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HomeMy WebLinkAboutMetals Data Package 04/2005Analytical Data Package For Y 9 TOWN OF SOUTHOLD PART 360 BASELINE SDG NO: TSL001 Water Samples Received: 4/1/05 & 4/4/05 METALS DATA PACKAGE APRIL 2005 H2M LASS_ 1 NC. .I Onvironmental Testing Laboratories 575 Broad Hollow Road, Melville, N.Y. 11747 U2M "US, INC. r3LOOi 0. METALS TABLE OF CONTENTS I. REPORTS II. QC SUMMARY III. RAW DATA IV. DOCUMENTATION • 0 v� E-� U.S. EPA - CLP COVER PAGE - INORGANIC ANALYSES DATA PACKAGE Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. SOW No.: ILM04.1 EPA Sample No. EQUIPT. BLANK MW-lSD MW-1SS MW -3D MW -3S MW -5D MW -5S MW -6D MW -6S MW -8D MW -8S • Contract: SAS No.: SDG No.: TSL001 Lab Sample ID. 0504024-009 0504067-001 0504067-002 U5U4Ub/-UUzaup 0504067-002MS 0504024-003 0504024-005 0504024-006 0504024-007 0504024-008 Were ICP interelement corrections applied? Yes/No YES Were ICP background corrections applied? Yes/No YES If yes -were raw data generated before application of background corrections? Yes/No NO Comments: Date Reported: 4/11/05 I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package and in the compute readable data submitted on diskette has been authorized by the Lab rat rrr Manager or the Manager's designee, as verified by the followirjg,signi e �n Signature: Name: Vincent Stancampiano Date: L('q Q Title: Vice President • COVER PAGE - IN ILM04.1 N O C/1 F-+ F12M "[3S, INC. • REPORTS FOR METALS t • • • U2M TAUS, INC. QUALIFIERS FOR METALS ANALYSIS Q (Quality Control) Qualifiers E - The reported value is estimated because of the presence of interference. An explanatory note is included in the SDG narrative. M - Duplicate injection precision not met. N - Matrix spike sample recovery not within control limits. S- The reported value was determined by the Method of Standard Additions (MSA). + - Correlation coefficient for the MSA is less than 0.995 W - Post digestion spike for Furnace AA analysis is out of control limits (85- 115%), while sample absorbance is less than 50% of spike absorbance. * - Duplicate analysis is not within control limits. C (Concentration) Qualifiers B - Entered if the reported value is less than the Contract Required Detection Limit (CRDL) but greater than the Instrument Detection Limit (IDL). U - Entered if the analyte was analyzed for but not detected, i.e., less than the IDL. M (Method) Qualifiers P - Analyzed by ICP. M - Analyzed by ICP -MS A - Analyzed by Flame AA. F - Analyzed by Furnace AA. CV - Analyzed by Manual Cold Vapor techniques. AV - Analyzed by Automated Cold Vapor techniques. C - Analyzed by Manual Spectrophotometric Method. CA- Analyzed by Midi -distillation Spectrophotometric Method. NR - Analyte not Required. U.S. EPA - CLP • 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: % Solids: 0.0 • Concentration Units (ug/L or mg/kg dry weight): UG/L ;'CAS No. Analyte Concentration C Q M i --!_- 97.4 B P 74_29-90-5 nu Alumim 7940-36-0 Antimony 3.3 U _ P ;7940-38-2 Arsenic 5.5 B P 17440-39-3 Barium 260 P 7440-41-7 Beryllium 0.20 U P ;_7440-42-8 Boron 512 _ P 7_440-43-9 Cadmium 0.44 _ B P 7440-70-2 _ Calcium _ _ 76700 1.0 U P P [7440-47-3 Chromium 17440-48-4 jCobalt 16.6 _ B P 7440-50-8 lCopper -- 29.9 10.0 U JC -- N _ P CA - - - 57-12-5 !Cyanide x439-89-6 lIron- 201 P 17439-92-1 - 'Lead 2.8 B P 17439 95-4 'Magnesium i 28600 P 7439 96-5}Manganese - 3360 - P — - 7439-97-6 'Mercury0.101 -- - U : Cv I -- -- 7440-02-0 {Nickel - � 30.8B!�—_ ---- — - _! P_ 7440-09-7 ;Potassium 79300 P 17782-49-2 'Selenium_ 2.5 B P 174-40- �22-9 Silver 4 0.40 Urt— P_ 7440-23-5 � Sodium - 171000 E P 7490-28-0 Thallium 3.1 U P 7440-62-2 jVanadium 2.7 B - P - 7440- _ --i- .-- -- Zinc -------- - - 68.2 i I �-I--- P Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: CLEAR EPA SAMPLE NO l MW -3D SDG No.: TSL001 4/1/2005 Texture: Artifacts: FORM I - IN ILM04.1 U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS CoDA�ac HEFT j MW -35 Lab Name: H2M LABS, INC, ---- Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Matrix (soil/water): WATER Lab Sample ID: 0504024-002 Level (low/med): LOW Date Received: 4/1/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L • • CAS No. Analyte Concentration C Q M 1 I� 7429-90-5 I - - p P Aluminum - 7440-36-0 Antimony — 85.6 B 3.3 U 7440-38-2 lArsenic j 4.5 B P -----t------- 7490-39-3 (Barium -- ------fi--P 17440-41-7 7440-42-8 _I Beryllium Boron _ _310 0.20 Ui f 580rB--- _ _ P P 17440-43-9 17440-70-2 Cadmium 0.41_ P - 47-3 Calcium Chromium 86300P - --7440 1.4 P_7440 48-4 (Cobalt 22.1 P 7440-50-8 Copper 28.7 10.0 U P 57-12-5 Cyanide N CA -- 7439 89-6 - iIron Lead _ - 265 — 2.4 B + - - -11- P — 7939 92-1 'Ma I P -- 7 95-4 nesium 439 4 3 9 -_ -I g 34100 -- -- --- --- - P 7- ;7439-96-5:Manganese 4290 P 17439-97-6 iMercury 7440-02-0 INickel 0.10 U 34.9 B iCv P 7490 09-7 ,Potassium 89100P i77_82-49-2 Selenium 2.5 B P 7440-22-4 jSilver I 0.40 U 187000 P ,7440-23-5 E P iSodium - ;7440-28-0 Thallium 3.1 U P 3.1 B 70.3 7440-62-2 Vanadium P P 7940-66-6 ,Zinc _ i Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: CLEAR Comments: Date Reported: 4/11/05 Texture: Artifacts: FORM I - IN ILM04.1 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET -- MW-5D Lab Name: H2M LABS, INC. Contract: I_--___ Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Matrix (soil/water): WATER Lab Sample ID: 0504024-003 Level (low/med): LOW Date Received: 4/1/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L ICAS No. Analyte Concentration C Q M - -- 7429-90-5 !Aluminum---- 108 B P 7440-36-0 jAntimony 3.3 U P 17440-38-2 ;Arsenic - _ 1.9 U _ P ;7440-39-3 !Barium 116 B P 7440-41-7 !Beryllium 0.20 U P 7 440-42 -8 - 7440-92 8 Boron - 745 P -- '7440-43-9 }Cadmium 0.85 B P 17440-70-2 (Calcium - _ _ 118000 _ P -- 7440-47-3 -----47777-- -- - -- 'Chromium - --- --- r--7777-- 1.6 BI ---.. P -- — 14.3 B; - P 7440-48-4 (Cobalt -- _ --7777 I�574102558 - - - - - - --- -P Cyanide --U-- -- _10.0 U N CA 7439-89- 6 !Iron 7439-92-1 Lead _ _ 147 3 3 P P 7439-95-4M -- agnesium 63400, -----r -, - - 7777 - P --- 7439-96-5 Manganese- _ 15000 � P_ 7439-97-6 0.10 CV- 7440-02-0 Nickel f _ 44.0 P 7440-09-7 'Potassium 154000: P t 17782-49-2 --- - 7440 22-9 Selenium -- - - - - Silver - -- 6.8, I 7777— �- 0.40 UI P P 7940-23-5 Sodium L7440_28-0_�Thallium 238000! 3 1U I E P - P 7440-62-2 !Vanadium 1UU -- - - - ,7440-66-6 Zinc 54.2 } F P 1 Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 4/11/05 L FORM I - IN ILM04.1 0 1-4 Cn U.S. EPA - CLP 0 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: % Solids: 0.0 • • Concentration Units (ug/L or mg/kg dry weight): UG/L ( EPA SAMPLE NO MW -SS --� SDG No.: TSL001 0504024-004 4/1/2005 Color Before: COLORLESS_ Clarity Before: CLEAR Texture: - Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 4/11/05 FORM I - IN ILM04.1 00 0 C!1 ,CAS No. Analyte Concentration C Q M i k7429-90-5 (Aluminum 66.6 B P 7440-36-0 (Antimony_ 3.3 U P 7990_-38-2 �A_ — nr es is_ _ - 1.9 U P 7440-39-3 ;Barium_ Beryllium 79.1 BI _ 0.20 U — P P 7440-41-7 7440-42-8 !Boron iCadmium — — ---_ 115 B 0.40U P 7440-43-9 - P 744_0-70-2_JCalcium 11400, -- --- P 7440-47-3 hr mi 0 3 �C o um 84.0 --- --- -- _- -- P 7440-48-4 Cobalt 2.0 U P 17440-50-8 +Copper P 32.4 _ 10.0 U1 CA W7-12-5 !Cyanide 7439-89-6 !Iron 564 'Lead P_ �P 17439-92-1 1.4 U -� 17439-95-9 Magnesium 78101 P P 17439-96-5 iManganese 909! _ j7440 02-0 Nickel 4.4 P _ 7440-09-7 Potassium 99_70', P - - - :7782-49-2 Selenium - __2.41 U -- 17440-22-4 Silver 0.40-U- 7440 23=5 'Sodium-- - _ E -- „P P i - --1300�i----4 7440-28-0 Thallium 3.1 U, j--- = 7990-62-2 1 . 0 U P --Vanadium - --- - - --- !7440 66 6 iZinc 52.8 P ( EPA SAMPLE NO MW -SS --� SDG No.: TSL001 0504024-004 4/1/2005 Color Before: COLORLESS_ Clarity Before: CLEAR Texture: - Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 4/11/05 FORM I - IN ILM04.1 00 0 C!1 • U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET - - - MW -6D Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Matrix (soil/water): WATER Lab Sample ID: 0504024-005 Level (low/med): LOW Date Received: 4/1/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte iConcentration C M ;74_29-_90-5 Aluminum �- 62.9 B ' �P- ;7440-36-0_ Antimony _ 3.3 U I P 7440_-38-2 Arsenic 2.7 B -- P 7440-39-3 Barium Bi P 7440-41-7 lBeryllium 0.20 U P 7440-42-8 .Boron (Cadmium 37.0 B, 0.40 UI - I P P .7440-43-9 40 0 - ---2 7440-47-3 Chromium - -- -_ 16100 BI t - P P :7_440-48-4 7440-50-8Copper-_ 'Cobalt 3.4 B; 8.3 B' _ PP P 157-12-5 Cyanide 10.0 U! N CA -- 7439-89-6 -- f- !'Iron -- 5-- 174 7439-92-1 Lead U P I U !Magnesium 4350 Bi ;7439-95-4 P 7439-96-5 ;Manganese 23601 i P 17439-97-6 y _ IMercury - - 0.1 i0 U _ �C P '7440-02-0 !Nickel 2.22 BU 7440-09_7 Potassium 4810'B 1 P i 7782-4 9-2 +Selenium 2.4 P !7440-22-4 ,Silver 0.40 U I P P 7440 23-5 'Sodium 7980' 1 E '7440-28-0 Thallium 3 li U P _ 7440-62-2 iVanadium �- _ 1. U' - P_I ;7440-66-6 jZinc ! 22.0 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 4/11/05 FORM I - IN ILM04.1 U.S. EPA - CLP • 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Matrix (soil/water): WATER Level (low/med): LOW % Solids: 0.0 Contract: SAS No.: Lab Sample ID: Date Received: Concentration Units (ug/L or mg/kg dry weight): r! r CAS No. j Analyte Concentration C{ Q M 7429-90-5 'Aluminum P 77.8 B -- - r7440-36-0- r--- - Antimon - 3.3 U; P 7440-38-2 Arsenic 1.9 U P j 7440-39-3 !Barium 57.3 BIP 7440 41-7 Beryllium 0.20 Ui P '7440-42-8 iBoron 40.6 B! P 7440-93-9 Cadmium ! 0.43 B i P 17490-70-2 lCalcium 11000 P 7440 47-3 (Chromium 1.0 B; _ P 17440-48-4 -- !Cobalt 4.7! B! _ P { (7440 50-8 jCo er 4.1 B r P 157-12-5 • -yPP !cyanide 10.0� �~ U _ N � I CA - 7439-89-6 ',Iron 70.51B P 7439-92-1 Lead r 1.4 U P 7439-95-4 !Ma nesium fi 30601, B ! P 7439-96-5 Manganese ! 2030' P 7439-97-6 Mercury-- _______0.1__0 U i- - j CV 7940 02-0 Nickel - t 7.2 B- ' - P - - 7490 09-7 4 -- Potassium - 3820 a BI P - 7782 49-2 -- - -- - Selenium - - - - 2.4 --- Uj - - - P 17440-22-4 ISilver 0.40 U P 7440-23-5 - Sodium -I 6160E i P 7440-28-0 'Thallium 3.1 U P -- '7440-62-2 (Vanadium 1.01 U ! P 7990 66-6 ,Zinc 37_8 -- -- T - -- - T-4--- Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: CLEAR Comments: Date Reported: 9/11/05 • FORM I - IN UG/L EPA SAMPLE NO MW -6S SDG No.: TSL001 0504024-006 4/1/2005 Texture: Artifacts: ILM04.1 0 U.S. EPA - CLP 0 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): CAS No. Analyte Concentration I C l Q I M i 7429-90-5 'Aluminum 141'B _ P 7440-36-0 'Antimony 3.3 U P 17440-38-2 }Arsenic 3.9 BI P 7440-39-3 Barium 139 B. P - --- - :7440-41-7 ,Beryllium 0.20 U P 7440-42-8 -Boron 482 B P 7440-43-9 ]Cadmium j 0.40 U P I 7440-70-2 Calcium 69300 P 7440-47-3 }Chromium-- -- 3_0 B- P 17440-48-4 ;Cobalt 9.2 B P ---- - - a- r--------� _. • 440-508 TCopper 27.51 P 7-12-5 Cyanide - 10.0; U_ N CA 7439 89-6 1Iron_- - - - 18401 - i P 7439-92-1 Lead 8.31 P 7439-95-4 Magnesium -r_...._- --- - 376001 P 7439-96-5 ';Manganese 1 -31901 { P 7439-97-6 'Mercur — - f--- --Y 0.10 U (_ CV , 744 07 02-0 Nickel 22 1 B j P 7440-09-7 lPotassium 97800 P ,7782-49-2 'Selenium 3.1 B+ P 7440-22-4 Silver 0.40 U P- ,7440-23-5 Sodium 82200] E P — - - --U -—t-P- 7440-28-0 iThallium 31 t -- 3. 1 '744062-2 Vanadium 1.0 U P --- - } --- - ----- :7440-66-6 'Zinc 59.7 P Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: CLEAR Comments: Date Reported: 4/11/05 UG/L EPA SAMPLE NO ' - MW -8D -..----- -� i SDG No.: TSL001 0504024-007 4/1/2005 Texture: Artifacts: FORM I - IN ILM04.1 V) U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW -8S Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Matrix (soil/water): WATER Lab Sample ID: 0504024-008 Level (low/med): LOW Date Received: 4/1/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS 'Concentration r 1 No. Analyte C Q M 7429-90-5 ;Aluminum 1640 P 1 7940-36-0 ony- _ -t _-- - 3.3 U _ P 7440-38-2 Arsenic 1.91 U' P 7440-32-3 ;Barium 107 B i P 7440 41-7 'Beryllium 0.20 U P ,7440-42-8 Boron 84.3 B P 17440-43-9 Cadmium 0.40 U P 7440-70-2 'Calcium 16000 P -— 7440-47-3 ,Chromium - 12.3------ -P-J 7440-48-4 !Cobalt 2.3 B; P , ;7440-50-8 Copper 20.0 B _ j P 157-12 5 - -6 :Cyanide i - - - ----- 10.0 U N - - - - CA 17439-89-- ',Iron I 160001 P 17439-92-1 Lead 5.4 P ,7439-95-4 Magnesium 6290 P 17439-96-5 !Manganese 1 181 1 P .7439-97-6 Mercury --- 0.10 U CV .7440-02-0 Nickel 8.4 B P ;7490-09-7 :Potassium 14600 P 7782-49-2 Selenium_ F-- 2.7 B P .7440-22-4 Silver 7440 23-5 'Sodium -- U . P P 11900 E 7440 28-0 Thallium 3.8 P - ,7490 62-2 Vanadium _B_j 7.9 B; - P '7_440-66-6 41.31`- P� (Zinc - I j - - - Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported: 4/11/05 • FORM I - IN ILM04.1 • U.S. EPA - CLP 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. Matrix (soil/water): WATER Level (low/med): LOW Solids: 0.0 SAS No.: Lab Sample ID: Date Received: Concentration Units (ug/L or mg/kg dry weight): CAS No. Analyte Concentration C Q TM 7429-90-5 Aluminum E 6.5 U P :7440-36-0 Antimony 3.31 U 11 P '7440-38-2 ,Arsenic 1.9 U P 17490 39 3�Barium 1.2 U P 7440-41-7 'B� eryllium 0.20 U P 7 49 0 42-8Boron 1.7 U P 7440 43-9 Cadmium f 0.401 U P 17440-70-2 'Calcium 79.7, B ' P 7440 --4-7-3 Chromium 1.0 U P 7940-98-9 ;Cobalt i 2.0 U P -- --- ------ - ,7440-50-8 !C� opper _ 3.2 B _ P • 157-12-5 - --- !- - - - -- �- , N CA 17439-92-1 Cyanide - --18 71 U - -- -- !79.39 89-6 }Iron 8.7 B � - P P - --- - - 7439-95-4 Magnesium 17 9� B P -- -- --- - - g _Y_—1 P CV_ 7440-02-0 Nickel 1.3iU + P '7.439 96- iMan anese 1 B 7_439 97-6 "Mercury 0.10 U 7440-09-7 Potassium 37.3 P :7782-49-2 Selenium 2.4 U P 7940 22-4 Silver 0.40 U; P r- - - - --- - - --.. 7440-23-5 !Sodium 113 B' E �P ,7440-28-0-- Thallium j ---3_1�U P 17940 62-2 'Vanadium- 1.0; U P - -� 7440 66-6 ,Zinc 19.8_B P 1 Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: CLEAR UG/L EPA SAMPLE NO i EQUIPT. BLANK SDG No.: TSL001 4/1/2005 Texture: Artifacts: FORM I - IN ILM04.1 U.S. EPA - CLP • 1 INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Lab Sample ID: Level (low/med): LOW Date Received: Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): ACAS No. Analyte (Concentration C Q M 7929-90-5 Aluminum 6.5 U P 7440-36-0 Antimony 3.3 U P 7990-38-2 Arsenic _ 1.9 U P 17990-39-3 Barium i 5.0 B P 7440-41-7 Beryllium 0.20 U P 7440-42-8 Boron 12.5 B P 7440-43-9 Cadmium 0.40 U P 7990-70-2 Calcium9430 P 7440-97-3 Chromium 1.0 U rt P 17440-48-4 jCobalt 2.0 U P 17440-50-8 'Copper ip 57-12-5 !Cyanide N CA 7439-89-6 ,Iron 374 P 7439 92-1 Lead 1.4 U P 7439-95-4 1Magnesium 3890 B P ,7439-96-5 (Manganese 36 3j - P- '7939 97-6 !Mercury 0.10j U CV x7940-02-0 !Nickel 1.31 U P 7440-09-7 ass 'Potium 1000 P 7782-49-2 Selenium 2.41U P 7440 22-4 Silver i 0.40rU P 7440-23-5 Sodium 23900 E P 7440-28-0 Thallium 3 11 j ! P 7490-62-2 7Vanadium 1.0 U; P 7440-66-6 {Zinc 299 P Color Before: COLORLESS Clarity Before: CLEAR Color After: COLORLESS Clarity After: CLEAR Comments: Date Reported: 4/11/05 • UG/L EPA SAMPLE NO MW -1D SDG No.: TSL001 4/4/2005 Texture: Artifacts: FORM I - IN ILM04.1 U.S. EPA - CLP • 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET I --- - - MW -1S Lab Name: H2M LABS, INC. Contract: I _ Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Matrix (soil/water): WATER Lab Sample ID: 0504067-002 Level (low/med): LOW Date Received: 4/4/2005 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L CAS No. Analyte Concentration �C Q T_ _t 7429-90_5 jAluminum _ 29.4; B -- --- P [7440 36-0 (Antimony 3.3 U _ P ,7440-38-2 Arsenic 3.5 BI P 7940-39-3 Barium 1 r_-__--- 5.5 B P 17440-41-7 Beryllium 0.43 B P 7990 42-8 Boron 14.6 B P 7440-43-9 Cadmium ! _0.56 B P 7440-70-2 jCalcfum �- — ---- 92601 P ---1----------- 1_- ------ '7990 74 3 Chromium _ 7490-48-4 Cobalt I _ 2.01 U; P 17440-50-8 lCopper! t 12.0 B! 57-12-5 lCyanide 10.0 Uf N { CA 17439-89-6 lIron 380 _P� ,7439-92-1 ;Lead 1.4 U P j1; 7439 95-4 Magnesium 3760 B P -- - - 6 - 7439 96-5 Manganese 38 8 } P '7439-97-6 Mercury a 0.10' U CV j 7440- 02-0 Nickel 1 3 U P 7440-09-7 'Potassium 1000_B P 7782-49-2 Selenium 1 2 4 U P 7440-22-4 ;Silver 0.40 U P 7940 23-5 Sodium 23800 E -P i7440-28-0 Thallium 3.1 U P 47440-62-2 'Vanadium 1.0 U P 17940-66-6 .Zinc _ _ 256 P_ Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported:_ 4/11/05 • FORM I - IN ILM04.1 C/� • • • U2M LABS, INC. Il. QC SUMMARY FOR METALS A. INITIAL AND CONTINUING CALIBRATION VERIFICATION B. CRDL STANDARD FOR AA AND ICP C. METHOD BLANK D. ICP INTERFERENCE CHECK SAMPLE E. SPIKE SAMPLE RECOVERY F. POST DIGEST SPIKE SAMPLE RECOVERY G. DUPLICATES H. LABORATORY CONTROL SAMPLE I. STANDARD ADDITION RESULTS J. ICP SERIAL DILUTIONS K. INSTRUMENT DETECTION LIMITS L. ICP INTERELEMENT CORRECTION FACTORS M. ICP LINEAR RANGES N. PREPARATION LOGS O. ANALYSIS RUN LOGS U.S. EPA - CLP • 2A INITIAL AND CONTINUING CALIBRATION VERIFICATION Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Initial Calibration Verification Source: MV Labs/High Purity Continuing Calibration Verification Source: MV Labs/High Purity Concentration Units: ug/L Initial Calibration Continuing Calibration Analyte True Found %R(1) { True I Found %R(1) Found %R(1) I M Aluminum Antimony 50000 01 49983 7610050000.0 6 1 100 1000.0 _ 50339.995100 7 1015.41 101 5 ' 50752 52 ' 1016.22 101.5 101.6 P Arsenic- Barium Beryllium Cadmium - 000 2500.0 2500.0 12531.07 2500.0 --- - . ,-5--03-29-.88-- 50000 9 005864 2469.61 2529.09 --10-0--.-7---1-500--0-0.--0j -1-00-.0- 98.8 101.2 101.2 500.0 2500.0 _2501.82 2500.0 2500.0 �- 507.17 2544.96 2545.79 -- -- 101.4 100.1 101.8 101.8 100 9 506.41_ 2515 76 2518.12 2535.48 49627 99 101.3 100.6 100.7 1_01.4 99.3 1 P P P P P 'Chromium - 2500 0 2524.65 101 0 _50470.55 2500 0 2542.04 101 7 2531.37 r 101.3 ! P rj P Cobalt FCo er PP 2500 0 2500.0 2537.12 - 2520.81 101.5 100.8 2500.0 2500.OT 2591.00 ; -- 2538.85 103 6 - 101.6 2602.86 - i -- -- - --- 2522.23 104.1 100.9 P -- ron - Fead 150000 01 --- 500.0 , 50886.66 j - - 494.66 101.8 -- 98.9 150000.0' 1 -- 500.0 I 51357.65 C 498.82 1 102 7 --- 99 8 51337 34 ; - - - , 489.93 102.7--j 98.0 P P Magnesium Manganese 150000.0, 12500.0 � 48542.7-2--I-- - .- 2539.78 � 97.1 1 -01--.6--t-2 50000. 098796.00 --- 500 0 -- -- - 2560.63 � 97 6 1-2--5-48.77 102.9 ; 48483.93 1 - -�- !_102.0_ 97.0 -0 P - P P 2500.0 '4 2526.78 r 101.1 2500.0 i 2536.72 101.5 2455.95 98.2 ;Nickel Potassium 180000.0, 79051 33 98.8 1:80000.01 8_0457.96 100.6 81510 86 101.9 P ,Selenium Silver } 500.0 1 � 1000 0 512.27 989.11-98 102.5 9 1 500 0 1000.0 512.91 999.69 102.6 100.0 515.48 1 998.47 103.1_ 99.8 P P iSodium - 80000 01 -- 75196 49 94 0 ;80000.0; 76153.64 r 95 2 -- 76187 72 95.2 P lThallium Vanadium Zinc 500.0 f 250_0.0 2500 0 �-2539.36 498.11 2538.49 99.6 101.5 101.4 500.0 502 59 2500.0 2557.93 25_0_0 0 2549 91 f 100 5 102.3 102 0 484.96 ! 2551 13 2511 06 � 9-7.