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Home My WebLink AboutSample Data Summary Package 12/2006Analytical Data Package For TOWN OF SOUTHOLD PART 360 ROUTINE SDG NO: TSL008 Water Samples Received: 12/6/06 SAMPLE DATA SUMMARY PACKAGE DECEMBER 2006 Onvironmental Testing Laboratories 575 Broad Hollow Road, Melville, N.Y. 11747 U28A "US, 1%C. SAMPLE DATA SUMMARY PACKAGE TABLE OF CONTENTS TOWN OF SOUTHOLD PART 360 ROUTINE WATER SAMPLES SAMPLES RECEIVED: 12/6/06 SDG NO.: TSL008 1. NYS DEC SUMMARY FORMS 2. CHAIN OF CUSTODY DOCUMENTATION 3. SDG NARRATIVES 4. SAMPLE REPORTS 4.1 METALS 4.2 WET CHEMISTRY 5. DUPLICATE SUMMARY RESULTS 5.1 METALS 5.2 WET CHEMISTRY 6. SPIKE SAMPLE RESULTS 6.1 METALS .6.2 WET CHEMISTRY 7. BLANK SUMMARY DATA AND RESULTS 7.1 METALS 7.2 WET CHEMISTRY 1. NYS DEC SUMMARY FORMS N 00 O O U0 N NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE IDENTIFICATION AND ANALYTICAL REQUIREMENT SUMMARY SDG: DMT029 Customer Laboratory Sample Sample GcvoA Code Code WW -7462-121206-00112120613 0612989-001 X TRIP BLANK 121206 0612989-002 X CLP,on-CLP (Please indicate year ofr`p protoco f 1J (0h! cit-i212yi0g- Analytical Requirements M 00 O O C� NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG: TSL008 INORGANIC ANALYSIS Laboratory Samp ID Client Sample ID Matrix Metals Requested DateRecd at Lab Date Analyzed 0612702-001 EB WATER CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 12/06 0612702-002 IMW-3D I WATER CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 12/06 0612702-003 MW -3S I WATER I CA,CD,FE,K,MG,MN,NA,PB, 106 -Dec -061 12/06 0612702-004 MW -4D WATER I CA,CD,FE,K,MG,MN,NA,PB, 106 -Dec -06 12/06 0612702-005 MW -4S I WATER I CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 , 12/06 0612702-006 MW -5D WATER CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -061 12/06 0612702-006DUP MW-5DD I WATER CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 12/06 0612702-006M5 MW-5DS I WATER CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 12/06 0612702-007 MW -5S I WATER CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 12/06 0612702-008 MW -6D WATER I CA,CD,FE,K,MG,MN,NA,PB, 106 -Dec -061 12/06 0612702-009 MW -6S WATER CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 12/06 0612702-010 MW -8D WATER CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 12/06 0612702-011 MW -8S WATER CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -061 12/06 0612702-012 ISOUTHHOLD 2 I WATER CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 12/06 0612702-013 FB WATER CA,CD,FE,K,MG,MN,NA,PB, 06 -Dec -06 12/06 TSL008 S4 NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG: TSI-008INORGANIC ANALYSIS Laboratory Samp ID 1 Client Sample IDI Matrix i I Tests 1 DateRec ( I d at Lab Date Analyze 0612702-001 EB Blank f SELECT WET CHEMISTRY * 12/06/06 I 12/06 0612702-002 MW -3D Groundwater SELECT WET CHEMISTRY ** 12/06/06 I 12/06 0612702-003 MW -3S I Groundwater SELECT WET CHEMISTRY ** I 12/06/06 12/06 0612702-004 MW -4D Groundwater SELECT WET CHEMISTRY ** I 12/06/06 ' 12/06 0612702-005 MW -4S i Groundwater SELECT WET CHEMISTRY ** 12/06/06 i 12/06 0612702-006 MW -51) Groundwater SELECT WET CHEMISTRY ** 12/06/06 12/06 0612702-006DUP MW-5DDUP Groundwater 1 SELECT WET CHEMISTRY ** 12/06/06 12/06 0612702-006MS MW-5DMS Groundwater ' SELECT WET CHEMISTRY ** I 12/06/06 12/06 0612702-007 I MW -5S Groundwater I SELECT WET CHEMISTRY ** I 12/06/06 I 12/06 0612702-008 MW -61) Groundwater I SELECT WET CHEMISTRY ** ; 12/06/06 I 12/06 0612702-009 1 MW -6S i Groundwater SELECT WET CHEMISTRY ** 12/06/06 I 12/06 0612702-010 I MW -813 I Groundwater SELECT WET CHEMISTRY ** I 12/06/06 12/06 0612702-011 I MW -8S Groundwater SELECT WET CHEMISTRY ** I 12/06/06 I 12/06 0612702-012 I SOUTHHOLD 2 I Groundwater SELECT WET CHEMISTRY ** ' 12/06/06 I 12/06 0612702-013 FB i Field Blank I SELECT WET CHEMISTRY I 12/06/06 I 12/06 ** Alkalinity, Total (As CaCO3) ; Biochemical Oxygen Demand ; Bromide; Chemical Oxygen Demand; Chloride; Hardness (As CaCO3) ; Nitrate as N ; Nitrogen, Ammonia (As N) ; Nitrogen, Kjeldahl, Total ; Phenolics, Total Recoverable; Sulfate; Total Dissolved Solids; Total Organic Carbon; Cn 00 O O Cn U28A "USS INC. 2. CHAIN OF CUSTODY DOCUMENTATION "13S, IMC. ..• i.WAW WAWA 18` EXTERNAL CHAIN OF CUSTODY �►-(6�u6943040Fax: (631) 420-8436 PROJECT NAMEINUMBER CLIENT! H2M-SDG NO: )SLO0 NOTES: Project Contact L) \\7 O V\ ``u�t�, o� L,a.•� �tl V S s -fir i _3 W er' ar - Phone Number: P1S(Quote # SAMPLERS: (signatureyClient DELIVERABLES: c € ~ ANALYSIS REQUESTED TURNAROUND TIME: ORGANIC cy INORG. . 10nd, �' Z V LAB I.D. NO. REMARKS: DATE' TIME MATRIX FIELD I.D. �► 1�� ob m \J,) �S IY\- k Z 2 � ` 3 I --bO n� s M s c0 ►' z�` new a fir' r9 ' ID NW -�7 ill .., (h`�� z z Z. Z ti i r l 3 3 ► ► —oa O C>Dz — Z . Relinquished 54SIgnature•)•_..___--•--•......."."" hed tr Date Time 14��( Received by: (S;gmtwe) ��-. ��'� Date J2�6Ie' Time (� ` �' LABORATORY USE ONLY Discrepancies Between1. Sample Labels and COC Record? Y or N N_«Hand Delnrered_E,r 2 Amblent or ciAlled, Temp 3. Received In good condition: Y or N Rel*uiahed by: (Signa7re) Date Time Received by: (Signature) Date Time Explain: 4. Property preserved: Y or N COC Tape was: Relinquished by: (Signature) Date Time Received by (Signature) Date Time t. Present on outer package: Y or N 2 Linbroken on outer package: Y or N 3. COC record present 3 complete upon sample receipt: Retlnquiahed by (Signature) Date Time Received by. (Signature) Date Time YorN T�VVU&FRJY - ORIGINAL YELLOW COPY - CLIENT PINK UUVY - L.HCUMA I LIMT �..r r,—J U-01 ... 004 UAhY111n AIV 447A7 5!179 1HAK IAUS9 INCO "'o EXTERNAL CHAIN OF CUSTODY I, .Q,fU LP/w0U ijviiv— ... ... .