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Home My WebLink AboutSample Data Summary Package 06/2006i Analytical Data Package For TOWN OF SOUTHOLD PART 360 ROUTINE SDG NO: TSL006 0 Water Samples Received: 6/23/06 SAMPLE DATA SUMMARY PACKAGE JUNE 2006 EInvironmental Testing Laboratories . 575 Broad Hollow Road, Melville, N.Y. 11747 U -12A ILAUS' IMC• SAMPLE DATA SUMMARY PACKAGE TABLE OF CONTENTS TOWN OF SOUTHOLD PART 360 ROUTINE WATER SAMPLES SAMPLES RECEIVED: 6/23/06 SDG NO.: TSL006 1. NYS DEC SUMMARY FORMS 2. CHAIN OF CUSTODY DOCUMENTATION 3. SDG NARRATIVES 4. SAMPLE REPORTS 4.1 METALS 4.2 WET CHEMISTRY 5. DUPLICATE SUMMARY RESULTS 5.1 METALS 5.2 WET CHEMISTRY 6. SPIKE SAMPLE RESULTS 6.1 METALS 6.2 WET CHEMISTRY 7. BLANK SUMMARY DATA AND RESULTS 7.1 METALS 7.2 WET CHEMISTRY "2M ILAUS, INC. NYS DEC SUMMARY FORMS N cn O O NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE IDENTIFICATION AND ANALYTICAL REQUIREMENT SUMMARY SDG: TSL006 Anal ical Requirements Customer Sample Code Laboratory Sample Code ME we �EQPT 0606916-001 X X i —__ LMW-1D _ 0606916-002 X i X MW -1S 0606916-003 X i X MW -3D 0606916-004 X X MW -3S _ 0606916-005 X (� X IMW-4D _ 0606916-006 X X M W -4S0606916-007 Mw 5D 0606916-008 X E X X_ MW -5S i 0606916-009 �X X X I MW -6D 0606916-010 X X - MW -6S00660669116-011 X _ I X IMW-8D lmw-8S—� 060I 6916-012 0606916-013 X I X ' X X'{ CL -CLP lease indicate year of protocol) /('f TCUTAL, HSL, Priority Pollutant, /WYS- B ki-S ;XXIA)6 NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG: TSI-006INORGANIC ANALYSIS Laboratory Samp ID Client Sample ID Matrix ` Metals Requested DateRecd at Lab I Date Analyzed i 0606916-001 !EQPT WATER CA,CD,FE,K,MG,MN,NA,PB, 23 -Jun -06 I 06/06 0606916-002 MW -1D WATER I CA,CD,FE,K,MG,MN,NA,PB, 123 -Jun -06 06/06 0606916-003 MW -IS WATER I CA,CD,FE,K,MG,MN,NA,PB, 23 -Jun -06 06/06 0606916-004 JMW-3D WATER I CA,CD,FE,K,MG,MN,NA,PB, 23 -Jun -06 06/06 0606916-005 IMW-3S I WATER CA,CD,FE,K,MG,MN,NA,PB, 23 -Jun -06 I 06/06 0606916-005DUP BMW-3SD I 0606916-005MS (MW-3SS 0606916-006 'MW -4D WATER WATER WATER CA,CD,FE,K,MG,MN,NA,PB, CA,CD,FE,K,MG,MN,NA,PB, CA,CD,FE,K,MG,MN,NA,PB, i 23 -Jun -06 06/06 23 -Jun -06 I 06/06 23 -Jun -06 I 06/06 0606916-007 BMW -4S WATER I CA,CD,FE,K,MG,MN,NA,PB, 23 -Jun -06 06/06 0606916-008 IMW-5D I WATER +'CA,CD,FE,K,MG,MN,NA,PB, 23 -Jun -06 I 06/06 0606916-009 jMW-5S WATER I CA,CD,FE,K,MG,MN,NA,PB, 23 -Jun -06 06/06 0606916-010 1MW-6D I WATER CA,CD,FE,K,MG,MN,NA,PB, 23 -Jun -06 06/06 0606916-011 iMW-6S I WATER CA,CD,FE,K,MG,MN,NA,PB, i 23 -Jun -06 I 06/06 0606916-012 IMW-8D I WATER I CA,CD,FE,K,MG,MN,NA,PB, 23 -Jun -06 I 06/06 0606916-013 BMW -8S i WATER CA,CD,FE,K,MG,MN,NA,PB, ( 23 -Jun -06 06/06 TSL006 S4 NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG: TSI-006INORGANIC ANALYSIS Laboratory Samp ID (Client Sample ID Matrix I Tests ,DateRecd j at Lab I Date i Analyze 0606916-001 j EQPT I Blank I SELECT WET CHEMISTRY ** € 06/23/06 ( 06/06 - 07/06 0606916-002 MW -ID Groundwater j SELECT WET CHEMISTRY ** 06/23/06 06/06 - 07/06 0606916-003 MW -IS Groundwater SELECT WET CHEMISTRY ** i 06/23/06 06/06 - 07/06 0606916-004 ; MW -3D Groundwater SELECT WET CHEMISTRY ** 06/23/06 j 06/06 - 07/06 0606916-005 MW -3S Groundwater ? SELECT WET CHEMISTRY ** 06/23/06 ' 06/06 - 07/06 0606916-005DUP ( MW-3SDUP Groundwater SELECT WET CHEMISTRY ** i 06/23/06 06/06 -07/06 0606916-005MS j MW-3SMS j Groundwater SELECT WET CHEMISTRY ** 06/23/06 06/06 - 07/06 0606916-006 MW -41) Groundwater SELECT WET CHEMISTRY ** 06/23/06 ( 06/06 - 07/06 0606916-007 MW -4S j Groundwater ! SELECT WET CHEMISTRY ** i 06/23/06 ` 06/06 - 07/06 0606916-008 MW -51) Groundwater SELECT WET CHEMISTRY ** I 06/23/06 06106 - 07/06 0606916-009 { MW -5S j Groundwater j SELECT WET CHEMISTRY ** 06/23/06 06/06 - 07/06 0606916-010 MW -6D Groundwater 1 SELECT WET CHEMISTRY ** 06/23/06 06/06 - 07/06 0606916-011 MW -6S Groundwater 1 SELECT WET CHEMISTRY ** j 06/23/06 f 06/06 - 07/06 0606916-012 j MW -8D Groundwater SELECT WET CHEMISTRY ** f 06/23/06 06/06 - 07/06 0606916-013 ( MW -8S Groundwater SELECT WET CHEMISTRY ** 06/23/06 I 06/06 - 07/06 ** Alkalinity, Total (As CaCO3) ; Biochemical Oxygen Demand ; Bromide; Chemical Oxygen Demand; Chloride; Hardness (As CaCO3) ; Nitrate as N ; Nitrogen, Ammonia (As N) ; Nitrogen, Kjeldahl, Total ; Phenolics, Total Recoverable ; Sulfate; Total Dissolved Solids; Total Organic Carbon ; O O F-+ V2AA ILA13S, INC. 2. CHAIN OF CUSTODY DOCUMENTATION "Us INC. .57.5 Arnad Hnl/nur Rd_ Melville_ NY 99747-5076 153-0 EXTERNAL CHAIN OF CUSTODY • Tel: (516) 694-3040 Fax. (516) 420.8436 CLIENT: 1-12M SDG NO: PROJECT NAME/NUMBER j 1014-,W V 0 i' SViTkd 1i0 � y�� R `c f A i QW V L 3 1 C0 0 v p E ° 1 TV 0 > \ e� a NOTES: Project Contact: BR C � (= C L. / So L' f Phone Number. 1 1 1L1/L T-r��' s Y C2) COD J NH3 N'0 3� Q hswL s TKN SAMPLERS: (signature)/Client DELIVERABXES: 86-70 a 0 Z o v I- 1 ANALYSIS REQUESTED TURNAROUND TIME: S76 ORGANIC INORG. DATE TIME MATRIXFIELD I.D. m. °m a� r 1 CI) Z U LAB I.D. NO. REMARKS: e 123A6 /2o v L, M W- I S 9 3 a1 1 moroWo-003 /13 W -- 1 6 $ 1 z 1 -- 02 as3 0 w— s a 361k 3 -005 M S MS D ogoo — I 112 �- la) 0'730 W — (o S 3 ( 1 211 1/00 — 2 S 1 1 2 1 -- 3 j03 'M Relinquis b : (Si re) Date Time Received b :(signature) Date Time 13'.S$ LABORATORY USE ONLY Discrepancies Between Sample Labels and COC Record? Y or N Explain: Samples were: 1. Shipped_ or Hand Delivered_ Airbill# 2. Ambient or chilled 3. Received in good condition: Y or N Property preserved: Y or N 4. Samples 5. Samples returned to lab _ Hrs from collection. COC Tape was: 1. Present on outer package: Y or N 2. Unbroken on outer package: Y or N 3. COC record present & complete upon sample receipt: YorN elinquish by: (Signature) D e Time Received by: (Signature) Date Time Relinquished by: (Signature) Date Time Received by: (Signature) Date Time Relinquished by: (Signature) Date Time Received by: (Signature) Date Time V�/8k@ftW- ORIGINAL YELLOW COPY - CLIENT PINK COPY - LABORATORY A I PS.9 ING LI—of— m-4 mfi�h�ffh% MV447A7.-CA79 187 ^In EXTERNAL CHAIN OF CUSTODY ,0/0 Oroau n4wilw" I\vl .! Te►: (631) 694-3040 Fax. (631) 420-8436 PROJECT NAME/NUMBER .SOH �r0 0 —F/� / OW,� / d F cS0UTH,d 1 -IJ -3(20 Rd (_Tr7AfF 20e6 02 CLIENT: c $ A CL rn a . � O _'yamz p -� -- I H2M SDG NO: TS L NOTES: Project Contact: (I) m) 5/ BR C'T CL .sot Phone Number: �'oT, ISLK } MS X ) 4 g q PIS/Quote # GCOO NH3 TKJ SAMPLERS: (signature Client 6ELIVERABLES:0 C — � � o v ANALYSIS REQUESTED TURNAROUND TIME:S T D ORGANIC J I INORG. . U\ �� J Z V LAB I.D. NO. REMARKS: DATE TIME IMATRIXFIELD I.D. h2 It/. �Ioo. 893 o —4s M W— 4,b 19 3 1 a -moo .. 