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HomeMy WebLinkAboutSample Data Summary Package 06/2005Analytical Data Package For TOWN OF SOUTHOLD PART 360 ROUTINE SDG NO: TSL002 Water Samples Received: 6110/05 JUNE 2005 0 U2M I AUS, INC. TABLE OF CONTENTS TOWN OF SOUTHOLD PART 360 ROUTINE WATER SAMPLES SAMPLES RECEIVED 6/10/05 SDG NO.: TSI -002 • 1. NYS DEC SUMMARY FORMS 2. CHAIN OF CUSTODY DOCUMENTATION 3. SDG NARRATIVES 4. SAMPLE REPORTS 4.1 METALS 4.2 WET CHEMISTRY 5. DUPLICATE SUMMARY RESULTS 5.1 METALS 5.2 WET CHEMISTRY 6. SPIKE SAMPLE RESULTS 6.1 METALS 6.2 WET CHEMISTRY 7. BLANK SUMMARY DATA AND RESULTS 7.1 METALS 7.2 WET CHEMISTRY • N2M "US, INC. 1. NYS DEC SUMMARY FORMS • • • • • NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE IDENTIFICATION AND ANALYTICAL REQUIREMENT SUMMARY Analytical Requirements Customer Laboratory Sample Sample ME we Code Code X X X X IMWAD 0506329-001 MWAS 0506329-002 MW -31) 0506329-003 X X IMW-3S 0506329-004 X X MW -4D 0506329-005 X X -� IMW-51) 0506329-006 X X x X BMW -5S 0506329-007 IMW-6D 0506329-008 X X !MW -6S 0506329-009 X ! X MW -8D 0506329-010 X X MW -8S 0506329-011 X X X X !EQPT BLANK 0506329-012 CLP,on-CLP lease indicate year of protocol) ASP TCUTAL, SL, Priority Pollutant, 101015 Kis 6�1-,1cs NEW YORK STATE DEPARTMENT OF ENV ONMENTAL CONSERVATION 0 • SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG: TSI -002 INORGANIC ANALYSIS Laboratory Samp ID Client Sample ID Matrix Metals Requested DateRecd at Lab Date Analyzed 0506329-001 MW -1D WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-002 MW -1S WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-002DUP MW -ISD WATER CA,CD,FE,K MG,MN,NA PB, 10 -Jun -05 06/05 0506329-002MS MW -ISS WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-003 MW -3D WATER CA,CD,FE,K,MG,MN,NA PB, 10 -Jun -05 06/05 0506329-004 MW -3S WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-005 MW -4D WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-006 MW -5D WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-007 MW -5S WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-008 MW -6D WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-009 MW -6S WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-010 MW -8D WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-011 MW -8S WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 0506329-012 EQPT BLANK WATER CA,CD,FE,K,MG,MN,NA,PB, 10 -Jun -05 06/05 TSL002 S4 NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION • SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG: TSI -002 INORGANIC ANALYSIS Laboratory Samp ID Client Sample ID Matrix j Tests DateRecd at Lab Date Analyze 0506329-001 MW -1D Groundwater SELECT WET CHEMISTRY ** 06/10/05 06/05 0506329-002 MW -IS Groundwater i SELECT WET CHEMISTRY ** 06/10/05 06/05 0506329-002DUP MW-1SDUP Groundwater SELECT WET CHEMISTRY "* 06/10/05 06/05 0506329-002MS MW -ISMS Groundwater SELECT WET CHEMISTRY *` 06/10/05 06/05 0506329-003 MW -31) Groundwater SELECT WET CHEMISTRY ** 06/10/05 06/05 0506329-004 MW -3S i Groundwater SELECT WET CHEMISTRY ** 06/10/05 06/05 0506329-005 MW4D Groundwater SELECT WET CHEMISTRY ** 06/10/05 06/05 0506329-006 MW -5D Groundwater SELECT WET CHEMISTRY ** 06/10/05 06/05 0506329-007 MW -5S Groundwater SELECT WET CHEMISTRY *" 06/10/05 06/05 0506329-008 MW -6D Groundwater SELECT WET CHEMISTRY ** 06/10/05 06/05 0506329-009 MW -6S Groundwater SELECT WET CHEMISTRY ** 06/10/05 06/05 0506329-010 MW -8D Groundwater SELECT WET CHEMISTRY ** 06/10/05 06/05 0506329-011 MW -8S Groundwater SELECT WET CHEMISTRY ** 06/10/05 06/05 0506329-012 EQPT BLANK Groundwater SELECT WET CHEMISTRY "" 06/10/05 06/05 • ** Alkalinity, Total (As CaCO3) ; Alkalinity, Total (As CaCO3), High; Biochemical Oxygen Demand; Bromide; Chemical Oxygen Demand; Chloride; Hardness (As CaCO3) ; Nitrate as N ; Nitrogen, Ammonia (As N) ; Nitrogen, Kjeldahl, Total ; Phenolics, Total Recoverable; Sulfate; Total Dissolved Solids ; Total Organic Carbon ; • t12M "US, INC. 0 2. CHAIN OF CUSTODY DOCUMENTATION • U2"US. INC. 575 Broa llow Rd, Melville, NY 11747-5076 . 4 5 80 EXTERNAL CHAIN OF CUSTODY0 Tel: (516) 694-3040 Fax: (516) 420-8436 CLIENT: P C'7 S L I H2M SDG NO: j . . PROJECT NAME/NUMBER S©HTOS01 7V W N OF S06/77401,6 L,'lIV bFI L Lo A o o ^- ° ---� Lo: o° of (� Cy ) --j — NOTES: Protect Contact: �iry N3 TKN P1 s Phone Number: n� / / 03 % "� <S 11I 2 3 1010 coo (2) ,80D 5 7D S S0 .q /IlJ C Q� SAMPLERS: (signature)/Client HOW DELIVERABLES: . c Z '1p o V I— 1 ANALYSIS REQ U TED TURNAROUND TIME: DA S ORGANIC ��' INORG. DATE TIME MATRIXFIELD I.D. a Q m M Z U LAB I.D. NO. REMARKS: to0im w — 1 s a I0 TTT 3 1 7W..Ye-1 f-, ;.. W/ M 5 M S 01001 422 W q30 I Iney ?000 w— 3 J 1. Relinquished by: (Signature) Date Time "ed by: (S nature) 44, D to Time LABORATORY USE ONLY Discrepancies Between Sample Labels and COC Record? Y or N Explain: Samples were: 1. Shipped_ or Hand Delivered_ Airbill# 2. Ambient or chilled 3. Received in good condition: Y or N 4. Properly preserved: Y or N 5. Samples returned to lab _ Hrs from collection. COC Tape was: 1. Present on outer package: Y or N 2. Unbroken on outer package: Y or N 3. COC record present 8 complete upon sample receipt: Y or N Relinquis by: (Signature) Date Time Rece: rd by: (Signature) Date Time Relinquished by: (Signature) Date Time Received by: (Signature) Date Time Relinquished by: (Signature) Date Time Received by: (Signature) Date Time TW I55�Y - ORIGINAL YELLOW COPY - CLIENT PINK COPY - LABORATnRY ULABS, INC. 575 !?d#ollow Rd, Melville, NY 11747-5076 - -544 EXTERNAL CHAIN OF CUSTODYO Tel: (516) 694-3040 Fax: (516) 420-8436 CLIENT: PC%S 1-12M SDG NO:�_ PROJECT NAME/NUMBERSo y �Q �� / NOTES: Project Contact: �G ✓N p F S'OU THOL Q /LL 1 t `� �J O In o 1� Q N 43 l /<A/ /':TS � w.D VG- 1. lV,� o a f Phone Number: Eo 3 /^ P�e hD�/ X/623. /&/o16-7 rj CC� SAMPLERS: (signature)/Client W L �� l DELIVERABLES: "7O o e --7 e c Z o V t - ANALYSIS REQUESTED TURNAROUND TIME: / CSL -S ORGANIC vii INORG. DATE TIME MATRI FIELD I.D. 1 m i a V z V LAB I.D. NO. REMARKS: 6/1/05 /05'0 Nq\J1 Al d — 3:S 3 I )/30 1 M VV- D /200 /h W 123o MW 1330 MW -- 1400 M W — ` 1430 MIN — � Relinquished by: (Signature) i - �`1`�1 1 Date Time Received by: (Signature) Date Time LABORATORY USE ONLY -1000, ' Discrepancies Between Sample Labels and Y N Samples were: t • Shipped_ or Hand Delivered_ Airbill# 2. Ambient or chilled Relinquished by: (Signature) ate tv Tint > jved by: ignature) �! t� DI(e Time , J) COC Record? Or 3. Received in condition: Y or N Explain: 4. Properly preserved: Y or N 5. Samples returned to lab ^ Hrs from collection. Relinquis ignature) Date Time Received by: (Signature) Date Time COC Tape was: 1. Present on outer package: Y or N 2. Unbroken on outer package: Y or N Relinquished by: (Signature) Date Time Received by: (Signature) Date Time 3. COC record present & complete upon sample receipt: Y or N T n°? e6PY - ORIGINAL YELLOW COPY - CLIENT PINK rnPY - I ARnROTnAV �1 1-12M LABS, INC. • Sample Receipt Checklist Client Name PCTSL Date and Time Receive Work Order Numbe 0506329 Received by LSD 6/10/2005 1:50:00 PM Checklist completed b x -A-, ��y`-S (� Signature Reviewed by Date t Initials Date Matrix Carrier name Hand Delivered Shipping container/cooler in good condition? Yes 0 NoEl Not Applicable ❑ Custody seals intact on shippping container/cooler? Yes ❑ No ❑ Not Applicable Custody seals intact on sample bottles? Yes D No ❑ Not Applicable Chain of custody present? Yes 0 No ❑ Chain of custody signed when relinquished and received? Yes W No ❑ Chain of custody agrees with sample labels? Yes V No Samples in proper container/bottle? Yes �a No ❑ Sample containers intact? Yes 0 No D Sufficient sample volume for indicated test? Yesd❑ No ❑ samples received within holding time? Yes No ❑ tainer/Temp Blank temperature in compliance? Yes No ❑ Water - VOA vials have zero headspace? No VOA vials submitted Yes ❑ No ❑ Water - pH acceptable upon receipt? Yes No ❑ Adjusted? Checked b Any No and/or NA (not applicable) response must be detailed in the comments section b --------------------------------------------- Client contacted Date contacted: Person contacted Contacted by: Regarding Comments: Corrective Action O - O t� H LABS, INC- INTERNAL CHAIN OF CUSTODY C DELIV, CLIETff � ERABLES: t7� iJ_ TURNAROUND THAE. SDG #: J 1� CASE #:__ MATRIX: � �c�- f' N REMARKS: R-li§-� Tg��� SIGNATURE: DATE. METALS P 0049 t12M UAUSq INC• sno INTERNAL CHAIN OF CUSTODY METALS ff t fir METALS ff t U2AA tA", INC. Ah CLIENT:�-- SDG #: I SlOD"? REMARKS: q)oe� INTERNAL CHAIN OF CUSTODY DELIVERABLES: K -"20-P TURN AROUND TIME: t� CASE MATRIX: ( pH CISCO N a RECEIVE -D BY: ISO SIGNATURE: r o ": t 3b i WET CHEMISTRY -w q Z P 009iL N C/] N O O H MEN I-- MIME! ONEW MEMO IN 1011100100101110 mi �,Mlmmmm i WET CHEMISTRY -w q Z P 009iL N C/] N O O H iH2A ILAUS,-,� A., Vc i - SDG #: F) NCO INTERNAL CHAIN OF CUSTODY WET CHEMISTRY 0 0092 U2M LAOS, INC. 0 3. SDG NARRATIVES • • U2M L U%a INC. For Samples: NARRATIVE FOR METALS ANALYSES SAMPLE RECEIVED: 6/10/05 SDG#: TSL002 EQPT BLANK MW -1D MW -1S MS/MSD MW -3D MW -3S MW -4D MW -5D MW -5S MW -6D MW -6S MW -8D MW -8S Twelve water samples were received by H2M Labs inc. on 6/10/05 for select metals analysis. • Samples were prepared and analyzed using EPA method 6010B with a TJA61 E Trace ICP instrument. Sample MW -1 S was utilized for QC analysis and reporting. No problems were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: June 20, 2005 ** * *** ********** * ******************* Vincent Stancampiano Vice President o:\gc\narr2005\tsl\metals\ts]002.doc r� U2M I AUS, INC. • SDG NARRATIVE FOR WET CHEMISTRY SAMPLES RECEIVED: 6/10/05 For Samples: SDG NO.: TSL002 EQPT BLANK MW -5D MW -1D MS/MSD MW -5S MW -IS MW -6D MW -3D MW -6S MW -3S MW -8D MW -4D MW -8S Samples were prepared and analyzed using the following methods: PARAMETER METHOD # Alkalinity EPA 310.1 BOD EPA 405.1 Bromide EPA 320.1 Chloride EPA325.2 COD EPA 410.4 Hardness EPA 130.2 Ammonia EPA 350.1 Nitrate EPA 353.2 Phenols EPA420.1 Sulfate EPA 9038 TDS EPA 160.1 TKN EPA 351.2 TOC EPA 9060 Sample MW -1D was utilized for duplicate and spike QC analysis and reporting. Several ammonia values exceeded the TKN concentration. All differences were within 20%RPD or ± the CRDL except for the following: Sample Ammonia mLy/L TKN m2/L RPD MW -5S 4.70 3.74 22.7% MW -8D 3.86 3.12 21.2% Samples were diluted and reanalyzed as required to keep instrument readings within calibration ranges. No other problems were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: April 21, 2005 • ************************* Vincent Stancampiano Vice President U2M ILAUS, INC. • 4. SAMPLE REPORTS 4.1 METALS 4.2 WET CHEMISTRY • • N O F-+ U2M LABS, INC. QUALIFIERS FOR METALS ANALYSIS Q (Quality Control) Qualifiers E - The reported value is estimated because of the presence of interference. An explanatory note is included in the SDG narrative. M - Duplicate injection precision not met. N - Matrix spike sample recovery not within control limits. S- The reported value was determined by the Method of Standard Additions (MSA). + - Correlation coefficient for the MSA is less than 0.995 W - Post digestion spike for Furnace AA analysis is out of control limits (85- 115%), while sample absorbance is less than 50% of spike absorbance. • * - Duplicate analysis is not within control limits. C (Concentration) Qualifiers B - Entered if the reported value is less than the Contract Required Detection Limit (CRDL) but greater than the Instrument Detection Limit (IDL). U - Entered if the analyte was analyzed for but not detected, i.e., less than the IDL. M (Method) Qualifiers P - Analyzed by ICP. M - Analyzed by ICP -MS A - Analyzed by Flame AA. F - Analyzed by Furnace AA. CV - Analyzed by Manual Cold Vapor techniques. AV - Analyzed by Automated Cold Vapor techniques. C - Analyzed by Manual Spectrophotometric Method. CA- Analyzed by Midi -distillation Spectrophotometric Method. NR - Analyte not Required. U.S. EPA - CLP 1 EPA SAMPLE N INORGANIC ANALYSIS DATA SHEET 0 Lab Name: H2M LABS, INC. EQPT BLANK Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Matrix (soil/water): WATER Lab Sample ID: 0506329-012 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7990-43-9 Cadmium 0.65 U p 7990-70-2 Calcium 39.6 B p 7939-89-6 Iron 3.6 U p 7939-92-1 Lead 1.7 U P 7439-95-4 Magnesium 6.9 U P 7939-96-5 Manganese 1.2 U P 7440-09-7 Potassium 39.6 U P 7440-23-5 Sodium 159 B p •Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED JUNE 15, 2005 FORM I - IN ILM04.1 H2M lAI3S, INC. 