP 0.4 mg/I 1 0.4 12/20/2007 10:22:03 AM tkn_w 21 0713771-007B t'` W - 19 � SAMP 0.8598 mg/I 50 42.99 12/20/2007 10:22:42 AM tkn w 22 07I3771-007BMS 'TV:- (4-0mj1,j ms 0.9356 mg/1 50 46.78 12/20/2007 10:23:23 AM tkn_w 23 0713771-007BDUP dup 0.8592 mg/1 50 42.96 12/20/2007 AtD= 01 10:24:03 AM tkn w 24 0713771-008B M W - $ 5 SAMP 2.0115 mg/l 20 40.23 12/20/2007 10:24:43 AM tkn_w 25 CCV 1.0 ccv 1.03 mg/l 1 1.03 12/20/2007 /031• 10:25:23 AM tkn_w 26 CCB ccb 0.04 mg/1 1 0.04 12/20/2007 4O.1 10:26:00 AM tkn_w 27 0713771-009B F� tZ�°s("� SAMP -0.02 mg/I 1 0.02 12/20/2007 10:26:43 AM tkn_w 28 0713817-OOIB hw -3'C' SAMP 1.215 mg/I 100 121.5 12/20/2007 10:27:23 AM tkn_w 29 0713817-002B M W 3 SAMP 1.3015 mg/1 20 26.03 12/20/2007 10:28:04 AM tkn_w 30 0713817-003B Mk% 67 SAMP 0.14 mg/I I 0.14 12/20/2007 10:28:41 AM tkn-w 2/20/2007 11:46:22 AM Pagel of 3 Peak SampleID �p�� E SampTy Cone Units DF Cone x DF AnalDate AnalTime TestCod tkn_w 36 0714238-004B LP+`^�`� SAMP 0.04 mg/l 1 0.04 31 0713817-004B h'1 W - b$ SAMP 0.63 mg/l 1 0.63 12/20/2007 10:29:23 AM tkn_w 32 0713817-005B 10:33:24 AM SAMP 0.14 mg/l 1 0.14 12/20/2007 10:30:03 AM tkn w 33 0714238-OOIB 10:34:04 AM SAMP 0.018 mg/l 5 0.090000000 12/20/2007 10:30:44 AM tkn_w u4 G 12/20/2007 10:34:43 AM tkn w 40 0714238-006B 43.3 SAMP 0.4 mgfl 5 34 0714238-002B ckc-t- l� SAMP 0.01 mg/l 5 0.05 12/20/2007 10:31:20 AM tkn_w ' 35 0714238-003B �p�� E SAMP 0.03 mg/l 1 0.03 12/20/2007 10:32:03 AM tkn_w 36 0714238-004B LP+`^�`� SAMP 0.04 mg/l 1 0.04 12/20/2007 10:32:43 AM tkn_w 37 CCV 1.0 ccv 1 mg/l 1 12/20/2007 /W'E 10:33:24 AM tkn_w 38 CCB ccb 0.04 mg/l 1 0.04 12/20/2007 40-1 10:34:04 AM tkn_w 39 0714238-005B _ ��kr 35.5 SAMP 0.534 mg/l 5 2.67 12/20/2007 10:34:43 AM tkn w 40 0714238-006B 43.3 SAMP 0.4 mgfl 5 12/20/2007 10:35:23 AM tkn_w 41 0714238-007B Sl: ( SAMP 0.492 mg/l 5 2.46 12/20/2007 10:36:03 AM tkn_w 42 0714238-008B 15'9. q SAMP 0.426 mg/l 5 2.13 1.2/20/2007 10:36:43 AM tkn_w 43 0714238-009B 64.1 SAMP 0.404 mg/l 5 2.02 12/20/2007 10:37:22 AM tkn w 44 0714238-OIOB ��' S SAMP 0.456 mg1l 5 2.28 12/20/2007 10:38:03 AM tkn_w 45 0714325-OOIB OZ 1-4- SAMP 0.42 mg/l 5 2.1 12/20/2007 10:38:44 AM tkn_w 46 0714325-002B G A -C 1-1. SAMP 0.442 mg/l 5 2.21 12/20/2007 10:39:24 AM tkn_w 47 0714325-003B L• ei-` - 751K SAMP 0.03 mg/l 1 0.03 12/20/2007 10:40:02 AM tkn w 48 0714325-004B L P�d� �` �" SAMP 0.02 mg/l 1 0.02 12/20/2007 10:40:43 AM tkn_w 49 CCV 1.0 cev I mg/l 1 12/20/2007 MY(- 10:41:23 AM tkn w 50 CCB ccb 0.03 mg/l 1 0.03 12/20/2007 ". ( 10:42:00 AM tkn_w 51 0714325-005B p i'►tr.t-kr SAMP 0.43 mg/l 5 2.15 12/20/2007 10:42:43 AM tkn_w 52 0714325-006B /35.6 `r3'3 SAMP 0.474 mg/l 5 2.37 12/20/2007 10:43:18 AM tkn_w 53 0714325-007B S/. SAMP 0.408 mg/l 5 2.04 12/20/2007 10:44:02 AM tkn_w 54 0714325-008B 58.9 SAMP 0.438 mg/l 5 2.19 12/20/2007 10:44:44 AM tkn_w 55 0714325-009B 4 V7 SAMP 0.416 mg/l 5 2.08 12/20/2007 10:45:22 AM tkn_w 56 0714325 -OI OB 7Y. S SAMP 0.404 mg/l 5 2.02 12/20/2007 10:46:02 AM tkn_w 57 LFB-24152 �%� `'f D''Slt. Ifb 0.383 mg/l 10 3.83 12/20/2007 961. 10:46:42 AM tkn_w 58 LFBD-24152 Itbd 0.382 mg/I 10 3.82 12/20/2007 lam= 0.1- 10:47:23 AM tkn_w 59 CCV 1.0 ccv 1.01 mg/l 1 I.O1 12/20/2007 /of'( 10:48:03 AM tkn_w 60 CCB ceb 0.04 mg/l 1 0.04 12/20/2007 Lo.