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Wet Chemistry Data Package 09/2005
Analytical Data Package For TOWN OF SOUTHOLD PART 360 ROUTINE, SDG NO: TSI.003 Water Samples Received: 9/16/05 WET CHEMISTRY DATA PACKAGE SEPTEMBER 2005 E :7 • IH2-A LABS, 1 N C. T&L-oo3 TABLE OF CONTENTS I. SAMPLE REPORTS II. Q.C. SUMMARY III. RAW DATA U2M LAOS, INC. • SAMPLE REPORTS • F12M LABS, INC. 575BMWHobN Road, Md ft NY 11747 (631)694MV.FAX (631)42MM NYSDOHD#t104M • Town of Southold Landfill Attn To Collected 9/162005 6:30:00 AM Received 9/16/2005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfaile Total Dissolved Solids Nitrogen, lgekiahl, Total Total Organic Carbon • LABORATORY RESULTS Lab No.: 0509510-001 Client ID.: MW -1D Results Qualifier D.F.. Units 41.0 1 mg/L <10 1 mg/L < 0.5 1 mg/L 28.4 1 mg/L <10 1 mg/L 74.0 2 mg/L < 0.10 1 mg/L 2.67 5 mg/L < 5.0 1 Pg/L 13.7 1 mg/L 685 1 mg/L < 0.10 1 mg/L < 1.0 1 mg/L • Qualifiers: E - V k. above 4uentifetion "",o D - Results for Dilution D.F. = Dilution Factor Date Reported : 10/72005 Page 1 of 13 Sample Information... Type : Groundwater Origin: Method Number Anahtzed E310.1 09202005 8:59 AM E405.1 09/162005 2:00 PM E320.1 09202005 2:25 PM E325.2 09/192005 3:36 PM E410.4 09202005 5:44 PM E130.2 09272005 3:10 PM E350.1 09/302005 12:58 PM E353.2 09212005 4:05 PM E420.1 09212005 8:30 AM SW9038 09202005 2:03 PM E160.1 09/192005 3:42 PM E351.2 09242005 8:16 PM SW9060 09202005 8:10 PM Laboratory Manager M M O F4 1-12M LAUS, INC. 575B(oadHdbv Road, M&le NY 11747 LABORATORY RESULTS (M1)6%-3DV.FAX MI)4208M NYSDOHD478 #10 Sample Information... Town of Southold Landfill Lab No. : 0509510-002 Type : Groundwater Attn To : Origin: Client ID. : MW -1S Collected 9/16/2005 6:50:00 AM Received 9/16/2005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameters) Results Qualftr D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 36.8 1 mg/L E310.1 09/20/2005 9:04 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/162005 2:05 PM Bromide < 0.5 1 mg/L E320.1 09202005 2:30 PM Chloride 22.7 1 mg/L E325.2 09/192005 3:37 PM Chemical Oxygen Demand <10 1 mg/L E410.4 09202005 5:45 PM Hardness (As CaCO3) 66.0 2 mg/L E130.2 09272005 3:15 PM Nitrogen, Ammonia (As N) 0.10 1 mg/L E350.1 09/30200512:58 PM Nitrate as N 2.63 5 mg/L E353.2 09212005 4:06 PM Phenolics, Total Recoverabie < 5.0 1 P91L E420.1 09212005 8:45 AM Sucrate 9.8 1 mg/L SW9038 0920/2005 2:05 PM Total Dissolved Solids 169 1 mg/L E160.1 09/192005 3:43 PM Nitrogen, ICleldahl, Total < 0.10 1 mg/L E351.2 09242005 8:17 PM Total Organic Carbon < 1.0 1 mg/L SW9060 09202005 8:39 PM • Qualifiers: E - Value above c#wnti jon ranpe D - Resub for Dilution D.F. = Dilution Factor Date Reported : 10!12005 Page 2 of 13 awo. �;(/ upcl� Laboratory Manager 7t M 0 F-4 t12M IA13S9 INC. 57513iU dHdbw Road, M&b NY 11747 LABORATORY RESULTS (631)694,9040. FAX (631)4208436 NYSDOH DV 10478 Sample Information... Town of Southold Landfill Lab No. : 0509510-003 Type: Groundwater Attn To : Origin: Client ID.: MW -3D Collected 9/15/2005 2:45:00 PM Received 9/16/2005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameter(s) Results uali r P.F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 39.6 1 mg/L E310.1 0920/2005 9:19 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/162005 2:15 PM Bromide < 0.5 1 mg/L E320.1 09202005 2:45 PM Chloride 22.7 1 mg/L E325.2 09/192005 3:40 PM Chemical Oxygen Demand < 10 1 mg/L E410.4 09202005 5:50 PM Hardness (As Ca=) 70.0 2 mg/L E130.2 09272005 3:30 PM Nitrogen' Ammonia (As N) 0.11 1 mg/L E350.1 09/302005 1:00 PM Nitrate as N 3.27 5 mg/L E353.2 09212005 4:08 PM Phenolics. Total Recoverable < 5.0 1 K/L E420.1 09212005 9:00 AM Sulfate 10.3 1 mg/L SVV9038 09202005 2:11 PM Total Dissolved Solids 191 1 mg/L E160.1 09/192005 3:46 PM Nitrogen, Kiekiahl, Total < 0.10 1 mg/L E351.2 09242005 8:19 PM Total Organic Carbon < 1.0 1 mg/L SW9060 09202005 10:06 PM • Qualifiers: E - Value above quantitation range D - Reaub for Dilution D.F. = Dilution Factor Date Reported : 10!72005 Page 3 of 13 Laboratory Manager U2M L ESO INC. 575BMWHObN Road M*b NY 11747 LABORATORY RESULTS (631)8B4aM.FAX 1631)4208436 NYSDOH ID# 10478 • Town of Southold Landfill Lab No. : 0509510-004 Sample Information... Type : Groundwater Attn To : Origin: Client ID.: MW -3S Collected 9/158005 2:20:00 PM Received 9/168005 9:53:00 AM Collected By CLIENT Copies To Original CC Parame111W Results Qualifier p F.lain' � Method Number Analvmd Alkalinity, Total (As CaCO3) 44.2 1 mg/L E310.1 09808005 9:24 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/16/2005 2:20 PM Bromide 1.2 1 mg/L E320.1 09808005 2:50 PM Chloride 22.3 1 mg/L E325.2 09/198005 3:41 PM Chemical Oxygen Demand 14.3 1 mg/L E410.4 09208005 5:51 PM Hardness (As CaCO3) 72.0 2 mg/L E130.2 09272005 3:35 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 09/30/2005 1:01 PM Nitrate as N 3.31 5 mg/L E353.2 09812005 4-08 PM Phenolics. Total Recoverable < 5.0 1 Ng/L E420.1 0921/2005 9115 AM Sulfate 11.0 1 mg/L SW9038 09/208005 2:13 PM Total Dissolved Solids 170 1 mg/L E160.1 09/192005 3:47 PM Nitrogen, Kjeldahl, Total < 0.10 1 mg/L E351.2 09242005 8:20 PM Total Organic Carbon < 1.0 1 mg/L SW9060 0920200510:36 PM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported: 10/72005 Page 4 of 13 Laboratory Manager U2M LA[3S9 INC. 575BIoedHobN Road, Moria W 11747 LABORATORY RESULTS (631)W-1(M.FAX,(631)4208436 NYSDOHD#10478 Sample Information... is Town of Southold Landfill Lab No. : 0509510-005 Type: Groundwater Attn To : Origin: Client ID.: MW -4D Collected 9/15/2005 12:40:00 PM Received 9/16/2005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameter(s) Results Qualifier D_F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 42.4 1 mg/L E310.1 09/20/2005 9:29 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/16/2005 2:25 PM Bromide < 0.5 1 mg/L E320.1 09420/2005 2:55 PM Chloride 23.0 1 mg/L E325.2 09/1942005 3:42 PM Chemical Oxygen Demand < 10 1 mg/L E410.4 0942042005 5:52 PM Hardness (As CaCO3) 72.0 2 mg/L E130.2 0942742005 3:40 PM Nitrogen, Ammonia (As N) 0.14 1 mg/L E350.1 09/3042005 1:02 PM Nitrate as N 3.15 5 mg/L E353.2 0942142005 4:09 PM Phenolics, Total Recoverable < 5.0 1 Ng/L E420.1 0942142005 9:30 AM Sulfate 11.5 1 mg/L SW9038 0942042005 2:15 PM Total Dissolved Solids 177 1 mg/L E160.1 09/19/2005 3:48 PM Nitrogen, Kjeldahl, Total < 0.10 1 mg/L E351.2 0942442005 8:37 PM Total Organic Carbon < 1.0 1 mg/L SW9060 09420/2005 11:06 PM �J • Qualiflen: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 10/742005 Page 5 of 13 Laboratory Manager U2M t AlBso INC. 575BMWHibm Road MWIle NY 11747 (631)6943040. FAX (631)42D8436 WSDOHD910478 Town of Southold Landfill Attn To Collected 9/152005 12:10:00 PM Received 9/162005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, lgektahl, Total Total Organic Carbon LABORATORY RESULTS Lab No. : 0509510-006 Client ID.: MW -4S Sample Information... Type: Groundwater Origin: Results Qualifier D.F.. Units Method Number Analyzed 37.8 1 mg/L E310.1 09202005 9:34 AM < 2 1 mg/L E405.1 09/162005 2:30 PM 1.2 1 mg/L E320.1 09202005 3:00 PM 22.5 1 mg/L E325.2 09/192005 3:42 PM <10 1 mg/L E410.4 09202005 5:53 PM 72.0 2 mg/L E130.2 09272005 3:45 PM 0.14 1 mg/L E350.1 09/302005 1:02 PM 3.41 5 mg/L E353.2 09212005 4:10 PM < 5.0 1 lrg/L E420.1 09212005 9:45 AM 11.0 1 mg/L SW9038 09202005 217 PM 181 1 mg/L E160.1 09/192005 3:49 PM < 0.10 1 mg/L E351.2 09242005 8:38 PM < 1.0 1 mg/L SW9060 09202005 11:35 PM • Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 10!12005 Page 6 of 13 Laboratory Manager 00 M 0 U 2M tAJUS, INC. 575BIoWMW RWA M&b W 11747 LABORATORY RESULTS (W1)W4.'i090.FAX(831)a)4) 6 WSDOHD#10478 • Town of Southold Landfill Lab No.: 0509510-007 Sample : Groundwater Type : Groundwater Attn To : Origin: Client ID.: MW -5D Collected 9/15800511:20:00 AM Received 9/168005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 37.6 1 mg/L E310.1 09/202005 9:39 AM Biochemical Oxygen Demand 28 1 mg/L E405.1 09/162005 2:35 PM Bromide < 0.5 1 mg/L E320.1 09202005 3:05 PM Chloride 23.7 1 mg/L E325.2 09/192005 3:43 PM Chemical Oxygen Demand 39.3 1 mg/L E410.4 09202005 5:54 PM Hardness (As CaCO3) 70.0 2 mg/L E130.2 09272005 3:50 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 09/3020051:03 PM Nitrate as N 2.70 5 mg/L E353.2 09212005 4:10 PM Phenolics, Total Recoverable < 5.0 1 W/L E420.1 09212005 10:00 AM Sulfate 20.8 1 mg/L SW9038 09202005 2:19 PM Total Dissolved Solids 413 1 mg/L E160.1 09/192005 3:50 PM Nitrogen, Kjeldahl, Total 0.34 1 mg/L E351.2 09242005 8:40 PM Total Organic Carbon < 1.0 1 mg/L SW9060 0921200512:05 AM • Quamera: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 10!72005 Page 7 of 13 ?anvo- �h X-jd�- � Laboratory Manager U2-" I -AUS, INC. 5756toedHolow Road, M&ft NY 11747 (M1)W4-W0. FAX (631)QU436 NYSDDHD#10478 0 Town of Southold Landfill Attn To : Collected 9/15/200510:50:00 AM Received 9/16/2005 9:53:00 AM Collected By CLIENT Copies To Original CC LABORATORY RESULTS Lae No. : 0509510-008 Client ID.: MW -6S Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier[�F. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 39.9 1 mg/L E310.1 09/20/2005 9:54 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/162005 2:40 PM Bromide < 0.5 1 mg/L E320.1 09202005 3:10 PM Chloride 22.7 1 mg/L E325.2 09/192005 3:44 PM Chemical Oxygen Demand 34.3 1 mg/L E410.4 09/20/2005 5:55 PM Hardness (As CaCO3) 72.0 2 - mg/L E130.2 09/27/2005 3:55 PM Nitrogen, Ammonia (As N) 0.42 1 mg/L E350.1 09/30/2005 1:04 PM Nitrate as N 2.70 5 mg/L E353.2 0921/2005 4:11 PM Phenolics, Total Recoverable < 5.0 1 yg/L E420.1 09212005 10:15 AM Sulfate 10.4 1 mg/L SW9038 09/20/2005 2:21 PM Total Dissolved Solids 181 1 mg/L E160.1 09/19/2005 3:51 PM Nitrogen, Kjeldahl, Total < 0.10 1 mg/L E351.2 09/24/2005 8:40 PM Total Organic Carbon < 1.0 1 mg/L SW9060 09/21/2005 12:34 AM • Qualifiers: E - Value above quantitation range D - Resutta for Dilution D.F. = Dilution Factor Date Reported: 10!12005 Page 8 of 13 Laboratory Manager U2M LA[3S9 INC. 575BroadHobN Road, Meloid NY 11747 LABORATORY RESULTS (631)694.MM.FAX (631)4208436 NYSDOHD#10478 Sample Information... • Town of Southold Landfill Lab No. : 0509510-009 Type: Groundwater Attn To : Origin: Client ID.: MW -613 Collected 9/16/2005 7:30:00 AM Received 9/16/2005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 37.9 1 mg/L E310.1 09/20/2005 9:59 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/16/2005 2:45 PM Bromide < 0.5 1 mg/L E320.1 09/20/2005 3:15 PM Chloride 22.3 1 mg/L E325.2 09/19/2005 3:44 PM Chemical Oxygen Demand 162 1 mg/L E410.4 09/20/2005 5:56 PM Hardness (As CaCO3) 68.0 2 mg/L E130.2 09/27/2005 4:10 PM Nitrogen, Ammonia (As N) 0.15 1 mg/L E350.1 09/302005 1:06 PM Nitrate as N 2.79 5 mg/L E353.2 09212005 4:13 PM Phenolics, Total Recoverable < 5.0 1 Ng/L E420.1 09212005 10:30 AM Sulfate 10.4 1 mg/L SW9038 09202005 2:23 PM Total Dissolved Solids 174 1 mg/L E160.1 09/192005 3:54 PM Nitrogen, Keklahl, Total < 0.10 1 mg/L E351.2 09242005 8:41 PM Total Organic Carbon 40.9 1 mg/L SW9060 09212005 1:58 AM 1r u 0 Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported : 10/72005 Page 9 of 13 Laboratory Manager U2M LABS, INC. 575BMWHobw Roel, M&b NY 11747 (631)694,9040. FAX (31)4208436 NYSDOHD#10478 • Town of Southold Landfill Attn To Collected 9/162005 8:00:00 AM Received 9/16/2005 9:53:00 AM Collected By CLIENT Copies To Original CC LABORATORY RESULTS Lab No. : 0509510-010 Cilent ID.: MW -6S Sample Information... Type: Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 40.3 1 mg/L E310.1 09/20/200510:04 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/16/2005 2:50 PM Bromide 0.6 1 mg/L E320.1 09202005 3:20 PM Chloride 22.5 1 mg/L E325.2 09/192005 3:45 PM Chemical Oxygen Demand 19.3 1 mg/L E410.4 09202005 5:57 PM Hardness (As CaCO3) 70.0 2 mg/L E130.2 09272005 4:15 PM Nitrogen, Ammonia (As N) 0.23 1 mg/L E350.1 09/302005 1:06 PM Nitrate as N 2.70 5 mg/L E353.2 09212005 4:14 PM Phenolics, Total Recoverable < 5.0 1 pg/L E420.1 0921200510:45 AM Sulfate 10.5 1 mg(L SW9038 09202005 2:25 PM Total Dissolved Solids 174 1 mg/L E160.1 09/192005 3:55 PM Nitrogen, Kjeldahl, Total < 0.10 1 mg/L E351.2 09242005 8:42 PM Total Organic Carbon < 1.0 1 mg/L SW9060 09212005 2:28 AM F- -I L_ J Qualifiers: E - Value above quantitation range • D - Resub for Dilution D.F. = Dilution Factor Date Reported : 10/72005 Page 10 of 13 Laboratory Manager U2M LABS, INC. MBMWHobv flood M*b NY 11747 LABORATORY RESULTS (631)%4,3D0.FAX(631KD84W NYSDOHD#10478 • Town of Southold Landfill Lab No. : 0509510-011 Sample Information... Type : Groundwater Attn To : Origin: Client ID.: MW -813 Collected 9/15/2005 1:55:00 PM Received 9/16/2005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameter(sl Results ualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 40.2 1 mg/L E310.1 09/20/200510:09 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/162005 2:55 PM Bromide 0.6 1 mg/L E320.1 09202005 3:25 PM Chloride 22.6 1 mg/L E325.2 09/192005 3:46 PM Chemical Oxygen Demand 51.8 1 mg/L E410.4 0920/2005 5:58 PM Hardness (As CaCO3) 70.0 2 mg/L E130.2 09272005 4:20 PM Nitrogen, Ammonia (As N) 0.14 1 mg/L E350.1 09/3020051:07 PM Nitrate as N 3.12 5 mg/L E353.2 09212005 4:14 PM Phenolics, Total Recoverable < 5.0 1 K& E420.1 09212005 11:00 AM Sulfate 11.1 1 mg/L SW9038 09202005 2:27 PM Total Dissolved Solids 192 1 mg/L E160.1 09/192005 3:56 PM Nitrogen, KwIdahl, Total < 0.10 1 mg/L E351.2 09242005 8:42 PM Total Organic Carbon < 1.0 1 mg/L SW9060 09212005 3:01 AM Qualifiers: E - Value above quantitation range D - Results for Dilution D.F. = Dilution Factor Date Reported: 10/72005 Page 11 of 13 Laboratory Manager U 4 TAUS, INC. 575Br adHdm Road, Mt'Wia NY 11747 (631)6943040. FAX (631)4208436 NYSDOH ID# 10478 Town of Southold Landfill Attn To : Collected 9/15/20051:20:00 PM Received 9/16/2005 9:53:00 AM Collected By CLIENT Copies To Original CC LABORATORY RESULTS Lab No. : 0509510-012 Client ID.: MW -8S Sample Information... Type : Groundwater Origin: Parameter(s) Results Qualifier D.F.. Units Method Number Analyzed Alkalinity, Total (As CaCO3) 38.6 1 mg/L E310.1 09201200510:14 AM Biochemical Oxygen Demand <2 1 mg/L E405.1 09/162005 3:00 PM Bromide 0.7 1 mg/L E320.1 09202005 3:30 PM Chloride 22.5 1 mg/L E325.2 09/192005 3:46 PM Chemical Oxygen Demand 41.8 1 mg/L E410.4 09202005 6:01 PM Hardness (As CaCO3) 70.0 2 mg/L E130.2 09272005 4:25 PM Nitrogen, Ammonia (As N) 0.10 1 mg/L E350.1 09/302005 1:08 PM Nitrate as N 2.85 5 mg/L E353.2 09212005 4:15 PM Phenolics, Total Recoverable < 5.0 1 Ng/L E420.1 09212005 11:15 AM Sulfate 12.2 1 mgA- SW9038 0920/2005 2:29 PM Total Dissolved Solids 180 1 mg/L E160.1 09/19/2005 3:57 PM Nitrogen, Kjeldahl, Total < 0.10 1 mg/L E351.2 09242005 8:43 PM Total Organic Carbon < 1.0 1 mg/L SW9060 09212005 3:30 AM Qualifiers: E - Value above quantitation range • D - ResuMs for Dilution D.F. = Dilution factor Date Reported : 10/7/2005 Page 12 of 13 ?awo;. �h Z-i�- � Laboratory Manager U2M tAJUS, INC. 57513108di—dw R°ed' Meda NY 11747 LABORATORY RESULTS (631)6943040. FAX (631)4208436 NYSDOH D# 10478 Sample Information... • Town of Southold Landfill Lab No. : 0509510-013 Type : Blank Attn To : Origin: Client ID.: EQPT BLANK 9/16 Collected 9/16/2005 6:30:00 AM Received 9/16/2005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameter(s) Results Qualifler D.F.. Units Method Number Ana Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310.1 09/20/200510:19 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/16/2005 3:05 PM Bromide 0.6 1 mg/L E320.1 09/20/2005 3:35 PM Chloride < 2.0 1 mg/L E325.2 09/19/2005 3:48 PM Chemical Oxygen Demand <10 1 mg/L E410.4 0920/2005 6:02 PM Hardness (As CaCO3) < 5.0 1 mg/L E130.2 09272005 4:30 PM Nitrogen, Ammonia (As N) 0.11 1 mg/L E350.1 09/302005 1:08 PM Nitrate as N < 0.10 1 mg/L E353.2 09212005 4:16 PM Phenolics, Total Recoverable < 5.0 1 ug/L E420.1 0921200511:30 AM Sulfate < 5.0 1 mg/L SW9038 09202005 2:31 PM Total Dissolved Solids 19 1 mg/L E160.1 09/192005 3:58 PM Nitrogen, Kjeldahl, Total < 0.10 1 mg/L E351.2 09242005 8:27 PM Total Organic Carbon < 1.0 1 mg/L SW9060 09212005 4:00 AM 1r u • Qualifiers: E - value above quantitation range 0 - Re& Ms for Dilution D.F. = Dilution Factor Date Reported: 10/72005 Page 13 of 13 Laboratory Manager U2M L,AUS, INC. 0 11. Q.C. SUMMARY • • • HZM LABS, INC. SDG: TSL003 Date: 07 -Oct -05 QC SUMMARY REPORT Spike Sample Recovery RPDRef %RPD Sample ID• Client Sample ID• Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -092005 MB -092005 Alkalinity, Total (As CaCO3) < 1 mg/L LCS-092005 LCS-092005 Alkalinity, Total (As CaCO3) 21.8 mWL 25 < 5 87 80 120 0509510-002dms MW-1SMS Alkalinity, Total (As CaCO3) 63.0 mg/L 25 36.8 105 75 125 0509510-002ddup MW-1SDUP Alkalinity, Total (As CaCO3) 36.5 mg/L 36.8 0.82 20 MB -091605 MB -091605 Biochemical Oxygen Demand < 0.5 < 2 mg/L 0509510-002bdup LCS-091605 LCS-091605 Biochemical Oxygen Demand Bromide 204 rnp/L 200 < 2 102 80 1120 ---20 0509510-002ddup MWASDUP Biochemical Oxygen Demand MWA SMS < 2 rn0/L < 2 MB -R53365 MB -1153365 Bromide — < 0.5 mWl MWASMS 0509510-002bdup MWA SDUP LCS-R53365 LCS-R53365 Bromide 5.4 mg/L5 LCS1-091905 < 0.5 108 80 120 MWA SMS 0509510-002DMS MWA SMS Bromide 4.5 n WL _ 5 < 0.5 90 75 125 0509510-00213dup MW-1SDUP Bromide — < 0.5 mg/t. < 0.5 20 MB -092005 MS -092005 LCS-092005 LCS-092005 0509510-002bms MWASMS 0509510-002bdup MWA SDUP Oxygen Demand < 10 MB1-091905 MBl-091905 LCS1-091905 LCS1-091905 0509510-002DMS MWA SMS 0509510-0021313UP MWASDUP Oxygen Demand <10 mg/ Oxygen Demand 1020_ —_ Oxygen Demand _ 1030 m9 Oxygen Demand < 10 mWl 1000 < 10 102 80 120 L 1000 < 10 103 75 125 —. — — < 10 — 20 Chloride < 2 mg/L Chloride _ _ 50.2 n�WL 50 < 2 100 80 Chloride 49.0 MWL 25 22.7 105 175 Chloride — — 22.7 mWl 22.7 1 0 MB -092705 MB -092705 Hardness (As CaCO3) < 5 mg/L LCS-092705 LCS-092705 Hardness (As CaCO3) 1040 moll. 1000 < 5 104 80 120 0509510-002cros MWASMS Hardness (As CaCO3) 276 mWL 200 66.0 105 75 125 0509510-002cdup MWASDUP Hardness (As CaCO3) 66.0 mWL 66.0 0 20 TSL003 W17 Chloride < 2 mg/L Chloride _ _ 50.2 n�WL 50 < 2 100 80 Chloride 49.0 MWL 25 22.7 105 175 Chloride — — 22.7 mWl 22.7 1 0 MB -092705 MB -092705 Hardness (As CaCO3) < 5 mg/L LCS-092705 LCS-092705 Hardness (As CaCO3) 1040 moll. 1000 < 5 104 80 120 0509510-002cros MWASMS Hardness (As CaCO3) 276 mWL 200 66.0 105 75 125 0509510-002cdup MWASDUP Hardness (As CaCO3) 66.0 mWL 66.0 0 20 TSL003 W17 TSL003 W17 • • • QC SUMMARY REPORT SDG: TSL003 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL �-092105 mb-092105 Nitrate as N < 0.1 moil. -092105 Ics-092105 Nitrate as N 1.10 41 1.13 1 <0.1 97 80 120 )9510-002BMS MWASMS Nitrate as N 5.03 myL. 2.5 2.63 96 75 125 )9510.002BDUP MW -1 SDUP Nitrate as N 2.65 m9/L 2.63 0.80 ; MS -14934 MB -093005 Nitrogen, Ammonia (As N) < 0.1 mg/L LCS-14934 LCS-093005 Nitrogen, Ammonia (As N) 1.03 mg/L 1 < 0.1 103 80 120 0509510-002BMS MW -1 SMS Nitrogen, Ammonia (As N) 5.55 mg/L 5 0.10 109 75 125 0509510-002BDUP MWASDUP Nitrogen, Ammonia (As N) 0.11 mg/L 0.10 13.1 20 mb-14877 mt-092405 Nitrogen, Kjeldahl, Total < 0.1 mg/L Ics-14877 Ics-092405 Nitrogen, Kjeldahl, Total 3.96 mg/L 4.1 < 0.1 97 80 120 0509510-002BMS MWA SMS Nitrogen, Kjeldahl, Total 3.96 mg/L 4.1 < 0.1 97 75 125 0509510-002BDUP MW-1SDUP Nitrogen, Kjeldahl, Total < 0.1 m9►L < 0.1 20 MB -092105 MB -092105 Phenolics, Total Recoverable < 5 ug/L LCS-092105 LCS-092105 Phenolics, Total Recoverable 27.7 ug/L 30 < 5 92 80 120 0509510-002bms MWA SMS Phenolics, Total Recoverable 18.8 ug/l- 20 < 5 94 75 125 0509510-002bdup MW-1SDUP Phenolics, Total Recoverable < 5 ug/L < 5 20 MB -092005 MB -092005 Sulfate < 5 mg/L LCS-092005 LCS-092005 Sulfate 19.0 mg/L 20 < 5 95 80 120 0509510-002DMS MW -ISMS Sulfate 29.5 mgk 20 9.8 98 75 125 0509510-002Ddup MW-1SDUP Sulfate 10.1 m91L 9.8 3.0 20 MB -091905 MB -091905 Total Dissolved Solids <10 MOIL LCS-091905 LCS-091905 Total Dissolved Solids 344 mgtL 300 <10 115 80 120 0509510-002dms MW -ISMS Total Dissolved Solids 529 mg/L 300 169 120 75 125 0509510-002ddup MW -1 SDUP Total Dissolved Solids 207 m9/L 169 20.2 20 2 TSL003 W18 • QC SUMMARY REPORT SDG: TSL003 Spike Sample Recovery RPDRef %RPD Sample ID• Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB -092005 MB -092005 Total Organic Carbon < 1 mg/L LCS-092005 LCS-092005 Total Organic Carbon 27.7 mWL 25 < 1 111 80 120 0509510-002AMS MWA SMS Total Organic Carbon 10.8 mg/L 10 < 1 108 75 125 0509510-002ADUP MW-1SDUP Total Organic Carbon < 1 mg/L < 1 20 TSL003 W19 U2M RAPS, INC. 0 III. RAW DATA • • • TALK low ICV TV=25MG/L 100 MOM= 9.33 2.26 4.18 0.08 21.80 87.20% 8:44.13 AM TALK low ICBi 100 94=004 4.87 0.06 4.16 0.05 0.10 <1.0. TALK bw 0509175-001 a 10Q 9/2=005` 5.16 0:08 4.10 0':09 _0:10 <1.0 8:59"08 AM, , I ad 1Q0 5 6:34 4.31 4.17 0.21 41.5 h= .1. TALK lOw' 0509510 002d 100 9202005 6.33 3.83 4.17 0;15 36.8Q.