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HomeMy WebLinkAboutSample Date Summary Package 09/2005_ Analytical Data Package For TOWN OF SOUTHOLD PART 360 ROUTINE SDG NO: TSL003 Water Samples Received: 9/16/05 SAMPLE DATA SUMMARY PACKAGE V I A ILAUSs IN C • Environmental Testing Laboratories 575 Broad Hollow Road, Melville, N.Y. 11747 • • 0 U2M "US, INC. TABLE OF CONTENTS TOWN OF SOUTHOLD PART 360 ROUTINE WATER SAMPLES SAMPLES RECEIVED: 9/16/05 SDG NO.: TSI -003 1. NYS DEC SUMMARY FORMS 2. CHAIN OF CUSTODY DOCUMENTATION 3. SDG NARRATIVES 4. SAMPLE REPORTS 4.1 METALS 4.2 WET CHEMISTRY 5. DUPLICATE SUMMARY RESULTS 5.1 METALS 5.2 WET CHEMISTRY 6. SPIKE SAMPLE RESULTS 6.1 METALS 6.2 WET CHEMISTRY 7. BLANK SUMMARY DATA AND RESULTS 7.1 METALS 7.2 WET CHEMISTRY U2M "US, INC. 0 1. NYS DEC SUMMARY FORMS • • N cn M O E-+ NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE IDENTIFICATION AND • ANALYTICAL REQUIREMENT SUMMARY SM,- TSI -003 Analytical Requirements Customer Sample Code Laboratory Sample Code ME we MW41D 0509510-001 X X MW4S 0509510-002 X X MW -3D 0509510-003 X X MW -3S 0509510-004 X X MW -41) 0509510-005 X X MW -4S 05095104M X X MW -51) 0509510-007 X X MW -5S 0509510-008 X X MW -6D 0509510-009 X X MW -6s 0509510-010 X X MW -8D 0509510-011 X X Mw4s 0509510-012 X X EQPT BLANK 9116 0509510-013 X X • • O O CLP, (Please indicate year of protocol) AS P TCUTAL, HSL, Priority Pollutant, ssw ie P) lar • NEW YORK STATE DEPARTMENT OF ENNONMENTAL CONSERVATION • SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG. TSI -003 INORGANIC ANALYSIS Laboratory Samp ID Client Sample ID Matrix Metals Requested DateRecd at Lab Date Analyzed 0509510-001 MW -11) WATER CACD,FE,K,MG,MN,NA,PB, 16 -Sep -05 09/05 0509510-002 MW -1S WATER CA,CD,FE,K,MG,MN,NA,PB, 16 -Sep -05 09/05 0509510-002DUP MW -ISD WATER CA.CD,FE,K,MG,MN,NA,PB, 16 -Sep -05 09/05 0509510-002MS MW -ISS WATER CA CD,FE,K,MG,MN,NA P8, 16 -Sep -05 09/05 0509510-003 MW -3D WATER CA,CD,FE.K,MG,MN,NA,PB, 16 -Sep -05 09/05 0509510-004 MW -3S WATER CA,CD,FE,K,MG,MN,NA,PB, 16 -Sep -05 09/05 0509510-005 MW -4D WATER CA.CD,FE,K,MG,MN,NA,PB, 16 -Sep -05 09/05 0509510-006 MW -4S WATER CA,CD,FE,K.MG,MN,NA,PB, 16 -Sep -05 09/05 0509510-007 MW -5D WATER CA,CD,FE.K,MG,MN,NA,PB, 16 -Sep -05 09/05 0509510-008 MW -5S WATER CA,CD,FE,K,MG,MN,NA,PB, 16 -Sep -05 09/05 0509510-009 MW -61) WATER CA,CD,FE,K,MG,MN,NA,PB, 16 -Sep -05 09/05 0509510-010 MW -6S WATER CA,CD,FE,K,MG,MN,NA,PB, 16 -Sep -05 09/05 0509510-011 MW -8D WATER CA.CD,FE,K,MG,MN,NAPB, 16 -Sep -05 09/05 0509510-012 MW -8S WATER CA,CD,FE,K,MG,MN,NA,PB, 16 -Sep -05 09/05 0509510-013 EQPT BLANK 9/16 WATER CA,CD,FE,K.MG,MN,NA.PB, 16 -Sep -05 09/05 TSL003 S4 NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SSAMPLE SDG: TSL003 PREPARATION AND ANALYSIS SUMMARY INORGANIC ANALYSIS Laboratory Samp ID Client Sample ID Matrix7 Tests DateRecd at Lab Date Analyze 0509510-001 MW -1D Groundwater SELECT WET CHEMISTRY " 09/16/05 09/05 0509510-002 MW -1S Groundwater SELECT WET CHEMISTRY" 09/16/05 09/05 0509510-002DUP MW-1SDUP Groundwater SELECT WET CHEMISTRY" 09/16/05 09/05 0509510-002MS MW -ISMS Groundwater SELECT WET CHEMISTRY " 09/16/05 09/05 0509510-003 MW -313 Groundwater SELECT WET CHEMISTRY" 09/16/05 09/05 0509510-004 MW -3S Groundwater SELECT WET CHEMISTRY" 09/16/05 09/05 0509510-005 MW -4D Groundwater SELECT WET CHEMISTRY " 09/05 0509510-006 MW -4S Groundwater SELECT WET CHEMISTRY" *09/16/05 09/0505095.10-007 MW -5D Groundwater SELECT WET CHEMISTRY" 09/05 0509510-008 MW -5S Groundwater I SELECT WET CHEMISTRY " 09/16/05 09/05 - 10/05 0509510-009 MW -613 i Groundwater I SELECT WET CHEMISTRY " 09/16/05 09/05 0509510-010 MW -6S Ground%% -ter SELECT WET CHEMISTRY " 09/16/05 09/05 -10/05 0509510-011 MW -813 Groundwater SELECT WET CHEMISTRY " 09/16/05 09/05 0509510-012 MW -8S Groundwater SELECT WET CHEMISTRY " 09/16/05 09/05 0509510-013 EQPT BLANK 9/16 Blank SELECT WET CHEMISTRY" 09/16/05 09/05 ** Alkalinity, Total (As CaCO3) ; Biochemical Oxygen Demand; Bromide; Chemical Oxygen Demand ; Chloride ; Hardness (As CaCO3) ; Nitrate as N ; Nitrogen, Ammonia (As N) ; Nitrogen, Kjeldahl, Total ; Phenolics, Total Recoverable ; Sulfate; Total Dissolved Solids; Total Organic Carbon; U2M "US, INC. P� 2. CHAIN OF CUSTODY DOCUMENTATION • • M O H U2,01AIRSmi -11%Ce 575. Broad Hollow Rd. Melville. NY 11747-5076. 1341 STERNAL CHAIN DF CU57'0-DY16 Tok (516)494-3040. (616) 420-"3.6 CLIENT:: pc7lg L= H2All PFt E. MBER' SA'°H T05,0 7'o W� :of EO U MOL b 1.�4-N �� L pr 3 r � Q-�, � n � .� _ � NOTES: prVeat'Contsov Rovhr+�- Pr,o,,. Nl„�1a..: 3(00 &.rcl1Ke I x1419 3 Cod/ NH3 NO3 � Pkle vols � T,K/V � C L So / � / To•T,+L -4 Lk 'At IN i',yJ W. p 'LER . (Signaturey IIent . Ham DELIVERABLES: eX .„1O— $ �► ANALYSIS REQUESTED TURNAROUND TIME: a ` t�1 V' �J ORGANIC - i INORG. DATE }TIME MATRIXFIELD .LD. $ U LAB I.D. NO �IREMIARKS: 1 1 12o L MW -3 S /'MW -30 III 1W10 M W - 4S -Cb 140 MW- - mso W — US 1. i w �. s _ o by `(s)glwwre) .. pr 0) Date to �A•�Time Time . by ( ) Date Date. Tlme Irr►e LABORATORY USE .ONLY Discrepancies Between Sample Labels and COC Record? Y or N Ex n` 1. Ste— or Hand Delivered_ Airbill8 3. R*aiwd in pond condition: Y or N 5. P1°Pe'I� p tamed t: Y or N S..Samplea�nitumed to tab ,_ HB from colleciion. COC Tion waL . 1: Rpt on ouW package: Y or N 2. iJnbrokm on wier pedwpe: Y or N 3. COC record pnpot 3 oompNle upon sample receipt: YorN RewquMW by. (Signature) ' Date Time Date Inio RelingWdW by: (Siprwhue) Data Tkne Received ty.'(ftneture) Date 1 �WHi �6PY - ORIGINAL YELLOW COPY - CLIENT PINK COPY - LABORATORY 1-12 lAI3S, I N�C. 919 6roid Hallow Rd.: MNvlllo. NY 11747-W76 1. 341�� EXTERNAL CHAIN,,OF CUSTODY16 TN: (616) 094-3040., Fix (510t4204436 CLIENT: P G'T 5 l� 142M SDG NO:'[ 5 (_0 PROJECT NAMEINUM R 'O.14TOSOI TOWN pF. SOuL0 �t� 1?F1LL wT E'3 v Ir'So 2 z 3 :r� -~`.,lL CV80j) �' 1.CJF NOTES:' Pro/eat Contact. R O cry Yom, Phone Number. e.1v. o ®CAS � N.M3 N43. j Plehb IS. 5 E3R C L TOTAL ALKALIN 4y �—MI S SAMPLERS: (signature)/CI nt :H W DELIVERABLES: ANALYSIS REQUESTED. TURNAROUND `TIME : .. ORGANIC J INOt2G. DATE TIME MATRIX FIELD I.D. � a � LAB I.D:'NO. REMARKS: 464 063 0 L W- I I a I p sv w- a 3 a�� M S M s'D 730 goo w -Ci O 30 ,E Q p?' 13L4N Relinquished by: (Signature) Date 9 /b 4 Time 9 %s3 {s wro) �Da e t U q `� LABORATORY.USE ONLY Discrepancies Between Sarripie labels and COC Record? Y or N Explain: SNPDad.