4 /000 /030 //00 A,W - 5S P. -r J � � Reiinqui by: (S Ralk�quiahed by. (Signature) Date e Tim9 Time Reeebved try (s Received by: (Signature) �� Date Time Time LABORATORY USE ONLY Discrepancies Between Sample Labels and COC Record? Y or N Explain, Samples were: t. ed_ Hand Delivered_ AtrbiikM 2 Ambi Ambient or chiNIiad, Temp 3. Received in good condition: Y or N 4. Property preserved: Y or N COC Tape web: t. Present on outer package: Y or N Z Unbroken on outer package: Y or N 3. COC recon! present 6 complete upon sample receipt: YcrN Relinquished by: (Signature) Date Tlme Received try. (Signature) Date Tfine Relinquished by (Signature) Date Time Received by: (Signature) Date Time T/fIL@0Z�Q8S — ORIGINAL YELLOW COPY — CLIENT PINK COPY — LABORATORY H21VI LABS, INC. Client Name PCTSL Work Order Numbe 0606916 Sample Receipt Checklist Date and Time Receive Received by PS -FSL- 0 C:) b 6/23/2006 1:58:00 PM Checklist completed b _ (9 2 06 Reviewed byA6) G D--� Signature Initials Date Matrix Carrier name Hand Delivered Shipping container/cooler in good condition? Yes 0 No ❑ Not Applicable ❑ Custody seals intact on shippping container/cooler? Yes ❑ No ❑ Not Applicable 0 Custody seals intact on sample bottles? Yes ❑ No ❑ Not Applicable Chain of custody present? Yes 0 No ❑ Chain of custody signed when relinquished and received? Yes No ❑ Chain of custody agrees with sample labels? Yes No ❑ Samples in proper container/bottle? Yes 9 No ❑ Sample containers intact? Yes No ❑ Sufficient sample volume for indicated test? Yes No ❑ \II samples received within holding time? Yes No ❑ t;ontainer/Temp Blank temperature in compliance? Yes 66 No ❑ Water - VOA vials have zero headspace? No VOA vials submitted ❑ Yes 2 No ❑ Water - pH acceptable upon receipt? Yes ❑d No ❑ Adjusted? Checked b Any No and/or NA (not applicable) response must be detailed in the comments section b — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — - ----------------------------------------------- Client contacted Contacted by: Comments: Corrective Action Date contacted: Regarding Person contacted Ln INOO O t� E—I IH2A LABS, INCO INFERNAL CHAIN OF CUSTODY CLIENT: FCTS L DELIVERABLES: - TURNAROUND TRAE: 21 T>Q!t& SDG 9: -!rrLQQG CASE MATRIX: GfOUMMA?y pH CHFCK@.. N REMARKS:— PIS PcTsL 05 PS gwo&Ta"W_ RECEIVED BY:. . SIGNAWRE__PATE: a3 —:58 CLIENT ID t12M LAB DATE COLLECTED ROME TYPE ' 0 OF BOTT LES17__ TESTS REQUESTED EQPT opal IE: CO- G-22,0� Ej . - 3D S Msi --Qp4E \V _MF_F O - ocGE s 5D • _mqE -2-3- 06 -011 E: -ol2E -c513E. W 62 `METALS P 0232 ��M ��►�as, Isco ,•LlErrr • �C�L_— r sm Ts Loo INTERNAL CHAIN OF CUSTODY DATE TIME SAMPLE RELINQUISHED BY SAMPLE RECEIVED BY BOTTLE TYPE PURPOSE OF CHANGE OF CUSTODY INIT 23 15�y HI SI E tq - - Blow 3I031 sIa31 slow mica slat 3IO31 slow 91031 BION 31031 Siam SION SIGH SIGN SIGN SION SIG" slom S17 SIGN GN SION SIGN SION CN SIGH SSON SIow SION SION SIGN ' Slow SIGN 3Iow SIGH ON SION SIOw SIGN ,ION SIG" SIGN SIGN 910" SIGN METALS P 0233 WAA LATS, INC, INTERNAL CHAIN OF CUSTODY cLmwr: K -'Tr, L DELIVERABLES: 05—IOD TURN AROUND TIME:_21 Txlur, Jr— SDG SDG#: . TSI -006 CASE 4: MATRIX: Gtuffidwow pH CHECK& REMARKS: ,pjs_j� ()q7 PCTSL 05 RECEWM BY: _SIGNATURF_j25ATE:*AMTU-W- 13 :5$ WET CHEMISTRY P 0283 i Pt, DAM !COLLECTED; �01 MINIM IMIRIMMIlmo. 0111101110 Elm, 1 0 MENRIM 111MENIMMomm MlIllMMMl= 111MMINEN IN Immilm HIM I El OEM is ME Elmom I - ME � MEN IME ammias'n, want I mpflow MEN WET CHEMISTRY P 0283 CLIEW: PC T& L a -sL 00cp INTERNAL CHAIN OF CUSTODY 0:1 �w WET CHEMISTRY VIA UAUS, INCW SDG INTERNAL CHAIN OF.CUSTODY W.ETCHEMISTRY P 0285 FL 0 r+ SAMPLE RECE . BY sx I sI BOTTLEINIT TYPE PURPOSE OF CHANGE OF CUSTODY DATE TIME 'SAMPLE RELINQUISHED BY LD aI IION SION SlOrm slow jpx cw SION slow fix Blom 3910W SION SIGN slobt Blom SION SICK SIGN SIGN SION SIGN SION BION 31om SIGN SIGN SIGN Slott 91 11 31" SION SIow SIGN SILO" Slott -SION SION Slott Slott 310H -7Z---- 31" $1014 SIG)z SIGN sxctl SIO SIGN. W.ETCHEMISTRY P 0285 FL 0 r+ u2A IAU*' INC, 3. SDG NARRATIVES U2M IAUS� INC. For Samples: NARRATIVE FOR METALS ANALYSES SAMPLE RECEIVED: 6/23/06 SDG#: TSL006 EQPT MW -5D MW -1D MW -5S MW -1S MW -6D MW -3D MW -6S MW -3S MS/MSD MW -8D MW -4D MW -8S MW -4S Thirteen water samples were received by H2M Labs, Inc. on 6/23/06 for select metals analysis. Samples were prepared and analyzed using EPA method 6010B with a TJA61E Trace ICP instrument. Sample MW -3S was utilized for QC analysis and reporting. TCP serial analysis did not reproduce within acceptance ranges for iron. Iron data was reported flagged `B" on Forms 1 and 9. No other problems were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: June 30, 2006 T � Vincent Stancampiano Vice President O O C/) N 1-128t "US41 1NC. For Samples: SDG NARRATIVE FOR WET CHEMISTRY SAMPLE RECEIVED: 6/23/06 SDG#: TSL006 EQPT MW -5D MW -1D MW -5S MW -IS MW -61) MW -3D MW -6S MW -3S MS/MSD MW -81) MW -4D MW -8S MW -4S EPA 325.2 Thirteen water samples were received by H2M Labs, Inc. on 6/23/06 for select wet chemistry analysis. Samples were prepared and analyzed using the following methods: Alkalinity EPA 310.1 Nitrate EPA 353.2 BOD EPA 405.1 Phenols EPA420.1 Bromide EPA 320.1 Sulfate EPA 9038 Chloride EPA 325.2 TDS EPA 160.1 COD EPA 410.4 TKN EPA 351.2 Hardness EPA 130.2 TOC EPA 9060 Ammonia EPA 350.1 Sample MW -3S was utilized for QC analysis and reporting Ammonia sample value for MW -8S (0.38 mg/L) was greater than the total kjeldahl nitrogen value (0.18 mg/L). The values slightly exceeded ± the CRDL of 0.1 mg/L. Duplicate TKN analysis did not reproduce within ± the CRDL of 0.1 mg/L (when value is less than five times the CRDL). Biochemical oxygen demand (BOD) analysis of sample MW -4D did not fall within the analytical dilution range (> 66 mg/L BOD). The reported BOD value of 182mg/L was estimated from the chemical oxygen demand (COD) analysis. No other problems were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: July 14, 2006 Vincent Stancampiano Vice President 2A® ILAI3S' INC, 4. SAMPLE REPORTS 4.1 METALS 4.2 WET CHEMISTRY U284 "US, INC. QUALIFIERS FOR METALS ANALYSIS Q (Quality Control) Qualifiers E - The reported value is estimated because of the presence of interference. An explanatory note is included in the SDG narrative. M - Duplicate injection precision not met. N - Matrix spike sample recovery