- MVU w�' ,. 01 AM ` 6.49 # 419 0'19 ' yx . X04 NW -1, WALK Iow OSQ951Q-0�}2ddup- 100 a ,4905 6.19 3.80' 4.19 0:15 3 50 rpd=0 820% M.1,S3'.I�` 1 Jill , �� 0 1 100 5 6.26 4.13 417 0:17 �.. Y TALK Iowa; 0509510.004d 100 9/2 5 6133 4.65' 4.14 0123 44.70 MV;3S. 1y5:IAM' T�♦♦ q >� 0., 10A k 8157 4,43 4:""17 Of"19 42 TALK low; 0509510�006d 100 91 OJ200S 6.50 3.94 4..1$, 0:18 37,80 TALK IoW -050951.0;0,D,074: 1,00,19/20�200� : 6:59 .4:06 '4:16 0 30 37;85 TALK low ccv t"25mgA 100 920/2005 9.46 2.54 4.16 0.12 24:25 97% 10:18:19 AM TALK low ccb 100 920/2005 5.11 0.08 4.19 0.09 -0.05 <1.0 10;29,36 AM TALK low :4509510-0084; 100 9/20/2005 6:38 4.18 4.14 0:19 39.90 MV1N5S 10:33:06 AM: '. 3.98' 4:13: 0.19 37:80 0509510�010d ;; 100 6;44 4.22! 4.15 0:19 40.30 r, '4:20 4:17 X0:18 °4010 ��- T'5 1- av 3 �%� /-",- %� D - 007N lof'brsio� Page 1 of 3 TSL003 W21 y�� Page 2 of 3 TSL003 W22 • Page 3 of 3 TSL003 W23 • AVON . Aff AFXM M M JS i XWIffa a dff tv 12M s p4c. BODs I-S"M3 JALYST: CALIBRATION CIiECK: IN OUT ATE IN: WINKLER ATE OUT: METER c 'ANDARD DUPLICATE :UE VALUE SAMPLE # f= mL = �• ►3•(0 =- ?SULT RESULT l mL RECOVERY i UZ 1, DUPLICATE m Chlorine -mg/L- :•. r• r• r• ® r• :•r Chlorine :•• • 1 Maw H Ad'.: A_B# Chlorine , SAMP. I DO. nnl AVG m /L BOD A DO S.C. DO -SC e a :•r� Ya•51A1WJ m WA: Chlorine mi/L :•.off r• r• r• I ff T191 �Tm:•r OEM Ya•51A1WJ m WA: Chlorine .� : •. r• r• r• I ff T191 �Tm:•r ltll►'% V ,u a.1wiwj EWA ne owl. P Ofl l i H2M tA13S, INC. BODS NALYST: 1ATE IN: 1ATE OUT: rANDARD DUPLICATE RUE VALUE --SAMPLE # ESULT RESULT RE ERY DUPLICATE WIRWX RPD !C%A. -0% r Chlorine •, `oto, R !! MKOMrr WIRWX ml ��Ltsl-ODIA H Ad•.: AVG kB# Chlorine _ m L BOD SAMP. DO, DOF 13 S.C. DO -SC BOD CALIBRATION CHECK: IN _ OUT WINKLER METEIC ML n�07 hl • :�� �%�uM: a •• I '' r�E: 'i�Lfl�ii��7�iis ►7�r� &gffMW-M 0_ � M• r �r� mac•»������r�N� Chlorine •, `oto, R !! MKOMrr CALIBRATION CHECK: IN _ OUT WINKLER METEIC ML n�07 hl • :�� �%�uM: a •• I '' r�E: 'i�Lfl�ii��7�iis ►7�r� &gffMW-M 0_ � M• r �r� mac•»������r�N� TNLUUJ WL-') v GO,;f';f Chlorine •� `oto, R !! MKOMrr TNLUUJ WL-') v GO,;f';f .mmmmww..1�. n i i ME non i i m m i -W w M2 -At I AUS, INC. BODS .NALYST: TATE IN: 1 1 b TATE OUT: Q I ()C TANDARD DUPLICATE 11 RUE VALUE SAMPLE # ESULT RESULT . . Chlorine mg1l I.1.1."I • M I` Me 1 • 1 • • 1 • ® 1 • • 1 CALIBRATION CHECK: IN ^ OUT W INKL TER f= mL = ML i�i� �• -Chlorine- EM :.. li Chlorine MR/L :.. 11 I.. •I• r�� 1• :61 _SSL• �■«+�����nr� I.1.1."I • M I` Me 1 • 1 • • 1 • ® 1 • • 1 CALIBRATION CHECK: IN ^ OUT W INKL TER f= mL = ML i�i� �• -Chlorine- EM :.. li i- :.. 1• 1• • 1• 1• • 1 _SSL• �■«+�����nr� lot — Chlorine—:..mail 1• 1• • 1• 1• • 1 _SSL• �■«+�����nr� N U2M IKES, INC. ANALYST: DATE IN: qW01K DATE OUT: STANDARD CATE TRUE VALUE SAMPLE # RESULTRESULT % RECOVE DUPLICATE �n✓�.. ntCM7rn,l►1� B01P5 CALIBRATION CHECK: IN OUT WINKL . ETER Chlorine M946 �i�'i7 Eta■ ������! Chlorine mg1L I1sialIJ �I�-Chlonne . 1 • ® 1 • : • • • 1 II O� TSL003 W29 f - mL = mL a i -�.• _ j :�• • / VA'� 1• 1• . 1• r�' 1• • 1 �c�■�:aw� aacI rr��. MM m ifs»�L�•����I�� W70 4 7 Chlorine mg/L Chlorine m /L �� 1• . 1• ® 1• c•1 !aFaia:� ar��a��a����aF.•r.-�� Chlorine mg/L :•• �� 1• . 1• ® 1• c•1 P OOLS t J H21VI LABS, INC, BROMIDE G g Br (mg/L) =13,320 xA x B_ D x E C F B&E-Nonud4ofrft"_ 11 &0075 N DATE: ANALYST:. — Nit 0 A=ASE-A KAW D=DsAwu-Dw_ua �2S�y0 AeL,. = 3- 3 mL E�LAW = i z ML TS�.4a 3 re& g,$7. BRAN+LUEBBE AACE 5.47 Post -run Report 0 H2M LABS INC. Post -run report Name of Run : CL091905A B Name of Analysis :cl.ANL Date of Report : 9/19/05 1 System No. :1 Date of Run . 9/19/05 2 Type of System :TRAACS Operator : CP 98.790 1 Start/Stop time :15:12 - 16:02 Comment S1 Sigh 98.969 1 MSL, TSL, DGN 0 / /� TSL 003 , /� 1, N 5L 0740 R W 0) �7 Channel Type 5 Real Data Channel 0.305 1 2 2 Method Cal. Method 2 Dilution 7 Unit C mg/l mg/L Calibr. Fit 3 Quadratic Cal. Corr. Coeff. 9 1.0000 C Base 19.925 1 68 5 Gain Cal. 18 11 Sensitivity C 0.4924 0.076 1 Sample Limit 1 9 QC3 CRA 2.0 Sample Limit 2 13 10 QC1 • Pk Cup Sample Id Value Value 0 0 B Baseline 0.022 0 1 1 P Primer 100.672 1 2 1 D Drift 98.790 1 3 1 S1 Sigh 98.969 1 4 0 L1 Low 0.305 1 5 0 L1 Low 0.305 1 6 1 C Cal. 100.079 1 7 2 C Cal. 74.712 1 8 3 C Cal. 50.327 1 9 4 C Cal. 19.925 1 10 5 C Cal. 9.859 1 11 0 C Cal. 0.076 1 12 9 QC3 CRA 2.0 1.926 1 13 10 QC1 LCS 50 50.218 100 % 1 14 0 QC10MBLR -0.130 0 1 15 11 S 0509516-003A 31.861 1 16 12 S 0509516-004A 31.054 1 17 13 S 0509523-001A 18.635 1 18 14 S 0509523-002A 18.352 1 19 15 S 0509523-003A 2.031 1 20 16 S 0509531-OOIA 25.874 1 1021 17 S 0509510-OO1D 11W - ►� 28.395 1 OC Limits BRAN+LUEBBE AACE 5.47 Channel 2 Post -run Report •22 Unused 18 S 0509510-002D 111A)_ IS 22.739 OC 3 1 OC 4 23 19 S 0509510-002DMS T r=2!9 49.019 JOS A 1 QC 6 Unused 24 20 S 0509510-002DDUP QC 8 22.688 2?17 Oy 1 • 25 2 QC1 ccv75 75.016 100 %• 1 26 0 OC1 ccb 0.005 2. 1 27 21 S 0509510-003D 1tw - 3' 22.728 1 28 22 S 0509510-004D 1(W - 3 5 22.327 1 29 23 S 0509510-005D fl - G J) 23.022 1 30 24 S 0509510-006D NW - 4 S 22.459 1 31 25 S 0509510-007D nib - S:)�> 23.737 1 32 26 S 0509510-008D H W-$ S 22.701 1 33 27 S 0509510-009D IhW - 6j7 22.321 1 34 28 S 0509510-OIOD MW CS 22.519 1 35 29 S 0509510-011D 111x1 " 9' 22.553 1 36 30 S 0509510-012D 8:5 22.487 1 37 2 QCl ccv75 75.013 100 /. 1 38 0 QC1 ccb -0.030 < 2- i% 1 39 31 S 0509510-013DF(gr1 80010 0.051 1 40 32 S 0509535-001E 238.712 10 .20 138- EC --OW -72- 01 19_C6_ 41 33 S 0509301-OO1F 2.623 1 tw -7462 - 040905- 124 - 001 42 34 S 0509301-002F 84.384 5 -007 43 35 S 0509301-002FMS; r- 125 211.602 jO2 % 5 44 36 S 0509301-002FDUP 79.760 Q ?17 6 X 5 45 37 S 0509301-003F 33.702 1 -003 •46 38 S 0509301-004F 33.289 1 -004 47 39 S 0509301-005F 32.057 1 -005- OOS48 48 40 S 0509331-002A 1533.853 50 49 2 QC1 ccv75 74.232 �� % 1 50 0 QC1 ccb -0.110 < Z, O 1 51 41 S 0509340-001A 29.173 1 52 42 S LFB-091905 T r-2 s 25.309 101 1 53 43 S LFBD-091905 25.715 V?D :i/• 1 54 2 QC1 ccv75 74.027 4f'q %• 1 55 0 QC1 ccb -0.052 < 2.. 0 1 56 1 D Drift 98.790 1 57 0 B FinalBase 0.022 1 OC Limits Channel 2 OC 1 Unused OC 2 Unused OC 3 Unused OC 4 Unused QC 5 Unused QC 6 Unused M QC 7 Unused r� QC 8 Unused M • 0 Cid BRAN+LUEBBE AACE 5.47 .QC 9 Unused QC10 Unused CORRECTIONS Channel Baseline Drift Carry over 8: ** <END OF REPORT> ** • • 2 Yes Yes Yes 1.9 Post -run Report BRhH+LUEBBE AWE 5.47 • Name of run :CL091905A.RUN Comment min Channel 2 Method Method 2 Unit mg/l Base 68 Gain 18 Corr. 1.0000 H2M LABS INC. Post -run chart Post -run chert Name of analysis :cl.ANL Page 1 of 3 r r r r r r r r r r r r r r r r 2 ---------------- J ------------------ L ----------------- ------------------' r r r r r r r r r r r r r r i r r r r r r r r r r r i r r 9 r r - - - -------- - - - - -------------------- r- - - - - - - - - - - - - - - r - - - --------------- - - - - -' r r r r r r r r r r i r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r i r r r r r r r r r r r r r r r r r r r r r r r r r r r i r r 8 ---------------------------------------------------- ------------------r ------- r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r r 10------------------ 4 ------------------ r------------------ 4 ------------------ I r r r r r r r r r r r r :OB 0.022 r r r r r r r 100.672 r r r r'1P 12 r r ----------' r 12D 98.790 r r r r r r :3H 98.969 r r r i 14L 0.305 r r i r 19-- -------------------------------------------------------------------� :5L 0.305 r r r r r i r '6C 100.079 r r r r i :7C 74.712 r r r Page 1 of 3 BRAWLUEBBE RACE 5.47 Name of run :CL091905A.RUN Comment Post -run chart Name of analysis :cl.ANL 22 --------------- ------- 17S 18.635 rrr;rr 18S 18.352 1 '19S 2.031 29 ------------------ ---------------- --------------------------------- ---- 20S 25.874 121S 28.395 22S 22.739 26 ----------------- ------------ ---- ' ------------------ j ------------------ ' ' 123S 49.019 rrr �8C 50.327 i r r r r r r ' :9C 19.925 r r r r 110C 9.859 r r r r 18 ----------------------------------- -------------- --- j------------------� �11C 0.076 r r r r r r r r r 112003 1.926 r r r r r r r i13QC150.218 r r r 20 ----------------+------------------'-------------------I------------------' r r r140C1D.130 r r r r r r r �15S 31.861 r r r i r r �16S 31.054 ' r r r r r i r r P 24 22.688 r r r r r :25QC175.016 28 --- ------------ r r r r260C1 0.005 r r r r r r r r :27S 22.728 r r r r r r r '28S 22.327 r i r 30 -------- ---------------------------------- - -----: r :29S 23.022 r r r r r r r 130S 22.459 r r r r r r r r r r r r r r31S 23.737 r i r 32 ----------------- ------------------ L ----------------- j ------------------ ' I i :32S 22.701 r r r r 133S 22.321 r i r r :34S 22.519 r r r r ' ' ' 135S 22.553 r r r r r r r r r r r Page 2 of 3 BPAN+LUnU RACE 5.47 Name of run :CL091905A.RUN Comment Post -nm chart Name of analysis :cl.ANL Page 3 of 3 r r r r r � ' 1370C175.013 36 ----------------� ------------------ ------------------ -- ----------------- :38QC1--0.030 r r r r r r r r r r r 139S 0.051 r r r r r r r r �40S 238.712 r r r 38 ----------------J------------------ -----------------------------------' 141S 2.623 r r r r r r r r r42S 84.384 r i r r r r r X435 211.602 90 ' r r r r r r44S 79.760 r r r r r r r :455 33.702 r r r r r r r r 146S 33.289 r r ----------------r �---- --------------------------- ---------42 r rrr rr 47S 32.057 i r r r r t :48SL533.853 r r r i r49QC174.232 r r r 500c1r0.110 r r r r r r r r r MS 29.173 r r r r i r :525 25.309 '---------------------------------r r 'S3S 25.715 r r r r r �540C174.027 r r r r r i r r r55QC1--0.052 :55M1-0. r r r r 8----------------- 48---- - - - - - - - - - - - -- - - -- r r r r56D 98.790 r i r r r r r r r i r r r r i r r r r r r r r r r r r r r r r 50 ---------------- J ------------------ ' ------------------ J ------------------' r 157B 0.022 r r i r r r i r r r r r r r r r r r r r r r r i r r r r i r r r 1 1 ------------------ ' r r r r r r r r r i r r r r i r r r r r r r r r r r r r r r r r r r r r Page 3 of 3 BRAN+LUEBBE AACE 5.47 H2M LABS INC. Calibration Curve Calibration Curve •Name of run :CL091905A.RUN Name of analysis :cl.ANL Comment . • Channel :2 Method :Method 2 Curve fit :quadratic a= -2.6546E+000 b=1.1215E-003 c=2.2996E-008 Corr. coeff. :1.0000 Peak [$] 100 80 60. 