-0 102.0 100.9 P P P _ _' (1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115 • FORM II (Part 1) - IN ILM04.1 U.S. EPA - CLP 2A INITIAL AND CONTINUING CALIBRATION VERIFICATION Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Initial Calibration Verification Source: MV Labs/High Purity Continuing Calibration Verification Source: MV Labs/High Purity Concentration Units: ug/L Initial Calibration Continuing Calibration Analyte True Found %R(l) I True Found %R(1) Found %R(1) I M� Aluminum- A- 50000.0 51666.69 103 3 -- + - -- �- - - --- - r - !Antimony�__ 1000.9j1032.92 103.3 P -- . - - --- ----- - Arsenic 500.0 517.17 ; 103.4 ; P ----- -- - - - - --- - ---- Barium 2500.0 2557.60 102.3 i P Beryllium 1 2500.0 1 258_2.46 103.3_ ! _ P Boron 2500.0 1 2496.88 99.9 I P aium � 2500.0 2572.61 102 9 P �- - --j2500.0 - -- Calcium 150000.0 51093.20_101 r P Chromium j2500 0 ' 2581.24 1043,2 -1 P (Cobalt ' 2500 0 ; 2543.38 101.7 -- - opper -- - I --- -- 2500.0 y- 2594.71 103.8 P - - -- - - ron 150000.Oi 51880.23 103.8 r t P Lead I f 500.0 501.58 -'11-00.3 P Magnesium 1- 150000.0, 99582.91 99.2 - -. P , Manganese i 2500.0 2593.16 i 103.7 P , { - - - - - 'Nickel _ _ J r 2500 0 � 2523.14 _ 100 9 _ � P i - r -- Potassium 80000 0 81868.89 102 3 P_ - - + -- - Selenium t 500.0 530.17 106.0 1 P ;Silver I 1000.0 1014.4_1 101.4 P -- r So id um -i ----- 180000.01 77585.98 97 0 -r- --- - -- P Thallium i 500.0 504.76 101 0 - P J Vanadium I 2500.0 2603.65 1 104.1 P - -- Zinc - - _+ 2-900.0! 2 537.57 101.5 j - } - P 11 (1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115 is FORM II (Part 1) - IN ILM04.1 00 O C/] F-+ 0 • U.S. EPA - CLP 2A INITIAL AND CONTINUING CALIBRATION VERIFICATION Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Initial Calibration Verification Source: MV Labs/High Purity Continuing Calibration Verification Source: MV Labs/High Purity Concentration Units: ug/L • FORM II (Part 1) - IN ILM04.1 �6 Initial Calibration Continuing Calibration Analyte True Found %R(1) True Found %R(1) Found %R(1) M1 - Iron Sodium - 2 00 - 25 .0 14 .2 9 {12500.0 1 2498. 91 - j P P ---- - --- 100.6 2500.0 2529.43 100.0 1I2500 0 2519.72 101.2 00 8 2568.23 102.7 - 2532.10 1 101.3 (1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115 • FORM II (Part 1) - IN ILM04.1 U.S. EPA - CLP • 2A INITIAL AND CONTINUING CALIBRATION VERIFICATION Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Initial Calibration Verification Source: MV Labs/High Purity Continuing Calibration Verification Source: MV Labs/High Purity Concentration Units: ug/L • • FORM II (Part 1) - IN ILM04.1 O N O V] H Initial Calibration Continuing Calibration Analyte 1 True Found %R(1) True Found %R(1) Found %R(1) Mi iIron Sodium 2500.0 2582.01 j 2500.0 2475.91 103.3 99.0 P P -- -- -- (1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115 • • FORM II (Part 1) - IN ILM04.1 O N O V] H U.S. EPA - CLP • 2A INITIAL AND CONTINUING CALIBRATION VERIFICATION • Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Initial Calibration Verification Source: MV Labs/High Purity Continuing Calibration Verification Source: MV Labs/High Purity Concentration Units: ug/L Initial Calibration Continuing Calibration I Analyte True Found %R(1) True Found %R(1) Found %R(1) Mi Mercury 6.0 6.02 100.3 75.0 r 5.08 101 6 5.22 104.4 ICV (1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115 N FORM II (Part 1) - IN ILM04.1 U.S. EPA - CLP . 2A INITIAL AND CONTINUING CALIBRATION VERIFICATION Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Initial Calibration Verification Source: MV Labs/High Purity Continuing Calibration Verification Source: MV Labs/High Purity Concentration Units: ug/L Initial Calibration Continuing Calibration j Analyte i True Found %R(1) True Found %R(1) Found %R(l) M G- - — — -- - -- - - - --i Mercury 5.0 5.16 103.2 - I -T CV (1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115 • N N • FORM II (Part 1) - IN ILM04.1 00 U.S. EPA - CLP i 2A INITIAL AND CONTINUING CALIBRATION VERIFICATION Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Initial Calibration Verification Source: MV Labs/High Purity Continuing Calibration Verification Source: MV Labs/High Purity Concentration Units: ug/L Initial Calibration Continuing Calibration Analyte I True Found %R(1) True Found %R(1) Found %R(1) M CCyanide 75.0 88.18 117.6 100. 0 112.56 112.6 112.56 112.6 CA - - -- - - i --- - - (1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115 • . FORM II (Part 1) - IN ILM04.1 U.S. EPA - CLP 0 2A INITIAL AND CONTINUING CALIBRATION VERIFICATION is Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Initial Calibration Verification Source: MV Labs/High Purity Continuing Calibration Verification Source: MV Labs/High Purity Concentration Units: ug/L Initial Calibration j Continuing Calibration Analyte True Found %R(1) True Found %R(1) Found %R(1) 1 M Cyanide 100 0 112.56 112.6 CA f -- - - (1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115 N FORM II (Part 1) - IN ILM04.1 00 h U.S. EPA - CLP • 2B CRDL STANDARD FOR AA AND ICP Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: AA CRDL Standard Source: ICP CRDL Standard Source: MV Labs/High Purity Concentration Units: ug/L SDG No.: TSL001 i CRDL Standard for AA - CRDL Standard for ICP Initial Final Analyte True Found %R True Found %R Found %R Antimony. 120.01 116.251 96.9r 119.66 99.7 I Arsenic 1 20.0 23.58 117.9 23.24 1_16.2 beryllium 1 10.0 9.93 99.3 10.32 103.2 Cadmium 10.0 9.93 99.3 10.36 103.6 - --- Chromium 20 0 19. 0 91 95.5 19.80 99.0 !Cobalt 100.0 99.73 99.7 103.59 103.6 -- - I. Copper 50.0 49.43 98.91 50.88 101.8 Lead 1 -- --6. 01 6.53 108.8 4.46 74.4 Manganese 30.01 29.57 98.6 30.43 101.4 iNickel 1 80.078.85 98.6 78.50 _98.1 - - -- 1 Selenium 10.0 7.871 78.7 9.68 96.8 Silver 20.0 19.081 95.4 19.01 95.1 Thallium i 20 01 22 26 111.3 21 56 107 8 Vanadium 100.01 97 77, 97.8101 " _101.5 40 34, 100.91 43 19,, 108.0 - - - - I ---- - ----- Zinc 40.01- L- -- i - -- 0 FORM II (Part 2) - IN ILM04.1 • U.S. EPA - CLP 2B CRDL STANDARD FOR AA AND ICP Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: AA CRDL Standard Source: MV Labs/High Purity SDG No.: TSL001 ICP CRDL Standard Source: Concentration Units: ug/L CRDL Standard for AA CRDL Standard for ICP Initial Final Analyte True Found %R True Found %R Found %R Mercury - 0.21 0 18I 88.5 FORM II (Part 2) - IN ILM04.1 U.S. EPA - CLP • 2B CRDL STANDARD FOR AA AND ICP Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 AA CRDL Standard Source: MV Labs/Hirth Puritv ICP CRDL Standard Source: Concentration Units: ug/L I CRDL Standard for AA CRDL Standard for ICP � I Initial Final Cyanide True Found oR True Found %R Found %R - --- -- - — -- -- r— Ianide- ' 10 .0 9.221 92.2 • 0 FORM II (Part 2) - IN ILM04.1 r— N O U.S. EPA - CLP •3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TS1,001 Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L ' t Initial j Calib. Continuing Calibration Prepa- j Blank Blank (ug/L) i ration /L) ( to Anal u C i y � g 1 C 2 C 3 C Blank C M Aluminum -9.21B i 6. 5! U -17.0 B 6. 5 U -8.180 B P Antimony 3.3 U 3.3 U-3 3 U I 3.3 U; _ 3.300 U P Arsenic i 1.9 U 1.9 1-U l 2.8' B I 1.9 BB 2.330 B P -- - - - -- L - - - - - -- +----- 1- L Barium 1.21 U: 1 .2 t U f 1.2 U 1.2 U j 1.200 U P 'Beryllium 0.21 U ! 0.2 U -- 0.2 U- 0.2 U _ 0.200 U P - r�- - -- Boron 1 7 U 1.7 U 1.7 U 1. 7 U 1.700 U P Cadmium 0 4.0 0.4 U 0.4 U 0.4 U 0.400 U P Calcium_- - 16 16.9 U 16.900 U P 9� U _ 16.9 U _ 16.9 U -- _-r Chromium i l 0 U 1.0 U 1.0 U 1.000 U P Cobalt 2 0 U 2.0 1 U 2.01 U 2.0 U 2.000 U P Cobalt - Copper ! 0.9 U 0.9 U 1. 5 B I0.-9 + U r Y 0. 900 U 1 P Iron 2.4. B 2.8 B 3.6 B 1 5.6 B t 10.200 B P j -- - g �U 1.9 �U' 1 4!U 1.9 iU ' 1.400 U P Lead � 1 4 Magnesium 6.21 U 6.2 U 6 UB - 6. 4 B - f 6.200 U P - - - - !Manganese 0. 5i -U T 0. 5 1 U 0.51U 0. 5 U 0.500 U P - - ! - -- Nickel 1 1 3 U� -- 1. 4 B' � 1. U U '_' 1.300 U P jPotassium 11.1 U 11.1 U - 11.1 U 11.1�U _11.100 U P Selenium 1 - - 2.4iU 2.9 U -- 3.4 BB 2.4 U - 2.400 U P iSilver -0. 41 B_ 0. 4! U 0. 4 U! 0.4 U T r 0. 400 U P ,Sodium 8 8 B 8.3 U 17.4 B r 8.300 U P Thallium I 3 1 U l 3.1 U 3.1 U 3.1 U 3.100 U P Vanadium : U 1.0 U ! 1.0 U 1.0 ; U ( 1.000 U P ----- Zinc 1.7 U' 1.7 UI 1 7;Ui 1.7 Ui 1.700 U IP , i • FORM III - IN ILM04.1 00 N O C/2 H • • U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg) Initial Calib. ; Continuing Calibration Blank Blank (ug/L) Analyte (ug/L) C1 1 C 2 C 3 jMercury 1 0.1; U 0.1 U! 0.1! U r- - -- -- --t -- UG/L I 0.1 1 U SDG No.: TSL001 Prepa- ration Blank C M 0.1001 U CV . FORM III - IN ILM04.1 U.S. EPA - CLP •3 BLANKS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Preparation Blank Matrix (soil/water): WATER Preparation Blank Concentration Units (ug/L or mg/kg): UG/L � Initial - ------------- - Calib. Continuing Calibration Blank Blank (ug/L) j Analyte (ug/L) CI 1 C 2 C 3 C _ _ I U 10.0 ; U j 10.01 U I 10.0 h U • Prepa- ration Blank C M 10. 0001 U CA • FORM III - IN ILM04.1 U.S. EPA - CLP • 4 ICP INTERFERENCE CHECK SAMPLE Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 ICP ID Number: TJA61EDV ICS Source: MV Labs/High Purit Concentration Units: ug/L f True Initial Found Final Found Sol. Sol. I Sol. Sol. Sol. Sol. Analyte A AB A AB %R A AB %R Aluminum 500000 500000 500000 1I 525525 527390.1 105.5' 528469 537267.51 107.51 !Arsenic i 1000 1029.6 103.01 1050.1 105.0 i 500 522.7 104.5 i 530.4 106.1 !Barium Beryllium - 500 - ---- 509.6 --- 101.9 - - 521.8 104.4 Boron 1000 1037.6 103.8 1038.6 103.9 Cadmium 1000 i ---972.3 97.2 996.5 99.7 !Calcium Y 500000 1 500000 + 501164 1 508221.61 101.6 520817 517422.2 103.5 Chromium 1 { 500 511.21 102.2 522.1 104.4 - Cobalt 502.4 100.5 999.0 99.8' Copper _500 500 - 555.4 111.1i - 1_ _ 561.8 112.4 Iron 200000 i 200000 - .. - -- 196858 199519.8 99 8T 203666 203445.9 101. 1000 1003.8 100.4 1019.3 101.9 Maanesium g 500000 500000 512344.4 506290 i- 102.5 525865 _ 529423.5 _104.9 Manganese 500 527.0 105.4 536.1 107.2 !Nickel - I 1000 - 979.7 - 98 Ol - 980.81 98.1 Selenium 1000 -- - 1020.6 - 102 1i 1047. 104 7 Silver 1000 1078.2 107 8j 1093.0 109_3 Thallium 1000 ! 989.8' 99.0 999.3 99.9 ,Vanadium 500 r1 _ 517.5L 103.5 � 528.2 105.6 Zinc 100 957.9 95.8 - - _ 971.3 f 97 .11 --_ _---_.l --0 M • O C!1 FORM IV - IN ILM04.1 [-� U.S. EPA - CLP • 5A SPIKE SAMPLE RECOVERY Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Solids for Sample: 0.0 Concentration Units (ug/L or mg/kg dry weight): - - r -- ---- -Co ntr_ol-! I I � Limit Spiked Sample Sample Analyte %R I Result (SSR) C Result (SR) C lAluminum 75-125 2054.1700 24.3600 BI (Antimony 75 125 494.6757 3.3000 U - - -- - - -- Arsenic 75-125 43.26681 3.4724 B Barium 75 125 I 2000.4300 _ 5.4900 B Beryllium 75 125 52 7700 0.4300 B I- - - 1Boron 75-125 1930 1500 19.6000 B - - -- Cadmium 75-125_ 52 4200 0.5600 B !Chromium 75-125 207.2100 1.H 00 U Cobalt 75-125 - 533 1400, Y 2.0000 UI 500.00 o e anide Iron 1 75 125 75-125 75-125 �y °S< 264.6800: -- - z� U 1422.0300 -11.9700 10. 0000 379.6900 , B U (Lead 75-125 1 18.8992 1 1.4000 U 250 00 101.1 k 100,00 ►_ _ l000.00_t 104.2 U� U _ Manganese 75-125 556.7300; - Mercury 75-125 1.0200' Nickel 75-125 522.9000 -- - - 38.8200 - -- --- 0.1000 1.3000 iSelenium 75-125 500.00 104.6 10.00 115.5 -- ---- - - 50.00 ; 82.3 11.5512 2.4000 U 1Silver 75-125 1 41.1477; 0.4000 U `Thallium 75-_125_ 50.1905 3.1000 U U - Vanadium 75 125 508.4800' 1.0000 - Zinc -- - 75-125 1 819.2700 -- 2-56.2700 1 Comments: • FORM V ( Part 1) - IN ff EPA SAMPLE NO MW-1Ss 1 SDG No.: TSL001 Level (low/med): LOW UG/L 1 -f -- ] Spike I Added (SA) 1 %R Q M _ L - 2000.001 101.5 98.9 --- 99.5 - 500.00 - 40.001-r 2000 00� 99.7 50.00 104.7 _ 2000.00 50.00 200._00 1 _95.8. 103.7 103.6 _ 500.00 106.6 250 00 101.1 k 100,00 ►_ _ l000.00_t 104.2 _ N 20.00 1 94.5 500.00 103.61_ 500.00 104.6 10.00 115.5 -- ---- - - 50.00 ; 82.3 --- 50 00.1 100 41 101 71 500.00 1 112.6; a 0 ILM04.1 N M O U.S. EPA - CLP S5B EPA SAMPLE NO POST DIGEST SPIKE SAMPLE RECOVERY --_ ---- -- MW-1SA Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Matrix (soil/water): WATER Level (low/med): LOW Concentration Units: ug/L -- - - - I Control Limit ` Spiked Sample Sample 1 Spike Analyte i %R Result (SSR) C Result (SR) C' Added (SA) ! %RQ M L-- - :-- - - - - - -- ----- - --- - i - — --- !cyanide 98.91 10.00 1 U 1 100.0! 98.91 C1 • Comments: U.S. EPA - CLP • 6 DUPLICATES Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER % Solids for Sample: 0.0 EPA SAMPLE NO !_- MW -1S ---- _� SDG No.: TSL001 Level (low/med): LOW % Solids for Duplicate: 0.0 Concentration Units (ug/L or mg/kg dry weight): UG/L Control Analyte I Limit I Sample (S) C Duplicate (D) C1 RPD jQ M, -- ---- - -- - Aluminum 20_0.0000 I 24.3600jB 14_0800 B' 53.5 P Antimony - 60.000 3.3000 LU 5. 1813 B ! 200.0 P Arsenic 10.0000 ' t 3.4724 ' B 1. 90001 U I 200.0 P Barium 200.0000, 5.4900 B L _ 5.1800'B 5.8 ' P1 Beryllium 5.0000 0.4300 1B 0.2000! U+ _ 200.0 P {Boron __500.00001 14.6000 B 13.4900 B' _ 7.91 P (Cadmium 5.0000 i 0 5600 B 0.40001U 20_0.0 PI Calcium 15000.0000 ! 9259 0700 i 9856.2800 6.2 P Chromium It 10.0000 1.0000 U 1.3600, 200.0 1 P LCobalt 50.0000 j 2.0000 U 2.1500 Bim- 200.0 ! P Koper _ 1 25.0.000 11.9700 B r 13.66 ' 13.2, P! 0000;U1 CA �'rde - --- - i 379.6900 - 386.3300. +,---1.7 P' 1IronP 100.0000 Lead - . I-! - - 10.4000 U -- -- 0000 U10. 4000} U - - - -� Magnesium .5000.0000 3761 3400 ;B 4027.6300rB' _ 6 !P Manganese 15.0000 38 8200 I 39.5300: - - -- - 1 . 8'j P -L.- Mercury - - - - 0. 1000- -a - - 0 ._10001 U - - - +-� ICV 'Nickel- _ 40 0000 1.3000 $U 1_.70001 B 200.0; P ;Potassium 5000 00001. 1003.4800 B 1047.0800!B 4.3' P Selenium - 1_ 2.4000 U 2.4000', U P - - -- - - Silver j _ _ 0.4000 U - 0_.40001 U 1 4 Sodium 15000. 0000 - - -23805 1000 -- L -- 24980_3300-- 4. , 'Thallium 10.0000 f _ 3.1000 U i- - -_ 4 . 07861 B ; -200 - ; P Vanadium 1.0000 U! 1.0000. U' U -Zinc I 256.2700' I 277.6900!_ 8.0 P • FORM VI - IN ILM04.1 U.S. EPA - CLP • 7 LABORATORY CONTROL SAMPLE Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Solid LCS Source: ERA Aqueous LCS Source: MV Labs/High Purity Aqueous (ug/L) Solid (mg/kg) ILAnalyte True Found %R True Found C Limits jAluminum _50000.055352.69 110.7 Antimony 1000.0 1091 I _ _ _ -.. - - .46 iArsenic 500.0 534.071_06.8 Barium 2500.01 2730.25 109.2 IBer llium 2500.0' 2826.50 113 1 - Boron } 2500.0 2865.85 114 6 Cadmium 1 2500.0 2742.40 109 7 Calcium -1 50000.0 55204.19t110 4 i Chromium 2500.0i. 2762.31 110.5 _ Cobalt 2500.0 2793.09 111.7 er 2500.0; 2818.01 112.711 J ron 50000.0 54903.24 109.81 ;Lead 500.0 528.67; 105.7 iMa nesium 50000.0 53068.91;106.1 'Man anese 2500.01 2785.67; 111.41 (Nickel 2500.0 2765.691 110. 6f Fo-tassium 80000.0; 81142.361 101.4 'Selenium 500.01 533.64!106.7 Silver 1000.0! 109_7.35 109.7 iu Sodm I - r -- _ 80000.0 81926.58 102.4E Thallium 500.0 532.44 106.51 Vanadium 2500.0, 2781.08 111.2 �- - -- - - - Zinc 2500.0 2732.97 109.3 • FORM VII - IN %R U.S. EPA - CLP 8 STANDARD ADDITION RESULTS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Concentration Units: ug/L EPA SampleJAn 0 ADD 1 ADD 2 ADD 3 ADD Final No. ABS CON ABS j CON ABS CON ABS Conc.r �Q • • FORM VIII - IN ILM04.1 U.S. EPA - CLP 9 ICP SERIAL DILUTIONS Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Matrix (soil/water): WATER Concentration Units: ug/L --MW-1 S - SDG No.: TS1,001 Level (low/med): LOW Serial s Initial Sample Dilution �iDiffer- Analyte i Result (I) C �I Result (S) C;� enceIIQ M - ---- --- - - -- -- ---- --- - - - - E Aluminum 24.36 BI 32.501U 100.0', P Antimony 3.30 U i 16.501 U P - -- - Arsenic 3.47 Bi 9 501 U r- 100.0' P iBarium 5.49 B 8. 15 B i 48. P - r - Beryllium ; 0.43 B I 1.00 U 100.0 1 P: ,Boron _ 14.60 B 27.40 B 87.7 _ P - -- - - -- Cadmium �I 0.56 B 2.00`U 100. 01 P Calcium ;� 9259.07 9428 60 B I 1.8 P --- - --- - IChromium _ 1. 00 U 5.00 U 1� - Cob' ---alt 2.00 U 10 00, U' P -- - - - - -- �Copper -- 11 .97� B 12 65; B f } 5.7 1 P - � - Lead 1.90 379 10; B 0.2' f P Ma nesium 3761 39 U378 7 00 U P Iron I _ _ - - --- - - -- - -- �- _, B- - 3780.251B - 0.5 r P Manganese 38.82; 38 051B Nickel i '. 1.30 U 6 50 U i j P-1 Potassium i 1003.48 B 981.30:B 2.21 P ' - -- -- - �elenium 1 I- - 2.40 U 12.00 U P Sodium i 23805.101 U 2.00 U� P Silver _ it - _ 0 4 0 - �- -- -- - - _ 28171.65 18 . 3 E P V adium - 1.00 U' - 17 08f B -i P U 5.001Ui - - - Zinc 256.27j 255 00i I_--_ _0_.5 ! P `t - -- • FORM IX - IN ILM04.1 U.S. EPA - CLP • 10 INSTRUMENT DETECTION LIMITS (SEMI ANNUALLY) • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. ICP ID Number: TJA61EDV Flame AA ID Number: Furnace AA ID Number: Comments: Contract: SAS No.: Date: 10/4/2004 SDG No.: TSL001 Analyte Wave- length (nm) Back- CRDL ground (ug/L) IDL (ug/L) M Aluminum 308.21 200.0 6.5 P ,Antimony 206.84 60.0 3.3 P Arsenic 189.04 10.0 1.9 P Barium 493.41 200.0 1.2 P Beryllium 313.04 5.0 0.2 P Boron 249.68 500.0 1.7 P Cadmium 226.50 5.0 0.4 P Calcium 317.93 5000.0 16.9 P Chromium 267.72 10.0 1.0 P Cobalt 228.62 50.0 2.0 P Copper 324.75 25.0 0.9 P Iron 259.94 100_.0 1.3 P Lead 220.35 3.0 1.4 P Magnesium 279.08 6.2_ P Manganese 257.61 _5_000.0 15.0 ____ 0.5 P Nickel 231.60 40.0_____ 1.3 P Potassium 766.49 5000.0 11.1 P Selenium 196.03 _ 5.0 2.4 P Silver 328.07 10.0 0.4 P Sodium 589.001 5000.0 8.3 P _ Thallium 190.86 10.0 3.1 P Vanadium 292.40 50.0 1.0 P Zinc213.86 20.0 1.7 P I* FORM X - IN ILM04.1 • U.S. EPA - CLP 10 INSTRUMENT DETECTION LIMITS (SEMI ANNUALLY) Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. ICP ID Number: Flame AA ID Number: HYDRA Furnace AA ID Number: Comments: Contract: SAS No.: Date: 1/31/2005 SDG No.: TSL001 � Wave- length Back- CRDL IDL alyte (nm) ground (ug/L)(ug/L) M rcury 253. 661 0.2 0.11 CV • FORM X - IN ILM04.1 U.S. EPA - CLP • 10 INSTRUMENT DETECTION LIMITS (SEMI ANNUALLY) Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 ICP ID Number: Date: 5/28/2004 Flame AA ID Number: SPEC20D+ CN Furnace AA ID Number: Comments: • FORM X - IN - Wave--- length Back- CRDL -1 IDL Analyte C anide Y (nm) 578.30 ground (ug/L) 10.0 (ug/L) M� 10.tO r ` I - --L --_--� _ - - - , � Comments: • FORM X - IN U.S. EPA - CLP • 11A ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY) Lab Name: H2M LABS, I Lab Code: 10478 ICP ID Number Case No.: TJA61EDV Contract: NRAS No.: Date: SDG No.: TSL001 04/28/2004 1 Wave- Interelement Correction Factors for: 1 i length Analyte (nm) Al Ca Aluminum 308.22 0.0000000 0.0000000 Antimony 206.83 0.00000001 0.0000000 Arsenic 189.04 0.00006-0-01-- 0.0000000 Barium _493 41 0._00000001 0.0000000 0.0000000 Beryllium 313.04 0.0000000 Boron 249.68 1 0.0000000 0.0000000 Cadmium 226.50 0.00000001 0.0000000 (Calcium 317.93( 0.00000001 __ 0.0000000 ;Chromium 1 267.62 0.00000001 0.0000000 Cobalt � 228.62 � 0.00000001 0.0000000 0.0000000 ;Copier _324.75, 0.0-000-00-01 - -51_ ,1ron 259.94' ' 0 0000000, ;.Iron - 271.44+� 0.0000000+ _0.0000000 0.0000000 Lead --- - . 220.35 - L -0.1677000' 0.0000000 Lead 220.351 0 3420000 0.0000000 (Magnesium } 279.08i 0.0000000 0.0000000 'Manganese 257.611 0.0000000' 0 .00000001 FMolvbdenum� 202.03{ 0.0000000, 0.0000000 Nickel 231.601 0.000000 0.0000000 Potassium Selenium 766.49,; _196.03+ 0.0000000 0.0000000 0.0000000 0.0000)000 Selen_ium i 196.0{ 0.0000000 0._0000000 Silicon_ 288.16 0.0000000 0.0000000 1Silver _ 32 8.0-77-1i --- 0.00000001 - 1Sodium [Sodium ', 330.231 589.00 0.000000 0 0.00000001 _ _ 0.0000000 0.0000000 i Strontium 407.7711 0.0000001 0.00000001 Thallium 190.861 _0.0 . 