( 10:48:41 AM tkn_w 61 Drift DRIF 3 mg/l 1 12/20/2007 10:49:23 AM tkn_w 2/20/2007 11:46:22 AM Page 2 of 3 ' PPak gmmnlPm 62 End SampTy Cone Units DF Cone x DF AnalDate AnalTime TestCod END 0.03 mg/l 1 0.03 12/20/2007 " 10:51:09 AM tkn_w ,.2/20/2007 11:46:22 AM Page 3 of 3 BRAN+LUEBBE RACE 5.48 H2M Labs Inc. Post -run report Name of Run tknl22007R1 Name of Analysis :TKN.ANL Date of Report 12/20/2007 System No. :1 Date of Run 12/20/2007 Type of System :TRAACS Operator Cmo Start/Stop time :09:58 - 10:51 Comment #24152 Channel Type Real Data Channel 2 2 Method Method 2 Dilution Unit mg/l mg/1 Calibr. Fit Linear Corr. Coeff. 0.9996 Base 76 Gain 25 Sensitivity 0.4188 Sample Limit 1 Sample Limit 2 ( �� Pk Cup Sample Id Value Val e 0 0 B Baseline 0.03 0 1 1 P Primer 3.01 1 2 1 D Drift 3.00 1 3 1 H1 High 3.01 1 4 0 L1 Low 0.05 1 5 0 L1 Low 0.05 1 6 1 C Cal. 3.02 1 7 2 C Cal. 0.96 1 8 3 C Cal. 0.47 1 9 4 C Cal. 0.19 1 10 5 C Cal. 0.09 1 11 0 C Cal. 0.03 1 12 8 QC1 OPTICAL BLK 0.70 1 13 9 QC1 LCS-24152 4.57 10 14 10 QC1 MB -24152 0.71 1 15 11 S 0713771-OOIB 0.89 1 16 12 S 0713771-0028 0.88 1 17 13 S 0713771-003B 17.85 5 18 14 S 0713771-004B 4.48 20 19 15 S 0713771-OOSB 63.62 50 TKN.ANL / tknl22007R1.run Page 1 Post -run Report BRAN+LUEBBE AACE 5.46 20 16 S 0713771-006B 1.10 21 17 S 0713771-007B 43.69 22 18 S 0713771-007BMS 47.48 23 19 S 0713771-007BDUP 43.66 24 20 S 0713771-008B 40.93 25 2 QC1 CCV 1.0 1.03 26 0 QCl CCB 0.04 27 21 S 0713771-009B 0.68 28 22 S 0713817-001B 122.20 29 23 S 0713817-002B 26.73 30 24 S 0713817-003B 0.84 31 25 S 0713817-004B 1.33 32 26 S 0713817-005B 0.84 33 27 S 0714238-00113 0.79 34 28 S 0714238-002B 0.75 35 29 S 0714236-003B 0.73 36 30 S 0714238-004B 0.74 37 2 QC1 CCV 1.0 1.00 38 0 QCl CCB 0.04 39 31 S 0714238-0058 3.37 40 32 S 0714238-006B 2.70 41 33 S 0714238-007B 3.16 42 34_,S 0714238-008B 2.83 43 35 S 0714238-009B 2.72 44 36 S 0714238-OIOB 2.98 45 37 S 0714325-OO1B 2.80 46 38 S 0714325-002B 2.91 47 39 S 0714325-003B 0.73 48 40 S 0714325-004B 0.72 49 2 QC1 CCV 1.0 1.00 50 0 QC1 CCB 0.03 51 41 S 0714325-005B 2.85 52 42 S 0714325-006B 3.07 53 43 S 0714325-007B 2.74 54 44 S 0714325-008B 2.89 55 45 S 0714325-009B 2.76 56 46 S 0714325-010B 2.72 57 47 S LFB-24152 4.53 58 48 S LFBD-24152 4.52 59 2 QC1 CCV 1.0 1.01 60 0 QC1 CCB 0.04 61 1 D Drift 3.00 62 0 B FinalBase 0.03 QC Limits 1 50 50 50 20 1 1 1 100 20 1 1 1 5 5 1 1 1 1 5 5 5 5 5 5 5 5 1 1 1 1 5 5 5 5 5 5 10 10 1 1 1 1 TKN.ANL / tknl22007R1.run Page 2 Post -run Report N r-1 L�L BRAN+LUEBBE AACE 5.48 Channel 2 QC 1 Unused QC 2 Unused QC 3 Unused QC 4 Unused QC 5 Unused QC 6 Unused QC 7 Unused QC 8 Unused QC 9 Unused QC10 Unused CORRECTIONS Channel 2 Baseline Yes Drift Yes Carry over Yes %; 1.6 ** <END OF REPORT> ** TKN.ANL / tkn122007R1.run Page 3 Post -run Report BRP_N.LUEBBE AACE 5.48 H2M Labs Inc. Calibration Curve Calibration Curve Name of run :tknl22007R1_RUN Name of analysis :TKN.ANL Comment Channel :2 Method :Method 2 Curve fit :linear a= -1.0633E-001 b=5.6317E-005 Corr. coeff. :0.9996 Peak [�] 100 80- 040200 40- 20- o6 0.00 0.50 1.00 1.50 2.00 .2.50 3.00 3.50 Conc. [ mg/l ] Page 1 of 1 BRAN.LUEESE RACE 5.48 H2M Labs Inc. Post -run chart Name of run :tknl22007R1.RUN Comment Post -run chart Name of analysis :TKN.ANL min Channel 2 Method Method 2 Unit mg/l Base 76 Gain 25 Corr. : 0.9996 2 4 6 8 10 OB 0.03 1P 3.01 2D 3.00 12 311 3.01 4L 0.05 5L 0.05 14 6C 3-02 7C 0.96, I 8C 0.47 16 Page 1 of 3 r N Ol Ln L SRAN•LUEEBE RACE 