� °' Hand Delivered— Airbilltt Z Ambient or.chilled 3. Reaived.inVod condition: Y or N 4. PropwV preserved: Y or N S. Swiplas atumad to lob _ Hrs from collection. COC I e wap: 1. Preprint on outer peckepe: Y or N 2 Unbroken on outer pockepg: Y or N. S. COC reowd present 6 complete upon sample receipt: Y or N trstnpd ( cure) Date lid Time �S__F . by ( Date 5 me 5 FtelMquiphed by: (Signpturo) Date Tim by ) Date Rellrquished'by. (Signature) Date Time Rtaoviwd try ($IpnNurr) Date Time Y - ORIGINAL YELLOW COPY - CLIENT PINK COPY - LABORATORY H2M LABS, INC. C -T-� �-CO3 • Sample Receipt Checklist Client Name PCTSL Date and Time Receive 9/16/2005 9:53:00 AM Work Omer Numbe 0549510 Received by BGL Checklist completedb - 5 Reviewed by PIW- -- ! f)(S)l 1A Z' — 1� .LJ bamats sb Matrix Carrier name Hand Delivered Shipping container/cooler in good condition? Yes 0 No ❑ Not Applicable ❑ Custody seals intact on shippping container/cooler? Yes ❑ No ❑ Not Applicable 0 Custody seals intact on sample bottles? Yes ❑ No ❑ Not Applicable 0 Chain of custody per? Yes 0 No ❑ Chain of custody signed when relinquished and received? Yes ® No ❑ Chain of custody agrees with sample labels? Yes 0 No ❑ Samples in proper contairw/bottle? Yes No ❑ Sample containers intact? Yes © No ❑ Sufficient sample volume for indicated test? Yes 0 No ❑ spiesreceived within holding time? Yes 0 No El Conter/Temp Blank temperature in compliance? am Yes 0 No ❑ Water - VOA vials have zero headspace? No VOA vials submitted 0 Yes ❑ No ❑ Water - pH acceptable upon receipt? Yes B No ❑ Adjusted? Checked b Any No and/or NA (not applicable) response must be detailed in the comments section b — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — - - — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — - Client contacted Contacted by: Comments: Corrective Action Date contacted: Regarding Person contacted VM tAILS, P%C-w JNrERNAL CHAIN OF CUSTODY amlrf-���DUWERJAXLES-SJW_TURN AROUND TWEAA6— sDG s- -TSLMA cAsE MATM:–GJ(4— pH CHM& 14 O METALS 0043 UAUS, INC. INTERNAL CHAIN OF CUSTODY METALS P 0044 tom+ TABS, Nc• • INTERNAL CHAIN OF CUSTODY car: C DEIavER�B1-�s: -MM AROUM TDAk snc #: '`i �- cASE #-.2!!��- MAIVIC VV ojN REMARKS: RECEPvM B WET CHEMISTRY P 0103 ro uPal- r INN J s INN IN I ON ON ONNO WET CHEMISTRY P 0103 gl- : if fs'ri�►'►� �b—.iWAMMm-r k In !!'il �� ,ice INTERNAL CHAIN OF.CUS-TODY RBLI1iQUISiiBD SAMpbB D7lTB ?IBB HT RECB BY Mob -*,n BOTTLE TTFB PURpOSB OF CHANGE OF CpS?ODT INIT Maw ;. alar slat s1cm slow . slaw slaw slaw . saw 2 slow slot slam slw slow llow llcw slow SIAll- Gs alw SIGs c slaw slcw slow - SIC" _ slow SIGs slow SSG" now slob 'SNOW slow slow sacs slow slot aaw slop slow slow saw slcx Maw sacs slow SIGs. s1w sJ cw i _0 WET CHEMISTRY U2M LABS, INC. 0 3. SDG NARRATIVES • 41 • • U2M IL AUS, INC. For Samples: NARRATIVE FOR METALS ANALYSES SAMPLE RECEIVED: 9/16/05 SDG#: TSL003 EQPT BLANK 9/16 MW -1D MW -1S MS/MSD MW -3D MW -3S MW -4D MW -4S MW -5D MW -5S MW -6D MW -6S MW -8D MW -8S Thirteen water samples were received by 112M Labs inc. on 9/16/05 for select metals analysis. Samples were prepared and analyzed using EPA method 6010B with a TJA61E Trace ICP instrument. Sample MW -1 S was utilized for QC analysis and reporting. No problems were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: October 4, 2005 o:\gc\narr2005\tsl\metals\u1003.doc Vincent Stancampiano Vice President U2M "UV, INC. SDG NARRATIVE FOR WET CHEMISTRY • SAMPLES RECEIVED: 9/16/05 SDG NO.: TSL003 For Samples: EQPT BLANK 9/16 MW -51) MW -1D MW -5S MW -1S MS/MSD MW -61) MW -31) MW -6S MW -3S MW -81) MW -4D MW -8S MW -4S Samples were prepared and analyzed using the following methods: PARAMETER Alkalinity METHOD # EPA 310.1 PARAMETER METHOD # Nitrate EPA 353.2 BOD EPA 405.1 Phenols EPA420.1 Bromide EPA 320.1 Sulfate EPA 9038 Chloride EPA325.2 TDS EPA 160.1 COD EPA 410.4 TKN EPA 351.2 Hardness EPA 130.2 TOC EPA 9060 Ammonia EPA 350.1 Sample MW -1S was utilized for duplicate and spike QC analysis and reporting. We results reported for BOD for samples MW -11) and MW -51) were derived from a calculation based on e COD reading due to BOD depletion. Several ammonia values exceeded the TKN concentration. All differences were within 20%RPD or ± the CRDL except for the following: Sample Ammonia mp-/L TKN me& RPD MW -5S 0.42 <0.1 200% MW -6S 0.23 <.01 200% Samples were diluted and reanalyzed as required to keep instrument readings within calibration ranges. No other problems were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: October 7, 2005 gc\narr2005\ts1\wet chem\ts1003.doc ******** **************** ******* ** ************** Joann . Slavin Senior ice President U2M "US, INC. L' 4. SAMPLE REPORTS 4.1 METALS 4.2 WET CHEMISTRY • • 00 cn M O C/) E-+ • • U2M UAUS, INC. QUALIFIERS FOR METALS ANALYSIS Q (Quality Control) Qualifiers E - The reported value is estimated because of the presence of interference. An explanatory note is included in the SDG narrative. M - Duplicate injection precision not met. N - Matrix spike sample recovery not within control limits. S- The reported value was determined by the Method of Standard Additions (MSA). + - Correlation coefficient for the MSA is less than 0.995 W - Post digestion spike for Furnace AA analysis is out of control limits (85- 115%), while sample absorbance is less than 50% of spike absorbance. " - Duplicate analysis is not within control limits. C (Concentration) Qualifiers B - Entered if the reported value is less than the Contract Required Detection Limit (CRDL) but greater than the Instrument Detection Limit (IDL). U - Entered if the analyte was analyzed for but not detected, i.e., less than the IDL. M (Method) Qualifiers P - Analyzed by ICP. M - Analyzed by ICP -MS A - Analyzed by Flame AA. F - Analyzed by Furnace AA. CV - Analyzed by Manual Cold Vapor techniques. AV - Analyzed by Automated Cold Vapor techniques. C - Analyzed by Manual Spectrophotometric Method. CA- Analyzed by Midi -distillation Spectrophotometric Method. NR - Analyte not Required. ON M O U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET j MW -1D Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TS1,003 Matrix (soil/water): WATER Lab Sample ID: 0509510-001 Level (low/med): LOW Date Received: 9/16/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.37 U P 7440-70-2 Calcium 26200 P 7439-89-6 Iron 32.7 B P 7439-92-1 ILead 1.2 U P 