000000; 0.0000000 Tin 189.991 0.00000001 0.00000001 Comments: • Fe Mg Co 0.000_00001 0.0000000; 0.0000000 1 0.0000000 _ 0.0000 00 0 0.0000000 -0.1480000 0.0000000 0.0000000 0.0000000 0.00000000.0000000 0.0000000' 0.00000000.0000000_ 0.0000560 0.0000000} 0.0001890 0.0000562 0.00_00000' 0.0000000 j 0.0000000 0.0000000 0.0000000 . 1 00000000 0.0000000 0.0000000 , 0.-000000_0 0.000_0000_0.0000000_ _-0. 0000000, 0. 0000000, _0. 0000000 0.0000000 0.00000 0 0.0000000 - - 0.00000001_ 0.0000000: 0.0000000 , 30 0.0400 00 0 0 00000001 0 00000 - - 4-- - - -- --- 0.0380000 0.0000000 0.0000000 0.0000000 0.00000001 0._0000_000_- 0.0000000' 0.00000001 0.0000000 0.00000001 0.0000000 0.0000000 1 0.0000000 0.0000000L 0.0006000 1 0.0000000, 0.0000000' 0.000000 0 . 0_0000000 -- o . 0_000000} 0 -0 9100000 1 0.0000000' 0.00000 0.2480000_ 0.0000000 0.0000000; 0.00_00000 -0.0170000 0.00000001 0.000000Q 0.000000_0 0.0000000: 0.0000000 0.0000000 0.0000000: 0.0000_000_ 0.00000001 0.0000000; 0.0000000 0.0000000 0_0000000 0.8200000j 0.0000000- _0.0000000: 0.-0000000 J U.S. EPA - CLP 0 11A ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY) Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No.: NRAS No.: SDG No.: TSL001 ICP ID Number: TJA61EDV Date: 04/28/2004 Wave- I� Interelement Correction Factors for: length Analyte (nm) Al Ca Fe Mg Co 'Titanium 334.94 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 Vanadium 292.40 0 0000000 0.0000000 0.0000000 0.0000000 0.0000000 Zinc 213.86 0 0000000' 0.0000000 0.00000001 0.0000000 0.0000000 Comments: • FORM XI (PART 1) - IN ILM04.1 N O E-� U.S. EPA - CLP • 11B ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY) Lab Name: H2M LABS. INC. Lab Code: 10478 Case No.: ICP ID Number: TJA61EDV Wave- ( Interelemeni I i length Analyte (nm) Cr Cu 0.0000000 i �Antmonm 206.83 I 5.5000000. - Y - -Y --- �Arsenic - i- 189.04 0.00000_00' - 'Barium _ 493.41 0.0000000 Beryllium 313.04 ____0_._0000000_____.______ 'Boron i 249.68 __ 0.0000000 Cadmium 226 50 0.0000000' ;Calcium 317.93,1 0.0000000 'Chromium 267.621 0.0000000 0Cobalt ! 228.62 0 0000000 copper i 324.75 0.0000000 !Iron 259.9 0.00000001 Iron 271.44 0 0000000 Lead 220.35,j 0.00000W Lead 220.35 �_ 0 0000000 ,Magnesium 279.08 0.0000000 Manganese 257.61 0 0000000 - - ,Molybdenum 202.033 0.0000000 iNickel i 231.6011 0.0000000. 1potassium 766.49 0.0000000 Selenium 196.031! 0.0000000 !Selenium 196.03 0.0000000 Silicon 288.16 0.0000000 -- - - - -- Silver 1 328 07,� _0_._0__0 00000 Sodium 330.231 006000OOt Sodium 589.00 1 0.00000001 ;Strontium 407.77, 0.0000000 Thallium 190.86 0.23350001 :Tin 189. 99, _; 0.0000000i Comments: 0 Contract: NRAS No.: SDG No.: TSL001 Date: 04/28/2004 Correction Factors for: Mn Ni V 0.0000000 0.00000000.0_140000 0.0000000 0.0000000 0.0000000 0.0000_000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0001200 0.0000000 0.0000000 0.0000000 - 0.0000000 0.0000600 0.0000000 0.0000000 0.0000000 0.0000000 --- - --- ------ 0.0000000 0.000006-0-1,0 .0000000 .I 0 0000000 0.0_000000 0.0000000 0.0000000 0.0000000! 0.0000000 I 0.0000000 ___0.0000000 0.0000000 0.0000000 0_.0000000. 0_.0000000 0.1300000 0.0000000 0.0000000_ 0.090 000i 0.0000000 0.0000000_- 1 -0.000000_0 0.0000000 0.0000000_ 0.0000000 0.0000000 0.0000000 _ 0.0000000 0.00000001 0.0000000 0.0000000 0.00000000 -0.000 00 00 0.0000000 0.00000001 0.000 00000 00 0.3409000 0.00000001 0.0000000_ 0.2200000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 -j ij- 0.0000000_-- 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 _0.0000000 i 0. 0000000, 0.00000001 0. 000000_0 _ 0.0000000 0.0000000 0.0000000 { 0.0000000',- 0.0000000 0.0000000 _I FORM XI (PART 2) - IN ILM04.1 U.S. EPA - CLP • 11B ICP INTERELEMENT CORRECTION FACTORS (ANNUALLY) Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No.: NRAS No.: SDG No.: TSL001 ICP ID Number: TJA61EDV Date: 04/28/2004 • Comments: • FORM XI (PART 2) - IN ILM04.1 !i Wave- Interelement Correction Factors for: length ,!Analyte (nm) Cr Cu Mn Ni V Titanium t 334.941 0.0000000 �0.0000000 0.0000000 0.0000000 Vanadium CZinc 292.40 213.86 1 0.0000000 0.00 0 0 0 0 0 _0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000 • Comments: • FORM XI (PART 2) - IN ILM04.1 U.S. EPA - CLP • 12 ICP LINEAR RANGES (SEMI ANNUALLY) Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 ICP ID Number: TJA61EDV Date: 10/04/2004 • Comments: 0 FORM XII - IN TInteg. Time Concentration Analyte (Sec.) (ug/L) M Aluminum 15.00 10.00000 P Antimo�_ _ - 15.00 100001p Arsenic 15.00 20000 P Barium 15.00 20000P Bervllium 15.00 10000 P Boron Cadmium 15.00 15.00 20000 P 20000 P Calcium 15.00 1000000 P !Chromium i- 15.00 50000 P Cobalt - 15.00 _ __ _ 50000 P Copper i 15.00 50000 P ,Iron 15.00 500000 P Lead 50000 P _ Magnesium j - rManganese _15.00 00 1000000 P -- 15.00 20000 P Nickel 'Potassium --- _ 15.00 15.00 - — - — 50000P 1 --- 200000 P Selenium !Silver r 15.00 15.00 - _ 10000P _ -_ 2000 P Sodium -! 15.00 y 500000 P Thallium Vanadium 15.00 15.00 50000 P 50000 P__ _J j!Zinc20000 - P - - — -1 0 FORM XII - IN • U.S. EPA - CLP 13 PREPARATION LOG Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: Method: P EPA Sample Preparation , Weight No. Date (gram) EQUIPT. BLANK 04/05/2005 LCSW 04/05/2005 - -- -r - 6-4-/-05-/-2-005 -,--- --- -- - - MW -1D � j Mw -is i 04/05/2005 I MW-1SD 04/05/2005 MW-1sS 04/05/2005 MW 3D 04/05/2005 Mw -3s 04/05/2005 _ MW -5D 04/05/2005 MW -5S_ 09/05/2005 MW -6D -- - -� 04/05/2005 - -- MW -6S 04/05/2005 MW-8D 04/05/2005 - - - - --- --- MW -8S 09/05/2005 PBW 04/05/2005 SDG No.: TSL001 Volume (mL) 50 __50 _ 50 50.---- 5 --0 50 --- 50 - -- ----50 50 -- 50 50 50 50 50---. j 50 • FORM XIII - IN ILM04.1 • Lab Name Lab Code Method: • H2M LABS, INC. 10478 Case No. CV U.S. EPA - CLP 13 PREPARATION LOG Contract: SAS No.: SDG No.: TSL001 EPA Sample Preparation I No. Date 1EQUIPT. BLANK 04/06/2005 IMw-1D 04/06/2005 !Mw -1s 04/06/2005 Mw-1SD 04/06_/20_05 Mw-lss 04/06/2005 _ Mw -3D 04/06/2005 �- Mw -3s 1 04/06/2005 Mw -5D # 04/06/2005 Mw- 6D 04/06/2005 Mw -6S Mw -8D 04/06/2005 04/06/2005 Mw -8S 04/06/2005 PBw 04/06/2005 Weight Volume (gram) (mL) ------- - ------100 100 100 100 _ 100 100 — - - - --- 100 - - - - - 0 100 100 100 - - -- - - - - - -- - 100-- 100 100 is FORM XIII - IN ILM04.1 U.S. EPA - CLP S 13 PREPARATION LOG Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Method: CA EPA 1 Sample I Preparation Weight Volume No. Date ! (gram) (mL) 1EQUIPT BLANK _ 04/05/2005 50 MW -1D 04/05/2005 r 50 Mw -1S 04/05/2005 50 MW-1SD 04/05/2005 50 - - - - - - -- -- — --- Mw-iss 04/05/2005 50 MW -3D 04/05/2005 50 Mw -3s I 04/05/2005 _ 50 I- -- - - -i— -- - - --- - - --_ -- ---- Mw-5D 1--04/05/2005 50 ----- - - --i -_� Mw 5S 04/05/2005 50 - - - - - t ---- - - - 5 0 MW -6D 04/05/200550 •_ 04/05/2005 -_I --- - - - ----� �04/05/2005 Mw -8 50 D - -_ Mw -8S 09/05/2005 50 _ PBw 04/05/2005 ' 50 ) . FORM XIII - IN ILM04.1 r J Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Instrument ID Number: TJA61EDV Start Date: 04/07/2005 EPA Sample D/F Time j No. 1 -A _.- SO . 1 .00 L- 0758 s -- 1-00 1 0807 Is 1.00 0821 s-1-00, 100, 0827 is - ; 1.00 ! 0834 IS ! 1 00 10841 i S 11.00 0_846 'ICV :1.00 ! 0850 ICV ;1 00 0900 :1 00 0910 1 00 0920 IICSA 1.00; 0938 ICSAB ;1.00 0948 CCv 1.00 0957 1 ccv 11.001 1007 CCB 1.00: 1017 PBW 1.00 1026 LCSW -1.00: 1036 Mw -is 1.00 1046 MW-1SD 1.00 1056 Mw-iSS 1.001 1105 MW-1SL ; 5.00 1115 MW -3D ;1-001 1125 MW -3S 1.00i 1134 MW -5D .1-00: 1144 MW -5S 1 1 00 ; 1154 ccv 1.00' 1203 ccv 1 .00 ; 1213 CCs 1.00, 1223 MW -6D 1.00 1233 MW -6S 1.00 1242 MW -8D .1.00 1252 MW -8S 1.00 1302 1r u U.S. EPA - CLP 14 ANALYSIS RUN LOG Contract: SAS No.: Method: P SDG No.: TSL001 End Date: 04/07/2005 Analytes L -r - SiA BIBIC C CjCLF PiM,M'HINKjSTA�N T V Z C B C M S S % R A! I I ff lBIS;A'E;D'A;R V EIB'G N1G`II fEIG A L N N O O I N 1-� - IxLXjlx'xlX{x1XIX] x!xlx1x!x x x x x x x x XI S x ' 1 1- 1 (i J - l-! --1 XL x x'• ;x� IX' IXI + 44 L 1 -�X 1 1- - ,L� -ix t—i X X] X -! x 1_X i--1- -1- x 1- l X- I I -1-- X x x x ! - i X l __ x L- - ice- -- ' -- - 1 I 1_ . I_1X1 L �J I-� _f _ X ------1 11- - �- - xIxLXLxjXjx!XIX�x�xlxlx X xrX1x;X LX X, xj jxixl -� - I �X X X X XjXX;X X XiX;X xlx XI XiXIX XIX X X X�- !x xl XIX: IXIXI 1x xl ;X' X X1 X X XjX XI - 1 - - r .- I r 1x x xlx x'x xlX x x x x xl Ix x .X X�xl x x } -- ----i - L--� i-- - 1 xlx`x xjx x x xlxjxlx;X'x.' Ix X x!x x xiX _xJ LX1XI !--:_X1--I!X,-- x;x-;x1x;x X;x x X'x'x xx, Ix Xlx x x x,x'xj x X 1 `- _- I - -� -L - - �_- 1X XIx x'Xlxlx X Xlx XiX X- tX1X xixL �X-I�XL IX 1-L.� - X X;XIXIXtX X X!XiX X XiX1 IX1X!X�X X1X X XI ix X X X X x!-x�xiXlxlX,X X XLX� IX'x1X'X X!X!X,x1 Ix x X XIX'X!XIXIX X':X_X XIIX'X X�X1,x x X XIX X IX X i I 1 i i -._X L I X X�1 X' X. iX i X! X-1 X I XiXL�_X..�_ X X X XIX XI jX 1 1•X x x xIxtx,x,XIX xlx1x,xl X xIxIX x1XIX X Ix X I �x:xlx,x;x�XIXIX.[Xjx�xLx;x, X�;x XIX1x X X xix xLX1:X X1-x'Xtx+_x -x x x x X_ --1,X- xiX x -x X'X XJ x X 1 ,, � i '! I I ; I � I I I 1 x Xlx X_i_xlx'X xi-Xlx x[xlxl X.!Xlxix-X_ix;XIX 1X_xI_ i ---� ,X X'X X X X X XI,X x;x X X 1XIX'X X x1xIx,XI '•XjX� X X X XIX X- -� L -- - i I _-. l J— i.- i L -'— - i I x x;xxlx�xlxL �X xlxlX'X�x1xIX� �Xi L_�—J j , �`- - - X x'x X X x x x!x x x_ xlX x x x X X x x;X 'xlx I X X'X;XIX.X`X{X1 x X X X'•x x xi ;X!X; � X X XX X - - -- -- - - x - --I - I - X X X X X X, X X LX X X X X X X �X' X - - - -- - - X X X XIX X X X X!X-X XIX X X,X X X,X X X -X'x FORM XIV - IN ILM04.1 00 E--� U.S. EPA - CLP 14 ANALYSIS RUN LOG Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Instrument ID Number: TJA61EDV Method: P Start Date: 04/07/2005 End Date: 04/07/2005 EPA Analytes Sample ' D/F Time i I i N KTS A N T V Z C B C M S S p R 'A�SjA B'B,CJC CC1F P M,M�H--- No. j L B SjA EIDIAIR!UIEB GIN GII iEIG A L N N OIO I N j ! I I 111 I i 1 00 i 1311 X X X1 X -X X X X X X IPT. BLANK 1_ 11 X� l X X X X X X X X X X I - -_ -L- 1 J _ I -��_ �__1 l- --1-1 1-� - ! • X X. _ IXIX!X!XIX X XIX X X X�X1x X!X X X x XIX X -_ -1 L -L _ = L 1--1--� _ ��--Lx—L_1__ LLI CRI 1D 1.00 1331 j IXIX �X'X XIXI !X Xj IX, X!X IXIX� X -- - I - - it _� x! !X, ---LX ---- - ! _� A. ICSA 1.00 134 6 X X X X � X I X X X X X' X X X I X1X � X X X X x ;CCVAB 1. 00, 1406 Ix x!xlxlxTx xlx Ix'xx!x1xl lxlx1xix!xjx x xi Ix.x �l - -00' 1356 -- - i XiCCv 1.001915 -- X B1 .00 1 1425 XXx x�xixlxlXX x fXIX xiXIX IX 'CCXX -AX L�X • . I -� FORM XIV - IN 0 ILM04.1 O C!� U.S. EPA - CLP 14 ANALYSIS RUN LOG Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Instrument ID Number: HYDRA Method: CV Start Date: 04/07/2005 End Date: 04/07/2005 EPA % { Analytes No. L�B4SIA�EID LR UiE�BG�NIG!I� E G A� --- - Sample D/F 1 Time % R A, S A B B C 1 C C C F P M M H N K T� V Z C B C M 8 li II I L �� N N O N - { — I i I 1 1 I J--L_LL _ 1 1_ i 1 l 1-- _ I- zzzzzz - L1. o0 1015 - 1- 1 i 1 -- X I i �_ zzzzzz 1.00 1017 L 1_ IX1__1 _ -- _ 1 -- L zzzzzz 11.00 1019 I i X1 II I - 4-- ZZZZZZ 11.00 { 1021 I X { zzzzzz I - -- -- - 1 - - - 1_ 00 1023 ! ( -I 1 1_-� 1 X I I _. _ ZZZZZZ 1 00 ; 1024 I I 1 1 I l L �� 1 - - -- X I ICV 1 00 1027 - XI — ICB I1.00 x1029 - }__ - 1.031--x 11-001 X 1 1.00 1 1033 ccv 1.00 i — — — I , 1 i x 1 j I 1.001 1039 X :PBw 1.00 ; 1037 1 1 I I I X MW -1D 1.00 1 1039 I —I -X : MW -1S i1.00 i 1040 { I X MW-1SD 1.00; 10431 IX A - . I i I _ fi 1_ 1 f i MW-1SS 1.00 1045 MW -3D 1.00 1097 X 1 MW -3S 1.00 1049 X--- MW-5D 11.001 1051 I X-1 - CCv 1.00 1 1055 1 - X I- - iCCB 1.00 1057 1- -MW-6D 1 1.00 ' 1059. MW -6S 1 00 1 1101 X I - I I MW -8D ;1.00; 1103 X ! MW 8S ;1.00 1105 i X IPT. BLANK11.00 1107 i I 1 X ZZZZZZ 1.00 1110 _L , I L --i_ }- . ---j `- A - �._ 1 J I --' 1 ! l L ZZZZZZ 1.00 ZZZZZZ 1.00 1113 zzzzzz 1.00 1115 ZZZZZZ 1.00 1117 ccv 1.00 1119 f X: CCB 1.00 1122 X 0 FORM XIV - IN ILM04.1 00 • Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Instrument ID Number: HYDRA Start Date: 04/07/2005 U.S. EPA - CLP 14 ANALYSIS RUN LOG Contract: SAS No.: Method: CV End Date: SDG No.: TSL001 04/07/2005 T _EPA -- - —I Analytes Sample D/F Time ! o R �A S A�BIBICrcTc C' F T P i M F M H� N j K�S A N T� V Z C B C M S S No. I L;IB S'AEID`A,R,UIE!BiG N�G II E G Ajhl IN�N� 010 I N - ;zzzzzz 1. A— I I I I - 1129 --' 1 zzzzzz__- �lo.00; 1125 I __�_ 1 I -- ! i' ! i �!- ZZZZZZ 1.00 1127 -- ! 1_ I l_- _ 1- l- l__-1 1 1 _J_ --ZZZZZZ 1.00 129 -- ---- _ — _ I _ 1- _I - IL --1 -1IJ ;ZZZZZZ 1.00 1132 1 i I I I - 1 1- I 1 __ I_J 11 1-L 'ZZZZZz- 11.001 1139-- I -- ,- - ;ZZZZZZ 1.00 1136 ' I zzzzzz :1.00 1138. I } 4� 1 i. ZZZZZZ 1.00 1140 7 7. 1.00 11142 Z 1.00 . 1144 1 - ZZZZZZ 1.00 r 1146 zzzzzz 11.00' 1148 L zzzzzz:1.00I , 1150 1 1 I I zzzzzz 1.00 1151 I J - i ZZZZZZ 1.00 115 5 1154 :ZZZZZZ 11.00 -_1 zzzzzz 1.00' 1157 i L zzzzzz 1. o0 1201 1 . -� I --� _� I ZZZZZZ 11-00 1 1159 I ZZZZZZ;1.00! 1203 -_ --i— ZZZZZZ 1.00: 1205 - . L zzzzzz 1.00 11208- ! zzzzzz 1.00 1210 .ZZZZZz 1.00 1211 : zzzzzz 1.001 1213 j - - -- - -- - zzzzzz 1.00 1215 L i zzzzzz 1.00 1217 zzzzzz 1.00 1219 zzzzzz 1.00' 1221 zzzzzz 1.00 1223 - - ZZZZZz 1.00 1224 - zzzzzz 1.00 1226 FORM XIV - IN ILM04.1 00 COO Lab Name: H2M LABS, INC. Lab Code: 10478 Case No. Instrument ID Number: HYDRA Start Date: 04/07/2005 U.S. EPA - CLP 14 ANALYSIS RUN LOG Contract: SAS No.: Method: CV End Date: SDG No.: TSL001 04/07/2005 EPA Analytes Sample D/F Time i s R A S. A B B C �C C:C F;P�M1M�H N K�S AIN T V�ZICIB�C M -I No. I j L_. 1 00 L.B'SIA E,DiAjRiU 1 i �;.;_� E!B G'N,G I E�GA�L 1 'NIN 010 � j ZZZZZZ - -. zzzzzz 1. oo 1230 - - - -- 1 ! - 1 - ----1 - �- - :-�--LI---1- — i I ; - zzzzzz 1.00 L1231 . FORM XIV - IN ILM04.1 M O U.S. EPA - CLP 14 ANALYSIS RUN LOG Lab Name: H2M LABS, INC. Contract: Lab Code: 10478 Case No. SAS No.: SDG No.: TSL001 Instrument ID Number: SPEC20D+ CN Method: CA Start Date: 04/05/2005 End Date: 04/05/2005 { EPA Analytes o '1 �.T ---... - T SLA N TiVZTCrB C M S S Sample D/F Time b R A (STA B B C C C C F P M �M H N K No. I LIBiSiA E'DIAR�`E B GINIGiI EAG A L' 1NIN' �O O I N I I so --- 1.001 0900 i--1 i 1 I i l_ LL 1 L L-1 x s10-�i.001 0901 i -i I 1 _� l- 1 I I_ 1 x_ _L Li S50 1.00 0902 l- L I. 1 - ! 1 LX i J r I- -- jS100 1.00 , 0903- 5100 1.00 0904 ICV 1 1. 001 0930E L j L---- _.I - 1-X�-- - - --- ICB 1.000931 i_i _ ' X �- - - — I f CRI 1.00 0932 . X -.IX _1 - 1 cCV - - L 1.00 0933 1— - - -! - - -- -- -1 -J- 1 1 1.00 0934 I 1 i f X 1. 00 0935 zzzzzz 1.00 0936 - i.__—L _ i 1 IMW-3D 1.00 0937 j i X L - _- I _ 1. 00� I 0938 i � i i I i . X Mw 5D 11.001 0939I I X 1- i � I MW 5S 1 .00 0940 '- X - -- l - --_ 1 1 -1 Ji - - -- MW -6D 1.00 ; 0941 I -I- X- 1--1 Ccv 11.00 0942 X I - 00 _ 0943 1 1 1 _! i MW -6S 1.00 0944 - I 1 1X - L 1 jM 8D 0 0945 MW -8S 1 1.00 1 0946 1 X IPT. BLANK 1.00J 0947 IX 1 _ _ -� II f MW -1D �000948 ; i � X t 1111 Mw -is 1 .00 ' 0949 I= 1 x-� I- - - - - - 1- Mw-iss '1.00! 0950 I ; 'X L. 1 _----�—- L —�- i I_ MW-1SD 1 .00 ! 0951 -_ I 1- - 1--1 IX ZZZZZZ ;1.00' 0952 f zzzzzz 1.00 0953 � ! I zzzzzz 1.00; 0959 ccv 1.00 0955 - - - .x CCB 1.00 0956 X •FORM XIV - IN ILM09.1 00 U2M LABS, INC. 0 III. RAW DATA FOR METALS A. ICP DATA B. HG DATA C. CYANIDE DATA • • L U) T � , w H N N �. z a Z0 a T N v v N 0 V v N N M M M W J H U. Q ~ J Z U) w ►- o z z w LU N H H N cf > s Z toSampler Report Table: M040605 04/07/05 07:53:35 AM ble Name: M040605 Autosampler Type: TYPE TJA mple Positions: 0/96 QC Positions: 12/19 # Sets: 1 ns e tation location is rack -1, pos. -1. ks --- ck # Type Usage ------------ #Pos Left --------- Analyses/Pos ------------ ---- 1 -------------------- Aux. (L) Rack STD/QC/BLANK 12 10 2 Sample (28mm) Samples 0 1 3 Sample (28mm) Samples 0 1 4 Sample (28mm) Samples 0 1 5 Sample (28mm) Samples 0 1 - Sample Sets --- t# Type Prepare? 1 Normal No - Preparation Info --- t# Uptake Uptake#2 -- -------- -------- Samples Prepared. ck #1 Description Method #Pos Rack# *FromMTD 96 2 Final Dil.Factor ------------------ )sw 0- Col Sample Name Set # #Used -- --- 1 - 1 1 --- 1 --------- - StdNAKHI --- ----- -NA- ----- 1 --Type-- ---- Standard 2 1 2 StdFENAL -NA- 1 Standard 3 1 3 StdMULTI -NA- 1 Standard 4 1 4 StdFURNC -NA- 1 Standard 5 1 5 StdICSEL -NA- 1 Standard 6 1 6 StdAGPSB -NA- 1 Standard 7 1 7 StdBLANK -NA- 1 Standard ...19 8 Not Used) -NA- Sample 9 Lck #2 >s Row Col - Sample Name Set # #Used Type -- --- 1 1 --- 1 -------------------- ICV ----- 1 ----- -NA- ------------ Sample 2 1 2 ICVL 1 -NA- Sample 3 1 3 ICB 1 -NA- Sample 4 1 4 CRII 1 -NA- Sample 5 1 5 ICSAI 1 -NA- Sample 6 1 6 ICSABI 1 -NA- Sample 7 1 7 CCV1 1 -NA- Sample 8 1 8 CCVL1 1 -NA- Sample 9 2 1 CCB1 1 -NA- Sample .0 2 2 MB -13147 1 -NA- Sample _1 2 3 LCS-13147 1 -NA- Sample _2 9 2 4 0504067-002G 1 -NA- Sample .3 2 5 0504067-002GDUP 1 -NA- Sample _4 2 6 0504067-002GMS 1 -NA- Sample page 1 StartPos 1 itoSampler Report Table: M040605 04/07/05 07:53:35 AM page 2 ick #2 >sI Row Col Sample Name Set # #Used Type _5 2 7 - - 0504067-002GSD 1 -NA- Sample _6 2 8 0504024-001G 1 -NA- Sample _7 3 1 0504024-002G 1 -NA- Sample -8 3 2 0504024-003G 1 -NA- Sample _9 3 3 0504024-004G 1 -NA- Sample ?0 3 4 CCV2 1 -NA- Sample ?1 3 5 CCVL2 1 -NA- Sample ?2 3 6 CCB2 1 -NA- Sample ?3 3 7 0504024-005G 1 -NA- Sample 24 3 8 0504024-006G 1 -NA- Sample ick #3 )s Row Col Sample Name Set # #Used Type -- 1 --- 1 --- 1 -------------------- 0504024-007G ----- 1 ----- -NA- ------------ Sample 2 1 2 0504024-008G 1 -NA- Sample 3 1 3 0504024-009G 1 -NA- Sample 4 1 4 0504067-001G 1 -NA- Sample 5 1 5 CRIF 1 -NA- Sample 6 1 6 ICSAF 1 -NA- Sample 7 1 7 ICSABF 1 -NA- Sample 8 1 8 CCV4 1 -NA- Sample 9 2 1 CCVL4 1 -NA- Sample 10 2 2 CCB4 1 -NA- Sample 11 2 3 ( empty ) 1 -NA- -NA- 12 2 4 ( empty ) 1 -NA- -NA- 13 2 5 ( empty ) 1 -NA- -NA- 14 2 6 ( empty ) 1 -NA- -NA- 15 2 7 ( empty ) 1 -NA- -NA- 16 2 8 ( empty ) 1 -NA- -NA- 17 3 1 ( empty ) 1 -NA- -NA- 18 3 2 ( empty ) 1 -NA- -NA- 19 3 3 ( empty ) 1 -NA- -NA- 20 3 4 ( empty ) 1 -NA- -NA- 21 3 5 ( empty ) 1 -NA- -NA- 22 3 6 ( empty ) 1 -NA- -NA- 23 3 7 ( empty ) 1 -NA- -NA- 24 3 8 ( empty ) 1 -NA- -NA- ack #4 os Row Col Sample Name Set # #Used Type -- --- 1 1 --- 1 -------------------- ( empty ) ----- 1 ----- -NA- ------------ -NA- 2 1 2 ( empty ) 1 -NA- -NA- 3 1 3 ( empty ) 1 -NA- -NA- 4 1 4 ( empty ) 1 -NA- -NA- 5 1 5 ( empty ) 1 -NA- -NA- 6 1 6 ( empty ) 1 -NA- -NA- 710 1 7 ( empty ) 1 -NA- -NA- 8 1 8 ( empty ) 1 -NA- -NA- 9 2 1 ( empty ) 1 -NA- -NA- 00 O O L/1 A oSampler Report Table: M040605 04/07/05 07:53:35 AM page 3 ack #4 :)s #w Col Sample Set # #Used Type --- LO 2 --- 2 -Name - ( empty ) --- ----- 1 ----- -NA- ------------ -NA- L1 2 3 ( empty ) 1 -NA- -NA- L2 2 4 ( empty ) 1 -NA- -NA- 13 2 5 ( empty ) 1 -NA- -NA- L4 2 6 ( empty ) 1 -NA- -NA- 15 2 7 ( empty ) 1 -NA- -NA- L6 2 8 ( empty ) 1 -NA- -NA- L7 3 1 ( empty ) 1 -NA- -NA- 18 3 2 ( empty ) 1 -NA- -NA- 19 3 3 ( empty ) 1 -NA- -NA- 20 3 4 ( empty ) 1 -NA- -NA- 21 3 5 ( empty ) 1 -NA- -NA- 22 3 6 ( empty ) 1 -NA- -NA- 23 3 7 ( empty ) 1 -NA- -NA- 24 3 8 ( empty ) 1 -NA- -NA- ack #5 Ds Row Col Sample Name Set # #Used Type -- --- 1 1 --- 1 -------------------- ( empty ) ----- 1 ----- -NA- ------------ -NA- 2 1 2 ( empty ) 1 -NA- -NA- 3 1 3 ( empty ) 1 -NA- -NA- 4 1 4 ( empty ) 1 -NA- -NA- 5 1 5 ( empty ) 1 -NA- -NA- 6• 1 6 ( empty ) 1 -NA- -NA- 7 1 7 ( empty ) 1 -NA- -NA- 8 1 8 ( empty ) 1 -NA- -NA- 9 2 1 ( empty ) 1 -NA- -NA- 10 2 2 ( empty ) 1 -NA- -NA- 