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HomeMy WebLinkAboutSample Data Summary Package 09/2006Analytical Data Package For TOWN OF SOUTHOLD PART 360 ROUTINE SDG NO: TSL007 Water Samples Received: 9/13/06 cennDi P nATA SUMMARY PArICAGE )6 I -A I -AUS. I SC. Onvironmental Testing Laboratories 575 Broad Hollow Road, Melville, N.Y. 11747 1-2M "USS ISC. SAMPLE DATA SUMMARY PACKAGE TABLE OF CONTENTS TOWN OF SOUTHOLD PART 360 ROUTINE WATER SAMPLES SAMPLES RECEIVED: 9/13/06 SDG NO.: TSI -007 1. - NYS 'DEC SUMMARY FORMS 2. CHAIN OF CUSTODY DOCUMENTATION 3. SDG NARRATIVES 4. SAMPLE REPORTS 4.1 METALS 4.2 WET CHEMISTRY 5. DUPLICATE SUMMARY RESULTS. 5.1 METALS 5.2 WET CHEMISTRY 6. SPIKE SAMPLE RESULTS 6.1 METALS 6.2 WET CHEMISTRY 7. BLANK SUMMARY DATA AND RESULTS 7.1 METALS 7.2 WET CHEMISTRY "uss INC. 1. NYS DEC SUMMARY FORMS NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION Snr- TRI nn7 SAMPLE IDENTIFICATION AND ANALYTICAL REQUIREMENT SUMMARY Anal ical Requirements Customer Sample Code Laboratory Sample Code ME we EQPT BLANK 0609809-001 X X MW -1D 0609809-002 X X MW -1S 0609809-003 X X MW -3D 0609809-004 X X MW -3S 0609809-005 X X MW -4D 0609809-006 X X _ MW -4S 0609809-007 X X MW -51) 0609809-008 X X� MW -5S 0609809-009 X X MW -6D 0609809-010 X I X MW -6S 0609809-011 X X MW -8D 0609809-012 X X MW -8S 0609809-013 X X CLP,(Gn-CLP) Please indicate year of ASP IBJ 10M protoco NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG: TSL007 INORGANIC ANALYSIS Laboratory Samp ID I`DateRecdj Client Sample ID 1 Matrix i Metals Requested Date I at Lab Analyzed 0609809-001 iEQPT BLANK I WATER I CA,CD,FE,K,MG,MN,NA,PB, i 13 -Sep -06 09/06 0609809-002 IMW-11) WATER I CA,CD,FE,K,MG,MN,NA,PB, 13 -Sep -06 09/06 0609809-003 lMW-1S i WATER CA,CD,FE,K,MG,MN,NA,PB, I 13 -Sep -06 I 09/06 0609809-004 IMW-3D I WATER CA,CD,FE,K,MG,MN,NA,PB, 113 -Sep -06 I 09/06 0609809-005 IMW-3S ( WATER I CA,CD,FE,K,MG,MN,NA,PB, 113 -Sep -06 09/06 0609809-006 IMW-4D WATER , CA,CD,FE,K,MG,MN,NA,PB, 113 -Sep -06 09/06 0609809-007 IMW-4S WATER CA,CD,FE,K,MG,MN,NA,PB, 13 -Sep -06 09/06 0609809-008 IMW-5D WATER j CA,CD,FE,K,MG,MN,NA,PB, 13 -Sep -06 09/06 0609809-009 IMW-5S I WATER I CA,CD,FE,K,MG,MN,NA,PB, 113 -Sep -06 I 09/06 0609809-009DUP IMW-5SD I WATER CA,CD,FE,K,MG,MN,NA,PB, 113 -Sep -06 I 09/06 0609809-009MS NW-5SS WATER I CA,CD,FE,K,MG,MN,NA,PB, 113 -Sep -06 09/06 0609809-010 IMW-6D IWATER CA,CD,FE,K,MG,MN,NA,PB, I 13 -Sep -06 I 09/06 0609809-011 MW -6S WATER CA,CD,FE,K,MG,MN,NA,PB, 113 -Sep -06 09/06 0609809-012 IMW-8D I WATER I CA,CD,FE,K,MG,MN,NA,PB, I 13 -Sep -06 09/06 0609809-013 MW -8S WATER I CA,CD,FE,K,MG,MN,NA,PB, 13 -Sep -06 09/06 TSL007 S4 NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG: TSL007 INORGANIC ANALYSIS ! ry LS mp ID iClient Sample ID ` Matrix I Tests DateRec I d at Lab j Date I Analyze 0609809-001 I EQPT BLANK Blank I SELECT WET CHEMISTRY ** I 09/13/06 09/06 - 10/06 0609809-002 I MW -1D I Groundwater I SELECT WET CHEMISTRY ** I 09/13/06 I 09/06 - 10/06 0609809-003 MW -1S I Groundwater I SELECT WET CHEMISTRY ** f 09/13/06 I 09/06 - 10/06 0609809-004 MW -3D I Groundwater I SELECT WET CHEMISTRY ** 09/13/06 I 09/06 -10/06 0609809-005 I MW -3S I Groundwater I SELECT WET CHEMISTRY ** I 09/13/06 I 09/06 - 10/06 0609809-006 MW -4D i Groundwater i SELECT WET CHEMISTRY ** 09/13/06 j 09/06 - 10/06 0609809-007 I MW -4S I Groundwater SELECT WET CHEMISTRY ** I 09/13/06 I 09/06 - 10/06 0609809-008 I MW -5D Groundwater I SELECT WET CHEMISTRY ** I 09/13/06 I 09/06 -10/06 0609809-009 I MW -5S I Groundwater I SELECT WET CHEMISTRY ** I 09/13/06 I 09/06 - 10/06 0609809-009DUP MW-5SDUP I Groundwater SELECT WET CHEMISTRY ** 09/13/06 I 09/06 - 10/06 0609809-009MS I MW-5SMS I Groundwater I SELECT WET CHEMISTRY ** I 09/13/06 I 09/06 - 10/06 0609809-010 I MW -6D I Groundwater SELECT WET CHEMISTRY ** I 09/13/06 I 09/06 - 10/06 0609809-011 I MW -6S I Groundwater I SELECT WET CHEMISTRY ** I 09/13/06 I 09/06 - 10/06 0609809-012 I MW -8D I Groundwater i SELECT WET CHEMISTRY ** I 09/13/06 I 09/06 - 10/06 0609809-013 I MW -8S ( Groundwater ; SELECT WET CHEMISTRY ** I 09/13/06 09/06 - 10/06 ** Alkalinity, Total (As CaCO3) ; Biochemical Oxygen Demand; Bromide; Chemical Oxygen Demand; Chloride; Hardness (As CaCO3) ; Nitrate as N ; Nitrogen, Ammonia (As N) ; Nitrogen, Kjeldahl, Total ; Phenolics, Total Recoverable ; Sulfate; Total Dissolved Solids; Total Organic Carbon; O O N V2M "US' INC. 2. CHAIN OF CUSTODY DOCUMENTATION iH*t LAPS, IMC. 575 Broad Hollow Rd MaM116 NY 91747-5076 EXTERNAL CHAIN OF CUSTODY • Tel. (639) 694-304OFax. (631)420-8436 CLIENT: H2M SDG NO: PROJECTNAME/NUMBER sOFI%%D / TOWN OF 90VT�0L./O Z.AN d FILL_ �3(oO RO IN 20010 a3 - i --► cmc - zz p g <3J Q �- �, J =- NOTES: ProjectContach �CT� C L J.50 4� Phone Number. Tb -r , ALK 0010 /X l42q TDS PIS/Quote # �i) COD X13 No3 P+H�N6LS TK/�l SAMPLERS: (s gnatureyCifent DELIVERABLES: BS--7� p o e o ZS c 0 ANALYSIS REQUESTED TURNAROUND TIME: STD ORGANIC A I =INORG. DATE TIME MATRIXFIELD I.D. {` Z LAB I.D. NO. REMARKS: qt2 lo�to • Mkv- S w -- 3.S -cos - //38 /I1W- 3D -OoU M vV -- 4 S I2:2s MW—'95 a �t1 .3 3 - C09 M t 12-Sa M W,- S D B 3 1 1 2- _00S Nv �3�3a /4! 0D M w— 6 S ` (19 JD 1 A — Olt `0I5 I I (S ) D to Time Received try. (s (3 Time LABORATORY USE ONLY Discrepancies Between Sample Labels and COC Record? Y or N Explain: Samples were: 2. shipped_ Hand Detivered�Airbilbl N 2 Ambient or c3�iiled, Temp— 3. Received in good i �onir .& N 4. Property Y N COC Tagg was: 1. Present on outer package: Y oC 2 1JnhM& on outer package: Y or N record present & complete upon sampie receipt: aN Relinqu} ed by: (Signature) a Time R ' by: (Signa Data Time Rellnquished by: (Signature) Date Time Received by: (Signature) Date Time Relinquished by. (Signature) Date Time Received t>Y (Signature) Date Time ,VgUtlf 5ffP - ORIGINAL YELLOW COPY - CLIENT PINK COPY - LABORATORY INC. 18 EXTERNAL CHAIN OF CUSTODY Te!•(631) 694-304OFax: (631) 420-8436 w. CLIENT: H2M SDG NO: '-r5GCA` PROJECT NAME/NUMBER S�7-060 TO GJ/1! Cj F SD u %�( OLb L,4/1(b SILL 6 0 P2-006 200, 0.3 I C 0 ---► p �� -� M O ZT, NOTES: Project Contact: (I) BODS $R/ 6-wD /CTS CL J SD 4� Phone Number A L K x/&10 /x 8 y Tt) S PIS/Quote # C2� COD NHS/ N 0 3 PF(�Enr0LS TK A/ SAMPLERS: (signatureyClient °` DELIVERABLES:_ 7 D c g ANALYSIS REQUESTED TURNAROUND TIME: STD ORGANIC INORG. . i` (2� I J U LAB I.D. NO. REMARKS: DATE TIME MATRIX FIELD I.D. 1246 15,10. L 1rIW— 85 In — 4 P 7- 8 L 4N $ 3. 