40 ............. 20 ............. 0- 0.00 10.00 20.00 30.00 40.00 50.00 60.00 70.00 80.00 90.00 100.00 110.00 Conc. [ mg/l ] Page 1 of 1 l 1 r [I N24 LABS, INC. T -.5 (-M5 COD Mai stAA Date: Start time: I mb �.! all =I . rim,. IM MW m1w, Ili . i� :: i�' i !. ►`. _�� u9n. �ommm� f12M LABS, INC. 10 nnabst • 410 ► T 1 Date: start time• 1x135 COD 9 Calibration 1/5/2005 cone abs 0 0 10 0.01 25 0.016 50 0.025 125 0.055 250 0.105 375 0.153 500 0.202 625 0.257 750 0.305 876 0.353 1000 0.404 Intercept (b) slope (m) r -10.742 2501 0.9999 COD Calibration 1/06/2006 1100- y = 00.7x -10.742 1000 900 800 700 600 • cone E 500 —Linear (cone) 0 400 v 300 200 100 0 -100 0.4 Z42 Absorbance OMN MOIS1 0 Page 0 • 10 0 -U2A "IPS"Oj* 3 1 INC.INCHARDNESS C6 ., DATE: ANALYST: HARDNESS = RAB x 100.0ooN TITRANT = 0, 0 Fl7t> A P 0065 OLOW ITI P LAW P 0065 Illvj4w I>K-,- L BRAN+LUEBBE RACE 5.47 i H2M LABS INC. Post -run report Name of Run nh3093005 Name of Analysis :NH3.ANL Date of Report : 9/30/05 System No. :1 Date of Run 9/30/05 Type of System :TRAACS Operator cp Start/Stop time :12:37 - 13:14 Comment :#14934 Base 78 tsl Gain -SL 003 Channel Type Real Data Channel 2 2 Method NH3 Dilution Unit mg/L mg/L Calibr. Fit Linear Corr. Coeff. 0.9998 Base 78 Gain 34 Sensitivity 0.2989 Sample Limit 1 . Sample Limit 2 . • Pk Cup Sample Id Value Value 0 0 B Baseline 0.013 0 1 1 P Primer 2.959 1 2 1 D Drift 3.010 1 3 1 H1 High 3.038 1 4 0 L1 Low 0.040 1 5 0 L1 Low 0.040 1 6 1 C Cal. 3.011 1 7 2 C Cal. 0.982 1 8 3 C Cal. 0.465 1 9 4 C Cal. 0.187 1 10 5 C Cal. 0.108 1 11 0 C Cal. 0.034 1 12 5 QC1 CRA 0.1 _ 0.071 1 13 9 QC4 LCS-14934 V = �'� 1.027 ) 1 14 10 QC10MB-14934 0.067 1� 0• 1 15 11 S 0509510-001B r(�j — Il,) 0.095 1 16 12 S 0509510-002B tiW — 1S 0.100 1 17 13 S 0509510-002BMS /1r5,0 5.551 (p CI % 10 18 14 S 0509510-002BDUP 1 0.114 QPD )tl"/. 1 19 15 S 0509510-003B KW — 3 0.108 1 20 16 S 0509510-004B mw -3S 0.067 1 21 17 S 0509510-005B KW — ji-t> 0.142 1 Post -run Report BRAN+LUEBBE AACE 5.47 •22 18 S 0509510-006B RW — k S 0.137 1 23 19 S 0509510-007B 14W -6J 0.091 1 24 20 S 0509510-008B f4 W - SS 0.415 1 25 2 QC4 CCV 1.0 0.943 9 y,, 1 26 0 QCl0CCB 0.041 < 0.1 1 27 21 S 0509510-009B k.W — `' 0.152 1 28 22 S 0509510-010B MW 6 S 0.226 1 29 23 S 0509510-011B t $� 0.143 1 30 24 S 0509510-012B 04 I - $s 0.102 1 31 25 S 0509510-013B SQj%j- gLk ��� 0.111 1 32 26 S 0509520-OOIA 0.355 10 33 27 S lfb-14934TCG.0 5.466 10CA 10 34 28 S lfbd-14934 5.280 9-tb 3;" 10 35 2 QC4 CCV 1.0 0.920 Z 'A 1 36 0 QC10CCB 0.037 1 37 1 D Drift 3.010 1 38 0 B FinalBase 0.013 1 OC Limits CORRECTIONS Channel 2 • Post -run Report Channel 2 QC 1 Cond. 1 Below Limit 1 0.080 • Cond. 2 Limit 2 Above 0.120 QC 2 Cond. 1 Below Limit 1 0.400 Cond. 2 Above Limit 2 0.600 QC 3 Cond. 1 Below Limit 1 2.000 Cond. 2 Above Limit 2 3.000 QC 4 Cond. 1 Below Limit 1 0.800 Cond. 2 Above Limit 2 1.200 QC 5 Unused QC 6 Unused QC 7 Unused QC 8 Unused 0C 9 Unused QC10 Unused CORRECTIONS Channel 2 • Post -run Report BRAN+LDEBBE AACE 5.47 •Baseline Yes Drift Yes Carry over Yes %: 2.9 ** <END OF REPORT> ** • • Post -run Report BRAN+LUEBBE AAM 5.47 2 of run :nh3093005.RUN Comment :#14934 H2M LABS INC. Post -run chart Post -run chart Name of analysis :NH3-ANL min Channel : 2 Method : NH3 Unit : mg/L Base 78 Gain 34 Corr. 0.9998 2 ---------------------------------- L ----------------- ------------------' 4 - ---------------4------------------ ------------------ +------------------� r r r r r r r ' ' 8 ---------------- : -- ---------- - - - - -------- � --- --------------------- - - - - - r � r r r r r r r r r r r 10 ---------------- a- ------------------------- ------- ---- a- - - - - - - - ----- - - - - -' r r r r :OB r r � r r r r ' r1P r' ------------------ :2D r r , r r r r r3H r ' r r r r �4L I r 19-- -------------- ------------------ ------------ --------------- r r r r r r r 15L r r r r r r r r 6C r r r r r r r r '7C r r Page 1 of 3 0.013 2.959 3.010 3.038 0.040 v7 0.040 3.011 M 0.982 BRATHLIB:BBE RACE 5.47 Name of run :nh3093005.RUN Comment :#14934 Post—run chart Name of analysis :NH3.ANL Page 2 of 3 ,8C 0.465 r r r i r r r r r r9C 0.187 r r r r ;10c 0.108 r r � 18 ----------------'------------------'-----------------j------------------; r r ' �11C 0.034 r r � ' ' r :12()C1 0.071 r r r r ' r r , , r r ' �13QC4 1.027 20 --- ------------4------------------ r ------------------------------------' r r r 14QC10D. 067 r r r r r r r r r r ' '15S 0.095 r r r r r i r r r r 116S 0.100 ------------------------------------------------ r r r �17S 5.551 r r � r r r r r r ' 118S 0.114 r r r r r r r r :19S 0.108 24 r ---------------------------------- r r L ------------------r r r ------------------r20S 0.067 r r r ' r i r r r r r r r MS 0.142 �22S 0.137 26 ---------------------------------- L ----------------- '------------------' i r r 123S 0.091 r r r r �24S 0.415 r r r r r r r250C4 0.943 r r r ' 260C10D.041 i r r r r r r 127S 0.152 r r r r �28S 0.226 30 ------- --- --------------- r --- - - - - - - -----------------------------------r r r r '29S 0.143 r r r r r r r r i30S 0.102 r r r r r i r 131S 0.111 r r r r 32 ------------------ J ------------------L-----------------1------------------' :32S 0.355 r r r r r r r r �33S 5.466 i r r r r r r r '34S 5.280 i r r r :35QC4 0.920 i r r r Page 2 of 3 BIINI+LunBE NICE 5.47 Name of run :nh3093005.RUN Comment :#14934 Post -ran art Name of analysis :NH3.ANL IN1 ' 1 ' I ',37D 3.010 i ' 1 --------------------------1 � � I ' 1 1 ' ` I 1 1 1 � � 1 ' 1 1 ' ' 1 1 � I 1 I 1 1 i 138B 0.013 38 -----------------J --------- L ----------------- J------------------' I 1 I I 1 ' -----------'t----- ------------- 1 l 1 i 1 1 ' i - - - - - - - - - - - - - - - - - 1 1 i ' ' 1 1 1 ' 1 ' ' ' 1 1 � 1 � I 1 i � 1 � I 1 ----------------- J_________ -________L ----------------- J------------------ 1 1 1 � 1 46 1 1 1 I _ _ _ _ t _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ i ------------------ 48 ___--__--__--_-__ 1 ' 1 I-----------------� 1 1 I 1 50------------------ J------------------ L ----------------- 1------------------` 1 I 1 1 52------------------------------------F------------------------------------� 1 1 I 1 Page 3 of 3 C J npjwtwLb1w piv.;b D.41 H2M LABS INC. Calibration Curve Name of run :nh3093005.RUN Comment :#14934 Name of analysis :NH3-ANL Channel :2 Method :NH3 Curve fit :linear a= -9.4907E-002 b=5.7535E-005 Corr. coeff. :0.9998 Peak [$] 100 80- 60 40- 20 0 0.00 0.50 1.00 1.50 2.00 2.50 3.00 3.50 Conc. [ mg/L ] Page 1 of 1 H2M «►[3S,INC. �s� °°� AMMONIA DISTILLATION NAME: 1.0 ► f DATE: lVo0- I(o'-')C) P 0067 CLIENT ID SAMPLE WEIGHT GRAMS SAMPLE VOLUME MLS FINAL VOLUME MLS DATE ANALYZED SPIKE LAB NO. 50 54 Mw - 1 S -off M4— 3 Cb M� -3S - ocSP 1Mw - yn 41vj - 5 -0mg �n�►-toD JA„J- (v S -o _011f, 'MW -2D —oa 6 Ov4 — 19 S --036 � nNk.1 05bl510. Oa QGDOG V_F6 �.b Lr6D 5.0 P 0067 • BRAN+LUEBBE AACE 5.47 Name of Run . no3092105 Date of Report : 9/21/05 Date of Run . 9/21/05 Operator Pit Comment pctsl KEY -PSS Channel Type Channel Method Unit Calibr. Fit Corr. Coeff. Base Gain Sensitivity Sample Limit 1 . Sample Limit 2 : • Pk Cup Sample Id • H2M LABS INC. Post -run report Name of Analysis :NO3.ANL System No. :1 Type of System :TRAACS Start/Stop time :15:34 - 16:27 56 40-90 --cS 1.00o Real Data 1 2 NO3 Dilution mg/1 mg/L Linear 2.001 1 0.9999 1 90 Drift 12 3 0.8167 H1 Value value 0 0 B Baseline 0.001 0 1 1 P Primer 2.001 1 2 1 D Drift 2.026 1 3 6 H1 High/no2 2.024 1 4 0 L1 Low 0.017 1 5 0 L1 Low 0.017 1 6 1 C Cal. 2.008 1 7 2 C Cal. 0.988 1 8 3 C Cal. 0.492 1 9 4 C Cal. 0.198 1 10 5 C Cal. 0.105 1 11 0 C Cal. 0.008 1 12 5 QC1 craO.1 0.098 1 13 10 QC1 lcsl.13 1.104 'JTA 1 14 0 QC1 mblk 0.008 G.D-� 1 15 11 S 0509642-001E JAW(u/— 06 0.019 1 16 12 S 0509642-002E t-VJ ti`s- 04 0.011 1 17 13 S 0509413-OOIA 0.018 1 18 14 S 0509413-002A 0.056 1 19 15 S 0509451-001A 0.417 1 20 16 S 0509454-001A 0.019 1 21 17 S 0509454-002A 1.192 1 Post -run Report QC Limits Channel BRAN+LUEBBE AACE 5.47 QC 1 Unused QC 2 •22 QC 3 18 S 0509456-001A 1.095 Unused 5 Unused 23 19 S 0509456-002A 0.632 1 24 20 S 0509475-OOIB 4.364 10 25 2 QC1 ccv1.0 1.004 {00% 1 26 0 QC1 ccb 0.008 Z0.1 1 27 21 S 0509510-001B%AvJ-%r) 2.673 5 28 22 S 0509510-002B TMw -1S 2.629 5 29 23 S 0509510-002BMS 5.032 �(o'� 5 30 24 S 0509510-002BDUP 2.650 (PD•9011A 5 31 25 S 0509510-003B jAVJ- 3n 3.269 5 32 26 S 0509510-004B ,^W -3S 3.310 5 33 27 S 0509510-005B jr^w--1a 3.154 5 34 28 S 0509510-006B ,rnvJ- y S 3.413 5 35 29 S 0509510-007B MVJ- S() 2.695 5 36 30 S 0509510-008B p*J-5 S 2.699 5 37 2 QCl ccvl .0 1.005 �o �`/. 