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Home My WebLink AboutSample Data Summary Package 04/2005Analytical Data Package For TOWN OF SOUTHOLD PART 360 BASELINE SDG NO: TSL001 Water Samples Received: 4/1/05 & 4/4/05 SAMPLE DATA SUMMARY PACKAGE APRIL 2005 F-IrIM I INL S 40 EInvironmental Testing Laboratories 575 Broad Hollow Road, Melville, N.Y. 11747 0 • • U2M "US, INC. SAMPLE DATA SUMMARY PACKAGE TABLE OF CONTENTS TOWN OF SOUTHOLD PART 360 BASELINE SAMPLES RECEIVED: 4/1/05 & 4/4/05 SDG #: TSL001 1. NYS DEC SUMMARY FORMS 2. CHAIN OF CUSTODY DOCUMENTATION 3. SDG NARRATIVES 4. SAMPLE REPORTS 4.1 VOLATILES 4.2 METALS 4.3 WET CHEMISTRY 5. SURROGATE SPIKE ANALYSIS RESULTS 5.1 SEMIVOLATILES 6. MATRIX SPIKE / MATRIX SPIKE DUPLICATE SUMMARY 6.1 VOLATILES 7. DUPLICATE SUMMARY RESULTS 7.1 METALS 7.2 WET CHEMISTRY 8. SPIKE SAMPLE RESULTS 8.1 METALS 8.2 WET CHEMISTRY 9. BLANK SUMMARY DATA AND RESULTS 9.1 VOLATILES 9.2 METALS 9.3 WET CHEMISTRY 10. INTERNAL STANDARD AREA DATA 10.1 VOLATILES U2M 1_,AUS, INC. • 1. NYS DEC SUMMARY FORMS • • NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE IDENTIFICATION AND ANALYTICAL REQUIREMENT SUMMARY SDG: TSL001 Anal ical Re uirements C Customer Laboratory Sample Sample ME Ms W Code Code 'MW -3D — ! 0504024-001 X X X MW -3S 0504024-002 X X X MW -5D 0504024-003 X X X Mw -5S 0504024-004 X X X iMW-6D 0504024-005 X X X MW -6S 0504024-006 X X X MW -81) 0504024-007 X X X MW -8S 0504024-008 X X X --- --- --- - - -- -- 'EQUIPT. BLANK 0504024-009 X X X ---------- TRIP BLANK 4/1/05 0504024-010 x MW -1D 0504067-001 X —X -4--x MW 1s ! 0504067-002 X X L- X -- - -_ TB 4-4-05 ! 0_504067-003 X � 1 CLP, on -C (Please indicate year of protocol) AS? � ;.I cj5 TCUTAL, HSL, Priority Pollutant, ujztij�s- M Cn O O C/1 •NEW YORK STATE DEPARTMENT OF ENV&MENTAL CONSERVATION • SAMPLE PREPARATION AND ANALYSIS SUMMARY VOLATILE (VOA) SDG: TSL001 ANALYSES Laboratory Analytical Date DateRecd i Date Date i Extraction ! j Samp ID Client Sample ID Matrix , Protocol ' Collected ; at Lab ;Extracted�Analyzed I Method DF Level Aux Cleanup 0504024-001A MW -3D Aqueous ! ASP 95-1 01 -Apr -05101 -Apr -05 04 -Apr -05 1 LOW 0504024-002A MW -3S Aqueous ASP 95-1 01 -Apr -05 ! 01 -Apr -05 j 04 -Apr -05 I I LOW 0504024-003A MW -5D Aqueous ASP 95-1 O1 -Apr -05 01 -Apr -051 04 -Apr -05 1 LOW 0504024-004A MW -5S Aqueous ASP 95-1 01 -Apr -05 ! 01 -Apr -05 04 -Apr -05 I LOW 0504024-005A MW -6D Aqueous ASP 95-1 01 -Apr -05 01 -Apr -05 04 -Apr -05 I LOW 0504024-006A MW -6S Aqueous ASP 95-1 O1 -Apr -05 OI -Apr -05 04 -Apr -05 1 LOW 0504024-007A MW -8D j Aqueous ASP 95-1 ! 01 -Apr -05 01 -Apr -05 i 04 -Apr -05 I I ! LOW 0504024-008A MW -8S Aqueous ASP 95-1 O1 -Apr -05 01 -Apr -05 04 -Apr -05 1 LOW 0504024-009A EQUIPT. BLK Aqueous ASP 95-1 O1 -Apr -05 01 -Apr -05 04 -Apr -05 I LOW 0504024-01OA ITB 4/1/05 Aqueous ASP 95-1 O1 -Apr -05 01 -Apr -05 ` 04 -Apr -05 j I j LOW 0504067-001A ;MW -ID Aqueous ASP 95-1 04 -Apr -05 04 -Apr -05I 04 -Apr -05 1 LOW 0504067-002A !MW -IS Aqueous ASP 95-1 104 -Apr -05 04 -Apr -05 04 -Apr -05 1 LOW 0504067-002AMS BMW - ISMS Aqueous ASP 95-1 ' 04 -Apr -05 04 -Apr -05 ! 04 -Apr -OS 1 LOW 0504067-002AMSD MW- ISMSD Aqueous ASP 95-I 104 -Apr -05 04 -Apr -05 04 -Apr -05 1 LOW 0504067-003A TB 4-4-05 Aqueous ASP 95-1 04 -Apr -05 04 -Apr -05 04 -Apr -05 1 LOW TSL001 S4 • SDG: TSI -001 NEW I • E YORK STATE DEPARTMENT OF E�ONMENTAL CONSERVATION O SAMPLE PREPARATION AND ANALYSIS SUMMARY INORGANIC ANALYSIS Laboratory Client Sample ID IDateRecdI Date Samp ID p Matrix I Metals Requested at Lab � Analyzed 0504024-001 MW -3D WATER AG.AL,AS.B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01 -Apr -05 04/05 0504024-002 M\L'-3S WATER AG,AL,AS.B, BA, BE, CA,CD,CN,CO,CR,CU,FE. HG, K,MG,MN,NA, NI,PB,SB,SE,TL,V,ZN, 01 -Apr -05 04/05 0504024-003 MW -5D WATER AG,AL,AS.B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01 -Apr -05 , 04/05 0504024-004 ;MW -5S WATER AG,AL,AS,B,BA,BE,CA.CD,CN,CO,CR,CU,FE.K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01 -Apr -05 04/05 0504024-005 MW -6D WATER AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01 -Apr -05 04/05 0504024-006 IMW-6S WATER i AG,AL.AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01 -Apr -05 04/05 0504024-007 MW -8D WATER AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01 -Apr -05 04/05 0504024-008 !MW -8S WATER AG,AL.AS,B,BA,BE,CA,CD,CN,CO.CR,CU,FE.HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01 -Apr -05 04/05 0504024-009 iEQUIPT. BLANK WATER AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01 -Apr -05 04/05 0504067-001 !MW -ID j WATER AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 04 -Apr -05 04/05 0504067-002 MW -Is WATER AG.AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 04 -Apr -05 04/05 0504067-0021)UP IMW-ISD WATER I AGAL,AS,B,BA,BE,CA,CD,CN,CO.CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 04 -Apr -05 04/05 0504067-002MS MW -ISS WATER AG,AL,AS,B,BA,BE.CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 04 -Apr -05 04/05 TSL001 S5 NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG. TSI -001 INORGANIC ANALYSIS Laboratory Samp ID Client Sample ID Matrix Tests DateRecd j I at Lab j Date Analyze 0504024-001 ; MW -3D Groundwater SELECT WET CHEMISTRY" 04/01/05 04/05 0504024-002 MW -3S Groundwater SELECT WET CHEMISTRY " 04/01/05 ! 04/05 0504024-003 'MW -5D Groundwater SELECT WET CHEMISTRY " I 04/01/05 04/05 0504024-004 i MW -5S Groundwater SELECT WET CHEMISTRY" 04/01/05 04/05 0504024-005 MW -61) ; Groundwater SELECT WET CHEMISTRY " 04/01/05 04/05 0504024-006 MW -6S Groundwater SELECT WET CHEMISTRY " 04/01/05 04/05 0504024-007 MW-8D5Groundwater SELECT WET CHEMISTRY " 04/01/05 04/0 0504024-008 MW -8S Groundwater SELECT WET CHEMISTRY " 04/01/05 04/05 0504024-009 EQUIPT. BLANK Blank SELECT WET CHEMISTRY " I 04/01/05 04/05 0504024-010 TRIP BLANK 4/1/05 j Blank SELECT WET CHEMISTRY " 04/01/05 04/05 0504067-001 MW -ID Groundwater SELECT WET CHEMISTRY" 04/04/05 i 04/05 0504067-002 MW -1S Groundwater i SELECT WET CHEMISTRY" I 04/04/05 04/05 0504067-003 TB 4-4-05 Trip Blank SELECT WET CHEMISTRY " 04/04/05 I 04/05 • ** 1,1,1,2 -Tetrachloroethane ; 1,1,1 -Trichloroethane ; 1,1,2,2 -Tetrachloroethane ; 1,1,2 - Trichloroethane ; 1,1-Dichloroethane ; 1,1-Dichloroethene ; 1,2,3-Trichloropropane ; 1,2- Dibromo-3-chloropropane ; 1,2-Dibromoethane ; 1,2 -Dichlorobenzene ; 1,2- Dichloroethane ; 1,2-Dichloroethane-d4 ; 1,2-Dichloropropane ; 1,4 -Dichlorobenzene ; 2- Butanone ; 2-Hexanone ; 4-Bromofluorobenzene ; 4-Methyl-2-pentanone ; Acetone ; Acrylonitrile; Alkalinity, Total (As CaCO3) ; Alkalinity, Total (As CaCO3), High ; •Aluminum; Antimony; Arsenic; Barium; Benzene; Beryllium; Biochemical Oxygen Demand; Boron; Bromide; Bromochloromethane ; Bromodichloromethane ; Bromoform ; Bromomethane ; Cadmium; Calcium; Carbon disulfide ; Carbon lH2M ILAUS, INC. • 2. CHAIN OF CUSTODY DOCUMENTATION 9 1-1 LAI3S, INC. 575 Br ollow Rd, Melville, NY 11747-5076 '�� EXTERNAL CHAIN OF CUSTODO Tel: (516) 694-3040 Fax: (516) 420-8436 CLIENT: S'ct 6iTH64�,o 1H2M SDG NO: 00 PROJECT NAME/NUMBER NOTES: Project Contact: ` D ��oSt P', C -i, V G-- j� }� (� I �o oU a S (I I l�J ( Phone Number: ��G S�� U E ° 1 ( C` �% G� (V�i/� r 7 SAMPLERS: (signature)/Client �' —' T DELIVERABLES: r- o c Z ro ANALYSIS _REQUESTED TURNAROUND TIME: 2i : t° U ORGANIC S► INORG. Q O> Q m „ m a o .L ~' n4 z Z V DATE TIME MATRIXFIELD I.D. LAB I.D. NO. REMARKS: bs opo o Ivy VJ M K, i i 'ol i I — 0Ci36, '.41 � f L /3;� 1000 lzco C Relinquished by: (Signature) Date i ime Received by: (Signature) ate I Time LABORATORY USE ONLY zz ^, ...,j i ! GLl/ Discrepancies Between Sample Labels and Samples were: t. Shipped, or Hand Delivered_ Airbill# 2. Ambient or chilled Relingwshed by (Signature) Date Time R ived : (Signilylil Palte . Time COC Record? Y or N 3. Received in good condition: Y or N Explain: 4. Properly preserved: Y or N S. Samples returned to lab _ Hrs from collection. Relinquished by: (Signature) Date Time Received by: (Signature) Date Time COC Tape was: 1. Present on outer package: Y or N 2. Unbroken on outer package: Y or N Relinquished by: (Signature) Date Time Received by: (Signature) Date Time 3. COC record present & complete upon sample receipt: Y or N TSWQJE�&PY - ORIGINAL YELLOW COPY - CLIENT PINK rnPY - I aRnRATnRy H2M LABS, INC. -T( �I- o 1 01 Sample Receipt Checklist Client Name PCTSL Date and Time Receive 4/1/2005 4:20:00 PM Work Order Numbe 0504024 Received by BGL — Checklist completed b `—f / p / �f e_ z _ S' � 1 / (� Reviewed by we ate In asf T Date Matrix Carrier name Hand Delivered Shipping container/cooler in good condition? Yes No L ) Not Applicable ❑ Custody seals intact on shippping container/cooler? Yes [V No ❑ Not Applicable ❑ Custody seals intact on sample bottles? Yes J No ❑ Not Applicable lw Chain of custody present? Yes No ❑ Chain of custody signed when relinquished and received? Yes (✓1 No ❑ Chain of custody agrees with sample labels? Yes 11/1 No 1- 1 Samples in proper container/bottle? Yes C] No Sample containers intact? Yes ILIA, No ❑ Sufficient sample volume for indicated test? Yes ;d] No SII samples received within holding time? Yes 1%j1No EJ 4ntainedfemp Blank temperature in compliance? Yes -Y!f No 49 Water - VOA vials have zero headspace? No VOA vials submitted L1 Yes V No C_i Water - pH acceptable upon receipt? Yes !i No L_I Adjusted? Checked b Any No and/or NA (not applicable) response must be detailed in the comments section b Client contacted Date contacted: ) Person contacted Contacted by: Regarding Comments: f2M t A US INC. t• INTERNAL CI:GAIN OF CUSTODY CLIENT LIVERABLES: PTURNAROUND TIME: I SDG CASE MATRIX: �t pH C}irCK y., • VOLATILE P 0205 J OWA tAus, V*W. ro i i INTERNAL CHAIN OF CUSTODY SAMPLE PURPOSE OF RELINQUISHED SAMPLE BOTTLE CHANGE OF D TETIHE BY RECEIVED BY TYPE CUSTODY INIT 46- Ell slow slow slawS1008100 SIow elan Slow slow 31 Ow ' slow 1 l orr slow 110w Slow 1ICw slow SICPO slow SICN 310n SIGN JIOx SIGN 11011 1IGN 11Ox SIGN Slow 11014 Slow SIGN SIOM SIGN ;T Slow _ slow Slow JIOw 11014 1I0x 1ICx 3IOw SICN now SICN VOLATILE P 0206 --..I r-..4 v/ 0 cn H i N2M► ILAUS, Nc. INTERNAL CHAIN OF CUSTODY ' CLIEN t J DELIVERABLES: - TURN AROUND TUAE: ( S SDG It: _ CASE #:� j (' MATRIX _6 I.ti „w r lwrvlv- X. METALS P 02,514 N �M L VK �!• CLIRNT: jIN'T'ERNAL CHA Tu nz• �,T,,,..,,.�__ no I0 MrrALs P U26( WA tAUs, INC. • INTERNAL CHAIN OF CUSTODY c __ CLIENT, ?�`r�L. DELIVERABLES: AROUND TIME: SDG #: 'T S QQ I CASE #: MATRIX: PH ctEc Y N REMARKS: RECEIVED BY: SIGNATURE: DATE:�� • WET CHEMISTRY ::2-wf WIJVS'w P 024'7 0 • WET CHEMISTRY ::2-wf WIJVS'w P 024'7 WA UAUS, INC. 6 I P HZITTul�r INTERNAL CHAIN OF CUSTODY tj� �_ J3•c'C WET CI-IEMIS"TRY Fri kotjt O�- /,n- — - sz$( IA C�- W) cn 0 N SAMPLE RELINQUISHED SAMPLE BOTTLE TYPE PURPOSE OF CRAMS OF CUSTODY INIT DATE TIM 1py ECEIVED BY Z ,yi jZ:�o °01 slob s !I a 17-30 !I c tF�� "49 1-S-aS w-.00 sI !I °aLS 1 1 • l � l l� � �J yhos j a ' o C — !I !I _ j 1 •.VJI I SI - iJ f1 ,, > • Gij/ !I !IO SI /� K os— !I SIC ! sic sI �-} slS Of sl 7/7/05-- tj� �_ J3•c'C WET CI-IEMIS"TRY Fri kotjt O�- /,n- — - sz$( IA C�- W) cn 0 N f -12A U AUS, INC. IHNT SDG #: S� W INTERNAL CHAIN OF -CUSTODY • WET CHEMISTRY P 0249 PURPOSE OF DATE TIME SAMPLE RELINQUISHED BY SAMPLE RECEIVED BY BOTTLE TYPE COF CUSTODY CUSTODY INIT lImt !I fy 000) fI I I Y- g- os /1: p0 !I Si17 MVV Y -g -o rY-oo ,law lIGOt %' �i slow-- slow �^ Y olw 10 slow KS 7KA,- q:.o ,IOrt ,IOr1 3l ow sIGY t, 39 Slow WOW . sIc" SIGN Q L slow SIGN slaw SIGN LION SIGN 9100 SIGN SION SIGN s1 Oil 91 oN 31" Slow .ION SIGN s1Ow SIO" - slow SIOrt LION SIGN LION sl GN slow SIGN slow SIGN i SION SIGN • WET CHEMISTRY P 0249 U26t LA US, INC. 575 Broad Hollow Rd, Melville, NY 11747-5076 030 EXTERNAL CHAIN OF CUSTODA Tel: (516) 694-3040 Fax: (516) 420-8436 CLIENT: SC (IT HOL)IO 11-12M SDG N0-7-'�-00 I PROJECT NAME/NUMBER TvrvN c"F= sc'c�TM�'�r7 O R r 36 C 4SFL 1I�/ < < E -_♦ i JE ? _ 3 g o� S —3 NOTES: Project Contact: PTS / V G' BQD 5 Bi -(J Phone Number: ) J CJ I o r / r (0J �( �I 23 x 1 b 2- SOLITa Ik�'TDS� TvYb SAMPLERS: (signature)/Client DELIVERABLES: '6 r Z c v H 1 ANALYSIS REQUESTED TURNAROUND TIME: Da S ORGANIC INORG. DATE TIME MATRIX FIELD I.D. 0 to ' ` 3 -o Z V LAB I.D. NO. REMARKS: Relinquished by: (Signature) Date Time Received by: (Signature) Date Time LABORATORY USE ONLY Discrepancies Between Sample Labels and COC Record? Y or N Explain: Samples wem 1 •Shipped, oyHand Delivered Airbill# 2. Ambient ochilled`: L ,� 3. Received in�go�condition:LY pr N 4. Property preserved( Y; or N 5. Samples returned l ab _ Hrs from collection. COC Taoe was: 1. Present on outer package., Y or N 2. Unbroken on outer package: Y or N 3. COC record present & complete upon sample receipt: YorN Relinquished by (Signature) Date Time Reobived by: (Si ature) Date Time Relinquished by: (Signature) Date Time Received by: (Signature) Date Time Relinquished by: (Signature) Date Time Received by: (Signature) Date Time rU q� �141WY - ORIGINAL YELLOW rnpv - r I I1=nIT ^"- -'-- 1-12M LABS, INC. • Client Name PCTSL Work Order Numbe 0504067 Sample Receipt Checklist Date and Time Receive Received by FS Checklist completed b Reviewed by ilgnA DateWe Initials Matrix Carrier name Hand Delivered Date 4/4/2005 Shipping container/cooler in good condition? Yes L] No ❑ Not Applicable ❑ Custody seals intact on shippping container/cooler? Yes No ❑ Not Applicable ❑ Custody seals intact on sample bottles? Yes ❑ No ❑ Not Applicable Vol Chain of custody present? Yes No ❑ Chain of custody signed when relinquished and received? Yes No ❑ Chain of custody agrees with sample labels? Yes (] No ❑ Samples in proper container/bottle? Yes D No ❑ Sample containers intact? Yes 0 No ❑ Sufficient sample volume for indicated test? Yes 0 No ❑ 11 samples received within holding time? Yes E] No ❑ tainer/Temp Blank temperature in compliance? Yes No ❑ Water - VOA vials have zero headspace? No VOA vials submitted Yes No ❑ Water - pH acceptable upon receipt? Yes L� No Adjusted? Checked b Any No and/or NA (not applicable) response must be detailed in the comments section b Client contacted ! %T -- _. - Date contacted: `" �; . ; Person contacted Contacted by: Regarding Comments: i Corrective Action 0- 00 O C/� tAUs, INC. T INTE RNA L CHAIN OF CUSTODY DELIVERABLES_ (5— W—DTURN AROUND TIME: y SDG 0- i� CASE kI c S _ MATRIX: CA) pH CHECK Y « REMARKS: Oz ►}�C, i 0 — RE(f1VEp BY: � SIGNATURE DATE: _qlWa;II W: V4, , J v NUM LAB DATE BOTTLE OF TESTS CLWxrID P COLLECTED TYPE BOTTLES 0-56- REQ�sTED fi� G y Z_- 3h 14� s -oo � �� 4165 D c c)-3 013 • ► y o� - � 1 4 0� 2 , -LA)-3 03 I r� O VOLATILE ►-� P 0214 O N cn O O cn H NSM tAUS, INC. INTERNAL CHAIN OF CUSTODY CLIENT: DELIVERABLES: SDG #: _7 - ll�!TURN AROUND T%ffi:_ i CASE MATRIX. Q: -j PH CHECX�cc N REMARKS RECEFVEI)BY.- -SIGNATURE: DATE: 4ME: ' J N2M tAUS, INC_ ' C'LIENT: sDO IN'T'ERNAL rerun TAT .,r • METALS P t32�2 UP4 tAUS9 INC. INTERNAL CHAIN OF CUSTODY I CLIENT: DELIVERABLES: E35 — 30 j TURN AROUND TIME: L S SDG #: TS LC' O CASE 0: MATRIX: C-1 CA P" clmcl0 N f REMARKS: 6 Z' _T L O� _ RECEIVED BY: Tl SIGNATURE:AJOAATE:y� v IOf CLIENT IDN HUM LAB DATE COLLECTED BOTTLE TYPE M OF BOTTLES TESTS REQUESTED 6y �- Z • �oo�C D �i w _ �a -tiff I CEJ—CL ' -c�a c ►3 F ! uft�vk 6i u � 313,3 - CA 41u --e— q q q M 1) ' M I/ a • WET CHEMISTR Y X256 it r M (V cn 0 H WAA ILAUS, INC. CI,IETTP: ` LTS L INTERNAL CHAIN OF CUSTODY R • V U WET CHEMISTRY P 0257 m m SAMPLE PURPOSE OP RELINQUISHED SAMPLE BOTTLE CHANGE OF TYPE CUSTODY INIT DATE TIME BY RECErm BY -AIL� I i °lufi slow % -S'OS :OO slw F 'J'OS � jQL- sl w cm G ,� sJ !2°ot Or slow 4 ��Cs 1`{ • 1 1 s 920.11 /= _i1i� C 4�s�v ISIS c) I — 9IG c5'3c DI O 5 rs Sj�r SI !I SIC lIOli SI vS �' 3I0 ITS c • �. J11,� fir, 920 � ,,,.