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Home My WebLink AboutMetal Data Package 12/2006Analytical Data Package For TOWN OF SOUTHOLD PART 360 ROUTINE SDG NO: TSL006 Water Samples Received: 12/6/06 ►i 1:1 11F."I 0 MITI IF.111 DECEMBER 2006 EInvironmental Testing Laboratories 575 Broad Hollow Road, Melville, N.Y. 11747 u2M LABS LNC. ANALYTICAL DATA PACKAGE TABLE OF CONTENTS TOWN OF SOUTHOLD PART 360 ROUTINE WATER SAMPLES SAMPLES RECEIVED: 12/6/06 SDG NO.: TSI -008 I. NYS DEC SUMMARY FORMS II. SDG NARRATIVES III. CHAIN OF CUSTODY DOCUMENTATION IV. ANALYTICAL DATA PACKAGE A. VOLATILES B. METALS C. WET CHEMISTRY DATA PACKAGE FOR CLIENT INFORMATION PURPOSES ONLY U2M "US-, INC. I. NYS DEC SUMMARY FORMS I NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE IDENTIFICATION AND ANALYTICALREQUIREMENT SUMMARY SDG: DMT029 Customer Laboratory Sample Sample ccvoA Code Code _ JWWP 0612989-001 x BLANK112 206112120613 ITRI0612989-002 ^X j CLP, Non -CLP (Please indicate year of protocol)��. i olq! CILL i212kj6,� Analytical Requirements M 00 O O. N NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG: TSL008 INORGANIC ANALYSIS Laboratory Samp ID I Client Sample ID Matrix Metals Requested DateRecd at Lab Date Analyzed 0612702-001 IEB WATER CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 12/06 0612702-002 IMW-3D WATER I CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 I 12/06 0612702-003 IMW-3S i WATER I CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -061 12/06 0612702-004 (MW -4D WATER I CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 12/06 0612702-005 IMW-4S WATER I CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -061 12/06 0612702-006 !MW -5D I WATER CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 12/06 0612702-006DUP IMW-5DD I WATER ( CA,CD,FE,K,MG,MN,NA,PB, 106 -Dec -06 12/06 0612702-006MS IMW-SDS WATER I CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 12/06 0612702-007 IMW-5S WATER I CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 12/06 0612702-008 MW -6D WATER I CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 12/06 0612702-009 IMW-6S I WATER I CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 I 12/06 0612702-010 IMW-8D WATER' I CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 12/06 0612702-011MW-8S WATER CA,CD,FE,K,MG.MN,NA,PB, 06 -Dec -06 0612702-012 ISOUTHHOLD2 I WATER CA,CD,FE,K,MG,MN,NA,PB, i 06 -Dec -06 12/06 0612702-013 PB I WATER CA,CD,FE,K,MG,MN,NA,PB, f 06 -Dec -06 12/06 TSL008 A4 NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG: TSL008 INORGANIC ANALYSIS 1 Laboratory Samp ID I I +Client Sample ID Matrix + Tests I DateRec d at Lab I Date Analyze 0612702-001 ; EB i Blank I SELECT WET CHEMISTRY * 12/06/06 12/06 0612702-002 I MW -3D i Groundwater SELECT WET CHEMISTRY " I 12/06/06 12/06 0612702-003 i MW -3S Groundwater SELECT WET CHEMISTRY 12/06/06 12/06 0612702-004 MW -4D Groundwater i SELECT WET CHEMISTRY ** i 12/06/06 I 12/06 0612702-005 MW -4S I Groundwater SELECT WET CHEMISTRY ** 12/06/06 ' 12/06 0612702-006 f MW -5D Groundwater I SELECT WET CHEMISTRY *' 12/06/06 12/06 0612702-006DUP I MW-5DDUP Groundwater I SELECT WET CHEMISTRY ** I 12/06/06 ' 12/06 0612702-006MS I MW-5DMS Groundwater SELECT WET CHEMISTRY ** 12/06/06 12/06 0612702-007 I MW -5S i Groundwater SELECT WET CHEMISTRY ** I 12/06/06 12/06 0612702-008 MW -6D Groundwater I SELECT WET CHEMISTRY *" ` 12/06/06 I 12/06 0612702-009 i MW -6S Groundwater SELECT WET CHEMISTRY ** 12/06/06 I 12/06 0612702-010 MW -8D Groundwater I SELECT WET CHEMISTRY ** I 12/06/06 12/06 0612702-01.1 MW -8S Groundwater SELECT WET CHEMISTRY ** 12/06/06 12/06 0612702-012 I SOUTHHOLD 2 Groundwater I SELECT WET CHEMISTRY ** 12/06/06 I 12/06 0612702-013 I FB I Field Blank SELECT WET CHEMISTRY ** 12/06/06 I 12/06 ** Alkalinity, Total (As CaCO3) ; Biochemical Oxygen Demand; Bromide; Chemical Oxygen Demand; Chloride; Hardness (As CaCO3) ; Nitrate as N ; Nitrogen, Ammonia (As N) ; Nitrogen, Kjeldahl, Total ; Phenolics, Total Recoverable ; Sulfate ; Total Dissolved Solids ; Total Organic Carbon ; >n 00 O O C/) F-+ u2M "U%S INC. SDG NARRATIVES U2A4 LAOS' Isco For Sample: SDG NARRATIVE FOR METALS SAMPLE RECEIVED: 12/6/06 SDG#: TSL008 EB MW -51) MS/MSD MW -8D MW -31) MW -5S MW -8S MW -3S MW -6D SOUTHHOLD 2 MW -4D MW -6S FB MW -4S Thirteen water samples were received by H2M Labs, Inc. on 12/6/06 for analysis of a select list of metals. Samples were prepared and analyzed using EPA method 6010B with a TJA 61E Trace ICP Instrument. Sample MW -5D was utilized for QC analysis and reporting. Sample MW -3S was reanalyzed at a dilution for manganese to keep instrument readings within the calibration range. No other problems were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: December 19, 2006 h= :F�,L•x�sc >,:xx:F �.Jc �'c �'c �;.xs': •x, r:;t�x Ursula Middel Technical Manager U2M "US, 1 %Co For Samples: SDG NARRATIVE FOR WET CHEMISTRY SAMPLE RECEIVED: 12/6/06 SDG#: TSL008 EB MW -6D MW -3D MW=6S MW -3S MW -8D MW -4D MW -8S MW -4S SOUTHHOLD 2 MW -5D FB MW -5S Thirteen water samples were received by H2M Labs, Inc. on 12/6/06 for select wet chemistry analysis. Samples were prepared and analyzed using the following methods: PARAMETER METHOD # PARAMETER METHOD # Alkalinity EPA 310.1 Nitrate EPA 353.2 BOD EPA 405.1 Phenols EPA420.1 Bromide EPA 320.1 Sulfate EPA 9038 Chloride EPA325.2 TDS EPA 160.1 COD EPA 410.4 TKN -EPA 351.2 Hardness EPA 130.2 TOC EPA 9060 Ammonia EPA 350.1 Sample MW -5D was utilized for duplicate and spike QC analysis and reporting. Duplicate analysis did not reproduce within acceptance ranges for biological oxygen demand (BODS) of ± the CRDL of 2 mg/L. Batch acceptance was based on LCS standard analysis. Initial TKN spike analysis did not recover within acceptance range. The sample group was diluted, redigested and reanalyzed. The reanalysis recovered acceptably. Samples were diluted and reanalyzed as required to keep instrument readings within calibration ranges. No other problems were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: December 28, 2006 V / 00 Vincent Stancampiano Vice President °O O O u2M "U%S INC. III. CHAIN OF CUSTODY DOCUMENTATION I A" INC __� u_u—... DJ u..t..tt1•. �lV./47/7_IJf7R 1�1 EXTERNAL CHAIN OF CUSTODY Tel. (631) 694-3040 Fax: (631) 420-8436 CLIENT: H2M SDG 'NO: ) SL oU PROJECT NAMEINUMBERAl NOTES: Project Contact 3 Phone Number: a N AM ` PIS/Quote # SAMPLERS: (signatureyClient t J DELIVERABLES: c g ci �► ANALYSIS REQUESTED TURNAROUND TIME: ORGANIC ✓' INORG. , a a 0rh 3 z U LAB I.D. NO.- REMARKS: DATE- TIME MATRI FIELD I.D. t -i,1' 1;,� oc, � V•! :a pskZ� ! t 3 t — �O �z "I a -�� Li 31(l—� nns e�ss7 !�1 ! - S 3 1 1 )13 od2 Z t, ; : a�w�. .:;� z a — Z Relinquished try (stgnaaue) ....,._.._. -_ Date Time lRaceived by. (Signature) Date - Time LABORATORY USE ONLY tiJ( Discrepancies Beteenwwere: ;:1 \o< Sample labels and 1. or Z Shipped_ NHand DelNered_Alrbi{h� 2 Ambient Or chiiled, Temp ReIlllqulshad by; (Signature) Date Time Received try: (signature) Date Time COC Record? Y or N 3. Received in good condition: Y or N Explain: 4. Property preserved: Y or N COC Tape was: Reunquisy:ign hed b(Signature) Date Time Received by. (signature) Date Time t. Present on outer package: Y or N 2. Unbroken on outer package: Y or N 3. COC record present 3 complete upon sample receipt. Relinquished by. (Signature) Date Time Received try (Siprature) Date Time YorN Tj lPlz' F'RP1Yo- ORIGINAL YELLOW COPY - CLIENT PINK COPY - LABORATORY IMC r..w a 1J../6r..0 Oil Asandlln A1V 447A7_JW7R EXTERNAL CHAIN OF CUSTODY • -Tel. (631) 694-3040 Fax: (631) 420-8436 CLIENT: H2M SDG NO: (c,Lia PROJECT NAME/NUMBER N rY ` ? r� �'� S NOTES: Project Contact: Phone Number: PIS/Quote # SAMPLERS: (signatureClient DELIVERABLES: c g 8 �► ANALYSIS REQUESTED TURNAROUND TIME: -ORGANIC , ' i\ - INORG. . DATE, TIME MATRIX FIELD I.D. 7 0— �d) F� U LAB I.D. NO. REMARKS: ?, L iDD Reiffgfi6d by. (Signature) :::: = Date �t-li�c�' Time a ,ri Received try: (Sgnature) �/j •' -- Date Ai hjll� Tim I �": 5, LABORATORY USE ONLY Discrepancies Between Sample labels and COC Record? Y or N Explain: sacral" e: 1. or H Ambtent or chilled mp Delivered_Atrbiifx 2 SNpped 3. Received in good condition: Y or N 4. Pmperly preserved: Y or N CDC Tape w9c i. Present on outer package: Y or N 2 Untxoksa on Qatar package: Y or N 3. COC record prpaent b complete upon sample receipt: YorN Relinquist>ad try. (signature) Date Time Received by: (Signature) Date Time Relinquished by: (Signature) Date Time Received by: (signature) Date Time Relinquished by: (Signature) Date Time Received by: (Signature) Date Time WHITE COPY — ORIGINAL YELLOW COPY — CLIENT PINK COPY — LABORATORY TSL008 A11 H2M LABS, INC. Client Name PCTSL Work Order Numbe 0612702 I > /_ cc �:' C/- Sample Receipt Checklist Date and Time Receive 12/6/2006 4:50:00 PM Received by CDS Checklist completed by �1 -� 1�lele Reviewed by U Signature D le Initials oatla Matrix: Carrier name Hand Delivered Shipping container/cooler in good condition? Yes C No ❑ Not Applicable ❑ Custody seals intact on shippping container/cooler? Yes ❑ No ❑ Not Applicable Custody seals intact on sample bottles? Yes ❑ No ❑ Not Applicable 0 Chain of custody present? Yes No ❑ Chain of custody signed when relinquished and received? Yes ❑O No U Chain of custody agrees with sample labels? Yes No ❑ Samples in proper container/bottle? Yes No ❑ Sample containers intact? Yes No ❑ Sufficient sample volume for indicated test? Yes No ❑ II samples received within holding time? Yes No ❑ _ontainer/Temp Blank temperature in compliance? Yes 0 No ❑ Water - VOA vials have zero headspace? No VOA vials submitted ❑ Yes I./] No ❑ Water - pH acceptable upon receipt? Yes ❑d No ❑ Adjusted? Checked b Any No and/or NA (not applicable) response must be detailed in the comments section be --------------------------------------------- - — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — - Client contacted _ Date contacted: tL't, L Person contacted Contacted by:t^Regarding: �— Comments: or -/D ()NI 1 S Corrective Action N 00 O 1.4 O Ln E-+ INTERNAL CHAIN OF CUSTODY _.. ICLIENT: i'�TSL DELIVERABLES: S —70 b TURN AROUND TIME:) a _ SDG #: TSS bOV CASE #: MATRIX: G,►,d►,ojel pH CHECK Y a N REMARKS: _Pi- 5 4 PCTs L- 0 s RECEIVED BY: i SIGNATURE: r/� — DATE:1 d L TDAE: %SO CLIENT ID � H2M LAB # oG)�-ta1 DATE COLLECTED BOTTLE TYPE 9 O BOTTLES TESTS REQUESTED �� CE Li_ Pte' Ali- 3D - E - A lJ- 3/lS1n clo E iz o M ij' -L. S o o s e , 41 Glo 'Vt�J o 006p 2- I LAme3 '• SS M lJ -ooZE �- �nl./ / M"VfV� evF� " / " L✓v g o to r ti -2 oto E . t f 0139 K 6 aG M A n .= A METALS P 0295 Z'/ v-�' UAB,. CLIENT:—Pc,fs,L SDG #: TgLooy .INTERNAL CHAIN OF CUSTODY I I METALS P 029,G SAMPLE PURPOSE OF RELINQUISHED SAMPLE PLE BOTTLE CHANGE OF DATE .TIHH BY RECEIVED BY TYPE CUSTODY INIT tl 1121041 IT41- slow 6S 4::: �— aI 33 1000 t lo 411 &4 6� 1-j W-rjL, �oo oll sIOii930Y slow SION SIGN IGN Siam SIGN slow SIGN SxOm SIGN slow SIGN • SION SIGN SION Siam SION SIGN SIGH SION SIGN slow SION slow SIGN slow SION SIGN SIGN SIGN SIGH slow SIGH SI ON SIGN 3 am SIGH SION SIGH I METALS P 029,G U28t UAIA9 INC, INTERNAL CHAIN OF CUSTODY CLIENT: PC T St- DELIVERABLES: 3S 77o 13 TURN AROUND TIME: SDG #: —FS C, oa CASE #: MATRIX: G+ti(%k dLf pH CHECK Y or N REMARKS: P t S G q a PC -Fs(- o S- — RECEIVED BY: i SIGNATURE: 6A 01l DATE: I 1 C QGTQvSE: � L• Lo CLIENT 1D H2M LAB 11 DATE COLLECTED BOTTLE TYPE N OF BOTTLES TESTS REQUESTED p' -I 3 I o (-- jo6C)_ w o� Fv C_0p_U,NN?--, _v PNENo1-s_ v TK// -u • valO � JLIC_U ib ns—U, aR_t/ ct—v So�I_U_5cs/ D � oul Aacn A5A�,vc As A-�,v,,,— . ' / yu ` q b &.q ka 0 0 do --L2- off 0 flARCE1 5 „ /UI J :- 9 D otoAR col c I ,' is ., WET CHEMISTRY M P 0235 I I r CLIENT: FCTSL SIDG J -71-L �Clos INTERNAL CHAIN OF CUSTODY WET CHEMISTRY P 0236 . I JF(,, cs� ILS/t7t, �l _ J�'��r ./� r.�.I�.7�� ow Mff Alk 31 WET CHEMISTRY P 0236 FLAUS, INC. CLIENT: PcTs t, SDG t: -r5 L (1) 1 INTERNAL CHAIN OF."CUSTODY WET CHEMISTRY P 0237 BOTTLE PURPOSE OF CHANGE OF "SAMPLE RE INQUISHED INQ SAMPLE CUSTODY INIT RECEIVED By TYPE DATE TIME B BY SION, ;I 31 SIGN . DIOai fixorA 'Slow SIGN SION IOU SION SICH tE.. BIOY 9I Wi BION Blou SlOw SIGH ICH -,AZ SIGH SIO" SIGH SIGH S] SiH SIGN IGH S SIGN LION SIGN 91011SIGN SION SIGH SION SIGH 31018 yI SIGH SION SIGH 1011 1. SIGH SIGH BION SIGN WET CHEMISTRY P 0237 U2/4 "US, INC. IV. ANALYTICAL DATA PACKAGE A. VOLATILES B. METALS C. WET CHEMISTRY Oo 00 0 0 U2M 1_A►I3S� INC. 15 LOob METALS TABLE OF CONTENTS I. REPORTS IL QC SUMMARY III. RA1ji11 DATA IV. DOCUMENTATION U.S. EPA - CLP COVER PAGE - INORGANIC ANALYSES DATA PACKAGE Lab Name: H2M LABS, INC. Lab Code: 10478 Case No SOW No.: ILM04.1 EPA Sample No. EB FB MW -3D MW -3S MW -4D MW -4S MW -5D MW-5DD MW-5DS MW -5S MW -6D MW -6S MW -8D MW -8S Contract: SAS No.: SDG No.: TSL008 Lab Sample ID. 0612702-001 0612702-013 0612702-002 0612702-003 0612702-004 0612702-005 0612702-006 0612702-006DUP 0612702-006MS 0612702-008 0612702-009 0612702-011 Were ICP interelement corrections applied? Yes/No YES Were ICP backqround corrections applied? Yes/No YES If yes -were raw data generated before application of background corrections? Yes/No NO Comments: Date Reported: 12/12/2006 I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package and in the computer -readable data submitted on diskette has been authorized by the Laboratory Manaqer or the Manaqer's desiqnee, as verified by the following signature Signature: _ Name: Vincent Stancampiano Date: Title: Vice President — COVER PAGE - IN ILM04.1 U2M "USs INC. REPORTS FOR METALS U2M "U%s INC. QUALIFIERS FOR METALS ANALYSIS Q (Quality Control) Qualifiers E - The reported value is estimated because of the presence of interference. An explanatory note is included in the SDG narrative. M - Duplicate injection precision not met. N - Matrix spike sample recovery not within control limits. S- The reported value was determined by the Method of Standard Additions (MSA). + - Correlation coefficient for the MSA is less than 0.995 W - Post digestion spike for Furnace AA analysis is out of control limits (85- 115%), while sample absorbance is less than 50% of spike absorbance. * - Duplicate analysis is not within control limits. C (Concentration) Qualifiers B - Entered if the reported value is less than the Contract Required Detection Limit (CRDL) but greater than the Instrument Detection Limit (IDL). U - Entered if the analyte was analyzed for but not detected, i.e., less than the IDL. M (Method) Qualifiers P - Analyzed by ICP. M - Analyzed by ICP -MS A - Analyzed by Flame AA. F - Analyzed by Furnace AA. CV - Analyzed by Manual Cold Vapor techniques. AV - Analyzed by Automated Cold Vapor techniques. C - Analyzed by Manual Spectrophotometric Method. CA- Analyzed by Midi -distillation Spectrophotometric Method. NR- Analyte not Required. 00 0 0 E� U.S. EPA - CLP % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. I Analyte Concentration C� 7440-43-9 (Cadmium 1.11 B, Q M �� 1 EPA SAMPLE NO 7439-89-6 Iron �— 28 1�B INORGANIC ANALYSIS DATA SHEET —� 7439-95-4 (Magnesium r _ 21.6 B( (7439-96-5 Manganese 1.1 B P i 7440-09-7 Potassium___ R - 84.6 B .7440-23-5 Isodium 76.3 B EB Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Matrix (soil/water): WATER Lab Sample ID: 0612702-001 Level (low/med)• LOW Date Received: 12/6/2006 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. I Analyte Concentration C� 7440-43-9 (Cadmium 1.11 B, Q M �� !7440-70-2 Calcium 66.3! B_I P 7439-89-6 Iron �— 28 1�B ----�� P 7439-92-1 Lead 1.5 U j P 7439-95-4 (Magnesium r _ 21.6 B( (7439-96-5 Manganese 1.1 B P i 7440-09-7 Potassium___ R - 84.6 B .7440-23-5 Isodium 76.3 B P 1 P II Color Before: COLORLESS_ Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 00 O O C/1 E-� U.S. EPA - CLP Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte ConcentrationjC) 1 EPA SAMPLE NO � INORGANIC ANALYSIS DATA SHEET ^— i 75400{ P ' 7439-89-6 MW -3D i Lab Name: H2M LABS, INC. Contract: Lead { 1pagnesium 1.5; U I Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Matrix (soil/water): WATER Lab Sample ID: 0612702-002 Level (low/med): LOW Date Received: 12/6/2006 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte ConcentrationjC) --1—� Q ! M 7940-43-9 ,Cadmium � -T— _ 0.281 —U -T- �— 17440 -70-2 17f 440-70-2 Calcium 4 -----64101 75400{ P ' 7439-89-6 Iron �— l— P '17439-92-1 Lead { 1pagnesium 1.5; U I { P P 17439-95-4 7439-96-5 i (Manganese i 338001 j_ — 4040 .7440-09-7 jPotassium 131000 I- P 17440-23-5 ISodium �_ 22100010 I P_l Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 00 O O Cn U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: Solids: 0_0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. 1 Analyte �Concentration.0 Q M i I 17440-43-9 jCadmium 1. 8!, B 7440-70-2 —.I 'Calcium + 5 + 74001 P 1 7439-89-6 IiIron 7439-92-1 (Lead 68900! s P 1.51 U _P +74_39-95-4 'Magnesium 25200; j ( P I 17439-96-5 IlManganese _( 235001 P 17440-09-7 iPotassium I _ 430011-1— ^I i P 17440-23-5 ISodium — 53300 I l— — EPA SAMPLE NO MW -3S SDG No.: TSL008 12/6/2006 Color Before: BROWN Clarity Before: CLOUDY Texture: Color After: COLORLESS Clarity After: CLEAR — Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 00 O O U.S. EPA - CLP Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET ------ Calcium —__--- 58800 MW -4D Lab Name: H2M LABS, INC. Contract: -i P i Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Matrix (soil/water): WATER Lab' -Sample ID: 0612702-004 Level (low/med): LOW Date Received: 12/6/2006 % Solids: 0_0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.42iB ; P 7490-70-2 Calcium —__--- 58800 P 7439-89-6 (Iron _+- 622 P i 7439-92-1 (Lead 4.01 P 7439-95-4 ,74� 39-96-5 7440-09-7 jMagnesium (Manganese Potassium _ 202001 ( 9640 —_I I 44800! ( P PP ( P 7940-23-5 �Sodium_� 192001 —1 P Color Before. COLORLESS_ Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 00 00 O O h U.S. EPA - CLP Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. ! Analyte 1 EPA SAMPLE NO 7940-43-9 INORGANIC ANALYSIS DATA SHEET ; 7440-70-2 (Calcium 114000 MW -4S I Lab Name: H2M LABS, INC. Contract: P x7439-92-1 Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Matrix (soil/water): WATER Lab Sample ID: 0612702-005 Level (low/med): LOW Date Received: 12/6/2006 % Solids: 0.0 j P 17440-23-5 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. ! Analyte 1 Concentration I C I Q M 7940-43-9 Cadmium �- 0.28 U P 7440-70-2 (Calcium 114000 { P ; 17439-89-6 ;Iron T 394 P x7439-92-1 ;Lead 1. 