7439-95-4 'Magnesium 5480 P 7439-96-5 ;`Manganese 7.2 B P 7440-09-7 Potassium 132001 1 P 7440-23-5 ISodium 184001 1 P Color Before: COLORLESS Clarity Before: CLEAR Texture: • Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 9/28/05 1 �J FORM I - IN ILM04.1 U2M lA BS, INC. 57513MOI-lolow Roaot MA & NY 11747 LABORATORY RESULTS (W1)684,3dt0.FAX (631)4208436 NYSD0H1D810418 Sample Information... •Town of Southold Landfill Lab No.: 0509510-001 Type: Groundwater I Origin: Attn To Client ID.: MW -1D Collected 9/16/2005 6:30:00 AM Received 9/16/2005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameters) Results Qualifier D.F.. 11aft Method Number An_ al rzed Akeinity, Total (As CaCO3) 41.0 1 mgA. E310.1 09202005 8:59 AM Biochemical Oxygen Demand <10 1 mg/L E405.1 09/162005 2:00 PM Bromide < 0.5 1 mg/L E320.1 09202005 2:25 PM Chloride 28.4 1 mgA. E325.2 09/192005 3:36 PM Chemical Oxygen Demand <10 1 mg/L E410.4 09202005 5:44 PM Hardness (As CaCO3) 74.0 2 mg/L E130.2 09272005 3:10 PM Nitrogen, Ammonia (As N) < 0.10 1 mg/L E350.1 09130200512:58 PM Nitrate as N 2.67 5 mg1L E353.2 09212005 4:05 PM Phenolics, Total Recoverable < 5.0 1 WIL E420.1 091.2112005 8:30 AM Sulfate 13.7 1 M90L SW9038 09202005 2.03 PM Total Dissolved Som 685 1 mg/L E160.1 09/192005 3:42 PM Nitrogen, ICeldaM, Total < 0.10 1 mg/L E351.2 09242005 8:16 PM Total Organic Carbon < 1.0 1 mgA. SW9060 09202005 8'10 PM 1r u QuiNfierw E - Value above quentitabontar •ps D - Results for Dilution D.F. = Dlution Factor Laboratory Manager Date Reported: 10!12005 Page 1 of 13 U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER Level (low/med): LOW % Solids: 0.0 MW -1S Contract: L -- SAS No.: SDG No.: TSL003 Lab Sample ID: 0509510-002 Date Received: 9/16/2005 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.59 B P 7440-70-2 Calcium 2n.2 P 7439-89-6 Iron P 7439-92-1 Lead P 7439-95-4 Magnesium 4700 BI P 7439-96-5 Manganese 7.9 B' P 7440-09-7 Potassium 1530 B P 7440-23-5 Sodium 16900 P •Color Before: COLORLESS Clarity Before: Color After: COLORLESS Clarity After: Comments: Date Reported: 9/28/05 • CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 1-12M I AI3S, INC. 575EImW clow Roads M&b NY 11747 (M1)69QM.FAX(631)420M WSDOHD#10478 blown of Southold Landfill Attn To : Collected 9/16/2005 6:50:00 AM Received 9/16/2005 9:53:00 AM Collected By CLIENT Copies To Original CC LABORATORY RESULTS Lab No.: 0509510-002 Client ID.: MW -1S Sample information... Type: Groundwater Origin: Parameters) Results ualifier D F Unft Method Number Ana ped Alkalinity, Total (As CaCO3) 36.8 1 M91L E310.1 09/20/2005 9:04 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/16/2005 2:05 PM Bromide < 0.5 1 mgfL E320.1 09/200005 2:30 PM Chloride 22.7 1 mgA. E325.2 09/192M 3:37 PM Chemical Oxygen Demand <10 1 m9/1- E410.4 0920/2005 5:45 PM Hardness (As CaCO3) 66.0 2 mg& E130.2 09/27/2005 3:15 PM Nitrogen, Ammonia (As N) 0.10 1 mg/L E350.1 09/30000512:58 PM Nitrate as N 2.63 5 mg/L E353.2 09/2120054:06 PM Phenolics, Total Recoverable < 5.0 1 WIL E420.1 09/212005 8:45 AM Sulfate 9.8 1 mgA- SW9038 09208005 2:05 PM Total Dissolved Solds 169 1 mg/L E160.1 09/19/2005 3:43 PM Nitrogen, ICeldahl, Total < 0.10 1 mg/L E351.2 0924/2005 8:17 PM Total Organic Carbon < 1.0 1 mg/L SW9060 0920/2005 8:39 PM 1 L ---A Q.IiriErs: E - Value above girentihdon range D - RewMs for Dilulion D.F. = D&Aw Factor Date Reported: 10/7/2005 Page 2 of 13 Laboratory Manager U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -3D Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL003 Matrix (soil/water): WATER Lab Sample ID: 0509510-003 Level (low/med): LOW Date Received: 9/16/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.37 U P 7440-70-2 Calcium 23800 P 7439-89-6 Iron 21.2 B P 7439-92-1 Lead 1.2 U P 7439-95-4 Magnesium 4670 B P 7439-96-5 Manganese 1 15.41 P 7440-09-7 Potassium 1530 B P 7940-23-5 Sodium 16500 P Color Before: COLORLESS Clarity Before: CLEAR Texture: • Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 9/28/05 • FORM I - IN ILM04.1 U24 LAUSO INC. 5758wadHolow Fb4 M*b N1(11747 (631)W43DV.FAX(631)42MM NYSDOHtD1t10M • Town of Southold Landfill Attn To : Collected 9/15/2005 2:45:00 PM Received 9/16/2005 9:53:00 AM Collected By CLIENT Copies To Original CC LABORATORY RESULTS Lab No.: 0509510-003 Client ID.: FLAW -31) Sample Information... Type: Groundwater Origin: Parameter(s) Resu QuaVw D.F.. Units Method NumberAnahrzed Alkalinity, Total (As CaCO3) 39.6 1 mg/L E310.1 09202005 9:19 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/162005 2:15 PM Bromide < 0.5 1 mg/L E320.1 0920/2005 2:45 PM Chloride 22.7 1 mg/L E325.2 09/19/2005 3:40 PM Chemical Oxygen Demand <10 1 mg/L E410.4 09202005 5:50 PM Hardness (As CaCO3) 70.0 2 mg1L E130.2 09272005 3:30 PM Nitrogen, Ammonia (As N) 0.11 1 mg/L E350.1 09/3020051:00 PM Nitrate as N 3.27 5 mg/l. E353.2 09212005 4:08 PM Phenolics, Total Recoverable < 5.0 1 Wt. E420.1 09212005 9:00 AM Sulfate 10.3 1 m90L SW9038 09202005 2:11 PM Total Dissolved Solids 191 1 mg/L E160.1 09/192005 3:46 PM Nitrogen, ICiekdahl, Total < 0.10 1 mg/L E351.2 09242005 8:19 PM Total Organic Carbon < 1.0 1 m91L SW9060 0920200510,06 PM • Qua6& fs: E - Value above quarrtitotion range D - Pmub for Dkdion D.F. = Dkilon Factor Date Reported : 10!7/2005 Page 3 of 13 �� )ho-e;d�- � Laboratory Manager U.S. EPA CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -3S Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL003 Matrix (soil/water): WATER Lab Sample ID: 0509510-004 Level (low/med): LOW Date Received: 9/16/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.37 U P 7440-70-2 Calcium 22100 P 7439-89-6 Iron 24.2 B P 7439-92-1 Lead 1.2 U P 7439-95-4 Ma nesium 4300 BI P 7439-96-5 Manganese 14.7 B I P 7440-09-7 Potassium 1320 B P 7440-23-5 Sodium 15000 P Color Before: COLORLESS Clarity Before: CLEAR Texture: • Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 9/28/05 • FORM I - IN ILM04.1 U 2M IMUS, INC. 575BMWHIM taped, M&b W 11747 06943040. FAX (Gi1)4W8M NYSDOH D1110478 •Town of Southold Landfill Attn To Collected 9/158005 2:20:00 PM Received 9/16!2005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameterts) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, lgekdahl, Total Total Organic Carbon • LABORATORY RESULTS Lab No. : 0509510-004 Client ID.: MW -3S Sample Information... Type : Groundwater Results Quafift D.F.n� Method Number Anglyed 