11 2 3 ( empty ) 1 -NA- -NA- 12 2 4 ( empty ) 1 -NA- -NA- 13 2 5 ( empty ) 1 -NA- -NA- 14 2 6 ( empty ) 1 -NA- -NA- 15 2 7 ( empty ) 1 -NA- -NA- 16 2 8 ( empty ) 1 -NA- -NA- 17 3 1 ( empty ) 1 -NA- -NA- 18 3 2 ( empty ) 1 -NA- -NA- 19 3 3 ( empty ) 1 -NA- -NA- 20 3 4 ( empty ) 1 -NA- -NA- 21 3 5 ( empty ) 1 -NA- -NA- 22 3 6 ( empty ) 1 -NA- -NA- 23 3 7 ( empty ) 1 -NA- -NA- 24 3 8 ( empty ) 1 -NA- -NA- 0 Cls O O C/) H andardization Rpt. ,thod: DVCLPI Standard: StdBLANK in Time: 04/07/05 07:58:13 ?leo Ag Al As1890 Avg .00013 .0090 -.03253 >Dev 00029 .0003 .00235 5RSD 217.14 3.796 7.2102 #1 .00017 .0089 -.03049 #2 .00040 .0093 -.03509 #3 -.00017 .0086 -.03201 "lem Cd Co Cr kvge -.0002 -.0002 .0003 3Dev .0005 .0003 .0001 RSD 269.7 191.6 21.97 #1 -.0002 .0002 .0002 #2 .0003 -.0002 .0003 #3 -.0007 -.0004 .0003 E1 em kvge 3Dev -RSD #1 #2 #3'0 Clem %vge 3Dev ''RSD 41 42 43 Clem %vge 3Dev 6RSD 41 42 43 • Mg .0001 .0001 100.3 .0001 .0000 .0001 2203/1 -.00602 .00292 48.428 -.00935 -.00389 -.00484 Mn .0002 .0001 25.41 .0002 .0002 .0003 2203/2 .00381 .00269 70.448 .00228 .00692 .00225 V Zn .0004 .0001 .0001 .0001 18.35 173.2 .0004 .0000 .0003 .0000 .0004 .0002 Mo .0006 .0006 96.16 .0004 .0013 .0002 Sb2068 .00500 .00275 54.926 .00758 .00211 .00530 04/07/05 08:07:48 AM page 1 G B .0022 .0007 32.69 0022 0029 0014 Cu .0103 .0001 1.285 .0104 .0102 .0104 Na .0008 .0005 63.55 .0002 .0011 .0012 1960/1 -.00370 .00320 86.604 -.00672 -.00034 -.00403 Ba .0004 .0000 8.995 .0003 .0004 .0003 Fe .0015 .0003 21.57 .0011 .0018 .0015 Na 0991 .0012 1.198 .1001 .0994 .0978 1960/2 .00837 .00279 33.282 .01145 .00760 .00605 Be .0011 .0001 5.780 .0010 .0011 .0012 Fe .0208 .0001 .4285 .0207 .0207 .0209 Ni .0014 .0005 33.08 .0017 .0016 .0009 Sn -.0020 .0012 61.59 -.0034 -.0014 -.0012 Ca .0049 .0001 1.115 .0048 .0049 .0050 K .0213 .0025 11.59 .0190 .0210 .0240 P .0003 .0013 485.0 .0005 -.0011 .0014 T11908 -.00342 .00139 40.575 -.00182 -.00434 -.00409 andardization Rpt. !thod: DVCLPI Standard: StdAGPSB in Time: 04/07/05 08:07:56 'sl Ag P Sb2068 Avg 1.6120 1.461 2.9750 3Dev .0032 .010 .0105 '3 -RSD .20145 .6682 .35310 11 1.6100 1.450 2.9629 #2 1.6157 1.467 2.9805 #3 1.6102 1.468 2.9816 • • 04/07/05 08:14:24 AM page 1 andardization Rpt. �thod: DVCLPI Standard: StdICSEL .in Time: 04/07/05 08:14:32 04/07/05 08:20:13 AM page 1 ;lAl Ca Fe Mg Avg 16.72 21.02 4.889 3.988 3Dev .15 .21 .048 .041 '6RSD .8950 .9820 .9831 1.018 #1 16.55 20.78 4.834 3.941 42 16.81 21.12 4.912 4.006 43 16.81 21.16 4.922 4.015 • • :andardization Rpt. 04/07/05 08:27:31 AM page 1 �thod: DVCLPI Standard: StdICSEL in Time: 04/07/05 08:21:49 :;,j Al Al Ca Fe Mg Avg 16.62 20.61 4.844 3.933 3Dev .01 .02 .003 .004 oRSD .0463 .1139 .0606 .1076 41 16.61 20.59 4.841 3.928 42 16.62 20.62 4.845 3.936 #3 16.63 20.63 4.847 3.935 • andardization Rpt. 04/07/05 08:34:06 AM -,thod: DVCLPI Standard: StdFURNC in Time: 04/07/05 08:27:38 3140 As1890 2203/1 2203/2 1960/1 1960/2 T11908 Wge 2.8579 2.7972 2.4488 .44362 1.0164 .77257 SDev .0091 .0031 .0058 .00069 .0070 .00230 'sRSD .31792 .11243 .23491 .15458 .68764 .29759 41 2.8631 2.8001 2.4554 .44284 1.0119 .77446 42 2.8631 2.7977 2.4463 .44390 1.0245 .77001 43 2.8474 2.7939 2.4447 .44412 1.0130 .77323 is page 1 'It O E -i andardization Rpt. 04/07/05 08:41:29 AM page 1 �thod: DVCLPI Standard: StdMULTI in Time: 04/07/05 08:34:14 ?lB Ba Be Cd Co Cr Cu WC 5.833 8.196 19.35 27.95 3.888 3.577 5.438 3Dev .006 .011 .03 .04 .019 .003 .003 -RSD .1019 .1306 .1546 .1453 .4968 .0729 .0548 41 5.832 8.186 19.32 27.91 3.869 3.577 5.441 $2 5.828 8.195 19.34 27.94 3.888 3.574 5.436 0 5.840 8.207 19.38 27.99 3.908 3.579 5.436 31em Mn Mo Ni Sn V Zn %vge 3.271 5.543 7.672 6.972 2.610 1.051 3Dev .003 .009 .012 .014 .003 .001 'sRSD .0876 .1582 .1621 .1975 .0986 .0992 41 3.270 5.533 7.685 6.958 2.609 1.051 42 3.269 5.547 7.670 6.971 2.609 1.051 43 3.275 5.548 7.661 6.986 2.613 1.052 • :andardization Rpt. �thod: DVCLPI Standard: in Time: 04/07/05 08:41:36 ;1 Fe Na kvg 5.229 15.13 >Dev .003 .05 'sRSD .0574 .3070 11 5.233 15.17 #2 5.227 15.08 #3 5.227 15.14 • s StdFENAL 04/07/05 08:46:31 AM page 1 --andardization Rpt. ethod: DVCLP1 Standard: StdNAKHI in Time: 04/07/05 08:46:39 Sl� K Na Avg 67.29 1.248 SDev .07 .001 6RSD .1055 .0497 #1 67.34 1.248 42 67.31 1.249- 43 .249#3 67.21 1.248 • 04/07/05 08:50:47 AM page 1 -andardization Report 04/07/05 08:50:47 AM page 1 �thod: DVCLPI Slope = Conc(SIR)/IR tem Wavelen High std Low std Slope Y -intercept Date Standardized 3 & 328.068 StdAGPSB StdBLANK 1240.82 -.164741 04/07/05 08:46:39 1 308.215 StdICSEL StdBLANK 1.51186 .013417 04/07/05 08:46:39 31890 189.042 StdFURNC StdBLANK 345.974 11.2544 04/07/05 08:46:39 249.678 StdMULTI StdBLANK .857460 -.001863 04/07/05 08:46:39 3 493.409 StdMULTI StdBLANK .610096 -.000221 04/07/05 08:46:39 313.042 StdMULTI StdBLANK .258486 -.000281 04/07/05 08:46:39 317.933 StdICSEL StdBLANK 1.81238 -.003078 04/07/05 08:46:39 3 226.502 StdMULTI StdBLANK .178896 .000034 04/07/05 08:46:39 D 228.616 StdMULTI StdBLANK 1.28583 .000197 04/07/05 08:46:39 r 267.716 StdMULTI StdBLANK 1.39809 -.000427 04/07/05 08:46:39 Li 324.754 StdMULTI StdBLANK .921197 -.009508 04/07/05 08:46:39 e 259.940 StdFENAL StdBLANK .960003 -.019964 04/07/05 08:46:39 e 271.441 StdICSEL StdBLANK 20.6499 -.030344 04/07/05 08:46:39 766.491 StdNAKHI StdBLANK 1.36625 .004309 04/07/05 08:46:39 279.079 StdICSEL StdBLANK 1.15566 .000092 04/07/05 08:46:39 n 257.610 StdMULTI StdBLANK 1.52850 -.000350 04/07/05 08:46:39 0 202.030 StdMULTI StdBLANK .902179 -.000567 04/07/05 08:46:39 a 330.232 StdNAKHI StdBLANK 1.30916 -.001067 04/07/05 08:46:39 a 588.995 StdFENAL StdBLANK .332652 -.032956 04/07/05 08:46:39 i 231.604 StdMULTI StdBLANK .651870 -.000907 04/07/05 08:46:39 178.287 StdAGPSB StdBLANK 3.42186 -.000923 04/07/05 08:46:39 203/1 220.351 StdFURNC StdBLANK 356.729 2.14847 04/07/05 08:46:39 203/2 220.352 StdFURNC StdBLANK 409.001 -1.55968 04/07/05 08:46:39 b2068 206.838 StdAGPSB StdBLANK 673.394 -3.36482 04/07/05 08:46:39 960 1 196.021 StdFURNC StdBLANK 2235.53 8.26948 04/07/05 08:46:39 96 196.022 StdFURNC StdBLANK 991.983 -8.29976 04/07/05 08:46:39 n 189.989 StdMULTI StdBLANK .716993 .001434 04/07/05 08:46:39 11908 190.864 StdFURNC StdBLANK 1288.69 4.40505 04/07/05 08:46:39 292.402 StdMULTI StdBLANK 1.91572 -.000695 04/07/05 08:46:39 n 206.200 StdMULTI StdBLANK 4.75683 -.000274 04/07/05 08:46:39 b2203 220.353 NONE NONE 1.00000 .000000 *NOT STANDARDIZED e1960 196.026 NONE NONE 1.00000 .000000 *NOT STANDARDIZED 00 �O O O H tandardization Readback Report 04/07/05 08:50:47 AM ethod: DVCLPI let Wavelength Standard g 328.068 StdBLANK StdAGPSB lement Wavelength Standard 1 308.215 StdBLANK StdICSEL lement Wavelength Standard s1890 189.042 StdBLANK StdFURNC lement Wavelength Standard 249.678 StdBLANK StdMULTI dement Wavelength Standard ,a 493.409 StdBLANK StdMULTI ;lement Wavelength Standard ce • 313.042 StdBLANK StdMULTI :lement Wavelength Standard 'a 317.933 StdBLANK StdICSEL :lement Wavelength Standard 'd 226.502 StdBLANK StdMULTI ,lement Wavelength Standard 10 228.616 StdBLANK StdMULTI ;lement Wavelength Standard 'r 267.716 StdBLANK StdMULTI Known Concentration .000000 2000.00 Known Signal .026972 25.1414 Known Concentration .000000 1000.00 Known Concentration .000000 5.00000 Known Concentration .000000 5.00000 Known Concentration .000000 5.00000 Known Signal .005809 37.3551 Known Concentration .000000 5.00000 Known Concentration .000000 5.00000 Known Concentration .000000 5.00000 Measured Concentration .000000 2000.00 Measured Signal .008966 16.6206 Measured Concentration -.000000 1000.00 Measured Concentration .000000 5.00000 Measured Concentration .000000 5.00000 Measured Concentration -.000000 5.00060 Measured Signal .004903 20.6127 Measured Concentration -.000000 5.00000 Measured Concentration .000000 5.00000 Measured Concentration -.000000 5.00000 Known Measured "lement Wavelength Standard Concentration Concentration lu324.754 StdBLANK .000000 .000000 • StdMULTI 5.00000 5.00000 page 1 Residual Concentration -.000000 .000000 Residual Signal .018006 8.52081 Residual Concentration .000000 .000000 Residual Concentration -.000000 .000000 Residual Concentration -.000000 .000000 Residual Concentration .000000 -.000600 Residual Signal .000905 16.7424 Residual Concentration .000000 .000000 Residual Concentration -.000000 .000000 Residual Concentration .000000 .000000 Residual Concentration -.000000 .000000 O H tandardization Readback Report 04/07/05 08:50:47 AM lement Wavelength Standard e • 259.940 StdBLANK StdFENAL lement Wavelength Standard e 271.441 StdBLANK StdICSEL lement Wavelength Standard 766.491 StdBLANK StdNAKHI ;lement Wavelength Standard [g 279.079 StdBLANK StdICSEL :lement Wavelength Standard In 257.610 StdBLANK StdMULTI :lement Wavelength Standard 10 202.030 StdBLANK • StdMULTI :lement Wavelength Standard 1a 330.232 StdBLANK StdNAKHI ;lement Wavelength Standard 1a 588.995 StdBLANK StdFENAL ;lement Wavelength Standard 7i 231.604 StdBLANK StdMULTI ;lement Wavelength Standard ? 178.287 StdBLANK StdAGPSB dement Wavelength Standard ?203/1 220.351 StdBLANK • StdFURNC Known Measured Concentration Concentration .000000 .000000 5.00000 5.00000 Known Measured Concentration Concentration .000000 .000000 100.000 100.000 Known Measured Signal Signal .033463 .021338 91.9351 67.2868 Known Measured Signal Signal .000159 .000057 4.54544 3.93313 Known Measured Concentration Concentration .000000 -.000000 5.00000 5.00000 Known Measured Concentration Concentration .000000 .000000 5.00000 5.00000 Known Measured Signal Signal .000034 .000841 1.63314 1.24829 Known Measured Concentration Concentration .000000 .000000 5.00000 5.00000 Known Measured Concentration Concentration .000000 .000000 5.00000 5.00029 Known Measured Concentration Concentration .000000 .000000 5.00000 5.00000 Known Measured Concentration Concentration .000000 .000000 1000.00 1000.00 page 2 Residual Concentration -.000000 .000000 Residual Concentration -.000000 .000000 Residual Signal .012124 24.6483 Residual Signal .000101 .612309 Residual Concentration .000000 .000000 Residual Concentration -.000000 .000000 Residual Signal -.000807 .384855 Residual Concentration -.000000 .000000 Residual Concentration -.000000 -.000291 Residual Concentration -.000000 .000000 Residual ConcentratiorO -.000000 .000000 O H tandardization Readback Report 04/07/05 08:50:47 AM Known Measured lement Wavelength Standard Concentration Concentration 2034 220.352 StdBLANK .000000 -.000000 StdFURNC 1000.00 1000.00 lement Wavelength Standard b2068 206.838 StdBLANK StdAGPSB lement Wavelength Standard 960/1 196.021 StdBLANK StdFURNC lement Wavelength Standard 960/2 196.022 StdBLANK StdFURNC lement Wavelength Standard n 189.989 StdBLANK StdMULTI lement Wavelength Standard 11908 190.864 StdBLANK • StdFURNC lement Wavelength Standard 292.402 StdBLANK StdMULTI lement Wavelength Standard n 206.200 StdBLANK StdMULTI lement Wavelength Standard b2203 220.353 NONE NONE 'lement Wavelength Standard e1960 196.026 NONE NONE • Known Concentration .000000 2000.00 Known Concentration .000000 1000.00 Known Concentration .000000 1000.00 Known Concentration .000000 5.00000 Known Concentration .000000 1000.00 Known Concentration .000000 5.00000 Known Concentration .000000 5.00000 Known Signal .000000 .000000 Known Signal .000000 .000000 Measured Concentration -.000000 2000.00 Measured Concentration -.000000 1000.000 Measured Concentration .000000 1000.00 Measured Concentration .000000 5.00000 Measured Concentration .000000 1000.000 Measured Concentration .000000 5.00000 Measured Concentration .000000 5.00000 Measured Signal .000000 .000000 Measured Signal .000000 .000000 page 3 Residual Concentration .000000 .000000 Residual Concentration .000000 .000000 Residual Concentration .000000 .000061 Residual Concentration -.000000 .000000 Residual Concentration -.000000 .000000 Residual Concentration -.000000 .000061 Residual Concentration -.000000 .000000 Residual Concentration -.000000 .000000 Residual Signal .000000 .000000 Residual Signal .000000 .000000 Ialysis Report 04/07/05 09:00:29 AM page 1 ?thod: DVCLPI Sample Name: ICV Operator: CO in Time: 04/07/05 08:50:55 DM m t: DdVONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Jnits ppb ppm ppb ppm ppm ppm ppm kvge 989.11 49.98 499.96 2.468 2.470 2.531 50.33 SDev 2.08 .03 .61 .001 .004 .001 .06 '.RSD .20996 .0524 .12127 .0239 .1659 .0350 .1122 41 987.21 49.95 500.64 2.469 2.465 2.531 50.39 42 988.78 49.99 499.77 2.468 2.470 2.530 50.31 43 991.33 50.01 499.47 2.467 2.474 2.532 50.29 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 1100.0 55.00 550.00 2.750 2.750 2.750 55.00 Low 900.00 45.00 450.00 2.250 2.250 2.250 45.00 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge 2.529 2.537 2.525 2.521 50.89 79.05 48.54 SDev .001 .009 .001 .001 .06 .12 .02 %RSD .0525 .3588 .0501 .0472 .1123 .1459 .0505 #1 2.530 2.527 2.525 2.521 50.87 78.92 48.52 #2 2.528 2.539 2.523 2.520 50.84 79.10 48.55 #3 2.530 2.545 2.525 2.522 50.95 79.14 48.57 Eros LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 2.750 2.750 2.750 2.750 55.00 88.00 55.00 Low 2.250 2.250 2.250 2.250 45.00 72.00 45.00 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge 2.540 2.496 75.20 2.527 .0035 505.44 489.31 SDev .000 .002 .20 .004 .0031 1.35 .28 %RSD .0030 .0895 .2655 .1540 87.67 .26718 .05625 #1 2.540 2.494 75.16 2.530 .0066 505.04 489.13 #2 2.540 2.499 75.41 2.528 .0034 504.35 489.18 #3 2.540 2.497 75.02 2.523 .0005 506.95 489.63 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High 2.750 88.00 2.750 Low 2.250 72.00 2.250 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge 1005.8 515.77 510.52 2.511 498.11 2.538 2.534 SDev 4.5 10.96 3.10 .005 3.66 .000 .001 %RSD .45003 2.1258 .60796 .2077 .73522 .0151 .0486 #1 1006.2 508.38 507.54 2.509 500.83 2.539 2.536 #* 1001.1 510.55 510.28 2.508 499.55 2.538 2.534 #3 1010.2 528.37 513.74 2.517 493.95 2.539 2.533 Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass ialysis Report 04/07/05 09:00:29 AM page 2 .4igh 1100.0 Low 900.00 Elem Pb2203 Se1960 Units ppb ppb Avge 494.68 512.27 SDev .63 5.64 %RSD .12642 1.1004 #1 494.43 507.82 42 494.23 510.37 43 495.40 518.61 Errors LC Pass LC Pass High 550.00 550.00 Low 450.00 450.00 • • 550.00 2.750 450.00 2.250 2.750 2.250 nalysis Report 04/07/05 09:10:12 AM page 1 ethod: DVCLPI Sample Name: ICVL Operator: CO un Time: 04/07/05 09:00:37 'om t : (odONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge -.09159 .0074 2.4384 .0183 .0004 .0004 .0094 SDev .59302 .0014 .5292 .0012 .0002 .0002 .0036 %RSD 647.44 18.20 21.702 6.698 40.22 37.29 38.14 #1 .14038 .0085 2.8274 .0196 .0006 .0006 .0131 #2 .35038 .0078 2.6520 .0182 .0004 .0004 .0090 #3 -.76553 .0059 1.8358 .0171 .0003 .0003 .0060 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK High Low Elem Cd. Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0003 .0004 .0003 .0005 2.514 .0153 .0132 SDev .0001 .0003 .0002 .0000 .002 .0109 .0058 %RSD 42.63 58.00 78.75 7.061 .0751 71.28 44.09 #1 .0003 .0007 .0005 .0005 2.514 .0248 .0194 #2 .0004 .0004 .0004 .0005 2.516 .0176 .0123 #3 .0001 .0002 .0000 .0005 2.512 .0034 .0079 E#s NOCHECK NOCHECK NOCHECK NOCHECK LC Pass NOCHECK NOCHECK High 2.750 Low 2.250 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge .0003 .0028 2.499 -.0007 -.0008 2.5608 -1.5922 SDev .0002 .0014 .011 .0007 .0035 1.7850 1.2799 %RSD 71.20 49.96 .4372 90.87 441.5 69.704 80.386 #1 .0005 .0044 2.511 -.0003 .0004 4.5365 -.84171 ##2 .0003 .0020 2.490 -.0004 -.0048 2.0818 -.86482 #3 .0001 .0020 2.496 -.0015 .0020 1.0642 -3.0700 Errors NOCHECK NOCHECK LC Pass NOCHECK NOCHECK NOCHECK NOCHECK High 2.750 Low 2.250 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -.54519 1.7126 -1.4802 .0018 4.1945 .0003 .0002 SDev 2.11164 2.2854 2.0446 .0003 1.8114 .0003 .0000 %RSD 387.32 133.45 138.13 14.87 43.185 72.42 1.792 #1 1.8772 1.7867 .62104 .0020 2.8326 .0005 .0002 ##-1.9973 -.60906 -3.4630 .0015 6.2503 .0005 .0002 O ##0 -1.5154 3.9600 -1.5985 .0018 3.5007 .0001 .0001 O Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK nalysis Report High Lo E10 Pb2203Se 1960 Units ppb ppb Avge -.20873 -.41655 SDev 1.35100 1.85392 %RSD 647.25 445.07 #1 .94968 1.0096 #2 .11692 -2.5122 #3 -1.6928 .25292 Errors NOCHECK NOCHECK High Low • 04/07/05 09:10:12 AM page 2 O N nalysis Report 04/07/05 09:19:53 AM page 1 ethod: DVCLPI Sample Name: ICB Operator: CO un Time: 04/07/05 09:10:19 omt: odWONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge -.44229 -.0092 1.0081 .0015 -.0000 .0001 .0022 SDev .18342 .0035 1.9972 .0010 .0001 .0001 .0016 %RSD 41.470 38.48 198.11 64.36 1094. 61.40 70.18 #1 -.23431 -.0052 -1.2631 .0021 .0001 .0002 .0038 #2 -.58090 -.0103 1.7973 .0020 -.0000 .0001 .0021 #3 -.51167 -.0121 2.4901 .0004 -.0001 .0001 .0007 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .2000 10.000 .0200 .2000 .0050 .2000 Low -10.000 -.2000 -10.000 -.0200 -.2000 -.0050 -.2000 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0001 .0003 -.0001 .0002 .0024 -.0106 .0046 SDev .0001 .0009 .0010 .0004 .0014 .0102 .0097 %RSD 84.47 255.1 1652. 204.0 58.11 95.84 211.3 #1 .0002 .0014 .0007 .0006 .0041 .0011 .0079 #2 .0002 -.0002 -.0012 .0000 .0016 -.0172 -.0063 #3 .0000 -.0002 .0004 -.0001 .0017 -.0159 .0122 Eos LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .0050 .0500 .0100 .0250 .1000 5.000 .2000 Low -.0050 -.0500 -.0100 -.0250 -.1000 -5.000 -.2000 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge -.0000 -.0000 .0088 -.0001 .0017 -1.1677 -.20140 SDev .0001 .0002 .0044 .0009 .0039 2.6007 .54796 %RSD 273.3 1904. 