- --- - . Tel. (631) 694-3040 Fax. (631) 420-8436 CLIENT: H2M SDG NO: Lia PROJECT NAME/NUMBER NOTES: Project Contact: M1 Phone Number: SAMPLERS: (signatureyClient y PIS/Quote # J DELIVERABLES: ANALYSIS REQUESTED c TURNAROUND TIME: ORGANIC INORG. , F.. A Z D TE TIME MATRI FIELD I.D. > m a , rJ 'd U LAB I.D. NO. REMARKS: �z� .r � � •L ( I Relinquisfiied by: (Slnature) Date Time Received by: (Signal—) Date Time LABORATORY USE ONLY Discrepancies Between Sample Labels and Samores were: 1. Shipped_ or Hand Delivered Alrbilta 2 Ambient or chilled, Temp A,t VE b �u': r Relinquished by. (Signature) Date Time Received by: (Signature) Date Time COC Record? Y or N 3, Received in good condition: Y or N Explain: 4. Property preserved: Y or N COC Tape was: Relinquished by: (Signature) Date Time Received try: (Signature) Date Time 1. Present on outer package: Y or N 2. Unbroken on outer package: Y or N 3. COC record present h complete upon sampie reoelpl: Relinquished by (Signature) Date Time Received by (Signature) Date Time YorN TV r65gC92Y - ORIGINAL YELLOW COPY - CLIENT PINK COPY - LABORATORY 92M LABS, INC. Sample Receipt Checklist Client Name PCTSL Date and Time Receive I S• (, oa � 12/6/2006 4:50:00 PM Work Order Numbe 0612702 Received by CDS Checklist completed by � 'S ---'CA-AI Reviewed by ) A Signature D le Initials Dat Matrix: Shipping container/cooler in good condition? Custody seals intact on shippping container/cooler Custody seals intact on sample bottles? Carrier name Hand Delivered Yes ? W Yes ❑ Yes ❑ Chain of custody agrees with sample labels? Yes Chain of custody present? Yes 6n Chain of custody signed when relinquished and received? Yes❑ Chain of custody agrees with sample labels? Yes Samples in proper container/bottle? Yes Sample containers intact? Yes ❑� Sufficient sample volume for indicated test? Yes All samples received within holding time? Yes ❑� Containerfremp _Blank temperature in compliance? Yes R1 Water - VOA vials have zero headspace? No VOA vials submitted ❑ Water - pH acceptable upon receipt? Yes R1 Adjusted? No ❑ No ❑ No ❑ No ❑ No ❑ No ❑ No ❑ No ❑ No ❑ No ❑ No ❑ Yes C No ❑ Checked b Not Applicable ❑ Not Applicable R) Not Applicable W No ❑ Any No and/or NA (not applicable) response must be detailed in the comments section be --------------------------------------------- --------------------------------------------- Client contacted Date contacted: I)A t? L Person contacted Contacted by: )(GiJ �(]` Regarding: Comments:Or �DLL--�F C/% C)d 1 lIJL C. 7— Corrective Corrective Action 00 O O C/� 1-i2M 1.AUS,1NC. INTERNAL CHAIN OF CUSTODY ICLIENT: ,PCIS DELIVERABLES: S -7U TURN AROUND TRAE:) l a SDG #: TS�,OoV CASE #: MATRIX: Grog„ uc*1 pH CHECK Y or N REMARKS: f- s o RECEIVED BY: / SIGNATURE: DATE: l 0 C TWE:A SC CLIENT ID 1-12M LAB # DATE COLLECTED BOTTLE TYPE M OF BOTTLES TESTS REQUESTED � OL,.t�oa of a P�a- �_ aoE li f /14tj- q S eosE 1�— /VIV D 006F t2AI u' /V1W ✓//l7(� oafE otoa 12 ou E ( n Somal NoL-o ,� olA- C J 6( J' ' 0139 " -NSA " 6 aG n n s METALS P 0295 C 00 CDC N i cLISNT: P61 SZ _.I sm TEL INTERNAL CHAIN OF•CUSTODY .: SAMPLE PURPOSE OF RELINQUISHED I SAMPLE BOTTLE CHANGE OF �� DATE TIME BY RECEIVED BY TYPE CUSTODY INIT 12 06 17 .J HI 3I � - �IQ 'Ti,e✓ i lnoO fN alGw s il� Y►. o � o� �: E.� � BI 9I )�dn o6 Wo al ow� sI )2) o Blow slow BIow 3I01A ' BIG& SIGN exalt SIGN - slow - SIGN BION SIGN slow SIGN SIGN SION slow SIGN BION SIGN 3I011 SIGN SIGN SIGN .. BION SIGN SION SIGN 3ION SION - 32Ow - SIGH slow SION SION SIGN 310" SIGN SION -SIGN SION SIGN i METALS .�J P 0296 r 00 C) C) e 1-12M LADS, INC. INTERNAL CHAIN OF CUSTODY CLIENT: PC T DELIVERABLES: 3S - 7013 TURN AROUND TIME='2� s SDC #: 'rS L OO � CASE #: MATRIX: C ml jtf4fl pH CHECK Y a N REMARKS: P r S X� G 9 a PCTS� o s RECEIVED BY: m SIGNA"I M: (�X o� DATE I C 4GTQvlEt C S 0 CLIENT ID HZM LAB N DATE COLLECTED BOTTLE TYPE BTED =#�OFTESTS E3 1 al 3 To Q- 1066_W = ' • o� oo t ooID F1v 1' h t S J- y FIA R 8 -c.1( VENO V NN; _ PNFNvts_ v TKN_ U aens_u,aR_v ct-v soil _U_9as� D Q A ` /AA��'uf MW��S ooS t''' � oor Aq ._ AU - 9 D01 ) ��tT�-j0(,►� as z ,. F g� G -'_ (� WET CHEMISTRY CHEMISTRY J P 0235 N' =—a cn 00 O O cn E-4 L I uAuss Isc- SDG L 00c4 INTERNAL CHAIN SOF CUSTODY WET CHEMISTRY P 0236 m SAMPLE BY RECEIVED �lJlil►)IN.�I�� I ! r iv WET CHEMISTRY P 0236 m LAUS, INC. CLIENT Pars t, STDG 4: � t co I TODY INTERNAL CHAIN OF. CUS WET CHEMISTRY I P 0237 u2M "Uss INC. 3e SDG NARRATIVES W') cn 00 0 0 N V2AA iLAUSs INCe For Sample: SDG NARRATIVE FOR METALS SAMPLE RECEIVED: 12/6/06 SDG#: TSL008 EB MW -5D MS/MSD MW -81) MW -31) MVV -5S MW -8S MW -3S MW -61) SOUTHHOLD 2 MW -41) MW -6S FB MW -4S Thirteen water samples were received by H2M Labs, Inc. on 12/6/06 for analysis of a select list of metals. Samples were prepared and analyzed using EPA method 6010B with a TJA 61E Trace ICP Instrument. Sample MW -5D was utilized for QC analysis and reporting. Sample MW -3S was reanalyzed at a dilution for manganese to keep instrument readings within the calibration range. No other problems were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: December 19, 2006 Ursula Middel Technical Manager U24 "US, INC. For Samples: SDG NARRATIVE FOR WET CHEMISTRY SAMPLE RECEIVED: 12/6/06 SDG#: TSL008 EB MW -6D MW -31) MW -6S MW -3S MW -81) MW -4D MW -8S MW -4S SOUTHHOLD 2 MW -5D FB MW -5S EPA 320.1 Thirteen water samples were received by H2M Labs, Inc. on 12/6/06 for select wet chemistry analysis. Samples were prepared and analyzed using the following methods: PARAMETER METHOD # PARAMETER METHOD # Alkalinity EPA 310.1 Nitrate EPA 353.2 BOD EPA 405.1 Phenols EPA420.1 Bromide EPA 320.1 Sulfate EPA 9038 Chloride EPA325.2 TDS EPA 160.1 COD EPA 410.4 TKN EPA 351.2 Hardness EPA 130.2 TOC EPA 9060 Ammonia EPA 350.1 Sample MW -5D was utilized for duplicate and spike QC analysis and reporting. Duplicate analysis did not reproduce within acceptance ranges for biological oxygen demand (BODs) of ± the CRDL of 2 mg/L. Batch acceptance was based on LCS standard analysis. Initial TKN spike analysis did not recover within acceptance range. The sample group was diluted, redigested and reanalyzed. The reanalysis recovered acceptably. Samples were diluted and reanalyzed as required to keep instrument readings within calibration ranges. No other problems were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: December 28, 2006 Vincent Stancampiano Vice President 00 O O C/) E-4 u2M "Uss INC. 4. SAMPLE REPORTS 4.1 METALS 4.2 WET CHEMISTRY 00 r 00 0 0 E� U28A -INC. QUALIFIERS FOR METALS ANALYSIS Q (Quality Control) Qualifiers E - The reported value is estimated because of the presence of interference. An explanatory note is included in the SDG narrative. M - Duplicate injection precision not met. N - Matrix spike sample recovery not within control limits. S- The reported value was determined by the Method of Standard Additions (MSA). + - Correlation coefficient for the MSA is less than 0.995 W - Post digestion spike for Furnace AA analysis is out of control limits (85- 115%), while sample absorbance is less than 50% of spike absorbance. * - Duplicate analysis is not within control limits. C (Concentration) Qualifiers B - Entered if the reported value is less than the Contract Required Detection Limit (CRDL) but greater than the Instrument Detection Limit (IDL). U - Entered if the analyte was analyzed for but not detected, i.e., less than the IDL. M (Method) Qualifiers P - Analyzed by ICP. M - Analyzed by ICP -MS A - Analyzed by Flame AA. F - Analyzed by Furnace AA. CV - Analyzed by Manual Cold Vapor techniques. AV - Analyzed by Automated Cold Vapor techniques. C - Analyzed by Manual Spectrophotometric Method. CA- Analyzed by Midi -distillation Spectrophotometric Method. NR- Analyte not Required. 