5750=dHolow Roed, Md& NY 11747 (631)694.9040. FAX (631)4208436 NYSDOH D# 10478 Town of Southold Landfill ;Mn To : Collected :6/10!200510:15:00 AM Received :6/10/20051:50:00 PM Collected By VG03 Copies To :Orional CC LABORATORY RESULTS Lab No. : 0506329-012 Client ID.: EQPT BLANK Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier 0.FUnits Method Number Analyzed Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310.1 06/14/200511:48 AM Biochemical Oxygen Demand < 2 1 m91L E405.1 06/10/2005 5:30 PM Bromide < 0.5 1 m9& E320.1 06/222005 4:15 PM Chloride < 2.0 1 m911- E325.2 06/13200512:07 PM Chemical Oxygen Demand <10 1 mg/L E410.4 06/16/200512:07 PM Hardness (As CaCO3) < 5.0 1 mg/L E130.2 06/14200510.35 AM Nitrogen, Ammonia (As N) 0.12 1 mg/L E350.1 06/22200511:55 AM Nitrate as N < 0.10 1 mg/L E353.2 06/112005 5:08 PM Phenolics, Total Recoverable < 5.0 1 Ng/L E420.1 06/22/200512:15 PM Sulfate < 5.0 1 mg/L SW9038 06/202005 7:56 AM Total Dissolved Solids 10 1 mg/L E160.1 06/142005 2:59 PM Nitrogen, Kjeldahl, Total 0.16 1 mg/L E351.2 062320051:36 PM Total Organic Carbon < 1.0 1 mg/L SW9060 06/142005 3:05 AM .7 Quakkm: E - Value above quantitation Targe D - Results for Dilution D.F. = Dilution Factor Date Reported: 6272005 Page 12 of 12 Laboratory Manager U.S. EPA - CLP 0 Analyte Concentration C Q M 7940-43-9 Cadmium 0.75 1 EPA SAMPLE NO 7440-70-2 Calcium INORGANIC ANALYSIS DATA SHEET P 7439-89-6 Iron 169 P 7439-92-1 Lead MW -1D U Lab Name: H2M LABS, INC. Contract: 7240 P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 P Matrix (soil/water): WATER Lab Sample ID: 0506329-001 P Level (low/med): LOW Date Received: 6/10/2005 P % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7940-43-9 Cadmium 0.75 B P 7440-70-2 Calcium 124001 P 7439-89-6 Iron 169 P 7439-92-1 Lead _ 1.7 U P 17439-95-4 Magnesium 7240 P 7439-96-5 Manganese 13.0 B P 7440-09-7 Potassium _ 2170 B P 7990-23-5 Sodium 94300 P is Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED JUNE 15, 2005 • FORM I - IN ILM04.1 U2AM L US, INC. 57513oedFUm Roel Mli& W 11747 (M1)6B4,W.FAX(8M)4208M NYSDWD#10478 LABORATORY RESULTS Sample Information... Town of Southold Landfill Lab No. : 0506329-001 Type: Groundwater *Attn Origin: To . Client ID.: MW -1D Collected :6/10/2005 9.00:00 AM Received :6/1020051:50:00 PM Collected By VG03 Copies To :Original CC Parameterfs) Results Qualifler D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 4.3 1 mg/L E310.1 06/14200511:37 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/102005 4:30 PM Bromide < 0.5 1 mg/L E320.1 06/22/2005 3:10 PM Chloride 74.6 1 mg/L E325.2 06/13200511:57 AM Chemical Oxygen Demand < 10 1 mg/L E410.4 06/16200511:52 AM Hardness (As CaCO3) 68.0 2 mg/L E130.2 06/142005 9:20 AM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 06/22200511:45 AM Nitrate as N 5.44 20 mg/L E353.2 06/112005 4:58 PM Phenolics, Total Recoverable < 5.0 1 Ng/L E420.1 0622/2005 9:00 AM Sulfate 27.7 1 mg/L SW9038 0620/2005 7:34 AM Total Dissolved Solids 208 1 mg/L E160.1 06/142005 2:44 PM Nitrogen, Kjeldahl, Total 0.29 1 mg/L E351.2 062320051:26 PM Total Organic Carbon < 1.0 1 mg/L SW9060 06/132005 7:59 PM r� Oualfiers: E - Value above quantltsbon range D - Results for Mudon • D.F. = DAutlon Factor Date Reported : 6272005 Page 1 of 12 �I Laboratory Manager U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -1S Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Matrix (soil/water): WATER Lab Sample ID: 0506329-002 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.65 U P 7440-70-2 Calcium 12000 P 7439-89-6 Iron 555 P 7439-92-1 Lead 1.7 U P 7439-95-4 Magnesium 7000 P 7439-96-5 Manganese 17.9 P 7440-09-7 Potassium 2050 B P 7440-23-5 Sodium 43100 P Color Before: COLORLESS Clarity Before: CLEAR • Color After: COLORLESS Clarity After: CLEAR Texture: Artifacts: Comments: DATE REPORTED JUNE 15, 2005 N • N O FORM I - IN ILM04.1 1-12M I -A US, INC. 5758 UWHObN Road IMM NY 11747 LABORATORY RESULTS (M1)W'MV.FAX#M)42DM WYSWHD#10478 Sample Information... Town of Southold Landfill Lab No.: 0506329-002 Type : Groundwater Attn To : Origin: Client ID.: MW4S Collected :6/10/2005 8:30:00 AM Received :6/10/20051:50:00 PM Collected By VG03 Copies To :Original CC ParameWsl Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 3.9 1 mg/L E310.1 06/14/200511:38 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/102005 4:35 PM Bromide < 0.5 1 mg/L E320.1 06/22/2005 3:15 PM Chide 73.6 1 mg/L E325.2 06113/2005 11:58 AM Chemical Oxygen Demand <10 1 mg/L E410.4 06/16/200511:53 AM Hardness (As CaCO3) 62.0 2 mg/L E130.2 06/14/2005 9.25 AM Nitrogen, Ammonia (As N) 0.12 1 mg/L E350.1 0622/200511:45 AM Nitrate as N 5.35 10 mg/L E353.2 06/112005 4:58 PM Phenolics, Total Recoverable < 5.0 1 Ng/L E420.1 06222005 9:15 AM Sulfate 23.8 2.5 mg/L SW9038 06202005 7:36 AM Total Dissolved Solids 223 1 mg/L E160.1 06/142005 2:45 PM Nitrogen, Kjeldahl, Total 0.16 1 mg/L E351.2 062320051:26 PM Total Organic Carbon < 1.0 1 mg/L SW9060 06/132005 8:28 PM Qualifiers: E - Value above quantltatlon range D - Results for DihAlon D.F.= Dilution Factor Date Reported: 6/272005 Page 2 of 12 Laboratory Manager U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET L Lab Name: H2M LABS, INC. Contract: MW -3D Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Matrix (soil/water): WATER Lab Sample ID: 0506329-003 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7990-93-9 Cadmium 0.65 U P 7440-70-2 Calcium 21300 P 7939-69-6 Iron 26.6 B P 7439-92-1 7439-95-4 Lead Magnesium 2,2 3900 g B p P 7439-96-5 Manganese___ 1500 P 7440-09-7 Potassium _ 11300 P 7990-23-5 Sodium 5220 P i •Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED JUNE 15, 2005 FORM I - IN ILM04.1 N (/1 N O V1 H U2M lAI3S9 INCe 575BMWHobN Roel Mduie NY 11747 (631)W4W 0.FAX(631)42 WM NYSD0HD#10478 Town of Southold Landfill 0 Attn To Collected :6110=0 10:00:00 AM Received :611020051:50:00 PM Collected By VG03 Copies To :Original CC LABORATORY RESULTS Lab No. : 0506329-003 Client ID.: MW -3D Sample Information... Type : Groundwater Origin: Parameterts) Results Qualill D.Fz Units Method Number Analyzed Alkalinity, Total (As CaCO3), High 59.2 1 mg/L E310.1 06/13200511:47 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/102005 4:45 PM Bromide 0.9 1 mg/L E320.1 06222005 