1 38 0 QC1 ccb 0.007 ZO.1 1 39 31 S 0509510-009Bvl\r►-(or> 2.793 5 40 32 S 0509510-OIOB V^VJ-6 S' 2.698 5 41 33 S 0509510-011B eVvJ' 4� 3.125 5 42 34 S 0509510-012B 4qy-*- �S 2.853 5 43 35 S 0509510-013BEQPf.F'k0►)K 0.050 1 44 36 S 0509520-001A 6.343 10 45 37 S 0509525-OO1A 0.027 1 •46 38 S 0509525-002A 0.505 1 47 39 S 0509570-OO1A 0.024 1 48 40 S 0509570-002A 2.190 5 49 2 QC1 ccvl.0 0.994 9(i/, 1 50 0 QC1 ccb 0.005 40.1 1 51 41 S 0509662-001A 0.063 1 52 42 S 0509662-002A 0.113 1 53 43 S LFB-092105 '� 0.55 0.472 14 % 1 54 44 S LFBD-092105 0.481 ilQr)% 1-i 4 1 55 2 QCl ccvl.0 0.988 'jq A i 56 0 QCl ccb 0.002 e- O A 1 57 1 D Drift 2.026 1 58 0 B FinalBase 0.001 1 QC Limits Channel 1 QC 1 Unused QC 2 Unused QC 3 Unused QC 4 Unused QC 5 Unused QC 6 Unused • QC 7 Unused Post -run Report BRAN+LUEBBE RACE 5.47 •QC 8 Unused QC 9 Unused QC10 Unused CORRECTIONS Channel 1 Baseline Yes Drift Yes Carry over Yes %: 1.8 ** <END OF REPORT> ** • • Post -run Report BRAN+LUEBBE AACE 5.47 H2M LABS INC. Calibration Curve Calibration Curve * ame of run :no3092105.RUN Name of analysis :NO3-ANL Comment Page 1 of 1 BRAN+LMBBL AAM 5.47 9 of run :no3092105.RUN Comment Bun Channel : 1 Method : 903 unit : mg/1 Base 90 Gain 12 Corr. 0.9999 H21VI LABS INC. Post -run chart Post -run chart Name of analysis :NO3.ANL Page 1 of 4 r r r r 2 ------------------ J ------------------ L ----------------- i ------------------ r r r r r r r r 4 --------- --- ---- -r- - - ---- ----- --------------- r -- - - - ------- - - - - - - r r r r r r r ------------------r ------------------ r , e ---------------- '------------------'----------- -------'------------------' ------ - - - - -� , r r r r 12 -------------� --------------i r ' SOB 0.001 r , , 14 ------------------'------------- - - - - --------------- , , -------------------' r - r1P 2.001 r :2D 2.026 � r r r , r r3H 2.024 , Page 1 of 4 BRAN+LUEBBE AACE 5.47 Name of run :no3092105.RUN Comment Post -run chart Name of analysis :NO3.ANL ,51, 0.017 r r I :20S 0.019 , , r ',21S 1.1921 28 --------- -------- ------------------ r -----------------I ------------------ r22S I 6C 2.008 ' , r 18 ------- ---------- �------------ -----L ----------------- j------------------ 7C 0.988 , , r '23S Sc 0.492 I ' '9C 0.196 I I '24S 4.364 r I r I 20 ----------------------------------------------------+------------------'lOC 0.105 r I r I 30 r I I r r r 111C 0.008 r I I r '26QC1 0.008 :120C1 0.098 22 I r ------------------------------- ---- r ----------------- I ------------------ 113QC11.104 I I 127S 2.673 :14QC1 0.008 ' 115S 0.019 r I r 32 ---------------- - ------------------ L ----------------- ------------------ ' ,285 2.629 24 ---------------------- ----------------------------� ------ i- 1165 0.011 , I r '29S 5.032 :17S 0.018 I Iles 0.056 26 ----'------------------L------------------'------------------' 19S 0.417 r I :20S 0.019 , , r ',21S 1.1921 28 --------- -------- ------------------ r -----------------I ------------------ r22S 1.095 '23S 0.632 I I '24S 4.364 r I r I 30 --------------------------- , --------------------------------------� - , - - 1 , 25QC1 1.004 '26QC1 0.008 I I 127S 2.673 r r I r 32 ---------------- - ------------------ L ----------------- ------------------ ' ,285 2.629 , I r '29S 5.032 ' �30S 2.650 , I r ----------------- -- ---------------r------------------ ------------------1315 3.269 :32S 3.310 Page 2 of 4 BRAN+LUEBBE DACE 5.47 Name of run :no3092105.RUN Comment Port -run chart Name of analysis :NO3.ANL '33S 3.154 r r r r 36 - - --------- - - - --- ------------- - - - - ------------ - - - - -- 2------------------�39S 3.413 , r r r r r r �35S 2.695 r r36S 2.699 , , r 38 - --------------------------------------------------- � � r - - - 37QC1 1.005 r , r r r r r ' r 1380C1 0.007 39S 2.793 40 - - - - - - - - - - - - - - - - -�----- - - - - -�- - - - - - r 7 --------------- - ------------------ ----------------- -------------------46S 0.505 147S 0.024 r , , r r r r r ,48S 2.190 46 - --- -a- --- - - - - -- , r r ------------- -------r-----------------y-------------------49QC1 0.994 , r r r50QC1 0.005 �51S 0.063 48' ' ' -- - ------------- -------------------�----------------- ------------- - - - - - r 525 0.113 �53S 0.472 154S 0.481 r , r 50 - - - - - - - - - - - - - - - ------ - - - - --------- L - - - - - - - - - - - - - - - ------------- - - - - -- - ' r , r,SSQC1 0.988 r r �40S 2.698 :560C1 0.002 :41S 3.125 , r , , r :57D 2.026 , :42S 2.853' 42 r -------------- r--------------� ------ r r --- ------ r ----------------- r r ---- - - - - -� ,43S 0.050 � r r �44S 6.343 r ,58B 0.001 ' r 0.027 r , r :45S r 7 --------------- - ------------------ ----------------- -------------------46S 0.505 147S 0.024 r , , r r r r r ,48S 2.190 46 - --- -a- --- - - - - -- , r r ------------- -------r-----------------y-------------------49QC1 0.994 , r r r50QC1 0.005 �51S 0.063 48' ' ' -- - ------------- -------------------�----------------- ------------- - - - - - r 525 0.113 �53S 0.472 154S 0.481 r , r 50 - - - - - - - - - - - - - - - ------ - - - - --------- L - - - - - - - - - - - - - - - ------------- - - - - -- - ' r , r,SSQC1 0.988 Page 3 of 4 r , r :560C1 0.002 r , r :57D 2.026 , , 52 - - - - - - - - - - - - - - - - -- , r r � r ,58B 0.001 Page 3 of 4 a w lD Js O M Al 0% 0% O\ 01 m N 111 O W 01 Js N O 0) (YA 1 1 1 I 1 1 I 1 I 1 I I 1 1 1 1 1 1 1 I 1 I 1 1 1 I 1 1 I I I 1 I 1 1 I I 1 I I 1 1 I 1 1 1 I I I I I I 1 I I I - - - J - - - - - - - - - - L - - - - - - - - - -'- - - - - - - - - - J t - - - - - - - - - - L - - - - - - - - - -'- - - - - - - - - - J - - - - - - - - - - 1 - - - - - - - - - - L - - - - - - - - - J ' I t I I 1 1 1 I 1 I I I I 1 I I I I I 1 I I I 1 1 I I I I I 1 1 I 1 I I I I 1 I I I I I I 1 I 1 I I I I t I I I I I I I I I 1 I I I I I 1 I I I 1 I I 1 I I 1 1 I 1 1 I I I I I I 1 I 1 1 1 1 I I I I 1 1 1 I I I 1 1 I I 1 1 1 I I 1 1 I I I I I I 1 I I I 1 1 1 I I I I I 1 I ---1----------r----------I----------1----------r----------r--------------------r----------f---------1 I 1 1 I I I 1 I I I I I I I 1 I 1 I I 1 1 I 1 1 1 I I I 1 I 1 I I I I I I 1 1 I 1 1 1 1 I I I 1 I I 1 1 I 1 I I I 1 1 I I I I 1 I I 1 1 I 1 1 1 I I I I I 1 I 1 1 1 1 1 1 I I I I I 1 1 I 1 1 I I I I I I 1 I I 1 I 1 I I I I I 1 1 1 I I I I I 1 I I I 1 I 1 I 1 I - - - J - - - - - - - - - - L - - - - - - - - - -'- - - - - - - - - - J - - - - - - - - - - L - - - - - - - - - - L - - - - - - - - - J - - -I - - - - - L - - - - L - - - J - - - - - - - - - - - - - - I I I 1 1 I 1 1 I I I I I 1 I I I 1 I I I I I I 1 I 1 I I I I I I I 1 1 I I 1 I I 1 1 I I 1 I I 1 I I 1 I 1 1 1 1 1 I I I I 1 I 1 1 1 I I I I 1 1 I I I I I I I 1 I 1 1 I 1 I I 1 I 1 I I I I I I I I 1 I I I I I I I i I I I I I I I I I 1 I 1 I 1 1 1 1 I I I I I I 1 I 1 I I 1 I I I I I 1 I I I 1 I I I I I I I 1 I 1 I I I I I I 1 I I I I ---------------------------------------------------------------------------------------------- - - - - -- TSL003 W57 0 z N rt° 1 I 9 PNMNW.... .... .�. ...�. r..r aeeee ..�rrr eerier sear rer recce 1 "7t Ocilsj�` 1d2A4 LABS, INC. Phenols Method 420.1 Distillation Date: oS Time: -!P- •o Pc rsl0-oo3 Analyst: /�jv01� Date: ff Jr CLIENT ID# H21VILABS mL SAMPLE GRAMS ABS UG/L DILUTION UG/L MG/KG %TS NOTES/CALCULATIONS DISTILLED USED !CV 30 UG/L o.. ! ICB NONE 0.000 ,��{', o AIX.* 5 UG/L STD NONE 0.010 Y- ' PREP BLANK 50 0. oao tS: o ,t •10 1 M* ../ 04000L S. O 'A 2 1 SO• dot 00 O t 3 0. I .8 , •8 4 0• o sS. .�S.O = /V S -10M 00 0 <ID 6 JAW I.S. dp . 0 S to -0-000 'es, .t ±E2,1046,O000 8 • r AS oCCV 30 UG/L50 0.067, •3 CCB NONE 1 ofo1po. 00 .M 0. o 0 3 -*x. 0 e, 0 2 • S S- 00r 0-400 .tS.o t.r.0 3 0.0,0 tS.a XS -0 4 o.ogv tS.0 ,c s,0 5 0.000 l r.0 tl• O d 0.001 tS.O tl. 7 Q S 0.000 tJ.O �J'•O 8. DUP aPK UG/L CCV 0 UG/L bo CCB NONE Pnene P 0.0640 Calibration 1.24-05 cone abs 0 0.000 5 0.01 10 0.022 20 0.048 30 0.072 40 0.099 501 0.122 Intercept (b) 0.6708 slope (m) 402.96 r 0.9997 Phenol Calibration 1/24/05 60 50 t02.96x + 0.6708 40 ,�. ♦ cone 30 - - ---Linear (cone) l r v 20 10— ---- 0 4 /00or 0.000 0.050 0.100 0.150 Absorbance 69M £00'IS1 0 Page e 0 i 1 r r 1 SULFATE KFy -lsS , 086 003 . DATE:pyr ANALYST: �j/; ; ByCKAIi CLIENT ID LAB# MLS USED ABS. MG/L (GRAPH) MG(L NOTES ICV (20.0 mg&) .. eco 19.0 9S , ICB LSA�'. 0 �+ oSp9 1 9-0 r iA 0 motjn( - oo/ o 2S o•v( 0.95 0 o • o f+•6 x too_ If. 1; noa= 3060 1090 - ` 9#D= t r � 12 V- 14 _M-001F,s. o 6-2t f 'o• i xs, 103.s CCV(20.0 mg/L) r� • O ?SI CCB -Io 91�j -00 ,/• oS0 6.2 ey ki,C -�I fJ Slo• oo '4• XYZ /3 J4� C�CpV(20.o mg&) 'f.D (► r �J CCB _ P41A v9.n8 - o st IS, /0-1 tG• 3 I 17. 9110 -mc j V. /0 0 IO. 5 -3$ STo•O�Y� . to I II -0 -YiO O'cro D• I lf II • S- -Ys slo .-0o6 0. /o 11-0 ocv(20.0 mg/L) CCB �s p. � /9.0 ,c S. C) qS so S10- 0+ 0. !3.0slo-o•to o.o� ACCV(20.0mgAL) �i o. to)- I0.S0-rlo JS 9s " /4 1 P 0070 SULFATE Q� Pe DATE: 9-,to-o� csk ks� -o70 ANALYST: lS; &PXH P i a V LAB# MLS USFA ABS =CLEWE (GH) MG/L NOTES ICV (20.0 mg/L) ICB 2- o4v5sto-otj s►o-VIS 44re 9s o. o o .tye-o oA IL 0 0.l o Y.rxJS� .. 60.3 r�►-.gAffAlY I. o 0.28 Y! -oe1 A !s p.,�jtp �Y.1 ccv(zoo mg/L) S� p , 19.0 9.� CCB �.� ° • ° o o .�S p 9 c'is.ik1� So YPi- oo S• d o • A 61 3.Y S•� j r IT r"" s.o - oot Y ivy 30 for -opt �S 0.0)72 g• p CCV(20.0 mg/L) a S z. CCB .e do Ccv(2o.o mg/L) CCB CCV(20.0 CCB 0 Calibration 08/2.2105 conc abs 0 0.000 5 0.032 10 0.09 15 0.142 20 0.207 25 0.271 30 0.338 35 0.417 40 0.480 Intercept (b) 2.3181 slope (m) 80.48 corr. Coeff. 0.9964 TSL003 W62 SO4 08/22/05 y=80.494x+2.3181 40- 30 E 20 ♦ conc c —Linear (conc) 0 V 10 0 0.000 0.100 0.200 0.300 0.400 0.500 0.600 Absorbance Page 1 of 1 ((Dried Wt.(o) - Tare Wt. (allx10001x1000 Sollds(mg/1)2 mL Sample ANALYST. - DATE: itt4 START- Ch-5�U OLIDS DS/SS/TS TEMP. a C-1 n ' 'c-, WI iuin TV- t Otn - �� �1 _ ----> % I 00FTs1._ . I� C�> rm u LAB # CLIENT ID PAN/ CRUC. SAMPLE ML DRIED WT G TARE WEIGHT G dLID WEIGHT G RESULT MG/L DRIED WT G IGNITED WT G VOL. WT G COND. kOa p ,�3CO �0 &jg5W '13LD 1(R 101 0111-P-5 .000(v O L 10 311 0-501�311 S D 0 brc�3� }-UJ f 0 4TI (� 05 GvA 5P i d0 lc ,C�l�ib � MIA t CC) c 9 �o`�to ��(s C`1�pQ5 t � on3� �Cv 69 4 C)© z k-1-0 \7 �C ICo 100 105 �05� � �. 4-L- 15 +9- r--�- 15; COD tv e3• 0.0 0�1 iC``1 ���� oo tcn C00D 10`1 -ot LF ,...�. . "MWAIW 160ond u a VgAk 0ogs1L---- SOLIDS (rDded Wc.(o) - Tare Wt. (c)VIDOON1000 L..J`• / SS/ TS Sollds(mgA)= mL Sample ANALYST: MP. DATE: L7o START- HUMIDITY: LAB # CLIENT ID PAN/ CRUC. SAMPLE ML DRIED WT G TARE WEIGHT G SOLID WEIGHT G RESULT MG/L DRIED WT G IGNITED WT G VOL. WT G COND. f�-34C� 1 I- oO> t . 00(p < cb2D L 105.is5) aolLUq t (0 0o cQu 15& ,547 r 10 1019 01 Qc) ri 4y ao a ;11P I l� CX) 0'3-&51(105 LgbLH o r (Di:> q �a CA M-ru I C-kP,Ak-) )W qLP 6,01q( 4ci i rn-3 Q& - � a i , .a n o �-' o OCE � (9 `7 Po to AC5 Vf5 iEr7S .0�9 7 t77 �� (moi �� C1q ,3� o� t (°�• 3 o•c i-� 4 l3 fO --5q #=mod fimmol immd u 6—J OLIDS Wrled Mal • Tam wt, cos x OOM1000 TDS i SS/ TS Solids(mgA)= mL Sample ANALYST: DATE: A holc< STARTt � HUMIDITY: DRIED TARE t _ Concentration listed after Optical Blank: Correction. L7 5L TKN Data Preparation dilation factor not applied to results. ` 3 aSample -1 -ID SampTy Cone Units DF Cone x DF AnalDate AnnMme TestCod I Primer PRIM 3.01E mg4 I 3.018 9!24/05 07:58:50 PM dM -w 2 Drift DR1F 3.015 mg/1 I 3.015 9/24/05 07:59.31 PM dM -w 3 High HIGH 3.027 m94 1 3.027 924/05 08.00:10 PM dM -w 4 Low LOW 0.007 mg4 1 0.007 924/05 08:00:50 PM dm w 5 Low LOW 0.007 mg/I 1 0.007 9/24/05 08:0131 PM dm w 6 Cal. CAM 3.01E me 1 3.01E 924/05 08:02:11 PM dM -w 7 Cal. CAM 0.956 mg/I 1 0.956 924/05 08:02:51 PM dM -w 8 Cal. CALB 0.474 mg/I 1 0.474 924/05 08.0331 PM dM -w 9 Cal. CAM 0.19 mg/1 1 0.19 924/05 08..04:12 PM dM -w 10 Cal. CALB 0.111 mgA 1 F---o.11-119124M 08:04:52 PM dM -w I I Cal. CALB 0.004 mgA 1 0.004 924/05 08:0532 PM ft -W 12 optical bink QUAL 0.801 mg/I 1 F---o-w-119/24/05 08:06:11 PM dM -w 13 Ics-14877 ICS 0.3958 me -AV -4-1 10 3.958 924/05 J7 1. 