00 0 0 rn E� U.S. EPA - CLP ' 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: Solids: 0_0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 1.1 B P 7440-70-2 Calcium 66.3 B P 7439-89-6 Iron 28.1 B P 7439-92-1 Lead 1.5 U P 7439-95-4 Magnesium 21.6 B P 7439-96-5 Imanganese 1.1 B P 7440-09-7 Y�E� Potassium 84.6 B P 7440-23-5 ISodium 76.3 B P EPA SAMPLE NO EB SDG No.: TSL008 12/6/2006 Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 O N 00 O O Vj F-+ 1-12M "US, INC. 575 Broad Hdow Road, McWe W 11747 LABORATORY RESULTS (631)6943040.FAX (631)42M436 WSDOHID#10478 Town of Southold Landfill Lab No. : 0612702-001 Attn To : Original Collected :12/6/2006 3:20:00 PM Received :1216/2006 4:50:00 PM Collected By VG03 Copies To :Original cc Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID.: EB Sample Information... Type: Blank Origin: Results Qualifier D.F. Units Method Number Analyzed < 1.0 1 mg/L E310.1 12/07/2006 4:00 PM < 2 1 mg/L E405.1 12/07/2006 2:50 PM < 0.5 1 mg/L E320.1 12/22/2006 9:10 AM < 2.0 - 1 mg/L E325.2 12/07/2006 1:00 PM <10 1 mg/L E410.4 12/12/2006 12:23 PM < 5.0 1 mg/L E130.2 12/15/2006 11:10 AM < 0.10 1 mg/L E350.1 12/21/2006 11:03 AM < 0.10 1 mg/L E353.2 12/07/2006 3:24 PM < 5.0 1 pg/L E420.1 12/20/2006 8:30 AM < 5.0 1 mg/L SW9038 12/20/2006 1:34 PM <10 1 mg/L E160.1 12/11/2006 3:44 PM < 0.10 1 mg/L E351.2 12/20/2006 11:54 AM < 1.0 1 mg/L SW9060 12/18/2006 8:48 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported: 12/28/2006 Page 1 of 13 ib-4-0--j . Laboratory Manager N 00 Ol� F --i U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA.SHEET 3L__j Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No..: TSL008 Matrix (soil/water): WATER Lab Sample ID: 0612702-002 Level (low/med): LOW Date Received: 12/6/2006 % Solids: 0_0 Concentration Units (ug/T, or mg/kg dry weight): UG/L CAS No. Analyte Q Concentration T - M T440 -4 3-9 Cadmium 0.28 P 7440-70-2 Calcium 75400 P 7439-89-6 Iron 6410 P 7439-92-1 Lead 1.5 U P 7439-95-4 Magnesium 33800 P 7439-96-5 Manganese 4040 P 7440-09-7 Potassium 131000 P 7440-23-5 ISodium 221000 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 N N 00 O O V1 U214 "U%S Isce 575 Broad Hollow Road, McMle NY 11747 (631)694-3040.FAX- (631)420.8436 NYSDOH1D#10478 Town of Southold Landfill Attn To Original Collected :12/6/2006 2:00:00 PM Received :1216/2006 4:50:00 PM Collected By VG03 Copies To :Original CC LABORATORY RESULTS Lab No. : 0612702-002 Client ID. : MW -3D Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 875 20 mg/L E310.1 12/07/2006 4:08 PM Biochemical Oxygen Demand 3 1 mg/L E405.1 12/07/2006 2:55 PM Bromide 1.4 1 mg/L E320.1 12/22/2006 9:15 AM Chloride 231 10 mg/L E325.2 12/07/20061:01 PM Chemical Oxygen Demand 112 1 mg/L E410.4 12/12/2006 12:24 PM Hardness (As CaCO3) 360 20 mg/L El 30.2 12/15/2006 11:15 AM Nitrogen, Ammonia (As N) 72.0 50 mg/L E350.1 12/21/2006 11:04 AM Nitrate as N < 0.10 1 mg/L E353.2 12/07/2006 3:25 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2006 8:45 AM Sulfate 45.0 2.5 mg/L SW9038 12/20/2006 1:36 PM Total Dissolved Solids 1050 2 mg/L E160.1 12/11/2006 3:46 PM Nitrogen, Kjeldahl, Total 108 100 mg/L E351.2 12/20/2006 4:04 PM Total Organic Carbon 35.3 1 mg/L SW9060 12/18/2006 9:19 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. ='Dilution Factor Date Reported : 12/28/2006 Page 2 of 13 Laboratory Manager U.S. EPA - CLP Solids: 0_0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 EPA SAMPLE NO 7440-43-9 Cadmium INORGANIC ANALYSIS DATA SHEET P 7440-70-2 Calcium 57400 P 7439-89-6 MW -3S Lab Name: H2M LABS, INC. Contract: E-e-adl 1.5 U P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Matrix (soil/water): WATER Lab Sample ID: 0612702-003 Level (low/med)• LOW Date Received: 12/6/2006 Solids: 0_0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte (Concentration C Q M 7440-43-9 Cadmium 1.8 B P 7440-70-2 Calcium 57400 P 7439-89-6 Iron 68900 P 7439-92-1 E-e-adl 1.5 U P 7439-95-4 Magnesium 25200 P 7439-96-5 Manganese 23500 P 7446-09-7 Potassium 43000 P 7440-23-5 Sodium 53300 P Color Before: BROWN Clarity Before: CLOUDY Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 12/12/2006 N FORM I - IN ILM04.1 t 2M 1NC. 575 Broad Hollow Road, MdAle NY 11747 LABORATORY RESULTS (631) 694-3040. FAX (631) 420436 NYSDOH ID# 10478 Town of Southold Landfill Lab No. : 0612702-003 Attn To : Original Collected :1215/2006 1:00:00 PM Received :12/6/2006 4:50:00 PM Collected By VG03 Copies To :Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID. : MW -3S Results Qualifier D.F.. Units 385 20 mg/L 4 1 mg/L 6.6 1 mg/L 61.2 1 mg/L 51.2 1 mg/L 324 4 mg/L 18.5 10 mg/L < 0.10 1 mg/L < 5.0 1 pg/L 49.2 2.5 mg/L 460 1 mg/L 26.6 20 mg/L 12.9 1 mg/L Qualifiers: E - Value above quantitation range D.- Results for Dilution D.F. = Dilution Factor Date Reported : 12/28/2006 Page 3 of 13 Sample Information... Type : Groundwater Origin: Method Number Analyzed E310.1 12/07/2006 4:16 PM E405.1 12107/2006.3:00 PM E320.1 12/22/2006 9:20 AM E325.2 12/07/2006 1:01 PM E410.4 12/12/2006 12:25 PM E130.2 12/15/2006 11:20 AM E350.1 12/21/2006 11:05 AM E353.2 12/07/2006 3:26 PM E420.1 12/20/2006 9:00 AM SW9038 12/20/2006 1:38 PM E160.1 12/11/2006 3:48 PM E351.2 12/20/2006 11:56 AM SW9060 12/18/2006 9:49 PM Laboratory Manager N i� 00 O �l 1--i U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: Solids: 0_0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7990-93-9 lCadmium 0.42 B P 7440-70-2 lCalcium 58800 P 7439-89-6 Iron 2260 P 7439-92-1 Lead 4.0 P 7439-95-4 Magnesium 20200 P 7439-96-5 Manganese 9640 P 7440-09-7 Potassium 44800 P 7940-23-5 Sodium 19200 P Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: CLEAR Comments: Date Reported: 12/12/2006 EPA SAMPLE NO MW -9D SDG No.: TSL008 12/6/2006 Texture: Artifacts: FORM I - IN ILM04.1 N 00 00 O O 1-12/4 "U%s INC. 575 Broad Hollow Road, MelAe NY 11747 (631)694-3040.FAX (631)42M436 