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HomeMy WebLinkAboutSample Data Summary Package 03/2006Analytical Data Package For TOWN OF SOUTHOLD PART 360 ROUTINE SDG NO: TSL005 Water Samples Received: 3/16/06 SAMPLE DATA SUMMARY PACKAGE MARCH 2006 V Ak V S 1 S • ?'>L Onvironmental Testing Laboratories 575 Broad Hollow Road, Melville, N.Y. 11747 U2M "US, INC. SAMPLE DATA SUMMARY PACKAGE TABLE OF CONTENTS TOWN OF SOUTHOLD PART 360 ROUTINE WATER SAMPLES SAMPLES RECEIVED: 3/16/06 SDG NO.: TSI -005 1. NYS DEC SUMMARY FORMS 2. CHAIN OF CUSTODY DOCUMENTATION 3. SDG NARRATIVES 4. SAMPLE REPORTS 4.1 VOLATILES 4.2 METALS 4.3 WET CHEMISTRY 5. SURROGATE SPIKE ANALYSIS RESULTS 5.1 VOLATILES 6. MATRIX SPIKE / MATRIX SPIKE DUPLICATE SUMMARY 6.1 VOLATILES 7. DUPLICATE SUMMARY RESULTS 7.1 METALS 7.2 WET CHEMISTRY 8. SPIKE SAMPLE RESULTS 8.1 METALS 8.2 WET CHEMISTRY 9. BLANK SUMMARY DATA AND RESULTS 9.1 VOLATILES 9.2 METALS 9.3 WET CHEMISTRY 10. INTERNAL STANDARD AREA DATA 10.1 VOLATILES U2M I AUS, INC. 1. NYS DEC SUMMARY FORMS NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE IDENTIFICATION AND ANALYTICAL REQUIREMENT SUMMARY SDG: TSL005 Anal ical Re ulrements M O O CLP(Non-CLP lease indicate year of protocol) AGP G iotcw rj TCL/TAL, HSL, Priority Pollutant, F-+ Ssw 4 J3to6 Customer Sample Code___ Laboratory Sample Code ME MsvoA we EQPT 0603561-001 X X X MW -1D 0603561-002 X X X MW -1S 0603561-003 X X X MW -3D 0603561-004 X X X MW -3S MW -4D 0603561-005 0603561-006 X X X X X X MW -4S 0603561-007 X X X MW -5D 0603561-008 X X X MW -5S 0603561-009 X X X MW -6D 0603561-010 X X X MW -6S 0603561=011 X X X 4W -8D 0603561-012 X X X MW -8S 0603561-013 X X X TRIP BLANK 3116 0603561-014 X M O O CLP(Non-CLP lease indicate year of protocol) AGP G iotcw rj TCL/TAL, HSL, Priority Pollutant, F-+ Ssw 4 J3to6 NEIN YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY VOLATILE (VOA) SDG: TSL005 ANALYSES Laboratory Samp ID Client Sample ID Matrix Analytical Protocol Date Collected DateRecd at Lab Date Date Extraction Extracted Analyzed Method DF Level Aux Cleanup 0603561-OOIA EQPT Aqueous ASPB 8260 16 -Mar -06 16 -Mar -06 23 -Mar -06 1 LOW 0603561-002A MW -1D Aqueous ASPB 8260 16 -Mar -06 16 -Mar -06 23 -Mar -06 1 LOW 0603561-003A MW -1S Aqueous ASPB 8260 16 -Mar -06 16 -Mar -06 23 -Mar -06 1 LOW 0603561-004AMW-3D Aqueous ASPB 8260 16 -Mar -06 16 -Mar -06 23 -Mar -061 1 LOW 0603561-005A MW -3S Aqueous ASPB 8260 16 -Mar -06 16 -Mar -06 23 -Mar -06 1 LOW 0603561-006A MW -4D Aqueous ASPB 8260 16 -Mar -06 16 -Mar -06 23 -Mar -06 1 LOW 0603561-007A MW -4S Aqueous ASPB 8260 16 -Mar -06 16 -Mar -06 23 -Mar -06 1 LOW 0603561-008A MW -5D Aqueous ASPB 8260 16 -Mar -06 16 -Mar -06 23 -Mar -06 1 LOW 0603561-009A MW -5S Aqueous ASPB 8260 16 -Mar -06 16 -Mar -06 23 -Mar -06 1 LOW 0603561-009AMS MW-5SMS Aqueous ASPB 8260 16 -Mar -06 16 -Mar -06 23 -Mar -06 1 LOW 0603561-009AMSD MW-5SMSD Aqueous ASPB 8260 16 -Mar -06 16 -Mar -06 23 -Mar -06 1 LOW 0603561-OIOA MW -6D Aqueous ASPB 8260 16 -Mar -06 16 -Mar -06 23 -Mar -06 1 LOW 0603561-011A MW -6S Aqueous ASPB 8260 16 -Mar -06 16 -Mar -06 23 -Mar -061 1 LOW 0603561-012A MW -8D Aqueous ASPB 8260 16 -Mar -06 16 -Mar -06 23 -Mar -06 1 LOW 0603561-013A MW -8S Aqueous ASPB 8260 16 -Mar -06 16 -mar -06123 -Mar -06 1 LOW 0603561-014A TRIP BLANK 3/16 A Aqueous ASPB 8260 16 -Mar -06 16 -Mar -06 23 -Mar -06 1 LOW TSL005 S4 NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG., TSL005 INORGANIC ANALYSIS TSL005 S5 NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG: TSI -005 INORGANIC .ANALYSIS Laboratory Samp ID Client Sample ID Matrix Tests DateRecd at Lab Date Analyze 0603561-001 EQPT Blank SELECT WET CHEMISTRY ** 03/16/06 03/06 0603561-002 MW -11) Groundwater SELECT WET CHEMISTRY ** 03/16/06 03/06 0603561-003 MW -1S Groundwater SELECT WET CHEMISTRY ** 03/16/06 03/06 0603561-004 MW -31) Groundwater SELECT WET CHEMISTRY ** 03/16/06 03/06 0603561-005 MW -3S Groundwater SELECT WET CHEMISTRY** 03/16/06 03/06 0603561-006 MW -41) Groundwater SELECT WET CHEMISTRY ** 03/16/06 03/06 0603561-007. MW -4S Groundwater SELECT WET CHEMISTRY ** 03/16/06 03/06 0603561-008 MW -51) Groundwater SELECT WET CHEMISTRY *' 03/16/06 03/06 0603561-009 MW -5S Groundwater SELECT WET CHEMISTRY ** 03/16/06 03/06 0603561-009DUP MW-5SDUP Groundwater SELECT WET CHEMISTRY'* 03/16/06 03/06 0603561-009MS MW-5SMS Groundwater SELECT WET CHEMISTRY ** 03/16/06 03/06 0603561-010 MW -6D Groundwater SELECT WET CHEMISTRY ** 03/16/06 03/06 060356 1-01 1 MW -6S Groundwater SELECT WET CHEMISTRY ** 03/16/06 03/06 0603561-012 MW -81) Groundwater SELECT WET CHEMISTRY ** 03/16/06 03/06 0603561-013 MW -8S Groundwater SELECT WET CHEMISTRY ** 03/16/06 03/06 ** Alkalinity, Total (As CaCO3) ; Biochemical Oxygen Demand; Bromide; Chemical Oxygen Demand; Chloride; Chromium, Hexavalent; Color; Hardness (As CaCO3) ; Nitrate as N; Nitrogen, Ammonia (As N) ;Nitrogen, Kjeldahl, Total; Phenolics, Total Recoverable; Sulfate ; Total Dissolved Solids ; Total Organic Carbon ; U2M 1AUS, 1 N C. 2. CHAIN OF CUSTODY DOCUMENTATION I M mss, INC. V5 Brod Haftow Rd, AlNvlft NY 11747-507e 11 5 EXTERNAL CHAIN OF CUSTODY T.k(637) 694-3040FVX. (637) 420-M6 CLIENT: CTS r_ H2M SDG NO: PROJECT NAMEINUMBER $Q HTO (t D -TOWN O F W07MO46 �a w 36° 10 Db Q 1 $ase l� h --►r4 -411 J �` Z �' �- � Z M ° cc 4 ? �'S o _ — NOTES: Pigpet Conbct (1) 800 S 8 R CL C T' F amtoR� CRt6�S�% ph"N 9 v K� �7`� S� l �( C0,0 NN3l A�sr�,�e PyF�Yots 't,1;/V - L M.67ry,� P vs eoRON ) GY A -N i D E S) P ART 3 0 V OC a -ra .4i SSS SAMPLERS: nature t VS fr �% DELIVERABLES: C ANALYSIS REQUESTED TURNAROUND TIME: ORGANIC INORG DATE TIME FIELD I.D. 1� �a �4� v LAB I.D. NO. REMARKS: Ibpb I :co 1- EQP% 11 3: 1 II low F— L I P B L4/I( TR) P 81�+N KS o L MW- IS 3 a a I I I I 010 . ab L M w - lb 11 a a I t r 2 3 VOL13'•15 L Mw- 3s. 13:q5 L I Mw ,. 3A /1 3 a I I I 1 co 10--25L_ Mw - 9�3o I-- M w- 6-s 33 9 b 6 3 313 3 rl s M s o , q•.55 1- M w-VA&*ddied by- ) Vs 6- Dab 3 /6 06 Tkw f g-07- Rowed Dab 3.i6-ub Tkne 17:07 LABORATORY USE ONLY ° "des tn sample Labels aria COC Reoad? Y a N semoiea : '• d arltand Dagrasa ,tee 2 Amblu t or r'— . Time s. Rao�ired in good aondbion: Y or N 4. Properly prawrved: Y or N COC TAw term: 1. Aw an aurr parkags: Y or N 2 WXolan on aubr pKkaga: Y or N a c0c nanoid pnasrrt a aarpbbPr YOM Rae,a�wbd )a Tkne Rsoaired by (Sig wkn) Data Tine PA&q *W by: MVwb") Dab Tkne RaoOW by: (Slgnabre) Dab TkneExplain: FOab ddod by: Mwob") Dab Time Racal, ad by ( ) Dab Time TSL"nFOPY - ORIGINAL YELLOW COPY - CLIENT PINK COPY - LABORATORY 1 A4 mss, isc. 373 Broad Hoffow Rd, Al akft NY 11747.3076 TN -(631) 694-30QOFax• (631) 420-8436 16 EXTERNAL CHAIN OF CUSTODY TSLVMTS90PY - ORIGINAL YELLOW COPY - CLIENT PINK COPY - LABORATORY CLIENT:L H2M SDG NO: 51, PROJECT NAlI MUMBER d'Ol! T06NOTES: a 7`d W/V' O F �SO(IrH OL b 'XICP a aob Q o Cr �• -j `r i' � o � J —` �— N z l�Ln z z o (tr o- � o Ln 0 WX ZP) J , Pr /wr Confect 86D� 8 R C L SCD L-0 R �R+bJ s�' c SF 7DT 4L9 -M5� 41 Pry,. l 4:9 cobN H3 j /►C3, MEAGs , T k N P1S/Quofe (3) -mi- arr&s Puts f+) 8 dE S) F•9R �'3(o Vo c (b) -I"OTi4 L H,4 )Rb IVES S SAMPLERS, (tignab"YClent 1/f Cr DELIVERABLES: — 7 1 ANALYSIS REQUESTED TURNAROUND TIME: LQ 1 b YS -ORGANIC INORG DATE- TIME4� n•. ZO � FIELD I.D. MVV- 3 a ��� a �2� �6� J lT V LAB I.D. NO. REMARKS: Ada 11*40 '• zs �-. A W— - 5. 11 11 -3 2- 3 2 2 I ►► I I :so LM (N- g 11 3 2 2 1/ I t2 7. ) i% S c owe 3 Time Dab . 3.4b• ,�,,, 1 9,v7 LABORATORY USE ONLY � 9etrreen Same labels and COC Record? Y or N Explain: semoleswwe: . I. or N.nd DNvwed AktW 2 AmWwd or ,' - Tim_ e. PAcelved In good oonditlm Y or N 4. Pmpody pnewNved: Y or N COC Tape vac t. Pim an oubr im " gm- Y or N 2 Unbmben an ouk+r package: Y or N a coc nvoad piaewd s upon swage rooetpt YorN by ) TkneRwMvW by (StM@Wm) Dab Time PAk4 d by iS��e) Dab Time fteaivad by (Slpne ") Dais Time R**d4wd- *. Mbmkn) Dab Time Received by (slen•kn)ate Tone TSLVMTS90PY - ORIGINAL YELLOW COPY - CLIENT PINK COPY - LABORATORY 1-12M LABS, INC. Sample Receipt Checklist Client Name PCTSL Work Order Numbe 0603561 Checklist completed b ?j l to O 1p Signature Dale Matrix Carrier name Hand Delivered Date and Time Receive Received by PS TSL Z)s- 3/16/2006 6:07:00 PM Reviewed by JGi( / India s 14 Date Shipping container/cooler in good condition? Yes © No ❑ Not Applicable ❑ Custody seals intact on shippping container/cooler? Yes ❑ No ❑ Not Applicable V Custody seals intact on sample bottles? Yes ❑ No ❑ Not Applicable 0 Chain of custody present? Yes (] No ❑ Chain of custody signed when relinquished and received? Yes No ❑ Chain of custody agrees with sample labels? Yes No ❑ Samples in proper container/bottle? Yes © No ❑ Sample containers intact? Yes No ❑ Sufficient sample volume for indicated test? Yes 0 No ❑ All samples received within holding time? Yes No ❑ Container/Temp Blank temperature in compliance? Yes ❑d No ❑ Water - VOA vials have zero headspace? No VOA vials submitted ❑ Yes No ❑ Water - pH acceptable upon receipt? Yes No ❑ Adjusted? Checked b Any No and/or NA (not applicable) response must be detailed in the comments section b ---------------------------------------------- Client contacted SES Date contacted: 3 21r1 – Person contacted Contacted by: J64 A(z�k11 Regarding Comments: ft o �4 � 0A— ���. Corrective Action" N2 1 w�� J it Q -11 rnt5 [P-oJi bb AV O CA 0 0 d2A tAUS, IW, INTERNAL CHAIN OF CUSTODY CLIENT:. ?OZL- DELIVERABLES:W--�o-o -TURN AROUND TM413: Ot F)"D SDG 0: CASE MATRIX: Crlu)V pHl CHECK Y REMARKS: -cNJ g RECEIVED BY: ? s SIGNS DAIS: '-UD T-&M-ALxtn VOLATILE 1. � i, i ■ ■ VOLATILE 1. 12M U AUS, INC. INTERNAL CHAIN OF CUSTODY LTE TI -M SAMPLE RELINQUISHED BY SAMPLE RECEIVED BY PURPOSE OF BOTTLE CHANGE OF - INIT Ka [� ��n s1aN �TY'PE /CUSTODY 1 X1 YT, BION slow Blow slow Blow slow slow slow LION Blom Blow sl ON Blow slam Blow 9I ON 9100 sits Blow SIC" Blow Sic" 3101 SIGN 91GS SIGN 31Ow siCN 310W SIC" slow slow 9Iow slow h• slow SIC" LION Sion slow Slow ' SIOiN BION -low BIC" Blow SIGN Blow SICK Sion SIGN 1 VOLATILE O o- U2A UAUSq NC. INTERNAL CHAIN OF CUSTODY CLIENT: DELIVERABLES: TURN AROUND TUNE: SDG - k 'T A"L CASE #: MATRIX: 0 LJ PH CHEC� Y REQUM BY: — Ps _ DA METALS P C, 1.5 1 t12A UAUSq ING SDO ---, .1 INTERNAL CHAIN OFCUSTODY METALS P 0152 1AIES9 INCO INTERNAL CHAIN OF CUSTODY Q.IENT: rl L- —DELIVERABLES--?S-'10'P TURNAROUND TIME: ZD(, #:-ff-,-)W3r�- CASE #: MATRIX: �c pH C.6 -x SBAARKS: pat IECEWM BY: SIGNATURE: DATE: `b T m: 1 �� WET CHEMISTRY VJ H P 016,9 m.m- m, E ���Kfaml wdl��Wmlm now 0��Wml PON mmom e WET CHEMISTRY VJ H P 016,9 I r4c• INTERNAL CHAIN OF CUSTODY u WET CHEMISTRY P 0170 Iwo T _ Iry ��� q` u WET CHEMISTRY P 0170 U2A «►Us,- mac. SDO Q INTERNAL CHAIN OF.CUSTODY DATE TIME 'SAMPLE RELINQUISHED BT SAMPLE RECEIVED BY BOTTLE TYPE PURPOSE OF CAAME OF CUSTODY INIT IIow SI 0 .:ON Slob . PION Slam slgn slow slow SIGN - a:GN slow alow SIGN Slow SIGN ' SIGN SIGN ' slow SIC" S10N SIGN Slow SIGN -.Slow SIGH Slow Sidi ' SIGN - SIG" Iow SI ly SIGN SIGN SIGN SIGN Slow SIGN SIGN- $1014 slow SIGH alow SIGN sloN SIGN SIon SIGN j WET CHEMISTRY a P OIL 71 x U2M "US, INC. 3. SDG NARRATIVES U2M lAust INC. For Samples: SDG NARRATIVE FOR VOLATILE ANALYSES SAMPLE RECEIVED: 3/16/06 SDG#: TSL005 EQPT MW -5D MW -1D MW -5S MS/MSD MW -1S MW -6D MW -3D MW -6S MW -3S MW -81) MW -41) MW -8S MW -4S TRIP BLANK 3/16 The above samples were analyzed according to the requirements of the NYSDEC ASP 10/95 method 8260B for the part 360 baseline list of volatile organic analytes. All QC data and calibrations met the requirements of the method, and no problems were encountered with sample analysis. The following should be noted: • Sample MW -5S was analyzed as the matrix spike/matrix spike duplicate. • 4-Bromofluorobenzene had a 26.5% RSD in the initial calibration of 3/20/06, which exceeded 20.5% but met the acceptance limit of 40%. The response factor for trichloroethene was greater than 0.3 in the initial calibration of 3/20/06. Tetrachloroethene had a 34.8% D in the continuing calibration of 3/23/06, which exceeded 25% D but met the acceptance limit of 40%. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: April 3, 2006 kSlavin Jo Senior Vice President o:\gc\narr2006\pctsl\volatiles\ts1005.doc i -2M TAUS, INC. For Samples: NARRATIVE FOR METALS ANALYSES SAMPLE RECEIVED: 3/16/06 SDG#: TSL005 EQPT MW -5D MW -1D MW -5S MS/MSD MW -1S MW -61) MW -3D MW -6S MW -3S MW -8D MW -4D MW -8S MW -4S Thirteen water samples were received by H2M Labs, Inc. on 3/16/06 for cyanide and select metals analysis. Samples were prepared and analyzed using EPA method 6010B with a TJA61E Trace ICP instrument, method 7470A with a Leeman Hydra mercury analyzer and cyanide method 335.2. Sample MW -5S was utilized for QC analysis and reporting. No problems were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: April 3, 2006 ************************* Vincent Stancampiano Vice President o:\gc\narr2006\pctsl\metals\tsIO05.doc U2M LABS, INC. For Samples: SDG NARRATIVE FOR WET CHEMISTRY SAMPLE RECEIVED: 3/16/06 SDG#: TSL005 EQPT MW -5D MW -1D MW -5S MS/MSD MW -IS MW -6D MW -3D MW -6S MW -3S MW -8D MW -4D MW -8S MW -4S EPA 320.1 Thirteen water samples were received by H2M Labs, Inc. on 3/16/06 for select wet chemistry analysis. Samples were prepared and analyzed using the following methods: PARAMETER METHOD # PARAMETER METHOD # Alkalinity EPA 310.1 Ammonia EPA 350.1 BOD EPA 405.1 Nitrate EPA 353.2 Bromide EPA 320.1 Phenols EPA420.1 Chloride EPA325.2 Sulfate EPA 9038 COD EPA 410.4 TDS EPA 160.1 Color EPA 110.2 TKN EPA 351.2 Hexavalent Chromium STDM 3500 -CR D TOC EPA 9060 Hardness EPA 130.2 Sample MW -5S was utilized for duplicate and spike QC analysis and reporting. Duplicate analysis did not reproduce within acceptance ranges for biochemical oxygen demand (BOD). Duplicate acceptance range for BOD is ± the CRDL of 2 mg/L. The difference between sample and duplicate values was 6 mg/L. Since the BOD values were low data usability should not be affected. Samples were diluted and reanalyzed as required to keep instrument readings within calibration ranges. No other problems were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: April 3, 2006 ************************* Vincent Stancampiano Vice President oAgc\narr2006\pcts1%wet chemsitry\ts1005.doc r N V1 Ln O O Z U2M L US, INC. 4. SAMPLE REPORTS 4.1 VOLATILES 4.2 METALS 4.3 WET CHEMISTRY U2A JLAUSs INC. WA #1arKWk(fA Value - If the result is a value greater than or equal to the quantification limit, report the value. U - Indicates compound was analyzed for but not detected The sample quantitation limit must be corrected for dilution and for percent moisture. For awmpk, l0U for phenol in water if the sample final vohnne is the protocol -specified final volume. If a 1 to 10 dilution of extract is necessary, the reported limit is 100 U. For a soil sampk, the value mast also be adjusted for percent moister 'For =Maple, if the sample had 24% moistare and a I to 10 dilution factor, the sample quantitation limit for pbeuol (3301n would be corrected to: (300 U) 100'/omoishve x df where D = D 100 and df- dilution factor 24 For example, at 24% moisture, D = 100— 0— = 0.76 100 (300 i)) x 10 - 4300 U rounded to the appropriate number of significant figures .76 For scmivolatile soil samples, the extract must be concentrated to 0.5 ml,, and the sensitivity of the analysis is not compromised by the cleanup procedures. Similarly, pesticide samples subjected to GPC are concentrated to 5.0 ml- Tberefore, the CRQL values in Exhibit C will apply to all samples, regardless of cle"up. However, if a sample extract cannot be concentrated to the protocol -specified vohmx (See Exhibit C, this fact must be accounted for in reporting the sample quantitation limit. - Indicates an estimated value. This flag is used either when estimating a concentration for tentatively identified compounds where a 1:1 response is assumed or when the mass spectral data indicates the presence of a compound that meets the identification criteria but the result is less than the specified quantification limit but greater than zero. (e.g.: If limit of