1 I 2 -013 15.30 L /0,00 Date q I; 06 Time 16;15 1M Received try: (S to Q 1 13 0(o Time 161 ( LABORATORY USE ONLY Reil t by ( ) Discrepancies Utween Sample Labels and COC Record? Y or N F�cplaln: 50mo e6 were^ or Hand oettveredL artit� 2. Ambient or cNIled, Temp 3. Received in good -Y N 4. Property preserved Y N COC Tape was: 1. Preserd on outer package: Y.0 2. Unbroken on outer package: Y or N COC record present d complete upon sample recelpt: N Relk►quished by (Signature) to Time R ) Dat Time Retinqulshed by: (Signature) Date Time Rea*/ed try: (Signature) Date Time Relinquished by (Signature) Date Time Received by (Signature) Date Time 1 §L;Bb�S%Y - ORIGINAL YELLOW COPY - CLIENT PINK COPY - LABORATORY "2M LABS, INC. S L °c'? Sample Receipt Checklist Client Name PCTSL Date and Time Receive 9/13/2006 4:15:00 PM Work Order Numbe 0609809 Received by dmc Checklist completed b �_- —T _ � �O Reviewed by _� si alure Dale Initials D e Matrix Carrier name Hand Delivered Shipping container/cooler in good condition? Yes W No ❑ Not Applicable ❑ Custody seals intact on shippping container/cooler? Yes ❑ No ❑ Not Applicable Custody seals intact on sample bottles? Yes ❑ No ❑ Not Applicable Chain of custody present? Yes 0 No ❑ Chain of custody signed when relinquished and received? Yes No ❑ Chain of custody agrees with sample labels? Yes ❑ No W Samples in proper container/bottle? Yes 0 No ❑ Sample containers intact? Yes No ❑ Sufficient sample volume for indicated test? Yes No ❑ I samples received within holding time? Yes No ❑ Container/Temp Blank temperature in compliance? Yes No ❑ Water - VOA vials have zero headspace? No VOA vials submitted Yes ❑ No ❑ Water - pH acceptable upon receipt? Yes No ❑ Adjusted? Checked b Any No and/or NA (not applicable) response must be detailed in the comments section b ------------------------------------------------ \t Client contacted Date contacted: Person contacted Contacted by: Regarding Comments: GL S l -06 r -Z.5 -y 4^16C, 66�4!!60_✓PA- w _i� 50q GVH �'Ii5�L LE r 6iU --64 Corrective Action IH2A UAUS, INC. INTERNAL CHAIN OF CUSTODY CLIENT: PC -TS G DELIVERABLES&j- 70D TURN AROUND TIME: SDG #: TSLOO:? CASE #: MATRIX: G W pH CHECK(r N REMARKS: -OV, ft -Ml- OY SIGNATURE: 4 DATE: Tom: RECEIVED BY. (DdG METALS P. 01,93 - mom mom 0111 mom - bqq 111111 AIM VMS 1110 Am METALS P. 01,93 - ■ ILA UAUSg 1SC• SDG INTERNAL CHAIN OF CUSTODY Da TIRE SAMPLE RELINQUISHED SAMPLE BOTTLE BY RECEIVED BY TYPE PURPOSE OF CHANGE OF CUSTODY INIT �J �V c� 930 aIaN BION ,,, 471 S /o�✓ /33o Bar 9I i%i!4 s Z, : 3 0 �I a X51 (r A ON SIGN BION SIGN slog SIGN BION SIGN '- SIoN SIGN SIGN SIGN SIGN SIGN SION SIGN SION SIGN SIGN SIC SION IGH ' SIGN 9I ON SIGN SION SION SIGN ' SIGN "SION - SIWt SIGN • SI SIGN 9ZON SIGN - SION .SIGN BION SIGN 1 SIGN SIGN ' METALS 0200 ITH lH2A I-A"s INC* ,INTERNAL CHAIN OF CUSTODY CLIENT:PC —(S(- DELlVERABLES:M--7aD'_TURN AROUND TllvlE: ,SDG 9: /5( 601. CASE It: MATRIX: pH CM06- N REMARKS: 097- ---------- -RECENEDBY: -SIGNATLYRE:�-.DAT&--j3fP6nw:-& WET CHEMISTRY N r --.q cn r - C:) 0 !9 'r --A IH2A UAIAs INC, - CLIENT: fs L P- - SDG #: 7St- crD— INTERNAL CHAIN OF CUSTODY M WET CHEMISTRY p mal., M WET CHEMISTRY p CLIEW: sl>G #: U) TNTERNAL CHAIN OF. CUSTODY WET CHEMISTRY 0084 v2A "Uss INC. 3. SDG NARRATIVES U28t "US' INC. For Samples: EQPT BI MW -1D MW -1S MW -3D MW -3S MW -4D MW -4S Thirteen water samples were received 1 Samples were prepared and instrument. Sample MW -5S was utilized for QC No problems were noted during the I certify that this data p: conditions of the contract other than the conditions i in this hardcopy data pac Manager or his designee, a Date Reported: October 9, 2006 FOR METALS ANALYSES E RECEIVED: 9/13/06 SDG#: TSL007 MW -5D MW -5S MS/MSD MW -6D MW -6S MW -8D MW -SS 112M Labs, Inc. on 9/13/06 for select metals analysis. using EPA method 6010B with a TJA61E Trace ICP ysis and reporting. of this sample group. ,kage is in compliance with the terms and both technically and for completeness, for etailed above. Release of the data contained age has been authorized by the Laboratory verified by the following signature. Vincent Stancampiano Vice President U2M -"US, INC. For Samples: SDG NARRATIVE FOR WET CHEMISTRY SAMPLE RECEIVED: 9/13/06 SDG#: TSL007 EQPT BLANK MW -1D MW -1S MW -3D MW -3S MW -4D MW -4S MW -5D MW -5S MS/MSD MW -6D MW -6,S MW -8D MW -8S Thirteen water samples were received by H2M Labs, Inc. on 9/13/6 for select wet chemistry analysis. Samples were prepared and analyzed using the following EPA methods: Alkalinity EPA 310.1 Nitrate EPA 353.2 BOD EPA 405.1 Phenols EPA420.1 Bromide EPA 320.1 Sulfate EPA SW846 9038 Chloride EPA 325.2 TDS EPA 160.1 COD EPA 410.4 TKN EPA 351.2 Hardness EPA 130.2 TOC EPA SW846 9060 Ammonia EPA 350.1 Sample MW -5S was utilized for QC analysis and reporting. Samples were diluted and reanalyzed as required to keep instrument readings within calibration range. No problems were `noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data kage has been authorized by the Laboratory Manager or his designee, as verified "e 4rdpowing signature. Date Reported: October 9, 2006 Vincent'�c, Vice President U2M "US, INC, 4. SAMPLE REPORTS 4.1 METALS 4.2 WET CHEMISTRY H2M -LABS, 1NC . QUALIFIERS FOR METALS ANALYSIS Q (Quality Control) Qualifiers E - The reported value is estimated because of the presence of interference. An explanatory note is included in the SDG narrative. M - . Duplicate injection precision not met. N - Matrix spike sample recovery not within control limits. S- The reported value was determined by the Method of Standard Additions (MSA). + - Correlation coefficient for the MSA is less than 0.995 W - Post digestion spike for Furnace AA analysis is out of control limits (85- 115%), while sample absorbance is less than 50% of spike absorbance. - Duplicate analysis is not within control. limits. C (Concentration) Qualifiers B'- Entered if the reported value is less than the Contract Required Detection Limit (CRDL) but greater than the Instrument Detection Limit (IDL). U - Entered if the analyte was analyzed for but not detected, i.e., less than the IDL. M (Method). Qualifiers P - Analyzed by ICP. M - Analyzed by ICP -MS A- Analyzed by Flame AA. F - Analyzed by Furnace AA. CV - 'Analyzed by Manual Cold Vapor techniques. AV - Analyzed by Automated Cold Vapor techniques. C - Analyzed by Manual Spectrophotometric Method. CA- Analyzed by Midi -distillation Spectrophotometric Method. NR- Analyte not Required. 