NYSDOHID#10478 Town of Southold Landfill Attn To : Original Collected :12/6/2006 11:45:00 AM Received :1216/2006 4:50:00 PM Collected By VG03 Copies To :Original CC LABORATORY RESULTS Lab No. : 0612702-004 Client ID. : MW -4D Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 173 10 mg/L E310.1 12/07/2006 6:24 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 12/07/2006 3:05 PM Bromide 1.4 1 mg/L E320.1 12/22/2006 9:25 AM Chloride 23.2 1 mg/L E325.2 12/07/2006 1:02 PM Chemical Oxygen Demand 28.6 1 mg/L E410.4 12/12/2006 12:26 PM Hardness (As CaCO3) 270 10 mg/L E130.2 12/15/2006 11:25 AM Nitrogen, Ammonia (As N) 0.65 1 mg/L E350.1 12/21/2006 11:06 AM Nitrate as N 8.59 10 mg/L E353.2 12/07/2006 3:27 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2006 9:15 AM Sulfate 79.5 2.5 mg/L SW9038 12/20/2006 1:40 PM Total Dissolved Solids 374 1 mg/L E160.1 12/11/2006 3:50 PM Nitrogen, Kjeldahl, Total 2.58 20 mg/L E351.2 12/20/2006 11:56 AM Total Organic Carbon 10.5 1 mg/L SW9060 12/18/2006 10:19 P.M Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Laboratory Manager Date Reported : 12/28/2006 Page 4 of 13 U.S. EPA - CLP Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 EPA SAMPLE NO 7440-43-9 INORGANIC ANALYSIS DATA SHEET P 7440-70-2 Calcium 114000 P 7439-89-6 MW -4S Lab Name: H2M LABS, INC. Contract: Lead 1.5 U P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Matrix (soil/water): WATER Lab Sample ID: 0612702-005 Level (low/med)• LOW Date Received: 12/6/2006 % Solids: 0_0 220000 P Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.28 U P 7440-70-2 Calcium 114000 P 7439-89-6 Iron 394 P 7439-92-1 Lead 1.5 U P 7439-95-4 Magnesium 56500 P 7439-96-5 Manganese 2880 P 7440-09-7 Potassium 129000 P 7440-23-5 Sodium 220000 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 00 N 00 O O E-� U28i "US43 INC. 575 Broad HdloN Road, Melville NY 11747 (631) 694-3040. FAX (631)420-84W NYSDOHID#10478 Town of Southold Landfill Attn To : Original Collected :1215/2006 3:15:00 PM Received :12/6/2006 4:50:00 PM Collected By VG03 Copies To :Original CC LABORATORY RESULTS Lab No. : 0612702-005 Client ID. : MW -4S Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 790 20 mg/L E310.1 12/07/2006 4:24 PM Biochemical Oxygen Demand 3 1 mg/L E405.1 12/07/200613:10 PM Bromide 2.7 1 mg/L E320.1 12/22/2006 9:30 AM Chloride 293 10 mg/L E325.2 12/07/2006 1:03 PM Chemical Oxygen Demand 83.9 1 mg/L E410.4 12/12/2006 12:27 PM Hardness (As CaCO3) 520 20 mg/L E130.2 12/15/2006 11:30 AM Nitrogen, Ammonia (As N) 51.5 50 mg/L E350.1 12/21/2006 11:07 AM Nitrate as N 0.36 1 mg/L E353.2 12/07/2006 3:28 PM Phenolics, Total Recoverable 5.9 1 pg/L E420.1 12/20/2006 9:30 AM Sulfate 120 5 mg/L SW9038 12/20/2006 1:42 PM Total Dissolved Solids 1200 2 mg/L E160.1 12/11/2006 3:52 PM Nitrogen, Kjeldahl, Total 75.6 100 mg/L E351.2 12/20/2006 4:05 PM Total Organic Carbon 25.9 1 mg/L SW9060 12/18/2006 10:49 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 12/28/2006 Page 5 of 13 K'11- Laboratory ixLaboratory Manager N 00 O Cl 1 U.S. EPA - CLP Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 EPA SAMPLE NO 7440-43-9 INORGANIC ANALYSIS DATA SHEET P 7440-70-2 Calcium 89000 MW -5D i Lab Name: H2M LABS, INC. Contract: i 7439-92-1 Lab Code: 10978 Case No. SAS No.: SDG No.: TSL008 Matrix (soil/water): WATER Lab Sample ID: 0612702-006 Level (low/med)• LOW Date Received: 12/6/2006 % Solids: 0_0 P 7440-23-5 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.35 B P 7440-70-2 Calcium 89000 P 7939-89-6 Iron 1280 _ P 7439-92-1 Lead 2.6 B P 7439-95-4 Magnesium 62800 P 7439-96-5 Manganese 11900 P 7440-09-7 Potassium 139000 P 7440-23-5 Sodium 194000 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 O M 00 O O N 1-128M "US, INC. 575 Broad Hollow Road, MdAee W 11747 (631)6943040. FAY,(631)420Z436 WSDOHID#10478 Town of Southold Landfill Attn To Original Collected :12/6/2006 9:15:00 AM Received :12/6/2006 4:50:00 PM Collected By VG03 Copies To :Original CC LABORATORY RESULTS Lab No. : 0612702-006 Client ID. : MW -5D Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 743 20 mg/L E310.1 _ 12/07/2006 4:32 PM Biochemical Oxygen Demand 12 1 mg/L E405.1 12/07/2006 3:15 PM Bromide 5.6 1 mg/L E320.1 12/22/2006 9:35 AM Chloride 280 10 mg/L E325.2 12/07/2006 1:04 PM Chemical Oxygen Demand 94.0 1 mg/L E410.4 12/12/2006 12:28 PM Hardness (As CaCO3) 520 20 mg/L E130.2 12/15/2006 11:35 AM Nitrogen, Ammonia (As N) 58.0 50 mg/L E350.1 12/21/2006 11:09 AM Nitrate as N < 0.10 1 mg/L E353.2 12/07/2006 3:30 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2006 9:45 AM Sulfate 142 10 mg/L SW9038 12/20/2006 1:44 PM Total Dissolved Solids 1230 2 mg/L E160.1 12/11/2006 3:54 PM Nitrogen, Kjeldahl, Total 92.0 10 mg/L E351.2 12/23/2006 9:46 AM Total Organic Carbon 24.4 1 mg/L SW9060 12/18/2006 11.19 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.E. = Dilution Factor Laboratory Manager Date Reported : 12/28/2006 Page 6 of 13 U.S. EPA - CLP _ % Solids: 0_0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 EPA SAMPLE NO 7940-43-9 INORGANIC ANALYSIS DATA SHEET P 7440-70-2 Calcium 16000 P 7439-89-6 =5S Lab Name: H2M LABS, INC. Contract: Lead 7.1 P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Matrix (soil/water): WATER Lab Sample ID: 0612702-007 Le vel (low/med)• LOW Date Received: 12/6/2006 _ % Solids: 0_0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7940-43-9 Cadmium 0.28 U P 7440-70-2 Calcium 16000 P 7439-89-6 Iron 8170 P 7439-92-1 Lead 7.1 P 13100 P 2460 P7439-95-4Wpotassium 8400 P 14100 P Color Before: BROWN Clarity Before: CLOUDY Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 N M 00 O O N U2M "US, INC. 575 Brad Hdlo✓v Road, Melville NY 11747 (631) 6943040. FAX (631) 420$436 NYSDOH ID# 10478 Town of Southold Landfill Attn To : Original Collected :12/6/2006 10:30:00 AM Received :12/6/2006 4:50:00 PM Collected By VG03 Copies To :Original CC LABORATORY RESULTS Lab No. : 0612702-007 Client ID.: MW -5S Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Anal Alkalinity, Total (As CaCO3) 64.0 5 mg/L E310.1 12/07/2006 5:12 PM Biochemical Oxygen Demand 8 1 mg/L E405.1 12/07/2006 3:25 PM Bromide 1.4 1 mg/L E320.1 12/22/2006 9:50 AM Chloride 16.0 1 mg/L E325.2 12/07/2006 1:06 PM Chemical Oxygen Demand 16.0 1 mg/L E410.4 12/12/2006 12:31 PM Hardness (As CaCO3) 96.0 2 mg/L E130.2 12/15/2006 11:50 AM Nitrogen, Ammonia (As N) 1.55 1 mg/L E350.1 12/21/2006 11:12 AM Nitrate as N 2.18 5 mg/L E353.2 