49.75 655.1 227.3 222.73 272.08 #1 .0001 .0001 .0138 .0009 .0012 1.8096 .39012 #2 -.0001 .0001 .0068 -.0009 -.0019 -2.3164 -.69168 #3 -.0001 -.0003 .0058 -.0004 .0058 -2.9962 -.30264 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High .0150 5.000 .0400 Low -.0150 -5.000 -.0400 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -1.0511 2.6393 -2.2699 .0003 1.6411 -.0007 .0005 SDev 1.5409 2.1238 4.1865 .0011 1.4497 .0005 .0008 %RSD 146.59 80.469 184.44 371.1 88.337 70.87 152.1 #1.71485 2.6268 -6.7956 .0003 1.2266 -.0002 .0005 #0 -1.7462 .52173 -1.4785 -.0008 .44384 -.0011 -.0003 #3 -2.1221 4.7692 1.4644 .0014 3.2529 -.0008 .0013 Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass nalysis Report 04/07/05 09:19:53 AM page 2 High 60.000 Low -60.000 Ell Pb2203 Se1960 Units ppb ppb Avge -.52268 -.63471 SDev 1.20043 3.11523 oRSD 229.67 490.81 #1 .86332 -3.6575 #2 -1.2323 -.81198 #3 -1.1991 2.5654 Errors LC Pass LC Pass High 3.0000 5.0000 Low -3.0000 -5.0000 • 10.000 .0500 -10.000 -.0500 .0200 -.0200 nalysis Report 04/07/05 09:29:35 AM page 1 ethod: DVCLPI Sample Name: CRII .un Time: 04/07/05 09:20:01 'om t: [od ONC Corr. Factor: 1 Elem Ag Al As1890 Units ppb ppm ppb Avge 19.083 -.0030 23.583 SDev .306 .0020 1.201 %RSD 1.6043 68.48 5.0934 #1 18.888 -.0040 24.846 #2 18.925 -.0006 23.448 #3 19.436 -.0043 22.455 Elem Cd Co Cr Units ppm ppm ppm Avge .0099 .0997 .0191 SDev .0000 .0006 .0003 %RSD .3378 .5808 1.642 #1 .0099 .0997 .0194 #2 .0100 .1003 .0191 #3 .0099 .0992 .0188 Elem Mn Mo Na Units ppm ppm ppm Av e .0296 .0255 .0176 S .0001 .0007 .0010 %R .2025 2.883 5.780 #1 .0296 .0262 .0186 #2 .0296 .0248 .0178 #3 .0295 .0254 .0166 Elem Sb2068 1960/1 1960/2 Units ppbppb ppm ppb Avge 116.25 11.813 5.9035 SDev 1.91 5.345 1.2540 %RSD 1.6428 45.242 21.241 #1 115.66 15.912 4.4871 #2 114.70 5.7683 6.3513 #3 118.38 13.760 6.8721 Elem Pb2203 Se1960 Units ppb ppb Avge 6.5271 7.8720 SDev .6360 1.5477 %RSD 9.7435 19.661 #1 6.8904 8.2920 #2 6.8982 6.1576 #30 5.7928 9.1662 Operator: CO B Ba Be Ca PPM ppm ppm ppm .1950 .0001 .0099 .0037 .0016 .0001 .0000 .0002 .8276 54.15 .2279 5.721 .1940 .0002 .0099 .0038 .1942 .0001 .0099 .0038 .1969 .0001 .0099 .0034 Cu Fe K Mg PPM ppm ppm ppm .0494 .0012 -.0014 -.0016 .0004 .0004 .0020 .0022 .8399 36.00 145.4 136.8 .0499 .0017 -.0032 .0008 .0491 .0009 .0008 -.0021 .0493 .0009 -.0017 -.0035 Ni P 2203/1 2203/2 PPM ppm ppb ppb .0789 -.0009 7.4177 6.0817 .0007 .0028 .9725 .7516 .9284 320.7 13.111 12.358 .0796 -.0034 8.5264 6.0728 .0787 -.0014 7.0178 6.8377 .0782 .0022 6.7088 5.3346 Sn T11908 v Zn PPM ppb ppm ppm .0803 22.260 .0978 .0403 .0005 1.331 .0001 .0003 .6266 5.9788 .1155 .8150 .0797 23.183 .0978 .0400 .0807 22.862 .0979 .0404 .0805 20.734 .0977 .0406 knalysis Report 4ethod: DVCLPI Sample Name: ICSAI Zun Time: 04/07/05 09:38:26 526.0 om t: .19740 524.9 Errors 4od CONC Corr. Factor: 1 High Elem Ag Al As1890 Units ppb ppm ppb Avge .01763 525.5 -.89824 SDev .16051 .5 1.67590 %RSD 910.41 .1045 186.58 #1 -.11133 525.7 #2 -.03318 526.0 #3 .19740 524.9 Errors LC Pass LC Pass High 10.000 600.0 Low -10.000 400.0 Elem Cd Co Units ppm ppm Avge L-.0050 .0021 SDev .0000 .0002 %RSD .9518 7.584 #1 L-.0050 .0023 #2 L-.0051 .0021 43 -.0050 .0019 Es LC Low NOCHECK Hig .0050 Low -.0050 Elem Mn Mo Units ppm ppm Avge .0095 -.0014 SDev .0001 .0013 %RSD 1.183 92.88 #1 .0096 -.0001 #2 .0095 -.0028 #3 .0094 -.0014 Errors LC Pass NOCHECK High .0150 Low -.0150 Elem Sb2068 1960/1 Units ppb ppb Avge 4.9314 15.014 SDev 2.8199 2.066 %RSD 57.183 13.763 41 3.7393 15.086 40 8.1515 17.043 # 2.9033 12.912 Errors LC Pass NOCHECK .29466 -2.8143 -.17508 04/07/05 09:48:01 AM page 1 B ppm .0053 .0007 12.82 .0055 .0059 .0046 Ba ppm .0011 .0001 4.923 .0011 .0011 .0012 Operator: CO Be Ca ppm ppm .0002 501.2 .0000 1.0 10.32 .2046 .0002 501.9 .0002 501.6 .0002 500.0 NOCHECK NOCHECK LC Pass .2000 -.2000 Cr ppm .0050 .0002 4.622 .0048 .0053 .0049 LC Pass .0100 -.0100 Na ppm .1015 .0006 .5622 .1009 .1017 .1020 NOCHECK 1960/2 ppb -2.1701 4.5754 210.84 -4.1443 -5.4269 3.0610 NOCHECK Cu ppm .0028 .0004 13.91 .0028 .0024 .0032 NOCHECK Ni ppm .0037 .0003 7.275 .0039 .0034 .0037 LC Pass .0400 -.0400 Sn ppm -.0122 .0021 16.86 -.0112 -.0109 -.0146 NOCHECK Fe ppm 196.9 .1 .0756 196.7 197.0 196.8 LC Pass 240.0 160.0 P ppm .0244 .0109 44.46 .0367 .0160 .0206 NOCHECK T11908 ppb H18.260 5.573 30.520 H13.200 H17.348 H24.233 LC High LC Pass .0050 -.0050 K ppm .0324 .0036 11.26 .0283 .0333 .0354 NOCHECK 2203/1 ppb 49.880 2.371 4.7532 49.456 52.434 47.749 NOCHECK V ppm .0044 .0002 4.669 .0046 .0043 .0043 LC Pass LC Pass 600.0 400.0 Mg ppm 506.3 .6 .1134 506.7 506.6 505.6 LC Pass 600.0 400.0 2203/2 ppb -21.447 1.818 8.4766 -20.922 -23.469 -19.949 NOCHECK Zn ppm .0089 .0003 3.006 LC Pass analysis Report 04/07/05 09:48:01 AM page 2 High 60.000 Lo -60.000 10 El Pb2203 Se1960 Units ppb ppb Avge 2.3055 3.5526 SDev .4336 2.4178 %RSD 18.807 68.057 #1 2.5142 2.2598 #2 1.8070 2.0560 #3 2.5953 H6.3419 Errors LC Pass LC Pass High 6.0000 5.0000 Low -6.0000 -5.0000 • 10.000 .0500 -10.000 -.0500 .0200 -.0200 nalysis Report 04/07/05 09:57:42 AM page 1 ethod: DVCLPI Sample Name: ICSABI un Time: 04/07/05 09:48:08 1077.7 omm nt: LC Pass High 1200.0 odWONC Corr. Factor: 1 Elem Elem Ag Al As1890 Units ppb ppm ppb Avge 1078.2 527.4 1029.6 SDev 1.0 .1 2.3 %RSD .09247 .0176 .22149 #1 1079.3 #2 1077.5 #3 1077.7 Errors LC Pass High 1200.0 Low 800.00 Elem Cd Units ppm Avge .9723 SDev .0011 %RSD .1105 #1 .9735 #2 .9715 #3 .9719 527.3 527.5 527.4 LC Pass 600.0 400.0 Co PPM .5024 .0012 .2380 .5023 .5013 .5037 LC Pass .6000 .4000 Mo ppm .9936 .0027 .2667 NOCHECK 1960/1 ppb 1015.5 15.6 1.5360 998.66 1029.5 1018.2 1030.0 1027.2 1031.7 LC Pass 1200.0 800.00 B PPM 1.038 .002 .1785 1.040 1.037 1.036 LC Pass 1.200 .8000 Operator: CO Ba PPM .5227 .0005 .0954 .5223 .5232 .5226 LC Pass .6000 .4000 Be ppm .5096 .0011 .2217 .5108 .5095 .5086 LC Pass .6000 .4000 Ca PPM 508.2 1.6 .3155 510.0 507.7 506.9 LC Pass 600.0 400.0 Cr Cu Ers LC Pass 'Hig 1.200 Low .8000 Elem Mn Units ppm Avge .5270 SDev .0006 %RSD .1086 #1 .5271 #2 .5275 #3 .5263 Errors LC Pass High .6000 Low .4000 Elem Sb2068 Jnits ppb kvge 2.6078 ',SDev 3.2434 %RSD 124.37 #1 4.8978 42 - -1.1036 #3 4.0292 527.3 527.5 527.4 LC Pass 600.0 400.0 Co PPM .5024 .0012 .2380 .5023 .5013 .5037 LC Pass .6000 .4000 Mo ppm .9936 .0027 .2667 NOCHECK 1960/1 ppb 1015.5 15.6 1.5360 998.66 1029.5 1018.2 1030.0 1027.2 1031.7 LC Pass 1200.0 800.00 B PPM 1.038 .002 .1785 1.040 1.037 1.036 LC Pass 1.200 .8000 Operator: CO Ba PPM .5227 .0005 .0954 .5223 .5232 .5226 LC Pass .6000 .4000 Be ppm .5096 .0011 .2217 .5108 .5095 .5086 LC Pass .6000 .4000 Ca PPM 508.2 1.6 .3155 510.0 507.7 506.9 LC Pass 600.0 400.0 Cr Cu Fe K Mg ppm ppm ppm ppm ppm .5112 .5554 199.5 -.0055 512.3 .0017 .0008 .1 .0061 1.2 .3410 .1390 .0667 110.3 .2248 .5132 .5107 .5098 LC Pass .6000 .4000 Na ppm .0289 .0006 2.009 .0295 .0289 .0283 NOCHECK 1960/2 ppb 1023.2 5.4 .52688 1019.6 1029.4 1020.6 Errors NOCHECK NOCHECK NOCHECK .5561 .5555 .5546 LC Pass .6000 .4000 Ni ppm .9797 .0039 .3948 .9832 .9802 .9756 LC Pass 1.200 .8000 Sn ppm .9782 .0036 .3713 .9824 .9765 .9758 NOCHECK 199.7 199.4 199.5 LC Pass 240.0 160.0 P PPM .0149 .0083 55.45 .0244 .0112 .0091 NOCHECK T11908 ppb 989.76 5.83 .58940 989.05 984.32 995.92 LC Pass -.0089 -.0091 .0015 NOCHECK 2203/1 ppb 1048.9 6.6 .62848 1049.8 1041.9 1055.0 NOCHECK V ppm .5175 .0010 .1994 .5184 .5178 .5164 LC Pass 513.6 512.0 511.4 LC Pass 600.0 400.0 2203/2 ppb 981.29 3.25 .33103 985.03 979.68 979.15 NOCHECK Zn ppm .9579 .0039 .4075 .9623 .9564 .9549 LC Pass nalysis Report 04/07/05 09:57:42 AM page 2 High Low ElO Pb2203 Se1960 Units ppb ppb Avge 1003.8 1020.6 SDev 3.1 8.4 %RSD .31218 .82548 #1 1006.6 1012.6 #2 1000.4 1029.4 #3 1004.4 1019.8 Errors LC Pass LC Pass High 1200.0 1200.0 Low 800.00 800.00 • 1200.0 .6000 800.00 .4000 1.200 .8000 N 00 O C/1 .nalysis Report 04/07/05 10:07:24 AM page 1 ethod: DVCLPI Sample Name: CCV1 Operator: CO un Time: 04/07/05 09:57:49 omment: od*ONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 999.69 50.34 507.17 2.492 2.502 2.545 50.47 SDev 1.24 .15 7.93 .006 .015 .025 .58 %RSD .12453 .3037 1.5637 .2468 .6173 .9868 1.143 #1 998.97 50.16 515.51 2.495 2.484 2.574 51.14 #2 998.98 50.42 499.72 2.485 2.510 2.529 50.12 #3 1001.1 50.44 506.28 2.496 2.512 2.532 50.16 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 1100.0 55.00 550.00 2.750 2.750 2.750 55.00 Low 900.00 45.00 450.00 2.250 2.250 2.250 45.00 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge 2.546 2.591 2.542 2.539 51.36 80.46 48.80 SDev .038 .027 .020 .015 .39 .65 .52 %RSD 1.482 1.025 .8024 .6025 .7584 .8029 1.070 #1 2.589 2.622 2.566 2.521 51.81 79.72 49.40 #2 2.522 2.576 2.530 2.548 51.13 80.89 48.50 #3 2.526 2.576 2.530 2.548 51.13 80.77 48.49 Er � LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 2.750 2.750 2.750 2.750 55.00 88.00 55.00 Low 2.250 2.250 2.250 2.250 45.00 72.00 45.00 iElem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb 'Avge 2.561 2.519 76.15 2.537 .0003 506.48 495.00 SDev .015 .020 .39 .025 .0041 10.89 6.22 %RSD .5888 .7795 .5168 .9990 1347. 2.1493 1.2566 #1 2.578 2.541 75.85 2.566 .0023 518.96 502.18 #2 2.550 2.504 76.01 2.522 .0030 498.98 491.15 #3 2.554 2.510 76.60 2.522 -.0044 501.49 491.68 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High 2.750 88.00 2.750 Low 2.250 72.00 2.250 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge 1015.4 518.96 509.89 2.530 502.59 2.558 2.550 SDev 8.1 10.15 11.44 .034 2.87 .009 .056 '%RSD .79828 1.9559 2.2445 1.332 .57105 .3375 2.213 #1 1024.5 529.27 523.10 2.569 505.90 2.568 2.615 #2 1012.9 508.97 503.25 2.508 500.89 2.552 2.518 43 1008.9 518.63 503.31 2.513 500.97 2.554 2.517 Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass M 00 O nalysis Report 04/07/05 10:07:24 AM page 2 High 1100.0 Low 900.00 J • Se1960 ppb 512.91 10.73 2.0922 525.15 505.15 508.41 LC Pass 550.00 450.00 550.00 2.750 450.00 2.250 2.750 2.250 ElO Pb2203 Units ppb Avge 498.82 SDev 7.77 %RSD 1.5574 #1 507.77 #2 493.76 #3 494.95 Errors LC Pass High 550.00 Low 450.00 J • Se1960 ppb 512.91 10.73 2.0922 525.15 505.15 508.41 LC Pass 550.00 450.00 550.00 2.750 450.00 2.250 2.750 2.250 nalysis Report 04/07/05 10:17:07 AM page 1 ethod: DVCLPI Sample Name: CCVLl Operator: CO un Time: 04/07/05 10:07:31 om t: o CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge -.18662 .0101 2.5568 .0176 .0003 .0003 .0189 SDev .04079 .0056 .9732 .0006 .0001 .0001 .0071 %RSD 21.860 55.26 38.063 3.418 33.77 36.49 37.39 #1 -.13952 .0164 1.4338 .0183 .0004 .0005 .0269 42 -.21018 .0074 3.1540 .0172 .0002 .0003 .0166 #3 -.21017 .0064 3.0827 .0174 .0002 .0002 .0133 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK High Low Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0003 .0005 .0002 .0009 2.529 .0060 .0191 SDev .0000 .0001 .0005 .0001 .009 .0010 .0093 %RSD 10.96 16.65 229.5 14.74 .3364 17.61 48.79 #1 .0004 .0004 -.0002 .0007 2.522 .0072 .0281 #2 .0003 .0006 .0008 .0009 2.527 .0052 .0196 #3 .0003 .0006 .0001 .0009 2.539 .0055 .0095 EY*s NOCHECK NOCHECK NOCHECK NOCHECK LC Pass NOCHECK NOCHECK High 2.750 Low 2.250 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge .0003 .0026 2.520 -.0006 -.0006 1.0873 -2.3501 SDev .0002 .0016 .002 .0005 .0061 1.7749 1.5477 %RSD 84.74 61.48 .0668 85.27 949.0 163.24 65.859 #1 .0005 .0043 2.520 -.0001 -.0054 .92986 -1.2555 #2 .0003 .0013 2.521 -.0005 -.0029 -.60366 -4.1208 #3 .0000 .0020 2.518 -.0012 .0063 2.9357 -1.6738 Errors NOCHECK NOCHECK LC Pass NOCHECK NOCHECK NOCHECK NOCHECK High 2.750 Low 2.250 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm j Avge -.31172 4.6272 -.06364 .0010 4.1799 .0001 -.0000 SDev .85631 5.0177 2.73088 .0007 1.5556 .0002 .0003 %RSD 274.70 108.44 4290.8 71.20 37.217 116.2 1394. #1-1.1174 .63042 .81496 .0004 5.9634 .0003 .0002 #0 .58756 2.9928 2.1198 .0018 3.1031 .0002 -.0004 #3 -.40537 10.258 -3.1257 .0009 3.4732 -.0000 .0002 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK .nalysis Report High Lo� Eler�i Pb22 03 Se1960 Units ppb ppb Avge -1.2049 1.4989 SDev 1.5230 .8411 %RSD 126.40 56.114 #1 -.52732 .75396 #2 -2.9491 2.4110 #3 -.13836 1.3316 Errors NOCHECK NOCHECK High Low • 0 04/07/05 10:17:07 AM page 2 110 00 O cn H ,nalysis Report 04/07/05 10:26:49 AM page 1 Iethod: DVCLPI Sample Name: CCB1 Operator: CO 'un Time: 04/07/05 10:17:14 'om t: I04CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge -.25757 -.0059 1.6289 .0015 .0001 .0001 .0042 SDev .28254 .0014 1.2793 .0001 .0000 .0000 0 .0018 0 oRSD 109.70 24.53 78.537 7.884 61.99 54.88 41.88 #1 -.51336 -.0044 2.6221 .0014 .0001 .0001 .0061 #2 -.30504 -.0059 2.0793 .0014 .0001 .0000 .0038 #3 .04570 -.0073 .18533 .0016 .0000 .0000 .0027 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .2000 10.000 .0200 .2000 .0050 .2000 Low -10.000 -.2000 -10.000 -.0200 -.2000 -.0050 -.2000 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0002 .0001 -.0003 .0002 .0028 -.0012 .0046 SDev .0001 .0008 .0005 .0001 .0008 .0035 .0022 aRSD 77.90 1094. 163.2 35.67 29.86 297.3 47.46 #1 .0002 .0001 -.0002 .0003 .0038 -.0048 .0051 #2 .0003 -.0007 -.0008 .0001 .0026 .0022 .0022 #3 .0000 .0009 .0001 .0002 .0021 -.0010 .0065 E*s LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .0050 .0500 .0100 .0250 .1000 5.000 .2000 Low -.0050 -.0500 -.0100 -.0250 -.1000 -5.000 -.2000 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge .0000 .0002 .0035 -.0014 .0033 -.08565 -.61506 SDev .0001 .0001 .0014 .0004 .0011 2.37408 1.04325 oRSD 214.3 44.80 40.59 27.72 35.27 2771.8 169.62 #1 -.0000 .0003 .0051 -.0016 .0045 -2.8221 -.11194 #2 -.0000 .0001 .0029 -.0016 .0031 1.1412 -1.8145 #3 .0001 .0002 .0024 -.0009 .0022 1.4240 .08127 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High .0150 5.000 .0400 Low -.0150 -5.000 -.0400 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -1.2977 .73736 -.14691 .0003 1.4484 -.0003 -.0004 SDev 2.0491 3.6656 1.74818 .0014 3.0634 .0003 .0004 oRSD 157.90 497.12 1189.9 424.2 211.50 109.6 112.9 #1 -2.7215 3.9985 .50991 .0018 2.2345 -.0004 -.0003 #* -2.2225 1.4435 -2.1284 .0002 4.0422 .0001 -.0008 ## 1.0508 -3.2299 1.1777 -.0010 -1.9314 -.0005 -.0000 Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass 00 O r� E'-� nalysis Report 04/07/05 10:26:49 AM page 2 High 60.000 Low -60.000 Ele* Pb2203 Se1960 Units ppb ppb Avge -.43826 .14800 SDev .84264 1.3592 %RSD 192.27 918.34 41 -1.0139 1.6720 42 -.82977 -.93848 43 .52891 -.28956 Errors LC Pass LC Pass High 3.0000 5.0000 Low -3.0000 -5.0000 • • 10.000 .0500 -10.000 -.0500 .0200 -.0200 00 00 0 0 lnalysis Report 04/07/05 10:36:31 AM page 1 lethod: DVCLPI Sample Name: MB-13147 Operator: CO Zun Time: 04/07/05 10:26:56 lo *t: 90* CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge -.14141 -.0082 2.3308 .0011 -.0000 .0000 .0035 SDev .52942 .0025 .9414 .0006 .0000 .0000 .0009 %RSD 374.38 30.46 40.388 48.27 50.92 62.62 26.84 #1 .32125 -.0054 1.3786 .0009 -.0000 .0000 .0046 #2 -.02670 -.0091 3.2609 .0018 -.0001 .0000 .0031 #3 -.71878 -.0101 2.3529 .0008 -.0001 .0000 .0029 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .2000 10.000 .0200 .2000 .0050 .2000 Low -10.000 -.2000 -10.000 -.0200 -.2000 -.0050 -.2000 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge -.0001 .0003 -.0004 .0003 -.0102 -.0025 .0022 SDev .0002 .0004 .0003 .0003 .0004 .0094 .0049 %RSD 148.3 111.6 78.55 74.78 3.441 374.4 224.0 #1 -.0003 -.0001 -.0005 .0005 -.0099 .0056 -.0006 42 .0001 .0006. -.0000 .0004 -.0101 -.0003 .0079 43 -.0001 .0005 -.0006 .0001 -.0106 -.0128 -.0006 E0rs LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High .0050 .0500 .0100 .0250 .1000 5.000 .2000 Low -.0050 -.0500 -.0100 -.0250 -.1000 -5.000 -.2000 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge -.0002 -.0005 .0025 -.0009 .0010 -.38756 -1.0249 SDev .0001 .0004 .0007 .0006 .0090 .84062 1.7793 0-.RSD 65.00 85.66 30.15 69.91 869.9 216.90 173.61 #1 -.0003 -.0009 .0029 -.0007 -.0057 -.80638 1.0263 42 -.0001 -.0005 .0029 -.0015 .0113 .58019 -2.1525 #3 -.0001 -.0001 .0016 -.0004 -.0025 -.93649 -1.9486 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High .0150 5.000 .0400 Low -.0150 -5.000 -.0400 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -1.3646 .03770 -2.6558 .0012 1.2295 -.0003 .0001 SDev 2.6805 7.1783 2.0318 .0018 3.1720 .0003 .0001 %RSD 196.43 19042. 76.504 151.2 257.99 88.49 188.4 C7.1 00 #1 -4.4577 -1.2401 -3.0854 .0031 -1.1538 -.0006 .0003 .08375 -6.4159 -4.4386 .0008 4.8298 -.0001 -.0000 ##� .28019 7.7691 -.44360 -.0004 .01246 -.0003 -.0000 O Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass P-4 nalysis Report 04/07/05 10:36:31 AM page 2 High 60.000 Lo -60.000 E1 Oe ppb Errors LC Pass LC Pass High 3.0000 5.0000 Low -3.0000 -5.0000 • • 10.000 .0500 -10.000 -.0500 .0200 -.0200 O CN O C/Z E-+ Pb2203 Se1960 Units ppb ppb Avge -.81219 -1.7585 SDev 1.07993 3.7452 %RSD 132.96 212.98 41 .41646 -2.4705 #2 -1.2420 L-5.0966 #3 -1.6111 2.2917 Errors LC Pass LC Pass High 3.0000 5.0000 Low -3.0000 -5.0000 • • 10.000 .0500 -10.000 -.0500 .0200 -.0200 O CN O C/Z E-+ ialysis Report =thod: DVCLPI Sample Name: LCS-13147 in Time: 04/07/05 10:36:38 LGSw Jmt: DdWONC Corr. Factor: 1 04/07/05 10:46:13 AM Elem Ag Al As1890 B Units ppb ppm ppb ppm Avge 1097.4 55.35 534.07 2.866 SDev 1.9 .11' .73 .009 %RSD .17399 .1987 .13665 .3167 ##1 1097.6 #2 1095.3 #3 1099.1 Errors LC Pass High 1200.0 Low 800.00 Elem Cd Units ppm Avge 2.742 SDev .007 %RSD .2698 #1 2.735 #2 2.743 #3 2.750 Errors LC Pass 55.32 55.26 55.47 LC Pass 60.00 40.00 Co ppm 2.793 .008 .2793 2.797 2.784 2.799 LC Pass 3.000 2.000 Mo ppm 2.747 .007 .2441 2.740 2.749 2.753 NOCHECK 1960/1 ppb 535.94 5.20 .97060 530.05 539.90 537.86 NOCHECK 534.25 2.857 E*s LC Pass High 3.000 Low 2.000 Elem Mn Units ppm Avge 2.786 SDev .006 %RSD .2262 #1 2.780 #2 2.785 #3 2.792 Errors LC Pass High 3.000 Low 2.000 Elem Sb2068 Units ppb Avge 1091.5 SDev 5.7 %RSD .51872 #0 1086.1 # 1090.8 ft 1097.4 Errors LC Pass 55.32 55.26 55.47 LC Pass 60.00 40.00 Co ppm 2.793 .008 .2793 2.797 2.784 2.799 LC Pass 3.000 2.000 Mo ppm 2.747 .007 .2441 2.740 2.749 2.753 NOCHECK 1960/1 ppb 535.94 5.20 .97060 530.05 539.90 537.86 NOCHECK 534.25 2.857 533.27 2.865 534.70 2.875 LC Pass LC Pass 600.00 3.000 400.00 2.000 Cr Cu ppm ppm 2.762 2.818 .007. .003 .2437 .1191 2.755 2.766 2.767 LC Pass 3.000 2.000 Na ppm 81.93 .13 .1548 LC Pass 96.00 64.00 1960/2 ppb 532.50 3.81 .71517 528.22 533.74 535.53 NOCHECK 2.816 2.816 2.822 LC Pass 3.000 2.000 Ni ppm 2.766 .013 .4630 2.751 2.771 2.775 LC Pass 3.000 2.000 Sn ppm 2.727 .006 .2148 2.721 2.730 2.731 NOCHECK Operator: CO Ba ppm 2.730 .006 .2313 2.733 2.723 2.735 LC Pass 3.000 2.000 Fe PPM 54.90 .13 .2409 54.79 54.86 55.05 LC Pass 60.00 40.00 P ppm .0101 .0053 52.58 .0043 .0148 .0113 NOCHECK T11908 ppb 532.44 4.96 .93163 527.79 537.66 531.87 LC Pass Be ppm 2.827 .008 .2743 2.819 2.826 2.834 LC Pass 3.000 2.000 K PPM 81.14 .27 .3307 81.39 80.86 81.17 LC Pass 96.00 64.00 2203/1 ppb 534.81 4.83 .90388 531.56 532.50 540.37 NOCHECK V ppm 2.781 .006 .2074 2.776 2.780 2.787 LC Pass page 1 Ca ppm 55.20 .19 .3423 54.99 55.26 55.36 LC Pass 60.00 40.00 Mg PPM 53.07 .15 .2786 52.91 53.08 53.21 LC Pass 60.00 40.00 2203/2 ppb 525.60 3.79 .72073 522.33 524.73 529.75 NOCHECK Zn ppm 2.733 .013 .4660 2.719 2.736 2.744 LC Pass nalysis Report 04/07/05 10:46:13 AM page 2 High 1200.0 Low 800.00 Elel* Pb2203 Se1960 Units ppb ppb Avge 528.67 533.64 SDev 4.11 4.18 oRSD .77774 .78237 #1 525.41 528.83 #2 527.32 535.79 #3 533.29 536.31 Errors LC Pass LC Pass High 600.00 600.00 Low 400.00 400.00 • • 600.00 3.000 400.00 2.000 3.000 2.000 N O C/1 F-+ nalysis Report 04/07/05 10:55:55 AM page 1 ethod: DVCLPI Sample Name: 0504067-002G Operator: CO un Time: 04/07/05 10:46:20 M w _fig omm t: od*ONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge -.04618 .0244. 