� SIC 1_ ('• v � J !I • !7 9I0 �S !I°,U - _ !I S F �v r oP5 920. Vt ----- R • V U WET CHEMISTRY P 0257 m m N2AA UAUS, INC_ CLIENT: � I <xoo I • SDO # INTERNAL CHAIN OF CUSTODY SAMPLE PURPOSE OF RELINQUISHED SAMPLE BOTTLE CHANGE OF DATE TIME Y RE C D BY TYPE CUSTODY IINIT Z _SV a4f !I y Cs C.30 gin, Gil/ slow 31 11: ov •IOY SI WI Igloo v I N • WET CHEMISTRY o 0 P G2S8 N Y-�►-os aIw q:3o lIoM �''•'O� IkS � � DIo30 LION y-tt-4s slow to:a� slots k S 2ro 31030 A:'j� sIGM y-�3-o slow to: 3o SIGN !1030 SIGM 31001 SIGN 3I0M SIGN Sion SIGM 31030 SIGN 3ION Sion llOn SION 3I0Y SIGN SIon SIoN 3I091 310" ! I On S I on 3I On 9I CM 3IOn SIGM 37 QN SIGN SIGN SIGN v I N • WET CHEMISTRY o 0 P G2S8 N U2M UAUS, INC. 0 SDG NARRATIVES • • 1-2M "US, INC. SDG NARRATIVE FOR VOLATILE ANALYSES • SAMPLE RECEIVED: 4/1/05-4/4/05 SDG#: TSL001 For Samples: MW -3D MW -6S TRIP BLANK 4/1/05 MW -3S MW -8D MW -1D MW -5D MW -8S MW-ISMS/MSD MW -5S EQUIPT. BLANK TB 4-4-05 MW -6D The above samples were analyzed according to the requirements of the NYSDEC ASP 10/95 method 8260B for the part 360 baseline list of volatile organic analytes. All QC data and calibrations met the requirements of the method, and no problems were encountered with sample analysis. The following should be noted: • Sample MW -1S was analyzed as the matrix spike/matrix spike duplicate. • 4-Bromofluorobenzene had a 20.8% RSD in the initial calibration of 4/4/05, which exceeded 20.5% but met the acceptance limit of 40%. Carbon tetrachloride had a 26.7% D in the continuing calibration of 4/4/05, which exceeded 25% D but met the acceptance limit of 40%. • I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: April 19, 2005 o:1gc',na1r2005�irr%oa`,tti1001.doc • ***** ********** ****** **** * * ** *********** Joarfi Slavin Senior Vice President U2M IL AUS, INC. NARRATIVE FOR METALS ANALYSES SAMPLE RECEIVED: 4/1/05 & 4/4/05 SDG#: TSL001 For Samples: MW -3D MW -8D MW -3S MW -8S MW -5D EQUIPT. BLANK MW -5S MW -1D MW -6D MW-ISMS/MSD MW -6S Eleven water samples were received by H2M Labs inc. on 4/1/05 and 4/4/05 for cyanide and TAL metals analysis. Samples were prepared and analyzed using EPA method 6010B with a TJA61E Trace 1CP instrument, method 7470A with a Leeman HYDRA mercury analyzer and cyanide method 335.2. Sample MW -1 S was utilized as the QC sample for QC analysis and reporting. Spike analysis did not recover within acceptance ranges for cyanide. The sample was post •spiked, reanalyzed and recovered acceptably. Cyanide data was reported flagged "N" on forms 1 and 5A. ICP serial dilution analysis did not reproduce within acceptance ranges for sodium. Sodium data was reported flagged "E" on forms I and 9. No other problems were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: April 19, 2005 • ent Stancampiano Vice President 00 N C/1 O Cn F-+ 0 • F12M UAU%4, INC. For Samples: SDG NARRATIVE FOR WET CHEMISTRY SAMPLES RECEIVED: 4/1/05 & 4/4/05 SDG NO.: TSL00I MW -3D MW -8D MW -3S MW -8S MW -5D EQUIPT. BLANK MW -5S MW -1D MW -6D MW-ISMS/MSD MW -6S Samples were prepared and analyzed using the following methods: PARAMETER Alkalinity BOD Bromide Chloride COD Color Hexavalent chromium Hardness Ammonia Nitrate Phenols Sulfate TDS TKN TOC METHOD # EPA 310.1 EPA 405.1 EPA 320.1 EPA325.2 EPA 410.4 EPA 110.2 STDM 3500- CR D EPA 130.2 EPA 350.1 EPA 353.2 EPA420.1 EPA 9038 EPA 160.1 EPA 351.2 EPA 9060 Sample MW -1 S was utilized for duplicate and spike QC analysis and reporting. Duplicate analysis did not reproduce within acceptance ranges for total kjeldahl nitrogen. The initial analysis was <0.10 mg/L. The duplicate aliquot was a negative 0.29 mg/L. Matrix interferences were suspected. Batch acceptance was based on ICV, CCV and LCS recoveries. No other problems were noted during the analysis of this sample group. I certifv that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: April 21, 2005 0 o:1gc'narr2W'irr',% et chem`ts1001.doc .� Vincent Stancampiano Vice President ,vv2c. 1-12/4 UAUS, INC. • 4. SAMPLE REPORTS 4.1 VOLATILES 4.2 METALS 4.3 WET CHEMISTRY • • • U2M IMUS, INC. QUALIFIERS FOR REPORTING ORGANICS DATA Value - If the result is a value greater than or equal to the quantification limit, report the value. U - Indicates compound was analyzed for but not detected.The sample quantitation limit must be corrected for dilution and for percent moisture. For example, l0U for phenol in water if the sample final volume is the protocol -specified final volume. If a 1 to 10 dilution of extract is necessary, the reported limit is 100 U. For a soil sample, the value must also be adjusted for percent moisture. For example, if the sample had 24% moisture and a 1 to 10 dilution factor, the sample quantitation limit for phenol (330 U) would be corrected to: (300 U) 100%moisture D x df where D = 100 and df - dilution factor For example, at 24% moisture, D = 100-24 - 0.76 100 (300 U) %6 x 10 - 4300 U rounded to the appropriate number of significant figures For semivolatile soil samples, the extract must be concentrated to 0.5 mL, and the sensitivity of the analysis is not compromised by the cleanup procedures. Similarly, pesticide samples subjected to GPC are concentrated to 5.0 mL. Therefore, the CRQL values in Exhibit C will apply to all samples, regardless • of cleanup. However, if a sample extract cannot be concentrated to the protocol -specified volume (see Exhibit C), this fact must be accounted for in reporting the sample quantitation limit. J - Indicates an estimated value. This flag is used either when estimating a concentration for tentatively identified compounds where a VI response is assumed or when the mass spectral data indicates the presence of a compound that meets the identification criteria but the result is less than the specified quantification limit but greater than zero. (e.g.: If limit of quantification is 10 ug/L and a concentration of 3 ug/L is calculated, report as 3J.) The sample quantitation limit must be adjusted for dilution as discussed for the U flag. N - Indicates presumptive evidence of a compound. This flag is only used for tentatively identified compounds, where the identification is based on a mass spectral library search. It is applied to all TIC results. For generic characterization of a TIC, such as chlorinated hydrocarbon, the N code is not used. P - This flag is used for a pesticide/Aroclor target analyte when there is greater than 25% difference for detected concentrations between the two GC columns (see Form X). The lower of the two values is reported of Form I with a 'P". C - This flag applies to pesticide results when the identification has been confirmed by CC/MS.. If GC/MS confirmation was attempted but was unsuccessful, do not apply this flag, instead use a Laboratory defined flag, discussed below. • • U2M TAUS, INC. B - This flag is used when the analyte is found in the associated blank as well as in the sample. It indicates possible probable blank contamination and warns the data user to take appropriate action. This flag must be used for a TIC as well as for a positively identified target compound. E - This flag identified compounds whose concentrations exceed the calibration range of the GC/MS instrument for that specific analysis. if one or more compounds have a response greater than full scale, except as noted in Exhibit D, the sample or extract must be diluted and re -analyzed according to the specifications in Exhibit D. All such compounds with a response greater than full scale should have the concentration flagged with an "E" on the Form I for the original analysis. If the dilution of the extract causes any compounds identified in the first analysis to be below the calibration ranges in the second analysis, then the results of both analyses shall be reported on separate copies of Form I. The Form I for the diluted sample shall have the "DL" suffix appended to the sample number. NOTE: For total xylenes, where three isomers are quantified as two peaks, the calibration range of each peak should be considered separately, e.g. a diluted analysis is not required for total xylenes unless the concentration of the peak representing the single isomer exceed 200 ug/L or the peak representing the two coeluting isomers on that GC column exceed 400 ug/L. Similarly, if the two 1,2-Dichloroethene isomers coelute, a diluted analysis is not required unless the concentration exceed 400 ug/L. D - This flag identifies all compounds identified in an analysis at a secondary dilution factor. If a sample or extract is re -analyzed at a higher dilution factor, as in the "E" flag above, the "DL" suffix is appended to the sample number on the Form I for the diluted sample, and all concentration values reported on that Form I are flagged with the "D" flag. This flag alerts data users that any discrepancies between the concentrations reported may be due to dilution of the sample or extract. is A - This flag indicates that a TIC is a suspected aldol -condensation product. X - Other specific flags may be required to properly define the results. If used, they must be fully described and such description attached to the Sample Data Summary Package and the SDG narrative. Begin by using "X". If more than one flag is required use "Y" and "Z" as needed. If more than five qualifiers are required for a sample result, used the "X" flag to combine several flags as needed. For instance. the "X" flag might combine "A", "B", and "D" flags for some samples. The laboratory defined flags limited to the letters "X", "Y" and "Z". The combination of flags "BU' or "UB" is expressly prohibited. Blank contaminants are flagged "B" only when they are detected in the sample. • • F12M► [AIRS, INC. QUALIFIERS FOR METALS ANALYSIS Q (Quality Control) Qualifiers explanatory note is included in the SDG narrative. E - The reported value is estimated because of the presence of interference. An M - Duplicate injection precision not met. N - Matrix spike sample recovery not within control limits. S- The reported value was determined by the Method of Standard Additions (MSA). + - Correlation coefficient for the MSA is less than 0.995 W - Post digestion spike for Furnace AA analysis is out of control limits (85- 115%), while sample absorbance is less than 50% of spike absorbance. • ' - Duplicate analysis is not within control limits. C (Concentration) Qualifiers B - Entered if the reported value is less than the Contract Required Detection Limit (CRDL) but greater than the Instrument Detection Limit (IDL). U - Entered if the analyte was analyzed for but not detected, i.e., less than the IDL. M (Method) Qualifiers P - Analyzed by ICP. M - Analyzed by ICP -MS A - Analyzed by Flame AA. F - Analyzed by Furnace AA. CV - Analyzed by Manual Cold Vapor techniques. AV - Analyzed by Automated Cold Vapor techniques. C - Analyzed by Manual Spectrophotometric Method. CA- Analyzed by Midi -distillation Spectrophotometric Method. NR - Analyte not Required. M M O C/) IA VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Lab Code: 10478 Case No.: PCTSL Matrix: (soil/water) WATER Sample wt/vol: 5 (g/mL) ML Level: (low/mod) LOW % Moisture: not dec. GC Column Contract: = R-502.2 ID: .53 (arm) Soil Extract Volume: (µL) BPA SAMPLE NO. EQUIPT. BLR SAS No.: SDG No.: TSL001 Lab Sample ID: 0504024-009A Lab File ID: A\A41199.D Date Received: 04/01/05 Date Analysed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (µL) FORM I VOA - 1 OLM04.2 CONCENTRATION UNITS: CAS NO. COMPOUND (µg/L or µg/Rg)UG/L Q 74-87-3 Chloromethane 75-01-4 Vinyl chloride 5 U 74-83-9 Bromomethane 5 U 75-00-3 Chloroethane 5 U 67-64-1 Acetone 5 U 107-13-1 AczYlonitrile 5 U 74-88-4 Iodomethane 5 U • 108-05-4 Vinyl acetate 5 U 78-93-3 2-Butanone 5 U 75-15-0 Carbon disulfide 5 U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichloroethane 5 U 156-59-2 cis-1,2-Dichloroethene 5 U 74-97-5 Bromochloromethane 5 U 67-66-3 Chloroform 5 U 107-06-2 1,2-Dichloroethane 5 U 71-55-6 1,1,1 -Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U 79-01-6 Trichloroethene 5 U 78-87-5 1,2-Dichloropropane 5 U 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-88-3 Toluene 5 U 10061-02-6 trans-1,3-Dichloropropene 5 U 79-00-5 1,1,2 -Trichloroethane 5 U 106-93-4 1,2-0ibromoethane 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-90-7 Chlorobenzene 5 U 127-18-4 Te trachloroethene 5 U 124-48-1 1 Dib romochloromethane 5 U 5 U FORM I VOA - 1 OLM04.2 • • • 1B VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Lab Code: 10478 Case No.: PCTSL Matrix: (soil/water) WATER Sample wt/vol: 5 (g/my) ML Level: (low/med) LOW Moisture: not dec. GC Column: R-502,2 ID: .53 Soil Extract Volume: ( L Contract: (mm) µ ) SPA SAMPLE NO. EQUIPT. BLR SAS No.: SDG No.: TSL001 Lab Sample ID: 0504024-009A Lab File ID: A\A41199.D Date Received: 04/01/05 Date Analysed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (µL) FORM I VOA - 2 OLM04.2 L LTJ U U -75- U U U M C!1 O CONCENTRATION WITS: CAS NO. COMPOUND ( µg/L or Ag/Kg) UG/L 591-78-6 2-Hexanone 630-20-6 1,1,1,2 -Tetrachloroethane 5 100-41-4 Ethylbenzene 5 1330-20-7 Xylene (total) 5 100-42-5Styrene 5 75-25-2 Bromoform 5 110-57-6 trans-l,4-Dichloro-2-butene 5 79-34-5 1,1,2,2 -Tetrachloroethane 5 96-18-4 1,2,3-Trichloropropane 5 106-46-7 1,4 -Dichlorobenzene 5 95-50-1 1,2 -Dichlorobenzene 5 96-12-8 1,2-Dibromo-3-chloropropane 5 5 FORM I VOA - 2 OLM04.2 L LTJ U U -75- U U U M C!1 O IF EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS EQUIPT. BLK Lab Name: H2M LABS INC. Contract: • Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL001 Matrix: (soil/water) WATER Lab Sample ID: 0504024-009A Sample wt/vol: 5 (g/mL) MIS Lab File ID: A\A41199.D Level: (low/med) LOW Date Received: 04/01/05 % Moisture: not dec. Date Analyzed: 04/04/05 GC Column: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volume: (µl) Soil Aliquot Volume: 0 (µL) C Number TICs found: 0 ONCENTRATION UNITS: (µg/L or pg/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST.CONC. Q • M Cn is--i FORM I VOA -TIC OLM04.2 � C/Z U.S. EPA - CLP • 1 INORGANIC ANALYSIS DATA SHEET EPA SAMPLE NO Lab Name: H2M LABS, INC. L�EQUIPT. BLANK Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Matrix (soil/water): WATER Lab Sample ID: 0504024-009 Level (low/med): LOW Date Received: 4/1/2005 5 solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L ACAS No. I Analyte iConcentration C �Q ---M 7429-90-5 tAluminum ------------ --- 6.5 U p 7990-36-0 �Antimon � �--- ' --------� --- — y - ____ _ 3.3 U p 7440-38-2 (Arsenic -------- --- - - ---- - - 1.9 U 1744-0-1-3-91-3- jBarium - -- - P — -- --- - - - - --- - - -- --- 1.2 U — 7440-41-7 P Beryllium_ _ 0.20 U+— ;7990-42-8 Boron -- -- - - --- - 1.71 U 7440-43-9 Cadmium------I-P — ---- - --- — - - 0.40 U p !7440-70-2 1 ---- Ca 1 c i um --- --- - — — -- -- 7 79.7 B P ;7440-47-3 1Chromium ------ -I- 440-50-8 —� ----- - 1.0 0 U - -P 7990-98-9 Cobalt I ---------------------------- t 2. IICo _ f—PPer ---+- • 57-12-5-Cy—-- _ 3.2 B P ide 10.0 U N — -CAS :7439-89-6 Iron - _ 8.7 B 7939 92-1 Lead P 1.4 U 7939-95-9 IMagnesium I -- 7439-56-5 !Manganese 17 B P _ -- 9 3.6 B _ ;7439-97-6 ;Mercury 0.10 U� .7440-02-0 Nickel 1 1.3 U - - - 7440 09-7 Potassium -- P --, ---- --- 37.3 B ,, _ _ p , 7782 99-2 Selenium - - 2.9 U i ,7490 22-4 (Silver II --- 7440-23-5 Sodium ---- 0.901 U _�p (7440 28-0 'Thallium I -- 1T3B E-- - -- P P 7490 62 2 Vanadium_— 7990 66 6 Zinc19Pi- Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESSY : CLEAR Clarity After- Texture: _ - __ Artifacts: Comments: Cate Reperted: 9/11/05 - C/1 O FORM I - IN ILM04.1 1-12M "US, INC. 575BmW FUDN Road Wile W 11747 (631)691,300. FAX (631)42D8435 NYSDOH JD# 10478 Town of Southold Landfill • , Attn To Collected :4/1/2005 12:00:00 PM Received :4/1/2005 4:20:00 PM Collected By VG Copies To :Original CC LABORATORY RESULTS Lab No. 0504024-009 Sample Information... Type: Blank Client ID. : EQUIPT. BLANK Origin: Parameterfs) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) < 1.0 1 mg/L Biochemical Oxygen Demand < 2 E310.1 04/07/2005 8:55 AM Bromide 1 mg/L E405.1 04/01/2005 5:10 PM Chloride < 0.5 1 mg/L E320.1 04/13/200510:20 AM Chemical Oxygen Demand < 2.0 <10 1 mg/L E325.2 04/04/2005 1:13 PM Color 1 mg/L E410.4 04/08/2005 10:10 AM Chromium, Hexavalent < 5 < 0.02 1 units E110.2 04/02/20051:19 PM Hardness (As CaCO3) < 5.0 1 mg/L M3500 -Cr D 04/02/2005 1:50 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E130.2 04/07/2005 1:50 PM Nitrate as N 1 mg/L E350.1 04/07/2005 10:57 AM Phenolics, Total Recoverable < 0.10 < 5,0 1 mg/L E353.2 04/05/2005 2:33 PM Sulfate 1 pg/L E420.1 04/12/2005 10:10 AM Total Dissolved Solids < 5.0 16 1 mg/L SW9038 04/08/2005 12:50 PM Nitrogen, Kjeldahl, Total < 0.10 1 mg/L E160.1 04/05/2005 3:16 PM Total Organic Carbon < 1.0 1 mg/L E351.2 04/12/2005 12:01 PM • 1 mg/L SW9060 04/07/2005 10:47 AM ------------ ---- - Qualifiers: E - Value above quantitation range A/�.�..