not within control limits. S- The reported value was determined by the Method of Standard Additions (MSA). + - Correlation coefficient for the MSA is less than 0.995 W - Post digestion spike for Furnace AA analysis is out of control limits (85-115%), while sample absorbance is less than 50% of spike absorbance. * - Duplicate analysis is not within control limits_ C (Concentration) Qualifiers B - Entered if the reported value is less than the Contract Required Detection Limit (CRDL) but greater than the Instrument Detection Limit (IDL). U - Entered if the analyte was analyzed for but not detected, i.e., less than the IDL. M (Method) Qualifiers P - Analyzed by ICP. A - Analyzed by Flame AA. F - Analyzed by Furnace AA. CV - Analyzed by Manual Cold Vapor techniques. AV - Analyzed by Automated Cold Vapor techniques. C - Analyzed by Manual Spectrophotometric Method. CA- Analyzed by Midi -distillation Spectrophotometric Method. NR- Analyte not Required. U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.67 B P 7440-70-2 Calcium 122 B P 7439-89-6 Iron 45.3 BE P 7439-92-1 ILead 1.9 U P 7439-95-4 Magnesium 10.3 B P 7439-96-5 Manganese 0.63 U P 7440-09-7 Potassium 41.2 B P 7440-23-5 Sodium 163 B .P Color Before: COLORLESS Clarity Before: Color After: COLORLESS Clarity After: Comments: DATEREPORTED: JUNE 29, 2006 EPA SAMPLE NO EQPT SDG No.: TSL006 6/23/2006 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 ULA "USS ISCo 575BroadHckw Road, Mdvae NY 11747 LABORATORY RESULTS (631) 6943040. FAX (631) 42()-8436 WSDOH ID# 10478 Town of Southold Landfill Lab No. : 0606916-001 Attn To : George Desmarias Collected 6/22/2006 11:00:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID. : EQPT Sample Information... Type: Blank Origin: Results Qualifier D.F. Units Method Number Analyzed < 1.0 1 mg/L E310.1 06/28/2006 11:25 AM < 2 1 mg/L E405.1 06/23/2006 5:15 PM < 0.5 1 mg/L E320.1 07/11/2006 11:20 AM < 2.0 1 mg/L E325.2 06/29/2006 11:21 AM <10 1 mg/L E410.4 07/03/2006 12:35 PM < 5.0 1 mg/L E130.2 07/11/2006 10:36 AM 0.12 1 mg/L E350.1 07/12/2006 9:34 AM < 0.10 1 mg/L E353.2 06/27/2006 1:02 PM < 5.0 1 pg/L E420.1 07/11/2006 8:30 AM < 5.0 1 mg/L SW9038 07/10/2006 2:40 PM 13 1 mg/L E160.1 06/27/2006 4:28 PM 0.73 1 mg/L E351.2 07/11/2006 11:00 AM < 1.0 1 mg/L SW9060 07/06/2006 5:36 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 1 of 13 Laboratory Manager U.S. EPA - CLP CAS No. Analyte I EPA SAMPLE NO M INORGANIC ANALYSIS DATA SHEET 0.34 U P 7440-70-2 Calcium 1210 MW -1D Lab Name: H2M LABS INC. Contract: 204 E P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL006 Matrix (soil/water): WATER Lab Sample ID: 0606916-002 Level (low/med): LOW Date Received: 6/23/2006 o Solids: 0.0 P 7440-09-7 Concentration Units (ug/L or mg/kg dry weight): UG/L 355 CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.34 U P 7440-70-2 Calcium 1210 B P 7439-89-6 Iron 204 E P 7439-92-1 Lead 1.9 U P 7439-95-4 Magnesium 231 B P 7439-96-5 Manganese 2.8 B P 7440-09-7 Potassium 355 B P 7440-23-5 Sodium 17900 P Color Before: COLORLESS_ Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: JUNE 29, 2006 FORM I - IN ILM04.1 IH2A "US, INC, 575Broad tcnow Road, Md,ae NY 11747 LABORATORY RESULTS (631)694-4340. FAX (631)4208436 WSDOH ID#10478 Sample Information... Town of Southold Landfill Lab No. : 0606916-002 Type : Groundwater Origin: Attn To George Desmadas Client ID. : MW -1D Collected 6/23/2006 11:30:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analvzed Alkalinity, Total (As CaCO3) 21.5 1 mg/L E310.1 06/28/200611:30 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/23/2006 5:20 PM Bromide < 0.5 1 mg/L E320.1 07/11/2006 11:30 AM Chloride 3.9 1 mg/L E325.2 06/29/2006 11:22 AM Chemical Oxygen Demand <10 1 mg/L E410.4 07/03/2006 12:36 PM Hardness (As CaCO3) < 5.0 1 mg/L E130.2 07/11/2006 10:39 AM Nitrogen, Ammonia (As N) 0.19 1 mg/L E350.1 07/12/2006 9:36 AM Nitrate as N < 0.10 1 mg/L E353.2 06/27/20061:28 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 07/11/2006 8:45 AM Sulfate 13.1 1 mg/L SW9038 07/10/2006 2:42 PM Total Dissolved Solids 77 1 mg/L E160.1 06/27/2006 4:30 PM Nitrogen, Kjeldahl, Total 0.26 1 mg/L E3512 07/11/2006 11:01 AM Total Organic Carbon < 1.0 1 mg/L SW9060 07/06/2006'6:07 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 2 of 13 i Laboratory Manager U.S: EPA - CLP Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 EPA SAMPLE NO M INORGANIC ANALYSIS DATA SHEET 0.34 U P 7990-70-2 Calcium 1090 MW -1S Lab Name: H2M LABS, INC. Contract: _ 188 E P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL006 Matrix (soil/water): WATER Lab Sample ID: 0606916-003 Level (low/med): LOW Date Received: 6/23/2006 o Solids: 0.0 P 7440-09-7 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.34 U P 7990-70-2 Calcium 1090 B P 7439-89-6 Iron _ 188 E P 7439-92-1 Lead 1.9 U P 7439-95-4 Magnesium 215 B P 7439-96-5 Manganese 2.5 B P 7440-09-7 Potassium 352 B P 7940-23-5 Sodium 17300 P Color Before: COLORLESS Clarity Before Color After. COLORLESS Clarity After: Comments: DATE REPORTED: JUNE 29, 2006 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 575BradFbua✓ Road, Mdvile NY 11747 LABORATORY RESULTS (631)694-1040. FAX (631)420-8436 NYSDOH ID#10478 Town of Southold Landfill Lab No. : 0606916-003 Attn To : George Desmarias Collected 6/23/2006 12:00:00 PM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID. : MWAS Sample Information... Type: Groundwater Origin: Results Qualifier D.F.. Units Method Number Analyzed < 1.0 1 mg/L E310.1 06/28/2006 11:35 AM < 2 1 mg/L E405.1 06/23/2006 5:25 PM < 0.5 1 mg/L E320.1 07/11/2006 11:40 AM 3.8 1 mg/L E325.2 06/29/2006 11:23 AM <10 1 mg/L E410.4 07/03/2006 12:37 PM < 5.0 1 mg/L E130.2 07/11/2006 10:42 AM < 0.10 1 mg/L E350.1 07/12/2006 9:37 AM < 0.10 1 mg/L E353.2 06/27/2006 1:30 PM < 5.0 1 pg/L E420.1 07/11/2006 9:00 AM 61.8 2.5 mg/L SW9038 07/10/2006 2:44 PM 125 1 mg/L E160.1 06/27/2006 4:32 PM 0.56 1 mg/L E351.2 07/11/2006 11:01 AM < 1.0 1 mg/L SW9060 07/06/2006 6:38 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 3 of 13 Laboratory Manager in N O Cl F --I U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.34 U P 7440-70-2 Calcium 1020 B P 7439-89-6 Iron 185 E P 7439-92-1 Lead 1.9 U P 7439-95-4 Magnesium 227 B P 7439-96-5 Manganese 11.8 B P 7440-09-7 Potassium 1190 B P 7440-23-5 Sodium 20200 P Color Before: COLORLESS Clarity Before: Color After: COLORLESS Clarity After: Comments: DATE REPORTED: JUNE 29, 2006 EPA SAMPLE NO MW -3D SDG No.: TSL006 6/23/2006 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 U2M "Uss INC, 575 BroadHc&w Road, Mile NY 11747 LABORATORY RESULTS (631)694-3040. FAX (631)4208436 NYSDOH ID#10178 Town of Southold Landfill Lab No. : 0606916-004 Attn To George Desmarias Collected 6/23/2006 9:00:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original Cc Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID.: MW -313 Sample Information... Type : Groundwater Origin: Results Qualifier D.F. Units Method Number Analyzed 4-8 1 mg/L E310.1 06/28/2006 11:40 AM 33 1 mg/L E405.1 06/23/2006 5:30 PM < 0.5 1 mg/L E320.1 07/11/2006 11:50 AM 4-4 1 mg/L E325.2 06/29/2006 11:23 AM 134 1 mg/L E410.4 07/03/2006 12:38 PM < 5.0 1 mg/L El 30.2 07/11/2006 10:45 AM 0.14 1 mg/L E350-1 07/12/2006 9:38 AM < 0.10 1 mg/L E353.2 06/27/2006 1:31 PM 38.8 1 pg/L E420.1 07/11/2006 9:15 AM < 5.0 1 mg/.L SW9038 07/10/2006 2:46 PM 120 1 mg/L E160.1 06/27/2006 4:34 PM 1.80 1 mg/L E351.2 07/11/2006 11:02 AM < 1.0 1 mg/L SW9060 07/06/2006 7:09 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 4 of 13 aly.11, �(/ tw�� Laboratory Manager U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID Level (low/med): LOW Date Received % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.34 U P 7440-70-2 Calcium 959 B P 7439-89-6 Iron_ 2027 E P 7439-92-1 Lead 1.9 U ; P 7439-95-4 Magnesium 213 B P 7439-96-5 IManganese 2.0 B P 7440-09-7 jPotassium 319 B P 7440-23-5 Sodium 16200 P Color Before: COLORLESS Clarity Before Color After: COLORLESS Clarity After: Comments: DATE REPORTED: JUNE 29, 2006 EPA SAMPLE NO MW-3S� SDG No.: TSL006 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 00 N O O U2M IAUS' INC, 575 Broad Hcbm Road, Mdvae NY 11747 LABORATORY RESULTS (631)694.3040. FAX (631)4208436 NYSDOH ID# 10478 Town of Southold Landfill Lab No. : 0606916-005 Attn To George Desmarias Collected 6/23/2006 8:30:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID. : MW -3S Sample Information... Type : Groundwater Origin: Results Qualifier D.F. Units Method Number Analyzed 31.0 1 mg/L E310.1 06/28/2006 11:45 AM < 2 1 mg/L E405.1 06/23/2006 5:35 PM < 0.5 1 mg/L E320.1 07/11/2006 12:00 PM 3.9 1 mg/L E325.2 06/29/2006 11:24 AM <10 1 mg/L E410.4 07/03/2006 12:39 PM < 5.0 1 mg/L E130.2 07/11/2006 10:48 AM 0.15 1 mg/L E350.1 07/12/2006 9:39 AM 0.10 1 mg/L E353.2 06/27/2006 1:35 PM 5.0 1 pg/L E42b.1 07/11/2006 9:30 AM < 5.0 1 mg/L SW9038 07/10/2006 2:48 PM 75 1 mg/L E160.1 06/27/2006 4:36 PM 0.25 1 mg/L E351.2 07/11/2006 11:03 AM < 1.0 1 mg/L SW9060 07/06/2006 7:37 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 5 of 13 Laboratory Manager N O O L�L U.S. EPA - CLP Concentration Units_(ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 EPA SAMPLE NO Q INORGANIC ANALYSIS DATA SHEET Cadmium 0.34 U P 7440-70-2 MW -9D Lab Name: H2M LABS, INC. Contract: P 7439-89-6 Iron Lab Code: 10478 Case No. SAS No.: SDG No.: TSL006 Matrix (soil/water): WATER Lab Sample ID: 0606916-006 Level (low/med): LOW Date Received: 6/23/2006 % Solids: 0.0 P Concentration Units_(ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.34 U P 7440-70-2 Calcium 1150 B P 7439-89-6 Iron 208 E P 7439-92-1 Lead 1.9 U P 7439-95-4 Magnesium 323 B P 7439-96-5 Manganese 38.7 P 7440-09-7 Potassium 3620 B P 7440-23-5 Sodium 24900 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: JUNE 29, 2006 FORM I - IN ILM04.1 O M O O C/1 F-+ U2A l U%s INC, 575BroadHrAwr Road, Mdvae NY 11747 LABORATORY RESULTS (631) 6N-3040 _ FAX (631)420-8436 NYSDOH ID#10178 Town of Southold Landfill Lab No. 0606916-006 Attn To George Desmarias Collected 6/22/2006 9:30:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID. : MW -4D Sample Information... Type : Groundwater Origin: Results Qualifier D.F. Units Method Number Analyzed 6.4 1 mg/L E310.1 06/28/2006 12:00 PM est. 182 1 mg1L E405.1 06/23/2006 5:45 PM < 0.5 1 mg/L E320.1 07/11/2006 12:30 PM 4.2 1 mg/L E325.2 06/29/2006 11:26 AM 260 1 mg/L E410.4 07/03/2006 12:42 PM < 5.0 1 mg/L E130.2 07111 /2006 10:57 AM 0.28 1 mg/L E350.1 07/12/2006 9:43 AM < 0.10 1 mg/L E353.2 06/27/2006 1:38 PM 49.3 1 pg/L E420.1 07/11/2006 10:15 AM < 5.0 1 mg/L SW9038 07/10/2006 2:54 PM 217 1 mg/L E160.1 06/27/2006 4:42 PM 2.53 10 mg/L E351.2 07/11/2006 1:46 PM 1.9 1 mg/L SW9060 07/06/2006 9:12 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 6 of 13 Qrml Laboratory Manager U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID Level (low/med): LOW Date Received % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. I Analyte Concentration C Q M 7440-43-9 lCadmium 0.34 U P 7440-70-2 Calcium 943 B P 7439-89-6 jIron _ 200 E P 7439-92-1 Lead 1.9 U P 7439-95-4 Magnesium 211 B P 7439-96-5 Manganese 2.1 B P 7440-0.9-7 Potassium 295 B P 7440-23-5 Sodium _ 15900 P EPA SAMPLE NO MW -4S I SDG No.: TSL006 0606916-007 6/23/2006 Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: JUNE 29, 2006 FORM I - IN ILM04.1 N M O O V) E-+ 1H2M "US, INC, 57513roadH9low Road, Mdvaa NY 11747 (631)694.';040.FAX (631)42084W NYSDOHID#10478 Town of Southold Landfill Attn To George Desmadas Collected 6/22/2006 9:00:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC LABORATORY RESULTS Lab No. : 0606916-007 Client ID. : MW -4S Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 32.6 1 mg/L E310.1 06/28/2006 12:05 PM Biochemical Oxygen Demand 11 1 mg/L E405.1 06/23/2006 5:50 PM Bromide 0.6 1 mg/L E320.1 07/11/2006 12:40 PM Chloride 3.9 1 mg/L E325.2 06/29/2006 11:27 AM Chemical Oxygen Demand 23.6 1 mg/L E410.4 07/03/2006 12:43 PM Hardness (As CaCO3) 5.0 1 mg/L E130.2 07/11/2006 11:00 AM Nitrogen, Ammonia (As N) 0.24 1 mg/L E350.1 07/12/2006 9:44 AM Nitrate as N < 0.10 1 mg/L E353.2 06/27/2006 1:39 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 07/11/2006 10:30 AM Sulfate < 5.0 1 mg/L SW9038 07/10/2006 2:56 PM Total Dissolved Solids 75 1 mg/L E160.1 06/27/2006 4:44 PM Nitrogen, Kjeldahl, Total 0.71 1 mg/L E351.2 07/11/2006 11:05 AM Total Organic Carbon 1.7 1 mg/L SW9060 07/06/2006 9:43 PM Qualifiers: E,- Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 7 of 13 Laboratory Manager U.S. EPA - CLP Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 EPA SAMPLE NO M INORGANIC ANALYSIS DATA SHEET 0.34 U P 7440-70-2 Calcium 1060 B MW -SD Lab Name: H2M LABS, INC. Contract: E P 7439-92-1 Lab Code: 10478 Case No. SAS No.: SDG No.: TSL006 Matrix (soil/water): WATER Lab Sample ID: 0606916-008 Level (low/med): LOW Date Received: 6/23/2006 % Solids: 0.0 7440-09-7 Potassium Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.34 