44.2 1 mg& E310.1 09808005 9:24 AM < 2 1 m91L E405.1 09(168005 220 PM 1.2 1 mg/L E320.1 09420(2005 2:50 PM 22.3 1 mg/L E325.2 09/198005 3:41 PM 14.3 1 mg& E410.4 09802005 5:51 PM 72.0 2 mg/L E1302 098MM 3:35 PM < 0.10 1 mg/L E350.1 09!30420051:01 PM 3.31 5 mg/L E3532 09(218005 4:08 PM < 5.0 1 W& E4M 1 09218005 9:15 AM 11.0 1 mg/L SW9036 094202005 2:13 PM 170 1 mg/L E160.1 09/192005 3:47 PM < 0.10 1 mg/L E351.2 09848005 8:20 PM < 1.0 1 mg/L SW9060 09420/200510:36 PM • Qualiftm: E - Value above quantitation rarpe D - Results for Didion D -F. = Dk*m Factor Date Reported : 10/78005 Page 4 of 13 ��/h Laboratory Manager • U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -4D Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL003 Matrix (soil/water): WATER Lab Sample ID: 0509510-005 Level (low/med): LOW Date Received: 9/16/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.37 U P 7440-70-2 Calcium 24100 P 7439-89-6 Iron 16.1 B P 7439-92-1 Lead 1.2 U P 7439-95-4 Magnesium 4700 B P 7439-96-5 Manganese 14.8 B P 7440-09-7 jPotassium 1770 B P 7440-23-5 ISodium 16800 P Color Before: COLORLESS Clarity Before: • Color After: COLORLESS Clarity After: Comments: Date Reported: 9/28/05 • CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 H2M tALS, INC. 575BroadFbl w RD4 RkMb W 11747 (6; i1)6943090.FAX WM420. M NYSD(* D#10418 • Town of Southold landfill Attn To : Collected 9/15/200512:40:00 PM Received 9/162005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameter(s) Alkalinity, Total (As CaCO3) Biochemical Oxygen Demand Bromide Chloride Chemical Oxygen Demand Hardness (As CaCO3) Nitrogen, Ammonia (As N) Nitrate as N Phenolics, Total Recoverable Sulfate Total Dissolved Solids Nitrogen, Kjeldahl, Total Total Organic Carbon • Qua116Ms: E - Value above quantitation. w •D - Reauft for Dikkon D.F. = Dilution Factor Date Reported: 10/712005 LABORATORY RESULTS Lab No.: 0509510-005 Client ID.: MW41) Sample Information... Type : Groundwater Origin: Results Qualifier D.F.. Urtits Method Number l� 42.4 1 mglL E310.1 09202005 9:29 AM < 2 1 mg/L E405.1 09(162005 2:25 PM < 0.5 1 m91L E320.1 09202005 2:55 PM 23.0 1 mg/L E325.2 09/1912005 3:42 PM <10 1 mg/L E410.4 092012005 5:52 PM 72.0 2 mg/L E130.2 09/2712005 3:40 PM _ 0.14 1 mg/L E350.1 09/3020051:02 PM 3.15 5 mg/L E353.2 09212005 4-09 PM < 5.0 1 WIL E420.1 0921!2005 9M AM 11.5 1 M94- Sw9038 09802006 215 PM 177 1 mg/L E160.1 091192005 3:48 PM < 0.10 1 mg/L E351.2 092412005 8:37 PM < 1.0 1 mg/L SW9060 0920200511:06 PM Page 5 of 13 Laboratory Manager O� N C/o Cn 0 Cn F -t U.S. EPA - CLP . 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER Level (low/med): LOW % Solids: 0.0 MW -4S Contract: SAS No.: SDG No.: TSL003 Lab Sample ID: 0509510-006 Date Received: 9/16/2005 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.37 U P 7440-70-2 Calcium 22700 P 7439-89-6 Iron 34.8 B P 7439-92-1 Lead 1.2 U1 P 7439-95-4 Magnesium 4400 B P 7439-96-5 Manganese 16.0 P 7440-09-7 jPotassium 1630 B P 7440-23-5 ISodium 15400 P Color Before: COLORLESS Clarity Before: • Color After: COLORLESS Clarity After: Comments: Date Reported: 9/28/05 • CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 1-12M tAIBS, INC. 575BtoedHdow Roel MA& NY 11747 (631)89CMV.FAX(631)QD8436 WSMHD910478 LABORATORY RESULTS Sample Information. -Tom of Southold Landfill Lab No. : 0509510-006 Type: Groundwater Origin: Attn To Client ID.: MW -4S Collected 9/ 15!200512:10:00 PM Received 9/162005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameter(s) Results Qualifier D.F.. Units Method Number A a M Alkalinity, Total (As CaCO3) 37.8 1 mg/L E310.1 09202005 9:34 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 091162005 2:30 PM Bromide 1.2 1 mgA. E320.1 09202005 3:00 PM Chloride 22.5 1 mg/L E325.2 09/1912005 3:42 PM Chemical Oxygen Demand < 10 1 mg/L E410.4 09202005 5:53 PM Hardness (As CaCO3) 72.0 2 mgA. E130.2 09272005 3:45 PM Nitrogen, Ammonia (As N) 0.14 1 mg/L E350.1 09/3020051:02 PM Nitrate as N 3.41 5 mg/L E353.2 09212005 4:10 PM Phenolics. Total Recoverable < 5.0 1 WIL E420.1 09021QD05 9:45 AM Sulfate 11.0 1 mg& SW9038 09202005 217 PM Total Dissolved Solids . 181 1 mgA. E160.1 09/192005 3:49 PM Nitrogen, ICeklah 1. Total < 0.10 1 mg/L E351.2 09242005 8:38 PM Total Organic Carton < 1.0 1 mg/L SW9060 09120200511:35 PM • Oualfierw. E - Value above quantitation range D - Resub for DAution D.F. = Dilution Factor Date Reported : 10!72005 Page 6 of 13 .0 Laboratory Manager U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -SD Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL003 Matrix (soil/water): WATER Lab Sample ID: 0509510-007 Level (low/med): LOW Date Received: 9/16/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.37 U P 7440-70-2 Calcium 21700 P 7439-89-6 Iron 24.1 B P 7439-92-1 ILead 1.2 U P 7439-95-4 Oagnesium 4810 B P 7439-96-5 anese .). bj B P 7440-09-7 Potassium 6620 P 7440-23-5 Sodium 15900 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Wolor After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 9/28/05 • FORM I - IN ILM04.1 IN2M t lBso INC. 5MBioedl-l*w Raadt Melwb NY 11747 LABORATORY RESULTS (631)W4aW.FAX(631)Q(Xl 6 WSDOHDft10478 Sample Information... #own of Southold Landfill Lab No. : 0509510-007 Type : Groundwater Origin: To Client ID.: MW51) Collected 9115/200511:20:00 AM Received 9/162005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameter(s) Results uaVw D.F.. Unci Method Number AnaryM Alkalinity, Total (As CaCO3) 37.6 1 mg1L E310.1 09202005 9:39 AM Biochemical Oxygen Demand 28 1 MA E405.1 09/162005 2:35 PM Bromide < 0.5 1 mg1L E320.1 09202005 3:05 PM Chloride 23.7 1 mg1L E325.2 09/192005 3:43 PM Chemical Oxygen Demand 39.3 1 m91L E410.4 09202005 5:54 PM Hardness (As CaCO3) 70.0 2 mg& E130.2 0927/2005 3:50 PM Nitrogen, Ammonia (As N) < 0.10 1 mgll. E350.1 09/3020051:03 PM Nitrate as N 2.70 5 mg1L E353.2 091212005 4:10 PM Phenolics, Total Recoverable < 5.0 1 W& E420.1 09129/200510.00 AM Sulfate 20.8 1 mg/L SW9038 091202005 219 PM Total Dissolved Solids 413 1 m90L E160.1 09/192005 3:50 PM Nitrogen, ICeldahl, Total 0.34 1 mg1L E351.2 09242005 8:40 PM Total Organic Carbon < 1.0 1 mglL SW9060 0921200512:05 AM Qualifiers: E - Vatua above quantitation rarpe • D - ResWa for Dhdion D.F.