�.. D - Results for Dilution D.F. = Dilution Factor Date Reported: 4/21/2005 Laboratory Manager Page 9 of 9 00 M r --t 0 r/1 FORM I VOA - 1 OLM04.2 lA SPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MW -1D Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No.: PCTSL SAS No.: 3DG No.: TSL001 Matrix: (coil/water) WATER Lab Sample ID: 0504067-OOJA Sample wt/vol: 5 (g/M,) ML Lab File ID: A\A41209.D Level: (low/mod) LOW Data Received: 04/04/05 % Moisture: not dec. Data Analysed: 04/04/05 GC Column: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volume: (µL) Soil Aliquot Volume (µL) CAS NO. CONCENTRATION UNITS - COMPOUND (µg/L or µ9/K9) UG/L Q 74 -87-3 Chloromethane 75-01-4 Vinyl chloride 5 U 74-83-9 Bromomethane 5 U 75-00-3 Chloroethane 5 U 67-64-1 Acetone 5 U 107-13-1 Acrylonitrile 5 U 74-88-4 • 108-05-4 Iodomethane Vinyl acetate 5 5 U U 78-93-3 2-Butanone 5 U 75-15-0 Carbon disulfide 5 U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U 75-09-2 Methylene chloride S U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichloroethane 5 U 156-59-2 cis-1,2-Dichloroethene 5 U 74-97-5 Bromochloromethane 5 U 67-66-3 Chloroform 5 U 107-06-2 1,2-Dichloroethane 5 U 71-55-6 1,1,1 -Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U 79-01-6 Trichloroethene 5 U 78-87-5 1,2-Dichloropropane 5 U 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-88-3 Toluene 5 U 10061-02-6 trans-1,3-Dichloropropene 5 U 79-00-5 1,1,2 -Trichloroethane 5 U 106-93-4 1,2-Dibromoethane 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-90-7 Chlorobenzene 5 U 127-18-4 Tetrachloroethene 5 U 124-48-1 1 Dibromochloromethane 5 U • 1 J FORM I VOA - 1 OLM04.2 • • CONCENTRATION UNITS: CAS NO. COMPOUND Nmr/L nr un/4ninn/r. n 591-78-6 1B 5 BPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET 5 U 100-41-4 Ethylbenzene 5 U MN -1D Lab Name: H2M LABS, INC. Contract: 100-42-5 Styrene 5 Lab Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL001 Matrix: (soil/water) WATER Lab Sample IDs 0504067-OOIA Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A41209.D Level: (low/mod) LOW Date Received: 04/04/05 % Moisture: not dec. 106-46-7 Date Analysed: 04/04/05 GC Column: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volume: (µL) Soil Aliquot Volume (µL) • • CONCENTRATION UNITS: CAS NO. COMPOUND Nmr/L nr un/4ninn/r. n 591-78-6 2-Hexanone 5 U 630-20-6 1,1,1,2 -Tetrachloroethane 5 U 100-41-4 Ethylbenzene 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene 5 U 75-25-2 Bromoform 5 U 110-57-6 trans-1,4-Dichloro-2-butene 5 U 79-34-5 1,1,2,2 -Tetrachloroethane 5 U 96-18-4 1,2,3-Trichloropropane 5 U 106-46-7 1,4 -Dichlorobenzene 5 U 95-50-1 1,2 -Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U FORM I VOA - 2 OLM04.2 O ,It Cn r-, O V) E-4 Lab Name: H2M LABS, IN ode: 10478 Matrix: (soil/water) Sample wt/vol: 5 Level: (low/med) LOW W Moisture: not dec. GC Column: R-502.2 Soil Extract Volume: Number TICS found: CAS NUMBER • IF EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS MW -1D C' Contract: Case No.: PCTSL SAS No.: SDG No.: TSL001 WATER Lab Sample ID: 0504067-OOIA (g/mL) ML Lab File ID: : \A 209.D Date Received: 04/04/05 Date Analyzed: 04/04/05 ID: .53 (mm) Dilution Factor: 1.00 (µl) Soil Aliquot Volume: 0 (µL) CONCENTRATION UNITS: 0 (µg/L or µg/Kg) UG/L COMPOUND NAME RT EST.CONC. Q FORM I VOA -TIC OLM04.2 U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET _l Lab Name: H2M LABS, INC. MW -1D I Contract: _JI Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Matrix (soil/water): WATER Lab Sample ID: 0504067-001 Level (low/med): LOW Date Received: 9/4/2005 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L iCAS No. Analyte Concentration CT Q M '7429-90 5 Aluminum - --- -�--- 1— - __ __ -- 6. 5 U -- P ----- -- 17490-36-0 Antimony 3.3 U! 7440-38-2 Arsenic -- - - 1 . 9 U:i-+- -_— -I p -- _ -- - -- -- 17990 3- 7 'Barium I ----5_01I P - --- B 7990 41-7 Beryllium _ - I_--1-- -- _-- _-- Y --___ - 0.20 U p 7440 92-8 Boron 12 SIB -- -- --- p 7990 93-9 Cadmium -- -- __ ___ 0.90 U p [7440-70-2 (Calcium -t 9 9 3 0 _ _ --- --- P 7490 -_4 7- 1.0 U p 7940 48-4 1Cobalt - - 2.0 U t - - - -- -- - -- 7990 50-8 jCopper ; ----- � --1 • --- - t — _ 13.6 B p --- - - '57-1 .-- __ 5 Cyanide - - - 1 ! 10.0 U N CpI 7939 89-6 (Iron _ - __ 374 7939-92-1 (Lead - P --- 1. 41 U 7939-95-4 Magnesium - - - 3890 B j , p 7939-96-5 Manganese 36.3 I P 7939-97-6 Mercury 0.- U -- - - CV i 7490-02-0 Nickel{ 1.3.0 I P 7990-09-7 ,Potassium 1000�B - - I P 7782-99-2 !Selenium l - 2. 9, U ; - ' -p 17440-22-4 Silver - 0.90' U.. 1--p- -' i7440-23-5 sodium - -- - _ 23900 E - p 7990 28-0 IThallium - -. __ p 7940 62-2 Vanadium 1.Oi U _11 Ur - - i._-__--- -- ---+ P - 1I ;7990-66-6 'Zinc -�---- - 2491 p Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 9/11/05 _ V1 O C/1 FORM I - IN ILM04.1 "AA "US, INC. 57513rcadHobitr Road, MEW NY 11747 (631)694,3040. FAX (631)4W84,36 NYSDOH ID# 10478 Town of Southold Landfill • Attn To Collected :4/4/2005 4:00.00 PM Received :4/4/2005 5:00:00 PM Collected By VG Copies To :Original CC LABORATORY RESULTS Lab No. 0504067-001 Sample Information... Type : Groundwater Client ID. : MW -1D Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 33.2 1 mg/L Biochemical Oxygen Demand < 2 E310.1 04/07/2005 9:00 AM Bromide 1 mg/L E405.1 04/05/2005 3:20 PM Chloride < 0.5 1 mg/L E320.1 04/13/200510:25 AM Chemical Oxygen Demand 19.5 < 10 1 mg/L E325.2 04/06/2005 1:34 PM Color 1 mg/L E410.4 04/08/2005 10:11 AM Chromium, Hexavalent < 5 < 0.02 1 units E110.2 04/05/2005 7:32 AM Hardness (As CaCO3) 1 mg/L M3500 -Cr D 04/05/2005 7:02 AM Nitrogen, Ammonia (As N) 42.0 < 0.10 2 mg/L E130.2 04/07/2005 1:55 PM Nitrate as N 1 mg/L E350.1 04/07/2005 11:48 AM Phenolics, Total Recoverable 1.17 < 5,0 5 mg/L E353.2 04/05/2005 2:36 PM Sulfate 1 pg/L E420.1 04/12/2005 10:15 AM Total Dissolved Solids 25.5 1 mg/L SW9038 04/08/2005 12:52 PM Nitrogen, Kjeldahl, Total 131 0.18 1 mg/L E160.1 04/05/2005 3:18 PM Total Organic Carbon < 1.0 1 mg/L E351.2 04/12/2005 12:03 PM • 1 mg/L SW9060 04/07/2005 11:13 AM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 4/21/2005 Laboratory Manager Page 1 of 2 lA VOLATILE ORGANICS ANALYSIS DATA SHEET • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No.: PCTSL Matrix: (soil/water) WATER Sample wt/vol: 5 (g/m,) M, Level: (low/med) LOW Moisture: not dec. GC .0 r� Contract: Column: R-502.2 ID: .53 (mm) Soil Extract Volume: (µL) CAS NO. COMPOUND BPA SAMPLE NO. MW -1S E SAS No.: SDG No.: TSL001 Lab Sample ID: 0504067-002A Lab File ID: A\A41210.D Date Received: 04/04/05 Date Analysed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (AL) CONCENTRATION UNITS: 74-87-3 Chloromethane `rye •• "� !*9/ngl utt/i, Q 75-01-4 Vinyl chloride 5 U 74-83-9 Bromomethane 5 U5 75-00-3 Chloroethane U 67-64-1 Acetone 5 U 107-13-1 Acrylonitrile 5 U5 74-88-4 Iodomethane U 108-05-4 Vinyl acetate 5 U5 78-93-3 2-Butanone U 75-15-0 Carbon disulfide 5 U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U 75-09-2 Methylene chloride 5 U Tq -Kn-c ........,_ ., .._ _. _ _ 5 U FORM I VOA - 1 OLM04.2 Cn --I C) C/� • • 1B VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Lab Code: 10478 Case No.: PCTSL Matrix: (soil/pater) WATER Sample pt/vol: 5 (g/mL) ML Contract: Level: (lop/mod) LOW % Moisture: not dec. GC Column: R-502.2 ID: .53 (mm) Soil Extract Volume: (;Q CAS NO. COMPOUND EPA SAMPLE NO. MN -1S SAS No.: SDG No.: TSL001 Lab Sample ID: 0504067-002A Lab File ID: A\A41210.D Date Received: 04/04/05 Date Analyzed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (AL) CONCENTRATION UNITS: 591-78-6 2-Hexanone Q 630-20-6 1,1,1,2 -Tetrachloroethane 5 U 100-41-4 Ethylbenzene 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene 5 U 75-25-2 Bromoform 5 U 110-57-6 trans-1,4-Dichloro-2-butene 5 U 79-34-5 1,1,2,2 -Tetrachloroethane 5 j7 96-18-4 1,2,3-Trichloropropane 5 U 106-46-7 1,4 -Dichlorobenzene 5 U 95-50-1 1,2 -Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U 5 U FORM I VOA - 2 OLM04.2 IF EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS MW -IS Lab Name: H2M LABS, INC. Contract: OCode: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL001 Matrix: (soil/water) WATER Lab Sample ID: 0504067-002A Sample wt/vol: 5 (g/mL) ML Lab File ID': A\A41210.D Level: (low/med) LOW Date Received: 04/04/05 % Moisture: not dec. Date Analyzed: 04/04/05 GC Column: R-502.2 ID: .53 (mm) — Dilution Factor: 1.00 Soil Extract Volume: (µl) Soil Aliquot Volume: 0 CONCENTRATION UNITS: Number TICS found: 0 (µg/L or µ9/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST.CONC. 4 • IND d' Ln is 0 O FORM I VOA -TIC 0 OLM04.2 U.S. EPA - CLP • 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. Matrix (soil/water): WATER Level (low/med): LOW Solids: 0.0 EPA SAMPLE NO -- MW -1S SAS No.: SDG No.: TSL001 Lab Sample ID: 0504067-002 Date Received: 4/4/2005 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte j Concentration) C I Q i M] 7-929-90-5 IA1uminum _ 24 4 B 7990-36-0 Antimony r 3.3 U+ P -- —. -- - ---- --- P 7440-38-2 'Arsenic - -- — --- _ 3 5 B P 7990-39-3 Barium -- --- --t P --- 5. 5f B !7990-91-7 Beryllium -- 0.93 B - I-- 7990 92-8 Boron - - ---- -- -- 14 6 B : ' P 7940_-93-9 Cadmium- -- - - �- - - 0.56 B P ,7440-70-2 Calcium 1 -__ -- r- P - --- --- I-- 9260 440-47-3 'Chromium - - -- _ _ _ 1.0! U p �71490-48-9 Cobalt --- - __L_ 0 U p 7940-50-8 Co - - - • Peer - _ -----12. 0 B� p r7439-89-6 -12-5�C anide- + 10 0 U N - -- �-Y-- � CA Iron - -" `-- -�- -- - 380 Lead p 7939 92-1 --" ' 1 4 U P-1 '7439 95-4 Magnesium j -- __ , _ 3760! B p_ _ i7439-96-5 Manganese - --- - - - 38.8; p !7439-97-6;Mercury 0.10 U CV ;7440-02-0 'Nickel 1.3 Up 7440-09-7 Potassium t _ --- - 1000, 0 B p 7782 49-2 jSelenium 2.9 U } - - --- I P 7440-22-4 Silver 0.9010 -- P !7440-23-5 Sodium - -- I -- - --- _ 23800 I E -p 17440-28-0 1Thallium -- - T- _ 3.1{ U I p 7940-62-2 Vanadium -- 1 . 0 U p :744C-66-6 'Zinc - --- - - -_ - 256! I P ---- jI Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR -_- Artifacts: Comments: Date Reported: 4111105 FORM I - IN ILM04.1 O C/Z H U2M "US, INC. 57513tnmdFUm Roel, MA* w 11747 (631)6W-W40.FAX, (631)4208436 WSDOH ID# 10478 Town of Southold Landfill • ' Attn To Collected :4/412005 4:10:00 PM Received :4/4/2005 5:00:00 PM Collected By VG Copies To :Original CC LABORATORY RESULTS 0504067-002 Sample Information... Lab No. Type: Groundwater Client ID. : MW -1S Origin: Parameters) Results ualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 33.8 1 mg/L E310.1 04/07/2005 9:05 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 04/05/2005 3:25 PM Bromide Chloride < 0.5 1 mg/L E320.1 04/13/200510:30 AM Chemical Oxygen Demand 20.6 1 mg/L E325.2 04/06/20051:35 PM Color <10 1 mg/L E410.4 04/08/2005 10:14 AM Chromium, Hexavalent < 5 1 units E110.2 04/05/2005 7:33 AM Hardness (As CaCO3) < 0.02 1 mg/L M3500 -Cr D 04/05/2005 7:03 AM Nitrogen, Ammonia (As N) 40.0 0.13 1 mg/L E130.2 04/07/2005 2:10 PM Nitrate as N 1 mg/L E350.1 04/07/2005 11:49 AM Phenolics, Total Recoverable 1.15 < 5.0 5 mg/L E353.2 04/05/2005 2:36 PM Sulfate 1 pg/L E420.1 04/12/2005 10:20 AM Total Dissolved Solids 47.5 5 mg/L SW9038 04/08/2005 12:54 PM Nitrogen, Kjeldahl, Total 236 < 0.10 1 mg/L E 160.1 04/05/2005 3:19 PM Total Organic Carbon 111 1 mg/L E351.2 04/12/2005 12:04 PM • 10 mg/L SW9060 04/06/2005 10:46 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported: 4/21/2005 Laboratory Manager Page 2 of 2 00 0l �-1 C/� • • 0 lA VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Lab Code: 10478 Case No.: PCTSL Matrix: (soil/water) WATER Sample wt/vol: 5 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. GC Column: R-502.2 Soil Extract Volume: CAS NO. Contract: ID: .53 (mm) (µL) COMPOUND SPA SAMPLE NO. MW -3D SAS No.: SDG No.: TSL001 Lab Sample ID: 0504024-OOlA Lab File ID: A\A41201.D Date Received: 04/01/05 Date Analyzed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (µL) CONCENTRATION UNITS: 3 Chloromethane Vinyl chloride 5 U Bromomethane 5 U Chloroethane 5 U ;74-88-4 pi Acetone 5 U Acrylonitrile 5 U Iodomethane 5 U Vinyl acetate 5 U 2-Butanone 5 U 75-15-0 Carbon disulfide 5 U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U .7r --An -, , .. ..— - 5 U FORM I VOA - 1 OLM04.2 C!1 C7 • • 1B VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No.: PCPSL Matrix: (soil/water) MATER Sample wt/vol: 5 (g/m,) ML Level: (low/med) LOW % Moisture: not dec. 04/04/05 GC Column: R-502.2 ID: .53 (mm) Soil Extract Volume: (AL) EPA SAMPLE NO. MW -3D SAS No.: SDG No.: TSL001 Lab Sample ID: 0504024-001A Lab File ID: A\A41201.D Date Received: 04/01/05 Date Analysed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (AL) CAS NO. COMPOUND 591-78-6 2-Hexanone 630-20-6 1,1,1,2-Tetrachlor0ethane 100-41-4 Ethylbenzene 1330-20-7 Xylene (total) 100-42-5 Styrene 75-25-2 Bromoform 110-57-6 trans-l,4-pichloro-2-butene 79-34-5 1,1,2,2 -Tetrachloroethane 96-18-4 1,2,3 -Tri Chloropropane 106-46-7 1,4 -Dichlorobenzene 95-50-1 1,2 -Dichlorobenzene 96-12-8 1,2-Dibromo-3-chlorommnwnp FORM I VOA - 2 CONCENTRATION UNITS: (µg/L or µg/Kg) UG/L Q 5 U 5 U 5 U 3 J 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U OLM04.2 IF EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS MW -3D Lab Name: H2 MLABS, INC. Contract: i9Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TS1,001 Matrix: (soil/water) WATER OLM04 .2 ,� Lab Sample ID: 0504024-OOlA Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A41201.D Level: (low/med) LOW Date Received: 04/01/05 % Moisture: not dec. Date Analyzed: 04/04/05 GC Column: R-502.2 ID: .53 (mm) — Dilution Factor: 1.00 Soil Extract Volume: (µl) Soil Aliquot Volume: 0 (µL) C ONCENTRATION UNITS: Number TICs found: 0 (µg/L or µg/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST.CONC. Q is FORM I VOA -TIC O OLM04 .2 ,� U.S. EPA - CLP 0 Concentration ! C; Q 1 EPA SAMPLE NO 7929-90-5 Aluminum ; INORGANIC ANALYSIS DATA SHEET ----------- Antimon 1�-- Y— P 7940-38-2 Arsenic Lab Name: H2M LABS, INC. Contract: MW-3D ' I Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Matrix (soil/water): WATER Lab Sample ID: 0504024-001 Level (low/med): LOW Date Received: 4/1/2005 s Solids: 0 0 1 0 U p , Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. I Analyte i Concentration ! C; Q I M 7929-90-5 Aluminum ; �33 P7440-36-0 Antimon 1�-- Y— P 7940-38-2 Arsenic ---- - l 490-39-3 ,Barium '__ _ --- ----- — ------ �--- 7490-91-7 !Beryllium i7440-42-8 ------- 260 — 0.20 U p i p I - jBoron i 512 1--.--_T-p 17440-43-9 Cadmium I 0.441E - 7990-70-2 Calcium - -- - ---- 7440-47-3 -- --l 76700 -- 1 P I I ,Chromium ! 1 0 U p , ;7940-48-4 ';Cobalt 16.6 B p 7990-50-8 (Copper 29.9 p 57-12-5 Cyanide --- _ 10.01 U ' N ICA 439-89-6 Iron 201 p -- — -- - 7939 92-1 'Lead 2.8rB1 - P 7439 95-4 Magnesium - -- 28600 P 7439 96-5-Manganese -- — -- -_- 3360 P 743Q-97-6Mercur -- Y-- _ - - 0.10 U CV - --t - !! 7440-02-01 7990-02-0 Nickel I -_ - 0. -- - 30.8, B I - p-- 7440-09-7 otassium 793001 P 7-782 49-2 Selenium -- — -- 2.5 B p 7440-22-9 Silver -- -4 - : 0.401U P ,7440-23-5 Sodium 171000i C E P I 7440-28-0 Thallium 17440-62-2 Vanadium - - 3. 11 U I P 7440-66-6 Zinc 2.71 B P 68.2 p Color Before_ COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: CorrLment s : Date Reported: 4/11/05 FORM I - IN ILM04.1 1-12M t AU,%s INC. 575B10adH*w Raad, MJ& NY 11747 (631)6943040. FAX (631)42(38436 WSDOH ID# 10478 Town of Southold Landfill •. Attn To LABORATORY RESULTS Lab No. : 0504024-001 Sample Information... Type : Groundwater Client ID. : MW -3D Origin: Collected :4/1/2005 9:30:00 AM Received :4/1/2005 4:20:00 PM Collected By VG Copies To :Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Anatvzed Alkalinity, Total (As CaCO3), High 305 Biochemical Oxygen Demand 31 4 mg/L E310.1 04/06/2005 12:01 PM Bromide < 0.5 1 mg/L E405.1 04/01/2005 4:40 PM Chloride 198 1 mg/L E320.1 04/13/2005 9:40 AM Chemical Oxygen Demand 74.3 10 mg/L E325.2 04/04/2005 1:05 PM Color 30 1 mg/L E410.4 04/08/200510:02 AM Chromium, Hexavalent < 0.02 1 units E110.2 04/02/20051:09 PM Hardness (As CaCO3) 400 1 mg/L M3500 -Cr D 04/02/2005 1:42 PM Nitrogen, Ammonia (As N) 23.5 10 mg/L g E130.2 04/07/2005 1:10 PM Nitrate as N 39.0 20 mg/L E350.1 04/07!2005 11:44 AM Phenolics, Total Recoverable < 5.0 20 mg/L E353.2 04/05/2005 2:25 PM Sulfate 47.0 1 Ng/L E420.1 04/12/2005 9:30 AM Total Dissolved Solids 938 5 mg/L SW9038 04/08/2005 12:34 PM Nitrogen, Kjeldahl, Total 22.6 2 mg/L E160.1 04/05/2005 3:06 PM Total Organic Carbon 24 20 mg/L E351.2 04/12/2005 11:56 AM • .0 1 mg/L SW9060 04/06/2005 5:45 PM Qualifiers: E - Value above quantitation range D - Results for Dilution F. = Dilution Factor Date Reported : 4/21/2005 Page 1 of 9 Laboratory Manager M �l FORM I VOA - 1 OLM04.2 lA SPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MN -33 • Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL001 Matrix: (soil/pater) WATER Lab Sample ID: 0504024-002A Sample pt/vol: 5 (g/mL) ML Lab File ID: A\A41202.D Level: (lop/med) LOW Date Received: 04/01/05 % Moisture: not dec. Date Analyzed: 04/04/05 GC Column: R-502.2 ID: .53• (mm) Dilution Factor: 1.00 Soil Extract Volume: (pL) Soil Aliquot Volume (KL) CAS NO. CONCENTRATION UNITS: COMPOUND (µg/L or µg/Rg) UG/L Q 74-87-3 Chloromethane 75-01-4 Vinyl chloride 5 U 74-83-9 Bromomethane 5 U 75-00-3 Chloroethane 5 U 67-64-1 Acetone 5 U 107-13-1 Acrylonitrile 5 U 74-88-4 Iodomethane 5 U • 108-05-4 Vinyl acetate 5 U 78-93-3 2-Butanone 5 U 75-15-0 Carbon disulfide 5 U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichloroethane 5 U 156-59-2 cis-1,2-Dichloroethene 5 U 74-97-5 Bromochloromethane 5 U 67-66-3 Chloroform 5 U 107-06-2 1,2-Dichloroethane 5 U 71-55-6 111,1 -Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U 79-01-6 Trichloroethene 5 U 78-87-5 1,2-D4ch1oropropane 5 U 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichloromethane 5 U 10061-01-5 ci5-1,3-D1ch1oropropene 5 U 108-88-3 Toluene 5 U 10061-02-6 trans-1,3-Dichloropropene 7 79-00-5 1,1,2 -Trichloroethane 5 U 106-93-4 1 1,2-Dibromoethane 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-90-7 Chlorobenzene 5 U 127-18-4 I Tetrachloroethene 5 U 124-48-1 1 Dibromochloromethane 5 U • 5 U FORM I VOA - 1 OLM04.2 1B EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MW -3S Lab Name•• H2M LAB • FORM I VOA - 2 OLM04.2 V) r--4 Of INC. Contract: Lab Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL001 Matrix: (soil/water) WATER Lab Sample ID: 0504024-002A Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A41202.D Level: (low/med) LOW Date Received: 04/01/05 % Moisture: not dec. Date Analysed: 04/04/05 GC Column: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volume: (µL) Soil Aliquot Volume (KL) CAS NO. CONCENTRATION UNITS: COMPOUND (µg/L or µg/Rg)UG/L Q 591-78-6 2-Hexanone 630-20-6 1,1,1,2 -Tetrachloroethane 5 U 100-41-4 Ethylbenzene 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene 10 75-25-2 Bromoform 5 U 110-57-6 trans-l,4-Dichloro-2-butene 5 5 U • 79-34-5 1,1,2,2 -Tetrachloroethane U 96-18-4 1,2,3-Trichloropropane 5 U 106-46-7 1,4 -Dichlorobenzene 5 U 95-50-1 1,2 -Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U 5 U • FORM I VOA - 2 OLM04.2 V) r--4 IF EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS MW -3S b La Name: H2M LABS, INC. Contract: • Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL001 Matrix: (soil/water) WATER Lab Sample ID: 0504024-002A Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A41202.D Level: (low/med) LOW Date Received: 04/01/05 % Moisture: not dec. Date Analyzed: 04/04/05 GC Column: R-502.2 ID: .53 (mm) — Dilution Factor: 1.00 Soil Extract Volume: (µl) Soil Aliquot Volume: 0 (µL) CONCENTRATION UNITS: Number TICs found: 0 (µg/L or µg/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST.CONC. 4 • O FORM I VOA -TIC O OLM04.2 U) E-4 U.S. EPA - CLP 0 1 INORGANIC ANALYSIS DATA SHEET EPA SAMPLE NO Lab Name: H2M LABS, INC. � MW -3S Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Matrix (soil/water): WATER Lab Sample ID: 0504024-002 Level (low/med): LOW Date Received: 9/1/2005 o Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. T �- Analyte Concentration CI Q I M 7429-90-5Aluminum 1- 7490-36-0 Antimony 85.6 B1 p 7990-38-2 Arsenic 3.3 U p 7990-39-3 Barium -- --- 9.5, B - - I -P� -- 3101 - 7990-41-7 !Beryllium -- - 7990-42-faL n ---- — 0.20 rJ - i p 580 7990-93-ium -_--- -i.