3:30 PM Chloride 6.6 1 m91L E325.2 06/13200512:01 PM Chemical Oxygen Demand 29.3 1 mg/L E410.4 06/16200511:56 AM Hardness (As CaCO3) 80.0 4 mg/L E130.2 06/142005 9:40 AM Nitrogen, Ammonia (As N) 0.11 1 m91L E350.1 0622200511:47 AM Nitrate as N 1.06 5 mg/L E353.2 06/112005 5:00 PM Phenolics, Total Recoverable < 5.0 1 Ng/L E420.1 06122/200510:00 AM Sulfate 14.9 1 mg/L SW9038 06202005 7:38 AM Total Dissolved Solids 136 1 m91L E160.1 06/142005 2:48 PM Nitrogen, Kjeldahl, Total 0.26 1 m91L E351.2 06232005128 PM Total Organic Carbon 6.7 1 mg/L SW9060 06/132005 9:54 PM • Qualifiers: E - Value above qumMNatlon range D - Resuft for D"on D.F. = DNution Factor Date Reported: 6272005 Page 3 of 12 Laboratory Manager N Un N O h U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET - MW-3S Lab Name: H2M LABS, INC. Contract: J Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Matrix (soil/water): WATER Lab Sample ID: 0506329-004 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7490-43-9 Cadmium 0.65 U P 7440-70-2 Calcium 20000 P 7439-89-6 Iron 31.8 B P 7439-92-1 _ Lead 1.7 U P 7439-95-4 Magnesium 3650 B P 7939-96-5 Manganese__ 1410 P 7940-09-7 Potassium -- _ _ 10400 P 7490-23-5 Sodium -------- 5150 P Before: COLORLESS Clarity Before: .Color Color After: COLORLESS Clarity After: Comments: DATE REPORTED JUNE 15, 2005 1, LLt M Texture: Artifacts: FORM I - IN ILM04.1 1-12M "US, INC. 5758 aWH*W Road MElVk NY 11747 (631)6W4lM. FAX (6M)4W84% NY50OH D#10478 Town of Southold Landfill Atin To : Collected :6/1 W005 9:30:00 AM Received :6/1020051:50:00 PM Collected By VG03 Copies To :Original CC LABORATORY RESULTS Lab No.: 0506329-004 Client ID.: MW -3S Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier E.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3), High 61.8 1 MOIL E310.1 06/13200511:52 AM Biochemical Oxygen Demand < 2 1 mglL E405.1 06/102005 4:50 PM Bromide < 0.5 1 mg/L E320.1 06/222005 3:35 PM Chloride - 6.6 1 mglL E325.2 06/13200512:02 PM Chemical Oxygen Demand 14.3 1 mg/L E410.4 06/16200511:59 AM Hardness (As CaCO3) 88.0 4 mg1L E130.2 06/142005 9.45 AM Nitrogen, Ammonia (As N) 0.10 1 mglL E350.1 0622200511:48 AM Nitrate as N 1.16 5 mg1t E353.2 06/112005 5:01 PM Phenolics, Total Recoverable < 5.0 1 Ng/L E420.1 06/22/200510:15 AM Sulfate 15.2 1 MOIL SW9038 06202005 7:40 AM Total Dissolved Solids 126 1 mg/L E160.1 06/142005 2:49 PM Nitrogen, Kjeldahl, Total 0.32 1 M91L E351.2 062320051:29 PM Total Organic Carbon 6.1 1 mg/L SW9060 06/13200510:22 PM Qualifiers: E - Value above quant bon range D - ResL tt for DiNAion F. = Dilution Factor Date Reported : 6272005 Page 4 of 12 Laboratory Manager 00 N Cn N O V] U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET I MW -4D Lab Name: H2M LABS, INC. Contract: L__ Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Matrix (soil/water): WATER Lab Sample ID: 0506329-005 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7490-43-9 Cadmium 0.65 U p 7490-70-2 Calcium 10200 P 7439-89-6 Iron 207 p 7439-92-1 Lead 1.7 U P 7439-95-4 Magnesium _ 7330 P 7439-96-5 Manganese 652 P 7940-09-7 Potassium 9670 P 7490-23-5 Sodium 17900 p •Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED JUNE 15, 2005 • FORM I - IN ILM04.1 1-12M I-AJUS, INC. 575BMedHdba Road, Mtfule W 11747 LABORATORY RESULTS (6M)694. W.FAX(631)4MaW WSDOHI)#10478 Sample information... Town of Southold Landfill Lab No. : 0506329-005 Type : Groundwater Attn To : Origin: Collected :6/9/200512:00:00 PM Received :6/10!20051:50:00 PM Collected By VG03 Copies To :Original CC Client ID.: MW -41) Parameteds) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 41.9 1 mg/L E310.1 06/14/200511:41 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/10/2005 4:55 PM Bromide 1.7 1 mg/L E320.1 06/22/2005 3,40 PM Chloride 24.6 1 mg/L E325.2 06/13200512:03 PM Chemical Oxygen Demand 14.3 1 mg/L E410.4 06/16200512:00 PM Hardness (As CaCO3) 60.0 2 mg/L E130.2 06/142005 9:50 AM Nitrogen, Ammonia (As N) 4.65 10 mg/L E350.1 0622200511:49 AM Nitrate as N 3.18 5 mg/L E353.2 06/112005 5:02 PM Phenolics, Total Recoverable < 5.0 1 Ng/L E420.1 06/721200510:30 AM Sulfate 19.8 1 mg/L SW9038 06202005 7:42 AM Total Dissolved Solids 135 1 mg/L E160.1 06/142005 2:50 PM Nitrogen, Kjeldahl, Total 4.17 10 mg/L E351.2 0623/20051:30 PM Total Organic Carbon 3.7 1 mg/L SW9060 06/13200510:50 PM • Qualifiers. E - Value above quarybtabon range D - Rem b for DNuean . D.F. = DILMon Factor Date Reported : 6272005 Page 5 of 12 Laboratory Manager U.S. EPA - CLP • 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID• Level (low/med): LOW Date Received: % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 443-9 E744E0-70-2 Cadmium 0.65 U P Calcium 10500 p 7439-89-6 Iron 7.7.6 B P I 7439-92-1 Lead 1.7 _ U P 7439-95-4 Magnesium _ 6850 p 7439-96-5 Manganese 686 p I 7990-09-7 Potassium 10500 P-1 7940-23-5 Sodium 15400 P •Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: CLEAR Comments: DATE REPORTED JUNE 15, 2005 • EPA SAMPLE NO MW -5D SDG No.: TSL002 6/10/2005 Texture: Artifacts: FORM I - IN ILM04.1 M N O H F24 L ES, INC. 575BoadHQbN Roel MEiwb NY 11747 LABORATORY RESULTS (631)694aM.FAX(8M)4W8436 NYSDWD#10478 Sample Information... Town of Southold Landfill Lab No.: 0506329-006 Type: Groundwater Attn To : Origin: Collected :6/9/20051:30:00 PM Received :6/10/20051:50:00 PM Collected By VG03 Copies To :Original CC Client ID.: MW -5D Parameter(s1 Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3), High 51.2 1 mg1L E310.1 06/13/200512:02 PM Biochemical Oxygen Demand < 2 1 mglL E405.1 06/102005 5:00 PM Bromide 0.7 1 mg/L E320.1 0622/2005 3:45 PM Chloride 23.1 1 mg/L E325.2 06113200512:03 PM Chemical Oxygen Demand 11.8 1 mg1L E410.4 06/16200512:01 PM Hardness (As CaCO3) 70.0 2 mg/L E130.2 06/142005 9:55 AM Nitrogen, Ammonia (As N) 4.63 10 mg/L E350.1 0622200511:49 AM Nitrate as N 3.08 5 mg1L E353.2 06/112005 5:02 PM Phenolics, Total Recoverable < 5.0 1 ug/L E420.1 0622200510:45 AM Sulfate 20.3 1 mg1L SW9038 06202005 7:44 AM Total Dissolved Solids 163 1 mg/L E160.1 06/142005 2:51 PM Nitrogen, Kjeldahl, Total 3.94 10 mg/L E351.2 062320051:32 PM Total Organic Carbon 4.4 1 mg/L SW9060 06/13200511:18 PM • Qua ffws: E - Value above quantifatlon range D - Results for Dilution D.F. = Diurion Factor Date Reported: 6272005 Page 6 of 12 