0 0 H U.S. EPA - CLP Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 EPA SAMPLE NO M INORGANIC ANALYSIS DATA SHEET 0.38 B P 744.0-70-2 Calcium 85.0 EQPT BLANK Lab Name: H2M LABS, INC. Contract: 17.8 U P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL007 Matrix (soil/water): WATER Lab Sample ID: 0609809-001 Level (low/med): LOW Date Received: 9/13/2006 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte (Concentration C� Q M 7440-43-9 lCadmium 0.38 B P 744.0-70-2 Calcium 85.0 B P 7439-89-6 Iron 17.8 U P Lead 2.1 B P IIIf7--7439=92-1 7439-95-9 Magnesium 8.3 B P 7439-96-5 Manganese 0.38 U P 7440-09-7 Potassium _ 599 B P 7990-23-5 Sodium 53.8 B P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments DATE REPORTED: SEPTEMBER 18, 2006 FORM I - IN ILM04.1 U2M "US, 1NC. 575 Broad How Road, Me%& NY 11747 LABORATORY RESULTS (631)6943040.FAX(631)420-8436 NYSDOHID#10478 Sample Information... Town of Southold Landfill Lab No. : 0609809-001 Type: Blank Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported: 10/9/2006 Page 1 of 13 Laboratory Manager Origin: Attn To George Desmarias Client ID.: EQPT BLANK Collected :9112/2006 10:00:00 AM Received :911312006 4:15:00 PM Collected By VG03 Copies To :Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310.1 09/19/2006 11:15 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/14/2006 12:10 PM Bromide < 0.5 1 mg/L E320.1 09/29/2006 9:40 AM < 2.0 1 mg/L E325.2 09/15/2006 3:14 PM Chloride Chemical Oxygen Demand <10 1 mg/L E410.4 09/18/2006 12:02 PM Hardness (As CaCO3) < 100 20 mg/L E130.2 09/20/2006 3:12 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 09/26/2006 4:40 PM Nitrate as N < 0.10 1 mg/L E353.2 09/21/2006 12:20 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 09/20/2006 6:32 AM < 5.0 1 mg/L SW9038 09/29/2006 11:04 AM Sulfate <10 1 mg/L E160.1 09/18/2006 1:04 PM Total Dissolved Solids 1 mg/L E351.2 09/19/2006 10:19 AM Nitrogen, Kjeldahl, Total 0.10 Total Organic Carbon < 1.0 1 mg/L SW9060 10/02/2006 1:42 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported: 10/9/2006 Page 1 of 13 Laboratory Manager U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -1D Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL007 Matrix (soil/water): WATER Lab Sample ID: 0609809-002 Level (low/med): LOW Date Received: 9/13/2006 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L ACAS No. Analyte Concentration C Q I M 7440-43-9 Cadmium 0.24 B P 7440-70-2 _ Calcium 28400 P 7439-89-6 Iron 139 P 7439-92-1 Lead 1.2 _ B P 7439-95-4 Magnesium j 13800 P 7439-96-5 Manganese 6.6 B P 7440-09-7 Potassium 2260 B P 7440-23-5 Sodium 202001 1 P Color Before: COLORLESS Clarity Before Color After: COLORLESS Clarity After: Comments: DATE REPORTED: SEPTEMBER 18, 2006 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 U2M INC. 575 Broad Hollow Road, Melville W 11747 LABORATORY RESULTS (631)694,3040.FAX(631)4208436 NYSDOH ID# 10478 Sample Information... Town of Southold Landfill Lab No. : 10609809-002 Type : Groundwater Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 10/9/2006 Page 2 of 13 Laboratory Manager Origin: Attn To George Desmarias Client ID. : MW -1D Collected :9112/2006 10:40:00 AM Received :9/1312006 4:15:00 PM Collected By VG03 Copies To :Original CC Parameter(s) Results Qualifier D_F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 25.2 1 mg/L E310.1 09/19/2006 11:40 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/14/2006 12:15 PM Bromide < 0.5 1 mg/L E320.1 09/29/2006 9:45 AM Chloride 23.9 1 mg1L E325.2 09/15/2006 3:14 PM Chemical Oxygen Demand <10 1 mg/L E410.4 09/18/2006 12:03 PM Hardness (As CaCO3) 160 5 mg/L E130.2 09/20/2006 3:14 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 09/26/2006 4:42 PM Nitrate as N 5.42 5 mg/L E353.2 09121/2006 12:22 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 09/20/2006 6:33 AM Sulfate 92.0 5 mg1L SW9038 09/29/2006 11:06 AM Total Dissolved Solids 221 1 mg/L El 60.1 09/18/2006 1:06 PM Nitrogen, Kjeldahl, Total < 0.10 1 mg/L E351.2 09/19/2006 10:20 AM Total Organic Carbon < 1.0 1 mg/L SW9060 10/02/2006 2:13 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 10/9/2006 Page 2 of 13 Laboratory Manager U.S. EPA - CLP Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 EPA SAMPLE NO M INORGANIC ANALYSIS DATA SHEET 0.12 - P 7440-70-2 Calcium 10200 MW -1S Lab Name: H2M LABS, INC. Contract: 188 P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL007 Matrix (soil/water): WATER Lab Sample ID: 0609809-003 Level (low/med): LOW Date Received: 9/13/2006 a Solids: 0.0 P 7440-09-7 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.12 U P 7440-70-2 Calcium 10200 P 7439-89-6 Iron 188 P 7439-92-1 ILead 1.2 B I P 7439-95-4 Magnesium 6260 P 7439-96-5 Manganese 16.9 P 7440-09-7 Potassium 3050 B P 7440-23-5 Sodium 44000 P Color Before: COLORLESS Clarity Before: CLEAR_ Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: SEPTEMBER 18, 2006 FORM I - IN ILM04.1 N V) 1H2M "US, INC. 575 Broad Hollow Road, Mable NY 11747 LABORATORY RESULTS (631) 69430 . FAX (631)42&8436 NYSDOH ID# 10478 Town of Southold Landfill Lab No. : 0609809-003 Attn To George Desmarias Collected :9/1212006 10:10:00 AM Received :9/13/2006 4:15:00 PM Collected By VG03 Copies To :Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID.: MWAS Sample Information... Type: Groundwater Origin: Results Qualifier D.F. Units Method Number Analyzed 10.2 1 mg/L E310.1 09/19/2006 11:45 AM < 2 1 mg/L E405.1 09/14/2006 12:20 PM < 0.5 1 mg/L E320.1 09/29/2006 9:50 AM 64.4 1 mg/L E325.2 09/15/2006 3:15 PM <10 1 mg/L E410.4 09/18/2006 12:04 PM 46.0 2 mg/L E130.2 09/20/2006 3:16 PM < 0.10 1 mg/L E350.1 09/26/2006 4:43 PM 4.84 10 mg/L E353.2 09/21/2006 12:23 PM < 5.0 1 pg/L E420.1 09/20/2006 6:34 AM 25.1 1 mg/L SW9038 09/29/2006 11:08 AM 186 1 mg/L E160.1 09/18/2006 1:08 PM < 0.10 1 mg/L E351.2 09/19/2006 10:22 AM < 1.0 1 mg/L SW9060 10/02/2006 2:44 PM Qualifiers: E -Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 10/9/2006 Page 3 of 13 Laboratory Manager U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEETINC =MW-3Contract: Lab Name: H2M LABS, SDG No.: TSL007 Lab Code: 10978 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: 0609809-004 Date Received: 9/13/2006 Level (low/med): LOW Solids: 0_0 ht) UG/L Concentration Units (ug/L or mg/kg dry weight): CAS No. I Analyte 7940-43-9 Cadmium 7440-70-2 Calc_ ium 7439-89-6 Iron 7439-92-1 Lead 7439-95-4Magnesium 7939-96-5 Manganese 7490-09-7 Potassium 7440-23-5 Sodium__ Concentration�C� 4 I M 0.12 U P -- _10300 P 199 F 1.5 B E 6280 F 21.0 3020 B 44500 CLEAR Texture: Color Before: COLORLESS Clarity Before: CLEAR Artifacts: Color After: COLORLESS Clarity After: Comments: DATE REPORTED: SEPTEMBER 18, 2006 FORM I - IN ILM04.1 N iJ1 O O V) E-4 1-2M "MI INC. 575 Broad Hdlovv Road, MdAle NY 11747 (631) 6943040. FAX (631)420.84W NYSDOHID#10478 Town of Southold Landfill Attn To George Desmarias Collected :9112/2006 11:38:00 AM Received :9/1312006 4:15:00 PM Collected By VG03 Copies To :Original CC LABORATORY RESULTS L"ab No. : 0609809-004 Client ID: : MW -3D Sample Information... Type: Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310.1 09/19/2006 11:50 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/14/2006 12:25 PM. Bromide < 0.5 1 mg/L E320.1 09/29/2006 9:55 AM Chloride 64.4 1 mg/L E325.2 09/15/2006 3:17 PM Chemical Oxygen Demand < 10 1 mg/L E410.4 09/18/2006 12:05 PM Hardness (As CaCO3) 46.0 2 mg/L E130.2 09/20/2006 3:18 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 09/26/2006 4:44 PM Nitrate as N 5.30 10 mg/L E353-2 09/21/2006 12:24 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 09/20/2006 6:35 AM Sulfate 35.3 1 mg/L SW9038 09/29/2006 11:10 AM Total Dissolved Solids 199 1 mg/L E160.1 09/18/2006 1:10 PM Nitrogen, Kjeldahl, Total 0.11 1 mg/L E351.2 09/19/2006 10:23 AM Total Organic Carbon < 1.0 1 mg/L SW9060 10/02/2006 3:16 PM Qualifiers: E - Value above.quantitation range D - Results for Dilution D.F.