U P 7440-70-2 Calcium 1060 B P 7439-89-6 Iron 185 E P 7439-92-1 Lead 1.9 U P 7439-95-4 Magnesium 234 B P 7439-96-5 Manganese 11.0 B P 7440-09-7 Potassium 1110 B P 7440-23-5 Sodium _ _ 175001 _ P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: JUNE 29, 2006 FORM.I - IN ILM04.1 d' M Cl] O O C/) E-+ 12A* "US, INC. 575 BroadHo5w Road, Mtdvde NY 11747 (631)694-3040.FAX (631)42084W WSDOHID#10478 Town of Southold Landfill Attn To George Desmarias Collected 6/22/2006 10:30:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC LABORATORY RESULTS Lab No. : 0606916-008 Client ID. : MW -5D Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310.1 06/28/2006 12:10 PM Biochemical Oxygen Demand 30 1 mg/L E405.1 06/23/2006 5:55 PM Bromide < 0.5 1 mg/L E320.1 07/11/2006 12:50 PM Chloride '4.1 1 mg/L E325.2 06/29/2006 11:27 AM Chemical Oxygen Demand 21.1 1 mg/L E410.4 07/03/2006 12:44 PM Hardness (As CaCO3) < 5.0 1 mg/L E130.2 07/11/200611:03 AM Nitrogen, Ammonia (As N) 0.10 1 mg/L E350.1 07/12/2006 9:45 AM Nitrate as N < 0.10 1 mg/L E353.2 06/27/2006 1:41 PM Phenolics, Total Recoverable 7.6 1 pg/L E420.1 07/11/2006 10:45 AM Sulfate < 5.0 1 mg/L SW9038 07/10/2006 2:58 PM Total Dissolved Solids 115 1 mg/L E160.1 06/27/2006 4:46 PM Nitrogen, Kjeldahl, Total 0.50 1 mg/L E351.2 07/11/2006 11:06 AM Total Organic Carbon < 1.0 1 mg/L SW9060 07/06/2006 10:15 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 8 of 13 Laboratory Manager M O C) i.-� Cn U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration I CI Q M 7440-43-9 ICadmium 0.34 U P 7440-70-2 lCalcium 1090 B I P 7439-89-6 lIron 216 1 E P 7439-92-1 jLead 1.9 U 1 P 7439-95-4 Magnesium 226 B I P 7439-96-5 Manganese 2.21 B I P 7440-09-7 Potassium 332 B P 7440-23-5 Sodium 16800 P Color Before: COLORLESS Clarity Before: Color After: COLORLESS Clarity After: Comments: DATE REPORTED: JUNE 29, 2006 EPA SAMPLE NO MW -5S SDG No.: TSL006 0606916-009 6/23/2006 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 U2A "U%s INC, 575 BroadHcl1W Road, MdvZe NY 11747 LABORATORY RESULTS (631)694-3 .FAX(631)4W8436 NYSDOHID#10478 Sample Information... Town of Southold Landfill Lab No. : 0606916-009 Type : Groundwater ' Origin: Attn To George Desmarias Client ID.: MW -5S Collected 6/22/2006 10:00:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 32.6 1 mg/L E310.1 06/28/2006 12:25 PM Biochemical Oxygen Demand 18 1 mg/L E405.1 06/23/2006 6:00 PM Bromide < 0.5 1 mg/L E320.1 07/11/2006 1:00 PM Chloride 4.0 1 mg/L E325.2 06/29/2006 11:29 AM Chemical Oxygen Demand 38.7 1 mg/L E410.4 07/03/2006 12:45 PM Hardness (As CaCO3) < 5.0 1 mg/L E130.2 07/11/2006 11:06 AM Nitrogen, Ammonia (As N) 0.38 1 mg/L E350.1 07/12/2006 9:51 AM Nitrate as N < 0.10 1 mg/L E353.2 06/27/2006 1:42 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 07/11/2006 11:00 AM Sulfate < 5.0 1 mg/L SW9038 07/10/2006 3:00 PM Total Dissolved Solids 70 1 mg/L E160.1 06/27/2006 4:48 PM Nitrogen, Kjeldahl, Total 1.15 1 mg/L E351.2 07/11/2006 11:08 AM Total Organic Carbon 1.8 1 mg/L SW9060 07/06/2006 11:47 PM 0 Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 9 of 13 Laboratory Manager U.S. EPA - CLP CAS No. Analyte 1 EPA SAMPLE NO M INORGANIC ANALYSIS DATA SHEET 0.34 U P 7440-70-2 MW -6D Lab Name: H2M LABS, INC. Contract: 7439-89-6 Lab Code: 10478 Case No. SAS No.: SDG No.: TSL006 Matrix (soil/water): WATER Lab Sample ID: 0606916-010 Level (low/med): LOW Date Received: 6/23/2006 % Solids: 0.0 7439-96-5 Imanganese Concentration Units (ug/L or mg/kg dry weight): UG/L B CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.34 U P 7440-70-2 Calcium 1080 B P 7439-89-6 Iron 243 E P 7439-92-1 Lead 1.9 U P 7439-95-4 IMagnesium 232 B I P 7439-96-5 Imanganese 2.7 B P 7440-09-7 1potassium 377 B P 7440-23-5 ISodium 17500 P _ Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: JUNE 29, 2006 FORM I - IN ILM04.1 00 M O O V) H 1-2M I USs INC. 57513[wdHc0ow Road, Mdvie NY 11747 (631) 6943040. FAX (631)4205436 NYSDOH ID#10478 Town of Southold Landfill Attn To George Desmarias Collected 6/23/200610:00:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC LABORATORY RESULTS Lab No. : 0606916-010 Client ID.: MW -6D Sample Information... Type : Groundwater Origin: Parameters) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310-1 06/28/2006 12:30 PM • Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/23/2006 6:05 PM Bromide < 0.5 1 mg/L E320.1 07/11/2006 1:10 PM Chloride 4.0 1 mg/L E325.2 06/29/2006 11:30 AM Chemical Oxygen Demand <10 1 mg/L E410.4 07/03/2006 12:46 PM Hardness (As CaCO3) 5.0 1 mg/L El 30.2 07/11/2006 11:09 AM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 07/12/2006 9:52 AM Nitrate as N < 0.10 1 mg/L E353.2 06/27/2006 1:43 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 07/11/2006 11:15 AM Sulfate 36-4 1 mg/L SW9038 07/10/2006 3:02 PM Total Dissolved Solids 82 1 mg/L E160.1 06/27/2006 4:50 PM Nitrogen, Kjeldahl, Total 0.16 1 mg/L E351.2 07/11/2006 11:09 AM Total Organic Carbon < 1.0 1 mg/L SW9060 07/07/2006 12:18 AM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 10 of 13 awl'. Laboratory Manager U.S. EPA - CLP % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. FAnalyte Concentration 1 EPA SAMPLE NO M INORGANIC ANALYSIS DATA SHEET U P 7940-70-2lCalcium 1100 B MW -61 Lab Name: H2M LABS, INC. Contract: E P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL006 Matrix (soil/water): WATER Lab Sample ID: 0606916-011 Level (low/med): LOW Date Received: 6/23/2006 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. FAnalyte Concentration C Q M 7440-43-9 (Cadmium 0.34 U P 7940-70-2lCalcium 1100 B P -6 7939-89Iron 208 E P 7439-92-1 Tead 1.9 U P ,Magnesium 221 B P 17439-95-4- 7439-96-5 Manganese 2.4 B P 7440-09-7 Potassium 370 B P 7440-23-5 Sodium 17600 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After. COLORLESS Clarity After: CLEAR - Artifacts: Comments: DATE REPORTED: JUNE 29, 2006 FORM I - IN ILM04.1 O 7t O O h U2M IAUS, INC, 575 BroadHc[lov Road, Mdvie NY 11747 LABORATORY RESULTS (631)694-.',040. FAX- (631)4MB436 NYSDOHID#10178 Town of Southold Landfill Lab No. : 0606916-01 Attn To George Desmadas Collected 6/23/2006 9:30:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID. : MW -6S Sample Information... Type: Groundwater Origin: Results Qualifier D.F.. Units Method Number Analyzed 2.8 1 mg/L E310.1 06/28/2006 12:35 PM < 2 1 mg/L E405.1 06/23/2006 6:10 PM < 0.5 1 mg/L E320.1 07/11/2006 1:20 PM 3.8 1 mg/L E325.2 06/29/2006 