5j U P (7439-9'41, Magnesium 56500 I P 7439-96-5 (Manganese 2880 ! j P j 17440-09-7 {Potassium I 129000 j P 17440-23-5 ISodium � _ 2200001 1 Color Before: COLORLESS Clarity Before: CLEAR _ Texture: Color After: COLORLESS Clarity After: CLEAR - Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 00 O O N U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET - -—"--"�--? MW -5D Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Matrix (soil/water): WATER Lab Sample ID: 0612702-006 Level (low/med): LOW Date Received: 12/6/2006 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. �-Analyte 1 Concentration C f Q ! M 7440-43-9 ;Cadmium 0.3.5 P 117440-70-2 7439-89-6 ICalcium 1 1Iron j 89000 ; P 1280 — P 7439-92-1 ;Lead_ _ i _ 2.61B; P X7439-95-4 [Magnesium628001 1—d P [7439-96-5 !Manganese 1 11900 ( P 1 17440-09-7 (Potassium ( _ 139000 P 1 194000 P� 7440-23-5 Isodium _ Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 O 00 O O N U.S. EPA - CLP Solids: 0_0 { Concentration Units (ug/L or mg/kg dry weight): UG/L ECAS No. i Analyte 'iConcentration C Q M 1 EPA SAMPLE NO 0.281U INORGANIC ANALYSIS DATA SHEET ;- P j7439-89-6 Iron j MW -5S Lab Name: H2M LABS, INC. Contract: 7.1 i P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Matrix (soil/water): WATER Lab Sample ID: 0612702-007 Level (low/med)• LOW Date Received: 12/6/2006 Solids: 0_0 { Concentration Units (ug/L or mg/kg dry weight): UG/L ECAS No. i Analyte 'iConcentration C Q M F7440-43-9 (Cadmium 0.281U I P I7-440-70-2 lcalcium 160.00 P j7439-89-6 Iron 81701 1 ! P Artifacts: 7.1 i P 17439-92-1 !Lead 7439-95-4 iMagnesium i 131001 ! P ' 17439-96-5 (Manganese 2460 P 7440-09-7 !Potassium 84001 14100, ! P I P :7440-23-5 i !Sodium !------� -- _ IT -J Color Before: BROWN Clarity Before: CLOUDY Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 00 O O C� U.S. EPA - CLP Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L r——�1 kCAS No. ( Analyte I I j Concentration ! C i Q 1 EPA SAMPLE NO 0.78B�— INORGANIC ANALYSIS DATA SHEET 44200" j P I 7439-89-6 Iron 28601 MW -6D 4 Lab Name: H2M LABS, INC. Contract: 17439-95-4 ,Magnesium 15300; I Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Matrix (soil/water): WATER Lab Sample ID: 0612702-008 Level (low/med): LOW Date Received: 12/6/2006 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L r——�1 kCAS No. ( Analyte I I j Concentration ! C i Q M I 7440-43-9 Cadmium 0.78B�— Pyi 7440-70-2 Calcium 44200" j P I 7439-89-6 Iron 28601 i P� 7439-92-1 Lead i 1.5; U j T_P 17439-95-4 ,Magnesium 15300; I P 17439-96-5 jManganese 7940; i i P- 17440-09-7 !Potassium 1 58301 1 17440-23-5-Lodium A_�_ 20300 _ ! P� f j I Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: - Date Reported: 12/12/2006 FORM I - IN ILM04.1 U.S. EPA - CLP Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L i C No Analyte 1 EPA SAMPLE NO 17440-43-9 INORGANIC ANALYSIS DATA SHEET j — (7440-70-2 !Calcium _i 19800, - MW -6S Lab Name: H2M LABS, INC. Contract:_— P i 17439-92-1 Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Matrix (soil/water): WATER Lab Sample ID: 0612702-009 T---1 (low/med)• LOW Date Received: 12/6/2006 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L i C No Analyte Concentration C i Q 17440-43-9 !Cadmiumj 0..28! U P (7440-70-2 !Calcium _i 19800, - I P iP t 7439-89-6 !Iron ! 296001 P i 17439-92-1 ',Lead _ 12.21 ( ! P _i7.9107439-5-4 ium - P 17439-96-5 !Manganese 5460; ` P 744040-09-7-7 Potassium 120001 ! P _i 7440-23-5 ',Sodium _' 33201B I P� Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: CLEAR Comments: orted: 12/12/2006 Texture: Artifacts: FORM I - IN ILM04.1 M 00 O O C/) E--+ U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET T" MW -8D 1 Lab Name: H2M LABS, INC. Contract: i Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Matrix (soil/water): WATER Lab Sample ID: 0612702-010 Level (low/med): LOW Date Received: 12/6/2006 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L ------------------- CAS No. ! Analyte Concentration 1 C Q M I 1 7440-43-9 17440-70-2 ]Cadmium Calcium — I 0.28]0 ' P 63400' I P 7439-89-6 iIron 2060 1 P 7939-92-1 _ ILIL aed 1.5I U P 7439-95-4 ]Magnesium 1 35700] I P 1 — —! 17439-96-5 Manganese 7490-09-7 Potassium 1890 P I 1 87700 P 1 244Q --?2-5 ]Sodium 753001 � P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 d' 00 O O V) H U.S. EPA -'CLP Concentration Units (ug/L or mg/kg dry weight): CAS No. Analyte Concentration I C 4 1 EPA SAMPLE NO 0.2811 U INORGANIC ANALYSIS DATA SHEET - P ; 7439-89-6 ;Iron 936 00 ; MVI -8S Lab Name: H2M LABS, INC. Contract: j 1, 247001 Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Matrix (soil/water): WATER Lab Sample ID: 0612702-011 Level (low/med): LOW Date Received: 12/6/2006 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): CAS No. Analyte Concentration I C 4 ; M {74_40-43-9 Cadmium 0.2811 U P i 0744_0-70-2 !Calcium _ - r---., __ _ 801001 ! P ; 7439-89-6 ;Iron 936 00 ; P j !47 39-92-1 1Lead _ _ 2.21 B P 7439-95-4 Imagnesium 1, 247001 P 439-96-5 jmanganese 779E �_ -- —— P 17440-09-7 ?Potassium 25800 ! I P 7 44 0-23-5 Sodium 32300 P Color Before: BROWN Clarity Before: CLOUDY Color After: YELLOW Clarity After: CLEAR Comments: Date 12/12/2006 UG/L Texture: Artifacts: FORM I - IN ILM04.1 00 O O F-+ U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix ('soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L I CAS No. f Analyte Concentration I C( Q M IIIIII 7440-43-9 1Cadmium-__j 0.281 U j i P } 17_440-70-2 jCalcium - 77100 _j_ j P J 7439-89-6 I Iron 6580 P 7439-92-1 ILead 1.5j U P I 7439-95-4 }Magnesium 34400; P 17439-96-5 IManganese j 41201 j P_� 7440-09-7 Potassium ; 1320001 P , i P - 7440-23-5 Sodium 2230001 EPA SAMPLE NO SOUTHHOLD 2 J SDG No.: TSL008 12/6/2006 Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 i 00 O O C/] H U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID Level (low/med): LOW Date Received % Solids: 0_0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte y 1 Concentration + C !! I i Q M I �7a40=43-9 �Ca�dmium---j 0.281[ U ! �_ 17440-70-2 ;Calcium 80.41 B j P 17439-89-6 Iron10. 5i U I P I -� P- 1[7439-92-1 !7439-95-4 ,Lead —; IMagnesium 1.5 U 1 15.51[ B�--` P— ;7439-96-5 !Manganese 1.81 B I 7440-09-7 jPotassium j 117 Bj 158, BT_—_ r i p 7440-23-5 {Sodium j EPA SAMPLE NO FB 1 SDG No.: TSL008 12/6/2006 Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 r- 00 O O C/1 u2M "uss 1NC. II. QC SUMMARY FOR METALS A. INITIAL AND CONTINUING CALIBRATION VERIFICATION B. CRDL STANDARD FOR AA AND ICP C. METHOD BLANK D. ICP INTERFERENCE CHECK SAMPLE E. SPIKE SAMPLE RECOVERY F. POST DIGEST SPIKE SAMPLE RECOVERY G. DUPLICATES H. LABORATORY CONTROL SAMPLE I. STANDARD ADDITION RESULTS J. ICP SERIAL DILUTIONS K. INSTRUMENT DETECTION LIMITS L. ICP INTERELEMENT CORRECTION FACTORS M. ICP LINEAR RANGES N. PREPARATION LOGS O. ANALYSIS RUN LOGS 00 00 0 0 F+ U.S. EPA - CLP 2A - INITIAL AND CONTINUING CALIBRATION VERIFICATION Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Initial Calibration Verification Source: MV Labs/High Purity Continuing Calibration Verification Source: MV Labs/High Purity Concentration Units: ug/L -----r-- Initial Calibration { Continuing Calibration ---Tr- Analyte i True Found %R(1) True Found %R(1) Found %R(1) j M! !cadmium 2500.0 j 2522.22 12500.0 12540.90 101.6 2568.53 102.7 P I (Ccium al (50000.0 5053_ _10_0.9 101.1 50000.0! 51249.03 1102.5i 51363.43 ( 102.7 P Iron X50000.0 50183,85 100.4 50000.01 50632.46 ( 101.3 50998.16 ! 102.0 P Lead E 500.0 493.50 98.7 500.0 500.77 100.2 501.39 100.3 i P Magnesium 150000.0 52510.13 105.0 150000.0 53239.86 106.5 ! 53233.48 { 106.5 P Manganese 2500.0 2529.33 101.2 1 2500.0 2547.01 ; 101.9 2564.11 10� 2 6 �i P i 1.Potassium (800.00.0 83953.67 104.9 !80000.0 _84092.73 ! 105.11 84591.97 105.7 P I !Sodium X80000.0 80914.56 101.1 80000.0 81312.93 101.6 i 81623.61 ! P - i 1102.0 (1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115 00 O O FORM II (Part 1) - IN ILM04.1 U.S. EPA - CLP 2A INITIAL AND CONTINUING CALIBRATION VERIFICATION Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Initial Calibration Verification Source: MV Labs/High Purity Continuing Calibration Verification Source: MV Labs/High Purity Concentration Units: ug/L Initial l Analyte f True Calibration ( Found %R(1) i True Continuing Calibration Found %R(1) Found %R(1) ? M Cadmium -� _1_ Calcium Iron I j � 2500.0 2587.23 j 50i 0_00.0 51622.42 _ 50000.0 51173.70 j 103.5 103_2 102.37 2635.13 52_717.77 52176.05 105.4 105.4 1104.4 i P j P i P Lead500.0 502.93 1 16-0 '61, 512.66 j 102.5 i P j Magnesium j j 50000.01i 53159.24 ; 106.3 ; 54372.38 j 108.7 j P jManganese I �---� 2500.0 j 2567.72 j 102.7 � 2605.23 �__+ 1042 P Potassium i �...�. 180000.01 84029.16 i 105.0T^! 85055.61 ; 106.3 P _ (� _ 80000^O j-'S13� 28.43 r 101.7 8222 102.8 (�I iSodiuin _I i _ i j ` (1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115 O N 00 O _ O FORM II (Part 1) - IN ILM04.1 U.S. EPA -.CLP 2A INITIAL AND CONTINUING CALIBRATION VERIFICATION Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Initial Calibration Verification Source: MV Labs/High Purity Continuing Calibration Verification Source: MV Labs/High Purity Concentration Units: ug/L E Initial Calibration i Continuing Calibration !' y Analyte True Found %R(1) True Found %R(1) Found "-99.4 %R(1) M Iron 2500.0 2475.06 99.0 2500.0 12991.96 ; 99.7 2983.99- P i Sodium 2500.0 2561.05 1102.4 ;_2500.0] 2583_89 j 103.4 2602.53 104.1 j P j TT (1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115 N 00 O O FORM II (Part 1) - IN ILM04.1 V) U.S. EPA - CLP 2A INITIAL AND CONTINUING CALIBRATION VERIFICATION Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Initial Calibration Verification Source:. MV Labs/High Purity Continuing Calibration Verification Source: MV Labs/High Purity Concentration Units: ug/L Analyte Initial Calibration 2— I True Found %R(l) i True Continuing Calibration Found %R(1) Found %R(l) j i Mi Iron �i 2500.0 ` 2511.51 F100.5 2531.99 101.3 P Sodium _ ( 27 2500-.0-1 2602.24 r 104.1-2588.57 j 103.5 P f (1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115 N N 00 O O FORM II (Part 1) - IN ILM04.1 U.S. EPA - CLP 2B CRDL STANDARD FOR AA AND ICP Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: AA CRDL Standard Source: ICP CRDL Standard Source: MV Labs/High Purity SDG No.: TSL008 FORM II (Part 2) - IN ILM04.1 Concentration Units: ug/L � Analyte CRDL Standard for AA ! CRDL Standard for ICP Initial Final % Found %R Found i True Found �R i True Fou i %R Cadmium -�— 10.0 10.62r 106.21 �----� 11.211. 112.11 'Lead I I ) j — 6.01 5.281 88.01 5.67; 94.5; IManganese 30.0; 31.1111 103.71 32.071 106.91 FORM II (Part 2) - IN ILM04.1 U.S. EPA - CLP 3 BLANKS . Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L SDG No.: TSL008 FORM III - IN ILM04.1 d' N 00 O O Initial i Calib. Continuing Calibration ;i Prepa- Blank Blank (ug/L) Ii ration i� Analyte ! (ug/L) C 1 C 2 C 3 C f i Blank C M Cadmium i 0.3 B 0.4 jBI 0.3 U1 -� 0.4 iB 1 0.283-- 1U lP� 5.659 U i S P j Calcium 5.7 U1 10.5 U! 19.4 B 11.2 B i 5.7 U j 10.5 U 1 5.7 U 10.5 U ; _ 10.489•U P Iron Lead j 1.5 Ui 1.5 Ui 1.5�Uj 1.5;U� 1.515 U! jP I Magnesium 6.4, U , 20.1 B U i 6.4 U. 0.41 U 6.4 iU� i 0.6 B i j 6.408 Uj !P I -+- - 0.394] U 1 P Manganese j 0.4j U; 48.0 B! 0.4 I 39.2 ; B� 45.1 B- 53.0 f B i 38.300LB I I P i Potassium Sodium __ 11.4 B I 7.3 B ( 17.7 B� 20.0 B r----- 5.894 U; �P FORM III - IN ILM04.1 d' N 00 O O Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. U.S. EPA CLP 3 BLANKS Contract: SAS No.: Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L SDG No.: TSL008 Initial !; } j I Calib. I Continuing Calibration j Prepa- I' Blank Blank (ug/L) �f ration Analyte ! (ug/L) C! 1 C 2 C 3 C Blank 7__ C I M i Laii�m i P} 0.5 BI 10.9 B I P I ) i P [callccium 1 -Iron -1 ! -- r-------_�—---c—, Lead 10.5 P ; i__.—. ^I_ ^- i P P .I Magnesium -114.8 Manganese ; B 0 4 P - I --- Potassium --- __ — 2 B T� - i._ i P _46.2 Sodium ! - — 12 •2_ BB� I --- rp - -f-`— FORM III - IN ILM04.1 U.S. EPA - CLP 4 ICP INTERFERENCE CHECK SAMPLE Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 ICP ID Number: TJA6IEA ICS Source: MV Labs/High Purity Concentration Units: ug/L 1 True Initial Found Final Found ( � I ! Sol. Sol. Sol. Sol. f Sol. Sol. Analyte A AB ) A AB %R A AB %R 1 Aluminum5' 00000 500000 503847 j 504072.61 100.8E 515149 514096.11 102.81 —� --- — 998.5; 99 8 Cadmium ; 1000 961.8' 9b.2I i Calcium 500000 ' 500000 ! 506771 507498.5! 101.5' 526160 529726.8! 104.91 Iron 200000 200000 ! 202840 j 203432.2! 101.71 210406 1210031.6 105.0! ; i , —100.9; Lead 1000 976.6 . ;__ . Magnesium 500000 i 500000 ; E 505199 ; 505731.5) 101. 1� 516098 515413.1 _ _ 10311; !— 1--`—� 494.8'' 99.01 j 503;4 100.71 Manganese i 500. ----------{ I i N 00 O O FORM IV - IN ILM04.1 Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER o Solids for Sample: 0.0 U.S. EPA - CLP 5A SPIKE SAMPLE RECOVERY Contract: SAS No. Concentration Units (ug/L or mg/kg dry weight) EPA SAMPLE NO MW-5DS SDG No.: TSL008 Level (low/med): LOW UG/L j Control I I i Limit Spiked Sample j Sample Spike [analyte oR Result (SSR) CI Result (SR) C Added (SA) bR - QOM jCadmium 75-125 i 51.7300 0. 3500 B ( - 50.00 i _ 102.81 ( PJ EIron 75-125 75-125-122.9334 _ 2160.3900 T! 1277 .5200 ; 2.6013 i_ 1000.00 i 20.00 88.3 101.7 P 121 !Lead _'` Mancranese ! _ —� 12259. 4100 ! 11940. 5800 j 500.00 i 63.8; ( P1 Comments: FORM V (Part 1) - IN ILM04.1 N 00 O O Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER % Solids for Sample: 0.0 U.S. EPA - CLP 6 EPA SAMPLE NO DUPLICATES MW -5D I Contract: _. SAS No.: SDG No.: TSL008 Level (low/med): LOW % Solids for Duplicate: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L 00 N 00 O O FORM VI - IN ILM04.1 Control � Analyte Limit � Sample (S) C Duplicate (D) Ci RPD { E Q M cadmium 5.0000 35001B 89 11.1700I 0.2828 U1 _90 —2-0-0—.0 1.2l P !Iron 1277.5200 { 1216.2200 -I _(j -- 4 .9IIPP (Lead 3.000 j 2.6013 B 62819.2400-!—=--62109.1000 2.6283 { B I. _ 1.0 ( P 1. 1; { i P1 iMagn`--esium {Man anese { L_____ i i _11940. 5800 i 11815. 0000 j 1. 1� P { 0.3 j Potassium i odium { a f ; 138884.93001 �T r 194040. 6900 i 138446.7600 191925. 092 01� _� ' ;P� I_ 1 • 1�� P I ISi I 00 N 00 O O FORM VI - IN ILM04.1 Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Solid LCS Source: Aqueous LCS Source: U.S. EPA - CLP 7 LABORATORY CONTROL SAMPLE Contract: SAS No.: ERA MV Labs/High Purity SDG No.: TSL008 Aqueous (ug/L) Solid (mg/kg) Analyte True Found %R I True Found C Limits %R Cadmium 2500.0j 2525.22 101.0 Calcium ! 50000.0 50179.721100_4 -^ —�--_ Iron j 50000 .0� 51115.521 102.21 Lead j 500 0 493.581 98.71Magnesium 1 50000.01 52113.04; 104.2 Man anese 2500.0 2532.681 101.3 Potassium 80000.Oj 8-5693.991 107.11 Sodium 80000.01 82914.121103.6 N 00 O O FORM VII - IN ILM04.1 U.S. EPA - CLP 8 STANDARD ADDITION RESULTS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Concentration Units: ug/L EPA { Sample Ani 0 ADD 1 ADB 2 ADD 3 ADD Final No. i ABS I CON ABS CON ABS f CON ABS E Conc. r 41 FORM VIII - IN O M 00 O O ILM04.1 Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER U.S. EPA - CLP 9 ICP SERIAL DILUTIONS Contract: SAS No.: Concentration Units: ug/L 1 MW -5D 1 —1 SDG No.: TSL008 Level (low/med). LOW M 00 O O FORM IX - IN ILM04.1 Serial Initial Sample I Dilution (Differ-� C! Result C ence Q ' M Analyte i Result (I) (S) ,Cadmium 1 0.35 B f 1.401 U1 1 100.0) I P Calcium 89011.171 1 92115.50; 1 1 3.51 1 jl P__1j Iron 1277.521 1 1332.351 1i_i4.31 1_� P , _ Lead 1 2.601 B -;— 7.60 U 1 1 100. 0 Magnesium El 62819.241 64649.051 1 2.9 i j P Maag,a�nese Potassium i _ 11940.581 i 126_93.501 , _6.3P_ 1 — 138884.931 1 133757.70] 3 F7 - -T-1 0. 51 -1 ' P P Sodium 194040.69 195084,051 1 M 00 O O FORM IX - IN ILM04.1 U.S. EPA - CLP 10 INSTRUMENT DETECTION LIMITS (SEMI ANNUALLY) Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. ICP ID Number: TJA6IEA Flame AA ID Number: Furnace AA ID Number: Comments: Contract: SAS No.: Date: 9/18/2006 SDG No.: TSL008 Analyte Wave- L length I Back- 1 (nm) 1groundl, CRDL ' (ug/L) IDL (ug/L) i i M i Cadmium 226.50( 5. 01 — 0.3 P ' Calcium j 317.93; E 5000.01 5.71 P Iron 259.90i 100.01 10.51 P _ Lead i 220.351 3.01 —1. 51 P Magnesium j_ 5000.0; 6.4 P Man anese- _279.08: 257.61 15.01 0.41 P Potassium Sodium 766.491 ; _88.90 5! 5000.01 5000.0; 14.51 P FORM X - IN ILM04.1 I' b oW'I I NI - ( T Md) IX HEOZ 9ooZ/6T/ZT :a-4eQ VET9KPZ :zagiunN ai doi 8001ISZ :'ON 9QS :'oN SVdN :'ON aseD 8LbOT :apoZ) qeI : goezquoO SNI ' SHK'I WZH : auiuN qez (T. 'dnNNK) S'dojov3 NOIJ321dd0o ZNNTdHgZ'dEZNI d3I KTT azo - Ards ' S' n S-4uaunuoo {00001£9'0-;0000000'0 ,0000Z££'o- 10000000'0 10000000'0 1198"061 wnziTeuL 1 0000000'_0 100000_00'0_ 100000000 10000000'0 0000000'0 _ LL'LO6 utnz�uozs i 0000000'0 i0000000'0 !10000000.0 L 000 0000'0 10000000'0 100'689 _umzP°S !_0000000'0 10000000'0 10000000'0 10000000'0 10000000'o 1 Icz, O££ ! iun?PoS 1 0000000'0_ 0000000'0 10000000'0 10000000'0 _.._--_-- jo00o000 0 I LO 8Z£ 1 za�TTS _ i-0000000'0 ,000.0000'0 --�_ !0000000'0 10000000'0 10000000'0 9T -88Z u°a?T?S 000080b'0 1000000_00 0000000.0 10000000'0 !0000000'0 1 £0'961 1 uinTualaS i 0000000'0 10000000'0 !0000000'0 i0000000'0_ - 10000_0_00'0 0 £0'961 i umrualaS uznisseDoa Or 000000'0 0000000'0 10000000'0 0000000'0 10000000' i66'99L 009b000'0-10000000'0 10000000'0 ';0000000'0 1oo00000'0 1109'T£Z Ta)f°TN TOV 0000000'0 10000000'0 T!0£Z0000'0 10000000'0 10000000'0_ i0000000*0 !OobT000'0- 1!£o'ZOZ—iuinuapq 1 T9'L9Z asauebuey 0 606b06 000 0 0000000'0 10000000'0 —; 0000000'0 1000000010 0000000'0 10000000'0 10000000'0 ! 80'6LZ tun Tsaub2y i 00oo99L'O- 0000000'0 0000£80'0 foo'00000'0 ;00009Z9'o 1 9£'OZZ _j PpaO 0000000'0 10000000'0 OOOOZ60'0 0000000.0 0000ZLZ'0- 1i9£'OZZ 1 Peal 0000000'0 10000000'0 0000000'0 10000000'0 ;0000000'0 !66'TLZ uozl �00�00000'0 0000000'0 (0000000'0 0000000'0 OO0000O'0_ 166'69Z uozl 10L9£000"0-10000000'0_ 00b0000.07 10000000'0 10000000'0 1 -SL Z£ 1 za o� 1_0000000'0 000000 o0 0000000'0 10000000'0 10000000'0 1 Z9'8ZZ_! �Teq°� j 0000000'0 !0000000"0 0000000'0 !0000000'0 10000000'0 _ 1 !Z9'L9Z ' utnTuioz T4Z 1 0000000'0 !0000000'0 .0000000'0 '0_� 10000000'0 l0000000"0 1f£6'LT£ 1 O9'9ZZ 1 uznToTe-. n? Pp-, 0000000'0 0000000'0 �TT00o'O 10000000'0 10000000'0 uozof 1_00£ 6T00'0 10000000'0 io0b£0_o0'o- 0000000'0 0000000'0 189'66Z 1 tun?TT 0000000'0 (0000000'0 10000000'0 0000000'0 !0000000'0 �I60"£T£ 1 unTZPf i 0000000'0 0000000'0-1000000'0 10000000'0 10000000'0 11Tb'£6b ! !000O60Z'0- 0000000'0 �OOOOOiO'0- 10000000'0 j--�— 0000000'0 60681 oTuasz� 1 0000000'0 10000000'0 (oo00Z£0'0 10000000'0 10000000'0 '!b8'90Z uouiz}u� 00_00000'0 0000000'0 1-- i00000Z0'0 10000000'0 10000000'0 168'9oZ 1 uoiuT-4ul 000£910'0 _10000000'0 1000000.0'0 100000000 0000000'0 ZZ uznuruin TE 00 6yy a3 e0 TK I (ucu) ! @2ATeu) j u-6uaT 1 :zog szogoL-a u0140azz0z) quauiaTazaqul 1 -aneM 9ooZ/6T/ZT :a-4eQ VET9KPZ :zagiunN ai doi 8001ISZ :'ON 9QS :'oN SVdN :'ON aseD 8LbOT :apoZ) qeI : goezquoO SNI ' SHK'I WZH : auiuN qez (T. 