quantification is 10 ug/L and a concentration of 3 ug/L is calculated, report as 37.) The sample quantitation limit must be adjusted for dilution as discussed for the U flag. N - Indicates presumptive evidence of a compotmd. This flag is only used for tentatively identified compounds, where the identification is based on a mass spectral library search. It is applied to all TIC results. For generic characterization of a TIC, such as chlorinated hydrocarbon, the N code is not used. P - Ibis flag is used for a pesticide/Arocim target analyte when there is greater than 25% diffcmuce for detected concentrations between the two GC cohrmas (see Form X). The lower of the two values is reported of Form I with a "P". C - This flag applies to pesticide results when the has been confirmed by GC/MS.. If GClMS confirmation was attempted but was unsuceasft* do not apply this flag, instead use a Laboratory defined flag, discussed below. U2AA "Use INC. B - This flag is used when the analyte is found in the associated blank as well as in the sample. It indicates possible probable blank contamination and warns the data user to take appropriate action. This flag must be used for a TIC as well as for a positively identified target compound. E - This flag identified compounds whose concentrations exceed the calibration range of the GO/MS instrument for that specific analysis. If one or more compounds have a response greater than full scale, eacent as noted in Exhibit D, the sample or extract most be dihrkd and re -analysed accotdmg to the specifications in Exhibit D. All such cads with a response greater than full seek should have the concentration flagged with an "B" on the Form I for the original analysis. If the dilution of the extract causes any compounds identified in the fast analysis to be below the ab'bration ranges in the second analysis, then the results of both analyses shall be reported on separate copies of Form L The Form I for the diluted sample shall have the "DL" suffix appended to the sample number. NOTE Yor total xylenes, where three isomers are quantified as two peaks, the calibration range of each should be considered separately, e.g, a diluted analysis is not required for total xylenes unless the concentration of the peak representing the single isomer exceed 200 ug/I, or the peak representing the two coeluting isomers on that GC column exceed 400 ug/L_ Similarly, if the two 1,2-Dich1oroethene isomers coeur a diluted analysis is not required unless the concentration exceed 400 ug/l._ D - This flag identifies all compounds identified in an analysis at a secondary dilution factor. If a sample or extract is re -analyzed at a higher dilution factor, as in the "T" flag above, the "DL" suffix is appended to the sample number on the Form I for the diluted sample, and all concentration values reported on that Form I are flagged with the "D" flag. This flag alerts data users that any discrepancies between the concentrations reported may be due to dilution of the sampk or extract. A - This flag indicates that a nC is a suspected aldo1-condensatim product. X - This flag indicates suspected cohinm bleed. Y - This flag denotes concentration of tentatively identified compounds (TICs) to be biased low due to matrix interference with internal standard. z - Other specific flags may be required to properly define the results. If used, they ist be frilly described and such description attached to the Sample Data Summary Package and the SDG narrative. Begin by using "7t"_ If more than one flag is required use "Y" and 'W as needed N more than five qualifiers are required for a sample result, used the "7t" flag to combine several flags as needed For instance, the W flag might combine "A", "W, and "D" flags for some samvks. The hboratory defined flags limited to the letters 'Xw, "Y" and W The combination of flags "BU or "UB" is expressly prohibited. Blank contaminants nue flagged 'B" Mb[ when they are detected in the sample. U2M LAUS9 INC. QUALIFIERS FOR METALS ANALYSIS Q (Quality Control) Qualifiers E - The reported value is estimated because of the presence of interference. An explanatory note is included in the SDG narrative. M - Duplicate injection precision not met. N - Matrix spike sample recovery not within control limits. S- The reported value was determined by the Method of Standard Additions (MSA). + - Correlation coefficient for the MSA is less than 0.995 W - Post digestion spike for Furnace AA analysis is out of control limits (85- 115%), while sample absorbance is less than 50% of spike absorbance. * - Duplicate analysis is not within control limits. C (Concentration) Qualifiers B - Entered if the reported value is less than the Contract Required Detection Limit (CRDL) but greater than the Instrument Detection Limit (IDL). U - Entered if the analyte was analyzed for but not detected, i.e., less than the IDL. M (Method) Qualifiers P - Analyzed by ICP. M - Analyzed by ICP -MS A - Analyzed by Flame AA. F - Analyzed by Furnace AA. CV - Analyzed by Manual Cold Vapor techniques. AV - Analyzed by Automated Cold Vapor techniques. C - Analyzed by Manual Spectrophotometric Method. CA- Analyzed by Midi -distillation Spectrophotometric Method. NR- Analyte not Required. 1A VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: H2M hAjiS, INC. Lab.Code: 1047.8 Cabe No.: VCtSL- Matrix: (soil/water) WATER Sample wt/vol: 5 (g/mL) ML Level: (low/meci) LOW Moisture: not ded. Bromcinidthane GC Coluibm: R-902.2 Ib: .53 So 11 Ektract Volume': (aL CAS NO. COMPOUND BPA SAMPLE NO. EQPT Contract: SAS No. -LOOS SDO No.: lks, Lab Sample D" 0603561-001A Lab File ID: A\A45402.D Date Rscei-Viid: 03/16/06 Date Analyzed: 03/23/06 (mm) Dilution Fadt6r'.- Soil - Aliquot.Volume (,uL) CONCENTRATION UNITS: (Ag/L or as/R9) UG/L 0 74-87-3 Chloromethane 5 U 75-01-4 Vinyl chloride 5 U 74-83-9 Bromcinidthane 5 U 75-00-3 Chloroethane 5 U 107-13-1 —Acrylonitrile. 5 U 75-69-4 Ttichlorofluorotnethane 5 U 75-35-4 1,1-Dichloroethene 5 U 74-88-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5 U 67-64-1 Acetone 5 U 75-15-0 Carbon disulfide 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans=1,2-Dichloroethene 5 U 75-34-3 1,41-Dichloroethane 5 U 156.-59-2 cis-1,2-Dichloraeth6h& 5 U 78-93-3 2-Butanon6 5- U 74-97-5 Bromochloromethane 5 U 67-66-3 Chlordforkn 5 U 71-55-6 1,1,1 -Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U. 71-43-2 Benzene 5 U 107-06-2 1,2-Dichloroethahe U .79-01-6 Trichloroethane 5 U .78-87-5 --74-95-3 1,2-Dichloiropropane 5 U Dibromomethane 5 U 75-27-4 Bromodichloromethane —cis-1,3-Dichloropropene 5 U 16061-01-5 5 U 108-10-1 4'-Methyl-2-pentanone 5 U 108-88-3 Toluene 5 U 10061-02-6 trans-1,3-Dichloropropene 5 U 79-00-5 1,1,2 -Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U 591-78-6 —2-Hexanone 5 124-48-1 Dibromochloromethane 5. 106-93-4 1 1,2-Dibromoethane 5 U FORM I VOA - 1 OLM04.2 IB VOLATILE ORGANICS ANALYSIS DATA SEEET Lab Name: 92k:- LAW, INC. tib Code: 10478 Case No.: PCTSL Matrix: (soil/water) WATER Sample wt/vol: 5 (q/M,) ML Level: (low/med) % Moisture: not dec. GC Column: R-502.2 Soil Extract Volume: CAS NO. LOW EPA* SAMPLE NO. EOPT Contract: SAS No.: SDG No..: TSL005 Lab Sample ID: 0603561-001A Lab File ID: A\A45402.D Date Received: 03/16/06 Date Analyzed: 03/23/06 ID: .53 (mm) Dilution Factor: 1.00 ()IL) Soil Aliquot Volume (µL) CONCENTRATION UNITS: COMPOUND bf- /T. nr "n /z A 108-90=7 Chlorobenzene 5 U 110-57-6 trans-l,4-Dichloro-2-butene 5 U 100-41-4 Ethylbenzene 5 U 630-20-6 1,1,1,2 -Tetrachloroethane 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene 5 U 75-25-2 Bromoform 5 U 79-34-5 1,1,2,2 -Tetrachloroethane 5. U 96-18=4 1,2,3-Trichloropropane 5 U 106-46-1 1,4 -Dichlorobenzene 5 U 95-50-1 1,2 -Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U FORM I VOA - 2 OLM04.2 FORM I VOA -TIC 00 N C O O OLM04.2 � Z IF EPA SAMPLE NO.. . VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS FEQPT Lab Name: H2M LASS; INC. Contract': Lab Code:. 104;78 Case.No.: PCTSL SAS No.: SDG No.: T6L005 Matrix: (soil/Water) WATER Lab Sample ID: 0603561-001A Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A45402.D Level: (low/med) LOW Date Received: 03/16/06 Moisture: not dec. Date Analyzed: 03/23/06 GC Column: 9-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volume: (µl) Soil Aliquot Volume: 0(µ L) _ CONCENTRATION UNITS: Number TICs found: 0 (µg/L or µg/Kg) UG/L CAS NUMBER COMPOUND NAME RT SST.CONC. Q FORM I VOA -TIC 00 N C O O OLM04.2 � Z U.S. EPA - CLP Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 EPA SAMPLE NO 7429-90-5 INORGANIC ANALYSIS DATA SHEET B P 7440-36-0 Antimony 2.9 U P 7440-38-2 Arsenic EQPT Lab Name: H2M LABS, INC. Contract: 1.5 U P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL005 Matrix (soil/water): WATER Lab Sample ID: 0603561-001 Level (low/med): LOW Date Received: 3/16/2006 % Solids: 0 0 68.5 B P Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7429-90-5 Aluminum 21.0 B P 7440-36-0 Antimony 2.9 U P 7440-38-2 Arsenic 1.8 U P 7440-39-3 Barium 1.5 U P 7440-41-7 Beryllium 0.23 U P 7440-42-8 Boron 2.2 B P 7440-43-9 Cadmium 0.12 U P 7440-70-2 Calcium 68.5 B P 7440-47-3 Chromium 1.2 B P 7440-48-4 Cobalt 1.2 U P 7440-50-8 Copper 0.96 U P 57-12-5 Cyanide 10.0 U CA 743.9-89-6 Iron 17.8 U P 7439-92-1 Lead 1.1 U P 7439-95-4 Magnesium 20.3 B P 7439-96-5 Manganese 3.4 B P 7439-97-6 Mercury 0.10 U CV 7440-02-0 Nickel 1.0 U P 7440-09-7 Potassium 162 B P 7782-49-2 Selenium 1.9 U P 7440-22-4 Silver 0.45 U P 7440-23-5 Sodium 118 B P 7440-28-0 Thallium 2.4 U P 7990-62-2 Vanadium 1.4 U P 7490-66-6 Zinc 13.8 B P Color Before: COLORLESS Clarity Before: Color After: COLORLESS Clarity After: Comments: Date Reported: 3/29/06 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 "A "US, INC. 575 BroadHolav Road, Mt#vle NY 11747 LABORATORY RESULTS (631) 694.040. FAX (631)42048436 NYSDOH ID# 10478 Sample Information... Town of Southold Landfill Lab No. : 0603561-001 Type: Blank Attn To Origin: Client ID.: EQPT Collected :3/16/2006 1.:00:00 PM Received :3/16/2006 6:07:00 PM Collected By VSG03 Copies To :Original CC Parameters) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310.1 03/20/2006 11:00 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 03/16/2006 4:28 PM Bromide < 0.5 1 mg/L E320.1 03/23/2006 9:30 AM Chloride < 2.0 1 mg/L E325.2 03/27/2006 1:54 PM Chemical Oxygen Demand <10 1 mg/L E410.4 03/21/2006 10:02 AM Color < 5 1 units E110.2 03/17/2006 1:02 PM Chromium, Hexavalent < 0.02 1 . mg/L M3500 -Cr D 03/17/2006 1:10 PM Hardness (As CaCO3) < 5.0 1 mg/L E130.2 03/17/2006 1:20 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 03/27/2006 11:23 AM Nitrate as N < 0.10 1 mg/L E353.2 03/25/2006 11:27 AM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 03/27/2006 10:30 AM Sulfate < 5.0 1 mg/L SW9038 03/28/2006 1:34 PM Total Dissolved Solids <10 1 mg/L E160.1 03/20/2006 11:40 AM Nitrogen, Kjeldahl, Total 0.26 1 mg/L E351.2 03/28/2006 1:33 PM Total Organic Carbon < 1.0 1 mg/L SW9060 03/22/2006 3:04 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor i Date Reported : 4/3/2006 Page 1 of 13 alu". A /-AWCIVIJ Laboratory Manager s 1A EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MVP -1D Lab Name-: H2M.LABS,.INC. Contract: Lab Code: 10478 Case -No.: PCTSL SAS No.: SDG No.: T3L005 Matrix: ('soil%water) WATER Lab Sample IDa 0603561-002A Sample ort/vol: 5 (g/M,) ML Lab File ID: A\A4_ 5403.D Level: (lour/med) LOFT Data Receivad:' 03/i6/06 $ Moistiure: not dec. Date Analyzed: 03/23/06 ad CoTumne R-502.2 ID: .53 (mm) Dilution Facto=: 1.00 Soil Extract- Volume: (µL) soil Aliquot Volume (µL) CONCENTRATION UNITS: CAS NO. COMPOUND (µg/L or µ9/Kg) UQ/L g 74-87-3 Chloromethane 75-01-4' Vinyl chloride 5 U 74-83-9 Bromomethane 5 U 75-00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 LJ 74-88-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5' U 67-64-1 Acetone 5 U 75-15-0 Carbon disulfide 8 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichloroethane 5 U 156-59-2 cis-1,2-Dichloroethene 5 U 78-93=3 2=Butanone 5 U 74-97-5 Bromochloromethane 3' J 67-66-3 Chloroform 5 U 71-5576._ 1,1,1 -Trichloroethane 5 U 56-23-5 . Carbon tetrachloride 5 U 71-43-2_Benzene 5 U 107-06-2 1,2-Dichloroethane 5 U 7970i76 Trichloroethene 5 U 78=87-5 1,2-Dichloropropane 5 U 74-95-3 Dibromomethane 5 U 75-27-4 Br omodichloromethane 5 U 10061-01-55 cis-1,3-Dichloropropene U 108-10-1 4-Methyl-2-pentanone 5 U 108-88-3 Toluene 5 U 10061-02-6 trans-1,3-Dichloropropene 5 U 79700-5 1,1,2 -Trichloroethane 5 U 127=18-4 Tetrachloroethene 5 U '--� M 591-78-65 2-Hexanone U 124-48-1. 1 Dibromochloromethane 5 U 106-93-4 1 1,2-Dibromoethane 5 U O 5 U 1- FORM I VOA - 1 OLM04.2 lB VOLATILE ORGANICS ANALYSIS DATA SHEET BPA SAMPLE NO. NW -ID' Lab Name: H2M LABS,:.. INC. Contract: Lab Coder 10978 Case No.: PCTSL SAS No.: SDa No.:, T3L005 Matrix: (soil/water) WATER Lab Sample ID: 0603561=002A. Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A45403.D L®vel: (low/coed) LOW Date Received: 03/16/06 Moisture: not dec. Date Analyzed: 03/23/06 GC Column: R-502..2 ID: .53 (mm) Dilution Factor: 1.00 SO l:Rktraci Vo]utnee OzL) Soil Aliquot Volume. ()zL) COMMMATION UNITS: CAS NO. C014POUND (ua/L or un/1[61 TSA/T. n 108-90-7 Chlorobenzene 5, U 110-57=6. trans7l,4-Dichloro-2-butene 5 U 100=41-4 Ethylbenzene 5 U 630-20-6 1,1,1,2-Tetrach1oroethane 5 U 1330-20-7 . Xylene (total) 5 U 100-42-5 Styrene 5 U 75-25-2 Bromoform 5 U 79-34-5 1,1,2,2 -Tetrachloroethane 5 U 9.6-18-4. 1,2,3-Trichloropropane 5 U 106-46.-7 1,4 -Dichlorobenzene 5 U 95-50=1. 1,2-Dichlorobenzerie 5 U 96-12-8 1;2-Dibromo-3-chloropropane 5 U FORM I VOA - 2 OLM0.4.2 IF EPA.SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS MW -1D Lab Name: H2k -LABS INC, Contract: Lab,Code: 104.79 Case - *No.': PCTSL SAS No.: SDG No.: TSI,605 Matkixe (Soil/water)..-. WATER Lab Sample ID: 0603561-002A Sample wt/vol: 5 (9/mL) ML Lab File ID:* A\A45403.D Level: (low/med) LOW Date Received: 03/16/06 Moisture: not . dec. Date Analyzed: 0 1 3/23/06 GC 6blumn:_ R-502.*2 ID: .93 (mm) Dilut . ion Factor: 1.00 Soil Extract Volume: Soil Aliquot Volume: 0 (,uL) CONCENTRATION UNITS: Number TICS idund:. 0 (pgIL or Ag/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST.CONC. L FORM I VdA=tjC O. O OLM04.2 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -1D Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL005 Matrix (soil/water): WATER Lab Sample ID: 0603561-002 Level (low/med): LOW Date Received: 3/16/2006 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7429-90-5 Aluminum 41.6 B P 7440-36-0 Antimony 2.9 U P 7440-38-2 Arsenic 1.8 U P 7440-39-3 Barium 14.7 B P 7440-41-7 Beryllium 0.23 U P 7440-42-8 Boron _ 42.7 B -- P 7440-43-9 _ Cadmium 0.15 B P 7440-70-2 Calcium 3730 B P 7440-47-3 Chromium 2.7 B P 7440-48-4 Cobalt 1.4 B P 7440-50-8 Copper 2.8 B P 57-12-5 Cyanide 10.0 U CA 7439-89-6 Iron 97.1 B P 7439-92-1 Lead 1.1 U P 7439-95-4 Magnesium 1120, B P 7439-96-5 Manganese 357 P 7439-97-6 Mercury 0.10 U CV 7440-02-0 Nickel _ 1.6 B P 7440-09-7 Potassium 12500 P 7782-49-2 Selenium 1.9 U P 7440-22-4 Silver 0.45 U P 7440-23-5 Sodium 14500 P 7440-28-0 Thallium 2.4 U P 7440-62-2 Vanadium 1.4 U P 7440-66-6 Zinc 1 31.4 P Color Before: COLORLESS Clarity Befote: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 3/29/06 FORM I - IN ILM04.1 U2M lAI3S9 INC. 575BroadHdoN Road, Mek& W 11747 LABORATORY RESULTS (631) 694.9040. FAX (631)42D8436 NYSDOH1D#10478 - Town of Southold Landfill Lab No. : 0603561-002 Attn To : Collected :3/16/2006 2:40:00 PM Received :3/16/2006 6:07:00 PM Collected By VSG03 Copies To :Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Color Chromium, Hexavalent Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID.: MW -1b Results Qualifier D.F.. Units < 1.0 1 mg/L 17 1 mg/L < 0.5 1 mg/L 26.4 1 mg/L 38.7 1 mg/L < 5 1 units < 0.02 1 mg/L 16.0 1 mg/L 0.68 1 mg/L 1.56 5 mg/L 27.0 1 pg/L 39.9 1 mg/L 130 1 mg/L 23.4 10 mg/L 21.7 1 mg/L Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 4/3/2006 Page 2 of 13 Sample Information... Type : Groundwater Origin: Method Number Analyzed E310.1 03/20/2006 11:05 AM E405.1 03/16/2006 4:32 PM E320.1 03/23/2006 9:45 AM E325.2 03/27/2006 1:55 PM E410.4 03/21/2006 10:03 AM E110.2 03/17/2006 1:03 PM M3500 -Cr D 03/17/2006 1:15 PM E130.2 03/17/20061:25 PM E350.1 03/27/200611:24 AM E353.2 03/25/2006 11:28 AM E420.1 03/27/2006 10:45 AM SW9038 03/28/2006 1:36 PM E160.1 03/20/2006 11:42 AM E351.2 03/28/2006 4:09 PM SW9060 03/22/2006 3:33 PM Laboratory Manager z r: lA VOLATILE ORGANICS ANALYSIS DATA SHEET Lab, Namee H2 : LABS,. INC. Contract: Lab BPA SAMPLE NO. MW -1S Code:. 