12/07/2006 3:33 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2006 10:30 AM Sulfate 38.5 1 mg/L SW9038 12/20/2006 1:50 PM Total Dissolved Solids 192 1 mg/L E160.1 12/11/20064:00 PM Nitrogen, Kjeldahl, Total 3.36 20 mg/L E351.2 12/20/2006 11:59 AM Total Organic Carbon 7.5 1 mg/L SW9060 12/19/2006 12:49 AM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 12/28/2006 Page 7 of 13 /K111' Laboratory Manager M M 00 O l-4 V) U.S. EPA - CLP Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 EPA SAMPLE NO 7440-43-9 INORGANIC ANALYSIS DATA SHEET P 7440-70-2 Calcium 44200 P 7439-89-6 MW -6D Lab Name: H2M LABS, INC. Contract: Lead 1.5 U P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Matrix (soil/water): WATER Lab Sample ID: 0612702-008 Level (low/med)• LOW Date Received: 12/6/2006 % Solids: 0_0 20300 P Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.78 B P 7440-70-2 Calcium 44200 P 7439-89-6 Iron 2860 P 7439-92-1 Lead 1.5 U P 7439-95-4 Magnesium 15300 P 7439-96-5 Manganese 7940 P 7440-09-7 Potassium 5830 P 7440-23-5 Sodium 20300 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 u2M "Uss INC. 575BroadHdlow Road, Melville W 11747 LABORATORY RESULTS (631)694-3040.FAX(631)42(1-8436 WSDOHID#10478 Town of Southold Landfill Lab No. : 0612702-008 Attn To Original Collected :12/6/2006 3:00:00 PM Received :12/6/2006 4:50:00 PM Collected By VG03 Copies To :Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID.: MW -6D Results Qualifier D.F.. Units 41.5 2 mg/L <2 1 mg/L 3.1 1 mg/L 38.0 1 mg/L. <10 1 mg/L 210 10 mg/L 0.12 1 mg/L 3.30 5 mg/L < 5.0 1 pg/L 145 10 mg/L 299 1 mg/L 0.23 1 mg/L 1.6 1 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 12/28/2006 Page 8 of 13 Sample Information... Type: Groundwater Origin: Method Number Analyzed E310.1 12/07/2006 5:20 PM E405.1 12/07/2006 3:30 PM E320.1 12/22/2006 9:55 AM E325.2 12/07/2006 1:07 PM E410.4 12/12/2006 12:32 PM E130.2 12/15/2006 11:55 AM E350.1 12/21/2006 11:13 AM E353.2 12/07/2006 3:34 PM E420.1 12/20/2006 10:45 AM SW9038 12/20/2006 1:52 PM E160.1 12/11/2006 4:02 PM E351.2 12/20/2006 12:00 PM SW9060 12/19/2006 1:17 AM Q/1V►'L Laboratory Manager W) M 00 O Cl M--1 F"t U.S. EPA - CLP % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 EPA SAMPLE NO 7440-43-9 INORGANIC ANALYSIS DATA SHEET P 7440-70-2 Calcium 19800 P 7439-89-6 MW -6S Lab Name: H2M LABS, INC. Contract: Lead 12.2 P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Matrix (soil/water): WATER Lab Sample ID: 0612702-009 Level (low/med): LOW Date Received: 12/6/2006 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.2B U P 7440-70-2 Calcium 19800 P 7439-89-6 Iron 29600 P 7439-92-1 Lead 12.2 P 7439-95-4 Magnesium 7910 P 7439-96-5 Manganese 5460 P 7440-09-7 Potassium 12000 P 7440-23-5 Sodium 3320 B P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 U2M "U%s INC. 575 Broad Hollow Road, MaVMe NY 11747 (631)694. 0 .FAX -(631)420$436 NYSDOH ID# 10478 Town of Southold Landfill Attn To : - Original Collected :12/5/2006 12:15:00 PM Received :12/6/2006 4:50:00 PM Collected By VG03 Copies To :Original cc LABORATORY RESULTS Lab No. 0612702-009 Client ID. : MW -6S Sample Information... Type: Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 54.2 5 mg/L E310.1 12/07/2006 5:28 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 12/07/2006 3:35 PM Bromide 0.6 1 mg/L E320.1 12/22/2006 10:00 AM Chloride 5.3 1 mg/L E325.2 12/07/2006 1:08 PM Chemical Oxygen Demand <10 1 mg/L E410.4 12/12/2006 12:33 PM Hardness (As CaCO3) 90.0 2 mg/L E130.2 12/15/2006 12:00 PM Nitrogen, Ammonia (As N) 0.11 1 mg/L E350.1 12/21/2006 11:19 AM Nitrate as N 2.64 5 mg/L E353.2 12/07/2006 3:38 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2006 11:00 AM Sulfate 8.2 1 mg/L SW9038 12/20/2006 1:54 PM Total Dissolved Solids 119 1 mg/L E160.1 12/11/2006 4:04 PM Nitrogen, Kjeldahl, Total 0.46 1 mg/L E351.2 12/20/2006 4:08 PM Total Organic Carbon 3.8 1 mg/L SW9060 12/19/2006 2:51 AM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Laboratory Manager Date Reported : 12/28/2006 Page 9 of 13 M U0 00 O 0 1 U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID Level (low/med): LOW Date Received % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration CT Q M 7440-43-9 Cadmium 0.28 U P 7440-70-2 Calcium 63400 P 7439-89-6 Iron 2060 P 7439-92-1 Lead 1.5 U j P 7439-95-4 Magnesium 35700 j P 7439-96-5 Manganese 1840 P 7440-09-7 Potassium 87700 P 7440-23-5 Sodium 75300 P EPA SAMPLE NO MW -8D SDG No.: TSL008 12/6/2006 Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 00 M DO 00 O O N 1--12/1 LABS, INC. 575 Broad Hollow Road, MaVM NY 11747 (631)694-3040. FAX (631)420$436 NYSDOHID#10478 Town of Southold. Landfill Attn To : Original Collected :12/6/2006 1:00:00 PM Received :12/6/2006 4:50:00 PM Collected By VG03 Copies To :Original CC LABORATORY RESULTS Lab No. : 0612702-010 Client ID. : MW -8D Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 431 20 mg/L E310.1 12/07/2006 5:36 PM Biochemical Oxygen Demand 3 1 mg/L E405.1 12/07/2006 3:40 PM Bromide 1.7 1 mg/L E320.1 12/22/2006 10:05 AM Chloride 111 5 mg/L E3252 12/07/2006 1:09 PM Chemical Oxygen Demand 53.8 1 mg/L E410.4 12/12/2006 12:34 PM Hardness (As CaCO3) 380 10 mg/L E130.2 12/15/2006 12:05 PM Nitrogen, Ammonia (As N) 31.9 20 mg/L E350.1 12/21/2006 11:20 AM Nitrate as N 6.68 10 mg/L E353.2 12/07/2006 3:39 PM Phenolics, Total Recoverable 10.5 1 pg/L E420.1 12/20/2006 11:15 AM Sulfate 108 5 mg/L SW9038 12/20/2006 1:56 PM Total Dissolved Solids 690 2 mg/L El 60.1 12/11/2006 4:06 PM Nitrogen, Kjeldahl, Total 46.3 20 mg/L E351.2 12/20/2006 12:03 PM Total Organic Carbon 19.5 1 mg/L SW9060 12/19/2006 3:21 AM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 12/28/2006 Page 10 of 13 Laboratory Manager M 00 O O I4 LC -1) L U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.28 U P 7440-70-2 Calcium 80100 P 7439189-6 Iron 93600 P 7439-92-1 Lead 2.2 B P 7439-95-4 Magnesium 24700 P 7439-96-5 Manganese 779 P 7440-09-7 Potassium 25800 P 7440-23-5 Sodium 32300 P EPA SAMPLE NO [--MW-BS SDG No.: TSL008 0612702-011 12/6/2006 Color Before: BROWN Clarity Before: CLOUDY Texture: Color After: YELLOW Clarity After: CLEAR Artifacts: Comments: Date Reported: 12/12/2006 FORM I - IN ILM04.1 O 04 O O N U2M I U%1 INC. 575 Broad Hollow Road, Mdvle NY 11747 LABORATORY RESULTS (631)6943040.FAY, (631)42M436 NYSDOHID#10478 Sample Information... Town of Southold Landfill Lab No. : 0612702-011 Type : Groundwater Origin: Attn To