-- -- P 7440-70-lcium---- --- 0.41 BI p7440-47-romium -- -86300! - --- -P 4 : - -{ - r--- -- -- I-- 1. 9 B 7990-98-9 ;Cobalt -1-------�-- 22.1! B------� F-! 7440-50-8 Copper - -------a 57-12-5 _ __ 28.71 P • Cyanide 10.0 U' 7939-69-6 Iron 5-_-_.N__ CA --- 2651 ;7939-92-1 Lead - - - - P 2.9 B - 7939-95-9 Magnesium 34100 - -- ! -I ----!7439----5 ;Manganese ! P - - 9290 939-97-6 ;Mercury - -- P 1 0.10 U 7490-02-0 {Nickel r -- CV -- 9.9!B; -- - p . !74-40-09-7 !Potassium ' --- 8 9100 -- P 7782 99-2 Selenium _ 2.5 B. P 1 7990 22=9 _jSiIve_r - - 7490 23-5 +Sodium --- 1go000 U I P I- - --- t--- - i7990-28-0 'Thallium — - - 3 1� U �� E ; -P - -- �7940-62-2 +Vanadium 3.1 B F - -- P 7490-66-6 lZinc - - -- - - 7 6.3 Color Before: - COLORLESS - Clarity Before: CLEAR - -- -- Texture: Color After: COLORLESS Clarity After: CLEAR _._ Artifacts: Comments: Date Reported: 4/11/05 FORM I - IN ILM04.1 f12M "US, INC. 575BroadHdowr Road, Mdvie NY 11747 (631)694..3040. FAX (631)4208436 NYSDOH ID# 10478 Town of Southold Landfill • Attn To LABORATORY RESULTS 0504024-002 Sample Information... Lab No. Type: Groundwater Client ID. : MW -3S Origin: Collected :4!1/2005 9:10:00 AM Received :4/1/2005 4:20:00 PM Collected By VG Copies To :Original CC Parameter(sl Results ualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3), High 180 2 Biochemical Oxygen Demand 4 mg/L E310.1 04/06/2005 12:06 PM Bromide 1 mg/L E405.1 04/01/2005 4:45 PM Chloride 0.6 1 mg/L E320.1 04/13/2005 9:45 AM Chemical Oxygen Demand 60.8 54.3 1 mg/L E325.2 04/06/20051:33 PM Color 1 mg/L E410.4 04/08/200510:03 AM Chromium, Hexavalent 20 < 0.02 1 units E110.2 04/02/2005 1:10 PM Hardness (As CaCO3) 450 1 mg/L M3500 -Cr D 04/02/2005 1:43 PM Nitrogen, Ammonia (As N) 29.5 10 mg/L E130.2 04/07/2005 1:15 PM Nitrate as N 20 mg/L E350.1 04/07/2005 11:45 AM Phenolics, Total Recoverable 2.57 < 5,0 5 mg/L E353.2 04/05/2005 2:26 PM Sulfate 1 pg/L E420.1 04/12/2005 9:35 AM Total Dissolved Solids 16.2 460 1 mg/L SW9038 04/08/2005 12:36 PM Nitrogen, Kjeldahl, Total 28.7 2 mg/L E160.1 04!05/2005 3:07 PM Total Organic Carbon 20.1 20 mg/L E351.2 04/12/2005 11:56 AM • 1 mg/L SW9060 04/06/2005 6:10 PM Qualifiers: E - Value above quantitation range D . Results for Dilution is D.F. = Dilution Factor Date Reported : 4/21/2005 Page 2 of 9 Laboratory Manager 00 0 lA VOLATILE ORGANICS ANALYSIS DATA SHEET • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No.: PCTSL Matrix: (soil/water) WATER Sample wt/vol: 5 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. GC Column: R-502.2 Soil Extract Volume: Contract: ID: .53 (mm) (µL) EPA SAMPLE NO. MPF- 5D SAS No.: SDG NO.: TSL001 Lab Sample ID: 0504024-003A Lab File ID: A\A41203.D Date Received: 04/01/05 Date Analyzed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (µL) FORM I VOA - 1 OLM04.2 CAS NO. CONCENTRATION UNITS: COMPOUND ( µg/L or Rg/Rg)UG/L Q 74-87-3 Chloromethane 75-01-4 Vinyl chloride 5 U 74-83-9 Bromomethane 5 1 U 75-00-3 Chloroethane 5 U 67-64-1 Acetone 5 U 107-13-1 AcZYlonitrile 5 U • 74-88-4 108-05-4 Iodomethane Vinyl acetate 5 5 U U 78-93-3 2-Butanone 5 U 75-15-0 Carbon disulfide 5 U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichl0roethane 5 U 156-59-2 cis-1,2-01chloroethene 2 J 74-97-5 Bromochloromethane 2 J 67-66-3 Chloroform 5 U 107-06-2 1,2-Dichloroethane 5 U 71-55-6 1,1,1 -Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U 79-01-6 Trichloroethene 5 U 78-87-5 1,2-Dichloropropane 5 U 74-95-3 Dibromomethane 6 75-27-4 Br omodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-88-3 Toluene 5 U 10061-02-6 trans-1,3-Dichloropropene 5 U 79-00-5 1,1,2 -Trichloroethane 5 U 106-93-4 1,2-Dibromoethane 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-90-7 Chlorobenzene 5 U 127-18-4 Tetrachloroethene 3 J 124-48-1 1 Dibromochloromethane 5 U 5 U FORM I VOA - 1 OLM04.2 • • C7 1B VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: 112M -- 0, INC. Contract: Lab Code: 10478 Case No.: PCTSL Matrix: (soil/water) WATER Sample wt/vol: 5 (g/M,) ML Level: (low/med) LOW % Moisture: not dec. GC Column: R-502.2 ID: .53 (mm) Soil Extract Volume: (µL) BPA SAMPLE NO. MW -5D SAS No.: SDG No.: TSL001 Lab Sample ID: 0504024-003A Lab File ID: A\A41203.D Date Received: 04/01/05 Date Analyzed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (AL) FORM I VOA - 2 OLM04.2 U U U U U U U U -5- U U U U O 1-4 O Cn E-4 CONCENTRATION UNITS: CAS NO. COMPOUND (µg/L or µg/Rg)UG/L 591-78-6 2-Hexanone 630-20-6 1,1,1,2 -Tetrachloroethane 5 100-41-4 Ethylbenzene 5 1330-20-7 Xylene (total) 5 100-42-5 Styrene 5 75-25-2 Bromoform 5 110-57-6 trans-1,4-Dichloro-2-butene 5 79-34-5 1,1,2,2 -Tetrachloroethane 5 96-18-4 1,2,3-Trichloropropane 5 106-46-7 1,4 -Dichlorobenzene 5 95-50-1 1,2 -Dichlorobenzene 5 96-12-8 1,2-Dibromo-3-chloropropane 5 5 FORM I VOA - 2 OLM04.2 U U U U U U U U -5- U U U U O 1-4 O Cn E-4 IF EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS MW -5D Lab Name: H2M LABS, INC. Contract: 40 Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TS1,001 Matrix: (soil/water) WATER Lab Sample ID: 0504024-003A Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A41203.D Level: (low/med) LOW Date Received: 04/01/05 W Moisture: not dec. Date Analyzed: 04/04/05 GC Column: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volume: (µl) Soil Aliquot Volume: p _ (µL) CONCENTRATION UNITS: Number TICS found: 0 (µg/L or µg/Kg) UG/L ECAS NUMBER COMPOUND NAME RT EST.CONC. 4 • O FORM I VOA -TIC O OLM04.2 U.S. EPA - CLP 01 INORGANIC ANALYSIS EPA SAMPLE NO DATA SHEET Lab Name: H2M LABS, INC. Mw -5D Contract: I Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Matrix (soil/water): WATER Lab Sample ID: 0504024-003 Level (low/med): LOW Date Received: 4/1/2005 b Solids: 0.0 Units (ug/L or mg/kg dry weight): UG/L rConcentration �---- I CAS No. Analyte Y Concentration C Q I M i 97 29-90-5 Aluminum Antimony - - 108 B -� P 7490-36-0 ----- -------- 7940-38-2 -- 3.3 U ---- ---- p -- - s enic -- U_ -- J 7440-39-3 Barium - - -- - - ---- - -1.9- 116 B P - --1 ---' 7490-91-7 Beryllium 7440-42-8 Boron ---- j----- --- - 0.20 U p -_ p 2 --- - - -- n -- - 7440-93-9 Cadmium -r---- — 9__ 7440-70-2 !Calcium_ i --- --95 - 0. 8 5 B 118000 ---- - T -P .a p ' 7490-47-3 - ---- P jChromium j -- - 7990 98-4 'Co_balt 1 --- - -1.6 B -- 14 3 B - P -- -' - ----- 7990-50-8 Co_p_per -f- P - - { --- - -- 57-12 5 iCyanide 3 9. 9 1 p i - --_ - -- - 7439 89-6 Iron 10.0 U --- - N CA -. --- -- 7439 92-1 Lead -- 147i -p -- _ 17939 95-9 I - - - esium 3.3. p -. --- 7939 96 5 63900 p Manganese -- 7939-97-6 15000 1 - -p ]Mercury - - I i 02-0 Nickel - -- 0.10; U r _ __ _-Cv - .- - ------ _ 7440 09-7 Potassium -----1 44.01 154000; P 7782-49-2 Selenium-- -- -- 6.81 P - p 7490-22-4 Silver + - -- --- �- - -- � U 4 0 P - - - 7440-23-5 Sodium`- ---- � -0. 238000 - - E 7440-28-0Thallium — - - 3.1 U P 7990 62-2 Vanadium -- --- --- - 40-66_-6 1. 0; U i p 1 -- - Zinc 5 4 . 21 t I p Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: - Y CLEAR Texture: _-_ Artifacts: Comments: Date Reported: 4/11/05 • FORM I - IN ILM04.1 U2M [AUS, INC. 575BioadH01kav Road, MEW NY 11747 (631)6943040 -FAX (631)420-436 NYSDOH ID# 10478 Town of Southold Landfill • Attn To LABORATORY RESULTS Lab No. : 0504024-003 Sample Information... Type: Groundwater Client ID. : MW -5D Origin: Collected :4/1/2005 1:30:00 PM Received :4/1/2005 4:20:00 PM Collected By VG Copies To :Original CC Parameters) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3), High 487 Biochemical Oxygen Demand 21 4 mg/L E310.1 04/06/2005 12:11 PM Bromide 0.5 1 mg/L E405.1 04/01/2005 4:50 PM Chloride 374 1 mg/L E320.1 04/13/2005 9:50 AM Chemical Oxygen Demand 107 10 mg/L E325.2 04/042005 1:07 PM Color 30 1 mg/L E410.4 04/08200510:04 AM Chromium, Hexavalent < 0.02 1 units E110.2 04/02/20051:11 PM Hardness (As CaCO3) 680 1 mg/L M3500 -Cr D 04/02/20051:44 PM Nitrogen, Ammonia (As N) 45.1 10 mg/L E130.2 04/07/2005 1:20 PM Nitrate as N 8.22 20 mg/L E350.1 04/07/2005 11:45 AM Phenolics, Total Recoverable < 5.0 5 mg/L E353.2 04/052005 2:26 PM Sulfate 87.0 1 pg/L E420.1 04/12/2005 9:40 AM Total Dissolved Solids 1240 5 mg/L SW9038 04/08/2005 12:38 PM Nitrogen, Kjeldahl, Total 42.7 4 mg/L E160.1 04/05/2005 3:08 PM Total Organic Carbon 25.8 20 mg/L E351.2 04/12/2005 AM • 1 mg/L SW9060 04/062005 6:34 PM :34 Qualifiers: E - Value above quanbtabon range D - Results for Dilution F. = Dilution Factor Date Reported : 4/21/2005 Page 3 of 9 Laboratory Manager M 0 E"'I lA VOLATILE ORGANICS ANALYSIS DATA SHEET • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No.: PCTSL Matrix: (soil/crater) NATER Sample wt/vol: 5 (g/mL) ML Level: (low/med) LOOP % Moisture: not dec. GC Col Contract: umn• R-502.2 ID: .53 (mm) Soil Extract Volume: (µL) BPA SAMPLE NO. MW -5S SAS No.: SDG No.: TSL001 Lab Sample ID: 0504024-004A Lab File ID: A\A41204.D Date Received: 04/01/05 Date Analysed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (µL) FORM I VOA - 1 OLM04.2 CAS NO. CONCENTRATION UNITS: COMPOUND ( µ9/L or µ9/R9) UG/L Q 74-87-3 Chloromethane 75-01-4 Vinyl chloride 5 U 74-83-9 Bromomethane 5 U 75-00-3 Chloroethane 5 U 67-64-1 Acetone 5 U 107-13-1 Acrylonitrile 5 U • 74-88-4 108-05-4 Iodomethane Vinyl acetate 5 5 U U 78-93-3 2-Buta110ne 5 U 75-15-0 Carbon disulfide 5 U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichloroethane 5 U 156-59-2 cis-1,2-Dichloroethene 5 U 74-97-5 Br omochloromethane 5 U 67-66-3 Chloroform 5 U 107-06-2 1,2-Dichloroethane 5 U 71-55-6 1,1,1 -Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U 79-01-6 Trichloroethene 5 U 78-87-5 1,2-Dichloropropane 5 U 74-95-3 Dibromomethane 5 U 75-27-4 Br omodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-88-3 Toluene 5 U 10061-02-6 trans-l,3-Dichloropropene 5 U 79-00-5 1,1,2 -Trichloroethane 5 U 106-93-4 1,2-Dibromoethane 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-90-7 Chlorobenzene 5 U 127-18-4 Tetrachloroethene 5 U • 124-48-1 Dibromochloromethane 5 U 5 U FORM I VOA - 1 OLM04.2 • • 1B VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No.: PCTSL Matrix: (soil/water) WATER Sample wt/vol: 5 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. GC Column: R-502.2 ID: .53 (mm) Soil Extract Volume: (µL) EPA SAMPLE NO. MW -53 SAS No.: SDG No.: TSL001 Lab Sample ID: 0504024-004A Lab File IDs A\A41204.D Date Received: 04/01/05 Date Analysed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (µL) CAS NO. CONCENTRATION UNITS: COMPOUND 591-78-6 2-Hexanone (µg/L orµg/Rg)UG/L 630-20-6 1,1,1,2 -Tetrachloroethane 5 100-41-4 Ethylbenzene 5 1330-20-7 Xylene (total) 5 100-42-5 Styrene 5 75-25-2 Bromoform 5 110-57-6 trans-1,4-Dichloro-2-butene 5 79-34-5 1,1,2,2 -Tetrachloroethane 5 96-18-4 1,2,3-Trichloropropane 5 106-46-7 1,4 -Dichlorobenzene 5 95-50-1 1,2-D4ch10robenzene 5 96-12-8 1,2-Dibromo-3-chloropropane 5 5 FORM I VOA - 2 OLM04.2 1F VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. TENTATIVELY IDENTIFIED COMPOUNDS MW -5S Lab Name: H2M LABS TM C' Contract: • Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL001 Matrix: (soil/water) WATER Lab Sample ID: 0504024-004A Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A41204.D Level: (low/med) LOW "— Date Received: 04/01/05 $ Moisture: not dec. Date Analyzed: 04/04/05 GC Column: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volume: (jul) Soil Aliquot Volume: 0 (µL) C Number TICs found: 0 ONCENTRATION UNITS: F-----T-(/tg/L or µg/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST.CONC. Q • S O FORM I VOA -TIC O OLM04.2 Cn U.S. EPA - CLP • 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW — Date Received: % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L EPA SAMPLE NO MW -5S SDG No.: TSL001 0504024-004 4/1/2005 CAS No. Anal to TT Y Concentration C Q M 7929-90-5 Aluminum -- - ----- 66.6 B - -- 7440-36-0 Antimony P --- ----- J410-'7490-38-2 Arsenic 3. 3 U ,-- _-..- -- . P 38-2 - -- --' 17490-39-3 Barium _ f -�-e c 1 9 Ui I_ 79 1, B 7440-91-7 Beryllium P --- - — ----- 0. 2� U p r-44 42-8 Boron ---------- 43-9 Cadmium 1151B _ 0.40 ti --- 70-2 Calcium_ --- - -- _ P 1900 - f47-3 Chromium -P -- -_.48-4 !Cobalt_— - , - 89.0 p 84. x7990-50-8 Co - 2.0; u - T p - i -- _ PPer 32—qr - _ --I _i • 57-12-5 Cyanide— _ - __ - - P -- -�— - 10 . 0' U N C� 7439 89-6 Iron - -- 1 —...__ 569, - 7439 92-1 (Lead P 7439 95-9 I a n_esium 1. 4 U I p 78101 - F7439 96-5 Manganese I P I i-- -- �__ g- - - - 9051 P 7940 02-0 Nickel --- - -- i 4.91' B p 940 09-7 (Potassium - 9970.' - 7782-49-2 Selenium - -- P ' -- - 2. 4I U P 7490 22-9 Silver --- _ 0.40; U 7440 23-5 Sodium p 440-28-0 Thallium 13000' g p - -- U : -! P 7990 62-2 Vanadium - - - -.. 