08.06:51 PM dm -w 14 mb-14877 mbik -0.005 mg4 IF ------O.0015 924/05 08:07:31 PM dm w �5 0508948-0OIA SAM/ 03024 mg/I 20 6.048 924/05 08:08:11 PM dM -w 16 0508948-002A SAMP 1.4456 mg/1 20E---2-8.9121 924/05 08:08:51 PM dM -w 17 0509413-OOIA SAM/ 1.4129 mgA 10 14.129 924/05 08.09:31 PM dM -w 18 0509413-002A SAMP 2.4464 mg/I 10 24.464 924/05 08:10:11 PM dM -w 19 0509421-OOIA SAMP 03973 mg4 20 7.94619/24/05 08:10:50 PM dM -w 20 0509421-002A SAMP 1.46515 mg/1 20E---29303 924/05 08:11:31 PM dM -w 21 0509426-OOIA SAM/ 0.2273 mg/1 50 11.365 9/24/05 08:12:11 PM dM -w 22 0509451-OOIA SAMP 0.67735 m&4 20 13347 924/05 08:12:51 PM dm w 23 0509454-OOIA SAM/ 09136 mg/1 10 9.136 924/05 08:1331 PM dm w 24 0509454-002A SAMP 0.74 mgA 10 7.4 924/05 08:14:11 PM dM -w 25 ccvLO CCv 0.962 mg4 I 0.962 924/05 °j6r % 08:14:51 PM dm -w 26 ccb ceb 0.015 mg4 1 F o -.o 1-51 924/05 tG • ( 08:1531 PM tlm w 27 0509475-001 B SAMP 1.229E mgA 10 1229E 924/05 08:16:11 PM dm w 28 0509510-001 B M%iJ - 1 SAM/ 0.048 mg/I I 0.04E 924/05 08:16:51 PM dm w 29 0509510-002BifVlvJ- S SAM/ 0.005 mg/I 1 0.005 924/05 08:17:30 PM dM -w 30 0509510-002BMS �J ms 0.3964 mgA '(\(_A.,10 3.964 924/05 `;% /� 08:18:11 PM dm OOS 8:59:42 PM Page 1 of 3 Peak SampleM SampTy Conc Unib DF Conc z DF AnalDate AnalTime TestCod 0509510-OMDUP MW-► 5 dup 0.016 m94 1 0.016 924/05 0 G08:19:51 PM 611 32 0509510-003B - 3T) SAW -0.0070 m94 1-0.00700000 924/05 08:19:31 PM dm -w 33 0509510 -MB - 5 SAMP -0.047 mg4 l -0.047 924/05 0820.11 PM dm -w 34 0509510 -MB _ 4t) SAW 0.0107 mall 10 0.107 924105 fglw\ 0820:52 PM ft -W y> -At -1 C& . 35 0509510.0068 -44) SAW 0.0125 mgAIO 0.125 92405 0821:30 PM dm w 36 0509510-007B SAW 0.042 mg4 10 0.42 92405 0822:12 PM dm -w 37 ccvl.0 ccv 0.966 mgA 1 � 0.96 924105 17% 0822:51 PM ft -w 38 ccb ccb 0.019 mg4 1 0.01 924A15 Z OA 082330 PM dm -w 39 0509510 -MB MW- 5S SAMP 0.0113 man 10 0.113 92405 ft 08:24:10PM da w Vrder ['l- 40 05095104X09B - (p t> SAW 0.0152 m94 10 0.152 92405 0824:52 PM tlmt w 41 0509510-01 OB - (t S SAW 0.0155 mall 10 0.155 924105 0925:24 PM dm -w 42 0509510-011B Sp SAMP 0.0174 mall 10 0.174 92405 0826.02 PM dm w 43 0509510-0128 SAMP 0.0185 m&4 10 0.185 924105 0826:52 PM drnw 44 0509510-013B EM Ij AWX 916 SADA -0.041 mgA 1 -0.041 924105 08:2731 PM dm w 45 0509525-OOIA SAW 0.4148 mg/l 10 4.148 92405 0828:10 PM dm -w 46 0509525-002A SAMP 0.8375 mgA 20 16.75 912405 0828:51 PM dm -w •7 0509570-OOIA SAMP 02999 mg4 20 5.998 924/05 0829:31 PM dm -w 48 0509570-002A SAMP 0.97715 mgA 20F--719.543 924/05 0830:11 PM dm w 49 ccv 1.0 ccv 0.974 mg/I I 0.974 924/05 17 %. 0830:51 PM dm -w 50 ccb ccb 0.03 mgA 1 0.03 92405 40.1 083130 PM dmw 51 0509662-OOIA SAM? 0.6521 m&4 10 6.521 92405 0832:10 PM dw w 52 0509662-002A SAMP 2.0566 mgA 101 924105 0832:51 PM dm -w 53 0509676-OOIA SAMP 1.334 maA 1 1334 92405 0833:31 PM dm -w 54 050%764)02A SAW 0.5032 m84 20E---10.0641 92405 0834:09 PM dm -w 55 0509716-OOIA SAW 0.4793 mg4 101 4.793 92405 0834:51 PM dm -w 56 0509716-002A SAMP 0.9902 mall 20E---19.3014 42405 0835:31 PM dm -w 57 LFB-14877 Ilb 0.4143 mgA 'V=*110 4.143 92405 %01;t. 0836:09 PM ft -W 58 LFBD-14877 Ilbd 0.4135 mgA 10 4.135 92405 Fn= 0:V 0836:52 PM tkn w 59 0509510-005b t%, J -'it) SAW -0.015 mg4 1 -0.015 924/05 0837:31 PM tim w 60 0509510-006b lv\W - -i S SAMP 0.032 m&4 1 0.032 92405 0838:10 PM tknw 61 ccvl.0 ccv 0.978 mg4 I 0.97a 92405 jb/ 0838:51 PM tim w 005 8:5439 PM Page 2 of 3 Peak SampleID SampTy Conc Units DF Conc z DF AnalDate AnaMme TestCod ccb ceb 0.037 mg/1 1 0.037 924/05 eD. 0839:30 PM dm -w 63 0509510-007b %v%VJ — S 7 SAW 0.339 mg/I I 0.339 924/05 08:40:11 PM dm -w 64 0509510-0086 — 5S SAMP -0.026 mg4 1 -0.026 924/05 08:40:51 PM dm -w 65 0509510-009b SAW 0.02 mg4 1 0.02 924/05 08:4131 PM dmw 66 0509510-010b (p S SAMP 0.032 mg/I I 0.032 MOW 08:42:11 PM dm w 67 0509510-01 Ib — i SAW 0.05 mg/1 1 0.05 924/05 08:42:50 PM dm–w 68 0509510-012b _ gS SAW 0.044 mg4 1 0.044 9241'05 08:4331 PM dm–w 69 ecv1.0 MY 0.979 mgn 1 0.979 924M5 it/. 08:44:10 PM dmw 70 ccb ccb 0.046 mg4 1 0.046 924/05 40 • 08:44:50 PM dmw 71 Drift DRIF 3.015 mg/1 I 3.015 924/05 08.4531 PM dmw 72 End END 0.048 mg4 1 —0.04819/24/05 08:46:49 PM dm–w C 8:5439 PM Page 3 of 3 00 M O O H • BRAN+LUEBBE AACS 5.47 H2M LABS INC. Post -run report Name of Run tkn092405a Name of Analysis :tkn.ANL Date of Report 9/24/05 System No. :1 Date of Run 9/24/05 Type of System :TRAACS Operator : pw Start/Stop time :19:47 - 20:47 Comment 914877 Channel Type Real Data Channel 2 2 Method tkn Dilution Unit mg/l Calibr. Fit Linear Corr. Coeff. 0.9996 Base 81 Gain 26 Sensitivity 0.3978 Sample Limit 1 . Sample Limit 2 : • Pk Cup Sample Id value Value 0 0 B Baseline 0.048 0 1 1 P Primer 3.018 1 2 1 D Drift 3.015 1 3 1 H1 High 3.027 1 4 0 L1 Low 0.007 1 5 0 L1 Low 0.007 1 6 1 C Cal. 3.018 1 7 2 C Cal. 0.956 1 8 3 C Cal. 0.474 1 9 4 C Cal. 0.190 1 10 5 C Cal. 0.111 1 11 0 C Cal. 0.004 1 12 8 QC1 optical bink 0.801 1 13 9 QC1 lcs 4.1 4.759 10 14 10 QC1 mblk 0.796 1 15 11 S 0508948-OOIA 6.849 20 16 12 S 0508948-002A 29.713 20 17 13 S 0509413-001A 14.930 10 18 14 S 0509413-002A 25.265 10 19 15 S 0509421-001A 8.747 20 20 16 S 0509421-002A 30.104 20 21 17 S 0509426-OOIA 12.166 50 Post -run Report CN M C/1 Post -run Report RACE 5.47 •BRAN+LOEBBE 22 18 S 0509451-001A 14.348 20 23 19 S 0509454-OOIA 9.937 10 24 20 S 0509454-002A 8.201 10 25 2 QC1 ccvl.0 0.962 1 26 0 QC1 ccb 0.015 1 27 21 S 0509475-001B 13.099 10 28 22 S 0509510-OOIE 0.849 1 29 23 S 0509510-002B 0.806 1 30 24 S 0509510-002BMS 4.765 10 31 25 S 0509510-002BDUP 0.817 1 32 26 S 0509510-003B 0.794 1 33 27 S 0509510-004B 0.754 1 34 28 S 0509510-OOSB 0.908 10 35 29 S 0509510-006B 0.926 30 36 30 S 0509510-007B 1.221 10 37 2 QC1 ccvl.0 0.966 1 38 0 QC1 ccb 0.019 1 39 31 S 0509510-008B 0.914 10 40 32 S 0509510-009B 0.953 10 41 33 S 0509510-010B 0.956 10 42 34 S 0509510-011B 0.975 10 43 35 S 0509510-012B 0.986 10 44 36 S 0509510-013B 0.760 1 37 S 0509525-001A 4.949 10 •45 96 38 S 0509525-002A 17.551 20 47 39 S 0509570-001A 6.799 20 48 40 S 0509570-002A 20.344 20 49 2 QC1 ccvl.0 0.974 1 50 0 QC1 ccb 0.030 1 51 41 S 0509662-001A 7.322 10 52 42 S 0509662-002A 21.367 10 53 43 S 0509676-001A 2.135 1 54 44 S 0509676-002A 10.865 20 55 45 S 0509716-001A 5.594 10 56 46 S 0509716-002A 20.605 20 57 47 S LFB-14877 4.944 10 58 48 S LFBD-14877 4.936 10 59 49 S 0509510-005b 0.786 1 60 50 S 0509510-006b 0.833 1 61 2 QC1 Quality Cup 0.978 1 62 0 QC1 Quality Cup 0.037 1 63 51 S 0509510-007b 1.140 1 64 52 S 0509510-008b 0.775 1 65 53 S 0509510-009b 0.821 1 66 54 S 0509510-010b 0.833 1 67 55 S 0509510-011b 0.851 1 68 56 S 0509510-012b 0.845 1 2 QC1 ccv1.0 0.979 1 •69 70 0 QC1 ccb 0.046 1 Post -run Report BRAN+LUEBBE AACE 5.47 • 71 1 D Drift 72 0 B FinalBase QC Limits Channel QC I Unused QC 2 Unused QC 3 Unused QC 4 Unused QC 5 Unused QC 6 Unused QC 7 Unused 0C 8 Unused 0C 9 Unused QC10 Unused CORRECTIONS 3.015 1 0.048 1 2 •• <END OF REPORT> " • Post -run Report Channel 2 Baseline Yes Drift Yes •Carry over Yes %: 0.8 •• <END OF REPORT> " • Post -run Report BRAN+LUEBBE AACE 5.47 0-ame of run :tkn092405a.RUN Comment is 11 H2M LABS INC. Calibration Curve Calibration Curve Name of analysis :tkn.ANL Channel :2 Method :tkn Curve fit :linear a= -2.0853E-001 b=5.6979E-005 Corr. coeff. :0.9996 Peak [$) 100 1 1 1 1 i I 1 1 I 1 1 1 80 ---L----------'----------1---------- "---------------------------- I 1 1 1 1 1 1 1 1 1 1 I 1 1 I 1 1 I 1 1 1 1 I 1 1 1 1 I 1 60 -------- ----------- --'- --------- +---- ------ - - - - -- --------------4----------- I 1 1 1 i I 1 1 1 1 1 1 1 40 4 - - - - - - - -- --------------------*---------- 1 1 I 1 t 1 t 1 1 1 1 1 1 I 1 I 1 1 1 1 1 1 1 1 1 20 1 ----------r----- ----I----------Y----------r----------1----------r---------- I t 1 t 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 i I 1 1 1 1 1 1 1 1 1 1 1 1 0 0 0.00 0.50 1.00 1.50 2.00 2.50 3.00 3.50 Conc. [ mg/l ] Page 1 of 1 BRAN+LULBBE AACL 5.47 H2M LABS INC. Post -run chart Name of run :tkn092405a.RUN Comment Post -run chart Name of analysis :tkn.ANL min Channel : 2 Method : tkn Unit : mq/l Base 81 Gain 26 Corr. 0.9996 2 ----------------------------------- L----------------- ------------------� 4 ---- -------------4-------- --- ------------------ ------------------' --- B---- ------------------------------'--------------------'------------------' 10 ----------------4------------------------------------+------------------� :OB 0.048 '1P 3.018 i ------------------------, i '2D 3.015 i3H 3.027 '4L 0.007 14 --------------------------------------------- ------------------' i i5L 0.007 :6C 3.018 i 1� 7C 0.956 Page 1 of 4 BRAN+LDLBBL 1NCE 5.47 Name of run :tkn092405a.RUN Comment Post -r= chart Name of analysis :tkn.ANL Page 2 of 4 BM+LUEBBE JUICE 5.47 Name of run :tkn092405a.RUN Comment Post -run chert Name of analysis :tkn.ANL ' r r i X475 6.799 r r , { r 148S 20.344 , r i r r 1490C1 0.9741 ----------- ----------------- L ----------------- J ------------------ 1 :500C1 0.030! r i 'SIS 7.322' r � ' r r r r52S 21.367' 46 - - - - - - - - - - - - - - - -- --- ----------- - - - - - - -r - - - - - - - - - - - -- - - - - - r , r r ' X535 2.135 r , r r X545 10.865 r r r r �55S 5.594 r -- - - - - -- - - - - - - - - - - - - - - - - - r i :56S 20.605 � r r �57S 4.944 r r � r r r r r r r r r ' 158S 4.936 50 - - - - - --------------------------- L - ---------- - - - - --------------- - - - - -' r r 1595 0.786 r r r ' 160S 0.833 , r r r i r r i610C1 0.978 52 - - - - - -- - - -------------------------------------+------------- - - - - -� r i r r 620C1 0.037 �63S 1.140 , r r r r r r Page 3 of 4 , r 136S 1.221 , , r r ' :370C1 0.966 36 ,------------------- -----------------, i380C1 0.019 r � r ' X395 0.914 , , r r r r '40S 0.953 38 ---------------- J ------------------ L- ----------------- ------------------' 141S 0.956 i r ' :42S 0.975 , � r 43S 0.986 ------------- -- _ - - -y- - - ---- - ----- - - - - -, , , r r ' '445 0.760 r � r r ' r45S 4.949 , , r '465 17.551 -- - - -- -------- ---------- r r i X475 6.799 r r , { r 148S 20.344 , r i r r 1490C1 0.9741 ----------- ----------------- L ----------------- J ------------------ 1 :500C1 0.030! r i 'SIS 7.322' r � ' r r r r52S 21.367' 46 - - - - - - - - - - - - - - - -- --- ----------- - - - - - - -r - - - - - - - - - - - -- - - - - - r , r r ' X535 2.135 r , r r X545 10.865 r r r r �55S 5.594 r -- - - - - -- - - - - - - - - - - - - - - - - - r i :56S 20.605 � r r �57S 4.944 r r � r r r r r r r r r ' 158S 4.936 50 - - - - - --------------------------- L - ---------- - - - - --------------- - - - - -' r r 1595 0.786 r r r ' 160S 0.833 , r r r i r r i610C1 0.978 52 - - - - - -- - - -------------------------------------+------------- - - - - -� r i r r 620C1 0.037 �63S 1.140 , r r r r r r Page 3 of 4 BPM+LUEBBE AACE 5.47 Name of run :tkn092405a.RUN Comment Post -nm chart Name of analysis :tkn.ANL Page 4 of 4 -- - - - - - , r i ' X655 r 0.821 � � , , r X665 0.833 , , r r 167S 0.851 56 r ---------- - ------------------L-----------------1------------------' ;685 0.845 � r , r i r r '69QC1 0.979 r i70QC1 0.046 , , ------------------ ------------------ r ------------------' r r ' ' .71D 3.015 r r � , r r r r r �72B 0.048 r 62 ----------------- ------------------ L ----------------- ------------------' 69 -----------------a--------------------- ---------------a------------- - - - - -' r r r r r r i r r r r r r r r r r r r r r r r r r r r r r r r r r r r r 68 ----------------------------------------------------------------------' r r ' r r r r r r r r 70 ------------------------------------------------------------------------' r r r r r r r r Page 4 of 4 JJZ 14 "I3S, IMC. %-15j, 003 1 TOTAL pol!OTXN DIGESTIONS 1 1b - M n 4-,UAM M CLIENT ID SAMPLE WEIGHT AMS LE s FINK VOLUME MLS DATE LAB NO. C 1 Nos, � H2M LAUS, INC. 11 TOTAL, PHOS/TXN DIGESTIONS NAME: DATE: p00911 oxe 00 M O C% F--4 C � p00911 oxe 00 M O C% F--4 'V-1011"" Sample Results Report Print Date/Time: �455*/--O"2 Sample ID Result Std. Dev. RSD Mode ALT --------------------------------- )I 0.1444 0.0127 8.78 UTILITY X =7-If re. jJ0 27.7176 0.3588 1.29 TOC [C 41.0 0.2309 0.2181 94.43 TOC :R ?JAVf% .................1.1644... 0.0481.. 4.14... TOC .. IBLK c/•0 0.0226 0.0239 105.86 TOC )509510-001A MND' Ip 41.0 0.1065 0.2963 278.23 TOC )509510-002A.MW:IS.....•... </,d 0.1640... 0.2812..171.44... TOC .. )509510-002AMS�i 1(�n` SGL. /LV%K 10.7674 0.1734 1.61 TOC )509510-002ADUP R -Nlc c/.b 0.4269 0.2012 47.13 TOC )509510-003A.MV.-?Q...............4J.0 0.2739... 0.1283.. 46.86...TOC .. 1509510-004A MW-'3S c0-0.0676 0.1302 -192.53 TOC 1509510-005A MN-40 eJ o-0.1111 0.0676 -60.90 TOC 1509510-006A.VW-AT.............41-.0 0.3885... 0.1754.. 45.15... TOC .. 1509510-007A MW SQ 1-1.0 0.2814 0.0608 21.62 TOC ,509510- 08A I* W-SS LI-d 0.0361 0.0794 220.38 TOC rv.l►'� `....................101%427.2752... 0.1355.. 0.50... TOC .. CB I-LO 0.1076 0.0971 90.26 TOC 509510-009A lm%J -64 40.8757 0.5535 1.35 TOC 509510-010A.rW65.............L1,O -0.1199... 0.4694..-391.38...TOC .. 509510-011A VWV-t0 L/,0 -0.0802 0.3181 -396.78 TOC 509510-012A r1W- K cl • e -0.2711 0.0957 -35.29 TOC 509510-013A.f yt.t?14r1 .......c1.0 0.1316... 0.0386.. 29.35... TOC .. FB Tvp = 10 pr4N 1Oy� 10.4322 0.0648 0.62 TOC FBD'f�: 0 Y- 10.5114 0.2742 2.61 TOC Cv.�/:?�y .................. III V 27.9893... 0.1569.. 0.56... TOC .. CB L/_o 0.5218 .0.0953 18.26 TOC 11W3 • Sample Results Report Print Date/Time: 2005/09/21 9:10:41 Method ID Sample Type Vial Timestamp Message leaning Procedure Sample sp 2005/09/20 17:43 O(AKSTE WATER Sample 1 2005/09/20 18:11 TE WATER Sample 2 2005/09/20 18:38 Low Sample OC WASTE WATER ...Sample .. 3..2005/09/20 19:10 ..Low Sample OC WASTE WATER Sample 4 2005/09/20 19:40 Low Sample OC WASTE WATER Sample 5 2005/09/20 20:10 Low Sample OC WASTE WATER ...Sample .. 6..2005/09/20 20:39 ..Low Sample OC WASTE WATER Sample 7 2005/09/20 21:07 OC WASTE WATER Sample 8 2005/09/20 21:33 Low Sample OC WASTE WATER ...Sample .. 9..2005/09/20 22:06 ..Low Sample OC WASTE WATER Sample 10 2005/09/20 22:36 Low Sample OC WASTE WATER Sample 11 2005/09/20 23:06 Low Sample OC WASTE WATER ...Sample .. 12..2005/09/20 23:35 ..Low Sample OC WASTE WATER Sample 13 2005/09/21 00:05 Low Sample OC WASTE WATER Sample 14 2005/09/21 00:34 Low Sample OC WASTE WATER ..Sample .. 15..2005/09/21 01:03 .•Low OC WASTE WATER Sample 16 2005/09/21 01:33 Sample OC WASTE WATER Sample 17 2005/09/21 01:58 OC WASTE WATER ...Sample .. 18..2005/09/21 02:28 ..Low Sample OC WASTE WATER Sample 19 2005/09/21 03:01 Low Sample OC WASTE WATER Sample 20 2005/09/21 03:30 Low Sample OC WASTE WATER ...Sample .. 21..2005/09/21 04:00 ..Low Sample OC WASTE WATER Sample 22 2005/09/21 04:25 DC WASTE WATER Sample 23 2005/09/21 04:56 OC WASTE WATER Sample .. 24..2005/09/21 05:25 .. Detect Detect Detect Detect Detect Detect Detect Detect Detect Detect Detect Detect Detect Detect Detect Detect Detect OC WASTE WATER •• Sample 25 2005/09/21 05:55 Low Sample Detect • • O 00 M CDO C!] H Detailed Analysis Report Print Date/Time: 2005/09/21 9:10:44 ample ID: DI ug C Mode: TOC Mode: UTILITY [ethod: Cleaning Procedure Filename: 09201719 a Curve: TOC WW CURVE 42805 Timestamp: 2005/09/20 17:43 ►pqwor ID: JASON SAMUEL Raw Data Sample Type: Sample .ep # ppm C ug C Raw Data Beginning Ending Integration 10.184 11.181 112 2 27.3874 1.3694 281818 Baseline Baseline Time 1 0.1256 0.0628 19993 10.055 10.254 120 2 0.1533 0.0767 22772 10.021 10.220 122 3 0.1484 0.0742 22277 10.112 10.312 121 4 0.1502 0.0751 22464 10.122 10.321 122 ---------------------------------------------------------------------------- <<Statistics>>> aerator ID: JASON SAMUEL Mean: 0.1444 Std Dev: 0.0127 RSD: 8.78 ample ID: LCS # ppm,C ug C Mode: TOC ethod: TOC WASTE WATER Filename: 09201719 al. Curve: TOC WW CURVE 42805 Timestamp: 2005/09/20 18:11 perator ID: JASON SAMUEL Baseline Sample Type: Sample ep # ppm C ug C Raw Data Beginning Ending Integration 10.026 10.034 120 Baseline Baseline Time 1 28.2067 1.4103 290027 10.184 11.181 112 2 27.3874 1.3694 281818 10.284 11.278 110 3 27.5255 1.3763 283202 10.246 11.244 111 4 27.7510 1.3875 285461 10.189 11.176 112 ---------------------------------------------------------------------------- < tistics>>> Mean: 27.7176 Std Dev: 0.3588 RSD: 1.29 ist Message: Low ample ID: ICB Mode: TOC ethod: TOC WASTE WATER 0.2309 Std Filename: 09201719 al. Curve: TOC WW CURVE 42805 Timestamp: 2005/09/20 18:38 aerator ID: JASON SAMUEL Sample Type: Sample ap # ppm,C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.5387 0.0269 12808 10.026 10.034 120 2 0.1539 0.0077 8953 10.008 9.978 120 3 0.2032 0.0102 9447 9.965 9.958 120 4 ---------------------------------------------------------------------------- 0.0279 0.0014 7691 9.927 9.895 120 ist Message: Low Sample Detected ,<Statistics»> Mean: 0.2309 Std Dev: 0.2181 RSD: 94.43 ample ID: CRI �thod: TOC WASTE WATER al. Curve: TOC WW CURVE 42805 )erator ID: JASON SAMUEL �P* ppm C ug C Raw Data Mode: TOC Filename: 09201719 Timestamp: 2005/09/20 19:10 Sample Type: Sample Beginning Ending Integration ample ID: MBLK fethod: TOC WASTE WATER :al. Curve: TOC WW CURVE 42805 Aerator ID: JASON SAMUEL Mode: TOC Filename: 09201719 Timestamp: 2005/09/20 19:40 Sample Type: Sample .ep # ppm C ug C Baseline Baseline Time 1 1.1978 0.0599 19413 9.804 9.831 120 2 1.1210 0.0560 18643 9.808 9.838 120 3 1.2135 0.0607 19570 9.800 9.853 120 4 1.1251 0.0563 18684 9.804 9.835 120 -0.0001 7387 9.748 ---------------------------- 120 4 as essage: Low Sample Detected 7911 9.738 9.734 <<Statistics>>> Mean: 1.1644 Std Dev. 0.0481 RSD: 4.14 ample ID: MBLK fethod: TOC WASTE WATER :al. Curve: TOC WW CURVE 42805 Aerator ID: JASON SAMUEL Mode: TOC Filename: 09201719 Timestamp: 2005/09/20 19:40 Sample Type: Sample .ep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.0344 0.0017 7756 9.737 9.752 120 2 0.0085 0.0004 7497 9.730 9.748 120 3 -0.0025 -0.0001 7387 9.748 9.762 120 4 0.0499 0.0025 7911 9.738 9.734 120 ---------------------------------------------------------------------------- ast Message: Low Sample Detected 120 ---------------------------------------------------------------------------- ast Message: <<Statistics>>> Mean: 0.0226 Std Dev: 0.0239 RSD: 105.86 ample ID: 0509510-001A fethod: TOC WASTE WATER al. Curve: TOC WW CURVE 42805 P* or ID: JASON SAMUEL Mode: TOC Filename: 09201719 Timestamp: 2005/09/20 20:10 Sample Type: Sample ep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.4916 0.0246 12337 9.751 9.751 120 2 0.1525 0.0076 8939 9.739 9.772 120 3 -0.0089 -0.0004 7322 9.737 9.756 120 4 -0.2092 -0.0105 5316 9.749 9.755 120 ---------------------------------------------------------------------------- ast Message: Low Sample Detected <<Statistics>>> Mean: 0.1065 Std Dev: 0.2963 RSD: 278.23 ample ID: 0509510-002A Mode: TOC ethod: TOC WASTE WATER Filename: 09201719 al. Curve: TOC WW CURVE 42805 Timestamp: 2005/09/20 20:39 perator ID: JASON SAMUEL Sample Type: Sample ep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.3950 0.0197 11369 9.746 9.763 120 2 0.3606 0.0180 11024 9.733 9.764 120 3 0.1141 0.0057 8554 9.739 9.755 120 cV 4 -------0_2137-----0_0107------5270---------9_765-------9_749 ------------ 120 00 essage: Low Sample Detected O _ � Cn H <<Statistics>>> Mean: 0.1640 Std Dev: 0.2812 RSD: 171.44 ample ID: 0509510-002AMS Mode: TOC et TOC WASTE WATER Filename: 09201719 2005/09/20 21:07 al rve• TOC WW CURVE 42805 Timestamp: perator ID: JASON SAMUEL Sample Type: Sample ep # ppm C ug C Raw Data. Beginning Ending Integration Baseline Baseline Time 1 10.8196 0.5410 115818 9.781 10.770 104 2 10.8226 0.5411 115848 9.789 10.785 105 3 10.9120 0.5456 116743 9.781 10.772 105 4 10.5154 0.5258 112770 9.807 10.796 104---- ------ --------------------------------------------------- <<Statistics>>> Mean: 10.7674 Std Dev: 0.1734 RSD: 1.61 ample ID: 0509510-002ADUP Mode: TOC ethod: TOC WASTE WATER Filename: 09201719 2005/09/20 21:33 al. Curve: TOC WW CURVE 42805 Timestamp: perator ID: JASON SAMUEL Sample Type: Sample ep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.7255 0.0363 14681 9.793 9.820 120 2 0.3681 0.0184 11099 9.782 9.813 120 3 0.3007 0.0150 10424 9.771 9.797 120 4 0.3133 0.0157 10550 9.766 9.793 120 --------------------------------------- a essage• Low Sample Detected <<Statistics>>> Mean: 0.4269 Std Dev: 