3.4724 .0146 .0055 .0004 9.259 SDev .48678 .0047 2.3745 .0004 .0003 .0003 .016 %RSD 1054.1 19.38 68.382 3.014 5.089 81.14 .1681 #1 .04538 .0296 6.1621 .0150 .0058 .0008 9.242 #2 .38832 .0231 2.5884 .0141 .0055 .0003 9.273 #3 -.57224 .0204 1.6667 .0146 .0052 .0001 9.262 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0006 .0010 .0004 .0120 .3797 1.003 3.761 SDev .0003 .0004 .0004 .0003 .0053 .014 .012 %RSD 55-26 37.47 94.77 2.067 1.387 1.439 .3082 #1 .0009 .0009 .0007 .0117 .3855 1.018 3.748 #2 .0003 .0013 -.0000 .0120 .3782 1.004 3.766 #3 .0005 .0006 .0007 .0122 .3753 .9890 3.770 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge .0388 .0013 23.81 .0013 .5244 -1.8470 -1.2910 SD � .0003 .0007 .12 .0005 .0136 1.3560 3.0119 %R .7038 53.59 .5059 41.36 2.590 73.418 233.29 #1 .0391 .0020 23.85 .0007 .5124 -2.8349 -.53360 #2 .0388 .0014 23.90 .0017 .5217 -.30100 -4.6093 #3 .0386 .0006 23.67 .0015 .5391 -2.4050 1.2698 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -.63347 -.86841 -3.3874 .0030 .83992 .0002 .2563 SDev .84534 6.99166 4.6992 .0013 2.2861 .0005 .0001 %RSD 133.45 805.11 138.72 41.08 272.18 233.3 .0504 #1 -1.3872 6.9570 -.39130 .0016 3.1928 .0006 .2561 #2 -.79376 -3.0619 -8.8034 .0040 -1.3730 .0005 .2563 #3 .28054 -6.5003 -.96760 .0035 .70002 -.0004 .2564 Elem Pb2203 Se1960 Units ppb ppb Avge -1.4756 -2.5481 SDev 1.6176 4.4793 %RSD 109.62 175.79 #1 -1.2994 2.0561 #2 -3.1741 -6.8910 #30 .04663 -2.8096 nalysis Report 04/07/05 11:05:37 AM ethod: DVCLPI Sample Name: 0504067-002GDUP Operator: CO un Time: 04/07/05 10:56:02 jY%w-�so:�p om nt: o4CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Units ppb ppm ppb ppm ppm ppm Avge -.09267 .0141 1.1794 .0135 .0052 .0001 SDev .24587 .0018 2.3185 .0006 .0001 .0001 %RSD 265.33 12.47 196.58 4.513 1.610 146.5 #1 .11196 .0129 -.33985 .0138 .0052 .0000 #2 -.36542 .0161 3.8481 .0139 .0051 .0000 #3 -.02453 .0132 .03005 .0128 .0053 .0002 Elem Cd Co Cr Cu Fe K Units ppm ppm ppm ppm ppm ppm Avge .0003 .0022 .0014 .0137 .3863 1.047 SDev .0005 .0026 .0023 .0019 .0017 .007 %RSD 162.8 120.9 169.7 14.08 .4349 .6288 #1 .0001 .0004 .0003 .0127 .3852 1.050 #2 -.0000 .0009 -.0002 .0125 .3856 1.052 #3 .0009 .0051 .0040 .0159 .3883 1.040 Elem Mn Mo Na Ni P 2203/1 Units ppm ppm ppm ppm ppm ppb Avge .0395 .0006 24.98 .0017 .6007 1.3718 So .0003 .0010 .24 .0031 .0026 3.5754 % .7083 164.4 .9632 180.4 .4251 260.63 .0394 .0394 .0399 Sb2068 ppb 5.1813 8.0995 156.32 -.44037 1.5192 14.465 Pb2203 ppb .67464 .12408 18.392 .80626 .65783 .55981 -.0002 .0003 .0017 1960/1 ppb 3.9793 3.8336 96.337 3.0351 8.1968 .70607 Se1960 ppb 1.9670 .8064 40.997 1.5093 2.8981 1.4936 25.12 25.11 24.70 1960/2 ppb .96170 .83788 87.125 .74691 .25212 1.8861 -.0005 .0005 .0052 Sn PPM .0013 .0014 109.8 -.0003 .0026 .0016 .5993 .5990 .6036 T11908 ppb 4.0786 1.4382 35.261 5.0458 2.4259 4.7641 .12955 5.4027 -1.4168 V PPM .0003 .0005 187.5 .0001 -.0002 .0009 page 1 Ca PPM 9.856 .013 .1286 9.842 9.865 9.862 Mg PPM 4.028 .025 .6208 4.006 4.021 4.055 2203/2 ppb .32574 1.7760 545.23 1.1433 -1.7118 1.5458 Zn PPM .2777 .0020 .7334 .2766 .2765 .2800 nalysis Report 04/07/05 11:15:18 AM ethod: DVCLPI Sample Name: 0504067-002GMS Operator: CO un Time: 04/07/05 11:05:44 ;X"(y%s om t: od ONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Units ppb ppm ppb ppm ppm ppm Avge 41.148 2.054 43.267 1.930 2.000 .0528 SDev .326 .004 .633 .004 .001 .0001 %RSD .79205 .1903 1.4634 .2003 .0721 .2063 #1 41.062 2.053 42.847 1.926 2.002 .0527 #2 40.873 2.051 42.959 1.930 1.999 .0528 #3 41.508 2.059 43.995 1.934 2.000 .0529 Elem Cd Co Cr Cu Fe K Units ppm ppm ppm ppm ppm ppm Avge .0524 .5331 .2072 .2647 1.422 1.077 SDev .0001 .0016 .0008 .0005 .003 .004 %RSD .1352 .2962 .3697 .2052 .2409 .3482 .0524 .5314 .2063 .0524 .5345 .2075 .0525 .5336 .2078 Mn PPM .5567 .0010 .1749 .5558 .5567 .5577 Sb2068 ppb 494.68 2.07 .41903 492.29 496.06 495.67 Pb2203 ppb 18.899 1.258 6.6589 19.530 19.717 17.450 Mo PPM -.0001 .0001 140.5 -.0001 .0000 -.0002 1960/1 ppb 13.741 1.990 14.486 15.596 13.989 11.638 Se1960 ppb 11.551 3.746 32.429 10.032 15.818 8.8038 Na PPM 25.37 .04 .1389 25.33 25.40 25.39 1960/2 ppb 10.457 5.434 51.958 7.2532 16.731 7.3881 .2642 .2646 .2653 Ni PPM .5229 .0027 .5068 .5207 .5222 .5258 Sn PPM .0004 .0008 202.4 .0004 .0012 -.0004 1.418 1.423 1.425 P PPM .5914 .0081 1.367 .5865 .5870 .6007 T11908 ppb 50.190 3.648 7.2685 51.338 46.107 53.127 1.073 1.079 1.080 2203/1 ppb 18.263 2.082 11.401 20.170 18.578 16.042 V PPM .5085 .0006 .1207 .5078 .5086 .5090 page 1 Ca PPM 9.874 .019 .1965 Mg PPM 4.029 .009 .2199 4.019 4.033 4.035 2203/2 ppb 19.216 1.067 5.5508 19.210 20.286 18.152 Zn PPM .8193 .0022 .2720 .8167 .8209 .8202 nalysis Report 04/07/05 11:25:00 AM page 1 ethod: DVCLPI Sample Name: 0504067-002GSD Operator: CO un Time: 04/07/05 11:15:26 �vlvv_�5 s0 omm od ONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge -.14094 -.0062 1.4970 .0055 .0016 -.0000 1.886 SDev .24353 .0035 1.9779 .0014 .0004 .0001 .006 %RSD 172.79 56.43 132.12 25.00 23.21 506.5 .3137 41 -.37212 -.0026 3.3897 .0069 .0020 .0001 1.892 42 .11330 -.0065 1.6576 .0055 .0016 .0000 1.884 43 -.16400 -.0096 -.55631 .0041 .0013 -.0001 1.881 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge -.0003 -.0007 -.0012 .0025 .0758 .1963 .7561 SDev .0005 .0023 .0023 .0015 .0017 .0049 .0178 %RSD 174.5 326.5 197.1 59.89 2.246 2.508 2.352 #1 .0001 .0011 .0002 .0037 .0770 .1995 .7700 42 -.0001 .0001 .0001 .0030 .0766 .1987 .7622 43 -.0009 -.0033 -.0038 .0008 .0739 .1906 .7360 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge .0076 -.0009 5.634 -.0019 .1108 5.6737 -5.8002 SDO .0004 .0011 .021 .0025 .0023 9.5611 3.1563 %R 5.379 116.0 .3720 129.1 2.049 168.52 54.418 41 .0079 -.0005 5.630 -.0001 .1133 -1.7722 -3.1143 42 .0078 -.0002 5.657 -.0009 .1101 2.3374 -5.0096 #3 IElem .0072 -.0022 5.616 -.0048 .1089 16.456 -9.2766 Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -3.6249 .48882 -4.6091 .0010 3.4158 -.0013 .0510 SDev 5.7790 10.441 3.8451 .0012 .9586 .0022 .0019 %RSD 159.43 2136.0 83.425 119.2 28.063 168.1 3.724 41 2.0197 -7.0961 -2.2221 .0018 4.2320 .0003 .0524 #2 -3.3648 -3.8346 -2.5604 .0016 2.3602 -.0004 .0518 43 -9.5296 12.397 -9.0447 -.0004 3.6551 -.0038 .0488 Elem Pb2203 Se1960 Units ppb ppb Avge -1.9789 -2.9110 SDev 1.1025 .9724 %RSD 55.716 33.403 #1 -2.6669 -3.8447 42 -2.5626 -2.9843 4310 -.70720 -1.9041 O r-� C/Z H .nalysis Report 04/07/05 11:34:43 AM page 1 ethod: DVCLPI Sample Name: 0504024-001G Operator: CO un Time: 04/07/05 11:25:08 omment : od'oONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .02686 .0974 5.4746 .5122 .2600 .0001 76.70 SDev .35778 .0026 2.6247 .0025 .0007 .0000 .29 %RSD 1332.1 2.659 47.943 .4819 .2683 36.53 .3844 #1 .40619 .1003 5.3101 .5150 .2606 .0001 77.02 42 -.30453 .0966 2.9360 .5114 .2603 .0000 76.45 #3 -.02108 .0953 8.1776 .5102 .2593 .0001 76.62 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm j Avge .0004 .0166 .0009 .0299 .2012 79.31 28.63 SDev .0001 .0002 .0004 .0002 .0019 .20 .07 %RSD 22.78 1.102 52.53 .6164 .9188 .2501 .2350 #1 .0003 .0168 .0013 .0300 .2033 79.48 28.70 #2 .0005 .0167 .0005 .0301 .1998 79.36 28.57 43 .0005 .0164 .0008 .0297 .2006 79.10 28.62 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb 'kvge 3.361 .0040 171.0 .0308 .6477 1.9219 3.2471 SDe .010 .0003 .8 .0004 .0052 2.0269 2.1841 %R� .3072 7.807 .4387 1.375 .8020 105.46 67.264 41 3.372 .0043 171.8 .0313 .6498 .57955 5.7403 42 3.352 .0038 170.9 .0305 .6417 4.2534 2.3293 43 3.357 .0039 170.3 .0308 .6514 .93261 1.6716 31em Sb2068 1960/1 1960/2 Sn T11908 V Zn Jnits ppb ppb ppb ppm ppb ppm ppm wge -.19377 5.1811 1.1983 .0055 .68430 .0027 .0682 SDev 1.56132 6.0651 .3601 .0010 1.4297 .0006 .0007 '0 -RSD 805.77 117.06 30.052 18.96 208.93 20.02 .9623 #1 .30152 3.1711 1.5621 .0051 -.94645 .0034 .0689 #2 1.0598 .37618 1.1907 .0067 1.2772 .0025 .0676 43 -1.9426 11.996 .84200 .0048 1.7222 .0024 .0681 '.lem Pb2203 Se1960 Units ppb ppb kvge 2.8063 2.5250 SDev 1.3059 1.8556 ;D -RSD 46.534 73.487 #1 4.0223 2.0983 f2 2.9705 .91995 k3 1.4261 4.5568 zalysis Report 04/07/05 11:44:25 AM =thod: DVCLPI Sample Name: 0504024-002G .0344 Operator: CO 3n Time: 04/07/05 11:34:50 Sn ppb ppm DM m t: .0043 2.4688 .0005 209.12 11.72 .53863 A ONC Corr. Factor: 1 .0038 -.90381 .0048 7lem A9 Al As1890 B Ba Be 7nits ppb ppm ppb ppm ppm ppm kvge -.16202 .0856 4.5436 .5799 .3101 .0001 3Dev .28699 .0018 .5400 .0019 .0004 .0000 kRSD 177.14 2.075 11.886 .3191 .1467 11.12 41 -.16209 .0870 3.9230 .5818 .3106 .0001 42 -.44897 .0836 4.9065 .5799 .3097 .0001 j 43 .12501 .0863 4.8013 .5781 .3100 .0001 Elem Cd Co Cr Cu Fe K Units ppm ppm ppm ppm ppm ppm Avge .0004 .0221 .0014 .0287 .2649 89.14 SDev .0000 .0004 .0005 .0005 .0006 .15 %RSD 7.689 1.724 38.51 1.657 .2263 .1643 41 .0004 .0221 .0013 .0285 .2655 89.25 42 .0004 .0218 .0009 .0284 .2649 89.20 43 .0005 .0225 .0020 .0293 .2643 88.97 Elem Mn Mo Na Ni P 2203/1 Units ppm ppm ppm ppm ppm ppb Avge 4.292 .0032 186.9 .0349 .5521 4.2913 SDO .007 .0003 .6 .0004 .0076 1.0002 %R .1630 10.40 .3094 1.124 1.379 23.308 4.299 4.285 4.292 Sb2068 ppb -1.0608 1.1028 103.96 .08229 -1.1463 -2.1183 Pb2203 ppb 2.4156 .2945 12.192 2.6964 2.4414 2.1091 .0033 .0028 .0035 1960/1 ppb 5.2098 1.6068 30.841 3.5465 6.7533 5.3295 Se1960 ppb 2.5228 2.0284 80.402 1.5407 4.8552 1.1724 187.6 .0351 186.7 .0344 186.5 .0351 1960/2 Sn ppb ppm 1.1806 .0043 2.4688 .0005 209.12 11.72 .53863 .0044 3.9069 .0038 -.90381 .0048 .5439 .5537 .5589 T11908 ppb 1.0593 2.1631 204.20 .25470 -.58618 3.5094 4.1326 3.3799 5.3614 V PPM .0031 .0004 13.33 .0033 .0034 .0026 page 1 Ca PPM 86.27 .20 .2284 86.49 86.11 86.20 Mg PPM 34.10 .04 .1098 34.14 34.07 34.09 2203/2 ppb 1.4784 .8607 58.218 1.9786 1.9721 .48456 Zn PPM .0703 .0002 .2983 .0705 .0703 .0701 00 ON O O E-� nalysis Report 04/07/05 11:54:07 AM =thod: DVCLPI Sample Name: 0504024-003G in Time: 04/07/05 11:44:32 �Mw' S `� mment : :)d*ONC Corr. Factor: 1 PPM Elem Ag Al As1890 B Jnits ppb ppm ppb ppm kvge -.09112 .1080 1.3532 .7450 3Dev .25990 .0015 1.5394 .0020 ''RSD 285.24 1.397 113.76 .2683 41 -.30733 .1064 1.9728 .7472 42 .19724 .1081 2.4863 .7446 43 -.16327 .1095 -.39939 .7432 Elem Cd Co Cr Cu Jnits ppm ppm ppm ppm kvge .0009 .0143 .0016 .0399 3Dev .0001 .0004 .0008 .0004 'RSD 10.37 2.485 49.04 .9252 #1 .0008 .0140 .0019 .0401 #2 .0009 .0142 .0007 .0395 #3 .0009 .0147 .0022 .0402 ?lem Mn Mo Na Ni Jnits ppm ppm ppm ppm kvge 15.04 .0005 238.2 .0440 3D -02 .0004 .1 .0009 sR .1287 68.37 .0481 1.986 t1 15.04 .0003 238.4 .0434 f2 15.02 .0010 238.2 .0450 'f3 15.06 .0004 238.1 .0437 ?lem Sb2068 1960/1 1960/2 Sn Jnits ppb ppb ppb ppm '�vge -1.6424 9.4666 5.4591 .0042 3Dev .9373 3.0857 2.4637 .0008 ;RSD 57.069 32.596 45.130 17.75 'k1 -1.3321 9.0673 5.8119 .0035 k2 -.89964 6.5998 7.7275 .0041 k3 -2.6955 12.732 2.8381 .0050 ',lem Pb2203 Se1960 Jnits ppb ppb ,vge 3.3151 6.7941 :Dev .4820 .6160 :RSD 14.539 9.0660 1 3.4520 6.8964 2 2.7795 7.3524 3 3.7138 6.1334 Operator: CO page 1 Ba Be Ca PPM ppm ppm .1155 .0000 117.8 .0002 .0000 .2 .1388 20.91 .1885 .1157 .0000 117.8 .1155 .0000 117.6 .1154 .0000 118.0 Fe K Mg PPM ppm ppm .1474 154.2 63.38 .0004 .2 .10 .2757 .1306 .1626 .1477 154.3 63.41 .1469 154.0 63.27 .1475 154.3 63.47 P 2203/1 2203/2 PPM ppb ppb .4785 4.3119 2.8166 .0057 1.4254 .6227 1.191 33.057 22.109 .4754 5.8121 2.2730 .4749 2.9754 2.6809 .4850 4.1483 3.4961 T11908 V Zn ppb ppm ppm -5.7641 .0006 .0543 .2639 .0003 .0006 4.5780 46.26 1.093 -5.9857 .0008 .0544 -5.4722 .0003 .0536 -5.8344 .0009 .0548 nalysis Report 04/07/05 12:03:49 PM ethod: DVCLPI Sample Name: 0504024-004G Operator: CO un Time: 04/07/05 11:54:15 114w- 55 om t: oONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Units ppb ppm ppb ppm ppm ppm Avge -.32313 .0666 1.4214 .1150 .0791 .0000 SDev .20323 .0036 3.4807 .0005 .0001 .0000 %RSD 62.894 5.376 244.88 .4351 .1310 26.20 #1 -.08846 .0703 1.0771 .1153 .0790 .0000 42 -.44121 .0632 -1.8744 .1153 .0792 .0000 43 -.43971 .0662 5.0615 .1144 .0792 .0000 Elem Cd Co Cr Cu Fe K Units ppm ppm ppm ppm ppm ppm Avge .0003 .0005 .0841 .0324 .5639 9.970 SDev .0003 .0003 .0004 .0004 .0011 .069 %RSD 88.57 53.55 .4549 1.365 .1875 .6877 41 .0002 .0003 .0836 .0322 .5627 10.05 42 .0007 .0004 .0841 .0321 .5642 9.936 43 .0001 .0008 .0844 .0329 .5647 9.925 --lem Mn Mo Na Ni P 2203/1 Jnits ppm ppm ppm ppm ppm ppb %vge .9092 -.0000 13.01 .0044 .4009 .88793 3D� .0024 .0004 .12 .0002 .0057 .91334 'sR 2676 2018. .8941 4.840 1.415 102.86 .9119 .9084 .9072 Sb2068 ppb -.46070 .91963 199.62 -.29742 -1.4510 .36636 Pb2203 ppb .52961 .76902 145.20 .33869 1.3761 -.12596 -.0001 -.0004 .0005 1960/1 ppb 1.1821 5.9826 506.12 .83255 -4.6181 7.3317 Se1960 ppb -.56484 .37607 66.579 -.73419 -.82646 -.13388 13.14 12.94 12.93 1960/2 ppb -1.4377 2.4648 171.44 -1.5171 1.0658 -3.8618 .0045 .0042 .0046 Sn PPM .0012 .0009 71.28 .0003 .0014 .0020 .3948 .4060 .4021 T11908 ppb .77237 2.6658 345.15 -.56297 3.8420 -.96190 .89845 -.03063 1.7960 V PPM -.0001 .0005 642.6 -.0005 -.0003 .0005 page 1 Ca PPM 11.36 .00 .0422 11.37 11.36 11.36 Mg PPM 7.815 .010 .1269 7.823 7.804 7.817 2203/2 ppb .34996 1.6020 457.76 .05846 2.0777 -1.0862 Zn PPM .0528 .0007 1.245 .0533 .0532 .0521 nalysis Report 04/07/05 12:13:31 PM page 1 ethod: DVCLPI Sample Name: CCV2 un Time: 04/07/05 12:03:56 omment: oC*CONC Corr. Factor: 1 Elem Ag Al As1890 Units ppb ppm ppb Avge 998.47 50.75 506.41 SDev 1.00 .03 2.55 %RSD .10017 .0679 .50267 #1 998.38 50.79 509.07 #2 997.51 50.75 503.99 43 999.51 50.72 506.18 Errors LC Pass LC Pass LC Pass High 1100.0 55.00 550.00 Low 900.00 45.00 450.00 Elem Cd Co Cr Units ppm ppm ppm Avge 2.535 2.603 2.531 SDev .004 .002 .003 %RSD .1467 .0821 .1332 41 2.532 2.604 2.530 42 2.534 2.600 2.529 #3 2.540 2.604 2.535 #1 1014.5 #� 1014.2 t_ 1019.9 LC Pass 2.750 2.250 Mo PPM 2.480 .006 .2531 2.475 2.479 2.487 NOCHECK 1960/1 ppb 528.13 1.58 .29906 528.75 529.31 526.34 LC Pass 2.750 2.250 Na ppm 76.19 .18 .2322 76.38 76.03 76.15 LC Pass 88.00 72.00 1960/2 ppb 509.16 1.60 .31453 510.77 509.16 507.56 'Irrors LC Pass NOCHECK NOCHECK B PPM 2.445 .003 .1254 2.445 2.442 2.448 LC Pass 2.750 2.250 Cu PPM 2.522 .003 .1313 2.526 2.519 2.522 LC Pass 2.750 2.250 Ni PPM 2.456 .003 .1072 2.454 2.455 2.459 LC Pass 2.750 2.250 Sn PPM 2.508 .006 .2331 2.506 2.503 2.515 NOCHECK Operator: CO Ba PPM 2.516 .002 .0882 2.518 2.514 2.515 LC Pass 2.750 2.250 Fe PPM 51.34 .08 .1591 51.25 51.36 51.40 LC Pass 55.00 45.00 P PPM .0093 .0048 51.78 .0148 .0063 .0067 NOCHECK T11908 ppb 484.96 5.98 1.2335 478.05 488.38 488.44 LC Pass Be PPM 2.518 .005 .1896 2.515 2.516 2.524 LC Pass 2.750 2.250 K PPM 81.51 .38 .4601 81.94 81.33 81.26 LC Pass 88.00 72.00 2203/1 ppb 501.97 3.63 .72319 504.83 497.89 503.20 NOCHECK V PPM 2.551 .000 .0131 2.551 2.551 2.551 LC Pass Ca PPM 49.63 .06 .1300 49.57 49.61 49.70 LC Pass 55.00 45.00 Mg PPM 48.48 .06 .1311 48.44 48.45 48.56 LC Pass 55.00 45.00 2203/2 ppb 483.92 .84 .17260 483.01 484.10 484.65 NOCHECK Zn PPM 2.511 .005 .2137 2.506 2.510 2.517 LC Pass Es LC Pass .4 if 2.750 Low 2.250 Elem Mn ]nits ppm Wge 2.549 SDev .003 '-RSD .1179 41 2.548 42 2.546 43 2.552 Errors LC Pass 4igh 2.750 mow 2.250 ?lem Sb2068 Jn i t s ppb Wge 1016.2 SDev 3.2 'RSD .31715 #1 1014.5 #� 1014.2 t_ 1019.9 LC Pass 2.750 2.250 Mo PPM 2.480 .006 .2531 2.475 2.479 2.487 NOCHECK 1960/1 ppb 528.13 1.58 .29906 528.75 529.31 526.34 LC Pass 2.750 2.250 Na ppm 76.19 .18 .2322 76.38 76.03 76.15 LC Pass 88.00 72.00 1960/2 ppb 509.16 1.60 .31453 510.77 509.16 507.56 'Irrors LC Pass NOCHECK NOCHECK B PPM 2.445 .003 .1254 2.445 2.442 2.448 LC Pass 2.750 2.250 Cu PPM 2.522 .003 .1313 2.526 2.519 2.522 LC Pass 2.750 2.250 Ni PPM 2.456 .003 .1072 2.454 2.455 2.459 LC Pass 2.750 2.250 Sn PPM 2.508 .006 .2331 2.506 2.503 2.515 NOCHECK Operator: CO Ba PPM 2.516 .002 .0882 2.518 2.514 2.515 LC Pass 2.750 2.250 Fe PPM 51.34 .08 .1591 51.25 51.36 51.40 LC Pass 55.00 45.00 P PPM .0093 .0048 51.78 .0148 .0063 .0067 NOCHECK T11908 ppb 484.96 5.98 1.2335 478.05 488.38 488.44 LC Pass Be PPM 2.518 .005 .1896 2.515 2.516 2.524 LC Pass 2.750 2.250 K PPM 81.51 .38 .4601 81.94 81.33 81.26 LC Pass 88.00 72.00 2203/1 ppb 501.97 3.63 .72319 504.83 497.89 503.20 NOCHECK V PPM 2.551 .000 .0131 2.551 2.551 2.551 LC Pass Ca PPM 49.63 .06 .1300 49.57 49.61 49.70 LC Pass 55.00 45.00 Mg PPM 48.48 .06 .1311 48.44 48.45 48.56 LC Pass 55.00 45.00 2203/2 ppb 483.92 .84 .17260 483.01 484.10 484.65 NOCHECK Zn PPM 2.511 .005 .2137 2.506 2.510 2.517 LC Pass nalysis Report 04/07/05 12:13:31 PM page 2 High 1100.0 Low 900.00 Ele* P r � 550.00 2.750 450.00 2.250 2.750 2.250 b2203 Se1960 Units ppb ppb Avge 489.93 515.48 SDev 1.11 1.51 %RSD .22587 .29255 #1 490.28 516.76 #2 488.70 515.87 #3 490.83 513.82 Errors LC Pass LC Pass High 550.00 550.00 Low 450.00 450.00 r � 550.00 2.750 450.00 2.250 2.750 2.250 zalysis Report 04/07/05 12:23:13 PM page 1 =thod: DVCLPI Sample Name: CCVL2 Operator: CO in Time: 04/07/05 12:13:38 Dmt: �d*ONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca inits ppb ppm ppb ppm ppm ppm ppm kvge .11320 -.0014 3.2552 .0173 .0005 .0005 .0166 SDev .31769 .0032 1.0640 .0008 .0002 .0002 .0040 0RSD 280.64 236.2 32.686 4.912 37.32 38.91 24.01 41 -.07013 .0024 2.2444 .0175 .0007 .0008 .0207 #2 .48004 -.0031 3.1558 .0180 .0005 .0005 .0163 V -.07030 -.0034 4.3654 .0164 .0003 .0003 .0128 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK High Low Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0005 .0010 -.0000 .0019 2.568 .0086 .0139 SDev .0002 .0003 .0007 .0006 .005 .0088 .0064 %RSD 41.62 32.03 1723. 