= Dilution Factor Date Reported: 10!72005 Page 7 of 13 Laboratory Manager U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -5S Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL003 Matrix (soil/water): WATER Lab Sample ID: 0509510-008 Level (low/med): LOW Date Received: 9/16/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.37 U P 7440-70-2 Calcium 22700 P 7439-89-6 Iron 18.3 B P 7439-92-1 ILead 1.2 U P 7439-95-4esium 4690 BI P 7439-96-5 Otanganese 4 P 7440-09-7 Potassium 1430 B P 7440-23-5 Sodium 16400 P Color Before: COLORLESS Clarity Before: OColor After: COLORLESS Clarity After: Comments: Date Reported: 9/28/05 • CLEAR Texture: CLEAR Artifacts: FORM I - IN ILM04.1 d' M M O Cn H U2M TAUS, INC. 575BMWHobv Road, M&* NY 11747 LABORATORY RESULTS (831)694W.FAX (631)4208436 NYSDOH D# 10478 Sample Information... •Town of Southold Landfill Lab No. : 0509510-008 Type : Groundwater Attn To Origin: Client ID.: MW -5S Collected 9/15/200510:50:00 AM Received 9/18/2005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameter(s) Results Qualifier D.F. Units Method Number Analyzed Akahnity, Total (As CaCO3) 39.9 1 m91L E310.1 09/20/2005 9:54 AM Biochemical Oxygen Demand < 2 1 mg& E405.1 09/16!2005 2:40 PM Bromide < 0.5 1 mg/L E320.1 09/20/2005 3:10 PM Chloride 22.7 1 mg/L E325.2 09/19/2005 3:44 PM Chemical Oxygen Demand 34.3 1 mg& E410.4 09/20/2005 5:55 PM Hardness (As CaCO3) 72.0 2 mg/L E130.2 09/27/2005 3:55 PM Nitrogen, Ammonia (As N) 0.42 1 mg/L E350.1 09/30/20051:04 PM Nitrate as N 2.70 5 mg/L E353.2 09/21/2005 4:11 PM Phenolics, Total Recoverable < 5.0 1 Ig& E420.1 09121/200510-1S AM Sulfate 10.4 1 mg/L SW9038 09!20/2005 2:21 PM Total Dissolved Solids 181 1 mg/L E160.1 09/19/2005 3:51 PM Nitrogen, Kjeldahl, Total < 0.10 1 mglL E351.2 09/24/2005 8:40 PM Total Organic Carbon < 1.0 1 mg/L SW9060 09/21/2005 12:34 AM Duafi iers: E - Value above quoi talion range • D - Results for Diution D.F_ = Dilution► Factor Date Reported: 10!7/2005 Page 8 of 13 Laboratory Manager U.S. EPA - CLP • Analyte 1 EPA SAMPLE NO M INORGANIC ANALYSIS DATA SHEET 0.37 U1 P 7440-70-2 Calcium 22500 �6D Lab Name: H2M LABS, INC. Contract: 43.2 B P Lab Code: 10478 Case No. SAS No.: SDG No.: TSL003 Matrix (soil/water): WATER Lab Sample ID: 0509510-009 Level (low/med): LOW Date Received: 9/16/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.37 U1 P 7440-70-2 Calcium 22500 P 7439-89-6 Iron 43.2 B P 7439-92-1 ILead 1.2 U P 7439-95-9 IMagnesium 4510;B P 7439-96-5 Manganese 6.2 B P 7440-09-7 Potassium 1330 B P 7440-23-5 Sodium 15300 P Color Before: COLORLESS Clarity Before: CLEAR Texture: • Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 9/28/05 • FORM I - IN ILM04.1 H2M lA US, INC. 5758 WH*W Road, Mririe W 11747 LABORATORY RESULTS (M1)694 3M.FAX (631)4208436 NYSDDHD# 10M Sample Information... •Town of Southold Landfill Lab No. : 0509510-009 Type: Groundwater Origin: Attn To Client ID.: MW -61) Collected 9/16/2005 7:30:00 AM Received 9/16/2005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameter(s) Resu Qual D.F.nl k Method NumberAnahrzed Alkalinity, Total (As CaCO3) 37.9 1 mg/L E310.1 09202005 9:59 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/162005 2:45 PM Bromide < 0.5 1 mg/L E320.1 09202005 3:15 PM Chloride 22.3 1 mg/L E325.2 09/192005 3:44 PM Chemical Oxygen Demand 162 1 mg/L E410.4 09202005 5:56 PM Hardness (As CaCO3) 68.0 2 mg/L E130.2 091272005 4:10 PM Nitrogen, Ammonia (As N) 0.15 1 mg/L E350.1 09/3020051:06 PM Nitrate as N 2.79 5 mg/L E353.2 09212005 4:13 PM Phenolics, Total Recoverable < 5.0 1 yg/L E420.1 09/21200510:30 AM Sulfate 10.4 1 mg/L SW9038 0920/2005 2:23 PM Total Dissolved Solids 174 1 mg/L E160.1 09/192005 3:54 PM Nitrogen, Kjeldahl, Total < 0.10 1 m9/L E351.2 09242005 8:41 PM Total Organic Carbon 40.9 1 m91L SW9060 092120051:58 AM r �i 0 Qualifiers: E - V" above quarvIdMion range D - Resut s for Dik ion D.F. = Dkition Factor Date Reported: 10/72005 Page 9 of 13 Laboratory Manager U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -6S Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL003 Matrix (soil/water): WATER Lab Sample ID: 0509510-010 Level (low/med): LOW Date Received: 9/16/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.37 U P 7440-70-2 Calcium 21100 P 7439-89-6 Iron 18.1 B P 7439-92-1 Lead 1.2 U P 7439-95-4 Magnesium 4290 B P 7439-96-5 iManganese 3.W B! P , 7440-09-7 Potassium 12301 B I I P 7440-23-5 Sodium 144001 1P Color Before: COLORLESS Clarity Before: CLEAR Texture: • Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 9/28/05 00 M • M O FORM I - IN ILM04.1 H2M LABS, INCe 5750ioedMw Rosi, NK& NY 11747 (531)694.9040. FAX (631)4208436 NYSDOH Dif 10418 . Town of Southold Landfill Attn To : Collected 9116/2005 8:00:00 AM Received 9/162005 9:53:00 AM Collected By CLIENT Copies To Original CC LABORATORY RESULTS Lab No. : 0509510-010 Client ID.: MW/ -6S Sample Information... Type : Groundwater Origin: Parameters) Results Qualifier IAF Units Method Number Mahrzed Alkalinity, Total (As CaCO3) 40.3 1 mg/L E310.1 0920800510:04 AM Biochemical Oxygen Demand < 2 1 m91L E405.1 09/16r2005 2:50 PM Bromide 0.6 1 mg/L E320.1 098012005 3:20 PM Chloride 22.5 1 m91L E325.2 09/192005 3:45 PM Chemical Oxygen Demand 19.3 1 m94- E410.4 09202005 5:57 PM Hardness (As CaCO3) 70.0 2 mg& E130.2 09272005 4:15 PM Nitrogen, Ammonia (As N) 0.23 1 m91L E350.1 09/308005 1:06 PM Nitrate as N 2.70 5 mg/L E353.2 09212005 4:14 PM Phenolics, Total Recoverable < 5.0 1 yg1L E420.1 09212005 10-45 AM Sulfate 10.5 1 mg/L SW9038 09802005 2:25 PM Total Dissolved Solids 174 1 mg/L E160.1 09/198005 3:55 PM Nitrogen, Kjeldahl, Total < 0.10 1 mg/L E351.2 09248005 8:42 PM Total Organic Carbon < 1.0 1 mg/L SW9060 09212005 2:28 AM 1r u Qualifiers: E - Value above querMation rarpe • D - Results for Dkdion D.F. = Dilution Fads Date Reported: 10(72005 Page 10 of 13 � )h . . Laboratory Manager U.S. EPA - CLP • 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.37 U P 7440-70-2 Calcium 23400 P 7439-89-6 Iron 14.3 B P 7439-92-1 jLead 1.2 U P 7439-95-9 IMagnesium 4510 B P 7439-96-5 Manganese 11.3 B P ' 7490-09-7 Potassium 1320 B P 7940-23-5 Sodium 15000 P EPA SAMPLE NO MW -8D SDG No.: TSL003 9/16/2005 •Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 9/28/05 • FORM I - IN ILM04.1 UZ14 tAlBso INC. W50f WHolow Hoed Mit& NY 11747 LABORATORY RESULTS (631)64.WV.FA>CW4 D8M WSDOHD#10418 Sampo Information... Town of Southold Landfill Lab No. : 0509510-011 Type: Groundwater Attn To : Origin: Client ID.: MW -8D Collected 9/1520051:55:00 PM Received 