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HomeMy WebLinkAboutWet Chemistry Data Package 06/2006Analytical Data Package For TOWN OF SOUTHOLD PART 360 ROUTINE SDG NO: TSL006 Water Samples Received: 6/23/06 WET CHEMISTRY DATA PACKAGE JUNE 2006 !nV I AA I -AUS, IN C. ' Bnvironmental Testing Laboratories 575 Broad Hollow Road, Melville, N.Y. 11747 U2M ILAUSs INC. WET CHEMISTRY TABLE OF CONTENTS 1. SAMPLE REPORTS II. Q.C. SUMMARY Ill. RAW DATA 0 0 v2M LAUS4� INC. SAMPLE REPORTS U2/4 "U%s INC. 575 BroadHdlow Road, Mdvdle NY 11747 (631)694,3 -FAX(631)42M436 WSDOHID#10478 Town of Southold Landfill Attn To : George Desmadas Collected 6/22/2006 11:00:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC LABORATORY RESULTS Lab No. : 0606916-001 Client ID. : EQPT Sample Information... Type : Blank Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310.1 06/28/200611:25 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/23/2006 5:15 PM Bromide < 0.5 1 mg/L E320.1 07/11/200611:20 AM Chloride < 2.0 1 mg/L E325.2 06/29/2006 11:21 AM Chemical Oxygen Demand < 10 1 mg/L E410.4 07/03/2006 12:35 PM Hardness (As CaCO3) < 5.0 1 mg/L E130.2 07/11/2006 10:36 AM Nitrogen, Ammonia (As N) 0.12 1 mg/L E350.1 07/12/2006 9:34 AM Nitrate as N < 0.10 1 mg/L E353.2 06/27/2006 1:02 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 07/11/2006 8:30 AM Sulfate < 5.0 1 mg/L SW9038 07/10/2006 2:40 PM Total Dissolved Solids 13 1 mg/L E160.1 06/27/2006 4:28 PM Nitrogen, Kjeldahl, Total 0.73 1 mg/L E351.2 07/11/2006 11:00 AM Total Organic Carbon < 1.0 1 mg/L SW9060 07/06/2006 5:36 PM Qualifiers: E - Value above quantitation range D -Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 1 of 13 Laboratory Manager U2A "USS INC. 575 Broad Hdlom Road, Mme NY 11747 (631)M4-1040 - FAX (631)42H436 NYSDOH ID#10478 Town of Southold Landfill Attn To George Desmarias Collected 6/23/2006 11:30:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original Cc LABORATORY RESULTS Lab No. : 0606916-002 Client ID. : MW -1D Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 21.5 1 mg/L E310.1 06/28/2006 11:30 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/23/2006 5:20 PM Bromide < 0.5 1 mg/L E320.1 07/11/2006 11:30 AM Chloride 3.9 1 mg/L E325.2 06/29/2006 11:22 AM Chemical Oxygen Demand <10 1 mg/L E410.4 07/03/200612:36 PM Hardness (As CaCO3) < 5.0 1 mg/L E130.2 07/11/200610:39 AM Nitrogen, Ammonia (As N) 0.19 1 mg/L E350.1 07/12/2006 9:36 AM Nitrate as N < 0.10 1 mg/L E353.2 06/27/2006 1:28 PM Phenolics, Total Recoverable < 5.0 1 N9/L E420.1 07/11/2006 8:45 AM Sulfate 13.1 1 mg/L SW9038 07/10/2006 2:42 PM Total Dissolved Solids 77 1 mg/l- E160.1 06/27/2006 4:30 PM Nitrogen, Kjeldahl, Total 0.26 1 mg/L E351.2 07/11/2006 11:01 AM Total Organic Carbon . < 1.0 1 mg/L- SW9060 07/06/2006 6:07 PM Qualifiers: E - Value above quantilation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/1412006 Page 2 of 13 Q/1V" Laboratory Manager IN U2M "US, INC. 575 Broad Hdloav Road, Mdville NY 11747 (631)6N-3040. FAX (631)4W8436 NYSDOHID#10478 Town of Southold Landfill Attn To : George Desmarias Collected 6/23/2006 12:00:00 PM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC LABORATORY RESULTS Lab No. : 0606916-003 Client ID. : MW -1S Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310.1 06/28/2006 11:35 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/23/2006 5:25 PM Bromide < 0.5 1 mg/L E320.1 07/11/2006 11:40 AM Chloride 3.8 1 mg/L E325.2 06/29/2006 11:23 AM Chemical Oxygen Demand <10 1 mg/L E410.4 07/03/2006 12:37 PM Hardness (As CaCO3) < 5.0 1 mg/L E130.2 07/11/2006 10:42 AM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 07/12/2006 9:37 AM Nitrate as N < 0.10 1 mg/L E353.2 06/27/2006 1:30 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 07/11/2006 9:00 AM Sulfate 61.8 2.5 mg/L SW9038 07/10/2006 2:44 PM Total Dissolved Solids 125 1 mg/L E160.1 06/27/2006 4:32 PM Nitrogen, Kjeldahl, Total 0.56 1 mg/L E351.2 - 07/11/200611:01 AM Total Organic Carbon < 1.0 1 mg/L SW9060 07/06/2006 6:38 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 3 of 13 Laboratory Manager 1-2M "USS INC. 575 Broad H0l Nv Road, Metvile NY 11747 (631)x4-3010.FAX(631)420.84W NYSDOHID#10478 Town of Southold Landfill Attn To : George Desmarias Collected 6/23/2006 9:00:00 AM Received 6/23/20061:58:00 PM Collected By VG Copies To Original CC LABORATORY RESULTS Lab No. : 0606916-004 Client ID.: MW -3D Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 4.8 1 mg/L E310.1 06/28/2006 11:40 AM Biochemical Oxygen Demand 33 1 mg/L E405.1 06/23/2006 5:30 PM Bromide < 0.5 1 mg/L E320.1 07/11/2006 11:50 AM Chloride 4.4 1 mg/L E325.2 06/29/2006 11:23 AM Chemical Oxygen Demand 134 1 mg/L E410.4 07/03/2006 12:38 PM Hardness (As CaCO3) < 5.0 1 mg/L E130.2 07/11/2006 10:45 AM Nitrogen, Ammonia (As N) 0.14 1 mg/L E350.1 07/12/2006 9:38 AM Nitrate as N < 0.10 1 mg/L E353.2 06/27/2006 1:31 PM Phenolics, Total Recoverable 38.8 1 pg/L E420.1 07/11/2006 9:15 AM Sulfate < 5.0 1 mg/L SW9038 07/10/2006 2:46 PM Total Dissolved Solids 120 1 mg/L E160.1 06/27/2006 4:34 PM Nitrogen, Kjeldahl, Total 1.80 1 mg/L E351.2 07/11/2006 11:02 AM Total Organic Carbon < 1.0 1 mg/L SW9060 07/06/2006 7:09 PM Qualifiers: E -Value above quanlilalion range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 4 of 13 Laboratory Manager 1-2M I AUS' INC. 575Broad Hollow Road, Mdnlle NY 11747 (631)694- 0- FAX (631)420-84W NYSDOHID#10478 Town of Southold Landfill Attn To George Desmarias Collected 6/23/2006 8:30:00 AM Received 6/23/20061:58:00 PM Collected By VG Copies To Original CC LABORATORY RESULTS Lab No. : 0606916-005 Client ID.: MW -3S Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 31.0 1 mg/L E310.1 06/28/2006 11:45 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/23/2006 5:35 PM Bromide < 0.5 1 mg/L E320.1 07/11/2006 12:00 PM Chloride 3.9 1 mg/L E325.2 06/29/2006 11:24 AM Chemical Oxygen Demand <10 1 mg/L E410.4 07/03/2006 12:39 PM Hardness (As CaCO3) < 5.0 1 mg/L E130.2 07/11/2006 10:48 AM Nitrogen, Ammonia (As N) 0.15 1 mg/L E350.1 07/12/2006 9:39 AM Nitrate as N 0.10 1 mg/L E353.2 06/27/2006 1:35 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 07/11/2006 9:30 AM Sulfate < 5.0 1 mg/L SW9038 07/10/2006 2:48 PM Total Dissolved Solids 75 1 mg/L E160.1 06/27/2006 4:36 PM Nitrogen, Kjeldahl, Total 0.25 1 mg/L E351.2 07/11/200611:03 AM Total Organic Carbon < 1.0 1 mg/L SW9060 07/06/2006 7:37 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 5 of 13 Laboratory Manager U2/4 t-AUS.9 INC, 575BmadHdlwv Road, Melville NY 11747 LABORATORY RESULTS (631)634-3040. FAX (631)4202436 NYSDOH ID# 10478 Town of Southold Landfill Lab No. :0606916-006 Sample Information...Type : Groundwater Attn To George Desmarias Origin: Client ID. MW -4D Collected 6/22/2006 9:30:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 6.4 1 mg/L E310.1 06/28/2006 12:00 PM Biochemical Oxygen Demand est. 182 1 mg/L E405.1 06/23/2006 5:45 PM Bromide < 0.5 1, mg/L E320.1 07/11/200612:30 PM Chloride 4.2 1 mg/L E325.2 06/29/2006 11:26 AM Chemical Oxygen Demand 260 1 mg/L E410.4 07/03/2006 12:42 PM Hardness (As CaCO3) < 5.0 1 mg/L E130.2 07/11/2006 10:57 AM Nitrogen, Ammonia (As N) 0.28 1 mg/L E350.1 07/12/2006 9:43 AM Nitrate as N < 0.10 1 mg/L E353.2 06/27/2006 1:38 PM Phenolics, Total Recoverable 49.3 1 pg/L E420.1 07/11/2006 10:15 AM Sulfate < 5.0 1 mg/L SW9038 07/10/2006 2:54 PM Total Dissolved Solids 217 1 mg/L E160.1 06/27/2006 4:42 PM Nitrogen, Kjeldahl, Total 2.53 10 mg/L E351.2 07/11/2006 1:46 PM Total Organic Carbon 1.9 1 mg/L SW9060 07/06/2006 9:12 PM Qualifiers: E - Value ovequantitationrange D - ReResults for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Laboratory Manager Page 6 of 13 00 O U284 dA USS INC, 575 Broad Hdlow Road, Melville NY 11747 LABORATORY RESULTS (631)6X3040.FAX(631)42M436 NYSDOHID#10478 Town of Southold Landfill Lab No. : 0606916-007 Attn To George Desmarias Collected 6/22/2006 9:00:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID. : MW -4S Sample Information... Type: Groundwater Origin: Results Qualifier D.F.. Units Method Number Analyzed 32.6 1 mg/L E310.1 06/28/2006 12:05 PM 11 1 mg1L E405.1 06/23/2006 5:50 PM 0.6 1 mg/L E320.1 07/11/2006 12:40 PM 3.9 1 mg/L E325.2 06129/2006 11:27 AM 23.6 1 mg/L E410.4 07/03/2006 12:43 PM 5.0 1 mg/L E130.2 07/11/200611:00 AM 0.24 1 mg/L E350.1 07/12/2006 9:44 AM < 0.10 1 mg/L E353.2 06/27/2006 1:39 PM < 5.0 1 pg/L E420.1 07/11/2006 10:30 AM < 5.0 1 mg/L SW9038 07/10/2006 2:56 PM 75 1 mg/L E160.1 06/27/2006 4:44 PM 0.71 1 mg/L E351.2 07/11/2006 11:05 AM 1.7 1 mg/L SW9060 07/06/2006 9:43 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 .Page 7 of 13 Laboratory Manager ULA "USI -13 Isce 575 Bred Hdlow Road, MdWe NY 11747 (631)694-3610.FAX (631)42054W NYSDOHID#10478 Town of Southold Landfill Attn To George Desmarias Collected 6/22/2006 10:30:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC LABORATORY RESULTS Lab No. : 0606916-008 Client ID. : MW -5D Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310.1 06/28/2006 12:10 PM Biochemical Oxygen Demand 30 1 mg/L E405.1 06/23/2006 5:55 PM Bromide <0.5 1 mg/L. E320.1 07/111200612:50 PM Chloride 4.1 1 mg/L E325.2 06/29/2006 11:27 AM Chemical Oxygen Demand 21.1 1 mg/L E410.4 07/03/2006 12:44 PM Hardness (As CaCO3) < 5.0 1 mg/L E130.2 07/11/2006 11:03 AM Nitrogen, Ammonia (As N) 0.10 1 mg/L E350.1 07/12/2006 9:45 AM Nitrate as N < 0.10 1 mg/L E353.2 06/27/2006 1:41 PM Phenolics, Total Recoverable 7.6 1 pg/L E420.1 07/11/2006 10:45 AM Sulfate < 5.0 1 mg/L SW9038 07/10/2006 2:58 PM Total Dissolved Solids 115 1 mg/L E160.1 06/27/2006 4:46 PM Nitrogen, Kjeldahl, Total 0.50 1 mg/L E351.2 07/11/2006 11:06 AM Total Organic Carbon < 1.0 1 mg/L SW9060 07/06/2006 10:15 PM Qualifiers: E - Value above quantilation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 8 of 13 Laboratory Manager 1-12A "US, INC. 575 Broad Hdlow Road, Mdvile NY 11747 (631) BN -3040. FAX (631)42M436 NYSDOH ID# 10478 Town of Southold Landfill Attn To : George Desmarias Collected 6/22/2006 10:00:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC LABORATORY RESULTS Lab No. : 0606916-009 Client ID. : MW -5S Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 