Laboratory Manager • U.S. EPA - CLP I EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: MW -SS Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Matrix (soil/water): WATER Lab Sample ID: 0506329-007 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0 0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7490-43-9 Cadmium 0.65 U P 7440-70-2 Calcium 10400 P 7439-89-6 Iron 89.9 g p 7939-92-1 Lead 1.7 U p 7939-95-4 Magnesium 6810 P 7939-96-5 Manganese 677 P 7940-09-7 Potassium 10600 P 7490-23-5 Sodium 15900 p � •Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: CLEAR Comments: DATE REPORTED JUNE -15,2005 Texture: Artifacts: FORM I - IN ILM04.1 M M N O V1 E-� U2M tAJUS, INC. 575BoadHdow PO4 M" NY 11747 LABORATORY RESULTS (631)U A-3X).FAX(831)42MM NYSMHD#10478 Sample Information... Town of Southold Landfill Lab No. : 0506329-007 Type : Groundwater 9. Atin To : Origin: Client ID.: MW -5S Coilec:ted :619200512:30:00 PM Received :6/1020051:50:00 PM Collected By VG03 Copies To :Original CC Parametws) Resul Quallfier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3), High 54.8 1 mg/L E310.1 06/13200512:07 PM Biochemical Oxygen Demand < 2 1 mgll. E405.1 06/102005 5:05 PM Bromide < 0.5 1 mg/L E320.1 06/2'12005 3:50 PM Chloride 23.3 1 m91L E325.2 06/13200512:04 PM Chemical Oxygen Demand 14.3 1 mglL E410.4 06/16/200512:02 PM Hardness (As CaCO3) 60.0 2 mg1L E130.2 06/14200510:10 AM Nitrogen, Ammonia (As N) 4.70 10 mg/L E350.1 0622200511:50 AM Nitrate as N 3.10 5 mg& E353.2 06/112005 5:03 PM Phenolics, Total Recoverable < 5.0 1 Ng/L E420.1 0622200511:00 AM Sulfate 19.8 1 mg/L SW9038 06202005 7:46 AM Total Dissolved Solids 148 1 m91L E160.1 06/142005 2:52 PM Nitrogen, Kjeldahl, Total 3.74 10 mg/L E351.2 062320051:32 PM Total Organic Carbon 4.5 1 mg/L SW9060 06114200512:45 AM is Qualifiers: E - Vafue above quw6t3t1on Targe D - Results for Dkd1on D.F. = Dilution Factor Date Reported: 6272005 Page 7 of 12 ?anvo- �;('- Laboratory Manager M N O l— F-+ • U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -6D Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TS1,002 Matrix (soil/water): WATER Lab Sample ID: 0506329-008 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.65 U P 7440-70-2 Calcium 10700 p 7439-89-6 Iron 325 P 7439-92-1 Lead _ 1.7 U P 7439-95-4 Magnesium 7400 P 7439-96-5 Manganese 691 P 7440-09-7 Potassium 10100 P 7440-23-5 Sodium 17400 P •Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: CLEAR Comments: DATE REPORTED JUNE 15, 2005 • FORM I - IN Texture: Artifacts: ILM04.1 kn M G/) N O O E-� V2M L US, INC. SMBMWHcJW Road Halals NY 11747 LABORATORY RESULTS (6M)6X3M.FAX1631)42D8436 NYSMHD#10478 Sample Information... Town of Southold Landfill lab No. : 0506329-008 Type : Groundwater O;MnTo: Origin: Collected :6/9/2005 2:30:00 PM Received :6/10/20051:50:00 PM Collected By VG03 Copies To :Original CC Client ID.: MW -6D Parameterts) Results ualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 41.0 2 mg/L E310.1 06/14/200511:42 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/10/2005 5:10 PM Bromide 0.6 1 mg/L E320.1 06/22/2005 3:55 PM Chloride 24.2 1 mg/L E325.2 06/13/200512:05 PM Chemical Oxygen Demand 11.8 1 mg/L E410.4 06/16/200512:03 PM Hardness (As CaCO3) 58.0 2 mg/L E130.2 06/14/200510:15 AM Nitrogen, Ammonia (As N) 4.09 10 mg/L E350.1 06/22/200511.51 AM Nitrate as N 3.19 5 mg/L E353.2 06/11/2005 5:04 PM Phenolics, Total Recoverable < 5.0 1 Ng/L E420.1 06/22/200511:15 AM Sulfate 19.7 1 mg/L SW9038 06/20/2005 7.48 AM Total Dissolved Solids 153 1 mg/L E160.1 06/14/2005 2:53 PM Nitrogen, Kjeldahl, Total 4.68 10 mg/L E351.2 06/23/20051:33 PM Total Organic Carbon 3.5 1 mg/L SW9060 06/14/20051:13 AM C, Qualifiers: E - Value above quantitation range D - Recalls for DBubon O.F. = MiUm Factor Date Reported : 6/27/2005 Page 8 of 12 � � � h '-" oi�- � Laboratory Manager U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -63 Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TS1,002 Matrix (soil/water): WATER Lab Sample ID: 0506329-009 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.65 U P 7440-70-2 Calcium 9860 P 7439-89-6 Iron 352--- P 7439-92-1 Lead 2.0 Bp 7439-95-4 Magnesium 7000 p 7439-96-5 Manganese 650 P 7440-09-7 Potassium 9440 p 7440-23-5 Sodium 17100 P •Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED JUNE 15, 2005 • FORM I - IN ILM04.1 U2A lAI3S, INCe 575810adFlobN Road, W& W 11747 (631)694aM.FAX(631)4208M MWOHD#10478 Town of Southold Landfill *Attn To : Collected :6/9/2005 2:00:00 PM Received :610/20051:50:00 PM Collected By VG03 Copies To :Original Cc LABORATORY RESULTS Lab No. : 0506329-009 Client ID.: MW -6S Sample information... Type: Groundwater Origin: Parameters) Results uali r D_F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 25.2 1 mg/L E310.1 06/14200511:43 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/0/2005 5.15 PM Bromide 1.0 1 mg/L E320.1 06222005 4:00 PM Chloride 24.9 1 mg/L E325.2 0613200512.05 PM Chemical Oxygen Demand 16.8 1 mg/L E410.4 06/16200512:04 PM Hardness (As CaCO3) 62.0 2 mg/L E1302 0614200510.20 AM Nitrogen, Ammonia (As N) 4.29 10 mg/L E350.1 0622200511:53 AM Nitrate as N 3.30 5 mg/L E353.2 06/112005 5:06 PM Phenolics, Total Recoverable < 5.0 1 Ng/L E420.1 0622200511:30 AM Sulfate 45.2 2.5 mg/L SW9038 06202005 7:50 AM Total Dissolved Solids 171 1 mg/L E160.1 06/142005 2:56 PM Nitrogen, Kjeldahl, Total 3.61 10 mg/L E351.2 062320051:34 PM Total Organic Carbon 3.6 1 mg/L SW9060 06/1420051:42 AM • Qualifiers: E - Value above quargitaaon range D - Reauft for Dilution F. = DNution Factor Date Reported: 6272005 Page 9 of 12 Laboratory ager 00 M N O E—1 • U.S. EPA - CLP % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte I EPA SAMPLE NO 7440-43-9 INORGANIC ANALYSIS DATA SHEET P 7440-70-2 .Calcium Lab Name: H2M LABS, INC. Contract: Iron MW -8D Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Matrix (soil/water): WATER Lab Sample ID: 0506329-010 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.65 U P 7440-70-2 .Calcium 10500 P 7439-89-6 Iron 235 P 7439-92-1 Lead 1.7 U P 7439-95-4 Magnesium 7150 P 7439-96-5 Manganese 661 P 7440-09-7 Potassium 9820 P 7440-23-5 Sodium 16400 P Color Before: COLORLESS Clarity Before: CLEAR • Color After: COLORLESS Clarity After: CLEAR Comments: DATE REPORTED