7490 66 6 Zinc 1 0 U� i P 52.8 Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS ClarityAfter: Texture: --- CLEAR Artifacts: Comments: Date Reported: 4/11/05 FORM I - IN ILM04.1 F12M "US, INC. 575810edHcloer Road, ME#Vk NY 11747 (631)MWM • FAX (631)4248436 NYSDOH ID# 10478 Town of Southold Landfill i. Attn To LABORATORY RESULTS Lab No. : 0504024-004 Sample Information... Type : Groundwater Client ID. : MW -5S Origin: Collected :4/1/20051:15:00 PM Received :4/1/2005 4:20:00 PM Collected By VG Copies To :Original CC PaMmeter(sl Results Qualifier D_F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 36.1 Biochemical O xygen Demand < 2 1 mg/L E310.1 04/07/2005 8:40 AM Bromide < 0.5 1 mg/L E405.1 04/01/2005 4:55 PM Chloride 13 9 1 mg/L E320.1 04/13/2005 9:55 AM Chemical Oxygen Demand 29.3 1 mg/L E325.2 04/04/2005 1:07 PM Color 80 1 mgt- E410.4 04/08/200510:05 AM Chromium, Hexavalent < 0.02 2 units E110.2 04/02/2005 1:14 PM Hardness (As CaCO3)68 0 1 mg/L M3500 -Cr D 04/02/2005 1:45 PM Nitrogen, Ammonia (As N) 3.60 2 mg/L E130.2 04/07/2005 1:25 PM Nitrate as N 2.09 5 mg/L E350.1 04/07/2005 10:52 AM Phenolics, Total Recoverable < 5.0 5 mg/L E353.2 04/05/2005 2:27 PM Sulfate 14.2 1 N9/L E420.1 04/12/2005 9:45 AM Total Dissolved Solids 106 1 mg/L SW9038 04/08/2005 12:40 PM Nitrogen, Kjeldahl, Total 4.34 1 mg/L E160.1 04/05/2005 3:11 PM Total Organic Carbon 33.1 10 mg/L E351.2 04/12/2005 11:58 AM • 1 mg/L SW9060 04/06/2005 6:59 PM Qualifiers: E - Value above quanttlahon range D - Results for Dilution D.F. = Dilution Factor Date Reported: 4/21/2005 Page 4 of 9 Laboratory Manager FORM I VOA - 1 OLM04.2 01 �0 Q0 r ..4 0 lA BPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MW -6D • Lab Name. H2M LABS, INC. Contract: Lab Code: 10478 Case No.: PCTSL SAS No,: SDG No.: TSL001 Matrix: (soil/water) NATER Lab Sample ID: 0504024-005A Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A41205.D Level: (low/zed) LOyP Date Received: 04/01/05 % Moisture: not dec. Date Analysed: 04/04/05 GC Column: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract volume: (µL) Soil Aliquot Volume (�L) CAS NO. CONCENTRATION UNITS: COMPOUND ( µg/L or µg/Rg)UG/L Q 74-87-3 Chloromethane 75-01-4 Vinyl chloride 5 U 74-83-9 BrOmomethane 5 U 75-00-3 Chloroethane 5 U 67-64-1 Acetone 5 U 107-13-1 Acrylonitrile 10 74-88-4 • 108-05-4 Iodomethane Vinyl acetate 5 5 U U 78-93-3 2-Butanone 5 U 75-15-0 Carbon disulfide 5 U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichloroethane 5 U 156-59-2 cis-1,2-Dichloroethene 5 U 74-97-5 ML. chloromethane 5 U 67-66-3 Chloroform 5 U 107-06-2 1,2-Dichloroethane 5 U 71-55-6 1,1,1 -Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U 79-01-6 Trichloroethene 1 J 78-87-5 1,2-Dichloropropane 5 U 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-88-3 Toluene 5 U 10061-02-6 trans-1,3-Dichloropropene 14 79-00-5 1,1,2 -Trichloroethane 5 U 106-93-4 1,2-Dibromoethane 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-90-7 Chi robenzene 5 U 127-18-4 Tetrachloroethene 5 U 124-48-1 1 Dibromochloromethane 5 U • 5 U FORM I VOA - 1 OLM04.2 01 �0 Q0 r ..4 0 IB VOLATILE ORGANICS ANALYSIS DATA SHEET • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No.: PCTSL Matrix: (soil/water) WATER Sample wt/vol: 5 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. GC Column: Contract: R-502.2 ID: .53 (mm) Soil Extract Volume: (µL) EPA SAMPLE NO. MW -6D SAS No.: SDG NO.: TSL001 Lab Sample ID: 0504024-005A Lab File ID: A\A41205.D Date Received: 04/01/05 Date Analysed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (,uL) CAS NO. CONCENTRATION UNITS: 591-78-6 COMPOUND 2-Hexanone (µ9/L or Rg/Rg)uG/L 630-20-6 1,1,1,2 -Tetrachloroethane 5 100-41-4 I Ethylbenzene 5 1330-20-7 I Xylene (total) 3 100-42-5 Styrene 20 75-25-2 Bromoform 5 110-57-6 trans-1,4-Dichloro-2-butene 5 5 • 79-34-5 1,1,2,2 -Tetrachloroethane 96-18-4 1,2,3-Trichloropropane 5 106-46-7 1,4 -Dichlorobenzene 5 95-50-1 112 -Dichlorobenzene 5 96-12-8 1,2-D11)romo-3-chloropropane 5 5 • FORM I VOA - 2 OLM04.2 Lab Name: H2M LABS, IN • Code: 10478 Matrix: (soil/water) Sample wt/vol: 5 Level: (low/med) LOW % Moisture: not dec. GC Column: R-502.2 Soil Extract Volume: Number TICS found: CAS NUMBER ,7 • 1F VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE N0. TENTATIVELY IDENTIFIED COMPOUNDS MW -6D C' Contract: Case No.: PCTSL SAS No.: SDG No.: TSL001 WATER Lab Sample ID: 0504024-OOSA (g/mL) ML Lab File ID: A\A41205.1) Date Received: 04 01/05 Date Analyzed: 04/04/05 ID: .53 (mm) Dilution Factor: 1.00 (µl) Soil Aliquot Volume: 0 (µL) CONCENTRATION UNITS: 0 (µg/L or µg/Kg) UG/L COMPOUND NAME RT EST.CONC. 4 FORM I VOA -TIC OLM04.2 E-� U.S. EPA - CLP • INORGANIC 1 EPA SAMPLE ANALYSIS DATA SHEET NO Lab Name: H2M LABS, INC. Contract: MW -6D Lab Code: 10478 Case No. - — SAS No.: SDG No.: TSL001 Matrix (soil/water): WATER Lab Sample ID: 0504024-005 Level (low/med): LOW Date Received: 4/1/2005 o Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7429-90-5 Aluminum 62.9 B p 7440-36-0 Antimony 3.3 b 7440-38-2 Arsenic 1 --�-- 2.7 B I—� P p 7440-39-3 Barium __�-__ —' 9.8 B ---- --I 7440-41-7 Beryllium _ 0.20 UIp� 7440-92-8 Boron 37.0 B- 7440 _ -93-9 CadmiumP ____ 7440-70-2 0. 9 0 U -----P p CalciumI 16300 7490-97-3 Chromium -- 1.3 B . p0 7 9 -9 - 3.4 7440-50-8 Cper - ------- op Bt 8.3 B p p 157-12-5 C snide • - - - ----- 10.0 U� N !7939-89-6 Iron --- - --' -------_---5770 — - - ----1-CA- P ------------- 17939-92-1 rLead1.4 !Magnesium -- U ;7439-95-4 4350 B p 7439 96-5 :Manganese - 2360 - -- 7439 97-6 :Mercury _ - -- - - 0.10 U P CV ;7440-02-0 Nickel -- -- 2 2 B 74_9.0 09-7 Potassium 7782 - --- 981 o�B - P - -- ---� P-� - ISelenium 2.4�-U P_j L440-22-4 ;Silver__ --- 0.90' U ---gyp - - - - - - --- - 7940-23-5 Sodium_ 1 --1- - - 79801 - E -- p --_ 7990-28-0 Thallium +------ -T __ --- - 3.1: U --- - T p 7990-62-2 IVanadium - - ---- -- ---- ----- 1.01 U1----- p -- -- 7-990-66-6 Zinc — - 22.0! �- ----�- _ i- _._--.�- ---- -- J------ ---- --=----..-A Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: - -- AR CLE --EAR - Artifacts: FORM I - IN ILM04.1 1-12M ILAUS, INC. 57513ta d Holow Road, M44a NY 11747 (631)69kW. FAX (631)4208436 NYSDOH ID# 10478 Town of Southold Landfill i. Attn To : Collected :4/1/200511:20:00 AM Received :4/1/2005 4:20:00 PM Collected By VG Copies To :Original CC LABORATORY RESULTS 0504024-005 Sample Information... Lab No. Type: Groundwater Client ID.: MW -6D Origin: Parameter(sl Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 14.1 1 mg/L Biochemical Oxygen Demand < 2 E310.1 04/07/2005 8:45 AM Bromide 1 mg/L E405.1 04/01/2005 5:00 PM Chloride < 0.5 1 mg/L E320.1 04/13/200510:00 AM Chemical Oxygen Demand 18.8 11.8 1 mg/L E325.2 04/04/2005 1:08 PM Color 1 mg/L E410.4 04/08/200510:06 AM Chromium, Hexavalent 100 2 units El 10.2 04/02/2005 1:15 PM Hardness (As CaCO3) < 0.02 1 mg/L M3500 -Cr D 04/02/2005 1:46 PM Nitrogen, Ammonia (As N) 252 < 0.10 4 mg/L E130.2 04/07/2005 1:30 PM Nitrate as N 1 mg/L E350.1 04/07/2005 11:46 AM Phenolics, Total Recoverable 0.20 < 5,0 1 mg/L E353.2 04/05/2005 2:28 PM Sulfate 1 Ngo E420.1 04/12/2005 9:50 AM Total Dissolved Solids 38.5 125 5 mg/L SW9038 04/08/2005 12:42 PM Nitrogen, Kjeldahl, Total 0.24 1 mg/L E160.1 04/05/2005 3:12 PM Total Organic Carbon 1.8 1 mg/L E351.2 04/12/2005 11:58 AM • 1 mg/L SW9060 04/07/2005 9:56 AM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported . 4/21/2005 Page 5 of 9 Laboratory Manager lA VOLATILE ORGANICS ANALYSIS DATA SHEET • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No.: PCTSL Matrix: (soil/water) WATER Sample wt/vol: 5 (g/mL) ML Contract: Level: (low/med) LOW % Moisture: not dec. GC Column: R-502.2 ID: .53 (mm) Soil Extract Volume: (µL) BPA SAMPLE NO. MW -63 SAS No.: SDG No.: TSL001 Lab Sample ID: 0504024-006A Lab File ID: A\A41206.D Date Received: 04/01/05 Date Analysed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (ILL) CONCENTRATION UNITS: (µg/L or µg/Rg) UG/L 5 5 . 5 5 11 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 1 5 5 5 5 5 14 5 5 5 5 5 5 5 FORM I VOA - 1 OLM04.2 X, CAS NO. COMPOUND 74-87-3 Chloromethane 75-01-4 Vinyl chloride 74-83-9 Bromomethane 75-00-3 Chloroethane 67-64-1 Acetone 107-13-1 Acrylonitrile 74-88-4 Iodomethane • 108-05-4 Vinyl acetate 78-93-3 2-Butanone 75-15-0 Carbon disulfide 75-69-4 Trichlorofluoromethane 75-35-4 1,1-Dichloroethene 75-09-2 Methylene chloride 156-60-5 trans-1,2-Dichloroethene 75-34-3 1,1-Dichloroethane 156-59-2 cis-1,2-Dichloroethene 74-97-5 Br omochloromethane 67-66-3 Chloroform 107-06-2 1,2-Dichloroethane 71-55-6 1,1,1 -Trichloroethane 56-23-5 Carbon tetrachloride 71-43-2 Benzene 79-01-6 Trichloroethene 78-87-5 1,2-Dichloropropane 74-95-3 Dibromomethane 75-27-4 Bromodichloromethane 10061-01-5 cis-1,3-Dichloropropene .108-88-3 Toluene 10061-02-6 trans-1,3-Dichloropropene 79-00-5 1,1,2 -Trichloroethane 106-93-4 1,2-Dibromoethane 108-10-1 4-Methyl-2-pentanone 108-90-7 Chlorobenzene 127-18-4 Tetrachloroethene • 124-48-1 Dibromochloromethane Soil Aliquot Volume (ILL) CONCENTRATION UNITS: (µg/L or µg/Rg) UG/L 5 5 . 5 5 11 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 1 5 5 5 5 5 14 5 5 5 5 5 5 5 FORM I VOA - 1 OLM04.2 X, 1B VOLATILE ORGANICS ANALYSIS DATA SHEET • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No.: PCTSL Matrix: (soil/water) WATER Sample wt/vol: 5 (9/mL) ML Level: (low/mod) LOW % Moisture: not dec. GC Col - Contract: R-502.2 IDs .53 (mm) Soil Extract Volume: (µL) EPA SAMPLE NO. MW -6S SAS No.: SDG No.: TSL001 Lab Sample ID: 0504024-006A Lab File ID: A\A41206.D Date Received: 04/01/05 Date Analyzed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (µL) 0 0 TM CAS NO. CONCENTRATION UNITS: COMPOUND (!+9/L or 09/Rg) UG/L 591-78-6 2-H exanone 630-20-6 1,1,1,2 -Tetrachloroethane 5 100-41-4 Ethylbenzene 5 1330-20-7 Xylene (total) 4 100-42-5 Styrene 21 75-25-2 Bromoform 5 110-57-6 trans-l,4-Dichloro-2-butene 5 • 79-34-5 1,1,2,2 -Tetrachloroethane 5 96-18-4 1,2,3-Trichloropropane 5 106-46-7 1,4 -Dichlorobenzene 5 95-50-1 1,2 -Dichlorobenzene 5 96-12-8 1,2-Dibromo-3-chloropropane 5 5 FORM I VOA - 2 OLM04.2 0 0 TM 1F EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS MW -6S Lab Name: H2M LABS, INC. Contract: eCode: 10476 Case No.: PCTSL SAS No.: SDG No.: TSL001 . Matrix: (soil/water) WATER Lab Sample ID: 0504024-006A Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A41206.D Level: (low/med) LOW Date Received: 04/01/05 96 Moisture: not dec. Date Analyzed: 04/04/05 GC Column: R-502.2 ID: .53 (mm) — Dilution Factor: 1.00 Soil Extract Volume: (µl) Soil Aliquot Volume: p _ (µL) CONCENTRATION UNITS: Number TICS found: 0 (µg/L or R9/Kg) UG/L CAS NUMBER COMPOUND NAME RT fiST.CONC. Q • FORM I VOA -TIC OLM04.2 E" � • U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEETL Lab Name: H2M LABS, INC. - MW -6S -JI Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Matrix (soil/water): WATER Lab Sample ID: 0504024-006 Level (low/med): LOW Date Received: 4/1/2005 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L ;CAS No. r Analyte Concent. - cation Q M _ i 7929-90-5 .IAluminum _ 77.8 B P 7990-36-0 Antimony 3.3 U, P -- _ 1 7940-38-2 Arsenic 1.9 U p -- - 17440-39-3 1Barium - - - 57.3 B P 17440-41-7 :Beryllium I-- - 0.20 U p 17440-42-8 Boron-— -------- -- T-- 40.6 B P I7440-43-9 Cadmium --- 0.43 B -- ----_I ------ ---� ------ - - -- P J 17440-70-2 iCalcium 11000 p i '7940-47-3 iChromium- - ------ - - --- ---- L----- ----- ---- ----- -- p !7440-48-4 Cobalt 4.7;B p 7990-50-8 57 12 5 (Copper •i n _.-- -- Cyanide 1 4.l; B P 0.0 U N CA [74-9--69-6 Iron- - - --- _ _ 70 5� B ! -p— [7 4 3 7439 92-1 iLead - - - _ 1 4 U-; -- 1-P- !7439-95-4 Magnesium - -- - - __ 3060 B; P 17939 96-5 Manganese 2030 ,7439-97-6 Mercury -- 0.10 U P - 30 - CV 17440-02-0 Nickel - 7.2 B p ,7440-09-7 Potassium -- --� -- --- 3820 B P 17-78-2--4.9-2 Selenium - - -- -- --------- -- 2. 4 U i p 1 - - 17440-22-4 !Silver --- - -- -- p _- _ __ 0.40 U :7440-23-5 ,Sodium - --- 6160 E-- P .7440-28-0 Thallium - _ 3.1 p -- P i 7940 62-2 1Vanadium 1.01U - _- P ' 17990 66-6 Zinc - - - - -- - - - - - i- - - - 37 _8' -- --- -P� Color Be fore: COLOR LESS Clarity Before: CLEAR - _ Texture: Color After: COLORLESS Clarity After: CLEAR - - Artifacts: Comments: Date Reported: 4/11/05 • FORM I - IN ILM04.1 F12M IA[�S, INC. 575BfoedH CbN Wad, M** NY 11747 (631)694- p FAX (631)4a)49%WSDOI..IID#10478 LABORATORY RESULTS Town of Southold Landfill Lab No. : 0504024-006 Sample Information... Type: Groundwater Attn To Origin: Client ID. : MW -6S Collected :4/1/2005 11:00:00 AM Received :4/1/2005 4:20:00 PM Collected By VG Copies To :Original CC Parameter(s) Results Qualifier D_F. Units Method Number Analyze Alkalinity, Total (As CaCO3) 11.0 Biochemical Oxygen Demand < 2 1 mg/L E310.1 04/07/2005 8:50 AM Bromide < 0.5 1 mg/L E405.1 04/01/2005 5:05 PM Chloride 11.1 1 m� E320.1 04/13/200510:05 AM Chemical Oxygen Demand 11.8 1 mg/L E325.2 04/04/2005 1:11 PM Color< 5 1 mg/L E410.4 04/08/2005 10:07 AM Chromium, Hexavalent < 0.02 1 units E110.2 04/02/2005 1:16 PM Hardness (As CaCO3) 60.0 1 mg/L M3500 -Cr D 04/02/2005 1:47 PM Nitrogen, Ammonia (As N) < 0.10 2 mg/L E130.2 04/07/2005 1:35 PM Nitrate as N 3.65 1 mg/L E350.1 04/07/2005 11:47 AM Phenolics, Total Recoverable < 5 0 5 L E353.2 04/05/2005 2:28 PM Sulfate 11.5 1 Pg/ E420.1 04/12/2005 9:55 AM Total Dissolved Solids 104 1 mg/ mg/L SW9038 04/08/2005 12:44 PM Nitrogen, Kjeldahl, Total < 0.10 1 mg/L E160.1 04/05/2005 3:13 PM Total Organic Carbon 1.1 1 mg/L E351.2 04/12/2005 11:59 AM • 1 mg/L SW9060 04/07/2005 10:22 AM Qualifiers: E - Value above quantitation range . D - Results for Dilution • D.F. = Dilution Factor Date Reported : 4/21/2005 Laboratory Manager Page 6 of 9 lA VOLATILE ORGANICS ANALYSIS DATA SHEET • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No.: PCTSL Matrix: (soil/water) WATER Sample wt/vol: 5 (g/mL) ML Level: (low/med) LOW Moisture: not dec. GCC1 Contract: o uma: R-502.2 ID: .53 (mm) Soil Extract Volume: (ItL) CAS NO. COMPOUND BPA SAMPLE NO. MW -8D SAS No.: SDG No.: TSL001 Lab Sample ID: 0504024-007A Lab File ID: A\A41207.D Date Received: 04/01/05 Date Analysed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (PL) CONCENTRATION UNITS: (µg/L or µ9/R9) UG/L Q 5 74-87-3 Chloromethane U 75-01-4 Vinyl chloride 5 74-83-9 Bromomethane U 75-00-3 Chloroethane 5 67-64-1 Acetone U 107-13-1 Acrylonitrile • 74-88-4 108-05-4 Iodomethane Vinyl acetate U 78-93-3 2-Butanone 5 75-15-0 Carbon disulfide U 75-69-4 Trichlorofluoromethane 5 75-35-4 1,1-Dichloroethene U 75-09-2 Methylene chloride 156-60-5 trans-1,2-Dichloroethene 75-34-3 1,1-Dichloroethane 156-59-2 cis-1,2-Dichloroethene 74-97-5 Br omochloromethane 67-66-3 Chloroform 107-06-2 1,2-Dichloroethane 71-55-6 1,1,1 -Trichloroethane 56-23-5 Carbon tetrachloride 71-43-2 Benzene 79-01-6 Trichloroethene 78-87-5 1,2-Dichloropropane 74-95-3 Dibromomethane 75-27-4 Bromodichloromethane 10061-01-5 cis-1,3-Dichloropropene 108-88-3 Toluene 10061-02-6 trans-1,3-Dichloropropene 79-00-5 1,1,2 -Trichloroethane 106-93-4 1,2-Dibromoethane 108-10-1 4-Methyl-2-pentanone 108-90-7 Chlorobenzene 127-18-4 Tetrachloroethene • 124-48-1 Dibromochloromethane Soil Aliquot Volume (PL) CONCENTRATION UNITS: (µg/L or µ9/R9) UG/L Q 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 rr 5 5 U U 5 U 5 U 5 U 5 U _ 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 1 U FORM I VOA - 1 OLM04.2 r— C/) F"� 1B VOLATILE ORGANICS ANALYSIS DATA SHEET • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No.: PCTSL Matrix: (soil/water) WATER Sample wt/vol: 5 (g/m,) ML Level: (low/med) LOW Moisture: not dec. is • Contract: SAS No.: GC Column: R-502.2 ID: .53 (mm) Soil Extract Volume: (µL) CAS NO. COMPOUND Lab Sample ID: Lab File ID: Date Received: Date Analysed: Dilution Factor: EPA SAMPLE NO. MW -8D SDG No.: TS1,001 0504024-007A A\A41207.D 04/01/05 04/04/05 1.00 Soil Aliquot Volume (µL) CONCENTRATION UNITS: un /i. nr - /t.-1 nn /r. n 591-78-6 2-Hexanone 5 U 630-20-6 1,1,1,2 -Tetrachloroethane 5 U 100-41-4 Ethylbenzene 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene 5 U 75-25-2 Bromoform 5 U 110-57-6 trans-1,4-Dichloro-2-butene 5 U 79-34-5 1,1,2,2 -Tetrachloroethane 5 U 96-18-4 1,2,3-Trichloropropane 5 U 106-46-7 1,4 -Dichlorobenzene 5 U 95-50-1 1,2 -Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U FORM I VOA - 2 OLM04.2 O 00 U) O C/] E-� 1F EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS MW -8D Lab Name: H2M LABS, INC. Contract: ode: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL001 Matrix: (soil/water) WATER Lab Sample ID: 0504024-007A Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A41207.D Level: (low/med) LOW Date Received: 04/01/05 $ Moisture: not dec. Date Analyzed: 04/04/05 GC Column: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volume: (µl) Soil Aliquot Volume: 0 ({tL) Number TICs found: C ONCENTRATION UNITS: 0 (µg/L or µg/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST .CONC. Q • r --o 00 FORM I VOA -TIC OLM04.2 � E"� U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. Matrix (soil/water): WATER Level (low/med): LOW % Solids: 0.0 SAS No.: EPA SAMPLE NO MW -8D SDG No.: TSL001 Lab Sample ID: 0504024-007 Date Received: 4/1/2005 Concentration Units (ug/L or mg/kg dry weight): UG/L re. CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date R(,?ported: 4%i1/05 FORM I - IN ILM04.1 N 00 U) O H CAS No. Analyte Y r-- C r Q (Concentration I M - 929-90-5 iAluminum -- - - --- ---- ---- 141 B ! -- - -�- 7990-36-0An_timon_ ---- -- -- -- Y - -- ---- 3. ' p -- - 7990-38-2Arsenic -- 3 U ----- --- -- P 1 ;7_940 39-3 Bar. _ - - - B - --- 134 B - i -- 47940-41-7 Beryllium - - - -- ---P0.20 U - -J-P-794 0-92--8-TBoron--- -- - - -- ------._ 744_0-43-9 Cadmium 7940-7-0-2---TC-al-'0.40 clum- _-482 B U P -- - - - 17490 47 3 Chromium 6-- p - 7490 48-4 'Cobalt - - !7440-50-8 3.0 B - 9.2 B - - -- - p p -- -- Kopper _ � i57 -12-5 Cyanide __ p - _ - - 7939-89-6 :Iron - ___ U, , N CA ' - -- 7439-92-1 Lead - 18 40 8. 3 P _1 ,7439-95-4 ;Magnesium '7439-96-5 37600 p P 'Manganese - 3190 P .. 