HomeMy WebLinkAbout2014 3rd Qtr
DRAFT
THIRD QUARTER 2014
GROUND WATER-MONITORING REPORT
FOR THE
TOWN OF SOUTHOLD LANDFILL
6155 COX LANE
CUTCHOGUE, NY 11944
Prepared for:
Southold Town Solid Waste Management District
6155 Cox Lane
Cutchogue, NY 11944
Prepared by:
Lockwood, Kessler & Bartlett, Inc.
1 Aerial Way
Syosset, NY 11791
Submitted to:
New York State Department of Environmental Conservation
Region 1 Headquarters
SUNY at Stony Brook
50 Circle Road
Stony Brook, NY 11790
October 30, 2014
Third Quarter 2014 Ground Water-Monitoring Report
Town of Southold Landfill, Cutchoque, NY
TABLE OF CONTENTS
Section Number and Title Page Number
1.0 INTRODUCTION 1
2.0 METHODS AND PROCEDURES 1
3.0 DISCUSSION OF RESULTS 2
3.1 Water-Level Results 2
3.2 Field Parameter Results 2
3.3 Leachate Indicator Results 4
3.4 Inorganic Parameter Results 5
4.0 CONCLUSIONS AND RECOMMENDATIONS 7
Figure Number and Title Follows Page Number
1. Site Location Map 1
2. Well Location Map 1
Table Number and Title Follows Page Number
1. Summary of Part 360 Routine Parameter Results for 2
Third Quarter 2014 Monitoring Round
Appendices
A. Sample Results
Lockwood, Kessler & Bartlett, Inc.
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Third Quarter 2014 Ground Water-Monitoring Report
Town of Southold Landfill, Cutchogue, NY
1.0 INTRODUCTION
The Town of Southold has retained Lockwood, Kessler & Bartlett, Inc. (LKB) to perform
post-closure ground-water monitoring and reporting for its closed and capped MSW
landfill in Cutchogue, NY (Site). The location of the Site is shown in Figure 1.
th
This report is for the third quarter 2014 monitoring round, conducted on September 17,
and describes the work performed and the results obtained. Section 2.0 (Methods and
Procedures) details the project requirements and the specific work performed. Section
3.0 (Discussion of Results) summarizes the key findings from this monitoring round,
including comparison of the laboratory results to standards and guidance values.
Section 4.0 (Conclusions and Recommendations) provides conclusions based on this
quarters results, and recommendations for upcoming quarters. Each report section is
supported by figures and/or tables, as appropriate, which follow the page on which they
are first referenced. The laboratory results for this monitoring round are provided in
Appendix A.
2.0 METHODS AND PROCEDURES
Water-level measurements and ground-water samples were collected from each of the
Sites 12 monitoring wells, as listed below. A site plan showing the locations of the wells
is provided in Figure 2.
MW-1S MW-5S
MW-1D MW-5D
MW-3S MW-6S
MW-3D MW-6D
MW-4S MW-8S
MW-4D MW-8D
Prior to sampling, the water-level in each well was measured to the nearest 0.01-feet
from the top of the well casing utilizing a decontaminated water-level meter. Ground-
water samples were collected utilizing a Grundfos RediFlo2 variable-speed electric
submersible pump connected to 160 feet of ¾-inch diameter polyethylene hose on a
Keck Reel. Utilizing the well construction records, the pump was placed at the mid-point
of each wells screen. Each well was then purged at a low flow rate until its turbidity was
less than 5 Nephelometric Turbidity Units (NTUs) and field parameter readings were
stabile.
The ground-water samples were collected directly from the pump discharge hose into
new laboratory-supplied bottles of the type required for each specific analysis. A blind
duplicate was collected from Well MW-4S and labeled MW-7S. Matrix spike and matrix
spike duplicate samples were collected from Well MW-8S. Field notes were recorded in
a bound field notebook.
Lockwood, Kessler & Bartlett, Inc.