Original Client ID.: MW -8S Collected :1215/2006 2:15:00 PM Received :12/6/2006 4:50:00 PM Collected By VG03 Copies To :Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 390 10 mg/L E310.1 12/07/2006 5:44 PM Biochemical Oxygen Demand 8 1 mg/L E405.1 12/07/2006 3:45 PM Bromide 3.2 1 mglL E320.1 12/22/2006 10:10 AM Chloride 52.5 1 ing/L E325.2 12/07/2006 1:09 PM Chemical Oxygen Demand 66.3 1 mg/L E410.4 12/12/2006 12:35 PM Hardness (As CaCO3) • 320 20 mg/L E130.2 12/15/2006 12:10 PM Nitrogen, Ammonia (As N) 14.2 10 mg/L E350:1 12/21/2006 11:21 AM Nitrate as N < 0.10 1 mg/L E353.2 12/07/2006 3:40 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2006 11:30 AM . Sulfate 7.3 1 mg/L SW9038 12/20/2006 1:58 PM Total Dissolved Solids 407 1 mg/L E160.1 12/11/2006 4:08 PM Nitrogen, Kjeldahl, Total 21.0 20 mg1L E351.2 12/20/2006 12:04 PM Total Organic Carbon 20.6 1 mg/L SW9060 12/19/2006 3:51 AM Qualifies: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 12/28/2006 Page 11 of 13 Laboratory Manager U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET SOUTHHOLD 2 —I Lab Name: H2M LABS, INC. Contract: --, Lab Code: 10478. Case No. SAS No.: SDG No.: TSLOO8 Matrix (soil/water): WATER Lab Sample ID: 0612702-012 Level (low/med): LOW Date Received: 12/6/2006 % Solids: 0_0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.28 U P 7440-70-2 Calcium 77100 P 7439-89-6 Iron _ 6580 P 7439-92-1 Lead 1.5 U P 7439-95-4 Magnesium 34400 P 7439-96-5 Manganese 4120 P 7440-09-7 Potassium 132000 P 7440-23-5 Sodium 223000 P Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: CLEAR Comments: Date Reported: 12/12/2006 Texture: Artifacts: FORM I - IN ILMO4.1 U28t "US, INC. 575 Broad Hollow Road, MdAle NY 11747 LABORATORY RESULTS (631) 694-3040. FAY, (631)42M436 WSDOHID#10478 Town of Southold Landfill Lab No. : 0612702-012 Attn To Original Collected :12/6/2006 2:05:00 PM Received :12/6/2006 4:50:00 PM Collected By VG03 Copies To :Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID. : SOUTHHOLD 2 Sample Information... Type : Groundwater Origin: Results Qualifier D.F.. Units Method Number Analyzed 882 10 mg/L E310.1 12/07/2006 5:52 PM 5 1 mg/L E405.1 12/07/2006 3:50 PM 2.1 1 mg/L E320.1 12/22/2006 10:15 AM 244 10 mg/L E325.2 12/07/2006 1:10 PM 114. 1 mg/L E410.4 12/12/2006 12:36 PM 380 20 mg/L El 30.2 12/15/2006 12:15 PM 78.8 50 mg/L E350.1 12/21/2006 11:22 AM < 0.10 1 mg/L E353.2 12/07/2006 3:42 PM 8.0 1 pg/L E420.1 12/20/2006 11:45 AM 45.2 2.5 mg/L SW9038 12/20/2006 2:00 PM 1060 2 mg/L E160.1 12/11/20064:10 PM 116 100 mg/L E351.2 12/20/2006 4:08 PM 36.0 1 mg/L SW9060 12/19/2006 4:22 AM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 12/28/2006 Page 12 of 13 Laboratory Manager M 00 O O 1--i U.S. EPA - CLP ev._ % Solids: 0_0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 EPA SAMPLE NO M INORGANIC ANALYSIS DATA SHEET 0.28 FB Lab Name: H2M LABS, INC. Contract: 80.4 ' P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Matrix (soil/water): WATER Lab Sample ID: 0612702-013 T-1 (low/med)• LOW Date Received: 12/6/2006 ev._ % Solids: 0_0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.28 U P 7440-70-2 Calcium 80.4 B P 7439-89-6 Zron 10.5 U P -1 Lead 1.5 U P -4 Magnesium 15.5 B P g7439-96-5 Manganese 1.8 B P -7 Potassium 117 B P -5 Sodium 1581 B P Color Before: COLORLESS Clarity Before Color After: COLORLESS Clarity After: Comments: Date Reported: 12/12/2006 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 It V) 00 O' O V) H 1-2M "USs INC. 575 Brad HcBaN Road, MeWe W 11747 (631) 6943040. FAX(631)4208436 WSDOH1D#10478 Town of Southold Landfill Attn To Original Collected :12/6/2006 3:15:00 PM Received :12/6/2006 4:50:00 PM Collected By VG03 Copies To :Original Cc LABORATORY RESULTS Lab No. : 0612702-013 Client ID. : FB Sample Information... Type: Field Blank Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310.1 12/07/2006 6:00 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 12/07/2006 3:55 PM Bromide < 0.5 1 mg/L E320.1 12/22/2006 10:20 AM Chloride < 2.0 1 mg/L E325.2 12/07/2006 1:10 PM Chemical Oxygen Demand <10 1 mg/L E410.4 12/12/2006 12:37 PM Hardness (As CaCO3) < 5.0 1 mg/L E130.2 12/15/2006 12:20 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 12/21/2006 11:24 AM Nitrate as N < 0.10 1 mg/L E353.2 12/07/2006 3:43 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 12/20/2006 12:00 PM Sulfate < 5.0 1 mg/L SW9038 12/20/2006 2:02 PM Total Dissolved Solids <10 1 mg/L E160.1 12/11/2006 4:12 PM Nitrogen, Kjeldahl, Total < 0.10 1 mg/L E351.2 12/20/2006 12:05 PM Total Organic Carbon 1.3 1 mg/L SW9060 12/19/2006 4:53 AM Qualifiers: E - Value above quantitation range D -Results for Dilution D.F. = Dilution Factor Laboratory Manager Date Reported : 12/28/2006 Page 13 of 13 in 00 O �l 1 U2M "U%s INC, 5. DUPLICATE SAMPLE RESULTS 5.1 METALS 5.2 WET CHEMISTRY Lab Name: H2M LABS, INC. Lab Code: 10478 -Case No. Matrix (soil/water): WATER % Solids for Sample: 0.0 U.S. EPA - CLP 6 EPA SAMPLE NO DUPLICATES MW -5D Contract: SAS No.: SDG No.: TSL008 Level (low/med): LOW % Solids for Duplicate: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L Analyte Control Limit Sample (S) C Duplicate (D) C RPD i Q M Cadmium 5.0000 0.3500 1 B 0.2828 U 200.0 P Calcium 89011.1700 87939.1000 1.2 P Iron_ 1277.5200 1216.2200 4.9 P_ Lead3.0000 _ J 2.6013 B 2.62837 B 1.0 P Magnesium 62819.2400 62109.1000 1.1 P Manganese 11940.5800 11815.0000 1.11 P Potassium 138884.9300 138446.7600 0.3 P Sodium 194040.6900 191925.2900 1.1 P FORM VI - IN ILM04.1 00 O O r4 - V) H2M LABS, INC. Date: 28 -Dec -06 QC SUMMARY .REPORT SDG: TSL008 Biochemical Oxygen Demand < 2 mglL S-120706 LCS-120706 Biochemical Oxygen Demand Sample ID: Client Samnle ID: Analyte Result Units Spike Amount Sample Result %REC Recovery RPDRef %RPD Limits Value %RPD UCL MB -120706 MB -120706 JAIkalinity, Total (As CaCO3) <1 mg/L LCS-120706 LCS-120706 Alkalinity, Total (As CaCO3) 27.2 mg/L 25 < 1 109 80 120 J20 0612702-006DMS 0612702-006DDUP MW-5DMS MW-5DDUP Alkalinity, Total (As CaCO3) Alkalinity, Total (As CaCO3) 1300 778 mg/L mg/L 500 743 111 75 125 743 4.6 3-120706 MB -120706 Biochemical Oxygen Demand < 2 mglL S-120706 LCS-120706 Biochemical Oxygen Demand 169 mg1L 20p < 2 84 80 120 12702-006DDUP MW-5DDUP Biochemical Oxygen Demand 5 mg/L 12 82 0612702-006Ddup MW-5DDUP Bromide 5.7 mg/L 5.6 1.8 20 MB -122206 MB -122206 Bromide < 0.5 mg/L LCS-122206 LCS-122206 Bromide 4.8 mg/L 5 < 0.5 96 80 120 0612702-006Dms