11:31 AM <10 1 mg/L E410-4 07/03/2006 12:47 PM < 5.0 1 mg/L E1302 07/11/2006 11:12 AM 0.23 1 mg/L E350.1 07/12/2006 9:53 AM < 0.10 1 mg/L E353.2 06/27/2006 1:44 PM < 5.0 1 pg/L E420.1 07/11/2006 11:30 AM 32.7 1 mg/L SW9038 07/10/2006 3:04 PM 78 1 mg/L E160.1 06/27/2006 4:52 PM 0.23 1 mg/L E351.2 07/11/2006 11:09 AM < 1.0 1 mg/L SW9060 07/07/200612:46 AM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 11 of 13 Laboratory Manager U.S. EPA -'CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID Level (low/med): LOW Date Received % Solids: 0.0 Concentration Units (ug/L or mg/kg dry .weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.34 U P 7440-70-2 lCalcium 1370 B P 7439-89-6 1.1ron 207 E P 7439-92-1 Lead 1.9 U P 7439-95-4 Magnesium 303 B P 7439-96-5 Manganese 26.3 P 7440-09-7 Potassium 2660 B P 7440-23-5 Sodium 230001 P Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: CLEAR Comments: DATE REPORTED: JUNE 29, 2006 EPA SAMPLE NO MW -8D SDG No.: TSL006 6/23/2006 Texture: Artifacts: FORM I - IN ILM04.1 U28t LAUs, INC. 575 BroadFICbv Road, MJV5e NY 11747 LABORATORY RESULTS (631) ag-3040. FAX (631)4208436 NYSDOH ID# 10478 Town of Southold Landfill Lab No. : 0606916-012 Attn To George Desmadas Collected 6123/2006 10:30:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID. : MW -8D Sample Information... Type : Groundwater Origin: Results Qualifier D.F. Units Method Number Analyzed < 1.0 1 mg/L E310.1 06/28/2006 12:40 PM 53 1 mg/L E405.1 06/23/2006 6:15 PM <0.5 1 mg/L E320.1 07/11/20061:30 PM 4.5 1 mg/L E325.2 06/29/2006 11:32 AM 134 1 mg/L E410.4 07/03/2006 12:48 PM < 5.0 1 mg/L E130.2 07/11/2006 11:15 AM 0.36 1 mg/L E350.1 07/12/2006 9:54 AM < 0.10 1 mg/L E353.2 06/27/2006 1:45 PM 39.6 1 pg/L E420.1 07/11/2006 11:45 AM < 5.0 1 mg/L SW9038 07/10/2006 3:06 PM 174 1 mg/L E160.1 06/27/2006 4:54 PM 1.90 1 mg/L E351.2 07/11/2006 11:10 AM 1.1 1 mg/L SW9060 07/07/2006 1:20 AM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 12 of 13 Laboratory Manager U.S_ EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID Level (low/med): LOW Date Received % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.34 U P 7440-70-2 Calcium 1310 B P 7439-89-6 Iron 207 E P 7439-92-1 ILead 1.9 U P 7439-95-4 Magnesium 244 B P 7439-96-5 Manganese 2.7 B P 7440-09-7 Potassium 511 B P 7440-23-5 jSodiLun 16900 P EPA SAMPLE NO 8S SDG SDG No.: TSL006 6/23/2006 Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED: JUNE 29, 2006 FORM I - IN _ILM04.1 U 12M "U%s INC, 575 BroadHoOov Road, Melville NY 11747 (631)69430!10. FAX (631)420&436 NYSDOH ID# 10478 Town of Southold Landfill Attn To : George Desmarias Collected 6/23/2006 11:00:00 AM Received 6/23/2006 1:58:00 PM Collected By VG Copies To Original CC LABORATORY RESULTS Lab No. : 0606916-013 Client ID. : MW -8S Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 21.4 1 mg1L E310.1 06/28/2006 12:45 PM Biochemical Oxygen Demand 2 1 mg/L E405.1 06/23/2006 6:20 PM Bromide < 0.5 1 mg/L E320.1 07/11/2006 1:40 PM Chloride 4.1 1 mg/L E325.2 06/29/2006 11:32 AM Chemical Oxygen Demand <10 1 mg/L E410.4 07/03/2006 12:49 PM Hardness (As CaCO3) 6.0 1 mg/L E130.2 07/11/2006 11:18 AM Nitrogen, Ammonia (As N) 0.38 1 mg/L E350.1 07/12/2006 9:55 AM Nitrate as N 0.12 1 mg/L E353.2 06/27/2006 1:49 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 07/11/2006 12:00 PM Sulfate 14.2 1 mg/L SW9038 07/10/2006 3:08 PM Total Dissolved Solids 67 1 mg/L E160.1 06/27/2006 4:56 PM Nitrogen, Kjeldahl, Total 0.13 1 mg/L E351.2 07/11/2006 11:11 AM Total Organic Carbon < 1.0 1 mg/L SW9060 07/07/2006 1:51 AM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 7/14/2006 Page 13 of 13 Laboratory Manager 5. DUPLICATE SAMPLE RESULTS 5.1 METALS 5.2 WET CHEMISTRY Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER % Solids for Sample: 0.0 U.S. EPA - CLP 6 EPA SAMPLE NO DUPLICATES MW -3S Contract: SAS No.: SDG No.: TSL006 Level (low/med): LOW % Solids for Duplicate: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L Analyte Control Limit Sample (S) C Duplicate (D) I C RPD Q M Cadmium 0.3439 U 0.3439 U P Calcium 5000.0000 959.1800 B 1023.4900 B 6.5 P Iron 100.0000 201.7600 215.7900 6.7 P Lead 1.9043 U 1.9043 U P Magnesium 5000.0000 213.4700 B 227.0600 B 6.2 P Manganese 15.0000 1.9700 B 2.1900 B 10.6 P Potassium 5000.0000 318.8500 B 325.2000 B 2.0 Sodium 5000.0000 16244.7300 16830.9700 MP FORM VI - IN ILM04.1 d' V) O O V) [--4 H2M LABS, INC. Date: 12 -Jul -06 QC SUMMARY REPORT SDG: TSL006 Spike Sample Recovery RPDRef %RPD SampleID: Client Sample ID: Analyte — Result Units Amount Result %REC Limits Value %RPD UCL MB -062806 MB -062806 - Alkalinity, Total (As CaCO3) < 1 mg/L LCS-062806 LCS-071106 LCS-062306 LCS-062306 Biochemical Oxygen Demand 209 mg/L LCS-062806 LCS-062806 Alkalinity, Total (As CaCO3) 24.3 mg/L 25 < 1 99 80 120 I -_ -I < 2 20 < 0.5 mg/L 0606916-005dms _ MW-3SMS jAlkalinity, Total (As CaCO3) 57.3 mg/L 25 31.0 _ 105 75 125 120 _ 0606916-005ddup MW-3SDUP lAlkalinity, Total (As CaCO3) 31.8 mg/L 31.0 2.9 20 MB -062306 MB -062306 Biochemical Oxygen Demand <2 mg/L LCS-062806 LCS-071106 LCS-062306 LCS-062306 Biochemical Oxygen Demand 209 mg/L 200 < 2 104 80 120 I 0606916-005DDUP MW-3SDUP Biochemical Oxygen Demand _ <2 _ mg/L 0606916-005Ddup _ I -_ -I < 2 20 MB -071106 MB -071106 Bromide < 0.5 1 mg/L LCS-062806 LCS-071106 LCS-071106 Bromide 4.7 mg/L 5 < 0.5 94 80 120 MW-3SMS IChemical Oxygen Demand 993 mg/L 1000 0606916-005DMS MW-3SMS Bromide 5.5 mg/L 5 < 0.5 110 75 125 _- 1� 0606916-005Ddup MW-3SDUP Bromide < 0.5 mg/L < 0.5 20 MB -062806 MB -062806 iChemical Oxygen Demand <10 mg/L mg/L �29 LCS-062806 LCS-062806 IChernical Oxygen Demand 998 mg/L 1000 <10 L 100 80 120 mg/L 50 < 80 0606916-005CMS MW-3SMS IChemical Oxygen Demand 993 mg/L 1000 <10 ! 99 75 125-� — 0606916_005CDUP MW-3SDUP --Chemical Oxygen Demand <10 - mg/L —1 _- 1� 106 mg/L 100 < 10 L i 20J MB -062906 MB -062906 Chloride 2 mg/L �29 LCS-062906 LCS-062906 7Chloride 49.4 mg/L 50 < 80 120 — 120 0606916-005DMS MW-3SMS Chloride 30.6 mg/L 25 3.9 107 75 125 106 mg/L 100 < 5 106 75 125 0606916-005DDUP MW-3SDUP Chloride 3.7 mg/L 0606916-005Bdup 3.9 - 5.1 20 MB -071106 MB -071106 Hardness (As CaCO3) < 5 mg/L LCS-071106 LCS-071106 Hardness (As CaCO3) 1030 mg/L 1000 < 5 103 80- 120 0606916-005Bms MW-3SMS Hardness (As CaCO3) 106 mg/L 100 < 5 106 75 125 0606916-005Bdup MW-3SDUP Hardness (As CaCO3) < 5 mg/L 1 <5 _ 120 TSL006 S48 QC SUMMARY REPORT SDG: TSL006 Spike Sample Recovery RPDRef %aRPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -062706 MB -062706 Nitrate aS N < 0.1 mg/L -4.1 < 0.1 116 LCS-062706 LCS-062706 INitrate as N 1.14 mg/L 1.13 < 0.1 101 80 1201 1 0606916-005Cms MW-3SMS INitrate as N 0.52 mg/L 0.5 0.10 83_I5_ 125 -� I 0606916-005Cdup MW-3SDUP !Nitrate as N < 0.1 mg/L 0.10 200 20 . MB -17454 MB -071206 Nitrogen, Ammonia (As N) 0.1 mg/L mg/L mg/L mgfL -4.1 < 0.1 116 80 --- LCS-17454 LCS-071206 - Nitrogen, Ammonia (As N) _< _ 1.07 1 < 0.1 107 80 1120 4.1 < 0.1 119 0606916-005CMS MW-3SMS Nitrogen, Ammonia (As N) 4.68 _mg/L mg/L 5 0.15 91 75 125 4.05 mg/L _ 0606916-005CDUP MW-3SDUP Nitrogen, Ammonia (As N) 0.15 mg/L 75 0606916-005CDUP 0.15 0 20 !i MB1 17453 MB 17453 LCS17453 MBI 071106 MB 071106 LCS-071106 Nitrogen, Kjeldahl, Total Nitrogen, Kjeldahl, Total Nitrogen, Kjeldahl, Total < 0.1 < 0.1 4.75 mg/L mg/L mgfL -4.1 < 0.1 116 80 120 LCS-071106 LCS-071106 1Phenolics, Total Recoverable 29.1 LCS1 17453 LCS1-071106 Nitrogen, Kjeldahl, Total 4.89 mg/L 4.1 < 0.1 119 80 120 ug7L 20 0606916-005CMS MW-3SMS Nitrogen, Kjeldahl, Total 4.05 mg/L _ 4.1 0.25 7 93 75 125 75 0606916-005CDUP MW-3SDUP Nitrogen, Kjeldahl, Total < 0.1 mg/L Sulfate 1 <5 mgfL 0.25 200 20 MB -071106 MB -071106 71PhenoIics, Total Recoverable <5 ug/L T < 5 - mg/L LCS-071106 LCS-071106 1Phenolics, Total Recoverable 29.1 ug/L 30 < 5 97 80 120 mg/L 20 0606916-005CMS MW-3SMS Phenolics, Total Recoverable 19A ug7L 20 <5 { 97 75 125 MW-3SMS Sulfate 0606916-005Cdup MW-3SDUP !Phenolics, Total Recoverable < 5 - _ ug/L _- _ 75 _ < 5 20 MB -071006 MB -071006 Sulfate T < 5 - mg/L LCS-071006 LCS-071006 Sulfate 19.7 mg/L 20 < 5 98 80 120 _ 0606916-005DMS MW-3SMS Sulfate 19.8 mg/L 20 < 5 99 75 125 _ 0606916-005Ddup MW-3SDUP Sulfate 1 <5 mgfL <5 20 TSL006 S49 QC SUMMARY REPORT SDG: TSL006 Spike Sample Recovery RPDRef %RPD Sample ID: Client SamDle ID: Analvte Result Units Amount Result %REC Limits Value %RPD UCL MB -062706 MB -062706 Total Dissolved Solids <10 mg/L LCS-062706 ILCS-062706 Total Dissolved Solids 298 mg/L 300 <10 99 80 120 0606916-005DMS MW-3SMS Total Dissolved Solids 389 mg/L 300 75 105 75 125 0606916-005DDUP MW-3SDUP Total Dissolved Solids 73 mg/L 75 2.7 20 MB -070606 MB -070606 Total Organic Carbon <1 mg/L �- LCS-070606 LCS-070606 Total Organic Carbon 22.3 mg/L 25 <1 89 80 120 0606916-005AMS MW-3SMS Total Organic Carbon 9.5 mg/L 10 < 1 95 75 125 0606916-005ADUP MW-3SDUP Notal Organic Carbon <1 mg/L j <1 20 TSL006 S50 U2A "US. INC. 6. SPIKE SAMPLE RESULTS 6.1 METALS 6.2 WET CHEMISTRY Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER % Solids for Sample: 0.0 U.S. EPA - CLP 5A SPIKE SAMPLE RECOVERY Contract: SAS No.: EPA SAMPLE NO MW-3SS SDG No.: TSL006 Level (low/med): LOW Concentration Units (ug/L or mg/kg dry weight): UG/L Analyte Control Limit %R Spiked Sample Result (SSR) C Sample Result (SR) C Spike Added (SA) %R Q M Cadmium 75-125 51.4100 0.3439 U 50.00 102.8 P Iron 75-125 1 1184.8900 201.7600 1000.00 98.3 P Lead 75-125 _ 20.1631 1.9043 U 20.00 100.8 P Manganese 75-125 516.8900 1.9700 BI 500.00 103.0 P Comments: FORM V (Part 1) - IN ILM04.1 N O O C/O 112M LABS, INC. SDG: TSL006 Date: 12 -Jul -06 QC SUMMARY REPORT Spike Sample Recovery RPDRe( %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -062806 _ _ MB -062806 Alkalinity, Total (As CaCO3) <1 mg/L mg/L < 2 99 80 — LCS-062806 - LCS-062306 ILCS-062306 LCS-062806 LCS-062806 Alkalinity, Total (As CaCO3) 24.8 mg/L 25 < 1 99 80 120 IMW-3SDUP Biochemical Oxygen Demand <2 0606916-005dms MW-3SMS Alkalinity, Total (As CaCO3) 57.3 mg/L 25 1 31.0 105 75 125 < 0,5 mg/L 0606916-005ddup MW-3SDUP Alkalinity, Total (As CaCO3) 31.8 mg/L 31.0 L2.9 20 MB -062306 MB -062306 Biochemical Oxygen Demand <2 mg/L < 2 99 80 — LCS-062806 - LCS-062306 ILCS-062306 Biochemical Oxygen Demand 209 mg/L 200 < 2 104 80 120 I 993 0606916-005DDUP IMW-3SDUP Biochemical Oxygen Demand <2 mg/L < 0.5 110 75 _12 _ 20 1 MB -071106 MB -071106 Bromide < 0.5 mg/L < 2 99 80 120 LCS-062806 ILCS-062806 LCS-071106 LCS-071106 (Bromide 4.7 mg/L 5 1 < 0.5 94 80 120 I 993 0606916-005DMS MW-3SMS — jBromide 5.5 mg/L 5 < 0.5 110 75 125F mg/L - < 10 0606916-005Ddup MW-3SDUP Bromide < 0,5 mg/L < 0.5 20 MB -062806 MB -062806 Chemical Oxygen Demand <10 mg/L I— < 2 99 80 120 LCS-062806 ILCS-062806 Chemical Oxygen Demand 998 mg/L 1000 < 10 100 80 120 i 3.9 107 75 125 0606916-005CMS MW-3SMS Chemical Oxygen Demand 993 mglL 1000 < 10 99 75 125 - '--- 75 125 0606916-005CDUP MW-3SDUP Chemical Oxygen Demand < 10 mg/L - < 10 < 5 20 MB -062906 _ MB -062906 LCS-062906 LCS-062906 IGhloride Chloride 49.4 mg/L 50 < 2 99 80 120 LCS-071106 0606916-005DMS MW-3SMS Chloride 30.6 mg/L 25 3.9 107 75 125 — d2O 0606916-005DDUP MW-3SDUP Chloride 3,7 mg/L 75 125 0606916-005Bdup J_ 3.9 5.1 Hardness (As CaCO3) MB -071106 MB -071106 — Hardness (As CaCO3) <5 mg/L LCS-071106 LCS-071106 Hardness (As CaCO3) 1030 mg/L 1000 15 103 80 120 0606916-005Bms MW-3SMS Hardness (As CaCO3) 106 mg/L 100 < 5 106 75 125 0606916-005Bdup MW-3SDUP Hardness (As CaCO3) _ < 5 mg/L < 5 20 TSL006 S53 QC SUMMARY REPORT SDG: TSL006 Spike Sample Recovery RPDRef %RPD Same ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value °/ RPD UCL MB -0 726 06 LCS-062706 MB -062706 LCS-062706 Nitrate as N Nitrate as N _ < 0.1 1.14 mg/L mg/L 1.13 < 0.1 101 80 120 20 0606916-005Cms MW-3SMS Nitrate as N 0.52 mg/L 0.5 10.10 83 75 125 { Nitrogen, Ammonia (As N) 0606916-005Cdup MW-3SDUP Nitrate as N < 0.1 mg/L 116 0606916-005CMS _L _ - 0.10 200 20 MBI 17453 MBI 071106 Nitrogen, Kjeldahl, Total MB Nitrogen, Ammonia (As N) < 0.1 mg/L 30 20 < 5 < 5 97 97 MB -17454 -071206 _ 20 _1 < 0.1 mg/L 80 120 _ 1 LCS-17454 LCS-071206 Nitrogen, Ammonia (As N) 1.07 mg/L 1 < 0.1 107 80 120 116 0606916-005CMS MW-3SMS Nitrogen, Ammonia (As N) 4.68 mg/L 5 0.15 91 75 125 119 0606916-005CDUP MW-3SDUP Nitrogen, Ammonia (As N) T0.15 mg/L mg/L 4.1 0.15 0 20 MBI 17453 MBI 071106 Nitrogen, Kjeldahl, Total < 0.1 _ mg/L 30 20 < 5 < 5 97 97 80 75 I __ 120 125 20 MB 17453 MB 071106 Nitrogen, Kjeldahl, Total < 0.1 mg/L 80 120 0606916-005DMS MW-3SMS Sulfate LCS17453 LCS-071106 Nitrogen, Kjeldahl, Total 4.75 mg/L 4.1 < 0.1 116 80 120 MW-3SDUP Sulfate _ LCS1 17453 LCS1-071106 Nitrogen, Kjeldahl, Total 4.89 mg/L 4.1 < 0.1 119 80 120 T __ 0606916-005CMS MW-3SMS Nitrogen, Kjeldahl, Total 4.05 mg/L 4.1 0.25 93 75 125 0606916-005CDUP MW-3SDUP INitrogen, Kjeldahl, Total < 0.1 mg/L _ 0_25 200 20 MB -071106 LCS-071106 - _ 0606916-005CMS 0606916-005Cdup _ MB -071106 Phenolics, Total Recoverable LCS-071106 _ Phenolics, Total Recoverable