32.6 1 mg/L E310.1 06/28/2006 12:25 PM Biochemical Oxygen Demand 18 1 mg/L E405.1 06/23/2006 6:00 PM Bromide < 0.5 1 mg/L E320.1 07/11/2006 1:00 PM Chloride 4.0 1 mg/L E325.2 06/29/2006 11:29 AM Chemical Oxygen Demand 38.7 1 mg/L E410.4 07/03/2006 12:45 PM Hardness (As CaCO3) < 5.0 1 mg/L E130.2 07/11/2006 11:06 AM Nitrogen, Ammonia (As N) 0.38 1 mg/L E350.1 07/12/2006 9:51 AM Nitrate as N < 0.10 1 mg/L E353.2 06/27/2006 1:42 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 07/11/2006 11:00 AM Sulfate < 5.0 1 mg/L SW9038 07/10/2006 3:00 PM Total Dissolved Solids 70 1 mg/L E160.1 06/27/2006 4:48 PM Nitrogen, Kjeldahl, Total 1.15 1 mg/L E351.2 07/11/2006 11:08 AM Total Organic Carbon 1.8 1 mg/L SW9060 07/06/2006 11:47 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 9 of 13 C1/K� � i����rt�►tiJ Laboratory Manager U2M /ARSB INC. 515 Broad Haw Road, Mdvle NY 11747 (631)x4-3040. FAX (631)420-8436 NYSDOH ID# 10478 Town of Southold Landfill Attn To : George Desmarias Collected 6/23/2006 10:00:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC LABORATORY RESULTS Lab No. : 0606916-010 Client ID. : MW -61) Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310.1 06/28/2006 12:30 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/23/2006 6:05 PM Bromide < 0.5 1 mg/L E320.1 07/11/2006 1:10 PM Chloride 4.0 1 mg/L E325.2 06/29/200611:30 AM Chemical Oxygen Demand <10 1 mg/L E410.4 07/03/2006,12:46 PM Hardness (As CaCO3) 5.0 1 mg/L E130.2 07/11/2006 11:09 AM Nitrogen, Ammonia (As N) < 0,10 1 mg/L E350.1. 07/12/2006 9:52 AM Nitrate as N • < 0.10 1 mg/L E353.2 06/27/2006 1:43 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 07/11/2006 11:15 AM Sulfate 36.4 1 mg/L SW9038 07/10/2006 3:02 PM Total Dissolved Solids 82 1 mg/L E160.1 06/27/2006 4:50 PM Nitrogen, Kjeldahl, Total 0.16 1 mg/L E351.2 07/11/2006 11:09 AM Total Organic Carbon < 1.0 1 mg/L SW9060 07/07/2006 12:18 AM N i Qualifiers: E -Value above quantitation range awl, O D - Results for Dilution D.F. = Dilution Factor E Date Reported : 7/14/2006 Laboratory Manager Page 10 of 13 l 1-2M IAUSs INC. 575 Broad Hclkw Road, Mme NY 11747 LABORATORY RESULTS (631)�t-3040.FAX(631)42(184W WSDOHID#10478 Town of Southold Landfill Lab No. s 0606916-011 Sample Information...Type : Groundwater Attn To George Desmadas Origin: Client ID. : MW -6S Collected 6/23/2006 9:30:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 2.8 1 mg/L E310.1 06/28/2006 12:35 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/23/2006 6:10 PM Bromide < 0.5 1 mg/L E320.1 07/11/20061:20 PM Chloride 3.8 1 mg/L E325.2 06/29/2006 11:31 AM Chemical Oxygen Demand <10 1 mg/L E410.4 07/03/2006 12:47 PM Hardness (As CaCO3) < 5.0 1 mg/L E130.2 07/11/2006 11:12 AM Nitrogen, Ammonia (As N) 0.23 1 mg/L E350.1 07/12/2006 9:53 AM Nitrate as N < 0.10 1 mg/L E353.2 06/27/2006 1:44 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 07/11/2006 11:30 AM Sulfate 32.7 1 mg/L SW9038 07/10/2006 3:04 PM Total Dissolved Solids 78 1 mg/L E160.1 06/27/2006 4:52 PM Nitrogen, Kjeldahl, Total 0.23 1 mg/L E351.2 07/11/200611:09 AM Total Organic Carbon < 1.0 1 mg/L SW9060 07/07/200612:46 AM Qualifiers: E - Value above quantitation range D -Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Laboratory Manager Page 11 of 13 U2/4 "US, INC. 575 Broad Hollow Road, W& NY 11747 LABORATORY RESULTS (631)694-3040.FAX (631)4X.84W NYSDOHID#10478 Town of Southold Landfill Lab No. : 0606916-012 Attn To George Desmarias Collected 6/23/2006 10:30:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID. : MW -8D Sample Information... Type: Groundwater Origin: Results Qualifier D.F.. Units Method Number Analyzed < 1.0 1 mg/L E310.1 06/28/2006 12:40 PM 53 1 mg/L E405.1 06/23/2006 6:15 PM < 0.5 1 mg/L E320.1 07/11/2006 1:30 PM 4.5 1 mg/L E325.2 06/29/2006 11:32 AM 134 1 mg/L E410.4 07/03/2006 12:48 PM < 5.0 1 mg/L E130.2 07/11/2006 11:15 AM 0.36 1 mg/L E350.1 07/12/2006 9:54 AM < 0.10 1 mg/L E353.2 06/27/2006 1:45 PM 39.6 1 pg/L E420.1 07/11/20061.1:45 AM < 5.0 1 mg/L SW9038 07/10/2006 3:06 PM 174 1 mg/L E160.1 06/27/2006 4:54 PM 1.90 1 mg/L E351.2 07/11/2006 11:10 AM 1.1 1 mg/L SW9060 07/07/2006 1:20 AM Qualifiers: E - Value above quantitalion range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 12 of 13 Q/w". AL- d, / ju� Laboratory Manager U2/4 "UN, INC. 575 BroadHdloar Road, MdvL- NY 11747 LABORATORY RESULTS (631)x4-3090. FAX(631)420B436 NYSD0HID#10178 Town of Southold Landfill Lab No. : 0606916-013 Attn To George Desmarias Client ID. : MW -8S Collected 6/23/2006 11:00:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC Parameter(s) Results Qualifier D.F. Units Alkalinity, Total (As CaCO3) 21.4 1 mg/L Biochemical Oxygen Demand 2 1 mg/L Bromide < 0.5 1 mg/L Chloride 4.1 1 mg/L Chemical Oxygen Demand <10 1 mg/L Hardness (As CaCO3) 6.0 1 mg/L Nitrogen, Ammonia (As N) 0.38 1 mg/L Nitrate as N 0.12 1 mg/L Phenolics, Total Recoverable < 5.0 1 pg/L Sulfate 14.2 1 mg/L Total Dissolved Solids 67 1 mg/L Nitrogen, Kjeldahl, Total 0.13 1 mg/L Total Organic Carbon < 1.0 1 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. =Dilution Factor Date Reported : 7/14/2006 Page 13 of 13 Sample Information... Type: Groundwater Origin: Method Number Analyzed E310.1 06/28/2006 12:45 PM E405.1 06/23/2006 6:20 PM E320.1 07/11/2006 1:40 PM E325.2 06/29/200611:32 AM E410.4 07/03/2006 12:49 PM E130.2 07/11/2006 11:18 AM E350.1 07/12/2006 9:55 AM E353.2 06/27/2006 1:49 PM E420.1 07/11/2006 12:00 PM SW9038 07/10/2006 3:08 PM E 160.1 06/27/2006 4:56 PM E351.2 07/11/2006 11:11 AM SW9060 07/07/20061:51 AM � I r-1 O 1.4 Laboratory Manager i F 2A I AUS INC. II. Q.C. SUMMARY 112M LABS, INC. SDG: TSL006 Date: 12 -Jul -06 QC SUMMARY REPORT Spike Sample Recovery RPDRef %RPD _Sample ID: Client.Sawle ID: — Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -062806 MB -062806 Alkalinity, Total (As CaCO3) < 1 mglL < 5 103 80 120 < 5 106 75 125 0606916-0056dup --...-...._.._..--005EI-------.___..._._ MW-3SDUP ------ .._-_—__.... LCS-062806 LCS-062806 Alkalinity, Total (As CaCO3) 24.8 mg/L 25 < 1 99 80 120 0606916-005dms MW-3SMS Alkalinity, Total (As CaCO3) _--....._.__._._..... 57.3 - - mg/L -- — --- - - - 25 31.0 105 - 75 --- --- - - 125 0606916-005ddup MW-3SDUP Alkalinity, Total (As CaCO3) 31.8 mg/L 31.0 2.9 20 MB -062306 MB -062306 Biochemical Oxygen Demand < 2 j mglL - -- 20 < 5 103 80 120 < 5 106 75 125 0606916-0056dup --...-...._.._..--005EI-------.___..._._ MW-3SDUP ------ .._-_—__.... - �i -._.......:_.._-.__-------- -._ ... - - — ---- -- Oxygen — -- _ ---- Demand — - �00 < 2 - 104- ------�--- 80 120 - 06 69166 005DDUP - - �MW-3SDUP --- ---- Biochemical Oxygen Demand--- < 29 _ i mg/L ( < 2 IMB-071106 'MB -071106 jBromide < 0.5 1 mg/L - -- 20 < 5 103 80 120 < 5 106 75 125 0606916-0056dup --...-...._.._..--005EI-------.___..._._ MW-3SDUP ------ .._-_—__.... (Hardness (As CaCO3) -- --- ----- LCS-071106 0606916-005DMS ILCS-071106 MW-3SMS Bromide Bromide 14.7 1 5.5 1 mg/L r 5 I < 0.5 5 < 0.5 94 80 110 75 120 125 _...__._...._..._..._...__._._..._._.-...-_-__.._.___._..----... .......... _..--- ----------- ---...__..___..__------.---____.___-.-__.----_-_._-- 0606916-005CMS IMW-3SMS 0606916-005Ddup MW-3SDUP Bromide —� < 0.5 mg/L ( < 0.5 0606916-005CDUP MW-3SDUP - 20 MB -062806 ln-062806 --Chemical Oxygen Demand <10 -mg/L- 50 < 2 25 I 3.9 - ( - -- I'I 99 80 120 107 175 125 I- 3.9 5.1 - -- 20 < 5 103 80 120 < 5 106 75 125 0606916-0056dup --...-...._.._..--005EI-------.___..._._ MW-3SDUP ------ .._-_—__.... (Hardness (As CaCO3) -- --- ----- ILCS-062806 ILCS-062806 Chemical Oxygen Demand 998 mg/L 1000 < 10 100- 80 120 _...__._...._..._..._...__._._..._._.-...-_-__.._.___._..----... .......... _..--- ----------- ---...__..___..__------.---____.___-.-__.----_-_._-- 0606916-005CMS IMW-3SMS Chemical Oxygen Demand 993 I mg/L 1000 <10 99 75 125 0606916-005CDUP MW-3SDUP - Chemical Oxygen Demand <10 mg/L ! <10 20 ___-.____...._-__._.._.__..__._-__._._.__._____.--__.__._._.._ �MB-062906 LCS-062906 0606916-005DMS - ------- 0606916_005DDUP-IMW_3SDUP MB -062906 Chloride � <2 � mg lL LCS-062906 Chloride f 49.4 mg1L IMW-3SMS Chloride --_ I-30.6 -- mg/L ----- -- — __ -- Chloride j 3.7 mg/L 50 < 2 25 I 3.9 - ( - -- I'I 99 80 120 107 175 125 I- 3.9 5.1 - -- 20 MB -071106 LCS-071106 0606916-005Bms 1106 LCS-071106 MW-3SMS Hardness (As CaCO3) Hardness (As CaCO3) Hardness (As CaCO3) <5 m91L 11030 mg/L 106 I mg/L 1000 100 < 5 103 80 120 < 5 106 75 125 0606916-0056dup --...-...._.._..--005EI-------.___..._._ MW-3SDUP ------ .._-_—__.... (Hardness (As CaCO3) -- --- ----- < 5 mglL ---- ---- < 5 20 -.--- --- TSL006 W17 QC SUMMARY REPORT SDG: TSL006 Spike Sample Recovery RPDRef %RPD _-_Sample ID: _ _ Client Sample. ID_Analyte _ Result Units Amount Result %REC Limits Value %RPD UCL M6-062706 IMB-062706 Nitrate as N < 0.1 mg/L- mg/L I mg/L 30 I < 5 -- 97 80 120 1 LCS-17454 LCS-071206Nitrogen, LCS-062706 INitrate as N 1.14 mg/L 1.13 < 0.1 101 80 1120 1 0606916-005CMS MW-3SMS Nitrogen, Ammonia (As N) 0606916-005Cms MW-3SMS INitrate as N 0.52 I mg/L 0.5 1 0.10 1 83 , 75 1251 Nitrogen, Ammonia (As N) 0.15 mglL 0606916-005Cdup MW-3SDUP Nitrate as N < 0.1 mg/L 93 75 125 �_� 0.10 200 20 MB -17454 FM6-071206 Nitrogen, Ammonia (As N) 1 - mg/L mg/L I mg/L 30 I < 5 -- 97 80 120 1 LCS-17454 LCS-071206Nitrogen, Ammonia (As N) .<.O. 1.07 mg/L 1 -1--<-6.T-107 i 80 120 0606916-005CMS MW-3SMS Nitrogen, Ammonia (As N) 4.68 mg/L 5 0.15 91 175 125 0606916-005CDUP MW-3SDUP Nitrogen, Ammonia (As N) 0.15 mglL mg/L 4 1 0.15 0 20 M61 17453 IM61 071106 MB 17453 WB 071106 Nitrogen, Kjeldahl, Total Nitrogen, Kjeldahl, Total mg/L I mg/L 30 I < 5 -- 97 80 120 1 66 66._._._-___ 0-606916-005CMS ;MW-3—SM—SPh_e_nolics, TotalRecoverableRecoverable — --11- 9_.4 L < 5 97 25 � _ _ LCS17453 _ 71 106 - - - LCS1 17453 LC51-071106 - - - Nitrogen, Kjeldahl, Total Nitrogen, Kjeldahl, Total 4.75 4.89 mg/L mgll- 4.1 4.1 < 0.1 < 0.1 116 80 120 119 80 120 -- I - - - -- - - - 0606916-005CMS BMW-3SMS -- - --- Nitrogen, Kjeldahl, Total --- 4.05 mg/L 4 1 0 25 93 75 125 10606916-OOSCDUP MW-3SDUP 6091-- ----- - - - - - - ----- � Nitrogen, Kjeldahl, Total j -- _-- < 0.1 mglL --- ? 