= Dilution Factor Date Reported : 10/9/2006 Page 4 of 13 iC1/w►� � . Laboratory Manager U.S. EPA - CLP % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No ( Analyte 744_0-43-9 Cadmium lConcentration 1 EPA SAMPLE NO M P INORGANIC ANALYSIS DATA SHEET I 10100 � MW -3 Lab Name: H2M LABS, INC. Contract: 331 1.1 U 1 1 P P 17439-95-4 Magnesium1___6 Lab Code: 10478 Case No. SAS No.: SDG No.: TSL007 Matrix (soil/water): WATER Lab.Sample ID: 0609809-005 Level (low/med): LOW Date Received: 9/13/2006 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No ( Analyte 744_0-43-9 Cadmium lConcentration 0.14 C; Q B M P 17_440-70-2 ICalcium I 10100 __P (7439-89-6 Iron ---^— `---89-6 F7439-92-1 Lead 331 1.1 U 1 1 P P 17439-95-4 Magnesium1___6 220 P 7439-96-5 Manganese 23.4 P 7440-09-7 lPotassium 3050 B P 7440-23-5 Sodium 44100 P L— Color Before: COLORLESS Clarity Before Color After: COLORLESS Clarity After: Comments: DATE REPORTED: SEPTEMBER 18, 2006 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 00 N C/1 U28t "Uss INC. 575 Broad Hollow Road, Me'vie NY 11747 LABORATORY RESULTS (631)694-3040. FAX (631)420-8436 NYSDOH ID# 10478 Town of Southold Landfill Lab No. : 0609809-005 Attn To George Desmarias Collected :9/12/2006 11:15:00 AM Received :9/13/2006 4:15:00 PM Collected By VG03 Copies To :Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID. : MW -3S Sample Information... Type : Groundwater Origin: Results Qualifier D.F.. Units Method Number Analyzed 10.2 1 mg/L E310.1 09/19/2006 11:55 AM < 2 1 mg/L E405.1 09/14/2006 12:30 PM 0.6 1 mg/L E320.1 09/29/2006 10:00 AM 64.9 1 mg/L E325.2 09/15/2006 3:18 PM <10 1 mg/L E410.4 09/18/2006 12:06 PM 52.0 2 mg/L E130.2 09/20/2006 3:20 PM < 0.10 1 mg/L E350.1 09/26/2006 4:45 PM 4.83 10 mg/L E353.2 09/21/2006 12:25 PM < 5.0 1 pg/L E420.1 09/20/2006 6:36 AM 24.8 1 mg/L SW9038 09/29/2006 11:12 AM 185 1 mg/L E160.1 09/18/2006 1:12 PM < 0.10 1 mg/L E351.2 09/19/2006 10:23 AM < 1.0 1 mg/L SW9060 10/02/2006 3:47 PM Qualifiers: E -Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 10/9/2006 Page 5 of 13 Laboratory Manager U.S. EPA - CLP 1 INORGANIC ANALYSIS.DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID Level (low/med): LOW Date Received Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration Q M 7440-43-9 Cadmium j 0.35 B P 7440-70-2 Calcium 14700 P 7439-89-6 7439-92-1 lIron Lead 17.8 U P 1.1 U P 7439-95-4 7439-96-5 74 Magnesium.—}-_ Manganese Potassium 10400-�— P 1970 _ P — P 7440-23-5 jSodium — _ __12600 - 18000 P EPA SAMPLE NO MW -4D SDG No.: TSL007 .0609809-006 9/13/2006 Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: PORTED: SEPTEMBER 18, 2006 FORM I - IN ILM04.1 1-2M "US, INC. 575 Broad Hdow Road, Me vile W 11747 (631) 69VW0 FAX (631)42084W NYSDOH ID# 10478 Town of Southold Landfill Attn To George Desmarias Collected :9/12/2006 2:40:00 PM Received :9/13/2006 4:15:00 PM Collected By VG03 Copies To :Original CC LABORATORY RESULTS Lab No. : 0609809-006 Client ID. : MW -41) Sample Information... Type: Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 43.6 1 mg/L E310.1 09/19/2006 12:00 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 .09/14/2006.12:35 PM Bromide 1.3 1 mg/L E320.1 09/29/2006 10:05 AM Chloride 15.2 1 mg/L E325.2 09/15/2006 3:19 PM Chemical Oxygen Demand <10 1 mg/L E410.4 09/18/2006 12:07 PM Hardness (As CaCO3) 80.0 4 mg/L E130.2 09/20/2006 3:22 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 09/26/2006 4:47 PM Nitrate as N 2.17 5 mg/L E353.2 09/21/200612:27 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 09/20/2006 6:37 AM Sulfate 41.0 2.5 mg/L SW9038 09/29/2006 11:14 AM Total Dissolved Solids 164 1 mg/L E160.1 09/18/2006 1:14 PM Nitrogen, Kjeldahl, Total 1.21 10 mg/L E351.2 09/1.9/2006 10:24 AM Total Organic Carbon < 1.0 .1 mg/L SW9060 10/02/2006 4:18 PM Qualifiers: E -Value above quantitation range D - Results dor Dilution' D.F. = Dilution Factor Date Reported : 10/9/2006 Page 6 of 13 Laboratory Manager U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No.. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. I Analyte ;Concentration: M 440-43-9 Cadmium -CUT 0.12P -Q- 17440-70-2 ;Calcium 14600 P _ 17439-89-6 Iron 17439-92-1 Lead 7439-95-4 Magnesium 36.4 B 1.5 B 10400 P P P 7439-96-5 IManganese 1980; P 7440-09-7 jPotassium 6670 P 7440-23-5 ISodium 12300 P EPA SAMPLE NO I MW -4S SDG No.: TSL007 9/13/2006 Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After:' COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: SEPTEMBER 18, 2006 FORM I - IN ILM04.1 N M V) O O F-+ U2M "Uss INC. 575BmadHdow Road, Melville NY 11747 LABORATORY RESULTS (631) 6943040. FAX(631)42a84436 NYSDOHID#10478 Town of Southold Landfill Lab.No. : 0609809-007 Attn To : George Desmarias Collected :911212006 2:10:00 PM Received :9/13/2006 4:15:00 PM Collected By VG03 Copies To :Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID.: MW -4S Sample Information... Type: Groundwater Origin: Results Qualifier D.F.. Units Method Number Analyzed 43.6 1 mg/L E310.1 09/19/2006 12:05 PM < 2 1 mg/L E405.1 09/14/2006 12:40 PM 22 1 mg/L E320.1 09/29/2006 10:10 AM 14.9 1 mg/L E325.2 09/15/2006 3:19 PM <10 1 mg/L E410.4 09/18/2006 12:08 PM 80.0 4 mg/L E130.2 09/20/2006 3:24 PM < 0.10 1 mg/L E350.1 09/26/2006 4:48 PM 2.11 10 mg/L E353.2 09/21/2006 1:14 PM < 5.0 1 pg/L E420.1 09/20/2006 6:38 AM 39.7 1 mg/L SW9038 09/29/2006 11:16 AM 175 1 mg/L E160.1 09/18/2006 1:16 PM 1.56 1 mg/L E351.2 09/19/2006 10:25 AM < 1.0 1 mg/L SW9060 10/02/2006 4:49 PM Qualifiers: E -Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 10/9/2006 Page 7 of 13 Laboratory Manager U.S. EPA - CLP Concentration Units (ug/L or mg/kg dry weight): UG/L rCAS No. I Analyte 1 EPA SAMPLE NO M INORGANIC ANALYSIS DATA SHEET 0.12 U P 7440-70-2 Calcium 10100 MW -5D Lab Name: H2M LABS, INC. Contract: 4.82 P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL007 Matrix (•soil/water): WATER Lab Sample ID: 0609809-008 Level (low/med): LOW Date Received: 9/13/2006 % Solids: 0.0 P —........ _. 7440-09-7 Concentration Units (ug/L or mg/kg dry weight): UG/L rCAS No. I Analyte Concentration C Q M X7440-43-9 lCadmium 0.12 U P 7440-70-2 Calcium 10100 P 7439-89-6 Iron 4.82 P 7439-92-1 Lead 2.2 B I P 7439-95-4 Magnesium 62401 P 7439-96=5 Manganese 26.6 P —........ _. 