MW-122206 Bromide 10.4 mg/L 5 5.6 96 75 125 0612702-006Ddup MW-5DDUP Bromide 5.7 mg/L 5.6 1.8 20 MB -121206 MB -121206 Chemical Oxygen Demand 7 10 mglL LCS-121206 LCS-121206 Chemical Oxygen Demand 942 94 80 120 mg/L flJ000E94.0 0612702-006CMS 0612702-006CDUP MW -5D VIS MW-5DDUP Chemical Oxygen Demand Chemical Oxygen Demand 1040 109 mg/L 95 75 125 mg/L 94.0 14.8 20 MB -127006 MB -127006 Chloride <5 mg1L LCS-120706 LCS-120706 Chloride 1030 mg/L 50 < 2 95 80 120 0612702-006DMS MW-5DMS Chloride K276 mg/L 250 280 104 75 125 0612702-006DDUP MW-50DUP Chloride 520 mg/L 280 1.5 20 MB -121506 MB -121506 Hardness (As CaCO3) <5 mg/L LCS-121506 LCS-121506 Hardness (As CaCO3) 1030 mg/L 1000g520, 0612702-006Bms MW -5D AS Hardness (As CaCO3) 2660 mglL 2000 0612702-006Bdup MW-5DDUP Hardness (As CaCO3) 520 mg/L TSL008 S48 520 I 0 I QC SUMMARY REPORT SDG: TSL008 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB1-120706 MB1-120706 Nitrate as N < 0.1 mg/L LCS1-120706 LCS1-120706 Nitrate as N 1.17 mg/L 1.13 <0.1 104 80 120 0612702-006CMS MW-5DMS Nitrate as N 0.57 mg/L 0.5 < 0.1 114 75 125 0612702-006CDUP MW-5DDUP Nitrate as N < 0.1 mg/L < 0.1 20 MB -19212 MB -122106 Nitrogen, Ammonia (As N) < 0.1 mg/L LCS-19212 LCS-122106 Nitrogen, Ammonia (As N) 1.03 mg/L 1. < 0.1 103 80 120 0612702-006CMS MW-5DMS Nitrogen, Ammonia (As N) 62.7 mg/L 5 58.0 94 75 125 0612702-006CDUP MW-51DDUP Nitrogen, Ammonia (As N) 58.6 mg/L 58.0 1.1 20 MB -19244 MB -122306 Nitrogen, Kjeldahl, Total < 0.1 mg/L LCS-19244 LCS-122306 Nitrogen, Kjeldahl, Total 4.16 mg/L 4.1 < 0.1 101 80 120 0612702-006CMS MW-5DMS Nitrogen, Kjeldahl, Total 127 mg/L 41 92.0 85 75 125 0612702-006CDUP MW-5DDUP Nitrogen, Kjeldahl, Total 92.2 mg/L 92.0 0.22 20 MBl-19210 MB1-122006 Nitrogen, Kjeldahl, Total < 0.1 mg/L MB -19210 MB -122006 Nitrogen, Kjeldahl, Total < 0.1 mg/L LCS1-19210 LCS1-122006 Nitrogen, Kjeldahl, Total 4.10 mglL 4.1 < 0.1 100 80 120 LCS-19210 LCS-122006 Nitrogen, Kjeldahl, Total 4.52 mg/L 4.1 < 0.1 110 80 120 MB -122006 MB -122006 Phenolics, Total Recoverable < 5 ug/L LCS-12206 LCS-12206 Phenolics, Total Recoverable 28.2 ug/L 30 < 5 94 80 120 0612702-006CMS MW-5DMS Phenolics, Total Recoverable 18.5 ug/L 20 < 5 92 75 125 0612702-006Cdup MW-51DDUP Phenolics, Total Recoverable < 5 ug/L < 5 20 MB=122006 MB -122006 Sulfate <5 mg/L LCS-122006. LCS-122006 Sulfate 18.9 mg/L 20 < 5 94 80 120 0612702-006DMS MW-51DMS Sulfate 342 mg/L 200 142 100 75 125 0612702-006DDUP MW-5DDUP Sulfate 143 mg/L 142 0.70 20 TSL008 S49 QC SUMMARY REPORT SDG: TSL008 SpIKe Sample nec every mrL)nui 1.1— Result Units Amount Result %REC Limits Value %RPD UCL Sample ID: Client Sample ID• Analyte MB -121106 MB -121106 Total Dissolved Solids <10 mg/L LCS-121106 LCS-121106 Total Dissolved Solids 313 mg/L 300 <10 104 80 120 0612702-006DMS MW-5DMS Total Dissolved Solids 1860 mg/L 600 1230 105 75 125 0612702-006DDUP MW-5DDUP Total Dissolved Solids 1220 mg/L 1230 0.65 20 MB -121806 MB -121806 Total Organic Carbon < 1 mg/L LCS-121806 LCS-121806 Total Organic Carbon 24.6 mg/L 25 < 1 98 80 120 0612702-006AMS 0612702-006ADUP MW-5DMS MW-5DDUP Total Organic Carbon Total Organic Carbon 34.8 23.8 mg/L 10 24.4 104 75 125 mg/L 24.4 2.6 20 TSL008 S50 U2M "USs INC. 6. SPIKE SAMPLE RESULTS 6.1 METALS 6.2 WET CHEMISTRY ,--, kr) 00 0 0 v) N Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER % Solids for Sample: 0.0 U.S. EPA - CLP 5A SPIKE SAMPLE RECOVERY Contract- SAS No.: EPA SAMPLE NO MW -5 SS� SDG No.: TSL008 Level (low/med): LOW Concentration Units (ug/L or mg/kg dry weight): UG/L Comments: FORM V (Part 1) - IN ILM04.1 N 00 O O Control Limit Spiked Sample Sample Spike Analyte %R Result (SSR) C Result (SR) C Added (SA) %R Q M Cadmium Iron Lead Man anese 75-125 -T5-125 75-125 51.7300 2160.3900 22.9334 12259.4100 0.3500 1277.5200 2.6013 11940.5800 B 50.00 1000.00 B 20.00 500.00 102.8 _ 88.3 101.7 63.8 P_ P P P Comments: FORM V (Part 1) - IN ILM04.1 N 00 O O 112M LABS, INC. Date: 28 -Dec -06 QC SUMMARY REPORT SDG: TSLOO8 Spike Sample Recovery RPDRef %RPD Sample ID: _ Client Sample ID: Analvte Result Units Amount Result %REC Limits Value %RPD UCL MB -120706 MB -120706 Alkalinity, Total (As CaCO3) < 1 mg/L LCS-120706 LCS-120706 Alkalinity, Total (As CaCO3) 27.2 mg/L 25 < 1 109 80120 0612702-006DMS MW-5DMS Alkalinity, Total (As CaCO3) 1300 mg/L 500 743 111 75 125 0612702-006DDUP MW-5DDUP Alkalinity, Total (As CaCO3) 778 mg/L 743 4.6 20 1B-120706 MB -120706 Biochemical Oxygen Demand < 2 mg/L CS -120706 LCS-120706 Biochemical Oxygen Demand 169 mg/L 200 < 2 84 80 120 612702-006DDUP MW-5DDUP Biochemical Oxygen Demand 5 mg/L 12 82 20 MB -122206 MB -122206 Bromide < 0.5 mg/L LCS-122206 LCS-122206 Bromide 4.8 120 mg/L 5 < 0.595 L75 0612702-006Dms MW-5DMS Bromide 10.4 mg/L 5 5.6 96 125 0612702-006Ddup MW-5DDUP Bromide 5.7 mg1L 1 5.6 1.8 20 MB -121206 MB -121206 Chemical Oxygen Demand <10 mg/L LCS-121206 LCS-121206 Chemical Oxygen Demand 942 mg/L 1000 < 10 94 80 120 0612702-006CMS MW-5DMS Chemical Oxygen Demand 1040 mg/L 1000 94.0 95 75 125 0612702-006CDUP MW-51DDUP Chemical Oxygen Demand 109 mg/L 94.0 14.8 20 MB -127006 MB -127006 Chloride < 2 mg/L LCS-120706 LCS-120706 Chloride 47.3 mg/L50 < 2 95 80 120 0612702-006DMS MW-5DMS Chloride 539 mg/L 250 280 104 75 11251 0612702-006DDUP MW-5DDUP Chloride 276 mg/L I 1 1 280 1.5 20 MB -121506 MB -121506 Hardness (As CaCO3) < 5 mg/L LCS-121506 LCS-121506 Hardness (As CaCO3) 1030 mg/L 1000 < 5 103 80 120 0612702-006Bms MW-5DMS Hardness (As CaCO3) 2660 mg/L 2000 520 107 75 125 0612702-006Bdup MW-5DDUP Hardness (As CaCO3) 520 mg/L 520 0 20 1 TSL008 S53 QC SUMMARY REPORT SDG: TSL008 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB1-120706 MB1-120706 Nitrate as N < 0.1 mgn- LCS1-120706 LCS1-120706 Nitrate as N 1.17 mg/L 1.13 <0.1 104 80 120 0612702-006CMS MW-51DMS Nitrate as N 0.57 mg/L 0.5 < 0.1 114 75 125 0612702-006CDUP MW-5DDUP Nitrate as N < 0.1 mg/L < 0.1 20 MB -19212 MB -122106 Nitrogen, Ammonia (As N) < 0.1 mg/L LCS-19212 LCS-122106 Nitrogen, Ammonia (As N) 1.03 mg/L 1 < 0.1 103 80 120 0612702-006CMS MW-5DMS Nitrogen, Ammonia (As N) 62.7 mg/L 5 58.0 94 75 125 0612702-006CDUP MW-5DDUP Nitrogen, Ammonia (As N) 58.6 mg/L 58.0 1.1 20 MB -19244 MB -122306 Nitrogen, Kjeldahl, Total < 0.1 1 mg/L LCS-19244 LCS-122306 Nitrogen, Kjeldahl, Total 4.16 mg/L 4.1 < 0.1 101 80 120 0612702-006CMS MW-51DMS Nitrogen, Kjeldahl, Total 127 mg/L 41 92.0 85 75 125 0612702-006CDUP MW-5DDUP Nitrogen, Kjeldahl, Total 92.2 mg/L 92.0 0.22 20 