0.25 L-- - -i----- 200 200J 20, 20 MB-071106 (Phenolics, Total Recoverable < 5 uglL !._.. _-07116666...66 66 _ -666 666 66-._ _...__-.- ---d- _- LCS-071106 jLCS-071106 •Phenolics, Total Recoverable 29.1 ug/L - _------__. 30 I < 5 -- 97 80 120 1 66 66._._._-___ 0-606916-005CMS ;MW-3—SM—SPh_e_nolics, TotalRecoverableRecoverable — --11- 9_.4 L < 5 97 25 � --ug 0606916-005CduP ;MW-3SDUP IPhenolics, Total Recoverable <5 u /L --2606 _7_5 5 MB -071006 MB -071006 Sulfate < 5 mg1L - -- ----------------6666-- -- .._...._._.. - - - ..._..-- --_ _. . _._._.6666- --- 6666 ---- --------!-- LCS-071006 -- - LCS-071006 Sulfate 19.7 mg/L 20 < 5 98 j 80 120 -- -- - ----._.._-..— - - ----.._.. -- 0606916-005DMS MW-3SMS Sulfate 19.8 mg/L 20 < 5 99 75 1 125 {-_--� 6666 - - --- -- -- - - - 0606916-005Ddup �MW-3SDUP Sulfate - < 5 �mg/L I I < 5 20 1 2 TSL006 W18 QC SUMMARY REPORT SDG: TSL006 Spike Sample Recovery RPDRef %RPD .._Sa_mple ID: —_ — Client Sample IDS_ _ Analyte — Result Units Amount Result %REC Limits Value %RPD UCL MB -062706 MB-062706Total Dissolved Solids < 10 mg/L — -_i mg/L mg/L mglL mglL { ---�—�- -�-- 89 1 80 120 95 ! 75 125 - < 1 20 LCS-062706 ILCS-062706 Total Dissolved Solids 298 mg/L 300 < 10 99 80 120 7 0606916-005DMS !MW-3SMS ITotal Dissolved Solids ` 389 mg/L 0606916-005DDUP iMW-3SDUP Total Dissolved Solids 73 mg/L 300 75 I 105 175 125 1 —j 75 2.7 20 MB -070606 — --- — SMB-070606!Total Organic Carbon - - - _ -1 < j LCS-070606 ICS -070606 Total Organic Carbon 22.3 0606916-00MS !MW-3SMS Total Organic Carbon 9.5 5A ------ A -- ... -- - ----- -- - - - ---- —� — 0606916-005ADUP MW-3SDUP Total Organic Carbon < 1 mg/L mg/L mglL mglL — - 25 <1 10 ! < 1 ---- ---�—�- -�-- 89 1 80 120 95 ! 75 125 - < 1 20 TSL006 W19 1-12M UAUS4� INC. III. RAW DATA CODES FOR MANUAL CORRECTIONS T: Transcription error. CE: Calculation error CC: Changed per client request SC: Sample cancelled LB: Wrong spot in logbook The following codes are specific to chromatography: GC / IC: MS (Match standard): The integration of the continuous calibration or the sample was different from that used for the initial calibration, e.g. more or less of the tail was included. BL Baseline): Incorrect integration due to changing baseline (rise or fall). NP (Negative peak): Due to a negative displacement in the baseline, wrong areas were integrated, which usually are too high. FP (Fused peak): A contamination is not resolved from the peak that is eluting in the retention time window and is included in the area. Areas are allocated for the two (or more) unresolved peaks in the manual integration. WB (Wrong basepoint): The start or finish of the peak ("basepoint") was put too high or too low, and the basepoint is corrected to match to projected baseline. R (RiderLThe peak is riding on a larger contamination, and is reintegrated as a rider. GC -MS: MP: Missed peak MIP: Misintegrated peak WI: Wrong isomer TI: Total of isomers TSL006 W22 cg�say� PS z1 LA ZXL., Vmss t I-ce 19 ITALK low '0606910-004f 100 6/28/2006 11:14:54 7.19 35.58 4119 0..57 350.10 062106 -TS -016 AM* 20 ITALK-low 060691.0-005f 50 6/281200611:24:28 7.16 18.61 4.15- 0:44''" 363:40 0622067S -017 AM 21 TALK low 0606910-006f .50 6128120061'1:33:54 7:28* 15.54 4.16 304010 062206-T87018. AM, 22 TALK,lbW 0606910-007f 50 6/28/2006 11:43-36 7:41- 13.32 4..-17 :9.33.- 259.-9.0. 062206=,T8,:61'5;' Am 23 TALK: low W�" 25 rn�/l 1.00 6/2812006-1:1:53-30 J10.04: 2.78 4;17:'':. 0,20.1 UZU 103.2 24 TALK16W lfbd tv=.25. mg/1'-100 6/28/2006112,0645' 9;98 2.75 25�55R R Dr 25 TALK low c tv= 25 �nd/l. 7 cv : : .1 ob 6/2812006'12:19� 9': ..4 9. -94 2;76 '411 0. -26:: 25:00 :1001- PM 26 TALK:IoW ccb 100-' '6/28/2006;'12:32:27' 5,.:82.-, 0.21 0,-19* 271 TALK low 0606916-001d. 1.00 6/28/200612737:12 5.69 0.20 4.,14 0:24 =035'.:..' EQPT P 28 TALK;low 0606916-002d.NW- 100 6:81 2;35 420' 16/28/200612.42f09' '0`20' 29 :TALK low 0606916m003cl MW.- :10.0 6 12 50; `55 3.55 0.00 3.53': O.OG- - 0*00' 18 PRI 30 TALK 16W 060691-6,004dm'MW= 100 6/28/200612:53:72 5.63- 0.82: P.34- 4,85- Z P 31 TALK low 0606916-005d MW- 100 6/28/2006-12-58:21 7.22 3.32 4- 0&.231-* 30;05 3S PM 32 TALK low 0606916-005dms 100 6/28/2006 1:07:23 PM 9.29 5.97 4.15 0.24 57.30 105.4 MW-3Sltv= 25 mg/l 33 TALK low 0606916-005,ddup 100 612812006 1:19:52 PM 7.12 3.38 4;17 0.20 31.85 RPD= MW -3s 2.8% M TTAL'UdW 0606916 `006d 100` 6/28!2006 1X29 13Dxh 0.: 4 35 TALK low' iI06069166'007dI':MW7j.1.00 6/2872006 1 0 4. 07.PM 7382: 3:48' 4.177 .02 4. AT -f - -7 1.9 3 0606916 0.08d 01 6,2 3B 4 3&- TALK low" M �54-' TSL006 W23 UM Lkc e— 7I13Io(o 37 ALK low ccv tv=25 mg/I 100 6/28/2006'1:47:15 PM 9.89 2.74 4.19. 0.19 25.55 102.2 38 TAL' IS low ccb 1.00`" 6/28/2006 2:00 3wipm. 15;75 1 Q.20 :.4.14 39 ALK=low 0606916=009d ':MW- 55... 100 6/28/2006 2 05:3 M 7:37 3:50' ...... 4 17. `" 0 24 `. 32:65' 53 TALK low 40 TALK'low 06069.16=0104 :MVV 1'00 6/28/2006 2;15 49 PM 4;52 0:04 417 0:22 =1;80 7 2T : " 8.45 ALK low 0606916-0134 MW 100. 6/281200&2:27 36 PM 6;93 234 419 0:20 21.45 41 TALK low 0606916-011d MW 1700 6/28/2006 &19 20 PM 5.92 0:50 4.17 0:22 2;85 W40 408 40 ' 86 6S.. 0606949:001 i 100 6/28/20062=3,6 41 PM 664 5 88 4 20 0:53 53 55` 42 TALK low 0606916=012d •MW 100 6!28%2006 2'25 13 PM ; :cv tv= 25mg/I 1:00 45 47 8D 48 TALK low 93 TALK low 0 00 3 90 0 00 0.0 53 TALK low 54 TALK low 17<88 419 :.. 293:80 ' )606949 006r 25 G 7 2T : " 8.45 ALK low 0606916-0134 MW 100. 6/281200&2:27 36 PM 6;93 234 419 0:20 21.45 8S. )606949 006ims 25 6/2872006 3 2045 PPM8 42 0 61 4 17 W40 408 40 ' 86 ALK low 0606949:001 i 100 6/28/20062=3,6 41 PM 664 5 88 4 20 0:53 53 55` 062306 031 •. ; :cv tv= 25mg/I 1:00 6/28/2006'3:32`37 PW 9.90 ACK low .... 0606949-002i 25 F 6/2812006 2 44 16 PM 7 01 :cb 100 6/28/2006 3:45`42'P,M..: 5;55' 0:17 4:.18. 47 TALK low 48 TALK low 49 TALK low 50 TALK low 51. 52 TALK -low TALK low 53 TALK low 54 TALK low TSL006 W24 )62306.'03 2 S 4.18 Oz32 365.40 )606949`0031 Yb 3M 033 50 '" 6/2872006 2 52 53 PM 7.10 17<88 419 319 293:80 ' )606949 006r 25 6!28/2006 3 11 29 P.,M 7 2T : " 8.45 414 0 39 322 40 )606949 006ims 25 6/2872006 3 2045 PPM8 42 0 61 4 17 W40 408 40 ' 86 ).'62306 '03*11'00 :cv tv= 25mg/I 1:00 6/28/2006'3:32`37 PW 9.90 2.76 4:17 02.1 25:50 102 :cb 100 6/28/2006 3:45`42'P,M..: 5;55' 0:17 4:.18. 0::18;` <1. 1606949 0061duq: 25 6/28/2006 3:50 09 PM 727 8:14 4 18: 0.2 6 31:1.2 RPD= 162306 037 350 '6065497.0071 100 6/2872006 3 59 28 PM_ 7 16 6 05 413 0 43 56x20 049"0 V 5C);-,-6/28/2006 4 09 01 PM 7 87 416 U34'. 1',91 DO 62305 039 606949 0091 50 6/28/2006 419 47 PM 7 29 16{95 4' 19c 0x5,13 328 80 62306, 040 /� Ie,' 142s,—�5 Ifil FAR, M-1 MIRURTIM"I, 55 TALK low 0606949-011 i 682306-'042 25 -6-/-28/2006 4:29:0.2 PM .7.18 14.16 420 313 441.40 56 TALK -IoW 0806949-012i' 062,06'-3.,. Q4 50 6/28/20065:04: P9:PM' : 8.07 1.9.22 4.20 2.:08 342-.80 57 TALK low 0606949-013i EB;-, 45328-7062306 100 6/28/2006-5:32:17 PM.*- 6.62 038 0:.21 1.70' 58 TALKIbW 06069.95-001:a 50: 6128/2006'6;37 59RM 7.28.'- 3.08 :4118. 56 50 59 TALK;l6w dcv tv=:25rii /110D 6/28/2006 5:47.20 PM 9. :Z77 4.14 O -2z 5' Oz. -2- 60 TALK -16W ccb100 6 12812006-8;0,1.3PVM* 5.72%` 0.18- 4-1 0;17 <1 TSL006 W25 .:Smf ,,,. an-MIL"i:ffi°d.&9 � � �, SxA sI f ,a8 . ��,"3� 1 III 16s'�M_ � �c�,.v°.'■ _. ■ ~— �..._.._i _ __.,... _ _ ■ l 1 U2A LABS, INC. 1 011 BOD5 ANALYST: Tn6b G6 CALIBRATION CHECK: •N , WINKLER OUT DATE IN: METER DATE OUT: d(; STANDARD DUPLICATE �/ mL TRUE VALUE 26rb SAMPLE # - r RESULT 6 RESULT Z- 2� % RECOVERY / S DUPLICATE G Z RPD L Lr�b H Ad'.: AVGZlijf'% H Ad'.: 3 -Y �7 ZZ AVG �d LAB# Chlorine m /L BOD LAB#!'jrpQ �16dDJ� Chlorine m /L C.' BOD DO -SC SOD % SAMP. DOr DOF ADO S.C. DO -SC BOD % SAMP. DOS DOF ADO /0 ( ` �O. VVVJJJ 6-7 w AVG ti.Ll� 511 -- --&IZ3 - Ges V 1 011 511 -- --&IZ3 - Ges V )3~ 1 011 )3~ U2M "US ,NC• BODS CALIBRATION CHECK: IN ANALYST: WINKLER DATE IN: METER -� DATE OUT: DUPLICATE m _ STANDARD f= TRUE VALUE SAMPLE # RESULT RE % RECOVERY .D LIGATE RPD H Ad'.: -'717.3f AVG I D LAB#o60je5_ GN/c LAB#e 6Va K LAB# D646�'19-� I oma- . syd- LAB# A OUT p®3� R L��. F2M LABS, INC. BOD5 ANALYST: CALIBRATION CHECK: fIN DATE IN: WINKLER DATE OUT:Z METER STANDARD DUPLIC E' TRUE VALUE SAMPLE # RESULT -,-'RESULT % RECOVERY .f " DUPLICATE fes. RPD J I LAB# OWN Chlorine- BOD f - mL = ML 13 . . ,•,, , %rye/ . . AVG :.. Y 0035 - a 4Gy 0 turd rt? S V iy''4 st Li U2M "US INC. BOD5 ANALYST: DATE IN: DATE OUT: STANDARD DUPLIC TRUE VALUE SA # RESULT SULT RECOVERY DUPLICATE g, ,��, RPD I . e... ••D BOD �r�a�s�v■���r��.� g, ,��, � • �r�®rte 141, ;• 0 • , A,p . e... ••D BOD g, ,��, � • �r�®rte 141, ;• 0 • , A,p . e... ••D g, ,��, � • �r�®rte mow_ 6Z) MW -GS LAB# C % SAMP. CALIBRATION CHECK: IN WI4 3 METER { ML H Ad'.: AVG Chlorine m / BOD GZ DOF I ADO S. DO -SC BOD P 0040 IH24 W13�, INC. ANALYST: J DATE IN: DATE OUT: ' L O6 (y 1'�. 9D LAB# ,�'-A2 BODS CALIBRATION CHECK: IN WINKLER METER mL = mI H2M LABS, INC. G Br (mg/L) = 13,320 x A x B Ll C B & E =Normality of Titrant= 0.0075 N BROMIDE. DATE: ANALYST: H A =Asp — ABLAW _ D x E D = DSAWLE - DBLAW F As, mL DBS = 1.Lf M, MLS OF 0.0075N Na2S,O, LAB. # CLIENT ID MLS USED TITRATED FOR + BR IODIDE DIFFERENCE RESULT IODIDE ICV 5.0 mg/L C& F v As u .1 DS.LE G- H MG/L ICB q 00o3s L 1 �. 66a6�16_� 2. 1-2. a - WOW 40 -' SA o . ordlo iSG �� c ' 1-000015o GO- 3. — cri �0 w-- 110 Mw --1 .� a. .q "L Q . tscodvav co -S —cfi40 s. Mw- 20 �(uIs _0W0 7. �s® .� ! l 470041V S - t o -G - 9000 1 B. 0 9. X10 3.7 � i , - WC) CCV 5.0 mg/L .3 U Cp CCB a 0CV70Uy 40- 1. -2 2 6611 1I -0106 PAW -Go 3 , Q p C_0 o c 1� 3: ��v-GS 3 0 ! 1- o . a� cr . � o `co 4. J MW-�� 0 - ) -0000 yj 0 . o� AJO TT v - 6. 7. 8. 