JUNE 15, 2005 • Texture: Artifacts: FORM I - IN ILM04.1 F12M LABS, INC. 57561DadHokw Riled Mdvb W 11747 (6M)6 W3M.FAX(631)4208436 WYSDOHID#10478 Town of Southold Landfill • Attn To Collected :6/9200511:30:00 AM Received :6/10/20051:50:00 PM Collected By VG03 Copies To :Original CC LABORATORY RESULTS Lab No.: 0506329-010 Client ID.: MW -8D Sample Information... Type: Groundwater Origin: Parameters) Results Qualili D.F. Vnits Method Number Analyzed Alkalinity, Total (As CaCO3) 44.1 2 mg/L E310.1 06/14/200511:44 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 06/102005 5:20 PM Bromide 0.6 1 mg/L E320.1 06/22/2005 4:05 PM Chloride 23.7 1 mg/L E325.2 06113200512:06 PM Chemical Oxygen Demand 26.8 1 mg/L E410.4 06/16200512:05 PM Hardness (As CaCO3) 60.0 2 mg/L E130.2 06114200510:25 AM Nitrogen, Ammonia (As N) 3.86 10 mg/L E350.1 06122/200511:53 AM Nitrate as N 3.19 5 mg/L E353.2 06/112005 5:06 PM Phenolics, Total Recoverable < 5.0 1 Ng/L E420.1 0622200511:45 AM Sulfate 20.1 1 mg/L SW9038 06202005 7:52 AM Total Dissolved Solids 161 1 mg/L E160.1 06/142005 2:57 PM Nitrogen, Kjeldahl, Total 3.12 10 mg/L E351.2 06/23/20051:34 PM Total Organic Carbon 3.9 1 mg/L SW9060 06/142005 2:11 AM • Qualifiers: E - Value above quantltallon range D - Results for DilutIon i D.F. = Dilution Factor Date Reported : 6272005 Page 10 of 12 ? amom Ax-"� Laboratory Manager O Tt V) N O C/1 E-4 U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -8S Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL002 Matrix (soil/water): WATER Lab Sample ID: 0506329-011 Level (low/med): LOW Date Received: 6/10/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.65 U P 7440-70-2 Calcium 8240 P 7439-89-6 Iron 320 P 7439-92-1 Lead 2.0 B P 7439-95-4 Magnesium 6600 P 7439-96-5 Manganese 596 P 7440-09-7 Potassium 8860 P 7440-23-5 Sodium 16700 P Color Before: COLORLESS Clarity Before: CLEAR Texture: • Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: DATE REPORTED JUNE 15, 2005 • FORM I - IN ILM04.1 U2M LAUS9 INC. 57511oedHdlav R04 MEMIa W 11747 LABORATORY RESULTS (6M)MQX).FAX(8M)4208436 NYSDOHD#10478 Sample Information... Town of Southold Landfill Lab No. : 0506329-011 Type : Groundwater *Attn To : Origin: Collected :6/9/2005 10:50:00 AM Received :8/1020051:50:00 PM Collected By VG03 Copies To :Original CC Client ID.: MW -8S Pammeter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 38.8 1 mg/L E310.1 06/14200511:45 AM Biochemical Oxygen Demand 3 1 mg/L E405.1 06/102005 5:25 PM Bromide < 0.5 1 mg/L E320.1 06/22/2005 4:10 PM Chloride 24.9 1 m91L E325.2 06/13200512:07 PM Chemical Oxygen Demand 14.3 1 mg/L E410.4 06/16200512:06 PM Hardness (As CaCO3) 58.0 2 mg/L E130.2 06114200510:30 AM Nitrogen, Ammonia (As N) 3.60 10 mg/L E350.1 0622200511:54 AM Nitrate as N 3.21 5 mg/L E353.2 06/112005 5:07 PM Phenolics, Total Recoverable < 5.0 1 Ng/L E420.1 0622200512:00 PM Sulfate 18.4 1 mg/L SW9038 06202005 7:54 AM Total Dissolved Solids 142 1 mg/L E160.1 06/142005 2:58 PM Nitrogen, Kjeldahl, Total 3.21 10 mg/L E351.2 062320051:35 PM Total Organic Carbon 3.4 1 mg/L SW9060 06/142005 2:39 AM • Qualifiers: E - Value above quardWon range 0. D - R� for DilutionDilutionF. = Ditution Factor Date Reported: 6272005 Page 11 of 12 Laboratory Manager U2M LABS, INC. • 5. DUPLICATE SAMPLE RESULTS 5.1 METALS 5.2 WET CHEMISTRY • • • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER % Solids for Sample: 0.0 U.S. EPA - CLP 6 EPA SAMPLE NO DUPLICATES MW -1S Contract: SAS No.: SDG No.: TSL002 Level (low/med): LOW % Solids for Duplicate: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L is • FORM VI - IN ILM04.1 jContrAnalyte LimiSample (S) C Duplicate (D) C RPD Q M Cadmium 0.6548 U 0.6548 U P Calcium Iron ---- Lead 5000.0000 --I — 12024.2500 - ----- 554. 9700 1.7430 U _ 12172.7200 571. 4900 1.7430 U 1.2 2.9 P P P Magnesium 5000.0000 7004.8100 7175.2700 2.4 P Manganese 115.0000 _ 17.9300 18.80001 4.7 P Potassium 15000.0000 2052.4000 B 2090.5000B 1.8 P Sodium 43087.1400 43554.2400 1.1 P is • FORM VI - IN ILM04.1 • • 0 H2M LABS, INC. Date: 24 -Jun -05 QC SUMMARY REPORT SDG: TSL002 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Anal_v_te Result Units Amount Result %REC Limits Value %RPD UCL iMBLK061405 IMBLK061405 Alkalinity, Total (As CaCO3) < 1 mg/L _ LCS061405 LCS061405 Alkalinity, Total (As CaCO3) 21.2 mg/L 25 < 1 85 ' 80120 0506329-0 * 02dms MW-1SMS Alkalinity, Total (As CaCO3) 28 8 mg/L 25 3.9 115 75 1: 06 05329 002ddup IMW-1SDUP Alkalinity, Total (As CaCO3) { 4.0 mg/L 3.9 3.8 20 (MBLK061 1 305 jMBLK061305 lAlkalinity, Total (As CaCO3) High <-5 mg/L r LCS061305 LCS061305 Alkalinity, Total (As CaCO3) High 1128 m9/L 125 < 5 102 fi 80 120 j ; IMBLK061005 'MBLK061005 Biochemical Oxygen Demand <2 mg/L r I ILCS061005LCS061005 Biochemical Oxygen Demand 203 mg/L 200 I < 2 102 80 120 1.0506329-002ddup ,MW-1SDUP Biochemical Oxygen Demand <2 mg/L <2 20 _... I _ MB R50421 MB -R50421 Bromide < 0.5 mg/l. _..-_ ILCS R50421 LCS-R50421 Bromide 14.8 mg/L 5 I < 0.5 96 80 120 j Y - — . ` _... _. i. �. 0506329-002DMS �MW-isms Bromide 4.2 mg/L 5 < 0.5 84 75 1125 0506329-002Ddup MW-1SDUP Bromide j < 0.5 j mg/L i < 0.5 20 IMBLK061605 IMBLK061605 (Chemical Oxygen Demand < 10 mg/L I ILCS061605 LCS061605 Chemical Oxygen Demand 1140 mg1L 1000 ! < 10 114 80 :120: 0506329-002cros MW-1SMS Chemical Oxygen Demand 1070 mg/L 1000 < 10 107 75 125' 0506329-002cdup iMW-1SDUP iChemical Oxygen Demand < 10 mg/L < 10 0 20 MB -061305 IMB-061305 Chloride < 2 mg/L LCS-061305 LCS-061305 Chloride 50.3 mg/L 50 < 2 101 80 120 0506329-002DMS MW -ISMS Chloride 97.6 mg/L 25 73.6 96 75 125 0506329-002DDUP MW-1SDUP Chloride 75.2 mg/L 73.6 2.0 20 1 TSL002 S45 0 t • QC SUMMARY REPORT SDG: TSL002 Spike Sample Recovery RPDRet %RPD Sample ID: Client Sa !_pje_ID-: Analvte Result Units Amount Result %REC Limits Value %RPD UCL jMBLK061405 IM13LK061405 Hardness (As CaCO3) < 5 mg/L - II ILCS061405 ICS061405 506329-002bms Mw-1SMS �00506329-002bdup MW-1SDUP Hardness As CaCO3) Hardness (As CaCO3) Hardness (As CaCO3) 1040 268 62.00 mg/L mg/L - mg/L 1000 <5 104 80 -i()0 162.0 I 103 ; 75 -1 20 125 i 62.0 0 20 mb-061105 mb-0611051 Nitrate as N < 0.1 mg/L Ics-061105 Ics-061105 �MW-1SMS Nitrate as N 1.05 mg/L 1 1.13 < 0.1 93 80 120 j 0506329-002CMS Nitrate as N 10.3 m9/L f 5 5.35 99 75 125 j __. 