7439-97-6Mercury 7940-02-0 Nickel 22.1 Bi 7440 09-7 iPotassium 97800 p _ 7782 4-9--2- Selenium - - - - 3.1i B - 7440-22-4 Silver 0.90 Ui P - -1 7990 23 5 Sodium _ 8 2_2_0 0 _ p -- - E 7990 28 0 Thallium- i -- -- -- P ----+ - _; - - - - 7440-62-2 Vanadium .7490-66-6 Zinc 3.1 U --- 1- OTU �- -_ - P — P 59.7 P I Color Before: COLORLESS Clarity Befo re. CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date R(,?ported: 4%i1/05 FORM I - IN ILM04.1 N 00 U) O H IH2M LABS, INC. 575BfoedHcbw Road, NIA* NY 11747 (631)ag-1040. FAX (631)420.8436 NYSDOH ID# 10478 Town of Southold Landfill S. Attn To : LABORATORY RESULTS Lab No. : 0504024-007 Sample Information... Type: Groundwater Client ID. : MW -8D Origin: Collected :4/1/200510:16:00 AM Received :4/1/2005 4:20:00 PM Collected By VG Copies To :Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3), High 376 Biochemical Oxygen Demand 31 4 mg/L E310.1 04/06/2005 12:21 PM Bromide < 0.5 1 mg/L E405.1 04/01/2005 5:10 PM Chloride 136 1 mg/L E320.1 04/13/200510:10 AM Chemical Oxygen Demand 69.3 5 mg/L E325.2 04/04/2005 1:12 PM Color 1 mg/L E410.4 04/08/2005 10:08 AM Chromium, Hexavalent 40 1 units E110.2 04/02/2005 1:17 PM Hardness (As CaCO3) < 0.02 530 1 mg/L M3500 -Cr D 04/02/2005 1:48 PM Nitrogen, Ammonia (As N) 40 1 10 mg/L E130.2 04/07/2005 1:40 PM Nitrate as N 18.7 20 mg/L E350.1 04/07/2005 11:47 AM Phenolics, Total Recoverable < 5.0 20 mg/L E353.2 04/05/2005 2:29 PM Sulfate 78.0 1 pg/L E420.1 04/12/2005 10:00 AM Total Dissolved Solids 776 5 mg/L SW9038 04/08/2005 12:46 PM Nitrogen, Kjeldahl, Total 37.9 2 mg/L E160.1 04/05/2005 3:14 PM Total Organic Carbon 24.3 20 mg/L E351.2 04/12/2005 12:00 PM • 1 mg/L SW9060 04/06/2005 8:15 PM Qualifiers: E - Value above quantitation range D - Results for Dilution 0D.F. = Dilution Factor Date Reported: 4/21/2005 Page 7 of 9 Laboratory Manager M 00 0 lA VOLATILB ORGANICS ANALYSIS DATA SHEET • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No.: PCTSL Matrix: (soil/water) WATHR Sample wt/vol: 5 (y/m,) My Level: (low/med) LOW % Moisture: not dec. GC Col • Contract: umn. R-502.2 ID: .53 (mm Soil Extract Volume: (µL) CAS NO. COMPOUM BPA SAMPLE NO. MW -83 SAS No.: SDG No.: TSL001 Lab Sample ID: 0504024-008A Lab File ID: A\A41208.D Date Received: 04/01/05 Date Analyzed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (µL) CONCENTRATION UNITS: 74-87-3 Chloromethane `flu vi 199/1L91 uw/L Q 75-01-4 Vinyl chloride 5 U 74-83-9 Bromomethane 5 U 75-00-3 Chloroethane 5 U 67-64-1 Acetone 5 U 107-13-1 Acrylonitrile 5 U 74-88-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5 U 78-93-3 2-Butanone 5 U 75-15-0 Carbon disulfide 5 U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 10061-02-6 trans- l,3-Dichloropropene 5 1 ri - -_ L, 1-Licnloroethane 5 - 156-59-2 cis-1,2-Dichloroethene U 74-97-5 Bromochloromethane 5 U 67-66-3 Chloroform 5 U 107-06-2 1,2-Dichloroethane 5 U5 71-55-6 1,1,1 -Trichloroethane U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U 79-01-6 Trichloroethene 5 U 78-87-5 1,2-Dichloropropane 5 U 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-88-3 Toluene 5 U 10061-02-6 trans- l,3-Dichloropropene 5 U 79-00-5 1,1,2 -Trichloroethane 5 U 106-93-4 1,2-Dibromoethane 5 U 108-10-1 4 -Methyl -2-p 5 Uentanone 108-90-7 Chlorobenzene 5 U 127-18-4 Tetrachloroethene 5 U 124-48-1 1 Dibromochloromethane 5 U 5 U FORM I VOA - 1 OLM04.2 1B VOLATILE ORGANICS ANALySIS DATA SHEET • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No.: PCTSL Matrix: (soil/water) WATER Sample wt/vol: 5 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. GC Column: R Contract: -502.2 ID: .53 (mm) Soil Extract Volume: (µL) EPA SAMPLE NO. MW -8S SAS No.: SDG No.: TSL001 Lab Sample ID: 0504024-008A Lab File ID: A\A41208.D Date Received: 04/01/05 Date Analysed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (FL) CAS NO. CONCENTRATION UNITS: 591-78-6 COMPOUND 2-Hexanone (/:g/L or gg/Rg) UG/L Q 630-20-6 1,1,1,2 -Tetrachloroethane 5 U 100-41-4 Ethylbenzene 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene 5 U 75-25-2 Bromoform 5 U 110-57-6 • 79-34-5 trans-1,4-Dichloro-2-butene 1,1,2,2 -Tetrachloroethane 5 5 U U 96-18-4 1,2,3-Trichloropropane 5 U 106-46-7 1,4 -Dichlorobenzene 5 U 95-50-1 1,2 -Dichlorobenzene 5 U 96-12-8 1 1,2-Dibromo-3-chloropropane 5 U 5 U • FORM I VOA - 2 OLM04.2 W) 00 0 Vj • 110 IF 00 EPA SAMPLE NO. Cn VOLATILE ORGANICS ANALYSIS DATA SHEET O FORM I VOA -TIC O TENTATIVELY IDENTIFIED COMPOUNDS MW-8S Lab Name: H2M LABS, INC. Contract: Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL001 Matrix: (soil/water) WATER Lab Sample ID: 0504024-008A Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A41208.D Level: (low/med) LOW Date Received: 04/01/05 % Moisture: not dec. Date Analyzed: 04/04/05 GC Column: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volume: (µl) Soil Aliquot Volume: 0 _ (µL) CONCENTRATION UNITS: Number TICS found: 0 (µg/L or µg/Kg) UG/L CAS NUMBER COMPOUND NAME RT EST.CONC. 4 • 110 00 Cn O FORM I VOA -TIC O OLM04.2 U.S. EPA - CLP • 1 INORGANIC ANALYSIS DATA SHEET EPA SAMPLE NO Lab Name: H2M LABS, INC. Mw -8S Contract: j Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Matrix (soil/water): WATER Lab Sample ID: 0504024-008 Level (low/med): LOW Date Received: 4/1/2005 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte ' Concentration I C I 4 M i 17429-- --90-5 Aluminum 1690 ---- p 17940=36-0 Antimony 3.3 U, 7440-38-2Arsenic--- --- P-1 ---- -- -- -- - --- 1 . 9 U p '7440-39-3 Barium - - - - ------------- ----------- - -- 107 B p (7490-91-7 7990-92--8 Boron 0.20 U� p __ 8 4.3 B '7440-43-9 Cadmium - -- P ------- ---- _— 1------- 0.40 U 7440-70-2 Calcium --------_.-_- - 16000 :74-40_—--1Chromium I -- 12.3,- ------- P - - - ---- :7990-98-9 ;Cobalt I -- --- P ---- ---- — ---- - �- - - - 2. 3 B P X57-12-5--- Copper _ 20.0 B 1-p- • 7490-50-8 Cyanide N I C _ --- --_ ._____ 10. 0, U 7439-89-6 Iron 16000 �p F -- :'7439-92-1 tLead - - - -- - -- 6.4I - --- r 7939 95-9 Magnesium 7439 96 5 Manganese 6290{ p 1811 - P I ,7439-97-6 LMercur - 0 10, U - 1 CV 7490 02-0 Nickel - -- - -- -- 8.9_B _ t p P 7490 09-7 Potassium P --- 14600 - - _ _._ ---__7782-49-2 - p , Selenium I - ---I _ j-- 2. 7 7440-22-4 'Silver - 0.40 U F--- -- 7440-23-5 tSodium - I - - —61— - - - --- -- -- ----- _ 11900. .7440-28-0 'Thallium ; --- - - -- ----'- —E - P -- 3.8 B p 7940-62 2 Vanadium - --- - - 7. 4 B7440-66 P 6 inr +- -- - 3 P I Color Before: COLORLF,SS Clarity Before: CLEAR Color After: COLORLESS Clarity AfterTexture: -_ Y : CLEAR Artifacts: Comments: Date Reported: 4/11/05 r� ILM04.1 00 C/) 0 Cid H2M "US, INC. (631)6 a'WFU-w (6 1)42D 43 11747 LABORATORY RESULTS (631)694,3p10.FAX(631)42084,96 NYSDOHID#10478 Town of Southold Landfill Lab No. :0504024-008 Sample Information... Type : Groundwater • Attn To Origin: Client ID.: MW -8S Collected :4/1/2005 10:00:00 AM Received :4/1/2005 4:20:00 PM Collected By VG Copies To :Original CC Parameterfs) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3), High 106 2 Biochemical O Oxygen Demand < 2 mg/L E310.1 04/06/2005 12:26 PM Bromide 1 mg/L E405.1 04/01/2005 5:10 PM Chloride 0.7 1 mg/L E320.1 04/13/2005 10:15 AM Chemical Oxygen Demand 18.5 86'8 1 mg/L E325.2 04/04/2005 1:13 PM Color 1 mg/L E410.4 04/08/2005 10:09 AM Chromium, Hexavalent 30 < 0.02 1 units E110.2 04/02/2005 1:18 PM Hardness (As CaCO3) 96.0 1 m 9n- M3500 -Cr D 04/02/2005 1:49 PM Nitrogen, Ammonia (As N) 43.6 2 mg/L E130.2 04/07/2005 1:45 PM Nitrate as N < 0.10 5 mg/L E350.1 04/07/2005 10:55 AM Phenolics, Total Recoverable < 5.0 1 mg/L E353.2 04/05/2005 2:30 PM Sulfate 1 Ng/L E420.1 04/12/2005 10:05 AM Total Dissolved Solids 14.8 151 1 mg/L SW9038 04/08/2005 12:48 PM Nitrogen, Kjeldahl, Total 46.9 1 mg/L E160.1 04/05/2005 3:15 PM Total Organic Carbon 31.8 20 mg/L E351.2 04/12/2005 12:00 PM • 1 mg/L SW9060 04/06/2005 8:40 PM Qualifiers: E - Value above quantitation range D - Results for Dilution OD.F. = Dilution Factor Date Reported: 4/21/2005 Laboratory Manager Page 8 of 9 DD 00 r --I C) 0 1--i lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET TB 4-4-05 Lab Name: H2N LABS, INC. Contract: Q Lab Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL001 Matrix: (soil/water) RATER Lab Sample ID: 0504067-003A Sample wt/vol: 5 (g/=,) ML Lab File ID: A\A41212.D Level: (low/mod) LOW Date Received: 04/04/05 % Moisture: not dec. Acrylonitrile Date Analysed: 04/04/05 GC Column: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volume: (µL) Soil Aliquot Volume (µL) • r� CAS NO. COMPOUND CONCENTRATION UNITS: 74-87-3 Chloromethane �f-W ..a PWA--/ uu/a' Q 75-01-4 Vinyl chloride 5 U 74-83-9 Bromomethane 5 U 75-00-3 Chloroethane 5 U 67-64-1 Acetone 5 U 107-13-1 Acrylonitrile 5 U 74-88-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5 U 78-93-3 2-Butanone 5 U 75-15-0 Carbon disulfide 5 U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 _ U FORM I VOA - 1 OLM04.2 Cn 00 C/� • • • 1B VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: 272M LABS, INC. Contract: Lab Code: 10478 Case No.: PCTSL Matrix: (soil/water) MATER Sample wt/vol: 5 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. GC Column: R-502.2 IDz .53 (mm) Soil Extract Volume: (µL) EPA SAMPLE NO. TB 4-4-05 SAS No.: SDG No.: TSL001 Lab Sample ID: 0504067-003A Lab File ID: A\A41212.D Date Received: 04/04/05 Date Analysed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot volume (µL) CAS NO. CONCENTRATION UNITS: COMPOUND ( µg/L or µg/Rg) UG/L 591-78-6 2-Hexanone 630-20-6 1,1,1,2 -Tetrachloroethane 5 100-41-4 Ethylbenzene 5 1330-20-7 Xylene (total) 5 100-42-5 Styrene 5 75-25-2 Bromofozm 5 110-57-6 trans-l,4-Dichloro-2-butene 5 79-34-5 .1,1,2,2 -Tetrachloroethane 5 96-18-4 1,2,3-Trichloropropane 5 106-46-7 1,4 -Dichlorobenzene 5 95 -50 -11,2 -Dichlorobenzene 5 96-12-8 1,2-DibrOMO-3-c1110ropropane 5 5 FORM I VOA - 2 OLM04.2 0 C/� IF EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS TB 4-4-05 Lab Name: H2M LABS, INC. Contract: ,Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL001 Matrix: (soil/water) WATER Lab Sample ID: 0504067-003A Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A41212.D Level: (low/med) LOW Date Received: 04/04/05 W Moisture: not dec. Date Analyzed: 04/04/05 GC Column: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volume: (µl) Soil Aliquot Volume: 0 (µL) C Number TICs found: 0 ONCENTRATION UNITS: (µg/L or µg/xg) UGL CAS NUMBER COMPOUND NAME RT EST.CONC. 4 • con • O FORM I VOA -TIC OLM04 .2 V) E--+ lA VOLATILE ORGANICS ANALYSIS DATA SHEET • Lab Name: H2M LABS, INC. Lab Code. 10478 Matrix: (soil/water) Sample wt/vol: 5 Level: (low/med) % Moisture: not dec. GC Columna R-502.2 Soil Extract Volume: Contract: SPA SAMPLE NO. TB 4/1/05 Case No.: PCTSL SAS No.: SDG No.: TSL001 WATER Lab Sample ID: 0504024-010A (g/mL) ML Lab File ID: A\A41200.D LOW Date Received: 04/01/05 Date Analysed: 04/04/05 ID: .53 (mm) Dilution Factor: 1.00 (µL) Soil Aliquot Volume (µL) CONCENTRATION UNITS: (µg/L or µg/Rg)UG/L Q 5 CAS NO. COMPOUND U 74-87-3 Chloromethane 5 75-01-4 Vinyl chloride U 74-83-9 Bromomethane 5 75-00-3 Chloroethane U U 67-64-1 Acetone 5 107-13-1 Acrylonitrile • 74-88-4 108-05-4 Iodomethane Vinyl acetate 5 78-93-3 2-Butanone U 75-15-0 Carbon disulfide 5 75-69-4 Trichlorofluoromethane U 75-35-4 1,1-Dichloroethene 5 75-09-2 Methylene chloride U 156-60-5 trans-1,2-Dichloroethene 75-34-3 1,1-Dichloroethane 156-59-2 cis-1,2-Dichloroethene 74-97-5 Bromochloromethane 67-66-3 Chloroform 107-06-2 1,2-Dichloroethane 71-55-6 1,1,1 -Trichloroethane 56-23-5 Carbon tetrachloride 71-43-2 Benzene 79-01-6 Trichloroethene 78-87-5 1,2-Dichloropropane 74-95-3 Dibromomethane 75-27-4 Bromodichloromethane 10061-01-5 cis-1,3-Dichloropropene 108-88-3 Toluene 10061-02-6 trans-l,3-Dichloropropene 79-00-5 1,1,2 -Trichloroethane 106-93-4 1,2-Dibromoethane 108-10-1 4-Methy1-2-pentanone 108-90-7 Chlorobenzene 127-18-4 Tetrachloroethene 124-48-1 I Dibromochloromethane CONCENTRATION UNITS: (µg/L or µg/Rg)UG/L Q 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 5 U U 5 5 U U 5 U 5 5 U U FORM I VOA - 1 OLM04.2 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U OLM04.2 1/ 11 u 11 1B VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Lab Code: 10478 Case NO.: PCTSL Matrix: (soil/water) WATER Sample wt/vol: 5 (g/m,) ML Level: (low/med) LOW % Moisture: not dec. GC Column: R-502.2 ID: .53 (mm) Soil Extract Volume: (µI,) Contract: EPA SAMPLE NO. TB 4/1/05 SAS No.: SDG No.: TSL001 Lab Sample IDs 0504024-010A Lab File ID: A\A41200.D Date Received: 04/01/05 Date Analysed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (pL) CAS NO. COMPOUND 591-78-6 2-Hexanone 630-20-6 1,1,1,2 -Tetrachloroethane 100-41-4 Ethylbenzene 1330-20-7 Xylene (total) 100-42-5 Styrene 75-25-2 Bromoform 110-57-6 trans-l,4-Dichloro-2-butene 79-34-5 1,1,2,2 -Tetrachloroethane 96-18-4 1,2,3-Trichloropropane 106-46-7 1,4 -Dichlorobenzene 95-50-1 1,2 -Dichlorobenzene 96-12-8 1,2-D1bromo-3-chloroDrnnanP CONCENTRATION UNITS: (µg/L or µg/Rg)UG/L Q 5 U U 5 U 5 U 5 45 U 5 5 5 5 AUU 5 5 5 FORM I VOA - 2 OLM04.2 IF VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. TENTATIVELY IDENTIFIED COMPOUNDS TB 4/1/05 Lab Name- H2M LABS, INC. Contract: SCode: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL001 Matrix: (soil/water) WATER Lab Sample ID: 0504024-010A Sample wt/vol: 5 (g/mL) MIA Lab File ID: A\A41200.D Level: (low/med) LOW Date Received: 04/01/05 W Moisture: not dec. Date Analyzed: 04/04/05 GC Column: R-502.2 ID: .53 (mm) Dilution Factor: 1.00 Soil Extract Volume: (µl) Soil Aliquot Volume: 0 (µL) C Number TICs found: 0 ONCENTRATION UNITS: (µg/L or µg/Kg) UG/L GAS NUMBER COMPOUND NAME RT EST.CONC. Q is CN Cn • 0 FORM I VOA -TIC � OLM04.2 V) E--4 U2M 1AUS, INC. 0 5. SURROGATE SPIKE ANALYSIS RESULTS 5.1 VOLATILES • C, QC Limit SMC1 DCE = 1,2-Dichloroethane-d4 (76-114) SMC 2 TOL Toluene -d8 (88-110) SMC3 BFB = 4-Bromofluorobenzene (86-115) # Column to be used to flag recovery values * Values outside of contract required QC limits page 1 of 1 FORM II VOA -1 K -] OLM04.2 2A WATER VOLATILE SYSTEM MONITORING COMPOUND RECOVERY Lab Name: H2M LABS, INC. Contract: Code: 10478 Case NO.: PCTSL SAS No.: SDG No.: TS1,001 EPA SMC1SMC2 SMC3 OTHER TOT SAMPLE NO. DCE # TOL # BFB # 01VBLK040405 97 OUT 02 LFB040405 102 gg 87 0 03MSB0404050 100 101 95 100 98 0 04 EQUIPT. BLK 94 98 94 05 TB 4/1/05 95 99 0 06 MW -3D 96 95 0 07 MW -3S 95 gg 97 0 08MW-5D 96 99 94 0 09 MW -5S 99 96 0 96 100 95 0 10 MW -6D 96 99 95 11 MW -6S 94 99 0 12 MW -8D 94 93 0 13 MW -8S 99 93 0 93 100 95 0 14 MW -11) 92 98 91 15 MW -1S 93 99 0 16 MW-1SMS 94 093 17 TB 4-4-05 100 95 0 95 99 93 18 MW-1SMSD 93 0 99 94 0 • QC Limit SMC1 DCE = 1,2-Dichloroethane-d4 (76-114) SMC 2 TOL Toluene -d8 (88-110) SMC3 BFB = 4-Bromofluorobenzene (86-115) # Column to be used to flag recovery values * Values outside of contract required QC limits page 1 of 1 FORM II VOA -1 K -] OLM04.2 U2/4 lAI3S, INC. • 6• MATRIX SPIKE / MATRIX SPIKE DUPLICATE SUMMARY 6.1 VOLATILES r� • .7 # Column to be used to flag recovery and RPD values with an asterisk * Values outside of QC limits RPD: 0 out of 5 outside limits Spike Recovery: 0 out of 10 outside limits COMMENTS: 00 O*N Cn FORM III VOA -1 olero4.2 � Z 3A PATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL001 Matrix Spike - EPA Sample No.: MW_IS SPIKE SAMPLE MS MS QC. COMPOUND ADDED CONCENTRATION CONCENTRATION % LIMITS 1,1-Dichloroethene (Ng/L) (Ng/L) (Ng/L) REC # REC. Benzene 50 0 47 93 61-145 Trichloroethene 50 50 0 49 99 76-127 Toluene 0 52 104 71-120 Chbrobenzene 50 0 53 105 76-125 50 0 55 111 75-130 SPIKE MSD MSD COMPOUND ADDED W/O CONCENTRATION % % OC LIMITS 1,1-Dichloroethene (Ng/L) REC #t RPD # RPD REC. Benzene 50 47 0 14 61-145 Trichloroethene 5093 49 98 1 11 76-127 Toluene 50 52 104 0 14 71-120- Chlorobenzene 50 52 105 0 13 76-125 50 56 112 1 13 1 75-130 .7 # Column to be used to flag recovery and RPD values with an asterisk * Values outside of QC limits RPD: 0 out of 5 outside limits Spike Recovery: 0 out of 10 outside limits COMMENTS: 00 O*N Cn FORM III VOA -1 olero4.2 � Z • # Column to be used to flag recovery and RPD values with an asterisk * Values outside of QC limits Spike Recovery: 0 out of 5 outside limits COMMENTS: isFORM III SW8260B 3A SYSTEM MONITORING SPIKE RECOVERY Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TS1,001 Sample ID MSB040405 Level:(low/med) ION SPIKE SAMPLE SPIKE SPIKE QC. COMPOUND ADDED CONCENTRATION CONCENTRATION 96 LIMITS 1,1-DIChWWthene �N9�) (N9/L) iP9�) REC # REC. Benzene 50 ° 100 61-145 dchloroethene so ° 105 76-127 duene ° los 71-120 Chbrobenzene U 10s 76-125 � 111 75-130 • # Column to be used to flag recovery and RPD values with an asterisk * Values outside of QC limits Spike Recovery: 0 out of 5 outside limits COMMENTS: isFORM III SW8260B C7 r� u • 3A SYSTEM MONITORING SPIKE RECOVERY Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL001 Sample ID LFB040.405 Level: (low/med) IQdI * Values outside of QC limits SAMPLE SPIKE SPIKE QC. CONCENTRATION ADDED % COMPOUND W/L) (PA) Chloromethane 50 0 yi chloride 50 70-114 Brornometbane 50 111 Chloroethane 50 52 oetone 50 0 itrile 50 71-116 lodornethane 50 87 nyl acetate 50 56 2-Butanone 50 Carbon disulfide 50 dchlorofluoromethane 50 1,1-Dichloroethene 50 Methylene chloride 50 trans-1,24ftbroethene 50 1,1-Dichloroethane 50 cis-1,2-Dichloroethene 50 Bron►ochloron�ethane 50 CAloroform 50 1,2-Dichloroethane 50 1,1,1 -Trichloroethane 50 Carbon tetrachloride 50 Benzene 50 Trichloroethene 50 1,2-Dichloropropane 50 Dibrornomethane 50 Brornodichloromethane 50 cis-1,3-Dichkwopropene 50 oluens 50 trans-1.3-Dichloropropene 50 1,1,2 -Trichloroethane 50 # Column to be used to flag 81-114 recovery * Values outside of QC limits SAMPLE SPIKE SPIKE QC. CONCENTRATION CONCENTRATION % LIMITS (N9/L) (PA) REC # REC. 0 55 110 70-114 0 55 111 66-117 0 52 103 50-136 0 52 104 71-116 0 44 87 71-125 0 56 112 74-122 0 52 105 70-122 0 47 93 76-118 0 47 94 74-121 0 54 109 61-126 0 57 113 64-124 0 54 108 67-120 0 50 1 101 80-112 0 52 104 74-115 0 53 105 77-114 0 50 101 78-116 0 49 97 81-114 0 52 104 75-119 0 51 101 76-120 0 57 113 66-126 0 57 115 64-126 0 51 102 77-116 0 53 107 72-121 0 50 100 81-115 0 48 97 82-114 0 51 102 78-118 0 50 100 79-116 0 52 104 70-125 ° 49 98 77-120 0 48 96 82-116 and RPD values with an asterisk Spike Recovery: 0 out of 47 outside limits COMMENTS: FORM III SW8260B # Column to be used to flag recovery and RPD values with an asterisk * Values outside of QC limits Spike Recovery: 0 out of 47 outside limits COMMENTS: • FORM III SW8260B 3A SYSTEM MONITORING SPIKE RECOVERY Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL001 Sample ID LFB040405 Level: (low/med) IQbT 1,2-Dibrornoethane 50 4-Methyl-213entanone 50 0 48 95 81-117 Chlorobenzene 50 0 43 87 79-121 etrachbroethene 50 0 51 102 72-124 Dibromochioromethane52 50 0 105 59-133 -Hexanone � 0 48 96 79-118 1,1,1,2 -Tetrachloroethane 0 43 76-119 Ethylbenzene 50 050 101 76-119 ylene (total) 0 52 104 68-128 Styrene 0 160 107 70-125 Bromoform 0 50 100 72-124 b 50 0ans-l,4-Dichloro.2-butene 46 75-121 1,1,2,2 -Tetrachloroethane 0 45 93 47-135 1.2.3-Trichloropropane 50 0 45 89 77 -120 1,4 -Dichlorobenzene 50 0 45 89 78-118 1.2 -Dichlorobenzene 50 0 50 100 67-128 1,2-Dibromo 3 -ch loropropane 50 0 49 99 71-123 0 44 89 1 74-123 # Column to be used to flag recovery and RPD values with an asterisk * Values outside of QC limits Spike Recovery: 0 out of 47 outside limits COMMENTS: • FORM III SW8260B U2M ILA[3S, IISC. L-1 7. DUPLICATE SUMMARY RESULTS 7.1 METALS 7.2 WET CHEMISTRY • • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER Solids for Sample: 0.0 U.S. EPA - CLP 6 EPA SAMPLE NO DUPLICATES --- Contract: MW-iS l SAS No.: SDG No.: TSL001 Level (low/med): LOW Solids for Duplicate: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L 1 Cont rol I --- --- - - ----- --- �- AnalyteLLimit -----II I Sample (S) C J +--- -+-{------------- Duplicate (D) C RPD Aluminum 1200.0000 ------ 4 M 24.3600 B Antimon - - - - --__ 14.0800 B -----�' 60.0000 I 3.30001U 3000 U -- ------ -53.5- - P Arsenic 10.0000 3 4729 B 5.1813..B! 200.0 p - - - - _ -- . 