9. ZE 10. CCV 5.0 mg/L FB 7' �* 1T,/, �J y_ 4"j, �� g16(0 Author: bnk • Original Run Filename: Original Run Author's Signature: Current Run Filename: Current Run Author's Signature: Description: H2M Lab: OM_6-29-2006_11-13-0 [bnk] CL062906.omn last mod [bnk] Default New Run Inc. Date : 6/29/2006 created 6/29/2006 11:13:08 AM 6/29/200611:47:05 AM coLozz/TSLo&b Sample Cup No. Channell chloride .. Conc. (m /L) 1 iArea ADF I(vs) MDF CalStd 6:ical6:cl dw S1 100.000 119.806 CalStd 5:ical5:cl dw S2 75.000 116.281 CalStd 4:ical4:cl dw, S3 50.000 111.956 CalStd 3:ical3:cl dw S4 20.000 1 5.716 CalStd 2:ical2.cl dw S5 10.000 2.998 O q3 CalStd 1:icall:cl dw S6 2.000 1 0.766 CalStd O:icalO:cl dw S16 -0.000 0.046 CRA:CRA:CL dw 60 2:216 1 0.756 Known Conc: 2:000 Calibration: Table/Fi 1 LCS-062906:LCS:CL dw 1 59 491374 111.865 Known Conc: 50.000 1 MB-062906:MBLK:CL dw S16 -0.072 1-0.022 Known Conc: 0.000 "0606916-001 D:SAMP:CL W" 1 0.142 0.053 "0606916-002D:SAMP:CL W" 2 3.860 1.288 "0606916-003D:SAMP:CL W" 3 3.790 1 1.266 "0606916-004D:SAMP:CL W" 4 4.376 1.451 "0606916-005D:SAMP:CL W" 5 3.918 1.306 "0606916-005DMS:MS:CL W" 6 30.552 8.140 "0606916-005DDUP:DUP:CL W" 7 3.724 1 1.245 "0606916-006D:SAMP:CL W° 8 4.157 1 1.382 1 "0606916-007D:SAMP:CL W" 9 3.908 1.303 "0606916-008D:SAMP:CL W" 10 4.081 1.358 CCV:CCV:CL DW S2 75.541 116.268 Known Conc: '75.000 1 CCB:CCB:CL DW S16 '0.126 10.0471 Known Conc: 0.000 "0606916-009D:SAMP:CL W" 11 3.971 11.323 "0606916-01OD:SAMP:CL W" 12 3.964 11.321 "0606916-011 D:SAMP:CL W' 13 3.839 1.281 "0606916-012D:SAMP:CL W' 14 4.513 11.494 "0606916-0131):SAMP:CL W" 15 4:086 1.360 "0606949-0011:SAMP:CL W" 16 66.465 14.820 "0606949-0021:SAMP:CL W" 17 14.384 14.315 "0606949-0031:SAMP:CL W"1 18 21.375 16.063 "0606949-0061:SAMP:CL W" 1 19 34.939 19.064 "0606949-0061MS:MS:CL W" 20 61.930 14.067 f CCV:CCV:CL DW S2 75.753 16.301 Known Conc: 75.000 1 CCB:CCB:CL DWF S16 0.118 110.045 Known Conc: 0.000 1 "0606949-0061DUP:DUP:CL W" 21 35.094 19.096 "0606949-0071:SAMP:CL W" 22 77.686 16.600 1 "0606949-0081:SAMP:CL W' 23 7:513 12.406 "0606949-0091:SAMP:CL W" 24 34.623 18.999 "0606949-0111:SAMP:CL W" 25 54.792 12.838 "0606949-0121:SAMP:CL W" 26 3.368 11.131 "0606949-0131:SAMP:CL W" 27 0.129 10.0481 t CCV:CCV:CL DW S2 76.138 16.361 F Known Conc: 75:000 1 CCB:CCB:CL DW S16 0.124 10.047 Known Conc: I 0.000 Run: CLO62906 I f eG • .2.. c SS LS J �S 032 C33 e37 Ze�iet6/c -2•G X3`6 c 3`j E't 0 8-4.r3zFr-GbZ 30( O q3 2c- io2%. -z•o Author: bnk Analyte Properties Table for CL062906.omn Property Channell chloride Concentration Units m /L Callibration Fit Type Second Order Clear Calibration True Force Through Zero False Calibration Weighting None Auto Dilution Trigger True % of High Standard 100 Quik Chem Method Chemist Direct/Bipolar Calibration by Height False Inject to Peak Start 4 Peak Base Width 34 Channel 1: Set 1 of 3 H21VI :Labs. Inc. 3.895 :2 U) U' m 75.00, A ig/L v U ro3 U -050.001ut g/L � U U vt a 20.00t2,g/L= II10.00(cotg/h I I 2.000 4?,]/L 2 0.984 --- 85.5 Run: CL062906 Date : 6/2912006 Time (s) I -2- 918.9 L U CZ) a) CO N O uj J p 49.374 mg/L §: U JI U JI U JI U -t Um (0 JI U JI U �I U ti30.55:a n: a a a o p n -,,/I< a a X D 0 p U)i O uai. M o 0 0 0 0 0 0 0 0 2 6i o q CD (0 D W CO CO M U:� CO M NCD C, ('D C) o Cl) - o O m o - o O - o O m - o O - 0 - /L m o 33..8603.7904.3763.91 / __ mg/L l 0.0720.1421Q/U\ I rig P i I l �24 �flI��f 708.4.081 �� Time (s) I -2- 918.9 Author: bnk Channel 1: Set 2 of 3 3.895 T U U 2 0 0.984 -F- 918.9 Channel 1: Set 3 of 3 3.895 -,- N O 0.984 -1- 1751.8 Run: CL062906 H2M Labs.l Inc. Date : 6/29/2006 0 M v rn m 0- (D CO, 3.368 mg/L 1751.8 2584.7 �_ IL rn U =a U o nU o 2 tD m 75.753 mg/LS ' 77.686 /lam 9 mQ < o O o rn 61.9 rig/L 0 0 V I , I v ,1 � � 54.792 mg/L 0 M v rn m 0- (D CO, 3.368 mg/L 1751.8 2584.7 Author: bnk Table 1: chloride 1-12M Labs. Inc. Date : 6/29/2006 Figure 1: chloride 19.80 Area = - 0.001 * Conc^2 + 0.278 * Conc + 0.227 Conc = 0.109 * Area^2 + 2.864 * Area - 0.010 ZCorrelation Coefficient (r) = 0.99981 5D No Weighting CU a� chloride concentration, mg/L 100.000 Conc. (mg/L) I Rep Peak Area (Volt -s) Pel ak Height (Volts) % Residual Detection Date Detection Time 1 100.000 1 19.806 2.510 -0.4 6/29/2006 11:15:12 AM 2 75.000 1 16.281 2.118 0.8 6/29/2006 11:15:54 AM 3 50.000 1 11.956 1.571 0.8 6/29/2006 11:16:35 AM 4 20,000 1 5.7161 1 0.776 -4.8 6/29/2006 11:17:17 AM 5 10.000 1 2.9981 1 0.406 -2.5 6/29/2006 11:17:59 AM 6 2.000 1 0.7661 1 0.102 1.7 6/29/2006 11:18:41 AM 7 0.000 1 0.0461 1 0.006 6/29/2006 11:19:25 AM Figure 1: chloride 19.80 Area = - 0.001 * Conc^2 + 0.278 * Conc + 0.227 Conc = 0.109 * Area^2 + 2.864 * Area - 0.010 ZCorrelation Coefficient (r) = 0.99981 5D No Weighting CU a� chloride concentration, mg/L 100.000 w U2AA I -AUS, INC. COD Analyst :fAA) Date: &Z Start time: zz CLIENT®®�� SAMPLE ID DOOMG/I) 0../.,. 1 - mm" • 4�'' /.�.,• , ® I Iii �� Mm �110 fill" ■ I �010 • Ma ® �_� fill, 71 U2M ILAUSs INC. a kBs. DILUTIONS MG/L NOTES 607 Wo 13 X2, oz J L /0 )o 4 o q3 2- q fl. 5z Do Z/O v Z, QA- - GID /0 b cis O O 72 Calibration 12/2912005 conc abs 10 0.007 25 0.011 50 0.018 125 0.06 250 0.109 375 0.158 600 0.209 625 0.263 750 0.303 875 0.345 1000 0.396, Intercept (b) 41.624 slope (m) 2514 0.9992 Pogo 1 of Mir I I HARDNESS= B x N x 100,000 A CGCG G NESS 5 locn6 c'? DATE: ANALYST: TITRANT —N CLIENT ID LAB# MLS US1715--F—MLS, MG/I, NOTES A () TITRATED B ICV(l 000 mg/1) fo,30 /0 z� ICB -31. <5 41Z -1b 062 - 100 3. 00 4. 1�iv-3D 00W lo /> 3 5. C-CS483 iao 0- IL/ & 0- ptsloa 6 lot WX1 7. [Al .04-100 lv\- s 6 ? 9 "13 i0o- f <ss 10. -SD - 6,ocli5 foz-> a , 'PL- CC'V(j 000 mg/1) l0i3_163,� (b 3;,;5 CCB too 0.3 )6- 2. tv oleo 01W -ES 6116 iop- 4. ur V'b WQ U) -9,5 -.16h o-� 6. O�O 7bFYq - go t F 100 0.1)- 9-0 T'l G© 003r �o S 1-75 3-0 3.3 40 5 )o CCV(I 000 mg/1) Ito L lo,5 jo 3,? CCB t(747 0022 AM. u2A IAUS.. -) INC* HARDNESS= B x N x 100,000 A NESS DATE: ANALYST: TITRANT = Dz-',( N CLIENT ID LAB# MLS USE (A) MLS. TITRATED TPn M) MG/L NOTES ICV(l 000 mg/1) JCB 1. Ol'-029?d -000�. 1), 170 0= P'n 3. RPVJ� 006F ?-6 /00 4. L-iq.0 0."7r S 75 5. 115 (38. 2 8'5 OiLF lo q, q 012 loo 0e; lo.-AI51v-la OW 100 0,5 CCV(l 000 MO) ja -7 /0-3 1 oY oe3o CCB too 1. 2- 3. 4, Yl 5. J OA 6. U Z 7. 8. 9. 10. CCV(1000 mgn) CCB P 0023 101 Author: bnk H2M Labs. Inc. Date: 7/12/2006 Original Run Filename: OM_7-12-2006 09-16-23AM:OMN created 7/12/2006 9:16:23 AM Original Run Author's Signature: [bnk] Current Run Filename: NH3071106.omn lastm dified 7/12/200610:17:14 AM Current Run Author's Signature: [bnk] Description: 10-107-041-C 00 Sample Cup No. Channell Conc. (mg/L)-(V Area ADF s MDF "CalStd7:ical7:nh3 W' S1 3.000 48.483 "CalStd6:ical6:nh3 W' S2 1.000 15.944 "CalStd5:ical5:nh3 w" S3 0.500 7:191 "CalStd4:ical4:nh3 w" S4 0.200 2.734 "CalStd3:ical3:nh3 W" S5 0.100 1.565 "CalStd2:ical2:nh3 w" S6 '0.050 0.757 "CalStdl:icall:nh3. w" S8 0.000 0.095 "CRA:cra:nh3 w" S5 •0.111 1.530 Known Conc: Calibration: 0.100 Table/Pi' f,I "LCS-17454:LCS:nh3 w" 1 2 1.069 17.071 Known Conc: 1:.000 "MB-17454:MBLK:nh3' w 1 0.010 -0.100 Known Conc: 0.000 "0606916-001C:SAMP:NH3 W" 3 0.121 11693 "0606916-002C:SAMP:NH3 W" 4 0.192 2.842 "0606916-003C:SAMP:NH3 W" 5 0.086 1.128 "0606916-004C:SAMPNH3 W" 6 0.142 2.028 "0606916-005C:SAMP:NH3 W" 7 0.146 2.096 "0606916-005CMS:MS:NH3 W" 8 4.683 7.3261 10.00 "0606916-005CDUP:DUP:NH3 W" 9 0.1-40 2.124 "0606916-006C:SAMP:NH3 W" 10 0.283 4.317 "0606916-007C:SAMP:NH3 W" 1 11 0.243 3.668 "0606916-008C:SAMP:NH3 W" 1 12 0.102 1.384 "CCV:CCV:NH3 W" I S2 0.987 15.745 Known Conc: "CCB:CCB:NH3 W" S8 _ 1.000 0.02g 0.083 Known Conc: `0,000 "0606916-009C:SAMP:NH3 W" 13 0.379 5.880 , "0606916-010C:SAMP:NH3 W" 14 0,087 1.140 "0606916-011 C:SAMP:NH3 W" 15 0:23 3.498 "0606916-012C:SAMP:NH3 W" 16 0.361 5.578 "0606916-013C:SAMP:NH3 W" 17 0.382 5.919 "0606993-001A:SAMP:NH3 W" 18 0:408 1.054 5.00 "LFB-17454:LFB:NH3-RT W" 19 5.290 8.310 10.00 "LFBD-17454:LFBD:NH3-RT W" 20 5.113 8.022 10.00 Sam le31 21 0.353 .5.454 Sam le34 21 0.353 5.457 "CCV:CCV:NH3 W" S2 0.98$ '15.759 Known Conc: 1.000 "CCB:CCB:NH3 W" I S8 0.022 0.087 Known Conc: 0.000 "0606993-001a:sam :nh3-rt w" 21 0.351 5.423 "CCV:CCV:NH3 W" S2 0.98 15.748 Known Conc: 1.000 "CCB:CCB:NH3 W' S8 - "0':022 0.089 Known Conc: 0.000 Analyte Properties Table for NH3071106.omn j Property Channell ; NH3 Run: NH3071106 -I. lik 40-0�- (4 �I) JL Qex, ; okf� RPD 3L Author: bnk Concentration Units m /L Calibration Fit Type First Order Clear Calibration True Force Through Zero False Calibration Weighting None Auto Dilution Trigger True % of High Standard 100 Quik Chem Method a. Chemist Direct/Bi olar Calibration by Height False Inject to Peak Start 41 Peak Base Width 68 Channel' 5.489- 3.624- M .489 -3.624-M : Set 1 of 2 H2M Labs. Inc: 0.000 75.6 Run: NH3071106 - 2 - Date : 7/12/2006 — M r c 1 a. r - co U =' z S = _ ti � U) in d. z =1 z = z I IL 3 m 3: z a p z 3.00021- g/L 3 - ¢a U Q i4 c t' MI rail 3I v ,V o p Um ��j U U¢J c c M 00 V' O lA O 4 O Uw 1.000 U g/L - U. � U -d U � C J 1.06 � (b M � 0.500 Ug/L U 0.2000.1000_p50n nnn 0...-V _1 m '1 0.000 75.6 Run: NH3071106 - 2 - Date : 7/12/2006 Time (s) 1565.1 N O O �J1 1 z Z =' z S = _ = in d. z =1 z = z I IL ? z z z a p z co ¢a Q Q Y COq? J Cj N ,V o p Um ��j U U¢J m M 00 V' O lA O 4 O LO O O O oO O C3 6 cfl � (b M � (b r — IB <D o(D o cOo 0 o m o 0 0 ccn 0 ED p m o 0.46803/L- o m o 0.192 - -' 0 2830.243 nan0.12 • •-0.0860.1420.1 y/L0.1�S�.:.y 0.102mg/ Time (s) 1565.1 N O O �J1 Author: bnk H2M iLatis Inc. Date: 7/1212006 Channel 1: Set 2 of 2 5.489-7- CO .489-r- Z Ce) I Z Z Z c+)!_ = cn Z 3.624 = a < n z m z Q Q cQn vat m LL Q U QLL U C� o Ur a Q v o _ O o 6 o U Z m o co o. r � (O CO 0.987 mg/L U o IS o CO � {� 0.379 i Itn g/LnzQnl�eg52�0�rt$I11 U 0.000 +--- 1565.6 Table 1: NH3 Time (s) 3055.1 i� S 7 i M � sCL C z Rep Peak Area (Volt -s)._', U =� o U Z rn co m U CL U 0) E E 0.988 mg/L �? 8) 2 1.000 1 Vo 0.775 mg/L 0.353L 7/12/2006 9:25:44 AM U 0.351 mg/L 3055.1 Figure 1: NH3 NH3 concentration, mg/L Run: NH3071106 3.000 a = 16.211 • Conc _ 0.265 is = 0.062' Area + 0.017 relation Coefficient (r) = 0.99981 .. Weighting i Cones (mg/L) Rep Peak Area (Volt -s)._', Peak Height (Volts) % Residual Detection Date Detection Time 1 3.000 1 481.483, 2.342 -0.2 7/12/2006 9:24:32 AM 2 1.000 1 15.944 0.775 0.0 7/12/2006 9:25:44 AM 3 0.500 1 7.191 .'.' 0.350 8.3 7/12/2006 9:26:57 AM 4 0.200. 1 2.734 J'' 0.133 8.2 7/12/2006 9:2810 AM 5 0.100 1 1.565 ) 0.076 -15.4 7/12/2006 9:29:23 AM 6 0.050 1 0.757 0.037 -38.7 7112!2006 9:3036 AM Z 0.000. 1 0.095 0.005 7/12/2006 9:31:51 AM Figure 1: NH3 NH3 concentration, mg/L Run: NH3071106 3.000 a = 16.211 • Conc _ 0.265 is = 0.062' Area + 0.017 relation Coefficient (r) = 0.99981 .. Weighting I. ooh. JH2A LAUS. ) INC. SYS AMMONIA DISTILLATION I NAME: -&j VA�L& &jLV� DATE: 7—lv-19A 10,00 - I Y., (2D ff I LAB NO. CLIENT ID SAMPLE WEIGHT GRAMS SAMPLE voi;UME Mis FINAL VOLUME NILS DATE ANALYZED SPIKE "A ul lovO6 ft-oote, PT - qU ao !