5.48 M -me of run :tknl22007R1.RUN mment Posc-run Charc Name of analysis :TKN.ANL min 9C 0.19 10C 0.09 11C 0.03 18 12QC1 0.70 13QC1 4.57 14QC1 0.71 20 i5S 0.89 16S 0-88 7S 17.85- 22 18S 4.48 19S 63.62 20S 1.10 24 21S 43.69 22S 47.48 23S 43.66 26 24S 40.93 25QC1 1.03 26QC1 0.04 28 27S 0.68 28S 122.20 29S 26.73 30 30S 0.84 31S 1.33 32S 0.84 32 33S 0.79 34S 0.75 35S 0.73 34 L370CI 36S 0.74 1.00 Page 2 of 3 BRFN.LUEBBE AACE 5.46 -me of run :tkn122007R1.RUN mment Post -run char[ Name of analysis :TKN.ANL min 38QC1 0.04 36 399 3.37 40S 2.70 41S 3.16 38 42S 2.83 43S 2.72 44S 2.98 40 45S 2.80 46S 2.91 47S 0.73 42 48S 0.72 49QC1 1-00 SOQC1 0.03 k4 51S 2.85 52S 3.07 53S 2.74 46 54S 2.89 55S 2.78 56S 2.72 48 57S 4.53 58S 4.52 59QC1 1.01 50 60QC1 0.04 61D 3.00 52 62B 0.03 54 Page 3 of 3 (,64--t Z77o1- I;Lott Concentration listed after Optical Blank Correction. KNData Preparation dilution factor not applied to results. Peak SampleID SampTy - Cone Units DF Cone x DF AnalDate AnalTime TestCod 1 Primer PRIM 3.01 mg/I 1 3.01 12/20/2007 11:40:27 AM tkn_w 2 Drift DRIF 3.01 mg/1 1 3.01 12/20/2007 11:41:07 AM tkn_w 3 High HIGH 3.02 mg/1 1 3.02 12/20/2007 11:41:48 AM tkn-w 4 Low LOW 0.04 mg/I 1 0.04 12/20/2007 11:42:26 AM tkn_w 5 Low LOW 0.04 mg/1 1 0.04 12/20/2007 11:43:10 AM tkn_w 6 Cal. CALB 3.01 mg/1 1 3.01 12/20/2007 11:43:48 AM tkn-w 7 Cal'. CALB 1 mg/I 1 l.J 12/20/2007 11:44:28 AM tkn-w 8 Cal. CALB 0.47 mg/I 1 0.47 12/2012007 11:45:08 AM tkn_w 9 Cal. CALB 0.18 mg/1 1 0.18 12/20/2007 11:45:49 AM tkn w 10 Cal. CALB 0.09 mg/I 1 0.09 12/20/2007 11:46:30 AM tkn w 11 Cal. CALB 0.03 mg/1 1 0.03 12/20/2007 11:47:10 AM tkn_w 12 OPTICAL BLK QUAL 0.7 mg/I 1 0.7 12/20/2007 11:47:49 AM tkn w 13 LCSI-24152 --y_ q.onj , Ics 0.391 mg/I 10 3.91 1'2/20/2007 911 11:48:29 AM tkn_w 14 MBI-24152 mblk 0 mg/I 1 12/20/2007 t0-1 11:49:08 AM tkn w 15 0713771-003B M W - L( 1i SAMP 1.8945 mg/I 20 37.89 12/20/2007 11:49:48 AM tkn w 16 0714238-OOIB SAMP 0.08000 mg/1 I 0.080000000 12/20/2007 11:50:16 AM tkn w 17 0714238-002B Gfl L-� �� SAMP 0.1 mg/I l 0.1 12/20/2007 11:51:08 AM tkn_w 18 LFBI-24152 lfb 0.384 mg/I 10 3.84 12/20/2007 q4' t. 11:51:49 AM tkn w 19 LFBDI-24152 lfbd 0.378 mg/I 10 3.78 12/20/2007 WbX1 11:52:29 AM tkn w 20 CCV 1.0 ccv 0.99 mg/I I 0.99 12/20/2007 -141 11:53:09 AM tkn w 21 CCB ccb 0.03 mg/I 1 0.03 12/20/2007 1 11:53:50 AM tkn_w 22 Drift DRIF 3.01 mg/I I 3.01 12/20/2007 11:54:29 AM tkn w 23 End END 0.03 mg/I 1 0:03 12/20/2007 11:56:03 AM tkn w 12/20/2007 12:02:52 PM O O N O Page 1 of 1 BRAN+LUEBBE RACE 5.48 Name of Run tkn122007a Date of Report 12/20/2007 Date of Run 12/20/2007 Operator Cmo Comment Method #{24152 11210 Labe Inc. Post -run report Name of Analysis :TKN.ANL System No. :1 Type of System :TRAACS Start/Stop time :11:29 - 11:56 Channel Type Real Data Channel 2 2 Method Method 2 Dilution Unit mg/l mg/l . Calibr. Fit Linear Corr. Coeff. 