7440-09-7 ----- Potassium 2630 B P 7440-23-5 Sodium 44300 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: SEPTEMBER 18, 2006 FORM I - IN ILM04.1 1H2M "US, INC. 575 Broad Hollow Road, Meld ie NY 11747 (631)694,3 . FAX (631)4205438 NYSDOH ID# 10478 Town of Southold Landfill Attn To George Desmarias Collected :9/12/2006 12:50:00 PM Received :9/13/2006 4:15:00 PM Collected By VG03 Copies To :Original cc LABORATORY RESULTS Lab No. : 0609809-008 Client ID.: MW -5D Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310.1 09/19/2006 12:10 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/14/2006 12:45 PM Bromide 4.7 1 mg/L E320.1 09/29/2006 10:15 AM Chloride 66.0 1 mg/L E325.2 09/15/2006 3:20 PM Chemical Oxygen Demand <10 1 mg/L E410.4 09/18/2006 12:09 PM Hardness (As CaCO3) 50.0 5 mg/L E130.2 09/20/2006 3:26 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 09/26/2006 4:49 PM Nitrate as N 5.33 10 mg/L E353.2 09/21/2006 12:29 PM Phenolics, Total Recoverable 49.7 1 pg/L E420.1 09/20/2006 6:39 AM Sulfate 43.5 2.5 mg/L SW9038 09/29/2006 11:18 AM Total Dissolved Solids 185 1 mg/L E160.1 09/18/2006 1:18 PM Nitrogen, Kjeldahl, Total 0.12 1 mg/L E351.2 09/19/2006 10:25 AM Total Organic Carbon < 1.0 1 mg/L SW9060 10/02/2006 5:20 PM Qualifiers: 'E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 10/9/2006 Page 8 of 13 Laboratory Manager U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW-5S� Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSLO07 Matrix (soil/water): WATER Lab Sample ID: 0609809-009 Level (low/med): LOW Date Received: 9/13/2006 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L ACAS No. i Analyte Concentration C' Q M 7940-93-9 Cadmium 0.37 B P 7440-70-2 Calcium 14700 P 74.3_9-89-6 Iron 17.8 U P 7439-92-1 Lead 1.2 B P 7439-95-4 Magnesium 10400 P t793 96-5 Manganese 1970 P 7440-09-7 Potassium 12300 P 7440-23-5 ISodium 17800 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: SEPTEMBER 18, 2006 FORM I - IN ILMO4.1 U2M "USS INC. 575 Broad Hollow Road, Me4le NY 11747 LABORATORY RESULTS (631) 6943040. FAX (631) 4208M WSDOH ID# 10478 Town of Southold Landfill Lab No. : 0609809-009 Attn To George Desmarias Collected :9/1212006 12:25:00 PM Received :9/13/2006 4:15:00 PM Collected By VG03 Copies To :Original cc Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID.: MW -5S Sample Information... Type : Groundwater Origin: Results Qualifier D.F. Units Method Number Analyzed 74.2 2 mg/L E310.1 09/21/2006 10:10 AM 16 1 mg/L E405.1 09/14/2006 12:50 PM 0.5 1 mg/L E320.1 09/29/2006 10:20 AM 29.5 1 mg/L E325.2 09/15/2006 3:28 PM <10 1 mg/L E410.4 09/18/2006 12:10 PM 84.0 4 mg/L E130.2 09/20/2006 3:28 PM 0.40 1 mg/L E350.1 09/26/2006 4:50 PM 2.18 5 mg/L E353.2 09/21/2006 12:30 PM < 5.0 1 pg/L E420.1 09/20/2006 6:40 AM 47.5 5 mg/L SW9038 09/29/2006 11:20 AM 166 1 mg/L E160.1 09/18/2006 1:20 PM 1.37 1 mg/L E351.2 09/19/2006 10:26 AM < 1.0 1 mg/L SW9060 10/02/2006 5:51 PM Qualifiers: E -Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 10/9/2006 Page 9 of 13 Laboratory Manager U.S. EPA - CLP Concentration Units (ug/L or mg/kg dry weight): UG/L �CAS No. Analyte 1 EPA SAMPLE NO 7440-43-9 lCadmium INORGANIC ANALYSIS DATA SHEET P 7440-70-2 jCalcium 18800 P 7439-89-6 MW -6D Lab Name: H2M LABS, INC. Contract: Lead i P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL007 Matrix (soil/water): WATER Lab Sample ID: 0609809-010 Level (low/med): LOW Date Received: 9/13/2006 $.Solids: 0.0 _ 3660 B P Concentration Units (ug/L or mg/kg dry weight): UG/L �CAS No. Analyte Concentration CI Q I M 7440-43-9 lCadmium 0.12 U1 P 7440-70-2 jCalcium 18800 P 7439-89-6 ;Iron 17.8 U P 7439-92-1 Lead 1.1 U P 7439-95-4 Magnesium _ 4-� B P 7439-96-5 Manganese 2540 P 7440-09-7 Potassium 10500 P 7440-23-5 Sodium _ 3660 B P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: SEPTEMBER 18, 2006 FORM I - IN ILM04.1 00 M O O V) U28A "US, INC. 575 B -ad Hcdow Road, Melville NY 11747 (631) 6943040. FAX (631) 4205436 NYSDOH ID# 10478 Town of Southold Landfill Attn To George Desmarias Collected :9/12/2006 2:00:00 PM Received :9/13/2006 4:15:00 PM Collected By VG03 Copies To :Original CC LABORATORY RESULTS Lab No. : 0609809-010 Client ID.: MW -6D Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 62.9 2 mg/L E310.1 09/19/2006 12:20 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/14/2006 1:00 PM Bromide < 0.5 1 mg/L E320.1 09/29/200610:35 AM Chloride 4.4 1 mg/L E325.2 09/15/2006 3:23 PM Chemical Oxygen Demand 11.0 1 mg/L E410.4 09/18/2006 12:13 PM Hardness (As CaCO3) 75.0 5 mg/L E130.2 09/20/2006 3:34 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 09/26/2006 4:58 PM Nitrate as N 1.58 5 mg/L E3532 09/21/2006 12:36 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 09/20/2006 6:41 AM Sulfate 13.5 1 mg/L SW9038 09/29/2006 11:26 AM Total Dissolved Solids 116 1 mg/L E160.1 09/18/2006 1:26 PM Nitrogen, Kjeldahl, Total 0.31 1 mg/L E351.2 09/19/2006 10:28 AM Total Organic Carbon < 1.0 1 mg/L SW9060 10/02/2006 8:24 PM Qualifiers: E -Value above quantitation range D -Results for Dilution D.F. = Dilution Factor Date Reported : 10/9/2006 Page 10 of 13 Laboratory Manager U.S. EPA - CLP % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): -UG/L (CAS No. Analyte 1 EPA SAMPLE NO IM INORGANIC ANALYSIS DATA SHEET 0.58 B P 7440-70-2 Calcium 19000 MW -6S P 7439-89-6 Iron 33.8 B Lab Name: H2M LABS, INC. Contract: 1.6 Lab Code: 10478 Case No. SAS No.: SDG No.: TSL007 Matrix (soil/water): WATER Lab Sample ID: 0609809-011 Level (low/med)• LOUD Date Received: 9/13/2006 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): -UG/L (CAS No. Analyte (Concentration C Q IM 7990-43-9 Cadmium 0.58 B P 7440-70-2 Calcium 19000 P 7439-89-6 Iron 33.8 B P _ 7439-92-1 Lead 1.6 B P 7439-95-4 Magnesium 4590 B P 7439-96-5 Manganese_ 2590 P 7440-09-7 10200 P 7990-23-5 Ptassium dium 3650 B P Color Before: COLORLESS Clarity Before Color After: COLORLESS Clarity After: Comments: DATE REPORTED: SEPTEMBER 18, 2006 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 U2M L U%3 INC. 575 Broad Hollow Road, Mddle NY 11747 LABORATORY RESULTS (631)694-3040. FAX(631)420$436 WSDOHID#10478 Town of Southold Landfill Lab No. : 0609809-011 Attn To : George Desmarias Collected :9112/2006 1:30:00 PM Received :9/13/2006 4:15:00 PM Collected By VG03 Copies To :Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID.: MW -6S Sample Information... Type : Groundwater Origin: Results Qualifier D.F. Units Method Number Analyzed 61.5 2 mg/L E310.1 09/19/2006 12:25 PM < 2 1 mg/L E405.1 09/14/2006 1:05 PM < 0.5 1 mg/L E320.1 09/29/2006 10:40 AM 4.4 1 mg/L E325.2 09/15/2006 3:23 PM 11.0 1 mg/L E410.4 09/18/2006 12:14 PM 72.0 4 mg/L El 30.2 09/20/2006 3:36 PM < 0.10 1 mg/L E350.1 09/26/2006 4:59 PM 1.60 5 mg/L E353.2 09/21/2006 12:37 PM < 5.0 1 pg/L E420.1 09/20/2006 6:42 AM 13.1 1 mg/L SW9038 09/29/2006 11:28 AM 115 1 mg/L E160.1 09/18/2006 1:28 PM 0.54 1 mg/L E351.2 09/19/2006 10:30 AM < 1.0 1 mg/L SW9060 10/02/2006 8:55 PM Qualifiers: E -Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 10/9/2006 Page 11 of 13 Laboratory Manager U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -8D