-gote m ir, —Y qA- tqvf� 7 &P 116 - 0,05C 916- 916-o(2 AD —95 11 'o M S. p 0018 -V A. .+ q-/,Zthor: bnk H2M Labs. Inc. 1 Original Run Filename: OM_6-27-2006_12-38-04PM.0 Original Run Author's Signature: [bnk] Current Run Filename: N03062706a.omn last mcadifiei Current Run Author's Signature: [bnk] Description: 10-107-04-1-C Date : 6/27/2006 created 6/27/200612:38:04 PM 6/27/2006 2:13:15 PM Sample Cup No. Channel 2 Nitrate as N Cone. (mg N/L ADF Area s MDF "Cal Std 5:ical5:no3 dw" Si 2.000 22.766 "Cal Std 4:ical4:no3 dw" S2 1.0001 11.145 "Cal Std 3:ieal3:no3 dw" S3 1 0.5001 5.727 "Cal Std 2:ical2:no3 dw" S4 0.1001 1.118 "Cal Std 1:ical1:no3 dw" S5 0.05011 0.563 "Cal Std O:ical0:no3 dw" S16 0.00011 0.007 "CRa:cra:no3 dw" S4 0.10011 1.111 Known Cone: 0.1001 1 Calibration: Table/Fig. 't1 "LCS-062706:lcs:no3 dw" I S6 ;,.js137 112.888 Known Cone: 1.130 "MB-062706:mblk:no3 dw S16 0.0041 0.023 Known Conor 0.0001 "0606795-001A:SAMP:NO3 W" 1 1.8281 4.130 5.00 "0606795-002A:SAMP:NO3 W" 2 3.4281 7.765 5.00 "0606840-001A:SAMP:NO3 W" 3 0.058 0.642 "0606840-002A:SAMP:NO3 W" 4 2.29611 5.195 5.00 "0606842-001A:SAMP:NO3 W" 5 0.38811 0.861 5.00 "0606848-001A:SAMP:NO3 W" 6 0.4821 1.075 5.00 "0606848-002A:SAMP:NO3 W" 7 0.926, 2.082 5.00 "0606895-001A:SAMP:NO3 W" 8 0.796, 1.789 5.00 "0606895-002A:SAMP:NO3 W" 9 2.190 4.9541 5.00 "0606916-001 C:SAMP:NO3 W" 10 0.025 0.263 "CCV:CCV:NO3 W" S2 0.980 11.113 Known Cone: 1.000, "CCB:CCB:NO3 W" I S16 0.0031, 0.014 Known Cone: 0:000' "0606916-002C:SAMP:NO3 W" 11 `0:115, 0.240 5.00 "0606916-003C:SAMP:NO3 W" 12 0.053, 0.099 5.00 "0606916-004C:SAMP:NO3 W" 13 0.093 0.191 5.00 "0606916-005C:SAMP:NO3 W" 14 0.136 0.134 10.00 "0606916-005CMS:MS:NO3 W" 15 14.125 16.019 10.00 "0606916-005CDUP:DUP:NO3 W" 16 0.145 0.144 10.00 "(1606916 006C:SAMP:NO3 W" 17 0.101 0.209 5.00 "0606916-007C:SAMP:NO3 W" 18 0.106 0.220 5.00 "0606916-008C:SAMP:NO3 W" 19 0.028 0.044 5.00 "0606916-009C:SAMP:NO3 W" 20 0.116 0.242 5.00- "CCV:CCV:NO3 W" S2 0.987 11.184 Known Cone: 1.000 "CCB:CCB:NO3 W" S16 0.003 0.011 Known Cone: 0.000 "0606916-01OC:SAMP:NO3 W" 21 0.043 0.078 5.00 "0606916-011C:SAMP:NO3 W" 22 0.052 0.097; 5.00 "0606916-012C:SAMP:NO3 W" 23 0.038 0.0671 5.00 "0606916-013C:SAMP:NO3 W" 24 0.158. 0.1601 10.00 "0606991-001A:SAMP:NO3 W" 25 0:045 0.487 "0606991-002A:SAMP:NO3 W" 26 0.291 0.641 5.00 "0606842-001A:SAMP:NO3 W" 5 0.204 2.297 "0606916-002C:SAMP:NO3 W" 27 0.084 0.930 "0606916-003C:SAMP:NO3 W" 28 0.025 0.268 "0606916-004C:SAMP:NO3 W" 29 0.073 0.808 "CCV:CCV:NO3 W" S2 0.908 110.296 Run: N03062706a -1 - &c /0 t o/ e -of - C qV L0-oS` f"V- 11W _/b is mfu---3b 47 -c -q!04. tn O O H Author: bnk H2M Labs, Inc. Analyte Properties Table for N03062706a.omn Property Known Conc: 1.000' mg N/L "CCB:CCB:NO3 W" 1 S16 0.004 0.020 Force Through Zero Known Conc: 0.000 None "0606916-005C:SAMP:NO3 W" 30 0.104, 1.162 "0606916-005Cms:SAMP:NO3 W" 31 0.519 5.877 "0606916-005Cdu :SAMP:NO3 W' 32 0.097 1.079 "0606916-006C:SAMP:NO3 W" 33 0.09211 1.022 "0606916-007C:SAMP:NO3 W" 34 1 0.087 "0606916-008C:SAMP:NO3 W" 35 0.0171 0.170 _ "0606916-009C:SAMP:NO3 W" 36 0.0881 0.975 "0606916-010C:SAMP:NO3 W" 37 0.021] 0.222 "0606916-011C:SAMP:NO3 W" 38 0.045 0.493 "0606916-012C:SAMP:NO3 W" 39 0.028 0.299 "CCV:CCV:NO3 W" S2 0.896 10.150 Known Conc: 1.00011 "CCB:CCB:NO3 W" 1 S16 0.003 1 0.018 Known Conc: 1 0.000 "0606916-013C:SAMP:NO3 W" 40 0.116 1.298 "CCV:CCV:NO3 W" S2 0.969 10.984 Known Conc: 1.00011 1 "CCB:CCB:NO3 W' I S16 O:00411 0.029 1�j Known Conc: 0.000,11- Analyte Properties Table for N03062706a.omn Property Channel2 Nitrate as N Concentration Units mg N/L Callibration Fit Type First Order Clear Calibration True Force Through Zero False Calibration Weightinj None Auto Dilution Trigger True % of High Standard 100 Quik Chem Method 10-107-04-1-C Chemist Direct/Bipolar Calibration by Height False Inject to Peak Start 22 Peak Base Width 55. Run: N03062706a - 2 - Date : 6/27/2006. Author: bnk Channel 2 (No2/No3) : Set 1 of 3 I 4.010 vEl yl I M Z MI M O T M z z U CO LO z io O OIa. Z CO U U z Q. a Ste, yl $I 0 Z < �I M z CO 'D Q Q MI Q MI U of Ll. MI < N c g vl Qo o o 2.495--2.000 W¢ U O d a C- w z C �. ao vl vl Q O > m (D V MO M C C CO O Q Q o 1.0006g � N cf°i u G p N4 n U a � o V! Q Q Q a 0.500.r g NC v> E rn m a o a o III I 100 nrn-= - m 0.000 +- 66.1 Channel 2 (No2/No3) : Set 2 of 3 4.010—. 2,495- 42 .495-42 H2M Labs 1 Inc. Date : 6/27/2006 0.000 +--f 1609.6 Run: N03062706a -3- (s) 1609:6 MI O I ss >I MI z yl I M Z MI �I >I M z z U CO U) z io O OIa. Z o: U z Q. a Ste, yl $I 0 Z < �I M z CO n �I Q Q MI Q MI MI z O Z Ll. MI < N 0 3 vl Qo o o z a W¢ z d a C- ¢ COU, z o 0 0 CO ON Q U c2 m W m (D co coo c2 coD I (p M Q Q o OI OI =J Y. 1.13.7,:.ng p N4 n to Q U O o qn Q V! Q Q Q a O Cn Z Z E rn m a o a o o O o - m U 0.980 mg N/ 1.412 NgN/� e6 m o O O C fA O In U col ON v 06 1- Q 0.459(D N(0 o 0 0.438og N/L LO 0 0 rfl 0.36 m No Im 0 U I� cfl m ' Nn nnk mh I i I 0.05 U m [ 0.0780.09 (D 01850.15 t` t m I 1 I h5- 0.02 m N/L 0.000 +--f 1609.6 Run: N03062706a -3- (s) 1609:6 MI O I ss >I MI z yl - Z �I �I >I M z z U CO U) z z d o: U z na a z a n: ? na a < < CO n �I 2 < n 2 :E < 0 Q 0 m < v < N < M Q Q N o o U 0.987 �g N/9 m o 0 0 o Q o o 0 0 co coo U c2 m W m (D co coo c2 coD I (p M '0 o o OI OI OI OI o Z OI OI C N/ Z Z z Z co M Z p Z Z a a n a o a n a Q Q 1.412 NgN/� Q a fn CA fA f0 p fn In U col ON v m 1- Q o CO Ln LO 0 0 0 m 0 0 0 U co cfl co c6 co co ca cc U m rn o (D w coo m coo coo a U. coo 0 0 0 0 0 0 "C U po 0.0039�N�fI1>JAcfd1N,(iicYl 0 0 : /fnd �II o o. %:o: - c N,�0140[f�19ltfdp�lk 0.000 +--f 1609.6 Run: N03062706a -3- (s) 1609:6 (s) 3062.9 I ss >I MI z yl �I �I �I �I >I M z z U CO m z z z d o: U z na a z a n: ? na a < < > U n �I 2 < n 2 :E < 0 Q 0 m < v < N < M Q Q N o o o 0.987 �g N/9 m o 0 0 o Q o co coo U c2 m W m (D co coo c2 coD o M '0 o o U o 0 0 0 0 oo,�D.204.mg N/ N(p 003@91�10[�ig�fhi�lt�/115�ti Y'�1g N/L (s) 3062.9 Author: bnk Channel 2 (No2/No3) : Set 3 of 3 4.010 2.495 - H2M Labs. Inc. Date : 6/27/2006 % Residual Detection Date Detection Time 1.984 -0.3 �I O z O z z O 0.501 o z EL a O > a z a U U 12:44:10 PM n Q 6/27/2006 u? � SS 71 �I I �I CI I U 0 � a o 0 O `OO Q z CQ O a E n O z a Z z a < U U 0 z a Q to o g Q z n < Q � U h c6 a uJ N U I U O to CO LO 0.. 0 0 0 co 0.908 mg CO N4 c0 0 o 0 co 0 m U ( co 0.519 f g N/C 0 0 0 0.084,atkNiW, U Nll.,, o 9-10Ln 0 0 N0 -097&Q Date : 6/27/2006 �I COO z U U U U 0.969 mg N/ 4516.1 ight (Volts) % Residual Detection Date Detection Time 1.984 -0.3 6/27/2006 O z O z z O 0.501 o z EL a a > a z a U U 12:44:10 PM n Q 6/27/2006 u? U U �I 12:46:37 PM ej UV 0 U 0 U M 0.896 Ce) N/Q o co 1,2m 0 6 cp U Y) (O rn �! O c(0 0 0 [T[3t F FAI�IV FFt¢t+P7 0 Ll�N&003n U o na1N/L g �I COO z U U U U 0.969 mg N/ 4516.1 ight (Volts) % Residual Detection Date Detection Time 1.984 -0.3 6/27/2006 12:40:32 PM 0.973 1.7 6/27/2006 12:41:44 PM 0.501 -1.2 6/27/2006 12:42:57 PM 0.098 -0.2 6/27/2006 12:44:10 PM 0.049 -2.7 6/27/2006 12:45:23 PM 0.000 6/27/2006 12:46:37 PM i54 * Conc - 0.019 88 * Area +0.002 Coefficient (r) = 0.99994 ng Phenols Method 420.1 Distillation Date: Time: g.Ao PE 7&4 oa 6 Analyst: -� Date: - 06 TSL006 W49 Phenols P 0026 ��� : , , . � weer � � . - e©r��■� � �■■e�� �� - r■�e■e �■�� - ��� �iT�1��— f •mss �®®—���J :� — TSL006 W49 Phenols P 0026 Calibration 1-4-06 conc abs 0 0.000 5 0,012 10 0.025 20 0.048 30 0.068 40 0.095 50 0.12 Intercept (b) -0.0069 slope (m) 421.33 0.9994 TSL006 W50 Page 1 of 1 Phenol Calibration 114106 60 50 - 21.33x - 0.0069 40 J =L i conc c30 —Linear (conc) 0 U 20 10 0 0.000 0.050 0.100 0.150 Absorbance Page 1 of 1 m p 11 T /W OWN 09 P675b 1004 SULFATE DATE: oz ANALYST: CLIENT ID LAB# NffiS USED I ABS. I MG/L (GRAPH) MG/L NOTES ICV (20.0 mg/L) I 0- no ;z- ICB 0.04 ZJ.'o — L& - jo CCV(20.0 ma) CCB to -'o ol'o 2 S' 10 q16 -,PoFD tf- 0. od y Zs. 0 14. lit -r 0 95 M.2 CCV(20.,O m&/L) �S- v ' .2 �o (f- � q CCB IS— D.10, v4t&—1p � 060 \9 0�0( 0 voko 9. o ss 914 r 10.0 94 Adloo CCV(20.0 mg/L) CCB 6.5 060016- 0160 ?/Z -0 1 �-n 19. (S'771 -zr— J/ SAO /yAk 7 v CCV(20.0 mg/L) iS- 0.13o CCB o Y' 0.,00 0 A ol A P 0021 Calibration 12/29/05 conc abs 0 0,000 5 0.034 10 0,089 15 0.149 20 0.229 25 0.298 30 0.351 35 0.44 40 0.510 Intercept (b) 2.3217 slope (m) 75.76 corr. Coeff. 0.9964 SO4 12/29/05 y = 75,764x + 2,3217 40 30 J E 20 ♦ conc Linear (cone) 10 0 ,l 1 . I I 0.000 0.100 0.200 0.300 0.400 0.500 0.600 Absorbance Page 1 of 1. z9A 9001SZ ((Dried Wt.(al. Tare Wt (allxl000lxl000' Solids(mg/I)= mL Sample ANAL- - --YST;' ` !- ^1 n^r _ EL • /iii LIDS vs ss/ -rs 'T5'L006 TEMP. Z3.3, Z -2.6 1.11 IA A 1111 TV.. 1A 1 1-7 _i Z LAB # CLIENT ID PANI CRUC. SAMPLE ML DRIED WT G TARE WEIGHT G SOLID WEIGHT G RESULT MGIL DRIED WT G IGNITED WT G VOL.. WT G - CON D. ✓ -r,/, v�� IjU ;� /o y 6 y/ , �l l o ; 0 160 /off 9645 vS. S 010009 Leo -o lb1,My /o7, 0.3 .o2 6") M 14 M [ AJ 9 . y� o•o//� //7 - nZ,4 I� T aG• �' D D �l3 0 2 1 /o5 CM7 2( /Ifv to S 72 21 /05190 `JO A o/S�' /s8/ o69g9-alA We- 3 019991 /07, /y 0. OM'? '77 42 , .3" �l _�3 /01. y06./ I o 7,3 9'5 o 0/03 /03 -SOLIDS HDried Wt,(Q)- Tare Wt. (o)WOOON1000 TDs SS/ TS Solids(mg/l)= mL Sample ANALYST: Ali TEMP. DATE- A J7 -7 IAr' RTAPT- HUMIDITY. - LAB# CLIENT IQ PAN/ CRUC. SAMPLE (ML) DRIED WT (G) TARE WEIGHT (G) SOLID WEIGHT (G) RESULT MG/L DRIED WT (G) IGNITED WT (G) VOL. WT (G) COND. 1/ R/vy zoX Kil dl 309 163,02., 12,5,?301 0,00V6 g, /0 1o7 ,950 IOqoWl- o, o/09 /0 060.- uz/,l Z�20 So z3. 6z10 I23.3AI o, 0 W S -/g/ 125,01r X 0 1,0Y,05YO 1041,0527 e9 -M/3 /3 91 �Y_ 020 66m v avo /a /0 y sj-?o o 0 35 6 leJ2P L oD zq 7.5 35 105 1Zf53-51 2 r oj 319 14 V 97� ly, PI) ! 2,'l 0 J/ qP AIL LIDS flDrled WLfgt - Tare Wt. lg11x10001x1000 TD SS/ TS Solids(mg/I)= mL Sample ANALYST: TEMP. r)ATG• /n 9^7 AZ !TART- HIIM11)ITY- LAB # CLIENT ID PAN/ CRUC. SAMPLE ML DRIED WT G TARE WEIGHT G SOLID WEIGHT(G) RESULT MOIL DRIED WT(G) IGNITED WT(G) VOL. WT(G) COND. xoy3o io 6 -- Lb� C� /off 16 Io . o ov'��' 175` �35� /03.I /,'S _3 0 -00 fOv lo3.713 /019 D.aW /7y /fit M do -Aldw 41D 'O% /O'7 Z 01 dvO��' �� • M 0 6 -g L-F� , G 9Moa S,2- 2 0. 