0.9998 Base 76 Gain 25 Sensitivity 0.4201 Sample Limit 1 Sample Limit 2 Pk Cup Sample Id Value Value 0 0 B Baseline 0.03 0 1 1 P Primer 3.01 1 2 1 D Drift 3.01 1 3 1 H1 High 3.02 1 4 0 L1 Low 0.04 1 5 0 L1 Low 0.04 1 6 1 C Cal. 3.01 1 7 2 C Cal. 1.00 1 8 3 C Cal. 0.47 1 9 4 C Cal. 0.18 1 10 .5 C Cal. 0.09 1 11 0 C Cal. 0.03 1 12 8 QC1 OPTICAL BLK 0.70 1 13 9 QC1 LCS1-24152 4.61 10 14 10 QCl MBl-24152 0.70 1 15 11 S 0713771-003B 38.59 20 16 12 S 0714238-OOIE 0.78 1 17 13 S 0714238-002B 0.80 1 18 14 S LFB1-24152 4.54 10 19 15 S LFBD1-24152 4.48 10 TKN.ANL / tknl22007a.run Page 1 Post -run Report BRAN+LUEBBE AACE 5.48 QC 1 20 2 QC1 CCV 1.0 0.99 1 21 0 QC1 CCB 0.03 1 22 1 D Drift 3.01, 1 23 0 B FinalBase 0.03 1 QC Limits Channel 2 QC 1 Unused QC 2 Unused QC 3 Unused QC 4 Unused QC 5 Unused QC 6 Unused QC 7 Unused QC 8 Unused QC 9 Unused QC10 Unused CORRECTIONS Channel 2 Baseline Yes Drift Yes Carry over Yes %; 1.5 ** <END OF REPORT> ** TKN.ANL / tknl22007a.run Page 2 Post -run Report BRM.LUEBBE RACE 5-48 H2M Labs Inc. Calibration Curve Name of run :tknl22007a.RUN Comment Calibration Curve Name of analysis :TKN.ANL Channel :2 Method :Method 2 Curve fit :linear a= -1.0595E-001 b=5.6313E-005 Corr. coeff. :0.9998 Peak [�] 100 80- 060402000.00 Go- 40- 20- Oz - 0.000.50 1.00 1.50 2.00 2.50 3.00 3.50 Conc. [ mg/l ] Page 1 of 1 BRM-LUEBBE NICE 5.48 H21VI Labs Inc. Post -run chart Name of run :tknl22007a.RUN Comment Post•run chart Name of analysis :TKN.ANL min Channel 2 Method Method 2 Unit mg/1 Base 76 Gain 25 Corr. 0.9998 2 4 6 8 10 12 OB 0.03 1P 3.01 2D 3.01 3H 3.02 4L 0.04 14 5L 0.04 6C 3.01 7C 1.00 16 8C 0.47 Page 1 of 2 BR;UJ.LUEBBE AACE 5.;8 to of run :tknl22007a.RUN tment Post -run chart Name of analysis :TKN.ANL min 9C 0.18 10C 0.09 0:03 18 11C 12QC1 0.70 13QC1 4.61 14QC1 0.70 20 15S 38.59 16S 0.78 17S 0.8.0 22 18S 4.54 19S 4.48 20QC1 0.99 24 21QC1 0.03 22D 3.01 26 23B 0.03 28 30 32 34 Page 2 of 2 �GiSk °��' ceew TOTAL 00P /S DIGESTIONS 'SiJ� NAME: All ? DATE • - �: kis 4t gtN, f t/r' LAB NO. T :' - e , SAMPLE SAMPLE CLIENT ID WEIGHT VOLUME GRAMS MLS FINAL VOLUME MLS DATE ANALYZED I - At - ) - vQL 3 - COD - ty- S o" )AW y,+9 3 — voq 1 z Lf a -f gaalh kw, - �S fa -o g - vp f/ -vaf - AD miz - 65 M� 7W y d P S � lk - 3s /"✓ �' Q'QL - a0 13 -O -0v �7 b -Y33 D I 0 I -12A LADS, INC. TOTALP S/TRN DIGESTIONS x i 911 'A 31 3Z 3Y 3 3� `Io t4 1� 1 I L�. NAME: I�S�JK Qf9� DATE • LAB NO. S CLIENT ID SAMPLE WEIGHT GRAMS SAMPLE VOLUME MLS FINAL VOLUME MLS DATESP ANALYZED fllf 13� �rQ -- •� Sas--ter �c2�.� eke- ., 31f 4p3 s i wRova 3i�- � -7A 3zr mrb Poe 0 - 32sovtb p = —sl•I 31 -oap — b6• 0top jb Tvx 'f o (` t f e p 00tiA- Multiple Analysis Report Print Date/Time: 2007/12/08 10:49:33 Sample ID Result Std. Dev. RSD Mode ALT Method ID Sample Type Vial Timestamp Message IDI 1155, 0.1324 0.0533 40.23 UTILITY Cleaning Procedure Sample sp 2007/12/07 17:50 LCS Pin ��V� 27.5711 0.1852 0.67 TOC TOC WASTE WATER Sample 1 2007/12/07 18:22 ICB G)_� -0.1229 0.0704 -57.24 TOC TOC WASTE WATER Sample 2 2007/12/07 18:50 Low Sample �> Detected CRIV;Npx..........7.1.%- 0.7115... 0.0294.. 4.13 ... TOC TOC WASTE WATER ...Sample 3..2007/12/07 19:24.Low Sample -o Detected MBLK 4)-0 0.0304 0.1983 651.72 TOC TOC WASTE WATER Sample 4 2007/12/07 19:56 Low Sample a Detected r"- 110 0713711-001E �" 2.2990 0.9871 42.94 TOC TOC WASTE WATER Sample 5 2007/12/07 20:27 Low Sample -,> Detected �,� (S I 07137'T1 -002E.1........... 40 0.9337... 0.3000.. 32.13 ... TOC TOC WASTE WATER ...Sample 6..2007/12/07 20:58.Low Sample -b Detected 07137".1-003E M - �`�• 27.4274 1.6937 6.18 TOC TOC WASTE WATER Sample 7 2007/12/0721:30 07137.1-0045 1��" 13.1639 0.7268 5.52 TOC TOC WASTE WATER Sample 8 2007/12/07 22:01 0713711-OOSE.ya� `TO ...... 25.4896... 2.5813.. 10.13 ... TOC TOC WASTE WATER ...Sample 9..2007/12/07 22:33. 