MB1-19210 MBI -122006 Nitrogen, Kjeldahl, Total <0.1 mg/L MB -19210 MB -122006 Nitrogen, Kjeldahl, Total < 0.1 mg/L LCS1-19210 LCS1-122006 Nitrogen, Kjeldahl, Total 4.10 mg/L 4.1 < 0.1 100 80 120 LCS-19210 LCS-122006 Nitrogen, Kjeldahl, Total 4.52 , mg/L 4.1 < 0.1 110 80 120 MB -122006 MB -122006 Phenolics, Total Recoverable < 5 ug/L LCS-12206 LCS-12206 Phenolics, Total Recoverable 28.2 ug/L 30 < 5 94 80 120 0612702-006CMS MW-51DMS Phenolics, Total Recoverable 18,5 ug/L 20 < 5 92 75 125 0612702-006Cdup MW-5DDUP Phenolics, Total Recoverable < 5 ug/L < 5 20 MB -122006 MB -122006 Sulfate < 5 mg/L LCS-122006 LCS-122006 Sulfate 18.9 mg/L 20 < 5 94 80 120 0612702-006DMS MW-51DMS Sulfate 342 mg/L 200 142 100 75 125 0612702-006DDUP MW-5DDUP Sulfate 143 mg/L 142 0.70 20 TSL008 S54 QC SUMMARY REPORT SDG: TSL008 Spike Sample Recovery RPDRef %RPD Sample ID: Client Samnle ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -121106 MB -121106 Total Dissolved Solids < 10 mg/L LCS-121106 LCS-121106 Total Dissolved Solids 313 mg/L 300 <10 104 80 120 0612702-006DMS MW-5DMS Total Dissolved Solids 1860 mg/L 600 1230 105 75 125 0612702-006DDUP MW-5DDUP Total Dissolved Solids 1220 mg/L 1230 0.65 20 MB -121806 MB -121806 Total Organic Carbon < 1 mg/L LCS-121806 LCS-121806 Total Organic Carbon 24.6 mg/L 25 < 1 98 80 1201 1 0612702-006AMS MW-5DMS Total Organic Carbon 34.8 mg/L 10 24.4 104 75 125 0612702-006ADUP MW-5DDUP Total Organic Carbon 23.8 mg/L 24.4 2.6 20 TSL008 S55 U2M "13%, INC. 7. BLANK SUMMARY DATA AND RESULTS 7.1 METALS 7.2 WET CHEMISTRY 00 0 0 E-1 U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L Analyte Initial Calib. Blank (ug/L) Continuing Blank C 1 C Calibration (ug/L) 2 C 3 C Prepa- ration Blank C M Cadmium 0.3 B 0.4 B 0.3 U 0.4 B 0.283 U P Calcium 5.7 U 19.4 B 5.7 U 5.7 U 5.659 U P Iron 10.5 U 11.2 B 10.5 U 10.5 U 10.489 U P Lead 1.5 U 1.5 U 1.5 U 1.5 U 1.515 U P Magnesium 6.4 U 20.1 B 6.4 U 6.4 U 6.408 U P Manganese 0.4 U 0.4 U 0.4 U 0.6 B 0.394 U P Potassium 48.0 B 39.2 B 45.1 B 53.0 B 38.300 B P Sodium 11.4 B 7.3 B 17.7 B 20.0 B 5.899 U P FORM III - IN C/] 00 O O ILM04.1 U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL008 Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L `Analyte Initial Calib. Blank (ug/L) C Continuing Calibration Blank (ug/L) 1 C 2 C 3 C Prepa- ration Blank C M Cadmium 0.5 BI I I P Calcium 10.9 B P Iron 10.5 U' P Lead 1.5 U P Magnesium 14.8 B P Manganese 0.4 U P Potassium 46.2 B P Sodium 12.2 B P FORM III - IN ti 00 00 O O ILM04.1 H2M LABS, INC. Date: 28 -Dec -06 QC SUMMARY REPORT SDG: TSL008 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -120706 MB -120706 Alkalinity, Total (As CaCO3) < 1 mg/L LCS-120706 LCS-120706 Alkalinity, Total (As CaCO3) 27.2 mg/L 25 <1 109 80 1201 1 0612702-006DMS MW-5DMS Alkalinity, Total (As CaCO3) 1300 mg/L 500 743 111 75 125 0612702-006DDUP MW-5DDUP Alkalinity, Total (As CaCO3) 778 mg/L 743 4.6 20 AB -120706 MB -120706 Biochemical Oxygen Demand < 2 mg/L -CS-120706 LCS-120706 Biochemical Oxygen Demand 169 mg/L 200 < 2 84 80 120 )612702-006DDUP MW-5DDUP jBiochemical Oxygen Demand 5 mg/L 1 12 1 82 20 MB -122206 MB -122206 Bromide < 0.5 mg/L LCS-122206 LCS-122206 Bromide 4.8 mg/L 5 < 0.5 96 80 120 0612702-006Dms MW-5DMS Bromide 10.4 mg/L 5 5.6 96 75 125 0612702-006Ddup MW-5DDUP Bromide 5.7 mg/L 5.6 1.8 20 MB -121206 MB -121206 Chemical Oxygen Demand <10 mg/L LCS-121206 LCS-121206 Chemical Oxygen Demand 942 mg/L 1000 < 10 94 80 120 0612702-006CMS MW-5DMS' Chemical Oxygen Demand 1040 mg/L 1000 94.0 95 75 125 0612702-006CDUP MW-5DDUP Chemical Oxygen Demand 109 mg/L 94.0 14.8 20 MB -127006 MB -127006 Chloride < 2 mg/L LCS-120706 LCS-120706 Chloride 47.3 mg/L 50 < 2 95 80 120 0612702-006DMS MW-5DMS Chloride 539 mg/L 250 280 104 75 125 0612702-006DDUP MW-5DDUP Chloride 276 mg/L 280 1,5 20 MB -121506 MB -121506 Hardness (As CaCO3) <5 mg/L LCS-121506 LCS-121506 Hardness (As CaCO3) 1030 mg/L 1000 < 5 103 80 120 0612702-006Bms MW-5DMS Hardness (As CaCO3) 2660 mg/L 2000 520 107 75 125 0612702-006Bdup MW-5DDUP Hardness (As CaCO3) 520 mg/L 520 0 20 1 TSL008 S59 QC SUMMARY REPORT SDG: TSL008 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MBl-120706 MBI -120706 Nitrate as N < 0.1 mg/L LCS1-120706 LCS1-120706 Nitrate as N 1.17 mg/L 1.13 <0.1 104 80 120 0612702-006CMS MW-51DMS Nitrate as N 0.57 mg/L 0.5 < 0.1 114 75 125 0612702-006CDUP MW-5DDUP Nitrate as N < 0.1 mg/L < 0.1 20 MB -19212 MB -122106 Nitrogen, Ammonia (As N) < 0.1 mg/L LCS-19212 LCS-122106 Nitrogen, Ammonia (As N) 1.03 mg/L 1 < 0.1 103 80 120 0612702-006CMS MW-51DMS Nitrogen, Ammonia (As N) 62.7 mg/L 5 58.0 94 75 125 0612702-006CDUP MW-5DDUP Nitrogen, Ammonia (As N) 58.6 mg/L 58.0 1.1 20 MB -19244 MB -122306 Nitrogen, Kjeldahl, Total < 0.1 mg/L LCS-19244 LCS-122306 Nitrogen, Kjeldahl, Total 4.16 mg/L 4.1 < 0.1 101 80 120 0612702-006CMS MW-5DMS Nitrogen, Kjeldahl, Total 127 mg/L 41 92.0 85 75 125 0612702-006CDUP MW-5DDUP Nitrogen, Kjeldahl, Total 92.2 mg/L 192.0 0.22 20 MB1-19210 MBl-122006 Nitrogen, Kjeldahl, Total < 0.1 mg/L MB -19210 MB -122006 Nitrogen, Kjeldahl, Total < 0.1 mg/L LCS1-19210 LCS1-122006 Nitrogen, Kjeldahl, Total 4.10 mg/L 4.1 < 0.1 100 80 120 LCS-I9210 LCS-122006 Nitrogen, Kjeldahl, Total 4.52 mg/L 4.1 < 0.1 110 80 120 MB -122006 MB -122006 Phenolics, Total Recoverable < 5 ug/L LCS-12206 LCS-12206 Phenolics, Total Recoverable 28.2 ug/L 30 < 5 94 80 120 0612702-006CMS MW-5DMS Phenolics, Total Recoverable 18.5 ug/L 20 < 5 92 75 125 0612702-006Cdup MW-51DDUP Phenolics, Total Recoverable < 5 ug/L. < 5 20 MB -122006 MB -122006 Sulfate < 5 mg/L LCS-122006 LCS-122006 Sulfate 18.9 mg/L 20 < 5 94 80 120 0612702-006DMS MW-50MS Sulfate 342 mg/L 200 142 100 75 125 0612702-006DDUP MW-5DDUP Sulfate 143 mg/L 142 0.70 20 TSL008 S60 QC SUMMARY REPORT SDG: TSL008 Spike Sample Recovery RPDRef °/ RPD Sample ID• Client Sample ID: Analvte Result Units Amount Result %REC Limits Value %RPD UCL MB -121106 MB -121106 Total Dissolved Solids <10 mg/L LCS-121106 LCS-121106 Total Dissolved Solids 313 mg/L 300 <10 104 80 120 0612702-006DMS MW-5DMS Total Dissolved Solids 1860 mg1L 600 1230 105 75 125 0612702-006DDUP MW-5DDUP Total Dissolved Solids 1220 mg/L 1230 0.65 20 MB -121806 MB -121806 Total Organic Carbon < 1 mg/L LCS-121806 LCS-121806 Total Organic Carbon 24.6 mg/L 25 < 1 98 80 120 0612702-006AMS MW-5DMS Total Organic Carbon 34.8 mg/L 10 24.4 104 75 125 0612702-006ADUP MW-5DDUP Total Organic Carbon 23.8 mg/L 24.4 2.6 20 TSL008 S61