0/7t 3 6 126 566 So50 EkR J IX. '15� �A g, () OL MY F6 SOLIDS [{Dried Wt. (a) - Tare Wt (Q)1x10001 1.000 DS / SSI TS Solids(mg/1)= mL Sample ANALYST: �. TEMP. nw*rc / �)l cruor• W1IMIf11TV- ' LAB CLIENT ID PAN/ CRUC. SAMPLE ML DRIED WT G TARE WEIGHT G SOLID WEIGHT G RESULT MG/L DRIED WT G IGNITED WT G VOL. WT G CON D. `# V V:3c" i16V, 3��l C 0 U3Z5 3ZS �af139� Effective immediately, when analyzing any matrix other than potable water for TDS, please take the conductivity of the sample and record it in the last column of the logbook.. Please use the following guide for dilutions based on the conductivity, READING ON CONDUCTIVITY METER MLS OF SAMPLE TO USE On•C up to 200/ on D under 800 10Q_mis Over 800 on D/up to 2.09 on E 50 ml's. 'On E from 2.00 to 5.00 25 mis On E from 5.00 to 8.00 20 mis A-4ything past 8.00 on E to F 10 mis. ..On F reading of 20 or higher 5 rnls for 25 or lower 1 rill for_Z5 of:,hi her All -potable water samples should be analyzed at 100 mis, For fresh kills total and filtered samples use the same amount of sample *volume for both sets of samples, TKN Data Peak SampleID I Primer 2 Drift 3 High 4 Low 5 Low 6 Cal. 7 Cal. 8 Cal. 9 Cal. 10 Cal. 11 Cal. 12 OPTICAL BLK 1 2.95 7/11/2006 13 LCS17453 1 2.93 7/11/2006 14 MB 17453 1 F 2.94 7/11/2006 15 0606916-OOICEM PT - 1I16 16 0606916-002C M D 17 0606916-003C is, 18 0606916-004C -36 1 0.93 7/11/2006 CALB 35 19 0606916-005C 0.24 mg/1 20 0606916-005CMS . 0.12 mg/1 21 0606916-005CDUP 0 mg/1 QQ 22 QUAL 0.66 mg/1 aidvLCJ- 0606916-0060 Qp 0.475 mg/1`� Ilp°� 23 0606916-007C 1i S 24 0606916-008C S D 25 CCV 1.0 0.26 mg/1., 26 CCB 0.56 mg/1 27 0606916-009C Jrs 28 0606916-OIOC $ 29 0606916-011C S 30 0606916-012C 1 0.04 7/11/2006 } 7/11/2006 I1:53:24 AM 2.48 mg/1 e 0Lp�2 Concentration listed after Optical Blank Correction. Preparation dilution factor not applied to results. SampTy Cone Units DF Cone x DF AnalDate AnalTime TestCod PRIM 2.95 mg/1 1 2.95 7/11/2006 DRIF 2.93 mg/1 1 2.93 7/11/2006 HIGH 2.94 mg/1 1 F 2.94 7/11/2006 LOW 0.01 mg/] 1 0.01 7/11/2006 LOW 0.01 mgll 1 0.01 7/11/2006 CALB 3.02 mg/1 1 3.02 '7/11/2006 CALB 0.93 mg/1') % e d 1 0.93 7/11/2006 CALB 0.48 mg,4 1 0.48 7/11/2006 CALB 0.24 mg/1 1 024 7/11/2006 CALB 0.12 mg/1 1 0.12 7/11/2006 CALB 0 mg/1 1 7/11/2006 QUAL 0.66 mg/1 1 F0.66 7/11/2006 LCS Qp 0.475 mg/1`� Ilp°� 10 4.75 7/11/2006 MBLK -0.02 mg/1 1 n.1 1 0.02 7/11/2006 SAMP 0.73 mg/l 1 0.73 7/11/2006 SAMP 0.26 mg/1., 1 F0:26 7/11/2006 SAMP 0.56 mg/1 1 0.56 7/11!2006 SAMP 1.8 mg/I 1 1.8 7/11/2006 SAMP 0.25 mg/1 1 025 7/11/2006 MS T d = �I10.405 mg/1 q 3 -,/610 4.05 7/11/2006 DUP 0.04 mg/1 APA 0 1 0.04 7/11/2006 SAMP 2.48 mg/1 1 2.48 7/11/2006 SAMP 0.71 mg/1 1 0.71 7/11/2006 SAMP 0.5 mg/1 1 0.5 7/11/2006 CCV 0.95 mg/1 H_5 1 0.95 7/11/2006 CCB 0 mg/1 1 7/11/2006 SAMP 1.15 mg/1 1 1.15 7/11/2006 SAMP 0.16 mg/1 1 0.16 7/11/2006 SAMP 0.23 mg/1 1 I 0.23 7/11/2006 SAMP 1.9 mg/1 1 1.9 7/11/2006 10:51:18 AM 10:51:58 AM 10:52:38 AM 10:53:09 AM 10:54.00 AM 10:54:38 AM 10:55:19 AM 10:55:59 AM 10:56:40 AM 10:57:16 AM 10:58:00 AM 10:58:39 AM 10:59:05 AM 10:59:59 AM 11:00:39 AM 11:01:19 AM 11:01:59 AM 11:02:39 AM 11:03:19 AM 11:03:57 AM 11:04:39 AM 11:05:19 AM 11:05:59 AM 11:06:39 AM 11:07:19 AM 11:07:57 AM 11:08:39 AM 11:09:19 AM 11:09:59 AM 11:10:39 AM Page 1 of 3 THIN W TEN -W TKN W TKN W TKN W THIN W TKN W TKN W TKN_W TKN W TKN W -TKN_W TKN W TKN W TKN W TKN W TKN_W TKN_W TKN_W TKN W TKN_W TKN_W TKN_W TKN W TKN_W TKN W TKN W TKN_W TKN_W TKN_W 00 kn O O H Peak SampleW SampTy Cone Units DF Cone x DF AnalDate AnalTime TestCod 31 0606916-013C b SAMP 0.13 mg/l 1 0.13 7/11/2006 11:11:17 Alva TKN W 32 0607080-OOID T r SAW 0.01 mg/l 1 0.01 7/11/2006 11:11:51 AM TK14 W 33 0607080-002D p�+-T R F + t� SAW 021 mg/l 1 021 7/11/2006 11:12:39 AM TK W 34 0607080,0030 SAW 0.61 mg/1 1 0.61 7/11/2006 11:13:19 AM THI W 35 0607080-004D 2 SAMP 1.37 mgll 1 1.37 7/11/2006 11:13:59 AM TKN W F 'j- 36 0607080-004DMSrV % �' MS 7S % 0.444 mgll 10 4.44 7/11/2006 11:14:39 AM TKN W 37 CCV 1.0 JI CCV Jt 1'4 O/ 0.94 mg/1 1 0.94 7/11/2006 11:15:19 AM TKN W 38 CCB CCB Godo 0 mgll 1 I� 7/11/2006 11:15:57 AM TKNW MIO'A 0.66 1 0.66 7/11/2006 11:16:34 AM TKN W 39 0607080-004DDUP DUP mg/l 40 0607080-005D it Fes, ��� SAMP 0.97 mg/l IF --7 0.97 7/11/2006 11:17:19 AM TKN W 41 0607080-006D - S SAMP 0.33 mgtl 1 033 7/11/2006 11:17:53 AM TKN W 42 0607080-007D 4 SAMP 0.62 mg/l 1 0.62 7/11/2006 11:18:39 AM TIIN_W 43 0607080-008D SAMP 0.52 mg/1 1 0.52 7/11/2006 11:19:19 AM TKN W e-�""" 44 0607080-009D �O SAMP 4.6 mg/l 1 I 4.6 7/11/2006 1120:00 AM TYN W "c:re- Call• e P -+k+1. 45 0607080-OIOD y !'S SAMP 4.53 mg/l 1 4.53 7/11/2006 11:20:40 AM TKN W --- C.n.(. 1.1. 46 0607080 -OI ID SAMP 4.53 mg/1 1 4:53 7/11/2006 11:21:20 AM TKN_W 47 0607080-012D 1 0 SAMP 1.24 mg/l 1 1.24 7/11/2006 11:21:56 AM TKN_W 48 0607080-013D 1 3 SAMP 0.35 mg/l 1 0.35 7/11/2006 11`.22:37 AM TKN W 49 CCV 1.0 CCV kft-1O76�o 1.07 mg/l 1 1.07 7/11/2006 11:23:15 AM TKN_W 50 CCB CCB L O' 1 02 mgll 1 0.2 7/11/2006 11:23:57 AM TKN_W 51 0607119-002A SAMP 1.2915 mg/l 20 25.83 7/11/2006 11:24:39 AM TKN W • 52 0607152-OOIA SAMP 0.56 mg/I 10 5.6 7/11/2006 11:25:07 AM TKN_W 53 0607152-002A SAMP 0.113 mg/1 10 1.13 7/11/2006 11:25:50 AM TKN_W 54 0607228-OOIA SAMP 0.106 mg/l 5 0.53 7/11/2006 11:26:30 AM TKN_W 55 0607228-002A SAMP 1.068 mg/l 101 10.68 7/11/2006 11:27:19 AM TKN_W 56 0606912-OO1H rin) p1aZ2 a� X023 SAMP 2.38 mg/I 1 2.38 7/11/2006 11:27:59 AM TKN_W 0.b�v�c�-� • 57 LFB 17453 -I- i2eL V = t4 -I + ^�l L LFB c/ 0.401 mg/l 10 4.01 7/11/2006 11:28:37 AM TKN W 58 LFBD 17453 LFBDRP�Qj !a OAII mg/l 10 4.11 7/11/2006 11:29:09 AM TYN W 59 CCV 1.0 CCV 1ePf- `j3%0.93 mg/l 1 0.93 7/11/2006 11:29:59 AM TKN_W 60 CCB CCB ,LO. 0 mg/l 1 7/11/2006 11:30:40 AM 'TKN W 61 Drift DRIF 2.93 mg/l 1 I 2.93 7/11/2006 11:31:19 AM T _W , N 7/11/2006 11,:53:24 AM Page 2 of 3 Peak SampleID 62 End SampTy Cone Units DF Cone a DF AnalDate AnalTime TestCod END 0 mg/I 1 2/11/2006 11:33:02 AM TKN W 7/11/2006 11:53:24 AM Page 3 of BRAN+LUEBBE AACE 5.48 Name of Run tkn071106R1 Date of Report 7/11/2006 Date of Run 7/11/2006 Operator BNK Comment 2 17453 H2M Labs Inc. Post -run report Name of Analysis :TKN.ANL System No. :1 Type of System :TRAACS Start/Stop time :10:40 - 11:33 Channel Type Real Data Channel 2 2 Method Method 2 Dilution Unit mg/l mg/l Calibr. Fit Linear Corr. Coeff. 0.9995 Base 61 Gain 15 Sensitivity 0.4497 Sample Limit 1 Sample Limit 2 Pk Cup Sample Id Value Value 0 0 B Baseline 0.00 0 1 1 P Primer 2.95 1 2 1 D Drift 2.93 1 3 1 Hl High 2.•94 1 4 0 Ll Low 0.01 1 5 0 L1 Low 0.01 1 6 1 C Cal. 3.02 1 7 2 C Cal. 0.93 1 8 3 C Cal. 0.48 1 9 4 C Cal. 0.24 1 10 5 C Cal. 0.12 1 11 0 C Cal. 0.00 1 12 8 QC1 OPTICAL BLK 0.66 1 13 9 QC1 LCS17453 5.41 10 14 10 QC1 MB 17453 0.64 1 15 11 S 0606916-001C 1.39 1 16 12 S 0606916-002C 0.92 1 17 13 S 0606916-003C 1.22 1 18 14 S 0606916-004C 2.46 1 19 15 S 0606916-005C 0.91 1 TKN.ANL / tkn071106R1.run Page 1 Post -run Report QC Limits Q TKN.ANL / tknO71106R1.run Page 2 Post -run Report BRAN+LUEBBE AACE 5.48 20 16 S 0606916-005CMS 4.71 10 21 17 S 0606916-005CDUP 0.70 1 22 18 S 0606916-006C 3.14 1 23 1.9 S 0606916-0070 1.37 1 24 20 S 0606916-008C 1.16 1 25 2 QC1 CCV 1.0 0.95 1 26 0 QC1 CCB 0.00 1 27 21 S 0606916-0090 1.81 1 28 22 S 0606916-010C 0.82 1 29 23 S 0606916-011C 0.89 1 30 24 S 0606916-012C 2.56 1 31 25 S 0606916-013C 0.79 1 32 26 S 0607080-OO1D 0.67 1 33 27 S 0607080-002D 0.87 1 34 28 S 0607080-003D 1.27 1 35 29 S 0607080-004D 2.03 1 36 30 S 0607080-004DMS 5.10 10 37 2 QC1 CCV 1.0 0.94 1 38 0 QC1 CCB 0.00 1 39 31 S 0607080-004DDUP 1.32 1 40 32 S 0607080-005D 1.63 1 41 33 S 0607080-006D 0.99 1 42 34 S 0607080-007D 1.28 1 43 35 S 0607080-008D 1.18 1 44 36 S 0607080-009D 5.26 1 45 37 S, 0607080-010D 5.19 1 46 38 S 0607080-011D 5.19 1 47 39 S 0607080-012D 1.90 1 48 40 S 0607080-013D 1.01 1 49 2 QC1 CCV 1.0 1.07 1 50 0 QC1 CCB 0.20 1 51 41 S 0607119-002A 26.49 20 52 42 S 0607152-001A 6.26 10 53 43 S 0607152-002A 1.79 10 54 44 S 0607228-001A 1.19 5 55 45 S 0607228-002A 11.34 10 56 46 S 0606912-001H 3.04 1 57 47 S LFB 17453 4.67 10 58 48 S LFBD 17453 4.77 10 59 2 QCl CCV 1.0 0.93 1 60 0 QC1 CCB 0.00 1 61 1 D Drift 2.93 1 N 62 0 B FinalBase 0.00 1 QC Limits Q TKN.ANL / tknO71106R1.run Page 2 BRAN+LUEBBE AACE 5.48 Channel 2 QC 1 Unused QC 2 Unused QC 3 Unused QC 4 Unused QC 5 Unused QC 6 Unused QC 7 Unused QC 8 Unused QC 9 Unused QC10 Unused CORRECTIONS Channel 2 Baseline Yes Drift Yes Carry over Yes ** <END OF REPORT> ** TKN.ANL / tkn071106R1.run Page 3 Post -run Report BRAN+LUEBBE RACE 5.48 H2M Labs Inc. Calibration Curve Name of run :tkn07llO6Rl.RUN Comment Calibration Curve Name of analysis :TKN.ANL Channel :2 Method :Method 2 Curve fit :linear a= -2.6886E-001 b=8.6614E-005 Corr. coeff. :0.9995 Peak [%] 100 80- 06040200 60- 40- 20- 0 i i i i I (Z4: 0.00 0.50 1.00 1.50 2.00 2.50 3.00 3.50 Conc. [ mg/1 ] Page 1 of 1 BRAN+LUEBBE RACE 5.48 H2M Labs Inc. Post -run chart Name of run :tkn07llO6Rl.RUN Comment Post -run chart Name of analysis :TKN.ANL min Channel 2 Method Method 2 Unit mg/1 Base 61 Gain 15 Corr. 0.9995 2 4 6 8 10 OB 0.00 1P 2.95 12 2D 2.93 3H 2.94 4L 0.01 14 5L 0.01 6C 3.02 7C 0.93 BC 0.48 Page 1 of 4 BRAN+LUEBBE AACE 5.48 3me of run :tkn071106R1.RUN „omment Post -run chart Name of analysis :TKN.Ak min 9C 0.24 10C 0•.12 11C 0.00 18 12QC1 0.66 13QC1 5.41 14QC1 0.64 20 15S 1.39 16S 0.92 17S 1.22 22 18S 2.46 19S 0.91 20S 4.71 24 21S 0.70 22S 3.14 23S 1.37 26 24S 1.16 25QC1 0.95 - 26QC1 0.00 28 27S 1.81 28S 0.82 29S 0.89 30 30S 2.56 31S 0.79 32S 0.67 32 33S 0.87 34S 1.21 35S 2.03 � 34 36S 5.10 Page 2 of 4 C) C) UD BRAN+LUEBBE RACE 5.48 ame of run :tkn071106R1.RUN omment Post -run Chart Name of analysis :TKN.ANL Page 3 of 4 min 37QC1 0.94 38QC1 0.00 36 39S 1.32 40S 1.63 41S 0.99 38 42S 1.28 43S 1.18 S 5.26* 40 S 5.19* S 5.19* 47S 1.90 42 48S 1.01 49QC1 1.07 5OQC1 0.20 94 51S 26.49 52S 6.26 53S 1.79 ' 46 54S 1.19 55S 11.34 56S 3.04 98 57S 4.67 58S 4.77 59QC1 0.93 50 i 60QC1 0.00 61D 2.93 52 62B 0.00 Page 3 of 4 BRAN+LUEBBE RACE 5.48 lame of run :tkn07llO6R1.RUN :ommen t— Post-run chart Name of analysis :TKN.ANL 62B 0.00 min 54 56 58 60 62 64 66 68 70 72 Page 4 of 4 00 O O V1 H ,6,03�t6 s" TKNData Peak SampleID 1PcT$L 0010 C o /O Z -2-- Concentration listed after Optical Blank Correction. Concentration Preparation dilution factor not applied to results. SampTy Cone Units: DF Cone x DF AnalDate AnalTime TestCod 1 Primer PRIM 3 1ngll 1 L� 7/11/2006 01:37:17 PM TKN W 2 Drift DRIF 3.01 mgll 1 3:01 7/11/2006 01:37:56 PM TKN_W 3 High HIGH 3.01 mg/I 1 3.01 7/11/2006 01:38:37 PM TKNW 4 Low IOW 0.01 mgll 1 O.OI 7/11/2006 01:39:15 PM TKN W 5 Low LOW 0.01 mg/I 1 0.01 7/11/2006 01:39:56 PM TKN W 6 Cal. CALB 3.02 mg/l 1 3.02 7/11/2006 01:40:37 PM TKNW 7 Cal. CALB 0.95 mg/1 1 0.95 7/11/2006 01:41:17 PM TKN W 8 Cal. CALB 0.48 mg/l 1 0.48 7/11/2006 01:41:53 PM TKN W 9 Cal. CALB 025 iiig%I{ 1 0.25 7/11/2006 01:42:32 PM TKN W 10 Cal. CALB 0.11 mg/l 1 0.11 7/11/2006 01:43:08 PM TKN_W 11 Cal. CALB 0.02 mg/I 1 0.02 7/11/2006 01:43:58 PM TKN W 12 OPTICALBLK QUAL 0.66 mg/1 1 0.66 7/11/2006 01:44:37 PM TKN W L 13 LCSI 17453 'T U =i1- I "JjLCS ReL I9% 0.489 mg/I 10 4.89 7/11/2006 01:45:17 PM TKN_W 14 MB117453 MBLKG0• 0 mg/l 1 7/11/2006 01:45:57 PM TKN W 15 0606916-006C M W- 4i -h sAMP 0.253 mg/! 