29.70 .1810 103.2 45.72 41 .0007 .0013 .0007 .0025 2.574 .0187 .0205 42 .0004 .0010 -.0004 .0016 2.566 .0039 .0135 43 .0004 .0007 -.0004 .0015 2.566 .0030 .0078 ErGs NOCHECK NOCHECK NOCHECK NOCHECK LC Pass NOCHECK NOCHECK High 2.750 Low 2.250 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge .0004 .0025 2.532 -.0001 .0127 -1.4467 -.30124 SDev .0002 .0021 .014 .0009 .0029 2.0678 1.05705 %RSD 51.57 82.49 .5648 887.4 23.14 142.93 350.90 #1 .0007 .0048 2.547 .0007 .0093 -2.4199 .78183 42 .0003 .0019 2.530 -.0011 .0139 .92812 -1.3302 #3 .0004 .0008 2.519 .0001 .0148 -2.8484 -.35537 Errors NOCHECK NOCHECK LC Pass NOCHECK NOCHECK NOCHECK NOCHECK High 2.750 Low 2.250 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -.82467 5.3376 -.84434 .0013 5.4629 .0003 .0000 SDev 1.40273 3.7124 5.92903 .0015 1.8249 .0006 .0007 %RSD 170.10 69.552 702.21 111.4 33.405 226.2 1492. #1 .55978 2.7721 5.2542 .0029 7.2769 .0009 .0001 4 -.78880 9.5945 -6.5879 .0010 5.4845 .0002 .0007 #3 -2.2450 3.6462 -1.1993 .0000 3.6273 -.0003 -.0007 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK nalysis Report High Lo El Pb22 03 Se1960 Units ppb ppb Avge -.68221 1.2147 SDev .45958 2.8975 %RSD 67.366 238.53 #1 -.28391 4.4281 #2 -.57767 -1.1987 #3 -1.1851 .41473 Errors NOCHECK NOCHECK High Low 04/07/05 12:23:13 PM page 2 O O E-� nalysis Report 04/07/05 12:32:56 PM page 1 ethod: DVCLPI Sample Name: CCB2 Operator: CO un Time: 04/07/05 12:23:21 omt: od*ONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge -.09737 -.0174 2.8205 .0016 .0001 .0001 .0073 SDev .54386 .0027 1.6860 .0006 .0001 .0000 .0008 %RSD 558.54 15.37 59.775 36.27 110.3 49.28 11.39 #1 .31450 -.0161 1.6156 .0023 .0001 .0001 .0083 #2 .10724 -.0205 2.0988 .0015 -.0000 .0001 .0067 43 -.71386 -.0157 4.7473 .0011 .0001 .0001 .0070 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 10.000 .2000 10.000 .0200 .2000 .0050 .2000 Low -10.000 -.2000 -10.000 -.0200 -.2000 -.0050 -.2000 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm kvge .0001 .0003 -.0002 .0015 .0036 .0095 .0068 SDev .0001 .0004 .0007 .0003 .0007 .0028 .0063 %RSD 90.60 147.8 306.6 22.94 19.66 29.88 92.68 41 .0002 .0008 -.0000 .0019 .0044 .0093 .0134 42 .0002 -.0001 -.0010 .0014 .0034 .0067 .0063 43 -.0000 .0002 .0003 .0012 .0030 .0124 .0008 Eros LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass Sigh .0050 .0500 .0100 .0250 .1000 5.000 .2000 Low -.0050 -.0500 -.0100 -.0250 -.1000 -5.000 -.2000 :lem Mn Mo Na Ni P 2203/1 2203/2 Jnits ppm ppm ppm ppm ppm ppb ppb kvge .0000 .0004 .0174 -.0003 .0040 .45999 -.27244 SDev .0001 .0004 .0021 .0008 .0011 2.5030 1.51422 '.RSD 111.0 112.9 12.31 249.0 26.31 544.15 555.81 41 .0001 .0008 .0198 .0006 .0049 -.64303 1.0115 �2 .0001 -.0001 .0163 -.0010 .0043 3.3251 -1.9423 43 -.0000 .0004 .0160 -.0005 .0029 -1.3021 .11346 ;rrors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK Sigh .0150 5.000 .0400 mow -.0150 -5.000 -.0400 -Ilem Sb2068 1960/1 1960/2 Sn T11908 V Zn Jnits ppb ppb ppb ppm ppb ppm ppm kvge -1.7831 -1.8296 -4.1941 .0004 2.3664 -.0002 .0002 SDev 1.5429 .4458 2.4951 .0007 1.7063 .0003 .0001 sRSD 86.527 24.365 59.492 162.9 72.107 113.3 93.91 #1 -.20690 -2.3369 -5.8899 -.0000 1.3503 -.0003 .0003 #2• -1.8521 -1.6517 -5.3633 .0013 4.3363 -.0005 -.0000 #3 -3.2903 -1.5003 -1.3290 .0001 1.4125 .0000 .0003 ,rrors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass nalysis Report 04/07/05 12:32:56 PM page 2 High 60.000 Low -60.000 Ele* #1 Pb2203 Se1960 Units ppb ppb Avge -.02804 -3.4063 SDev .43197 1.7738 %RSD 1540.4 52.074 #1 .46104 -4.7063 #2 -.18774 -4.1269 43 -.35743 -1.3856 Errors LC Pass LC Pass High 3.0000 5.0000 Low -3.0000 -5.0000 • • 10.000 .0500 -10.000 -.0500 .0200 -.0200 .nalysis Report 04/07/05 12:42:38 PM ethod: DVCLPI Sample Name: 0504024-005G un Time: 04/07/05 12:33:03 G � omm .0369 .0590 3.1432 .0368 odONC Corr. Factor: 1 ppm .0034 Elem Ag Al As1890 B Units ppb ppm ppb ppm Avge -.03684 .0629 2.7464 .0370 SDev .12094 .0037 .3711 .0002 %RSD 328.31 5.948 13.514 .5232 -.10747 -.10585 .10281 Cd PPM -.0003 .0001 21.95 -.0003 -.0002 -.0003 Mn PPM 2.361 .041 1.744 2.342 2.408 2.333 Sb2068 ppb -1.5248 .8584 56.295 -2.4134 -.70018 -1.4608 Pb2203 ppb .94012 .71244 75.782 .13749 1.1852 1.4977 .0632 2.4078 .0372 .0664 2.6883 .0369 .0590 3.1432 .0368 Operator: CO Ba Be PPM ppm .0099 .0000 .0002 .0000 1.821 35.72 .0098 .0001 .0100 .0000 .0097 .0000 page 1 Ca PPM 16.32 .27 1.675 16.21 16.63 16.11 Co Cr Cu Fe K Mg PPM ppm ppm ppm ppm ppm .0034 .0013 .0083 5.774 4.811 4.355 .0003 .0001 .0007 .101 .077 .068 8.345 4.279 8.518 1.744 1.605 1.570 .0036 .0013 .0076 5.727 4.769 4.309 .0031 .0013 .0090 5.889 4.901 4.433 .0036 .0014 .0084 5.705 4.764 4.323 Mo Na Ni P 2203/1 2203/2 PPM ppm ppm ppm ppb ppb .0001 7.977 .0022 .3257 2.6379 .09175 .0002 .113 .0006 .0064 2.5031 .1.6439 138.6 1.412 26.13 1.978 94.891 1791.7 .0000 7.928 .0016 .3259 3.2717 -1.4280 .0000 8.106 .0024 .3320 -.12121 1.8366 .0004 7.898 .0027 .3191 4.7631 -.13332 1960/1 1960/2 Sn T11908 V Zn ppb ppb ppm ppb ppm ppm 4.4480 .32544 .0035 2.7084 .0002 .0220 2.0100 2.7490 .0021 1.6491 .0001 .0003 45.190 844.69 59.70 60.889 61.73 1.455 3.8338 3.1304 .0035 4.4073 .0001 .0220 6.6935 -2.3639 .0055 2.6037 .0003 .0224 2.8167 .20985 .0014 1.1141 .0003 .0217 Se1960 ppb 1.6987 1.4587 85.873 3.3651 .65266 1.0784 nalysis Report 04/07/05 12:52:20 PM ethod: DVCLPI Sample Name: 0504024-006G Operator: CO un Time: 04/07/05 12:42:46 .0789 -.16405 omm t: Cd Co PPM ppm .0004 od*ONC Corr. Factor: 1 .0003 8.101 6.180 Elem Ag Al As1890 B Ba Units ppb ppm ppb ppm ppm Avge -.35034 .0778 1.3964 .0406 .0573 SDev .17572 .0014 2.3797 .0001 .0002 oRSD 50.158 1.780 170.42 .3744 .2793 -.37382 .0762 -.51314 .0789 -.16405 .0783 Cd Co PPM ppm .0004 .0047 .0000 .0003 8.101 6.180 .0004 .0048 .0004 .0050 .0005 .0044 Mn PPM 2.027 .001 .0326 2.028 2.026 2.027 Sb2068 ppb -.92538 .51285 55.420 -1.2394 -.33356 -1.2032 Pb2203 ppb .08864 .41988 473.70 -.11797 -.18790 .57179 Mo PPM -.0001 .0007 480.6 -.0008 .0006 -.0003 1960/1 ppb 4.2917 3.2378 75.444 5.6329 6.6433 .59875 Se1960 ppb . 1.7747 1.9333 108.94 1.0965 3.9557 .27190 .36239 4.1182 -.29137 Cr PPM .0010 .0003 26.57 .0011 .0008 .0013 Na PPM 6.158 .006 .0981 .0406 .0407 .0404 Cu PPM .0041 .0004 9.488 .0045 .0038 .0039 Ni PPM .0072 .0005 6.593 6.161 .0067 6.161 .0073 6.151 .0077 1960/2 Sn ppb ppm .51742 .0011 1.9241 .0022 371.86 193.6 -1.1690 -.0011 2.6133 .0012 .10804 .0033 .0572 .0572 .0575 Fe PPM .0705 .0023 3.212 .0730 .0699 .0686 P PPM .3167 .0007 .2319 .3175 .3162 .3163 T11908 ppb -.10342 1.04939 1014.6 -.78374 -.63164 1.1051 Be PPM .0001 .0000 35.38 .0001 .0000 .0001 K PPM 3.821 .004 .1068 3.816 3.823 3.824 2203/1 ppb -.40946 2.61254 638.05 -1.3550 2.5442 -2.4176 V PPM -.0002 .0002 86.00 -.0004 -.0000 -.0002 page 1 Ca PPM 10.95 .01 .0894 10.96 10.95 10.94 Mg PPM 3.065 .008 .2760 3.070 3.055 3.069 2203/2 ppb .33655 1.8135 . 538.85 .49884 -1.5527 2.0635 Zn PPM .0378 .0003 .8212 .0381 .0380 .0375 nalysis Report 04/07/05 01:02:03 PM ethod: DVCLPI Sample Name: 0504024-007G #2 .0002 Operator: CO un Time: 04/07/05 12:52:28 /yjw_ is� Mn om t. So odCONC Corr. Factor: 1 % .1468 #1 Elem Ag Al As1890 B Ba Be Units ppb ppm ppb ppm ppm ppm Avge -.38798 .1407 3.9016 .4816 .1343 .0001 SDev .58292 .0010 .3311 .0011 .0001 .0000 %RSD 150.24 .7119 8.4855 .2297 .0488 23.16 #1 -.94476 .1419 4.2464 .4829 .1344 .0001 #2 .21797 .1404 3.8722 .4810 .1343 .0001 #3 -.43716 .1399 3.5863 .4809 .1343 .0001 Elem Cd Co Cr Cu Fe K Units ppm ppm ppm ppm ppm ppm Avge .0002 .0092 .0030 .0275 1.837 97.77 SDev .0001 .0005 .0003 .0003 .002 .24 %RSD 41.01 5.547 10.20 1.062 .0947 .2505 #1 .0002 .0096 #2 .0002 .0094 #3 .0004 .0086 Elem Mn So .005 % .1468 #1 #2 #3 Avge SDev %RSD #1 #2 #3 Elem Se196 Units Avge SDev %RSD #1 #2 3.195 3.191 3.185 Sb2068 ppb 10647 1.4309 1344.0 1.7560 -.63613 -.80046 Pb2203 ppb 8.3331 1.4489 17.387 Mo Units ppm PPM Avge 3.190 .0015 .0001 5.18? .0016 .0015 .0014 Elem 1960/ Units 1 ppb 11.566 4.015 5 3 9 34.71 8.116 10.60 15.974 0 ppb1 0 5 3.125 2.719 87.00 9.6487 -.00758 0 8.5704 4.5110 6.7803 4.872 #. 0033 0032 0027 Na PPM 82.25 .04 0547 82.30 82.24 82.21 1960/2 ppb -1.0898 3.0375 278.73 -4.0641 2.0072 -1.2124 _0275 .0277 .0272 Ni PPM .0221 .0002 1.091 .0224 .0219 .0221 Sn PPM 0057 0014 24.81 0073 0053 0045 1.839 1.837 1.836 P PPM .4951 .0092 1.853 .4845 .5007 .5001 T11908 ppb 1.6837 5224 31.025 1.1381 2.1792 1.7336 97.85 97.49 97.96 2203/1 ppb 9.3828 2.4754 26.382 10.569 6.5375 11.042 V PPM .0008 .0003 33.85 .0009 .0011 .0005 page 1 Ca PPM 69.35 .14 .2025 69.47 69.38 69.20 Mg PPM 37.62 .02 .06321.2 37.64 37.64 37.60 2203/2 ppb 7.8083 1.2148 15.558 9.1884 6.9007 7.3358 Zn PPM .0597 .0001 .2006 nalysis Report 04/07/05 01:11:46 PM ethod: DVCLPI Sample Name: 0504024-008G un Time: 04/07/05 13:02:10 1.643 om t: 1.628 Cd Co PPM od�CONC Corr. Factor: 1 .0023 .0002 Elem Ag Al As1890 B Units ppb ppm ppb ppm Avge -.32776 1.636 1.6567 .0843 SDev .74493 .008 1.2722 .0001 %RSD 227.28 .4589 76.795 .1830 -.48888 1.636 -.97896 1.643 .48454 1.628 Cd Co PPM ppm -.0005 .0023 .0002 .0005 41.88 22.43 -.0007 .0019 -.0006 .0021 -.0003 .0029 Mn Mo PPM ppm .1813 .0003 .0003 .0006 .1527 193.2 .1816 .0004 .1810 -.0003 .1814 .0008 Sb2068 1960/1 ppb ppb .23056 8.5511 4.0784 3.7790 1768.9 44.193 -2.9897 10.470 -1.1351 10.986 4.8165 4.1976 Pb2203 Se1960 ppb ppb 6.3562 2.6634 .9285 3.8647 14.608 145.11 5.5194 7.1096 6.1941 .77147 7.3551 .10906 2.3079 2.4715 .19065 Cr PPM .0123 .0007 5.949 .0118 .0120 .0132 Na PPM 11.93 .03 .2907 11.96 11.94 11.89 1960/2 ppb -.27675 5.08627 1837.9 5.4312 -4.3286 -1.9328 .0842 .0845 .0843 Cu PPM .0201 .0006 2.879 .0200 .0195 .0206 Ni PPM .0084 .0005 6.119 t1' Sn PPM .0013 .0015 115.0 .0016 -.0003 .0028 Operator: CO Ba PPM .1065 .0002 .2010 .1063 .1067 .1066 Fe PPM 16.04 .06 .3644 15.97 16.07 16.07 P PPM .5674 .0054 .9575 .5637 .5737 .5649 T11908 ppb 3.7593 .0447 1.1892 3.8005 3.7118 3.7656 Be PPM .0002 .0000 17.47 .0001 .0001 .0002 K PPM 14.65 .03 .2136 14.68 14.62 14.64 2203/1 ppb 6.3670 1.9795 31.091 6.4289 4.3573 8.3149 V PPM .0074 .0004 5.548 .0072 .0070 .0078 page 1 Ca PPM 16.02 .05 .2933 15.96 16.05 16.04 Mg PPM 6.239 .020 .3136 6.216 6.247 6.253 2203/2 ppb 6.3500 1.1195 17.629 5.0646 7.1104 6.8752 Zn PPM .0413 .0001 .2110 .0413 .0414 .0412 nalysis Report 04/07/05 01:21:28 PM ethod: DVCLPI Sample Name: 0504024-009G un Time: 04/07/05 13:11:53 om t: o�ONC Corr. Factor: 1 Elem Ag Al As1890 B Units ppb ppm ppb ppm Avge -.37435 -.0159 .69704 .0008 SDev .63899 .0047 .54508 .0006 %RSD 170.69 29.85 78.199 71.38 #1 -1.0718 -.0214 .67152 .0002 #2 -.23430 -.0137 1.2544 .0011 43 .18300 -.0127 .16518 .0013 Elem Cd Co Cr Cu Units ppm ppm ppm ppm Avge -.0001 .0003 -.0003 .0032 SDev .0001 .0005 .0002 .0007 %RSD 102.7 138.7 45.11 22.06 #1 -.0002 -.0002 -.0002 .0040 #2 .0000 .0008 -.0005 .0028 #3 -.0001 .0004 -.0003 .0027 Elem Mn Mo Na Ni Units ppm ppm ppm ppm Avge .0037 -.0003 .1129 -.0007 S5 .0000 .0002 .0025 .0003 % 1.191 83.51 2.234 38.66 #1 .0036 -.0004 .1150 -.0004 #2 .0037 -.0004 .1136 -.0007 43 .0037 -.0000 .1101 -.0010 Elem Sb2068 1960/1 1960/2 Sn Units ppb ppb ppb ppm Avge -.44209 1.7027 -2.9671 .0005 SDev 1.73666 5.4745 2.2576 .0010 %RSD 392.83 321.52 76.088 200.9 41 -1.8122 -1.6608 -2.1590 -.0006 #2 1.5111 8.0197 -1.2247 .0008 43 -1.0252 -1.2508 -5.5176 .0013 Elem Pb2203 Se1960 Units ppb ppb Avge -.74085 -1.4116 SDev .84817 3.0174 %RSD 114.49 213.76 41 -.25889 -1.9927 42 -1.7202 1.8541 43 0 -.24346 -4.0963 Operator: CO Ba Be PPM ppm .0001 -.0000 .0001 .0000 171.2 77.34 -.0000 -.0000 .0001 -.0000 .0001 -.0000 Fe K PPM ppm .0087 .0373 .0021 .0103 23.57 27.76 .0106 .0285 .0089 .0347 .0066 .0487 P 2203/1 PPM ppb .0141 -2.5321 .0064 1.4364 45.17 56.727 .0156 .0196 .0071 T11908 ppb -1.2814 1.1804 92.119 -2.3287 -.00232 -1.5131 -1.3373 -2.1332 -4.1258 V PPM -.0003 .0003 80.47 -.0006 -.0000 -.0004 page 1 Ca PPM .0797 .0019 2.407 .0819 .0787 .0785 Mg PPM .0179 .0015 8.149 .0194 .0179 .0165 2203/2 ppb .15268 1.6081 1053.3 .27877 -1.5148 1.6940 Zn PPM .0198 .0001 .6351 .0198 .0197 .0200 nalysis Report 04/07/05 01:31:11 PM ethod: DVCLPI Sample Name: 0504067-001G .0127 Operator: CO un Time: 04/07/05 13:21:36 .0017 1.5190 .0121 omm t: .0003 .2505 -.0005 .2488 od*ONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Units ppb ppm ppb ppm ppm ppm Avge -.76427 .0050 1.6257 .0125 .0050 .0000 SDev .46274 .0046 1.0506 .0003 .0000 .0000 %RSD 60.547 91.19 64.622 2.728 .2832 258.3 -.23117 -.99954 -1.0621 Cd PPM -.0001 .0002 149.1 -.0001 .0001 -.0003 Mn PPM .0363 .0002 .5505 .0364 .0365 .0361 Sb2068 ppb -3.8422 1.6226 42.232 -4.4695 -1.9996 -5.0576 Pb22 03 ppb -.89433 2.26526 253.29 -3.3851 1.0427 -.34062 .0032 .63259 .0127 .0103 2.7256 .0128 .0017 1.5190 .0121 Co PPM .0008 .0006 69.01 .0009 .0013 .0002 Mo PPM -.0005 .0003 66.34 -.0003 -.0003 -.0008 1960/1 ppb 4.5215 5.7489 127.15 -.15441 2.7787 10.940 Se1960 ppb -1.6490 .1949 11.816 -1.4791 -1.8617 -1.6062 Cr PPM .0001 .0004 617.4 .0002 .0004 -.0004 Na PPM 23.91 .15 .6357 24.05 23.92 23.75 1960/2 ppb -4.7303 2.9042 61.396 -2.1412 -4.1792 -7.8707 Cu PPM .0136 .0012 8.600 .0150 .0131 .0128 Ni PPM -.0002 .0006 252.8 -.0009 .0003 -.0002 S PPM .0012 .0014 118.5 .0005 .0029 .0003 .0050 .0050 .0050 Fe PPM .3743 .0031 .8186 .3764 .3758 .3708 P PPM .4838 .0119 2.465 .4907 .4701 .4907 T11908 ppb 1.5949 1.8730 117.43 .31480 3.7446 .72540 m$e K PPM 1.001 .004 .3938 1.000 1.006 .9980 2203/1 ppb 2.6988 4.3615 161.61 page 1 Ca PPM 9.425 .049 .5183 9.435 9.469 9.373 Mg PPM 3.895 .030 .7615 3.916 3.908 3.861 2203/2 ppb -2.6891 3.2034 119.13 -.65597 -4.7485 1.1233 1.0017 7.6291 -4.3203 V Zn PPM ppm -.0003 .2486 .0005 .0020 172.2 .7942 .0003 .2505 -.0005 .2488 -.0007 .2465 nalysis Report 04/07/05 01:40:53 PM page 1 .ethod: DVCLPI Sample Name: ORIF .un Time: 04/07/05 13:31:18 bmm nt : od�CONC Corr. Factor: 1 Elem Ag Al As1890 Units ppb ppm ppb Avge 19.013 -.0151 23.241 SDev .130 .0015 1.499 %RSD .68516 10.19 6.4517 41 19.126 -.0159 22.950 42 18.870 -.0160 24.865 #3 19.042 -.0133 21.908 Elem Cd Co Cr Units ppm ppm ppm Avge .0104 .1036 .0198 SDev .0002 .0011 .0008 %RSD 2.224 1.097 4.089 #1 .0103 .1048 .0207 42 .0106 .1026 .0191 #3 .0102 .1033 .0196 Elem Mn Mo Na Units ppm ppm ppm Avge .0304 .0261 .0351 SD .0000 .0003 .0043 % .0881 1.182 12.41 #1 .0304 .0264 .0396 #2 .0305 .0259 .0346 #3 .0304 .0259 .0310 Elem Sb2068 1960/1 1960/2 Units ppb ppb ppb Avge 119.66 20.332 4.3586 SDev 1.32 16.793 11.884 %RSD 1.1009 82.593 272.65 41 118.58 19.030 6.6842 #2 119.27 4.2277 14.908 #3 121.13 37.737 -8.5162 Elem Pb2203 Se1960 Units ppb ppb Avge 4.4619 9.6781 SDev 1.3010 2.4334 %RSD 29.157 25.144 #1 5.2853 10.796 42 5.1383 11.352 #3 2.9621 6.8866 Operator: CO B Ba Be Ca PPM ppm ppm ppm .1947 .0001 .0103 .0094 .0005 .0001 .0000 .0017 .2694 83.28 .3649 17.88 .1941 .0001 .0104 .0111 .1950 .0001 .0103 .0094 .1950 .0000 .0103 .0077 Cu Fe K Mg PPM ppm ppm ppm .0509 .0015 .0012 .0036 .0007 .0004 .0021 .0073 1.397 26.10 182.2 203.5 .0517 .0020 .0035 .0078 .0508 .0012 .0007 .0077 .0502 .0014 -.0007 -.0048 Ni P 2203/1 2203/2 PPM ppm ppb ppb .0785 .0150 15.776 -1.1874 .0003 .0057 17.981 10.9271 .3577 37.71 113.98 920.29 .0788 .0143 4.8553 5.4992 .0783 .0211 5.9430 4.7359 .0783 .0098 36.529 -13.797 Sn T11908 V Zn PPM ppb ppm ppm .0842 21.556 .1015 .0432 .0014 2.342 .0005 .0002 1.714 10.864 .4491 .4932 .0858 19.664 .1018 .0434 .0835 24.175 .1016 .0430 .0832 20.829 .1009 .0432 nalysis Report 04/07/05 01:56:19 PM page 1 ethod: DVCLPI Sample Name: ICSAF Operator: CO un Time: 04/07/05 13:46:44 omt: odWONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .20462 528.5 -1.1001 .0100 .0014 .0002 520.8 SDev .25530 .4 1.6934 .0007 .0001 .0000 .5 %RSD 124.77 .0832 153.93 6.589 6.647 10.49 .0932 41 .44824 528.9 -.21412 .0093 .0015 .0002 520.6 #2 .22657 528.1 -3.0527 .0102 .0014 .0001 521.4 #3 -.06094 528.4 -.03355 .0106 .0013 .0002 520.5 Errors LC Pass LC Pass NOCHECK NOCHECK LC Pass LC Pass LC Pass High 10.000 600.0 .2000 .0050 600.0 Low -10.000 400.0 -.2000 -.0050 400.0 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge -.0045 .0022 .0046 .0028 203.7 .0154 525.9 SDev .0004 .0002 .0004 .0003 .5 .0058 .7 %RSD 8.164 8.561 8.625 10.06 .2550 37.30 .1347 41 -.0048 .0021 .0043 .0026 203.1 .0199 525.2 #2 -.0047 .0024 .0051 .0031 204.0 .0175 526.6 #3 -.0041 .0020 .0045 .0027 204.0 .0089 525.8 E*s LC Pass NOCHECK LC Pass NOCHECK LC Pass NOCHECK LC Pass High .0050 .0100 240.0 600.0 Low -.0050 -.0100 160.0 400.0 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge .0091 -.0016 .0615 .0033 .0186 60.483 -24.132 SDev .0001 .0006 .0013 .0004 .0046 5.904 1.970 %RSD 1.047 40.00 2.038 12.47 24.93 9.7612 8.1631 #1 .0091 -.0010 .0623 .0034 .0137 67.263 -25.710 #2 .0092 -.0023 .0621 .0037 .0191 56.479 -24.764 #3 .0090 -.0015 .0601 .0028 .0229 57.706 -21.924 Errors LC Pass NOCHECK NOCHECK LC Pass NOCHECK NOCHECK NOCHECK High .0150 .0400 Low -.0150 -.0400 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge 3.6481 15.855 -.59042 -.0107 H14.154 .0040 .0091 SDev 5.1612 8.151 4.83857 .0038 3.774 .0002 .0003 %RSD 141.48 51.406 819.51 35.50 26.664 5.363 2.786 II## 4.3290 11.412 4.5089 -.0137 H10.033 .0040 .0093 #� -1.8198 10.892 -5.1173 -.0119 H14.989 .0038 .0091 #3 8.4351 25.262 -1.1628 -.0064 H17.442 .0042 .0088 Errors LC Pass NOCHECK NOCHECK NOCHECK LC High LC Pass LC Pass nalysis Report High 60.000 Lo -60.000 l High 6.0000 Low -6.0000 E e Pb2203 Se1960 Units ppb ppb 4.8865 4.0674 83.238 H6.8080 .21431 Avge 4.0449 SDev 1.5543 oRSD 38.425 #1 5.2509 #2 2.2909 #3 4.5931 Errors LC Pass • • LC Pass 5.0000 -5.0000 04/07/05 01:56:19 PM page 2 10.000 .0500 .0200 -10.000 -.0500 -.0200 O O E-� H7.6372 • • LC Pass 5.0000 -5.0000 04/07/05 01:56:19 PM page 2 10.000 .0500 .0200 -10.000 -.0500 -.0200 O O E-� .nalysis Report , 04/07/05 02:06:02 PM page 1 lethod: DVCLPl Sample Name: ICSABF Operator: CO .un Time: 04/07/05 13:56:27 'omt : Iod#WONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1093.0 537.3 1050.1 1.039 .5304 .5218 517.4 SDev 1.8 .6 4.1 .001 .0003 .0003 .8 %RSD .16504 .1043 .39067 .0839 .0573 .0650 .1593 #1 1094.0 537.9 1054.3 1.038 .5306 .5214 516.5 #2 1094.0 537.0 1046.1 1.040 .5306 .5218 517.7 #3 1090.9 536.9 1049.7 1.039 .5301 .5221 518.1 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 1200.0 600.0 1200.0 1.200 .6000 .6000 600.0 Low 800.00 400.0 800.00 .8000 .4000 .4000 400.0 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .9965 .4990 .5221 .5618 203.4 -.0056 524.4 SDev .0003 .0041 .0004 .0006 .3 .0071 .3 %RSD .0265 .8197 .0830 .1068 .1258 125.3 .0579 #1 .9964 .5035 .5222 .5611 203.7 -.0132 524.8 #2 .9963 .4956 .5224 .5622 203.2 -.0046 524.3 #3 .9968 .4979 .5216 .5621 203.4 .0008 524.2 Eos LC Pass LC Pass LC Pass LC Pass LC Pass NOCHECK LC Pass High 1.200 .6000 .6000 .6000 240.0 600.0 Low .8000 .4000 .4000 .4000 160.0 400.0 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge .5361 1.006 .0310 .9808 .0201 1085.2 986.37 SDev .0006 .002 .0005 .0035 .0039 6.4 4.99 %RSD .1102 .1724 1.575 .3549 19.60 .58970 .50564 41 .5367 1.006 .0315 .9771 .0178 1092.6 983.48 #2 .5356 1.008 .0307 .9841 .0179 1081.8 992.13 43 .5359 1.004 .0307 .9811 .0247 1081.2 983.51 Errors LC Pass NOCHECK NOCHECK LC Pass NOCHECK NOCHECK NOCHECK High .6000 1.200 Low .4000 .8000 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge 1.0269 1061.7 1040.1 .9941 999.32 .5282 .9713 SDev 2.2925 4.6 13.7 .0038 4.88 .0008 .0015 %RSD 223.23 .43554 1.3137 .3793 .48792 .1474 .1572 #1 3.0973 1066.0 1055.9 .9985 993.70 .5291 .9726 #S -1.4367 1062.4 1032.7 .9924 1001.9 .5275 .9696 #3 1.4202 1056.8 1031.8 .9915 1002.4 .5281 .9717 Errors NOCHECK NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass nalysis Report 04/07/05 02:06:02 PM page 2 High Lo El Pb2203 Se1960 Units ppb ppb Avge 1019.3 1047.3 SDev 3.0 10.4 %RSD .29678 .99401 #1 1019.8 1059.3 #2 1022.0 1042.6 #3 1016.0 1040.1 Errors LC Pass LC Pass High 1200.0 1200.0 Low 800.00 800.00 • • 1200.0 .6000 800.00 .4000 1.200 .8000 nalysis Report 04/07/05 02:15:45 PM page 1 ethod: DVCLPI Sample Name: CCV4 Operator: CO .un Time: 04/07/05 14:06:10 om t: b CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge 1014.4 51.67 517.17 2.497 2.558 2.582 51.04 SDev 4.4 .20 5.70 .012 .011 .013 .21 %RSD .42895 .3889 1.1018 .4654 .4224 .5154 .4208 #1 1010.1 51.46 510.73 2.485 2.545 2.568 50.82 #2 1014.3 51.67 521.54 2.497 2.561 2.587 51.07 #3 1018.8 51.87 519.24 2.508 2.566 2.593 51.24 Errors LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 1100.0 55.00 550.00 2.750 2.750 2.750 55.00 Low 900.00 45.00 450.00 2.250 2.250 2.250 45.00 Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge 2.573 2.543 2.581 2.595 51.88 81.87 49.58 SDev .015 .025 .013 .009 .31 .27 .18 %RSD .5708 .9975 .5156 .3337 .5982 .3330 .3539 41 2.556 2.514 2.567 2.585 51.54 81.56 49.39 #2 2.577 2.556 2.583 2.598 51.96 81.97 49.62 #3 2.585 2.560 2.593 2.601 52.14 82.08 49.74 Eos LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass LC Pass High 2.750 2.750 2.750 2.750 55.00 88.00 55.00 Low 2.250 2.250 2.250 2.250 45.00 72.00 45.00 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge 2.593 2.533 77.59 2.523 .0070 514.42 495.17 SDev .013 .014 .61 .011 .0016 8.18 .95 0 -.RSD .4916 .5600 .7901 .4254 22.81 1.5898 .19274 #1 2.579 2.519 77.25 2.512 .0059 506.43 496.27 #2 2.597 2.533 77.21 2.523 .0063 514.07 494.55 #3 2.603 2.547 78.29 2.534 .0089 522.77 494.69 Errors LC Pass NOCHECK LC Pass LC Pass NOCHECK NOCHECK NOCHECK High 2.750 88.00 2.750 Low 2.250 72.00 2.250 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge 1032.9 539.75 525.39 2.547 504.76 2.604 2.538 SDev 3.7 3.32 4.19 .019 8.82 .012 .019 %RSD .35784 .61557 .79706 .7477 1.7472 .4770 .7303 #1 1029.0 536.36 524.81 2.526 497.11 2.590 2.518 ##0 1036.3 543.00 529.83 2.552 502.75 2.607 2.540 #3 1033.5 539.89 521.52 2.563 514.41 2.614 2.554 Errors LC Pass NOCHECK NOCHECK NOCHECK LC Pass LC Pass LC Pass inalysis Report 04/07/05 02:15:45 PM page 2 High 1100.0 Loo 900.00 Elem Pb2203 Se1960 Units ppb ppb Avge 501.58 530.17 SDev 2.24 3.54 %RSD .44691 .66822 #1 499.65 528.66 #2 501.05 534.22 #3 504.04 527.64 Errors LC Pass LC Pass High 550.00 550.00 Low 450.00 450.00 • • 550.00 2.750 450.00 2.250 2.750 2.250 nalysis Report 04/07/05 02:25:28 PM page 1 ethod: DVCLPI Sample Name: CCVL4 Operator: CO an Time: 04/07/05 14:15:53 a t: o CONC Corr. Factor: 1 Elem Ag Al As1890 B Ba Be Ca Units ppb ppm ppb ppm ppm ppm ppm Avge .13253 .0201 2.9952 .0043 .0004 .0004 .0255 SDev .42306 .0079 .3541 .0009 .0001 .0002 .0103 %RSD 319.23 39.08 11.821 20.56 34.90 41.03 40.42 #1 -.20651 .0282 2.6605 .0053 .0004 .0006 .0368 #2 -.00254 .0197 3.3659 .0041 .0005 .0004 .0233 #3 .60663 .0125 2.9592 .0036 .0002 .0003 .0165 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK High Low Elem Cd Co Cr Cu Fe K Mg Units ppm ppm ppm ppm ppm ppm ppm Avge .0005 .0004 .0003 .0004 2.582 .0129 .0235 SDev .0002 .0006 .0002 .0002 .005 .0066 .0090 --.RSD 41.21 157.6 66.61 46.13 .1772 51.05 38.34 #1 .0007 .0010 .0005 .0005 2.585 .0053 .0326 #2 .0005 .0006 .0003 .0006 2.584 .0173 .0231 #3 .0003 -.0003 .0001 .0002 2.577 .0160 .0146 Ars NOCHECK NOCHECK NOCHECK NOCHECK LC Pass NOCHECK NOCHECK High 2.750 Low 2.250 Elem Mn Mo Na Ni P 2203/1 2203/2 Units ppm ppm ppm ppm ppm ppb ppb Avge .0002 .0024 2.476 -.0007 .0010 -1.2933 .60972 SDev .0002 .0013 .011 .0009 .0053 2.0045 .81781 %RSD 75.31 57.00 .4350 127.1 514.3 155.00 134.13 #1 .0004 .0039' 2.480 .0002 -.0050 .89229 -.28342 #2 .0002 .0017 2.484 -.0007 .0045 -1.7261 1.3219 #3 .0001 .0015 2.464 -.0017 .0036 -3.0460 .79070 Errors NOCHECK NOCHECK LC Pass NOCHECK NOCHECK NOCHECK NOCHECK High 2.750 Low 2.250 Elem Sb2068 1960/1 1960/2 Sn T11908 V Zn Units ppb ppb ppb ppm ppb ppm ppm Avge -.92675 .71147 -1.2151 .0011 7.6491 .0000 .0001 SDev 2.02145 4.4092 1.4943 .0007 3.2990 .0004 .0000 %RSD 218.12 619.73 122.98 62.90 43.129 11700. 