071371.1-006E pwv%-S$ 3.8009 0.2365 6.22 TOC TOC WASTE WATER Sample 10 2007/12/07 23:04 Low Sample Detected 3 0713TJI-007E M a 9 18.7453 0.7442 3.97 TOC TOC WASTE WATER Sample 11 2007/12/07 23:36 071371:1-007EMS..��oQ{0?..7� 28.5116... 1.7708.. 6.21 ... TOC TOC WASTE WATER ...Sample 12..2007/12/08 00:08. 0713 nl-007EDUP �Lfkwh / 18.9554 0.8213 4.33 TOC TOC WASTE WATER Sample 13 2007/12/08 00:39 0713-ql -008E 1�U(J $ 11.0854 0.7553 6.81 TOC TOC WASTE WATER Sample 14 2007/12/08 01:11 CCV.rjZl;.LseerP^ .......%(J.d'X 27.1183... 0.7566.. 2.80 ... TOC TOC WASTE WATER ...Sample 15..2007/12/08 01:43. CCB SS C)0-0.1533 0.0907 -59.18 TOC TOC WASTE WATER Sample 16 2007/12/08 02:14 Low Sample. -> Detected D07 0713711-009E 0 4).O -0.2195 0.1484 -67.62 TOC TOC WASTE WATER Sample 17 2007/12/08 02:45 Low Sample >Detected 0713817-001E P Ai -.:30 ..... 30.8419... 2.4543.. 7.96 ... TOC TOC WASTE WATER ...Sample 18..2007/12/08 03:17. 0713817-002E M1,V - 3 1.0604 0.1179 11.11 TOC TOC WASTE WATER Sample 19 2007/12/08 03:48 Low Sample -D Detected ,,,}� , C /1 0713817-003E M UU 12.1586 0.7485 6.16 TOC TOC WASTE WATER Sample 20 2007/12/08 04:20 0713817-004E. JA w : �.S..... 7.2194... 0.5544.. 7.68 ... TOC TOC WASTE WATER ...Sample 21..2007/12/08 04:51. 0713817-005E rl Q -60 1.5175 0.1601 10.55 TOC TOC WASTE WATER Sample 22 2007/12/08 05:22 Low Sample -�> Detected +,� CCVj,( Z'15 , �0 Y/i'26.0923 1.3165 5.05 TOC TOC WASTE WATER Sample 23 2007/12/06 05:54 CCB....................ej.O -0.2601... 0.2614..-100.49 ... TOC TOC WASTE WATER ...Sample 24..2007/12/08 06:25.Low Sample ':>Detected Printed: 121810710:49:34 AM AM TSL012 W108 Page 1 of 1 -0 -0 -0 Detailed Analysis Report Print Date/Time: 2007/12/08 10:49:36 ----------------------------------------------------------------------------- Sample ID: IDI Mode: UTILITY Method: Cleaning Procedure Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/07 17:50 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.1115 0.0558 15443 12.731 12.931 147 2 0.2095 0.1048 23747 12.636 12.836 171 3 0.1209 0.0604 16237 12.604 12.800 147 4 0.0877 0.0439 13426 12.536 12.734 152 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 0.1324 Std Dev: 0.0533 RSD: 40.23 Sample ID: LCS Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/07 18:22 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 27.6723 1.3836 240472 12.404 13.404 139 2 27.2948 1.3647 237273 12.391 13.389 138 3 27.6358 1.3818 240163 12.340 13.339 138 4 27.6813 1.3841 240548 12.198 13.195 138 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 27.5711 Std Dev: 0.1852 RSD: 0.67 Sample ID: ICB Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/07 18:50 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.1131 -0.0057 5035 12.116 12.304 120 2 -0.0838 -0.0042 5283 12.133 12.331 120 3 -0.0698 -0.0035 5402 12.149 12.345 120 4 -0.2249 -0.0112 4088 12.196 12.416 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: -0.1229 Std Dev: 0.0704 RSD: -57.24 Sample ID: CRI Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/07 19:24 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C. _Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.7003 0.0350 11927 12.524 12.854 120 2 0.7512 0.0376 12358 12.652 12.958 120 3 0.7127 0.0356 12032 12.714 12.993 120 - 4 0.6817 0.0341 11770 12.775 13.072 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 0.7115 