'dnNNK) S'dojov3 NOIJ321dd0o ZNNTdHgZ'dEZNI d3I KTT azo - Ards ' S' n U.S. EPA - CLP 11A ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY) Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No.: NRAS No.: SDG No.: TSL008 ICP ID Number: TJA6IEA Date: 12/19/2005 Wave- �j Interelement Correction Factors for: length i Analyte I (nm) 1 Al Ca Fe Mg Co 189.99 I 0.0000000, 0.0000000 -0.00020401_ 0.0000000! 0.0000000 Tin 334.94 1 0.0000000[ 0.00000001 0.0000000' 0.0000000! 0.0000500 I Titanium Vanadium 292.4011 Zinc 213. 86T I 0.00000001 001 0.00000�— 0.0000000 0.00002001 0.0000000 0.0001580; 0.00000001 0. OOOOO�v0.0000000 0.00000 00 � I I Comments: FORM XI (PART 1) - IN ILM04.1 d' M 00 O O L/) H I' bONIII NI - (Z IEV6) IX N'dO-q S00Z/6T/ZT . :a-42cl V3T9VfJ, :jaquinN CII doi 80075'L :-ON ExIs :'°N SVdN ON aseD 8L60T apo3 qerj :4012aquoo 'ONI 'SeVq WZH atueN qPri (7,rjqV0NNV) S'd0I3V3 NOIIDEEWD INHHSqZ'dZINI aDI ETT dqo - Vda 'S'n C) 00 squamoo 0000£58'0-j0000000'0__ __ !0000099'0- 0000000.0 �OOOOOOZ'O w iaTTTeLlI _00b_b000*0 10000000'0 10000000*0 0000000-0 10000000'0 lCL0 A _'!98'06T 11LCLOb 1 ! wnT:IuO-T_4S -6-0-6 0 b 0 - 0 '0000000.0 10000000.0 0000000-0 10000000 -0 -i .001689 WnTPOS? ob0000-o b 'b- i0000000 -o 10000000,0 0000000,0 10000000,0 iU H�: � _i_ i uin-cpOS! __ . i 0000000*0 10000000-0 F0000S81*0 !0000000'0 I �0000000,0 LO 9ZE i IGATTSI 0000000,0 10000000,0 10000000,0 0-0000000 0000000-0 9T eBz do- D T T T S F-6-0-0-0 s E z - 0 10000000.01 0 s 10000000"o 10000000,0- EO'96T W TuaT@Sl 1 0000000.0 10000000*0 _1�o 10000SLZ*0 0000000,0000,0 00 EO*96T wn_1uz)T@Sj 0000000-0 10000000-0 �o 000000'0 10000000,0 _L0_0 10000000,0 :6�-99L 1 1 1 iun-csseqod -- & - 0000000"0 !0000000'0 10000000,0 10000000'0 '000_0000'0 _1__! 0.9'TEZ 0000000,0 !0000000*0 10000000*0 10000000"o 10000000*0 lu-zoz luinu@Pq TON OOOT000.0-10000000.0 10000000,0 0000000"0 10000000*0 1 1T9 * LgZ asaup UPH 0000000,0 10000000*0 OOOSE00*0- 10000000*0 i 80 '6 LZ 0000000.0 100006T£'0 10000000'010000000'0 _J000T000'0- 10000000,0 Gc*0zz peaz --0 0 0 L S -C �o - Q� 10000E�T.q , 0 10000000,0 0000000,0 ise .0�z peal I IF i 0000000,0 !0000000'0 _10000SST i i 0000000-0 _,,(�00(?000 - 0 10000000*0 -- UO;(I i 0000000,0 10000000-0 10000000.0 - _ 10000000.0 -- 10606000.6 1 R6'69Z UO -TI It 0000000,0 0000000-0 10000000.0 jW00000,0 10000000.0 !SL'6ZE -Taddooi 0000000*0 OPOZ000,0 10000000,0 10000000*0 10000000,0 1z9*8zz ITeqo3l OOT9000'0 0000000-0 10000000'0X0000000.0_10000000' _ 0 Z9 - L§Z- wn,.cwo-7143 0000000,0 0000000,0 i0000000,0 !0000000*0 10000000,0 1£6' LTE wn TOT23 boO0000-0 - - 10�8fmb'T_ 10000000-0 1OT90000 i -0 09*9zz uin-ruipi2ol i 00qz000,0_ 10000000,0 !0000000,0 10000000,0 i0000000,0 89'6bZ -TE UO-Tos 0 it 000Z000,0 !0000000*0 10000000*0 !0000000'0 ;0000000'0 RFE . ul:n::T T �Ta e 1 0000000,0 110000000,0 10000000-0 ;0000000-0 1000000(5 T� E6P WnTapa WnT,2a 1! 0000000-0 10000000*0 i00000LZ*0_ 0000000*0 100009bz,0 160*68T 1 3-cuas-Tv! 0000066*9`000OZOT'T- 10000000*0 10000000*0 it 0 0 0 0 L S 8 * 6 11b8'90Z j AUOWTquvl 0000000-0 10000000*0 i0000000,0 10000000,0 ,0000TLS-8 I 8.90Z Ourc quv OOOOLTO-0 10000000-0 _118HO00 0- 10000000 0 10000000*0 llzZ, L c wnuTul A TN UN no (luu) T44IDuGT :aOj s3043EZ uOT40a=03 qu@uIGT@3a4uI -aAEM S00Z/6T/ZT . :a-42cl V3T9VfJ, :jaquinN CII doi 80075'L :-ON ExIs :'°N SVdN ON aseD 8L60T apo3 qerj :4012aquoo 'ONI 'SeVq WZH atueN qPri (7,rjqV0NNV) S'd0I3V3 NOIIDEEWD INHHSqZ'dZINI aDI ETT dqo - Vda 'S'n r 0 0 00 4 w T' bOMI NI - (z luvd ) IX W2iO3 : squaunuoo �- IOObOS00'0 _ I-0000000'0 0000000'0 X0000000'0 (-0000000'0 0000000-0 0000000*0�0000000'0� 10000000'0 0000000'0 0000000'0 10000000'0 M000 000'0 ;0000000'0 !0000000'0 10000000^0^"0000000'0 0000000'0 98'8TZ ouTZI '00000000 Ob'Z6Z uinTpeuenj 100000_0_0'0 1 b6'b£E umrue411 -� 66'681 ; uTs n TN uW n0 aO (wu) I LPbuaT " 84ATeUV i :aog saog0e3 uoT4091aoO quaucaTaaa4ul -anent j SOOZ/61/ZT :a_4eQ 8007S,L :-ON OQS : ' ON SF'IN goeaquOD v3T9vrl :aaglunN QI dOI :-ON aseO 8LbOT :apoO QeZ ONI 'SHK'I WZH :aweM ae'I (2TgaVONNV) S2 IM4 NOI133E D ZNEW3'12USINI d3I HT1 a'10 - gra 3 'S'O U.S. EPA - CLP ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY) Lab Name: H2M LABS, INC,.. Contract: Lab Code: 10478 Case No.: NRAS No.: SDG No.: TSL008 ICP -ID Number: TJA6IEA Date: 12/19/2005 Wave- 1� Interelement Correction Factors for: length (Analyte (nm) Alm um� inum 308.22; I----- -- -r- --- AntimonV ;, 206.841 A,nt imqny 206.84, Arsenic_( 18 9. 0 4 +�;-- Barium — I 493.411 _ I -` ---- - — --- — -^ 1eryllium - ---313.0 _ _�---- _ --'--- �- B Boron j_-249.68; 1, �� 226.501 _ - --- -- 1 Cadmium ��------ - Calcium 317. 93 1,, Calcium Ch_romium2 67 . 621' ; }} - '------ !Cobalt 228.62—_ ' ---- ---- I - _-` — - _ - Co _e r - 3 2 4 .7.5 1' s — j _ --------- Iron 259.94) — jIron 271.44; 1 1 Lead _ 220.351 220.351' 1 i ` Lead 220.3511 Ma nl esium 27_9. 08 11 Macanese _ 257.611 Mol by de m 202.031 1 a -- - ' -i-- --------- Nickel j 231.60 i i - -- -- Pot a s s i um - i 7 6 6. 4 9 1___ t _ _ _ -----------{ Selenium 1 196.031 i !Selenium i 196.03; iS i l i con -288.16. -(- Silve1 328.071 j— r _! _-- _--------=_--.--- 1 ! �S m 1,__ 3 30-.2311- 1-- ----!— -- S" odium _-589 00 -- ;Strontium 467.771 j - Thallium --190.86;-' --_--- ---_�---'----- ---- - Comments: FORM XI (PART 1) - IN ILM04.1 U.S. EPA - CLP ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY) Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No.: NRAS No.: SDG No.: TSL008 ICP ID Number: TJA6IEA Date: 12/19/2005 Wave- I( Interelement Correction Factors for: I i length Analyte (nm) Tin 18 9. 9 9;-i-- -- - !Titanium i .339.94;—�--- Vanadium 292.40 —_ --- -- Zinc 213. 86i ---- Comments : FORM XI (PART 1) - IN ILM04.1 00 M 00 O O U.S. EPA - CLP 12 ICP LINEAR RANGES (SEMI ANNUALLY) Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 ICP ID Number: TJA6IEA Date: 10/23/2006 Comments: }Analyte Integ. Time (Sec.) j Concentration i (ug/L) M ICadmium 15.001 200001P —j `Calcium 15.00; 1000000P Iron 15.001 _ 27500W P JLead j 15.001 5000011P 1 _ Magnesium _ ;15.00; T — 10000000 P Man a_nese I 15.001 2000012 Potassium 15.00'; ;Potassium Sodium 1 15.001 225000iP 3500001P FORM XII - IN ON M 00 O O ILM04.1 Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Method: P U.S. EPA - CLP 13 PREPARATION LOG Contract: SAS No.: SDG No.: TSLO08 EPA Sample No. Preparation } Weight Date (gram) Volume -(mL) i EB ---1 12/07/2 _006 --___ 50 (FB 1 12/07/2006 i 50 _ v LCSW j 12/07/2006 50 j MW -3D i 12/07/2006 j 50 — MW -33 ! 12/07/20061 50 IMW-4D - - ----- - -_-1 12/07/_2006 --� BMW -4S _ ! 12_/07/2006 - �` _50 MW -5D 12/07/2006 i M 5 D ^ _ i 12/07/2006 50 — _ —i MW -SDS Mw -5S --�-T-12_/07/2006 12/07/2006 I 50 I-- 50 -- MW-6D — 12/07/2006 I — - 50 �Mw-6S MW -8D i 12/07/2006 ;-- - 12/07/2006 50 --; 50� Mw -8S 12/07/2006 50 PBW i 12/07/2006 j - ---- - , ---5 0 --- S0 TU HOLD 2 i _ -- 12/07/2006 ( 50 0 00 0 0 FORM XIII - IN ILM04.1 Lab Name: H2M LABS, INC. Lab Code; 10478 Case No. Instrument ID Number: TJA61EA Start Date: 12/12/2006 U.S. EPA - CLP 14 ANALYSIS RUN LOG Contract: SAS No.: Method: P End Date: SDG No.: TSL008 12/12/2006 tui"M A -LV - _-LiN Analyces EPA i sample I D/F Time R A SIAIBIB CIC C C C F P M M H Ni IV 1 z C IN No. L BIS A E D I A R 1 0 U IE i BIG N IS 1 1 L N ISO I 1. 1 0600 1 1x IXIX' x x x xg XJ S_ S 1. 00__i 1.00 0608 0614 iT x x S i 1.00 0619, x 1.00 0625 x X4__ i x x S 00 0632 i 0637 1 x S 1.00 0642 X i X I X x x x 1 xx x 1cv jcB t1.00 1 0649 1 1.00 0657 1 x x xI X X i X X x i x x CRI 1.00 0704 _XXx x I x ,ICSA 1. 0712 XX_i I rX X! X x x x ICSAB 1.00 1 0-7-2-0- x x X 1111 X x x CCV 1.00 0727 x x X x x x x T ccv 1.00 0735 x I x I ccs j 1.00 1.00 0-743 1 0750 x x x x 1 x Ix x x I X i X x x PBW LCSW 1.00 1 0758 x x x x i x! X Xx x x x � x x x x EB 1.00 0 05 1- 1 1 x MW -3D 1.00 0813 xi x XIX x! I x ix x MW -3S 1.00 0821 i x x x x _ -- T x x x T X- x MW -4D 00 0828 I T _MW. - 4 _SF__ 1.00 0836 jx x XIx x !X !X x MW -5D 1.00 10844 I I j x XI j i GX!X!X;X( x x ,MW-5DD MW-5DS j 1.00 1.00 0851 i 0859 1 x ix x x x! x x IXX x &E-V I, . 1 00 1 �)06_ 0 i Ix xX; I x x x x ccv CCB 1.00 1.00 0914 0922 X :MW-5DL 5.00 j 0929 1 X XI j X X x MW -5S 1.00 1 0937 x X T5C, 7 i X! 1.00 0945 x x x x 1 x x x i4w-iss I 1.00 0952 x I x XIx x _bC MW -BD 1 1. 00 i 1000 1 x x I-?- 1 �X'x !X x 1 X X x x 1 x 1 x _70 Fmw-8s 1.00 1 1007 ---- J_ I I tui"M A -LV - _-LiN Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Instrument ID Number: TJA6IEA Start Date: 12/12/2006 U.S. EPA - CLP 14 ANALYSIS RUN LOG Contract: SAS No.: Method: P End Date: SDG No.: TSL008 12/12/2006 EPA I I Sample I No. i D/F I Time: o ; j Analytes I R ;AISIA BiBC CIC,CIC FIPiMIMiH!NiKIS;A N TjVIZiCI iL4B�SIAj(E;D;A'R;0 ULE B NIG Il E GAIL ;NjNI OUTHHOLD 2; FB 1.00 i 1 0 0 j 1015 10 j i�X I X!i L X Iv iXXIXiXX� j jX j j i� X j X XIX i j.. X IMw-3S CCv 2.00 { i.00� 1030 1038 ; ^j i ! } I i ' X'_XiX!— IXX_ �X! j i l CCv 1.00 1045Iv ICCB 1.00 j 1053 X xX�-{_XI CRI 1.00 i 1101 1 00 j j ?�iXjXjX{X I-I� ICSA { (ICSAB j 11108�X;X� 1.00 1116 Xi IX_jX� iXX;X,X ? _� iccv I 1.00 - 1 124 { j'I i (-; X X j �_-r_.- —' " X I X X X; i X I X jccv -- -i ICCB i 1.00 - 1.00 ; 11_31 1139 j I- i i + j I XiXi. I ' X I i I ;_ X i jX;X;X{X! X j iX FORM XIV - IN ILM04.1 IH2M "US, INC. 111: RAW DATA FOR METALS A. ICP DATA �. till L AUS4 1?%Co CLIENT ISLoo`� DATE 12112 Lot, TASK: Cj-?I RESULT FILE: k17-MOU ANALYST !� # 1 SAMPLE 1 NOTES # SAMPLE 1 NOTES 1 1 1 I 1 1 1 i ✓ 26 i D(o(��— 662E1 �w- S 1 1 2 1 :11-V'- 1 1 1 1 271 a ar' 1 1 1 Wj- 3 1 3 1 -Jo-L 1 1 1 281 1 1 r 1 i 4 1 29 i b ttE ^ i SO17T41rHcx� oC i 5 1 14541i i 301 ZS%3/4 i Fg i 1:2 1 6 1 �$1 1 31; Dn'�E 1 tw- 3S 1 1 1 1 1 7 1 Cil I 1 1 1 1 1 I 1 321 CC. Q s 1 1 I 1 1 1 1 s 1 CLut.t 331 CCJ t-3 1 1 9` 1 Cc -61 I 1 1 1 34 1 I 1 i 10 i -th- RO t) l.-mWW ZS\.Opqz, 11 35 i Qk4 r— i 1 11 1 L s- C`ldid 1 usx,) t 36: 1 ,. 11- 1 121 VblL 3LpZ- OD16 37 1 Z ,54e)F 1 1 1 13 1 DOS 1 �i1.1 �� 1 381, Cu LA 1 1 r 1 1 141 ea3� � 1 ►-IW-3S • 1 , 391 C�►L`j , 1 1 1 It d' 00 O O r� C/1 Standardization Rpt. 12/12/06 06:07:54 AM page 1 N od: CLP1 Standard: StdBLANK R -.,'Time: 12/12/06 06:00:22 Elem Ag Al As1.890 B Ba Be Ca Avge =.00366 .0048 -.00111 .0008 .0000 -.0009 .0049 SDev .00003 .0002 .00113 .0001 .0001 .0000 .0001 %RSD .72220 5.019 101.90 7.250 262.0 1.163 2.386 #1 -.00367 .0047 -.00111 .0008 .0000 -.0009 .0049 #2 -.00363 .0050 .00002 .0008 .0001 -.0009 .0050 #3 -.00368 .0046 -.00225, .0009 -.0000 -.0009 .0048 Elem Cd Co Cr Cu Fe Fe K Avge -.0002 -.0000 .0003 .0021 .0000 .0180 .0051 SDev .0010 .0001 .0001 .0001 .0000 .0078 .0006 %RSD 439.2 565.4 45.17 2.411 43.62 43.52 11.87 #1 -.0007 -.0001 .0003 0022 .0000 .0136 .0052 #2 .0009 .0000 .0005 .0021 .0000 .0270 .0056 #3 -.0009 .0000 .0002 .0021 .0000 .0133 .0045 Elem Mg Mn Mo Na Na Ni 2203/1 Avge .0006 .0005 .0002 -.0182 .2951 .0002 .00898 SDev .0003 .0002 .0001 .0012 .0074 .0001 .00275 %RSD 48.42 47.95 64.74 6.849 2.520 73.13 30.569 .0008 .0005 .0001 -.0173 .2920 .0001 .01049 .0007 .0007 .0004 -.0177 .3036 .0003 .00581 #3 .0003 .0002 .0001 -.0196 .2898 .0002 .01065 Elem 2203/2 2068/1 2068/2 1960/1 1960/2 Si Sn Avge -.00097 -.00355 -.00025 -.00603 .00189 .0713 .0025 SDev .00078 .00093 .00076 .00022 .00060 .0016 .0011 %RSD 79.813 26.084 300.61 3.6840 32.004 2.308 44.27 #1 -.00183 -.00443 -.00076 -.00585 .00134 .0717 .0013 #2 -.00078 -.00258 -.00063 -.00596 .00254 .0727 .0034 #3 -.00031 -.00364 .00062 -.00628 .00179 .0695 .0029 Elem Sr Ti T11908 v Zn Avge .0001 .0002 -.00240 .0001 .0007 SDev .0001 .0000 .00057 .0000 .0001 %RSD 54.21 13.56 23.826 66.88 13.88 #1 .0001 .0003 -.00195 .0000 .0007 #2 .0001 .0003 -.00304 .0001 .0008 #3 .0000 .0002 -.00220. .0001 .0006 tn 00 O O N Standardization Rpt. N tod: CLP1 Standard: StdAGSBH k,- Time: 12/12/06 06:08:00 Elem Ag 2068/1 2068/2 Avge .61651 2.1257 1.3682 SDev .00219 .0293 .0060 %RSD .35520 1.3762 .43685 #1 .61852 2.0987 1.3722 #2 .61417 2.1217 1.3613 #3 .61685 2.1568 1.3710 12/12/06 06:13:58 AM page 1 d' 00 O O F-+ Standardization Rpt. 12/12/06 06:19:15 AM page 1 v od: CLP1 Standard: StdICSH Cru.: Time: 12/12/06 06:14:04 Elem Al Ca Fe Avge 27.45 38.80 .4687 SDev .04 .04 .0006 %RSD .1456 .0958 .1181 #1 27.49 38.83 .4692 #2 27.41 38.76 .4681 #3 27.47 38.82 .4688 Mg 52.03 .05 .1009 52.07 51.97 52.04 Standardization Rpt. 12/12/06 06:25:19 AM b iod: CLP1 Standard: StdFURNH Time: 12/12/06 06:19:21 Elem As1890 2203/1 2203/2 1960/1 1960/2 T11908 Avge .79405 2.9587 1.1852 .59604 .42696 .65019 SDev .00194 .0085 .0016 .00155 .00199 .00317 %RSD .24433 .28754 .13407 .25947 .46713 .48734 #1 .79287 2.9502 1.1860 .59552 .42525 .65273 #2 .79299 2.9588 1.1834 .59483 .42649 .64664 #3 .79629 2.9672 1.1863 .59778 .42915 .65121 page 1 Standardization Rpt. D Lod: CLP1 Standard: StdMULTH L- Time: 12/12/06 06:25:25 1.396 Elem B Ba Be Avge 1.115 4.856 5.095 SDev .001 .004 .006 %RSD .1008 .0743 .1215 #1 1.115 4.860 5.102 #2 1.114 4.852 5.090 #3 1.1,16 4.857 5.094 Elem Mn Mo Ni Avge 13.35 1.272 1.414 SDev .01 .004 .001 %RSD .0943 .2814 .0747 #1 13.36 1.269 1.415 #2 13.34 1.270 1.414 #3 1.3.35 1.276 1.413 Elem v Zn Avge .9968 3.201 SDev .0012 .004 %RSD .1181 .1230 .9979 3.205 .9956 3.197 #3 .9969 3.200 12/12/06 06:32:10 AM page 1 Cd Co Cr Cu 40.86 1.396 1.905 1.224 .05 .001 .002 .000 .1338 .0965 .1073 .0313 40.92 1.397 1.907 1.224 40.82 1.394 1.903 1.223 40.83 1.396 1.904 1.224 Si Sn Sr Ti 1.491 6.028 9.411 2.311 .046 .009 .006 .002 3.079 .1495 .0599 .0716 1.443 6.038 9.416 2.313 1.498 6.020 9.405 2.310 1.534 6.026 9.412 2.312 d' 00 O O N Standardization Rpt. 12/12/06 06:37:27 AM page 1 [� iod: CLP1 Standard: StdFENAL F_-__ Time: 12/12/06 06:32:16 Elem Fe Na Avge 33.40 39.49 SDev .07 .05 %RSD .2134 .1248 #1 33.36 39.46' #2 33.35 39.47 #3 33.48 39.55 O 00 O O H Standardization Rpt. } zod: CLP1 Standard: StdNAKH 1--_- Time: 12/12/06 06:37:34 Elem K Na Avge 8.524 1.726 SDev .022 .007 %RSD .2639 .4193 #1 8.522 1.725 #2 8.548 1.734 #3 8.503 1.719 12/12/06 06:41:58 AM page 1 r-+ 00 O O V) N Standardization Report 12/12/06 06:41:58 AM page 1 I iod: CLP1 Slope = Conc(SIR)/IR Element Wavelen High std Low std' Slope Y -intercept Date Standardized Ag 328.068 StdAGSBH StdBLANK 3224.90 11.8081 12/12/06 06:37:34 Al 308.215 StdICSH StdBLANK 18.21'56 -.086781 12/12/06 06:37:34 As1890 189.042 StdFURNH StdBLANK 1257.60 1.39899 12/12/06 06:37:34 B 249.678 StdMULTH StdBLANK 4.49598 -.003668 12/12/06 06:37:34 Ba 493.409 StdMULTH StdBLANK 1.02957 -.000022 12/12/06 06:37:34 Be 313.042 StdMULTH StdBLANK .981358 .000876 12/12/06 06:37:34 Ca 317.933 StdICSH StdBLANK 1.48474 -.002004 12/12/06.06:37:34 Cd 226.502 StdMULTH StdBLANK .122365 .000028 12/12/06 06:37:34 Co 228.616 StdMULTH StdBLANK 3.58180 .000050 12/12/06 06:37:34 Cr 267.716 StdMULTH StdBLANK 2.62586 -.000862 12/12/06 06:37:34 Cu 324.754 StdMULTH StdBLANK 4.09172 -.008733 12/12/06 06:37:34 Fe 271.441 StdICSH StdBLANK 1.28640 .000019 12/12/06 06:37:34 Fe 259.940 StdFENAL StdBLANK .149782 -.002691 12/12/06 06:37:34 K 766.491 StdNAKH StdBLANK .938487 .001966 12/12/06 06:37:34 Mg 279.079 StdICSH StdBLANK 1.20379 -.000114 12/12/06 06:37:34 Mn 257.610 StdMULTH StdBLANK .374507 -.000191 12/12/06 06:37:34 Mo 202.030 StdMULTH StdBLANK 3.93230 -.000851 12/12/06 06:37:34 Na 330.232 StdNAKH StdBLANK 1.15600 -.007555 12/12/06 06:37:34 Na 588.995 StdFENAL StdBLANK .127557 -.037646 12/12/06 06:37:34 Ni 231.604 StdMULTH StdBLANK 3.53444 -.000666 12/12/06 06:37:34 2203/1 220.351 StdFURNH StdBLANK 339.016 -3.04598 12/12/06 06:37:34 2203/2 220.352 StdFURNH StdBLANK 843.018 .818868 12/12/06 06:37:34 2068/1 206.831 StdAGSBH StdBLANK 939.282 3.33407 12/12/06 06:37:34 3/2 206.832 StdAGSBH StdBLANK 1461.50 .370795 12/12/06 06:37:34 )/1 196.021 StdFURNH StdBLANK 1660.92 10.0190 12/12/06 06:37:34 1960/2 196.022 StdFURNH StdBLANK 2352.53 -4.44743 12/12/06 06:37:34 Si 288.158 StdMULTH StdBLANK 3.48339 -.248313 12/12/06 06:37:34 Sn 189.989 StdMULTH StdBLANK .829597 -.002088 12/12/06 06:37:34 Sr 421.552 StdMULTH StdBLANK .531290 -.000052 12/12/06 06:37:34 Ti 334.941 StdMULTH StdBLANK 2.16346 -.000528 12/12/06 06:37:34 T11908 190.864 StdFURNH StdBLANK 1532.35 3.67748 12/12/06 06:37:34 v 292.402 StdMULTH StdBLANK 5.01649. -.000315 12/12/06 06:37:34 Zn 213.856 StdMULTH StdBLANK 1.56252 -.001112 12/12/06 06:37:34 Pb2203 220.353 NONE NONE 1.00000 .000000 *NOT STANDARDIZED Sb2068 206.838 NONE NONE 1.00000 .000000 *NOT STANDARDIZED Se1960 196.026 NONE NONE 1.00000 .000000 *NOT STANDARDIZED N 00 O O h Standardization Readback Report 12/12/06 06:41:58 AM A Lod: CLP1 Element Wavelength Standard Ag 328.068 StdBLANK StdAGSBH Element Wavelength. Standard Al 308.215 StdBLANK StdICSH Element Wavelength Standard As1890 189.042 StdBLANK StdFURNH Element Wavelength Standard B 249.678 StdBLANK StdMULTH Element Wavelength Standard Ba 493.409 StdBLANK StdMULTH I hent Wavelength Standard Be 313.042 StdBLANK StdMULTH Element Wavelength Standard Ca 317.933 StdBLANK StdICSH Element Wavelength Standard Cd 226.502 StdBLANK StdMULTH Element Wavelength Standard Cc 228.616 StdBLANK StdMULTH Element Wavelength Standard Cr 267.716 StdBLANK StdMULTH Element- Wavelength Standard ( 324.754 StdBLANK StdMULTH Known Concentration .000000 2000.00 Known - Concentration .000000 500.000 Known Concentration .000000 1000.00 Known Concentration .000000 5.00000 Known Concentration .000000 5.00000 Known Concentration .000000 5.00000 Known Signal .005266 57.6118 Known Concentration .000000 5.00000 Known Concentration .000000 5.00000 Known Concentration .000000 5.00000 Known Concentration .000000 5.00000 Measured Concentration -.000000 2000.00 Measured Concentration -.000000 500.000 Measured Concentration -.000000 1000.00 Measured Concentration .000000 5.00840 Measured Concentration .000000 5.00000 Measured Concentration -.000000 5.00095 Measured Signal .004896 38.8039 Measured Concentration .000000 4.99930 Measured Concentration .000000 5.00000 Measured Concentration .000000 5.00108 Measured Concentration .000000 4.99875 page 1 Residual Concentration .000000 .000000 Residual Concentration .000000 .000000 Residual Concentration .000000 .000000 Residual Concentration -.000000 -.008400 Residual Concentration -.000000 .000000 Residual Concentration .000000 -.000950 Residual Signal .000369 18.8079 Residual Concentration -.000000 .000700 Residual Concentration -.000000 .000000 Residual Concentration -.000000 -.001080 Residual 00 O 0 Concentration O -.000000 001245 �, Standardization Readback Report Element Wavelength Standard K 766.491 StdBLANK StdNAKH Element Wavelength Standard Mg 279.079 StdBLANK StdICSH Element Wavelength Standard Mn 257.610 StdBLANK StdMULTH T --nent Wavelength Standard P 202.030 StdBLANK StdMULTH Element Wavelength Standard Na 330.232 StdBLANK StdNAKH Element Wavelength Standard Na 588.995 StdBLANK StdFENAL Element Wavelength Standard Ni 231.604 StdBLANK StdMULTH Element Wavelength Standard 2203/1 220.351 StdBLANK StdFURNH Element Wavelength Standard 2203/2 220.352 StdBLANK StdFURNH Known Signal .0067 8.002 Known Signal .0005 62.63 Know Concent .0000 5.000 Know Concent .000 5.00 Known Signa -.02 1.98 Know Concent .000 5.00 