4116!2005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameter($) Results Qualifier D -F. Units Method Number Ani Akak*y, Total (As CaCO3) 40.2 1 mg/L E310.1 09202005 10:09 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/162005 2:55 PM Bromide 0.6 1 mg/L E320.1 09202005 3:25 PM Chloride 22.6 1 mg/L E325.2 09/192005 3:46 PM Chemical Oxygen Demand 51.8 1 m91L E410.4 0920/2005 5:58 PM Hardness (As CaCO3) 70.0 2 mg/L E130.2 09272005 4:20 PM Nitrogen, Ammonia (As N) 0.14 1 mg/L E350.1 09/302005 1:07 PM Nitrate as N 3.12 5 mg/L E353.2 09212005 4:14 PM Plrcnoics, Total RecWm able < 5.0 1 I91L E420.1 0921200511:00 AM Sulfate 11.1 1 mg/L SW9038 09202005 2:27 PM Total Dissolved Solids 192 1 mg/L E160.1 09/192005 3:56 PM Nitrogen, Kjeldahl, Total < 0.10 1 mg/L E351.2 09242005 8:42 PM Total Organic Carbon < 1.0 1 mg& SW9060 09212005 3:01 AM r �i • Quat flew. E - Value above gwnt"ion range D - ReaRs for Dikkon D.F. = Dilution Factor Date Reported: 10f72005 Page 11 of 13 �� �;(,-00,�- Laboratory Manager U.S. EPA - CLP is 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER Level (low/med): LOW % Solids: 0.0 MW -8S Contract: SAS No.: SDG No.: TSL003 Lab Sample ID: 0509510-012 Date Received: 9/16/2005 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.37 U P 7440-70-2 Calcium 24200 P 7439-89-6 Iron 15.9 B P 7439-92-1Lead 1.2 U P 7439-95-9 Ma nesium 4740 B P 7439-96-5 'Manganese 9.2: B P 7440-09-7 Potassium 1390 B P 7440-23-5 Sodium 15700 P Color Before: COLORLESS Clarity Before: CLEAR Texture: • Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 9/28/05 U FORM I - IN ILM04.1 FVA tAI3S, INC. 575BwedHdk w FID4 Mdiie W 11747 LABORATORY RESULTS 9M)W44XW.FAX9MaW 36WYSDOHD/f10478 Sample Information... 0ow" of Southold Landfill Lab No. : 0509510-012 Type: Groundwater Origin: Attn To Client ID.: MW -8S Collected 9!15/20051:20:00 PM Received 9/16/2005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameters) ResultsuQ alifier D.F.. Units Method Number Anahme6 AtkW ty, Total (As CaCO3) 38.6 1 mg/L E310.1 09120/200510:14 AM Biochemical Oxygen Demand < 2 1 mg/L E405.1 09/162005 3:00 PM Bromide 0.7 1 mg/L E320.1 09/202005 3:30 PM Chloride 22.5 1 mg/L E325.2 09/192005 3:46 PM Chemical Oxygen Demand 41.8 1 mg/L E410.4 09202005 6:01 PM Hardness (As CaCO3) 70.0 2 mg/L E130.2 09/272005 4:25 PM Nitrogen, Ammonia (As N) 0.10 1 mg/L E350.1 09/3020051:08 PM Nitrate as N 2.85 5 mg/L E353.2 09212005 4:15 PM Phenoics, Total Recoverable < 5.0 1 lJWL E420.1 09212005 11:15 AM Sulfate 122 1 mg/L SW9038 09200005 2:29 PM Total Dissolved Solids 180 1 mg/L E160.1 09/192005 3:57 PM Nitrogen, Kpklahl, Total < 0.10 1 mg/L E351.2 09242005 8:43 PM Total Organic Carbon < 1.0 1 mg/L SW9060 09212005 3:30 AM r �J Qualifiers: E - V" above quan0lation range D - RewAs for Dikdion D.F. = Dtkrkn Factor Date Reported: 10!72005 Page 12 of 13 Laboratory Manager U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET EQPT BLANK 9/16 Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL003 Matrix (soil/water): WATER Lab Sample ID: 0509510-013 Level (low/med)• LOW Date Received: 9/16/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.37 U P 7440-70-2 Calcium 141 BI P 7439-89-6 Iron 6.3 U P 7439-92-1 Lead 1.2 U P 7439-95-4 Magnesium 11.6 U1 P 7439-96-5 Manganese 2.1 U' P 7440-09-7 Potassium 32.3 B P 7440-23-5 Sodium 284 B P Color Before: COLORLESS Clarity Before: CLEAR Texture: . Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 9/28/05 Z' • M O 07 FORM I - IN ILM04.1 UZA L USO INC. 575BroedHdlwv R04 M&& W 11747 (631)6943D90.FWC (631)4208436 WSDOHDi10478 • Town of Southold Landfill AMn To : LABORATORY RESULTS Lab No.: 0509510-013 Client ID.: EQPT BLANK 9/16 Sample Information... Type : Blank Origin: Collected 9/162005 6:30:00 AM Received 9/1612005 9:53:00 AM Collected By CLIENT Copies To Original CC Parameter(s) ResultsaQu rfier D.F.. Units Method Number Ani Alkalinity, Total (As CaCO3) < 1.0 1 mg/L E310.1 09/202005 10:19 AM Biochemical Oxygen Demand <2 1 mg/L E405.1 09/1612005 3:05 PM Bromide 0.6 1 mg/L E320.1 09202005 3:35 PM Chloride < 2.0 1 mg/L E325.2 09/192005 3:48 PM Chemical Oxygen Demand < 10 1 mg/L E410.4 0920/2005 6:02 PM Hardness (As CaCO3) < 5.0 1 mg/L E130.2 09272005 4:30 PM Nitrogen, Ammonia (As N) 0.11 1 mg/L E350.1 0913020051:08 PM Nitrate as N < 0.10 1 mg/L E353.2 0921QW5 4:16 PM Phenolics. Total Recoverable < 5.0 1 P90L E420.1 091'21200511:30 AM Sulfate < 5.0 1 m9/L SW9038 0920r2005 2-31 PM Total Dissolved Solids 19 1 ng/L E160.1 09/190005 3:58 PM Nitrogen, Kjeldahl, Total < 0.10 1 mg/L E351.2 09/242005 8:27 PM Total Organic Carbon < 1.0 1 mglL SW9060 09/212005 4:00 AM i • Quaf iers: E - V". above quantitation carpe D - Resub for Dikkon D.F. = Didion Factor Date Reported: 10/7/2005 Page 13 of 13 A - Laboratory Manager Un M E—� U2M "US, INC. E 5. DUPLICATE SAMPLE RESULTS 5.1 METALS 5.2 WET CHEMISTRY • 110 Nt cn M O H • • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER % Solids for Sample: 0.0 U.S. EPA - CLP 6 EPA SAMPLE NO DUPLICATES MW -1S Contract: SAS No.: SDG No.: TSL003 Level (low/med): LOW % Solids for Duplicate: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L Analyte Control Limit Sample (S) C Duplicate (D) C RPD Q M Cadmium 5.0000 0.5900 B 0.3655 U 200.0 P Calcium 5000.0000 22465.7800 21673.2000 3.6 P Iron 100.0000 45.9300 B 40.5400 B 12.5 1P Lead 1.1592 U11 1.1592 U P Magnesium 5000.0000 4698.8300 B 4523.6800 B 3.8 P Manganese 15.0000 7.9200 B 7.8000 B 1.5 P Potassium 5000.0000 1532.9900 B 1481.5300 B 3.4 P Sodium 5000.0000 16926.0400 16106.6700 5.0 P • FORM VI - IN ILM04.1 • H2M LABS, INC. SDG: TSL003 Date: 07 -Oct -05 QC SUMMARY REPORT Spike Sample Recovery RPDRet %RPD Sample ID• Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL M8492005 MEI -092005 Alkalinity, Total (As CaCO3) < 1 mg/L LCS-853365 LCS-092005 LCS-092005 Alkalinity, Total (As CaCO3) 21.8 mgJL 25 < 5 87 80 120 0509510.002dm3 MAWS Alkalinity, Total (As C&CO3) 63.0 mg/L 25 36.8 105 75 125 0509510.002ddup MWASDUP Alkalinity, Total (As CaCO3) 36.5 rnyL 36.8 0.82 20 g/L. . MB -1153365 Bromide < 0.5 mg/L LCS-853365 LCS-853365 Bromide p/L 200 <2 102 80 120 nv/L 5 <0.5 90 75 125 0509510-00213dup yL Bromide < 0.5 mit < 0.5 20 <2 20 MS -R53365 MB -1153365 Bromide < 0.5 mg/L LCS-853365 LCS-853365 Bromide 5.4 mg/L 5 < 0.5 108 80 120 0509510-002DMS MW -ISMS Bromide 4.5 nv/L 5 <0.5 90 75 125 0509510-00213dup MW-1SDUP Bromide < 0.5 mit < 0.5 20 MS -092005 