10478 Case No.: PCPSL SAS No.: SMG No.: TSL005 Matzixe (coil/pater] WATER Lab Sample ID: 0603561-003A Sample wt/vol: 5 (9/mL) ML Lab File ID: A\A45404.D Level: (low/coed) LOW Date Received: 03/16/06 Moisturee.not dee. Date Analyzed: 03/23/06 GC Column: R-502..2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volume: (At) Soil Aliquot Volume (AL) CONCENTRATION UNITS: CAS NO. COMPOUND _ 74-87=3 Chloromethane 5 U 75-01-4 Vinyl chloride 5 U 74-83-9 Brbmomethane 5 U 75=00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U 74788-4 Iodomethane 108=05=4 uinvl nr.nf��e 5 U FORM I VOA - 1 OLM04.2 108-90-7 1B 5 BPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET trans-1,4-DiChloro-2-butene 5 U 100-41=4 Ethylbenzene 5 U MW -1S 1,1,1,2 -Tetrachloroethane Lab Na'mee 42i[. LASS, INC. Contract: Xylene (total) Lab Code':,, 10"478 Case No.: PCTSL SAS No.: SDG No.: TSL005 Matiix '" (eoil/*a, ter) iPATER Lab Sample ID: 0603561-003A Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A45404.D Level: .(low/mad) LOW Date Received: 03/16/06 % Moisture: not dec. U Date Analysed: 03/23/06 GC'Columa: R-602.2 SD: .53 (mm) Dilution Factor: 1.00 Soil S9ctizact Volume: (AL) Soil Aliquot Volume (AL) 1,2-Dibromo-3-chloropropane 5 CONCENTRATION UNITS: CAS NO.. COMPOUND ( uo %L ejr f,e /Iran 1 TTh /r. n 108-90-7 Chlorobenzene 5 U 110=57-6 trans-1,4-DiChloro-2-butene 5 U 100-41=4 Ethylbenzene 5 U 630-20-6 1,1,1,2 -Tetrachloroethane 5 U 1330-20=7 Xylene (total) 5 U 100-42-5 Styrene 5 U 75-25-2 Bromoform 5 U 79-34-5 1,1,2;2 -Tetrachloroethane 5 U 96-18-4 1,2,3-Trichloropropane 5 U 106-46-7 1,4 -Dichlorobenzene 5 U 95-50-1 1,2 -Dichlorobenzene 5 U 96-1278 1 1,2-Dibromo-3-chloropropane 5 U M O O FORM I VOA - 2 OLM04.2 [� I 1F EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET e TENTATIVELY IDENTIFIED COMPOUNDS Lab' Name: mm.Lm6'; INC. Contract: Lab Codec, ;;:104 T8 Case No.: PCTSL SAS No.: SDG No'.: TSL005 Matrix.:(`so'l%water):. WATER Lab Sample ID: 0603561-003A Sample wt/Vole 5 (9/mL) ML Lab File ID: A\A45404.D Level: (low/med) LOW Date Received: 03/16/06 $ Moisture: not'dec: Date Analyzed: 03/23/06 GC Column.: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Ektract Volume: (µ1) Soil Aliquot Volume: 0 (At) CONCENTRATION UNITS: Number TICs found: 0 (µ9/L or Ag/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST.CONC. Q 00 M O' O FORM I VOA -TIC OLM04.2 I4 V) i U.S. EPA - CLP Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte 1 EPA SAMPLE NO 7429-90-5 INORGANIC ANALYSIS DATA SHEET B P Ant_im_ony 2.9 U P r440-_36-_0 440-38-2 Arsenic MW -1S Lab Name: H2M LABS, INC. Contract: _ 14.5 B P 7440-41-7 Beryllium Lab Code: 10478 Case No. SAS No.: SDG No.: TSL005 Matrix (soil/water): WATER Lab Sample ID: 0603561-003 Level (low/med): LOW Date Received: 3/16/2006 % Solids: 0.0 7440-47-3 Chromium Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7429-90-5 Aluminum 30.1 B P Ant_im_ony 2.9 U P r440-_36-_0 440-38-2 Arsenic - 1.8 U P 7440-39-3 Barium _ 14.5 B P 7440-41-7 Beryllium 0.23 U P 7440-42-8 Boron 43.7 B P 7440-43-9 Cadmium 0.12 U P 7440-70-2 Calcium 3640 B P 7440-47-3 Chromium 2.0 B P 7440-48-4 Cobalt 1.2 B P 7440-50-8 Copper 3.3 B P 57-12-5 Cyanide 10.0 U CA 7439-89-6 lIron 47.2 B P 74_39-92-1 Lead 1.1 B P _ _ 1080 _ B P ,7439-95-4 j7439-96-5 -Magnesium _ Manganese _ _-- _ 346 P 9-97-6 Mercury 0.10 _ _ _ U CV 0-02-0 Nickel _ 1.6 B P 0-09-7 Potassium 12200 P 2-49-2 Selenium 1.9 U P 0-22-4 [74 Silver 0.45 U P 0-23-5 Sodium 14100 P 0-28-0 Thallium 2.4 U P 0-62-2 Vanadium 1.4 U P 0-66-6 Zinc 37.7 P Color Before: _CO_LORLESS_ Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 3/29/06 FORM I - IN ILM04.1 UZ44 LAES43 INC. 575 Broad Hollow Road NW& NY 11747 LABORATORY RESULTS (631)694.3040. FAX (631)4M6436 NYSDOH1D#10478 Sample Information... Town of Southold Landfill Lab No. 0603561-003 Type : Groundwater Attn To Origin: Client ID.: MW -1S Collected :3/16/2006 2:10:00 PM Received :3/16/2006 6:07:00 PM Collected By VSG03 Copies To :Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310.1 03/20/2006 11:10 AM Biochemical Oxygen Demand 16 1 mg/L E405.1 03/16/2006 4:36 PM Bromide < 0.5 1 mg/L E320.1 03/23/2006 10:00 AM Chloride 29.7 1 mg/L E325.2 03/27/2006 1:56 PM Chemical Oxygen Demand 48.7 1 mg/L E410.4 03/21/2006 10:04 AM Color < 5 1 units Ell 10.2 03/17/2006 1:04 PM Chromium, Hexavalent < 0.02 1 mg/L M3500 -Cr D 03/17/2006 1:20 PM Hardness (As CaCO3) 17.0 1 mg/L E130.2 03/17/2006 1:30 PM Nitrogen, Ammonia (As N) 0.65 1 mg/L E350.1 03/27/2006 11:25 AM Nitrate as N 1.37 5 mg/L E353.2 03/25/2006 11:29 AM Phenolics, Total Recoverable 26.1 1 pg/L E420.1 03/27/2006 11:00 AM Sulfate 63.0 2.5 mg/L SW9038 03/28/2006 1:38 PM Total Dissolved Solids 138 1 mg/L E160.1 03/20/2006 11:44 AM Nitrogen, Kjeldahl, Total 25.1 10 mg/L E351.2 03/28/2006 4:09 PM Total Organic Carbon 22.1 1 mg/L SW9060 03/22/20064:03 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 4/3/2006 Page 3 of 13 Laboratory Manager CAS NO: COMPOIIND CONCENTRATION UNITS: IA �. - -- rte. -•o i ��, �• SPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET 5 U MW -3D Lab' Name: Ha1d':LAH3.,. i INC. Contract: Bromomethane Lib. Code:., 10478. Case No.: PCT SL SAS No.: SDG No.: TSL005 Mat'rixe (soil%afar) -WATER Lab,Sample ID: 0603561-004A Sample ort/vol: 5 (g/mL) ML Lab File ID: A\A45405.D Level: (torr/mad) LOWDate Received: 03/16/06 .Moisture: not dec: U Date Analyzed: 03/23/06 GC Column: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 toil Extract Vo].umee (µL) Soil Aliquot Volume (,uL) CAS NO: COMPOIIND CONCENTRATION UNITS: FORM I VOA - 1 OLM04.2 r-+ Cn O O Chloromethane �. - -- rte. -•o i ��, �• til 5 U Vinyl 'chloride 5 E..175-00-3 Bromomethane 5 U U Chlbroethane Acrylonitrile 5 U U 75-69-4 Trichlorofluoromethane 5 U 75-35=4.11,17Dichloroethene 5 U 74-88-4 Iodomethane 5 U 108705-4 Vinyl acetate 5 U 67-64-1 Adetone 5 U 75-15-0 Carbon disulfide 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans=l,2-Dichloroethene 5 U 75-34-3 1,1=Dichloroethane 186-59-2 cis-1,2-Dichloroethene 5 U 5 U 78-93-3 .2-Butanone 74-97=5 Bi:omochloromethane 5 U 67-66=3 Chloroform 5 U 71-55-6 1,1;1 -Trichloroethane 5 U 56-23-5 Carbon tetrachloride . 5 5 U U 71-43-2 Benzene 107-06=2. 1;2 -Di chloroethane 5 U 79=01-6 5 U 78-87-5 ,Trichloroethene 1,2-Dichloropropane 5 U_ 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U 5 U 108-88-3 Toluene 10061-02=6 trans-1,3-Dic1,1oropropene 5 U 79-00-5 1,1,2 -Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U 5 U 591-78=6 2-Hexanone 124-48-.1 Dibromochloromethane 5 U 5 U 106-93-A 1,2-Dibromoethane 5 U FORM I VOA - 1 OLM04.2 r-+ Cn O O FORK I VOA - 2 OLM04.2 IB CONCENTRATION UNITS: BPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET COMPOUND (Pg/L or F9/R9) UG/L Q 108-90-7 MPT -3D Lab NaIDes H2M,LAB3,_I2JC. Contract: trans-l;4-Dichloro-2-butene LaFi.Codee 10:478 Ca's® No.: PCTSt SAS No.s SDG No.: TSL005 Matrixe (sbil/mater) WATER Lab Sample ID: 0603561-004A Sample :at/vol: 5 (g/mL) ML Lab File ID:, A\A45405.D Levels.' ,(Toiv/med) LOW Date Received: 03/16/06 %'MOieture5 not d®c. Date Analyzed: 03/23/06 GC Column: R-502:2 ID: .53 (mm) Dilution Factor: 1.00 Soil Nxt'iact Volumed (AL) Soil Aliquot Volume ( L) µ FORK I VOA - 2 OLM04.2 CONCENTRATION UNITS: CAS NO. COMPOUND (Pg/L or F9/R9) UG/L Q 108-90-7 Chlorobenzene 110,-57-6 trans-l;4-Dichloro-2-butene 5 U 5 U 100741-4 Ethylbenzene 5 U 630-20-6 1,1,1,2 -Tetrachloroethane 5 U 1330-20-7 Xylene (total) 100=42-5 Styrene 5 U 75725-2. Broinoform 5 U 79-34-5 1,1,2,2 -Tetrachloroethane 5 U 96-18-4. 1,2,3-Trichloropropane 5 U 106-46-7 1,4 -Dichlorobenzene 5 U 95-50-1. 1,2 -Dichlorobenzene 5 U 96-12=8 1,2-Dibromo-3-chloropropane 5 U 5 U FORK I VOA - 2 OLM04.2 M 'd' V) O O FORM I VOA -TIC OLM04.2 i 1F EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS MW-3D Lab'. Name: H2M..LABS;.'I116.. Contract: Lab": Godee.: 1'0478"Cd ee. No.: PCTSL SAS No.: SDG IJo.: TSL005 Matrix: (soil/water) WATER Lab Sample ID: 0603561-004A Sample wt/'vol a 5': (g/mL) ML Lab File ID: A\A45465.D Level: (low/med) LOW Date Received: 03/16/06 *-Moisture: not dec. Date Analyzed: 03/23/b6 GC Column: R=502.2 ID: :53 (mm) Dilution Factor: 1:00 Soil Extract Volume: (Al) Soil Aliquot Volume: 0R ( L) _ CONCENTRATION UNITS: Number TI03 found: 0 (µg/L or/K ] Ag 9 UG/L CAS NUMBER COMPOUND NAME I RT I EST.CONC. Q M 'd' V) O O FORM I VOA -TIC OLM04.2 i U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -3D Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL005 Matrix (soil/water): WATER Lab Sample ID: 0603561-004 Level (low/med): LOW Date Received: 3/16/2006 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L ICAS No. Analyte Concentration C Q M 7429-90-5 Aluminum 50.0 B P 7440-36-0 Antimony 2.9 U P 7440-38-2 Arsenic 1.8 U P 7440-39-3 Barium 41.9 B P 7440-41-7 Beryllium 0.23 U P 7440-42-8 Boron 82.7 B P 7440-43-9 Cadmium 0.12 U P 17440-70-2 Calcium 10500 P E0-47-3 Chromium 3.5 B P 0-48-4 Cobalt 3.6 B P 7440-50-8 6.0 B P 57-12-5 -Copper Cyanide 10.0 U CA 7439-89-6 Iron 75.4 B P 7439-92-1 Lead 1.4 B P 7439-95-4 Magnesium 2870 B P 7439-96-5 Manganese 1070 P 7439-97-6 Mercury 0.10 U CV 7440-02-0 Nickel 4.1 B P 7440-09-7 Potassium 8860 P 7782-49-2 Selenium 1.9 U P 7440-22-4 Silver_ 0.45 U P 7_440-23-5 Sodium 5030 P 7990-28-0 _ _ Thallium 2.6 B P 7490-62-2 Vanadium 1.4 U P 7440-66-6 Zinc 26.3 P Color Before: COLORLESS Clarity Before: Color After: COLORLESS Clarity After: Comments: Date Reported: 3/29/06 CLEAR Texture: CLEAR Artifacts: FORM .I - IN ILM04 . 1 U2M "US, INC. 575BroadFlobv Road, Metvie NY 11747 LABORATORY RESULTS (631)694-3040. FAX (631)420&W NYSDOH ID# 10478 Sample Information... Town of Southold Landfill Lab No. : 0605561-004 Type : Groundwater Attn To Origin: Client ID. : MW -3D Collected :3/16/2006 1:45:00 PM Received :3/16/2006 6:07:00 PM Collected By VSG03 Copies To :Original cc Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 7.0 1 mg/L E310.1 03/20/200611:15 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 03/16/2006 4:40 PM Bromide 0.6 1 mg/L E320.1 03/23/2006 10:15 AM Chloride 10.3 1 mg/L E325.2 03/27/2006 1:56 PM Chemical Oxygen Demand 13.5 1 mg/L E410.4 03/21/2006 10:05 AM Color < 5 1 units E110.2 03/17/2006 1:05 PM Chromium, Hexavalent < 0.02 1 mg/L M3500 -Cr D 03/17/2006 1:25 PM Hardness (As CaCO3) 43.0 1 mg/L E130.2 03/17/2006 1:35 PM Nitrogen, Ammonia (As N) 0.20 1 mg/L E350.1 03/27/2006 11:25 AM Nitrate as N 3.91 5 mg/L E353.2 03/25/2006 11:29 AM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 03/27/2006 11:15 AM Sulfate 21.7 1 mg/L SW9038 03/28/2006 1:40 PM Total DissolvedSolids 101 1 mg/L E160.1 03/20/2006 11:46 AM Nitrogen, Kjeldahl, Total 4.51 20 mg/L E351.2 03/28/2006 1:35 PM Total Organic Carbon 3.0 1 mg/L SW9060 03/22/2006 4:34 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 4/3/2006 Page 4 of 13 Q/IVK mil//�d�Ta�" Laboratory Manager IA VOLATILE ORGANICS ANALYSIS DATA SHEST Lab .Name: H2id LAHS., INC. Contract - BPA SAMPLE NO. Moo- 3 S Lab Code: ..10,478 Caee No.: PCTSL SAS No.: 3D(i No.: TSL005 ldaix:` (soil/late) i4AT8R Lab Sample Ib: 060356i=005A Sample wt/vol: 5 (9/mL) ML Lab File ID: A\A45406.D Level: (lowCmed) LOOP Date Received: 03%16/06 $•.14distu=e: not dec. Bromomethane Date Analyzed: 03/23/06 dc Columaz R=:502. ID: .53 (mID) Dilution Factor: 1.00 3iiil �i$ract Volumez Chloroethane o quot Volume (µL) CONCMURATION UNITS: CAS NO. COMPOUND f... -Pr _fe_....,- 74-87-3 Chloromethane 5 U 75-01-4. Vinyl chloride 5 U 74-83-9 Bromomethane 5 U 75-00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U 74-88-4 Iodomethane 5 U 108-05=4 Vinyl acetate 5 U 67-64-1 Acetone 5 U 75-15-0. Carbon disulfide 5 U 75=09-2 Methylene chloride 5 U .156-60=5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichloroethane 5 1:56-59=2 cis-1,2-Dichloroethene 5 U 78-53=3" 2=Butanone 5 U U 74-97=5 1 mochloromethane 5 67-56-3 Chloroform U 5 u 71-55-6 1,1,1_Trichloroethane 5 56,-23=5 Carbon tetrachloride 5 U 71=43,2 Benzene 5 U 107=0&:2 1,2-Dichloroethane 5 U 7.9'0.1=6 Trichloroethene U 78=87.5 1,2-Dichloropropane 5, 5 U 74-95-3 Dibromomethane U 5 U 75-27-4 Bromodichloromethane' 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-88-3 Toluene 5 U 10061-02-6 trans-1,3-Dichloropropene 5 U 79-00-5 1,1,2 -Trichloroethane 5 127-18-4 Tetrachloroethene 5 U U 591-78-6 2-Hexanone 5 U 124-48-1 Dibromochloromethane 5 U 106-53-4 1, 2-Dibromoethane 5 U FORM I VOA - 1 OLM04.2 18 SPA SAMPLE NO. vOLAT*LE.ORQARICS ANALYSIS DATA SSSST NW -3S Leib Na>ise: H�"6[ LRBS,; INC, Contract: Lab Cods: 1447$. Case.No.: PCTSL SAS No:: SD(; NO.: TSL005 Matrix: `(soil%hater) mATBR Lab Sample ID: 0603561-005A Sample wt/vol: 5 (9/mL) ML Lab File ID: A\A45406.D Lever ,,:: (1or�%wed) iOWDate Received: 03/16%06 :'NoisCuYes not`dec. 1330=2077 Data Analyzed: 03/23/06 CSC Coluu R.'=502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil EittadC Volumee (µL) Soil Aliquot volume ;.., 75..-2572 Hromoform CONCENTRATION UNfTS: CAS NO c6UPOIIND (µg/L or µg/Kg) UG/L Q 108--.90-7 - Chlorobenzene 5 U T10-57`6- trans=l,4-;1,4-2-butene 5 U 100=41-4 E'thylbenzene 5 U 63020=6 1,1,1,2-Tetrachlor6ethane 5 U 1330=2077 Xylene (total) 5 U 100-42-5 Styrene 5 U ;.., 75..-2572 Hromoform 5 U 79.34-5 1,1,2,2 -Tetrachloroethane 5 U 96'-18 4 1,2,3-Trichloropropane 5 U 106.46-7 1,47Dichlorobenzene 5 U 95-5071 1,2 -Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U FORM I VOA - 2 OLMo4.2 f 1F EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS.DATA SHEET I.MW-3S TENTATIVELY IDENTIFIED COMPOUNDS Lab Name e H2M LABS,,INd: Contract: LaTi Code':. 10478 Case No.: PCTSL. SAS No.: SDG No.: TSL005 Matrixa.=(soil•/wateb),:: WATER Lab Sample ID: 0603561-005A Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A45406.D Level: (low/med) LOW Date Received: 03/16/06 Moisture not dec..'' Date Analyzed: 03/23/06 GC Col"umn R-502`.2 ID;- .53 (min) Dilution Factor: 1.00 Soil `Ektract.Volume: _ (µl) Soil Aliquot Volume: 0 (µL)' FOI VOA -TIC U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -3S Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL005 Matrix (soil/water): WATER Lab Sample ID: 0603561-005 Level (low/med): LOW Date Received: 3/16/2006 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7429-90-5 Aluminum 72.4 B P 7440-36-0 Antimony 2.9 U P 7440-38-2 Arsenic 1.8 U P 7440-39-3 lBarium 47.0 B P 7440-41-7 JBeryllium 0.23 U P 7440-42-8 Boron__ 89.7 B P 7440-43-9_Cadmiu_m 0.24 B P 7440-70-2 Calcium P 7440-47-3 Chromium --- _11800 2.4 _ B P 7440-48-4 Cobalt 2.4 B P 7440-50-8 Copper 2.7 B P 57-12-5 Cyanide 10.0 U CA 7439-89-6 Iron 92.6 B P 7439-92-1 Lead 1.1 U P 7439-95-4 Magnesium 3220 B P 7439-96-5 Manganese 1150 P 7439-97-6 Mercury 0.10 U CV 7440-02-0 Nickel 3.6 B P 7440-09_-7 Potassium 9900 P 7782-49-2 Selenium 1.9 U P 7440-22-4 Silver _ _ 0.45 U P 7440-23-5 _ ISodium _ 5440 P 7440-28-0 Thallium 2.4 U P 7440-62-2 Vanadium 1.4 U P 7440-66-6 Zinc 39.8 P Color Before: COLORLESS Clarity Before: Color After: COLORLESS Clarity After: Comments: Date Reported: 3/29/06 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 1h2A I AUS, INC. 575 Broad Hollow Road, Melville NY 11747 LABORATORY RESULTS (631)694,904D. FAX (631)42(.K% NYSDOH ID# 10478 Sample information... Town of Southold Landfill Lab No. : 0603561-005 Type : Groundwater Origin: Attn To Client ID. : iMW-3S Collected :3/16/20061:15:00 PM Received :3/16/2006 6:07:00 PM Collected By VSG03 Copies To :Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 25.2 1 mg/L E310.1 03/20/2006 11:20 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 03/16/2006 4:44 PM Bromide < 0.5 1 mg/L E320.1 03/23/2006 10:30 AM Chloride 8.8 1 mg/L E325.2 03/27/20061:57 PM Chemical Oxygen Demand <10 1 mg/L E410.4 03/21/200610:06 AM Color < 5 1 units E110.2 03/17/2006 1:06 PM Chromium, Hexavalent < 0.02 1 mg/L M3500 -Cr D 03/17/2006 1:30 PM Hardness (As CaCO3) 48.0 2 mg/L E130.2 03/17/2006 1:40 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 03/27/2006 11:26 AM. Nitrate as N 4.33 10 mg/L E353.2 03/25/2006 11:30 AM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 03/27/2006 11:30 AM Sulfate 10.4 1 mg/L SW9038 03/28/2006 1:42 PM Total Dissolved Solids 101 1 mg/L E160.1 03/20/2006 11:48 AM Nitrogen, Kjeldahl, Total 0.42 1 mg/L E351.2 03/28/2006 1:36 PM Total Organic Carbon 3.0 1 mg/L SW9060 03/22/2006 5:05 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 4/3/2006 Page 5 of 13 Laboratory Manager 3A SPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SSBET MW -4D Lab Name: 82M,LAB$,.INC. Chloromethane Contract: U Lab' 6ddet>..__I0,47,8. Case No.: PCTSL SAS No.: SDG No.: T3L005 Matrix: (soil•/vate=) WATER Lab Sample ID: 0603561-006A Sample Mt/ool: 5 (g/2iL) ML Lab File ID: A\A45407.D ®vel: (lo;ijmea) LOW Date Received:. 03/16/06 $ Moistiltd: $ot;deC. Trichlbrofluor6methane Date Analysed: 03/23/06 Gc Colui&:;. A.=502..2 'ID: (mm) Dilution .Factor: 1.00 Saih.Sktract:Vol ume: (AL) Soil Aliquot Volume (µL) CONCENTRATION UNITS: CA3 NO. COMPOUND (µg/L or gg/Kg)UG/L Q 74-87-3 Chloromethane 5 U 75-01-4 Vinyl chloride 5 U 74-83'=9 Broc4omethane 5 U 75-00-3 Chloroethane 5 U _107-13.'l Acrylonitrile 5 U 75-69=4 Trichlbrofluor6methane 5 U .757357!4 1,1-Dichloroethene 5 U 74-88-4 Iodomethane 5 U 108=05-4 Vinyl acetate 5 U 67.-64-1 Acetone 6 75-15=0 Carbon disulfide 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1;2-Dichloroethene 5 U 75-34-3 1,1-Dichloroethane 5 U . `156-59-2 cis-.1;2=Dichloroethene 5 U.: 78,793=3. 2=BUtan6ne 2 J 74=97.=5. Brombchloromethane 5 U . 67-66=3. Chloroform. 5 U 71,55=6 1;.1,:1-Ttichloroethane 5 U 56 23 .5 Carbon tetrachloride 5 U 71 43=2 Be'ntene. 5 iT ]107-06-2 1,2-Dichloroethane 5 U Trichloroetheiie .. 5 U . 79=.t)7-:5 1; 2=Dichloro)Sropane 2 J 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-88-3 Toluene 5 U 10061-02-6 trans-1,3-Dichloropropene 5 U 79-00-5 1,1,2 -Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U 591-78-6 2-Hexanone 5 U 124-48-1 Dibromochloromethane 5 U 106=93-4 1,2-Dibrotrioethane 5 U FORK I VOA - 1 OLM04.2 lg 1 SPA SAMPLE NO. . VOLATILE ORGANICS ANALYSIS DATA SWMT 5 U 100-41=4 .. 5 U 630-20-6 MiO-4D 5 r 1330-20=7 - Xylene (total) 5 U 100-42-5: Styrene 5 U 75 - 25 -2 .. Brc4h0fortn Lab Code' 10:478: Case No.: ffCTSL SAS No.:SD(; No.: TSL005 5 Matrix:.(soil/crater) WATER . Lab Sample ID: 0603561-006A U Sample wt/vols 5.. (9/ML) NL Lab File ID: A\A45407.D 95-50-1 I9vels ,•: (Io�i/med) LOW Date R®ceivad: 03/16/66 1,2-Dibromo-3-chloropropane *"Moi'gtu 'e"e"_ not d'ec-. U Date Analyzed: 03/23/06 Cid'Column: R -502-I ID: .53 UkO Dilution Factor: 1.06 soil" $Xtract Volume: (µL) Soil A.114dot Volume (µL) CONCENTRATION UNITS: CAS NO: COMgOUjb (µg"/L or Ag/Kg)UG/L 4 1.08-90-7t :. Chl'orokienzene 1 J 110-57-6 t'raYfs=1;_4-Dichloro-2=butene 5 U 100-41=4 gthylbrenzene 5 U 630-20-6 1;1;1) 2-Tetrachl0ro-eth"ane 5 U 1330-20=7 - Xylene (total) 5 U 100-42-5: Styrene 5 U 75 - 25 -2 .. Brc4h0fortn 5 U 79-3475 .1,1,2,.2 -Tetrachloroethane 5 U 96=18-4- 1_;2;37Tri"chloropropane 5 U 106-46=7 1;4 -Dichlorobenzene 5 U 95-50-1 1,271?ichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U N O O CA FORM I VOA - 2 OLM04.2 E-1 FORM I VOA -TIC OLM64.2 IF EPA SAMPLE NO. VOLATILE.ORGANICS ANALYSIS DATA SHEET MW'=4D TENTATIVELY IDENTIFIED COMPOUNDS -ab Name: H2M LABS;: INC. Contract e' Lab Code",; _ 10.4,78.. Case N6. `.,PCTSL. o.: TSLO05 Matrix.. (soil/water):: WATER Lab Sample ID: 0603561-006A . Sample wt/vol: 5. (g/mL) ML Lab File ID: A\A45407.D Level: (low/med) LOW Date Received: 03/16/06 'Moisture:` not dec. Date Analyzed: 03/23/06 GCColuTrin: R -502`i2' ID 53: (timj Dilution Factor: 1.00 Soil Ektract Volume: (µl) Soil Aliquot Volume: 0 (AL) CONCENTRATION UNITS: Number TIC6 found: 0 (µg/L or µg/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST-CONC. 4 FORM I VOA -TIC OLM64.2 U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER Level (low/med): LOW Contract: SAS No.: EPA SAMPLE NO MW -4D SDG No.: TSL005 Lab Sample ID: 0603561-006 Date Received: 3/16/2006 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7429-90-5 Aluminum 117 B P 7440-36-0 Antimony 2.9 U P 7440-38_-2 Arsenic 1.8 U P 7440-39-3 _ Barium 51.4 B P 7440-41-7 744_0-42-8 Beryllium Boron ____ 0.23 238 U P P 7440-43-9 Cadmium 0.17 B P 7440-70-2 Calcium 31700 P 7440-47-3 Chromium 5.2 B P 7440-48-4 Cobalt 8.4 B P 7440-50-8 Copper 22.8 B P 57-12-5 Cyanide 10.0 U CA 7439-89-6 Iron 230 P 7439-92-1 Lead 3.8 P 7439-95-4 Magnesium 21900 P 7439-96_-5 Manganese 4560 P 7439-97-6 Mercury _ _ _ 0.10 U CV 7440-02-0 Nickel 18.6 B P 7_440-09-7 Potassium _ _ 5_1500 P 7782-49-2 Selenium 1.9 U P 7440-22-4 Silver _ 0.45 U P 7440-23-5 Sodium 73900 P 7440-28-0 Thallium 2.7 B P 7440-62-2 Vanadium 1.4 U P 7440-66-6 Zinc 20.2T P Color Before: COLORLESS Clarity Before Color After: COLORLESS Clarity After: ommen s: Date Reported: 3/29/06 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 H U2M tAUS, INC. 575 BroadHdav Road, Mdvie NY 11747 LABORATORY RESULTS (631)694,9040. FAX (631)4248436 NYSDOH ID# 10478 Sample Information... Town of Southold Landfill Lab No. : 0603561-006 Type : Groundwater Attn To Collected :3/16/2006 10:55:00 AM Received :3/16/2006 6:07:00 PM Collected By VSG03 Copies To :Original CC Client ID. : MW -4D Origin: Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 250 2 mg/L E310.1 03/20/2006 11:25 AM Biochemical Oxygen Demand 5 1 mg/L E405.1 03/16/2006 4:48 PM Bromide 2.6 1 mg/L E320.1 03/23/2006 10:45 AM Chloride 117 5 mg/L E325.2 03/27/2006 1:58 PM Chemical Oxygen Demand 33.6 1 mg/L E410.4 03/21/2006 10:07 AM Color < 5 1 units E110.2 03/17/2006 1:07 PM Chromium, Hexavalent < 0.02 1 mg/L M3500 -Cr D 03/17/2006 1:35 PM Hardness (As CaCO3) 205 5 mg/L E130.2 03/17/2006 1:45 PM Nitrogen, Ammonia (As N) 22.3 20 mg/L E350.1 03/27/2006 12:37 PM Nitrate as N 1.32 5 mg/L E353.2 03/25/2006 11:30 AM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 03/27/2006 11:45 AM Sulfate 38.8 1 mg/L SW9038 03/28/2006 1:44 PM Total Dissolved Solids 450 2 mg/L E160.1 03/20/2006 11:50 AM Nitrogen, Kjeldahl, Total 28.8 10 mg/L E351.2 03/28/2006 1:36 PM Total Organic Carbon 8.5 1 mg/L SW9060 03/22/2006 5:34 PM tI') Qualifiers: E- Value above quantitalion range D - Results for Dilution D.F. = Dilution Factor O Laboratory Manager f/] Date Reported : 4/3/2006 Page 6 of 13 IA EPA SAMPLE NO: VOLATILE ORGANICS ANALYSIS DATA 'Skkft MW-' 48 Lab Names N2M.LASS, INC. C0nt3e&Ct:' Lab Code: Cila e* No.: PCTSL SAS No.e 9DO No.: tAL005 Matrix: (soil/water). WATER tab Sample ID: 0603561-007A Sample wt/vol: 5 (g/mL) ML Lab File ID:. A\A45408.D (jow/mecj) Low -6166 DWte;ReceiveAz 03/1 Moisture: not dec. Date Analyzed: 03/23/06 GC Column: R-502.2- ID: .53 (mm) Dilution Factor: 1.06 Soil lwtk'act V'Olu* i6d: 96il Aliquot Volume (fgL) CONCffiITRATION UNITS: CAS NO. COMPOUND (ua/L.or n6hrey) Trel/T. n 74-87-3 Chlor6methane U 75-01-4 Vinyl chloride 5 U 74-83-9 Bfbmbifiethane 5 U 75-00-3 6hloroethane 5 U 107-13-1 Acrylonitrile s U 75-69-4 .,Trichlorofluorotnethane, 5 U 71 - 1,1-Dichloroethene 5 U 74-88-14 iodoiftethane s U 108-05'-4,- Vinyl acetate 5 U 67-64-1 Acetone 75-15-0 Carbon disulfide 5 U 75-09-2 +Methylene chloride 5 U 156-60-5 trans-1,27Dichlproethene- 5— U 75-34-3 ....1,1-Dichloroethand- 5— U 156-59-2 <cis-lj2=Dichlot6ethehe 5. U 78-93--3 ..2-�Butanone 74-97-5. Bromochlorom ethane 5 U 67-66--i.�ELorofo= - - .5 U 71"55-6 -1,1,1-Trichloroethane 5 U 56-23-5 -Carbon tetrachloride 5 U 71-43-2+ Benzene. .5 U 107=0672++. ..1i2-Dichlorbethane 5 U 79701-6 Trichl6r6ethene 5 U1. 7878.7-5 1,2-Dichloropropane 74-95-3 Dibromomethane 5 U 75-27-4 Br6modichloromethano 5 U 10061-01-5 cis-1,3-Dichloropro+pene. —4-Methyl-2-pentanone 5 U 108-10-1 5 U 108-88-3 Toluene 5 U 1006 trans-1,3-Dichloroprop6ne 5 U 79-00-5 1,1,2 -Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U 591-78-6 2-Hexanone 1 5 U 124-48-1 Dibromochloromethane 5. U 106=93-4 1,2-Dibromoethahe 5 U FORK I VOA 1 OLM04.2 1B BPA SAMPLE N6. VOLATILE ORGAViCS ANALYSIS DATA.SBEET Lab Name: IdM- LAB§.,• INC.. Contract: Lab Code: 10:478' Cas® NO.:. PCTSL 9A9 No.: SDG No.: T$L00.5 Matrix: (soil/water) WATER Lab.Sample I.. 06035617001A sample wt/vol: 5 (g/mL) ML Lab File IDs A\A45408.D Level: (low/coed) ib* Date Received: 03/1.6/06 Moisture: not dec. Date Aaalyaed: ;03/23/06 GC. Column: R-502.2 ID: .53 (mm) Dilutioa Factor: 1.00 Soil lgxtract volume: (pL) soil Aliquot Volume (µL) CONCENTRATION UNITS: cis NO. COMPOUND (04/L or nO/kd) UO/L O 108-90-7 Chlorobenzene 1 J 110=57-6 trans-1,4-Dichloro-2-butene 5 U 100-41-4 Ethylbenzene 5 U 630-20=6 .1,1,1,2-Tetrach1dr6etharie 5 U 1330-2077 Xylene (total) 5 U 100-42-5 Styrene 5 U 75-25-2 Bromoform 5 U 79-34-5 1,1,2,2 -Tetrachloroethane .5 U 96-18-4 ,1,2,3-Trichloropropane 5 U 106-46-7 1,4 -Dichlorobenzene 5 U 95-50-1 1,2 -Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U FORM I VOA - 2 OLM04.2 1F EPA, SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEgT. TENTATIVELY IDENTIFIED COMPOUNDS FW=4S Lab Name: H2M IABS;;,.SNC. Contracto Lab Coc)e:. 10478 Case No.: PCTSL. SAS.Nb.. S Matrix: (soil/water) WATER Lab Sample ID: 060561-007A Sample wt/vol: 5 (g/mL) ML Lab File IDc A\A45408.D Level: (low/med) LOW Date Received: 03/16/06. $ Moisture: not dec. Date Analyzed: 03/23/66- 3/23 06GC GCColumn: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volume: (µl) Soil Aliquot Volume: 0 (µL) CONCENTRATION UNITS: Number TICS found: 0 (µg/L or.µg/*Kg UG/L CAS NUMBER COMPOUND NAME RT EST.CONC. Q E U.S. EPA - CLP Concentration Units (ug/L or mg/kg dry weight): UG/L rCAS No. i Analyte 1 EPA SAMPLE NO 7429-90-5 INORGANIC ANALYSIS DATA SHEET B P 7440-36-0 Antimony 2.9 U P 7440-38-2 Arsenic MW -4S Lab Name: H2M LABS, INC. Contract: 50.3 B P 7440-41-7 Beryllium Lab Code: 10478 Case No. SAS No.: SDG No.: TSL005 Matrix (soil/water): WATER Lab Sample ID: 0603561-007 Level (low/med): LOW Date Received: 3/16/2006 % Solids: 0.0 7_440-47-3 Chromium Concentration Units (ug/L or mg/kg dry weight): UG/L rCAS No. i Analyte Concentration C Q M 7429-90-5 Aluminum 112 B P 7440-36-0 Antimony 2.9 U P 7440-38-2 Arsenic 1.8 U P 7440-39-3 Barium 50.3 B P 7440-41-7 Beryllium 0.23 U P 7440-42-8 Boron 234 P 7440-43-9 Cadmium 0.22 B P 7440-70-2 Calcium 31100 P 7_440-47-3 Chromium 5.2 B P 7440-48-4 Cobalt 8.6 B P 7440-50-8 [57-12-_5 Copper _ Cyanide _ 22.1 10.0 B P U CA 7439-89-6 Iron 123 P 7939-92-1 Lead 3.6 P 7439-95-4 Magnesium 21500 P 7439-96-5 Manganese 4480 P 7439-97-6 Mercury 0.10 U CV 7440-02-0 Nickel 18.3 B P 7440-09-7 Potassium 49600 P 7782-49-2 Selenium 1.9 U P 7440-22-4 Silver 0.45 U P 7440-23-5 Sodium 72300 P 7440-28-0 Thallium 2.4 U P 7440-62-2 Vanadium 1.4 U P 7490-66-6 Zinc 17.4 B P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 3/29/06 F FORM I - IN ILM04.1 U2A4 [AUS, INC. 575BmadHobN Road, Melville NY 11747 LABORATORY RESULTS (631)6943040. FAX(631)4205436 NYSDOHID#10478 Town of Southold Landfill Lab No. : 0603561-007 Attn To : Collected :3/16/2006 10:25:00 AM Received :3/16/2006 6:07:00 PM Collected By VSG03 Copies To :Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Color Chromium, Hexavalent Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 4/3/2006 Client ID.: MW -4S Sample Information... Type : Groundwater Origin: Results Qualifier D.F.. Units Method Number Analyzed 295 2 mg/L E310.1 03/20/2006 11:30 AM 4 1 mg/L E405.1 03/16/2006 4:52 PM 2.4 1 mg/L E320.1 03/23/2006 11:00 AM 116 5 mg/L E325.2 03/27/2006 1:58 PM 28.6 1 mg/L E410.4 03/21/2006 10:08 AM < 5 1 units E110.2 03/17/2006 1:08 PM < 0.02 1 mg/L M3500 -Cr D 03/17/2006 1:40 PM 190 5 mg/L E130.2 03/17/2006 1:50 PM 22.3 20 mg/L E350.1 03/27/2006 12:37 PM 1.01 5 mg/L E353.2 03/25/2006 11:31 AM < 5.0 1 pg/L E420.1 03/27/2006 12:00 PM 38.5 1 mg/L SW9038 03/28/2006 1:46 PM 526 2 mg/L E160.1 03/20/2006 11:52 AM 26.9 50 mg/L E351.2 03/28/2006 1:37 PM 8.5 1 mg/L SW9060 03/22/2006 6:04 PM Page 7 of 13 Q/w►� 5 /�r'1�+ Laboratory Manager O C/1 1.4 V) z :74-.8.7-3 lA 7 .7- EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA qkZ*T sl U _5 012 75-01-4 UK -5D tab Nate:. Contract, Bromomethane Lab Cd(dd: 20.479 Case Ro.: Pctst SAS Ud.:: SDG No.. TSL005. 5- E. i- U 5_00 • Matrix: (Bbi-1/wAter) WATER Lab, Sample ID:- . 0603561-008A Sample at/vol: 5 (g/mL) Mi Lab File ID:, .A\A45409.D Level- (l:ow /zed) LOW Data Rsd6iVedt 03'/16%06 % NOistute' not d6c. U batie �Ahaly;j:jcjj 0°3/23/66 GC Column: R-502.2 ID: .53 — (m m Dilutid n Fadtdr. 1i00 Soil ftttadt-volume: (AL) Soil Aliquot Volume Iodomethan6 CONCENTRATION- UNITS: CAS NO. COMPOZMD U :74-.8.7-3 Chloromethane 7 .7- 5 U _5 012 75-01-4 Vinyl chloride 74-83-9 9 E.EE75-00-3 Bromomethane 5- E. i- U 5_00 Chloroethane 10 1 1 107-13-1 Acrylonitrile 5 5 U 75--69-4 Trichlorofluoromethane 5 U 5 U 1,1-Dichloroethene .75-35-4 5 74-88-4 Iodomethan6 U Vinyl acetate 5 FORK I VOA OLM04-2 108-90-7 18 3 SPA SAMPLE NO. VOLATILB ORGANICS ANALYSIS DATA,S88ST trans-1,4-Dichloro-2-butene 5 U 100-41-4 Ethylbenzene 5 -5D LaS.Namee H2Mit"S",...INC: 1,1,1,2 -Tetrachloroethane Contract: U Lab Code'e 10'478 Case No.: PCTSL SAS No.: SDG No.: 43L005 Matrix: (soil/water) WATER Lab Sample ID: 0603561-008A .Sample wt/vol:. 5 (g/mL) ML Lab File ID: .A\A45409.0 Level: (low/med) LOW Date Receiveds 03/16/..06 % Moiature: not dec. 1;2;3-Trichloropropane Date Analyied: 03/23/06 GC Column: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil gXtract Volume: (µL) Soil Aliquot Volume (µL) U . 96-12-B CONCENTRATION Mdt6 e CAS NO. COMPOUND (ied/L`or ua/ita) [T(a/i. n 108-90-7 Chlorobenzene 3 J .110-57-6 trans-1,4-Dichloro-2-butene 5 U 100-41-4 Ethylbenzene 5 U 630-20-6 1,1,1,2 -Tetrachloroethane 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene 5 U .75-25-2 Brdmoform 79-34-5, 1,1,2,2 -Tetrachloroethane 5 U 96-18-4 1;2;3-Trichloropropane 5 106-46-7 1,4 -Dichlorobenzene 5 U 95-50-1 1,2 -Dichlorobenzene 5 U . 96-12-B 1,2-Dibroino-3-chloropropane 5 U FORM I VOA - 2 N O. OLM04.2 [� IF EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS FMW-5D -3b Name-. H2McLABS, INC. Contract: Lab ICddes 10478 Case No:: PCTSL SAS No.: SDG No.' TSL005 Matrix: (evil/water.).. WATER Lab Sample ID:. 0603561 -008A - Sample vit/vol: S. (g/mL) ML Lab File ID: A\A45409.D Level: (low/med) LOW Date Received: 03/16/06 1k Moisture': not dec. Date Analyzed: 03/23/06 GC Coluinri: R-502.•2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volumes (Al) Soil Aliquot Volume: 0 (µL) CONCENTRATION UNITS: Number TICs found`: 1 r,, -/T. :,r ._ CAS -NUMBER COMPOUND NAME RT EST.CONC. Q 1 unknown 6.25 10 1 FORM I VOA -TIC OLM64.2 s s' U.S. EPA - CLP ACAS No. Analyte 1 EPA SAMPLE NO M INORGANIC ANALYSIS DATA SHEET 80.9 B P 7440-36-0 Antimony 2.9 MW -5D Lab Name: H2M LABS, INC. Contract: 1.8 U P 7440-39-3 Lab Code: 10478 Case No. SAS No.: SDG No.: TSL005 Matrix (soil/water): WATER Lab Sample ID: 0603561-008 Level (low/med): LOW Date Received: 3/16/2006 % Solids: 0.0 7440-43-9 Cadmium Concentration Units (ug/L or mg/kg dry weight): UG/L P ACAS No. Analyte Concentration C Q M 7429-90-5 Aluminum 80.9 B P 7440-36-0 Antimony 2.9 U P 7440-38-2 Arsenic 1.8 U P 7440-39-3 Barium 134 B P 7440-41-7 Beryllium 0.23 U P 7440-42-8 Boron 631 P 7440-43-9 Cadmium 0.38 B P 7440-70-2 Calcium 81800 P 7440-47-3 Chromium 5.8 B P 7440-48-4 _ Cobalt 20.5 B P 7440-50-8 _ Copper _ 22.0 B P 57-12-5 _ Cyanide _ 10.0 U CA 7439-89-6 _ Iron _ 80.7 B P 7439-92-1 _ Lead 2.8 B P 7439-95-4 Magnesium 56500 P 7439-96-5 Manganese 12500 _ P 7439-97-6 Mercury 0.10 U CV 7440-02-0 Nickel 41.4 P 7440_-09-7 Potassium 137000 P 7782-49-2 Selenium 1.9 U P 7440-22-4 Silver 0.84 B P 7440-23-5 Sodium 196000 P 7440-28-0 Thallium _ 5.1 B P 7440-62-2 Vanadium _ 1.4 U P 7440-66-6 Zinc 15.31 B P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 3/29/06 FORM I - IN ILM04.1 U2M LABS, INC. 5758rcadHolm Road, Mdvile NY 11747 LABORATORY RESULTS ,. (631) 691-,W. FAX (631)42D8M NYSDOH ID # 10478 Sample Information... Town of Southold Land Landfill Lab No. 0603561-008 Type : Groundwater Attn To Origin: Client ID. : MW -5D Collected :3/16/2006 9:55:00 AM Received :3/16/2006 6:07:00 PM Collected By VSG03 Copies To :Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 686 4 mg/L E310.1 03/20/2006 11:35 AM Biochemical Oxygen Demand 3 1 mg/L E405.1 03/16/2006 4:56 PM Bromide 6.5 1 mg/L E320.1 03/23/2006 11:15 AM Chloride 301 10 mg/L E325.2 03/27/2006 1:59 PM Chemical Oxygen Demand 94.0 1 mg/L E410.4 03/21/2006 10:09 AM Color 5 1 units El 10.2 03/17/2006 1:09 PM Chromium, Hexavalent < 0.02 1 mg/L M3500 -Cr D 03/17/2006 1:45 PM Hardness (As CaCO3) 490 10 mg/L E130.2 03/17/2006 1:55 PM Nitrogen, Ammonia (As N) 24.2 50 mg/L E350.1 03/27/2006 1:15 PM Nitrate as N 1.65 5 mg/L E353.2 03/25/2006 11:32 AM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 03/27/2006 12:15 PM Sulfate 103 10 mg/L SW9038 03/28/2006 1:48 PM Total Dissolved Solids 1100 4 mg/L E160.1 03/20/2006 11:54 AM Nitrogen, Kjeldahl, Total 73.1 50 mg/L E351.2 03/28/2006 4:10 PM Total Organic Carbon 27.5 1 mg/L SW9060 03/22/2006 6:30 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 4/3/2006 Page 8 of 13 Laboratory Manager IA SPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MW -5S Lab' Na7mee H2M. XMS, INC. Contract: Lab Code:, 16.478 Case No.: PCTSL SAS No.: SDG No.: T3L005 .Matrix: (soil/water) WATER Lab Sample ID: 0603561-0U9A Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A45410.D Level:. (low/ked) LOW Date Received: 03/16/06 k,Moisture. not dec. 107-13-1 Date Analyzed: 03/23/06 GC Column: R-502.1 ID: .53 (mm)' Dilution Factor: 1.00 Soil $xtract Volume: (,uL) Soil Aliquot Volume (gL) 75-35-4 1,1-Dichloroethene CONCENTRATION UNITS: CAS NO. COMPOUND (µg/L or ug/Ra) UG/L 0 74-87-3 Chloromethane 5 U 75-01-4 Viriyl chloride 5 U 74-83-9 Brotnomethane 5 U 75-00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U .75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U 74-88-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5 U 67-64-1 Acetone 5 U 75-15-0 Carbon disulfide 5 U 75=09=2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichloroethane 5 U 156-5972 cis-1;2-Dichloroethene 5 U 78=93=3 2-Butanone 5 U 74-97-5 Bromochloromethane 5 U . 67-66-3 Chloroform 5 U 71=55-6 1-,1,1=Trichloroethane 5 U . 56-23.5 Carbon tetrachloride 5 U 71=43-2 Benzene 5 U 107,706-25 1,2-Dichloroethane U 7.9-01-6 Trichloroethene 5 U ,. 7887-5 1,'2-Dichloropropane 5 U 74-95-3 Dibromomethane 5 U 75=27-4 Broinodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-88-3 Toluene 5 U 10061-02-6 tr6ns-1,3-D1ch1oropropene 5 U 79-00-5 1,1,2 -Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U 591-78-6 2-Hexanone 5 U 124-48-1 Dibromochloromethane 5 U 106-93-4 1,2-Dibromoethane 5 U FORM I VOA -1 OLM04.2 18 EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET Mq-5S Lab"Name: H2M, LABS,' ,INC. Coritract: L" Code: 10476 Case No.: PCTSL SAS No.: SDC3 No. TS LOOS Matrix: (aoil/water) WATER Lab Sample ID: 0603561-009A Sample at/vol: 5 (g/mL) NL Lab File ID: A\A45410.1i Level:. (lon/med) T.O➢� Date Received: 03/16/0.6 Mo'i'sture: not 'd'ec{ . 1330-20-7 Date. Analyzed: 03/23/06 GC. iC Column: R-502:2' ID: .53 (mm) Dilution Factor: 1.00 Soil Hxtract Volume: (AL) Soil Aliquot Volume (AL) 75-25-2 $romoform CONCENTRATION UNITS: CAS NO. COMPOUND (¢a/L or ua/Ralinit [: 108=90-7 Chlorobenzene 5 U 110-57-6 - -trans-1,4-Dichloro-2-butene 5 U 100-41-4 Ethylb6nzene 5 U 630=20=6 1,1,1,2 -Tetrachloroethane 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene 5 U 75-25-2 $romoform 5 U 79-34-5 .1,1,2,2 -Tetrachloroethane 5 U 96-18-4 1,2,3-Trichloropropane 5 U 106-46-7 ..:1',4 -Dichlorobenzene 5 U 95-50-1 1,2 -Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U FORM I VOA - 2 OLM04.2 1F EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET ' MW -SS TENTATIVELY IDENTIFIED COMPOUNDS Lab Name. $2M LABS;-..INC. Contract: Cage 'No.:. PCTSL SAS No.: SDG No.: TSL005 . . Man x': (soil/water) WATER Lab Sample ID: 0603561-.009A Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A45410.D Level: (low/med) LOW Date Received: 03/16/06 W Moisture: not dec.' Date Analyzed: 03/23/06 ccc-Columns A-.: r2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volume: (µl) Soil Aliquot Volume: 0 (µL) CONCENTRATION UNITS: Number TICS found: 0 (µg/L or µg/Kg) UG/L CAS, NUMBER COMPOUND NAME RT EST.CONC. Q 1 FORM I VOA -TIC OLM04.2 00 O O U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -5S Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL005 Matrix (soil/water): WATER Lab Sample ID: 0603561-009 Level (low/med): LOW Date Received: 3/16/2006 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L ICAS No. Analyte Concentration C Q M 7429-90-5 Aluminum 64.6 B P 7440-36-0 Antimony 2.9 U P 7440-38-2 Arsenic 1.8 U P 7440-39-3 Barium 85.8 B P 7440-41-7 Beryllium 0.82 B P 744_0-42-8 Boron 115 P 7440-43-9 _ Cadmium 1.1 B P 7440-70-2 Calcium _ _ _ 13400 P 74_4_0-_47-3 Chromium 8.5 B P 7440-48-4 Cobalt 2.7 B P 7440-50-8 Copper 10.8 B P 57-12-5 Cyanide 10.0 U CA 7439-89-6 Iron 113 P 7439-92-1 Lead 2.6 B P 7439-95-4 Magnesium 9740 P 7439-96-5 Manganese 1370 P 7439-97-6 Mercury 0.10 U Cv 7440-02-0 Nickel 9.7 B P 7440-09-7 Potassium 13000 P 778_2-49-2 Selenium_ 1.9 U P 7440-22-4 Silver 0.54 B P X7440-23-5 7440-28-0 Sodium _ Thallium 14800 2.4 U P P 7440-62-2 Vanadium 1.4 U P 7440-66-6 Zinc 17.9 B P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 3/29/06 FORM I - IN ILM04.1 1-12" "Uso INC. 5758rtedHdlav Road, MtW& NY 11747 LABORATORY RESULTS �- (631A114.3040.FAX(631)424.8436NYSDOHID#10478 Sample Information... Town of Southold Landfill Lab No. .0603561-009 Type: Groundwater Attn To Origin: Client ID. : MW -5S Collected :3/16/2006 9:30:00 AM Received :3/16/2006 6:07:00 PM Collected By VSG03 Copies To :Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 63.5 1 mg/L E310.1 03/20/2006 11:40 AM Biochemical Oxygen Demand 9 1 mg/L E405.1 03/16/2006 5:00 PM Bromide 0.8 1 mg/L E320.1 03/23/2006 11:30 AM Chloride 23.8 1 mg/L E325.2 03/27/2006 2:00 PM Chemical Oxygen Demand <10 1 mg/L E410.4 03/21/2006 10:10 AM Color < 5 1 units E110.2 03/17/2006 1:10 PM Chromium, Hexavalent < 0.02 1 mg/L M3500 -Cr D 03/17/2006 1:50 PM Hardness (As CaCO3) 85.0 5 mg/L E130.2 03/17/2006 2:00 PM Nitrogen, Ammonia (As N) 4.85 5 mg/L E350.1 03/27/2006 11:29 AM Nitrate as N 1.70 5 mg/L E353.2 03/25/2006 11:33 AM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 03/27/2006 12:30 PM Sulfate 33.8 2.5 mg/L SW9038 03/28/2006 1:50 PM Total Dissolved Solids 167 1 mg/L E160.1 03/20/2006 11:56 AM Nitrogen, Kjeldahl, Total 5.77 10 mg/L E351.2 03/28/2006 4:11 PM Total Organic Carbon 6.8 1 mg/L SW9060 03/22/2006 7:04 PM Qualifiers: E : Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 4/3/2006 Page 9 of 13 Laboratory Manager IA BPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MOP- 6D Lab Name': =k ,LABS,__INCContract: Lab Code:1:0479 Cage No.: PCTSL SAS No.: SDG'No.: TSL005 Matrix: (soil/water) WATER Lab Sample ID: 0603561-OIOA Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A45413.D Level: (loo*/coed) LOW. Date Received: 03/16/06 Molstlire: not-dec. Date Analyzed: 03/23/06 GC,66lumne R-502.11 ID: .53 (mm) Dilution Pactor: 1.00 Soil Eitric.t volume- (µL) Soil Aliquot Volume (µL) CONCENTRATION UNITS: CAS NO. COMPOUND (gg/L or gg/Rg) UG/L 4 74=8773. Chloromethane 5 U 75-01-4 Vinyl.chloride 5 U 74'-83-9 Broaiomethane 5 U 75=00=3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane 5 U 75=35=4 1,,1=Dichloroethene 5 U 74=88-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5 U 67764-1 Acetone 5 75-15-0 Carbon disulfide 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichloroethane. 5 U .156759=2 ciS-1,2-Dichloroethene 5 U 78�,913 .2-Butanone 5 U 74=97-5 Bromochloromethane 5 U 67-66-3 Chloroform 5 U 71,55-6 1;1,1 -Trichloroethane 5 U 56'-23=5 ... C.dtbon tetrachloride . 5 U 71=43.2. Benzene 5 U 107-062 ...... ...... ... 1;2-Dichloroethane _ 5 U 79'-01'-6 Trichloroethene 5 U 7B=g7.�5 .1,'2=Dichloropropene 5 U 74-9573 Dibromomethane 5 U 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108=88-3 Toluene 5 U 10061=02=6 trans-1,3-Dichloropropene 5 U 79-00-5 1,1,2 -Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U 591-78-6 2-Hexanone 5 U 124-48-1 Dibromochloromethane 5 U 106=93=4 1,2-Dibromoethane 5 U FORM I VOA - 1 OLMO4.2 18 EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET 1* -6D Lab Name k s"..- Ilk. Contract: LabCode Cabe No..: PCTSL' SAS No. SDG No TSLO - 05 Matrix: (soil/mater) WATER Lab Sample ID: 0603961-010A Sample wt/vol: 5. (g/mL) ML Lab File ID': A\A45413.D LdVial: 1;1,1,2-Tetrachloroe"thane bate Received: 03116?06 soisture'-."libit ded'. 1330-20-7 Date Aiialyzed: 03/23/06 GC C0lumn6' 1-501.2 ID: .53 (mm) Dilution Factor": 1.00 Soil Ebttradt.,v6lume: (I&W Soil Aliquot Volume (,uL) Broinoform CONCENTRATION UNITS: U COMPOUND (ua/T. n -r -/WrA TTf3/T- 10 Chl8kobenzene U 110-57=6 trans-1,4-Dichl6ro-2-butene U 100-41-4 Ethylbenzena 630-20-6 1;1,1,2-Tetrachloroe"thane 5 U 1330-20-7 Xylene (total) 5 U 100=42-5 Styrene 5 U Broinoform U �79-34-5 1,1,2,2 -Tetrachloroethane 5 U 96=1'8 4 1,2,3-'Trichlotopr6pane 5 U 106-46-7 1,4 -Dichlorobenzene 5 U 95-50-1 1,2-D—ichlotobehiten6 5 U 96-12-8 .1,2-Dibromo-3-chloropr a -he 5 FORM I VOA - 2 OLM04.2 IC 1F. EPA. SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MW-6D TENTATIVELY IDENTIFIED COMPOUNDS Lab Name : 112A LABS- :. INC. Contract: I". d6de: 1U47g. Case No.: PCTSL SAS:.No.: SDG No.: TSLU05 Maitrix (soil/iatdr)_..., WATER Lab Sample ID: 0603561-010A Sample wt/vol:. 5. (g/mL) ML Lab File ID: A\A45413.D Level: (160/med),,. LOW Date Received: 03/16/06 16.M6istuie: not,dec Date Analyzed: 03/23/06 GC..Column: R=502-.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volume: (µl) Soil Aliquot Volume: 0 (µL) CONCENTRATION. UNITS: Number TIes found: 0 (µg/L or µg/Kg) UG/L CAS NUMBER. COMPOUND NAME RT EST.CONC. Q U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7429-90-5 Aluminum 42.0 B P 7_440-36-0 Antimony 2.9 U P 7440-38-2 Arsenic 1.8 U P 17440-39-3 17440-41-7 Barium Be r llium —_44.2 0.23 B U _ P P 7440-42-8 Boron 88.8 B P 7440-43-9 Cadmium _ 0.15 B P 7440-70-2 Calcium 11200 P 7440-47-3 Chromium 2.3 B P 7440-48-4 Cobalt 2.7 B P 7440-50-8 Copper 5.7 B P 57-12-5 Cyanide 10.0 U CA 7439-89-6 Iron 57.6 B P 7439-92-1 Lead_ 1.5 B P 7439-95-4 Magnesium 3020 B P 9-96-5Manganese 7439-97-6 Mercury _ _ 1090 0.10 _ U P CV 17440-02-0 __- Nickel 3.7 B P 7440-09-7 Potassium 8900 P 7782-49-2 Selenium 1.9 U P 7440-22-4 Silver 0.45 U P 7440-23-5 Sodium 5110 P 7440-28-0 Thallium 2.4 U P 7440-62-2 Vanadium 1.4 U P 7440-66-6 Zinc 24.1 P Color Before: COLORLESS Clarity Before Color After: COLORLESS Clarity After: Comments: Date Reported: 3/29/06 EPA SAMPLE NO MW -6D SDG No.: TSL005 0603561-010 3/16/2006 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 O� Ln O O N 1-2M ILAUS, INCe 575BrcadHolm Road, W& NY 11747 LABORATORY RESULTS (631)6943040. FAX (631)42(164.96 NYSDOH ID# 10478 Sample Information... Town of Southold Landfill Lab No. : 0603561-01 O Type : Groundwater Attn To Collected :3/16/2006 11:40:00 AM Received :3/16/2006 6:07:00 PM Collected By VSG03 Copies To :Original CC Client ID. : MW -6D Origin: Parameters) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310.1 03/20/2006 12:15 PM Biochemical Oxygen Demand < 2 1 mg/L E405:1 03/16/2006 5:08 PM Bromide < 0.5 1 mg/L E320.1 03/23/2006 12:15 PM Chloride 11.4 1 mg/L E325.2 03/27/2006 2:03 PM Chemical Oxygen Demand <10 1 mg/L E410.4 03/21/2006 10:13 AM Color < 5 1 units E110.2 03/17/2006 1:11 PM Chromium, Hexavalent < 0.02 1 mg/L M3500 -Cr D 03/17/2006 1:55 PM Hardness (As CaCO3) 52.0 2 mg/L E130.2 03/17/2006 2:15 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 03/27/2006 11:32 AM Nitrate as N 3.83 5 mg/L E353.2 03/25/2006 11:36 AM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 03/27/20061:15 PM Sulfate 28.1 1 mg/L SW9038 03/28/2006 1:56 PM Total Dissolved Solids 117 1 mg/L E160.1 03/20/2006 12:02 PM Nitrogen, Kjeldahl, Total 1.18 10 mg/L E351.2 03/28/2006 1:42 PM Total Organic Carbon 17.6 1 mg/L SW9060 03/22/2006 9:33 PM Qualifiers: E - Value above quantitation range 4 D - Results for Dilution . D.F. = Dilution Factor Laboratory Manager Date Reported : 4/3/2006 Page 10 of 13 FORM I VOA - 1 OLM04.2 E"( IA CONCENTRATION UNITS: BPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET COMPOUND (199/1; or µg/Kg) IIG/L Q 74-87-3 Chloromethane EMW-6S7 Lab Na$e H2k L"S,.INC. Contract: 5 U5 Lab Cod'et: 10478 Case No.: PCTSL SAS No.: 3D(i No.: TSL005 Matrix: (soil/water) WATER Lab Sample ID: 0603561-011A Sample rt/vol:. 5 (g/mL) ML Lab File ID: A\A45414.D h'evel: .(lop/med) LOW Date Received: 03/16/06 $ Moiatiireb'riot dec. Acrylonitrile Date Analysed: 03/23/06 GC col'umth R=502.2 IDt :53 (mm) Dilution Factors 1.00 Soil Extract Volume: (µL) —� Soil Aliquot Volume (µ L) FORM I VOA - 1 OLM04.2 E"( CONCENTRATION UNITS: CAS NO.. COMPOUND (199/1; or µg/Kg) IIG/L Q 74-87-3 Chloromethane 5 U5 75-01-4 Vinyl.chloride 74-83-9 Bromomethane U 15-00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane 5 5 U 75-35-4 1,1-Dichloroethene 5 U 74-88-4 Iodomethane 5 U 108-05-4 Vinyl acetate U 67-64-1 Acetone 5 U 75-15=0 Carbon disulfide 6 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75.34-3, 1,1-Dichloroethane 5 U 156-59-2- Cis71,2=Dichloroethene 5 U 78=9332=Butanone 5 U 74-97-5 Bromochloromethane 5 U5 67-66-3 Chloroform U 71-55-6 1,1,1 -Trichloroethane 5 U5 56=23-5 Carbdn tetrachloride U. .71-43-2. Benzene 5 U 107-06-2. 1, 2-Dichlorbethane 5 U ,. 79=01-6 Trichloroethene• 5 i7 ..78-87-5 1,2-Dichloropropane 5 U 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-88-3 Toluene 5 U 10061702-6 trans-1,3-Dichloropropene 5 77 79-00-5 1,1,2 -Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 i7 591-78-6 2-Hexanone 5 U 124748-1 1 Dibromochloromethane 5 U 106-93=4 1,2-Dibromoethane 5 U 5 FORM I VOA - 1 OLM04.2 E"( 1B BPA SAMPLE NO. VOLATILB.6RO;ANIC3 ANALYSIS DATA SHEET ilii- 6$ Lab: Name: HZii;:.LA85; :,INC. Contract: tab'.Code'e 1.0478 Case No.: POT, L SAS No.: SDG 'No.: T3L005 Matrix: (soil/crater) WATER Lab Sample ID: 0603561-011A Sampl's nt/vol: 5 (g/M,) M, Lab File ID: A\A45414.D Le:►ai: (lob/meA). LOW Date Received: 03/16/06 Mssa'tuee ad't dec.. Date Analyzed: 03/23/06 aC C61ilid: R=502:2 ID: .53(mm) Dilution Factor: 1.00 §oil Extract Volume: (µL) Soil Aliquot Volume R CONCENTRATION UNITS: CAS 'ifb.. COMPOUND (µg/L or Ag/kg) IIO/L 108-90-•7 Chlorobenzene 5 110-57=6 tr4ns=l;47Dichloro-2-butene S 100=41-4 Ethylberizene 5 630-.20-6 1,1,1,2 -Tetrachloroethane 5 1330-20-7 Xylene (total) 5 100-42-5 Styrene 5 75-25-.2„ Bromoform .. 5 79-34-5 1,1;2;2 -Tetrachloroethane 5 '96718=4 1,2,3-Trichloropropane 5 106-46-7. 1,4 -Dichlorobenzene 5 90-1 L1,2 -Dichlorobenzene 5 92-8 1,2-Dibromo-3-chloropropane 5 FORM I VOA - 2 OLM04.2 IF EPA SAMPLE NO. VOLATI' ORGANICS ANALYSIS DATA SHEET. TENTATIVELY IDENTIFIED COMPOUNDS MW -6S Contracts LaY Cdde; 10478 Case•: No : PCTSI,. SAS No. c SDG No.: TSL0.05 Matirec; (soil/.mater) : RATER LaYi Sample ID: 0603561-011A Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A45414.D Level:, (low/med) LOW Date Received: 03/16/06 �rMbi-stute: :not ded. Date Analyzed: 03/23/06 ID•e :53 (mm) Dilution Factor: 1.00 . §oil EXtact Volume: (µi) Soil Aliquot Volume: 0• (µL) CONCENTRATION UNITS: Niimber:Tics found: 0 (µg/L or µg/Kg) UG/L CAS NUMBER. COMPOUND NAME RT EST.CONC. Q U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -6S Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL005 Matrix (soil/water): WATER Lab Sample ID: 0603561-011 Level (low/med): LOW Date Received: 3/16/2006 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 17429-90-5 Aluminum 66.3 B P 7440-36-0—Antimony 2.9 _ U P 7440-38-2 Arsenic 1.8 U P 7440-39-3 Barium 46.0 B P 7440-41-7 Beryllium 0.23 U P 7440-42-8 Boron 94.1 B P 7440-43-9 Cadmium 0.29 B P 7440-70-2 Calcium 11900 P 7440-47-3 Chromium 3.1 B P 7440-48-4 Cobalt 4.6 B P 7440-50-8 IC, 4.8 B P 57-12-5 Cyanide 10.0 U _ CA 7439-89-6_ Iron - --- 87.6 B _ P 7439=92-1 Lead- 1.6 B P 7439_-95-4 Magnesium 3140 B P 7439-96-5 Manganese 1250 P 7439-97-6 Mercury 0.10 U CV 7440-02-0 Nickel 3.9 B P 7440-09-7 Potassium 10200 P 7782-49-2 Selenium 1.9 U P 7440-22-9 Silver 0.45 U P 749_0_-23-5 Sodium 5040 P Thallium 2.4 U P F7440-28_-0 1F74_90-62-2 Vanadium 1.4 U P 7490-66-6 Zinc 17.4 B P - Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported_ 3/29/06 FORM I - IN ILM04.1 U2M I AUS, INC. 575 BradHdlow Road McKie NY 11747 LABORATORY RESULTS (631)6t34.3040.FAX(631)42(18M NYSDOHID#10478 Sample Information... Town of Southold Landfill Lab No. : 0603561-011 Type : Groundwater Attn To : Origin: Client ID.: MW -6S Collected :3/16/2006 11:20:00 AM Received :3/16/2006 6:07:00 PM Collected By VSG03 Copies To :Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 28.6 1 mg/L E310.1 03/20/2006 12:20 PM Biochemical Oxygen Demand < 2 1 mg/L E405.1 03/16/2006 5:12 PM Bromide < 0.5 1 mg/L E320.1 03/23/2006 12:30 PM Chloride 7.9 1 mg/L E325.2 03/27/2006 2:04 PM Chemical Oxygen Demand <10 1 mg/L E410.4 03/21/2006 10:14 AM Color < 5 1 units E110.2 03/17/2006 1:12 PM Chromium, Hexavalent < 0.02 1 mg/L M3500 -Cr D 03/17/2006 2:00 PM Hardness (As CaCO3) 47.0 1 mg/L E130.2 03/17/2006 2:20 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 03/27/2006 11:33 AM Nitrate as N 3.32 5 mg/L E353.2 03/25/200611:37 AM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 03/27/2006 1:30 PM Sulfate 10.7 1 mg/L SW9038 03/28/2006 1:58 PM Total Dissolved Solids 103 1 mg/L E160.1 03/20/2006 12:04 PM Nitrogen, Kjeldahl, Total 2.19 20 mg/L E351.2 03/28/2006 1:42 PM Total Organic Carbon 40.8 1 mg/L SW9060 03/22/2006 10:04 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 4/3/2006 Page 11 of 13 Laboratory Manager O 00 V) 0 r FORM I VOA - 1 OLMo4.2 00 CA O O H IA 5 8PA SAMPLE NO. VOLATILE. ORdAliICB ANALYSIS DATA.3888T Vifiyl ,chloride 5 U -8 74-83- E75-00-3 BtaThomethane 5 U MW -8D 'Chloroethane5 Lab N6driee "k LABS,_INC:.: U Contract: ------------ .Acrylonitrile Lab Codes 1048 Cae®'No.e PCTSL SAS No*.:. SDG No.: TSL005 .Matrix: (soil/water) WATER Lab Sample ID: 0603561-012A 5a p1e k/vol: 5. (q/m,) ML: Lab File.ID: A\A45415.D L®ve1: Ci A,:" LOii Date Received: 03/16/06 Ai-' So 'a ure. riot dec: U Date Analyt6a: 03/23/06 Gd Column: R=5.02:2 ID: .53 (mm) Dilution Factor: 1.00 So (IQ Soil Aliquot Volume ()zL) .. Methylene chloride 5 CONCENTRATION UNITS: CAS- NO- , dOAPOUND lua/L er amIr"l TMIT. n FORM I VOA - 1 OLMo4.2 00 CA O O H . Chloromethane 5 U Vifiyl ,chloride 5 U -8 74-83- E75-00-3 BtaThomethane 5 U 'Chloroethane5 U .Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane 5 U ,.: 75-35 4 1,1-Dichloroethene 5 U 74788-4- .,lodomethane. 5 U .•.108-05 .4' Vinyl acetate 5 U 67-64-1 :Acetone 9 75715-0. .Carbon disulfide 5 U 75709-2 .. Methylene chloride 5 U 156=60-5 trans-l,2-Dichloroethene 5 U 75=34-3' ;1,1-Dichloroethane 5 U 156755 2 cid:=1;2-Dichlorodthene 5 U 7893 3 2 gilt annone 5 U 74.=57 5. ' Broihochloromethane 5 U 67=66=3 Chloroform 5 U 71-55-'6 ..1,1;1=Trichloroethane .. 5 U 56-23 5 :.Carbon tetrachloride. 5 U 71=43 2 Benzene S U 7-96---m2 1, 2 ' Dichloroet2iaae 5 U .. '_' 79`=OY 6 ;,Trichltlrdethene —78-87-5- -1 2=Dichloropiropane 5 U 74795-3.. Dibromomethane 5 U 75-2774 Bromodichloromethane 5 U 10061-01=5 ciB71,3-Dichloropropene 5 U 108=30-1 4-Methyl-2-pentanone 5 U 108-88-3 Toluene 5 U 10061-02-6 trans-1,3-Dichloropropene 5 U 79-00-5 1,1,2 -Trichloroethane 5 U 127-1874 Tetrachloroethene 5 U 591-78-6 2-Hexanone 5 U 124-48-1 Dibromochloromethane 5 U 106=93-4 1,2-Dibromoethane 5 U FORM I VOA - 1 OLMo4.2 00 CA O O H Lab NaiIIe s H2t4 `,LAS$;:-., INC. Contract: Lab Codes 10478 Case No.: PCTSL SAS No.: SDG No.: T8L005 Matrix: (soil/water) WATER Lab Sample ID: 0603561-012A Sample at/vol:.: .5:* g/mL ML Lab File ID: A\A45415.D Level (low/med) I.ON, Date Received: 03/16%06 sh Moisture' not: did: 1330-20-7, Date Abalyzed: 03/13/06 dc -Columi4 R'=50j....2 ID: .53 (mm) Dilution Factor: 1.00 Soil Exuact Volume:..- (µL) Soil Aliquot Volume (µL) .75=25 2 Bromoform CONCENTRATION UNITS: CAS NO. COMPOUND l.,.. /r. .,� ... w:.i T4^1 108-90-7 . , Chloiobenzene - - 5 U '• 110=57-6•.._.tra1Ts-1,4-Dichl0ro-2-butene 5 U HO. 417-4. Ethylbenzene 5 U .630-20=6. 111,1,2 -Tetrachloroethane 5 U 1330-20-7, ,Xylene (total) 5 U 100-42-5 Styrene 5 U .75=25 2 Bromoform 5 U 79-34-5,_jjl ,2,2-Tetrachlor0ethane 5 U 96-18=:4: 1,2,3-Trichloropropane 5 U 106-46'-7 1,4 -Dichlorobenzene 5 U 95-50-1 ,. 1,127Dichlorobenzene 5 U 96'=12-8. 1,2-Dibromo-37chloropropane: 5 U N 00 C/1 O V1 FORM I VOA - 2 OLM04.2 1F EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MW-8D TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: ' . H2M LAB'S; r ING:. Contracts Lab Code,: 10478 Cade. 90- P.CTSL SAS •No.: SDG No.: TSL005 Matrix: (soil/water) -WATER Lab Sample ID: .0603561-mA Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A45415.D Level: (low/med) LOW Date Received: 03/16/66 96 Moisture.: riot- ec. .' Date Analyzed: 03/,23/06 'GC 'Column: R `502 T ID 53 (min) ` Dilution Factor: 1.00 . Soil Extract Doluine:. (µl) Soil Aliquot Volume: 0 (µL) CONCENTRATION UNITS: Number TICs found.: 0. (µg/L or µg/Kg) UG/L CPiS N[7GSBER 'COMPOUND NAME RT EST . CONC . Q U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract:. Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L ;CAS No. Analyte Concentration C Q M 7_429-90-5 Aluminum_ 60.2 B P 7440-36-0 Antimony 2.9 U P 7440-38-2 Arsenic 1.8 U P 7440-39-3 Barium 44.6 B P 7440-41-7 Beryllium 0.23 U P 7440-42-8 Boron 114 P 7440-43-9 Cadmium _ 0.18 B P 7440-70-2 _ Calcium_ 11900 P _ 7440-47-3 Chromium 7440-48-4 ICobalt 2.8 3.3 B P B P 7440-50-8 Copper — -- 4.9 B P 57-12-5 Cyanide 10.0 U CA 7439-89-6 Iron 73.7 B P 7439-92-1 Lead 1.6 B P 7439-95-4 Magnesium 3600 B P 7439-96-5 Manganese 1120 P 7439-97-6 Mercury 0.10 U Cv 7440-02-0 Nickel 4.0 B P 7440-09-7 Potassium 41300 P 7782-49-2 Selenium 1.9 U P 7440-22-4 Silver 0.45 U P 7440-23-5 Sodium_ 46900 P 74_4_0-28-0 _ Thallium _ 2.4 U P 7990-62-2 Vanadium _ 1.4 U P 7940-66-6 Zinc 45.2 P Color Before: COLORLESS Clarity Before: Color After: COLORLESS Clarity After: Comments: Date Reported: 3/29/06 EPA SAMPLE NO MW -8D SDG No.: TSL005 3/16/2006 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 FS U28t LADS, INC. 5758mad HDlow Road, Mdvile NY 11747 (631)694-3 . FAX {631)4208436 NYSDOH ID# 10478 Town of Southold Landfill Attn To : Collected :3/16/2006 12:50:00 PM Received :3/16/2006 6:07:00 PM Collected By VSG03 Copies To :Original CC LABORATORY RESULTS Lab No. : 0603561-012 Client ID.: ll Sample Information... Type: Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310.1 03/20/2006 12:25 PM Biochemical Oxygen Demand 55 1 mg/L E405.1 03/16/2006 5:16 PM Bromide < 0.5 1 mg/L E320.1 03/23/2006 12:45 PM Chloride 84.8 2 mg/L E325.2 03/27/2006 2:05 PM Chemical Oxygen Demand 152 1 mg/L E410.4 03/21/2006 10:15 AM Color < 5 1 units El 10.2 03/17/2006 1:13 PM Chromium, Hexavalent < 0.02 1 mg/L M3500 -Cr D 03/17/2006 2:05 PM Hardness (As CaCO3) 52.0 2 mg/L El 30.2 03/17/2006 2:25 PM Nitrogen, Ammonia (As N) 2.18 1 mg/L E350.1 03/27/2006 11:34 AM Nitrate as N 3.82 5 mg/L E353.2 03/25/2006 11:37 AM Phenolics, Total Recoverable 49.3 1 pg/L E420.1 03/27/2006 1:45 PM Sulfate 47.8 2.5 mg/L SW9038 03/28/2006 2:00 PM Total Dissolved Solids 385 1 mg/L E160.1 03/20/2006 12:06 PM Nitrogen, Kjeldahl, Total 71.1 50 mg/L E351.2 03/28/2006 4:13 PM Total Organic Carbon 40.0 1 mg/L SW9060 03/22/2006 10:30 PM Qualifiers: E - Value above quantitation range , D - Results for Dilution D.F. = Dilution Factor Date Reported : 4/3/2006 Page 12 of 13 Laboratory Manager kn 00 V) 1A RPA SAMBLR NO. VOLATILE akdANICs ANALYSIS DATA SHSET MW -8S Lab' Name: H2MLASSINC. Contraot: tab Code: 10;478 Case No.: PCTSL SAS No.: SDG No.: TSL005 Matrix: (soil/'Water) WATER Lab Sample ID: 0663561-013A Sample 'it/vol: 5 (g/") ML Lab File. ID: A\A45416.D - Level : (.1'owymed) LO➢P • Date Received: 03/16/06 Moiafur® not a®c. Date Abalysed: 03/23/06 GC Columae R-502.2 ID: .53 (mmj Dilutioa Factor: 1.00 Soil Extiact Volume: (µL) Soil Aliquot Volume (l+ L) CONCM1TRATION UNITS: CAS NO'.. COMPOUND (µg/L or µg/xg) uG/L Q 74-87-3. Chloromethane 75-01=4 Vinyl chloride 5 U 74=83-9 Bromomethane 5 U 75-00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75=69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichlorbetheni 5 U 74-8874. Iodomethane 5 U 108-05-4 Vinyl.acetate 5 U 67-64-1 Acetone S. U 75-,15=0. Carbon disulfide:.. 9 75-09-2 Methylene chloride 5 U 156=60-5 trans-1,2-Dichloroethene 5 U 75-34-31,1-Dichloroethene 5 U 156=59-2 I is-1,2-Dichloroethene 5 U 78-93-3. 2-Butanbne 5 U 74-97-5 Bromochloromethane 5 U 67=66-3 Chloroform 5 U 71-55-6 ._ 1,1,1 -Trichloroethane 5 U .- 56,23-5 CaYbon.tietrachlarcie; 5 U _ 71-43-2`- Benzene 5 U 107-06-2 1,2'-Dichloroethene,: 5' U Trichloroethene 5 U 78'-87=5 1,2-W dhloropropane 5 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-88-3 Toluene 5 U 10061=02-6 trans-l,3-Dichloropropene 5 U 79-00-5 1,1,2 -Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U 591-78-6 2-Hexanone 5� U 124-48-1 Dibromochloromethane 5 U � 106-93-4 1,2-Dibromoethane 5 U 5 U FORK I VOA - 1 OLM04.2 108j90-7 IB EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SBEST trans-1,4-Dichloro-2=butene 5 5 U U 100=41-4 Ethylbenzene l®P-BS Lab Na"me:.. . HZDS. LABS.; ..INC. C62itract. U 630-20-6 1,1,1,2 -Tetrachloroethane Lab Coded. Ilia CAse No.: PCTSL AS No.: SDC; No.: T6L005 Matrix: (soil/water) WATER Lab Sample ID: 0603561-013A Sample wttvol: 5 (9/mL) ML. Lab.i+ile ID: A\A45416.D Level: .16w med) LO➢i Date. Received: 03/16/06 Moistuie: not dec: Date Analyzed': 03/Z3/06 GC Column: R-502:2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volume: (AL) goof 9611 Ali' Volume (µL) 1,2,3-TrichlorbpYopane 5 CONCMITRATION UkITS: CAS NO. COMPOUND 108j90-7 Chlorobenzene 110-57=6 trans-1,4-Dichloro-2=butene 5 5 U U 100=41-4 Ethylbenzene 5 U 630-20-6 1,1,1,2 -Tetrachloroethane 5 U 1330-20-7 Xylene (total) 100-42-5 Styrene 5 U 5 U 75=25-2 Bromoform... 5 U. 79=34-5 .1,1,2;2 -Tetrachloroethane 5 U 96-18-4 1,2,3-TrichlorbpYopane 5 106-4'6-7 1,4 -Dichlorobenzene- U 95-50-1 112=Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 1 U 5 1U FORM I VOA - 2 OLM04.2 00 L/) kn O O c 00 00 1F EPA SAMPLE NO. VOLATILE ORGANICS. ANALYSIS DATA SHEET, TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: H2M,.LABS; INC; Contract: I,ab Code: Case,.No.:, PCTSL SAS No:: . SDC No..:.. TSL005 Matrix: (soil/.water):: . WATER Lab' Sainple'ID: 0603561.-013A Sample wt/ vol:. 5 (g/mL) MI, Lab File ID: A\A45416.D Level: (low/med) LOW Date Redeived: 03116106 Moisture: not dec. Date.Arialyzed: 03/23/06 GC Column: R=,502::2 ID: .53 (mti)* Dilution,Factor: 1:00 Soil. Extract Volume: (Al) Soil Aliquot Volume: 0 (µ L) CONCENTRATION. UNITS`: Number TICS £oiind: 0 (µg/L or µg/kg) UG/L CAS NUMBER COMPOUND NAME RT EST.CONC. Q 00 00 U.S. EPA - CLP CAS No. Analyte 1 EPA SAMPLE NO M INORGANIC ANALYSIS DATA SHEET 63.5 B P 7440-36-0 Antimony 2.9 MW -8S Lab Name: H2M LABS, INC. Contract: 1.8 U P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL005 Matrix (soil/water): WATER Lab Sample ID: 0603561-013 Level (low/med): LOW Date Received: 3/16/2006 % Solids: 0.0 P P P P 7440-48-4 Concentration Units (ug/L or mg/kg dry weight): UG/L B CAS No. Analyte Concentration C Q M 7429-90-5 Aluminum 63.5 B P 7440-36-0 Antimony 2.9 U P 7440-38-2 Arsenic 1.8 U P 7440-39-3 Barium 45.3 B P 7440-41-7 Beryllium 0.23 U P 7440-42-8 !7440-43-9 7440-70-2 7440-47-3 Boron116 Cadmium Calcium Chromium _ 0.27 12200 3.0 B B P P P P 7440-48-4 _ Cobalt 3.6 B P 744_0_-50-8 Copper 5.1 B P 57-12-5 Cyanide 10.0 U CA 7439-89-6 Iron 79.2 B P 7439-92-1 Lead 1.8 B P 7439-95-4 Magnesium 3700 B P 7439-96-5 Manganese 1150 P 74_39-97-6 0.10 U Cv 7440-02-0 _Mercury Nickel 4.2 B P 17490-09-7 Potassium 43500 P 7782-49-2 Selenium _ B _ P 7490-22-4 Silver _1.9 ---- - 0.46 B P 7440-23-5 Sodium 49300 P 7440-28-0 Thallium 2.4 U P 7440-62-2 Vanadium 1.4 U P 7440-66-6 Zinc 45-91 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported_ 3/29/06 FORM I - IN ILM04.1 ►�1 U2M LABS, INC. 575BroadHdlav Road, Md& NY 11747 LABORATORY RESULTS (631)694-M. FAX (631)42D8436 NYSDOHID#10478 Town of Southold Landfill Lab No. : 0603561 Attn To Collected :3/16/2006 12:25:00 PM Received :3/16/2006 6:07:00 PM Collected By VSG03 Copies To :Original Cc Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Color Chromium, Hexavalent Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon Client ID. : MW -8S Sample Information... Type : Groundwater Origin: Results Qualifier D.F.. Units Method Number Analyzed < 1.0 1 mg/L E310.1 03/20/2006 12:30 PM 38 1 mg/L E405.1 03/16/2006 5:20 PM < 0.5 1 mg/L E320.1 03/23/2006 1:00 PM 82.7 1 mg/L E325.2 03/27/2006 2:05 PM 154 1 mg/L E410.4 03/21/2006 10:16 AM < 5 1 units E110.2 03/17/2006 1:14 PM < 0.02 1 mg/L M3500 -Cr D 03/17/2006 2:10 PM 54.0 2 mg/L E130.2 03/17/2006 2:30 PM 2.12 1 mg/L E350.1 03/27/2006 11:34 AM 4.07 10 mg/L E353.2 03/25/2006 11:38 AM 47.2 1 pg/L E420.1 03/27/2006 2:00 PM 48.2 2.5 mg/L SW9038 03/28/2006 2:02 PM 363 1 mg/L E160.1 03/20/2006 12:08 PM 71.7 50 mg/L E351.2 03/28/2006 4:13 PM 56.7 1 mg/L SW9060 03/22/2006 11:04 PM Qualifiers: E - Value above quantitation range D - Results for Dilution i D.F. = Dilution Factor Date Reported : 4/3/2006 Page 13 of 13 Qnv� /►l. Laboratory Manager CONCXN4XRATION UNITS: CAS 140: COMPOUND OWL or Ilk Q114) UG/Y, O 74-87-3' IA 5 SPA SALE NO. VOLATILE ORGANICS ANALYSIS DATA SHSBT Vinyl chloride 5 U 74-83=9 Bromomethane 5 U TRIP BLANK 3/16 Chlorbethane Lab. Name: H2k.-LABS,. INC. Contract: Acrylonitrile Lab•dodo: 10478 Case No.: PCTSL SAS No.: SDG Nb,,e TSL005 Matrix= (soil/grater) WATER Lab Sample ID: 0603561-014A Sample Mt/vol: 5 (g/nL) ML Lab File ID: A\A45417.D .Level:. .(low/med) LOW Date Redeivdds.... 03_/16/06. Moisture: not dec. U Date Aaalysedi _ 03/23/06 GC Column: R-50.2.2 ID: .53 (mm) Dilution Babtbr: 1.00 Soil Rittract Volume: (AL) Soil Aliqudt Volume CONCXN4XRATION UNITS: CAS 140: COMPOUND OWL or Ilk Q114) UG/Y, O 74-87-3' Chloromethane 5 U 75-01-4 Vinyl chloride 5 U 74-83=9 Bromomethane 5 U 75-00=3 Chlorbethane 5 U 107-13-1 Acrylonitrile 5. U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U 74-88-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5 U 67-64-1 Acetone 5 U 75-15-0 Carbon disulfide 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3. 1,1-Dichloroethane 5 U 156-59-2 cis-1,2-Dichloroethene 5 U. 78-93-3 2-Butanone 5 74-97-5 Bromochloromethane 5 U 67-66-3 Chloroform 5 U 71-55-6 111,17Trichloroethane .5 U' 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene .5'. ;.U.' .. 107-06-'2 1,2=Dichloroethane .. 5 U ' 79=01-6 Trichloroethene -5 .:U 78-87-5 1,2=5ichloropropane 5 U 74-95-3 Dibromomethane 5 U 75-27-4 BYomodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-88-3 Toluene 5 U 10061-02-6 trans-1,3-Dichloropropene 5 U 79-00-5 1,1,2 -Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U 591-78-6 2-Hexanone 5 U 124-48-1 Dibromochloromethane 5 U 106-93-4 1,2-Dibroiioethane 5 U V1 FORM I VOA - 1 OLM04.2 108-90-7 1H SPA SAMPLE NO: VOLATILE ORGANICS ANALYSIS DATA 3HSBT 110-57-6 trans-1,4-Dickiloro-2-butene 5 U 100-41-4 TRIS BLANK 3%16 5 Lab Name: H2M..LABS, INC. 1,1,1,2 -Tetrachloroethane Cont=act: -Lab 'Coae: T04ll Case No.: PCTSL SAS No.: Slid.No.: T3L00'5 Matrix: (soil/water) WATER Lab Sample ID: 0603561-014A Sample wt/vol: 5 (g/mL) ML Lab File #: A\A45417..D Leirel: (low/med) LOOP Date Received: 03/16%06 Moisture: sot•dec. 79-34-5 Date Ahalyaed: 03723[06 GC Column: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract volume: (AL)' Soil Aliquot volume (µL) 106-46-7 1,4 -Dichlorobenzene CONCENTRATION UNITS: CAS NO. COMPOUND (µg/L or µg/xg) UO/L O 108-90-7 Chlorobenzenei 5 U 110-57-6 trans-1,4-Dickiloro-2-butene 5 U 100-41-4 Ethylbeniene 11 5 U 630-20-6 1,1,1,2 -Tetrachloroethane 5 U 1330-20-7 Xylene (total)' 5 U 100-42-5 Styrene 5 U 75.25-2� Bromoform 5 w U 79-34-5 1,1,2,2 -Tetrachloroethane 5 U 96-18=4 1,2,3-Trichloropropane 5 U' 106-46-7 1,4 -Dichlorobenzene 5' U 95-50-1 1,2 -Dichlorobenzene 5 U 96-12-8 1 1,2-Dibromo-3-chloropropane 5 U FORM I VOA - 2 N O V1 OLM04.2 I i 1F. EPA ,SAMPLE,, NO.. VOLATILE ORGANICS ANALYSIS DATA SHEET TRIP BLANK 3/16 TENTATIVELY IDENTIFIED COMPOUNDS Lab Name':•= INC: Contract:. Lab .0ode, i .10478 Case No.: PCTSL SAS No.: SDG No.:''TSL005: - Matrix: (soil%water); WATER Lab Sample ID: 06035'6T�"014A Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A45417.1) Level: (low/med) LOW Date Received: 63/16/06 Moisture: not'dec. Date"Analyzed: 03/23/06 GC Column:`'..R-502-.2 ID: .53 (mm) Dilution' Factor: 11.06 Soil Extract Volume: (µl) Soil Aliquot Volume: 0' (µL) CONCENTRATION UNITS: Number TICS found: 0. (µg/L or Ag/Kg) UG/L . CAS NUMBER COMPOUND NAME RT EST.CONC. Q U2M IAU%, INC. 5. SURROGATE SPIKE ANALYSIS RESULTS 5.1 VOLATILES i f 2A WATER VOLATILE SYSTEM MONITORING COMPOUND RECOVERY . Lab'Nemee HIM LASS;:INC: Contract: Lab Code: 10478 Case.No.: PCTSL SAS No.: SDG No.: TSL005 01 02 03 04 pc OE Oi OE pc 1C 1] li 13 14 1E lE 11 .lE 15 EPA SAMPLE< N0: - SMC1 Nit # SMC2 TOL # SMC3 OTHER BFB # TOT OUT VBLK032306 96 101 101 0 LF803230'6 101. 100 100 0 W9032366 99 101 102 0 E¢PT 96. 100 101 0 MW-; 1D '. 97 99 101 0 MW=1S 96 99 100 0 MW -3D 9'6 99 100 0 MW -3S 96 100' 100 0 MW44D 96 100 101 0 MW -4S 95 99 100 0 MW -SD 95 100 100 0 MW=5S 94 99 99 0 MW=SSMS 95 100. 99 0 MW--5SMSb°' 95 101 100 0 MW=6D''... .. 94 .99 100 0 MW=6S' 94 100 100 0 MW -8D 94 99 99 0 MW -8S 94.' 991. 99 0 TRIP BLANK 3/16 92 99 99 0 QC Limit :i.'SMC 1 I7CE •2 1,-Dichloroethane=d4 (76-114) SMC2'. TOL Toluene= 8 (88-110) SMC 3 BFB = 4-Bromofiuorobenzene (86-115) # Column to be used to flag recovery values * Values outside of contract required QC limits page 1 of 1 FORM II VOA -1 OLM04.2 U284 "US, INC. 6. MATRIX SPIKE / MATRIX SPIKE DUPLICATE SUMMARY 6.1 VOLATILES .3A ..WATER VOLATILE MATRIX SPIRE/MATRIX SPIRE DUPLICATE RECOVERY Lab�,NameV. .H2k LAW, INC:,. Contract: Lab:C6de`i,10478 Case No.i PCTSL SAS No.: SDG No.: TSL005 Mait=re Spike - EPA Sample No.: MW -5S GOMP'OUND. SPIKE ADDED (Ng/L) SAMPLE CONCENTRATION (ug/L) MS CONCENTRATION (Ng/L) MS % REC # QC. LIMITS REC: 1 T-0ichloroeftWne.° 50 0 53 106 61-145 Benz®ne 50 0 55 111 76-127 Trichloroethene 50 0 52 104 71-120 Toluene' 50 0 53 107 76-125 Chlorobenerie 50 0 54 108 75-130 COMPOUND SPIKE ADDED MSD CONCENTRATION (uglL) MSD % REC # RPD # QC LIMITS RPD I REC. 1,14Didhbroeftne 50 57 114 7 14 61-145 Beltzife 50 61 121 9 11 76-127 TridhIditfhene 50 57 114 9 14 71-120 Toliteiie 50 58 117 9 13 76-125 Chlor6be�ene 50 59 119 10 13 75-130 VAO £e's- oiii side . of QG .limits RPD: 0 out of 5 outside limits Spike Recovery: 0 out of 10 outside limits COMMENTS: lORD[ III VOA -1 OLH04.2 3A SYSTEM MONITORING SPIKE RECOVERY . Lab -Name:HIM LABS;. INC. Contract: Lab Codei 10478 Case No.: PCTSL SAS No.: SDG No.: TSL005 Sample ID. MSB032306 Level:(low/med) LOW COMPOUND SPIKE ADDED (PA) SAMPLE CONCENTRATION SPIKE C6NCENTF2ATI0N SPIKE % REC 9 QC. LIMITS REC. 1,1-Dichioroethene 50 0 50 100 61-145 Benzene 50 0 54. 108 76-127 Triehbfoett end 50 0 51 102 71-120 Toluene 50 0 51 103 76-125 Ctil&owi�zene 50 0 52 104 75-130 $'Column to be used to flag recovery and RPD values.witli an asterisk *.Values outside 'of .QC'limits Spike Recovery: 0 . out of 5 outside limits . . -COMMENTS: .- FORM III SW8260B z 3A SYSTEM MONITORING.SPIKE RECOVERY SDG No.: TSL005 Level:(low/med) LOW COMPOUND SPIKE ADDED ( GVQ SAMPLE CONCENTRATION (09/0 SPIKE CONCENTRATION (14L) . SPIKE % REC # QC. LIMITS REC. Chloromethahe 5o 0 53 106 70-114 hA chloride 50 0 55 111 66-117 Bromorfiet lane 50 . 0 54 109 50-136 Chbroetfiiine 50 0 54 109 71-116 cr*nitnle 50 0 58 1116, 74122 Trictilordfluoromethane 50 0 55 109 64124 1,1-Dich1o'roethene 50 0 53 105 67-120 lodo nethane 50 0 54 108 70-122 myl acetate 50 0 53 106 76-118 Acetone 50 0 63 125 71-125 Carbon disuffide 50 0 54 107 61-126 Methylene_ chloride 50 0 55 111 80-112 naris-1,2-Dichlorootherie 50 0 54. 108 74-115 1,16Dichloroethane 50 0 55 110 77-114 cis 1;2-pkhloroethene 50 0. m. 109 78-116 2�13utanofie 50 0 58 117 74121 Br6hWchloromethane 50 0 55 110 81-114 Chloroform 50 0 56 112 75-119 1,1,1 Trich)oroethahe 50 0 55 110 66-126 Carbon tetrachloride 50 0 58 116 64126 Benzene 50 0 55 111 77-116 1,24)ichloroethane 50 0. 57 115 76-120 Tridildroettiene .50 0 56 112 72-121 1;2t4dhloroEf 6r* 50 0 56 112 81-115 Diliioniomethane 50 0 56 113 82-114 Bromodichloromethane 50 0 57 113 78-118 cis-r;3-bldiloroproliene 50 ... 0 57 . 114 79-118 4 #Rtitti*-2-pentandne • 50 0 57. 114 79-121 Tolud" . 5o 0' 56 . 111 - 70-125 trartis�l;3 DicFiloropiGpene: _50., 0 . 57 ;. 113 77-120 # Column to be, used:Eo flag recovery and RPD values With An asterisk * ,Values:.outside of QC lifaitb Spike Recovery: 0 out of 47 outside.limits C� COMMENTS: FORM III SW826013 i 3A SYSTEM MONITORING SPIKE RECOVERY Lab.Name: H2M LABS,.INC.. Coritract: Lab Codec 10478 Caee 146.: PCTSL SAS No.: SDG No.: TS1,005 Sample_ID LFB032Sd6' Level:(low/med) LOW 1A.,24ridiWwthane . 50 .0 57 114 82-116 etrechtdroAthene. ". • ; . 50 0 . 59 . .118 59-133 2=He7tarieiie. 50 0 59 118 76-119 Dbmmochbromethane 50 0 58 115 79-118 1,2-Dibroerioeth6ne 50 0 57 114 81-117 Cnlorobentene 50 0 56 111 72-124 trap A',* ' Ibro-2-butene 50 .0 55 110 47-135 Ethylbenzene 50 0 54 109 68-128 1,1,1,2 -Tetrachloroethane 50 0 57 114 76-119 ylene (totaq 150 0 160 109 70-125 Styrene' 50 0 55 110 72-124 Bromoform 50 0 58 116 75-121 1,A2-Tet(achlofoetha6e .:.. 50 0 57 113 77-120 1;2;3=Trichloropropane 50 0 57 113 78-118 I koibtrloroben erie 50 0 55 110 67-128 1,2 -Dichlorobenzene 50 0 56 112 71-123 1,2-0ibromo-3-chloropropane 50 0 57. 114 74-123 COMMENTS: FORM III ;. .. SW826013 c U2M "US, INC. 7. DUPLICATE SUMMARY RESULTS 7.1 METALS 7.2 WET CHEMISTRY Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER % Solids for Sample: 0.0 U.S. EPA - CLP 6 EPA SAMPLE NO DUPLICATES MW -5S Contract: SAS No.: SDG No.: TSL005 Level (low/med): LOW % Solids for Duplicate: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L Analyte Control Limit Sample (S) C Duplicate (D) C RPD Q M Aluminum_ 200.0000 64.6200 B 36.8800 B 54.7 P Antimony _ - 2.9176 U 2.9176 U P Arsenic 1.7682 U 1.7682 U P _ Barium 200.0000 1 85.8200 B 87.9200 B 2.4 P _ Beryllium 5.0000 0.8200 B 0.2297 U 200.0 P Boron 100.0000 115.4000 117.4000 1.7 P Cadmium 5.0000 1.1200 B 0.2500 B 127.0 P _ Calcium 5000.0000 13422.3500 13768.2200 2.5 P Chromium 10.0000 8.4800 B 7.3900 B 13.7 P Cobalt 50.0000 2.7300 B 2.3000 B 17.11 P Copper 25.0000 10.8300 B 10.3800 B 4.2 P Cyanide 10.0000 U 10.0000 U CA _ Iron 100.0000 _ 113.0800 55.7100 B 68.0 P Lead _ _ 2.5965 B 2.4671 B 5.1 P Magnesium _3.0000 5000.0000 9735.9200 10018.7000 2.9 P Manganese 1367.5400 1405.5300 2.7 P Mer_cur 0.1000 U 0.1000 U CV Nickel 40.0000 9.6800 B 9.0300 B 6.9 P Potassium 5000.0000 13017.5800 13970.9100 7.1 P Selenium 1.9100 U 1.9100 U P Silver 10.0000 0.5414 B 0.4485 U 200.0 P Sodium 5000.0000 14805.0400 15351.0900 3.6 P Thallium 2.4157 U 2.4157 U P Vanadium 1.3551 U 1.3551 U P Zinc 20.0000 17.3600 B 18.9000 B 8.5 P FORM VI - IN ILM04.1 H2M LABS, INC. SDG: TSL005 Date: 30 -Mar -06 QC SUMMARY REPORT Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -032006 MB -032005 Alkalinity, Total (As CaCO3) < 1 mg/L LCS-032006 LCS-032006 Alkalinity, Total (As CaCO3) 21.3 mg/L 25 < 1 85 180 120 0603561-009fms MW-5SMS Alkalinity, Total (As CaCO3) 90.6 mg/L 25 63.5108 75 125 0603561-009fdup MW-5SDUP Alkalinity, Total (As CaCO3) 62.1 mg/L 63.5 2.2 20 MB -03-16-06 MB -03-16-06 Biochemical Oxygen Demand < 2mg/L mg/L LCS-03 16 06 LCS-03 16-06 Biochemical Oxygen Demand 196 mg/L 200 <2 98 80 120 D603561-009FDUP MW-5SDUP Biochemical Oxygen Demand 3 mg/L 9 1 100 20 MB -032306 MB -032306 Bromide < 0.5 mg/L LCS-032306 LCS-032306 Bromide 4.9 mg/L 5< 0.5 98 80 120 0603561-009FMS MW-5SMS Bromide 5.6 mg/L 5 0.8 96 75 125 0603561-009Fdup MW-5SDUP Bromide 0.8 mg/L I 0.8 0 20 MB -03-21-06 MS -03-21-06 Chemical Oxygen Demand <10 mg/L LCS-03-21-D6 LCS-03-21-06 Chemical Oxygen Demand 993 mg/L 1000 < 10 99 80 120 0603561-009CMS MW-5SMS Chemical Oxygen Demand 1020 mg/L 1000 < 10 102 75 125 0603561-009CDUP MW-5SDUP Chemical Oxygen Demand <10 mg/L < 1020 MB -032706 MB -032706 Chloride <2 mg/L LCS-032706 LCS-032706 Chloride 47.8 mg/L 50 < 2 96 80 120 0603561-009FMS MW-5SMS Chloride 51.1 mg/L 25 23.8 109 75 125 d2O 0603561-009FDUP MW-5SDUP Chloride 25.1 mg/L 23.8 5.5 MB -031706 MB -031706 Chromium, Hexavalent < 0.02 mg/L LCS-031706 LCS-031706 Chromium, Hexavalent 0.18 mglL 0.2 < 0.02 90 80 120 0603561-009FMS MW-5SMS Chromium, Hexavalent 0.17 mg/L 0.2 < 0.02 85 75 125 0603561-009FDUP MW-5SDUP Chromium, Hexavalent < 0.02 mg/I- < 0.02 20 1 TSL005 S103 QC SUMMARY REPORT SDG: TSL005 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -031706 MB -031706 Color < 5 units LCS-031706 LCS-031706 Color 40 units 40 < 5 100 80 120 0603561-009FDUP MW-5SDUP Color < 5 units I 1 1 <5 20 MB -031706 MB -031706 Hardness (As CaCO3) < 5 mg/L LCS-031706 LCS-031706 Hardness (As CaCO3) 1040 mg/L 1000 < 5 1 104 80 120 0603561-009Dms MW-5SMS Hardness (As CaCO3) 605 75 125 mg/L 500�!P� 0603561-009Ddup MW-5SDUP Hardness (As CaCO3) 90.0 mg/L 85.0 5.7 20 MB -032506 MB -032506 Nitrate as N < 0.1 mg/L LCS-032506 LCS-032506 Nitrate as N :1.12. mg/L 1.13 <0.1 99 80 120 0603561-009CMS MW-5SMS Nitrate as N 4.11 mglL 2.5 1.70 96 75 125 0603561-009CDUP MW-5SDUP Nitrate as N 1.70 mg/L 1.70 0 20 MB3-16478 MB3-032706 Nitrogen, Ammonia (As N) < 0.1 mg/L MB -16488 MB -032806 Nitrogen, Kjeldahl, Total < 0.1 MB2-16478 MB2-032706 Nitrogen, Ammonia (As N) < 0.1 mg/L m9/L 4.1 < 0.1 112 80 120 LCS-16488 LCS-032806 Nitrogen, Kjeldahl, Total MBl-16478 MB1-032706 Nitrogen, Ammonia (As N) < 0.1 mg/L 10.2 mg/L 4.1 5.77 108 75 125 0603561-009CDUP MW-5SDUP LCS3-16478 LCS3-032706 Nitrogen, Ammonia (As N) 1.04 mg/L 1 < 0.1 104 80 120 LCS2-16478 LCS2-032706 Nitrogen, Ammonia (As N) 1.03 mg/L 1 < 0.1 103 80 120 LCS1-16478 LCS1-032706 Nitrogen, Ammonia (As N) 1.03 mg/L 1 < 0.1 103 80 120 0603561-009CMS MW-5SMS Nitrogen, Ammonia (As N) 11.0 mg/L 5 4.85 123 75 125 0603561-009CDUP MW-5SDUP Nitrogen, Ammonia (As N) 5.36 mg/L 4.85 10 20 MB1-16488 MB1-032806 Nitrogen, Kjeldahl, Total < 0.1 m91L MB -16488 MB -032806 Nitrogen, Kjeldahl, Total < 0.1 mg/L LCS1-16488 LCS1-032806 Nitrogen, Kjeldahl, Total 4.60 m9/L 4.1 < 0.1 112 80 120 LCS-16488 LCS-032806 Nitrogen, Kjeldahl, Total 4.53 mg/L 4.1 < 0.1 110 80 120 0603561-009CMS MW-5SMS Nitrogen, Kjeldahl, Total 10.2 mg/L 4.1 5.77 108 75 125 0603561-009CDUP MW-5SDUP Nitrogen, Kjeldahl, Total 6.01 M91L 5.77 4.1 20 TSL005 S104 QC SUMMARY REPORT SDG: TSL005 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Umits value %RPD UCL MB -0327066 MB -0327066 Phenolics, Total Recoverable < 5 ug/L LCS-032706 LCS-032706 Phenolics, Total Recoverable 29.1 ug/L 30 < 5 97 80 120 0603561-009CMS MW-5SMS Phenolics, Total Recoverable 19.8 ug/L 20 < 5 99 75 125 0603561-009Cdup MW-5SDUP Phenolics, Total Recoverable < 5 ug/L < 5 20 MB -0328D6 MB -032806 Sulfate < 5 mg/L LCS-032806 LCS-032806 Sulfate 19.7 mg/L20 < 5 98 80 120 0603561-009FMS MW-5SMS Sulfate 84.5 �L 50 33.8 102 75 125 0603561-009Fdup MW-5SDUP Sulfate 34.2 mg/L 33.8 1.5 20 MB -03-20-06 MB -03-20-06 Total Dissolved Solids <10 rng/L LCS-03=20-06 LCS-03-20-06 Total Dissolved Solids 336 ing/L ' 300,'.' .<10 112' 80 120 0603561-009FMS MW-5SMS Total Dissolved Solids 490 mg/L 300 167 108 75 125 0603561-009FDUP MW-5SDUP Total Dissolved Solids 171 mg/L 1 167 2.4 20 MB -032203 MB -032203 Total Organic Carbon <1 mg/L LCS-032203 LCS-032203 Total Organic Carbon 26.4 mg/L 25 <1 106 80 120 0603561-009BMS MW-5SMS Total Organic Carbon 16.8 mg/L 10 6.8 100 75 125 0603561-009BDUP MW-58DUP Total Organic Carbon 5.9 mg/L 6.8 14.2 20 TSL005 5105 U2M "US, INC. 8. SPIKE SAMPLE RESULTS 8.1 METALS 8.2 WET CHEMISTRY i Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER % Solids for Sample: 0.0 U.S. EPA - CLP 5A SPIKE SAMPLE RECOVERY Contract: SAS No.: Concentration Units (ug/L or mg/kg dry weight) EPA SAMPLE NO MW-5SS SDG No.: TSL005 Level (low/med): LOW UG/L Control Limit I Analyte %R Spiked Sample Result (SSR) C Sample Result (SR) C Spike Added (SA) %R Q M _ •_ L- Aluminu_m •----•-- 75-125 1993.6700 64.6200 B 2000.00 96.5 P Antimon _ _ Arsenic 75-125 75-125 _ 498.1016 39.0805 _ 2.9176 1.7682 U1 U 500.00 40.00 99.6 97.7 P P ___ Barium_ 75-125 _ _ _ 2186.3000 85.8200 B 2000.00 105.0 P Berllium _ Boron 75-125 75-125 52.8500 714.8800 0.8200 115.4000 B 50.00 500.00 104.1 119.9 P P Cadmium 75-125 52.4800 1.1200 B 50.00 102.7 P Chromium 75-125 216.3200 8.4800 B 200.00 103.9 P Cobalt 75-125 498.6100 2.7300 B 500.00 99.2 P Co er 75-125 276.4900 10.8300 B 250.00 106.3 P Cyanide 75-125 81.2692 10.0000 U 100.00 81.3 CA Iron 75-125 1002.5300 113.0800 1000.00 88.9 P Lead 75-125 21.6229 2.5965 B 20.00 95.1 P _ Manganese Mercury___ 75-125 75-125 1866.1300 1.0700 1367.5400 0.1000 U 500.00 1.00 99.7 107.0 P CV Nickel 75-125 505.2700 9.6800 B 500.00 99.1 P Selenium_ 75-125 11.0318 1.9100 U 10.00 110.3 P Silver 75-125 _ 48.6932 0.5414 B 50.00 96.3 P Thallium 75-125 48.3492 2.4157 U 50.00 96.7 P Vanadium 75-125 500.9500 1.3551 U 500.00 100.2 P Zinc 75-125 551.0800 17.3600 B 500.00 106.7 P Comments: FORM V (Part 1) - IN ILM04.1 z H2M LABS, INC. SDG: TSL005 Date: 30 -Mar -06 QC SUMMARY REPORT Spike Sample Recovery RPDRef °/ RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -032006 MB -032006 Alkalinity, Total (As CaCO3) < 1 mg/L LCS-032006 LCS-032006 Alkalinity, Total (As CaCO3) 21.3 mg/L 25 < 1 85 80 120 0603561-009fms MW-5SMS Alkalinity, Total (As CaCO3) 90.6 mg/L 25 63.5 108 75 125 0603561-009fdup MW-5SDUP Alkalinity, Total (As CaCO3) 62.1 mg/L 63.5 2.2 20 MB -03-16-06 MB -03-16-06 Biochemical Oxygen Demand < 2 mg/l LCS-03-16-06 LCS-03-16-06 Biochemical Oxygen Demand 196 mg/L 200 < 2 98 80 120 3603561-009FDUP MW-5SDUP Biochemical Oxygen Demand 3 mg/L I 1 9 100 20 MB -032306 MB -032306 Bromide < 0.5 mg/L LCS-032306 LCS-032306 Bromide 4.9 mg/L 5 < 0.5 98 80 120 0603561-009FMS MW-5SMS Bromide 5.6 mg/L 5 0.8 96 75 125 0603561-009Fdup MW-5SDUP Bromide 0.8 mg/L I I0.8 0 20 MB -03-21-06 MB -03-21-06 Chemical Oxygen Demand <10 mg/L LCS-03-21-06 LCS-03-21-06 Chemical Oxygen Demand 993 mg/L 1000 < 10 99 80 120 0603561-009CMS MW-5SMS Chemical Oxygen Demand 1020 mg/L 1000 < 10 102 75 125 0603561-009CDUP MW-5SDUP Chemical Oxygen Demand <10 mg/L <10 20 MB -032706 MB -032706 Chloride < 2 mg/L LCS-032706 LCS-032706 Chloride 47.8 mg/L 50 < 2 96 80 120 0603561-009FMS MW-5SMS Chloride 51.1 mg/L 25 23.8 109 75 125 0603561-009FDUP MW-5SDUP Chloride 25.1 mg/L 23.8 5.5 20 MB -031706 MB -031706 Chromium, Hexavalent < 0.02 mg/L LCS-031706 LCS-031706 Chromium, Hexavalent 0.18 mg/L 0.2 < 0.02 90 80 120 0603561-MFMS MW-5SMS Chromium, Hexavalent 0.17 M91L 0.2 < 0.02 85 75 125 0603561-009FDUP MW-5SDUP Chromium, Hexavalent < 0.02 m91L < 0.02 20 I TSL005 S108 QC SUMMARY REPORT SDG: TSL005 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REG Limits Value %RPD UCL MB -031706 MB -031706 Color < 5 units LCS-031706 LCS-031706 Color 40 units 40 < 5 100 80 120 0603561-009FDUP MW-5SDUP Color < 5 units I I I< 5 20 MB -031706 MB -031706 Hardness (As CaCO3) < 5 mg/L LCS-031706 LCS-031706 Hardness (As CaCO3) 1040 mg/L 1000 < 5 104 80 120 0603561-009Dms MW-5SMS Hardness (As CaCO3) 605 mg/L 500 85.0 104 75 125 0603561-009Ddup MW-5SDUP Hardness (As CaCO3) 90.0 mg/L 85.0 5.7 20 MB -032506 MB -032506 Nitrate as N < 0.1 mg/L LCS-032506 LCS-032506 Nitrate as N 1.12 mg/L 1.13 <0.1 99 80, 120 0603561-009CMS MW-5SMS Nitrate as N 4.11 mg/L 2.5 1.70 96 75 125 0603561-009CDUP MW-5SDUP Nitrate as N 1.70 mg/L 1.70 0 20 MB3-16478 MB3-032706 Nitrogen, Ammonia (As N) < 0.1 mg/L MB -16488 MB -032806 Nitrogen, Kjeldahl, Total < 0.1 mg/L MB2-16478 M132-032706 Nitrogen, Ammonia (As N) < 0.1 mg/l. LCS-16488 LCS-032806 Nitrogen, Kjeldahl, Total 4.53 mg/L 4.1 < 0.1 110 80 120 MBl-16478 MBl-032706 Nitrogen, Ammonia (As N) < 0.1 mg/L 0603561-009CDUP MW-5SDUP Nitrogen, Kjeldahl, Total 6.01 mg/L 15.77 4.1 20 LCS3-16478 LCS3-032706 Nitrogen, Ammonia (As N) 1.04 mg/L 1 < 0.1 104 80 120 LCS2-16478 LCS2-032706 Nitrogen, Ammonia (As N) 1.03 mg/L 1 < 0.1 103 80 120 LCS1-16478 LCS1-032706 Nitrogen, Ammonia (As N) 1.03 mg/L 1 < 0.1 103 80 120 0603561-009CMS MW-5SMS Nitrogen, Ammonia (As N) 11.0 mg/L 5 4.85 123 75 125 0603561-009CDUP MW-5SDUP Nitrogen, Ammonia (As N) 5.36 mg/L 4.85 10 20 MBl-16488 MBI -032806 Nitrogen, Kjeldahl, Total < 0.1 m9tL MB -16488 MB -032806 Nitrogen, Kjeldahl, Total < 0.1 mg/L LCS1-16488 LCS1-032806 Nitrogen, Kjeldahl, Total 4.60 rr4/L 4.1 < 0.1 112 80 120 LCS-16488 LCS-032806 Nitrogen, Kjeldahl, Total 4.53 mg/L 4.1 < 0.1 110 80 120 0603561-009CMS MW-5SMS Nitrogen, Kjeldahl, Total 10.2 mgIL 4.1 5.77 108 75 125 0603561-009CDUP MW-5SDUP Nitrogen, Kjeldahl, Total 6.01 mg/L 15.77 4.1 20 2 TSL005 5109 QC SUMMARY REPORT SDG: TSL005 Spike Sample Recovery RPDRef %RPD Sample ID' Client Sample ED: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -0327066 MB -0327066 Phenolics, Total Recoverable < 5 ug/L LCS-032706 LCS-032706 Phenolics, Total Recoverable 29.1 ug/L 30 < 5 97 80 120 0603561-009CMS MW-5SMS Phenolics, Total Recoverable 19.8 ug/L 20 < 5 99 75 125 0603561-009Cdup MW-5SDUP Phenolics, Total Recoverable < 5 ug/L < 5 20 MB -032806 MB -032806 • Sulfate < 5 mg/L LCS-032806 LCS-032806 Sulfate 19.7 ngfL 20 < 5 98 80 120 0603561-009FMS MW-5SMS Sulfate 84.5 mg/L 50 33.8 102 75 125 0603561-009Fdup MW-5SDUP Sulfate 34.2 mg/L 33.8 1.5 20 MB -03-20-06 MB -03-20-06 Total Dissolved Solids <10 mg/L LCS-03=20-06 LCS-03-20-06 Total Dissolved Solids 336 mg1t: 300'• .<10 112' 80 120 0603561-009FMS MW-5SMS Total Dissolved Solids 490 mg/L 300 167 108 75 125 0603561-009FDUP MW-5SDUP Total Dissolved Solids 171 mg/L 167 2.4 20 MB -032203 MB -032203 Total Organic Carbon < 1 mg/L LCS-032203 LCS-032203 Total Organic Carbon 26.4 mg/L 25 < 1 106 80 120 0603561-009BMS MW-5SMS Total Organic Carbon 16.8 mg/L 10 6.8 100 75 125 0603561-009BDUP MW-5SDUP Total Organic Carbon 5.9 mg/L 6.8 14.2 20 TSL005 S 110 U2M "US. INC. 9. BLANK SUMMARY DATA AND RESULTS 9.1 VOLATILES 9.2 METALS 9.3 WET CHEMISTRY c 4A EPA SAMPLE NO. VOLATILE METHOD BLANK SUMMARY VBLK032306 Lab:Name: 1 M,LABS,•INC.. Contract: 'Lab'Code-: 10478.: Gase:No.: PCTSL SAS No.: SDG No.: TSL005 Lab.'File,ID:.:A\°A45.399`:D: Lab. Sample ID: VBLK032306 :Date Analyzed: .03/23/06 Time.Analyzed: 10:34 GC'Columat 'R-`50'2:2'•ID .53 (mm) HeaCed Purge: (YIN) N Iriatrdmeat ID: HP5971 THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS, AND MSD: EPA SAMPLE NOr LAB SAMPLE 10 LAB FILE ID TIME ANALYZED LF8032306 LFBO32306 _ A1A45400.D 11:05 MSaMM MSBO32306. A1A45401.13 12:69 -EOPT 0603561-001A A%A45402.1) 12:49 MW -113. 0603561-002A A1A45403.1) 13:21 MW=15 0603561-003A A1A45404.D 13:53 MW30 0603561-004A AWW6.1) 1424 MW S. 0603561-005A AA45406.1) 14:56 MW -.4D 0603561400GA AW5407.1) 15:27 MW -4S 0603561-007A AV145408.D 15:59 MIN -SD 0603561-OOBA AW45409.'D 16:30 MWSS' 0603561-009A A1A45410.D 17:02 MW-5sw 060$561-009AMS A1A45411.1) 17:34 MWS.SMSD 0603561-OOAMSD AA45412.1) 18:05 MW -60 0603561-010A A%A45413.1) 18:36 rune► -es 0603561-011A AW45414.D 19:68 MW -8D 0603561-012A AVW5415.13 19:39 MW -BS 0603561-013A A1A45416.1) 20:11 TRIP BLANK 3/16% 0603561-014A A\A45417.D 20:42 COMMENTS: page A of 1 FORM IV VOA OLM04.2 N Ln O O cn sm CONCENTRATION -UNITS: CAS NO. COMPOUND (µg/L or aa/Ka) UG/L 0 74-87-3 IA 5 BPA SAMPLENO. VOLATILE ORGANICS ANALYSIS DATA SHBBT Vinyl chloride 5 U . 74=83=_9 Bromomethane 5 U �BLK032306'. Chloroethane Lab Name: ii2m.LABS',:INC. U Contract: Acrylonitrile Lab Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL005 Matrix: (soil/water) WATER Lab Sample ID: VBLR032306 Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A45399..D Level: _ (low/med) LOW Date Re'ceive'd: Vinyl acetate +k M6iatUte6 not'dec'. U Date Analyzed: 03/23/06 GC Column: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Attract Volume: (pL) Soil Aliquot Volume (µL) CONCENTRATION -UNITS: CAS NO. COMPOUND (µg/L or aa/Ka) UG/L 0 74-87-3 -Chloromethane 5 U 75-01=4 Vinyl chloride 5 U . 74=83=_9 Bromomethane 5 U 75700-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4. Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U 74-88-4 Iodomethane 5 U 108-05=4 Vinyl acetate 5 U 67-664=1 Acetone 5 U 75-15-0 Carbon disulfide 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichloroethane 5 U 156-59-2 cis-1,2=Dichloroethene 5 U 78-93-3 2-.Butanone 5 U 74=97-5 Bromochloromethane 5 U 67=66-3 Chloroforin 5 U 71-55-6 1,1,1 -Trichloroethane 5 U 56=23-5:-:•Chrbon tetrachloride 5 U 71-43-2 Benzene 5 U 107=06-2 1;2-Dichloroethane 5 U 79-01-6 Trichloroethene 5 U 78=87-5 1,2-Dichloropropane 5 U 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-88-3 Toluene 5 U 10061-02-6 trans-1,3-Dichloropropene 5 U 79-00-5 1,1,2 -Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U 591-78-6 2-Hexanone 5 U 124-48-1 Dibromochloromethane 5 U 106=93=4 1,2-Dibromoethane 5 U FORM I VOA - 1 OLM04.2 IB' BPA SAMPLE NO. VOLATILB • ORdANiCS ANALYSIS DATA SARET VBLK032306 Lab Name: H2M.LAB3,,.INC. Chlorobenzene Contract: Lab Code: 10478 Case No.: PCTSL SAS No.: SDO No.: T8L005 Matrix: (Boil/,Water) WATER Lab Sample ID: VBLR032306 Sample Ott/vol': 5. (g/mL) ML Lab File ID: A\A45399.D Bevel: (tor/med) LOW Date Received: % Moisture: not dec. 1330-20-7 Date Analyzed: 03/23/66 GC Column: R-.502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil lixtract Volume: (µL) Soil Aliquot Volume (µL) 75-25-2 Bromoform CONCENTRATION U91TS: CAS NO. COMPOUND 1,1,2,2 -Tetrachloroethane 108-90-7 Chlorobenzene 110=57-6 trarTB-1,4-Dichloro-2-butene U 100-41.-4 Ethylbeilzene a5,u U630=20-6 1,1,1,2 -Tetrachloroethane U 1330-20-7 Xylene (total) U 100-42-5 Styrene 5 U 75-25-2 Bromoform 5 U 79=34-5 1,1,2,2 -Tetrachloroethane 5 U -96=18-4 1,2,3-Trichloropropane 5 U 10:6 -46 -7.1,4 -Dichlorobenzene 5 U 95-50-1 1,2 -Dichlorobenzene 5 U 96=12-8 1 1,2-Dibromo-3-chloropropane 5 U FORM I VOA - 2 OLM04.2 IF EPA SAMPLE NO. .,'v6i..ATIL,E ORGANICS .ANALYSIS DATA SHEET VBLK02306- TENTATIVELY IDENTIFIED COMPOUNDS Lab kam*ef - Contract: Lab Code: 161417.' Caad-Ji6.: PC'TSL SAS No. SDG No.: - Matrix: (66ill*i . jej.),- WATER Lab Sample ID: VBLK032306 SAmpld wt/vol: 5 (g/mL) ML Lab File ID: A\A45399.1) Level: (low/me"d).. Loiq Date Received: m6i dturb: hot. dee. Date Analyzed: 03/23/H .GC' d6lum fi: :�,k=502 . 2 (mm) Dilution Factor: 1.00 Soil Extriat Volume: . Soil Aliquot Volume: 0 (11L) CONCENTRATION UNITS: Number TIC's .6und2':.. (,ug/L or Ag/K4) UG/L CAS. NUMBER COMPOUND NAM RT I EST.CONC. I I Q 0IM04.'2' U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL005 Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L Analyte I Initial Calib. Blank (ug/L) Continuing Blank C 1 C Calibration (ug/L) 2 C 3 C Prepa- ration Blank C M Aluminum 9.9 U 9.9 U 9.9 U 16.0 B 9.921 U P Antimony 2.9 U 2.9 U 2.9 U 2.9 U 2.916 U P Arsenic 1.8 U 1.8 U 1.8 U 1.8 U 1.768 U P Barium 1.5 U 1.5 U 1.5 U 1.5 U 1.511 U P Beryllium 0.2 U 0.2 U 0.2 U 0.2 U 0.230 U P Boron 1.3 U 1.5 B 1.3 U 1.3 U 1.310 B P Cadmium 0.3 B 0.2 B 0.2 B 0.1 U 0.122 U P Calcium _ 7.4 U 7.8 B 7.4 U 7.4 U 9.420 B P Chromium.-.--,- 0.3 U 0.3 U 0.3 U 0.3 U 0.930 B P Cobalt __ 1.2 U 1.2 U 1.2 U 1.2 U 1.198 U P _ Copper Iron_ _ 1.0 17.8 U _ 1.0 U 17.8 U U -1.2 17.8 B U -1.8 17.8 B U 0.964 25.100 U B P P _ Lead_ 1.1 U 1.1 U 1.1 U 1.1 U 1.126 U P Magnesium 8.2 U 8.2 U 8.2 U 8.2 U 8.230 U P Manganese 0.4 U 0.4 U 0.4 U 0.4 U 0.376 U P Nickel 1.0 U 1.0 U 1.0 U 1.0 U 1.042 U P Potassium 49.8 B 36.7 B 37.0 B 34.4 B 37.600 B P Selenium_ 1.9 U 1.9 U 2.0 B 1.9 U 1.910 U P Silver 0.4 U 0.4 U 0.4 U 0.4 U 0.449 U P Sodium 15.0 U 15.0 U 15.0 U 15.0 U 14.979 U P _ rihallium _ 2.4 U 2.4 U 2.4 U 2.4 U 2.416 U P (Vanadium !Zinc 1.4 1.4 U 1.4 U 1.4 U U 1.4 1.4 U U 1.4 1.4 U U 1.355 3.790 U B P P FORM III - IN U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL005 Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L FORM III - IN ILM04.1 TInitial Calib. Continuing Calibration Prepa- Analyte i Blank (ug/L) C 1 Blank (ug/L) C 2 C 3 ration C Blank C M Aluminum Antimony _ Arsenic - — 26.1 2.9 1.8 B U U P p p B_a_riIum —} 1.5 U P Beryllium Boron Cadmium 0.2 1.3 0.1 U U U P P Calcium - - —__--- 7.4 U P Chromium 0.3 U p Cobalt 1.2 U P Copper -1.9 B P Iron 17.8 U P Lead 1.1 U P Magnesium Manganese Nickel 8.8 0.4 1.0 B U U P P P Potassium Selenium Silver ( Sodium------ Thallium Vanadium Zinc _ —_ -- —_ 34.6 1.9 0.4 15.0 2.4 1.4 3.2 B U U U U U B P P P P P P P FORM III - IN ILM04.1 U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL005 Preparation Blank Matrix (soil/water),: WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L Initial Calib. Continuing Calibration Prepa- Blank Blank (ug/L) ration Analyte (ug/L) C1 1 C 2 C 3 C Blank C M Mercury 0. if 0.1 U 0.1 U 0.1 U 0.100 U CV FORM III - IN ILM04.1 z U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL005 Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L FORM III - IN Initial Calib. Continuing Calibration Prepa- Blank Blank (ug/L) ration Analyte (ug/L) C 1 C 2 C 3 C Blank C M lCyanide U 10 _0 U 10.01 U I 10.§T 1 10.0001 U ICA :- - — -10.OI FORM III - IN H2M LABS, INC. SDG: TSL005 Date: 30 -Mar -06 QC SUMMARY REPORT Spike Sample Recovery RPDRef %RPD Sample ID• Client Sample ID: Analyte Result Units Amount Result %REC Umits Value %RPD UCL MB -032006 MB -032006 Alkalinity, Total (As CaCO3) < 1 mg/L LCS-03-16-06 LCS-032006 LCS-032006 Alkalinity, Total (As CaCO3) 21.3 mg/L 25 < 1 85 80 120 0603561-009fms MW-5SMS Alkalinity, Total (As CaCO3) 90.6 mg/L 25 63.5 108 75 125 0603561-009fdup MW-5SDUP Alkalinity, Total (As CaCO3) 62.1 mg/L 163.5 2.2 20 MB -03-16-06 MB -03-16-06 Biochemical Oxygen Demand < 2 mg/L LCS-03-16-06 LCS-03-16-06 Biochemical Oxygen Demand 196 mg/L 200 < 2 98 80 120 3603561-009FDUP MW-5SDUP Biochemical Oxygen Demand 3 mg/L 1 9 1 100 20 MB -032306 MB -032306 Bromide < 0.5 mg/L LCS-032306 LCS-032306 Bromide 4.9 mg/L 5 < 0.5 98 80 120 0603561-009FMS MW-5SMS Bromide 5.6 mg/L 5 0.8 96 75 125 0603561-009Fdup MW-5SDUP Bromide 0.8 mg/L 0.8 0 20 MB -03-21-06 MB -03-21-06 Chemical Oxygen Demand <10 mg/L LCS-03-21-06 LCS-03-21-06 Chemical Oxygen Demand 993 mg/L 1000 <10 99 80 120 0603561-009CMS MW-5SMS Chemical Oxygen Demand 1020 mg/L 1000 <10 102 75 125 0603561-009CDUP MW-5SDUP Chemical Oxygen Demand <10 mg/L <10 20 MB -032706 MB -032706 Chloride < 2 mg/L LCS-032706 LCS-032706 Chloride 47.8 mg/L 50 < 2 96 80 120 0603561-009FMS MW-5SMS Chloride 51.1 mg/L 25 23.8 109 75 125 0603561-009FDUP MW-5SDUP Chloride 25.1 mg/L 23.8 5.5 20 MB -031706 MB -031706 Chromium, Hexavalent < 0.02 mg/L LCS-031706 LCS-031706 Chromium, Hexavalent 0.18 mg/L 0.2 < 0.02 90 80 120 0603561-009FMS MW-5SMS Chromium, Hexavalent 0.17 mg/L 0.2 < 0.02 125 0603561-009FDUP MW-5SDUP Chromium, Hexavalent < 0.02 E85 E75 m91L < 0.02 20 I TSL005 S120 QC SUMMARY REPORT SDG: TSL005 Spike Sample Recovery RPDRef %RPD Sample ID• Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -031706 MB -031706 Color < 5 units LCS-031706 LCS-031706 Color 40 units 40 < 5 100 80 120 0603561-009FDUP MW-5SDUP Color < 5 units I I I < 5 20 MB -031706 MB -031706 Hardness (As CaCO3) < 5 mg/L LCS-031706 LCS-031706 Hardness (As CaCO3) 1040 mg/L 1000 < 5 104 80 120 0603561-009Dms MW-5SMS Hardness (As CaCO3) 605 mg/L 500 85.0 104 75 125 0603561-009Ddup MW-5SDUP Hardness (As CaCO3) 90.0 mg/L 85.0 5.7 20 MB -032506 MB -032506 Nitrate as N < 0.1 ng/L LCS-032506 LCS-032506 Nitrate as N 1.12 mg/L 1.13 <0.1 99 80 120 0603561-009CMS MW-5SMS Nitrate as N 4.11 mg/L 2.5 1.70 96 75 125 0603561-009CDUP MW-5SDUP Nitrate as N 1.70 mg/L 1.70 0 20 MB3-16478 MB3-032706 Nitrogen, Ammonia (As N) < 0.1 mg/L MB -16488 MB -032806 Nitrogen, IGeldahl, Total < 0.1 M82-16478 MB2-032706 Nitrogen, Ammonia (As N) < 0.1 mg/L mg/L 4.1 < 0.1 112 80 120 LCS-16488 LCS-032806 Nitrogen, Kjeldahl, Total MB1-16478 MBl-032706 Nitrogen, Ammonia (As N) < 0.1 mg/L 10.2 ng/L 4.1 5.77 108 75 125 0603561-009CDUP MW-5SDUP LCS3-16478 LCS3-032706 Nitrogen, Ammonia (As N) 1.04 mg/L 1 < 0.1 104 80 120 LCS2-16478 LCS2-032706 Nitrogen, Ammonia (As N) 1.03 mg/L 1 < 0.1 103 80 120 LCS1-16478 LCSl-032706 Nitrogen, Ammonia (As N) 1.03 mg/L 1 < 0.1 103 80 120 0603561-009CMS MW-5SMS Nitrogen, Ammonia (As N) 11.0 mg/L 5 4.85 123 75 125 0603561-009CDUP MW-5SDUP Nitrogen, Ammonia (As N) 5.36 mg/L 4.85 10 20 MBI -16488 MB1-032806 Nitrogen, Kjeldahl, Total < 0.1 mg/L MB -16488 MB -032806 Nitrogen, IGeldahl, Total < 0.1 mg/L LCS1-16488 LCS1-032806 Nitrogen, Kjeldahl, Total 4.60 mg/L 4.1 < 0.1 112 80 120 LCS-16488 LCS-032806 Nitrogen, Kjeldahl, Total 4.53 mg/L 4.1 < 0.1 110 80 120 0603561-009CMS MW-5SMS Nitrogen, Kjeldahl, Total 10.2 ng/L 4.1 5.77 108 75 125 0603561-009CDUP MW-5SDUP Nitrogen, Kjeldahl, Total- 6.01 m9/L 5.77 4.1 20 TSL005 S121 QC SUMMARY REPORT SDG: TSL005 Spike Sample Recovery RPDRef %RPD Sample IID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -0327066 MB -0327066 Phenolics, Total Recoverable < 5 ug/L LCS-032706 LCS-032706 Phenolics, Total Recoverable 29.1 ug/L 30 < 5 97 80 120 0603561-009CMS MW-5SMS Phenolics, Total Recoverable 19.8 ug/L 20 < 5 99 75 125 0603561-009Cdup MW-5SDUP Phenolics, Total Recoverable < 5 ug/L < 5 20 MB -032806 MB -032806 Sulfate < 5 m9fL LCS-032806 LCS-032806 Sulfate 19.7m9/L 0<5 98 80 1200603561-009FMS ]!50 0603561-009FMS MW-5SMS Sulfate 84.5 m9n 33.8 102 75 125 0603561-009Fdup MW-5SDUP Sulfate 34.2 mg/L. 33.8 1.5 20 MB -03-20-06 MB -03-20-06 Total Dissolved Solids <10 mg/L. LCS-03-20-06 LCS-03-20-06 Total Dissolved Solids 336 mg/L 300 <10 112 80 120 0603561-009FMS MW-5SMS Total Dissolved Solids 490 mg/L. 300 167 108 75 125 0603561-009FDUP MW-5SDUP Total Dissolved Solids 171 m91L 167 MB -032203 MB -032203 Total Organic Carbon < 1 LCS-032203 LCS-032203 Total Organic Carbon 26.4L mg/L 2 < 1 106 80 120 �150 0603561-009BMS MW-5SMS Total Organic Carbon 16.8 mg/L. 6.8 100 75 125 0603561-009BDUP MW-5SDUP Total Organic Carbon 5.9 mg/L 6.8 14.2 20 TSL005 S122 U2M "US, 1 %C. 10. INTERNAL STANDARD AREA DATA 10.1 VOLAMES 8A .:VOLATILE:INTERNAL STANDARD AREA AND RT SUMMARY Lab Name: JbM LAE$, INC. Contract: h' b' Code: :10478 Case No.: PCTSL SAS No.: SDG Ito.: TSL005 Lab File. ID (Standard): A\A45398.D Date Analyzed: 03/23/06 EPA Sample No.(VSTD050##): VSTD050 Time Analyzed: 10:01 Instt"6iit.;.ID: FIP597I Heated Purge: (YIN) N GC Column: 4..502•:2 1D: .53 (mm) .'I$1;;PFB'=;'Pentiafluo'robenzene . IS2" Dv$ =-. , 4 Diflu6r6behi6ne IS3 CBZ = Chlorobenzene-d5 UPPER`LIMIT''= +100$ of internal standard area AREA LOWER -LIMIT = -50% of internal standard area RT UPPER LIMIT = +0.50 minutes of internal standard RT RT LOWER LIMIT = -0.50 minutes of internal standard RT # Column used to flag values outside QC limits with an asterisk. * Values outside of QC limits. Page 1 of._1 FORM VIII VOA OLM04.2 7t N ISl- PFB AREA # RT # '9.35 IS2 DFB AREA #. RT # IS3.. •CBZ AREA # RT # 12 HOUR -,STD 586456 9.33 1028946 10.31 551788 14.14 UPPER LIMIT 1172912 9:83 2057892 10.81 1103576 14.64 LOWER-- LIMIT .293228 8.83 514473 9.81 275894 13.64 EPA SAMPLE VBLK032306 816006 9.34 1034999 10.32 564278 14.14 LF.OM2306 620227 9.34 1064787 10.32 572951 14.15 MM323W .638865 9.35 1059479 10.31 576874 14.15 EQPT 630610 9.34 1059523 10.32 575055 14.15 MW 1b ...: 638271 9.35• 10860:18 10.33 586682 14.15 MW=1S. 64$982 1100158 10.33 590866 14.15 MEND 631089 35 1083471 10.33 579204 14.15 291 34 1090108 10.32 578999 14.15 MW4b . 639154 35 1080396 10.32 582678 14.15 MW4S 634098 35 1087438 10.32 584770 14.15 MW=5U629222 34 1081'801 10.32 577365 14.15 MW45S . 653198 9.34 1111797 10.32 588688 14.15 MIN 5SIUIS .. 644938 9.34 1091270 10.31 580223 14.15 MW -t§0815`: .639677 9.34 1078024 10.31 573033 14.15 9.34 1089440 10.32 579784 • 14.15 M1N s :.-•..::: ; : 643327. . 9.34. :1001970 10.32 581914. 14.14 ►' :'.. - : 6348&t 9.34 1098220 10:31 583096 14:14 641422 9.34 1093396 10.31 581086 14.14 '1' P BLAN)G3/16 634962 9.34 11091964 - 10.32 579971 14.14 .'I$1;;PFB'=;'Pentiafluo'robenzene . IS2" Dv$ =-. , 4 Diflu6r6behi6ne IS3 CBZ = Chlorobenzene-d5 UPPER`LIMIT''= +100$ of internal standard area AREA LOWER -LIMIT = -50% of internal standard area RT UPPER LIMIT = +0.50 minutes of internal standard RT RT LOWER LIMIT = -0.50 minutes of internal standard RT # Column used to flag values outside QC limits with an asterisk. * Values outside of QC limits. Page 1 of._1 FORM VIII VOA OLM04.2 7t N