2.755 1.3690 -3.3333 -2.6450 .0019 10.665 .0000 .0001 -2.4398 5.4117 .33627 .0007 8.1564 -.0004 .0001 #3 -1.7095 .05604 -1.3367 .0007 4.1258 .0004 .0001 Errors NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK NOCHECK O N O H .nalysis Report High Lo � Elei4� P b2203 Se1960 Units ppb ppb Avge -.02349 -.57314 SDev .41307 2.46396 %RSD 1758.7 429.91 #1 .10858 -2.8738 #2 .30740 2.0268 #3 -.48644 -.87247 Errors NOCHECK NOCHECK High Low • • 04/07/05 02:25:28 PM page 2 ,--i (V O H nalysis Report 04/07/05 02:35:11 PM page 1 ethod: DVCLPI Sample Name: CCB4 un Time: 04/07/05 14:25:.36 Units omt: Avge .0003 SDev odWONC Corr. Factor: 1 65.93 Elem Ag Al As1890 Units ppb ppm ppb Avge -.11889 .0003 1.9239 SDev .07932 .0023 .2994 %RSD 66.721 828.5 15.560 #1 -.16466 #2 -.02729 #3 -.16470 Errors LC Pass High 10.000 Low -10.000 Elem Cd Units ppm Avge .0003 SDev .0002 %RSD 65.93 #1 .0005 #2 .0004 #3 .0001 %RSD 106.38 Erles LC Pass High .0050 Low -.0050 Elem Mn Units ppm Avge -.0000 SDev .0000 %RSD 121.5 #1 -.0000 #2 -.0001 #3 -.0000 Errors LC Pass High .0150 Low -.0150 Elem Sb2068 Units ppb Avge .72178 SDev .76784 %RSD 106.38 #1 1.5467 #2i .02791 #3 .59070 Errors LC Pass .0025 1.6969 -.0021 1.8116 .0004 2.2631 LC Pass LC Pass .2000 10.000 -.2000 -10.000 Co Cr ppm ppm .0001 .0001 .0006 .0004 463.2 318.1 .0008 -.0001 -.0000 -.0001 -.0004 .0007 LC Pass LC Pass .0500 .0100 -.0500 -.0100 Mo Na ppm ppm .0008 .0097 .0003 .0014 33.01 14.36 .0005 .0010 .0007 NOCHECK 1960/1 ppb .35571 4.4042 1238.1 -3.4644 -.64140 5.1729 NOCHECK .0109 .0099 .0082 LC Pass 5.000 -5.000 1960/2 ppb -.70611 3.85214 545.54 2.4467 .43486 -4.9998 NOCHECK B ppm .0007 .0008 108.0 .0010 .0014 -.0002 LC Pass .0200 -.0200 Cu PPM .0003 .0001 38.25 .0003 .0002 .0004 LC Pass .0250 -.0250 Ni ppm -.0009 .0003 36.49 -.0007 -.0008 -.0013 LC Pass .0400 -.0400 Sn ppm .0014 .0021 149.7 .0033 .0019 -.0009 NOCHECK Ba PPM .0001 .0001 48.61 .0001 .0001 .0000 Operator: CO Be ppm .0001 .0001 61.27 LC Pass .2000 -.2000 Fe ppm .0056 .0019 34.41 .0078 .0051 .0040 LC Pass .1000 -.1000 P ppm .0019 .0032 174.4 -.0019 .0034 .0040 NOCHECK T11908 ppb 1.4600 1.1883 81.391 1.8457 .12677 2.4076 LC Pass .0001 .0000 .0001 LC Pass .0050 -.0050 K ppm -.0031 .0053 172.7 -.0022 .0017 -.0087 LC Pass 5.000 -5.000 2203/1 ppb -.47509 2.83822 597.40 -3.1731 2.4851 -.73731 NOCHECK Ca PPM .0059 .0016 27.23 .0078 .0051 .0049 LC Pass .2000 -.2000 Mg PPM .0064 .0042 65.89 .0106 .0064 .0022 LC Pass .2000 -.2000 2203/2 ppb .28189 .90523 321.13 -.45203 1.2934 .00427 NOCHECK V Zn ppm ppm -.0003 .0003 .0003 .0007 105.6 277.0 .0000 -.0004 -.0006 LC Pass .0005 .0008 -.0005 LC Pass nalysis Report 04/07/05 02:35:11 PM page 2 High 60.000 Lo* -60.000 Elem Pb2203 Se1960 Units ppb ppb Avge .03031 -.35208 SDev 1.5424 1.10935 %RSD 5088.5 315.08 41 -1.3577 .47872 #2 1.6908 .07691 #3 -.24218 -1.6119 Errors LC Pass LC Pass High 3.0000 5.0000 Low -3.0000 -5.0000 • • 10.000 .0500 -10.000 -.0500 .0200 -.0200 M N O O E-� f -12M L,A[3S, INC.>1�� Cal. Stds. Prep: Dc-wW� �ource : H1; h 0vc, �Z jF b ccccL- Instrument I.D. LecwNaAA 41AWAO MERCURY (Hg) ANALYST SIGNATURE: 1 1 1 a u 7 .,2 2 5-7 b :25U 53L88 13 af, % Zb23 (o DATE • 'i 67& - Tm 1010 # SPR LAB NO. RESULT (UG/L) DIL. FACTOR SAMPLE WEIGHT 4s TS MG/RG SAMPLE ID/NOTES v - 3 CGd t y c c.3 i Zo.1 LD. iS�c 7 1-0.1 - 14w IN la -1 1 ' L eo• w- D ill L0.i 13 LG_i )y 0 A \ J•))� S 15 , S. �a 1% L0 17 -VgCW4-WS 1-0-1 roto 1 u U" LOo 60.` lbD ascce6 /-o- �S K4 -i' i5 LD a3 40' 1Q'•\ O V' Gb 1 P 0097 b� �� ,—r �.r ■mmW A6=mmi . MERCURY STANDARDS AND -REAGENTS ICV DATE LOT # CALIBRATION LOT # POTASSIUM PERS FATE H2M LOT # OD(, POTASSIUM PERMANGANATE H2M LOT # �M b HYDROXYLAMINE SULFATE H2M LOT # STANNOUS CHLORIDE H2M LOT # SULFURIC NITRIC ACID DATE lOT # K 6 of K3H 5 SOURCE r' ACID LOT # 3a �1'�3a SOURCE NAME NAME A JU2AA UA", INC. Cisal. Stds. PrejS: 4 i ource:_Jiih PVi& IFI,M Instrument I.D. MERCURY (Hg) 00, ANALYST SIGNATURE • DATE: los # SPR LAB NO. RESULT (UG/L) DIL. FACTOR SAMPLE WEIGHT % TS MG/RG SAMPLE ID/NOTES .9 v 7-7--42-Z CL4 5 5-%(o —TV-- IS- cc7 2-6- CC.4,3 40.1 M - 611 1o• �q 7✓ - I 1J I lU o cV 32 a7AD 0. to 33 i J 'I - z `a - - bwin&1 µS 37 « 3 cc4l koH 'O�iv: �cxJ �2 1 �• J�/ v. `H 002,9 0.45k , tx� c 0.51 f cb i 1H �. - r 1 a -40 Q u b � ',C- 'Paw �v 1 A. %CW -LP a0+4 M"gr ILLP DEx`ou 1M IL _ _.. I MERCURY STANDARDS AND REAGENTS I lzIw fod-is' i DATE ICV LO CALIBRATION LOT # POTASSIUM PERSULFATE H2M LOT # POTASSIUM PERMANGANATE H2M LOT # HYDROXYLAMINE SULFATE H2M LOT # STANNOUS CHLORIDE H2M LOT # NAME DATE NITRIC ACID LOT # SOURCE Sul Fl ACID LOT # !i;E> ME 4 Q M O F•1 �H2M LABS, INC. al. Stds. Prep: LJJOS u rc e : hl-, R-, 1& j Instrument I.D. L I&J140 MERCURY (Hg) JANALYST SIGNATURE • 1 3 DATE • 7 r� # SPR LAB NO. RESULT (UG/L) DIL. FACTOR SAMPLE WEIGHT % TS MG/RG SAMPLE ID/NOTES •7 &M - - S-0 -t V-- S- co _WA e©- SIs 10 003A Z- 0. Cave o 1% OVA Zb`i t'L A p.l7Qj S- -ca t3 0.13 „p Ob?►� 0. i Yv Z WA Lp-% Oo r7 A e3 X2(0 001 1S 0 4f Dos if CCN 6 KI P 0101 Co 2 Folder: Protocol: 0705 MERCURY , Afiage 1 �A �g� ***POST-RUN REPORT*** Line Conc. -------------------------------------------------------------------------------- Units SD/RSD 1 2 3 4 5 *** Standard: 1 Rep: 1 Seq: 1 10:15:55 07 Apr 05 HG Hg 22 .000 ug/L *** Standard: 2 Rep: 1 Seq: 2 10:17:33 07 Apr 05 HG Hg .200 ug/L 578 *** Standard: 3 Rep: 1 Seq: 3 10:19:13 07 Apr 05 HG Hg 1.00 ug/L 2532 *** Standard: 4 Rep: 1 Seq: 4 10:21:25 07 Apr 05 HG Hg 2.00 ug/L 5288 *** Standard: 5 Rep: 1 Seq: 5 10:23:04 07 Apr 05 HG Hg 5.00 ug/L 13201 *** Standard: 6 Rep: 1 Seq: 6 10:24:57 07 Apr 05 HG Hg 10.0 ug/L 26236 *** Sample ID: ICV Seq: 7 10:27:37 07 Apr 05 HG Hg 6.02 ug/L .000 6.02 *** Sample ID: ICB Seq: 8 10:29:42 07 Apr 05 HG • -.013 Hg -.013 ug/L .000 *** Sample ID: CCV1 Seq: 9 10:31:22 07 Apr 05 HG Hg 5.08 ug/L .000 5.08 *** Sample ID: CCB1 Seq: 10 10:33:12 07 Apr 05 HG Hg -.020 ug/L .000 -.020 *** Sample ID: CRA Seq: 11 10:34:59 07 Apr 05 HG Hg .177 ug/L .000 .177 *** Sample ID: MB-13152 Seq: 12 10:37:16 07 Apr 05 HG TSL001 Hg -.002 ug/L .000 -.002 *** Sample ID: 04067001G Seq: 13 10:39:15 07 Apr 05 HG N Hg -.013 ug/L .000 -.013 ^� o 0 H • 0 • Folder: HG040705 Page 2 Protocol: MERCURY ***POST -RUN REPORT*** Line Conc. Units SD/RSD 1 2 3 4 5 -------------------------------------------------------------------------------- *** Sample ID: 04067002G Seq: 14 10:40:52 07 Apr 05 HG Hg .006 ug/L .000 .006 c� S - *** Sample ID: CCV2 Seq: *** Sample ID: 04067002GD Se 15 10:43:41 07 Apr 05 HG Hg -.002 ug/L .000 - 002 *** Sample ID: CCB2 Seq: 22 10:57:03 07 Apr 05 *** Sample ID: 04067002GS Sec: 16 10:45:24 07 Apr 05 HG Hg 1.02 ug/L .000 .02 Sample ID: 04024005G Seq: 23 10:59:30 07 Apr 05 FSS Hg .017 ug/L = *** Sample ID: 04024001G Seq: 17 10:47:33 07 Apr 05 HG Hg .009 ug/L .000 *** Sample ID: 04024002G Hg .043 ug/L .000 *** Sample ID: 04024003G 09 Seq: 18 10:49:42 07 Apr 05 HG 43 35 = Seq: 19 10:51:33 07 Apr 05 HG Hg .019 ug/L .000 9 5D = *** Sample ID: 04024004E Seq: 20 10:53:33 07 Apr 05 HG Hg .121 ug/L .000 .1 c� S - *** Sample ID: CCV2 Seq: 21 10:55:12 07 Apr 05 HG Hg 5.22 ug/L .000 5.22 *** Sample ID: CCB2 Seq: 22 10:57:03 07 Apr 05 HG Hg -.005 ug/L .000 -.005 *** Sample ID: 04024005G Seq: 23 10:59:30 07 Apr 05 HG Hg .017 ug/L .000 .017 KW-_L0 ----- *** Sample ID: 04024006G Se 24 11:01:39 07 Apr 05 HG Hg .002 ug/L .000 .002 *** Sample ID: 04024007G Se : 25 11:03:11 07 Apr 05 HG Hg -.010 ug/L .000 -.010 Folder: HG040705 Page 3 Protocol: MERCURY ***POST -RUN REPORT*** Line Conc. Units SD/RSD 1 2 3 4 5 -------------------------------------------------------------------------------- 1-4 M O Cn E__4 *** Sample ID: 04024008G Seq: 26 11:05:46 07 Apr 05 HG Hg .028 ug/L .000 .028 K W == 9S *** Sample ID: 04024009G Seq: 27 11:07:24 07 Apr 05 HG Hg .012 ug/L .000 .012 v____________________________ *** Sample ID: MB -13151 Seq: 28 11:10:14 07 Apr 05 HG Hg .009 ug/L .000 .009 *** Sample ID: 04042002A Seq: 29 11:11:51 07 Apr 05 HG Hg .064 ug/L .000 .064 2Z.22:Z 7— - *** Sample ID: 03775002A Seq: 3 11:13:59 07 Apr 05 HG Hg .044 ug/L .000 .044 *** Sample ID: 03775002AD Seq: 3 11:15:49 07 Apr 05 HG Hg .053 ug/L .000 .053 • *** Sample ID: 03775002AS Seq: 3 11.17:58 07 Apr 05 HG Hg .980 ug/L .000 .980 *** Sample ID: CCV3 Seq: 33 11:19:46 07 Apr 05 HG Hg 5.16 ug/L .000 5.16 *** Sample ID: CCB3 Seq: 34 11:22:28 07 Apr 05 HG Hg .050 ug/L .000 .050 *** Sample ID: MB -13153 Seq: 35 11:24:06 07 Apr 05 HG CRA4 98, DEX001 Hg -.006 ug/L .000 -.006 *** Sample ID: LCS-13153 Seq: 36 11:25:57 07 Apr 05 HG lox Lot#D039-540 Hg 2.19 ug/L .000 2.19 *** Sample ID: 04110001A Seq: 37 11:27:34 07 Apr 05 HG Hg 3.36 ug/L .000 3.36 ZZ'ZZ'LZ - 1-4 M O Cn E__4 Folder: HG040705 Page 4 Protocol: MERCURY ***POST -RUN REPORT*** Line Conc. Units SD/RSD 1 2 3 4 5 -------------------------------------------------------------------------------- N M O V1 E-� *** Sample ID: 04110001AD Seq: 38 11:29:32 07 Apr 05 HG . Hg 2.62 ug/L .000 2.62 Z-LZ'Z"2-Z - *** Sample ID: 04110001AS Seq: 39 11:32:20 07 Apr 05 HG Hg 4.21 ug/L .000 4.21 *** Sample ID: 04040001B Seq: 40 11:34:03 07 Apr 05 HG Hg .464 ug/L .000 .464 ==___________ *** Sample ID: 09090001BD Seq: 41 11:36:00 07 A 05 HG Hg .646 ug/L .000 .646 *** Sample ID: 04040001BS Seq: 42 11:38:50 07 Ap 05 HG Hg 1.46 ug/L .000 1.46 b0-1--====_____ *** Sample ID: 04040002B Seq: 43 11:40:26 07 Apr 05 HG Hg .460 ug/L .000 .460 doZ - • *** Sample ID: 04040003B Seq: ------- 44 ------------------------------ 11:42:43 07 Apr 05 HG Hg 1.25 ug/L .000 1.25 0o3 *** Sample ID: CCV4 Seq: 45 11:44:36 07 Apr 05 HG Hg 5.22 ug/L .000 5.22 *** Sample ID: CCB4 Seq: 46 11:46:15 07 Apr 05 HG Hg -.035 ug/L .000 -.035 *** Sample ID: 04065001B Seq: 47 11:48:04 07 Apr 05 HG Hg 1.49 ug/L .000 1.49 D - k- _ *** Sample ID: 04065001BD Seq: 48 11: 0:14 07 Apr 05 HG Hg 4.30 ug/L .000 4.30 ------------ *** Sample ID: 04065001BS Seq: 49 11:5 :54 07 Apr 05 HG Hg 3.46 ug/L .000 3.46 N M O V1 E-� Folder: HG040705 Page 5 Protocol: MERCURY ***POST -RUN REPORT*** Line Conc. Units SD/RSD 1 2 3 4 5 -------------------------------------------------------------------------------- *** Sample ID: 04065002B Seq: 50 11:54:04 07 Apr 05 HG Hg .451 ug/L .000 .451 -------------- *** Sample ID: 04065003B Seq: 51 11:55:53 07 Apr 05 HG Hg .518 ug/L .000 .518 *** Sample ID: 04065004B Seq: 52 11:57 36 07 Apr 05 HG Hg 1.74 ug/L .000 1.74 *** Sample ID: MB -13162 Seq: 53 11:59:19 07 Apr 05 HG CRA4 99, DEX002 Hg .000 ug/L .000 .000 Q, *** Sample ID: MBl-13162 Seq: 54 12:01:19 07 Apr 05 HG MBLKTCLP CRA499 Hg -.005 ug/L .000 -.005 *** Sample ID: MB2-13162 Seq: 55 12:03:16 07 Apr 05 HG MBLKTCLP DEX002 Hg .002 ug/L .000 .002 • *** Sample ID: 04066001A Seq: 56 12:05:44 07 Apr 05 HG Hg .001 ug/L .000 .001 *** Sample ID: CCV5 Seq: 57 12:08:15 07 Apr 05 HG Hg 5.19 ug/L .000 5.19 -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- *** Sample ID: CCB5 Seq: 58 12:10:08 07 Apr 05 HG Hg -.002 ug/L .000 -.002 *** Sample ID: 04066002A Seq: 59 12:11:55 07 Apr 05 HG Hg .007 ug/L .000 .007 *** Sample ID: 04066003A Seq: 60 12:13:36 07 Apr 05 HG Hg .011 ug/L .000 .011 *** Sample ID: 04066004A Seq: 61 12:15:56 07 Apr 05 HG Hg .018 ug/L .000 .018 ca -S L�(�•�i - �'1 = Folder: HG040705 Page 6 Protocol: MERCURY ***POST -RUN REPORT*** Line Conc. Units SD/RSD 1 2 3 4 5 -------------------------------------------------------------------------------- • *** Sample ID: 04069001A Seq: 62 12:17:49 07 Apr 05 HG Hg .178 ug/L .000 .178 *** Sample ID: 04069001AD Seq: 63 12:19:27 7 Apr 05 HG Hg .157 ug/L .000 .157 ---------------------------------------------- ----��---------- *** Sample ID: 04069001AS Seq: 64 12:21:19 0 Apr 05 HG Hg 1.20 ug/L .000 1.20 *** Sample ID: 04069002A Seq: 65 12:23:00 07 Apr 05 HG Hg .198 ug/L .000 .198 *** Sample ID: 04069003A Seq: 66 .12:24:43 07 Apr 05 HG Hg .043 ug/L .000 .043 ----------------------------------------------- ----------------------------------------------- -------------------------------- -------------------------------- �3 *** Sample ID: 04069004A Seq: 67 12:26:26 07 Apr 05 HG Hg .126 ug/L .000 .126 ----------------------------------------------- -------------------------------- • *** Sample ID: 04069005A Seq: 68 12:28:14 07 Apr 05 HG Hg .124 ug/L .000 .124 -------------------------------------------------------------------------------- -------------------------------------------------------------------------------- *** Sample ID: CCV6 Seq: 69 12:30:03 07 Apr 05 HG Hg 4.99 ug/L .000 4.99 *** Sample ID: CCB6 Seq: 70 12:31:40 07 Apr 05 HG Hg -.027 ug/L .000 -.027 • =ile Utlity Help RPl RNg . 'rotocol MERCURY • Dataset/Proto HG O 4 0 7 0 S /MERCURY Pr I Line inf6 Cal Curve, Report Ctrl:Chartl Viewer1. R e — ___ ___—, A µAbs. Calib Coeffs I B 3 80368e-4 26236 New Cal G f5.33298e 3 Calbrated Accepted Rho 999982 rv, Accepted New Update Coeffs Type: ® � Accept Spike Coeffs - 5 -- I"de ' Rep 1 f✓ 12 r— 31- 4i _---._ .$� 07-Apr-0510-25 Cone: 10.0 S Conc. Calc. Dev. Mean SD or /RSD - Rep 1 Rep2I Rep 3 01 .00000 .003 .003 23 0 22 02 .20000 .215 .015 578 0% 578 03 1.0000 .959 -.041 2533 Oi 2532 04 2.0000 2.01 .009 5289 Oi 5288 05 5.0000 5.02 .024 13201 07/. 13201 na in nnn 9 99 - rn n A23F; n 297 g ady 16AP • 't/ '/DS TSL001 M136 i� lien •---- • M3 - • : -•NOTES CALCULATIONS OWN -- • r1 r i M _mm TSL001 M136 2M «►Us, INC. CYANIDE DISTILLATION LOG DATE: y - .7 - el - ANALYST: _LZkr ►sce "4210 L '`' 1 1 1- 1- 1 1 1 * Amount of ascorbic acid used ** Amount of Cd CO3 used ARDS PREPARED FOR THIS RUN: 'ONC. I.D. VOOTO VOLUME KI TEST Pb ACETATE LAB. 1 SSEL LAB. CLIENT SAMPLE PAPER +�- TEST PAPER NO. -.I. D. I.D. SAMPLE PH * + - ** CO S L '`' 1 1 1- 1- 1 1 1 * Amount of ascorbic acid used ** Amount of Cd CO3 used ARDS PREPARED FOR THIS RUN: 'ONC. I.D. OUANTITY VOLUME KI TEST Pb ACETATE SSEL LAB. 1 CLIENT I OF ISAMPLEI SAMPLE PAPER +/- TEST PAPER I+/- NO. 1. D. I.D. PN * (**)ICOMMENTS L '`' 1 1 1- 1- 1 1 1 * Amount of ascorbic acid used ** Amount of Cd CO3 used ARDS PREPARED FOR THIS RUN: 'ONC. I.D. OUANTITY DISTILLED: YES NO LOT # AND SOURCE c%ZJ V , • ��.rG }� 0038 t C I . C C r li r r r I t U2M "US, INC. • IV. DOCUMENTATION FOR METALS A. DIGESTION LOG SHEETS B. REPORTING ANALYST SIGNATURE PAGE • F -j 00 M O E-� _J T112M Labs, Inc. CLP ient: L Coll �llatrix: LT 4J Method: 'SC -10 tion ianature: Date:-nAN%Mb Time Started/Ended: Description �mments: ' 'fir Ih�" lb O.JOUBOOKSJCLPDigestionlog 'Description of colors: red, blue, yellow, green, orange, violet, white, colorless, brown, grey, black. •Description of texture: fine, medium, coarse. 'Description of clarity: clear, cloudy, opaque. 'Description of artifacts: no loin SMOM ININN ME WME INE IN WIN WEEINEENESCIE &WN �mments: ' 'fir Ih�" lb O.JOUBOOKSJCLPDigestionlog 'Description of colors: red, blue, yellow, green, orange, violet, white, colorless, brown, grey, black. •Description of texture: fine, medium, coarse. 'Description of clarity: clear, cloudy, opaque. 'Description of artifacts: Yes or no and describe 1 1 1 1 l i 1 1 1 1 1 1 112M 1_A US, INC. 5";1 0.5 goo- io co Lily D,5 9ctz:P--i'00 u i 'h -,U- rA..— ,M rl 0 sLOO 1 C"` -QC6 Dtx(20 I HG DIGESTIONS NAME: DATE: iA LAB NO. CLIENT ID SAMPLE WEIGHT GRAMS SAMPLE VOLUME MLS FINAL VOLUME MLS DILUTION FACTOR SPIKE 0-G00J- 10© toz> l�3 Com! T✓= S Lu 00 t o0 Cc.a C P.if 6 - j>iJ i �6W S ZZ2 ZZ Z- 0-01104.11- 0- C - lel OOZE c3 cnsr, SID c) 5 to wifla S Cox �S €l1iJl i K J Olo7- - i �w ap 00 p rif1Z d d' 0 UO . l V2M LABS, INC. i l —c NAM: DATE: =+ 05 HG DIGESTIONS ) LAB NO. CLIENT ID SAMPLE WEIGHT GRAMS SAMPLE VOLUME MIS FINAL VOLUME MLS DILUTION FACTOR SPIKE 110�'Gp1A 222222 S - 374 b i-CL005r Qel Oce MS � G 'L Z KCIT p;lv�o� CUP i f7 iiaF• .ii. Vc- 4 --V� Cck 0 00 L /00 'Ac lar o. o 1. ov 10 aZ o o 040 I ;. D [—to - C) 0 v 1 -00 ± I w [--- 4 1 1 P nols U2M LABS, INC. o'�-" �a 7YS-115 HG DIGESTIONS NAME: // DATE:— L1,17,10-3, 1/1 LAB NO. CLIENT ID SAMPLE WEIGHT GRAMS SAMPLE VOLUME MLS FINAL VOLUME MLS DILUTION FACTOR SPIRE :, C.1 vv /010 -1 as Ctv N= 5.0, We, L C� i fi"lb -1 i 2 uc P - �CoN U+�v�:ov N� c c-"4 te- tot -A.- Is J 0604 V,4i 'ODO S - 3`1C�'iy-t7-ioYoj_ i- la�A 00 0 003. 1 P WAG i - sAt,E m (4(A'IRQC: i�4' cin, . -►� f Cweoo tris t (KJ[4 — C r JrDF W103m: c s f�s...a.lc rAw Oil. - sa s•� c.��.6.. ciri - C..aeatratia (�c� Rt) (mC/k�i =v r of - - fl',rS �(• = Fiut s�wpk wi.a�ci [mss �U _ " • _ - �- a Qjt/dOR FaC-iOf ' i Li = -y zt\v ���.t �iC'��2�c �� svf i - cl s -- ( �« it ism«) tc t� _ - __- MATRM- L lC�T m BY= l v -/ i V`�I/r i � �F C combtrim !�C t V WISE: c tm*wmd VI&W ifwL _ V iir�ca0oa.daR.c(R(? DIF = Maim Factor s a SeaV4ccdaat.G.. CKV c..ocstca6i a OCT WO of Wks • w:taRE: c ck�(Wgou v s wpfc.". R c is Gioors (L� x - ivd smtk - s Y. 5~ 00 - ,�• of - O&o4;* . Fa~ (C) ,• U2M "US, INC. SDG NO.: SCAN: /rf c 1 This data package was reported by the undersigned. This reporting includes data calculations, manual edits if necessary and compilation of raw data. The information presented is true and correct to the best of • my knowledge. c c Signature: c � �-- Date: Yr « /c : - Reviewed By Signature: Date: r •