MS -092005 Chemical Oxygen Demand < 10 mg/L LCS-092005 LCS-092005 Chemical Oxygen Demand 1020 mg/L 1000 < 10 102 80 120 0509510-002bms MWASMS Chemical Oxygen Demand 1030 mg/L 1000 < 10 103 75 125 0509510-002bdup MWASDUP Chemical Oxygen Demand <10 mg/L <10 20 MBI -091905 MBI -091905 Chloride < 2 mg/L LCS1-091905 LCS1-091905 Chloride 50.2 mg/L 50 < 2 100 80 120 0509510-002DMS MWASMS Chloride 49.0 mWL 25 22.7 105 75 125 0509510-002DDUP MWASDUP Chloride 22.7 mg/L 22.7 0 20 MS -092705 MB -092705 Hardness (As C&CO3) < 5 mg/l. LCS-092705 LCS-092705 Hardness (As CaCO3) 1040 mg/l. 1000 < 5 104 80 120 0509510-002cros MAWS Hardness (As CaCO3) 276 mg/t. 200 66.0 105 75 125 0509510.002odup MWASDUP Hardness (As CaCO3) 66.0 m91L 66.0 0 20 1 TSL003 S48 • • • QC SUMMARY REPORT SDG: TSL003 Spike Sample Reoovery RPDRef %RPD Sample ID• Client Sample ID: Analyte Result Units Amount Result %REC Umib value %RPD UCL mb-092105 mb-092105 Nitrate as N < 0.1 MOIL Ica -092105 Ica -092105 Nitrate as N 1.10 mOIL 1.13 <0.1 97 80 120 0509510-002SMS MWASMS Nitrate as N 5.03 mg/L 2.5 2.63 96 75 125 0509510.002BDUP MW -1 SDUP Nitrate as N 2.65 mplL 2.63 0.80 20 MB -14934 MS -093005 Nitrogen, Ammonia (As N) < 0.1 mg/L LCS-14934 LCS-093005 Nitrogen, Ammonia (As N) 1.03 Vt. 1 < 0.1 103 80 120 0509510-002SMS MWASMS Nitrogen, Ammonia (As N) 5.55 r►gil 5 0.10 109 75 125 0509510-002BOUP MW-1SDUP Nitrogen, Ammonia (As N) 0.11 mg/L 0.10 13.1 20 mb-14877 mb492405 Nitrogen, Kjeldahl, Total < 0.1 MOIL Ics-14877 1a-092405 Nitrogen, Kjeldahl, Total 3.96 4.1 < 0.1 97 80 120 0509510-002BMS MW -ISMS Nitrogen, Kjeldahl, Total 3.96 mall 4.1 < 0.1 97 75 125 0509510-002BDUP MW-1SDUP Nitrogen, Kjeldahl, Total < 0.1 mOIl < 0.1 20 MB -092105 MB -092105 Phenolics, Total Recoverable < 5 ug/L LCS-092105 LCS-092105 Phenolics, Total Recoverable 27.7 uOIL 30 < 5 92 80 120 0509510.002bms MWASMS Phenolics, Total Recoverable 18.8 uyL 20 < 5 94 75 125 0509510-002bdup MW -1 SDUP Phenolics, Total Recoverable < 5 uOIl < 5 20 MS -092005 MB -092005 Sulfate <5 M9iL LCS-092005 LCS-092005 Sulfate 19.0 mg/l. 20 < 5 95 80 120 0509510-002DMS MWASMS Sulfate _ 29.5 mg/L 20 9.8 98 75 125 0509510-002Ddup MW-1SDUP Sulfate 10.1 M91L 9.8 3.0 20 MB -091905 MS -091905 Total Dissolved Solids <10 mg/L LCS-091905 LCS-091905 Total Dissolved Solids 344 mg/L 300 <10 115 80 120 0509510.002dms MWASMS Total Dissolved Solids 529 mg/L 300 169 120 75 125 0509510-002ddup MWASDUP Total Dissolved Solids 207 MOIL 169 20.2 20 2 TSL003 S49 • • • QC SUMMARY REPORT SDG: TSL003 spike Sample R000my RPDRef %RPD Sample ID: Client Sample ID: Analyte Result UnMa _Amount Result %REC Umib Value %RPD UCL -092005 MB -092005 Total Organic Carbon 5492005 LCS-092005 Total Organic Carbon 27.7 "*/L 25 < 1 111 80 120 19510-002AMS MW -ISMS Total Organic Carbon 10.8 mA 10 < 1 108 75 125 19510.002ADUP MW-1SDUP Total Organic Carbon _ < 1 mgrL < 1 3 TSL003 S50 U2M "US, INC. n u 6. SPIKE SAMPLE RESULTS 6.1 METALS 6.2 WET CHEMISTRY • • C7 • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER % Solids for Sample: 0.0 U.S. EPA - CLP 5A SPIKE SAMPLE RECOVERY Contract: SAS No.: EPA SAMPLE NO MW-1sS SDG No.: TSL003 Level (low/med): LOW Concentration Units (ug/L or mg/kg dry weight): UG/L Analyte Control Limit %R Spiked Sample Result (SSR) C Sample Result (SR) C Spike Added (SA) $R Q M Cadmium 75-125 49.9500 0.5900 B 50.00 98.7 P Iron 75-125 992.5700 45.9300 B 1000.00 94.7 P Lead 75-125 19.6078 1.1592 U 20.00 98.0 P Man anese 1 75-125 513.6300 7.9200':B 500.00 101.11 P! Comments: • FORM V (Part 1) - IN N M ILM04.1 0 C/� H2M LABS, INC. Date: 07 -oar -05 QC SUMMARY REPORT SDG: TSL003 Spike sample Rowvwy RPDRer %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Umib Value %RPD UCL MS -092005 MS -092005 Alkalinity, Total (As CaCO3) < 1 LCS-092005 LCS-092005 Alkalinity, Total (As CaCO3) 21.8 0509510-002dms MWASMS Alkalinity, Total (As CaCO3)_ _ 63.0 0509510.002ddup MWASDUP Alkalinity, Total (As CaCO3) 36.5 MS -091605 MB -091605 Biochemical Oxygen Demand < 2 melt 25 < 5 87 80 120 204 MOIL 200 < 2 -L-11021 80 11201 25 36.8 105 75 125 < 2 mQVL I I I I < 2 20 0509510-002Ddup MWASDUP 36.8 0.82 20 MS -091605 MB -091605 Biochemical Oxygen Demand < 2 melt LCS-091605 LCS-091605 Biochemical Oxygen Demand 204 MOIL 200 < 2 -L-11021 80 11201 0509510-002ddup MWASDUP Biochemical Oxygen Demand < 2 mQVL I I I I < 2 20 MS-RS3365 MS -R53365 Bromide < 0.5 MOIL LCS-853365 LCS-853365 Bromide 5.4 mOIL 5 < 0.5 108 80 120 0509510-002DMS MWASMS Bromide 4.5 mOIL 5 <0.5 90 75 125 0509510-002Ddup MWASDUP Bromide < 0.5 mOIL < 0.5 20 MB -092005 MS -092005 Chemical Oxygen Demand <10 MOIL LCS-092005 LCS-092005 Chemical Oxygen Demand 1020 mOIL 1000 < 10 102 80 120 0509510-002bms MW -ISMS Chemical Oxygen Demand 1030 ­mg/L- 1000 < 16 103 75 125 0509510-0021)dup MW -1 SDUP Chemical Oxygen Demand <10 mal- <10 20 MB1-091905 MBI -091905 Chloride <2 mp/L LCS1-091905 LCS1-091905 Chloride 50.2 mp/L 50 <2 100 80 120 0509510.002DMS MWASMS Chloride 49.0 mgt 25 22.7 105 75 125 OW9510-002DDUP MWASDUP Chloride 22.7 mg/L. 22.7 0 20 MS -092705 MB -092705 Hardness (As C&CO3) < g mg/L LCS-092705 LCS-092705 Hardness (As CaCO3) 1040 mOIL 1000 < 5 104 80 120 0509510-002ems MW -ISMS Hardness (As CaCO3) 276 mOIL 200 66.0 105 75 125 0509510-002cdup MW-1SDUP Hardness (As CaCO3) 66.0 MOIL. 66.0 0 20 1 TSL003 S53 • QC SUMMARY REPORT SDG: TSL003 Spike Sample Recovery RPDRer %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Umits Value %RPD UCL mb-092105 mb-092105 Nitrate as N < 0.1 mWL Ice -092105 ics-092105 Nitrate as N 1.10 MOIL 5509510.002SMS MWASMS Nitrate as N 5.03 myL 0509510-002BDUP MW-1SDUP Nitrate as N _ 2.65 myL MB -14934 MS -093005 Nitrogen, Ammonia (As N) < 0.1 LCS-14934 LCS-093005 Nitrogen, Ammonia (As N) 1.03 0509510-002BMS MWASMS Nitrogen, Ammonia (As N) 5.55 0509510-002BDUP MWASDUP Nitrogen, Ammonia (As N) 0.11 n ._ 1.13 mb-092405 < 0.1 97 80 120 2.5 2.63 96 75 125 Ica -14877 2.63 0.80 20 mb-14877 mb-092405 1 < 0.1 103 80 120 < 0.1 _ 5 0.10 109 75 125 Ica -14877 0.10 13.1 20 mb-14877 mb-092405 Nitrogen, Kjeldahl, Total < 0.1 mWL Ica -14877 ics-092405 Nitrogen, Kjeldahl, Total _ 3.96 M WL 4.1 < 0.1 97 80 120 0509510-002SMS MWASMS Nitrogen, Kjeldahl, Total 3.96 WWC 4.1 < 0.1 97 75 125 0509510-002BDUP MWASDUP Nitrogen, Kjeldahl, Total < 0.1 mWL < 0.1 20 MB -092105 MS -092105 Phenolics, Total Recoverable < 5 udL LCS-092105 LCS-092105 Phenolics, Total Recoverable 