0 Barium 200.000Ot -_ 1_9000 U ; Ber llium 5.0000 - --5 4900 B 200.0 I - p 5.1800 B - E�- - 0_4 300 B - - ---- 5.8 p Boron _ - ___ 0.2000 U:� 500_ 0000 i 14 . 6000 B - 200.0 �_ p 'Cadmium I- - 13.4900 B r'-_ -- 7, 9 p 5 0000 -- - _ - - -- -- -- - _ 0.5600 �B - 0.9000 U 200.0 }-- -p Calcium J5000 0000' - (Chromium 10 0000 ' - 9259.0700, 9856.2800 r - - --- 6 - - --- ! - - ;Cobalt_ - 50_0000 I - _.-0000 ! U T - - - ----1.3600 B I _ 200.OJ p 1 - - - -- 2.0000 U _opper 25.0000 -__ - -T t- ----- ___ 2.1500 B � 200.0 ' - - - !- - 11.9700 B J ;- 13.6600 B ��-- P Cyanide I - --- 0 U - - - _- B 13 .2 P Iron ,- - 10.0000 U _ - (- 100.0000 7 379.6900 , - - _ -- !Lead - - -__386 3300 - - 1. 4 000 U -- -- 1 7 _1 p iMagnesium _50.00.0000 -- - 1.4000 U -- 3761. 3400 B -- I P. Nanganese 15.0000 - ,_ 4027.6300'B - 38.820039.5Y60- 6 8 _ I _ 0.10000 0 100U� --- 1 'Nickel 40.0000 -- 8,T �P 1 . 3000 U 1 . 70001 B 2 Potassium 15000 0000 800 10- 4800 - - - _- _ 00 0' .CV - --- 1047.0800 B --- -H P um - 2.4000 U [,Se,en ilver -- 2.4000 U _ - - -- -- 0.4000 U -- - 0 4000 U P (Sodium 5000 0004 T (Thallium X10 0000 23805.1000 - --- - ---9 8 24980 3300 -10 -- P - ! - - 3.1000 U - P - 4 0786 B ---- 0; i -_ I Vanadium -- p 1.0000 U - -- - --� j Zinc 256.2700' t - - 1.0000_0 P -- -._ _ 277 .6900 8-0 p • FORM VI - IN ILM09.1 • • H2M LABS, INC. Date: 11 -Apr -05 QC SUMMARY REPORT SDG: TSL001 Biochemical Oxygen Demand Biochemical Oxygen Demand < 2 178 mg/L mg/L 200 < 2 89 $0 120 0504067-002bdup ;MW-1SDUP Biochemical Oxygen Demand < 4 mg/L < 2 1 20 Sample ID: _ Client Sample ID: Analyte T` Result Units Spike Amount Sample Result %REC Recovery RPDRet %RPO Limits value %RPD UCL MBLK040705 MBLK040705 jAlkalinity, Total (As CaCO3) <1 mg/L MBLK040805 MBLK040805 Chemical Oxygen Demand <10 LCSO40705 0504067-002bms iLCS040705 ----- ----- MW-1SMS Alkalinity, Total (As CaCO3) --- Alkalinity, Total (As CaCO3) 21.8 58.0 mg/L mg/L 25 25 <1 33.8 87 97 80 75 120 125 1000 r0504067_002bdup -—',MW-1SDUP (Alkalinity, Total (As CaCO3) 33,3 mg/L MW -ISMS Chemical Oxygen Demand IMW.ISDUP lChernical Oxygen Demand 1090 < 10 mg/L myL 1000 33.8 1.3 20 109 75 125 < 10 20 fMBL-K040605 MBLK040605 jAlkalinity, Total (As CaCO3), High < 5 mg/L �LCSO40605 LCSO40605 jAlkalinity, Total (As CaCO3), High 126 mg/L 125 1 <5 101 180 11201 - --------------- MBLK040105 ;MBLK040105 Biochemical Oxygen Demand <2 mg/L f ILCSO40105 �LCSO40105 Biochemical Oxygen Demand 186 I mg/L 200 j <2 1 93 80 11201 1 IMBLK040505 LCSO40505 IMBLK040505 LCSO40505 Biochemical Oxygen Demand Biochemical Oxygen Demand < 2 178 mg/L mg/L 200 < 2 89 $0 120 0504067-002bdup ;MW-1SDUP Biochemical Oxygen Demand < 4 mg/L < 2 1 20 MB -041305 �LCCS-041305 MB -041305 Bromide ,LCS-041305 Bromide < 0.5 4.9 1 mg/L mg/L 5 < 0.5 98 80 120 0504067-002BMS ,0504067-002BDUPMW-1SDUP IMWiSMS Bromide 18romide^ 4.5 < 0.5 mg/L mg/L 5 <0.5 90 75 125 < 0.5 20 MBLK040805 MBLK040805 Chemical Oxygen Demand <10 mg/L rLCSO40805_ CSO40805 IChemical Oxygen Demand 1100 mg/L 1000 < 10 110 80 120 _l 0�504067-002dms- ,0504067-002ddup MW -ISMS Chemical Oxygen Demand IMW.ISDUP lChernical Oxygen Demand 1090 < 10 mg/L myL 1000 < 10 109 75 125 < 10 20 M81.040405 M81-040405 Chloride i < 1 mg/L LCS1-Oa0405 LCS1-040405 Chloride 1 50.5 1 mg/L 1 50 1 < 1 1 101 180 11201 J TSL001 S 104 • SDG: TSL001 • QC SUMMARY REPORT mb-040505 mb-040505 Nitrate as N < 0.1 mg/L Spike Sample Nitrate as N Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL IM6-040605 'MB -040605 'Chloride <1 mg/L - -- - � CLChloride LCS-040605 S-040605 50.8 mg/L 50 < 1 102 80 120 !0504067-002BMS '--0000-- !MW -ISMS Chloride 46.8 mg/L 25 20.6 105 175 125 - _ - --- _ _ 0504067-002BDUP 0000 --- BMW-1SDUP --- --- Chloride 20.3 mg/L 20.6 1.2 20 MBLK040205 MBLK040205 Chromium, Hexavalent r < 0.02 mg/L I I LCSO40205 -- _2-v LCSO40205 -.. --- Chromium, Hexavalent 0.20 I mg/L 0.2 < 0.02 100 80 I� 120 F ^ MB -040505 MB -040505 Chromium, Hexavalent < 0.02 mg/L _ ILCS-04_0505 ILCS-040505 jChrorniurn, Hexavalent - 0.17 mg/L 0.2 < 0.02 85 80 120 10504067-002BMS !MW -ISMS jChromium,Hexavalent 0.17 mg/L 0.2 <0.02 85 75 125 0504067-002Bdup i_ _4-�_- !MW-1SDUP jChrorniurn, Hexavalent <0.02 mg/L <0.02 20 FMB -447906 MB -R47906 Color < 5 units IL6S-R47906 4479-06 iColor 40 units 40 <5 100 j 80 11201 0504067-0028dup_ --- ILCS MI W-1SDUPColor < 5 units < 5 20 - BLK04 MBLK040205 'MBLK040205 Color < 5 units 0 - - -- LCSO40205 - -i ]LCSO40205 Color 40 units 40 1 <5 100 80 120 0444 4004_.___..._. MBLK040705 - MBLK 440705 Hardness (As CaCO3) < 5 mg/L LCSO40705_.- -- - - - - - - _ LCSO40705 Hardness (As CaCO3) 1040 mg/L 1000 < 5 104 80 120 _ 10504067-002ern mw isms Hardness (As CaCO3) 144 mg/L 100 40.0 104 75 125 0504067-002edup MW-1SDUP Hardness (As CaCO3) 40.0 mg/L 40.0 j 0 120 mb-040505 mb-040505 Nitrate as N < 0.1 mg/L Ics-040505 Ics-040505 Nitrate as N 1.12 mg/L 1.13 < 0.1 99 80 120 0504067-002DMS (MW -ISMS Nitrate as N 3.52 mg/. 2.5 1.15 95 75 125 0504067-002DDUP MW-1SDUP Nitrate as N 1.12 mg/L 1.15 2.6 20 2 TSL001 S 105 � � w QC SUMMARY REPORT SDG: TSL001 MBLK040505 MBLK040505 Total Dissolved Solids < 10 mg/L Spike Sample Total Dissolved Solids Recovery RPDRef %RPD _._Sample ID_ _ Client Sample ID: Analvte Result Units Amount Result %REC Limits value %RPD UCL MB1-13164 MB1-040705 Nitrogen, Ammonia (As N) < 0.1 mg/L 'M8-13164 MB -040705 Nitrogen, Ammonia (As N) < 0.1 mg/L 1-CSI1-13164 LCSI1-040705 Nitrogen, Ammonia (As N) 0.55 mg/L 0.5 < 0.1 110 80 1201 1LCSI-13164 ICSI-040705 Nitrogen, Ammonia (As N) 0.52 mg/L 0.5 < 0.1 104 80 120 $CSh1-13164 'LCSh1-040705 !Nitrogen, Ammonia (As N) 2.74 mg/L 2.5 < 0.1 110 80 120 ILCSh-13164 LCSh-040705 Nitrogen, Ammonia (As N) 2.68 mg/L 2.5 < 0.1 107 80 120 ;0504067-002DMS iMW-1SMS ,Nitrogen, Ammonia (As N) 5.17 mg/L 5 0.13 101 1 75 1125 ;0504067-002DDUP^ MW-1SDUP Nitrogen, Ammonia (As N) < 0.1 mg/L 0.13 200 20 mb-13204 Amb -041205 jNitrogen, Kjeldahl, Total < 0.1 mg/L Ics-13204 Ics-041205 INitrogen, Kjeldahl, Total 4.44 mg/L 4.1 < 0.1 108 80 120 •0504067-002DMS MW-1SMS Nitrogen, Kjeldahl, Total 4.30 mg/L 4.1 <0.1 105 75 125 0504067-002DDUP MW-1SDUP ;Nitrogen, Kjeldahl, Total -0.29 mg/L < 0.1 1 98.2 20 ,MBLK1041205 MBLK-041205 Phenolics, Total Recoverable <5 ug/L - LCS-041205 �LCS-041205 ` - iPhenolics, Total Recoverable 27.7 ug/L 30 <5 92 80 120 I ,0504067-002DMS __ MW-1SMS lPhenolics, Total Recoverable 18.8 ug/L 20 <5 94 1 75 125 10504067-002Ddup !MW-1SDUP Phenolics, Total Recoverable <5 ug/L <5 20 MB -040805 MB -040805 Sulfate <5 mg/L LCS-040805 ILCS-040805 Sulfate 20.2 mg/L 20 1 <5 1 101 180 120 '0504067-0026MS 11AW-1SMS ISulfate 148 mg/L 100 47.5 100 75 125 X0504067-002Bdup BMW-1SDUP Sulfate 47.0 mg/L 47.5 1 1.1 120 MBLK040505 MBLK040505 Total Dissolved Solids < 10 mg/L _-_ _ LCSO40505 LCSO40505 Total Dissolved Solids 297 mg/L 300 < 10 99 80 120 0504067-002bms MW-1SMS Total Dissolved Solids 542 mg/L 300 236 1 102 1 75 125 0504067-002bdup 'MW-1SDUP Total Dissolved Solids 245 mg/L 236 3.7 2C 3 TSL001 S 106 0 0 0 QC SUMMARY REPORT SDC: TSL001 Sample.ID: _ _ Client Sample ID: Analyte Result Units Spike Amount Sample Result %REC Recovery RPDRet %RPD Limits value %RPD UCL MBLK-040605-TI BLK-040605 ITotal Organic Carbon I <1 mg/L LCS-040605 LCS-040605 Total Organic Carbon 22.4 mg/L 25 < 1 90 1 80 120 10504067-002CMS MW -ISMS Total Organic Carbon 202 mg/L 100 111 91 , 75 125 0504067-002CDUP TMW-1 SOUP jTotal Organic Carbon 119 mg/L 111 7.1 20 MBLK-040705 �MBLK-040705 Total Organic Carbon <1 mg/L LCS-040705 !LCS-040705 jTotal Organic Carbon 23.7 mg/L 1 25 <1 95 1 80 11201 4 TSL001 S107 U2M "U%s INC. 0 8. SPIKE SAMPLE RESULTS 8.1 METALS 8.2 WET CHEMISTRY • • 00 0 0 H • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER o Solids for Sample: 0.0 U.S. EPA - CLP 5A SPIKE SAMPLE RECOVERY Contract: SAS No.: EPA SAMPLE NO - MW-1ss SDG No.: TSL001 Level (low/med): LOW Concentration Units (ug/L or mg/kg dry weight): UG/L Control ! --------- Limit I Spiked Sample Sample ' Analyte- ! aR JSpike Result (SSR) C Result (SR) C Added (SA) oR 'Q M Aluminum 75-125 - - _ i-- ---- 2_ _0.5 4.17 0 0 _ ---- --- -- - I "-- ____ _ 24.3600 B 2000.00 101.5 { P Ant -mon 75-125 I 999.6757 - -- - -- - 125 - _ _3.3000_ U --500.00 8 Arsenic t 75-125 -- - --- - - 98_ 9 Barium _--� ---im 43263.4729 B P �75 125 ! 5.4900 B 2000.00 ----99-5 -tp, Ber llium 75-1-25;---- --- 00 Boron -- _ 0.9300 B 99.7 -:_0 -- -- r ----- 75-125 1 -50=00--_109 7 p,Cadmium7 19.6000 B 2000.00_ 8 rP-j5-125 -- 1 - -- - -_ 52.4200 0.5600 B 9 ----- Chromium 75-125 !_ -- ----- ----- 50.00 103 7 -- _ 207.2100 f- 1.0000 0 ---I- - 3 P, Cobalt 75-125 I - - _-._200.00_ 103 6 P C --- 533.1400 2.0000 U - - C_ opp-e 75-125 264.6800 --- - 500.00 106.6i p- - 11.9700 B Cyanide 75-12_5 - °�< -cam �� U ----- -- 250.00 ,_{10_1 1 p -- 10 10.0000 U 100.00 �( 'Iron ! _75_125 __ 1922 0300 - ---- - ---- )g 3b CA7 .-- - -1 75 125 - 18 8991 -_ 379.9000 j -- -� -- i Lead _ 1000.00 104 2 p Manganese 75-125 556. 7300 ' - -- 99 5 P ;' - -- - - 38 . 8200 t p Op Op 103 6 P Mercury - - - - 50 75-125 ------ -. _ , - -_- 1 0200 - -0.1000 U - - 2-. - CV' -- --� 1. io Nickel 7 -- 5-125 522.9000 1 . 3000 U , - Selenium 75 125 i ---- 500. 00 109.6 _-p - - - 11 5 512 � - ; - , -- Silver ' 75 125 - --- -- --�-- -- -- - _2_ 4000 U . 10.00 ' 115_ . 5, P - _ 41.1477 ' 0.9000 lU - 0 i Thallium 75-125 50.0 50. 1905 _ 82.3 1 p 3. 1000 I U - �Vanadium 75-125 - ---- - 50.00 100.9 {P; 508. 4800 --- - 1.0000 U -- Zinc -- -75-125_ - ---- - 500.001 101.7 p �_- 819 2700 - - - 256.2700-�- - ---- - - -- - -- --- -- --- --- 500 00 112.6 Comments: • FORM V (Part 1) - IN U.S. EPA - CLP • SB POST DIGEST SPIKE SAMPLE RECOVERY EPA SAMPLE NO Lab Name: H2M LABS, INC. I MW -ISA Contract: Lab Code: 10978�---- -----� Case No. SAS No.: : Matrix (soil/water): WATER SDG No.TS1,001 Level (low/med): LOW Concentration Units: ug/L Fcontrol ------ — - — — — ---- �- -- Limit i Spiked Sample Sample Analyte j %R Result (SSR) C Result (SR) C Add pike °sR !Cyanide —i--- 14 Mi ---- I ---------98.91 10.00 U 100.0 �— 98.9 —ICA; ------ -- --- -- • Comments: 0 FORM V (Part 2) - IN ILM09.1 0 0 0 H2M LABS, INC. Date: 21 -Apr -05 QC SUMMARY REPORT SDG: TSL001 Spike Sample Recovery RPDRef %RPD Sammi ID__ Client Sample [D: Analvte Result Units Amount Result %.REC Limits Value %RPD UCL MBLK040705 ;LCSO40705 - !0504067-002bms 0504067-002bdup MBLK040705 Alkalinity, Total (As CaCO3) < 1 mg/L LCS040705 Alkalinity, Total (As CaCO3) 21.8 mg/L 25 < 1 87 1 80 120 MW -isms Alkalinity, Total (As CaCO3) 58.0 mg/L 25 33.8 97 75 125 _ -- MW-1SDUP Alkalinity, Total (As CaCO3) 33.3 mg/L 33.8 1.3 20 MBI -040405 MBI -040405 IChloride < 1 I mg/L LCSI-04040 IChloride MBLK040605 _ i jftatinity, Total (As CaCO3), High <5 m9/L �LCSO40605 JMBLK040605 ILCS040605 lAlkalinity, Total (As CaCO3), High 126 m9lL 1 125 1 <5 j 101 1 80 112011 -- 2MBLK040105 TMBLK040105 Biochemical Oxygen Demand < 2 mg/L SO40105 ` — !LC OS 014 05 JBiochemical Oxygen Demand 186 ! mg/L 1 200 1 <2 93 1 80 11201 IMBLK040505— MBLK040505 Biochemical Oxygen Demand < 2 m9/L ILCSO40505 LCSO40505 181ochernical Oxygen Demand 178 mg/L 200 < 2 89 80 11201 0504067.002bdup MW-1SDUP Biochemical Oxygen Demand < 4 mg/L <2 20 'MB -041305 _ I-- -- — iMB-041305 Bromide < 0.5 I mg/L - ..-.. -- - -- CCS -041305 - ---- LCS 041305 _. Bromide 4.9 m9/L 5 < 0.5 98 80 120 !0504067-002BMS 0504067-0028DUP IMW-ISMS _ ;MW - —IS DUP jBromide `! Bromide 4.5 < 0.5 mg/L mg/L 5 <0.5 90 75 125 < 0.5 1 20 7WLK040805 iMBLK040805 Chemical Oxygen Demand < 10 mg/L !LCS040805_ i LCSO40805 Chemical Oxygen Demand 1100 mg/L 1000 < 10 j 110 80 120 -- 0504067-002dms _ im-ISMS Chemical Oxygen Demand 1090 mg/L 1000 < 10 109 75 125 ;0504067-002ddup !MW.1SDUP Chemical Oxygen Demand <10 mg/L <10 j 20 MBI -040405 MBI -040405 IChloride < 1 I mg/L LCSI-04040 IChloride 50.5 j mg/L 1 50 1 < 1 1 101 180 11201 I TSL001 5111 QC SUMMARY REPORT SDG: TSL001 Sample ID:__ Client Sample ID: Analyte Result Spike Units Amount Sample Result %REC Recovery Limits RPDRef %RPD Value %RPD UCL _ IMB-040605 -. MB -040605 ,Chloride -- < 1 mg/L LCS-040605 LCS-040605 Chloride 50.8 mg/L 50 < 1 102 80 120 '0504067-002BMS !MW -ISMS Chloride 46.8 mg/L 25 20.6 105 175 125 0504067-002BDUP- Chloride 20.3 mg/L 20.6 1 1.2 20 --!MW-1SDUP MBLK040205 MBLK040205 Chromium, Hexavalent - < 0.02 mg/L ILCSO40205 iLCSO40205 Chromium, Hexavalent 0.20 mg/L 1 0.2 1 < 0.021 100 j80 11201 MB -040505 ILLS -040505 - -- ----_ ... II0504067-002BMS 10504067-00213dup IMB-040505 �LCS-040505 - 1MW-ISMS MW -1 SDUP Chromium, Hexavalent Chromium, Hexavalent Chromium, Hexavalent Chromium, Hexavalent < 0.02 0.17 0.17 < 0.02 mg/L mg/L mg/L mg/L 0.2 0.2 < 0.02 <0.02 85 85 80 75 120 125 < 0.02 20 MB -R47906 MB -R47906 Color <5 units LCS-R47906 LCS-R47906 Color 40 units 40 < 5 100 80 120 0504067-0028dup MW-1SDUP Color <5 units <5 1 120 _ �MBLK040205 MBLK040205 Color < 5 units j LCSO40205 ,LCSO40205 Color 40 units 40 <5 100 80 120 MBLK040705MBLK040705 �... - .. LC 040705 10504067-002ems - . -- - ILCSO40705 MW -ISMS -- - Hardness (As CaCO3) -- jHardness (As CaCO3) ',Hardness (As CaCO3) <5 1040 144 mg/L mg/L mg/L 1000 100 < 5 40.0 104 104 80 75 120 125 1 '0504067-002edup �MW-1SDUP Hardness (As CaCO3) 40.0 mg/L 40.0 0 20 mb-040505 mb-040505 Nitrate as N < 0.1 mg/L ilcs�04_0505 ilcs-040505 Nitrate as N 1.12 mg/L 1.13 <0.1 99 80 120 051 04067-002DMS MW -ISMS Nitrate as N 3.52 mg/L 2.5 1.15 95 75 125 _ 0504067-002DDUP IMW-1SDUP Nitrate as N 1.12 mg/L 1.15 2.6 20 2 TSL001 S 112 QC SUMMARY REPORT SDG: TSL001 < 0.1 mg/L _- - 1cs-041205 MW-1SMS INitrogen, Kjeldahl, Total 4.44 mg/L 4.1 < 0.1 108 80 120 S -- MW -ISMS Sample ID; Client Sample ID: Analyte Result Units Spike Amount Sample Result %REC Recovery RPDRet %RPD Limits Value %RPD UCL TC -S040505 X0504067-002bms MW -ISMS 0504067.002bdupSMW 11 DUP - -! Phenolics, Total Recoverable < 5 ug/L MBI -13164 _ 'M81-040705 Nitrogen, Ammonia (As N) < 0,1 mg/L MB -13164 1MB-040705 Nitrogen, Ammonia (As N) < 0.1 mg/L jSulfate 20.2 mg/L LCSI1-13164 ,LCSII-040705 Nitrogen, Ammonia (As N) 0.55 mg/L 0.5 < 0.1 110 80 120 'LCSI-13164 iLCSI-040705 Nitrogen, Ammonia (As N) 0.52 MOIL 0.5 < 0,1 104 80 120 iLCSh1-13164 !LCSh-13164 iLCSh1-040705 LCSh-040705 Nitrogen, Ammonia (As N) Nitrogen, Ammonia (As N) 2.74 2.68 mg/L mg/L 2.5 2.5 < 0.1 < 0.1 110 107 80 80 120 120 47.0 ,0504067-002DMS ;MW -ISMS INitrogen, Ammonia (As N) 5.17 mg/L 5 0.13 101 75 11251 ,0504067-002DDUP MW-1SDUP INitrogen, Ammonia (As N) < 0.1 mg/L I 1 0.13 200 , 20 !mb-13204 - - i Ics-13204 0504067-002DM j0504067-00200 !mb-041205 Nitrogen, Kjeldahl, Total < 0.1 mg/L _- - 1cs-041205 MW-1SMS