0506329-002CDUP MW-1SDUP _ (Nitrate as N 5.41 mg/L i _ j 5.35 1.2 20 l _en, Ammonia ( ) g IN 9 1 CS1139115 CS -062205 tro en, Ammonia As N 1.105 m L 1 < 0.1 115 80 0506329-002CMS �MW-1SMS Nitrogen, Ammonia As N) 5.57 mg/L g L 5 I 0.12 ! 109 1120 75 125 I 1 10506329-002CDUP MW-1SDUP INitrogen, Ammonia (As N) 0.11 mg/L 0.12 I 6.8 j 20 mb-13925 mb-062305 Nitrogen, Kjeldahl, Total < 0.1 mg/L Ics-13925 flcs-062305 g_ i Nitrogen, Kjeldahl, Total 4.11 , mg/L j 4.1 < 0.1 100 � 80 120 0506329-002CMS _. !Mw-isMS , Nitrogen, Kjeldahl, Total I 3.90 mg/L 4.1 0.16 91 If 75 125 i 10506329-002CDUP MW-1SDUP Nitrogen, Kjeldahl. Total 0.11 mg/L 0.16 40.9 20 :MB -062205 MB -062205 Phenolics, Total Recoverable < 5 ug/L LCS-062205 LCS-062205 Phenolics, Total Recoverable 29.3 ug/L 30 < 5 98 80 120 10506329-002CMS 'MW-1SMS Phenolics, Total Recoverable 19.6 ug/L 20 < 5 98 75 125 10506329-002Cdup MW-1SDUP 'Phenolics, Total Recoverable < 5 ug/L < 5 20 MBLK 062005 (- MBLK 062005 Sulfate < 5 f. < mg/L LC S 062005 (LCS-062005 Sulfate 19.3 L 20 5 96 80 120 0506329-0021DMS Mw- 1SMSSulfate 73.5 mg/L I 50 I 23. 100 75 125 I8 --- 0 506329-002DDUP ...-. I MW-1SDUP lfat e . Sulfate 24.2 mg/L 23.8 21 20 2 TSL002 S46 0 0 0 QC SUMMARY REPORT SDG: TSL002 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MBLK061405 �MBLK061405 Total Dissolved Solids <10 mg/L LCS06I405 LCS061405 'Total Dissolved Solids 313 mg/L 300 < 10 104 80 120 1 0506329-002dms �MW-ISMS (Total Dissolved Solids 549 mg/L 300 223 109 75 125 0506329-002ddup MW-ISMS iTotal Dissolved Solids 209 mg/L 223 6. I_ 5 20 MBLK-061305 IlMBLK-061305 Total Organic Carbon < 1 mg/L LCS-061305 rLCS-061305 4 - ---- Total Organic Carbon 26.6 (Total mg/L 25 < 1 106 80 120 0506329-002AMS IMW-ISMS Organic Carbon 10 -- mg/L 10 < 1 100 75, 125 0506329-002ADUP IMW-1SDUP ,Total Organic Carbon 1.2 mg/L + <1 200 20 3 TSL002 S47 U2M "US, INC. • 6. SPIKE SAMPLE RESULTS 6.1 METALS 6.2 WET CHEMISTRY C • • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER % Solids for Sample: 0.0 U.S. EPA - CLP 5A SPIKE SAMPLE RECOVERY Contract: SAS No.: EPA SAMPLE NO MW-lss SDG No.: TSL002 Level (low/med): LOW Concentration Units (ug/L or mg/kg dry weight): UG/L Control Limit Analyte %R Spiked Sample Result (SSR) C Sample Result (SR) Spike C Added (SA) %R Q M Cadmium 75-125 49.8400 0.6548 U 50.00 99.7 P Iron _ 75-125 1562.5900 554.9700 1000.00 100.8 P Lead 75-125 21.6253 1.7430 U 20.00 108.1 P Manganese 75-125 529.1200 17.9300 500.00 102.2 P Comments: • FORM V (Part 1) - IN ILM04.1 0 0 0 112M LABS, INC. Date: 24 -Jun -0 QC SUMMARY REPORT SDG: TSL002 Spike Sample Recovery RPDRef %RPD Sample IDc Chent_SamDle ID: Analyte . __- - Result Units Amount Result %REC Limits Value %RPD UCL MBLK061405 MBLK061405 Alkalinity, Total (As CaCO3) <1 i mg/L LCS061405 LCS061405 Alkalinity, Total (As CaCO3) 21.2 mg/L 25 < 1 85 80 120 _.. 0506329 002dms MW-1SMS Alkalinity, Total (As CaCO3) 28 8 mg/L 25 3 9 115 75 125 0506329 002ddup MW-1SDUP Alkalinity, Total (As CaCO3) 4.0 mg/L 3.9 3 8 20 MBLK061305 �MBLK061305 Alkalinity, Total (As CaCO3) High < < 5 mglL f LCS061305 �LCS061305 Alkalinity, Total (As CaCO3) High 1128 ' mg/L 125 � < 5 r 102 �80 120 MBLK061005 IMBLK061005 Biochemical Oxygen Demand < 2 mglL LCS061005 LCS061005 Biochemical Oxygen Demand 203 mg/L 200 < 2 102 80 120 -- - — 0506329-002ddup MW-1SDUP Biochemical Oxygen Demand <2 mg/L <2 20 MB R50421 SMB R50421 Bromide <0 5 mg/L I ... I-_ LCS R50421 LCS-R50421 Bromide i 4.8 I m<yL 5 < 0.5 I 96 80 120 0506329 002DMS fMw_isms. Bromide 14.2 mg/L 5 4 < 0.5 84 75 11 ;0506329-002Ddup MW-1SDUP Bromide i < 0.5 mg/L < 0 5 20 MBLK061605 !MBLK061605 !Chemical Oxygen Demand LCS061605 L(;b061605 Chemical Oxygen Demand 10506329-002cros MW-1SMS Chemical Oxygen Demand 10506329-002cdup iMW-1SDUP (Chemical Oxygen Demand MB 061305 IMB-061305 (Chloride LCS-061305 LCS-061305 �Mw_isms Chloride 0506329-002DMS < 10 Chloride 0506329-002DDUP BMW-1SDUP Chloride TSL002 S50 < 10 mg/L 1140 mg/L 1000 i < 10 114 80 120 1070 mg/L 1000 < 10 107 75 :125 < 10 mg/L I < 10 i 0 20 ; .. ii 50.3 n g/L _ 50 < 2 1011 80 97.6 mg/L – 25 f 73.6 I 96 75 125 r 75.2 mglL 73.6 2.0 120 1 • • t QC SUMMARY REPORT SDG: TSL002 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID:_ Analyte Result Units Amount Result %REC Limits value %RPD UCL MB LK061405 iMBLK061405 Hardness (As CaCO3) < 5 mg/L I - --._..- ILCS061405 ;LCS061405 Hardness (As CaCO3) 1040 mg/L 1000 I <5 j 104 180 120 -_...) -- -- - --L I 162.0 0 0506329268MW-1SMS Hardness (As CaCO3 268 m9/L 200 62.0 103 75 125; (0506329-002bdup MW-1SDUP Hardness (As CaCO3) 62.0 mg/L l.. I. lmb-061105 Amb -061105 Nitrate as N ,,0.-1-M 9/L, I Ics-061105 ics-061105 Nitrate as N 1.05 mg/L 1.13 <0.1 93 80 120, 5 5 35 99 75 125 0506329-002CDUP MW-1SDUP Nitrate as N 5 41 mg/L i 5.35 1.2 120 MB -13915 L. SMB -062205 Nitrogen, Ammonia (As N) < 0.1 mg/L _. LCS 13915 ,LCS-062205 Nitrogen, Ammonia (As N) 1.15 1 1 < 0.1 115 80 120 - 0506329-002CMS - -- IMW-1SMS Nitrogen, Ammonia (As N) 5.57 mg L g 5 0. 2 109 75 125 0506329-002CDUP 'MW-1SDUP !Nitrogen, Ammonia (As N) 0.11 mg/L 0.12 6.8 i 20 mb-13925 Imb-062305 'Nitrogen, Kjeldahl, Total < 0.1 m g/L lcs-13925 Ics-062305 Nitrogen, Kjeldahl, Total 4.11 mg/L 4.1 < 0.1 100 80 120 :0506329-002CMS ,MW-1SMS Kjeldahl, Total 3.90 mg/L 4.1 0.16 91 75 125 !0506329-002CDUP 1.MW-1SDUP (Nitrogen, Nitrogen, Kjeldahl, Total 0.11 mg/L I 0.16 40.9 20 ;MB -062205 MB -062205 'Phenolics, Total Recoverable < 5 ug/L �-_�. .._ ------_--- -- :LCS-062205 -=--- _ ___ _ LCS-062205 --- _------------------- Phenolics, Total Recoverable 29.3 ug/L 30 << 5 98 _ 80 120 '..__..,-_------- 10506329-002CMS ,MW-1SMS !Phenolics, Total Recoverable 19.6 ug/L 20 < 5 98 75 125 0506329-002Cdup 'MW-1SDUP (Phenolics, Total Recoverable < 5 ug/L < 5 20 5 'MBS 5 mg/L ` 96 CS 062005 062005 Sulfate 19.3 ; 20 5 ' l 80 120 !0506329-002DMS MW -ISMS Sulfate 73.5 mg/L 50 23.8. 100 75 125 110506329-0020DUP BMW-1SDUP ..-- Sulfate __ ..._ 24.2 ` mg/L I i _ � 23.8 2.1 20 j P TSL002 S51 0 0 0 QC SUMMARY REPORT SDG: TSL002 MBLK-061305 MBLK-061305 Total Organic Carbon < 1 m9/L Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: „Analyte Result Units Amount Result %REC Limits Value %RPD UCL MBLK061405 0506329-002ADUP �IVIBLK061405 jTotal Dissolved Solids < 10 mg/L j LCS061405 LCS061405 jTotal Dissolved Solids 313 300 < 10 104 80 120 0506329-002dms MW-1SMS (Total Dissolved Solids _f_mg/L 549 mg/L 300 223 109 75 125 66329-00 052ddup _..