Kno Concent .000 5.00 Kno Concentr .000 1000 Kno Concentr .000 1000 12/12/06 06:41:58 AM ration ration 000 000 1 8601 779 ration 000 000 wn ration 000 000 wn 000 wn 000 Measured Residual Known E --..lent Wavelength Standard Signal Fe 271.441 StdBLANK .0000 00 .000000 StdICSH .6029 .000000 Measured Residual Know Element Wavelength Standard Concentr Fe 259.940 StdBLANK ..0000 84 .000580 StdFENAL 5.000 Element Wavelength Standard K 766.491 StdBLANK StdNAKH Element Wavelength Standard Mg 279.079 StdBLANK StdICSH Element Wavelength Standard Mn 257.610 StdBLANK StdMULTH T --nent Wavelength Standard P 202.030 StdBLANK StdMULTH Element Wavelength Standard Na 330.232 StdBLANK StdNAKH Element Wavelength Standard Na 588.995 StdBLANK StdFENAL Element Wavelength Standard Ni 231.604 StdBLANK StdMULTH Element Wavelength Standard 2203/1 220.351 StdBLANK StdFURNH Element Wavelength Standard 2203/2 220.352 StdBLANK StdFURNH Known Signal .0067 8.002 Known Signal .0005 62.63 Know Concent .0000 5.000 Know Concent .000 5.00 Known Signa -.02 1.98 Know Concent .000 5.00 Kno Concent .000 5.00 Kno Concentr .000 1000 Kno Concentr .000 1000 12/12/06 06:41:58 AM ration ration 000 000 1 8601 779 ration 000 000 wn ration 000 000 wn 000 wn 000 Measured Residual Signal 55 .000028 76 .468718 n Measured ation Concentration 00 .000000 00 5.00000 .000000 Measured Residual Signal 59 .005107 05 8.52446 -.522402 Measured Residual Signal 84 .000580 16 52.0288 n Measured Residual Concentration 00 .000000 00 5.00000 n Measured Residual Concentration Concentration -.000000 .000000 5.00000 .000000 Measured Residual Signal Signal -.018206 -.010395 1.72607 n Measured Residual Concentration Concentration -.000000 .000000 5.00000 -.000000 Measured Residual Concentration Concentration .000000 _.000000 4.99790 .002100 Measured ation Concentration Concentration .000000 00 1000.00 .000000 Measured ation Concentration .000000 00 1000.00 page 2 i Residual Signal .000027 .134258 i Residual r i Concentration -.000000 .000000 Residual Signal .001651 -.522402 I Residual i Signal i .000004 10.6029 i Residual Concentration -.000000 .000000 Residual Concentration .000000 .000000 Residual Signal -.010395 .261717 Residual Concentration .000000 -.000000 i Residual Concentration _.000000 .002100 Residual i Concentration -.000000 .000000 Residual Concentration � -.000000 O .000000 Standardization Readback Report L --.:tent Wavelength Standard 2068/1 206.831 StdBLANK StdAGSBH Element Wavelength Standard 2068/2 206.832 StdBLANK StdAGSBH Element Wavelength Standard 1960/1 196.021 StdBLANK StdFURNH Element Wavelength Standard 1960/2 196.022 StdBLANK StdFURNH Element Wavelength Standard Si 288.158 StdBLANK StdMULTH F"--Zent Wavelength Standard 189.989 StdBLANK StdMULTH Element Wavelength Standard Sr 421.552 StdBLANK StdMULTH Element Wavelength Standard Ti 334.941 StdBLANK StdMULTH Element Wavelength Standard T11908 190.864 StdBLANK StdFURNH Element Wavelength Standard V 292.402 StdBLANK StdMULTH Element Wavelength Standard 7n 213.856 StdBLANK StdMULTH Know Concentr ..0000 2000. Know Concentr .0000 2000. Know Concentr .0000 1000. Know Concentr .0000 1000. Know Concentr .0000 5.000 Know Concentr .0000 5.000 Know Concentr .0000 5.000 Know Concentr .0000 5.000 Know Concentr .0000 1000. Know Concentr .0000 5.000 Know Concentr .0000 5.000 12/12/06 06:41:58 AM n Measured ation Concentration 00 .000000 00 2000.00 n Measured ation Concentration 00 -.000000 00 2000.00 n Measured ation Concentration 00 -.000000 00 1000.000 n Measured ation Concentration 00 -.000000 00 1000.00 n Measured ation Concentration 00 .000000 00 4.94713 n Measured ation Concentration 00 .000000 00 4.99870 n Measured ation Concentration 00 -.000000 00 5.00000 n Measured ation Concentration 00 -.000000 00 5.00000 n Measured ation Concentration 00 .000000 00 1000.00 n Measured ation Concentration 00 .000000 00 5.00000 n Measured ation Concentration 00 .-.000000 00 5.00000 page 3 Residual Concentration -.000000 j .000000 Residual Concentration .000000 .000122 Residual Concentration .000000 .000061 Residual Concentration .000000 .000000 i Residual Concentration -.000000 I .052870 Residual Concentration -.000000 .001300 Residual ' Concentration .000000 .000000 Residual i Concentration .000000 .000000 Residual Concentration -.000000 .000000 Residual Concentration -.000000 :00-0000 Residual Concentration 0 I .000000 O .000000 C- N Standardization Readback Report 12/12/06 06:41:58 AM L --,went Wavelength Standard Pb2203 220.353 NONE NONE Element Wavelength Standard Sb2068 206.838 NONE NONE Element Wavelength Standard Se1960 196.026 NONE NONE Known Measured Concentration Concentration .000000 .000000 .000000 .000000 Known Measured Concentration Concentration .000000 .000000 .000000 .000000 Known Measured Concentration Concentration .000000 .000000 .000000 .000000 page 4 Residual Concentration .000000 .000000 Residual Concentration .000000 .000000 Residual Concentration .000000 .000000 Analysis Report 12/12/06 06:49:36 AM page 1 A iod: CLP1 Sample Name: ICV Operator: MAG F_->_ Time: 12/12/06 06:42:04 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1004.1 50.34 514.85 2.630 2.559 2.568 50.53 SDev 1.2 .04 .75 .002 .002 .001 .07 %RSD .12312 .0805 .14620 .0918 .0732 .0458 .1447 #1 1004.5 50.32 514.00 2.627 2.558 2.569 50.57 #2 1005.1 50.39 515.44 2.631 2.558 2.568 50.58 #3 1002.7 50.32 515.10 2.632 2.561 2.566 50.45 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 1100.0 55.00 550.00 2.750 2.750 2.750 55.00 Low 900.00 45.00 450.00 2.250 2.250 2.250 45.00 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge 2.522 2.544 2.535 2.608 50.18 83.95 52.51 SDev .005 .002 .003 .003 .02 .11 .04 %RSD .1836 .0801 .1134 .1021 .0439 .1276 .0702 #1 2.527 2.545 2.537 2.605 50.18 83.86 52.52 2.523 2.545 2.536 2.607 50.21 84.07 52.54 2.517 2.542 2.532 2.611 50.16 83.93 52.47 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 2.750 2.750 2.750 2.750 55.00 88.00 55.00 Low 2.250 2.250 2.250 2.250 45.00 72.00 45.00 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 Units ppm ppm ppm ppm ppb ppb ppb Avge 2.529 2.619 80.91 2.507 499.04 490.74 985.86 SDev .002 .013 .22 .002 2.56 1.79 18.16 %RSD .0663 .5061 .2684 .0796 .51213 .36443 1.8424 #1 .2.530 2.605 80.82 2.510 499.09 488.67 964.93 #2 2.530 2.620 81.16 2.506 501.57 491.73 995.21 #3 2.527 2.631 80.76 2.507 496.46 491.81 997.44 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High 2.750 88.00 2.750 Low 2.250 72.00 2.250 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 986.92 513.76 512.08 2.403 2.558 2.609 1.967 SDev 10.07 1.30 1.30 .053 .005 .000 .000 %RSD 1.0206 .25264 .25317 2.188 .1898 .0149 .0157 O O 975.30 512.86 512.16 2.348 2.553 2.609 1.967 992.50 515.24 513.34 2.407 2.559 2.609 1.967 [� #3 992.98 513.16 510.75 2.453 2.563 2.609 1.967 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK Analysis Report 12/12/06 06:49:36 AM Low Elem T11908 v 2n Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb . ppb ppb Avge 503.14 2.551 2.645 493.50 986.57 512.64 SDev 5.33 .001 .003 1.44 12.76 1.23 %RSD 1.0602 .0279 .0975 .29168 1.2938 .23971 #1 496.99 2.550 2.646 492.14 971.84 512.40 #2 505.91 2.551 2.648 495.01 993.40 513.97 #3 506.52 2.551 2.643- 493.36 994.46 511.55 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 550.00 2.750 2.750 550.00 1100.0 550.00 Low 450.00 2.250 2.250 450.00 900.00 450.00 page 2 00 00 O O V1 E-+ Analysis Report N iod: CLP1 Sample Name: ICVL Time: 12/12/06 06:49:42, ppm Comment: TSL008 .0089 .0010 Mode: CONC Corr. Factor: 1 .0018 Elem Ag Al As1890 Units ppb ppm ppb Avge .35183 .0213 1.5637 SDev .33025 .0051 1.1213 %RSD 93.866 23.91 71.709 #1 .52999 .0255 2.7867 #2 -.02924 .0227 1.3204 #3 .55474 .0156 .58401 Errors NOCHECK NOCHECK NOCHECK High ppb ppb .0011 Low .59052 20.707 .0005 Elem Cd Co Cr Units ppm ppm ppm Avge .0012 .0013 .0009 SDev .0004 .0005 .0005 %RSD 35.44 38.09 50.53 #1..0016 NOCHECK .0017 .0013- - .0012 .0014 .0012 .0008 .0008 .0004 Errors NOCHECK NOCHECK NOCHECK High Low Elem Mn Mo Na Units ppm ppm ppm Avge .0008 .0165 2.561 SDev .0004 .0064 .030 %RSD 50.56 39.02 1.152 #1 .0012 .0235 2.594 #2 .0008 .0149 2.553 #3 .0004 .0110 2.536 Errors NOCHECK NOCHECK LC Pass High 2.750 Low 2.250 Elem 2068/2 1960/1 1960/2 Units ppb ppb ppb Avge 19.317 3.1787 1.8636 SDev 8.186 2.9265 1.9001 %RSD 42.377 92.066 101.96 28.558 6.5252 2.3102 16.4.20 1.9120 3.5005 #3 12.974 1.0989 -.22007 Errors NOCHECK NOCHECK NOCHECK 12/12/06 06:57:14 AM page 1 Operator: MAG B Ba Be Ca ppm ppm ppm ppm .0089 .0010 .0010 .0176 .0018 .0004 .0004 .0081 19.,96 41.28 42.04 45.93 .0107 .0015 .0014 .0259 .0087 .0010 .0010 .0171 .0072 .0006 .0006 .00.98 NOCHECK NOCHECK NOCHECK NOCHECK Cu Fe K Mg ppm -ppm ppm ppm .0011 2.475 .0845 .0194 .0004 .002 .0224 .0063 34.41 .0994 26.52 32.50 .0014 2.475 .1086 .0249 .0013 2.478 .0806 .0208 .0007 2.473 .0643 .0125 NOCHECK LC Pass NOCHECK NOCHECK 2.750 2.250 Ni 2203/1 2203/2 2068/1 ppm ppb ppb ppb .0011 1.4703 .59052 20.707 .0005 1.8767 .22284 9.672 44.20 127.64 37.735 46.709 .0013 2.7861 .63198 31.336 .0013 2.3035 .34987 18.360 .0005 -.67871 .78972 12.424 NOCHECK NOCHECK NOCHECK NOCHECK Si Sn Sr Ti ppm ppm ppm ppm .0408 .0008 .0010 .0012 .0253 .0030 .0004 .0004 6.1.96 371.1 40.86 39.02 .0682 .0042 .0015 .0016 .0355 -.0010 .0010 .0011 .0185 -.0008 .0006 .0007 NOCHECK NOCHECK NOCHECK NOCHECK Analysis Report - 12/12/06 06:57:14 AM page 2 --- jh Zn Low Sb2068 Elem T11908 Units ppb Avge .00193 SDev .42711 %RSD 22153. #1 -.13773 #2 -.33787 #3 .48138 Errors NOCHECK High 43.836 Low .0014 v Zn Pb2203 Sb2068 Se1960 PPM ppm ppb ppb ppb .0009 .0016 .88353 19.780 2.3015 .0005 .0005 .53398 8.671 1.8412 58.48 32.03 60.437 43.836 79.997 .0014 .0021 1.3493 29.483 3.7138 .0009 .0015 1.0005 17.066. 2.9716 .0004 .0011 .30077 12.791 .21918 NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK O 00 O O L/� Analysis Report 12/12/06 07:04:51 AM page 1 P iod: CLP1 Sample Name: ICB Operator: MAG Time: 12/12/06 06:57:19 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge -.05598 .0060 .41101 .0024 .0002 .0002 .0048 SDev .39943 .0007 .26216 .0004 .0001 .0000 .0006 %RSD 713.48 12.50 63.784 17.59 23.74 19.83 13.12 #1 .06785 .0065 .53742 .0026 .0002 .0002 .0048 #2 -.50267 .0063 .58601 .0026 .0003 .0002 .0054 #3 .26687 .0051 .10960 .0019 .0002 .0002 .0041 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .2000 10.000 .2000 .2000 .0050 .2000 Low -10.000 -.2000 -10.000 -.2'000 -.2000 -.0050 -.2000 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0004 .0004 .0002 .0005 .0045 .0480 .0031 SDev .0002 .0001 .0002 .0001 .0009 .0015 .0014 %RSD 47.66 37.62 135.1 21.27 19.25 3.049 43.93 ##1 .0005 .0004 .0004 .0006 .0048 .0479 .0027 - .0004 .0002 .0001 .0005 .0052 .0495 .0047 .0002 .0004 -.0000 .0004 .0035 .0466 .0020 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .0050 .0500 .0100 .0250 .1000 5.000 .2000 Low -.0050 -.0500 -.0100 -.0250 -.1000 -5.000 -.2000 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 Units ppm ppm ppm ppm ppb ppb ppb Avge .0002 .0052 .0114 .0002 -.50246 .59140 4.9725 SDev .0000 .0010 .0021 .0001 .81919 .89350 1.6310 %RSD 8.090 19.08 18.15 48.63 163.03 151.08 32.801 #1 .0002 .0063 .0122 .0003 .08712 .81949 6.8332 #2 .0003 .0051 .0130 .0001 -.15667 -.39404 4.2940 #3 .0002 .0043 .0091 .0001 -1.4378 1.3488 3.7902 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High .0150 5.000 .0400 Low -.0150 -5.000 -.0400 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 4.7827 .53466 .07445 -.0413 .0017 .0002 .0003 SDev 2.9042 .90537 1.3211 .0114 .0018 .0000 .0001 %RSD 60.722 169.34_ 1774.5 27.65' 108.5 18.38 28.17 7.5354 .13060 1.5979 -.0298 -.0004 .0002 .0004 ff� 5.0651 -.09834 -.61973 -.0414 .0029 .0002 .0003 #3 1.7477 1.5717 -.75486 -.0526 .0026 .0002 .0002 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK r ---i 00 O O H Analysis Report ----gh Low Elem T11908 Units ppb Avge -.21817 SDev .35724 %RSD 163.74 #1 -.61841 #2 .06841 #3 -.10452 Errors LC Pass High 10.000 Low -10.000 v ppm .0003 .0002 66.03 .0003 .0001 .0005 LC Pass .0500 -.0500 Zn ppm .0006 .0001 7.312 .0006 .0007 .0006 LC Pass .0200 -.0200 12/12/06 07:04:51 AM page 2 Pb2203 ppb .22717 .47584 209.47 .57563 -.31497 .42084 LC Pass 3.0000 -3.0000 Sb2068 ppb 4.8459 2.4371 50.292 7.3016 4.8083 2.4278 LC Pass 60.000 -60.000 Se1960 ppb .22772 .79826 350.55 1.1093 -.44608 .01991 LC Pass 5.0000 -5.0000 N 00 O O V) E-+ Analysis Report P iod: CLP1 Sample Name: CRII F_.,.._ Time: 12/12/06 07:04:56 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 Units ppb ppm ppb Avge 20.097 .0051 22.483 SDev .561 .0025 1.514 %RSD 2.7931 48.84 6.7322 #1 20.057 .0067 22.153 #2 19.556 .0064 21.161 #3 20.677 .0022 24.134 Elem Cd Co Cr Units ppm ppm ppm Avge .0106 .1040 .0208 SDev .0001 .0003 .0001 %RSD 1.087 .2468 .5259 #1 .0107 .1039 .0209 #2 .0105 .1038 .0207 #3 .0107 .1043 .0207 Elem Mn Mo Na L t s ppm ppm ppm 4e .0311 .0305 .0101 SDev .0001 .0002 .0022 %RSD .3140 .5711 21.33 #1 .0312 .0305 .0125 #2 .0310 .0307 .0093 #3 .0311 .0304 .0084 Elem 2068/2 1960/1 1960/2 Units ppb ppb ppb Avge 126.78 10.985 11.167 SDev 2.67 5.147 .901 %RSD 2.1060 46.854 8.0654 #1 124.65 16.397 10.638 #2 129.78- 10.405 12.207 #3. 125.92 6.1523 10.657 Elem T11908 V- Zn Units ppb ppm ppm Avge 18.538 .1030 .0465 SDev .734 .0004 .0002 %RSD 3.9574 .4322 .3545 #1 17.864 .1027 .0467 #2 19.320 .1029 .0464 18.429 .1035 .0465 12/12/06 07:12:28 AM page 1 Operator: MAG B ppm .2136 .0004 .2002 .2140 .2132 .2136 Cu ppm .0524 .0003 .5843 .0522 .0522 .0527 Ni PPM .0817 .0008 1.007 .0827 .0813 .0812 Si PPM .0385 .0012 3.068 .0376 .0399 .0382 Pb2203 ppb 5.2798 1.1331 21.461 5.1578 6.4690 4.2127 Ba ppm .0001 .0000 44.73 .0002 .0001 .0001 Fe PPM .0013 .0009 68.68 .0022 .0012 .0004 .2203/1 ppb 4.8159 2.7638 57.390 6.3169 6.5044 1.6263 Sn PPM .0809 .0018 2.260 .0830 .0800 .0797 Sb2068 ppb 126.91 1.26 .99430 125.58 128.09 127.05 Be PPM .0107 .0000 .3941 .0107 .0106 .0106 K PPM .0455 .0032 7.062 .0490 .0427 .0448 2203/2 ppb 5.5114 .9361 16.985 4.5791 6.4513 5.5039 Sr ppm .0001 .0000 40.72 .0001 .0001 .0001 Se1960 ppb 11.107 1.754 15.789 12.555 11.607 9.1571 Ca ppm .0042 .0009 22.76 .0053 .0036 .0037 Mg PPM -.0009 .0014 160.2 .0007 -.0013 -.0020 2068/1 ppb 127.16 2.32 1.8211 127.45 124.72 129.33 Ti ppm .1622 .0002 .0989 .1620 .1622 .1623 M 00 O O C/� Analysis Report 12/12/06 07:20:05 AM page 1 i N .od: CLPI Sample Name: ICSAI Operator: MAG F Time: 12/12/06 07:12:33 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .35009 503.8 5.3462 .0350 .0012 .0004 506.8 SDev .08969 2.6 5.9127 .0003 .0001 .0001 4.0 %RSD 25.619 .5202 110.60 .9879 5.640 20.10 .7943 ##1 .26367 503.0 8.2192 .0350 .0012 .0003 504.1 #2 .44273 501.7 9.2735 .0354 .0012 .0003 504.8 #3 .34385 506.8 -1.4540 .0347 .0013 .0005 511.4 Errors LC Pass LC Pass NOCHECK NOCHECK LC Pass LC Pass LC Pass High- 10.000 600.0 .2000 .0050 600.0 Low -10.000 400.0 -.2000 -.0050 400.0 Elem Cd Cc Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge -.0025 -.0004 .0033 .0011 202.8 .0420 505.2 SDev .0004 .0001 .0002 .0001 1.5 .0066 2.8 %RSD 14.59 36.93 4.840 5.723 .7542 15.58 .5583 ##1 -.0023- -.0002 .0'035 .0010 201.9 .0392 503.6 -.0023 -.0005 .0032 .0011 202.0 .0374 503.6 -.0030 -.0004 .0032 .0012 204.6 .0495 508.5 Errors LC Pass NOCHECK LC Pass NOCHECK LC Pass NOCHECK LC Pass High 0050 .0100 240.0 600.0 Low -.0050 -.0100 160.0 400.0 i Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 Units ppm ppm ppm ppm ppb ppb ppb Avge -.0051 .0004 .0670 .0048 -4.1798 2.4320 -1.8305 SDev .0017 .0011 .0005 .0005 3.4266 1.6027 10.0326 %RSD 33.72 263.8 .7416 11.35 81.979 65.900 548.06 ##1 -.0042 .0014 .0665 .0053 -7.4811 4.2121 6.6430 i #2 -.0041 -.0008 .0672 .0042 -.64040 1.1036 -12.908 #3 -.0071 .0006 .0674 .0049 -4.4179 1.9804 .77379 Errors LC Pass NOCHECK NOCHECK LC Pass NOCHECK NOCHECK NOCHECK High .0150 .0400 Low -.0150 -.0400 i Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb . ppm ppm ppm ppm Avge 2.5565 3.9289 -10.136 -.0734 .0367 -.2998 .0058 SDev 7.4851 4.3876 7.842 .0016, .0024 .0043 .0001 %RSD 292.78 111.68 77.365 2.117 6.653 1.435 1.234 00 O O -1.5686 -.38051 -2.2325 -.0740 .0378 -.2979 .0058 �4 11.197 8.3908 -10.261 -.0716 .0384 -.2968 .0058 #3 -1.9585 3.7764 -17.915 -.0745 .0339 -.3047 .0059 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK Analysis Report 12/12/06 07:20:05 AM --- � h Low Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge -3.1762 .0057 -.0135 .23033 1.0956 L-5.4524 SDev 1.9553 .0003 .0002 .34508 2.1100 4.6976 %RSD 61.560 4.326 1.729 149.82 192.58 86.156 #1 -5.4309 .0055 -.0134 .31831 1.1659 -1.6158 #2 -1.9469 .0060 -.0133 .52290 3.1696 -4.0499 #3 -2.1509 .0056 -.0138 -.15023 -1.0487 L-10.691 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Low High 10.000 .0500 .0200 6.0000 60.000 5.0000 Low -10.000 -.0500 -.0200 -6.0000 -60.000 -5.0000 page 2 00 O O cn H Analysis Report M od: CLP1 Sample Name: ICSABI pl- Time: 12/12/06 07:20:11 ppm Comment: TSL008 -.2989 .0054-+ Mode: CONC Corr. Factor: 1 .0007 Elem Ag Al As1890 Units ppb ppm ppb Avge 1086.3 504.1 1043.4 SDev 2.2 1.0 4.5 %RSD .20003 .1902 .42793 ##1 1084.3 503.1 1039.4 ##2 1086.2 504.2 1042.5 #3 1088.6 505.0 1048.2 Errors LC Pass LC Pass LC Pass High 1200.0 600.0 1200.0 Low 800.00 400.0 800.00 Elem Cd Co Cr Units ppm ppm ppm Avge .9618 .4887 .5050 SDev .0034 .0014 .0014 %RSD .3539 .2950 .2727 #1 .9600 .4885 .5045 ' .9597 .4874 .5039 .9657 .4902 .5066 Errors LC Pass LC Pass LC Pass High 1.200 .6000 .6000 Low .8000 .4000 .4000 Elem Mn Mo Na Units ppm ppm ppm Avge .4948 1.034 .0689 SDev .0009 .006 .0005 %RSD .1924 .5668 .7547 ##1 .4944 1.028 .0695 ##2 .4942 1.034 .0687 #3 .4959 1.040 .0686 Errors LC Pass NOCHECK NOCHECK High .6000 Low .4000 Elem 2068/2 1960/1 1960/2 Units ppb ppb ppb Avge -6.8008 1021.2 1016.1 SDev 1.4807 6.5 3.7 %RSD 21.773 :63276 .36566 -8.4914 1015.9 1015.7 -5.7341 1019.4 1012.7 #3 =6.1770 1028.4 1020.1 Errors NOCHECK NOCHECK NOCHECK 12/12/06 07:27:42 AM page 1 Operator: MAG B ppm 1.108 .004 .3452 1.105 1.107 1.112 LC Pass 1.200 .8000 Cu ppm .5690 .0014 .2537 .5674 .5698 .5699 LC Pass .6000 .4000 Ni ppm .9555 .0032 .3397 .9566 .9518 .9580 LC Pass 1.200 .8000, Si ppm -.0081 .0000 .4147 -.0081 -.0081 -.0080 NOCHECK Ba ppm .5338 .0014 .2677 .5323 .5341 .5351 LC Pass .6000 .4000 Fe ppm 203.4 .6 .3108 203.1 203.0 204.2 LC Pass 240.0 160.0 2203/1 ppb 976.09 4.05 .41445 973-.25 974.30 980.72 NOCHECK Be ppm .5175 .0016 .3076 .5168 .5164 .5193 LC Pass .6000 .4000 K ppm .0348 .0064 18.35 .0368 .0276 .0399 NOCHECK 2203/2 ppb 976.91 4.05 .41492 977.53 972.59 980.62 NOCHECK Ca ppm 507.5 1.7 .3289 507.4 505.9 509.2 LC Pass 600.0 400.0 Mg ppm 505.7 1.0 .1928 505.5 504.9 506.8 LC Pass 600.0 400.0 2068/1 ppb -11.035 4.937 44.742 -5.6395 -12.139 -15.328 NOCHECK Sn Sr Ti ppm ppm ppm 1.086 -.2989 .0054-+ .004 .0007 .0000 .4011 .2378 .7175 00 C) O O 1.082 -.2989 .0054 1.085 -.2982 .0053 1.091 -.2996 .0054 NOCHECK NOCHECK NOCHECK Analysis Report 12/12/06 07:27:42 AM Jh Low Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge 989.85 .5152 1.076 976.64 -8.2109 1017.8 SDev 2.23 .0013 .002 3.78 .8924 4.4 %RSD .22570 .2550 .1992 .38673 10.869 .42800 #1 987.80 .5146 1.075 976.10 -7.5417 1015.7 #2 989.54 .5143 1.075 973.16 -7.8668 1014.9 #3 992.23 .5167 1.079 980.65 -9.2241 1022.8 Errors LC Pass LC Pass LC Pass LC Pass NOCHECK LC Pass High 1200.0 .6000 1.200 1200.0 1200.0 Low 800.00 .4000 .8000 800.00 800.00 page 2 00 O O F-, Analysis Report 12/12/06 07:35:19 AM page 1 N od: CLP1 Sample Name: CCVI Operator: MAG K4-. Time: 12/12/06 07:27:48 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1006.9 50.36 523.63 2.651 2.544 2.594 51.25 SDev 17.3 .79 12.47 .048 .046 .044 .73 %RSD 1.7167 1.570 2.3820 1.822 1.793 1.690 1.425 #1 987.00 49.45 509.23 2.595 2.492 2.544 50.41 #2 1015.8 50.83 530.52 2.675 2.569 2.615 51.60 #3 1018.0 50.81 531.1.3 2.681 2.573 2.623 51.74 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 1100.0 55.00 550.00 2.750 2.750 2.750 55.0.0 Low 900.00 45.00 450.00 2.250 2.250 2.250 45.00 Elem Cd Co Cr Cu. Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge 2.541 2.570 2.554 2.606 50.63 84.09 53.24 SDev .040 .044 .043 .049 .81 1.38 .77 %RSD 1.559 1.704 1.697 1.864 1.599 1.647 1.452 #1 2.495 2.520 2.504 2.550 49.70 82.49 52.35 - 2.560 2.590 2.575 2.632 51.02 84.85 53.64 2.567 2.601 2.583 2.636 51.18 84.93 53.73 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 2.750 2.750 2.750 2.750 55.00 88.00 55.00 Low 2.250 2.250 2.250 2.250 45.00 72.00 45.00 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 Units ppm ppm ppm ppm ppb ppb ppb Avge 2.547 2.631 81.31 2.515 505.76 498.28 992.34 SDev .043 .054 1.24 .040 8.00 5.63 34.53 %RSD 1.694 2.040 1.521 1.598 1.5825 1.1298 3.4796 #1 2.497 2.569 79.88 2.468 497.30 491.90 953.14 #2 2.568 2.653 82.04 2.536 506.79 500.39 1005.6 #3 2.576 2.669 82.01 2.539 513.21 502.54 1018.3 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High 2.750 88.00 2.750 Low 2.250 72.00 2.250 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 991.35 526.29 521.71 2.267 2.592 2.606 1.966 SDev 27.62 8.79 5.47 .095 .042 .047 .035 %RSD 2.7864 1.6698 1.0490 4.208 1.628 1.816 1.779 960.43 516.65 515.88 2.164 2.543 2.552 1.926 1000.0 528.36 522.52 2.286 2.612 2.631 1.984 #3 1013.6 533.85 526.74 2.353 2.619 2.636 1.989 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK 00 00 O O C/1 N Analysis Report 12/12/06 07:35:19 AM - h Low Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb - ppb ppb Avge 508.32 2.564 2.674 500.77 991.68 523.24 SDev 9.15 .044 .046 6.38 29.91 6.57 %RSD 1.8009 1.711 1.708 1.2745 3.0160 1.2560 #1 497.77 2.513 2.622 493.70 958.01 516.14 #2 514.12 2.587 2.696 502.52 1001.9 524.46 #3 513.08 2.592 2.705 506.09 1015.1 529.11 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 550.00 2.750 2.750 550.00 1100.0 550.00 Low 450.00 2.250 2.250 450.00 900.00 450.00 page 2 00 O O Analysis Report 12/12/06 07:42:57 AM page 1 M od: CLP1 Sample Name: CCVL1 Operator: MAG R. Time: 12/12/06 07:35:26 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .49694 .0850 2.6243 .0077 .0011 .0011 .0919 SDev .56667 .0481 1.1740 .0020 .0006 .0006 .0545 %RSD 114.03 56.54 44.734 25.72 49.53 50.99 59.36 #1 1.0950 .1374 3.7381 .0097 .0018 .0017 .1520. #2 -.03206 .0747 2.7366 .0076 .0010 .0010 .0778 #3 .42793 .0429 1.3983 .0058 .0007 .0006 .0458 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK High Low Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0014 .0012 .0013 .0015 2.492 .0735 .0929 SDev .0007 .0006 .0007 .0006 .025 .0209 .0558 %RSD 53.26 45.76 55.53 37.98 .9993 28.48 60.06 #1 .0022 .0018 .0020 .0021 2.520 .0970 .1547 .0011 .0012 .0010 .0014 2.483 .0668 .0781 .0008 .0007 .0007 .0009 2.473 .0568 .0460 Errors NOCHECK NOCHECK NOCHECK NOCHECK LC Pass NOCHECK NOCHECK High 2.750 Low 2.250 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 Units ppm ppm ppm ppm ppb ppb ppb Avge .0009 .0162 2.584 .0012 -.60541 -.14707 21.555 SDev .0006 .0071 .013 .0010 1.65267 .34904 9.683 %RSD 67.97 43.81 .5211 87.10 272.98 237.33 44.921 #1 .0016 .0239 2.589 .0023 -1.6397 -.43895 32.437 #2 .0007 .0150 2.594 .0008 1.3006 .23957 18.340 #3 .0004 .0098 2.569 .0004 -1.4772 -.24182 13.889 Errors NOCHECK NOCHECK LC Pass NOCHECK NOCHECK NOCHECK NOCHECK High 2.750 Low 2.250 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 18.340 3.5790 .49753 -.0022 .0004 .0010 .0010 SDev 8.444 2.3675 2.3654 .0198 .0009 .0005 .0005 %RSD 46.043 66.150 475.42 891.1 206.9 52.36 52.03 27.373 4.6729 3.2196 .0184 .0013 .0015 .0016 17.004 5.2017 -.66889 -.0041 .0005 .0008 .0009 ffz #3 10.644 .86234 -1.0581 -.0209 -.0005 .0005 .0006 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK O 00 O O N Analysis Report 12/12/06 07:42:57 AM Low Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge .95438 .0010 .0018 -.29965 19.411 1.5237 SDev 1.0219 .0009 .0006 .77856 8.832 2.0713 %RSD 107.08 88.72 33.49 259.82 45.502 135.94 #1 .85988 .0020 .0024 -.83875 29.059 3.7036 #2 -.01702 .0003 .0016 .59294 17.449 1.2860 #3 2.0203 .0008 .0013 -.65315 11.724 -.41857 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK High Low page 2 Analysis Report 12/12/06 07:50:35 AM page 1 N :od: CLP1 Sample Name: CCB1 Operator: MAG R`.<__ Time: 12/12/06 07:43:03 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .06964 .0160 .67345 .0017 .0002 .0002 .0194 SDev .22400 .0057 1.5165 .0003 .0001 .0001 .0060 %RSD 321.66 35.86 225.18 18.06 29.37 38.82 31.11 #1 .01795 .0205 2.4242 .0019 .0002 .0003 .0246 #2 .31497 .0180 -.17321 .0018 .0002 .0002 .0208 #3 -.12400 .0096 -.23063 .0013 .0001 .0001 .0128 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .2000 10.000 .2000 .2000 .0050 .2000 Low -10.000 -.2000 -10.000 -.2000 -.2000 -.0050 -.2000 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0004 .0001 .0001 .0003 .0112 .0392 .0201 SDev .0001 .0001 .0001 .0002 .0036 .0040 .0082 %RSD 27.66 59.88 57.83 62.66 31.73 10.32 40.78 #1 .0005 .0002 .0001 .0003 .0141 .0436 .0277 - .0004 .0001 .0002 .0004 .0123 .0356 .0212 .0003 .0001 .0001 .0001 .0072 .0384 .0114 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .0050 .0500 .0100 .0250 .1000 5.000 .2000 Low -.0050 -.0500 -.0100 -.0250 -.1000 -5.000 -.2000 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 Units ppm ppm ppm ppm ppb ppb ppb Avge .0001 .0047 .0073 -.0000 -.66526 .39721 5.5082 SDev .0001 .0011 .0026 .0004 .93482 1.0575 1.7853 %RSD 74.10 22.76 34.73 1525. 140.52 266.25 32.411 #1 .0003 .0059 .0097 -.0004 .38659 -.41152 5.3550 #2 .0001 .0046 .0077 .0004 -1.4012 1.5940 7.3652 #3 .0001 .0038 .0046 -.0000 -.98120 .00918 3.8045 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High .0150 5.000 .0400 Low -.0150- -5.000 -.0400 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm Ppm ppm Avge 4.4308 2.9722 -.96044 -.0694 -.0008 .0002 .0002 SDev 3.1016 4.5605 .36581 .0069 .0014 .0001 .0000 %RSD 70.001 153.44 38.088 10.00 169.8 39.24 15.14 7.4842 6.0283 -.90890 -.0630 -.0024 .0003 .0002 1.2831 -2.2698 -.62313 -.0685 .0002 .0002 .0001 n.� #3 4.5251 5.1581 -1.3493 -.0768 -.0002 .0001 .0002. Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK N 00 O O E ..q Analysis Report 12/12/06 07:50:35 AM page 2 -__ 1h Zn Low Sb2068 Elem T11908 Units ppb Avge -.92335 SDev .74739 %RSD 80.944 #1 -.06037 #2 -1.3620 #3 -1.3477 Errors LC Pass High 10.000 Low -10.000 v Zn Pb2203 Sb2068 Se1960 PPM ppm ppb ppb ppb .0001 .0003 .04343 4.7896 .34916 .0001 .0001 .48699 1.7876 1.3488 175.7 22.25 1121.3 37.322 386.31 .0002 .0004 -.14573 6.7752 1.4012 -.0000 .0003 .59662 3.3085 -1.1714 -.0000 .0002 -.32060 4.2852 .81769 LC Pass LC Pass LC Pass LC Pass LC Pass .0500 .0200 3.0000 60.000 5.0000 -.0500 -.0200 -3.0000 -60.000 -5.0000 M 00 O O C!1 N Analysis Report 12/12/06 07:58:12 AM page 1 N tod: CLP1 Sample Name: M13-19090 Operator: MAG k- Time: 12/12/06 07:50:41 Comment: TSL008 Mode: CONC Corr. Factor: 1�" Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge -.58070 -.0001 -.40847 .0000 .0001 -.0000 .0032 SDev .50046 .0005 1.48451 .0003 .0000 .0001 .0009 %RSD 86.183 968.9 363.43 1372. 65.68 170.8 26.79 ##1 -1.0927 -.0006 -1.5510 .0000 .0001 -.0000 0042 #2 -.09259 -.0000 1.2695 .0003 .0001 .0000 .0030 #3 -.55685 .0004 -.94391 -.0003 .0000 -.0001 .0025 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .2000 10.000 .2000 .2000 .0050 .2000 Low -10.000 -.2000 -10.000 -.2000 -.2000 -.0050 -.2000 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0000 .0003 .0007 .0003 .0018 .0383 -.0007 SDev .0001 .0002 .0001 .0002 .0004 .0023 .0022 %RSD 148.6 63.04 19.77 61.59 21.26 6.054 308.4 #1 -.0000 .0004 .0008 .0004 .0021 .0410 .0003 "- .0001 .0006 .0006 .0001 .0019 .0372 .0008 .0000 .0001 .0006 .0002 .0014 .0368 -.0032 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .0050 .0500 .0100 .0250 .1000 5.000 .2000 Low -.0050 -.0500 -.0100 -.0250 -.1000 -5.000 -.2000 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 Units ppm ppm ppm ppm ppb ppb ppb Avge .0001 .0028 .0004 .0002 4.9260 -1.4143 2.0901 SDev .0001 .0003 .0004. .0007 3.2745 1.7152 1.6364 %RSD 61.47 11.36 90.12 429.1 66.474 121.28 78.290 #1 .0002 .0031 .0006 .0007 8.5416 -2.0423 .67007 #2 .0002 .0029 -.0000 -.0006 4.0759 -2.7270 1.7207 #3 .0001 .0025 .0007 .0003 2.1604 .52641 3.8796 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High .0150 5.000 .0400 Low -.0150 -5.000 -.0400 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 3.9779 -5.2072 1.8923 -.1239 .0016 .0000 .0010 SDev 1.3963 3.0248 1.8232 .0043 .0009 .0000 .0001 %RSD 35.101 58.088 96.345 3.496 56.46 73.47 10.37 5.5083 -2.5752 2.0071 -.1272 .0025 .0000 .0011 3.6517 -4.5350 .01447 -.1254 .0016 .0000 .0011 ff� #3 2.7735 -8.5116 3.6554 -.1190 .0007 .0000 .0009 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK- NOCHECK NOCHECK Analysis Report 12/12/06 07:58:12 AM Low Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge -2.4213 -.0003 .0035 .69704 3.3493 -.47181 SDev .8253 .0002 .0001 1.0243 .4792 .99302 %RSD 34.083 68.39 2.323 146.95 14.307 210.47 #1 -3.0930 -.0005 .0035 1.4822 3.8972 .48124 #2 -2.6709 -.0003 .0034 -.46162 3.0087 -1.5005 #3 -1.5001 -.0001 .0036 1.0706 3.1419 -.39620 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .0500 .0200 3.0000 60.000 5.0000 Low -10.000 -.0500 -.0200 -3.0000 -60.000 -5.0000 page 2 00 O O E-4 Analysis Report N Lod: CLPl Sample Name: LCS-19090 Time: 12/12/06 07:58:18 517.97 2.214 Comment: TSL008 518.53 2.273 Errors NOCHECK Mode: CONC Corr. Factor: 1 NOCHECK Elem Ag Al As1890 B Units ppb ppm ppb pp Avge 1006.0 49.53 514.22 2. SDev 4.0 .21 4.03 %RSD .39480 .4273 .78303 41 1007.4 49.63 511.97 2. #2 1001.5 49.28 511.83 2. #3 1009.1 49.67 518.87 2. Errors LC Pass LC Pass LC Pass LC High 1200.0 60.00 600.00 3. Low 800.00 40.00 400.00 2. Elem Cd Co Cr C Units ppm ppm ppm pp Avge 2.525 2.557 2.538 2. SDev .013 .013 .013 %RSD .5302 .5243 .5093 #1 2.527 2.565 2.543 2. "-2.511 2.541 2.524 2. 2.538 2.564 2.548 2. Errors LC Pass LC Pass LC Pass LC High 3.000 3.000 3.000 3. Low 2.000 2.000 2.000 2. Elem Mn Mo Na Ni Units ppm ppm ppm pp Avge 2.533 2.605 82.91 2 SDev .012 .016 .37 %RSD .4801 .6211 ..4469 #1 2.537 2.595 83.18 2 #2 2.519 2.595 82.49 2 #3 2.542 2.623 83.07 2 Errors LC Pass NOCHECK LC Pass LC High 3.000 96.00 3 Low 2.000 64.00 2 Elem. 2068/2 1960/1 1960/2 Si Units ppb - ppb ppb pp Avge 997.23 519.90 515.82 2 SDev 13.54 5.44 4.22 %RSD 1.3576 1.0466 .81760 1 12/12/06 08:05:49 AM Operator: MAG s m 642 009 3404 643 632 650 Pass 000 000 u m 602 010 3777 I 000 000 m 501 011 4237 504 489 510 Pass 000 000 m 227 .041 .862 984.04 522.17 510.96 2.193 n- 996.54, 513.69 517.97 2.214 #3 1011.1 523.84 518.53 2.273 Errors NOCHECK NOCHECK NOCHECK NOCHECK Ba ppm 2.538 .010 .4042 2.543 2.526 2.545 LC Pass 3.000 2.000 Fe ppm 51.12 .27 .5344 51.24 50.80 51.31 LC Pass 60.00 40.00 2203/1 ppb 499.01 2.80 .56018 500.18 495.82 501.04 NOCHECK Sn ppm 2.564 .015 .5702 2.571 2.548 2.574 NOCHECK Be ppm 2.583 .012 .4773 2.586 2.569 2.593 LC Pass 3.000 2.000 K ppm 85.69 .29 .3401 85.89 85.36 85.84 LC Pass 96.00 64.00 2203/2 ppb 490.86 2.23 .45509 489.95 489.23 493.41 NOCHECK Sr ppm 2.598 .010 .3987 2.603 2.587 2.606 NOCHECK page 1 Ca ppm 50.18 .26 .5213 50.25 49.89 50.40 LC Pass 60.00 40.00 Mg ppm 52.11 .24 .4661 52.21 51.84 52.29 LC Pass 60.00 40.00 2068/1 ppb 1001.4 16.0 1.5979 983.38 1007.0 1013.9 NOCHECK Ti ppm 1.951 .009 .4603 1.954 1.941 1.958 NOCHECK Analysis Report 12/12/06 08:05:49 AM -,:4h Low Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge 502.64 2.551 2.668 493.58 998.62 517.18 SDev 2.28 .013 .012 2.27 14.15 2.85 %RSD .45270 .4938 ..4624 .45994 1.4172 .55195 #1 502.58 2.555 2.672 493.36 983.82 514.69 42 500.40 2.537 2.654 491.42 1000.0 516.54 #3 504.95 2.561 2.677 495.95 1012.0 520.30 Errors LC Pass LC Pass LC Pass LC Pass LCPass LC Pass High 600.00 3.000 3.000 600.00 1200.0 600.00 Low 400.00 2.000 2.000 400.00 800.00 400.00 page 2 00 O O Analysis Report 12/12/06 08:13:27 AM page 1 P iod: CLP1 Sample Name: 0612702-OOIE Operator: MAG Fes_: Time: 12/12/06 08:05:55 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .30185 .0252 1.1970 .0042 .0011 .0008 .0663 SDev .23269 .0090 2.2071 .0018 .0005 .0005 .0094 %RSD 77.088 35.82 184.38 42.17 43.47 56.71 14.21 #1 .52030 .0351 3.7327 .0062 .0016 .0014 .0767 #2 .05714 .0234 -.29217 .0035 .0010 .0007 .0639 #3 .32812 .0173 .15058 .0029 .0007 .0004 .0584 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0011 .0010 .0013 .0025 .0281 .0847 .0216 SDev .0005 .0004 .0006 .0008 .0097 .0208 .0117 %RSD 48.10 41.68 49.17 31.68 34.42 24.53 54.26 #1 .0016 .0015 .0020 .0034 .0386 .1084 .0350 #2 .0009 .0007 .0009 .0021 .0261 .0753 .0157 #3 .0007 .0008 .0009 .0019 .0195 .0702 .0139 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 its ppm ppm ppm ppm ppb ppb ppb je .0011 .0150 .0763 .0015 .59788 .73711 13.536 SDev .0005 .0063 .0171 .0000 .27939 .26745 8.993 %RSD 49.46 42.14 22.38 .5475 46.731 36.284 66.439 #1 .0017 .0219 .0948 .0015 .74963 .57348 23.580 #2 .0009 .0135 .0730 .0015 .27545 .59210 10.798 #3 .0006 .0096 .0611 .0015 .76857 1.0457 6.2303 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 10.443 -.11400 1.8641 .1039 .0011 .0009 .0016 SDev 6.418 4.24781 .3762 .0155 .0008 .0005 .0005 %RSD 61.458 3726.1 20.179 14.88 77.21 57.08 29.31 #1 16.871 -.10024 1.9727 .1207 .0019 .0014 .0021 $#2 10.421 -4.3687 1.4456 .1010 .0002 .0008 .0015 #3 4.0358 4.1269 2.1740 .0902 .0012 .0005 .0012 Elem T119.08 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge -.73527 .0007 .0399 .69083 11.473 1.2054 SDev .35284 .0004 .0005 .23885 7.214 1.6588 %RSD 47.987 57.84 1.319 34.574 62.881 137.61 #1 -.45097 .0011 .0405 .63222 19.105 1.2824 #k2 -1.1302 .0003 .0397 .48674 10.546 -.49053 -.62468 .0007 .0395 .95353 4.7666 2.8244 00 00 O O C/1 H Analysis Report 12/12/06 08:21:04 AM page 1 P iod: CLP1 Sample Name: 0612702-002E Operator: MAG 1,_.,, Time: 12/12/06 08:13:32 Comment: TSL008W 37 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .12246 .0797 6.3582 .966.2 .2071 .0001 75.41 SDev .25719 .0011 .2958 .0061 .0017 .0000 .53 %RSD 210.03 1.352 4.6517 .6305 .8185 21.17 .7064 #1 -.15747 .0808 6.6795 .9731 .2091 .0001 75.98 #2 .34832 .0796 6.0972 .9633 .2062 .0001 75.33 #3 .17652 .0787 6.2978 .9620 .2061 .0001 74.92 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0002 .0374 .0021 .0086 6.413 131.3 33.81 SDev .0002 .0002 .0002 .0001 .047 1.0 .23 %RSD 75.35 .5693 9.214 1.407 .7266 .7972 .6921 #1 .0004 .0374 .0022 .0086 6.465 132.5 34.07 #2 .0002 .0376 .0022 .0087 6.398 130.6 33.74 #3 .0001 .0372 .0019 .0084 6.376 130.8 33.61 Elem Mn Mo Na Ni 2203/1 2.203/2 2068/1 Lts ppm ppm ppm ppm ppb ppb ppb 3e 4.044 .0051 220.8 .0449 .73971 -.56685 1.2521 SDev .028 .0006 1.5 .0003 .98314 .43087 1.4385 %RSD .6915 12.29 .6989 .6227 132.91 76.011 114.89 #1 4.075 .0057 222.6 .0453 1.8434 -.87050 2.0409 #2 4.036 .0051 220.0 .0448 .41802 -.07371 -.40829 #3 .4.021 .0045 219.9 .0448 -.04228 -.75.635 2.1237 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 5.0252 .35498 -1.7154 5.456 .0010 .4727 .0041 SDev 2.0250 3.0476 2.5491 .046 .0009 .0038 .0001 %RSD 40.296 858.54 148.60 .8491 90.59 .8003 1.317 #1 7.3574 1.5941 .90398 5.509 .0019 .4771 .0041 #2 4.0048 2.5879 -1.8624 5.434 .0008 .4704 .0041 #3 3.7134 -3.1170 -4.1879 5.424 .0002 .4706 .0040 Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge -1.4684 .0005 .0496 -.13174 3.7688 -1.0260 SDev 1.0732 .0002 .0004 .33618 1.607-7 2.5447 %RSD 73.088 40.15 .7405 255.17 42.658 248.03 ##1 -2.5226 .0003 .0500 .03325 5.5870 1.1338 -1.5055 .0005 .0495 .09006 2.5353 -.38046 -.37713 .0007 .0493 -.51854 3.1841 -3.8313 00 O O h Analysis Report 12/12/06 08:28:41 AM page 1 N.' od: CLP1 Sample Name: 0612702-003E Operator: MAG R-,.. Time: 12/12/06 08:21:10 Comment: TSLO 0 8 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .64649 6.138 7.4592 .2553 .2247 .0004 57.35 SDev .10033 .013 1.1386 .0007 .0004 .0000 .24 %RSD 15.520 .2099 15.265 .2726 .1698 2.537 .4117 ##1 .70818 6.130 8.0276 .2547 .2242 .0004 57.09 #2 .53071 6.132 8.2017 .2551 2248 .0004 57.44 #3 .70057 6.153 6.1483 .2561 .2249 .0004 57.53 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0018 .0324 .0239 .0813 68.92 43.03 25.18 SDev .0002 .0002 .0001 .0000 .25 .06 .07 %RSD 8.887 .5121 .3672 .0520 .3588 .1454 .2975 #1 .0019 .0323 .0238 .0814 68.63 43.03 25.10 #2 .0017 .0323 .0240 .0813 69.05 42.97 25.22 #3 .0017 .0326 .0240 .0813 69.07 43.09 25.24 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 -- '_ t s ppm ppm ppm ppm ppb- ppb ppb 4e 22.12 .0018 53.31 .0194 6.9751 -5.6833 -2.5928 SDev .08 .0003 .06 .0002 1.4618 .5854 2.2685 %RSD .3597 17.64 .1197 .8287 20.957 10.300 87.491 #1 22.03 .0022 53.29 .0196 8.5301 -6.1703 -4.1176 #2 22.15 .0018 53.26 .0193 6.7661 -5.8458 .01410 #3 22.18 .0015 53.38 .0193 5.6290 -5.0338 -3.6750 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 10.221 -3.6279 -2.7737 10.28 .0113 .3783 .4369 SDev 1.215 1.9252 .6878 .02 .0002 .0009 .0013 %RSD 11.885 53.067 24.799 .2048 1.988 .2283 .2952 #1 11.261 -1_.6135 -3.5573 10.26 .0115 .3774 .4355 #2 10.517 -3.8208 -2.4942 10.28 .0110 .3790 .4374 #3 8.8860 -5.4495 -2.2696 10.30 .0113 .3786 .4379 Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm. ppm ppb ppb ppb Avge 4.7724 .0195 .0958 -1.4681 5.9541 -3.0581 SDev 1.8445 .0002 .0003 .1860 1.1692 .2345 %RSD 38.650 1.207 .3526 12.667 19.636 7.6674- .6674#1 #1 4.1338 .0193 .0954 -1.2750 6.1400 -2.9100 2 3.3321 .0198 .0961 -1.6460 7.0193 -2,9360 6.8515 .0195 .0958 -1.4831 4.7032 -3.3285 O 00 00 O O V) Analysis Report 12/12/06 08:36:19 AM page 1 N' Lod: CLP1 Sample Name: 0612702-004E Operator: MAG Rui, Time: 12/12/06 08:28:47 Comment: TSL008W_ytJ Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .54150 .8352 1.7034 .1348 .1249 .0001 58.79 SDev .16465 .0043 .2083 .0005 .0002 .0000 .15 %RSD 30.407 .5117 12.226 .3662 .1850 28.75 .2586 #1 .35271 .8392 1.8116 .1353 .1252 .0001 58.85 #2 .61646 .8357 1.8353 .1346 .1249 .0001 58.90 #3 .65534 .8307 1.4633 .1344 .1247 .0001 58.62 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0004 .0053 .0221 .0084 2.264 44.78 20.21 SDev .0001 .0003 .0003 .0002 .017 .09 .04 %RSD 13.73 5.030 1.186 1.893 .7620 .2114 .2076 #1 .0004 .0055 .0221 .0083 2.281 44.81 20.23 ##2 .0005 .0055 .0223 .00.85 2.266 44.68 20.23 #3 .0004 .0050 .0218 .0082 2.246 44.87 20.16 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 Lts ppm ppm ppm ppm ppb ppb ppb je 9.642 .0016 19.17 .0105 4.8183 3.6321 -.64735. SDev .025 .0006 .03 .0001 1.7397 .5030 .84115 %RSD .2554 35.61 .1617 1.193 36.107 13.849 129.94 #1 9.658 .0023 19.18 .0107 6.5362 4.1362 -1.6051 #2 9.655 .0015 19.13 .0105 4.8612 3.6299 -.02862 #3 9.614 .0011 19.19 .0104 3.0575 3.1302 -.308.32 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 4.5727 -3.7286 -.62146 3.545 .0006 .1885 .0382 SDev .9496 1.2973 1.22490 .004 .0013 .0005 .0002 0 -,RSD 20.767 34.792 197.10 .1047 232.4 .2618 .5259 #1 3.5578 -3.7426 .70930 3.550 .0010 .1891 .0382 #2 4.7206 -2.4245 -1.7018 3.543 -.0009 .1884 .0384 #3 5.4397 -5.0189 -.87186 3.543 .0016 .1881 .0380 Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge 1.0055 .0029 .0436 4.0272 2.8344 -1.6561 SDev 1.2950 .0002 .0002 .9148 .8838 .7803 %RSD 128.79 7.805 .4051 22.715 31.181 47.114 41 1.7781 .0028 .0438 4.9355 1.8386 -.77316 1.7278 .0031 .0437 4.0400 3.1391 -1.9424 -.48954 .0027 .0434 3.1061 3.5256 -2.2528 00 00 O O r4 V) H Analysis Report 12/12/06 08:43:57. AM page 1 N od: CLP1 Sample Name: 0612702-005E Operator: MAG R_i_ Time: 12/12/06 08:36:25 Comment: TSL008 Aw_ is Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .36830 .0790 3.1117 .8279 .1755 .0000 114.2 SDev .28567 :0030 1.4748 .0165 .0038 .0000 2.2 %RSD 77.563 3.833 47.395 1.995 2.164 159.6 1.951 #1 .27292 .0778 4.4210 .8203 .1743 .0000 113.3 #2 .68945 .0768 3.3999 .8166 .1725 .0001 112.5 #3 .14253 .0825 1.5141 .8469 .1798 -.0000 116.7- 16.7Elem Elem Cd Co Cr Cu Fe K ' Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0002 .0188 .0012 .0043 .3937 128.6 56.53 SDev .0001 .0002 .0003 .0002 .0066 2.8 1.09 %RSD 69.90 1.279 20.95 5.167 1.684 2.197 1.933 ##1 .0001 .0186 .0010 .0042 .3931 127.5 56.14 ##2 .0004 .0187 .0012 .0042 .3874 126.5 55.68 #3 .0001 .0191 .0015 .0046 .4006 131.8 57.76 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 " `ts ppm ppm ppm ppm ppb ppb ppb fe 2.883 .0022 220.1 .0396 1.9696 .30210 .33879- SDev .056 .0004 4.2 .0004 .8124 1.2550 1.7704 %RSD 1.926 17.41 1.904 1.054 41.245 415.43 522.55 #1 2.866 .0022 218.4 .0395 1.8655 -1.0236 .22471 ##2 2.838 .0019 217.1 .0393 2.8290 .45819 -1.3718 ##3 2.945 .0026 224.9 .0401 1.2143 1.4717 2.1634 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 2.8509 -2.3535 .20834 4.071 -.0001 .5215 .0038 SDev_ .3045 3.6292 1.6604 .088 .0005 .0115 .0001 %RSD 10.681 154.21 796.96 2.168 331.4 2.214 1.948 ##1 2.5002 -2.4882 2.1068 4.033 -.0007 .5182 .0037 #2 3.0481 1.3412 -.50875 4.008 .0003 .5119 .0038 #3 3.0044 -5.9135 -.97301 4.172 -.0001 .5343 .0039 Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge -.30357 .0004 .0149 .85744 2.0144 -.64473 SDev 1.41972 .0001 .0002 .79883 .6204 1.72508 %RSD 467.67 33.99 1.576 93.165 30.800 267.56 #1 1.1773 .0003 .0148 -.06150 1.7425 .57667 #k2 -1.6530 .0003 .0147 1.2477 1.5763 .10729 -.43502 .0006 .0151 1.3861 2.7244 -2.6182 N 00 00 O O N Analysis Report 12/12/06 08:51:34 AM page 1 od: CLP1 Sample Name: 0612702-006E Operator: MAG rN' RUL, Time: 12/12/06 08:44:03 ' Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .42963 .8240 2.1361 .6629 .1391 .0001 89.01 SDev .49519 .0277 2.2659 .0199 .0043 .0000 2.56 %RSD 115.26 3.364 106.08 3.000 3.121 35.64 2.876 ##1 .24056 .8333 3.0445 .6687 .1404 .0001 89.85 #2 .99150 .7928 3.8068 .6407 .1343 .0002 86.14 #3 .05683 .8458 -.44303 .6791 .1427 .0001 91.05 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0004 .0219 .0054 .0309 1.278 138.9 62.82 SDev .0001 .0004 .0002 .0011 .038 4.4 1.84 %RSD 28.16 1.891 3.183 3.524 2.989 3.180 2.922. #1 .0005 .0220 .0055 .0314 1.289 140.3 63.41 #2 .0004 .0214 .0054 .0297 1.235 133.9 60.76 #3 .0003 .0222 .0052 .0317 1.309 142.4 64.29 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 -- its ppm ppm ppm ppm ppb - ppb ppb �e 11.94 .0004 194.0 .0418 3.6525 2.0765 -1.4108 SDev .35 .0007 5.6 .0013 1.1450 1.1573 1.1094 %RSD 2.894 183.7 2.888 3.146 31.349 55.735 78.632 ##1 12.05 .0001 195.9 .0418 4.4533 2.6860 -.23158 #2 11.55 -.0001 187.8 .0405 2.3410 .74181 -1.5672 #3 12.22 .0012 198.5 .0432 4.1632 2.8017 -2.4337 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 5.7952 -.17988 -.23190 4.234 .0022 .6290 .0374 SDev 1.0970 1.00293 1.94835 .136 .0005 .0203 .0011 %RSD 18.929 557.54 840.17 3.219 22.38 3.219 2.893 #1 6.4033 .88083 1.9102 4.280 .0025 .6353 .0379 #2 4.5289 -1.1128 -1.8984 4.081 .0024 .6063 .0362 #3 6.4535 -.30769 -.70757 4.342 .0016 .6453 .0383 Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge -.60780 .0019 .0471 2.6013 3.3956 -.21456 SDev .62361 .0001 .0013 1.1492 .8518 1.63214 %RSD 102.60 6.962 2.756 44.179 25.084 760.68 #1 -1.3237 .0018 .0474 3.2745 4.1939 1.5675 -.31680 .0021 .0456 1.2744 2.4989 -1.6368 -.18288 .0018 .0481 3.2551 3.4941 -.57439 M 00 00 O O E-+ Analysis Report 12/12/06 08:59:12 AM page 1 N 'od: CLP1 Sample Name: 0612702-006EDUP Operator: MAG R,.. Time: 12/12/06 08:51:40 Comment: TSL008 Kw ^ -b\.,P Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .59663 .8034 2.7956 .6537 .1374 .0001 87.94 SDev .29618 .0008 .6736 .0016 .0002 .0000 .06 %RSD 49:642 .1019 24.096 .2447 .1367 15.50 .0736 #1 .55658 .8028 2.0204 .6545 .1375 .0001 87.86 ##2 .32252 .8043 3.1280 .6547 .1374 .0001 87.98 #3 .91080 .8031 3.2384 .6519 .1372 .0001 87.97 Elem Cd Cc Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0002 .0217 .0052 .0309 1.216 138.4 62.11 SDev .0001 .0002 .0003 .0002 .000 .2 .05 0 -.RSD 76.92 1.072 5.475 .6050 .0085 .1782 .0783 #1 .0003 .0217 .0055 .0307 1.216 138.5 62.10 #2 .0002 .0215 .0052 .0311 1.216 138.7 62.16 #3 .0000 .0219 .0049 .0309 1.216 138.2 62.07 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 tts ppm ppm ppm ppm ppb ppb ppb 4e 11.82 .0002 191.9 .0416 3.7079 2.0893 -1.9262 SDev .00 .0001 .4 .0003 1.3956 1.3493 2.0565 %RSD .0275 59.83 .2185 .7854 37.639 64.583 106.76 #1 11.81 .0002 192.1 .0413 3.0984 3.5434 -1.0531 #2 11.82 .0004 192.2 .0419 2.7207 1.8469 -.45027 #3 11.82 .0002 191.4 .0417 5.3047 .87756 -4.2751 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 7.1702 -1.2481 -.53573 4.174 .0019 .6220 .0363 SDev .5725 3.2517 1.26928 .006 .0011 .0003 .0001 '-.RSD' 7.9842 260.52 236.93 .1541 59.44 .0463 .3071 #1 7.8254 -1.4891 -1.7013 4.173 .0019 .6223 .0364 #2 6.7668 -4.3727 -.72250 4.181 .0031 .6218 .0363 #3 6.9183 2.1173 .81659 4.168 .0008 .6218 .0362 Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge .59349 .0020 .0529 2.6283 4.1411 -.77296 SDev 2.0492 .0002 :0000 .6727 .8608 1.75844 %RSD 345.29 8.074 .0825 25.595 20.7.87 227.50 #1 2.3125 .0021 .0530 3.3952 4.8689 -1.6306 -1.6742 .0018 .0529 2.1379 4.3635 -1.9380 1.1422 .0020 .0529 2.3518 3.1909 1.2497 It 00 00 O O F-+ y O O 00 4 00 C!i ZS80"8 OT"9ES v80'EZ E609 119 ES" L6T"ES ZZ9E"8 8E'IVES LVO "ZZ LS09' Ti7ZS' 68T OS 60£"8 EO'SES 699'EZ IV909" 9SZS' 7v6T'OS T# ZS98'1 9EZ9T' OZ8S'£ OSTE" LZZZ' T68E'E QSE% T'vST' L8' TZ8' 6T00' ZT00' SEL 'T Aa(IS 8Z9Z'8 LT'SES EE6'ZZ TL09' :�SZd' 'v6T'TS abnV qdd qdd qdd wdd wdd qdd SgTua 096TGS 890ZgS EOZZgd uZ A 806TTZ i;DTg SSEO' Z6T9' tIT00' 8TU:i E9:H L 6E9S'8 OL'8ES E# �SEO' 9029• ST00' ZOZ'� Z90S'8 8EL0'8 9L'9ES Z# SSEO' EOZ9" 6200' LOZ':� VZS6'9 ZZT'TT EE'LES T# 8LZZ' fii£ZT' ZL'Z:� 806T' 8E0'0T 069'LT LEST' QS -d% T000" 8000' 8000• 800' 86LL' 69E9'T 00'T AaQS SSEO' OOZ9" OZOO' -6OF, `� E89L'L EESZ'6 09"LES GGAV wdd wdd wdd wdd qdd qdd qdd sgTufl z,L as us TS Z/096T T/096T Z/8902 waTg 06'OES S86'ZZ ESZ'Ez 09SS' T'T6T fii000' OE'ZT E# Z9'6ZS EOL'TZ 9EL"ZZ STSS' b"T6T E000"- ZZ'ZT Z# T:�'OES L90':�Z ZL8"ZZ ZSSS' L'06T 2000' 9Z'ZT T# T8TZT' Oti9T'S 86EZ'T S9Zip" EZ8T' 0"ELZ 9S6Z' CISH% S9' :�8T' T :i8Z' :iZ00' £' E000' Ii0' AaQS TE'OES 8T6'ZZ ti96'ZZ ZbSS' T ' T 6 T T000" 9Z'ZT of qdd qdd qdd wdd wdd wdd wdd sq-. T/890Z Z/£OZZ T/EOZZ TN PN ON uw waTg :H, Z9 L'LET 99T'Z 690U ZvTZ' ZTDS' 6TS0' E# LL'T9 8'L£T SST'Z E80E' 6ZTZ' OLES' 9TS0' Z# 68'T9 S'LET 09T'Z ELOE' LETZ' T8ES" LTSO' T# TOZZ' L060• LLEZ' i79ZZ' 6ZOE' :�OTTP' EO£E' QSE% :PT" T" SOO' L000' 9000' ZZOO' 2000' naQS 06'T9 9'LET 09T"Z SLOE• 9ETZ' 88ES" LTSO' abnV wdd wdd wdd wdd wdd wdd wdd SgTufl f3W x a3 nD zO oa PD waTg 80.88 OlvSO" SZZ'Z bZS9• 896'Z 996'6E E# TZ'L8 8ES0' :EZ'Z SOS9' 6£S':�Tv L96"Z LEL'8E Z# 6S'L8 6£SO• TEZ'Z OES9" '8T0'Ziv T96'Z L08'6E T# 9005' iv69Z' S80Z" T:MT' L:H8 :'E 68ZT' OZ69 • T QSE% iv:�' T000' S00" ET00' SE:�'T b00' 899' naQS E9"L8 6£SO• OEZ"Z 6TS9' :PL9'£:� S96"Z £OS'6E GBAV wdd wdd wdd wdd qdd wdd qdd sgTu11 Pa ag Pg g 068TsV TV Fov waTg SY1 Q� -(i'11^f T : aO-IDP3 aaOD ONO : aPoW 800rISZ : quawwoD 8T:6S:80 90/ZT/ET :awTs —E OKw :.zogi2aadO SWg900-ZOLZT90 :awPN aTdw-eS TdZD :Po W T ab -2d KV 6:�:90:60 90/ZT/ZT gaodau sTsAT72u-q Analysis Report 12/12/06 09:14:27 AM page 1 D iod: CLP1 Sample Name: CCV2 Operator: MAG F--__ Time: 12/12/06 09:06:55 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1013.6 50.80 524.53 2.667 2.560 2.607 51.36 SDev 1.0 .09 1.46 .006 .005 .002 .03 %RSD .09596 .1798 .27751 .2087 .1902 .0824 .0594 #1 1012.6 50.70 523.07 2.660 2.555 2.608 51.38 #2 1013.8 50.87 525.98 2.670 2.561 2.605 51.33 #3 1014.5 50.85 5.24.54 2.670 2.564 2.610 51.38 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 1100.0 55.00 550.00 2.750 2.750 2.750 55.00 Low 900.00 45.00 450.00 2.250 2.250 2.250 45.00 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge 2.569 2.579 2.566 2.617 51.00 84.59 53.23 SDev .-002 .002 .002 .006 .05 .19 .03 %RSD .0659 .0718 .0927 .2129 .0968 .2211 .0517 #1 2.567 2.581 2.565 2.611 50.94 84.38 53.20 - 2.568 2.577 2.564 2.620 51.02 84.73 53.24 2.570 2.580 2.569 2.621 51.04 84.66 53.26 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 2.750 2.750 2.750 2.750 55.00 88.00 55.00 Low 2.250 2.250 2.250 2.250 45.00 72.00 45.00 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 Units ppm ppm ppm ppm ppb ppb ppb Avge 2.564 2.649 81.62 2.549 505.09 499.55 996.04 SDev .002 .014 .15 .005 1.85 .76 21.45 %RSD .0644 .5119 .1884 .1941 .36584 .15175 2.1531 #1 2.565 2.635 81.49 2.547 502.96 498.71 972.08 ##2 2.562 2.651 81.79 2.546 506.05 500.19 1002.6 #3 2.565 2.662 81.59 2.555 506.26 499.76 1013.4 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High 2.750 88.00 2.750 Low 2.250 72.00 2.250 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti -Units ppb ppb ppb ppm ppm ppm ppm Avge 999.90 532.82 526.32 2.267 2.594 2.611 1.978 SDev 11.27 2.82 4.29 .076 .009 .004 .003 %RSD 1.1273 .52892 .81506 3.359 .3645 .1524 .1578 986.98 529.87 521.37 2.191 2.588 2.608 1.975 1005.0 533.09 529.00 2.268 2.589 2.6-11 1.978 #3 1007.7 535.49 528.59 2.343 2.604 2.616 1.982 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK 00 00 O O N Analysis Report 12/12/06 09:14:27 AM page 2 v Zn Low Sb2068 Elem T11908 Units ppb Avge 512.21 SDev .91 %RSD .17690 #1 511.16 #2 512.75 #3 512.71 Errors LC Pass High 550.00 Low 450.00 v Zn Pb2203 Sb2068 Se1960 ppm ppm ppb ppb ppb 2.572 2.694 501.39 998.62 528.48 .002 .002 1.10 14.63 3.72 .0969 .0582 .22031 1.4647 .70322 2.572 2.695 500.13 982.02 524.20 2.570 2.693 502.14 1004.2 530.36 2.575 2.696 501.92 1009.6 530.89 LC Pass LC Pass LC Pass LC Pass LC Pass 2.750 2.750 550.00 1100.0 550.00 2.250 2.250 450.00 900.00 450.00 r- 00 00 O O C/j N Analysis Report 12/12/06 09:22:05 AM page 1 P iod: CLP1 Sample Name: CCVL2 Operator: MAG F_.:.__ Time: 12/12/06 09:14:33 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be. Ca Units ppb ppm ppb ppm ppm ppm ppm Avge -.02994 .0169 1.7746 .0076 .0008 .0007 .0181 SDev .22047 .0069 .0799 .0016 .0002 .0002 .0057 %RSD 736.25 40.47 4.5009 20.96 28.20 30.10 31.26 ##1 .22352 .0233 1.6877 .0094 .0011 .0009 .0240 #2 -.13609 .0178 1.8447 .0070 .0008 .0007 .0177 #3 -.17726 .0097 1.7915 .0064 .0006 .0005 .0127 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK High Low Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0009 .0008 .0008 .0007 2.484 .0784 .0171 SDev .0002 .0001 .0002 .0003 .007 .0099 .0046 %RSD 18.68 18.15 25.27 46.31 .2686 12.66 27.18 ##1 .0011 .0009 .0009 .0011 2.490 .0898 .0222 - .0009 .0007 .0006 .0008 2.485 .0738 .0160 .0007 .0010 .0008 .0004 2.477 .0716 .0131 Errors NOCHECK NOCHECK NOCHECK NOCHECK LC Pass NOCHECK NOCHECK High 2.750 Low 2.250 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 Units ppm ppm ppm ppm ppb ppb ppb Avge .0013 .0161 2.603 .0005 .39023 -.10860 20.013 SDev .0004 .0061 .015 .0004 .90682 .47038 12.456 %RSD 28.76 38.25 .5812 77.70 232.38 433.15 62.239 #1 .0017 .0227 2.604 .0001 -.60132 .31212 33.604 ##2 .0012 .0148 2.617 .0006 1.1774 -.02146 17.289 #3 .0009 .0107 2.587 .0008 .59456 -.61645 9.1438 Errors NOCHECK NOCHECK LC Pass NOCHECK NOCHECK NOCHECK NOCHECK High 2.750 Low 2.250 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 19.470 .35189 .68417 .0198 -.0007 .0007 .0010 SDev 8.084 3.6171 .97267 .0180 .0005 .0002 .0003 %RSD 41.518 1027.9 142.17 90.77 68.92 28.04 29.44 27.791 2.7751 1.8045 .0393 -.0005 .0009 .0013 18.971 -3.8058 .05553 .0164 -.0012 .0007 .0010 #3 11.647 2.0864 .19245 .0038 -.0003 .0005 .0007 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK 00 00 00 O O F-, Analysis Report 12/12/06 09:22:05 AM Low Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge .20463 .0005 .0014 .05756 19.650 .57354 SDev 1.2822 .0005 .0002 .29858 9.517 1.6929 0 -.RSD 626.58 91.32 13.27 518.76 48.433 295.16 #1 1.6650 .0011 .0016 .00799 29.727 2.1278 #2 -.73644 .0004 .0013 .37782 18.411 -1.2303 #3 -.31467 .0002 .0013 -.21314 10.813 .82315 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK High Low page 2 00 00 O i O Analysis Report 12/12/06 09:29:43 AM page 1 M od: CLP1 Sample Name: CCB2* Operator: MAG R-.. Time: 12/12/06 09:22:11 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge -.11128 .0031 .63651 .0012 .0001 .0001 .0009 SDev .05383 .0007 1.4980 .0002 .0000 .0000 .0006 %RSD 48.372 21.80 235.34 15.55 24.00 22.17 66.00 #1 -.15951 .0025 2.1072 .0013 .0002 .0001 .0015 #2 -.12111 .0031 .68965 .0014 .0001 .0001 .0007 #3 -.05321 .0038 -.88731 .0010 .0001 .0001 .0004 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .2000 10.000 .2000 .2000 .0050 .2000 Low -10.000 -.2000 -10.000 -.2000 -.2000 -.0050 -.2000 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0002 .0000 .0001 .0001 .0047 .0451 -.0009 SDev .0001 .0002 .0001 .0001 .0008 .0017 .0023 %RSD 40.09 49000. 156.8 84.82 16.30 3.747 266.7 #1 .0001 -.0002 -.0000 .0001 .0055 .0452 .0002 "- .0003 .0003 .0002 .0002 .0048 .0467 .0007 .0003 -.0001 .0001 .0001 .0039 .0434 -.0036 Errors LC Pass -LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .0050 .0500 .0100 .0250 .1000 5.000 .2000 Low -.0050 -.0500 -.0100 -.0250 -.1000 -5.000 -.2000 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 Units ppm ppm ppm ppm ppb ppb ppb Avge .0003 .0039 .0177 -.0003 -.09891 .42988 5.5734 SDev .0001 .0010 .0014 .0004 1.51374 1.7900 2.0609 %RSD 16.49 25.22 7.612 109.6 1530.4 416.39 36.978 #1 .0003 .0050 .0192 -.0004 -1.8246 2.3299 7.8606 #2 .0003 .0034 .0173 -.0007 .52333 .18439 4.9989 #3 .0002 .0032 .0166 .0001 1.0045 -1.2247 3.8607 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High .0150 5.000 .0400 Low -.0150 -5.000 -.0400 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 6.1571 1.7751 -.76475 -.0449 -.0005 .0001 .0002 SDev 1.5895 1.1193 1.93558 .0049 .0010 .0000 .0001 %RSD 25.815 63.056 253.10 10.85 209.3 27.59 30.67 7.8362 2.8857 1.1928 -.0395 .0006 .0002 .0002. 4.6758 1.7922 -2.6776 -.0466 -.0012 .0001 .0003 Tr- #3 5.9595 .64729 -.80945 -.0488 -.0008 .0001 .0001 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK O 00 O O F-+ Analysis Report 12/12/06 09:29:43 AM �- -Ih Low Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge -1.3015 -.0000 .0000 .25382 5.9628 .08.103 SDev 2.1834 .0005 .0001 .71541 1.6468 1.5141 %RSD 167.77 40670. 165.6 281.86 27.619 1868.6 #1 -.60042 .0005 .0001 .94651 7.8443 1.7565 #2 -3.7493 -.0001 -.0000 .29730 4.7834 -1.1891 #3 .44532 -.0004 .0001 -.48234 5.2606 -.32433 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .0500 .0200 3.0000 60.000 5.0000 Low -10.000 -.0500 -.0200 -3.0000 -60.000 -5.0000 page 2 00 O O C!] N knalysis Report 12/12/06 09:37:20 AM page 1 M od: CLP1 Sample Name: 0612702-006ESD Operator: MAG Ru�� Time: 12/12/06 09:29:49 Comment: TSL008 J.&W-� S� mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .08656 .1652 1.7441 .1339 .0283 .0000 18.42 SDev .34995 .0022 .7604 .0007 .0002 .0000 .07 %RSD 404.26 1.343 43.602 .5313. .6603 24.16 .3853 #1 -.29712 .1677 .88849 .1346 .0285 .0000 18.50 #2 .16862 .1634 2.0008 .1332 .0283 .0001 18.41 #3 .38819 .1646 2.3429 .1340 .0281 .0000 18.36 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0002 .0048 .0011 .0061 .2665 26.75 12.93 SDev .0001 .0001 .0002 .0000 .0017 .12 .06 %RSD 60.62 2.116 20.88 .6490 .6411 .4581 .4756 #1 .0003 .0050 .0012 .0061 .2684 26.89 13.00 ##2 .0004 .0048 .0013 .0061 .2660 26.65 12.91 #3 .0001 .0048 .0009 .0061 .2650 26.72 12.88 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 is ppm ppm ppm ppm ppb ppb ppb fe 2.539 .0018 39.02 .0091 .17343 .45124 2.5796 SDev .011 .0006 12 .0009 .77498 1.0553 1.9220 %RSD .4292 33.66 .3090 10.38 446.85 233.86 74.506 #1 2.551 .0025 39.16 .0094 .97540 -.39149 .98307 #2 2.535 .0013 38.95 .0098 .11629 .11040 2.0429 #3 2.530 .0016 38.94 .0080 -.57139 1.6348 4.7129 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 4.5988 -.74750 .17831 .7987 .0013 .1251 .0078 SDev 3.0123 1.35652 1.8092 .0083 .0012 .0006 .0002 %RSD 65.501 181.47 1014.6 1.039 95.00 .5056 2.176 #1 7.2030 -.61261 1.0882 .8083 .0000 .1258 .0078 #2 5.2936 -2.1664 -1.9053 .7945 .0024 .1247 .0079 #3 1.2999 .53653 1.3520 .7934 .0013 .1248 .0076- Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge -.53337 .0004 .0114 .35877 3.9264 -.12996 SDev 1.35281 .0004 .0001 .46951 1.3700 1.63675 %RSD 253.64 90.52 .9166 130.87 34.893 1259.4 #1 -.18061 .0001 .0115 .06373 5.1318 .52185 -41) .60812 .0003 .0114 .11240 4.2111 -1.9922 -2.0276 .0008 .0113 .90018 2.4364 1.0805 N 00 O O V) F-+ Analysis Report 12/12/06 09:44:58 AM page 1 M od: CLP1 Sample Name: 0612702-007E Operator: MAG R-.. Time: 12/12/06 09:37:26 Comment: TSL008 mow- 5S Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .07168 4.543 2.5727 .1094 .1207 .0003 16.01 SDev .25020 .003 1.1079 .0008 .0001 .0000 .02 %RSD 349.06 .0768 43.064 .7435 .0673 .4706 .1522 #1 -.09430 4.547 1.7949 .1089 .1208 .0003 16.01 #2 .35946 4.542 2.0820 .1103 .1207 .0003 16.03 #3 -.05012 4.541 3.8412 .1089 .1206 .0003 15.98 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0002 .0092 .0295 .0171 8.167 8.403 13.12 SDev .0001 '.0001 .0003 .0001 .012 .018 .02 %RSD 49.51 1.400 1.087 .6915 .1450 ..2194 .1150 #1 .0003 .0093 .0295 .0170 8.166 8.418 13.12 #2 .0002 .0092 .0298 .0172 8.180 8.382 13.13 #3 .0001 .0090 .0291 .0170 8.156 8.408 13.10 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 -- "ts ppm ppm ppm ppm ppb ppb ppb [e 2.457 .0018 14.10 .0173 8.7030 6.2440 1.2186 SDev .004 .0005 .03 .0007 1.0086 .3470 .7378 %RSD .1459 28.79 .2070 4.269 11.589 5.5577 60.544 #1 2.457 .0013 14.12 .0180 9.1750 6.5126 1.5448 #2 2.460 .0018 14.07 .0175 9.3891 5.8522 1.7371 #3 2.453 .0024 14.12 .0165 7.5449 6.3673 .37394 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 3.6795 -.93446 .33906 7.221 .0021 .0911 .1833 SDev .7363 .66335 2.7753 .005 .0009 .0001 .0003 %RSD 20.010 70.988 818.53 .0669 43.50 .0999 .1491 #1 2.9780 -1.2399 -1.5479 7.225 .0032 .0912 .1833 #2 3.6145' -1.3901 -.96065 7.221 .0018 .0911 .1836 #3 4.4462 -.17341 3.5257 7.216 .0014 .0911 .1830 Elem T11908 V Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge -1.1912 .0114 .0523 7.0629 2.8601 -.08500 SDev .7185 .0003 .0001 .3211 .3152 2.06730 %RSD 60.321 2.282 .1507 4.5467 11.022 2432.1 #1 -1.8460 .0111 .0523 7.3992 2.5007 -1.4453 ##2 -.42249 .0116 .0524 7.0300 2.9893 -1.1036 -1.3051 .0116 .0523 6.7595 3.0901 2.2939 M 00 -O O Analysis Report 12/12/06 09:52:35 AM page 1 N iod: CLP1 Sample Name: 0612702-008E Operator: MAG RU1, Time: 12/12/06 09:45:04 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge -.13881 .0877 1.7177 .0730 .0309 .0000 44.17 SDev .50134 .0014 1.7588 .0005 .0003 .0000 .42 %RSD 361.17 1.609 102.40 .7285 .8928 57.11 .9560 #1 .43914 .0893 -.27533 .0732 .0310 .0000 44.42 #2 -.39915 .0871 3.0524 .0733 .0311 .0000 44.41 #3 -.45642 .0866 2.3760 .0724 .0306 .0000 43.68 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0008 .0117 .0018 .0050 2.862 5.833 15.34 SDev .0001 .0002 .0002 .0001 .026 .031 .13 %RSD 13.73 1.889 13.27 3.104 .8970 5321 .8762 #1 .0008 .0115 .0018 .0049 2.876 5.851 15.41 #2 .0009 .0119 .0020 .0052 2.878 5.851 15.42 #3 .0007 .0115 .0015 .0049 2.833 5.797. 