0.2012 RSD: 47.13 ample ID: 0509510-003A Mode: TOC ethod: TOC WASTE WATER Filename: 09201719 al. Curve: TOC WW CURVE 42805 Timestamp: 2005/09/20 22:06 ,perator ID: JASON SAMUEL Sample Type: Sample .ep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.4308 0.0215 11728 9.771 9.798 120 2 0.3209 0.0160 10627 9.775 9.794 120 3 0.1421 0.0071 8835 9.782 9.786 120 4 0.2017 0.0101 9432 9.774 9.793 120 ---------------------------------------------------------------- ,ast Message: Low Sample Detected <<Statistics>>> Mean: 0.2739 Std Dev: 0.1283 RSD: 46.86 ;ample ID: 0509510-004A Mode: TOC lethod: TOC WASTE WATER Filename: 09201719 .a&urve: TOC WW CURVE 42805 Timestamp: 2005/09/20 22:36 M 00 M O O H perator ID: JASON SAMUEL ep # ppm C ug C Raw Data 1 0.0963 0.0048 8376 2a -0.0312 -0.0016 7099 3� -0.2036 -0.0102 5371 4 -0.1319 -0.0066 -------------- 6090 Sample Type: Sample Beginning Baseline 9.848 9.848 9.857 9.871 ------------ Ending Baseline 9.853 9.857 9.855 9.893 -------------- Integration Time 120 120 120 120 ------------------------ ast Message: Low Sample Detected <<Statistics>>> Mean: -0.0676 Std Dev: 0.1302 RSD: -192.53 ample ID: 0509510-005A ethod: TOC WASTE WATER al. Curve: TOC WW CURVE 42805 perator ID: JASON SAMUEL Mode: TOC Filename: 09201719 Timestamp: 2005/09/20 23:06 Sample Type: Sample ep # ppm C ug C Raw Data Beginning Ending Integration 10657 0 0.3089 0.0154 Baseline Baseline Time 1 -0.0619 -0.0031 6791 9.876 9.888 120 2 -0.1191 -0.0060 6218 9.868 9.884 120 3 -0.2037 -0.0102 5371 9.865 9.875 120 4 -0.0595 -0.0030 6815 9.839 9.869 120 ---------------------------------------------------------------------------- ast Message: Low Sample Detected <<Statistics>>> Mean: -0.1111 Std Dev: 0.0676 RSD: -60.90 ar 0 ID: 0509510-006A a TOC WASTE WATER al. Curve: TOC WW CURVE 42805 aerator ID: JASON SAMUEL Mode: TOC Filename: 09201719 Timestamp: 2005/09/20 23:35 Sample Type: Sample ap # ppm C ug C Raw Data Beginning Ending Integration 10657 0 0.3089 0.0154 Baseline Baseline Time 1 0.6332 0.0317 13756 9.880 9.908 120 2 0.2350 0.0117 9766 9.899 9.907 120 3 0.3917 0.0196 11336 9.896 9.926 120 4 0.2943 0.0147 10360 9.907 9.924 120 ---------------------------------------------------------------------------- 3st Message: Low Sample Detected '<Statistics>>> Mean: 0.3885 Std Dev: 0.1754 RSD: 45.15 ample ID: 0509510-007A �thod: TOC WASTE WATER 31. Curve: TOC WW CURVE 42805 aerator ID: JASON SAMUEL ap # ppm C ug C Raw Data 1 0.3014 0.0151 10431 2 0.3239 0.0162 10657 0 0.3089 0.0154 10506 Mode: TOC Filename: 09201719 Timestamp: 2005/09/21 00:05 Sample Type: Sample Beginning Ending Integration Baseline Baseline Time 10.007 10.017 120 9.999 10.003 120 9.986 9.998 120 00 M O Cn H 4 0.1912 0.0096 9327 10.006 10.019 120 ast Message: Low Sample Detected <<Statistics>>> Mean: 0.2814 Std Dev: 0.0608 RSD: 21.62 • ample ID: 0509510-008A Mode: TOC ethod: TOC WASTE WATER Filename: 09201719 al. Curve: TOC WW CURVE 42805 Timestamp: 2005/09/21 00:34 perator ID: JASON SAMUEL Sample Type: Sample ep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.1137 0.0057 8550 9.996 9.980 120 2 0.0873 0.0044 8286 9.977 9.977 120 3 0.0030 0.0002 7441 9.964 9.953 120 4 ---------------------------------------------------------------------------- -0.0598 -0.0030 6813 9.952 9.940 120 ast Message: Low Sample Detected 27.2752 Std Dev: 0.1355 RSD: 0.50 <<Statistics>>> imple Mean: 0.0361 Std Dev: 0.0794 RSD: 220.38 ample ID: CCV athod: TOC WASTE WATER 31. Curve: TOC WW CURVE 42805 aerator ID: JASON SAMUEL Mode: TOC Filename: 09201719 Timestamp: 2005/09/21 01:03 Sample Type: Sample �p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 27.1336 1.3567 279275 9.906 10.906 112 20 27.3030 1.3652 280973 9.952 10.948 112 3 27.4500 1.3725 282445 9.966 10.959 112 4 ---------------------------------------------------------------------------- 27.2144 1.3607 280084 9.954 10.950 112 :<Statistics»> Mean: 27.2752 Std Dev: 0.1355 RSD: 0.50 imple ID: CCB Mode: TOC !thod: TOC WASTE WATER Filename: 09201719 il. Curve: TOC WW CURVE 42805 Timestamp: 2005/09/21 01:33 >erator ID: JASON SAMUEL Sample Type: Sample !p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.2267 0.0113 9683 9.812 9.827 120 2 0.1464 0.0073 8878 9.798 9.804 120 3 0.0360 0.0018 7772 9.761 9.784 120 4 --------------------------------------------------------------------------- 0.0212 0.0011 7623 9.772 9.796 120 st Message: Low Sample Detected <Statistics>>> Mean: 0.1076 Std Dev: * ID: 0509510-009A 0.0971 RSD: 90.26 Mode: TOC 00 M O H ethod: TOC WASTE WATER Filename: 09201719 Timestamp: 2005/09/21 01:58 al. Curve: TOC WW CURVE 42805 pez for ID: JASON SAMUEL Sample Type: Sample ep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 41.4340 2.0717 422557 9.763 10.759 114 2 40.1747 2.0087 409940 9.822 10.815 114 3 41.1770 2.0589 419983 9.781 10.772 114 4 40.7171 2.0359 415374 9.780 10.779 114 -------------------------------------------------------------- <<Statistics>>> Mean: 40.8757 Std Dev: 0.5535 RSD: 1.35 ample ID: 0509510-010A Mode: TOC ethod: TOC WASTE WATER Filename: 09201719 al. Curve: TOC WW CURVE 42805 Timestamp: 2005/09/21 02:28 perator ID: JASON SAMUEL Sample Type: Sample .ep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.5316 0.0266 12738 9.587 9.602 120 2 -0.1845 -0.0092 5562 9.580 9.566 120 3 -0.2402 -0.0120 5005 9.557 9.567 120 4 -0.5866 -0.0293 1534 9.567 9.524 120 ---------------------------------------------------------------------- ,ast Message: Low Sample Detected <<Statistics>>> Mean: -0.1199 Std Dev: 0.4694 RSD: -391.38 :a* ID: 0509510-011A Mode: TOC lethod: TOC WASTE WATER Filename: 09201719 .al. Curve: TOC WW CURVE 42805 Timestamp: 2005/09/21 03:01 1perator ID: JASON SAMUEL Sample Type: Sample .ep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.3758 0.0188 11177 9.479 .9.488 120 2 -0.1933 -0.0097 5474 9.455 9.452 120 3 -0.1418 -0.0071 5990 9.420 9.439 120 4 -0.3614 -0.0181 3791 9.406 9.395 120 ------------------------------------------------------------------------- ,ast Message: Low Sample Detected :«Statistics>>> Mean: -0.0802 Std Dev: 0.3181 RSD: -396.78 ample ID: 0509510-012A TOC lethod: TOC WASTE WATER :al. Curve: TOC WW CURVE 42805 >perator ID: JASON SAMUEL :ep # ppm C ug C Raw Data 0 -0.1671 -0.0084 5737 rko Mon Filename: 09201719 Timestamp: 2005/09/21 03:30 Sample Type: Sample Beginning Ending Integration Baseline Baseline Time 9.323 9.319 120 2 -0.3911 -0.0196 3493 9.299 9.292 120 3 -0.2958 -0.0148 4448 9.282 9.285 120 4 -0.2306 -0.0115 5101 9.248 9.235 120 ---------------------------------------------------------- ast Message: Low Sample Detected 9.228 120 3 0.0768 = istics>>> Mean: -0.2711 Std Dev: 0.0957 RSD: -35.29 ample ID: 0509510-013A ethod: TOC WASTE WATER al. Curve: TOC WW CURVE 42805 perator ID: JASON SAMUEL Mode: TOC Filename: 09201719 Timestamp: 2005/09/21 04:00 Sample Type: -Sample ep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.1328 0.0066 8742 9.241 9.254 120 2 0.1546 0.0077 8961 9.221 9.228 120 3 0.0768 0.0038 8181 9.214 9.220 120 4 0.1623 0.0081 9038 9.173 9.184 120 ------------------------------------------------------------------- ,ast Message: Low Sample Detected <<Statistics>>> Mean: 0.1316 Std Dev: 0.0386 RSD: 29.35 ample ID: LFB Mode: TOC fethod: TOC WASTE WATER Filename: 09201719 .al. Curve: TOC WW CURVE 42805 Timestamp: 2005/09/21 04:25 operator ID: JASON SAMUEL Sample Type: Sample .e� ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 10.4860 0.5243 112476 9.155 10.149 105 2 10.4844 0.5242 112459 9.180 10.179 104 3 10.3531 0.5177 111144 9.170 10.160 105 4 10.4054 0.5203 111668 9.162 10.150 104 -------------------------------------------------------------------- :«Statistics>>> Mean: 10.4322 Std Dev: 0.0648 RSD: 0.62 ample ID: LFBD Mode: TOC fethod: TOC WASTE WATER Filename: 09201719 :al. Curve: TOC WW CURVE 42805 Timestamp: 2005/09/21 04:56 >perator ID: JASON SAMUEL Sample Type: Sample I # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 10.3937 0.5197 111550 9.094 10.090 104 2 10.9200 0.5460 116824 9.055 10.055 105 3 10.3315 0.5166 110927 9.070 10.063 105 4 10.4003 0.5200 111616 9.052 10.047 104 ------------------------------------------------------------------------- :«Statistics>>> Mean: 10.5114 Std Dev: 0.2742 RSD: 2.61 :7 ample ID: CCV Mode: TOC ethod: ITOC WASTE WATER Filename: 09201719 2005/09/21 05:25 al. Curve: -TOC WW CURVE 42805 Timestamp: perator ID: JASON SAMUEL Sample Type: Sample ep,* ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 27.9593 1.3980 287548 9.087 10.080 110 2 28.2186 1.4109 290146 9.100 10.087 112 3 27.8735 1.3937 286688 9.105 10.095 110 4 27.9057 1.3953 287011 9.120 10.117 112 ------------------------------------------------------------ <<Statistics>>> Mean: 27.9893 Std Dev: 0.1569 RSD: 0.56 ample ID: CCB Mode: -TOC ethod: TOC WASTE WATER Filename: 09201719 al. Curve: TOC WW CURVE 42805 Timestamp: 2005/09/21 05:55 perator ID: JASON SAMUEL Sample Type: Sample ep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 0.6137 0.0307 13560 9.034 9.054 120 2 0.5938 0.0297 13361 9.021 9.040 120 3 0.4490 0.0225 11910 9.002 9.000 120 4 0.4306 0.0215 11726 8.986 8.984 120 -------------------------------------------------------------------- ast Message: Low Sample Detected <<Statistics>>> Mean: 0.5218 Std Dev: 0.0953 RSD: 18.26 0 00 00 M O C/� Calibration Report Print Date/Time: 2005/09/21 9:11:20 al. Curve ID: TOC WW CURVE 42805 reated: 2005/07/13 09:09 alibration Factor (m): 2.004e+05 arcept (b) : 4931 red: 0.99970 Standard ID Y X Expected Measured Message Date & Raw Data ug C ug C Time I 11765 0.000 0.034 Low Sample De 2005/04/28 16:09 .SPPM 13772 0.025 0.044 Low Sample De 2005/04/28 16:27 .OPPM 17398 0.050 0.062 Low Sample De 2005/04/28 16:45 .OPPM 50434 0.250 0.227 2005/04/28 17:02 O.OPPM 98824 0.500 0.469 2005/04/28 17:20 S.OPPM 250200 1.250 1.224 2005/04/28 17:38 O.OPPM 506419 2.500 2.503 2005/04/28 17:56 S.OPPM 758873 3.750 3.762 2005/04/28 18:14 is is OIN 00 M O h U24 "US, INC. • SDG NO.: TZ003 SCAN: This data package was reported by the undersigned. This reporting includes data calculations, manual edits if necessary and compilation of raw data. The information presented is true and correct to the best of my knowledge. • Signature: Date: Reviewer: A8 D - I�� t IV I •