10 2.53 7/11/2006 01:46:31 PM TKN_W 16 0607080-009D PW- � tN SAMP 0.285 mg/1 20 5.7 7/11/2006 01:47:17 PM TKN_W 17 0607080-01 OD I' 75 sAMP 0.7725 mg/I 20 15.45 7/11/2006 01:47:58 PM TKN W 18 0607080-011D J s � SAMP 4.934 m � 20 98.68 7/11/2006 01:48:39 PM TKN_W tb�� c�.pA- 19 0606912 001H GcW-y 532-=- • SAMP 0.5 mg/I 5 2.5 7/11/2006 01:49:16 PM TKN W 01. i2c 1.--0-23 20 LFBI-r�=y,�. LFB Qe-c-,64 .471 mg/l 10 4.71 7/11!2006 01:49:59 PM TKN_W 21 LFBDI LFBD RP I) 2.0`/b 0.46 mg/I 10 4.6 7/11/2006 01:50:39 PM TKN_W 22 CCV 1.0 CCV eec-iiye 0.99 mg/1 1 0.99 7/11/2006 01:51:19 PM TKN_W 23 CCB CCB G 0. 10 0.1 mg/I 1 D.] 7/11/2006 01:51:59 PM TKN W 24 Drift DRIF 3.01 mg/l 1 3.01 7/11/2006 01:52:36 PM TKN_W 25 End END -0.02 m@/1 1 0.02 7/11/2006 01:54:39 PM TKN_W 7/11/2006 2:10:21 PM Page I of 1 O O Cn BRAN+LUEBBE AACE 5.48 Name of Run TKN 071106AR1 Date of Report 7/11/2006 Date of Run 7/11/2006 Operator Comment 2 17453 H2M Labs Inc. Post -run report Name of Analysis :TKN.ANL System No. :1 Type of System :TRAACS Start/Stop time :13:26 - 13:54 Channel Type Real Data Channel 2 2 Method Method 2 Dilution Unit mg/l mg/l Calibr. Fit Linear Corr. Coeff. 0.9996 Base 61 Gain 16 Sensitivity 0.4625 Sample Limit 1 Sample Limit 2 Pk Cup Sample Id Value Value 0 0 B Baseline -0.02 0 1 1 P Primer 3.00 1 2 1 D Drift 3.01 1 3 1 H1 High 3.01 1 4 0 L1 Low 0.01 1 5 0 L1 Low 0.01 1 6 1 C Cal. 3.02 1 7 2 C Cal. 0.95 1 8 3 C Cal. 0.48 1 9 4 C Cal. 0.25 1 10 5 C Cal. 0.11 1 11 0 C Cal. 0.02 1 12 8 QC1 OPTICAL BLK 0.66 1 13 9 QC1 LCS1 17453 5.55 10 14 10 QC1 MBI 17453 0.66 1 15 11 S 0606916-006C 3.19 10 16 12 S 0607080-009D 6.36 20 17 13 S 0607080-010D 16.11 20 18 14 S 0607080-011D 99.34 20 19 15 S 0606912-001H 3.16 5 TKN.ANL / TKN 071106ARl.run Page 1 Post -run Report BRAN+LUEBBE AACE 5.48 2 Post -run Report 20 16 S LFB1 5.37 10 21 17 S LFBD1 5.26 10 22 2 QC1 CCV 1.0 0.99 1 23 0 QC1 CCB 0.10 1 24 1 D Drift 3.01 1 25 0 B FinalBase -0.02 1 QC Limits Channel 2 QC 1 Unused QC 2 Unused QC 3 Unused QC 4 Unused QC 5 Unused QC 6 Unused QC 7 Unused QC 8 Unused QC 9 Unused QC10 Unused CORRECTIONS Channel 2 Baseline Yes Drift Yes Carry over Yes %. 0.8 ** <END OF REPORT> ** TKN.ANL / TKN 071106ARl.run Page 2 BRAN+LUEBBE AACE 5.46 H2M Labs Inc. Calibration Curve Name of run :TKN 071106AR1.RUN Comment Calibration Curve Name of analysis :TKN.ANL Channel :2 Method :Method 2 Curve fit :linear a= -2.8648E-001 b=8.0780E-005 Corr. coeff. :0.9996 Peak [%] 100 80 60 40 20 Z 0 0.00 0.50 1.00 1.50 2.00 2.50 3.00 3.50 Conc. [ mg/l ] Page 1 of 1 BRAN+LUEBBE RACE 5.48 H2M Labs Inc. Post -run chart Name of run :TKN 071106AR1.RUN Comment Post -run chart Name of analysis :TKN.ANL min Channel 2 Method Method 2 Unit mg/1 Base 61 Gain 16 Corr. 0.9996 j 2 4 6 8 10 OB -0.02 1P 3.00 12 2D 3.01 3H 3.01 4L 0.01 5L 0.01 14 6C 3.02 7C 0.95irl I 8C 0.481 Page 1 of 2 BRAN+LUEBBE RACE 5.48 dame of run :TKN 071106AR1.RUN ,omment Post -run chart Name of analysis :TKN.ANL min 9C 0.25 10C 0.11 11C 0.02 18 12QC1 0.66 13QC1 5.55 14QC1 0.66 20 15S 3.19 16S 6.36 17S 16.11 22 5 99.34* 19S 3.16 20S 5.37 24 I 21S 5.26 22QC1 0.99 23QC1 0.10 26 24D 3.01 28 25B -0.02 30 32 34 Page 2 of 2 9 V1( Cot 012. �2/� L, US19 12- LAUS19 Isca PVU,006 PC CqW 0,02 - TOTAL YXO'SITKN DIGESTIONS 516tt ft SAMPLE SAMPLE FINAL I., NAME: k-pvr- DATE: gw — Wd 141 Or f - LAB NO. CLIENT ID WEIGHT GRAMS VOLUME MLS VOLUME MLS DATE ANALYZED SPIKE qrZ^ pok g it— 1p 9rb-ov -Y Got vise 1(e oto -o0 Y. YK job NEI IH2A LAAS,INC. TOTAL YR6S/TldT DIGESTIONS NAME.. -H kvr, Ae��,� DATE.: q�10- PY, LAB N.O. CLIENT, ID SAMPLE WEIGHT GRAMS SAMPLE VOLUME MIS- FINAL VOLUME MLS DATE ANALYZED SPIKE -190 FW, 1090-0070- ova, -s5p- —9 7 oro vgo- Otto lig-0,0 spec 50 -1 V'- Y, I tS- Imulm �Tl Multiple Analysis Report Print Date/Time: 2006/07/07 8:45:10 Sample ID Result Std. Dev. RSD Mode ALT Method ID Sample Type Vial Timestamp Message ID1 0.1010 0 10.57 Sample LCS�:"1S q-'\ ?9 x'.22.3078 .0907 15.34 TOC TOC TOCaWASTE Psp2 WATER Sample 1 2006/07/06006/07/06 115032 ICB �" Gj-0 0.1707 0.0675 39.52 TOC TOC WASTE WATER Sample 2 2006/07/06 16:03 Low Sample -0 Detected CRI. ......... �� . 0.8640... 0.0836.. 9.67... TOC TOC WASTE WATER ...Sample 3..2006/07/06 16:34.Low Sample -D Detected MBLK <i-0 -0.2993 0.0894 -29.87 TOC TOC WASTE WATER Sample 4 2006/07/06 17:05 Low Sample -0 Detected 0606916-001A ECY <J-0 0.0430 0.0956 222.44 TOC TOC WASTE WATER Sample 5 2006/07/06 17:36 Low Sample -0 Detected 0606916-002A.Mi,O7N 0.3952... 0.0584.. 14.78 ... TOC TOC WASTE WATER' ...Sample 6..2006/07/06 18:07.Low Sample -0 Detected 0606916-003A MW -`S 41-0 0.5129 0.1841 35.90 TOC TOC WASTE WATER Sample 7 2006/07/06 18:38 Low Sample -0 Detected 0606916-004A M"'- 30 /-1.6 0.4624 0.1454 31.44 TOC TOC WASTE WATER Sample 8 2006/07/06 19:09 Low Sample -P Detected 0606916-005A.MW_ 3Y...Ab9 0.5843... 0.0396.. 6.78... TOC TOC WASTE WATER ...Sample 9..2006/07/06 19:37.Low Sample -0 Detected i 0606916-005AMSIr:ra` Mq- 9.5185 0.1812 1.90 TOC TOC WASTE WATER Sample 10 2006/07/06 20:10 0606916-005ADUP iRaW^N(� 0.9006 0.0773 8.59 TOC TOC WASTE WATER Sample 11 2006/07/06 20:38 Low Sample -0 Detected �w� yo 0606916-006A ... ........... 1.9172... 0.0376.. 1.96... TOC TOC WASTE WATER ...Sample 12..2006/07/06 21:12.Low Sample -0 Detected 0606916-007A MW -4S 1.7385 0.0699 4.02 TOC TOC WASTE WATER Sample 13 2006/07/06 21:43 Low Sample -0 Detected 0606916-OOBA MW -5�a1-0 0.9819 0.2087 21.25 TOC TOC WASTE WATER Sample 14 2006/07/06 22:15 Low Sample -P Detected Q? CCV. TIL:.LS�S:.........9.P 23.3567... 0.5660.. 2.42... TOC TOC WASTE WATER ...Sample 15..2006/07/06 22:45. CCB G%-0 0.1515 0.1223 80.76 TOC TOC WASTE WATER Sample 16 2006/07/06 23:16 Low Sample -D Detected 0606916-009A MW'SS 1.8082 0.0676 3.74 TOC TOC WASTE WATER Sample 17 2006/07/06 23:47 Low Sample •D Detected MW-�Q 3 0606916-010A...........L.1: 0.6773... 0.0878.. 12.97... TOC TOC WASTE WATER ...Sample 18..2006/07/07 00:18.Low Sample -P Detected 0606916-011A MW< 41-6 0.6867 0.0699 10.18 TOC TOC WASTE WATER Sample 19 2006/07/07 00:46 Low Sample -0 Detected 0606916-012A MW_ as et -4- 1.0504 0.0656 6.25 TOC TOC WASTE WATER Sample 20 2006/07/07 01:20 Low Sample -0 Detected 0606916-013A M,- t5.....zi.G 0.8123... 0.0766.. 9.43 ... TOC TOC WASTE WATER ...Sample 21..2006/07/07 01:51.Low Sample -0 Detected CCV TV:'ZSef{h rl' 22.3605 0.8127 3.63 TOC TOC WASTE WATER Sample 22 2006/07/07 02:22 CCB Ll -0 -0.6122 0.0717 -11.72 TOC TOC WASTE WATER Sample 23 2006/07/07 02:49 Low Sample -0 Detected Printed: 7/7/06 8:45:10 AM AM Page 1 of 1 -0 Detailed Analysis Report Print Date/Time: 2006/07/07 8:45:12 Sample ID: ID1 Mode: UTILITY Method: Cleaning Procedure Filename: 07061437 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/06 15:01 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.0940 0.0470 15790 9.045 9.241 115 2 0.0901 0.0451 15431 9.050 9.249 117 3 0.1069 0.0535 16970 9.037 9.236 116 4 0.1128 0.0564 17504 9.015 9.213 117 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 0.1010 Std Dev: 0.0107 RSD: 10.57 Sample ID: LCS Mode: TOC Method: TOC WASTE WATER Filename: 07061437 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/06 15:32 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 22.3996 1.1200 212336 9.085 10.082 109 2 23.0565 1.1528 218352 9.066 10.056 111 3 20.5969 1.0298 195825 9.057 10.052 109 4 23.1780 1.1589 219465 9.033 10.028 110 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 22.3078 Std Dev: 1.1907 RSD: 5.34 Sample ID: ICB Mode: TOC Method: TOC WASTE WATER Filename: 07061437 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/06 16:03 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.2644 0.0132 9599 8.999 9.019 120 2 0.1327 0.0066 8393 9.004., 8.993 120 3 0.1122 0.0056 8205 8.995' 8.991 120 4 0.1736 0.0067 8768 9.001 9.032 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 0.1707 Std Dev: 0.0675 RSD: 39.52 Sample ID: CRI Mode: TOC - Method: TOC WASTE WATER Filename: 07061437 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/06 16:34 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.7801 0.0390 14323 9.074 9.126 120 2 0.8806 0.0440 15243 9.092 9.106 120 3 0.8221 0.0411 14708 9.109 9.105 120 4 0.9730 0.0487 16090 9.095 -------------------------------------- 9.122 120 -------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 0.8640 Std Dev: 0..0836 RSD: 9.67 Sample ID: MBLK Mode: TOC Method: TOC WASTE WATER Filename: 07061437 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/06 17:05 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.3213 -0.0161 4235 9.185 9.170 120 2 -0.1696 -0.0085 5624 9.148 9.142 120 Printed: 7/7/06 8:45:12 AM AM Page 1 of 6 Printed: 717/06 8:45:12 AM AM Page 2 of 6 3 -0.3322 -0.0166 4135 9.140 9.116 120 4 -0.3741 -0.0187 3751 9.108 9.088 120 --------------------------- 1 Last Message: Low Sample Detected Q <<<Statistics>>> Mean: -0.2993 Std Dev: 0.0894 RSD: -29.87 Sample ID: 0606916-001A Mode: TOC Method: TOC WASTE WATER Filename: 07061437 \10 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/06 17:36 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.0894 -0.0045 6359 9.023 9.029 120 2 0.0910 0.0046 8012 9.010 9.031 120 3 0.1302 0.0065 8370 9.013 9.024 120 4 0.0402 0.0020 7546 9.019 9.047 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 0.0430 Std