- MW-1SDUP Total Dissolved Solids ----- 209 mg/L -- - 223 ` 6.5 20 MBLK-061305 MBLK-061305 Total Organic Carbon < 1 m9/L LCS-061305 LCS-061305 Total Organic Carbon j 26.6 mg/L 25 < 1 106 80 120 0506329-002AMS MW-1SMS Total Organic Carbon ; 10 mg/L 10 < 1 100 75 125 0506329-002ADUP MW-1SDUP Total Organic Carbon 1.2 mg/L I I < 1 200 1 20 3 TSL002 S52 U2M LABS, 1%C. • 7. BLANK SUMMARY DATA AND RESULTS 7.1 METALS 7.2 WET CHEMISTRY • 0 • U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L SDG No.: TSL002 Analyte Initial Calib. Blank (ug/L) C Continuing Blank 1 C Calibration (ug/L) 2 C 3 C Prepa- ration Blank C M Cadmium 0.7 U 0.7 U 0.9 B 0.7 U 0.655 U P Calcium 29.3 U 29.9 B 29.3 U 29.3 U 29.300 U P Iron 10.8 B 19.3 B 15.3 B 14.4 B 5.820 B P Lead 1.7 U 1.7 U 1.7 U 1.7 U 1.743 U P Magnesium 6.9 U 25.9 B 10.5 B 6.9 U 6.922 U P Manganese 1.2 U 1.2 U 1.2 U 1.2 U 1.239 U P Potassium 58.6 B 50.5 B 54.51 B 39.6 U 40.900 B P Sodium 44.3;B _ 26.6 B 38.2 B 137.0 B 23.600 U P • FORM III - IN ILM04.1 0 • U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L SDG No.: TSL002 Analyte Initial Calib. Blank (ug/L) C Continuing Calibration Blank (ug/L) 1 C 2 C 3 Prepa- ration C Blank C M Cadmium 0.7 B P Calcium _ 29.8 B P Iron 21.6 B P Lead 1.7 U IP Magnesium 28.0 B P Manganese 1.2 U P Potassium 54.9 B P Sodium _ _ 36.1 B P . FORM III - IN ILM04.1 0 0 0 H2M LABS, INC. Date: 24 -Jun -05 QC SUMMARY REPORT SDG: TSL002 IMBLK061305 !MBLK061305 Alkalinity, Total (As CaCO3), High <5 mg/L LCS061305 �L061305 Alkalinity, Total (As CaCO3), High 1128 4 mg/L L 125 < 5 I 102 80 CS { 120 MBLK061005 MBLK061005 Biochemical Oxygen Demand < 2 mg/L i LCS061005 LCS061005 Biochemical Oxygen Demand 203 mg/L 200 < 2 102 i 80 120 0506329-002ddup MW-1SDUP Biochemical Oxygen Demand < 2 mg/L ! <_2 20 MB R50421 -- MB R50144241 - Bromide < 0 5 mg/L mg/L Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MBLK061405 MBLK061405 ILCS061405 Alkalinity, Total (As CaCO3) m9/L < 1 mg/L 84 75 125 t 20 0506329-002Ddup jMW-1SDUP Bromide ! <p:5 mg/L IMW-1SDUP Chemical Oxygen Demand Y9_ LCS061405 < 0 5 Alkalinity, Total (As CaCO3) 21.2 mg/L 25 < 1 85 80 120 0506329 002dms mw- isms Alkalinity, Total (As CaCO3) Chloride 28.8 mg/L 25 3.9 115 75 125 65_C6_29_-6_0_2_ddup Alkalinity, Total (As CaCO3) 1-4.-0 mg/L MW-1SMS I 97.6 mg/L -- 25 73.6 3.9 3.8 20 0506329 002DDUP IMBLK061305 !MBLK061305 Alkalinity, Total (As CaCO3), High <5 mg/L LCS061305 �L061305 Alkalinity, Total (As CaCO3), High 1128 4 mg/L L 125 < 5 I 102 80 CS { 120 MBLK061005 MBLK061005 Biochemical Oxygen Demand < 2 mg/L i LCS061005 LCS061005 Biochemical Oxygen Demand 203 mg/L 200 < 2 102 i 80 120 0506329-002ddup MW-1SDUP Biochemical Oxygen Demand < 2 mg/L ! <_2 20 MB R50421 -- MB R50144241 - Bromide < 0 5 mg/L mg/L f R50421 0421Bromide 4 8 mg/L 5 < 0.5 96 80--0506329-002DMS _- _— 1SMS -- - Bromide 4.2 Bromide I m9/L 5 < 0.5 84 75 125 t 20 0506329-002Ddup jMW-1SDUP Bromide ! <p:5 mg/L IMW-1SDUP Chemical Oxygen Demand Y9_ <en < 0 5 IMBLK061605 IMBLK061605 I Chemical Oxygen Demand < 10 mg/L LCS061605 LCS061605 !Chemical Oxygen Demand 1140 mg/L 1000 ! < 10 114 80 120! Demand 70 010 1000 < 10 107 75 125 i� 0506329 002cdu p IMW-1SDUP Chemical Oxygen Demand Y9_ <en mg/L < 10 0 20 I I, MB -061305 MB -061305 TChloride < 2 mg/L LC_ - 61305 LCS-061305 Chloride 50.3 mg/L 50 I < 2 101 80 120 I 1 0506329-002DMS MW-1SMS Chloride 97.6 mg/L -- 25 73.6 96 75 125 0506329 002DDUP MW-1SOUP Chloride 75.2 mg/L 73.6 2.0 20 TSL002 S56 SDG: TSL002 • QC SUMMARY REPORT mb-061105 mb-061105 Nitrate as N < 0.1 < 0.1 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits value %RPD UCL MBLK061405 MBLK061405 Hardness (As CaCO3) 1 <5 mg/L 199 5.41 ! mg/L i l -- 1MW-1SDUP ! LCS061405 ' CS061405 Hardness CaCO3) 1040 mg/L 1000 ', < 5 104 80 120 0506329 002bm 0506329-002CDUP -- - MW -ISMS (As - _ Hardness CaCO3) 268 m9/L 200 62.0 103 75 125 10506329-002bdu P ;MB -062205 MW-1SDUP (As Hardness As CaCO3) 62.0 mg/L t ! 62.0 0 20 ; mb-061105 mb-061105 Nitrate as N < 0.1 < 0.1 i Ics 061105 Ics 061105 Nitrate as N 1 05 mg/L 1.13 < 0.1 93 80 120 1 0506329-002CMS MW -ISMS Nitrate as N 10.3 mg/L 5 5.35 75 125I 5 57 ! mg/L 0506329-002CDUP MW -1 SDUP Nitrate as N 199 5.41 ! mg/L i l -- 1MW-1SDUP 5.35 1.2 20 IMB 13915 IMB-062205 Nitrogen Ammonia (As N) I < 0.1 mg/L < 0.1 i l ILCS-13915 ICS -062205 Nitrogen Ammonia (As N) i 1.15 � mg/L 1 < 0.1 115 ! 80 120 0.66i329-002CIVIS Mw-_ 1 SMS Nitrogen, Ammonia (As N) 5 57 ! mg/L 5 0.12 i 109 75 125 0506329-002CDUP -- 1MW-1SDUP - Nitrogen, Ammonia (As N) ._.. 0.11 mg/L Nitrogen, Kjeldahl, Total -.... 3.90 0.12 6.8 20 mb-13925 Amb -062305 Nitrogen, Kjeldahl, Total < 0.1 m9/L j _ Ics-13925 �0506329-002CIVIS Ics-062305 _. _ Nitrogen, Kjeldahl, Total 4.11 mg/L 4.1 < 0.1 ! 100 180 120 ---- _.. MW-ISMS Nitrogen, Kjeldahl, Total -.... 3.90 mg/L 4.1 0.16: _ 91 I , 75 125 'i ! 0506329-002CDUP _. iMW-1SDUP Nitrogen, Kjeldahl, Total 0.11 mg/L j ! 0.16 40.9 20 MB -062205 ;MB -062205 ;Phenolics, Total Recoverable < 5 ug/L 'ILCS-062205 LCS-062205 iPhenolics, Total Recoverable 29.3 ug/L l 30 < 5 98 80 !120' 0506329-002CMS iMW-ISMS (Phenolics, Total Recoverable 19.6 ug/L I 20125 <5 98 75 10506329-002Cdup IMW-1SDUP ;Phenolics, Total Recoverable ! < 5 ug/L ( ! < 5 1 20 �MBLK 062005 MBLK 062005 Sulfate 5 I. mg /L ILCS 062005 - LCS-062005 - }Sulfate 19.3 mg/L 20 ` <5 i 96 80 120 0506329 002DMS MW -ISMS Sulfate 73.5 mg/L 50 23.8 100 75 125 0506329 002DDUPL _ MW-1 SDUP Sulfate 24 2 � mg/L � I ! I 23.8 I 2.1 20 2 TSL002 S57 0 0 0 QC SUMMARY REPORT SDG: TSL002 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MBLK061405 MBLK061405 Total Dissolved Solids < 10 mg/L LCS061405 jLCS061405 Total Dissolved Solids 313 mg/L 300 < 10 104 80 120 0506329-002dms MW-1SMS Total Dissolved Solids 549 mg/L 300 223109 75 125 ---- - – — — -- _-- _ --... I 0506329-002ddup MW-1SDUP Total Dissolved Solids 209 mg/L 223 6.5 20 MBLK-061305 �MBLK-061305 Total Organic Carbon < 1 mg/L I LCS-061305 LCS-061305 Total Organic Carbon 26.6 mg/L 25 < 1 106 80 120 0506329-002AMS MW -1 SMS Total Organic Carbon 10 mg/L i 10 < 1 100 75 125 0506329-002ADUP MW-1SDUP iTotal Organic Carbon 1.2 mg/L < 1 200 20 3 TSL002 S58