Std Dev: 0.0294 RSD: 4.13 Sample ID: MBLK Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/07 19:56 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.1240 0.0062 7044 13.127 13.255 120 2 0.1059 0.0053 6890 13.197 13.364 120 Printed: 12/8/0710:49:36 AM AM Page 1 of 6 3 0.1571 0.0079 7325 13.265 13.390 120 4 -0.2653 -0.0133 3745 13,.322 13.451 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected - <<<Statistics>>> Mean: 0.0304 Std Dev: 0.1983 RSD: 651.72 Sample ID: 0713711-001B Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/07 20:27 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 3.7392 0.1870 37677 13.444 14.100 120 2 2.0847 0.1042 23658 13.496 13.930 120 3 1.8466 0.0923 21640 13.483 13.884 120 4 1.5254 0.0763 18918 13.502 ------------------------- 13.865 120 --------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 2.2990 Std Dev: 0.9871 RSD: 42.94 Sample ID: 0713711-002E Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/07 20:58 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 1.3471 0.0674 17408 13.649 13.893 120 2 0.8187 0.0409 12931 13.687 13.889 120 3 0.9282 0.0464 13859 13.684 13.926 120 4 0.6407 0.0320 11423 13.710 13.909 120 ------=---------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 0.9337 Std Dev: 0.3000 RSD: 32.13 Sample ID: 0713711-003E Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/07 21:30 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 29.5697 1.4785 256549 13.881 14.875 130 2 27.8194 1.3910 241718 13.835 14.827 130 3 26.7310 1.3365 232496 13.815 14.809 130 4 25.5894 1.2795 222823 13.819 14.808 130 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 27.4274 Std Dev: 1.6937 RSD: 6.18 Sample ID: 0713711-004E Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/07 22:01 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 14.1959 0.7098 126281 13.881 14.880 124 2 12.5300 0.6265 112165 13.887 14.882 123 3 12.8258. 0.6413 114671 13.871 14.869 124 4 13.1041 0.6552 117029 13.831 14.828 124 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 13.1639 Std Dev: 0.7268 RSP: 5.52 Sample ID: 0713711-005E Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE -110607 Timestamp: 2007/12/07 22:33 Operator ID: JASON SAMUEL Sample Type: Sample Printed: 12/8/0710:49:37 AM AM Page 2 of 6 Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 29.0850 1.4543 252443 13.865 14.860 i29 2 25.4736 1.2737 221841 13.858 14.856 129 3 24.2728 1.2136 211667 13.810 14.800 129 4 23.1270 1.1564 201958 13.750 14.745 128 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 25.4896 Std Dev: 2.5813 RSD: 10.13 Sample ID: 0713711-006E Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/07 23:04 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 4.1133 0.2057 40847 13.697 14.142 120 2 3.8524 0.1926 38636 13.619 14.093 120 3 3.6435 0.1822 36866 13.595 14.050 120 4 3.5942 0.1797 36448 13.531 14.008 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 3.8009 Std Dev: 0.2365 RSD: 6.22 Sample ID: 0713711-007E Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/07 23:36 Operator ID: JASON SAMUEL. Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 19.6825 0.9841 172771 13.545 14.542 127 2 18.7721 0.9386 165057 13.492 14.487 126 3 17.8647 0.8932 157368 13.492 14.484 127 4 18.6621 0.9331 164125 13.435 14.428 126 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 18.7453 Std Dev: 0.7442 RSD: 3.97 Sample ID: 0713711-007EMS Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/08 00:08 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 30.5079 1.5254 264499 13.401 14.395 130 2 28.8671 1.4434 250596 13.374 14.369 130 3 28.4605 1.4230 247150 13.281. 14.275 130 4 26.2109 1.3105 228089 13.208 14.201 129 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 28.5116 Std Dev: 1.7708 RSD: 6.21 Sample ID: 0713711-007EDUP Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/08 00:39 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 20.1278 1.0064 176545 12.391 13.386 127 2 18.7455 0.9373 164831 12.270 13.267 127 3 18.7403 0.9370 164787 12.116 13.111 127 4 18.2079 0.9104 160277 12.013 13.012 127 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 18.9554 Std Dev: 0.8213 RSD: 4.33 Sample ID: 0713711-008E Mode: TOC Printed: 12/8/0710:49:37 AM AM Page 3 of 6 Method: TOC WASTE WATER Cal. Curve: TOC WW CURVE 110607 Operator ID: JASON SAMUEL Filename: 12071722 Timestamp: 2007/12/08 01:11 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 11.3238 0.5662 101944 11.582 12.576 123 2 11.6912 0.5846 105058 11.479 12.479 124 3 9.9810 0.4991 90567 11.396 12.395 122 4 11.3457 0.5673 102130 11.365 12.358 124 ----------------------------------------------------------------------------- <<<Statistics>>> [dean: 11.0854 Std Dev: 0.7553 RSD: 6.81 -------------- Sample ID: CCV Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE.110607 Timestamp: 2007/12/08 01:43 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 27.3677 1.3684 237891 11.206 12.205 131 2 27.6487 1.3824 240272 11.187 12.182 131 3 27.4627 1.3731 238696 11.170 12.169 131 4 25.9939 1.2997 226250 11.076 12.066 131 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 27.1183 Std Dev: 0.7586 RSD: 2.80 Sample ID: CCB Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/08 02:14 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.1372 -0.0069 4831 10.970 11.050 120 2 -0.0543 -0.0027 5533 10.945 11.065 120 3 -0.1475 -0.0074 4743 10.900 11.001 120 4 -0.2741 -0.0137 3671 10.872 10.976 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: -0.1533 Std Dev: 0.0907 RSD: -59.18 Sample ID: 0713711-009E Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/08 02:45 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.4389 -0.0219 2274 10.827 10.882 120 2 -0.1811 -0.0091 4459 10.798 10.886 120 3 -0.1228 -0.0061 4953 10.777 10.869 120 4 -0.1351 -0.0068 4849 10.751 10.857 120 ----------------------- ----------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: -0.2195 Std Dev: 0.1484 RSD: -67.62 Sample ID: 0713817-OOIE Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/08 03:17 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C -ug C _Raw Data Beginning Ending Integration Baseline Baseline Time 1 33.5462 1.6773 290244 10.822 11.821 133 2 31.7187 1.5859 274759 10.775 11.775 133 3 27.7141 1.3857 240826 10.789 11.787 132 4 30.3884 1.5194 263487 10.778 11.776 133 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 30.8419 Std Dev: 2.4543 RSD: 7.96 Printed: 1218/0710:49:37 AM AM Page 4 of 6 N e --I r -I N r-1 V) Sample ID: 0713817-002E Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/08 03:48 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.9813 0.0491 14309 10.714 10.982 120 2 1.0709 0.0535 15067 10.702 