1
N
SITE
FIGURE 1
SITE LOCATION MAP
TOWN OF SOUTHOLD LANDFILL, CUTCHOGUE, NY
WELL LOCATION PLAN
FIGURE 2
ANDFILL, CUTCHOGUE, NY
TOWN OF SOUTHOLD L
: Base map provided by Town of Southold
Note
Third Quarter 2014 Ground Water-Monitoring Report
Town of Southold Landfill, Cutchogue, NY
Each sample was labeled with the well number, time and date, etc., placed in a cooler
o
with ice to keep it at 4C, and delivered to the laboratory the following day. The samples
were analyzed for the 6NYCRR Part 360 Routine Parameters. The field parameters
were monitored by LKB. Laboratory analyses were performed by Spectrum Analytical,
Inc. in North Kingston, RI. This laboratory is certified by the New York State Department
of Healths Environmental Laboratory Approval Program in all required analytical
categories, and employs the required internal QA/QC procedures, including analysis of
matrix spikes, matrix spike duplicates, method blanks and continuing calibration
samples. They also participate in the required biennial proficiency testing. The field data
and laboratory results were reviewed by LKB per QA/QC Plan requirements and
determined to be useable.
3.0 DISCUSSION OF RESULTS
The field and laboratory results for the third quarter 2014 ground water-monitoring round
are summarized and compared to the New York State Department of Environmental
Conservation Ambient Water Quality Standards and Guidance Values for Class GA
(Potable) ground water, as applicable, in Table 1. A review of the results for the water-
level measurements and each analytical parameter group is provided below.
3.1 Water-Level Results
As shown in Table 1, water-table elevations in the shallow (S) wells at the Site ranged
from 5.74 feet above mean sea level (MSL) in Well MW-1S, located on the south end of
the Site, to 3.78 feet above MSL in Well MW-8S, located on the west side of the Site.
These water-table elevations are consistent with ground-water flow information
published by the United States Geological Survey in Scientific Investigations Map 3066,
Water Table Sheet 1 of 4, which indicates a relatively low horizontal hydraulic gradient
and a northerly horizontal ground water-flow direction. Based on these elevations, Well
Cluster MW-1 is located upgradient of the Site, and the other wells are located along the
downgradient boundary of the Site. Potentiometric surface elevations in the deep (D)
wells at the Site are consistent with the shallow well results, except for the higher water-
level in Well MW-8D, and indicate flat or downward vertical hydraulic gradients.
3.2 Field Parameter Results
Review of the field parameter results in Table 1 indicates the following key findings:
Ground-water conductivity values are higher relative to the main area of Long
Island, which may be at least partly due to the Sites North Fork location, where
naturally higher ground-water salinities may occur due to the proximity to saline
surface-water bodies. Conductivity values are highest in the deep wells located
directly downgradient of the Site (e.g., Wells MW-3D, MW-4D and MW-5D).
Lockwood, Kessler & Bartlett, Inc.
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No OdorNo OdorNo OdorNo OdorNo OdorNo OdorNo OdorNo OdorNo OdorNo OdorNo OdorNo Odor
0.041 J1.010.023 J0.099 J0.320 J0.460 J