15.18 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 is ppm ppm ppm ppm ppb ppb ppb fe 7.939 .0008 20.28 .0113 2.4144 -1.6836 -.65375 SDev .071 .0003 .12 .0007 1.7364 .7311 .98929 %RSD .8905 42.11 .5694 5.922 71.921 43.424 151.33 #1 7.976 .0011 20.36 .0120 2.4817 -.85639 -.08024 #2 7.984 .0006 20.32 .0109 .64522 -1.9513 -.08493 #3 7.858 .0005 20.14 .0108 4.1161 -2.2431 -1.7961 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 5.1055 .37574 -.49185 3.775 .0020 .1317 .0036 SDev 1.7089 2.4517 1.66579 .032 .0006 .0009 .0000 %RSD 33.472 652.50 338.68 .8547 31.42 .7148 .9009 #1 3.1327 -1.3208 -1.3044 3.791 .0026 .1321 .0036 #2 6.1294 3.1867 1.4243 3.796 .0013 .1323 .0036 #3 6.0544 -.73869, -1.5955 3.738 .0020 .1306 .0036 Elem T11908 V Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge -.02575 -.0001 .0390 -.31889 3.1877 -.20293 SDev .85811 .0004 .0004 .69153 1.0223 1.91747 %RSD 3332.3 468.6 .9978 216.85 32.070 944.89 #1 -.35.366 .0003 .0392 .25528 2.0628 -1.3098 44 -?94797 -.0006 .0392 -1.0866 4.0601 2.0112 -.67156 .0000 .0385 -.12540 3.4402 -1.3102 .knalysis Report 12/12/06 10:00:11 AM page 1 M od: CLP1 Sample Name: 0612702-009E Operator: MAG R, -,,,'Time: 12/12/06 09:52:41 Comment : TSL008 MW-lnS Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .14345 11.92 3.6858 .0778 .1564 .0008 19.78 SDev .06498 .00 1.0812 .0007 .0000 .0000 .05 %RSD 45.298 .0403 29.333 .9047 .0248 .0087 .2637 #1 .13665 11.92- 2.9613 .0772 .1564 .0008 19.75 #2 .21157 11.93 3.1677 .0786 .1565 .0008 19.76 #3 .08214 11.92 4.9286 .0778 .1564 .0008 19.84 Elem Cd Co Cr Cu Fe K Mg. Units ppm ppm ppm ppm ppm ppm ppm Avge -.0000 .0412 .0284 .0440 29.63 12.03 7.910 SDev .0002 .0006 .0004 .0000 .08 .02 .010 %RSD 375.3 1.354 1.270 .0743 .2647 .1294 .1243 #1 -.0002 .0406 .0281 .0440 29.59 12.03 7.903 #2 .0001 .0412 .0282 .0440 29.58 12.05 7.906 #3 -.0000 .0417 .0288 .0440 29.72 12.02 7.922 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 1_ts ppm PPM PPM Ppm Ppb Ppb Ppb �e 5.457 .0020 3.323 .0266 15.481 10.553 -.40054 SDev .010 .0006 .011 .0003 1.000 .516 1.34116 %RSD .1909 32.59 .3422 1.065 6.4569 4.8862 334.84 #1 5.450 .0027 3.332 .0266 14.383 10.250 1.0910 #2 5.453 .0015 3.327 .0263 16.338 10.261 -1.5070 #3 5.469 .0017 3.310 .0269 15.723 11.149 -.78563 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 3.1359 -.89153 -1.4647 13.67 .0073 .0538 .7138 SDev 2.8857 1.13592 1.1112 .01 .0011 .0001 .0008 %RSD 92.022 127.41 75.866 .0769 14.47 .1543 .1072 #1 4.7427 -2.1646 -2.7434 13.66 .0080 .0539 .7130 #2 4.8605 .01843 -.91758 13.67 .0078 .0538 .7138 #3 -.19554 -.52841 -.73312 13.68 .0061 .0537 .7146 Elem T11908 V Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge .32620 .0364 .0984 12.194 1.9583 -1.2738 SDev 1.1631 .0003 .0003 .529 2.0731 1.1061 %RSD 356.55 .8204 .3542 4.3347 105.86 86.838 #1 -.94977 .0364 .0982 11.627 3.5267 -2.5506 .0362 .0982 12.284 2.7402 -.60587 .60133 1.3270 .0368 .0988 12.672 -.39202 -.66493 00 O O E-+ Analysis Report 12/12/06 10:07:48 AM page 1 1 hod: CLP1 Sample Name: 0612702-010E Operator: MAG '?tun Time: 12/12/06 10:00:18 Comment: TSL008 �U-�� Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm Ppb Ppm Ppm ppm ppm Avge .03821 .1331 1.8495 .4523 .0849 .0001 63.45 SDev .20322 .0034 .5212 .0020 .0001 .0000 .19 %RSD 531.84 2.583 28.181 .4322 .1050 22.58 .3063 ##1 .22491 .1365 2.3259 .4503 .0848 .0001 63.26 ##2 .06797 .1331 1.9298 .4526 .0850 .0001 63.44 ##3 -.17825 .1297 1.2928 .4542 .0849 .0000 63.65 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0001 .0062 .0011 .0095 2.060 87.70 35.74 SDev .0001 .0002 .0003 .0001 .000 .14 .09 %RSD 44.62 2.705 29.44 1.370 .0231 .1549 .2582 #1 .0001 .0060 .0008 .0096 2.061 87.65 35.65 #2 .0002 .0062 .0015 .0095 2.060 87.86 35.75 #3 .0002 .0064 .0012 .0093 2.061 87.60 35.84 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 lits ppm ppm Ppm ppm Ppb Ppb Ppb rge 1.837 .0013 75.31 .0105 -.75268 .69762 1.4230 SDev .003 .0002 .16 .0003 1.35448 .71934 1.5043 %RSD .1826 18.29 .2072 2.776 179.95 103.11 105.71 #1 1.834 .0011 75.17 .0103 .81012 1.5259 2.0568 #2 1.837 .0015 75.48 .0105 -1.4806 .33743 2.5067 #3 1.840 .0015 75.29 .0108 -1.5875 .22953 -.29440 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb Ppm Ppm ppm ppm Avge 3.0577 -1.9451 1.2703 7.199 .0023 .4260 .0054 SDev .4845 .4949 .9383 .012 .0009 .0008 .0001 %RSD 15.845 25.444 73.864 .1729 37.03 .1842 1.676 #1 3.4845 -1.5084 1.3894 7.187 .0015 .4251 .0054 #2 2.5310 -1.8442 2.1434 7.197 .0032 .4262 .0054 #3 3.1577 -2.4826 .27815 7.212 .0022 .4266 .0053 Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb Ppb Avge -.51827 .0005 .0485 .21469 2.5134 .19960 .46177 .0002 .0001 .93070 .5005 .75393 .SDev %RSD 89.098 48.41 .2889 433.52 19.913 377.72 #1 -.17084 .0003 .0485 1.2876 3.0091 .42445 u2 -.34171 .0007 .0484 -.26796 2.5230 .81552 3 -1.0423 .0004 .0486 -.37555 2.0082 -.64117 Analysis Report 12/12/06 10:15:25 AM page 1 hod: CLP1 Sample Name: 0612702-011E Operator: MAG Kuii Time: 12/12/06 10:07:54 Comment: TSL008 Kw - QHS Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .09548 7.326 10.856 .1577 .3147 .0007 80.13 SDev .16117 .011 1.099 .0008 .0001 .0000 .09 %RSD 168.79 .1442 10.125 .5164 .0474 1.751 .1171 #1 .18337 7.316 9.6105 .1575 .3148 .0007 80.03 42 .19361 7.325 11.266 .1585 .3147 .0007 80.16 #3 -.09053 7.337 11.691 .1569 .3145 .0007 80.21 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge -.0008 .0062 .0222 .0460 93.62 25.81 24.71 SDev .0001 .0002 .0001 .0001 .10 .03 .01 %RSD 17.94 2.815 .2960 .1553 .10.41 .1323 .0576 #1 -.0006 .0064 .0222 .0459 93.51 25.83 24.69 #2 -.0009 .0061 .0221 .0460 93.68 25.77 24.71 #3 -.0008 .0061 .0221 .0460 93.68 25.83 24.72 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 lits ppm ppm ppm ppm ppb ppb ppb rge .7788 .0002 32.30 .0140 13.707 -3.4723 .31808 SDev .0003 .0005 .14 .0008 .752 1.1265 1.2807 %RSD .0392 218.6 .4211 6.003 5.489,8 32.441 402.63 #1 .7785 .0005 32.31 .0130 14.389 -2.9450 -.98421 #2 .7791 -.0004 32.16 .0142 13.833 -4.7657 .36240 #3 .7789 .0006 32.43 .0147 12.899 -2.7062 1.5761 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 2.4701 -1.9009 -1.2869 12.36 .0148 .3018 .3914 SDev .9738 3.1968 1.2018 .01 .0018 .0001 .0002 %RSD 39.425 168.17 93.386 .0897 12.10 .0149 .0457 #1 3.5182 1.7758 -2.0535 12.34 .0163 .3018 .3912 #2 1.5933 -4.0243 .09817 12.36 .0153 .3019 .3915 #3 2.2987 -3.4543 -1.9054 12.36 .0128 .3018 .3916 -Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge 1.9822 .0273 .0988 2.2484 1.7535 -1.4913 SDev .1519 .0002 .0003 .7305 .4940 .8426 %RSD 7.6621 .5900 .3022 32.489 28.175 56.498 #1 2.0966 .0272 .0989 2.8271 2.0189 -.77832 -4`2 2.0400 .0275 .0985 1.4276 1.1835 -1.2746 3 1.8099 .0272 .0991 2.4905 2.0581 -2.4211 00 O O F-4 Analysis Report 12/12/06 10:23:01 AM page 1 hod: CLPl Sample Name: 0612702-012E Operator: MAG Time: 12/12/06 10:15:31 Comment: TSL008 Sil ��ol�t a Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .28462 .0553 5.7200 .9776 .2072 .0001 77.15 SDev .32938 .0024 .5109 .0039 .0005 .0000 .33 %RSD 115.73 4.379 8.9321 .3977 .2600 46.70 .4267 ##1 .48628 .0576 5.1713 .9731 .2066 .0000 76.83 ##2 -.09548 .0556 6.1821 .9799 .2075 .0001 77.13 #3 .46306 .0528 5.8066 .9797 .2075 .0001 77.49 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0000 .0378 .0016 .0064 6.580 132.3 34.39 SDev .0001 .0002 .0001 .0002 .015 .3 .12 %RSD 154.9 .5856 6.118 3.083 .2245 .2359 .3485 ##1 -.0000 .0376 .0015 .0062 6.567 132.1 34.26 #2 .0001 .0378 .0017 .0065 6.576 132.7 34.39 #3 .0001 .0381 .0017 .0066 6.596 132.2 34.50 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 --,its ppm ppm ppm ppm ppb ppb ppb -ge 4.120 .0016 222.6 .0463 1.5561 -.80887 -.50756 SDev .019 .0006 .3 .0003 .5786 .82337 1.12647 %RSD .4682 39.13 .1535 .7348 37.182 101.79 221.94 #1 4.102 .0024 222.5 .0459 1.9117 .12613 -1.3318 #2 4.118 .0012 2'23.0 .0463 .88849 -1.1271 .77600 #3 4.140 .0013 222.3 .0466 1.8682 -1.4256 -.96684 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 2.8293 -.75392 -.03425 5.443 .0013 .4737 .0024 SDev 2.1338 3.39022 1.39684 .013 .0007 .0010 .0000 %RSD 75.417 449.68 4078.1 .2425 51.41 .2196 1.104 #1 3.4608 1.1792 -1.3323 5.428 .0006 .4725 .0024 #2 .45107 1.2276 -.21434 5.448 .0014 .4743 .0024 #3 4.5760 -4.6685 1.4439 5.453 .0020 .4743 .0024 Elem T11908 V Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge 1.7771 .0006 .0415 -.02124 1.7181 -.27389 SDev 1.0575 .0002 .0002 .64577 1.0929 .46987 oRSD 59.508 27.59 .5290 3040.1 63.610 171.55 #1 2.7880 .0007 .0414 .72080 1.8649 -.49599 42 .67843 .0006 .0415 -.45585 .55929 .26585 1.8649 .0004 .0418 -.32868 2.7303 -.59154 00 00 O O C/� Analysis Report 12/12/06 10:30:38 AM page 1 ] iod: CLP1 Sample Name: 0612702-013E Operator: MAG Time: 12/12/06 10:23:08 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge -.24220 .0057 -1.0050 .0000 .0002 -.0000 .0804 SDev .11595 .0131 1.5963 .0023 .0000 .0000 .0163 %RSD 47.873 229.0 158.84 14890. 13.07 152.2 20.25 #1 -.30812 .0136 -2.2083 .0020 .0003 -.0000 .0978 #2 -.10832 -.0094 .80593 -.0026 .0003 -.0000 .0779 #3 -.31015 .0129 -1.6125 .0006 .0002 .0000 .0655 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge -.0000 -.0000 .0002 .0012 .0102 .1168 .0155 SDev .0001 .0001 .0002 .0001 .0043 .0270 .0050 %RSD 149.2 312.1 125.8 5.442 42.29 23.11 32.44 #1 -.0001 -.0000 -.0000 .0011 .0148 .1456 .0212 #2 -.0001 -.0001 .0002 .0013 .0063 .1128 .0140 #3 .0000 .0001 .0003 .0012 .0093 .0921 .0115 Elem Mn - Mo Na Ni 2203/1 2203/2 2068/1 -- its ppm ppm ppm ppm ppb ppb ppb ge .0018 -.0003 .1582 .0001 1.3820 .47060 .47443 SDev .0009 .0013 .0522 .0008 1.0458 .42696 .92509 %RSD 51.36 419.1 32.99 616.0 75.671 90.726 194.99 #1 .0027 .0008 .2156 .0005 1.0549 .94057 .59848 #2 .0016 -.0017 .1455 .0007 2.5522 .36465 -.50643 #3 .0010 .0000 .1136 -.0008 .53891 .10660 1.3312 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge .92269 -3.2489 -1.3891 -.0076 .0002 .0002 .0006 SDev .31703 1.8352 2.3238 .0022 .0001 .0001 .0000 %RSD 34.359 56.486 167.28 28.82 79.38 52.22 .6209 #1 1.2871 -4.8398 .40790 -.0057 .0003 .0003 .0006 #2 .77028 -3.6658 -4.0133 -.0072 .0000 .0001 .0006 #3 .71066 -1.2412 -.56201 -.0100 .0002 .0001 .0006 Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge -1.1178 -.0002 .0352 .77418 .77344 -2.0084 SDev 1.1506 .0001 .0002 .45700 .37750 1.6591 %RSD 102.94 48.94 .5554 59.030 48.808 82.608 #1 -1.4371 -.0002 .0354 .97870 1.0578 -1.3396 R9 .15878 -.0003 .0351 1.0932 .34515 -3.8976 -2.0750 -.0001 .0351 .25064 .91733 -.78815 ON 00 O O L/1 Analysis Report 12/12/06 10:38:15 AM page 1 hod: CLP1 Sample Name: 0612702-003E Operator: MAG Time: 12/12/06 10:30:44 Comment: TSL008! Mode: CONC Corr. Factor: 1 W Db Elem Ag Al As1890 B Ba Be Units ppb ppm ppb ppm ppm ppm Avge .02119 3.091 4.1161 .1300 .1134 .0002 SDev .07257 .009 .3706 .0003 .0001 .0000 %RSD 342.53 .2897 9.0039 .2202 .1089 5.324 #1 .02643 3.084 4.4766 .1300 .1135 .0002 #2 .09099 3.088 4.1356 .1297 .1134 .0002 #3 -.05386 3.101 3.7362 .1303 .1133 .0002 Elem Cd Co Cr Cu Fe K Units ppm ppm ppm ppm ppm ppm Avge .0007 .0164 .0122 .0405 35.53 21.16 SDev .0001 .0003 .0001 .0001 .03 .05 %RSD 15.71 1.920 .7278 .3258 .0919 .2218 #1 .0008 .0162 .0122 :0406 35.53 21.11 #2 .0006 .0162 .0121 .0404 35.56 21.17 #3 .0008 .0168 .0123 .0406 35.49 21.21 Elem Mn Mo Na Ni 2203/1 2203/2 --.its ppm ppm ppm ppm ppb ppb -ge 11.74 .0010 27.21 .0106 4.4333 -3.3933 SDev .00 .0005 .15 .0000 .9350 .3361 %RSD .0245 48.94 .5507 .3514 21.092 9.9054 #1 11.75 .0006 27.05 .0106 3.9919 -3.0525 #2 11.74 .0015 27.26 .0106 3.8006 -3.7246 #3 11.74 .0008 27.33 .0106 5.5073 -3.4028 Elem 2068/2 1960/1 1960/2 Si Sn Sr Units ppb ppb ppb ppm ppm ppm Avge 4.6807 .45252 -1.6536 5.180 .0038 .1886 SDev 2.1181 1.7775 2.5558 .008 .0015 .0001 %RSD 45.252 392.80 154.57 .1549 39.46 .0486 #1 5.1702 -1.4757 -4.1790 5.172 .0022 .1887 #2 6.5112 2.0257 .93164 5.178 .0052 .1886 ##3 2.3607 .80757 -1.7134 5.188 .0039 .1885 Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge 3.2254 .0099 .0520 -.78702 2.7086 -.95221 SDev 1.5181 .0002 .0001 .39759 1.5215 2.28838 %RSD 47.067 1.611 .1338 50.518 56.174 240.32 #1 4.4281 .0101 .0520 -.70672 2.7565 -3.2788 449 1.5196 .0098 .0521 -1.2186 4.2055 1.2960 3.7284 .0100 .0519 -.43572 1.1636 -.87386 Ca PPM 29.74 .01 .0253 29.74 29.73 29.74 Mg ppm 12.97 .00 .0331 12.97 12.96 12.97 2068/1 ppb -1.2416 .8326 67.059 -2.0780 -.41277 -1.2342 Ti PPM .2227 .0001 .0292 .2227 .2227 .2226 O O 00 O O V1 E --q Analysis Report hod: CLP1 Sample Name: CCV3 Time: 12/12/06 10:38:21 ppm Comment:'TSL008 2.596 2.594 1.972 Mode: CONC Corr. Factor: 1 .046 Elem Ag Al As1890 Units ppb ppm ppb Avge 1010.8 50.73 526.06 SDev 17.8 1.02 8.38 %RSD 1.7589 2.007 1.5926 #1 1029.6 51.81 535.04 #2 1008.5 50.58 524.68 #3 994.25 49.79 518.46 Errors LC Pass LC Pass LC Pass High 1100.0 55.00 550.00 Low 900.00 45.00 450.00 Elem Cd Co Cr Units ppm ppm ppm Avge 2.587 2.580 2.571 SDev .051 .049 .051 %RSD 1.956 1.889 1.967 #1 2.639 2.630 2.623 -, 2.584 2.575 2.567 2.538 2.533 2.522 Errors LC Pass LC Pass LC Pass High 2.750 2.750 2.750 Low 2.250 2.250 2.250 Elem Mn Mo Na Units ppm ppm ppm Avge 2.568 2.649 81.33 SDev .049 .039 1.39 %RSD 1.906 1.465 1.703 #1 2.618 2.686 82.76 #2 2.564 2.653 81.23 #3 2.521 2.608 79.99 Errors LC Pass NOCHECK LC Pass High 2.750 88.00 Low 2.250 72.00 Elem 2068/2 1960/1 1960/2 Units ppb ppb ppb Avge 997.87 530.74 526.08 SDev 4.61 3.15 9.38 %RSD .46158 .59423 1.7839 993.28 532.86 536.62 n 997.83 532.25 522.97 #3 1002.5 527.12 518.64 Errors NOCHECK NOCHECK NOCHECK 12/12/06 10:45:51 AM page 1 Operator: MAG B ppm 2.664 .045 1.688 2.711 2.659 2.622 LC Pass 2.750 2.250 Cu ppm 2.595 .048 1.842 2.645 2.590 2.549 LC Pass 2.750 2.250 Ni ppm 2.561 .049 1.906 2.613 2.556 2.516 LC Pass 2.750 2.250 Si ppm 2.329 .037 1.602 2.295 2.323 2.369 NOCHECK Ba ppm 2.539 .045 1.756 2.585 2.536 2.496 LC Pass 2.750 2.250 Fe ppm 51.17 1.02 1.986 52.23 51.09 50.20 LC Pass 55.00 45.00 2203/1 ppb 505.39 4.08 .80689 509.61 505.10 501.47 NOCHECK Be ppm 2.614 .049 1.867 2.664 2.610 2.567 LC Pass 2.750 2.250 K ppm 84.03 1.51 1.795 85.63 83.82 82.64 LC Pass 88.00 72.00 2203/2 ppb 501.71 10.65 2.1230 511.33 503.53 490.26 NOCHECK Ca ppm 51.62 1.01 1.955 52.67 51.54 50.66 LC Pass 55.00 45.00 Mg ppm 53.16 1.00 1.883 54.20 53.08 52.20 LC Pass 55.00 45.00 2068/1 ppb 995.54 9.64 .96838 991.22 1006.6 988.81 NOCHECK Sn Sr Ti Ppm Ppm ppm O 2.596 2.594 1.972 .046 .036 .052 2.000 1.791 1.826 0 O 2.650 2.643 2.009 2.592 2.590 1.969 H i 2.547 2.550 1.937 i NOCHECK NOCHECK NOCHECK Analysis Report 12/12/06 10:45:51 AM nigh Low Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge 512.90 2.567 2.700 502.93 997.09 527.63 SDev 8.16 .049 .050 8.44 4.14 7.08 %RSD 1.5901 1.915 1.869 1.6776 .41537 1.3426 #1 520.41 2.618 H2.752 510.75 992.59 535.37 #2 514.07 2.564 2.696 504.06 1000.7 526.06 #3 504.23 2.519 2.652 493.99 997.94 521.46 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 550.00 2.750 2.750 550.00 1100.0 550.00 Low 450.00 2.250 2.250 450.00 900.00 450.00 page 2 Analysis Report 12/12/06 10:53:28 AM page 1 hod: CLP1 Sample Name: CCVL3 Operator: MAG Time: 12/12/06 10:45:58 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .19857 .0222 1.6712 .0079 .0009 .0009 .0191 SDev .11948 .0045 .8537 .0023 .0003 .0003 .0077 0 -.RSD 60.172 20.14 51.081 29.14 36.04 35.45 40.45 #1 .30763 .0273 2.6540 .0103 .0013 .0012 .0280 #2 .07085 .0206 1.2457 .0076 .0008 .0007 .0160 #3 .21724 .0188 1.1139 .0057 .0006 .0007 .0135 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK High Low Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0011 .0010 .0009 .0008 2.512 .0762 .0174 SDev .0004 .0006 .0006 .0005 .009 .0121 .0063 %RSD 34.77 60.30 63.05 56.77 .3564 15.94 35.93 #1 .0015 .0016 .0015 .0013 2.522 .0887 .0246 ?0009 .0009 .0008 .0008 2.505 .0755 .0146 3 .0008 .0005 .0004 .0004 2.508 .0645 .0131 Errors NOCHECK NOCHECK NOCHECK NOCHECK LC Pass NOCHECK NOCHECK High 2.750 Low 2.250 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 Units ppm ppm ppm ppm ppb ppb ppb Avge .0017 .0149 2.602 .0007 -.24956 -.54298 19.484 SDev .0007 .0068 .014 .0007 1.64120 .45240 10.087 %RSD 42.48 45.63 .5427 109.4 657.63 83.318 51.769 #1 .0025 .0225 2.618 .0015 -.19592 -.86512 30.694 #2 .0014 .0131 2.591 .0002 1.3642 -.73804 16.616 #3 .0012 .0092 2.598 .0003 -1.9169 -.02577 11.142 Errors NOCHECK NOCHECK LC Pass NOCHECK NOCHECK NOCHECK NOCHECK High 2.750 .Low 2.250 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti O Units ppb ppb ppb ppm ppm ppm ppm Avge 16.004 4.9932 1.0819 .0316 -.0005 .0009 .0011 SDev 10.991 1.7017 2.4018 .0170 .0007 .0003 .0004 04 %RSD 68.679 34.080 221.99 53.72 152.5 38.65 33.27 O O `1 27.533 4.1971 2.7216 .0498 -.0007 .0013 .0016 ff2 14.835 3.8354 -1.6750 .0291 .0003 .0007 .0010 #3 5.6440 6.9469 2.1991 .0161 -.0011 .0006 .0009 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK Analysis Report 12/12/06 10:53:28 AM page 2 nigh Zn Low Sb2068 Elem T11908 Units ppb Avge 1.7973 SDev 1.1214 %RSD 62.391 #1 2.8945 #2 1.8443 #3 .65320 Errors NOCHECK High 62.122 Low .0015 v Zn Pb2203 Sb2068 Se1960 PPM ppm ppb ppb ppb .0008 .0014 -.44523 17.163 2.3844 .0006 .0004 .35276 10.662 1.9471 83.40 32.06 79.232 62.122 81.662 .0015 .0019 -.64224 28.586 3.2130 .0003 .0012 -.03796 15.428 .16001 .0006 .0011 -.65548 7.4749 3.7802 NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK It O 00 O O N Analysis Report hod: CLP1 Sample Name: CCB3 tcuii Time: 12/12/06 10:53:34 Units Comment: TSL008 ppm ppm Mode: CONC Corr. Factor: 1 .0004 Elem Ag Al As1890 Units ppb ppm ppb Avge .01916 .0087 1.9999 SDev .30374 .0019 1.2924 %RSD 1585.1 22.19 64.621 ##1 .35093 .0105 .82469 ##2 -.24525 .0067 3.3840 #3 -.04819 .0090 1.7911 Errors LC Pass LC Pass LC Pass High 10.000 .2000 10.000 Low -10.000 -.2000 -10.000 12/12/06 11:01:05 AM page 1 Operator: MAG B ppm .0013 .0002 17.35 .0014 .0010 .0014 LC Pass .2000 -.2000 Elem Cd Co Cr Cu Units ppm ppm ppm ppm Avge .0004 .0004 .0003 .0003 SDev .0001 .0001 .0001 .0002 %RSD 29.05 25.41 27.66 62.54 #1 .0005 .0003 .0004 .0004 .0003 .0006 .0003 .0001 .0005 .0004 .0002 .0003 Errors LC Pass LC Pass LC Pass LC Pass High .0050 .0500 .0100 .0250 Low -.0050 -.0500 -.0100 -.0250 Elem Mn Mo Na Ni Units ppm ppm ppm ppm Avge .0006 .0040 .0200 .0002 SDev .0002 .0010 .0034 .0009 %RSD 26.04 25.74 16.82 443.1 ##1 .0008 .0052 .0238 .0012 #2 .0006 .0032 .0183 -.0007 #3 .0005 .0036 .0177 .0002 Errors LC Pass NOCHECK LC Pass LC Pass High .0150 5.000 .0400 Low -.0150 -5.000 -.0400 Elem 2068/2 1960/1 1960/2 Si Units ppb ppb ppb ppm Avge 4.9828 1.9685 -1.3368 -.0390 SDev 2.1524 2.7019 .5124 .0064 %RSD 43.197 137.25 38.332 16.28 5.8944 .32191 -1.8573 -.0326 2 6.5293 5.0868 -.83283 -.0391 #3 2.5246 .49694 -1.3203 -.0454 Errors NOCHECK NOCHECK NOCHECK NOCHECK Ba ppm .0003 .0001 31.98 .0004 .0002 .0003 LC Pass .2000 -.2000 Fe ppm .0069 .0022 31.31 .0094 .0063 .0052 LC Pass .1000 -.1000 2203/1 ppb .13468 1.1178 829.94 -.27638 1.3998 -.71938 NOCHECK Sn PPM -.0002 .0009 418.1 .0004 -.0013 .0002 NOCHECK Be ppm .0002 .0001 32.42 .0003 .0002 .0002 LC Pass .0050 -.0050 K PPM .0530 .0033 6.239 .0566 .0523 .0501 LC Pass 5.000 -5.000 2203/2 ppb -.31272 1.05706 338.03 -.89697 -.94868 .90751 NOCHECK Sr ppm .0003 .0001 27.45 ._0004 .0003 .0002 NOCHECK Ca ppm .0024 .0016 65.28 .0042 .0017 .0013 LC Pass .2000 -.2000 Mg ppm .0038 .0028 73.55 .0071 .0022 .0022 LC Pass .2000 -.2000 2068/1 ppb 5.4664 .8342 15.260 6.4201 4.8725 5.1067 NOCHECK Ti PPM . 