Lab Name: H2M LABS, INC. Contract: -- Lab Code: 10478 Case No. SAS No.: SDG No.: TSL007 Matrix (soil/water): WATER Lab Sample ID: 0609809-012 Level (low/med): LOW Date Received: 9/13/2006 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No Analyte Concentration C Q ( M 7440-43-9 Cadmium 0.12 U P 7440-70-2 Calcium 19100 P 7439-89-6 Iron 116 P 7439-92-1 Lead 1.5 B I P 7439-95-4 Magnesium 4630 B P 7439-96-5 Imanganese 2700, 10200 P P I 7440-09-7 !Potassium _ 17440-23-5 iSodium 3770 BI P Color Before: COLORLESS Clarity Before Color After: COLORLESS Clarity After: Comments: DATE REPORTED: SEPTEMBER 18, 2006 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 N 7t O O U2M IAUS,' INC. 575 Broad Hc0ow Road, Melvi e W 11747 (631) 694 3040. FAX (631)4208436 WSDOH ID# 10478 Town of Southold Landfill Attn To George Desmarias Collected :9/12/2006 3:30:00 PM Received :9113/2006 4:15:00 PM Collected By VG03 Copies To :Original CC LABORATORY RESULTS Lab No. : 0609809-012 Client ID.: MW -8D Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 61.4 2 mg/L E310.1 09/19/2006 3:25 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/14/2006 1:10 PM Bromide 0.6 1 mg/L E320.1 09/29/200610:45 AM Chloride 4.6 1 mg/L E325.2 09/15/2006 3:26 PM Chemical Oxygen Demand 46.2 1 mg/L E410.4 09/18/2006 12:15 PM Hardness (As CaCO3) 76.0 4 mg/L E130.2 09/20/2006 3:38 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 09/26/2006 5:00 PM Nitrate as N 1.69 5 mg/L E353.2 09/21/2006 12:39 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 09/20/2006 6:43 AM Sulfate 12.4 1 mg/L SW9038 09/29/2006 11:30 AM Total Dissolved Solids 111 1 mg/L E160.1 09/18/2006 1:30 PM Nitrogen, Kjeldahl, Total 0.32 1 mg/L E351.2 09/19/2006 10:31 AM Total Organic Carbon < 1.0 1 mg/L SW9060 10/02/2006 9:26 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 10/9/2006 Page 12 of 13 Laboratory Manager U.S. EPA - CLP Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 EPA SAMPLE NO 7990-43-9 INORGANIC ANALYSIS DATA SHEET P — Calcium 19300 I_ P 17439-_8_9-6 MW -8S Lab Name: H2M LABS, INC. Contract: Lead 1.11U P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL007 Matrix (soil/water): WATER Lab Sample ID: 0609809-013 Level (low/med): LOW Date Received: 9/13/2006 o Solids: 0.0 3840 B P Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M i 7990-43-9 Cadmium 0.14 BI P ``7440-70-2 Calcium 19300 I_ P 17439-_8_9-6 Iron -. --- --� 325 P 7439-92-1 Lead 1.11U P 7939-95-9 Magnesium 4740 B P 9-96-5 Manganese 2750 P 0-09-7 Potassium 10200 P 0-23-5 r Sodium 3840 B P Color Before:_ COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: SEPTEMBER 18, 2006 FORM I - IN ILM04.1 '�t d' C/1 O O V) N U2M "USS INC. 575 Broad Hollow Road, Melville NY 11747 (631) 6943040.FAX (631)420&136 WSDOH ID# 10478 Town of Southold Landfill Attn To : George Desmarias Collected :9/12/2006 3:10:00 PM Received :9/13/2006 4:15:00 PM Collected By VG03 Copies To :Original CC LABORATORY RESULTS Lab No. : 0609809-013 Client ID.: MW -8S Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 42.8 2 mg/L E310.1 09/19/2006 4:25 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/14/2006 1:15 PM Bromide < 0.5 1 mg/L E320.1 09/29/2006 10:50 AM Chloride 4.6 1 mg/L E325.2 09/15/2006 3:26 PM Chemical Oxygen Demand 46.2 1 mg/L E410.4 09/18/2006 12:16 PM Hardness (As CaCO3) 72.0 4 mg/L E130.2 09/20/2006 3:40 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 09/26/2006 5:01 PM Nitrate as N 1.65 1 mg/L E353.2 09/21/2006 12:40 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 09/20/2006 6:44 AM Sulfate 30.5 1 mg/L SW9038 09/29/2006 11:32 AM Total Dissolved Solids 129 1 mg/L E160.1 09/18/2006 1:32 PM Nitrogen, Kjeldahl, Total 0.36 1 mg/L E351.2 09/19/2006 10:31 AM Total Organic Carbon < 1.0 1 mg/L SW9060 10/02/2006 9:54 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 10/9/2006 Page 13 of 13 Laboratory Manager kn 7t O u2M LABS, INC, 5. DUPLICATE SAMPLE RESULTS 5.1 METALS 5.2 WET CHEMISTRY Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER % Solids for Sample: 0.0 U.S. EPA - CLP 6 EPA SAMPLE NO DUPLICATES MW -SS Contract: SAS No.: SDG No.: TSL007 Level (low/med): LOW % Solids for Duplicate: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L Analyte Control Limit Sample (S) C Duplicate (D) C RPD Q M Cadmium 5.0000 0.3700 IB 0.2400 B 42.6 P Calcium 5000.0000 14673.7100 14881.0300 1.4 P Iron 17.7629 U 17.7629 U _ P Lead ; 3.0000 1. 1.2364 B 1.4795 B 17.9 P Magnesium 5000.0000 10369.9800 10515.9500 1.4 P Manganese f_ _ 1966.6300 1993.5700 1.4 P ipotass_i_u_m__ 5000.0000 12288.0300 125.22.9100 1.9 P Sodium 15000.0000 17779.3400 18068.4300 1.6 P FORM VI - IN ILM04.1 O O V) H2M LABS, INC. Date: 03 -Oct -06 QC SUMMARY REPORT SDG: TSL007 Spike Sample Recovery RPDRef %RPD Sanlnle ID Client Sample ID Analyte Result Units Amount Result %REC Limits Value %RPD UCL_ MB -091906 MB -091906 Alkalinity, Total (As CaCO3)< 1 mg/L LCS-091906 LCS-091906 Alkalinity, Total (As CaCO3) 26.6 mg/L 25 < 1 106 80 120 MB 091406 Biochemical Oxygen Demand <1 mg/L _ LCS-091806 LCS-091806 LCS-092906 �I MB -092106 MB -092106 Alkalinity, Total (As CaCO3) 167 mg/L 200 <2 84 80 120 Bromide 5.8 LCS-092106 LCS-092106 Alkalinity, Total (As CaCO3) 25.2 mg/L 25 –<1 101 80 120 16 _ 0609809-009dms MW-5SMS Alkalinity, Total (As CaCO3) 124 mg/L 50 74.2 100 75 125 0609809-009ddup— MW-5SDUP Alkalinity, Total (As CaCO3) 72.7 mg/L _ 74.2 2.0 20 MB -091906 MB -091906 Alkalinity, Total (As CaCO3)< 1 mg/L LCS-091906 LCS-091906 Alkalinity, Total (As CaCO3) 26.6 mg/L 25 < 1 106 80 120 MB 091406 MB -091406 Biochemical Oxygen Demand <2 d mg/L _ LCS-091806 LCS-091806 LCS-092906 �I LCS-091406 LCS-091406 Biochemical Oxygen Demand 167 mg/L 200 <2 84 80 120 Bromide 5.8 0609809-009DDUP MW-SSDUP Biochemical Oxygen Demand 18 mg/L MW-5SDUP Bromide 0.6 16 11.8 20 MB -092906 MB -092906 Bromide < 0.5 mg/L __ LCS-091806 LCS-091806 LCS-092906 LCS-092906 Bromide 4.7 mg/L 5 < 0.5 94 80 120 Chemical Oxygen Demand 988 0609809-009DMS MW-5SMS Bromide 5.8 mg/L 5 0.5 106 75 mg/L 0609809-009DDUP MW-5SDUP Bromide 0.6 mg/L 75 125 MB -091806 MB -091806 Chemical Oxygen Demand <10 mg/L <2 - __ LCS-091806 LCS-091806 Chemical Oxygen Demand 967 mg/L 1000 < 10 97 80 120 80 120 0609809-009CMS MW-5SMS Chemical Oxygen Demand 988 mg/L 1000 < 10 99 E75 1250609809-009CDUP mg/L MW-5SDUP Chemical Oxygen Demand < 10 mg/L 0609809-009DMS MW-5SMS <10 20 MBI -091506 MB1-091506 Chloride <2 mg/L LCS1-091506 LCS1-091506 Chloride 50.3 mg[- 50 <2 101 80 120 0609809-009DUP MW-5SDUP Chloride 29.9 mg/L 29.5 1.3 20 0609809-009DMS MW-5SMS Chloride 56.6 mg/L 25 29.5 108 75 125 1 TSL007 S48 QC SUMMARY REPORT SDG: TSL007 Spike Sample Recovery RPDRef %RPD Sample -ID: Client Sample ID: _ Analyte Result Unils Amount Result %REC Limits Value%RPD UCL_ -_ _--- - MB -92006 MB -92006 Hardness (As CaCO3) < 5 mg/L-T- LCS-092906 LCS-92006 