10.973 120 3 1.2231 0.0612 16357 10.682 10.957 120 4 0.9664 0.0483 14182 .10.690 10.947 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 1.0604 Std Dev: 0.1179 RSD: 11.11 Sample ID: 0713817-003E Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/08 04:20 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 13.1019 0.6551 117011 10.716 11.708 125 2 12.4016 0.6201 111077 10.708 11.703 125 3 11.4464 0.5723 102.983 10.705 11.697 126 4 11.6847 0.5842 105002 10.664 11.655 125 ----------------------------------------------------------------------------- <Statistics>>> Mean: 12.1586 Std Dev: 0.7485 RSD: 6.16 Sample ID: 0713817-004E Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/08 04:51 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 7.3089 0.3654 67924 10.702 11.697 121 2 7.6543 0.3827 70851 10.688 11.682 122 3 6.4153 0.3208 60353 10.686 11.682 121 4 7.4992 0.3750 69537 10.685 11.679 123 ------------------------------------------------=---------------------------- <<<Statistics>>> Mean: 7.2194 Std Dev: 0.5544 RSD: 7.6B Sample ID: 0713817-005E Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2007/12/08 05:22 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 1.6563 0.0828 20028 11.229 11.549 120 2 1.4767 0.0738 18506 11.389 11.691 120 3 1.3086 0.0654 17081 11.526 11.812 120 4 1.6285 0.0814 19793 11.652 11.974 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 1.5175 Std Dev: 0.1601 RSD: 10.55 Sample ID: CCV Mode: TOC Method: TCC :BASTE WATER Filename: 12071722 Cal. Curve: TOC 1*7 CURVE 110607 Timestamp: 2007/12/08 05:54 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 26.1620 1.3081 227674 12.444 13.439 130 2 27.9169 1.3958 242545 12.502 13.492 130 Printed: 12/8/0710:49:37 AM AM Page 5 of 6 3 25.3338 1.2667 220657 12.555 13.553 130 4 24.9566 1.2478 217461 12.582 13.581 130 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 26.0923 Std Dev: 1.3165 RSD: 5.05 Sample ID. CCB Mode: TOC Method: TOC WASTE WATER Filename: 12071722 Cal. Curve: TOC WW CURVE 110607 Timestamp: 2001/12/08 06:25 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.4528 -0.0226 2156 12.787 12.851 120 2 -0.2076 -0.0104 4234 12.784 12.852 120 3 -0.4686 -0.0234 2023 12.794 12.882 120 4 0.0886 0.0044 6744 12.792 12.924 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: -0.2601 Std Dev: 0.2614 RSD: -100.49 Printed: 121810710:49:37 AM AM Page 6 of 6 Calibration Report Print Date/Time: 2007/12/10 11:43:20 Cal. Curve ID: TOC WW CURVE 110607 Created: 2007/11/06 21:33 Calibration Factor (m): 1.695e+05 Y Intercept (b): 3585 r -squared: 0.99875 Standard ID Y X Expected Measured Message Raw Data ug C ug C DI 8753 0.000 0.030 Low Sample De 0.5PPM 12110 0.025 0.050 Low Sample De 1.OPPM 19805 0.050 0.096 Low Sample De S.OPPM 44288 0.250 0.240 10.OPPM 83468 0.500 0.471 25.OPPM 202963 1.250 1.176- 50.OPPM 418226 2.500 2.447 75.OPPM 649888 3.750 3.814 Date & Time 2007/11/06 15:53 2007/11/06 16:16 2007/11/06 16:39 2007/11/06 17:01 2007/11/06 17:24 2007/11/06 17:47 2007/11/06 18:10 2007/11/06 18:33 Printed: 12/10/0711:43:20 AM AM Page 1 of 1 SDG NO.: --Mo I'L SCAN: � U(M- This data package was reported by the undersigned. This reporting includes data calculations, manual edits if necessary and compilation of raw data. The information presented is true and correct to the best of my knowledge. ,. Signature: Date: