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Metals Data Package 06/2005
Analytical Data Package For 'SOWN OF S4UTHOLa SRT 360 ROUTINE ,S,DG NO: `TSL002 ..y Water Samples Received: 6/10105 .'.PMTALS DATAPACKAGE I= P.4 U2M LABS, INC. ANALYTICAL DATA PACKAGE TABLE OF CONTENTS TOWN OF SOUTHOLD PART 360 ROUTINE WATER SAMPLES SAMPLES RECEIVED: 6/10/05 SDG NO.: TSL002 • I. NYS DEC SUMMARY FORMS il. SDG NARRATIVES III. CHAIN OF CUSTODY DOCUMENTATION IV. ANALYTICAL DATA PACKAGE A. METALS B. WET CHEMISTRY DATA PACKAGE FOR CLIENT INFORMATION PURPOSES ONLY N O H U2M !LABS, INC. • NYS DEC SUMMARY FORMS • • NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE IDENTIFICATION AND • ANALYTICAL REQUIREMENT SUMMARY SDG: TSL002 Anal ical Requirements • • CLP, E TCUT, Please indicate year of protocol) ASP 6 10/C15 K55 Priority Pollutant, bpnjor? Customer Sample Code Laboratory Sample Code ME we MW -1D 0506329-001 X X MW -1S 0506329-002 X X MW -31) 0506329-003 X X MW -3S 0506329-004 X X MW -4D 0506329-005 X X MW -5D 0506329-006 X X MW -5S 0506329-007 X X MW -6D 0506329-008 X X Mw -6S 0506329-009 X X MW -8D 0506329-010 X X MW -8s 0506329-011 X X EQPT BLANK 0506329-012 X X • • CLP, E TCUT, Please indicate year of protocol) ASP 6 10/C15 K55 Priority Pollutant, bpnjor? •NEW YORK STATE DEPARTMENT OF ENANMENTAL CONSERVATION • SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG. TSI -002 INORGANIC ANALYSIS Laboratory Samp ID Client Sample ID Matrix Metals Requested DateRecd at Lab Date Analyzed 0506329-001 MWAD WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-002 MWAS WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-002DUP MWASD WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-002MS MW -ISS WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-003 MW -3D WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-004 MW -3S WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-005 MW -4D WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-006 MW -5D WATER CA,CD,FE,K,MG,MN,NA PB, 10 -Jun -05 06/05 0506329-007 MW -5S WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-008 MW -6D WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-009 MW -6S WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-010 MW -8D WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-011 MW -8S WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-012 EQPT BLANK WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 TSL002 A4 NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION • SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG: TSI -002 INORGANIC ANALYSIS Laboratory Samp ID Client Sample71D Matrix Tests DateRecd at Lab Date I Analyze 0506329-001 MW -ID Groundwater SELECT WET CHEMISTRY" 06/10/05 06/05 0506329-002 MW -IS Groundwater SELECT WET CHEMISTRY *' 06/10/05 06/05 0506329-002DUP MW-1SDUP Groundwater SELECT WET CHEMISTRY *' 06/10/05 06/05 0506329-002MS MW -ISMS Groundwater SELECT WET CHEMISTRY *' 06/10/05 06/05 0506329-003 MW -313 Groundwater SELECT WET CHEMISTRY" 06/10/05 06/05 0506329-004 MW -3S Groundwater SELECT WET CHEMISTRY'* 06/10/05 06/05 0506329-005 MW -413 Groundwater SELECT WET CHEMISTRY ** 06/10/05 06/05 0506329-006 MW -5D Groundwater SELECT WET CHEMISTRY " 06/10/05 06/05 0506329-007 MW -5S Groundwater SELECT WET CHEMISTRY" 06/10/05 06/05 0506329-008 MW -613 Groundwater SELECT WET CHEMISTRY *` 06/10/05 06/05 0506329-009 MW -6S Groundwater SELECT WET CHEMISTRY *' 06/10/05 06/05 0506329-010 MW -813 Groundwater SELECT WET CHEMISTRY" 06/10/05 06/05 0506329-011 MW -8S Groundwater SELECT WET CHEMISTRY" 06/10/05 06/05 0506329-012 EQPT BLANK Groundwater SELECT WET CHEMISTRY ** 06/10/05 06/05 • ** Alkalinity, Total (As CaCO3) ; Alkalinity, Total (As CaCO3), High; Biochemical Oxygen Demand ; Bromide ; Chemical Oxygen Demand ; Chloride ; Hardness (As CaCO3) ; Nitrate as N ; Nitrogen, Ammonia (As N) ; Nitrogen, Kjeldahl, Total; Phenolics, Total Recoverable; Sulfate; Total Dissolved Solids ; Total Organic Carbon ; • U2M HAUS, INC. 0 II. SDG NARRATIVES • • U2M ILAUS, INC. NARRATIVE FOR METALS ANALYSES SAMPLE RECEIVED: 6/10/05 SDG#: TSL002 For Samples: EQPT BLANK MW -1D MW -1S MS/MSD MW -3D MW -3S MW -4D MW -5D MW -5S MW -6D MW -6S MW -8D MW -8S Twelve water samples were received by H2M Labs inc. on 6/10/05 for select metals analysis. •Samples were prepared and analyzed using EPA method 6010B with a TJA61 E Trace ICP instrument. Sample MW -1 S was utilized for QC analysis and reporting. No problems were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: June 20, 2005 ** ******************* Vincent Stancampiano Vice President o:\gc\narr2005\tsl\metals\ts1002. doc • U2M LABS, INC. SDG NARRATIVE FOR WET CHEMISTRY 0 SAMPLES RECEIVED: 6/10/05 For Samples: SDG NO.: TSL002 EQPT BLANK MW -5D MW -1D MS/MSD MW -5S MW -1S MW -6D MW -3D MW -6S MW -3S MW -8D MW -4D MW -8S Samples were prepared and analyzed using the following methods: PARAMETER METHOD # Alkalinity EPA 310.1 BOD EPA 405.1 Bromide EPA 320.1 Chloride EPA325.2 COD EPA 410.4 Hardness EPA 130.2 Ammonia EPA 350.1 Nitrate EPA 353.2 Phenols EPA420.1 Sulfate EPA 9038 TDS EPA 160.1 TKN EPA 351.2 • TOC EPA 9060 Sample MW -1D was utilized for duplicate and spike QC analysis and reporting. Several ammonia values exceeded the TKN concentration. All differences were within 20%RPD or ± the CRDL except for the following: Sample _Ammonia mg/L TKN mg/L RPD MW -5S 4.70 3.74 22.7% MW -81) 3.86 3.12 21.2% Samples were diluted and reanalyzed as required to keep instrument readings within calibration ranges. No other problems were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: April 21, 2005 Vincent Stancampiano 4C - VVice President U24 ILAUS, INC. 0 III. CHAIN OF CUSTODY DOCUMENTATION • • U2A81 I AUS, INC. 575 Broad Hollow Rd, Melville, NY 11747-5076 14 5 8 0 EXTERNAL CHAIN OF CUSTODY 0 Tel: (516) 694-3040 Fax: (516) 420-8436 CLIENT: P C'7 -S L I 1-12M SDG NO: JJ,.) PROJECT NAME/NUMBER Sv H TO -570/ 7VW N OF S0077401-6 �NbF1 � L o 0 '- m� (� O � �" r � y (16 'o ,' NOTES: Project Contact: N3 7-/<N pi- 5 GWAI Yfr Phone Number: �O3 i P Is X423/4/0/ 162 (F) 80D S 7D S so L � / �' � `✓ KJ G 1' a� SAMPLERS: (signature)/Client i7'OW DELIVERABLES: 65-70 o c Z :' c v H 1 ANALYSIS REQ U TED TURNAROUND TIME: C9 DA S ORGANIC �' IND G, DATE TIME MATRIX FIELD I.D. m a ` U LAB I.D. NO. REMARKS: s a (0 3 3 w /h s S 0200 1 422 W- /,0 3 1 1 1 00 1 93o In ry- 3-5 /000 �v - 3 8 3( I I , j Io►� P i3L�N 8 3 ►� L �V Relinquished by: (Signature) Date (► Iv Timeby: 1 Sa�°:,_.� (S nature) D to j Timre� LABORATORY USE ONLY Discrepancies Between Sample Labels and COC Record? Y or N Explain: Samples were: 1. Shipped_ or Hand Delivered_ Airbill# 2. Ambient or chilled 3. Received in good condition: Y or N 4. Properly preserved: Y or N 5. Samples returned to lab , Hrs from collection. COC Tape was: 1. Present on outer package: Y or N 2. Unbroken on outer package: Y or N 3. COC record present 6 complete upon sample receipt: Y or N Relinquishby: (Signature) Date Time Rece'vvd by: (Signature) Date Time Relinquished by: (Signature) Date Time F:eceived by: (Signature) Date Time Relinquished by: (Signature) Date Time Received by: (Signature) Date Time TUPff� 6dA - ORIGINAL YELLOW COPY - CLIENT PINK COPY - LABORATORY U24L LAPS, IING -` 544 EXTERNAL CHAIN OF CUSTODY0 575 Broad Hollow Rd, Melville, NY 11747-5076 Tel: (516) 694-3040 Fax: (516) 420-8436 CLIENT: P %S L_ 1-12M SDG NO: PROJECT NAME/NUMBER s�y�osa/ NOTES: Project Contact: %G G�/N OF S Ov OL %L_ `� o N� Tk.N ass �wD V67 - Q 3 )_AIM c o 'M l / Phone Number: E 3 � v. .3 1 �l^8 hofs. x/623.1610 / co O 6R SAMPLERS: (signature)/Client lin 1 i 8 0'OSI 7Dsj .5`CY1 C L DELIVERABLES: 12 8 S _ _ 7 c 2 =° a V H ANALYSIS REQUESTED TURNAROUND TIME: a / / Oi �j ORGANIC INORG. DATE TIME MATRIXFIELD I.D. j►T 0 ` d V D f° g z U LAB I.D. NO. REMARKS: 6/1/05 /05-0 INVJ M c �- 3S -2 3 r l I I /200 /)q w — 1230 W -- S `J 1330 1 MW -- l4� 30 M wTiy \J/ I �S Relinquished by: (Signature) ( ,� Date Time Received by: (Signature) Date Time LABORATORY USE ONLY Discrepancies Between Sample Labels and COC Record? Y or N Samples were: 1. Shipped_ or Hand Delivered_ Airbill# 2. Ambient or chilled Relinquished by: (Signature) _ ate Ti teed by: Signature) {D� to N�131 Time 1 JS 3. Received in good condition: Y or N Explain: 4. Properly preserved: Y or N 5. Samples returned to lab _ Hrs from collection. Relinquis ignature) Date Time Received by: (Signature) Date Time COC Tape was: 1. Present on outer package: Y or N 2. Unbroken on outer package: Y or N Relinquished by: (Signature) Date Time Received by: (Signature) Date Time 3. COC record present 3 complete upon sample receipt: YorN , � LIMY - ORIGINAL YELLOW COPY - CLIENT PINK rnPY - I ARnR,&TnAv TVe H2M LABS, INC. • Client Name PCTSL Work Order Numbe 0506329 Sample Receipt Checklist Date and Time Receive Received by LSD 6/10/2005 1:50:00 PM Checklist completed b Reviewed by('�-r Signature Date tnilials Date Matrix Carrier name Hand Delivered Shipping container/cooler in good condition? Yes No ❑ Custody seals intact on shippping container/cooler? Yes ❑ Custody seals intact on sample bottles? Yes ❑ Chain of custody present? Yes Chain of custody signed when relinquished and received? Yes 0 Chain of custody agrees with sample labels? Yes Samples in proper container/bottle? Yes W Sample containers intact? Yes ❑ No ❑ Sufficient sample volume for indicated test? Yes Checked b samples received within holding time? Yes RJ tainer/Temp Blank temperature in compliance? Yes OV Water - VOA vials have zero headspace? No VOA vials submitted Water - pH acceptable upon receipt? Yes 0 Adjusted? No ❑ Not Applicable ❑ No ❑ Not Applicable No ❑ Not Applicable RJ No ❑ No ❑ No ❑ No ❑ No ❑ No ❑ No ❑ No ❑ Yes ❑ No ❑ No ❑ Checked b Any No and/or NA (not applicable) response must be detailed in the comments section b — — — — — — — — — — — — — — — — — — — — — — — — — — — - Client contacted Date contacted: Contacted by: _ _ _ _ Regarding Comments: Corrective Action Person contacted �M AADS, Isc• CHAIN OF CUSTODY INTERNAL p�l CLIENT: L DELIVERABLES: TURN AROUND TIME= - SDG N:.�z� CASE #:--- MATRIX: pH CHECI& N Lv) -UGNATME: DATE: TD�E:� 110 METALS P 0049 M N O O E� NSA «►Us, INC• am": INTERNAL CHAIN OF CUSTODY I0 METALS �f 1 V2M tA", INC. CLIENT:��� SDG #: J Sid REMARKS: INTERNAL CHAIN OF CUSTODY DELIVERABLES: �� �I� - TURN AROUND TIME: (� ` CASE Ie: MATRIX: pH CHECC s N ,C6 - RECEIVED BY: ISD SIGNATURE: DAX'o I �i WET CHEMISTRY -Vv l' 009JL N O H man �i WET CHEMISTRY -Vv l' 009JL N O H t12A UA", INC. : ��►�� SDG #: i SuUZ INTERNAL CHAIN OF CUSTODY WET CHEMISTRY P 0092 N O cn E-4 U24 ILAI3S, INC. 0 IV. ANALYTICAL DATA PACKAGE A. METALS B. WET CHEMISTRY • • U24 "US, INC. Tama • MEJALS TABLE OF CONTENTS I. REPORTS 11. QC SUMMARY III. RAW DATA IV. DOCUMENTATION • • N 0 h • U.S. EPA - CLP COVER PAGE - INORGANIC ANALYSES DATA PACKAGE Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 SOW No.: ILM04.1 EPA Sample No. EQPT BLANK MW -1D MW -1S MW-lSD MW-1SS MW -3D MW -3S MW -4D MW -5D MW -5S MW -6D MW -6S MW -8D MW -8S Were ICP interelement corrections applied? Were ICP backqround corrections applied? If yes -were raw data generated before application of background corrections? Comments: DATE REPORTED NNE 15, 2005 Lab Sample ID. 0506329-012 0506329-002DUP 0506329-002MS 0506329-005 0506329-008 0506329-009 0506329-010 0506329-011 Yes/No YES Yes/No YES Yes/No NO I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package and in the uter-readable data submitted on diskette has been authorized b t e bo tory Manaqer or the Manaqer's desiqnee, as verified by the follow'n gn ure signature: Name: Vincent Stancampiano Date: (A ffl'� Title: Vice President IaCOVER PAGE - IN ILM04.1 U2M "US, INC. 0 I. REPORTS FOR METALS • • U2M "US, INCe J QUALIFIERS FOR METALS ANALYSIS Q (Quality Control) Qualifiers E - The reported value is estimated because of the presence of interference. An explanatory note is included in the SDG narrative. M - Duplicate injection precision not met. N - Matrix spike sample recovery not within control limits. S- The reported value was determined by the Method of Standard Additions (MSA). + - Correlation coefficient for the MSA is less than 0.995 W - Post digestion spike for Furnace AA analysis is out of control limits (85- 115%), while sample absorbance is less than 50% of spike absorbance. • * - Duplicate analysis is not within control limits. C (Concentration) Qualifiers B - Entered if the reported value is less than the Contract Required Detection Limit (CRDL) but greater than the Instrument Detection Limit (IDL). U - Entered if the analyte was analyzed for but not detected, i.e., less than the IDL. M (Method) Qualifiers P - Analyzed by ICP. M - Analyzed by ICP -MS A - Analyzed by Flame AA. F - Analyzed by Furnace AA. CV - Analyzed by Manual Cold Vapor techniques. AV - Analyzed by Automated Cold Vapor techniques. C - Analyzed by Manual Spectrophotometric Method. CA- Analyzed by Midi -distillation Spectrophotometric Method. NR - Analyte not Required. • U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET F - 1D Lab Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Matrix (soil/water): WATER Lab Sample ID: 0506329-001 Level (low/med)• LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.75 B P 7440-70-2 Calcium 12400 P 7439-89-6 Iron 169 P 7439-92-1 Lead 1.7 U P 7439-95-4 Magnesium 7240 P 7439-96-5 Manganese 13.0 B P 7440-09-7 Potassium 2170 B P 7440-23-5 Sodium 44300 P • Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: CLEAR Comments: DATE REPORTED NNE 15, 2005 • Texture: Artifacts: FORM I - IN ILM04.1 N O N U.S. EPA - CLP • 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.65 U P 7440-70-2 Calcium 12000 P 7439-89-6 Iron 555 P 7439-92-1 Lead 1.7 U P 7439-95-4 Magnesium 7000 P 7439-96-5 Manganese 17.9 P 7440-09-7 Potassium 2050 B P 7440-23-5 Sodium 43100 P Color Before: COLORLESS Clarity Before: CLEAR . Color After: COLORLESS Clarity After: CLEAR Comments: DATE REPORTED JUNE 15, 2005 • EPA SAMPLE NO MW -1S SDG No.: TSL002 0506329-002 6/10/2005 Texture: Artifacts: FORM I - IN ILM04.1 N O Cn U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -3D Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Matrix (soil/water): WATER Lab Sample ID: 0506329-003 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.65 U P 7440-70-2 Calcium 21300 P 7439-89-6 Iron 26.6 B P 7439-92-1 Lead 2.2 B P 7439-95-4 Magnesium 3900 B P 7439-96-5 Manganese 1500 P 7440-09-7 Potassium 11300 P 7440-23-5 Sodium 5220 P •Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: CLEAR Comments: nATF. RRPnRTED JUNE 15. 2005 • Texture: Artifacts: FORM I - IN ILM04.1 U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -3S Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Matrix (soil/water): WATER Lab Sample ID: 0506329-004 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.65U P 7440-70-2 Calcium 20000 P 7439-89-6 Iron 31.8 B P 7439-92-1 Lead 1.7 U P 7439-95-4 Magnesium 3650 B P 7439-96-5 Manganese 1410 P 7440-09-7 Potassium 10400 P 7440-23-5 Sodium 5150 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: • Comments: DATE REPORTED JUNE 15, 2005 FORM I - IN ILM04.1 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -4D Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Matrix (soil/water): WATER Lab Sample ID: 0506329-005 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.65 U P 7440-70-2 Calcium 10200 P 7439-89-6 Iron 207 P 7439-92-1 Lead 1.7 U P 7439-95-4 Magnesium 7330 P 7439-96-5 Manganese 652 P 7440-09-7 Potassium 9670 P 7440-23-5 Sodium 17900 P •Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: CLEAR Comments: DATE REPORTED JUNE 15, 2005 • Texture: Artifacts: FORM I - IN ILM04.1 U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -5D Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Matrix (soil/water): WATER Lab Sample ID: 0506329-006 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.65 U P 7440-70-2 Calcium 10500 P 7439-89-6 Iron 77.6 B P 7439-92-1 Lead 1.7 U P 7439-95-4 Magnesium 6850 P 7439-96-5 Manganese 686 P 7440-09-7 Potassium 10500 P 7440-23-5 Sodium 15400 P Color Before: COLORLESS Clarity Before: • Color After: COLORLESS Clarity After: Comments: DATE REPORTED JUNE 15, 2005 • CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 El U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -5S Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Matrix (soil/water): WATER Lab Sample ID: 0506329-007 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.65 U P 7440-70-2 Calcium 10400 P 7439-89-6 Iron 89.9 B P- 7439-92-1 Lead 1.7 U P 7439-95-4 Magnesium 6810 P 7439-96-5 Manganese 677 P 7440-09-7 Potassium 10600 P 7440-23-5 Sodium 15900 P Color Before: COLORLESS Clarity Before: CLEAR • Color After: COLORLESS Clarity After: CLEAR Comments: DATE REPORTED JUNE 15, 2005 • Texture: Artifacts: FORM I - IN ILM04.1 N C) U.S. EPA - CLP • 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.65 U P 7440-70-2 Calcium 10700 P 7439-89-6 Iron 325 P 7439-92-1 Lead 1.7 U P 7439-95-4 Magnesium 7400 P 7439-96-5 Manganese 691 P 7440-09-7 Potassium 10100 P 7440-23-5 Sodium 17400 P EPA SAMPLE NO MW -6D SDG No.: TSL002 6/10/2005 •Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED JUNE 15, 2005 • FORM I - IN ILM04.1 • U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. Matrix (soil/water): WATER Level (low/med): LOW % Solids: 0.0 SAS No.: Lab Sample ID: Date Received: Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.65 U P 7440-70-2 Calcium 9860 P 7439-89-6 Iron 352 P 7439-92-1 Lead 2.0 B P 7439-95-4 Magnesium 7000 P 7439-96-5 Manganese 650 P 7440-09-7 Potassium 9440 P 7440-23-5 Sodium 17100 P Color Before: COLORLESS Clarity Before: CLEAR • Color After: COLORLESS Clarity After: CLEAR Comments: DATE REPORTED JUNE 15, 2005 • EPA SAMPLE NO MW -6S SDG No.: TSL002 6/10/2005 Texture: Artifacts: FORM I - IN ILM04.1 U.S. EPA - CLP • Analyte Concentration C Q M 7440-43-9 Cadmium 1 EPA SAMPLE NO 7440-70-2 INORGANIC ANALYSIS DATA SHEET P 7439-89-6 Iron 235 P 7439-92-1 MW -8D Lab Name: H2M LABS, INC. Contract: Magnesium 7150 P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Matrix (soil/water): WATER Lab Sample ID: 0506329-010 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.65 U P 7440-70-2 Calcium 10500 P 7439-89-6 Iron 235 P 7439-92-1 Lead 1.7 U P 7439-95-4 Magnesium 7150 P 7439-96-5 Manganese 661 P 7440-09-7 Potassium 9820 P 7440-23-5 Sodium 16400 P •Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED JUNE 15, 2005 • FORM I - IN ILM04.1 U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -8S Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Matrix (soil/water): WATER Lab Sample ID: 0506329-011 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.65 U P 7440-70-2 Calcium 9240 P 7439-89-6 Iron 320 P 7439-92-1 Lead 2.0 B P 7439-95-4 Magnesium 6600 P 7439-96-5 Manganese 596 P 7440-09-7 Potassium 8860 P 7440-23-5 Sodium 16700 P •Color Before: COLORLESS Clarity Before: Color After: COLORLESS Clarity After: Comments: DATE. REPORTED JUNE 15. 2005 0 CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 U.S. EPA - CLP 0 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET EQPT BLANK Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Matrix (soil/water): WATER Lab Sample ID: 0506329-012 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.65 U P 7440-70-2 Calcium 39.6 B P 7439-89-6 Iron 3.6 U P 7439-92-1 Lead 1.7 U P 7439-95-4 Magnesium 6.9 U P 7439-96-5 Manganese 1.2 U P 7440-09-7 Potassium 39.61 U I P 7440-23-5 Sodium 1591 B P •Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: CLEAR Comments: DATE REPORTED JUNE 15, 2005 Texture: Artifacts: FORM I - IN ILM04.1 9 • U2M !LABS, 1 N C. II. QC SUMMARY FOR METALS A. INITIAL AND CONTINUING CALIBRATION VERIFICATION B. CRDL STANDARD FOR AA AND ICP C. METHOD BLANK D. ICP INTERFERENCE CHECK SAMPLE E. SPIKE SAMPLE RECOVERY F. POST DIGEST SPIKE SAMPLE RECOVERY G. DUPLICATES H. LABORATORY CONTROL SAMPLE I. STANDARD ADDITION RESULTS J. ICP SERIAL DILUTIONS K. INSTRUMENT DETECTION LIMITS L. ICP INTERELEMENT CORRECTION FACTORS M. ICP LINEAR RANGES N. PREPARATION LOGS O. ANALYSIS RUN LOGS U.S. EPA - CLP 2A INITIAL AND CONTINUING CALIBRATION VERIFICATION Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Initial Calibration Verification Source: MV Labs/High Purity Continuing Calibration Verification Source: MV Labs/High Purity Concentration Units: ug/L Analyte Initial Calibration True Found %R(1) True Continuing Calibration Found %R(1) Found %R(1) M Cadmium 2500.0 2482.98 99.3 2500.0 2508.63 100.3 2538.54 101.5 P Calcium 50000.0 49823.96 99.6 50000.0 51108.43 102.2 52344.78 104.7 P Iron 50000.0 50977.31 102.0 50000.0 50852.30 101.7 50752.75 101.5 P Lead 500.0 475.17 95.0 500.0 495.41 99.1 511.64 102.3 P Magnesium 50000.0 48856.18 97.7 50000.0 49391.62 98.8 49602.76 99.2 P Manganese 2500.0 2525.36 101.0 2500.0 2556.20 102.2 2568.79 102.8 P Potassium 180000.0 81511.69 1101.9 80000.0 81819.79 102.3 81573.39 1 102.0 P Sodium 180000.0 76592.69 1 95.7 80000.0 77011.34 96.3 76253.30 95.3 P • (1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115 40 FORM II (Part 1) - IN ILM04.1 00 N O V) F-+ U.S. EPA - CLP • 2A INITIAL AND CONTINUING CALIBRATION VERIFICATION Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Initial Calibration Verification Source: MV Labs/High Purity Continuing Calibration Verification Source: MV Labs/High Purity Concentration Units: ug/L Analyte Initial Calibration True Found %R(1) True Continuing Calibration Found %R(1) Found %R(1) M Cadmium 2500.0 1 2532.79 101.3 2531.44 101.3 P Calcium 50000.0 52114.00 104.2 52470.32 104.9 P Iron 50000.0 50712.95 101.4 50575.24 101.2 P Lead 500.0 502.18 100.4 504.79 101.0 P Magnesium 50000.0 49828.12 99.7 50026.55 100.1 P Manganese 2500.0 2550.37 102.0 2552.89 102.1 P Potassium 80000.0 82453.27 103.1 82186.16 102.7 P Sodium 80000.0 77102.98 96.4 77245.23 96.6 P • (1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115 • FORM II (Part 1) - IN ILM04.1 C1� N O O L/1 H U.S. EPA - CLP • 2B CRDL STANDARD FOR AA AND ICP Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: AA CRDL Standard Source: ICP CRDL Standard Source: MV Labs/High Purity Concentration Units: ug/L SDG No.: TSL002 Analyte CRDL Standard for AA CRDL Standard Initial True Found %R True Found %R for ICP Final Found %R Cadmium 10.0 10.08 100.8 10.55 105.5 Lead 6.0 6.77 112.8 8.16 136.0 Manganese 30.0 29.88 99.6 30.02 100.1 1 +- 0 FORM II (Part 2) - IN ILM04.1 • C U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg) UG/L SDG No.: TSL002 Analyte Initial Calib. Blank (ug/L) C Continuing Blank 1 C Calibration (ug/L) 2 C 3 C Prepa- ration Blank C M Cadmium 0.7 U 0.7 U 0.9 B 0.7 U 0.655 U P Calcium 29.3 U 29.9 B 29.3 U 29.3 U 29.300 U P Iron 10.8 B 19.3 B 15.3 B 14.4 B 5.820 B P Lead 1.7 U 1.7 U 1.7 U 1.7 U 1.743 U P Magnesium 6.9 U 25.9 B 10.5 B 6.9 U 6.922 U P Manganese 1.2 U 1.2 U 1.2 U 1.2 U 1.239 U P Potassium 58.6 B 50.5 B 54.51 B 1 39.6 U 40.900B P Sodium 44.3 B 26.6 B 38.21B 137.0 B 23.600111 P • FORM III - IN ILM04.1 U.S. EPA - CLP • 3 BLANKS • Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L SDG No.: TSL002 Analyte Initial Calib. Blank (ug/L) C Continuing Calibration Blank (ug/L) 1 C 2 C 3 Prepa- ration C Blank C M Cadmium 0.7 B P Calcium 29.8 B P Iron 21.6 B P Lead 1.7 U P Magnesium 28.0 B P Manganese 1.2 U P Potassium 54.9 B P Sodium 36.1 B P 0 FORM III - IN ILM04.1 U.S. EPA - CLP 4 ICP INTERFERENCE CHECK SAMPLE Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 ICP ID Number: TJA61EDV ICS Source: MV Labs/High Purity Concentration Units: ug/L Analyte True Sol. Sol. A AB Initial Found Sol. Sol. A AB %R Final Found Sol. Sol. A AB %R Aluminum 500000 1 500000 524962 525962.2 105.2 536844 536009.41 107.2 Cadmium 1000 968.3 96.8 978.8 97.9 Calcium 500000 500000 522156 496744.7 99.3 534245 524970.8 105.0 Iron 200000 200000 205299 201092.9 100.5 200434 197560.5 98.8 Lead 1000 963.0 96.3 1033.1 103.3 Magnesium 500000 500000 531003 519462.3 103.91 535114 528446.4 105.7 Manganese 500 529.7 104.9 527.4 105.5 FORM IV - IN ILM04.1 F"4 • • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER % Solids for Sample: 0.0 U.S. EPA - CLP 5A SPIKE SAMPLE RECOVERY Contract: SAS No.: EPA SAMPLE NO MW-1SS SDG No.: TSL002 Level (low/med): LOW Concentration Units (ug/L or mg/kg dry weight): UG/L Analyte Control Limit %R Spiked Sample Result (SSR) C Sample Result (SR) C Spike Added (SA) %R Q M Cadmium 75-125 49.8400 0.6548 U 50.00 99.7 P Iron 75-125 1562.5900 554.9700 1000.00 100.8 P Lead 75-125 21.6253 1.7430 U 20.00 108.1 P Manganese 75-125 529.1200 17.9300 500.00 102.2 P Comments: 0 FORM V (Part 1) - IN ILM04.1 • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER % Solids for Sample: 0.0 U.S. EPA - CLP 6 EPA SAMPLE NO DUPLICATES MW -1S Contract: F SAS No.: SDG No.: TSL002 Level (low/med): LOW % Solids for Duplicate: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L Analyte Control Limit Sample (S) C Duplicate (D) C RPD Q M Cadmium 0.6548 U 0.6548 U P Calcium 5000.0000 12024.2500 12172.7200 1.2 P Iron 554.9700 571.4900 2.9 P Lead 1.7430 U 1.7430 U P Magnesium 5000.0000 7004.8100 7175.2700 2.4 P Manganese 15.0000 17.9300 18.8000 4.7 P Potassium 5000.0000 2052.4000 B 2090.5000 B 1.8 P Sodium 43087.1400 43554.2400 1.1 P • • FORM VI - IN ILM04.1 • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Solid LCS Source: Aqueous LCS Source: U.S. EPA - CLP 7 LABORATORY CONTROL SAMPLE Contract: SAS No.: ERA MV Labs/High Purity SDG No.: TSL002 Analyte Aqueous (ug/L) True Found Solid (mg/kg) %R True Found C Limits %R Cadmium 2500.0 2506.10 100.2 Calcium 50000.0 51198.21 102.4 Iron 50000.0 52172.81 104.3 Lead 500.0 502.66 100.5 Magnesium 50000.0 50094.81 100.2 Manganese 2500.0 2580.91 103.2 ;a Potassium 80000.0 80467.78 100.6 Sodium 80000.0 79694.12 99.6 F I • • FORM VII - IN r L ---j Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. U.S. EPA - CLP 8 STANDARD ADDITION RESULTS Contract: SAS No.: Concentration Units: ug/L SDG No.: TSL002 EPA Sample 0 ADD 1 ADD 2 ADD 3 ADD Final No. An ABS CON ABS CON ABS CON ABS Conc. r Q • FORM VIII - IN ILM04.1 • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER U.S. EPA - CLP 9 ICP SERIAL DILUTIONS Contract: SAS No.: Concentration Units: ug/L MW -1S SDG No.: TSL002 Level (low/med): LOW Analyte Initial Sample Result (I) C Serial Dilution Result (S) C % Differ - ence Q M Cadmium 0.65 U 3.30 U P Calcium 12024.25 12228.25 B 1.7 P Iron 554.97 563.35 1.5 P Lead 1.70 U 8.70 U P Magnesium 7004.81 6976.65 B 0.4 P Manganese 17.93 18.75 Potassium 2052.40 B 2039.65 Sodium 43087.14 47515.05 10.3 P iFORM IX - IN ILM04.1 U.S. EPA - CLP i 10 INSTRUMENT DETECTION LIMITS (SEMI ANNUALLY) i Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. ICP ID Number: TJA61EDV Flame AA ID Number: Furnace AA ID Number: Comments: Contract: SAS No.: Date: 4/4/2005 SDG No.: TSL002 Analyte Wave- length Back- (nm) ground CRDL (ug/L) IDL (ug/L) M Cadmium 226.50 5.0 0.7 P Calcium 317.93 5000.0 29.3 P Iron 271.44 100.0 3.6 P Lead 220.35 3.0 1.7 P Magnesium 279.08 5000.0 6.9 P Manganese 257.61 15.0 1.2 P Potassium 766.49 5000.0 39.6 P Sodium 330.23 5000.0 23.6 P iFORM X - IN ILM04.1 U.S. EPA - CLP • 11A ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY) Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No.: NRAS No.: SDG No.: TSL002 ICP ID Number: TJA61EDV Date: 04/29/2005 r, Analyte Wave- length (nm) Interelement Al Ca Correction Factors for: Fe Mg Co Aluminum 308.22 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Antimony 206.83 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Arsenic 189.04 0.0000000 0.0000000 -0.1180000 0.0000000 0.0000000 Barium 493.41 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Ber llium 313.04 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Boron 249.68 0.0000000 0.0000000 -0.0000500 0.0000000 0.0002000 Cadmium 226.50 0.0000000 0.0000000 0.0000700 0.0000000 0.0000000 Calcium 317.93 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Chromium 267.62 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Cobalt 228.62 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Copper 324.75 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Iron 259.94 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Iron 271.44 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Lead 220.35 -0.0810000 0.0000000 -0.1620000 0.0000000 0.0000000 Lead 220.35 0.1700000 0.0000000 0.2400000 0.0000000 0.0000000 magnesium 279.08 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 manganese 257.61 0.0000000 0.0000000 0.0000250 0.0000000 0.0000000 Molybdenum 202.03 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Nickel 231.60 0.0000000 0.0000000 0.0000410 0.0000000 0.0000000 Potassium 766.49 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Selenium 196.03 0.0000000 0.0000000 -0.3800000 0.0000000 -0.9100000 Selenium 196.03 0.0000000 0.0000000 0.0500000 0.0000000 0.2080000 Silicon 288.16 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Silver 328.07 0.0000000 0.0000000 -0.0100000 0.0000000 0.0000000 Sodium 330.23 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Sodium 589.00 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Strontium 407.77 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Thallium 190.86 0.0000000 0.0000000 -0.4200000 0.0000000 0.8230000 Tin 189.99 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Comments: FORM XI (PART 1) - IN ILM04.1 U.S. EPA - CLP i 11A ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY) Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No.: NRAS No.: SDG No.: TSL002 ICP ID Number: TJA61EDV Date: 04/29/2005 Analyte Wave- length (nm) Al Interelement Ca Correction Fe Factors for: Mg Co Titanium 334.94 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Vanadium 292.40 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Zinc 213.861 0.0000000 0.0000000 0.0001500 0.0000000 0.0000000 C, Comments: • FORM XI (PART 1) - IN ILM04.1 U.S. EPA - CLP • 11B ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY) Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No.: NRAS No.: SDG No.: TSL002 ICP ID Number: TJA61EDV Date: 04/29/2005 L_J • Analyte Wave- length (nm) Cr Interelement Mn Correction Ni Factors for: V Aluminum 308.22 0.0000000 0.0000000 0.0000000 0.0160000 Antimony 206.83 3.7300000 0.0000000 0.0000000 0.2100000 Arsenic 189.04 0.0000000 0.0000000 0.0000000 0.0000000 Barium 493.41 0.0000000 0.0000000 0.0000000 0.0000000 Beryllium 313.04 0.0000000 0.0000000 0.0000000 0.0001200 Boron 249.68 0.0000000 0.0000000 0.0000000 0.0000000 Cadmium 226.50 0.0000000 0.0000000 0.0000410 0.0001000 Calcium 317.93 1 0.0000000 0.0000000 0.0000000 0.0000000 Chromium 267.62 0.0000000 0.0000000 0.0000000 0.0000000 Cobalt 228.62 0.0000000 0.0000000 0.0000000 0.0000000 Copper 324.75 0.0000000 0.0000000 0.0000000 0.0000800 Iron 259.94 0.0000000 0.0000000 0.0000000 0.0000000 Iron 271.441 0.0000000 0.0000000 0.0000000 -1.2500000 Lead 220.35 0.0000000 0.1300000 0.0000000 -0.1380000 Lead 220.35 0.0000000 0.0950000 0.0000000 -0.1960000 Magnesium 279.08 0.0000000 0.0000000 0.0000000 0.0000000 Manganese 257.61 0.0000000 0.0000000 0.0000000 0.0000000 Molybdenum 202.03 0.0000000 0.0000000 0.0000000 0.0000000 Nickel 231.60 0.0000000 0.0000000 0.0000000 0.0000000 Potassium 766.49 0.0000000 0.0000000 0.0000000 0.0000000 Selenium 196.03 0.0000000 0.3040000 0.0000000 0.2200000 Selenium 196.03 0.0000000 0.2860000 0.0000000 0.0838000 Silicon 288.16 0.0000000 0.0000000 0.0000000 0.0000000 Silver 328.07 0.0000000 0.0000000 0.0000000 0.0000000 Sodium 330.23 0.0000000 0.0000000 0.0000000 0.0000000 Sodium 589.00 0.0000000 0.0000000 0.0000000 0.0000000 Strontium 407.77 0.0000000 0.0000000 0.0000000 0.0000000 Thallium 190.86 0.1850000 -0.5780000 0.0000000 0.000000011 Tin 1 189.99 0.0000000 0.0000000 0.0000000 0.0000000 Comments: FORM XI (PART 2) - IN ILM04.1 U.S. EPA - CLP • 11B ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY) Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No.: NRAS No.: SDG No.: TSL002 ICP ID Number: TJA61EDV Date: 04/29/2005 Analyte Wave- length (nm) Cr Interelement Mn Correction Ni Factors for: V Titanium 334.94 0.0000000 0.0000000 0.0000000 0.0000000 Vanadium 292.40 0.0000000 0.0000000 0.0000000 0.0000000 Zinc 213.86 -0.0003800 0.0000000 0.0000000 0.0000000 • Comments: 0 FORM XI (PART 2) - IN ILM04.1 • is U.S. EPA - CLP 12 ICP LINEAR RANGES (SEMI ANNUALLY) Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 ICP ID Number: TJA61EDV Date: 05/12/2005 Comments: Analyte Integ. Time (Sec.) Concentration (ug/L) M Cadmium 15.00 20000 P Calcium 15.00 1000000 P Iron 15.00 250000 P Lead 15.00 50000 P Magnesium 15.00 1000000P Manganese 15.00 20000 P Potassium 15.00 250000P Sodium 15.00 500000 P • FORM XII - IN ILM04.1 • • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Method: P U.S. EPA - CLP 13 PREPARATION LOG Contract: SAS No.: SDG No.: TSL002 EPA Sample No. Preparation Weight Date (gram) Volume (mL) EQPT BLANK 06/11/2005 50 LCSW 06/11/2005 50 MW -1D 06/11/2005 50 Mw -is 06/11/2005 50 MW-1SD 06/11/2005 50 Mw-1ss 06/11/2005 50 MW -3D 06/11/2005 50 MW -3s 06/11/2005 50 MW -4D 06/11/2005 50 MW -5D 06/11/2005 50 MW -5S 06/11/2005 50 MW -6D 06/11/2005 50 MW -6S 06/11/2005 50 MW -8D 06/11/2005 50 Mw -8S 06/11/2005 50 PBW 06/11/2005 50 • FORM XIII - IN ILM04.1 • • • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Instrument ID Number: TJA61EDV Start Date: 06/14/2005 U.S. EPA - CLP 14 ANALYSIS RUN LOG Contract: SAS No.: Method: P End Date: SDG No.: TSL002 06/14/2005 , E PA Sample �� • FORM XIV - IN A ILM04.1 C!1 • • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Instrument ID Number: TJA61EDV Start Date: 06/14/2005 U.S. EPA - CLP 14 ANALYSIS RUN LOG Contract: SAS No.: Method: P End Date: SDG No.: TSL002 06/14/2005 0 FORM XIV - IN ILM04.1 will= Me Mie 0 FORM XIV - IN ILM04.1 U2M LABS, INC. L-� Ill. RAW DATA FOR METALS A. ICP DATA • • CLIENT '�St.�u-'��tMOil'1' DATE 3upc_111,22MS TASK: QWQk RESULT FILE: CgG14O4;,' ANALYST � : SAMPLE NOTES # SAMPLE : NOTES 1 1Cv : : 26:050(-3Z.9ro17x:: FQpT • • 2 27: !Yi e2, - 3 Ga•S : : 28, 1. ; ; ; • • � (�j-O(aCl�S-SAM-C-F(. • 4 : sc-swT : : 29 :OSo(o-Lss l -OCO : - �- 5 : Z cs RBz : : 30: C c.v 20 6 : • ' ' : : � (pH80 SDS-QA•► - �f �- ' 7 ; GLC31 ; : 32: Q5C91 2.g► -061 Ouo Qup_, 8 -N—icir 33: -od a t4,5 �l • 9 :mss 137d(o : l-GSw : 34:••S o••.,��.,,� sr.�_z 10:050(o32q miC : /-A \O : 35: : 11: -OOZE: /mow- S : 36: ac SAC- 12 ; co-z a :m h% w -1 S QU4 ; 37, Ic-sAQsF : -� : : 13: cb2,E ic+ns Mw i s M S : 38: Lc.l y ' /tAw-1S Sp • . • 14 ; 391,�- • ' ZZZ2Z Z- 15; 15; Cb3E', /y1 u1 30 : 40:OSOinCA4-O Qi Zoo--1 a-: • 16: -0046 Mw-SS : 41:M�3-13FfL`t ; Gob_R:-� • 17' - Ni 42' • • 18' ' ; 4,3: : 19' GG Z : : 44:USOin2lo`l-Co2p►: Z : 20' - QO(PO Mw - S : 45: -063 P ' yZ2yZZ ' : 21's - OD'1C: to W r aflis%s 46' 1 22,-OobE:- MeafiJKic 2ao-1 f-cl 77-ZZ29 23' -me" hiw --GS : 48' - l3gZG Z 24: OipE: /`r[W�8 O ; 49 LGS 1-13,VLL : 1:2 1.2 • 25: • z.: M lAM INC. CLIENT TSL 00.11- e" Owllxr 1 DATE 3o"S IV toCC' TASK : OLIC Lp RESULT FILE: CoW qor ANALYSI;fG ^ 8 SAMPLE NOTES a 8 SAMPLE nmw NOTES • • , • 1 Gcg26.1 39, i 15 40' 7 41' 27 , , 42, • 18' 3 SGtSO -243-oo1A; 28. • i • ISS"tXo2-S4 - act N,, • Z-�'? • 29 • , ; • • ' S '05.a(o2,95 -ctZA' Z 30 , ' , • � ' � , . • • 21'----------------- ; , ' 7 'Lc 9 - t3ltLg 22 ' 32' • • , 8 'OSotnogz-opik ' 47; • � 123148' 1 • � Z2 2.Z ' 33' • • ' • , ' 9 • , -COIN � Z •ZZ.'l, ' • • 34 - , 10- oot A •�,.g •2•• Z z ' 35' ; 36' 12: 37 • , . . , 13 38 • , • 14, , • • , • . 39, i 15 40' ' 41' • , , 42, • 18' 43 • 19' 20, 45 • • • 21'----------------- ; 46' , 22: ' 47; 123148' , • • • • • • • • , , 24� : 49; . 25, , • O cV O Ln N utoSampler Report Table: C061405 06/14/05 08:31:31 AM page 1 able Name: C061405 Autosampler Type: TYPE TJA # Sets: 1 ample Positions: 0/96 QC Positions: 12/19 _ ij& Station location is rack -1, pos. -1. _- NA- Sample -- Racks --- 1 1 ICV 1 -NA- Usage 2 #Pos-Left Analyses/Pos ack # Type 1 -NA- Sample 3 _ ---- - -- 1_ -- - Aux. (L) Rack ----------- STD/QC/BLANK 12 10 1 2 Sample (28mm) Samples 4 0 1 3 Sample (28mm) Samples -NA- 0 0 1 4 Sample (28mm) Samples ICSABI 0 1 5 Sample (28mm) Samples 1 6 CCV1 -- Sample Sets --- -NA- Sample 7 1 ;et# Type Prepare? Yp Description 1 Method -------- #Pos Rack# StartPos --------------- 1 Normal No -------------------- g *FromMTD 96 2 --- Preparation Info --- -NA- Sample g 2 Set# UptakeUptake#2 Final --- Dil_Factor -NA- - to Samples Prepared. 10 2 2 0506329-001E Zack #1 -NA- Sample 2 ? RowCol Sample Name Set # #Used Type _ -------------------- 1 1 1 StdNAKHI • -NA- 1 1 Standard Standard 2 1 2 StdFENAL -NA- -NA- -NA- 1 Standard 3 1 3 StdMULTI 0506329-002EMS -NA- 1 Standard 4 1 4 StdFURNC 2 -NA- 1 Standard 5 1 5 StdICSEL -NA- 1 Standard 6 1 6 StdAGPSB -NA- 1 Standard 7 1 7 StdBLANK (8...19 Not Used) Rack #2 Pos Row Col Sample Name Set # ----- #Used Type _ __ 1 _- NA- Sample 1 1 1 ICV 1 -NA- Sample 2 1 2 ICB 1 -NA- Sample 3 1 3 CRII 1 -NA- Sample 4 1 4 ICSAI 1 -NA- Sample 5 1 5 ICSABI 1 -NA- Sample 6 1 6 CCV1 1 -NA- Sample 7 1 7 CCB1 1 -NA- Sample1 8 1 g MB -13796 -NA- Sample g 2 1 LCS-13796 1 -NA- Sample 10 2 2 0506329-001E 1 -NA- Sample 2 3 0506329-002E 1 -NA- Sample • 2 4 0506329-002EDUP 1 -NA- Sample 13 2 5 0506329-002EMS 1 -NA- Sample 14 2 6 0506329-002ESD AutoSampler Report Table: C061405 06/14/05 08:31:31 AM Rack #2 PoRow --0 --- Col --- Sample Name--------- --------- Set # ----- #Used ----- Type ------------ 15 2 7 0506329-003E 1 -NA- Sample 16 2 8 0506329-004E 1 -NA- Sample 17 3 1 0506329-005E 1 -NA- Sample 18 3 2 CCV2 1 -NA- Sample 19 3 3 CC132 1 -NA- Sample 20 3 4 0506329-006E 1 -NA- Sample 21 3 5 0506329-007E 1 -NA- Sample 22 3 6 0506329-008E 1 -NA- Sample 23 3 7 0506329-009E 1 -NA- Sample 24 3 8 0506329-010E 1 -NA- Sample Zack #3 ?os Row Col Sample Name Set # #Used Type --- 1 --- 1 --- 1 -------------------- 0506329-011E ----- 1 ----- -NA- ------------ Sample 2 1 2 0506329-012E 1 -NA- Sample 3 1 3 MB -13797 1 -NA- Sample 4 1 4 LCS-13797 1 -NA- Sample 5 1 5 0506281-001E 1 -NA- Sample 6 1 6 CCV3 1 -NA- Sample 7 1 7 CCB3 1 -NA- Sample 8 1 8 0506281-001EDUP 1 -NA- Sample 9 2 1 0506281-001EMS 1 -NA- Sample 2 2 0506281-001ESD 1 -NA- Sample 10 2 3 CRIF 1 -NA- Sample 12 2 4 ICSAF 1 -NA- Sample 13 2 5 ICSABF 1 -NA- Sample 14 2 6 CCV4 1 -NA- Sample 15 2 7 CCB4 1 -NA- Sample 16 2 8 0506094-001A 1 -NA- Sample 17 3 1 MB -13827 1 -NA- Sample 18 3 2 LCS-13827 1 -NA- Sample 19 3 3 LCS1-13827 1 -NA- Sample 20 3 4 0506264-002A 1 -NA- Sample 21 3 5 0506264-003A 1 -NA- Sample 22 3 6 0506264-004A 1 -NA- Sample 23 3 7 MB -13826 1 -NA- Sample 24 3 8 LCS-13826 1 -NA- Sample .ack #4 los Row Col Sample Name Set # #Used Type -- --- 1 1 --- 1 -------------------- LCS1-13826 ----- 1 ----- -NA- ------------ Sample 2 1 2 CCV5 1 -NA- Sample 3 1 3 CCB5 1 -NA- Sample 4 1 4 0506214-001A 1 -NA- Sample 5 1 5 0506243-001A 1 -NA- Sample 1 6 0506284-001A 1 -NA- Sample 1 7 0506295-002A 1 -NA- Sample 8 1 8 MB -13828 1 -NA- Sample 9 2 1 LCS-13828 1 -NA- Sample page 2 AutoSampler Report Table: C061405 06/14/05 08:31:31 AM page 3 Rack #4 PoRow --0 --- Col --- Sample Name--------- --------- Set # ----- #Used ----- Type ------------ 10 2 2 0506092-001A 1 -NA- Sample 11 2 3 0506092-001ADUP 1 -NA- Sample 12 2 4 0506092-001AMS 1 -NA- Sample 13 2 5 CCV6 1 -NA- Sample 14 2 6 CCB6 1 -NA- Sample 15 2 7 ( empty ) 1 -NA- -NA- 16 2 8 ( empty ) 1 -NA- -NA- 17 3 1 ( empty ) 1 -NA- -NA- 18 3 2 ( empty ) 1 -NA- -NA- 19 3 3 ( empty ) 1 -NA- -NA- 20 3 4 ( empty ) 1 -NA- -NA- 21 3 5 ( empty ) 1 -NA- -NA- 22 3 6 ( empty ) 1 -NA- -NA- 23 3 7 ( empty ) 1 -NA- -NA- 24 3 8 ( empty ) 1 -NA- -NA- Zack #5 ?os Row Col Sample Name Set # #Used Type --- --- 1 1 --- 1 -------------------- ( empty ) ----- 1 ----- -NA- ------------ -NA- 2 1 2 ( empty ) 1 -NA- -NA- 3 1 3 ( empty ) 1 -NA- -NA- 1 4 ( empty ) 1 -NA- -NA- 1 5 ( empty ) 1 -NA- -NA- 1 6 ( empty ) 1 -NA- -NA- 7 1 7 ( empty ) 1 -NA- -NA- 8 1 8 ( empty ) 1 -NA- -NA- 9 2 1 ( empty ) 1 -NA- -NA- 10 2 2 ( empty ) 1 -NA- -NA- 11 2 3 ( empty ) 1 -NA- -NA- 12 2 4 ( empty ) 1 -NA- -NA- 13 2 5 ( empty ) 1 -NA- -NA- 14 2 6 ( empty ) 1 -NA- -NA- 15 2 7 ( empty ) 1 -NA- -NA- 16 2 8 ( empty ) 1 -NA- -NA- 17 3 1 ( empty ) 1 -NA- -NA- 18 3 2 ( empty ) 1 -NA- -NA- 19 3 3 ( empty ) 1 -NA- -NA- 20 3 4 ( empty ) 1 -NA- -NA- 21 3 5 ( empty ) 1 -NA- -NA- 22 3 6 ( empty ) 1 -NA- -NA- 23 3 7 ( empty ) 1 -NA- -NA- 24 3 8 ( empty ) 1 -NA- -NA- 0 Standardization Rpt. 06/14/05 08:54:31 AM page 1 4ethod: DVCLPI Standard: StdBLANK tun Time: 06/14/05 08:45:48 E* Ag Al As1890 B Ba Be Ca Avge -.00141 .0109 -.03999 .0002 -.0002 .0014 .0076 SDev .00205 .0038 .00736 .0029 .0005 .0002 .0004 %RSD 145.51 34.63 18.400 1196. 242.0 17.66 4.703 #1 -.00040 .0143 -.03286 .0022 .0001 .0012 .0076 #2 -.00006 .0117 -.03956 .0016 .0001 .0013 .0079 #3 -.00377 .0068 -.04756 -.0031 -.0008 .0017 .0072 Elem Cd Co Cr Cu Fe Fe K Avge -.0002 .0004 .0004 .0136 -.0008 .0019 .0050 SDev .0012 .0009 .0008 .0023 .0021 .0016 .0261 %RSD 545.0 209.3 188.3 16.82 275.3 83.31 521.1 #1 -.0013 -.0001 .0001 .0117 .0007 .0011 .0216 #2 -.0004 -.0001 -.0002 .0129 .0001 .0008 .0185 #3 .0011 .0014 .0013 .0161 -.0031 .0037 -.0251 Elem Mg Mn Mo Na Na Ni P Avge .0003 .0002 -.0001 -.0027 .0812 .0014 .0016 SDev .0002 .0001 .0007 .0030 .0037 .0015 .0010 %RSD 77.43 95.20 570.0 112.6 4.572 107.1 63.74 #1 .0002 .0000 -.0008 -.0006 .0794 .0005 .0006 0002 .0002 -.0002 -.0013 .0787 .0006 .0015 .0006 .0003 .0006 -.0061 .0855 .0032 .0027 Elem 2203/1 2203/2 Sb2068 1960/1 1960/2 Sn T11908 Avge -.04544 .01593 .00677 -.00725 .01036 -.0050 -.00388 SDev .06159 .03249 .00441 .00877 .00828 .0050 .00379 %RSD 135.56 203.99 65.119 121.01 79.921 99.57 97.677 #1 -.01321 .00132 .00259 -.00138 .00385 -.0029 -.00161 #2 -.00664 -.00670 .00635 -.00303 .00756 -.0014 -.00177 #3 -.11646 .05316 .01137 -.01733 .01968 -.0107 -.00825 Elem V Zn Avge .0005 .0002 SDev .0006 .0001 %RSD 115.5 67.94 #1 .0004 .0001 #2 .0000 .0002 #3 .0012 .0003 cV O O H Standardization Rpt. Method: DVCLPI Standard: StdAGPSB Run Time: 06/14/05 08:54:38 0 Ag P Sb2068 Avge 1.6070 1.329 2.6479 SDev .0041 .006 .0327 %RSD .25667 .4323 1.2355 #1 1.6022 1.325 2.6152 #2 1.6098 1.326 2.6478 #3 1.6089 1.335 2.6806 • • 06/14/05 09:00:13 AM page 1 Standardization Rpt. 06/14/05 09:05:08 AM page 1 Method: DVCLPI Standard: StdICSEL Run Time: 06/14/05 09:00:21 sk Al Ca Fe Mg Avge 16.56 18.41 4.490 3.615 SDev .03 .04 .011 .006 %RSD .1988 .2338 .2541 .1704 #1 16.60 18.46 4.501 3.621 #2 16.54 18.38 4.489 3.615 #3 16.55 18.39 4.479 3.609 • • N O V) H Standardization Rpt. 06/14/05 09:10:51 AM Method: DVCLPI Standard: StdFURNC Run Time: 06/14/05 09:05:16 4 As1890 2203/1 2203/2 1960/1 1960/2 T11908 Avge 2.5855 2.4476 2.1229 .41439 .93499 .67641 SDev .0017 .0137 .0055 .00220 .00393 .00159 %RSD .06538 .55868 .26079 .53032 .41995 .23444 #1 2.5873 2.4601 2.1165 .41692 .93081 .67628 #2 2.5839 2.4330 2.1259 .41299 .93860 .67489 #3 2.5853 2.4496 2.1263 .41326 .93557 .67805 • page 1 r - CIA O H Standardization Rpt. 06/14/05 09:17:20 AM page 1 Method: DVCLPI Standard: StdMULTI Run Time: 06/14/05 09:10:58 Eq B Ba Be Cd Co Cr Cu Avge 5.699 8.283 18.57 24.08 3.319 3.319 5.691 SDev .010 .007 .02 .03 .022 .002 .008 %RSD .1824 .0837 .1242 .1272 .6633 .0573 .1469 #1 5.696 8.279. 18.54 24.10 3.316 3.322 5.685 #2 5.691 8.291 18.59 24.10 3.342 3.318 5.687 #3 5.711 8.278 18.58 24.04 3.298 3.318 5.700 Elem Mn Mo Ni Sn V Zn Avge 3.056 4.892 7.085 5.856 2.511 .8424 SDev .002 .012 .020 .008 .001 .0018 %RSD .0507 .2506 .2843 .1445 .0546 .2151 #1 3.058 4.878 7.094 5.862 2.512 .8441 #2 3.056 4.899 7.062 5.860 2.511 .8424 #3 3.055 4.898 7.099 5.846 2.509 .8405 • Standardization Rpt. Method: DVCLPI Standard: StdFENAL Run Time: 06/14/05 09:17:27 a Fe Na Avge 5.012 14.52 SDev .004 .03 %RSD .0824 .2108 #1 5.008 14.55 #2 5.016 14.50 #3 5.011 14.50 • C1 06/14/05 09:21:28 AM page 1 Standardization Rpt. Method: DVCLPI Standard: StdNAKHI Run Time: 06/14/05 09:21:36 0 K Na Avge 63.52 1.147 SDev .21 .001 %RSD .3266 .0777 #1 63.71 1.146 #2 63.55 1.148 43 63.30 1.147 • • 06/14/05 09:24:51 AM page 1 Standardization Report 06/14/05 09:24:51 AM page 1 Method: DVCLPI Slope = Conc(SIR)/IR Epent Wavelen High std Low std Slope Y -intercept Date Standardized A 328.068 StdAGPSB StdBLANK 1243.49 1.75389 06/14/05 09:21:36 Al 308.215 StdICSEL StdBLANK 1.51720 .010374 06/14/05 09:21:36 As1890 189.042 StdFURNC StdBLANK 380.878 15.2327 06/14/05 09:21:36 B 249.678 StdMULTI StdBLANK .877331 -.000211 06/14/05 09:21:36 Ba 493.409 StdMULTI StdBLANK .603661 .000131 06/14/05 09:21:36 Be 313.042 StdMULTI StdBLANK .269325 -.000370 06/14/05 09:21:36 Ca 317.933 StdICSEL StdBLANK 2.02946 -.009530 06/14/05 09:21:36 Cd 226.502 StdMULTI StdBLANK .207647 .000046 06/14/05 09:21:36 Co 228.616 StdMULTI StdBLANK 1.50681 -.000624 06/14/05 09:21:36 Cr 267.716 StdMULTI StdBLANK 1.50650 -.000623 06/14/05 09:21:36 Cu 324.754 StdMULTI StdBLANK .880752 -.011980 06/14/05 09:21:36 Fe 259.940 StdFENAL StdBLANK .998003 -.001864 06/14/05 09:21:36 Fe 271.441 StdICSEL StdBLANK 22.2687 .016792 06/14/05 09:21:36 K 766.491 StdNAKHI StdBLANK 1.44692 .026208 06/14/05 09:21:36 Mg 279.079 StdICSEL StdBLANK 1.25733 -.000233 06/14/05 09:21:36 Mn 257.610 StdMULTI StdBLANK 1.63615 -.000254 06/14/05 09:21:36 Mo 202.030 StdMULTI StdBLANK 1.02210 .000131 06/14/05 09:21:36 Na 330.232 StdNAKHI StdBLANK 1.42049 .003832 06/14/05 09:21:36 Na 588.995 StdFENAL StdBLANK .346331 -.028119 06/14/05 09:21:36 Ni 231.604 StdMULTI StdBLANK .705918 -.001005 06/14/05 09:21:36 P 178.287 StdAGPSB StdBLANK 3.76741 -.005993 06/14/05 09:21:36 2203/1 220.351 StdFURNC StdBLANK 401.121 18.2260 06/14/05 09:21:36 2203/2 220.352 StdFURNC StdBLANK 474.622 -7.55988 06/14/05 09:21:36 Sb2068 206.838 StdAGPSB StdBLANK 757.266 -5.12777 06/14/05 09:21:36 19 /1 196.021 StdFURNC StdBLANK 2371.71 17.1871 06/14/05 09:21:36 1 2 196.022 StdFURNC StdBLANK 1081.52 -11.2083 06/14/05 09:21:36 S 189.989 StdMULTI StdBLANK .853089 .004257 06/14/05 09:21:36 T11908 190.864 StdFURNC StdBLANK 1469.97 5.70075 06/14/05 09:21:36 V 292.402 StdMULTI StdBLANK 1.99192 -.001089 06/14/05 09:21:36 Zn 206.200 StdMULTI StdBLANK 5.93694 -.001037 06/14/05 09:21:36 Pb2203 220.353 NONE NONE 1.00000 .000000 *NOT STANDARDIZED Se1960 196.026 NONE NONE 1.00000 .000000 *NOT STANDARDIZED Standardization Readback Report Method: DVCLPI E nt Wavelength Standard A 328.068 StdBLANK StdAGPSB Element Wavelength Standard Al 308.215 StdBLANK StdICSEL Element Wavelength Standard As1890 189.042 StdBLANK StdFURNC Element Wavelength Standard B 249.678 StdBLANK StdMULTI Element Wavelength Standard Ba 493.409 StdBLANK StdMULTI El ent Wavelength Standard Bf 313.042 StdBLANK StdMULTI Element Wavelength Standard Ca 317.933 StdBLANK StdICSEL Element Wavelength Standard Cd 226.502 StdBLANK StdMULTI Element Wavelength Standard Co 228.616 StdBLANK StdMULTI Element Wavelength Standard Cr 267.716 StdBLANK StdMULTI Element Wavelength Standard Cio 324.754 StdBLANK StdMULTI 06/14/05 09:24:51 AM Known Concentration .000000 2000.00 Known Signal .026972 25.1414 Known Concentration .000000 1000.00 Known Concentration .000000 5.00000 Known Concentration .000000 5.00000 Known Concentration .000000 5.00000 Known Signal .005809 37.3551 Known Concentration .000000 5.00000 Known Concentration .000000 5.00000 Known Concentration .000000 5.00000 Known Concentration .000000 5.00000 Measured Concentration .000000 2000.00 Measured Signal .010940 16.5642 Measured Concentration .000000 1000.00 Measured Concentration -.000000 5.00000 Measured Concentration .000000 5.00000 Measured Concentration -.000000 5.00060 Measured Signal .007558 18.4111 Measured Concentration .000000 5.00000 Measured Concentration -.000000 5.00000 Measured Concentration .000000 5.00000 Measured Concentration -.000000 5.00000 page 1 Residual Concentration -.000000 .000000 Residual Signal .016032 8.57728 Residual Concentration -.000000 .000000 Residual Concentration .000000 .000000 Residual Concentration -.000000 .000000 Residual Concentration .000000 -.000599 Residual Signal -.001749 18.9440 Residual Concentration -.000000 .000000 Residual Concentration .000000 .000000 Residual Concentration -.000000 .000000 N Residual `n Concentration .000000 .000000 p H Standardization Readback Report 06/14/05 09:24:51 AM Element Wavelength Standard Fe • 259.940 StdBLANK StdFENAL Element Wavelength Standard Fe 271.441 StdBLANK StdICSEL Element Wavelength Standard K 766.491 StdBLANK StdNAKHI Element Wavelength Standard Mg 279.079 StdBLANK StdICSEL Element Wavelength Standard Mn 257.610 StdBLANK StdMULTI Element Wavelength Standard Mo 202.030 StdBLANK 0 StdMULTI Element Wavelength Standard Va 330.232 StdBLANK StdNAKHI Element Wavelength Standard Va 588.995 StdBLANK StdFENAL Element Wavelength Standard vi 231.604 StdBLANK StdMULTI Element Wavelength Standard ? 178.287 StdBLANK StdAGPSB Element Wavelength Standard ?203/1 220.351 StdBLANK 0 StdFURNC Known Measured Concentration Concentration .000000 -.000000 5.00000 5.00000 Known Measured Concentration Concentration .000000 .000000 100.000 100.000 Known Measured Signal Signal .033463 .005014 91.9351 63.5202 Known Measured Signal Signal .000159 .000311 4.54544 3.61533 Known Measured Concentration Concentration .000000 .000000 5.00000 5.00000 Known Measured Concentration Concentration .000000 -.000000 5.00000 5.00000 Known Measured Signal Signal .000034 -.002674 1.63314 1.14700 Known Measured Concentration Concentration .000000 .000000 5.00000 5.00000 Known Measured Concentration Concentration .000000 .000000 5.00000 5.00029 Known Measured Concentration Concentration .000000 -.000000 5.00000 5.00000 Known Measured Concentration Concentration .000000 .000000 1000.00 1000.000 page 2 Residual Concentration .000000 .000000 Residual Concentration -.000000 .000000 Residual Signal .028449 28.4148 Residual Signal -.000153 .930110 Residual Concentration -.000000 .000000 Residual Concentration .000000 .000000 Residual Signal .002708 .486138 Residual Concentration -.000000 .000000 Residual Concentration -.000000 -.000291 Residual Concentration .000000 .000000 Residual cn Concentration -.000000 .000061 NO F-+ Standardization Readback Report 06/14/05 09:24:51 AM Element Wavelength Standard 2JJ/2 220.352 StdBLANK StdFURNC Element Wavelength Standard Sb2068 206.838 StdBLANK StdAGPSB Element Wavelength Standard 1960/1 196.021 StdBLANK StdFURNC Element Wavelength Standard 1960/2 196.022 StdBLANK StdFURNC Element Wavelength Standard Sn 189.989 StdBLANK StdMULTI Element Wavelength Standard x11908 190.864 StdBLANK • StdFURNC Element Wavelength Standard J 292.402 StdBLANK StdMULTI ;lement Wavelength Standard ;n 206.200 StdBLANK StdMULTI :lement Wavelength Standard 'b2203 220.353 NONE NONE ;lement Wavelength Standard e1960 196.026 NONE NONE Known Concentration .000000 1000.00 Known Concentration .000000 2000.00 Known Concentration .000000 1000.00 Known Concentration .000000 1000.00 Known Concentration .000000 5.00000 Known Concentration .000000 1000.00 Known Concentration .000000 5.00000 Known Concentration .000000 5.00000 Known Signal .000000 .000000 Known Signal .000000 .000000 Measured Concentration -.000000 innn nn Measured Concentration -.000000 2000.00 Measured Concentration -.000000 1000.00 Measured Concentration -.000000 1000.00 Measured Concentration .000000 5.00000 Measured Concentration -.000000 1000.00 Measured Concentration .000000 5.00000 Measured Concentration .000000 5.00000 Measured Signal .000000 .000000 Measured Signal .000000 .000000 page 3 Residual Concentration .000000 .000000 Residual Concentration .000000 .000000 Residual Concentration .000000 .000000 Residual Concentration .000000 .000000 Residual Concentration -.000000 .000000 Residual Concentration .000000 -.000061 Residual Concentration -.000000 .000000 Residual Concentration -.000000 .000000 Residual Signal .000000 .000000 Residual Signal .000000 .000000 Analysis Report 06/14/05 09:33:40 AM page 1 Method: DVCLPI Sample Name: ICV Operator: CO Run Time: 06/14/05 09:24:59 C nt: M CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1015.4 50.14 487.28 2.499 2.580 2.497 49.82 SDev .8 .10 2.36 .003 .005 .002 .06 %RSD .07792 .2008 .48362 .1368 .1985 .0999 .1114 #1 1016.3 50.26 485.67 2.498 2.586 2.496 49.82 #2 1015.0 50.09 486.19 2.496 2.579 2.495 49.77 #3 1014.9 50.08 489.99 2.502 2.576 2.500 49.88 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 1100.0 55.00 550.00 2.750 2.750 2.750 55.00 Low 900.00 45.00. 450.00 2.250 2.250 2.250 45.00 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge 2.483 2.745 2.488 2.546 50.98 81.51 48.86 SDev .002 .017 .001 .010 .08 .60 .02 %RSD .0719 .6292 .0509 .3808 .1533 .7418 .0364 #1 2.483 2.744 2.487 2.552 51.02 82.20 48.86 #2 2.485 H2.763 2.489 2.535 51.02 81.24 48.84 2.481 2.728 2.487 2.551 50.89 81.09 48.87 ,*Ors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 2.750 2.750 2.750 2.750 55.00 88.00 55.00 Low 2.250 2.250 2.250 2.250 45.00 72.00 45.00 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge 2.525 2.426. 76.59 2.368 -.0013 479.82 472.84 SDev .001 .010 .17 .009 .0061 1.87 3.06 %RSD .0500 .4293 .2171 .3972 457.3 .38900 .64637 #1 2.527 2.416 76.75 2.366 .0051 481.35 475.43 #2 2.524 2.424 76.62 2.359 -.0019 477.74 469.47 #3 2.525 2.437 76.42 2.378 -.0072 480.37 473.63 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High 2.750 88.00 2.750 Low 2.250 72.00 2.250 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge 1032.8 514.08 485.93 2.471 486.69 2.535 2.418 SDev 1.6 10.18 7.64 .003 4.09 .003 .003 %RSD .15394 1.9811 1.5721 .1174 .84052 .1179 .1133 1031.5 504.13 494.70 2.467 482.81 2.538 2.415 1032.3 513.61 482.37 2.473 490.97 2.532 2.420 O #3 1034.6 524.48 480.72 2.472 486.30 2.534 2.420 Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass Analysis Report 06/14/05 09:33:40 AM page 2 High 1100.0 1900.00 Pb2203 Se1960 Units ppb ppb Avge 475.17 495.31 SDev 2.66 2.53 %RSD .55978 .51153 #1 477.40 497.84 #2 472.22 492.78 #3 475.88 495.30 Errors LC Pass LC Pass High 550.00 550.00 Low 450.00 450.00 • 550.00 2.750 450.00 2.250 2.750 2.250 "Ic N O V] H Analysis Report 06/14/05 09:42:28 AM page 1 Method: DVCLPI Sample Name: ICB Operator: CO Run Time: 06/14/05 09:33:47 C ent: M . CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1.8720 .0141 3.6156 .0063 .0008 .0006 .0113 SDev .3630 .0114 .5258 .0012 .0001 .0001 .0036 %RSD 19.390 80.76 14.543 19.32 15.02 21.27 31.58 #1 1.9666 .0019 3.2102 .0077 .0009 .0007 .0153 #2 2.1783 .0159 4.2097 .0057 .0008 .0006 .0105 #3 1.4711 .0244 3.4269 .0055 .0007 .0005 .0083 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .2000 10.000 .0200 .2000 .0050 .2000 Low -10.000 -.2000 -10.000 -.0200 -.2000 -.0050 -.2000 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0005 .0001 -.0005 .0004 .0108 .0586 .0017 SDev .0002 .0003 .0001 .0010 .0018 .0023 .0057 %RSD 35.41 304.4 19.46 233.8 16.94 3.984 342.6 #1 .0007 -.0001 -.0006 .0015 .0124 .0611 .0064 #2 .0006 -.0000 -.0005 .0004 .0111 .0565 -.0046 #3 .0003 .0004 -.0005 -.0006 .0088 .0583 .0032 *rs LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .0050 .0500 .0100 .0250 .1000 5.000 .2000 Low -.0050 -.0500 -.0100 -.0250 -.1000 -5.000 -.2000 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge .0005 .0042 .0443 -.0001 -.0031 16.343 -6.6662 SDev .0001 .0027 .0017 .0006 .0019 2.206 2.0156 %RSD 19.13 63.99 3.761 605.2 61.07 13.501 30.236 #1 .0006 .0071 .0438 .0006 -.0051 17.560 -7.6929 #2 .0005 .0037 .0461 -.0004 -.0026 13.796 -7.9616 #3 .0004 .0018 .0429 -.0004 -.0015 17.672 -4.3440 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High .0150 5.000 .0400 Low -.0150 -5.000 -.0400 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge .97787 11.970 -3.4689 .0045 3.3912 -.0003 .0002 SDev .91900 4.502 4.3980 .0014 1.5812 .0002 .0002 %RSD 93.979 37.610 126.78 31.56 46.625 66.91 97.65 # 1.7334 15.025 -1.8976 .0056 2.0219 -.0004 .0003 1.2454 14.086 -.07239 .0049 5.1217 -.0001 -.0000 # -.04522 6.8002 -8.4367 .0029 3.0301 -.0003 .0003 Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass Analysis Report High 60.000 Se1960 -60.000 E em P • • 06/14/05 09:42:28 AM page 2 10.000 .0500 .0200 -10.000 -.0500 -.0200 00 N O C/1 H b2203 Se1960 Units ppb ppb Avge .99619 1.6729 SDev 1.8677 4.3840 %RSD 187.49 262.07 #1 .71670 3.7382 #2 -.71605 4.6427 #3 2.9879 -3.3624 Errors LC Pass LC Pass High 3.0000 5.0000 Low -3.0000 -5.0000 • • 06/14/05 09:42:28 AM page 2 10.000 .0500 .0200 -10.000 -.0500 -.0200 00 N O C/1 H Analysis Report Method: DVCLPI Sample Name: CRII Run Time: 06/14/05 09:42:35 ppm C nt: ppm .2069 .0004 M CONC Corr. Factor: 1 .0003 Elem Ag Al As1890 Units ppb ppm ppb Avge 20.774 .0326 24.435 SDev .430 .0022 .429 %RSD 2.0715 6.838 1.7563 #1 20.318 .0352 24.856 #2 20.831 .0312 23.998 #3 21.173 .0315 24.451 Elem Cd Co Cr Units ppm ppm ppm Avge .0101 .1009. .0188 SDev .0001 .0002 .0004 %RSD 1.163 .2176 1.903 #1 .0101 .1009 .0192 #2 .0099 .1007 .0188 #3 .0102 .1011 .0185 Elem Mn Mo Na Units ppm ppm ppm e .0299 .0305 .0428 -.0092 .0001 .0009 .0026 SD .4288 2.889 6.011 #1 .0298 .0315 .0453 #2 .0300 .0300 .0430 #3 .0298 .0299 .0402 Elem Sb2068 1960/1 1960/2 Units ppb ppb ppb Avge 123.02 15.960 4.8899 SDev 2.39 1.425 5.8564 %RSD 1.9442 8.9318 119.76 #1 123.14 15.281 11.646 #2 120.57 17.598 1.7671 #3 125.35 15.000 1.2568 Elem Pb2203 Se1960 Units ppb ppb Avge 6.7704 8.5766 SDev 1.4136 3.7554 %RSD 20.879 43.787 #1 6.6733 12.857 #2 8.2300 7.0391 0 5.4078 5.8339 06/14/05 09:51:16 AM page 1 Operator: CO B Ba Be Ca ppm ppm ppm ppm .2069 .0004 .0101 .0054 .0003 .0001 .0001 .0002 .1281 19.77 .6981 3.998 .2069 .0004 .0102 .0056 .2066 .0003 .0101 .0052 .2071 .0003 .0101 .0054 Cu Fe K Mg PPM ppm ppm ppm .0479 .0021 .0422 -.0025 .0003 .0012 .005 .0040 .6898 56.26 15.36 162.1 .0483 .0032 .0377 -.0062 .0478 .0021 .0394 -.0030 .0476 .0009 .0497 .0018 Ni P 2203/1 2203/2 PPM ppm ppb ppb .0796 -.0061 20.967 -.31790 .0009 .0069 4.283 3.21914 1.155 114.1 20.427 1012.6 .0794 -.0109 16.123 1.9547 .0807 -.0092 22.523 1.0933 .0789 .0019 24.253 -4.0016 Sn T11908 V Zn ppm ppb ppm ppm .0810 21.499 .0984 .0403 .0023 .894 .0003 .0006 2.890 4.1574 .3418 1.566 .0786 22.499 .0981 .0399 .0832 21.217 .0987 .0401 .0813 20.779 .0984 .0410 Analysis Report 06/14/05 10:00:04 AM page 1 Method: DVCLPI Sample Name: ICSAI Operator: CO Run Time: 06/14/05 09:51:23 C nt: . M CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 2.3497 525.0 1.9649 .0120 .0014 .0002 522.2 SDev .1339 1.2 .3967 .0008 .0000 .0000 2.5 %RSD 5.6982 .2368. 20.188 6.268 1.488 11.95 .4783 #1 2.2279 526.3 2.2962 .0112 .0013 .0002 525.0 #2 2.3281 524.7 2.0732 .0125 .0014 .0002 520.3 #3 2.4931 523.9 1.5253 .0124 .0013 .0001 521.1 Errors LC Pass LC Pass NOCHECK NOCHECK LC Pass LC Pass LC Pass High 10.000 600.0 .2000 .0050 600.0 Low -10.000 400.0 -.2000 -.0050 400.0 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0029 .0021 .0041 .0018 205.3 .0327 531.0 SDev .0006 .0002 .0006 .0013 1.6 .0079 1.1 %RSD 20.75 9.261 14.16 72.93 .7707 24.23 .2040 #1 .0023 .0019 .0044 .0004 203.6 .0293 530.1 #2 .0028 .0023 .0034 .0021 205.5 .0270 530.7 0035 .0020 .0045 .0030 206.8 .0417 532.2 *Ors LC Pass NOCHECK LC Pass NOCHECK LC Pass NOCHECK LC Pass High .0050 .0100 240.0 600.0 Low -.0050 -.0100 160.0 400.0 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge .0087 .0000 .0289 .0032 .0097 -27.947 15.155 SDev .0000 .0003 .0018 .0007 .0070 4.670 1.721 %RSD .2074 668.6 6.272 23.08 72.46 16.709 11.355 #1 .0086 -.0001 .0308 .0038 .0177 -33.265 14.077 #2 .0087 .0004 .0286 .0034 .0044 -26.062 14.249 #3 .0087 -.0002 .0272 .0024 .0070 -24.515 17.140 Errors LC Pass NOCHECK NOCHECK LC Pass NOCHECK NOCHECK NOCHECK High .0150 .0400 Low -.0150 -.0400 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge 2.6361 14.394 -3.8781 -.0034 H14.244 .0043 .0066 SDev 5.4541 9.611 3.2590 .0023 10.000 .0006 .0002 %RSD 206.90 66.774 84.037 67.49 70.206 13.51 3.671 -3.6056 3.6806 -3.0585 -.0008 4.9498 .0048 .0068 Is 5.0299 22.260 -1.1071 -.0050 H12.957 .0037 .0065 #3 6.4840 17.241 -7.4687 -.0043 H24.826 .0044 .0064 Errors LC Pass NOCHECK NOCHECK NOCHECK LC High LC Pass LC Pass O NO N O F-� Analysis Report 06/14/05 10:00:04 AM page 2 High 60.000 w -60.000 AL m Pb2203 Se1960 Units ppb ppb Avge .80273 2.2069 SDev 2.4786 3.9483 %RSD 308.77 178.90 #1 -1.6875 -.81387 #2 .82611 H6.6745 #3 3.2695 .76018 Errors LC Pass LC Pass High 6.0000 5.0000 Low -6.0000 -5.0000 • 10.000 .0500 -10.000 -.0500 .0200 -.0200 Analysis Report 06/14/05 10:08:52 AM page 1 Method: DVCLPI Sample Name: ICSABI Run Time: 06/14/05 10:00:11 Co ent: McCONC Corr. Factor: 1 Elem Ag Al As1890 Units ppb ppm ppb Avge 1112.4 526.0 978.56 SDev 3.2 1.0 5.75 %RSD .28743 .1890. .58740 #1 1115.7 527.1 973.48 #2 1112.2 525.5 984.80 #3 1109.3 525.3 977.39 Errors LC Pass LC Pass LC Pass High 1200.0 600.0 1200.0 Low 800.00 400.0 800.00 Elem Cd Co Cr. Units ppm ppm ppm Avge .9683 .5334 .5041 SDev .0007 .0020 .0012 %RSD .0714 .3701 .2449 #1 .9676 .5334 #2 .9690 .5353 #3 .9682 .5314 .5456 .5002 496.7 E*rs LC Pass LC Pass High 1.200 .6000 Low .8000 .4000 Elem Mn Mo Units ppm ppm Avge .5247 .9714 SDev .0004 .0016 %RSD .0691 .1638 #1 .5244 .9700 #2 .5251 .9732 #3 .5246 .9710 Errors LC Pass NOCHECK High .6000 ppm Low .4000 201.1 Elem Sb2068 1960/1 Units ppb ppb Avge -3.1723 986.78 SDev 1.9041 12.77 %RSD 60.022 1.2942 # -1.5670 1000.1 .5688 -5.2760 974.67 # -2.6740 985.55 Errors NOCHECK NOCHECK .5040 .5053 .5029 LC Pass .6000 .4000 Na ppm .0204 .0008 3.959 .0208 .0195 .0209 NOCHECK Operator: CO B Ba Be Ca ppm ppm ppm ppm 1.041 .5456 .5002 496.7 .002 .0015 .0003 .6 .1772 .2746 .0641 .1174 1.039 .5472 .5002 496.1 1.041 .5453 .5004 496.9 1.042 .5442 .4998 497.2 LC Pass LC Pass LC Pass LC Pass 1.200 .6000 .6000 600.0 .8000 .4000 .4000 400.0 Cu Fe K Mg ppm ppm ppm ppm .5695 201.1 .0151 519.5 .0006 .1 .0325 .4 .1033 .0646 216.2 .0685 .5698 201.2 -.0220 519.8 .5698 201.1 .0391 519.6 .5688 200.9 .0280 519.1 LC Pass LC Pass NOCHECK LC Pass .6000 240.0 600.0 .4000 160.0 400.0 Ni P 2203/1 2203/2 ppm ppm ppb ppb .9274 .0076 937.32 975.89 .0006 .0164 .98 1.60 .0670 216.7 .10470 .16401 .9267 .0167 937.23 975.13 .9275 .0174 938.34 974.82 .9280 -.0114 936.38 977.73 LC Pass NOCHECK NOCHECK NOCHECK 1.200 .8000 1960/2 Sn T11908 V ppb ppm ppb ppm 963.20 .9649 983.97 .5184 5.66 .0012 8.39 .0004 .58714 .1256 .85229 .0753 963.40 .9636 974.32 .5180 968.75 .9651 989.52 .5184 957.44 .9660 988.06 .5187 NOCHECK NOCHECK LC Pass LC Pass Zn ppm .9070 .0022 .2422 .9048 .9092 .9072 LC Pass Analysis Report 06/14/05 10:08:52 AM page 2 High AL E m Unit Avge SDev %RSD #1 #2 #3 Error High Low • • Se1960 ppb 971.05 4.42 .45538 975.63 970.72 966.81 LC Pass 1200.0 800.00 1200.0 .6000 800.00 .4000 1.200 .8000 Pb2203 s ppb 963.05 .80 .08272 962.51 962.67 963.96 s LC Pass 1200.0 800.00 • Se1960 ppb 971.05 4.42 .45538 975.63 970.72 966.81 LC Pass 1200.0 800.00 1200.0 .6000 800.00 .4000 1.200 .8000 Analysis Report 06/14/05 10:17:41 AM page 1 Method: DVCLPI Sample Name: CCV1 Operator: CO Run Time: 06/14/05 10:09:00 C nt: M CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1013.4 50.36 496.73 2.556 2.567 2.526 51.11 SDev 2.7 .04 2.47 .010 .006 .003 .11 %RSD .26355 .0882 .49795 .3817 .2499 .1309 .2178 #1 1016.4 50.38 494.54 2.547 2.574 2.528 51.01 #2 1011.4 50.38 499.41 2.556 2.567 2.522 51.09 #3 1012.3 50.31 496.23 2.566 2.561 2.528 51.23 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 1100.0 55.00 550.00 2.750 2.750 2.750 55.00 Low 900.00 45.00 450.00 2.250 2.250 2.250 45.00 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge 2.509 2.603 2.523 2.606 50.85 81.82 49.39 SDev .008 .039 .001 .007 .14 .01 .11 %RSD .3324 1.493 .0575 .2713 .2741 .0117 .2165 #1 2.516 2.648 2.523 2.598 51.01 81.83 49.52 #2 2.500 2.582 2.521 2.611 50.74 81.81 49.33 #3 *rs 2.510 2.579 2.524 2.610 50.82 81.81 49.33 LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 2.750 2.750 2.750 2.750 55.00 88.00 55.00 Low 2.250 2.250 2.250 2.250 45.00 72.00 45.00 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge 2.556 2.483 77.01 2.481 .0025 493.12 496.55 SDev .001 .007 .14 .018 .0032 3.99 3.86 %RSD .0573 .2629 .1789 .7365 127.6 .80889 .77664 #1 2.557 2.476 76.95 2.460 .0042 488.63 493.33 #2 2.555 2.482 76.92 2.490 .0046 494.47 495.50 #3 2.557 2.489 77.17 2.494 -.0012 496.26 500.83 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High 2.750 88.00 2.750 Low 2.250 72.00 2.250 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge 1046.5 517.02 507.31 2.481 496.85 2.557 2.449 SDev 4.1 6.87 6.96 .005 3.81 .002 .008 %RSD .39330 1.3287 1.3726 .1971 .76671 .0927 .3280 # 1043.0 524.90 499.33 2.486 498.23 2.560 2.457 1051.0 512.34 510.49 2.476 499.78 2.556 2.441 # 1045.5 513.80 512.12 2.480 492.55 2.555 2.450 Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass Analysis Report 06/14/05 10:17:41 AM page 2 High 1100.0 0 900.00 Elem Pb2203 Se1960 Units ppb ppb Avge 495.41 510.54 SDev 3.78 2.47 %RSD .76212 .48305 #1 491.77 507.84 #2 495.16 511.11 #3 499.31 512.68 Errors LC Pass LC Pass High 550.00 550.00 Low 450.00 450.00 • • 550.00 2.750 450.00 2.250 2.750 2.250 Analysis Report 06/14/05 10:26:29 AM page 1 Method: DVCLPI Sample Name: CCB1 Operator: CO Run Time: 06/14/05 10:17:48 C ent: M�: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1.8031 .0618 5.3798 .0067 .0008 .0005 .0299 SDev .2239 .0043 .8577 .0015 .0001 .0001 .0062 %RSD 12.415 7.047 15.943 22.05 14.97 19.33 20.71 #1 1.7541 .0638 4.4015 .0083 .0008 .0006 .0337 #2 1.6078 .0648 5.7351 .0063 .0008 .0005 .0333 #3 2.0474 .0568 6.0027 .0054 .0006 .0004 .0228 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .2000 10.000 .0200 .2000 .0050 .2000 Low -10.000 -.2000 -10.000 -.0200 -.2000 -.0050 -.2000 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0005 .0003 .0000 -.0011 .0193 .0505 .0259 SDev .0001 .0001 .0002 .0001 .0032 .0053 .0057 %RSD 23.50 58.04 656.4 9.500 16.71 10.46 22.04 #1 .0006 .0004 .0001 -.0012 .0219 .0521 .0199 #2 .0004 .0004 -.0002 -.0010 .0203 .0548 .0313 *Ors 0005 .0001 .0002 -.0011 .0157 .0446 .0265 LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .0050 .0500 .0100 .0250 .1000 5.000 .2000 Low -.0050 -.0500 -.0100 -.0250 -.1000 -5.000 -.2000 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge .0005 .0046 .0266 -.0003 -.0047 15.188 -4.9711 SDev .0001 .0031 .0049 .0005 .0062 .993 .4422 %RSD 20.13 67.11 18.46 160.3 133.3 6.5400 8.8957 #1 .0006 .0082 .0310 -.0008 -.0002 15.092 -4.7282 #2 .0006 .0034 .0273 .0002 -.0118 14.246 -4.7035 #3 .0004 .0024 .0213 -.0003 -.0020 16.226 -5.4815 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High .0150 5.000 .0400 Low -.0150 -5.000 -.0400 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge .46150 15.420 -5.1751 .0054 4.1543 -.0001 -.0002 SDev 1.9646 1.996 5.2088 .0003 3.0074 .0001 .0002 %RSD 425.70 12.947 100.65 5.926 72.391 120.8 89.69 2.5873 13.696 -3.2385 .0058 6.9247 -.0000 -.0003 .08425 14.956 -1.2120 .0053 .95587 -.0000 .0000 #3 -1.2871 17.608 -11.075 .0052 4.5824 -.0003 -.0003 Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass Analysis Report High 60.000 Z� -60.000 Elem Pb2203 Se1960 Units ppb ppb Avge 1.7423 1.6835 SDev .1327 2.9148 %RSD 7.6172 173.14 #1 1.8724 2.4013 #2 1.6071 4.1724 #3 1.7475 -1.5231 Errors LC Pass LC Pass High 3.0000 5.0000 Low -3.0000 -5.0000 • 06/14/05 10:26:29 AM page 2 10.000 .0500 .0200 -10.000 -.0500 -.0200 r - IC N O F-+ Analysis Report 06/14/05 10:35:18 AM page 1 Method: DVCLPI Sample Name: MB -13796 Operator: CO Run Time: 06/14/05 10:26:37 ¢ C� V- C nt : Mo CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1.7064 .0016 4.4439 .0032 .0003 .0001 .0009 SDev .4105 .0067 1.3192 .0004 .0001 .0001 .0009 %RSD 24.057 412.8 29.686 11.69 16.68 59.43 105.9 #1 2.1804 .0078 3.1725 .0036 .0004 .0001 .0019 #2 1.4696 .0025 5.8063 .0028 .0003 .0001 .0007 #3 1.4692 -.0055 4.3531 .0032 .0003 .0000 .0001 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .2000 10.000 .0200 .2000 .0050 .2000 Low -10.000 -.2000 -10.000 -.0200 -.2000 -.0050 -.2000 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0001 -.0005 -.0007 .0005 .0058 .0409 -.0009 SDev .0000 .0006 .0007 .0006 .0016 .0030 .0024 %RSD 5.533 119.3 97.23 111.4 27.85 7.304 257.8 #1 .0001 -.0006 -.0013 -.0001 .0074 .0443 -.0015 #2 .0001 .0002 .0001 .0009 .0058 .0386 .0017 # .0001 -.0010 -.0010 .0008 .0042 .0398 -.0030 E ors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .0050 .0500 .0100 .0250 .1000 5.000 .2000 Low -.0050 -.0500 -.0100 -.0250 -.1000 -5.000 -.2000 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge -.0000 .0017 .0158 -.0008 -.0062 15.991 -7.7135 SDev .0001 .0003 .0027 .0005 .0061 1.231 1.6583 %RSD 148.9 20.00 17.00 61.09 98.36 7.7010 21.499 #1 -.0001 .0019 .0182 -.0012 -.0084 17.375 -6.0931 #2 .0000 .0013 .0161 -.0008 .0007 15.014 -7.6401 #3 -.0001 .0019 .0129 -.0003 -.0110 15.585 -9.4072 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High .0150 5.000 .0400 Low -.0150 -5.000 -.0400 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -2.5874 6.9699 -6.6304 .0035 1.5282 -.0006 .0008 SDev .9176 1.4833 2.3152 .0009 .9020 .0000 .0004 %RSD 35.466 21.281 34.919 25.37 59.019 .0621 50.82 -3.0068 7.8334 -5.8890 .0041 1.3356 -.0006 .0003 is -1.5350 5.2572 -4.7766 .0025 2.5110 -.0006 .0010 #3 -3.2203 7.8191 -9.2255 .0039 .73818 -.0006 .0010 Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass Analysis Report High 60.000 9 -60.000 Elem Pb2203 Units ppb Avge .18071 SDev 1.4235 %RSD 787.73 #1 1.7221 #2 -.09573 #3 -1.0843 Errors LC Pass High 3.0000 Low -3.0000 • r� Se1960 ppb -2.1010 1.2555 59.755 -1.3190 -1.4349 -3.5492 LC Pass 5.0000 -5.0000 06/14/05 10:35:18 AM page 2 10.000 .0500 .0200 -10.000 -.0500 -.0200 Analysis Report 06/14/05 10:44:07 AM page 1 Method: DVCLPI Sample Name: LCS-13796 Run Time: 06/14/05 10:35:26 Le.S-' C nt: M CONC Corr. Factor: 1 Elem Ag Al As1890 B Units ppb ppm ppb ppm Avge 1037.7 52.27 512.86 2.517 SDev 11.6 .65 8.35 .027 %RSD 1.1209 1.243 1.6283 1.090 #1 1033.0 51.94 506.66 2.501 #2 1050.9 53.02 522.36 2.549 #3 1029.1 51.86 509.57 2.502 Errors LC Pass High 1200.0 Low 800.00 Elem Cd Units ppm Avge 2.506 SDev .032 %RSD 1.262 #1 2.487 #2 2.543 1047.0 is 1073.1 #3 1042.5 Errors LC Pass LC Pass 60.00 40.00 Co ppm 2.712 .047 1.731 2.703 2.763 2.671 LC Pass 3.000 2.000 Mo ppm 2.484 .032 1.297 2.462 2.521 2.469 NOCHECK 1960/1 ppb 532.14 12.02 2.2595 518.61 541.60 536.22 NOCHECK LC Pass 600.00 400.00 Cr ppm 2.539 .031 1.228 2.519 2.575 2.523 LC Pass 3.000 2.000 Na ppm 79.69 .78 .9787 79.41 80.58 79.09 LC Pass 96.00 64.00 1960/2 ppb 508.28 8.50 1.6715 498.82 510.76 515.25 NOCHECK LC Pass 3.000 2.000 Cu ppm 2.681 .029 1.083 2.665 2.714 2.663 LC Pass 3.000 2.000 Ni ppm 2.439 .028 1.128 2.415 2.469 2.432 LC Pass 3.000 2.000 Operator: CO Ba Be O2.489 ors LC Pass High 3.000 Low 2.000 Elem Mn Units ppm Avge 2.581 SDev .033 %RSD 1.295 #1 2.561 #2 2.620 #3 2.562 Errors LC Pass High 3.000 Low 2.000 Elem Sb2068 Units ppb Avge 1054.2 SDev 16.5 %RSD 1.5673 1047.0 is 1073.1 #3 1042.5 Errors LC Pass LC Pass 60.00 40.00 Co ppm 2.712 .047 1.731 2.703 2.763 2.671 LC Pass 3.000 2.000 Mo ppm 2.484 .032 1.297 2.462 2.521 2.469 NOCHECK 1960/1 ppb 532.14 12.02 2.2595 518.61 541.60 536.22 NOCHECK LC Pass 600.00 400.00 Cr ppm 2.539 .031 1.228 2.519 2.575 2.523 LC Pass 3.000 2.000 Na ppm 79.69 .78 .9787 79.41 80.58 79.09 LC Pass 96.00 64.00 1960/2 ppb 508.28 8.50 1.6715 498.82 510.76 515.25 NOCHECK LC Pass 3.000 2.000 Cu ppm 2.681 .029 1.083 2.665 2.714 2.663 LC Pass 3.000 2.000 Ni ppm 2.439 .028 1.128 2.415 2.469 2.432 LC Pass 3.000 2.000 Operator: CO Ba Be ppm ppm 2.656 2.593 .034 .033 1.289 1.272 2.645 2.573 2.694 2.631 2.628 2.576 LC Pass 3.000 2.000 Fe ppm 52.17 .73 1.399 51.80 53.01 51.71 LC Pass 60.00 40.00 P ppm -.0041 .0085 205.3 .0031 -.0135 -.0020 NOCHECK LC Pass 3.000 2.000 Ca ppm 51.20 .62 1.209 50.72 51.90 50.98 LC Pass 60.00 40.00 K Mg ppm ppm 80.47 50.09 .91 .62 1.137 1.231 80.72 49.71 81.23 50.81 79.45 49.77 LC Pass 96.00 64.00 2203/1 ppb 510.15 8.36 1.6380 503.87 519.63 506.94 NOCHECK Sn T11908 V ppm ppb ppm 2.482 517.76 2.591 .038 14.39 .034 1.513 2.7791 1.302 2.464 505.61 2.525 533.65 2.456 514.01 NOCHECK LC Pass 2.571 2.630 2.572 LC Pass LC Pass 60.00 40.00 2203/2 ppb 498.91 3.51 .70448 494.88 500.57 501.30 NOCHECK Zn ppm 2.414 .036 1.504 2.389 2.456 2.398 LC Pass Analysis Report 06/14/05 10:44:07 AM page 2 High 1200.0 1* 800.00 Elem Pb2203 Se1960 Units ppb ppb Avge 502.66 516.22 SDev 4.55 9.39 %RSD .90423 1.8184 #1 497.87 505.41 #2 506.92 521.03 #3 503.18 522.23 Errors LC Pass LC Pass High 600.00 600.00 Low 400.00 400.00 • 0 600.00 3.000 400.00 2.000 3.000 2.000 Analysis Report 06/14/05 10:52:56 AM Method: DVCLPI Sample Name: 0506329-001E Operator: CO Run Time: 06/14/05 10:44:15 nt : C*CONC Mme+- �tJ M Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Units ppb ppm ppb ppm ppm ppm Avge 1.8953 .1160 5.4924 .0313 .0723 .0007 SDev .1848 .0080 .6835 .0013 .0004 .0003 %RSD 9.7502 6.857 12.445 4.265 .5275 48.71 #1 1.9650 .1225 4.9510 .0326 .0726 .0010 #2 2.0352 .1185 6.2605 .0315 .0724 .0007 #3 1.6858 .1071 5.2657 .0299 .0719 .0003 Elem Cd Co Cr Cu Fe K Units ppm ppm ppm ppm ppm ppm Avge .0008 -.0001 .0258 .0012 .1692 2.167 SDev .0005 .0005 .0003 .0003 .0072 .016 %RSD 67.94 602.5 .9974 22.07 4.226 .7511 #1 #2 #3 Elem Units #1 #2 #3 Elem Units Avge SDev %RSD #1 #2 #3 Elem Units Avge SDev %RSD #1 #2 0 .0011 .0010 .0002 Mn ppm .0130 .0004 2.915 .0134 .0130 .0127 Sb2068 ppb .11335 .21033 185.56 -.11316 .15071 .30249 Pb2203 ppb .42015 .65266 155.34 -.06065 .15797 1.1631 .0002 -.0007 .0002 Mo ppm .0034 .0017 50.38 .0054 .0027 .0021 1960/1 ppb 13.249 1.731 13.064 13.070 15.063 11.615 Se1960 ppb 1.9320 1.1328 58.635 1.0910 3.2201 1.4848 .0258 .0261 .0255 Na ppm 44.27 .28 .6430 44.41 44.45 43.94 1960/2 ppb -3.7188 1.1058 29.736 -4.8902 -2.6929 -3.5733 .0013 .0014 .0009 Ni ppm .0052 .0006 10.57 .0046 .0056 .0055 Sn ppm .0052 .0009 17.04 .0058 .0042 .0055 .1756 .1705 .1615 P ppm .1354 .0144 10.65 .1190 .1416 .1458 T11908 ppb 3.8680 .8317 21.503 3.9825 2.9850 4.6366 2.178 2.173 2.148 2203/1 ppb 14.003 1.420 10.141 13.548 15.594 12.866 V ppm .0003 .0001 45.18 .0004 .0004 .0001 page 1 Ca PPM 12.38 .02 .1541 12.39 12.38 12.35 Mg ppm 7.244 .016 .2251 7.261 7.244 7.228 2203/2 ppb -6.3618 1.4971 23.533 -6.8558 -7.5495 -4.6801 Zn ppm .0113 .0007 6.095 .0113 .0120 .0106 Analysis Report 06/14/05 11:01:44 AM page 1 Method: DVCLPI Sample Name: 0506329-002E Operator: CO Run Time: 06/14/05 10:53:03 M� - � S Co nt : MAW CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1.5019 .2564 5.0926 .0283 .0708 .0000 12.02 SDev .3318 .0118 .9641 .0007 .0002 .0000 .04 %RSD 22.094 4.587 18.931 2.363 .2507 58.20 .3574 #1 1.6188 .2610 4.4867 .0290 .0709 .0000 12.05 #2 1.7594 .2652 6.2043 .0282 .0709 .0000 12.05 #3 1.1274 .2430 4.5868 .0277 .0706 .0000 11.97 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0001 -.0004 .0771 .0022 .5550 2.052 7.005 SDev .0002 .0002 .0007 .0009 .0024 .006 .013 %RSD 241.3 61.38 .8579 39.99 .4415 .2902 .1824 #1 .0002 -.0003 .0773 .0017 .5576 2.054 6.997 #2 .0001 -.0002 .0776 .0017 .5547 2.057 7.020 #3 -.0001 -.0006 .0764 .0033 .5527 2.046 6.997 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb A*vAv .0179 .0014 43.09 .0060 .1233 15.590 -5.6488 0000 .0003 .14 .0009 .0026 .563 1.0522 .1109 23.24 .3265 15.59 2.120 3.6080 18.626 #1 .0180 .0017 43.00 .0059 .1263 16.211 -5.9189 #2 .0179 .0011 43.25 .0070 .1222 15.113 -4.4879 #3 .0179 .0013 43.01 .0051 .1214 15.447 -6.5396 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -1.7552 12.653 -4.7568 .0053 1.1832 .0003 .0138 SDev 1.5449 2.416 2.8104 .0008 .6186 .0001 .0002 %RSD 88.016 19.097 59.081 15.06 52.278 43.06 1.637 #1 -2.5585 15.337 -1.5171 .0045 1.2694 .0004 .0137 #2 .02580 11.969 -6.2133 .0061 1.7542 .0003 .0140 #3 -2.7330 10.652 -6.5399 .0053 .52607 .0001 .0136 Elem Pb2203 Se1960 Units ppb ppb Avge 1.4243 1.0411 SDev .6291 2.6658 %RSD 44.166 256.06 #1 1.4507 4.0959 #22.0398 -.15811 #0 .78248 -.81449 Analysis Report 06/14/05 11:10:32 AM Method: DVCLPI Sample Name: 0506329-002EDUP Operator: CO Run Time: 06/14/05 11:01:51 �S 0-f ,-'*t n : M CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Units ppb ppm ppb ppm ppm ppm Avge 2.1124 .2346 5.8845 .0281 .0727 .0000 SDev .3733 .0018 1.2506 .0004 .0001 .0000 %RSD 17.672 .7842 21.253 1.296 .1367 12.06 #1 1.6887 .2352 4.4429 .0278 .0728 .0000 #2 2.2556 .2361 6.5315 .0285 .0727 .0000 #3 2.3929 .2326 6.6790 .0279 .0726 .0000 Elem Cd Co Cr Cu Fe K Units ppm ppm ppm ppm ppm ppm Avge .0002 -.0001 .0800 .0041 .5715 2.091 SDev .0001 .0004 .0006 .0001 .0006 .018 %RSD 79.82 275.5 .7737 3.821 .1120 .8532 #1 #2 #3 Elem Units e PSVD #1 #2 #3 Elem Units Avge SDev %RSD #1 #2 #3 Elem Units Avge SDev %RSD #1 #2 �.J .0001 .0003 .0001 Mn PPM .0188 .0001 .4242 .0189 .0188 .0187 Sb2068 ppb -1.4532 .4800 33.034 -.94002 -1.8913 -1.5282 Pb2203 ppb 1.3738 1.3479 98.111 2.3120 -.17073 1.9803 -.0005 -.0001 .0002 Mo PPM .0011 .0006 56.04 .0016 .0004 .0013 1960/1 ppb 11.497 3.736 32.494 10.049 8.7010 15.739 Se1960 ppb -.63461 2.67556 421.61 -3.1207 -.97995 2.1969 .0793 .0804 .0802 Na PPM 43.55 .09 .1978 43.65 43.49 43.52 1960/2 ppb -6.6918 2.6761 39.990 -9.6966 -5.8140 -4.5650 .0039 .0042 .0041 Ni PPM .0058 .0009 15.60 .0048 .0059 .0066 Sn PPM .0049 .0005 9.874 .0044 .0050 .0054 .5708 .5719 .5719 P PPM .1126 .0007 .6128 .1124 .1121 .1134 T11908 ppb 4.0359 1.0494 26.001 4.7576 2.8321 4.5180 2.110 2.087 2.075 2203/1 ppb 16.599 2.975 17.920 19.856 14.026 15.916 V PPM .0005 .0000 1.334 .0005 .0005 .0005 page 1 Ca PPM 12.17 .02 .1558 12.15 12.18 12.19 Mg PPM 7.175 .007 .0920 7.173 7.183 7.170 2203/2 ppb -6.2281 1.1564 18.567 -6.4474 -7.2590 -4.9777 Zn PPM .0120 .0003 2.401 .0117 .0121 .0123 Analysis Report 06/14/05 11:19:20 AM Method: DVCLPI Sample Name: 0506329-002EMS Operator: CO Run Time: 06/14/05 11:10:39 C ent: tA%Aj-1S M S M�: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Units ppb ppm ppb ppm ppm ppm Avge 48.617 2.333 44.012 .0275 2.188 .0510 SDev .486 .015 .821 .0005 .006 .0001 %RSD 1.0005 .6482 1.8663 1.696 .2840 .0915 #1 48.636 2.318 44.608 .0269 2.195 .0510 #2 48.121 2.333 44.353 .0277 2.186 .0510 #3 49.094 2.348 43.075 .0278 2.184 .0511 Elem Cd Co Cr Cu Fe K Units ppm ppm ppm ppm ppm ppm Avge .0498 .5149 .2824 .2666 1.563 2.118 SDev .0003 .0158 .0003 .0017 .006 .017 %RSD .5992 3.069 .1015 .6389 .3929 .8018 #1 .0498 .5310. .2822 .2649 1.558 2.125 #2 .0501 .5142 .2827 .2666 1.561 2.099 #3 .0495 .4994 .2824 .2683 1.569 2.130 Elem Mn Mo Na Ni P 2203/1 Units ppm ppm ppm ppm ppm ppb A e .5291 .0010 43.36 .4988 .1448 37.070 .0003 .0006 .26 .0083 .0089 2.279 % .0553 60.23 .6069 1.655 6.126 6.1470 #1 .5289 .0003 43.38 .4902 .1438 39.226 #2 .5295 .0014 43.08 .4994 .1364 34.686 #3 .5290 .0012 43.60 .5067 .1541 37.298 Elem Sb2068 1960/1 1960/2 Sn T11908 V Units ppb ppb ppb ppm ppb ppm Avge 508.63 22.381 5.2539 .0035 54.511 .5104 SDev 4.07 2.228 2.3031 .0001 .310 .0008 %RSD .80062 9.9531 43.836 2.878 .56850 .1516 #1 504.40 21.619 3.5914 .0036 54.708 .5104 #2 512.52 20.634 7.8827 .0035 54.671 .5096 #3 508.97 24.890 4.2876 .0034 54.154 .5112 Elem Pb2203 Se1960 Units ppb ppb Avge 21.625 10.958 SDev .959 1.278 %RSD 4.4366 11.663 #1 20.571 9.5950 #2 21.858 12.129 v22.447 11.148 page 1 Ca PPM 11.87 .07 .6102 11.80 11.86 11.95 Mg PPM 6.962 .006 .0886 6.969 6.959 6.957 2203/2 ppb 13.914 2.311 16.609 11.256 15.453 15.032 Zn PPM .4963 .0007 .1360 .4970 .4956 .4963 Analysis Report 06/14/05 11:28:08 AM Method: DVCLPI Sample Name: 0506329-002ESD Operator: CO Run Time: 06/14/05 11:19:27 �� �^-� ' C ent : So 4: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Units ppb ppm ppb ppm ppm ppm Avge 1.7312 .0885 3.5078 .0074 .0153 .0000 SDev .2909 .0076 .8200 .0006 .0004 .0000 %RSD 16.802 8.621 23.375 7.657 2.539 352.3 #1 1.4674 .0943 4.4525 .0071 .0157 .0000 #2 2.0431 .0913 2.9799 .0080 .0153 .0000 #3 1.6831 .0799 3.0912 .0070 .0149 -.0000 Elem Cd Co Cr Cu Fe K Units ppm ppm ppm ppm ppm ppm Avge .0001 -.0000 .0154 -.0019 .1127 .4079 SDev .0001 .0002 .0001 .0003 .0009 .0040 %RSD 177.5 508.5 .9136 18.12 .7773 .9829 #1 .0002 -.0000 .0153 -.0017 .1133 .4092 #2 -.0001 -.0003 .0153 -.0022 .1130 .4035 #3 .0001 .0002 .0156 -.0016 .1117 .4112 Elem Mn Mo Na Ni P 2203/1 Units ppm ppm ppm ppm ppm ppb Avge .0038 .0002 9.503 .0003 .0218 15.035 0002 .0003 .087 .0006 .0057 3.985 5.301 141.9 .9152 183.4 26.43 26.503 #1 .0039 .0005 9.581 .0006 .0265 19.505 #2 .0038 -.0001 9.518 .0007 .0235 13.746 #3 .0035 .0002 9.409 -.0004 .0154 11.855 Elem Sb2068 1960/1 1960/2 Sn T11908 V Units ppb ppb ppb ppm ppb ppm Avge .44986 9.9643 -6.0128 .0044 .63039 .0001 SDev 1.7600 3.6505 3.6496 .0011 1.8372 .0002 %RSD 391.25 36.636 60.696 24.37 291.44 312.7 #1 1.3102 8.0027 -10.227 .0054 .49217 .0002 #2 -1.5749 7.7139 -3.8986 .0043 -1.1338 -.0002 #3 1.6142 14.176 -3.9130 .0033 2.5328 .0002 Elem Pb2203 Se1960 Units ppb ppb Avge .54302 -.69201 SDev 1.1659 3.18545 %RSD 214.71 460.32 #1 1.8550 -4.1560 #2 -.37423 -.03119 #16 .14824 2.1112 page 1 Ca ppm 2.446 .004 .1766 2.450 2.446 2.441 Mg PPM 1.395 .006 .4255 1.402 1.394 1.390 2203/2 ppb -6.6929 .8935 13.350 -6.9575 -7.4243 -5.6970 Zn PPM .0026 .0002 7.647 .0024 .0027 .0027 Analysis Report 06/14/05 11:36:57 AM Method: DVCLPI Sample Name: 0506329-003E Operator: CO Run Time: 06/14/05 11:28:16 Co ent: IA w -a b M CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Units ppb ppm ppb ppm ppm ppm Avge 1.7780 .0011 5.5188 .2057 .0637 .0000 SDev .2520 .0173 .9391 .0021 .0004 .0001 %RSD 14.171 1562. 17.016 1.032 .6121 299.9 #1 1.5388 .0150 5.2330 .2070 .0638 .0000 #2 1.7541 -.0183 6.5676 .2032 .0641 .0001 #3 2.0411 .0066 4.7559 .2068 .0633 -.0000 Elem Cd Co Cr Cu Fe K Units ppm ppm ppm ppm ppm ppm Avge .0000 .0016 .0001 .0073 .0266 11.33 SDev .0002 .0004 .0002 .0030 .0005 .30 %RSD 875.3 22.81 180.0 41.26 2.031 2.669 #1 .0001 .0014 -.0000 .0049 .0270 11.55 #2 -.0002 .0014 .0000 .0107 .0260 11.45 #3 .0002 .0020 .0003 .0064 .0267 10.98 Elem Mn Mo Na Ni P 2203/1 Units ppm ppm ppm ppm ppm ppb Avge 1.496 -.0003 5.223 .0036 .1419 17.232 A .008 .0004 .056 .0004 .0095 2.793 -D .5582 129.7 1.067 10.88 6.665 16.206 #1 1.500 -.0007 5.287 .0033 .1423 16.180 #2 1.486 .0000 5.186 .0035 .1511 20.398 #3 1.502 -.0002 5.196 .0041 .1322 15.118 Elem Sb2068 1960/1 1960/2 Sn T11908 V Units ppb ppb ppb ppm ppb ppm Avge -2.0042 11.350 -2.9942 .0032 3.3843 -.0007 SDev 1.8022 3.757 1.4316 .0003 1.3963 .0003 %RSD 89.922 33.098 47.811 8.958 41.257 40.84 #1 .07365 7.0582 -1.6470 .0029 3.8490 -.0004 #2 -3.1427 12.949 -4.4973 .0034 4.4890 -.0010 #3 -2.9437 14.042 -2.8383 .0032 1.8149 -.0007 Elem Pb2203 Se1960 Units ppb ppb Avge 2.1575 1.7828 SDev .9177 .8669 WRSD 42.536 48.625 11 1.7748 1.2523 f2 3.2046 1.3129 #340 1.4930 2.7832 page 1 Ca ppm 21.33 .25 1.155 21.48 21.04 21.46 Mg ppm 3.903 .010 .2564 3.893 3.913 3.903 2203/2 ppb -5.3691 .0545 1.0157 -5.4175 -5.3798 -5.3100 Zn ppm .0097 .0005 5.484 .0096 .0103 .0092 Analysis Report 06/14/05 11:45:46 AM Method: DVCLPI Sample Name: 0506329-004E Operator: CO Run Time: 06/14/05 11:37:04 /you, -35 Co ent: M CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Units ppb ppm ppb ppm ppm ppm Avge 1.4482 .0498 5.6700 .1935 .0593 -.0000 SDev .0414 .0043 .4563 .0008 .0001 .0000 %RSD 2.8622 8.590 8.0474 .4304 .1572 48.96 #1 1.4717 .0478 5.4361 .1925 .0594 -.0000 #2 1.4003 .0469 6.1958 .1942 .0592 -.0000 #3 1.4725 .0547 5.3781 .1937 .0592 -.0000 Elem Cd Co Cr Cu Fe K Units ppm ppm ppm ppm ppm ppm Avge .0002 .0013 .0003 .0015 .0318 10.45 SDev .0001 .0003 .0003 .0001 .0001 .03 %RSD 54.04 26.71 111.8 7.309 .2809 .3000 #1 .0002 .0016 .0007 .0015 .0318 10.46 #2 .0002 .0009 .0001 .0016 .0317 10.41 #3 .0001 .0013 .0001 .0014 .0319 10.47 Elem Mn Mo Na Ni P 2203/1 Units ppm ppm ppm ppm ppm ppb Avge 1.413 .0005 5.146 .0034 .1522 13.713 .002 .0006 .019 .0004 .0023 1.121 ° .1292 120.7 .3728 10.98 1.486 8.1711 #1 1.412 .0002 5.140 .0035 .1498 13.585 42 1.415 .0001 5.131 .0038 .1527 12.662 #3 1.411 .0012 5.167 .0030 .1543 14.892 Elem Sb2068 1960/1 1960/2 Sn T11908 V Units ppb ppb ppb ppm ppb ppm Avge -1.8597 9.9168 -5.3593 .0046 2.4599 -.0007 SDev 1.1544 2.5576 1.8234 .0006 2.1843 .0001 %RSD 62.073 25.791 34.023 12.85 88.799 15.14 #1 -3.1921 7.0850 -6.4660 .0043 3.8813 -.0006 #2 -1.1621 12.059 -3.2548 .0053 -.05528 -.0007 #3 -1.2248 10.607 -6.3571 .0042 3.5536 -.0009 Elem Pb2203 Se1960 Units ppb ppb Avge -.17471 -.27189 SDev 1.06450 1.93620 %RSD 609.30 712.11 #1 -1.3393 -1.9531 #2 .74817 1.8451 #: .06697 -.70769 page 1 Ca ppm 20.03 .02 .0788 20.01 20.04 20.04 Mg ppm 3.649 .012 .3180 3.647 3.661 3.638 2203/2 ppb -7.1090 1.8059 25.403 -8.7910 -5.2006 -7.3353 Zn PPM .0222 .0003 1.381 .0219 .0223 .0225 00 N O F-� Analysis Report 06/14/05 11:54:34 AM Method: DVCLPI Sample Name: 0506329-005E Operator: CO Run Time: 06/14/05 11:45:53 Cent: NO M : CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Units ppb ppm Ppb ppm ppm Ppm Avge 1.6134 .2232 5.4106 .0868 .0870 SDev .6406 .0035 .5017 .0011 .0002 .0000 %RSD 39.702 1.581 9.2718 1.267 .2177 .0000 148.6 #1 2.2540 .2272 5.4277 .0881 .0869 #2 .97294 .2216 4.9006 .0861 .0870 .0000 #3 1.6132 .2208 5.9035 .0862 .0872 .0000 .0000 Elem Cd Co Cr Cu Fe K Units ppm ppm ppm ppm ppm ppm Avge .0003 .0011 .0162 .0020 .2067 9.670 SDev .0003 .0004 .0003 .0002 .0006 %RSD 97.86 35.87 1.587 12.06 .2812 .021 .2190 #1 .0002 .0014 .0164 .0019 .2074 9.650 #2 .0001 .0007 .0159 .0018 .2065 9.667 #3 .0005 .0012 .0161 .0023 .2063 9.692 Elem Mn Mo Na Ni P 2203/1 Units ppm ppm ppm ppm ppm ppb Avge .6524 .0006 17.93 .0153 .2006 13.881 .0013 .0003 .07 .0003 .0100 1.164 .2005 53.71 .4181 1.895 4.977 8.3848 #1 .6539 .0009 17.85 .0155 .1917 12.583 #2 .6521 .0002 17.97 .0150 .2114 14.832 #3 .6514 .0008 17.98 .0154 .1987 14.226 Elem Sb2068 1960/1 1960/2 Sn T11908 V Units ppb ppb ppb ppm ppb ppm Avge -.80474 12.760 -2.7857 .0038 .87446 .0001 SDev .71296 .202 1.3190 .0010 2.3049 .0002 %RSD 88.595 1.5818 47.351 27.10 263.57 191.9 #1 -.01450 12.719 -3.5792 .0050 -1.1668 .0003 #2 -1.3997 12.581 -3.5148 .0032 3.3740 .0001 #3 -.99996 12.979 -1.2631 .0032 .41615 -.0001 Elem Pb2203 Se1960 Units ppb ppb Avge .66141 2.3914 SDev 1.3221 .9427 %RSD 199.90 39.421 #1 -.21947 1.8485 #2 .02198 1.8457 #6 2.1817 3.4800 page 1 Ca ppm 10.24 .05 .4459 10.29 10.22 10.20 Mg ppm 7.328 .004 .0602 7.323 7.328 7.332 2203/2 ppb -5.9390 1.8637 31.380 -6.6119 -7.3729 -3.8323 Zn ppm .0217 .0006 2.620 .0224 .0214 .0214 Analysis Report 06/14/05 12:03:23 PM page 1 Method: DVCLPI Sample Name: CCV2 Run Time: 06/14/05 11:54:42 998.17 Co ent: LC Pass High 1100.0 M�: CONC Corr. Factor: 1 Elem Elem Ag Al As1890 Units ppb ppm ppb Avge 995.96 50.22 505.85 SDev 1.99 .14 .79 %RSD .19959 .2737 .15661 #1 995.40 #2 994.32 #3 998.17 Errors LC Pass High 1100.0 Low 900.00 Elem Cd Units ppm Avge 2.539 SDev .005 %RSD .1976 #1 2.533 #2 2.543 #3 2.539 Ors LC Pass High 2.750 Low 2.250 Elem Mn Units ppm Avge 2.569 SDev .002 %RSD .0885 #1 2.569 #2 2.571 #3 2.566 Errors LC Pass High 2.750 Low 2.250 Elem Sb2068 Units ppb Avge 1054.2 SDev 5.7 %RSD .54399 # 1048.1 1059.5 # 1055.1 Errors LC Pass 50.35 50.23 50.07 LC Pass 55.00 45.00 Co ppm 2.457 .021 .8419 2.437 2.456 2.478 LC Pass 2.750 2.250 Mo ppm 2.528 .005 .1784 2.524 2.533 2.528 NOCHECK 1960/1 ppb 523.95 4.66 .88965 528.73 519.42 523.70 NOCHECK 504.99 506.55 506.01 LC Pass 550.00 450.00 Cr ppm 2.550 .002 .0726 2.549 2.552 2.550 LC Pass 2.750 2.250 Na ppm 76.25 .31 .4037 76.35 76.50 75.91 LC Pass 88.00 72.00 1960/2 ppb 519.67 1.84 .35497 519.62 521.54 517.85 NOCHECK B ppm 2.602 .007 .2881 2.608 2.604 2.593 LC Pass 2.750 2.250 Cu ppm 2.618 .009 .3415 2.627 2.618 2.609 LC Pass 2.750 2.250 Ni ppm 2.584 .013 .5211 2.594 2.590 2.569 LC Pass 2.750 2.250 Sn ppm 2.501 .008 .3221 2.494 2.510 2.500 NOCHECK Operator: CO Ba ppm 2.537 .003 .0994 2.540 2.536 2.535 LC Pass 2.750 2.250 Fe ppm 50.75 .09 .1861 50.65 50.78 50.83 LC Pass 55.00 45.00 P ppm .0033 .0089 272.1 .0133 .0002 -.0037 NOCHECK T11908 ppb 504.76 3.10 .61377 501.75 504.59 507.94 LC Pass Be ppm 2.549 .006 .2469 2.542 2.551 2.554 LC Pass 2.750 2.250 K ppm 81.57 .71 .8669 82.36 81.36 81.00 LC Pass 88.00 72.00 2203/1 ppb 506.35 3.10 .61131 506.66 509.27 503.11 NOCHECK V ppm 2.562 .002 .0927 2.561 2.565 2.561 LC Pass Ca ppm 52.34 .08 .1486 52.35 52.42 52.26 LC Pass 55.00 45.00 Mg ppm 49.60 .04 .0863 49.62 49.64 49.55 LC Pass 55.00 45.00 2203/2 ppb 514.29 .45 .08835 514.68 513.79 514.40 NOCHECK Zn ppm 2.492 .007 .2738 2.486 2.499 2.492 LC Pass O 00 N O H Analysis Report 06/14/05 12:03:23 PM page 2 High 1100.0 900.00 E em Pb2203 Se1960 Units ppb ppb Avge 511.64 521.10 SDev .88 1.45 %RSD .17221 .27761 #1 512.01 522.66 #2 512.29 520.83 #3 510.64 519.80 Errors LC Pass LC Pass High 550.00 550.00 Low 450.00 450.00 • • 550.00 2.750 450.00 2.250 2.750 2.250 00 N O H Analysis Report 06/14/05 12:12:11 PM page 1 Method: DVCLPI Sample Name: CCB2 Run Time: 06/14/05 12:03:30 SDev C ent: %RSD 32.03 #1 M�: CONC Corr. Factor: 1 .0008 Elem Ag Al As1890 Units ppb ppm ppb Avge 1.8481 .0391 4.8376 SDev .1468 .0013 .9468 %RSD 7.9448 3.384 19.572 #1 1.9660 .0404 3.7444 #2 1.6837 .0389 5.3829 #3 1.8947 .0378 5.3857 Errors LC Pass LC Pass LC Pass High 10.000 .2000 10.000 Low -10.000 -.2000 -10.000 Elem Cd Co Cr Units ppm ppm ppm Avge .0009 -.0001 -.0001 SDev .0002 .0006 .0007 %RSD 27.65 1020. 497.8 #1 .0011 .0006 .0006 #2 .0009 -.0003 -.0002 #3 .0006 -.0005 -.0008 Ors LC Pass LC Pass LC Pass High .0050 .0500 .0100 Low -.0050 -.0500 -.0100 Elem Mn Units ppm Avge .0007 SDev .0002 %RSD 32.03 #1 .0010 #2 .0008 #3 .0005 Errors LC Pass High .0150 Low -.0150 Elem Sb2068 Units ppb Avge -.67384 SDev 3.76936 %RSD 559.38 # 3.6061 -3.4991 # -2.1286 Mo ppm .0042 .0031 75.12 .0077 .0029 .0019 NOCHECK 1960/1 ppb 7.0249 4.4942 63.976 11.663 2.6904 6.7208 Na ppm .0382 .0067 17.68 .0442 .0394 .0309 LC Pass 5.000 -5.000 1960/2 ppb -5.2976 .9339 17.630 -4.3805 -5.2647 -6.2475 Errors LC Pass NOCHECK NOCHECK Operator: CO B Ba Be Ca Ppm Ppm Ppm ppm .0061 .0009 .0007 .0133 .0019 .0001 .0001 .0037 31.10 15.09 22.62 28.19 .0081 .0011 .0008 .0167 .0058 .0009 .0007 .0139 .0043 .0008 .0005 .0093 LC Pass .0200 -.0200 Cu ppm -.0016 .0003 18.13 -.0014 -.0014 -.0019 LC Pass .0250 -.0250 Ni ppm -.0001 .0003 276.9 -.0002 .0002 -.0004 LC Pass .0400 -.0400 Sn ppm .0047 .0013 26.91 .0049 .0033 .0058 NOCHECK LC Pass LC Pass .2000 .0050 -.2000 -.0050 Fe K Ppm Ppm .0153 .0545 .0040 .0077 25.92 14.20 .0192 .0156 .0112 LC Pass .1000 -.1000 P ppm .0028 .0059 214.4 .0064 .0059 -.0041 NOCHECK T11908 ppb 2.9070 1.4879 51.182 4.5421 1.6326 2.5464 LC Pass .0629 .0530 .0476 LC Pass 5.000 -5.000 2203/1 ppb 16.507 2.790 16.900 13.588 19.146 16.787 NOCHECK V ppm .0000 .0005 1224. .0003 .0004 -.0005 LC Pass LC Pass .2000 -.2000 Mg ppm .0105 .0066 62.41 .0158 .0126 .0032 LC Pass .2000 -.2000 2203/2 ppb -5.7879 .2032 3.5110 -5.5581 -5.8619 -5.9438 NOCHECK Zn ppm -.0000 .0003 1129. -.0000 .0003 -.0004 LC Pass N 00 N O Analysis Report 06/14/05 12:12:11 PM page 2 High 60.000 -60.000 E em #1 Pb2203 Se1960 Units ppb ppb Avge 1.6369 -1.1937 SDev .8242 1.8987 %RSD 50.351 159.06 #1 .81816 .96261 #2 2.4664 -2.6152 #3 1.6260 -1.9286 Errors LC Pass LC Pass High 3.0000 5.0000 Low -3.0000 -5.0000 C. • 10.000 .0500 -10.000 -.0500 .0200 -.0200 M 00 N O O Cl1 Analysis Report 06/14/05 12:21:00 PM Method: DVCLPI Sample Name: 0506329-006E Operator: CO R T' V... ime. 06/14/05 12:12:19 Be C ent: PPM Ppm PPM M�: CONC Corr. Factor: 1 .0001 Elem Ag Al As1890 B Units ppb ppm ppb ppm Avge 1.7321 .0769 4.8478 .0993 SDev .3994 .0109 1.3822 .0006 %RSD 23.058 14.16 28.513 .5971 #1 1.9623 .0668 3.3713 .0987 #2 1.2709 .0755 5.0611 .0994 #3 1.9631 .0885 6.1110 .0999 Elem Cd Co Cr Cu Units ppm ppm ppm ppm Avge .0002 .0002 .0248 .0015 SDev .0001 .0003 .0004 .0008 %RSD 23.40 116.6 1.688 54.93 #1 .0003 -.0000 .0244 .0024 #2 .0002 .0005 .0252 .0013 #3 .0002 .0002 .0246 .0008 Elem Mn Mo Na Ni Units ppm ppm ppm ppm Av e 6857 .0016 15.38 .0096 .0009 .0007 .17 .0004 .1362 43.36 1.102 3.895 #1 .6868 .0024 15.22 .0099 #2 .6851 .0011 15.37 .0092 #3 .6853 .0013 15.56 .0097 Elem Sb2068 1960/1 1960/2 Sn Units ppb ppb ppb ppm Avge -.42891 14.729 -6.1019 .0051 SDev 2.23481 5.458 2.1726 .0015 %RSD 521.04 37.057 35.606 30.05 #1 -2.7676 19.699 -4.3156 .0064 #2 -.20423 8.8878 -5.4696 .0034 #3 1.6851 15.601 -8.5206 .0054 Elem Pb2203 Se1960 Units ppb ppb Avge .57720 .83530 SDev .04821 2.4672 %RSD 8.3530 295.37 #1 .54683 3.6818 #2 .63280 -.68813 to.55199 -.48780 page 1 Ba Be Ca PPM Ppm PPM .0794 .0002 10.48 .0001 .0001 .03 .1432 92.20 .2960 .0796 .0003 10.45 .0793 .0001 10.48 .0794 .0000 10.51 Fe K Mg PPM PPM PPM .0776 10.50 6.854 .0029 .07 .010 3.786 .6899 .1397 .0809 10.48 6.859 .0768 10.44 6.843 .0752 10.58 6.859 P 2203/1 2203/2 ppm ppb ppb .1676 17.277 -7.7610 .0065 1.528 .7954 3.886 8.8429 10.248 .1617 19.021 -8.6773 .1665 16.634 -7.3568 .1746 16.176 -7.2489 T11908 V Zn Ppb PPM PPM 1.8689 -.0004 .0110 1.8188 .0001 .0005 97.318 16.20 4.439 -.22707 -.0004 .0115 2.8022 -.0003 .0108 3.0314 -.0004 .0106 It 00 N O O H Analysis Report 06/14/05 12:29:49 PM page 1 Method: DVCLPI Sample Name: 0506329-007E Operator: CO Run Time: 06/14/05 12:21:07 �Y) SS C ent: _ M�: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1.3292 .0896 4.2535 .0992 .0807 -.0000 10.39 SDev .2462 .0059 1.2098 .0009 .0001 .0000 .01 %RSD 18.522 6.602 28.441 .8919 .1683 163.8 .1229 #1 1.1865 .0938 5.6483 .0999 .0808 -.0000 10.40 #2 1.1875 .0921 3.6238 .0982 .0807 -.0001 10.37 #3 1.6134 .0828 3.4886 .0995 .0806 -.0000 10.39 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0000 .0002 .0309 .0008 .0899 10.64 6.809 SDev .0002 .0002 .0004 .0003 .0003 .05 .008 %RSD 1621. 122.7 1.206 39.17 .2842 .5017 .1123 #1 .0001 .0004 .0313 .0011 .0900 10.69 6.816 #2 -.0002 .0001 .0306 .0005 .0901 10.66 6.801 #3 .0001 -.0000 .0309 .0008 .0896 10.58 6.809 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb e .6765 .0013 15.85 .0114 .1797 16.377 -7.9549 WD .0004 .0002 .11 .0008 .0023 .836 1.2903 .0586 12.62 .7233 7.153 1.305 5.1037 16.220 #1 .6770 .0011 15.95 .0106 .1772 17.341 -9.4086 #2 .6763 .0014 15.88 .0123 .1800 15.856 -7.5109 #3 .6763 .0014 15.73 .0114 .1818 15.933 -6.9453 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -2.5669 7.0049 -7.2505 .0044 -.03299 -.0006 .0161 SDev 1.3797 3.3168 .4603 .0008 2.06119 .0004 .0002 %RSD 53.749 47.350 6.3482 19.38 6247.7 65.17 1.020 #1 -1.5373 3.2369 -7.6525 .0053 -.12775 -.0004 .0159 #2 -4.1346 9.4829 -7.3504 .0042 -2.0452 -.0010 .0162 #3 -2.0289 8.2949 -6.7484 .0037 2.0739 -.0003 .0162 Elem Pb2203 Se1960 Units ppb ppb Avge .14800 -2.5030 SDev .59674 1.3189 %RSD 403.19 52.693 #1 -.50055 -4.0259 #2 .27072 -1.7445 40 .67385 -1.7386 W) 00 N O H Analysis Report 06/14/05 12:38:37 PM Method: DVCLPI Sample Name: 0506329-008E Operator: CO Run Time: 06/14/05 12:29:56 I-Aw, _6O C nt: M CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Units ppb ppm ppb ppm ppm ppm Avge 1.6151 .2928 5.4356 .0921 .0911 -.0000 SDev .0714 .0063 1.1705 .0015 .0008 .0000 %RSD 4.4186 2.167 21.535 1.624 .8451 165.9 #1 1.6157 .2992 4.5473 .0937 .0905 -.0000 #2 1.6862 .2927 6.7620 .0908 .0908 -.0000 #3 1.5435 .2865 4.9975 .0919 .0920 .0000 Elem Cd Co Cr Cu Fe K Units ppm ppm ppm ppm ppm ppm Avge .0001 .0009 .0353 .0024 .3246 10.11 SDev .0002 .0001 .0005 .0004 .0025 .03 %RSD 322.4 14.22 1.524 15.26 .7723 .2671 #1 -.0001 .0009 .0351 .0022 .3238 10.13 #2 .0002 .0010 .0348 .0022 .3227 10.08 #3 -.0000 .0008 .0359 .0028 .3275 10.13 Elem Mn Mo Na Ni P 2203/1 Units ppm ppm ppm ppm ppm ppb .6908 .0005 17.42 .0213 .1820 16.619 WDe .0063 .0005 .05 .0007 .0075 3.544 .9160 100.3 .2732 3.233 4.121 21.322 #1 .6876 .0009 17.47 .0212 .1734 14.264 #2 .6868 -.0000 17.38 .0207 .1857 14.898 #3 .6981 .0006 17.41 .0221 .1869 20.695 Elem Sb2068 1960/1 1960/2 Sn T11908 V Units ppb ppb ppb ppm ppb ppm Avge -2.3508 8.6351 -3.9283 .0043 1.8320 .0002 SDev 1.4044 5.4131 .1536 .0011 2.7544 .0001 %RSD 59.742 62.687 3.9104 26.33 150.35 71.15 #1 -.73438 4.1180 -4.0109 .0033 -1.2281 .0000 #2 -3.2720 14.635 -3.7510 .0055 2.6110 .0003 #3 -3.0461 7.1523 -4.0229 .0040 4.1130 .0002 Elem Pb2203 Se1960 Units ppb ppb Avge .68181 .25579 SDev 1.3849 1.9000 %RSD 203.12 742.80 #1 -.09685 -1.3036 #2 -.13850 2.3720 0 2.2808 -.30109 page 1 Ca ppm 10.68 .08 .7601 10.65 10.62 10.77 Mg PPM 7.403 .065 .8797 7.385 7.349 7.475 2203/2 ppb -7.2757 .3668 5.0409 -7.2675 -7.6465 -6.9131 Zn ppm .0200 .0003 1.338 .0199 .0199 .0203 00 N O E-+ Analysis Report 06/14/05 12:47:26 PM page 1 Method: DVCLPI Sample Name: 0506329-009E Operator: CO Run Time: 06/14/05 12:38:45 : Mw -GS Wnt CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1.5186 .2559 5.3757 .0839 .0894 -.0000 9.857 SDev .2898 .0033 1.0842 .0006 .0004 .0000 .027 %RSD 19.080 1.294 20.169 .6588 .4039 724.8 .2754 #1 1.6857 .2594 4.4057 .0845 .0898 -.0000 9.887 #2 1.6860 .2556 6.5462 .0837 .0892 -.0000 9.833 #3 1.1840 .2528 5.1752 .0834 .0891 .0000 9.851 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0001 .0011. .0316 .0033 .3520 9.438 7.000 SDev .0000 .0003 .0004 .0003 .0013 .086 .020 %RSD 4.643 30.99 1.202 9.949 .3585 .9121 .2808 #1 .0001 .0007 .0315 .0037 .3529 9.537 7.021 #2 .0002 .0013 .0320 .0033 .3506 9.384 6.982 #3 .0001 .0012 .0312 .0030 .3526 9.392 6.998 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Av a .6498 .0003 17.06 .0220 .1906 14.518 -4.2292 .0016 .0004 .10 .0004 .0040 .711 1.3247 .2458 108.5 .5916 1.825 2.107 4.8943 31.323 #1 .6516 -.0000 17.17 .0223 .1951 15.022 -2.7485 #2 .6486 .0004 16.99 .0222 .1874 14.827 -5.3020 #3 .6492 .0007 17.01 .0215 .1892 13.705 -4.6373 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -2.4826 11.922 -7.6877 .0043 4.2046 -.0001 .0232 SDev .6204 2.604 2.6179 .0015 2.3657 .0003 .0004 %RSD 24.992 21.842 34.054 34.20 56.263 527.0 1.668 #1 -1.8100 9.2747 -5.6500 .0040 4.2000 -.0003 .0232 #2 -2.6053 14.480 -10.640 .0060 1.8413 .0003 .0228 #3 -3.0325 12.010 -6.7728 .0031 6.5725 -.0002 .0236 Elem Pb2203 Se1960 Units ppb ppb Avge 2.0141 -1.1573 SDev 1.0012 .9710 %RSD 49.709 83.902 #1 3.1695 -.67957 #2 1.4016 -2.2746 16 1.4713 -.51772 r- 00 N O H Analysis Report 06/14/05 12:56:15 PM page 1 Method: DVCLPI Sample Name: 0506329-010E Operator: CO Run Time: 06/14/05 12:47:33 M CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1.1095 .1979 1.6766 .0907 .0849 -.0000 10.53 SDev .3194 .0029 1.5678 .0008 .0001 .0000 .02 %RSD 28.786 1.465 93.511 .9285 .0642 119.8 .1799 #1 .92535 .1946 2.8536 .0902 .0849 -.0000 10.51 #2 1.4783 .2001 2.2794 .0917 .0850 -.0000 10.55 #3 .92488 .1990 -.10314 .0903 .0849 .0000 10.53 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge -.0006 .0009 .0309 .0010 .2355 9.818 7.152 SDev .0014 .0001 .0002 .0004 .0028 .025 .035 %RSD 239.6 5.249 .5912 40.75 1.203 .2594 .4959 #1 .0002 .0010 .0311 .0014 .2373 9.789 7.174 #2 -.0022 .0010 .0308 .0006 .2322 9.830 7.111 #3 .0002 .0009 .0308 .0009 .2370 9.836 7.172 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Av e .6614 .0004 16.39 .0160 .2081 15.833 -7.4356 .0005 .0001 .09 .0001 .0032 2.924 .8744 .0812 20.14 .5581 .5241 1.555 18.465 11.759 #1 .6616 .0004 16.29 .0159 .2061 12.641 -6.5280 #2 .6618 .0005 16.41 .0160 .2119 16.478 -7.5063 #3 .6608 .0004 16.47 .0161 .2064 18.381 -8.2724 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -4.3508 11.564 -6.0532 .0041 3.6436 -.0002 .0164 SDev 2.5180 5.910 3.9985 .0020 1.9767 .0003 .0004 %RSD 57.875 51.107 66.055 48.32 54.253 172.6 2.273 #1 -5.6759 6.3696 -9.7932 .0053 2.7208 -.0004 .0161 #2 -1.4469 17.994 -6.5278 .0053 2.2970 .0001 .0162 #3 -5.9294 10.328 -1.8387 .0018 5.9130 -.0002 .0168 Elem Pb2203 Se1960 Units ppb ppb Avge .31353 -.18633 SDev .40104 3.66955 %RSD 127.91 1969.3 #1 -.14410 -4.4105 #2 .48097 1.6384 4) .60371 2.2132 00 00 N O 07 H Analysis Report 06/14/05 01:05:04 PM page 1 Method: DVCLPI Sample Name: 0506329-011E Operator: CO Run Time: 06/14/05 12:56:22y�_ s Cent: nt: M CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1.7575 .2750 6.3733 .0779 .0841 .0000 9.239 SDev .2602 .0033 .8453 .0003 .0001 .0000 .018 %RSD 14.804 1.197 13.264 .4536 .0567 81.09 .1896 #1 2.0462 .2778 7.2346 .0781 .0841 .0000 9.258 #2 1.5411 .2757 6.3404 .0775 .0841 .0000 9.223 #3 1.6852 .2714 5.5449 .0782 .0840 .0000 9.238 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0001 .0008 .0284 .0019 .3197 8.863 6.598 SDev .0001 .0002 .0001 .0000 .0009 .039 .004 %RSD 84.29 22.43 .4655 2.208 .2959 .4422 .0563 #1 .0001 .0010 .0285 .0018 .3208 8.893 6.600 #2 .0000 .0008 .0284 .0018 .3191 8.876 6.594 #3 .0002 .0007 .0283 .0019 .3193 8.819 6.601 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb A e .5955 .0005 16.67 .0193 .1738 15.495 -4.7179 .0009 .0005 .07 .0005 .0072 2.852 1.2813 D .1539 96.53 .4476 2.784 4.154 18.403 27.158 #1 .5962 -.0000 16.73 .0198 .1777 12.227 -4.9477 #2 .5945 .0007 16.70 .0187 .1654 17.476 -3.3372 #3 .5959 .0010 16.59 .0193 .1781 16.782 -5.8687 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -1.9380 7.5345 -6.1793 .0022 1.8737 .0001 .0171 SDev 1.6321 3.9523 1.0768 .0024 1.6754 .0005 .0004 %RSD 84.216 52.456 17.426 111.1 89.417 805.5 2.330 #1 -.33021 3.4182 -5.8061 .0043 2.1179 .0006 .0175 #2 -3.5934 11.299 -7.3931 -.0005 .08961 -.0001 .0171 #3 -1.8905 7.8862 -5.3388 .0028 3.4137 -.0004 .0168 Elem Pb2203 Se1960 Units ppb ppb Avge 2.0135 -1.6122 SDev 1.4412 .9785 %RSD 71.580 60.694 #1 .77185 -2.7339 #2 3.5940 -1.1681 0 1.6746 -.93445 00 N O V) F-4 Analysis Report 06/14/05 01:13:53 PM page 1 Method: DVCLPI Sample Name: 0506329-012E Operator: CO Run Time: 06/14/05 13:05:11 C Q9 r1,* - C ent: M CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1.5391 .0575 3.2913 .0029 .0003 -.0000 .0396 SDev .3118 .0086 .7303 .0003 .0000 .0000 .0018 %RSD 20.256 15.01 22.188 10.69 7.925 67.37 4.483 #1 1.6818 .0644 4.0117 .0026 .0003 -.0001 .0412 #2 1.7539 .0602 2.5515 .0031 .0003 -.0000 .0400 #3 1.1815 .0478 3.3106 .0032 .0002 -.0001 .0377 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge -.0002 -.0007 -.0007 -.0034 .0019 .0394 -.0003 SDev .0001 .0002 .0003 .0002 .0000 .0107 .0040 %RSD 42.18 24.50 36.80 5.561 2.200 27.09 1170. #1 -.0003 -.0009 -.0010 -.0036 .0019 .0468 -.0046 #2 -.0001 -.0008 -.0007 -.0032 .0019 .0441 .0002 #3 -.0003 -.0005 -.0004 -.0034 .0020 .0272 .0034 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb A* .0001 -.0003 .1590 -.0016 .0020 15.236 -6.8096 .0001 .0004 .0042 .0002 .0046 1.150 3.3589 157.3 146.8 2.619 14.47 230.9 7.5449 49.326 #1 .0002 -.0008 .1626 -.0016 -.0005 15.283 -3.1778 #2 .0001 -.0003 .1599 -.0018 .0073 16.360 -9.8044 #3 -.0001 .0001 .1544 -.0013 -.0008 14.063 -7.4465 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -2.9941 10.063 -4.0953 .0029 4.3722 -.0006 .0002 SDev 1.9002 3.859 5.1922 .0006 1.1873 .0002 .0002 %RSD 63.465 38.344 126.78 20.65 27.155 36.57 91.37 #1 -2.1414 13.336 1.7761 .0035 3.9968 -.0009 .0003 #2 -1.6697 5.8084 -8.0817 .0023 5.7018 -.0004 .0003 #3 -5.1713 11.046 -5.9801 .0028 3.4181 -.0006 -.0000 Elem Pb2203 Se1960 Units ppb ppb Avge .53196 .62006 SDev 2.1499 4.6118 %RSD 404.15 743.77 #1 2.9703 5.6260 #2 -1.0910 -3.4559 0 -.28341 -.30992 O O� N O Cn H Analysis Report 06/14/05 01:22:41 PM page 1 Method: DVCLPI Sample Name: MB -13797 Operator: CO Run Time: 06/14/05 13:14:00 R'�`b'r`Z (��k C ent : M�: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1.6098 .0406 4.4458 .0012 .0002 -.0001 -.0127 SDev .3290 .0018 .8753 .0008 .0000 .0000 .0010 %RSD 20.438 4.397 19.688 61.08 .0887 36.93 8.189 #1 1.5380 .0422 5.2239 .0010 .0002 -.0001 -.0116 #2 1.3226 .0409 3.4981 .0021 .0002 -.0000 -.0129 #3 1.9688 .0386 4.6153 .0006 .0002 -.0001 -.0136 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .2000 10.000 .0200 .2000 .0050 .2000 Low -10.000 -.2000 -10.000 -.0200 -.2000 -.0050 -.2000 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge -.0000 -.0009 -.0009 -.0028 .0013 .0345 -.0089 SDev .0001 .0004 .0001 .0003 .0003 .0034 .0033 %RSD 609.9 50.14 11.68 12.15 19.18 9.998 37.55 #1 .0001 -.0011 -.0008 -.0031 .0015 .0383 -.0078 #2 .0000 -.0004 -.0008 -.0029 .0010 .0333 -.0126 #3 -.0002 -.0011 -.0010 -.0024 .0014 .0318 -.0062 Mors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .0050 .0500 .0100 .0250 .1000 5.000 .2000 Low -.0050 -.0500 -.0100 -.0250 -.1000 -5.000 -.2000 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge -.0000 .0007 .0107 -.0011 .0006 16.825 -7.2081 SDev .0001 .0003 .0005 .0005 .0074 2.214 1.4235 %RSD 158.7 35.73 4.896 41.74 1206. 13.158 19.748 #1 -.0001 .0006 .0113 -.0015 -.0014 18.079 -5.6607 #2 -.0001 .0010 .0104 -.0012 .0088 18.126 -8.4618 #3 .0000 .0005. .0103 -.0006 -.0056 14.268 -7.5019 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High .0150 5.000 .0400 Low -.0150 -5.000 -.0400 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -2.2418 14.350 -3.8562 .0039 2.5617 -.0006 .0002 SDev 1.5131 5.417 .8439 .0006 1.2180 .0001 .0002 %RSD 67.494 37.752 21.885 15.73 47.544 12.26 90.96 -3.8128 8.1267 -2.8818 .0034 3.9148 -.0005 .0003 -.79423 18.010 -4.3311 .0039 2.2175 -.0005 .0003 # -2.1183 16.914 -4.3557 .0046 1.5529 -.0006 -.0000 Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass 4nalysis Report 06/14/05 01:22:41 PM page 2 High 60.000 L� -60.000 Elem Pb2203 Se1960 Units ppb ppb Avge .79527 2.2070 SDev 1.2963 1.2466 %RSD 163.00 56.483 #1 2.2452 .78449 #2 .39249 3.1089 #3 -.25183 2.7276 Errors LC Pass LC Pass High 3.0000 5.0000 Low -3.0000 -5.0000 • 10.000 .0500 -10.000 -.0500 .0200 -.0200 Analysis Report 06/14/05 01:31:31 PM page 1 Method: DVCLPI Sample Name: LCS-13797 Operator: CO Run Time: 06/14/05 13:22:49 Cent:MoCONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 988.57 50.72 505.28 2.482 2.565 2.508 50.66 SDev .56 .04 2.35 .007 .001 .001 .01 %RSD .05693 .0774 .46483 .2785 .0349 .0513 .0182 #1 988.15 50.68 506.40 2.476 2.564 2.507 50.65 #2 989.21 50.72 502.58 2.482 2.566 2.507 50.66 #3 988.34 50.76 506.86 2.489 2.565 2.509 50.67 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 1200.0 60.00 600.00 3.000 3.000 3.000 60.00 Low 800.00 40.00 400.00 2.000 2.000 2.000 40.00 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge 2.421 2.290 2.458 2.660 49.48 79.62 48.59 SDev .002 .008 .000 .004 .05 .13 .04 %RSD .0844 .3546 .0178 .1367 .0942 .1695 .0905 #1 2.423 2.299 2.458 2.656 49.53 79.71 48.59 #2 2.421 2.288 2.457 2.662 49.47 79.46 48.54 ## 2.419 2.283 2.458 2.663 49.44 79.68 48.63 E ors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 3.000 3.000 3.000 3.000 60.00 96.00 60.00 Low 2.000 2.000 2.000 2.000 40.00 64.00 40.00 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge 2.480 2.447 77.08 2.465 -.0076 502.58 510.66 SDev .001 .007 .11 .003 .0047 4.07 1.90 %RSD .0412 .2730 .1368 .1391 62.07 .80978 .37259 #1 2.479 2.440 77.14 2.461 -.0031 502.54 508.60 #2 2.480 2.447 77.14 2.467 -.0072 498.54 512.35 #3 2.481 2.453 76.96 2.467 -.0124 506.67 511.03 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High 3.000 96.00 3.000 Low 2.000 64.00 2.000 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge 1021.8 513.56 515.16 2.368 508.29 2.501 2.290 SDev 1.3 3.98 4.11 .004 9.74 .002 .004 M %RSD .12391 .77447 .79766 .1781 1.9156 .0638 .1659 1022.8 518.07 518.77 2.372 497.15 2.502 2.294 0 1020.4 512.08 510.69 2.364 515.21 2.502 2.286 � #3 1022.2 510.54 516.02 2.367 512.50 2.499 2.289 V) Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass 1--' Analysis Report 06/14/05 01:31:31 PM page 2 High 1200.0 I� 800.00 Elem Pb2203 Se1960 Units ppb ppb Avge 507.97 514.63 SDev 1.51 3.71 %RSD .29788 .72122 #1 506.58 518.54 #2 507.75 511.15 #3 509.58 514.20 Errors LC Pass LC Pass High 600.00 600.00 Low 400.00 400.00 • 600.00 3.000 400.00 2.000 3.000 2.000 knalysis Report 06/14/05 01:40:20 PM page 1 Method: DVCLPI Sample Name: 0506281-001E Operator: CO tun Time: 06/14/05 13:31:38 QA" -(SH' nt: 4 CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1.9222 .0845 6.0114 .0250 .5560 .0008 6.877 SDev .0414 .0073 1.2141 .0010 .0010 .0003 .018 %RSD 2.1536 8.630 20.197 4.024 .1813 42.30 .2647 #1 1.9700 .0914 6.9959 .0256 .5572 .0011 6.896 #2 1.8981 .0852 4.6547 .0254 .5554 .0009 6.875 #3 1.8986 .0769 6.3835 .0238 .5555 .0004 6.859 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0010 .0048 .0005 -.0024 .0255 3.815 7.478 SDev .0003 .0004 .0004 .0004 .0072 .020 .013 %RSD 36.07 9.180 92.42 18.02 28.17 .5137 .1724 #1 .0013 .0049 .0009 -.0020 .0324 3.836 7.490 #2 .0009 .0051 .0006 -.0022 .0260 3.812 7.479 #3 .0006 .0043 -.0000 -.0028 .0181 3.797 7.464 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb A#eA e 1.635 .0031 26.02 .0023 .1243 14.230 -5.8458 .004 .0024 .09 .0003 .0142 .983 1.8358 .2248 74.57 .3527 14.17 11.43 6.9100 31.404 #1 1.639 .0056 26.04 .0020 .1080 15.348 -3.7308 #2 1.633 .0029 26.10 .0026 .1338 13.841 -6.7797 #3 1.632 .0010 25.92 .0024 .1312 13.501 -7.0269 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -2.1192 10.220 -3.3051 .0050 2.6491 .0003 .0186 SDev 3.0668 4.233 3.4018 .0008 1.2693 .0005 .0006 %RSD 144.71 41.416 102.92 15.57 47.915 138.8 3.064 #1 .96155 10.740 .56647 .0051 3.5926 .0008 .0192 #2 -2.1475 14.169 -5.8153 .0042 1.2060 .0004 .0182 #3 -5.1718 5.7513 -4.6666 .0057 3.1486 -.0002 .0183 Elem Pb2203 Se1960 Units ppb ppb Avge .84000 1.1992 SDev 1.5504 2.5946 %RSD 184.58 216.36 ##1 2.6231 3.9548 ##2 .08744 .83981 0 -.19053 -1.1970 Analysis Report 06/14/05 01:49:09 PM page 1 Method: DVCLPI Sample Name: CCV3 Operator: CO Run Time: 06/14/05 13:40:27 C nt: . M CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1009.1 50.74 506.70 2.574 2.580 2.560 52.11 SDev .7 .08 2.61 .010 .005 .005 .05 %RSD .06670 .1620 .51459 .3884 .2053 .1974 .1009 #1 1009.2 50.82 507.74 2.586 2.586 2.556 52.15 #2 1009.7 50.73 508.62 2.571 2.580 2.560 52.05 #3 1008.3 50.66 503.73 2.567 2.575 2.566 52.14 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 1100.0 55.00 550.00 2.750 2.750 2.750 55.00 Low 900.00 45.00 450.00 2.250 2.250 2.250 45.00 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge 2.533 2.416 2.540 2.642 50.71 82.45 49.83 SDev .007 .031 .005 .013 .18 1.08 .05 %RSD .2620 1.273 .1862 .4893 .3523 1.313 .0909 #1 2.527 2.382 2.536 2.656 50.54 83.62 49.81 #2 2.532 2.424 2.538 2.640 50.70 82.26 49.79 2.540 2.442 2.545 2.630 50.90 81.48 49.88 Oors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 2.750 2.750 2.750 2.750 55.00 88.00 55.00 Low 2.250 2.250 2.250 2.250 45.00 72.00 45.00 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge 2.550 2.508 77.10 2.528 .0019 500.99 502.77 SDev .004 .001 .48 .012 .0069 5.86 1.80 %RSD .1578 .0458 .6201 .4926 356.5 1.1705 .35746 #1 2.548 2.509 77.54 2.542 .0095 503.94 503.83 #2 2.549 2.508 77.17 2.520 -.0042 504.80 500.70 #3 2.555 2.507 76.59 2.520 .0005 494.24 503.79 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High 2.750 88.00 2.750 Low 2.250 72.00 2.250 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge 1054.3 530.39 515.07 2.482 506.23 2.569 2.435 SDev 3.7 4.48 3.77 .006 3.85 .002 .012 110 %RSD .34942 .84402 .73171 .2278 .76013 .0823 .4885 1050.7 533.03 511.61 2.477 502.90 2.568 2.424 N 1058.0 532.92 519.09 2.482 505.35 2.568 2.434 O #3 1054.3 525.22 514.50 2.488 510.44 2.571 2.448 Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass Analysis Report 06/14/05 01:49:09 PM page 2 High 1100.0 900.00 Elem Pb2203 Se1960 Units ppb ppb Avge 502.18 520.17 SDev 1.63 3.07 %RSD .32444 .59019 #1 503.86 518.75 #2 502.06 523.69 #3 500.61 518.07 Errors LC Pass LC Pass High 550.00 550.00 Low 450.00 450.00 .7 • 550.00 2.750 450.00 2.250 2.750 2.250 knalysis Report 06/14/05 01:57:58 PM page 1 4ethod: DVCLPI Sample Name: CCB3 tun Time: 06/14/05 13:49:16 "o t: 4o CONC Corr. Factor: 1 Elem Ag Al As1890 Units ppb ppm ppb Avge 1.3327 .0450 3.4870 SDev .7334 .0156 2.4070 %RSD 55.031 34.63 69.027 #1 1.6833 .0546 5.9529 #2 1.8250 .0534 3.3647 #3 .48980 .0270 1.1436 Errors LC Pass LC Pass LC Pass High 10.000 .2000 10.000 Low -10.000 -.2000 -10.000 Elem Cd Co Cr Units ppm ppm ppm Avge .0003 -.0001 .0001 SDev .0009 .0006 .0002 %RSD 307.4 426.3 151.6 #1 .0012 .0003 .0002 #2 -.0007 .0001 -.0001 # .0004 -.0008 .0003 Er ors LC Pass LC Pass LC Pass High .0050 .0500 .0100 Low -.0050 -.0500 -.0100 Elem Mn Mo Na Units ppm ppm ppm Avge .0008 .0043 .1372 SDev .0003 .0028 .0124 %RSD 36.01 65.58 9.071 #1 .0010 .0076 .1512 #2 .0009 .0032 .1331 #3 .0005 .0023 .1274 Errors LC Pass NOCHECK LC Pass High .0150 .0056 5.000 Low -.0150 401.9 -5.000 Elem Sb2068 1960/1 1960/2 Units ppb ppb ppb Avge .48906 9.9653 -3.2758 SDev 3.0350 3.4826 .6670 %RSD 620.59 34.947 20.361 3.6255 9.0853 -2.9482 0 27491 13.804 -4.0432 #3 -2.4332 7.0071 -2.8359 NOCHECK Errors LC Pass NOCHECK Operator: CO B Ba Be Ca ppm ppm ppm ppm .0058 .0009 .0007 .0118 .0027 .0003 .0002 .0075 47.08 34.97 31.94 63.71 .0086 .0011 .0008 .0174 .0057 .0010 .0007 .0147 .0031 .0005 .0004 .0033 LC Pass LC Pass LC Pass LC Pass .0200 .2000 .0050 .2000 -.0200 -.2000 -.0050 -.2000 Cu Fe K Mg ppm ppm ppm ppm -.0021 .0144 .0291 -.0063 .0002 .0058 .0570 .0334 9.545 40.11 196.0 531.2 -.0020 .0210 .0600 .0190 -.0020 .0121 .0639 -.0441 -.0023 .0101 -.0367 .0063 LC Pass LC Pass LC Pass LC Pass .0250 .1000 5.000 .2000 -.0250 -.1000 -5.000 -.2000 Ni P 2203/1 2203/2 ppm ppm ppb ppb -.0002 .0001 15.384 -7.4714 .0008 .0056 1.566 .6115 401.9 7916. 10.179 8.1852 .0007 .0060 17.047 -7.7683 -.0008 -.0051 15.169 -6.7681 -.0005 -.0007 13.937 -7.8778 LC Pass NOCHECK NOCHECK NOCHECK .0400 -.0400 Sn T11908 V Zn ppm ppb ppm ppm .0032 4.1260 .0000 .0001 .0030 1.2538 .0001 .0002 O0 92.81 30.388 2349. 221.7 01 .0047 4.5405 .0002 -.0000 0 .0051 5.1201 -.0001 -.0000 -.0002 2.7175 -.0001 .0003 NOCHECK LC Pass LC Pass LC Pass F'' analysis Report 06/14/05 01:57:58 PM page 2 High 60.000 -60.000 Elem Pb2203 Se1960 Units ppb ppb Avge .14006 1.1340 SDev .65245 .7318 %RSD 465.83 64.537 #1 .49565 1.0594 #2 .53748 1.9002 #3 -.61294 .44227 Errors LC Pass LC Pass High 3.0000 5.0000 Low -3.0000 -5.0000 • C. 10.000 .0500 -10.000 -.0500 .0200 -.0200 Analysis Report 06/14/05 02:06:47 PM page 1 Method: DVCLPI Sample Name: 0506281-001EDUP Operator: CO Run Time: 06/14/05 13:58:05 C nt: M CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1.6820 .0862 4.2402 .0248 .6049 .0003 7.618 SDev .6386 .0077 .8212 .0001 .0005 .0002 .003 %RSD 37.964 8.905 19.368 .5429 .0849 51.03 .0345 #1 1.3871 .0913 5.1853 .0247 .6051 .0005 7.620 #2 2.4147 .0898 3.7005 .0249 .6052 .0003 7.615 #3 1.2442 .0773 3.8347 .0250 .6043 .0002 7.619 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0002 .0047 -.0000 -.0028 .0211 4.154 8.079 SDev .0004 .0002 .0004 .0001 .0039 .024 .009 %RSD 153.5 4.392 1231. 5.024 18.70 .5743 .1101 #1 .0006 .0048 .0003 -.0027 .0256 4.160 8.089 #2 -.0001 .0049 .0001 -.0028 .0190 4.174 8.077 #3 .0003 .0045 -.0004 -.0030 .0187 4.128 8.071 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb 1.762 .0012 27.85 .0027 .1265 15.052 -5.4952 WD .000 .0008 .22 .0009 .0064 2.087 2.1553 .0169 64.24 .8023 33.36 5.026 13.865 39.222 #1 1.762 .0019 27.74 .0037 .1241 13.634 -3.1776 #2 1.762 .0012 28.11 .0027 .1217 17.448 -5.8685 #3 1.761 .0004 27.71 .0018 .1337 14.073 -7.4395 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -1.2588 9.5117 -2.0976 .0030 1.9039 -.0002 .0505 SDev 1.6869 2.7700 1.9210 .0016 .5731 .0003 .0004 %RSD 134.01 29.122 91.582 52.13 30.102 130.7 .7433 #1 .23663 7.8079 -1.1749 .0030 2.4174 .0001 .0508 #2 -.92565 12.708 -4.3058 .0046 1.2856 -.0003 .0505 #3 -3.0874 8.0193 -.81198 .0015 2.0086 -.0005 .0501 Elem Pb2203 Se1960 Units ppb ppb Avge 1.3475 1.7688 SDev 1.4296 .3868 %RSD 106.09 21.866 #1 2.4213 1.8168 #2 1.8966 1.3602 40 -.27521 2.1293 Analysis Report 06/14/05 02:15:36 PM Method: DVCLPI Sample Name: 0506281-001EMS Operator: CO Run Time: 06/14/05 14:06:55 �o`�v - OtacrisOS- 2Arn -l?FF nr► S C : M�ent : CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Units ppb ppm ppb ppm ppm ppm Avge 47.660 2.160 43.444 .0245 2.707 .0521 SDev .224 .005 2.095 .0002 .001 .0001 %RSD .47046 .2282 4.8218 .8213 .0212 .2433 #1 47.887 2.165 41.098 .0243 2.707 .0522 #2 47.439 2.155 45.126 .0245 2.706 .0519 #3 47.653 2.160 44.109 .0247 2.707 .0522 Elem Cd Co Cr Cu Fe K Units ppm ppm ppm ppm ppm ppm Avge .0507 .4673 .2025 .2666 1.019 4.035 SDev .0002 .0015 .0006 .0005 .001 .007 %RSD .3064 .3311 .3082 .1947 .1027 .1777 #1 .0509 .4656 .2022 .2660 1.019 4.041 #2 .0507 .4685 .2021 .2670 1.018 4.036 #3 .0506 .4679 .2032 .2668 1.020 4.027 Elem Units Av e v OD #1 #2 #3 Elem Units Avge SDev %RSD #1 #2 #3 Elem Units Avge SDev %RSD #1 #2 �J Mn ppm 2.276 .003 .1433 2.276 2.273 2.279 Sb2068 ppb 514.86 2.13 .41452 516.22 512.40 515.95 Pb2203 ppb 21.786 .771 3.5406 22.219 20.895 22.243 Mo PPM .0007 .0005 71.45 .0011 .0002 .0007 1960/1 ppb 23.501 1.395 5.9342 24.984 23.303 22.216 Se1960 ppb 12.430 .349 2.8053 12.672 12.030 12.587 Na ppm 27.69 .15 .5471 27.67 27.85 27.55 1960/2 ppb 6.9017 .7629 11.053 6.5242 6.4012 7.7797 Ni ppm .5148 .0023 .4491 .5163 .5121 .5159 Sn ppm .0033 .0016 47.64 .0027 .0051 .0021 P ppm .1407 .0016 1.115 .1423 .1392 .1407 T11908 ppb 49.840 1.390 2.7885 49.725 51.284 48.511 2203/1 ppb 35.660 .826 2.3170 35.556 34.890 36.533 V ppm .5082 .0014 .2664 .5071 .5078 .5098 page 1 Ca ppm 7.478 .010 .1288 7.483 7.466 7.483 Mg ppm 8.127 .006 .0785 8.128 8.119 8.132 2203/2 ppb 14.858 .854 5.7465 15.559 13.907 15.108 Zn ppm .4932 .0012 .2395 .4919 .4936 .4941 knalysis Report 06/14/05 02:24:26 PM page 1 Method: DVCLPI Sample Name: 0506281-001ESD Operator: CO tun Time: 06/14/05 14:15:44 &gw0-Cwd05-(L"-cFF so --ant: MCONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1.6813 .0513 5.3840 .0061 .1126 .0000 1.382 SDev .1258 .0075 1.2036 .0005 .0007 .0000 .002 %RSD 7.4827 14.53 22.355 8.747 .5816 833.2 .1337 ##1 1.6081 .0598 4.3583 .0059 .1134 .0000 1.383 ##2 1.6092 .0457 5.0846 .0067 .1124 .0000 1.380 #3 1.8266 .0485 6.7090 .0057 .1121 -.0000 1.383 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm PPM Avge .0001 .0007 -.0003 -.0032 .0019 .7308 1.487 SDev .0001 .0002 .0000 .0003 .0005 .0104 .004 %RSD 139.6 33.41 .5052 8.040 25.09 1.429 .2690 #1 -.0000 .0005 -.0003 -.0035 .0024 .7427 1.483 #2 .0000 .0006 -.0003 -.0031 .0016 .7235 1.487 #3 .0002 .0010 -.0003 -.0030 .0016 .7261 1.491 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb e .3309 .0010 5.649 -.0007 .0239 15.972 -5.9564 .0002 .0001 .058 .0003 .0019 2.349 .6881 % D .0713 15.55 1.029 36.55 7.932 14.706 11.552 #1 .3311 .0011 5.716 -.0010 .0256 15.793 -6.2469 #2 .3306 .0008 5.614 -.0005 .0218 18.405 -6.4515 #3 .3309 .0010 5.615 -.0007 .0242 13.717 -5.1707 Elem Sb2068 1960/1. 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -1.3078 9.3780 -4.4539 .0036 2.8153 -.0004 .0030 SDev .6222 4.0457 2.8322 .0005 2.6067 .0003 .0002 %RSD 47.571 43.141 63.589 14.36 92.590 79.67 7.113 #1 -.59930 9.8177 -7.7200 .0032 5.7021 -.0000 .0031 #2 -1.5594 13.186 -2.9655 .0042 2.1099 -.0006 .0028 #3 -1.7649 5.1304 -2.6763 .0035 .63390 -.0005 .0031 Elem Pb2203 Se1960 Units ppb ppb Avge 1.3462 .15261 SDev .4158 2.1555 %RSD 30.887 1412.5 #1 1.0929 -1.8794 #2 1.8260 2.4134 0 1.1195 -.07619 Analysis Report Method: DVCLPI Sample Name: CRIF Run Time: 06/14/05 14:24:34 .0001 C nt: .4511 177.3 .0101 M CONC Corr. Factor: 1 .0005 Elem Ag Al As1890 Units ppb ppm ppb Avge 20.734 .0581 24.028 SDev .320 .0113 .878 %RSD 1.5436 19.48 3.6538 #1 21.045 .0512 24.884 #2 20.752 .0519 24.071 #3 20.405 .0711 23.129 Elem Cd Co Cr Units ppm ppm ppm Avge .0106 .0951 .0194 SDev .0000 .0011 .0005 %RSD .3365 1.152 2.418 #1 .0105 .0959 .0197 #2 .0106 .0956 .0195 #3 .0106 .0939 .0188 Elem Mn Mo Na Units ppm ppm ppm A e .0300 .0298 .0263 .0002 .0004 .0013 % .5489 1.492 4.922 #1 .0302 .0303 .0275 #2 .0300 .0295 .0266 #3 .0299 .0295 .0249 Elem Sb2068 1960/1 1960/2 Units ppb ppb ppb Avge 125.18 21.433 5.9203 SDev 1.34 4.772 1.3056 %RSD 1.0741 22.263 22.054 #1 125.19 22.911 5.5696 #2 123.84 16.097 7.3654 #3 126.53 25.291 4.8258 Elem Pb2203 Se1960 Units ppb ppb Avge 8.1586 11.086 SDev 2.0964 .719 %RSD 25.695 6.4891 #1 7.0269 11.345 #2 6.8712 10.274 0 10.578 11.641 06/14/05 02:33:16 PM Operator: CO B ppm .2072 .0027 1.327 .2043 .2075 .2098 Cu ppm .0475 .0005 1.116 .0481 .0475 .0470 Ni PPM .0811 .0010 1.263 .0809 .0802 .0822 Sn PPM .0813 .0008 .9438 .0810 .0822 .0808 Ba PPM .0004 .0001 27.47 .0005 .0003 .0003 Fe ppm -.0004 .0002 47.34 -.0007 -.0003 -.0003 P ppm -.0006 .0016 273.7 -.0010 .0012 -.0020 T11908 ppb 22.501 4.761 21.160 25.549 17.014 24.940 page 1 Be Ca PPM ppm .0102 .0004 .0001 .0008 .4511 177.3 .0101 .0012 .0102 .0005 .0101 -.0004 K PPM .0400 .0054 13.63 .0438 .0424 .0337 2203/1 ppb 24.321 2.227 9.1557 25.201 21.788 25.973 V PPM .0989 .0004 .4344 .0993 .0984 .0990 Mg PPM -.0035 .0024 68.23 -.0014 -.0030 -.0062 2203/2 ppb .08883 2.5354 2854.1 -2.0472 -.57692 2.8907 Zn PPM .0393 .0005 1.314 .0392 .0389 .0399 Analysis Report 06/14/05 02:42:05 PM page 1 Method: DVCLPI Sample Name: ICSAF Operator: CO Run Time: 06/14/05 14:33:23 C ent: M�: CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm Ppb ppm Ppm Ppm ppm Avge 1.5039 536.8 5.2220 .0096 .0015 .0002 534.2 SDev .4256 .3 3.4852 .0005 .0001 .0000 %RSD 28.298 .0597 66.741 4.911 4.180 6.130 .2 .0414 #1 1.8226 536.9 9.0175 .0100 .0015 .0002 534.5 #2 1.0206 537.1 2.1656 .0091 .0015 .0002 534.0 #3 1.6686 536.5 4.4829 .0098 .0014 .0002 534.3 Errors LC Pass LC Pass NOCHECK NOCHECK LC Pass LC Pass LC Pass High 10.000 600.0 .2000 .0050 600.0 Low -10.000 400.0 -.2000 -.0050 400.0 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0015 .0006 .0036 -.0021 200.4 .0359 535.1 SDev .0004 .0006 .0007 .0002 .2 .0129 %RSD 28.34 94.45 18.99 10.76 .1149 36.04 .3 .0575 #1 .0013 -.0000 .0040 -.0019 200.5 .0506 535.0 #2 .0013 .0008 .0040 -.0020 200.2 .0310 534.9 lo .0021 .0011 .0028 -.0023 200.7 .0262 535.5 ors LC Pass NOCHECK LC Pass NOCHECK LC Pass NOCHECK LC Pass High .0050 .0100 240.0 600.0 Low -.0050 -.0100 160.0 400.0 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge .0086 -.0011 .0263 .0037 .0211 -25.391 14.628 SDev .0001 .0010 .0016 .0Q05 .0085 2.663 .902 %RSD .6790 98.19 5.953 13.42 40.23 10.489 6.1675 #1 .0086 -.0020 .0277 .0042 .0153 -22.700 14.543 #2 .0087 .0001 .0267 .0035 .0308 -28.025 13.771 #3 .0086 -.0013 .0246 .0033 .0172 -25.447 15.569 Errors LC Pass NOCHECK NOCHECK LC Pass NOCHECK NOCHECK NOCHECK High .0150 .0400 Low -.0150 -.0400 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge 8.1966 9.3967 .33770 -.0068 -8.5291 .0050 .0050 SDev 3.3369 2.7786 5.0439 .0039 2.7904 .0002 .0004 %RSD 40.710 29.570 1493.6 57.51 32.716 4.675 7.058 11.769 12.595 -3.1536 -.0023 -5.3335 .0052 .0051 5.1604 8.0173 -1.9538 -.0087 L-10.484 .0048 .0047 #3 7.6604 7.5777 6.1205 -.0095 -9.7700 .0048 .0054 Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass Analysis Report 06/14/05 02:42:05 PM page 2 Elem Pb2203 Se1960 Units ppb ppb Avge 1.3021 3.3549 SDev 1.2600 2.8390 %RSD 96.764 84.621 #1 2.1418 2.0913 #2 -.14669 1.3672 #3 1.9114 H6.6063 Errors LC Pass LC Pass High 6.0000 5.0000 Low -6.0000 -5.0000 is • 10.000 .0500 -10.000 -.0500 .0200 -.0200 O N O CD cn H Analysis Report 06/14/05 02:50:54 PM page 1 Method: DVCLPI Sample Name: ICSABF Operator: CO Run Time: 06/14/05 14:42:13 C ent: M CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1100.6 536.0 1028.3 1.090 .5502 .5120 525.0 SDev .5 1.2 4.1 .005 .0011 .0003 .8 %RSD .04900 .2263 .39743 .4585 .2060 .0514 .1581 #1 1101.2 537.3 1033.0 1.092 .5509 .5122 525.9 #2 1100.2 535.9 1025.4 1.093 .5508 .5117 524.7 #3 1100.4 534.8 1026.6 1.084 .5489 .5121 524.3 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 1200.0 600.0 1200.0 1.200 .6000 .6000 600.0 Low 800.00 400.0 800.00 .8000 .4000 .4000 400.0 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .9788 .4464 .5160 .5931 197.6 .0297 528.4 SDev .0004 .0042 .0011 .0021 .2 .0051 .5 %RSD .0446 .9411 .2214 .3607 .1144 17.18 .1012 #1 .9789 .4432 .5173 .5941 197.5 .0295 529.0 #2 .9783 .4448 .5151 .5946 197.4 .0247 528.3 # .9791 .4511 .5158 .5907 197.8 .0349 528.0 ors LC Pass LC Pass LC Pass LC Pass LC Pass NOCHECK LC Pass High 1.200 .6000 .6000 .6000 240.0 600.0 Low .8000 .4000 .4000 .4000 160.0 400.0 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge .5274 1.015 .0206 1.005 .0087 979.60 1059.8 SDev .0005 .003 .0008 .006 .0039 4.83 4.5 %RSD .0879 .3232 3.742 .6104 44.40 .49294 .42794 #1 .5269 1.016 .0208 1.010 .0054 985.17 1064.1 #2 .5274 1.018 .0197 1.007 .0130 977.08 1060.2 #3 .5278 1.012 .0212 .9984 .0078 976.55 1055.0 Errors LC Pass NOCHECK NOCHECK LC Pass NOCHECK NOCHECK NOCHECK High .6000 1.200 Low .4000 .8000 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge 4.8833 1013.9 1042.0 .9649 989.45 .5259 .8987 O SDev 2.3319 9.0 6.6 .0037 4.53 .0003 .0030 %RSD 47.752 .88930 .63371 .3889 .45824 .0488 .3321 3.2028 1004.5 1049.6 .9674 984.38 .5261 .8954 CD 3.9015 1022.4 1038.6 .9667 993.11 .5259 .9013 p #3 7.5455 1014.9 1037.7 .9606 990.86 .5256 .8994 Errors NOCHECK NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass Analysis Report 06/14/05 02:50:54 PM page 2 High 1200.0 .6000 1.200 LO 800.00 .4000 .8000 Elem Pb2203 Se1960 Units ppb ppb Avge 1033.1 1032.6 SDev 4.5 2.3 %RSD .43317 .22038 #1 1037.8 1034.6 #2 1032.5 1033.2 #3 1028.9 1030.1 Errors LC Pass LC Pass High 1200.0 1200.0 Low 800.00 800.00 • • Analysis Report 06/14/05 02:59:44 PM page 1 Method: DVCLPI Sample Name: CCV4 Operator: CO Run Time: 06/14/05 14:51:02 Co nt Mc CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1010.6 51.06 509.39 2.592 2.603 2.564 52.47 SDev 1.1 .06 3.15 .008 .004 .004 .06 %RSD .11107 .1253 .61897 .2899 .1389 .1642 .1150 #1 1011.6 51.13 509.05 2.590 2.606 2.560 52.40 #2 1010.9 51.01 512.70 2.586 2.599 2.568 52.52 #3 1009.4 51.02 506.42 2.601 2.602 2.566 52.49 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 1100.0 55.00 550.00 2.750 2.750 2.750 55.00 Low 900.00 45.00 450.00 2.250 2.250 2.250 45.00 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge 2.531 2.382 2.546 2.671 50.58 82.19 50.03 SDev .004 .011 .003 .005 .08 .71 .05 %RSD .1509 .4462 .1006 .1918 .1658 .8690 .0957 #1 2.528 2.380 2.543 2.675 50.54 83.01 50.01 #2 2.536 2.393 2.548 2.665 50.67 81.70 50.08 #3 2.530 2.372 2.545 2.674 50.52 81.86 49.99 Efrs LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 2.750 2.750 2.750 2.750 55.00 88.00 55.00 Low 2.250 2.250 2.250 2.250 45.00 72.00 45.00 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge 2.553 2.525 77.25 2.546 .0002 501.45 506.45 SDev .001 .004 .18 .006 .0086 2.89 1.89 %RSD .0449 .1770 .2291 .2481 5018. .57589 .37390 #1 2.552 2.520 77.04 2.542 -.0087 498.64 508.14 #2 2.554 2.527 77.32 2.543 .0008 501.31 506.82 #3 2.552 2.529 77.37 2.554 .0084 504.41 504.41 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High 2.750 88.00 2.750 Low 2.250 72.00 2.250 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge 1062.3 524.34 519.97 2.483 506.37 2.579 2.421 00 SDev 1.5 6.96 4.96 .007 6.66 .001 .005 p %RSD .14352 1.3269 .95326 .2621 1.3160 .0459 .2007 ^' 1062.9 529.58 525.29 2.479 501.52 2.579 2.418 NO 1060.5 516.45 519.15 2.490 513.97 2.581 2.427 O #3 1063.3 527.00 515.48 2.479 503.61 2.579 2.419 ,..a V) Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass F-' Analysis Report 06/14/05 02:59:44 PM page 2 High 1100.0 Oem 900.00 Pb2203 Se1960 Units ppb ppb Avge 504.79 521.43 SDev .33 4.61 %RSD .06537 .88474 #1 504.98 526.72 #2 504.98 518.25 #3 504.41 519.32 Errors LC Pass LC Pass High 550.00 550.00 Low 450.00 450.00 lJ 550.00 2.750 450.00 2.250 2.750 2.250 Analysis Report 06/14/05 03:08:34 PM page 1 Method: DVCLPI Sample Name: CCB4 Operator: CO Run Time: 06/14/05 14:59:52 C ent: : CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1.6097 .1055 4.3605 .0067 .0008 .0006 .0299 SDev .1251 .0017 2.8828 .0013 .0001 .0001 .0100 %RSD 7.7690 1.622 66.112 19.25 13.97 22.30 33.33 #1 1.5383 .1044 4.2178 .0079 .0009 .0007 .0388 #2 1.7541 .1047 1.5517 .0068 .0008 .0006 .0317 #3 1.5367 .1075 7.3121 .0053 .0007 .0004 .0191 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .2000 10.000 .0200 .2000 .0050 .2000 Low -10.000 -.2000 -10.000 -.0200 -.2000 -.0050 -.2000 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0007 -.0003 -.0004 -.0036 .0216 .0549 .0280 SDev .0002 .0006 .0003 .0006 .0057 .0029 .0071 %RSD 33.66 210.3 68.96 17.77 26.23 5.385 25.49 #1 .0008 -.0008 -.0006 -.0030 .0270 .0581 .0354 #2 .0008 -.0004 -.0004 -.0035 .0222 .0523 .0273 O.0004 .0003 -.0001 -.0043 .0157 .0543 .0212 tors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .0050 .0500 .0100 .0250 .1000 5.000 .2000 Low -.0050 -.0500 -.0100 -.0250 -.1000 -5.000 -.2000 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge .0006 .0048 .0361 -.0007 -.0046 14.940 -6.3538 SDev .0002 .0029 .0056 .0007 .0016 2.811 2.0158 %RSD 34.58 61.58 15.40 88.46 35.75 18.815 31.726 #1 .0008 .0080 .0417 -.0001 -.0062 14.721 -7.7943 #2 .0005 .0041 .0360 -.0006 -.0047 12.245 -4.0502 #3 .0004 .0022 .0305 -.0015 -.0029 17.853 -7.2169 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High .0150 5.000 .0400 Low -.0150 -5.000 -.0400 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -.74169 12.837 -6.8848 .0050 5.2518 -.0001 -.0002 SDev 2.25566 4.488 4.0928 .0008 1.7552 .0005 .0004 %RSD 304.12 34.963 59.446 15.79 33.422 409.8 164.2 1.7508 18.012 -5.8793 .0054 5.7156 .0004 -.0000 0 -2.6426 10.497 -11.387 .0054 6.7286 -.0006 -.0000 #3 -1.3333 10.002 -3.3885 .0041 3.3112 -.0002 -.0007 Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass Analysis Report 06/14/05 03:08:34 PM page 2 High 60.000 0 -60.000 Elem Pb2203 Se1960 Units ppb ppb Avge .73738 -.31695 SDev .90354 3.31354 %RSD 122.53 1045.4 #1 -.29634 2.0769 #2 1.3765 -4.0988 #3 1.1320 1.0710 Errors LC Pass LC Pass High 3.0000 5.0000 Low -3.0000 -5.0000 • • 10.000 .0500 -10.000 -.0500 .0200 -.0200 Analysis Report 06/14/05 03:17:23 PM Method: DVCLPI Sample Name: 0506094-001A Run Time: 06/14/05 15:08:42 ZZZZ�-Z C nt: .0005 .0001 .0001 .0001 . M CONC Corr. Factor: 1 9.850 17.083 Elem Ag Al As1890 B Units ppb ppm ppb ppm Avge 1.7060 .1069 6.0582 .0057 SDev .5098 .0058 1.1276 .0006 %RSD 29.886 5.461 18.613 9.919 #1 1.1738 .1136 7.3481 .0063 #2 2.1901 .1028 5.2595 .0058 #3 1.7540 .1044 5.5671 .0052 Elem Cd Co Cr Cu Units ppm ppm ppm ppm Avge .0000 -.0005 .0010 -.0038 SDev .0002 .0004 .0004 .0001 %RSD 479.7 70.06 38.79 2.370 #1 .0003 -.0002 .0010 -.0039 #2 .0001 -.0004 .0015 -.0037 #3 -.0002 -.0009 .0007 -.0039 Elem Mn Mo Na Ni Units ppm ppm ppm ppm h'Imain .0002 .0017 4.603 -.0005 WD .0002 .0003 .012 .0005 74.23 17.65 .2608 108.3 #1 .0004 .0020 4.616 -.0001 #2 .0001 .0014 4.601 -.0011 #3 .0001 .0017 4.592 -.0002 Elem Sb2068 1960/1 1960/2 Sn Units ppb ppb ppb ppm Avge -2.7554 13.035 -8.1553 .0034 SDev 1.3181 1.412 1.4926 .0020 %RSD 47.837 10.832 18.303 58.59 #1 -2.5661 12.761 -9.8788 .0057 #2 -1.5422 11.781 -7.2851 .0018 #3 -4.1580 14.564 -7.3020 .0028 Elem Pb2203 Se1960 Units ppb ppb Avge .54360 -1.0983 SDev 1.6083 1.1681 %RSD 295.86 106.36 #1 -1.1074 -2.3392 #2 2.1055 -.93568 0 .63266 -.02002 Operator: CO Ba Be PPM ppm .0005 .0001 .0001 .0001 15.11 65.81 .0006 .0002 .0006 .0001 .0004 .0001 Fe K ppm ppm .0101 11.53 .0024 .03 23.82 .3001 .0127 11.56 .0095 11.52 .0080 11.49 P 2203/1 ppm ppb 9.850 17.083 .021 1.219 .2131 7.1337 9.855 15.841 9.868 18.277 9.827 17.132 T11908 V ppb ppm 2.9333 -.0007 .8199 .0004 27.953 56.77 3.7358 -.0009 2.0970 -.0003 2.9670 -.0011 page 1 Ca ppm .0347 .0051 14.61 .0404 .0331 .0306 Mg ppm .0100 .0043 43.07 .0132 .0116 .0051 2203/2 ppb -7.7146 1.8029 23.370 -9.5695 -5.9687 -7.6055 Zn ppm -.0003 .0000 .4064 -.0003 -.0003 -.0003 N r-+ (V O O C/1 N knalysis Report 06/14/05 03:26:35 PM page 1 Kethod: DVCLPI Sample Name: MB -13827 Operator: CO Run Time: 06/14/05 15:17:54 .iLLZZZ nt: Ko CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1.5572 .0778 4.2069 .0024 .0002 .0000 -.0157 SDev .2989 .0103 .8742 .0002 .0001 .0000 .0005 %RSD 19.192 13.24 20.779 7.182 30.68 307.8 3.271 ##1 1.8290 .0887 5.0740 .0024 .0001 .0001 -.0163 ##2 1.6056 .0763 3.3258 .0025 .0002 -.0000 -.0152 #3 1.2372 .0683 4.2210 .0022 .0002 -.0000 -.0157 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .2000 10.000 .0200 .2000 .0050 .2000 Low -10.000 -.2000 -10.000 -.0200 -.2000 -.0050 -.2000 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0001 -.0005 -.0013 -.0043 .0046 .0348 -.0045 SDev .0002 .0001 .0002 .0002 .0006 .0046 .0017 %RSD 350.1 28.90 19.20 5.515 13.56 13.09 37.52 #1 .0001 -.0004 -.0014 -.0045 .0052 .0393 -.0028 #2 .0002 -.0006 -.0010 -.0042 .0047 .0350 -.0061 -.0002 -.0004 -.0013 -.0041 .0039 .0302 -.0045 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .0050 .0500 .0100 .0250 .1000 5.000 .2000 Low -.0050 -.0500 -.0100 -.0250 -.1000 -5.000 -.2000 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge -.0001 .0003 .0096 -.0013 .0004 15.464 -7.2083 SDev .0001 .0002 .0014 .0007 .0043 1.455 1.2132 %RSD 46.69 64.36 14.96 55.41 1114. 9.4078 16.831 #1 -.0001 .0004 .0110 -.0007 -.0010 16.346 -8.5258 #2 -.0002 .0004 .0097 -.0011 .0052 13.785 -6.1372 #3 -.0002 .0001 .0082 -.0021 -.0031 16.261 -6.9620 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High .0150 5.000 .0400 Low -.0150 -5.000 -.0400 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb Ppb Ppb Ppm Ppb Ppm ppm Avge -.64006 7.0621 -7.3356 .0038 1.9090 -.0007 -.0003 SDev 2.45430 7.1721 2.4165 .0003 2.6860 .0003 .0000 %RSD 383.45 101.56 32.942 9.190 140.70 36.14 1.793 -3.1627 15.327 -5.1365 .0034 -1.0383 -.0005 -.0003 (Vo 1.7396 2.4712 -6.9478 .0040 2.5461 -.0010 -.0003 0 #3 -.49708 3.3883 -9.9226 .0041 4.2193 -.0006 -.0003 Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass �' Analysis Report 06/14/05 03:26:35 PM page 2 High 60.000 (Ow -60.000 em Pb2203 Se1960 Units ppb ppb Avge .34195 -2.5407 SDev .52483 3.7489 %RSD 153.48 147.55 #1 -.24299 1.6782 #2 .49725 -3.8108 #3 .77161 L-5.4896 Errors LC Pass LC Pass High 3.0000 5.0000 Low -3.0000 -5.0000 • • 10.000 .0500 -10.000 -.0500 .0200 -.0200 Analysis Report Method: DVCLPI Sample Name: LCS-13827 Run Time: 06/14/05 15:26:43 ZZZzzL CMent: : CONC Corr. Factor: 1 06/14/05 03:35:25 PM Operator: CO Elem Ag Al As1890 B Units ppb ppm ppb ppm Avge 1033.3 52.15 530.87 2.623 SDev 4.2 .26 2.22 .007 %RSD .40973 .4895 .41911 .2568 #1 1037.6 #2 1033.2 #3 1029.1 Errors LC Pass High 1200.0 Low 800.00 Elem Cd Units ppm Avge 2.619 SDev .004 %RSD .1509 #1 2.623 #2 2.619 # 2.615 ors LC Pass High 3.000 Low 2.000 Elem Mn Units ppm Avge 2.612 SDev .007 %RSD .2523 #1 2.619 #2 2.610 #3 2.606 Errors LC Pass High 3.000 Low 2.000 Elem Sb2068 Units ppb Avge 1112.8 SDev 3.9 %RSD .34600 1116.7 10 1112.7 1109.0 52.43 52.09 51.93 LC Pass 60.00 40.00 Co ppm 2.403 .005 .2265 2.406 2.396 2.406 LC Pass 3.000 2.000 Mo ppm 2.632 .006 .2288 2.634 2.636 2.625 NOCHECK 1960/1 ppb 526.63 3.25 .61625 523.94 525.72 530.23 532.34 531.96 528.31 LC Pass 600.00 400.00 Cr ppm 2.618 .008 .2897 2.626 2.617 2.611 LC Pass 3.000 2.000 Na ppm 78.72 .40 .5102 79.18 78.54 78.44 LC Pass 96.00 64.00 1960/2 ppb 529.68 3.64 .68771 529.34 526.23 533.49 Errors LC Pass NOCHECK NOCHECK 2.628 2.627 2.616 LC Pass 3.000 2.000 Cu ppm 2.733 .015 .5473 2.748 2.734 2.718 LC Pass 3.000 2.000 Ni ppm 2.652 .007 .2562 2.658 2.652 2.644 LC Pass 3.000 2.000 Sn ppm 2.586 .005 .1896 2.591 2.587 2.581 NOCHECK Ba ppm 2.622 .015 .5550 2.636 2.622 2.607 LC Pass 3.000 2.000 Fe ppm 52.47 .11 .2082 52.59 52.44 52.37 LC Pass 60.00 40.00 P ppm -.0016 .0039 251.9 -.0014 -.0055 .0023 NOCHECK T11908 ppb 526.80 3.22 .61127 526.18 530.29 523.94 LC Pass Be ppm 2.690 .005 .2040 2.696 2.688 2.685 LC Pass 3.000 2.000 K ppm 79.79 .92 1.148 80.79 79.58 79.00 LC Pass 96.00 64.00 2203/1 ppb 527.47 3.36 .63688 529.96 523.65 528.79 NOCHECK V ppm 2.630 .009 .3494 2.640 2.629 2.622 LC Pass page 1 Ca ppm 55.02 .15 .2773 55.18 54.99 54.88 LC Pass 60.00 40.00 Mg ppm 51.76 .19 .3727 51.97 51.73 51.59 LC Pass 60.00 40.00 2203/2 ppb 534.70 3.87 .72435 533.60 531.50 539.01 NOCHECK Zn ppm 2.530 .003 .1228 2.532 2.527 2.532 LC Pass Analysis Report 06/14/05 03:35:25 PM page 2 Hi h 1200.0 800.00 Elem Pb2203 Se1960 Units ppb ppb Avge 532.29 528.67 SDev 3.36 3.32 %RSD .63150 .62805 #1 532.39 527.54 #2 528.89 526.06 #3 535.61 532.40 Errors LC Pass LC Pass High 600.00 600.00 Low 400.00 400.00 • • 600.00 3.000 400.00 2.000 3.000 2.000 Analysis Report 06/14/05 03:44:15 PM page 1 Method: DVCLPI Sample Name: LCS1-13827 Run Time: 06/14/05 15:35:33-ZZZZ;Zz C ent: MW CONC Corr. Factor: 1 Elem Ag Al As1890 B Units ppb ppm ppb ppm Avge 1064.8 53.82 549.39 2.744 SDev 3.4 .03 3.47 .013 %RSD .31478 .0574 .63102 .4766 #1 1068.6 53.79 551.70 2.729 #2 1062.2 53.85 545.41 2.752 #3 1063.7 53.81 551.08 2.752 Errors LC Pass LC Pass LC Pass LC Pass High 1200.0 60.00 600.00 3.000 Low 800.00 40.00 400.00 2.000 Elem Cd Co Cr Cu Units ppm ppm ppm ppm Avge 2.712 2.429 2.700 2.831 SDev .006 .036 .002 .008 %RSD .2107 1.501 .0572 .2849 #1 2.718 2.471 2.701 2.822 #2 2.707 2.411 2.698 2.836 2.711 2.406 2.700 2.836 ,*ors LC Pass LC Pass LC Pass LC Pass High 3.000 3.000 3.000 3.000 Low 2.000 2.000 2.000 2.000 Elem Mn Mo Na Ni Units ppm ppm ppm ppm Avge 2.691 2.735 81.51 2.767 SDev .004 .009 .24 .016 %RSD .1477 .3376 .2885 .5913 #1 2.695 2.724 81.78 2.748 #2 2.688 2.739 81.39 2.777 #3 2.688 2.741 81.35 2.776 Errors LC Pass NOCHECK LC Pass LC Pass High 3.000 96.00 3.000 Low 2.000 64.00 2.000 Elem Sb2068 1960/1 1960/2 Sn Units ppb ppb ppb ppm Avge 1150.1 553.35 556.68 2.665 SDev 3.0 7.36 3.78 .008 %RSD .26069 1.3308 .67906 .2833 1147.0 547.18 552.32 2.674 1152.9 551.37 558.64 2.660 #3 1150.3 561.50 559.07 2.663 Errors LC Pass NOCHECK NOCHECK NOCHECK Operator: CO Ba Be ppm ppm 2.700 2.780 .002 .004 .0762 .1607 2.698 2.785 2.702 2.777 2.700 2.777 LC Pass 3.000 2.000 Fe ppm 53.90 .23 .4260 54.17 53.81 53.74 LC Pass 60.00 40.00 P ppm -.0086 .0022 25.76 -.0068 -.0111 -.0080 T11908 ppb 553.28 4.73 .85523 548.45 553.50 557.90 LC Pass LC Pass 3.000 2.000 K ppm 82.82 .27 .3230 82.59 82.75 83.11 LC Pass 96.00 64.00 2203/1 ppb 549.90 5.50 .99967 544.37 555.36 549.96 Q101W.We"t V ppm 2.707 .003 .1139 2.711 2.706 2.705 LC Pass Ca ppm 56.95 .04 .0780 56.90 56.97 56.99 LC Pass 60.00 40.00 Mg ppm 53.44 .03 .0512 53.47 53.43 53.42 LC Pass 60.00 40.00 2203/2 ppb 564.68 2.50 .44222 561.81 565.88 566.35 NOCHECK Zn ppm 2.615 .007 �+ .2774 2.624 NO 2.610 O 2.612 LC Pass Analysis Report 06/14/05 03:44:15 PM page 2 Hi h 1200.0 T 800.00 Elem Pb2203 Se1960 Units ppb ppb Avge 559.76 555.57 SDev 3.34 4.67 %RSD .59592 .84071 #1 556.00 550.61 #2 562.38 556.22 #3 560.89 559.88 Errors LC Pass LC Pass High 600.00 600.00 Low 400.00 400.00 • • 600.00 3.000 400.00 2.000 3.000 2.000 Analysis Report 06/14/05 03:53:05 PM Method: DVCLPI Sample Name: 0506264-002A Run Time: 06/14/05 15:44:23 .4830 ZZZZz.z� .4687 C ent: Co PPM ppm .0011 .0008 M CONC Corr. Factor: 1 50.23 56.98 Elem Ag Al As1890 B Ba Units ppb ppm ppb ppm ppm Avge 2.1501 .4829 4.9357 .0408 .0107 SDev .1867 .0142 .1005 .0014 .0006 %RSD 8.6820 2.934 2.0355 3.330 5.255 #1 #2 #3 Elem Units Avge SDev %RSD #1 #2 #3 Elem Units e v ID #1 #2 #3 Elem Units Avge SDev %RSD #1 #2 #3 Elem Units Avge SDev %RSD #1 #2 f� 2.1259 .4970 2.3477 .4830 1.9767 .4687 Cd Co PPM ppm .0011 .0008 .0005 .0004 50.23 56.98 .0016 .0010 .0011 .0011 .0005 .0003 Mn ppm .0045 .0006 13.27 .0052 .0044 .0040 Sb2068 ppb 1.6555 1.4533 87.791 .41749 3.2556 1.2932 Pb2203 ppb 4.0727 .7287 17.891 4.9037 3.5432 3.7712 Mo ppm .0051 .0027 53.78 .0082 .0041 .0030 1960/1 ppb 16.299 3.230 19.816 12.678 17.337 18.883 Se1960 ppb 1.6861 .6052 35.895 1.0461 2.2492 1.7631 4.9604 4.8252 5.0216 Cr ppm .0041 .0008 18.83 .0044 .0047 .0032 Na PPM 41.47 .20 .4740 41.59 41.58 41.25 1960/2 ppb -5.6103 1.0500 18.715 -4.7621 -5.2842 -6.7847 .0424 .0402 .0399 Cu ppm .0260 .0003 1.078 .0263 .0258 .0259 Ni ppm .0057 .0018 31.32 .0074 .0060 .0038 Sn ppm .0088 .0004 4.426 .0092 .0088 .0084 .0112 .0106 .0101 Fe ppm .1763 .0119 6.754 .1890 .1745 .1654 P ppm 22.40 .08 .3719 22.47 22.42 22.31 T11908 ppb 2.9430 .3108 10.561 3.2668 2.6470 2.9153 Operator: CO page 1 Be Ca ppm ppm .0010 8.960 .0006 .030 60.10 .3379 .0016 8.988 .0009 8.965 .0004 8.928 K ppm 12.68 .10 .7937 12.79 12.67 12.59 2203/1 ppb 21.228 1.718 8.0932 21.010 23.044 19.629 V ppm .0008 .0005 64.44 .0012 .0010 .0002 Mg PPM 2.112 .015 .6901 2.128 2.108 2.100 2203/2 ppb -4.4927 1.5569 34.653 -3.1380 -6.1935 -4.1466 Zn ppm .2893 .0006 .2040 .2898 .2894 .2887 N O F Analysis Report 06/14/05 04:01:55 PM Method: DVCLPI Sample Name: 0506264-003A Run Time: 06/14/05 15:53:13 2ZZzz-L- ent : : CONC Corr. Factor: 1 Elem Ag Al As1890 B Units ppb ppm ppb ppm Avge 1.6598 .2339 4.0515 .0623 SDev .4037 .0143 2.3658 .0013 %RSD 24.324 6.113 58.394 2.111 #1 2.1243 .2474 6.1081 .0633 #2 1.4624 .2355 4.5804 .0628 #3 1.3928 .2189 1.4660 .0608 Elem Cd Co Cr Cu Units ppm ppm ppm ppm Avge .0001 -.0018 .0022 .0083 SDev .0001 .0030 .0022 .0016 %RSD 90.52 168.6 101.3 19.90 #1 .0001 -.0001 .0032 .0086 #2 .0000 -.0053 -.0004 .0065 #3 .0003 -.0000 .0036 .0098 Elem Mn Mo Na Ni Units ppm ppm ppm ppm e .0051 .0008 11.00 .0000 v .0004 .0018 .17 .0010 D 7.657 212.5 1.557 2194. #1 .0053 .0029 11.16 .0006 #2 .0047 -.0005 11.02 -.0011 #3 .0054 .0002 10.82 .0007 Elem Sb2068 1960/1 1960/2 Sn Units ppb ppb ppb ppm Avge -5.3669 11.033 -.68776 .0050 SDev 5.6187 3.989 2.28264 .0014 %RSD 104.69 36.149 331.90 29.07 #1 -.22576 15.080 -1.8509 .0055 #2 -11.365 10.914 1.9422 .0060 #3 -4.5101 7.1059 -2.1545 .0033 Elem Pb2203 Se1960 Units ppb ppb Avge 2.4140 3.2159 SDev 1.0179 2.0607 %RSD 42.165 64.079 #1 1.8434 3.7877 #2 3.5892 4.9303 10 1.8095 .92964 Operator: CO Ba ppm .0138 .0001 .9947 .0139 .0138 .0136 Fe PPM .1148 .0012 1.007 .1161 .1144 .1140 P PPM 5.021 .034 .6761 5.045 5.036 4.982 T11908 ppb 1.1589 1.1355 97.982 1.9235 1.6991 -.14586 Be PPM -.0000 .0001 554.7 .0001 -.0001 .0000 K PPM 2.600 .060 2.319 2.663 2.594 2.543 2203/1 ppb 15.492 2.330 15.038 14.106 18.182 14.189 V ppm .0003 .0011 352.4 .0010 -.0010 .0009 page 1 Ca PPM 4.939 .023 .4678 4.959 4.945 4.914 Mg ppm .5846 .0069 1.184 .5919 .5781 .5837 2203/2 ppb -4.1162 .3658 8.8862 -4.2798 -3.6972 -4.3716 Zn PPM .1857 .0018 .9648 .1872 .1837 .1861 Analysis Report 06/14/05 04:10:44 PM Method: DVCLPI Sample Name: 0506264-004A Operator: CO Run Time: 06/14/05 16:02:03 ZLZLLZ C ent: ppm ppm ppm .0229 : CONC Corr. Factor: 1 .0000 .14 Elem Ag Al As1890 B Units ppb ppm ppb ppm Avge 1.4975 .7420 7.0580 .0842 SDev .2913 .0098 .7502 .0003 %RSD 19.454 1.321 10.629 .3936 #1 1.1859 .7325 6.9661 .0840 #2 1.7631 .7412 7.8499 .0846 #3 1.5437 .7521 6.3580 .0841 Elem Cd Co Cr Cu Units ppm ppm ppm ppm Avge .0003 .0005 .0021 .0348 SDev .0002 .0004 .0002 .0005 %RSD 66.51 91.06 11.24 1.489 #1 .0005 -.0000 .0019 .0342 #2 .0003 .0006 .0021 .0352 #3 .0001 .0008 .0024 .0351 Elem Mn Mo Na Ni Units ppm ppm ppm ppm Av e .0943 .0015 4.772 .0026 .0008 .0004 .039 .0007 .8693 29.40 .8078 26.69 #1 .0934 .0019 4.728 .0031 #2 .0950 .0016 4.791 .0030 #3 .0944 .0010 4.799 .0018 Elem Sb2068 1960/1 1960/2 Sn Units ppb ppb ppb ppm Avge -1.4512 11.268 -4.2022 .0042 SDev .8291 2.312 .9275 .0005 %RSD 57.133 20.514 22.071 12.55 #1 -1.8773 11.179 -3.9642 .0038 #2 -1.9806 13.623 -5.2256 .0040 #3 -.49568 9.0029 -3.4170 .0048 Elem Pb2203 Se1960 Units ppb ppb Avge 14.231 .94998 SDev .833 .20024 %RSD 5.8530 21.078 #1 14.346 1.0790 #2 15.001 1.0516 #41 13.347 .71931 page 1 Ba Be Ca ppm ppm ppm .0229 .0000 17.86 .0002 .0000 .14 .9680 59.91 .7872 .0226 .0000 17.70 .0230 .0000 17.91 .0230 .0001 17.96 Fe K Mg ppm ppm ppm .9129 .9890 2.599 .0080 .0129 .029 .8804 1.303 1.110 .9036 .9749 2.566 .9169 .9920 2.620 .9181 1.000 2.610 P 2203/1 2203/2 ppm ppb ppb .2108 27.076 7.8173 .0046 2.057 2.2759 2.175 7.5986 29.113 .2130 26.819 8.1173 .2055 25.159 9.9284 .2138 29.249 5.4063 T11908 V Zn Ppb PPM PPM 2.0896 .0035 .1455 3.1939 .0002 .0021 152.84 4.715 1.445 .39964 .0033 .1442 .09587 .0036 .1444 5.7734 .0036 .1479 Analysis Report Method: DVCLPI Sample Name: MB -13826 Run Time: 06/14/05 16:10:52 ZZ -Z -t2 -Z C ent: M CONC Corr. Factor: 1 El A 06/14/05 04:19:34 PM page 1 em g Al As1890 B Units ppb ppm ppb ppm Avge 1.5586 .0987 4.7606 .0023 SDev .3585 .0145 1.2813 .0002 %RSD 23.003 14.65 26.915 9.641 #1 1.9704 #2 1.3902 #3 1.3153 Errors LC Pass High 10.000 Low -10.000 Elem Cd Units ppm Avge -.0000 SDev .0002 %RSD 661.7 #1 -.0001 #2 -.0001 #3 .0002 *rs LC Pass High .0050 Low -.0050 Elem Mn Units ppm Avge .0001 SDev .0001 %RSD 82.91 #1 .0001 #2 .0000 #3 .0000 Errors LC Pass High .0150 Low -.0150 Elem Sb2068 Units ppb Avge -3.6269 SDev 2.7957 %RSD 77.083 # -6.8413 -1.7607 # -2.2788 Errors LC Pass .0823 3.6538 .0021 .1045 6.1642 .0024 .1094 4.4637 .0025 LC Pass .2000 -.2000 Co ppm -.0007 .0003 41.73 -.0004 -.0007 -.0011 LC Pass .0500 -.0500 Mo ppm .0006 .0003 53.35 .0009 .0003 .0005 NOCHECK 1960/1 ppb 6.6486 3.5850 53.920 9.4815 2.6182 7.8462 NOCHECK LC Pass 10.000 -10.000 Cr ppm -.0003 .0002 86.34 -.0002 -.0005 -.0001 LC Pass .0100 -.0100 Na ppm .0210 .0017 8.033 .0197 .0229 .0204 LC Pass 5.000 -5.000 1960/2 ppb -6.2652 2.1089 33.661 -3.9902 -6.6504 -8.1549 NOCHECK LC Pass .0200 -.0200 Cu ppm -.0052 .0004 8.102 -.0047 -.0054 -.0055 LC Pass .0250 -.0250 Ni ppm -.0008 .0007 82.25 -.0002 -.0008 -.0015 LC Pass .0400 -.0400 Sn ppm .0030 .0009 29.61 .0023 .0041 .0028 NOCHECK Operator: CO Ba Be Ca ppm Ppm Ppm .0002 -.0000 -.0045 .0001 .0000 .0044 23.68 102.8 97.69 .0003 -.0001 -.0032 .0002 -.0000 -.0009 .0002 -.0000 -.0095 LC Pass .2000 -.2000 Fe ppm .0052 .0007 13.33 .0051 .0059 .0045 LC Pass .1000 -.1000 P ppm .0018 .0051 274.0 .0021 .0068 -.0033 NOCHECK T11908 ppb 4.3375 2.3083 53.217 2.8891 3.1240 6.9994 LC Pass LC Pass .0050 -.0050 K ppm .0441 .0126 28.55 .0542 .0480 .0300 LC Pass 5.000 -5.000 2203/1 ppb 17.631 .683 3.8740 17.699 16.916 18.277 NOCHECK V ppm -.0008 .0001 16.95 -.0006 -.0009 -.0009 LC Pass LC Pass .2000 -.2000 Mg ppm .0052 .0057 109.6 -.0014 .0084 .0085 LC Pass .2000 -.2000 2203/2 ppb -7.8882 1.1507 14.588 -9.1772 -7.5228 -6.9645 NOCHECK Zn ppm -.0001 .0002 184.1 -.0003 .0000 .0000 LC Pass Analysis Report 06/14/05 04:19:34 PM page 2 High 60.000 -60.000 em Pb2203 Units ppb Avge .61011 SDev .83420 %RSD 136.73 #1 -.22695 #2 .61584 #3 1.4414 Errors LC Pass High 3.0000 Low -3.0000 • • Se1960 ppb -1.9644 2.1627 110.10 .49633 -3.5635 -2.8261 LC Pass 5.0000 -5.0000 10.000 .0500 -10.000 -.0500 .0200 -.0200 • Se1960 ppb -1.9644 2.1627 110.10 .49633 -3.5635 -2.8261 LC Pass 5.0000 -5.0000 10.000 .0500 -10.000 -.0500 .0200 -.0200 Analysis Report Method: DVCLPI Sample Name: LCS-13826 Run Time: 06/14/05 16:19:42 Z.Z2Z7-7- C ent: : CONC Corr. Factor: 1 Ele A 06/14/05 04:28:24 PM Operator: CO m 9 Al As1890 B Units ppb ppm ppb ppm Avge 1032.1 52.91 533.48 2.686 SDev 1.0 .11 3.01 .011 %RSD .10015 .2110 .56439 .4230 #1 1032.3 #2 1030.9 #3 1033.0 Errors LC Pass High 1200.0 Low 800.00 Elem Cd Units ppm Avge 2.603 SDev .002 %RSD .0789 #1 2.605 #2 2.602 #3 2.601 Oors LC Pass High 3.000 Low 2.000 Elem Mn Units ppm Avge 2.603 SDev .002 %RSD .0730 #1 2.605 #2 2.602 #3 2.601 Errors LC Pass High 3.000 Low 2.000 Elem Sb2068 Units ppb Avge 1134.0 SDev 5.4 %RSD .47392 # 1139.9 1132.7 # 1129.4 53.04 52.82 52.87 LC Pass 60.00 40.00 Co ppm 2.291 .011 .4803 2.279 2.292 2.301 LC Pass 3.000 2.000 Mo ppm 2.665 .003 .1268 2.669 2.663 2.664 NOCHECK 1960/1 ppb 541.05 1.88 .34826 542.13 542.15 538.88 534.38 535.93 530.12 LC Pass 600.00 400.00 Cr ppm 2.614 .004 .1459 2.618 2.612 2.612 LC Pass 3.000 2.000 Na ppm 80.31 .28 .3541 80.63 80.14 80.15 LC Pass 96.00 64.00 1960/2 ppb 539.92 6.99 1.2943 547.98 535.55 536.23 Errors LC Pass NOCHECK NOCHECK 2.699 2.678 2.681 LC Pass 3.000 2.000 Cu ppm 2.790 .009 .3350 2.801 2.783 2.787 LC Pass 3.000 2.000 Ni ppm 2.705 .015 .5572 2.723 2.699 2.694 LC Pass 3.000 2.000 Sn ppm 2.566 .005 .2028 2.568 2.571 2.561 NOCHECK Ba ppm 2.663 .008 .2826 2.671 2.658 2.659 LC Pass 3.000 2.000 Fe ppm 51.83 .05 .1033 51.86 51.77 51.87 LC Pass 60.00 40.00 P ppm .0036 .0047 128.3 .0027 .0087 -.0005 NOCHECK T11908 ppb 529.84 8.67 1.6358 520.98 538.30 530.25 LC Pass Be ppm 2.672 .002 .0651 2.672 2.670 2.673 LC Pass 3.000 2.000 K ppm 83.31 .59 .7032 83.98 82.90 83.04 LC Pass 96.00 64.00 2203/1 ppb 532.78 2.37 .44525 535.51 531.18 531.66 NOCHECK V ppm 2.626 .001 .0533 2.627 2.627 2.624 LC Pass page 1 Ca ppm 55.18 .07 .1180 55.25 55.15 55.13 LC Pass 60.00 40.00 Mg ppm 51.78 .05 .0993 51.84 51.75 51.76 LC Pass 60.00 40.00 2203/2 ppb 551.09 2.13 .38573 553.33 549.10 550.83 NOCHECK Zn ppm 2.491 .001 .0440 2.490 2.492 2.491 LC Pass Analysis Report 06/14/05 04:28:24 PM page 2 High 1200.0 Ofem 800.00 Pb2203 Se1960 Units ppb ppb Avge 544.99 540.30 SDev 2.18 4.98 %RSD .40046 .92109 #1 547.40 546.03 #2 543.13 537.75 #3 544.45 537.11 Errors LC Pass LC Pass High 600.00 600.00 Low 400.00 400.00 • r L J 600.00 3.000 400.00 2.000 3.000 2.000 Analysis Report 06/14/05 04:37:13 PM Method: DVCLPI Sample Name: LCS1-13826 Operator: CO Run Time: 06/14/05 16:28:32 ZZZZZz ent: : CONC Corr. Factor: 1 Elem Ag Al As1890 B Units ppb ppm ppb ppm Avge 976.94 49.34 499.82 2.509 SDev 1.44 .11 6.08 .016 %RSD .14785 .2142 1.2174 .6342 #1 978.53 49.44 506.21 2.523 #2 975.71 49.34 499.16 2.513 #3 976.59 49.23 494.10 2.492 Errors LC Pass LC Pass LC Pass LC Pass High 1200.0 60.00 600.00 3.000 Low 800.00 40.00 400.00 2.000 Elem Cd Co Cr Cu Units ppm ppm ppm ppm Avge 2.430 2.141 2.424 2.604 SDev .007 .014 .004 .008 %RSD .2995 .6752 .1538 .3069 #1 2.438 #2 2.429 #3 2.424 Gors LC Pass High 3.000 Low 2.000 Elem Mn Units ppm Avge 2.418 SDev .004 %RSD .1855 #1 2.423 #2 2.417 #3 2.414 Errors LC Pass High 3.000 Low 2.000 Elem Sb2068 Units ppb Avge 1051.4 SDev 4.8 %RSD .45746 1056.0 fo 1051.7 1046.4 Errors LC Pass 2.133 2.133 2.158 LC Pass 3.000 2.000 Mo ppm 2.477 .011 .4621 2.485 2.481 2.464 NOCHECK 1960/1 ppb 500.22 4.34 .86824 498.92 505.06 496.67 NOCHECK 2.429 2.422 2.422 LC Pass 3.000 2.000 Na ppm 74.86 .42 .5666 75.33 74.75 74.50 LC Pass 96.00 64.00 1960/2 ppb 515.21 .59 .11446 515.83 515.15 514.65 NOCHECK 2.610 2.606 2.595 LC Pass 3.000 2.000 Ni ppm 2.492 .018 .7061 2.507 2.497 2.473 LC Pass 3.000 2.000 Sn ppm 2.388 .006 .2410 2.395 2.383 2.388 NOCHECK Ba ppm 2.489 .006 .2321 2.494 2.491 2.483 LC Pass 3.000 2.000 Fe ppm 48.19 .02 .0475 48.22 48.17 48.19 LC Pass 60.00 40.00 P ppm -.0060 .0108 179.5 .0053 -.0071 -.0163 NOCHECK T11908 ppb 497.42 4.24 .85213 499.80 492.52 499.93 LC Pass Be ppm 2.496 .004 .1649 2.500 2.495 2.492 LC Pass 3.000 2.000 K ppm 77.39 .78 1.002 78.10 77.52 76.56 LC Pass 96.00 64.00 2203/1 ppb 493.90 3.47 .70241 497.74 492.96 491.00 NOCHECK V ppm 2.445 .004 .1685 2.450 2.443 2.442 LC Pass page 1 Ca ppm 51.05 .21 .4178 51.28 51.02 50.86 LC Pass 60.00 40.00 Mg ppm 48.04 .12 .2588 48.16 48.04 47.91 LC Pass 60.00 40.00 2203/2 ppb 508.14 3.30 .64932 511.94 506.52 505.96 NOCHECK Zn ppm 2.313 .005 .2230 2.318 2.310 2.309 LC Pass Analysis Report 06/14/05 04:37:13 PM page 2 High 1200.0 Oem800.00 Pb2203 Units ppb Avge 503.40 SDev 3.34 %RSD .66362 #1 507.21 #2 502.00 #3 500.98 Errors LC Pass High 600.00 Low 400.00 C • Se1960 ppb 510.22 1.56 .30638 510.20 511.79 508.67 LC Pass 600.00 400.00 600.00 3.000 400.00 2.000 3.000 2.000 N N O F-4 Analysis Report 06/14/05 04:46:03 PM page 1 Method: DVCLPI Sample Name: CCVS Operator: CO Run Time: 06/14/05 16:37:21 C ent: : CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1008.4 51.59 512.70 2.641 2.625 2.568 52.64 SDev 1.8 .04 .99 .003 .003 .004 %RSD .18192 .0721 .19315 .1169 .1084 .1694 .05 .0873 #1 1008.5 51.62 511.79 2.641 2.629 2.571 52.69 #2 1010.2 51.55 513.75 2.637 2.625 2.570 52.63 #3 1006.5 51.59 512.57 2.644 2.623 2.563 52.60 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 1100.0 55.00 550.00 2.750 2.750 2.750 55.00 Low 900.00 45.00 450.00 2.250 2.250 2.250 45.00 Elem Cd. Co Cr Cu Fe K Mg Units ppm Ppm Ppm Ppm Ppm Ppm Ppm Avge 2.514 2.293 2.538 2.718 49.98 83.25 49.94 SDev .004 .007 .003 .005 .04 .51 %RSD .1713 .2944 .1042 .1746 .0862 .6078 .04 .0846 #1 2.518 2.290 2.540 2.723 50.03 83.83 49.98 #2 2.513 2.301 2.539 2.715 49.98 82.94 49.93 #3 2.510 2.288 2.535 2.716 49.94 82.97 49.90 Sors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 2.750 2.750 2.750 2.750 55.00 88.00 55.00 Low 2.250 2.250 2.250 2.250 45.00 72.00 45.00 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge 2.539 2.552 78.11 2.578 -.0022 502.68 515.43 SDev .002 .002 .24 .003 .0099 3.80 4.60 %RSD .0886 .0948 .3030 .1148 451.7 .75581 .89165 #1 2.540 2.554 78.39 2.581 .0081 498.71 519.71 #2 2.541 2.550 78.01 2.577 -.0030 503.05 510.58 #3 2.536 2.551 77.95 2.575 -.0116 506.29 515.99 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High 2.750 88.00 2.750 Low 2.250 72.00 2.250 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge 1066.8 525.01 530.12 2.475 511.68 2.571 2.394 SDev 5.5 1.42 3.97 .004 6.10 .002 .005 %RSD .51866 .27003 .74916 .1651 1.1923 .0693 .2112 # 1062.1 525.49 533.54 2.471 504.68 2.572 2.392 1072.9 526.12 525.76 2.479 515.88 2.571 2.400 # 1065.3 523.41 531.05 2.474 514.47 2.569 2.390 Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass 00 N N O O H Analysis Report 06/14/05 04:46:03 PM page 2 High 1100.0 Oerm 900.00 Pb2203 Units ppb Avge 511.18 SDev 2.70 %RSD .52749 #1 512.72 #2 508.07 #3 512.76 Errors LC Pass High 550.00 Low 450.00 • • Se1960 ppb 528.42 2.49 .47124 530.86 525.88 528.51 LC Pass 550.00 450.00 550.00 2.750 450.00 2.250 2.750 2.250 Analysis Report 06/14/05 04:54:53 PM page 1 Method: DVCLPI Sample Name: CCBS Run Time: 06/14/05 16:46:11 ment: Cr Cu : CONC Corr. Factor: 1 Elem Ag Al As1890 Units ppb ppm ppb Avge 1.6273 .1367 5.4035 SDev .3079 .0077 .5630 %RSD 18.919 5.607 10.419 #1 1.4499 .1287 5.7317 #2 1.4492 .1440 4.7534 #3 1.9828 .1375 5.7253 Errors LC Pass LC Pass LC Pass High 10.000 .2000 10.000 Low -10.000 -.2000 -10.000 Elem Cd Units ppm Avge .0011 SDev .0004 %RSD 37.65 #1 .0015 #2 .0010 #3 .0007 hors LC Pass High .0050 Low -.0050 Elem Mn Units ppm Avge .0007 SDev .0003 %RSD 35.31 #1 .0009 #2 .0008 #3 .0004 Errors LC Pass High .0150 5.000 Low -.0150 -5.000 Elem Sb2068 Units ppb ppb ppb Avge -.72314 SDev 2.54579 %RSD 352.05 Operator: CO B Ba ppm ppm ppm ppm Co Cr Cu .0090 .0010 .0019 .0003 21.44 31.19 .0111 .0014 .0088 .0009 .0072 .0008 LC Pass LC Pass .0200 .2000 -.0200 -.2000 Co Cr Cu Fe ppm ppb ppm ppm .0051 2.4694 .0002 .0004 .0015 1.0086 .0005 .0000 28.62 40.843 294.6 .7542 LC Pass LC Pass .0500 .0100 -.0500 Mo Na ppm ppm .0056 .0499 0024 .0107 44.14 44.127 -.0100 94.575 2.0970 7.1800 -.74863 -1.4147 13.554 -2.1200 -2.8517 18.788 -6.2948 NOCHECK 21.54 .0083 .0604 .0047 .0504 .0036 .0389 NOCHECK LC Pass 1960/1 1960/2 13.174 -3.0545 5.813 2.8888 Errors LC Pass NOCHECK LC Pass .0250 -.0250 Ni ppm .0001 .0007 494.9 .0008 -.0007 .0003 LC Pass .0400 -.0400 LC Pass .1000 -.1000 P ppm -.0023 .0072 311.7 -.0007 .0039 -.0102 NOCHECK Be ppm .0008 .0003 32.81 .0011 .0009 .0005 LC Pass .0050 -.0050 K ppm .0601 .0141 23.42 .0750 .0582 .0470 LC Pass 5.000 -5.000 2203/1 ppb 14.782 3.177 21.495 16.211 11.141 16.994 NOCHECK Ca ppm .0115 .0059 50.64 .0171 .0121 .0054 LC Pass .2000 -.2000 Mg ppm .0097 .0059 60.99 .0159 .0041 .0092 LC Pass .2000 -.2000 2203/2 ppb -6.0454 2.3359 38.640 -4.7882 -4.6073 -8.7407 NOCHECK Sn T11908 V Zn ppm ppb ppm ppm .0051 2.4694 .0002 .0004 .0015 1.0086 .0005 .0000 28.62 40.843 294.6 .7542 .0046 .0068 .0040 NOCHECK 1.8482 1.9270 3.6332 LC Pass .0007 -.0002 .0000 LC Pass .0004 .0004 .0004 LC Pass Analysis Report 06/14/05 04:54:53 PM page 2 High 60.000 0ew -60.000 m Pb2203 Se1960 Units ppb ppb Avge .89075 2.3501 SDev 1.2079 .6547 %RSD 135.60 27.858 #1 2.2052 1.8921 #2 .63747 3.1000 #3 -.17038 2.0583 Errors LC Pass LC Pass High 3.0000 5.0000 Low -3.0000 -5.0000 • r� 10.000 .0500 -10.000 -.0500 .0200 -.0200 Analysis Report 06/14/05 05:03:43 PM Method: DVCLPI Sample Name: 0506214-001A Operator: CO R 'r, ime. 06/14/05 16:55:01 ZZZZ.iL ent: ppm .0107 .0002 40.47 : CONC Corr. Factor: 1 .12 1.857 Elem Ag Al As1890 B Units ppb ppm ppb ppm Avge 2.1885 .3704 4.1537 .3273 SDev .1565 .0109 .3972 .0005 %RSD 7.1504 2.935 9.5615 .1582 #1 2.3640 .3830 3.8021 .3278 #2 2.1378 .3639 4.0745 .3269 #3 2.0636 .3645 4.5845 .3270 Elem Units Avge SDev %RSD #1 #2 #3 Elem Units WD #1 #2 #3 Elem Units Avge SDev %RSD #1 #2 #3 Elem Units Avge SDev %RSD #1 #2 Cd ppm .0003 .0002 80.16 page 1 Ba Be Ca ppm ppm ppm .0107 .0002 40.47 .0002 .0002 .12 1.857 78.58 .3084 .0109 .0005 40.59 .0106 .0001 40.47 .0105 .0001 40.34 Co Cr Cu Fe K ppm ppm Ppm Ppm Ppm .0003 .0006 .0322 1.094 9.065 .0003 .0004 .0005 .006 .021 111.5 69.62 1.417 .5643 .2369 .0005 .0005 .0006 .0002 .0005 .0010 .0001 -.0001 .0002 Mn ppm .1454 .0005 .3303 .1458 .1455 .1449 Sb2068 ppb -2.0646 1.9771 95.763 -2.1635 -.03990 -3.9905 Pb2203 ppb 5.5210 1.2343 22.357 5.0824 6.9147 4.5658 Mo ppm .0017 .0003 19.35 .0019 .0020 .0014 1960/1 ppb 14.958 3.713 24.826 13.100 19.234 12.540 Se1960 ppb 1.9613 3.7235 189.85 4.3341 3.8800 -2.3303 Na ppm 59.67 .16 .2746 59.69 59.83 59.50 1960/2 ppb -4.5280 4.8982 108.18 -.04306 -3.7861 -9.7549 .0327 .0319 .0320 Ni ppm .0022 .0007 31.60 .0027 .0024 .0014 Sn ppm .0043 .0010 22.95 .0049 .0031 .0048 1.101 1.093 1.089 P ppm 2.645 .012 .4408 2.632 2.655 2.648 T11908 ppb 2.9741 1.2088 40.645 2.4112 4.3617 2.1494 9.089 9.048 9.057 2203/1 ppb 21.749 3.672 16.886 23.114 24.543 17.589 V ppm .0000 .0003 969.1 .0004 -.0001 -.0001 Mg ppm 7.621 .008 .1038 7.629 7.620 7.614 2203/2 ppb -2.5817 1.1601 44.934 -3.9209 -1.8871 -1.9370 Zn ppm .0820 .0008 1.000 .0828 .0821 .0812 N M N O Cn H Analysis Report 06/14/05 05:12:34 PM page 1 Method: DVCLPI Sample Name: 0506243-001A Operator: CO Run Time: 06/14/05 17:03:52 C ent: ZZZ.ZZZ : CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb Ppm Ppb Ppm Ppm Ppm Ppm Avge 1.4589 .1454 4.0009 .0333 .0083 -.0000 SDev .4111 .0285 4.1265 .0016 .0002 .0000 .5795 %RSD 28.175 19.64 103.14 4.746 1.991 231.2 .0188 3.250 #1 1.8285 .1714 7.5712 .0349 .0084 .0000 #2 1.5321 .1498 4.9485 .0330 .0082 -.0000 .5991 #3 1.0162 .1149 -.51698 .0318 .0081 -.0000 .5779 .5616 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0001 -.0001 .0003 -.0028 .0138 .3581 .0927 SDev .0001 .0002 .0003 .0006 .0007 .0907 %RSD 111.8 192.6 103.4 20.56 5.235 25.34 .0034 3.714 #1 .0002 -.0004 .0003 -.0034 .0146 .4207 #2 .0000 -.0001 .0006 -.0027 .0132 .3995 .0933 #3 .0000 .0001 .0000 -.0023 .0135 .2540 .0959 .0891 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Av e .0008 .0011 71.58 .0013 .2911 14.917 -6.8914 .0001 .0002 .98 .0001 .0086 .190 1.3890 8.109 18.06 1.366 10.95 2.957 1.2750 20.156 #1 .0008 .0012 72.49 .0014 .2814 14.975 -5.4122 #2 .0007 .0009 71.71 .0014 .2979 15.072 -7.0940 #3 .0007 .0012 70.54 .0011 .2940 14.705 -8.1680 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -1.0409 9.8434 -3.9649 .0022 3.3973 .0006 .0430 SDev 1.1052 1.6134 2.7093 .0048 1.8351 .0002 .0004 %RSD 106.18 16.390 68.331 213.3 54.017 39.18 .9490 #1 -2.2256 9.9448 -2.5894 .0033 1.3076 .0003 .0430 #2 -.03771 11.404 -7.0860 .0064 4.7462 .0007 .0435 #3 -.85933 8.1817 -2.2194 -.0030 4.1382 .0008 .0426 Elem Pb2203 Se1960 Units ppb ppb Avge .37133 .63372 SDev .96675 1.3636 %RSD 260.35 215.17 M M #1 1.3772 1.5850 #2 .28770 -.92847 # -.55088 1.2446 N O N Analysis Report 06/14/05 05:21:26 PM Method: DVCLPI Sample Name: 0506284-001A Operator: CO Run Time: 06/14/05 17:12:43 C ent: ZZ2ZLZ : CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Units ppb ppm Ppb PPM PPM Ppm Avge 1.6051 .1534 5.5566 .2489 .1121 -.0000 SDev .0757 .0046 1.8424 .0009 .0003 %RSD 4.7177 3.019 33.157 .3818 .2258 .0000 52.34 #1 1.5291 .1551 7.3300 .2492 .1124 -.0000 #2 1.6056 .1481 3.6522 .2478 .1120 -.0000 #3 1.6806 .1569 5.6875 .2496 .1119 -.0000 Elem Cd Co Cr Cu Fe K Units ppm ppm PPM Ppm Ppm Ppm Avge -.0000 -.0007 .0002 .0064 .1368 13.22 SDev .0002 .0001 .0005 .0002 .0006 %RSD 419.3 20.22 313.3 2.836 .4667 .08 .6068 #1 -.0001 -.0007 .0000 .0066 .1364 13.31 #2 -.0002 -.0005 .0007 .0063 .1375 13.16 #3 .0001 -.0008 -.0003 .0063 .1365 13.20 Elem Mn Mo Na Ni P 2203/1 Units ppm ppm ppm ppm ppm ppb Avge .1339 .0046 136.3 .0019 2.869 16.418 .0001 .0008 .3 .0007 .028 2.631 .0585 17.84 .2175 36.66 .9867 16.022 #1 .1338 .0044 136.4 .0018 2.901 19.456 #2 .1338 .0055 135.9 .0026 2.856 14.861 #3 .1340 .0039 136.5 .0012 2.849 14.939 Elem Sb2068 1960/1 1960/2 Sn T11908 V Units ppb ppb ppb ppm ppb ppm Avge -2.4378 9.7571 -7.9834 .0055 3.1179 .0007 SDev 1.4527 .7947 1.0933 .0016 .3024 .0003 %RSD 59.591 8.1447 13.695 29.19 9.6993 36.55 #1 -3.3376 8.8558 -8.2064 .0067 3.2809 .0005 #2 -3.2140 10.058 -6.7958 .0063 2.7690 .0009 #3 -.76187 10.357 -8.9481 .0037 3.3040 .0006 Elem Pb2203 Se1960 Units ppb ppb Avge 1.0482 -2.0753 SDev 1.5551 .7729 %RSD 148.36 37.242 #1 2.4960 -2.5242 #2 1.2440 -1.1829 #6 -.59558 -2.5190 page 1 Ca PPM 72.42 .13 .1779 72.54 72.28 72.43 Mg ppm 20.51 .02 .0852 20.52 20.49 20.50 2203/2 ppb -6.6263 1.5088 22.770 -5.9718 -5.5552 -8.3518 Zn ppm .0246 .0007 2.872 .0238 .0250 .0250 Analysis Report 06/14/05 05:30:17 PM Method: DVCLPI Sample Name: 0506295-002A Run Time: 06/14/05 17:21:34 ZZZZzz ent: : CONC Corr. Factor: 1 Elem Ag Al As1890 B Units ppb ppm ppb ppm Avge 2.3155 .2139 3.4694 .2120 SDev .3080 .0019 .9214 .0005 %RSD 13.301 .8974 26.557 .2570 #1 2.5956 .2147 3.7881 .2114 #2 1.9857 .2152 2.4310 .2123 #3 2.3652 .2117 4.1891 .2124 Elem Cd Co Cr Cu Units ppm ppm ppm ppm Avge .0000 -.0003 .0006 .0193 SDev .0002 .0006 .0002 .0001 %RSD 541.8 184.6 33.30 .5922 #1 .0003 -.0011 .0004 .0195 #2 -.0001 .0000 .0008 .0193 #3 -.0001 .0000 .0008 .0193 Elem Mn Mo Na Ni Units ppm ppm ppm ppm Avge .0379 .0007 65.51 .0022 v.0001 .0006 .13 .0003 D .2782 93.08 .1975 16.19 #1 .0380 .0014 65.36 .0019 #2 .0380 .0004 65.55 .0021 #3 .0378 .0002 65.61 .0025 Elem Sb2068 1960/!1 1960/2 Sn Units ppb ppb ppb ppm Avge -1.5490 11.531 -3.8100 .0042 SDev 2.3300 4.394 3.6633 .0013 %RSD 150.42 38.108 96.150 29.69 #1 .86591 10.069 -2.5530 .0051 #2 -1.7294 16.471 -.94068 .0048 #3 -3.7837 8.0545 -7.9364 .0028 Elem Pb2203 Se1960 Units ppb ppb Avge 1.4515 1.2992 SDev 1.6344 3.7467 %RSD 112.60 288.38 #1 2.7481 1.6508 #2 1.9909 4.8578 0 -.38441 -2.6109 Operator: CO Ba ppm .0271 .0001 .1810 .0271 .0270 .0271 Fe ppm .2499 .0009 .3489 .2506 .2502 .2489 P ppm 3.060 .007 .2347 3.059 3.054 3.068 T11908 ppb 3.0453 3.1498 103.43 6.1993 3.0370 -.10031 Be ppm .0000 .0000 38.90 .0000 .0001 .0000 K ppm 9.510 .025 .2636 9.481 9.526 9.522 2203/1 ppb 16.578 .694 4.1874 16.628 15.861 17.246 V ppm -.0004 .0003 58.52 -.0004 -.0002 -.0007 page 1 Ca PPM 26.45 .10 .3842 26.54 26.45 26.34 Mg ppm 6.679 .034 .5065 6.714 6.675 6.647 2203/2 ppb -6.1014 2.6989 44.234 -4.1823 -4.9345 -9.1875 Zn ppm .0352 .0003 .9934 .0350 .0351 .0356 Analysis Report Method: DVCLPI Sample Name: MB -13828 Run Time: 06/14/05 17:30:26 2zzzz-z C menta : CONC Corr. Factor: 1 06/14/05 05:39:09 PM Operator: CO Elem Ag Al As1890 B Units ppb ppm ppb ppm Avge 1.2632 .1453 1.4992 .0019 SDev .1609 .0046 .7163 .0007 %RSD 12.736 3.201 47.780 38 60 #1 1.2096 #2 1.4440 #3 1.1359 Errors LC Pass High 10.000 Low -10.000 Elem Cd Units ppm Avge -.0001 SDev .0003 %RSD 423.1 #1 .0000 #2 -.0004 #3 .0002 cors LC Pass High .0050 Low -.0050 Elem Mn Units ppm Avge -.0001 SDev .0001 %RSD 70.24 #1 -.0000 #2 -.0001 #3 -.0002 Errors LC Pass High .0150 Low -.0150 Elem Sb2068 Units ppb Avge -1.6245 SDev 3.7046 %RSD 228.05 #0-1.5525 -5.3645 2.0436 .1506 .1423 .1429 LC Pass .2000 -.2000 Co ppm -.0003 .0001 34.60 -.0004 -.0002 -.0002 LC Pass .0500 -.0500 Mo ppm -.0004 .0005 126.8 -.0003 .0001 -.0009 NOCHECK 1960/1 ppb 2.5065 1.8947 75.593 1.9120 4.6272 .98028 2.0147 1.8017 .68128 .0025 .0020 .0011 Ba ppm .0011 .0000 3.454 .0012 .0011 .0011 Be ppm -.0000 .0000 160.6 LC Pass LC Pass LC Pass LC Pass 10.000 .0200 .2000 .0050 -10.000 -.0200 -.2000 -.0050 Cr ppm -.0006 .0003 55.71 -.0006 -.0002 -.0009 LC Pass .0100 -.0100 Na ppm .1494 .0187 12.51 .1697 .1456 .1329 LC Pass 5.000 -5.000 1960/2 ppb -4.1956 3.4084 81.237 -4.2426 -.76399 -7.5803 Errors LC Pass NOCHECK NOCHECK Cu ppm -.0062 .0004 6.723 -.0067 -.0061 -.0059 LC Pass .0250 -.0250 Ni ppm -.0008 .0001 8.737 -.0008 -.0007 -.0008 LC Pass .0400 -.0400 Sn ppm .0024 .0006 23.80 .0023 .0019 .0030 NOCHECK Fe ppm .0002 .0002 122.1 .0003 .0003 -.0001 LC Pass .1000 -.1000 P ppm .0138 .0084 60.71 .0159 .0046 .0209 NOCHECK T11908 ppb -.19563 1.87178 956.79 -1.1010 -1.4426 1.9567 K ppm .0462 .0014 3.046 .0449 .0477 .0461 LC Pass 5.000 -5.000 2203/1 ppb 16.090 2.172 13.497 15.567 14.228 18.476 NOCHECK V ppm -.0006 .0001 22.60 -.0007 -.0005 -.0007 LC Pass LC Pass page 1 Ca ppm .0365 .0032 8.915 .0401 .0357 .0337 LC Pass .2000 -.2000 Mg ppm .0003 .0044 1651. .0043 .0008 -.0044 LC Pass .2000 -.2000 2203/2 ppb -5.2595 3.3749 64.168 -6.3013 -1.4865 -7.9907 NOCHECK Zn ppm .0120 .0006 4.574 .0116 .0126 .0119 LC Pass Analysis Report 06/14/05 05:39:09 PM page 2 High 60.000 fem -60.000 Pb2203 Units ppb Avge 1.8505 SDev 1.6443 %RSD 88.859 #1 .98125 #2 H3.7470 #3 .82321 Errors LC Pass High 3.0000 Low -3.0000 • • Se1960 ppb -1.9633 2.8873 147.06 -2.1926 1.0318 -4.7291 LC Pass 5.0000 -5.0000 10.000 .0500 -10.000 -.0500 .0200 -.0200 Analysis Report 06/14/05 05:47:58 PM page 1 Method: DVCLPI Sample Name: LCS-13828 Run Time: 06/14/05 17:39:17 ZzzZ�.L Camment: CONC Corr. Factor: 1 E1A em g Al As1890 B Units ppb ppm ppb ppm Avge 1.5725 .1578 4.1528 .0022 SDev .0901 .0094 1.6675 .0003 %RSD 5.7293 5.940 40.154 13.27 #1 1.5201 .1671 5.9466 .0019 #2 1.5209 .1579 3.8620 .0024 #3 1.6766 .1484 2.6498 .0024 Elem Units Avge SDev %RSD #1 #2 #3 Elem Units Avge Dv D #1 #2 #3 Elem Units Avge SDev %RSD #1 #2 #3 Elem Units Avge SDev %RSD #1 #2 Cd Ppm .0001 .0001 60.26 .0001 .0000 .0001 Mn PPM .0001 .0001 137.7 .0002 .0002 -.0001 Sb2068 ppb -2.6663 2.6870 100.78 -.23881 -5.5535 -2.2065 Pb2203 ppb 398.95 2.29 .57351 400.09 400.45 396.32 Co PPM -.0005 .0003 70.95 -.0002 -.0008 -.0004 Mo Ppm .0000 .0009 34180. .0001 -.0009 .0008 1960/1 ppb 7.4201 6.5966 88.902 14.214 1.0406 7.0054 Se1960 ppb 3.4786 .9145 26.289 3.9513 2.4245 4.0599 Cr ppm -.0001 .0002 430.4 .0001 -.0003 .0000 Na PPM .0365 .0039 10.80 .0407 .0358 .0329 1960/2 ppb 1.5100 2.3386 154.87 -1.1732 3.1147 2.5887 Cu PPM -.0051 .0002 3.567 -.0052 -.0049 -.0051 Ni ppm -.0010 .0001 14.53 -.0009 -.0011 -.0009 Sn PPM .0031 .0014 46.58 .0040 .0039 .0014 Ba PPM .0527 .0001 .2741 .0529 .0527 .0527 Fe ppm .0058 .0001 2.448 .0058 .0056 .0059 P PPM .0035 .0009 25.63 .0042 .0025 .0039 T11908 ppb 2.3077 1.2135 52.586 3.2162 .92952 2.7772 Operator: CO Be ppm -.0000 .0000 68.60 -.0000 -.0000 -.0001 K ppm .0363 .0070 19.20 .0291 .0369 .0430 2203/1 ppb 398.90 2.64 .66071 401.94 397.49 397.28 Ca PPM .4791 .0018 .3721 .4807 .4795 .4772 Mg PPM .0152 .0026 17.17 .0130 .0181 .0146 2203/2 ppb 398.98 3.05 .76463 399.16 401.93 395.84 V Zn ppm ppm -.0004 .0825 .0003 .0002 66.74 .2801 -.0005 .0823 -.0006 .0828 -.0001 .0824 Analysis Report 06/14/05 05:56:48 PM page 1 Method: DVCLPI Sample Name: 0506092-001A Operator: CO Run Time: 06/14/05 17:48:06 Z.ZZz.z.L ment: : CONC Corr. Factor: 1 Elem Units Ag ppb Al As1890 B Ba Be Ca Avge 1.5680 PPM 1.855 Ppb 5.5330 Ppm PPM 1.644 PPM PPM SDev %RSD .6895 .003 2.4505 .0029 .0008 .001 -.0001 .0000 .1640 43.975 .1605 44.289 25.71 .0756 27.21 .0003 .1646 #1 #2 .78273 2.0745 1.853 4.0371 .0021 1.646 -.0001 .1643 #3 1.8466 1.858 1.854 8.3610 .0034 1.644 -.0001 .1638 4.2009 .0033 1.643 -.0001 .1638 Elem Cd Co Cr Cu Fe K Mg Units Avge ppm .0001 PPM PPM PPM PPM PPM PPM SDev .0002 .0005 .0002 .0471 .0006 .0422 9.249 .0770 .0831 %RSD 137.0 32.95 1.309 .0005 1.246 .030 .3226 .0126 16.34 .0027 3.215 #1 #2 .0001 .0004 .0467 .0419 9.217 .0674 .0801 #3 -.0000 .0007 .0468 .0420 9.255 .0913 .0852 .0003 .0004 .0478 .0428 9.276 .0724 .0839 Elem Units Mn Mo Na Ni P 2203/1 2203/2 Avge ppm .0387 PPM .0003 PPM .1330 PPM PPM Ppb Ppb IDv .0001 .0003 .0019 .0052 .0005 .0685 .0026 226.17 1.03 218.54 2.26 D .2310 129.1 1.431 9.296 3.767 .45453 1.0359 #1 #2 .0386 .0000 .1351 .0057 .0660 225.67 215.94 #3 .0387 .0001 .1314 .0053 .0712 225.49 219.67 .0388 .0006 .1325 .0047 .0682 227.35 220.03 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb Ppb PPM Ppb PPM PPM Avge -1.8527 5.6032 -6.4128 .0029 1.9147 .0007 SDev %RSD 1.4333 1.1602 1.1524 .0008 2.4574 .0005 .0274 .0004 77.362 20.707 17.971 27.08 128.35 70.45 1.550 #1 -1.0575 6.2039 -7.7059 .0022 -.72242 .0002 #2 -3.5074 6.3399 -6.0384 .0028 4.1406 .0012 .0270 #3 -.99336 4.2657 -5.4941 .0037 2.3260 .0006 .0273 .0278 Elem Pb2203 Se1960 Units ppb ppb Avge 221.08 -2.4110 SDev 1.71 .5966 %RSD .77133 24.746 #1 219.18 -3.0734 M #2 221.61 -1.9159 222.47 -2.2436 N O O E-+ Analysis Report 06/14/05 06:05:38 PM page 1 Method: DVCLPI Run Time: Sample Name: 0506092-001ADUP Operator: CO 06/14/05 17:56:56 ment : ZZ.Lz : CONC Corr. Factor: 1 Elem Units Ag ppb Al As1890 B Ba Be Ca Avge 1.5683 ppm 1.173 ppb 5.6803 PPM .0019 Ppm PPM Ppm SDev .4707 .015 2.1979 .0003 .8837 -.0000 .0439 %RSD 30.013 1.266 38.693 13.33 .0037 .4228 .0000 52.68 .0009 2.029 #1 #2 1.5703 1.0966 1.156 8.1619 .0019 .8795 -.0001 .0433 #3 2.0380 1.178 1.185 4.8996 3.9793 .0016 .8848 -.0000 .0449 .0021 .8868 -.0000 .0436 Elem Cd Co Cr Cu Fe K Units Avge ppm .0000 PPM -.0002 PPM PPM PPM •0604 pm Mg pm SDev .0003 .0001 .0279 .0004 .0202 4.840 •0205 %RSD 802.3 65.15 1.391 .0000 .1649 .032 .0036 5.986 .0034 .6545 16.70 #1 #2 -.0002 -.0002 .0283 .0201 4.804 .0572 .0231 #3 .0004 -.0001 -.0001 -.0001 .0275 .0202 4.854 .0644 .0219 .0279 .0202 4.863 .0597 .0167 Elem Units Mn Mo Na Ni. P 2203/1 2203/2 Avge ppm .0133 PPM .0002 PPM PPM PPM Ppb Ppb v.0000 .0003 .0855 .0014 .0023 .0351 143.90 127.08 D .0692 109.4 1.599 .0006 28.01 .0073 20.74 .30 .20612 2.45 1.9250 #1 #2 .0132 .0004 .0839 .0023 .0277 143.73 124.73 #3 .0133 .0133 .0004. -.0001 .0863 .0030 .0422 144.24 129.61 .0863 .0017 .0354 143.72 126.89 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units Avge ppb -4.8547 ppb 12.306 Ppb -5.7816 PPM Ppb 2.7407 PPM PPM SDev 1.2527 2.415 2.8039 .0024 .0025 .9421 .0001 .0157 %RSD 25.804 19.626 48.496 102.4 34.375 .0002 234.5 .0004 2.548 #1 #2 -5.5979 14.777 -4.1456 .0000 1.8635 .0003 .0156 #3 -3.4084 9.9507 -4.1800 .0023 2.6222 -.0001 .0162 -5.5579 12.191 -9.0191 .0050 3.7365 .0000 .0155 Elem Pb2203 Se1960 Units ppb ppb Avge 132.68 .24219 SDev 1.72 2.0705 %RSD 1.2963 854.91 O #1 131.06 2.1561 d' #2 134.48 .52606 132.50 -1.955640 cV O O Cn P-4 Analysis Report 06/14/05 06:14:28 PM Method: DVCLPI Sample Name: 0506092-001AMS Operator: CO Run Time: 06/14/05 18:05:46 ent : ZZZzzz. : CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Units ppb ppm ppb ppm ppm ppm Avge 51.864 .7071 -351.85 .0050 1.606 .6210 SDev 86.655 1.857 621.39 .0046 .085 1.075 %RSD 167.08 262.7 176.61 92.23 5.273 173.0 #1 1.7956 1.782 6.2893 .0023 1.559 .0007 #2 1.8733 1.777 7.5299 .0024 1.555 .0007 #3 151.92 -1.438 -1069.4 .0103 1.704 1.862 Elem Cd Co Cr Cu Fe K Units ppm ppm ppm ppm ppm ppm Avge .0154 .0063 .0417 .1135 11.11 3.913 SDev .0233 .0090 .0066 .1060 1.46 6.606 %RSD 151.2 141.5 15.93 93.42 13.14 168.8 #1 .0021 .0015 .0457 .0523 11.96 .0979 #2 .0018 .0008 .0453 .0522 11.94 .1008 #3 .0423 .0167 .0340 .2359 9.422 11.54 Elem Mn Mo Na Ni P 2203/1 Units ppm ppm ppm ppm ppm ppb A e .0393 .0552 1.490 -.0421 .2719 -18708. v.0100 .0948 2.350 .0909 .3594 34864. D 25.47 171.7 157.8 216.2 132.2 186.36 #1 .0452 .0001 .1327 .0101 .0610 1417.9 #2 .0449 .0009 .1327 .0107 .0679 1423.6 #3 .0277 .1646 4.203 -.1471 .6869 -58965. Elem Sb2068 1960/1 1960/2 Sn T11908 V Units ppb ppb ppb ppm ppb ppm Avge -138.19 80.801 145.16 -.1358 134.15 -.1595 SDev 239.06 122.39 260.63 .2438 229.82 .2792 %RSD 172.99 151.47 179.55 179.5 171.32 175.0 #1 2.0827 9.0196 -5.7143 .0054 4.3607 .0014 #2 -2.4318 11.266 -4.9160 .0045 -1.4142 .0019 #3 -414.23 222.12 446.11 -.4174 399.50 -.4819 Elem Pb2203 Se1960 Units ppb ppb Avge -52SQ . 123.74 SDev 11638.9 214.62 %RSD A%y 221.69 173.44 % yc, 0%. t`u►st"` #1 1467.2 -.80739 #2 1471.8 .47314 --o(O,0371.57 3cci tce o� 9- � P cobs uQ AAS page 1 Ca PPM .5828 .7750 133.0 .1354 .1352 1.478 Mg ppm .1985 .2344 118.1 .0650 .0613 .4692 2203/2 ppb 1468.5 44.0 2.9975 1491.9 1495.9 1417.7 Zn ppm .0586 .0653 111.4 .0213 .0205 .1340 Analysis Report 06/14/05 06:30:44 PM page 1 Method: DVCLPI Sample Name: CCV6 Operator: CO Run Time: 06/14/05 18:22:01 C ent: : CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units Avge ppb 1000.4 ppm 52.21 Ppb 534.41 ppm H2.799 Ppm Ppm Ppm SDev 2.0 .20 2.77 .026 2.650 2.613 54.58 %RSD .20400 .3894 .51740 .9270 .014 .5302 .005 .1867 .23 .4127 #1 1002.5 52.43 537.21 H2.828 2.665 2.619 54.83 #2 1000.4 52.16 534.34 H2.791 2.646 2.611 54.51 #3 998.43 52.04 531.68 H2.778 2.638 2.610 54.40 Errors LC Pass LC Pass LC Pass LC High LC Pass LC Pass LC Pass High 1100.0 55.00 550.00 2.750 2.750 2.750 55.00 Low 900.00 45.00 450.00 2.250 2.250 2.250 45.00 Elem Cd Co Cr Cu Fe K Mg Avges 2.578 L2.201 2.600 H2.774 50.09 SDev .010 .019 .011 .019 .06 86.94 1.49 51.08 %RSD .3756 .8446 .4193 .6778 .1276 1.712 .20 .3882 #1 2.589 L2.180 2.612 H2.794 50.03 H88.56 51.29 #2 2.576 L2.208 2.599 H2.772 50.07 86.64 51.03 #3 Dors 2.570 L2.215 2.590 H2.757 50.16 85.62 50.91 LC Pass LC Low LC Pass LC High LC Pass LC Pass LC Pass High 2.750 2.750 2.750 2.750 55.00 88.00 55.00 Low 2.250 2.250 2.250 2.250 45.00 72.00 45.00 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm Ppb Ppb Avge 2.577 2.674 79.35 2.746 -.0021 522.79 548.16 SDev .005 .017 .35 .027 .0031 7.79 5.73 %RSD .2007 .6225 .4436 .9917 145.8 1.4892 1.0447 #1 2.582 2.692 79.73 H2.773 -.0030 529.42 554.11 #2 2.575 2.669 79.30 2.744 -.0047 524.74 542.69 #3 2.573 2.660 79.03 2.719 .0013 514.22 547.68 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High 2.750 88.00 2.750 Low 2.250 72.00 2.250 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge H1111.4 548.21 556.39 2.574 533.22 2.597 2.491 SDev 15.2 8.33 5.52 .011 3.07 .005 .007 %RSD 1.3654 1.5196 .99200 .4342 .57652 .1766 .2831 H1125.1 557.64 557.86 2.587 536.50 2.603 2.499 H1114.0 541.85 561.03 2.570 530.40 2.594 2.488 40 1095.0 545.15 550.29 2.566 532.76 2.595 2.486 Errors LC High NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass Analysis Report 06/14/05 06:30:44 PM page 2 Hi h 1100.0 900.00 Elem Pb2203 Se1960 Units ppb ppb Avge 539.71 H553.67 SDev 5.35 4.68 %RSD .99119 .84557 #1 545.89 H557.79 #2 536.71 H554.64 #3 536.53 548.58 Errors LC Pass LC High High 550.00 550.00 Low 450.00 450.00 • • 550.00 2.750 450.00 2.250 2.750 2.250 Analysis Report Method: DVCLPI Sample Name: CCB6 Run Time: 06/14/05 18:30:53 C ent: Ba Be Ca : CONC Corr. Factor: 1 Elem Ag Al As1890 Units ppb ppm ppb Avge 1.8337 .1841 3.9338 SDev .6376 .0032 .7019 %RSD 34.770 1.728 17.843 #1 2.5352 .1863 3.7988 #2 1.6762 .1855 4.6933 #3 1.2896 .1805 3.3091 Errors LC Pass LC Pass LC Pass High 10.000 .2000 10.000 Low -10.000 -.2000 -10.000 Elem Cd Co Cr Units ppm ppm ppm Avge .0008 .0001 .0000 SDev .0003 .0009 .0005 %RSD 38.19 700.0 1327. 41 .0011 .0009 .0003 #2 .0007 .0004 -.0005 #3 .0005 -.0009 .0003 Sors -.0250 -.1000 -5.000 -.2000 LC Pass LC Pass LC Pass High .0050 .0500 .0100 Low -.0050 -.0500 -.0100 Elem Mn Mo Na Units ppm ppm ppm Avge .0006 .0050 .0588 SDev .0002 .0028 .0087 %RSD 26.73 56.60 14.87 #1 .0008 .0082 .0665 #2 .0006 .0038 .0606 #3 .0005 .0029 .0493 Errors LC Pass NOCHECK LC Pass High .0150 Ppb 5.000 Low -.0150 4.0279 -5.000 Elem Sb2068 1960/1 1960/2 Units ppb ppb ppb Avge -1.4550 9.0835 -4.1366 SDev 3.2246 6.3842 4.3463 %RSD 221.62 70.283 105.07 # 2.1028 15.400 -5.2214 LC Pass -2.2827 2.6342 .64935 # -4.1851 9.2159 -7.8378 Errors LC Pass NOCHECK NOCHECK 06/14/05 06:39:35 PM Operator: CO page 1 B Ba Be Ca Ppm Ppm Ppm Ppm .0085 .0010 .0007 .0100 .0023 .0002 .0002 .0042 27.39 17.68 28.15 41.31 .0111 .0012 .0009 .0135 .0070 .0010 .0008 .0112 .0072 .0008 .0005 .0054 LC Pass LC Pass LC Pass LC Pass .0200 .2000 .0050 .2000 -.0200 -.2000 -.0050 -.2000 Cu Fe K Mg ppm Ppm Ppm Ppm -.0057 .0169 .0668 .0095 .0004 .0050 .0120 .0046 7.337 29.79 18.05 47.83 -.0052 .0220 .0802 .0113 -.0057 .0170 .0568 .0043 -.0061 .0119 .0633 .0129 LC Pass LC Pass LC Pass LC Pass .0250 .1000 5.000 .2000 -.0250 -.1000 -5.000 -.2000 Ni P 2203/1 2203/2 ppm ppm Ppb Ppb -.0002 -.0016 16.376 -5.2307 .0007 .0096 1.568 2.0203 347.9 579.9 9.5755 38.625 .0004 .0094 17.710 -7.5414 -.0001 -.0069 14.649 -3.7977 -.0009 -.0074 16.769 -4.3529 LC Pass NOCHECK NOCHECK NOCHECK .0400 -.0400 Sn T11908 V Zn ppm Ppb ppm ppm .0053 4.0279 .0001 .0006 .0027 2.3922 .0005 .0006 50.71 59.390 448.7 99.82 .0083 6.6362 .0005 .0005 .0045 1.9363 -.0005 .0012 .0031 3.5113 .0003 .0001 NOCHECK LC Pass LC Pass LC Pass Analysis Report .I f; Elem Pb2203 Se1960 Units ppb ppb Avge 1.9649 .26619 SDev .9648 2.1065 %RSD 49.099 791.34 #1 .86792 1.6462 #2 2.3456 1.3109 #3 2.6813 -2.1584 Errors LC Pass LC Pass High 3.0000 5.0000 Low -3.0000 -5.0000 • 06/14/05 06:39:35 PM page 2 10.000 .0500 .0200 -10.000 -.0500 -.0200 U2M LABS, INC. 17� IV. DOCUMENTATION FOR METALS A. DIGESTION LOG SHEETS B. REPORTING ANALYST SIGNATURE PAGE • • Dig Type InkW VoM Final Vol spike sol 4 Lot # I Volume • U2M I_,AUS, INC. SDG NO.: S C- -Ocu?' SCAN: 11'YL=T-r This data package was reported by the undersigned. This reporting includes data calculations, manual edits if necessary and compilation of raw data. The information presented is true and correct to the best of my knowledge. • Signature: Date: G/ Reviewed By • 00 rt- N O O C/1 N