LCS-92006 Hardness (As CaCO3) 1030 - mg/L 1000 < 5 103 80 1120 0609809-009Bms 0609809-009Bdup MW-5SMS MW-5SDUP Hardness (As CaCO3) Hardness (As CaCO3) 492 88.0 mg/L 400 84,0 102 mg/L 75 125 84.0 - 4.6 20 MB -092106 MB -092106 Nitrate as N < 0.1 mg/L LCS-092906 - - -_r LCS-18304 LCS-092106 LCS-092106 Nitrate as N 1.19 mg/L 1.13 <0.1 105 180 0609809-009CMS MW-5SMS 0609809-009CMS MW-5SMS Nitrate as N 4.66 mg/L 2.5 2.18 99 175 125 INItrogen, Kjeldahl, Total 0609809-009CDUP MW-5SDUP Nitrate as N 2.18 mg/L - 0.40 2.18 0 20 MB -18403 MB -092606 Nitrogen, Ammonia (As N) < 0.1 mg/L --� LCS-092906 - - LCS-092006 LCS-18304 LCS-18403 LCS-092606 Nitrogen, Ammonia (As N) 1.00 mg/L 1 < 0.1 100 80 1120 _ 0609809-009CMS MW-5SMS 0609809-009CMS - MW-5SMS Nitrogen, Ammonia (As N) 5.91 mg/L 5 0.40 j 110 75 125 0609809-009CDUP MW-5SDUP INItrogen, Kjeldahl, Total 0609809-009CDUP MW-5SDUP Nitrogen, Ammonia (As N) 0.40 mg/L 1.5 20 0.40 0 20 MB -18304 MB -091906 Nitrogen, Kjeldahl, Total < 0.1 mg/L LCS-092906 - - LCS-092006 LCS-18304 LCS-091906 Nitrogen, Kjeldahl, Total 3.91 mg/L 4.1 < 0.1 95 80 120 0609809-009Cms _ 0609809-009CMS MW-5SMS Nitrogen, Kjeldahl, Total 5.55 mg/L 4.1 1.37 102 75 1 125 MW-5S�U� _ 0609809-009CDUP MW-5SDUP INItrogen, Kjeldahl, Total 1.35 mglL 1.37 1.5 20 MB -092006 MB -092006 Phenolics, Total Recoverable <5 ug/L LCS-092906 I - LCS-092006 LCS-092006 Phenolics, Total Recoverable 28.6 J ug/L 30 < 5 95 80 120 0609809-009DDUP` 0609809-009Cms MW-5SMS Phenolics, Total Recoverable 19.4 ug/L 20 < 5 97 75 125 _ 060�E09 OO�Cdup MW-5S�U� Phenolics Total Recoverable < 5 _ ug/L < 5 20 MB -092906 MB -092906 Sulfate <5 mg/L LCS-092906 LCS-092906 Sulfate 18.9 mg/L 20 I <5 94 80 120 - 0609809-009DMS MW-5SMS Sulfate 146 mg/L 100 47.5 1 98 75 125 _ 0609809-009DDUP` MW-5SDUPSulfate 48.5 mglL 47.5 2,1 20 TSL007 S49 QC SUMMARY REPORT SDG: TSL007 Spike Sample Recovery RPDRef %RPD Sample ID:__ Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -091806 MB -091806 Total Dissolved Solids — <10 mg/L _—_�- T _ LCS-091806 — LCS-091806 ITotal Dissolved Solids 306 mg/L 300 < 10 102 80 120 0609809-009AMS MW-5SMS Total Organic Carbon 0609809-009DMS MW-5SMS Total Dissolved Solids 511 mg/L 300 166 115 75 125 MW-5SDUP_ Total Organic Carbon <1 0609809-009DDUP MW-5SDUP ITotal Dissolved Solids 175 mg/L 166 5.3 20 MB -100206 MB -100206 Total Organic Carbon < 1 mg/L I _T--- TI LCS-100206 LCS-100206 Total Organic Carbon 24.1 mg/L 25 < 1 96 80 120 _ 0609809-009AMS MW-5SMS Total Organic Carbon 9.9 mg/L 10 j < 1 99 75 125 0609809-009ADUP MW-5SDUP_ Total Organic Carbon <1 mg/L r <1 - 20 TSL007 S50 U2M "USs INC. 6. SPIKE SAMPLE RESULTS 6.1 METALS 6.2 WET CHEMISTRY Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix. (soil/water): WATER % Solids for Sample: 0.0 U.S. EPA - CLP 5A SPIKE SAMPLE RECOVERY Contract: SAS No.: EPA SAMPLE NO MW-5ss I SDG No.: TSL007 Level (low/med): LOW Concentration Units (ug/L or mg/kg dry weight): UG/L Analyte Control Limit %R i Spiked Sample Result (SSR) C Sample Result (SR) C Spike Added (SA) %R Q M Cadmium 75-125 ! 50.9100 0.3700 B 50.00 101.1 P Iron 75-125 986.3700 17.7629 U 1000.00 98.6 P Lead 75-125 20.2590 1.2364 B 20.00 95.1 P Man anese 75-125 2419.4800 1966.6300 500.00 90.6 P Comments: FORM V (Part 1) - IN ILM04.1 N O O H2M LABS, INC. Date: 03-0ct-06 QC SUMMARY REPORT SDG: TSL007 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount _Result %REC Limits Value %RPD UCL M_B-092106 MB -092106 Alkalinity, Total (As CaCO3) <1 mg/L `mg/L mg/L mg/L mg/L LCS-092106 LCS-092106 Alkalinity, Total (As CaCO3) 25.2 25 < 1 101 80 120 0609809-009dms MW-5SMS Alkalinity, Total (As CaCO3) 124 mg/L 50 74.2 100 75 125 0609809-009ddup MW-5SDUP Alkalinity, Total (As CaCO3) 72,7 mg/L 0.5 18.2 20 74.2 2.0 20 06 Alkalinity, Total (As CaCO3) LI S-091906 —� CS -091906 -Alkalinity, Total (As CaCO3) 126.6 mg/L 25 < 1 106 �8EJ12(]) MB -091406 _ MB -091406 jBiochemical Oxygen Demand <2 mg/L mg/L mg/L 1-_ ___ --�— LCS-091406 _ LCS-091406 jBiochernical Oxygen Demand 167 mg/L 200 < 2 84 80 120 _ 0609809-009DDUP _MW-5SDUP jBlochemical Oxygen Demand 18 mg/L 0.5 106 75 I_ 120 16_L11_8 120 MB -092906 MB -092906 Bromide < 0.5 1 mg/L mg/L mg/L I!� --�— LCS-092906 LCS-092906 Bromide 4.7 mg/L 5 < 0.5 1 94 80 120 967 mg/L 1000 _ 0609809-009DMS MW-5SMS Bromide 5.8 mg/L 5 0.5 106 75 125 120 0609809-009CMS MW-5SMS Chemical Oxygen Demand 0609809-009DDUP MW-5SDUP Bromide — 0_6 mg/L �_ 75 0.5 18.2 20 MB -091806 MB -091806 IChemical Oxygen Demand <10 mg/L mg/L I!� --�— --�— LCS-091806 LCS-091806 Chemical Oxygen Demand 967 mg/L 1000 < 10 97 80 120 101_ 80 120 0609809-009CMS MW-5SMS Chemical Oxygen Demand 988 mg/L 1000 <10 99 75 125 Ii-0 0609809-009CDUP MW-5SDUP 'Chemical Oxygen Demand <10 mg/L MW-581VIS Chloride _ mg/L < 10 29.5 108 MB1-091506 MBl-091506 Chloride <2 mg/L --�— --�— LCS1-091506 LCS1-091506 Chloride 50.3 mg/L 50 <2 101_ 80 120 0609809-009DUP MW-5SDUP Chloride 29.9 mg/L 29.5 _ 1,3 20 0609809-009DMS MW-581VIS Chloride 56.6 mg/L 25 29.5 108 75 125 TSL007 S53 QC SUMMARY REPORT SDG: TSL007 Spike Sample Recovery RPDRef %RPD _ Sample ID:__. Client Sample ID: - Analyte -- ResultUnits Amount Result %REC-_Limits Value _/oRPD UCL MB -92006 - LCS-92006 MB -92006 LCS-92006 Hardness (As CaCO3) --� IHardness (As CaCO3) - < 5 mgJL 1030 mg/L - 1000 < 5 103 80 120 0609809-009CDUP MW-5SDUP Nitrate as N 0609809-009Bms MW-5SMS Hardness (As CaCO3) 492 mg/L 400 84.0 102 75 125 ug/L 30 < 5 95 80 0609809009Bdup -_ MW-5SDUP Hardness (As CaCO3) _ - 88.0 - mg/L - �__ t- �- L84.0 -� 4- . F 20 MB -092106 T LCS-092106 0609809-009CMS --�--- -�- MB -092106 - Nitrate as N LCS-092106 Nitrate as N MW-5SMS INitrate as N _- - < 0.1 mg/L! --- i 1.19 m9/L 4.66 mg/L - - - ---�-- 1.13 < 0.1 2.5 2.18 � 105 - _ 99 --�- - 4 80 120 ---��-- -- - - - 1--- 75 1251l_ 7, 2.18 0 20 0609809-009CDUP MW-5SDUP Nitrate as N 2.18 mg/L 20 < 5 1 94 LCS-092006 LCS-092006 MB -18403 - MB -092606 Nitrogen, Ammonia (As N) - < 0,1 -mg/L -CS-1 8403 - LCS-092606 Nitrogen, Ammonia (As N) 1.00 mg/L 1 < 0.1 100 80 120 -_ 0609809-009CMS MW-5SMS Nitrogen, Ammonia (As N) 5.91 mg/L 5 0.40 110 75 125 0609809-009CDUP MW-5SDUP Nitrogen, Ammonia (As N) 0.40 mg/L 0.40 MB -18304 MB -091906 Nitrogen,Kjeldahl, Total _ < 0.1 mg/L LCS-18304 LCS-091906 Nitrogen, Kjeldahl, Total 3,91 _ i mg/L 4.1 < 0.1 95 80 1120 _- 0609809-009CMS MW-5SMS Nitrogen, Kjeldahl, Total 5.55 mg/L 4.1 1.37 102 75 125----. _ 0609809-009CDUP MW-5SDUP -.Nitrogen, Kjeldahl, Total 1.35 mg/L 1.37 1.5 20 MB -092006 MB -092006 Phenolics, Total Recoverable < 5 ug/L LCS-092906 -LCS-092906 Sulfate 18,9 T 20 < 5 1 94 LCS-092006 LCS-092006 lPhenolics, Total Recoverable 28.6 ug/L 30 < 5 95 80 120 T-� - _ - - 0609809-009Cms 0609809-009Cdup MW-5SMS -MW-5 IlPhenolics, Total Recoverable Phenolics, Total Recoverable 19.4 _ < 5 ug/L ug/L 20 < 5 97 75 I I �- 1 125 < 5 20� MB -092906 A MB -092906 Sulfate <5 mg/L LCS-092906 -LCS-092906 Sulfate 18,9 mglL 20 < 5 1 94 80 120 j 0609809-009DMS MW-5SMS Sulfate 146 mg/L 100 1 47.5 98 - 75 1251 - T-� - 0609809-009DDUP MW-5SDUP Sulfate 48.5 mg/L 47.5 --2.1 20 TSL007 S54 QC SUMMARY REPORT SDG:- TSL007 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -091806 JMB-091806 Total Dissolved Solids LCS-091806 LCS 90 1806 Total Dissolved Solids <10 306 mg,L mgiL 300 <10 102 _ 80 120 0609809-009DMS MW-5SMS Total Dissolved Solids 511 L mg300 166 115 75 125 �20 0609809-009DDUP MW-5SDUP Total Dissolved Solids 175 mg/L 166 5.3 MB -100206 MB -100206 Total Organic Carbon < 1 mg/L LCS-100206 LCS-100206 Total Organic Carbon 24.1 mg/L 25 < 1 96 80 120 0609809-009AMS MW-5SMS Total Organic Carbon _ 9.9mg/L 10 < 1 99 75 125 0609809-009ADUP MW-5SDUP Total Organic Carbon < --J— L _ _. 