INitrogen, Kjeldahl, Total 4.44 mg/L 4.1 < 0.1 108 80 120 S -- MW -ISMS INitrogen, Kjeldahl, Total 4.30 mg/L 4,1 < 0.1 105 75 125 UP iMW-1SDUP INitrogen. Kjeldahl, Total -0.29 mg/L <0.1 98.2 20 !MBLK-041205 IMBLK-041205 LCS-041205 !LCS-041205 - --- !0504067-002DMS MW-1SMS 0504067-0020dup ;MW-1SOUP- fMB-040805 MB -040_805 ILCS-040805 LCS-040805 0504067-002BMS MW -1 SMS !0504067-002Bdup - ,MW-1SDUP MBLK040505 jMBLK040505 LCSO40505 TC -S040505 X0504067-002bms MW -ISMS 0504067.002bdupSMW 11 DUP TSL001 S 113 Phenolics, Total Recoverable < 5 ug/L Phenolics, Total Recoverable 27.7 ug/L 30 < 5 92 80 120 Phenolics, Total Recoverable 18.8 ug/L 20 < 5 94 75 125 - -! Phenolics, Total Recoverable < 5 ug/L I < 5 Sulfate < 5 mg/L jSulfate 20.2 mg/L 20 <5 101 ' 80 120 - - -_ -` !Sulfate__ 148 mg/L 100 47,5 100 75 125 - ! _ Sulfate 47.0 mg/L 1 47.5 1.1 Dissolved Solids < 10 mg/L Dissolved Solids 297 Mg/L 300 < 10 99 80 120 Dissolved Solids 542 mg/L 300 236 1 102 75 11251 Dissolved Solids 245 mg/L I 1 1 235 3.7 3 QC SUMMARY REPORT SDG: TSL001 MBLK-040705 MBLK-0407C LCS-040705 _ LCS-040705 TSL001 S 114 Organic Carbon < 1 mg/L Organic Carbon 23.7 mg/L 25 1 < 1 1 95 4 Spike Sample Recovery RPDRet %RPD Sample ID: _ _Client Sample ID: Analyte _ Result Units Amount Result %REC Limits Value %RPD UCL MBLK-040605 IMBLK-040605 Total Organic Carbon < 1 mg/L LCS-040605LCS-040605 Total Organic Carbon 22.4 mg/l 25 < 1 90 80 120 10� 504067-002CMS -�M—W-isms Total Organic Carbon 202 mg/L 100 111 91 75 125 0504067-002C6UP IMW-1SDUP Total Organic Carbon 119 mg/L 111 7.1 20 MBLK-040705 MBLK-0407C LCS-040705 _ LCS-040705 TSL001 S 114 Organic Carbon < 1 mg/L Organic Carbon 23.7 mg/L 25 1 < 1 1 95 4 U2M UAUS, INC. • 9. BLANK SUMMARY DATA AND RESULTS 9.1 VOLATILES 9.2 METALS 9.3 WET CHEMISTRY L� • Cn O Cn F-4 4A EPA SAMPLE NO. VOLATILE METHOD BLANK SUMMARY VBLK040405 Lab Name: H2M LABS, INC. Contract: • Lab Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL001 Lab File ID: A\A41196.D Lab Sample ID: VBLK040405 Date Analyzed: 04/04/05 Time Analyzed: 15:03 GC Column: R-502.2 ID: .53 (mm) Heated Purge: (YIN) N Instrument ID: HP5971 THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS, AND MSD: EPA LAB LAB TIME SAMPLE NO. SAMPLE ID FILE ID ANALYZED 01 LFBO40405 LF8040405 A%A41197.D 15:39 02 MS8040405 MSBO40405 A1A41198.1) 16:06 03 Eouvr. BLK 0504024-009A A1A41199.D 16:39 TB 4/1/05 0504024-010A A1A41200.D 17:06 05 MW -3D 0504024-001A AW41201.D 17:34 06 MW -3S 0504024-002A A1A41202.1) 18:01 07 MW -51) 0504024-003A A1A41203.D 18.34 08 MW -5S 0504024-004A A%A41204.D 19:01 09 MW -6D 0504024-005A AW41205.D 19:29 10 MW -6S 0504024-006A AW41206.D 19:56 11 MW -8D 0504024-007A A%A41207.D 20:23 12 MW -8S 0504024-008A AIA41208.D 20:51 13 MW -ID 0504067-001A A%A41209.D 21:54 14 MW -1S 0504067-002A AIA41210.D 22:21 • 15 Mw -Isms 0504067 002AMS A�A41211.D 16 78 4.4-0522:48 0504067-003A AW41212.D 23:16 17 MW-1SMSD 0504067-002AMSD A1A41213.D 23:44 COMMENTS: • page 1 of 1 FORM IV VOA OLM04.2 Cn O Cn F-4 1A VOLATILE ORGANICS ANALYSIS DATA SHBBT • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No.: PCTSL Matrix: (soil/water) WATER Sample wt/vol: 5 (g/mL) ML Level: (low/med) LOW % Moisture: not dec. GC Column• R Contract: • -502.2 ID: .53 (mm) Soil Extract Volume: (�L) BPA SAMPLE NO. VBLK040405 SAS No.: SDG No.: TSL001 Lab Sample IDs VELK040405 Lab File IDs A\A41196.D Date Received: U Date Analyzed: 04/04/05 Dilution Factor: 1.00 CAS NO. COMPOUND 74-87-3 Chloromethane 75-01-4 Vinyl chloride 74-83-9 Bromomethane 75-00-3 Chloroethane 67-64-1 Acetone 107-13-1 Acrylonitrile 74-88-4 Iodomethane 108-05-4 Vinyl acetate 78-93-3 2-Butanone 75-15-0 Carbon disulfide 75-69-4 Trichlorofluoromethane 75-35-4 1,1-Dichloroethene 75-09-2 Methylene chloride 156-60-5 trans-1,2-Dichloroethene 75-34-3 1,1-Dichloroethane 156-59-2 cis-1,2-Dichloroethene 74-97-5 Bromochloromethane 67-66-3 Chloroform 107-06-2 1,2-Dichloroethane 71-55-6 1,1,1 -Trichloroethane 56-23-5 Carbon tetrachloride 71-43-2 Benzene 79-01-6 Trichloroethene 78-87-5 1,2-Dichloropropane 74-95-3 Dibromomethane 75-27-4 Bromodichloromethane 10061-01-5 cis-1,3-Dichloropropene 108-88-3 Toluene 10061-02-6 trans-l,3-Dichloropropene 79-00-5 1,1,2- 1 106-93-4 1,2-Dibromoethane 108-10-1 4-Methyl-2-pentanone 108-90-7 Chlorobenzene 127-18-4 Tetrachloroethene 124-48-1 I Dibromochloromethane Soil Aliquot Volume (µL) CONCENTRATION UNITS: (µg/L or pg/Rg)UG/L Q 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 1 J 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U 5 U FORM I VOA - 1 OLM04.2 1B VOLATILE ORGANICS ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Lab Code: 10478 Case No.: PCTSL Matrix: (soil/water) WATER Sample wt/vol: 5 (g/m,) ML Level: (low/zed) LON % Moisture: not dec. GC Col - Contract: R-502.2 ID: .53 (mm) Soil Extract Volume: (µL) EPA SAMPLE NO. VBLK040405 SAS No.: SDG No.: TSL001 Lab Sample ID: VBLK040405 Lab File ID: A\A41196.D Date Received: Date Analyzed: 04/04/05 Dilution Factor: 1.00 Soil Aliquot Volume (µL) G M U U U U U U U U U U U 00 r--4 Cn .--4 CD 0 CONCENTRATION UNITS: CAS NO. COMPOUND (µg/L or µg/Xg) UG/L 591-78-6 2-Hexanone 630-20-6 1,1,1,2 -Tetrachloroethane 5 100-41-4 Ethylbenzene 5 1330-20-7 1 Xylene (total) 5 100-42-5 Styrene 5 75-25-2 Bromoform 5 110-57-6 trans-1,4-Dichloro-2-butene 5 • 79-34-5 1,1,2,2 -Tetrachloroethane 5 96-18-4 1,2,3-Trichloropropane 5 106-46-7 1,4 -Dichlorobenzene 5 95-50-1 1,2 -Dichlorobenzene 5 96-12-8 1,2-Dibromo-3-chloropropane 5 5 FORM I VOA - 2 OLM04.2 G M U U U U U U U U U U U 00 r--4 Cn .--4 CD 0 IF VOLATILE ORGANICS ANALYSIS DATA SHEET EPA SAMPLE NO. TENTATIVELY IDENTIFIED COMPOUNDS VBLK040405 Lab Name: H2M LABS, INC. Contract: • Code: 10478 Case No.: PCTSL SAS No.: SDG No.: TSL001 Matrix: (soil/water) WATER Lab Sample ID: VBLK040405 Sample wt/vol: 5 (g/mL) ML Lab File ID: A\A41196.D Level: (low/med) LOW Date Received: $ Moisture: not dec. Date Analyzed: 04/04/05 GC Column: R-502.2 ID: .53 (mm) — Dilution Factor: 1.00 Soil Extract Volume: (µl) Soil Aliquot Volume: 0 (µL) Number TICS found:CONCENTRATION UNITS: 0 (µg/L or pg/Kg) UG L CAS I�7MBER COMPOUNDNAME RT EST.CONC. Q • CN r---1 r --r C/] O FORM I VOA -TIC O OLM04.2 I4 DO U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg) : UG/L SDG No.: TSI,001 Calib. Initial UContinuing Calibration Blank j Prepa- Blank (ug/L) ration Analyte (ug/L) U1 I C 2 C 3 C C M 'Aluminum Blank 9. 6.� [A -17-01 Bi 6. 5 Lu -8,1801 B P 3.3 1 U 3.30011 U �n ril I---- 3.3 U Ars- -- Arsenic 1.9 3.3! U P B 1.9 B ium - -- L 1 9 U 1 2 . !Bar J -21U --6f - " - --- 2. B, I -_a -4 U, 1.2 j u - - -- - Beryllium --tJ 1.2001 1.2 21 U 0.2iU 0.2 UU I 1k1Bqron_ -0. 2--,r-U- -.7 1.7 L L 0 - 200; u U admiu - m U. 41 U - 1. 700! u 1 -�Pp 0.4 1 U lCalcium i � -6 1 - -- - -- - 0. 4: U 0.4 U 16 16.9 --6-400! u P IU ! , 2 Chromium I U --- - 0-i- -46-- 91 16.9 1.0 - U 16. 9001, U P U- U J- ICobalt 1.0 U! 1.0001 U P 2. 0:' U 1-01 - - I -- 2.0 U 2.0 i !Copper 0.9 1 U U 2.0 u r- - I I . - . - 2.000:U Iron - - ' -0. 9- VU 51 B 0.9 U 2.41 B 2.8 �B -- -- I - I -- 0 900�u P--! .Lead - 3.6, B -5 B 1.4; U f--- - 1 -1 .6 10-200 B i - - - - - --i - 1 1.4 1U 1.4! U; P �Magnesium --l-.4 U I.400, -u 6.2 6_2_ -- P Manganese 6.51 i ----- .6. 8!,-B, 6. 4 B6.200-'- - - --! U, 0.5 1 U ;u P iNi-ckel -- - 0.5! U 4 i_J - 0.5 U 0-500,u P I 31U Potassium __-I.-4 U -1. - 3 It _U T m U 1.300,u P I 11 1 U 1.1 U 1 11.100. 1 u p :Selenium 2. 4 --- - Silver - - 2.4 U �14 2.4 U 0.41 B ---- 2. 400 U P yi �Sodium -0-4 11 U 0-. 4- U i 0.4 U: --T 8 8' B 8-3 U, : 0. 400�' U�, P ITha-Ifium - 1 -_- - �.*-1 61--- -.-117-.4!-B - ; .- 9.7 B 8.300;' ui-' P 3.1, u ! - - i --- - � ---+ --;- - - I - 3.1 3.1001 U I p Zinc 1.01 U 1 U. 1.0t U f-:- 1 1.0 U 1.000 U- - I . 7' U -U- - -I - - -- - 4 - - . P 1.7 1.7r U 1.7 U 1.700 U P 0 FORM III - IN U.S. EPA - CLP S3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L iInitial Calib. Continuing Calibration I II Blank I Blank (ug/L) I Prepa- i Analyte I (ug/L) C' 1 Ii ration II --- — — i C 2 C 3 C Blank C' Mercury- -- — ----- — - - i I-- 1 o l00 U Cv L` Ia FORM III - IN ILM04.1 U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L SDG No.: TSL001 Initial r - Calib. Continuing Calibration Blank BlankPrepa- Analyte (u /L (ug/L) ration (ug/L) C 1 C 2 3 C1 Blank (Cyanide10.0— + — -- U 10.0 U 10. DI U 10.0 p -,- -- C M _L 10.000'U: CAJ - - --- - - ------ — —. ---- ------ r� SFORM III - IN ILM04.1 N N E-� • 112M LABS, INC. SDG: TSL001 Date: 21 -Apr -05 QC SUMMARY REPORT Spike Sample Recovery RPDRef %RPD _ Sample ID: _ Client Sample ID: Analvte Result Units Amount Result %REC Limits Value %RPD UCL �MBLK040705 MBLK040705 Alkalinity, Total (As CaCO3) <1 mg/L LCSO40705 ILCSO40705 Alkalinity, Total (As CaCO3) 21.8 mg/L 25 <1 87 80 120 0504067-002bms MW -1 SMS Alkalinity, Total (As CaCO3) 58.0 mg/L 25 33.8 97 75 125 0504067-002bdup IMW.lSDUP Alkalinity, Total (As CaCO3) 33.3 mg/L 33.8 1.3 20 MBLK040605 MBLK040605 jAlkalinity, Total (As CaCO3), High I < 5 1 mg/L I I j I I I I I ] LCSO40605 LCSO40605 Alkalinity, Total (As CaCO3), High 1 126 j mg/L 1 125 1 < 5 1 101 180 11201 �M�BLK�040105 iMBLK040105 Biochemical Oxygen Demand -2 mg/L MBLK040505 ,LCSO40105 LCS040105 Biochemical Oxygen Demand 186 mg/L 200 < 2 1 93 180 11201 MBLK040505 MBLK040505 Biochemical Oxygen Demand <2 mg/L LCSO40505 LCSO40505 Biochemical Oxygen Demand 178 mg/L 200 < 2 89 80 11201 0504067-002bdup MW-1SDUP Biochemical Oxygen Demand < 4 mg/L I 1 1 <2 +20 MB -041305 MB -041305 Bromide < 0.5 mg/L LCS-041305 LCS-041305 Bromide 4.9 mg/L 5 < 0.5 98 80 120 0504067-002BMS MW -ISMS Bromide 4.5 mg/L 5 <0.5 90 75 125 0504067-002BDUP MWASDUP Bromide < 0.5 mg/L < 0.5 20 MBLK040805 MBLK040805 Chemical Oxygen Demand <10 mg/L LCSO40805 LCSO40805 Chemical Oxygen Demand 1100 mg/L 1000 < 10 110 80 120 0504067-002dms MW -ISMS Chemical Oxygen Demand 1090 mg/L 1000 < 10 109 75 125 0504067-002ddup MWASDUP Chemical Oxygen Demand <10 mg/L <10 20 MBI -040405 M81-040405 lChlorlde < 1 I mg/L LCS1-040405 LCSI-040405 lChloride 50.5 1 mg/L 1 50 1 < 1 1 101 180 11201 1 TSL001 S 123 0 0 0 QC SUMMARY REPORT SDG: TSL001 Spike Sample Recovery RPDRef %RPD _ Sample ID_ _ Client Sample ID: Analyte Result Units Amount Result %REC Limits value %RPD UCL JMB-040605 MB -040605 Chloride < 1 mg/L 'LCS-040605 LCS-040605 Chloride 50.8 m91L 50 < 1 102 80 120 0504067-002BMS MW -ISMS Chloride 46.8 mg/L 25 20.6 105 75 125 0504067-002BDUP MW-ISDUP Chloride 20.3 mg/L 20.6 1.2 20 ,MBLK040205 MBLK040205 Chromium, Hexavalent < 0.02 mg/L LCS-040505 _ LCSO40205 LCSO40205 IChromium, Hexavalent LO.20 Jn+9/L 0504067-002Bdup 0.2 < 0.02 100 80 11201 �MB 040505 MB -040505 IChrorniurn, Hexavalent < 0.02 mg/L LCS-040505 LCS-040505 Chromium, Hexavalent 0.17 mg/L 0.2 < 0.02 85 80 120 0504067-002Bdup MW-1SDUP IColor <5 units I I i< 5 20 0504067-002BMS MW -ISMS IChromium, Hexavalent 0.17 mg/L 0.2 < 0.02 85 75 125 0504067-002Bdup ' MW -1 S D U P Chromium, Hexavalent < 0.02 mg/L < 0.02 1 20 MB -R47906 iMB-R47906 Icolor < 5 units LCS-R47906 LCS-R47906 Color 40 units 40 1 < 5 100 180 120 0504067-002Bdup MW-1SDUP IColor <5 units I I i< 5 20 IMBLK040205 IMBLK040205 lColor <5 1 units I i I I I I I I ILCSO40205 LCSO40205 jColor 40 1 units 1 40 1<511001801120i d MBLK040705 MBLK040705 Hardness (As CaCO3) < 5 mg/L _ LCSO40705 LCSO40705 Hardness (As CaCO3) 1040 mg/L 1000 < 5 104 80 120 0504067-002ems MW -ISMS Hardness (As CaCO3) 144 mg/L 100 40.0 104 75 125 0504067-002edup IMW-1SDUP Hardness (As CaCO3) 40.0 mg/L 40.0 0 20 mb-040505 mb-040505 Nitrate as N < 0.1 mg/L les -040505 Ics-040505 Nitrate as N 1.12 mg/L 1.13 <0.1 99 80 120 0504067-002DMS MW -ISMS Nitrate as N 3.52 m9/L 2.5 1.15 95 75 125 0504067-002DDUP MW -1 SDUP Nitrate as N 1.12 mg/L 1.15 2.6 20 2 TSL001 S 124 QC SUMMARY REPORT SDG: TSL001 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits value %RPD UCL M81-13164 MBI -040705 Nitrogen, Ammonia (As N) < 0.1 mg/L Ices -1-13204 Ics-041205 Nitrogen, Kjeldahl, Total 4.44 mg/L 4.1 < 0.1 108 80 120 MB -13164 MB -040705 Nitrogen, Ammonia (As N) < 0.1 mg/L 0504067-002DDUP MW-1SDUP Nitrogen, Kjeldahl, Total -0.29 mg/L <0.1 98.2 20 LCSI1-13164 LCSI1-040705 Nitrogen, Ammonia (As N) 0.55 mg/L 0.5 < 0.1 110 80 120 LCSI-13164 LCSI-040705 Nitrogen, Ammonia (As N) 0.52 mg/L 0.5 < 0.1 104 80 120 LCSht-13164 LCSht-040705 Nitrogen, Ammonia (As N) 2.74 mg/L 2.5 < 0.1 110 80 120 LCSh-13164 LCSh-040705 Nitrogen, Ammonia (As N) 2.68 mg/L 2.5 < 0.1 107 80 120 0504067-002DMS MWASMS Nitrogen, Ammonia (As N) 5.17 mg/L 50.13 101 75 125 0504067-002DDUP MW -1 SDUP Nitrogen, Ammonia (As N) < 0.1 1 mg/L I I I I j 0.13 1 200 120 Imb-13204 mb-041205 Nitrogen, Kjeldahl, Total < 0.1 mg/L Ices -1-13204 Ics-041205 Nitrogen, Kjeldahl, Total 4.44 mg/L 4.1 < 0.1 108 80 120 0504067-002DMS MW -ISMS Nitrogen, Kjeldahl, Total 4.30 mg/L 4.1 < 0.1 105 75 125 0504067-002DDUP MW-1SDUP Nitrogen, Kjeldahl, Total -0.29 mg/L <0.1 98.2 20 MBLK-041205 MBLK-041205 Phenolics, Total Recoverable < 5 ug/L LCS-041205 ILCS-041205 Phenolics, Total Recoverable 27.7 ug/L 30 < 5 92 80 120 0504067-002DMS MW -ISMS Phenolics, Total Recoverable 18.8 ug/L 20 <5 94 75 125 0504067-002Ddup MW -1 SDUP Phenolics, Total Recoverable < 5 ug/L < 5 20 IMB 040805 MB-040805 Sulfate < 5 mg/L I- --- - ILCS-040805_ - - jLCS-040805 Sulfate 20.2 mg/L 20 <5 101 80 120 1 504067-002BMS 05 04067-0028dup MW-1SMS Sulfate148 0504067-002bms mg/L 100 47.5 100 75 125 MW -1 SDU P Sulfate 47.0 mg/L 47.5 1.1 MBLK040505 MBLK040505 Total Dissolved Solids < 10 mg/L LCS040505 LCS040505 Total Dissolved Solids 297 mg/L 300 < 10 99 80 120 0504067-002bms MW -ISMS Total Dissolved Solids 542 mg/L 300 236 102 75 125 0504067-002bdup MW-1SDUP Total Dissolved Solids 245 mg/L 236 3.7 20 3 TSL001 S 125 QC SUMMARY REPORT SDG: TSL001 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID• Analyte Result Units Amount Result %REC Limits Value %RPD UCL MBLK-040605 MBLK-040605 Total Organic Carbon < 1 mg/L LCS-040605 LCS-040605 Total Organic Carbon 22.4 mg/L 25 < 1 90 80 120 0504067-002CMS MW-1SMS Total Organic Carbon 202 mg/L 100 111 91 75 125 0504067-002CDUP MW-1SDUP Total Organic Carbon 119 mg/L 111 7.1 20 MBLK-040705 MBLK-040705 ITotal Organic Carbon I <1 I mg/L LCS-040705 — ILCS-040705 jTotal Organic Carbon j 23.7 1 mg/L 1 25 1 < 1 1 95 180 j 1201 1 1 4 TSL001 S126 lH2M ILAIUS, INC. 10. INTERNAL STANDARD AREA DATA 10.1 VOLATILES • • r - N cn O cn F-+ 0 .ab Name: H2M LABS. INC. .ab Code: 10478 .ab File ID (Standard): nstrument ID: HP5971 3,C Column: R-502.2 ID: 52 01 02 03 D4 D5 D6 D7 D8 39 10 11 12 13 14 l5 18i 17' 18 I 8 INTERNAL STANDARD AREA AND RT SUMMARY SDG No.: TSI -001 A1A41195.13 Date Analyzed: 4/4/2005 Time Analyzed: 14:31 (mm) Heated Purge: (Y/N) N --- � v..Ka..VVIVVVIKQ110 IS2 DFB = 1,4-Dilluorobenzene AREA UPPER LIMIT = +100% of internal standard area AREA LOWER LIMIT = -50% of Internal standard area RT UPPER LIMIT = +0.50 minutes of internal standard RT RT LOWER LIMIT = -0.50 minutes of internal standard RT # Column used to flag values outside QC limits with an asterisk. ' Values outside of QC limits. IS3 CBZ = Chlorobenzene-05 IS4 DCB = 1,4 -Dichlorobenzene -d4 w 15:17 FORM VIII sw82so6 00 N O E -I IS1 PFB IS2 DFB IS3 CBZ IS4 DCB AREA # RT # AREA # RT # AREA # RT # AREA # RT # 12 HOUR STD 332824 9.390 347437 10.390 195269 15.030 169820 17.670 UPPER LIMIT 665648 9.890 694874 10.890 390538 15.530 339640 18.170 OWER LIMIT 166412 8.890 173719 9.890 97635 14.530 84910 17.170 SAMPLE NO. VBLK040405 318511 9.40 329738 10.40 174042 15.04 140135 17.67 LFB040405 312980 10.45 186400 15.04 ` 17.67 MS8040405 346009 9.38 356428 10.39 191629 15.03 1634775 I 17.67 EQUIPT. BLK 346871 ( 9.44 354500 10.42 187094 15.04 157193 I 17.67 TB 4/1/05 334438 9.33 346170 10.35 184441 15.02 158344 � 17.65 MW -3D 332321 9.39 344711 10.39 181953 15.03 157229 17.65 M 321797 9.34 333263 10.35 177396 15.01 148766 17.64 341487 9.42 349194 10.42 185396 � 15.03 160200 17.65 IA WW -61) W 331418 9.37 340095 10.38 180801 15.02 154946 17.65 -6S 343322 9.39 356004 10.40 187753 15.03 164207 17.66 WW -BD 336620 9.33 349791 10.34 184502 15.01 159181 17.64 ww-8S 371501 9.36 376788 10.36 197401 15.01 168357 17.65 NW -1D 322970 9.36 335753 10.37 177905 15.02 155432 17.64 uIW-1S 374082 9.49 378918 � 10.47 196078 � 15.05 165597 � 17.65 AW -ISMS 9.36 366917 10.36 191620 15.01 169216 17.64 '13 4-4-05 335769 335769 9.33 344703 10.34 183056 15.00 158058 17.63 AW-1SMSD 3562819. 10.37 15.01 159729 I 17.64 104 Mc. 380283 9.35 3696J89 10.35 1993596 15.01 170225 17.84 --- � v..Ka..VVIVVVIKQ110 IS2 DFB = 1,4-Dilluorobenzene AREA UPPER LIMIT = +100% of internal standard area AREA LOWER LIMIT = -50% of Internal standard area RT UPPER LIMIT = +0.50 minutes of internal standard RT RT LOWER LIMIT = -0.50 minutes of internal standard RT # Column used to flag values outside QC limits with an asterisk. ' Values outside of QC limits. IS3 CBZ = Chlorobenzene-05 IS4 DCB = 1,4 -Dichlorobenzene -d4 w 15:17 FORM VIII sw82so6 00 N O E -I