Dev: 0.0956 RSD: 222.44 Sample ID: 0606916-002A Mode: TOC Method: TOC WASTE WATER Filename: 07061437 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/06 18:07 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.3886 0.0194 10737 9.097 9.102 120 2 0.4641 0.0232 11429 9.081 9.080 120 3 0.4058 0.0203 10895 9.096 9.091 120 4 0.3222 0.0161 10128 9.120 9.137 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 0.3952 Std Dev: 0.0584 RSD: 14.78 Sample ID: 0606916-003A Mode: TOC Method: TOC WASTE WATER Filename: 07061437 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/06 18:38 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.7017 0.0351 13605 9.152 9.149 120 2 0.6353 0.0318 12996 9.144 9.166 120 3 0.3940 0.0197 10786 9.096 9.072 120 4 0.3207 0.0160 10115 9.079 9.0.60 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 0.5129 Std Dev: 0.1841 RSD: 35.90 Sample ID: 0606916-004A Mode: TOC Method: TOC WASTE WATER Filename: 07061437 Cala Curve: TOC WW CURVE 070506 Timestamp: 2006/07/06 19:09 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.6124 0.0306 12787 8.903 8.898 120 2 0.5396 0.0270 12120 8.887 8.899 120 3 0.4162 0.0208 10989 8.863 8.872 120 4 0.2813 0.0141 9754 8.823 8.786 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 0.4624 Std Dev: 0.1454 RSD: 31.44 Sample ID: 0606916-005A Mode: TOC Method: TOC WASTE 'WATER Filename: 07061437 Printed: 717/06 8:45:12 AM AM Page 2 of 6 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/06 19:37 H Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time O 1 0.6211 0.0311 12866 8.686 8.656 120 2 0.5765- 0.0288 12458 8.637 8.651 120 3 0.6078 0.0304 12745 8.602 8.614 120 4 0.5319 0.0266 12050 8578 8541 120 00 ---------------------------------------------_-------_----------- - O Last Message: Low Sample Detected <<<Statistics>>> Mean: 0.5843 Std Dev: 0.0396 RSD: 6.78 Sample ID: 0606916-005AMS Mode: TOC Method: TOC WASTE WATER Filename: 07061437 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/06 20:10 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 9.6995 0.4850 96015 8.506 9.501 104 2 9.3349 0.4667 92676 8.494 9.491 103. 3 9.6465 0.4823 95530 8.481 9.467 103 4 9.3933 0.4697 93211 8.475 9.462 103 ------------------------------------------------------------------------------ <<<Statistics>>> Mean: 9.5185 Std Dev: 0.1812 RSD: 1.90 Sample ID: 0606916-005ADUP Mode: TOC Method: ' TOC WASTE WATER Filename: 07061437 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/06 20:38 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.9902 0.0495 16247 8.505 8.518 120 2 0.8206 0.0410 14694 8.501 8.483 120 3, 0.9374 0.0469 15763 8.497 8.523 120 4 0.8542 0.0427 15001 8.512 8.511 120 ----------------------------------------------------------------_------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 0.9006 Std Dev: 0.0773 RSD: 8.59 Sample ID: 0606916-006A Mode: TOC Method: TOC WASTE WATER Filename: 07061437 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/06 21:12 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 1.9463 0.0973 ' 25003 8.562 8.579 120 2 1.9490 0.0975 25029 8.571 8.585 120 3 1.8706 0.0935 24310 8.564 8.589 120 4 1.9028 0.0951 24605 8.570 8.635 120 --------------------------- ------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 1.9172 Std Dev: 0:0376 RSD: 1.96 Sample ID: 0606916-007A Mode: TOC Method: TOC WASTE WATER Filename: 07061437 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/06 21:43 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 1.8074 0.0904 23731 8.666 8.687 120 2 1.7193 0.0860 22925 8.706 8.725 120 3 1.7781 0.0889 23463 8.716 8.769 120 4 1.6493 0.0825 22284 8.778 8.764 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected Printed: 7/7/06 8:45:12 AM AM Page 3 of 6 y r O O 00 <<<Statistics>>> Mean: 1.7385 Std Dev: 0.0699 RSD: 4.02 2 0.2003 Sample ID: 0606916-008A Mode: TOC 3 -0.0298 Method: TOC WASTE WATER Filename: 07061437 10.020 120 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/06 22:15 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Sample ID: 0606916-009A Mode: Baseline Baseline Time 1 1.1668 0.0583 17865 8.937 8.997 120 2 0.9086 0.0454 15499 9.015 9.059 120 3 1.1322 0.0566 17547 9..075 9.157 120 4 0.7202 0.0360 13774 9.256 9.288 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected 10.118 120 3 1.8074 0.0904 23732 <<<Statistics>>> Mean: 0.9819 Std Dev: 0.2087 RSD: 21.25 10.102 ------------------------------------- Sample ID: CCV --------------------------------------- Last Message: Low Sample Detected Mode: TOC <<<Statistics>>> Method: TOC WASTE WATER Filename: 07061437 RSD: 3.74 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/06 22:45 Operator ID: JASON SAMUEL Sample Type: Sample Cal. Curve: TOC Rep # ppm C ug C Raw Data Beginning Ending Integration Type: Sample Rep # ppm C ug C Raw Data Baseline Baseline Time 1 22.6743 1.1437 216683 9.646 10.641 110 2 22.8665 1.1433 216612 9.690 10.687 109 3 23.7561 1.1878 224760 9.706 10.699 109 4 23.9300 1.1965 226352 9.738 10.727 110 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 23.3567 Std Dev: 0.5660 RSD: 2.42 Sample ID: CCB Method: TOC WASTE WATER Cal. Curve: TOC WW CURVE 070506 Operator ID: JASON SAMUEL Rep # ppm C ug C Raw Data Mode: TOC Filename: 07061437 Timestamp: 2006/07/06 23:16 Sample Type: Sample Beginning Ending Integration Baseline Baseline Time 1 0.1967 0.0098 8979 9.927 9.966 120 2 0.2003 0.0100 9012 9.957 10.012 120 3 -0.0298 -0.0015 6904 10.019 10.020 120 4 0.2387 0.0119 9364 10.016 10.050 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 0.1515 Std Dev: 0.1223 RSD: 80.76 Sample ID: 0606916-009A Mode: TOC Method: TOC WASTE WATER Filename: 07061437 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/06 23:47 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 1.7969 0.0898 23636 10.121 10.113 120 2 1.8964 0.0948 24547 10.099 10.118 120 3 1.8074 0.0904 23732 10.111 10.119 120 4 1.7321 0.0866 23042 10.102 ------------------------------------- 10.112 120 --------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 1.8082 Std Dev: 0.0676 RSD: 3.74 Sample ID: 0606916-010A Mode: TOC Method: TOC WASTE WATER Filename: 07061437 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/07 00:18 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time Printed: 7/7/06 8:45:12 AM AM Page 4 of 6 Printed: 7/7/06 8:45:12 AM AM Page 5 of 6 1 0.5688 0.0284 12387 10.069. 10.062 120 2 0.6481 0.0324 13114 10.014 10.000 120 3 0.7231 0.0362 13800 9.967 10.002 120 r 4 0.7690 0.0384 14221 9.941 9.979 120 O----------------------------------------------------------------------------- O Last Message: Low Sample Detected D1 <<<Statistics>>> Mean: 0.6773 Std Dev: 0.0878 RSD: 12.97 00 N Sample ID: 0606916-011A Mode: TOC Method: TOC WASTE WATER Filename: 07061437 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/07 00:46 Operator ID: JASON SAMUEL :Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.7558 0.0378 14100 9.938 9.942 120 2 0.6912 0.0346 13509 9.925 9.945 120 3 0.5901 0.0295 12582 9.921 9.933 120 4 0.7097 0.0355 13678 9.906 9.935 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 0.6867 Std Dev: 0.0699 RSD: 10.18 Sample ID: 0606916-012A Mode: TOC - Method: TOC WASTE WATER Filename: 07061437 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/07 01:20 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 1.0934 0.0547 17193 9..91.5;. 9.920 120 2 1.0612 0.0531 16897 9'.912`.'. 9.938 120 3 1.0926 0.0546 17185 9.906 9.924 120 4 0.9546 0.0477 15921 9.908 9.919 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: 1.0504 Std Dev: 0.0656 RSD: 6.25 Sample ID: 0606916-013A Mode: TOC Method: TOC WASTE WATER Filename: 07061437 Cal. Curve: TOC WW -CURVE 070506 Timestamp: 2006/07/07 01:51 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.8224 0.0411 14710 9.909 9.920 120 2 0.8630 0.0432 15082 9.890 9.901 120 3 0.8628 0.0431 15080 9.881 9.917 120 4 0.7011 0.0351 13599 9.876 -------------------------- 9.860 120 -------------------------------------- Last Message: Low Sample Detected ;. , <<<Statistics>>> Mean: 0.8123 Std Dev: 0.0766 RSD: 9.43 Sample ID: CCV Mode; TOC Method: TOC WASTE WATER Filename: 07061437 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/07 02:22 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 22.8237 1.1412 216220 9.862 10.861 109 2 23.2688 1.1634 220297 9.890 10.876 109 3 21.7010 1.0851 205937 9.873 10.863 109 4 21.6486 1.0824 205458 9.887 10.877 108 ----------------------------------------------------------------------------- <<<Statistics>>> Mean: 22.3605 Std Dev: 0.8127 RSD: 3.63 Sample ID: CCB Mode: TOC Printed: 7/7/06 8:45:12 AM AM Page 5 of 6 H r 00 W Method: TOC WASTE WATER Filename: 07061437 Cal. Curve: TOC WW CURVE 070506 Timestamp: 2006/07/07 02:49 Operator ID: JASON SAMUEL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.7113 -0.0356 663 9.563 9.490 120 2 -0.6188 -0.0309 1510 9.450 9.362 120 3 -0.5600 -0.0280 2049 9.351 9.312 120 4 -0.5588 -0.0279 2059 9.276 9.237 120 ----------------------------------------------------------------------------- Last Message: Low Sample Detected <<<Statistics>>> Mean: -0.6122 Std Dev: 0.0717 RSD: -11.72 Printed: 7/7/06 8:45:12 AM AM Page 6 of 6 Printed: 7/7/06 8:45:16 AM AM Page 1 of 1 Calibration Report Print Date/Time: 2006/07/07 8:45:16 y Cal. Curve ID: TOC WW CURVE 070506 r Created: 2006/07/05 15:12 O Calibration Factor (m): 1.832e+05 O Y Intercept (b): -2039 r -squared: 0.99674 Standard ID Y X Expected Measured Message Date & 00 Raw Data ug C ug C Time -P DI 7797 0.000 0.054 Low Samnle De 2006/07/05 12:10 0.5PPM 10767 0.025 0.070 Low Sample De 2006/07/05 12:33 l.OPPM 18159 0.050 0.110 Low Sample De 2006/07/05 12:57 5.OPPM 37896 0.250 0.218 2006/07/05 13:19 10.OPPM 83483 0.500 0.467 2006/07/05 13:41 25.OPPM 209989 1.250 1.157 2006/07/05 14:04 50.OPPM 435296 2.500 2.387 2006/07/05 14:26 75.OPPM 705277 3.750 3.861 2006/07/05 14:49 Printed: 7/7/06 8:45:16 AM AM Page 1 of 1 U2M "U%S INC. SDG NO.: Ts- , SCAN: This data package was reported by the undersigned. This reporting includes data calculations, manual edits if necessary and compilation of raw data. The information presented is true and correct to the best of my knowledge. Signature:. Date: Date.