MW-8DCalciumug/LNo Standard6,40024,00060,00070,00059,000160,0008,80075,00014,00031,00061,00050,000 48,00010,000 6,00032,0004,50018,00021,00026,000Potassiumug/LNo Standard3,4001,40027,000110,00026,000
36,0003,600110,0004,1002,60047,00044,000 23,00055,000
Field ObservationsN/ANo StandardClear,Clear,Clear,Clear,Clear,Clear,Clear,Clear,Clear,Clear,Clear,Clear,
N/A44.8344.8849.5049.1963.0362.9268.1467.6455.7755.7154.1655.29N/A39.0939.0144.5444.2658.4758.3863.5663.1250.7850.8050.3849.20 ConductivitymS/cmNo Standard0.2020.3020.8601.4200.6002.2500.1922.0600.16
00.4290.9801.000 9,6001,8007007501,500
Floaters or SinkersN/ANoneNoneNoneNoneNoneNoneNoneNoneNoneNoneNoneNoneNone
ORPmVNo Standard5215.8-28.3-53.47.2-27.066.114.487.262.3-54.1-33.3
Total Organic Carbonmg/LNo Standard<10<107.2 J186.6 J20<102813<10169.3 J
17.517.7
N/A5.745.874.964.934.564.544.584.524.994.913.786.09 TemperatureoCNo Standard14.113.616.216.216.616.014.914.913.513.616.115.86.54 Dissolved Oxygenmg/LNo Standard8.281.950.270.580.560.384.190.480.752.0
50.490.39 TurbidityNTU<50.760.963.070.640.484.740.913.154.862.580.483.0225.117711.139.941.183.4Sulfatemg/L25014.669.536.341.832.277.917.932.98.4486.835.980.3TKNmg/LNo Standard0.210.2113.759.90.4919.9
0.2177.818.00.7719.34.83
Alkalinity mg/LNo Standard<20332705001607803277049<20380240 507
Hardnessmg/LNo Standard371102203002106604632054150240230
<0.102.06<0.100.8177.53<1.0<1.0
EhpHmVNo Standard94.023.422.320.630.0-8.284.21.957.260.59.01.4BODmg/LNo Standard<3.0<3.07.0<3.0<3.0<3.0<3.0<3.0<3.0<3.0<3.0<3.0Cadmiumug/L5<5.0<5.0<5.0<5.0<5.0<5.0<5.0<5.0<5.0<5.0<5.0<5.0
CODmg/LNo Standard<2014 J39552361<20753313 J4631Leadug/L25<10<10<10<10<10<10<10<10<10<10<10<10
<8<8<8
MSL= Mean Sea Level.TKN= Total Kjeldahl Nitrogen.mg/L= milligrams per Liter. exceed Class GA Standard or Guidance Value.
MW-4DMW-8S
5.535.476.41 T.O.C.= Top of Casing.COD= Chemical Oxygen Demand.mV= milliVolts.Results in bold font and highlighted in yellow
131195374
MW-5SMW-5DMW-6SMW-6D6,80015,000
0.210.14 J
120 J210
9
Summary of Part 360 Routine Parameter Results for Third Quarter 2014 Monitoring Round
130,000
6.53 72.8
752510
Phenolsug/L1<8<8<8<8<8<8<8<8
Well Number and Result
14,000
130 J
5.05 0.2147 J
107
= Degrees Celsius.ug/L= micrograms per Liter.
Town of Southold Landfill, Cutchogue, NY
200,000
62,000
BOD= Biological Oxygen Demand.NTU= Nephelometric Turbidity Units.GV = Guidance Value.
1,2203,9009,2003,7002,500
ORP= Oxygen Reduction Potential.pHmV= pH in milliVolts.N/A= Not Applicable.
6.71 15.92.05
297730
0.049 J0.071 J0.320 J0.530 J0.029 J
5,10012,00016,00030,00016,000
MW-1SMW-1DMW-3SMW-3DMW-4S
9,200
4.876.136.166.206.03 0.28 17.0
Chloridemg/L25043.325.061.714813.3
Total Dissolved Solidsmg/L500128239313488400Ironug/L300<200270<200110 J<200
Table 1
130,000
12.957.4
Nitratemg/L101.584.610.380 J<1.0
Sodiumug/L20,00018,00019,0009,500
Ammoniamg/L20.210.14 J
Manganeseug/L30012 J<50
C
o
mS/cm= milliSiemens per centimeter.
NYSDEC Part 360Class GA
Routine ParametersStandard
GV
pHUnits6.5-8.5
35000
GV
2
Feet MSLFeet MSL
Feet
Units
Bromidemg/L
Magnesiumug/L
:
Notes
Inorganic Parameters:
Water-Level Elevation
Leachate Indicators:
:
Field Parameters:
Water-Level Data
T.O.C. Elevation
Depth to Water
Third Quarter 2014 Ground Water-Monitoring Report
Town of Southold Landfill, Cutchogue, NY
These highest values appear to be Site-related. There is no Class GA standard
or guidance value for conductivity.