MW-3SMS Phenolics, Total Recoverable_1 MW-3SDUP (Phenolics, Total Recoverable < 5 ug/L 29.1ug/L 19.4 ug/L < 5 _L ug/L--�- 30 20 < 5 < 5 97 97 80 75 I __ 120 125 20 MB -071006 MB -071006 Sulfate < 5 mg/L LCS-071006 LCS-071006 Sulfate 19.7 mg/L 20 < 5 98 80 120 0606916-005DMS MW-3SMS Sulfate 19.8 mg/L 20 < 5 99 75 125 EEW 0606916-005Ddup MW-3SDUP Sulfate < 5 mg/L < 5 TSL006 S54 QC SUMMARY REPORT SDG: TSL006 Spike Sample Recovery RPDRef °/ RPD _Sample ID: Client Sample ID: Analyte _Result Units Amount Result %REC Limits Value °/RPD UCL ^_ MB -062706 MB -062706 Total Dissolved Solids <10 mg/L LCS-062706 LCS-062706 Total Dissolved Solids 298 mg/L 300 <10 99 80 120 0606916-005DMS MW-3SMS Total Dissolved Solids 389 mg/L 300 75 105 75 125 i2.7 20 0606916-005DDUP MW-3SDUP ITotal Dissolved Solids 73 mg/L 75 20 MB -070606 MB -070606 Total Organic Carbon LCS-070606 LCS-070606Total Organic Carbon 22.3 mg/L 25 <1 89 180 120 0606916-005AMS 0606916-005ADUP MW-3SMS MW-3SDUP ITotal Organic Carbon 9.5 ITotal Organic Carbon < 1 mg/L mglL 10 <1 95 75 125 _ <1 20 TSL006 S55 1-2M "USs 1SC. 7. BLANK SUMMARY DATA AND RESULTS 7.1 METALS 7.2 WET CHEMISTRY U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL006 Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L Analyte Initial Calib. Blank (ug/L) C Continuing Blank 1 C Calibration (ug/L) 2 C 3 C Prepa- ration Blank C M Cadmium 0.3 U 0.3 Ul 0.3 U1 0.3 U 0.344 U P Calcium 12.5 U 12.5 U 12.51 U 1 12.5 U 16.600 B P Iron 3.7 U 3.7 U 3.7 U 3.7 U 3.668 U P Lead 1.9 U 1.9 U 1.9 ul 1.9 U 1.904 U P Magnesium___ 9.7 U 9.7 U 9.7 _F; 9.7 U 9.702 P Manganese _ 0.6 U 0.6 U 0.6 U1 0.6 U 0.628 _U U P Potassium 15.9 U 19.9 B 25.0 B 22.8 B 18.100 B P Sodium 57_l B 44.2 B 48.1 B 52.4 B 114.000_B P FORM III - IN U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL006 Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L Analyte Initial Calib. Blank (ug/L) C Continuing Calibration Blank (ug/L) 1 C 2 C 3 Prepa- ration C Blank C M Cadmium 0.3 U1 P Calcium_ 12.5 U1 P Iron 3.7 ul P Lead 1.9 U P Magnesium 9.7 U P Manganese _ 0.6 U p Potassium 15.9 U p Sodium 30.4 B p 00 C!] �O O O FORM III - IN ILM04.1 112M LABS, INC. SDG: TSL006 Date: 12 -Jul -06 QC SUMMARY REPORT Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -062806 MB -062806 Alkalinity, Total (As CaCO3) <1 mg/L LCS-071106 �— 5 < 0.5 94 80 LCS-062306 LCS-062306 LCS-062806 LCS-062806 Alkalinity, Total (As CaCO3) 24.8 '57.3 T mg1L 25 < 1 99 80 120 MW-3SDUP Biochemical Oxygen Demand ^ 0606916-005dms MW-3SMS Alkalinity, Total (As CaCO3) 107 ( 75 mg-/ 25 31.0 105 75 125 3.7 1 mg/L 0606916-005ddup MW-3SDUP Alkalinity, Total (As CaCO3) 31.8 mg/L _ 31_0 2.9 20 MB -062306 MB -062306 Biochemical Oxygen Demand < 2 mg1L LCS-071106 �— 5 < 0.5 94 80 LCS-062306 LCS-062306 Biochemical Oxygen Demand 209 mg/L 200 < 2 104 80 120 MW-3SDUP Bromide < 0.5 rr 0606916-005CDUP 0606916-005DDUP MW-3SDUP Biochemical Oxygen Demand <2 mg/L 20 3.9 107 ( 75 1 <2 — 20 MB -071106 MB -071106 Bromide <0,5—mg1L <10 mg/L —T- mg/L LCS-071106 LCS-071106 Bromide 4.7 mg/L 5 < 0.5 94 80 120 0606916-005DMS MW-3SMS Bromide 5.5 mg/L 5 < 0.5 110 75 125 0606916-005Ddup MW-3SDUP Bromide < 0.5 rr 0606916-005CDUP —1 < 0.5 20 MB -062806 MB -062806 Chemical Oxygen Demand <10 mg/L <2 mg/L I LCS-062806 LCS-062806 Chemical Oxygen Demand 998 mg/L 1000 <10 100 80 120 LCS-062906 IChloride 0606916-005CMS MW-3SMS Chemical Oxygen Demand 993 mg/L 1000 <10 99 75 125 120 0606916-005CDUP MW-3SDUP Chemical Oxygen Demand < 10 mg1L Chloride < 10 I mg/L 20 MB -062906 MB -062906 Chloride <2 mg/L I 1 LCS-071106 Hardness (As CaCO3) 1030 LCS-062906 LCS-062906 IChloride 49.4 mg4 /L 50 < 2 99 1 80 120 0606916-005Bdup 0606916-005DMS MW-3SMS Chloride 30.6 I mg/L 25 3.9 107 ( 75 125 0606916-005DDUP MW-3SDUP lChloride 3.7 1 mg/L 3.9 5.1 20 MB -071106 MB -071106 Hardness (As CaCO3) <5 mg/L LCS-071106 LCS-071106 Hardness (As CaCO3) 1030 mg/L 1000 < 5 103 80 120 0606916-005Bms MW-3SMS Hardness (As CaCO3) 106 mg1L 100 < 5 106 75 125 0606916-005Bdup MW-3SDUP Hardness (As CaCO3) <5- mg/L < 5 20 TSL006 S59 QC SUMMARY REPORT SDG: TSL006 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL_^_— MB -062706 ^� MB -062706 Nitrate as N < 0.1 mg/L I_ LCS-062706 LCS-062706 INitrate as N 1.14 mg/L 1.13 < 0.1101 80 120 0606916-005Cms MW-3SMS Nitrate as N 0.52 mg/L 0.5 0.10 83 75 j 125 .0606916-005Cdup IMW-3SDUP INitrate as N < 0.1 mg/L 0.10 1 200 20 MB -17454 MB -071206 INItrogen, Ammonia (As N) < 0.1 mg/L mg/L LCS-17454 LCS-071206 Nitrogen, Ammonia (As N) 1.07 mg/L 1 < 0.1 1 107 180 1120 Nitrogen, Kjeldahl, Total 0606916-005CMS MW-3SMS Nitrogen, Ammonia (As N) 4.68 mg/L 50.15 91 75 125 _^_IPhenolics, Total Recoverable -- 0606916-005CDUP MW-3SDUP Nitrogen, Ammonia (As N) 0.15 mg/L _ mg/L 0,15 0 20 MBI 17453 MB1 071106 Nitrogen, Kjeldahl, Total < 0.1 mg/L LCS-071106 LCS-071106 MB 17453 MB 071106 Nitrogen, Kjeldahl, Total < 0.1 mg/L 120 0606916-005CMS MW-3SMS _^_IPhenolics, Total Recoverable -- 19.4 LCS17453 LCS-071106 _� Nitrogen, Kjeldahl, Total 4.75 mg/L 4.1 < 0.1 116 80 120 ug/L _ LCS1 17453 LCS1-071106 Nitrogen, Kjeldahl, Total 4.89 mg/L 4'-1 < 0:1 119 80 1 120 0606916-005CMS MW-3SMS Nitrogen, Kjeldahl, Total 4.05 mg/L 4.1 0,25 93 75 125 _ _ 0606916-005CDUP MW-3SDUP Nitrogen, Kjeldahl, Total < 0.1 mg/L 0.25 _ 200 20 MB -071106 MB -071106 Phenolics, Total Recoverable < 5 I ug/L LCS-071106 LCS-071106 IlDhenolics, Total Recoverable 29.1 f ug/L 30 < 597 80 120 9880 120 0606916-005CMS MW-3SMS _^_IPhenolics, Total Recoverable -- 19.4 ug/L 20 < 5 97 75 1125 —� < 5 99 75 0606916-005Cdup MW-3SDUP IIPP enolics, Total Recoverable <5 ug/L _ <5 _ 20 MB -071006 MB -071006 Sulfate < 5 mg/L LCS-071006 LCS-071006 Sulfate 19.7 mg/L 20 < 5 9880 120 0606916-005DMS MW-3SMS Sulfate 19.8 mglL 20 < 5 99 75 125 0606916-005Ddup MW-3SDUP Sulfate — < 5 mg/L < 5 _ 20 TSL006 S60 QC SUMMARY REPORT SDG: TSL006 Spike Sample Recovery RPDRef %RPD _Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -062706 MB -062706 Total Dissolved Solids <10 mglL _ LCS-062706 LCS-062706 Total Dissolved Solids 298 mglL 300 <10 99 80 120 . 89 80 120 0606916-005DMS MW-3SMS Total Dissolved Solids 389 mglL 300 75 105 75 125 95 125 F 0606916-005DDUP MW-3SDUP Total Dissolved Solids 73 mgrL _^ _75 I 2.7 20 MB -070606 MB -070606 Total Organic Carbon < 1 mg/L LCS-070606 LCS-070606 Total Organic Carbon 22.3 mglL 25 < 1 . 89 80 120 0606916-005AMS MW-3SMS Total Organic Carbon 9.5 mg/L 10 < 1 95 125 F 0606916-005ADUP MW-3SDUP Total Organic Carbon < 1 mg/L < 1 20 TSL006 S61