27.7 uWL 30 < 5 92 80 120 0509510-002bms MW -ISMS Phenolics, Total Recoverable 18.8 uWL 20 < 5 94 75 125 0509510-002bdup MW-1SDUP Phenolics, Total Recoverable < 5 uWL < 5 20 MS -092005 LCS-092005 192005 Sulfate < 5 mWL 092005 Sulfate 19.0 mWL ISMS Sulfate 29.5 _ RqK 1SDUP Sulfate 10.1 mplL TSL003 S54 _-_mm__m L L 300 <10 115 80 120 L 300 169 120 75 125 L 169 20.2 20 2 L L 300 <10 115 80 120 L 300 169 120 75 125 L 169 20.2 20 2 QC SUMMARY REPORT SDG: TSL003 Sample ID: Client Sample ID• Analyte Result Units Spike Amount Sample Recovery RPDRef %RPD Result %REC Umlb Value %RPD UCL M"92005 MB -092005 Total Organic Carbon LCS-092005 LCS-092005 Total Organic Carbon E27.7 25 <1 111 80 120 0509510-002AMS MWASMS Total Organle Carbon _ 10.8 0509510-002ADUP MW-1SDUP Total Organic Carbon _ _ < 1 � 10 < 1 108 75 125 ngil < 1 20 3 TSL003 S55 U2M I -AUS, INC. 0 7. BLANK SUMMARY DATA AND RESULTS 7.1 METALS 7.2 WET CHEMISTRY • • C J U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L SDG No.: TSL003 Analyte Initial Calib. Blank (ug/L) C Continuing Blank 1 C Calibration (ug/L) 2 C 3 C; i Prepa- ration Blank C I M Cadmium 0.5 BI 0.4 BI 0.6 BI 0.4 U 1 0.365 U11 P Calcium 41.2 B 54.7 BI 51.0 B 36.4 B 18.022 U P Iron 8.4 B 12.6 BI 9.4 B 6.3 U 6.302 U P Lead 1.2 U 1.2 U 1.2 U 1.2 U 1.159 U P Magnesium 11.6 U 18.4 B 11.6 U 11.6 U 11.554 U P Manganese 2.11U 2.1 U 2.1 U 2.1 U 2.111 U P Potassium 70.4 B 65.5 B 67.21B 57.4 B 36.200 B P Sodium 58.4 B 55.5 B 58.21B 50.4 B 30.099 U P • FORM III - IN ILM04.1 C U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L SDG No.: TSL003 Analyte Initial Calib. Blank (ug/L) C Continuing Calibration Blank (ug/L) 1 C 2 C 3 C Prepa- ration Blank C MI Cadmium 0.4 BI I P Calcium 55.2 BI I P Iron 12.0 BI P Lead 1.2 U1 P Magnesium 19.8 B P Manganese 2.1 U P Potassium 62.8 B P Sodium 65.5 B P SFORM III - IN ILM04.1 00 Cn M O F-� • H2M LABS, INC. Date: 07 -Oct -05 QC SUMMARY REPORT SDG: TSL003 Spike Sample Recovery RPDRer %RPD Sample ID• Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL B-092005 M8492005 Alkalinity, Total (As CaCO3) < 1 mp/L 3S492005 LCS-092005 Alkalinity, Total (As CaCO3) 21.8 L 25 < 5 87 80 120 W9510-002dms MW -ISMS Alkalinity, Total (As CaCO3) 63.0 mplL 25 36.8 105 75 125 109510-002ddup MW-1SDUP Alkalinity, Total (As CaCO3) 36.5 mQl/L 36.8 0,82 2( MB -091605 MB -091605 Blochemical Oxygen Demand LCS-1153365 < 2 rr LCS-091605 LCS-091605 Blochemlcal Oxygen Demand`! 102 80 n 0509510-002ddup MW-1SDUP Biochemical Oxygen Demand~ 0509510-002DDUP _204 <2 R MB -853365 MB -1153365 LCS-853365 LCS-1153365 0509510-002DMS MW -ISMS 0509510-002Ddup MW-1SDUP Dn A Bromide < 0.5 M91L Bromide _ _ 5.4 MOIL 5 < 0.5 108 80 120 Bromide ~_ 4.5 mg/L 5 < 0.5 90 75 125 Bromide < 0.5 MGVL < 0.5 20 MS -092005 MB -092005 Chemical Oxygen Demand <10 LCS-092005 LCS-092005 Chemical Oxygen Demand 1020 00 !0:0S < 2 102 80 120 MW-1SDUP Chemical Oxygen Demand _ T <10 0509510-002DDUP MW-1SDUP Chloride 22.7 <2 20 Bromide < 0.5 M91L Bromide _ _ 5.4 MOIL 5 < 0.5 108 80 120 Bromide ~_ 4.5 mg/L 5 < 0.5 90 75 125 Bromide < 0.5 MGVL < 0.5 20 MS -092005 MB -092005 Chemical Oxygen Demand <10 LCS-092005 LCS-092005 Chemical Oxygen Demand 1020 0509510.002bms MW-1SMS _ Chemical Oxygen Demand 1030 0509510-002bdup MW-1SDUP Chemical Oxygen Demand _ T <10 MOIL ,#L mplL rWL M81-091905 MBI -091905 Chloride 1000 < 10 102 80 120 1000 < 10 103 75 125 -- 0509510-0021DMS <10 20 M81-091905 MBI -091905 Chloride <2 maL LCS1-091905 LCS1-091905 Chloride 50.2 mg/L 50 <2 100 80 120 0509510-0021DMS MWASMS Chloride 49.0 mg/L 25 22.7 105 75 125 0509510-002DDUP MW-1SDUP Chloride 22.7 M91L 22.7 0 20 MB -092705 MS -092705 Hardness (As CaCO3) < 5 mg/L LCS-092705 LCS-092705 Hardness (As CaCO3) 1040 mg& 1000 < 5 104 80 120 0509510-002Cm3 MW-1SMS Hardness (As CaCO3) 276 mOIL 200 66.0 105 75 125 0509510-002Cdup MWASDUP Hardness (As CaCO3) 66.0 frwL 66.0 0 20 TSL003 S59 • • QC SUMMARY REPORT SDG: TSL003 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Anal -vile Result Unite Amount Result %REC Umits value %RPD UCL mb-092105 mb-092105 Nitrate as N < 0.1 msn� Ice -092105 Ics-092105 Nitrate as N 1.10 rnwL _ 1.13 <0.1 97 80 120 0509510.002BMS MW -ISMS Nitrate as N 5.03 nWL 2.5 2.63 96 75 125 0509510-002BDUP MW-1SDUP Nitrate as N 2.65 mWL 2.63 0.80 20 MS -14934 MB -093005 Nitrogen, Ammonia (As N) < 0.1 myL LCS-14934 LCS-093005 Nitrogen, Ammonia (As N) 1.03 mon 1 < 0.1 103 80 120 0509510-002SMS MW-1SMS Nitrogen, Ammonia (As N) 5.55 WAIL 5 0.10 109 75 125 0509510-002BDUP MW-1SDUP Nitrogen, Ammonia (As N) 0.11 myL 0.10 13.1 20 MS -092105 MS -092105 Phenolics, Total Recoverable < 5 uyL LCS-092105 LCS-092105 Phenolics, Total Recoverable mb-14877 mb-092405 Nitrogen, Kjeldahl, Total_ ^R� < 0,1 3.96 ^ myL ^_mWL Ics-14877 1a-092405 Nitrogen, Kjeldahl, Total 0509510-002BMS MWASMS Nitrogen, Kjeldahl, Total T _ 3.96 "WL 0509510-002BDUP MW-1SDUP Nitrogen, Kjeldahl, Total < 5 < 0.1 M91L MS -092105 MS -092105 Phenolics, Total Recoverable < 5 uyL LCS-092105 LCS-092105 Phenolics, Total Recoverable 27.7 uo/L 0509510-002bm3 MWASMS Phenolics, Total Recoverable 18.8 uWL 0509510-002bdup MW-1SDUP Phenolics, Total Recoverable < 5 u9IL MS -092005 MB -092005 Sulfate w < 5 myL LCS-092005 0509510-002DMS LCS-092005 MW -ISMS Sulfate _ _ _ _ Sulfate 19.0 29.5 10.1 myL myL myL _ 0509510-002Ddup MWA SDUP SuKate �! - 120 75 125 20 < 5 '4.1 < 0.1 97 80 120 MB -091905 Total Dissolved Solids 4.1 < 0.1 97 75 125 myL <0.1 20 MB -091905 MB -091905 Total Dissolved Solids <10 myL LCS-091905 20 _ 20 - 30 < 5 92 80 120 75 125 20 < 5 94 75 125 myL 169 20.2 20 < 5 20 MB -091905 MB -091905 Total Dissolved Solids <10 myL LCS-091905 20 _ 20 - < 5 95 9.8 98 80 120 0509510.002dms MW -ISMS 75 125 mplL 300 169 120 75 125 9.8 3.0 20 MB -091905 MB -091905 Total Dissolved Solids <10 myL LCS-091905 LCS-091905 Total Dissolved Solids 344 molL 300 <10 115 80 120 0509510.002dms MW -ISMS Total Dissolved Solids 529 mplL 300 169 120 75 125 0509510-002ddup MW-1SDUP Total Dissolved Solids 207 myL 169 20.2 20 2 TSL003 S60 0 0 0 QC SUMMARY REPORT SDG: TSL003 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Unita Amount Result %REC Umite Value %RPD UCL M"2005 M"2005 Total Organic Carbon < 1 mg/l. LCS-092005 LCS-092005 Total Organic Carbon 27.7 rrg/L 25 <1 111 80 120 0509510.002AMS MWASMS Total Organic Carbon 10.8 mplL 10 <1 108 75 125 0509510.002ADUP MWASDUP Total Organic Carbon < 1 mplt. < 1 20 TSL003 S61