1 .. 20 TSL007 S55 U2M "US' INC, 7. BLANK SUMMARY DATA AND RESULTS 7.1 METALS 7.2 WET CHEMISTRY U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL007 Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L FORM III - IN ILM04.1 i Initial i I Calib. Continuing Calibration Prepa- 1 Blank Blank (ug/L) ration Analyte (ug/L) C 1 C 2 C 3 CI Blank C M Cadmium 0.21B_-- 0.2 B 0.2 B ' 0. 1 U -0:.180 B P _ 7.4 U�7.4 UI 7.4 U 7,4 U1 -10.800 B P ECalcium 17.8!U17.8 17.8 U 17.8 Ul-17.8 U 17.763 U P !Lead , 1.1 U 1.1 U 1-1 U 1.1 U 1.126 U P _ Magnesium -j— 8.2� U 1 _ - 9.9 B 8.2 U1 8.2 U 8.230 U - P Manganese.- 0.4.0 0.4 ;U 0.4 U 0.4 U� -0.380 B Potassium _ —�-30.0B 26.0 B 25.8 B 22. 9 B I 19.800 BSodium qP {15.0 U -r__ 15.0 U 15.0 U� 15.0 U 14.979U I � FORM III - IN ILM04.1 i Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Preparation Blank Matrix (soil/water) U.S. EPA - CLP 3 BLANKS Contract: SAS No.: WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L SDG No.: TSL007 00 O O FORM III - IN ILM04.1 Initial Calib. Continuing Calibration Prepa- Blank Blank (ug/L) ration Analyte (ug/L) C 1 C 2 C 3 C Blank C M Cadmium —i 0.3 B P !Calcium -----;- 1 7.4 U �— _ P Iron (Lead-- —�I'-- Magnesium -f - ! 17.8 U P 1 .1 U f P 14.7 ' B P Manganese 0.4 U P Potassium 1 29.2 B P Sodium � 15.0 U � _i P 00 O O FORM III - IN ILM04.1 H2M LABS, INC. Date: 03 -Oct -06 QC SUMMARY REPORT SDG: TSL007 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits_ Value %RPD UCL -- MB-092106 MB -092106 Alkalinity, Total (As CaCO3) —� < 1 mg/L Biochemical Oxygen Demand < 2 mg/L mg/L LCS-091806 Chemical Oxygen Demand �- LCS-092906 LCS-091406 LCS-091406 LCS-092106 LCS-092106 Alkalinity, Total (As CaCO3) 25.2 mg/L 25 < 1 101 80 120 Biochemical Oxygen Demand 18 mglL mg/L 5 0.5 106 75 1.25 0609809-009dms MW-5SMS Alkalinity, Total (As CaCO3) L124 mg/L 50 74.2 100 75 125 0.5 18.2 20 _ 0609809_009ddup MW-5SDUP —'-- Alkalinity, Total (As CaCO3) 72.7 mg/L 74_2— - 20 MB -091906 MB -091906 _ Alkalinity, Total (As CaCO3) L< 1 _ mg/L LCS-091906 LCS-091906 Alkalinity, Total (AS CaCO3) 26.6 I mg/L 25 �< 1 106 80 120 ^� — -- MB -092906 MB-091406 MB -091406 Biochemical Oxygen Demand < 2 mg/L mg/L LCS-091806 Chemical Oxygen Demand �- LCS-092906 LCS-091406 LCS-091406 Biochemical Oxygen Demand 167 mg/L 200 < 2 84 80 120 mg/L 0609809-009DMS 0609809-009DDUP MW-5SDUP Biochemical Oxygen Demand 18 mglL mg/L 5 0.5 106 75 1.25 16 11.8 20 MB -092906 MB -092906 Bromide < 0.5 mg/L LCS-091806 Chemical Oxygen Demand 967 LCS-092906 ILCS-092906 Bromide 4.7 mg/L 5 < 0.5 94 80 120 _ mg/L 0609809-009DMS MW-5SMS Bromide 5.8 mg/L 5 0.5 106 75 1.25 mg/L – 0609809-009DDUP MW-5SDUP Bromide 0.6 mg/L 1 0.5 18.2 20 MB -091806 MB -091806 IChemical Oxygen Demand <10 mg/L LCS-091806 LCS-091806 Chemical Oxygen Demand 967 mg/L 1000 < 1.0 97 80 120 –� 0609809-009CMS MW-5SMS IChemical Oxygen Demand 988 mg/L 1000 <10 99 75 125 0609809-009CDUP MW-5SDUP IChemical Oxygen Demand < 10 mg/L – i <10 20 MBl-091506 MBI -091506 Chloride < 2 mg/L LCS1-091506 LCS1-091506 Chloride 50.3 mglL 50 <2 101 80 120 0609809-009DUP MW-5SDUP Chloride 29.9 mg/L 29.5 1.3 20 0609809-009DMS MW-5SMS Chloride 56.6 mg/L 25 29.5 108 75 125 TSL007 S59 QC SUMMARY REPORT SDG: TSL007 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC- Limits Value %RPD _UCL --�- T MB -92006 MB -92006 Hardness (As CaCO3) <5 mg/L - - mg/L -^�- - LCS-92006 LCS-92006 Hardness (As CaCO3) 1030 mg/L 1000 < 5 103 80 120 1.00 5.91 mg/L 1- mg/L 5 0609809-009Bms MW-5SMS Hardness (As CaCO3) 492 mg/L 400 84.0 102 75 125 - Nitrogen, Ammonia (As N) 0609809-009Bdup MW-5SDUP Hardness (As CaCO3) 88.0 mg/L _ _ 84.0 4.6 20 MB -092106 MB -092106 Nitrate as N < 0.1 mg/L Ammonia (As N) <0.1 mg/L mg/L LCS-092106 LCS-092106 Nitrate as N 1.19 mg/L 1.13 < 0.1 105 80 1120 1.00 5.91 mg/L 1- mg/L 5 0609809-009CMS MW-5SMS Nitrate as N 4.66 mg/L 2.5 2.18 99 75 125 - Nitrogen, Ammonia (As N) 0609809-009CDUP LMW-5SDUP Nitrate as N 2.18 mg/L mg/L - _ _ 2_18 - 0 - 20 MB -18403 MB -092606 1Nitrogen, Ammonia (As N) <0.1 mg/L mg/L LCS-092906 LCS-092906 Sulfate - LCS-18403 - LCS-092606 0609809-009CMS MW-5SMS Nitrogen, Ammonia (As N) Nitrogen, Ammonia (As N) 1.00 5.91 mg/L 1- mg/L 5 < 0.1 100 0.40 110 80 1120 75 1125-- 4.1 < 0.1 95 0609809-009CDUP MW-5SDUP Nitrogen, Ammonia (As N) 0.40 mg/L Nitrogen, Kjeldahl, Total - 0.40 0 20 MB -18304 MB -091906 Nitrogen, Kjeldahl, Total 0.1 mg/L LCS-092906 LCS-092906 Sulfate - LCS-092006 IlPhenolics, Total Recoverable LCS-18304 LCS-091906 Nitrogen, Kjeldahl, Total _< 3.91 mg/L 4.1 < 0.1 95 80 120 -� ug/L 0609809-009CMS MW-5SMS Nitrogen, Kjeldahl, Total 5.55 mg/L 4.1 1.37 102 75 125 _ 0609809-009CDUP MW-5SDUP Nitrogen, Kjeldahl, Total 1.35 mg/L 1.37 1.5 20 MB -092006 MB -092006 lPhenolics, Total Recoverable <5 ug/L 11 LCS-092906 LCS-092906 Sulfate LCS-092006 LCS-092006 IlPhenolics, Total Recoverable 28.6 ug/L 30 < 5 95 80 1120 0609809-009DMS MW-5SMS Sulfate 146 0609809-009Cms MW-5SMS Phenolics, Total Recoverable 19.4 ug/L 20 < 5 97 751 125 48.5 mg/L 0609809-009Cdup MW-5SDUP Phenolics, Total Recoverable < 5 ug/L < 5 20 MB -092906 MB -092906 Sulfate < 5 mg/L LCS-092906 LCS-092906 Sulfate 18.9 mg/L 20 < 5 94 80 120 0609809-009DMS MW-5SMS Sulfate 146 mg/L 100 47.5 98 75 125 0609809-009DDUP MW-5SDUP Sulfate 48.5 mg/L _ 47.5 2.1 20 TSL007 S60 QC SUMMARY REPORT SDG: TSL007 Spike Sample Recovery RPDRef %RPD _- Sample ID: __Client Sample ID: Analyte Result Units Amount Result %REC Limits _ Value%RPD UCL ^-- M13-091806 MB -091806 Total Dissolved Solids <10 mg/L 25 <1 96 1 80 { 120 0609809-009AMS MW-5SMS Total Organic Carbon LCS-091806 LCS-091806 u� Total Dissolved Solids 306 mg/L 300 < 10 102 80 120 < 1 0609809-009DMS MW-5SMS Total Dissolved Solids 511 mg/L 300 166 115 75 125 0609809-009DDUP MW-5SDUP Total Dissolved Solids 175 mg/L 166 5.3 20 MB -100206 — MB -100206 Total Organic Carbon LCS-100206 LCS-100206 Total Organic Carbon < 1 24.1 mg/L mg/L 25 <1 96 1 80 { 120 0609809-009AMS MW-5SMS Total Organic Carbon 9.9 mg/L 10< 1 _� 75 1125 1 99 20 0609809-009ADUP MW-5SDUP Total Organic Carbon < 1 mg1L < 1 TSL007 S61