0004 .0001 14.66 .0004 .0003 .0003 NOCHECK Analysis Report 12/12/06 11:01:05 AM ---gh Low Elem T11908 v Zn Pb2203 Sb2068 Se1960 .Units ppb ppm ppm ppb ppb ppb Avge -.85880 .0003 .0001 -.16370 5.1438 -.23609 SDev 1.54178 .0005 .0002 .52804 1.5244 1.20844 %RSD 179.53 154.0 162.5 322.57 29.635 511.86 ##1 .78601 .0008 .0003 -.69027 6.0695 -1.1316 42 -1.0912 .0002 -.0000 -.16661 5.9776 1.1384 #3 -2.2712 -.0001 .0000 .36580 3.3844 -.71512 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .0500 .0200 3.0000 60.000 5.0000 Low -10.000 -.0500 -.0200 -3.0000 -60.000 -5.0000 page 2 Analysis Report hod: CLP1 Sample Name: CRIF Time: 12/12/06 11:01:11 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 Units ppb ppm ppb Avge 20.359 .0109 22.319 SDev .142 .0027 .692 0 -.RSD .69638 24.82 3.1001 #1 20.473 .0115 21.992 #2 20.404 .0133 23.113 #3 20.200 .0080 21.851 Elem Cd Cc Cr Units ppm ppm ppm Avge .0112 .1064 .0214 SDev .0001 .0003 .0001 %RSD .7695 .3043 .4150 #1 .0113 .1067 .0215 #2 .0112 .1064 .0214 #3 .0111 .1061 .0213 Elem Mn Mo Na -- Lits ppm ppm ppm ,ge .0321 .0304 .0181 SDev .0002 .0004 .0028 %RSD .7586 1.339 15.53 #1 .0323 .0299 .0213 ##2 .0320 .0308 .0171 #3 .0319 .0303 .0160 Elem 2068/2 1960/1 1960/2 Units ppb ppb ppb Avge 130.64 13.653 8.7383 SDev 1.39 1.412 1.0377 %RSD 1.0606 10.342 11.876 #1 132.23 13.169 7.7938 #2 129.71 12.546 9.8492 #3 129.98 15.243 8.5718 Elem T11908 v Zn Units ppb ppm ppm Avge 18.654 .1049 .0478 SDev .133 .0002 .0000 %RSD .71321 .1930 .0241 #1 18.733 .1051 .0478 3t2 18.728 .1048 .0478 4 18.500 .1048 .0478 12/12/06 11:08:42 AM page 1 Operator: MAG B PPM .2176 .0009 .4080 .2166 .2184 .2178 Cu PPM .0525 .0001 .2660 .0527 .0524 .0525 Ni PPM .0859 .0007 .8192 .0867 .0857 .0853 Si ppm .0520 .0020 3.812 .0534 .0529 .0497 Pb2203 ppb 5.6678 .3931 6.9352 5.9323 5.2161 5.8550 Ba PPM .0001 .0001 57.89 .0002 .0001 .0001 Fe PPM .0025 .0015 59.87 .0042 .0021 .0013 2203/1 ppb 5.6829 .5068 8.9183 5.9480 5.0986 6.0023 Sn PPM .0823 .0008 .9168 .0821 .0817 .0832 Sb2068 ppb 129.88 .78 .60013 130.69 129.13 129.83 Be PPM .0110 .0001 .7226 .0111 .0110 .0110 K PPM .0493 .0052 10.51 .0546 .0490 .0442 2203/2 ppb 5.6602 .3414 6.0309 5.9244 5.2748 5.7815 Sr PPM .0002 .0001 48.97 .0002 .0001 .0001 Se1960 ppb 10.375 .685 6.6064 9.5839 10.747 10.793 Ca PPM .0021 .0016 74.01 .0039 .0015 .0010 Mg ppm .0001 .0037 2596. .0042 -.0009 -.0029 2068/1 ppb 128.36 1.02 .79779 127.59 127.97 129.52 Ti PPM .1650 .0002 .1391 .1651 .1652 .1647 Analysis Report 12/12/06 11:16:19 AM page 1 .hod: CLP1 Sample Name: ICSAF Operator: MAG Time: 12/12/06 11:08:48 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .38153 515.1 9.9515 .0364 .0013 .0004 526.2 SDev .43242 .2 1.9453 .0009 .0000 .0000 1.5 %RSD 113.34 .0474 19.548 2.508 .1846 .2979 .2791 #1 .76404 515.2 11.452 .0369 .0013 .0004 526.9 #2 .46822 515.3 7.7536 .0370 .0013 .0004 527.1 #3 -.08767 514.9 10.649 .0354 .0013 .0004 524.5 Errors LC Pass LC Pass NOCHECK NOCHECK LC Pass LC Pass LC Pass High 10.000 600.0 .2000 .0050 600.0 Low -10.000 400.0 -.2000 -.0050 400.0 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge -.0041 -.0005 .0035 .0008 210.4 .0437 516.1 SDev .0001 .0003 .0003 .0001 .5 .0031 .8 %RSD 2.960 56.08 9.480 .12.02 .2230 7.053 .1636 #1 -.0039 -.0002 .0038 .0007 210.6 .0433 516.4 - -.0042 -.0008 .0032 .0009 210.7 .0470 516.7 -.0040 -.0006 .0036 .0008 209.9 .0409 515.1 Errors LC Pass NOCHECK LC Pass NOCHECK LC Pass NOCHECK LC Pass High .0050 .0100 240.0 600.0 Low -.0050 -.0100 160.0 400.0 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 Units ppm ppm ppm ppm ppb ppb ppb Avge -.0075 -.0001 .0770 .0044 -1.9869 1.4382 -2.1686 SDev .0003 .0008 .0010 .0008 2.2718 1.3167 3.4766 %RSD 4.424 594.0 1.342 17.90 114.34 91.555 160.32 ##1 -.0072 -.0002 .0762 .0052 -4.4755 1.8014 -.62428 #2 -.0076 -.0009 .0766 .0043 -1.4612 2.5352 -6.1497 ##3 -.0078 .0007 .0782 .0036 -.02409 -.02204 .26831 Errors LC Pass NOCHECK NOCHECK LC Pass NOCHECK NOCHECK NOCHECK High .0150 .0400 Low -.0150 -.0400 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 7.0872 -4.5645 -5.0205 -.0601 .0386 -.3022 .0060 SDev 3.8311 4.1600 1.5020 .0038 .0010 .0009 .0000 %RSD 54.056 91.138 29.917 6.291 2.657 .3060 .6040 4 L 7.0625 -6.5433 -3.3095 -.0563 .0382 -.3032 .0060 r,Z 3.2685 .21550 -6.1213 -.0601 .0398 =.3022 .0060 #3 10.931 -7.3657 -5.6308 -.0639 .0379 -.3013 .0060 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK 00 O 00 O O Analysis Report 12/12/06 11:16:19 AM -gh Low Elem T11908 V' Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge -2.4420 .0060 -.0141 .29765 4.0051 -4.8686 SDev 4.3953 .0006 .0000 .79646 3.6495 1.1754 %RSD 179.99 10.73 .1642 267.58 91.121 24.143 #1 1.3696 .0064 -.0141 -.28875 4.5028 -4.3863 #2. -1.4456 .0063 -.0141 1.2044 .13227 -4.0111 #3 -7.2500 .0053 -.0141 -.02270 7.3801 L-6.2085 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .0500 .0200 6.0000 60.000 5.0000 Low -10.000 -.0500 -.0200 -6.0000 -60.000 -5.0000 page 2 Analysis Report 12/12/06 11:23:56 AM page 1 ]' hod: CLP1 Sample Name: ICSABF Operator: MAG 1_._.__ Time: 12/12/06 11:16:26 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1105.4 514.1 1077.2 1.127 .5380 .5305 524.7 SDev 3.6 1.9 3.7 .001 .0015 .0013 1.5 %RSD .32950 .3718 .34059 .1159 .2855 .2359 .2766 #1 1108.8 515.5 1081.3 1.128 .5393 .5316 526.1 ##2 1105.9 514.8 1076.2 1.128 .5385 .5308 524.8 #3 1101.5 511.9 1074.1 1.126 .5363 .5291 523.2 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 1200.0 600.0 1200.0 1.200 .6000 .6000 600.0 Low 800.00 400.0 800.00 .8000 .4000 .4000 400.0 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge '.9985 .4982 .5173 .5703 210.0 .0441 515.4 SDev .0003 .0010 .0014 .0022 .5 .0032 1.4 %RSD .0312 .2114 .2812 .3902 .2313 7.370 .2729 ##1 .9986 .4985 .5189 .5715 210.5 .0476 516.8 - .9987 .4991 .5170 .5716 210.1 .0412 515.4 .9981 .4971 .5160 .5677 209.5 .0435 514.0 Errors LC Pass LC Pass LC Pass LC Pass LC Pass NOCHECK LC Pass High 1.200 .6000 .6000 .6000 240.0 600.0 Low .8000 .4000 .4000 .4000 160.0 400.0 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 Units ppm ppm ppm ppm ppb ppb ppb Avge .5034 1.062 .0804 .9901 1001.9 1004.4 -12.607 SDev .0014 .002 .0005 .0013 7.8 3.9 5.009 %RSD .2854 .1903 .5803 .1315 .78252 .38698 39.729 #1 .5048 1.061 .0808 .9909 1010.6 1007.4 -11.624 #2 .5034 1.065 .0806 .9908 999.67 1005.9 -18.034 #3 .5019 1.061 .0799 .9886 995.43 1000.0 -8.1628 Errors LC Pass NOCHECK NOCHECK LC Pass NOCHECK NOCHECK NOCHECK High .6000 1.200 Low .4000 .8000 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge -5.6038 1049.8 1038.5 .0053 1.107 -.3013 .0055 SDev .8793 8.4 5.1 .0054 .007 .0012 .0000 %RSD 15.692 .80265 .49023 100.6 .6757 .3967 .7312 -5.4147 1051.6 1044.2 .0063 1.115 -.3023 .0055 -4.8345 1057.2 1034.5 .0101 1.103 -.3016 .0056 #3 -6.5624 1040.6 1036.8 -.0005 1.102 -.3000 .0056 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK Analysis Report 12/12/06 11:23:56 AM - -gh Low Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge 1019.3 ..5239 1.104 1003.6 -7.9358 1042.2 SDev 1.5 .0019 .003 5.0 1.1373 4.3 %RSD .14970 .3537 .2662 .49655 14.332 .41452 41 1019.4 .5246 1.107 1008.5 -7.4822 1046.7 #2 1020.7 .5252 1.103 1003.8 -9.2300 1042.0 #3 1017.7 .5218 1.101 998.50. -7.0953 1038.0 Errors LC Pass LC Pass LC Pass LC Pass NOCHECK LC Pass High 1200.0 .6000 1.200 1200.0 1200.0 Low 800.00 .4000 .8000 800.00 800.00 page 2 00 O O F-+ Analysis Report hod: CLP1 Sample Name: CCV4 Time: 12/12/06 11:24:02 Ca Comment: TSL008 ppm ppm Mode: CONC Corr. Factor: 1 2.657 Elem Ag Al As1890 Units ppb ppm ppb Avge 1026.3 51.56 537.18 SDev 12.7 .56 6.81 %RSD 1.2329 1.083 1.2673 #1 1015.5 51.10 529.39 #2 1023.1 51.39 540.18 #3 1040.2 52.18 541.97 Errors LC Pass LC Pass LC Pass High 1100.0 55.00 550.00 Low 900.00 45.00 450.00 Elem Cd Co Cr Units ppm ppm ppm Avge 2.635 2.621 2.616 SDev .038 .037 .039 %RSD 1.431 1.431 1.487 #1 2.603 2.589 2.584 LC Pass 2.625 2.611 2.606 55.00 2.677 2.662 2.659 Errors LC Pass LC Pass LC Pass High 2.750 2.750 2.750 Low 2.250 2.250 2.250 Elem Mn Mo Na Units ppm ppm ppm Avge 2.605 2.707 82.23 SDev .038 .051 .76 %RSD 1.441 1.879 .9210 #1 2.573 2.662 81.51 #2_ 2.596 2.697 82.16 #3 2.646 2.762 83.02 Errors LC Pass NOCHECK LC Pass High 2.750 ppm 88.00 Low 2.250 2.640 72.00 Elem 2068/2 1960/1 1960/2 Units ppb ppb ppb Avge 1019.3 542.04 539.49 SDev 23.1 6.54 9.37 %RSD 2.2670 1.2073 1.7373 2.036 997.69 537.43 532.23 Tr- 1016.7 539.17 536.17 #3 1043.7 549.53 550.07 Errors NOCHECK NOCHECK NOCHECK 12/12/06 11:31:33 AM page 1 Operator: MAG B Ba Be Ca ppm ppm ppm ppm 2.700 2.578 2.657 52.72 .037 .033 .039 .73 1.352 1.266 1.449 1.390 2.668 2.551 2.624 52.13 2.693 2.570 2.648 52.49 2.740 2.615 2.700 53.54 LC Pass LC Pass LC Pass LC Pass 2.750 2.750 2.750 55.00 2.250 2.250 2.250 45.00 Cu Fe K Mg ppm ppm ppm ppm 2.626 52.18 85.06 54.37 .031 .76 .79 .69 1.187 1.457 .9333 1.260 2.598 51.53 84.37 53.83 2.619 51.98 84.87 54.15 2.660 53.02 85.93 H55.14 LC Pass LC Pass LC Pass LC Pass 2.750 55.00 88.00 55.00 2.250 45.00 72.00 45.00 Ni 2203/1 2203/2 2068/1 ppm ppb ppb ppb 2.609 514.60 511.69 1014.4 .039 8.05 9.17 37.2 1.489 1.5641 1.7918 3.6679 2.575 507.52 504.26 977.44 2.601 512.92 508.86 1013.8 2.652 523.35 521.93 1051.8 LC Pass NOCHECK NOCHECK NOCHECK 2.750 2.250 Si Sn Sr Ti ppm ppm ppm ppm 2.372 2.640 2.633 2.005 .091 .037 .034 .028 3.838 1.409 1.281 1.397 2.284 2.606 2.604 1.981 2.365 2.634 2.625 1.999 2.466 2.679 2.670 2.036 NOCHECK NOCHECK NOCHECK NOCHECK N 00 O O N Analysis Report 12/12/06 11:31:33 AM _> _ gh Low Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge 525.51 2.608 2.743 512.66 1017.7 540.34 SDev 7.79 .037 .037 8.79 27.8 8.43 %RSD 1.4832 1.424 1.358 1.7143 2.7294 1.5593 #1 517.73 2.577 2.711 505.35 990.95 533.96 #2 525.47 2.599 2.735 510.21 1015.7 537.17 ##3 533.32 2.649 H2.784 522.41 1046.4 549.89 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 550.00 2.750 2.750 550.00 1100.0 550.00 Low 450.00 2.250 2.250 450.00 900.00 450.00 page 2 M r --i r-+ 00 O O C/] h Analysis Report 12/12/06 11:39:10 AM page 1 hod: CLP1 Sample Name: CCVL4 Operator: MAG �"�.. Time: 12/12/06 11:31:39 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .10386 .0679 2.6386 .0088 .0008 .0008 .0614 SDev .12548 .0311 .6628 .0024 .0003 .0003 .0352 %RSD 120.82 45.78 25.119 27.16 42.07 42.60 57.29 #1 -.03994 .1011 2.2153 .0113 .0012 .0012 .0991 ##2 .19118 .0632 3.4024 .0085 .0008 .0008 .0555 #3 .16035 .0395 2.2981 .0066 .0005 .0005 .0295 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK High Low Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0011 .0010 .0009 .0006 2.532 .0665 .0628 SDev .0003 .0003 .0005 .0004 .012 .0110 .0362 %RSD 29.89 32.55 61.17 75.21 .4708 16.54 57.62 #1 .0015 .0014 .0015 .0010 2.545 .0786 .1016 " .0012 .0011 .0006 .0006 2.528 .0636 .0569 .0008 .0007 .0006 .0001 2.522 .0572 .0299 Errors NOCHECK NOCHECK NOCHECK NOCHECK LC Pass NOCHECK NOCHECK High 2.750 Low 2.250 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 Units ppm ppm ppm ppm ppb ppb ppb Avge .0006 .0163 2.589 .0009 .24655 .09910 17.801 SDev .0003 .0064 .023 .0007 2.3322 .90378 6.907 %RSD 47.14 38.90 .8878 79.35 945.91 912.00 38.800 #1 .0009 .0233 2.614 .0010 2.3766 -.92859 24.935 ##2 .0006 .0150 2.582 .0016 -2.2454 .45575 17.323 #3 .0003 .0108 2_.570 .0002 .60846 .77013 11.146 Errors NOCHECK NOCHECK LC Pass NOCHECK NOCHECK NOCHECK NOCHECK High 2.750 Low 2.250 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 16.083 5.6537 1.5260 .0127 .0005 .0007 .0009 SDev 6.874 3.7862 1.9752 .0208 .0005 .0003 .0003 %RSD 42.739 66.969 129.43 164.1 104.7 43.87 38.58 23.630 9.8095 3.7532 .0343 .0004 .0010 .0012 n- 14.439 2.3999 -.01336 .0110 .0011 .0006 .0008 #3 10.180 4.7518 .83833 -.0072 .0000 .0004 .0006 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK It 00 O O N Analysis Report 12/12/06 11:39:10 AM nigh Low Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge 2.0858 .0006 .0015 .14824 16.655 2.9006 SDev .5529 .0001 .0004 .58039 6.868 2.5751 %RSD 26.510 18.19 29.66 391.51 41.236 88.780 #1 1.8675 .0008 .0019 .17209 24.065 5.7699 #2 2.7146 .0006 .0015 -.44370 15.400 .79029 #3 1.6754 .0006 .0010 .71634 10.502 2.1415 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK High Low page 2 00 O O L/) N Analysis Report 12/12/06 11:46:47 AM page 1 ] Zod: CLP1 Sample Name: CCB4 Operator: MAG 1_-__ Time: 12/12/06 11:39:17 Comment: TSL008 Mode: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .26414 .0211 .1.4356 .0019 .0002 .0002 .0109 SDev .24114 .0015 2.0333 .0002 .0000 .0000 .0012 %RSD 91.292 7.254 141.64 12.05 11.11 19.36 10.74 #1 .53975 .0222 3.3464 .0017 .0002 .0002 .0121 #2 .16064 .0193 1.6618 .0022 .0002 .0002 .0098 #3 .09203 .0216 -.70140 .0019 .0002 .0002 .0108 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .2000 10.000 .2000 .2000 .0050 .2000 Low -10.000 -.2000 -10.000 -.2000 -.2000 -.0050 -.2000 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0005 .0002 .0002 .0000 .0089 .0463 .0148 SDev .0001 .0002 .0001 .0001 .0014 .0003 .0009 %RSD 18.47 137.7 39.03 667.7 15.76 .6633 6.224 #1 .0006 -.0001 .0003 .0001 .0105 .0459 .0146 "- .0005 .0003 .0002 .0001 .0079 .0464 .0141 .0004 .0003 .0001 -.0001 .0082 .0464 .0159 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .0050 .0500 .0100 .0250 .1000 5.000 .2000 Low -.0050 -.0500 -.0100 -.0250 -.1000 -5.000 -.2000 Elem Mn Mo Na Ni 2203/1 2203/2 2068/1 Units ppm ppm ppm ppm ppb ppb ppb Avge .0002 .0047 .0122 -.0003 -1.3704 .07780 5.0948 SDev .0000 .0016 .0017 .0001 1.2278 1.0746 2.2603 %RSD 13.65 33.70 13.65 24.80 89.588 1381.3 .44.365 #1 .0002 .0064 .0141 -.0004 -2.7862 1.2636 7.6374 #2 .0002 .0042 .0118 -.0003 -.72589 -.19845 4.3335 #3 .0002 .0033 .0108 -.0002 -.59919 -.83172 3.3134 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High .0150 5.000 .0400 Low -.0150 -5.000 -.0400 Elem 2068/2 1960/1 1960/2 Si Sn Sr Ti Units ppb ppb ppb ppm ppm ppm ppm Avge 3.8697 1.4702 -1.1876 -.0536 -.0007 .0002 .0003 SDev 1.3605 2.0414 1.3031 .0039 .0020 .0000 .0001 %RSD 35.157 138.85 109.72 7.204 293.7 18.65 19.69 2.7232 .87914 -1.9372 -.0499 .0004 .0002 .0003 5.3730 -.21040 -1.9427 -.0532 .0005 .0001 .0002 Tr- #3 3.5128 3.7419 .31706 -.0576 -.0029 .0001 .0002 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK 00 O O H Analysis Report 12/12/06 11:46:47 AM -gh Low Elem T11908 v Zn Pb2203 Sb2068 Se1960 Units ppb ppm ppm ppb ppb ppb Avge .68354 .0003 .0002 -.40442 4.2777 -.30252 SDev .62389 .0002 .0001 .33567 .7934 1.53525 %RSD 91.274 57.59 83.00 82.999 18.547 507.49 #1 .66921 .0004 .0003 -.08498 4.3596 -.99931 #2 .06693 .0003 .0002 -.37405 5.0269 -1.3658 #3 1.3145 .0001 .0000 -.75425 3.4465 1.4576 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .0500 .0200 3.0000 60.000 5.0000 Low -10.000 -.0500 -.0200 -3.0000 -60.000 -5.0000 page 2 00 O O E-� U2M "US' 1NC. IV. DOCUMENTATION FOR METALS A. DIGESTION LOG SHEETS B. REPORTING ANALYST SIGNATURE PAGE 00 00 0 con 0 F-4 FIR, awt, H2K Labs, Inc. CLI' Digestion Log"� Client: Analyst Signature: /y, - Izl- SDG #. , Date:_ id -71m, Matrix: IG W Time Started/Ended:_ t o3o - 133 o Method:it 3aloi� Description Sample ID # Lab # Dig Type Initial VoIANt Final Vol Spike Sol # Lot # Volume Before After -Eb O(O\%.-v..^ ooI FL. 50ML, �OrL (o1o+�G5s�c icor ,,, MW3D white, colorless, brown, grey, black. I fine, medium, coarse. idW-SS oo3E "Description of clarity: 'Description of artifacts: clear, cloudy, opaque. yes or no and describe 0l l4 UW -ti ` _ O:1QC/BOOKS/CLPDigeslJonlog F-1 � ib --C\ 1 Ck..r MW-Lts ooS� NW -sem WOE A.tu1 519215 a.5r`t_ Ind W- (aD �a- �tW-`�D OW �! U/ -$S WWW\ y&, ow � �2E Co1or��` C.o\c�ILS us- 1C(CAO Lie 1,r Comments:_ t'��i IRo90 PH: L 2-. `Description of colors: red, blue, yellow, green, orange, violet, white, colorless, brown, grey, black. `Description of texture: fine, medium, coarse. 000 "Description of clarity: 'Description of artifacts: clear, cloudy, opaque. yes or no and describe 0l l4 ` _ O:1QC/BOOKS/CLPDigeslJonlog F-1 � U2M l UV3 INC. SDG NO.: ►S�ooB SCAN: This data package was reported by the undersigned. This reporting includes data calculations, manual edits if necessary and compilation of raw data. The information presented is true and correct to the best of my knowledge. Signature:�� Date: Reviewed By Signature: -4—e Date: f,Z / %9 /4 rp O N 00 O O F-,