Ground-water temperatures are approximately 1 to 2 degrees Celsius higher in
eight of the 10 downgradient wells relative to the upgradient wells. The highest
temperatures occurred in Well Clusters MW-3, MW-4 and Well MW-8. There is
no Class GA standard or guidance value for temperature.
No floaters or sinkers were noted during this monitoring round.
Ground-water pH is acidic, and is lower than the minimum Class GA standard of
6.5 Standard Units in both upgradient wells and seven of the 10 downgradient
wells. The results are consistent with the naturally low pH of Long Island ground
water. Ground-water pH is higher in the deep well at five of Sites well clusters.
Eh is noticeably lower in Downgradient Wells MW-4D and MW-5D, and Well
Cluster MW-8, relative to the upgradient wells. There is no Class GA standard or
guidance value for Eh.
Dissolved oxygen (DO) concentrations are lower in every downgradient well
except Wells MW-5S and MW-6D, relative to the upgradient wells, but dissolved
oxygen is present in all 12 Site monitoring wells. There is no Class GA standard
or guidance value for DO.
The ground water in all 12 Site monitoring wells was observed to be clear, and
did not have noticeable odor.
The turbidity of ground water is low, was less than the 5-NTU (Nephelometric
Turbidity Units) Class GA standard in all 12 Site monitoring wells this quarter.
Therefore, the collection of filtered samples for dissolved metals analyses was
not required.
The ORP (oxidation-reduction potential) of ground water is positive in both
upgradient wells, Well MW-4S, and Well Clusters MW-5 and MW-6; and negative
in Well Clusters MW-3 and MW-8, and Well MW-4D this quarter. The highest
ORP readings occurred in Wells MW-5S and MW-6S. The lowest (most negative)
ORP readings occurred in Well Clusters MW-3 and MW-8, and Well MW-4D.
There is no Class GA standard or guidance value for ORP.
Overall, the field parameter results obtained this quarter are consistent with the Sites
usage and its North Fork setting. Potential Site-related impacts are relatively minor in
magnitude and limited to higher conductivity, and lower Eh, dissolved oxygen levels and
ORP in certain downgradient wells.
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Third Quarter 2014 Ground Water-Monitoring Report
Town of Southold Landfill, Cutchogue, NY
3.3 Leachate Parameter Results
Review of the leachate parameter results in Table 1 indicates the following key findings:
Ground-water alkalinity is significantly higher in seven of the 10 downgradient
wells relative to the upgradient wells. The highest alkalinity concentrations were
detected in Wells MW-3D, MW-4D and MW-5D. There is no Class GA ground-
water standard or guidance value for alkalinity.
Ammonia was detected in all 12 Site monitoring wells. Ammonia concentrations
are low in both upgradient wells and four of the 10 downgradient wells. Ammonia
concentrations in the other six downgradient wells exceed the 2-mg/L Class GA
ground-water standard. The highest concentrations occurred in Wells MW-3D
and MW-5D.
BOD (biological oxygen demand) was only detected in one well (Well MW-3S), at
a low concentration this quarter. There is no Class GA ground-water standard or
guidance value for BOD.
Bromide was detected in all 12 Site monitoring wells, primarily at low, estimated
concentrations. Bromide concentrations in Well Clusters MW-3 and MW-8, and
Wells MW-4D and MW-5D, are higher relative to the upgradient wells. The
highest bromide concentration occurred in Well MW-4D, and is slightly higher
than the 2-mg/L Class GA ground-water guidance value.
Chloride levels are noticeably higher in four of the 10 downgradient wells (Wells
MW-3D, MW-4D, MW-5D and MW-8D) relative to the upgradient wells, but with
the exception of Well MW-4D are lower higher than the 250-mg/L Class GA
ground-water standard. The fact that the highest chloride concentrations occur in
deep wells suggests that they may be due in part to naturally saline ground-water
conditions.
COD (chemical oxygen demand) was detected in one upgradient well and nine of
the 10 downgradient wells. COD concentrations were generally higher in the
downgradient wells. The highest COD concentrations were detected in Wells
MW-3D, MW-4D and MW-5D. There is no Class GA ground-water standard or
guidance value for COD.
Ground-water hardness values are higher in nine of the 10 downgradient wells
relative to the upgradient wells. The highest hardness values occurred in Wells
MW-3D, MW-4D and MW-5D. There is no Class GA ground-water standard for
guidance value or hardness.
Nitrate is present in both upgradient wells and five of the 10 downgradient wells
this quarter. Concentrations are lower than the 10-ug/L Class GA ground-water
standard in every well except Well MW-4S.
Phenols were only detected in one Site monitoring well (Well MW-6S) this
quarter. The phenol concentration in Well MW-6S is higher than the 1-ug/L Class
GA ground-water standard.
Lockwood, Kessler & Bartlett, Inc.
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Third Quarter 2014 Ground Water-Monitoring Report
Town of Southold Landfill, Cutchogue, NY
Sulfate is present in all 12 Site monitoring wells, at relatively similar
concentrations in the upgradient and downgradient wells. All concentrations are
lower than the 250-ug/L Class GA ground-water standard. Sulfate concentrations
are higher in the deep well at each well cluster, which suggests that they may be
partly associated with saline ground-water conditions.
TDS (total dissolved solids) results are noticeably higher in seven of the 10
downgradient wells relative to the upgradient wells, and exceed the 500-mg/L
Federal MCL in Wells MW-4D, MW-5D and MW-8D. The highest TDS
concentration at each well cluster occurs in the deep well, which suggests that
they may be partly associated with naturally saline ground-water conditions.
TKN (total Kjeldahl nitrogen) is present in all 12 Site wells this quarter. TKN
concentrations in seven of the 10 downgradient wells are significantly higher
relative to the upgradient wells. The highest TKN concentrations occurred in
Wells MW-3D and MW-5D. There is no Class GA ground-water standard or
guidance value for TKN.
TOC (total organic carbon) was not detected in the upgradient wells, but is
present in eight of the 10 downgradient wells. The highest concentrations
occurred in Wells MW-3D, MW-4D and MW-5D. There is no Class GA ground-
water standard or guidance value for TOC.
Overall, the leachate parameter results obtained this quarter are also consistent with the
Sites usage and its North Fork setting. Potential Site-related impacts indicated by these
results include downgradient increases in most of the detected parameters, primarily in
the deep wells. However, it is important to note that 1) the there are no Class GA
ground-water standards or guidance values for six of the parameters; and 2) the
downgradient increases occur in a limited number of wells.
Moreover, ground water beneath the Site is naturally saline at depth, and ultimately
discharges to a saline surface-water body (Long Island Sound). Therefore, the
exceedances for ammonia, bromide, chloride, nitrate and TDS, which occur naturally in
saline ground water and seawater, are not a significant concern with respect to public
health or the environment.
3.4 Inorganic Parameter Results
Review of the inorganic parameter results in Table 1 indicates the following key
findings:
Cadmium was not detected in any of the 12 Site monitoring wells this quarter.
Calcium was detected in all 12 Site monitoring wells this quarter. Calcium
concentrations are noticeable higher in eight of the 10 downgradient wells
relative to the upgradient wells. The highest calcium concentrations were
detected in Wells MW-4D and MW-5D. There is no Class GA ground-water
standard or guidance value for calcium.
Lockwood, Kessler & Bartlett, Inc.
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Third Quarter 2014 Ground Water-Monitoring Report
Town of Southold Landfill, Cutchogue, NY
Iron was detected in one upgradient well and eight of the 10 downgradient wells
this quarter. Most of these iron concentrations are relatively low. However, the
concentrations in Downgradient Wells MW-4D and MW-5D, and Well Cluster
MW-8, exceed the 300-ug/L Class GA ground-water standard. The highest iron
concentrations occurred in Well Cluster MW-8. The highest iron concentration
occurred in the shallow well at this cluster, which suggests that the iron at this
location is Site-related.
Lead was not detected in any of the Site monitoring wells this quarter.
Magnesium was detected in all 12 Site monitoring wells this quarter, and
concentrations in nine of the 10 downgradient wells are higher relative to the
upgradient wells. The magnesium concentration in Well MW-4D is higher than
the 35,000-ug/L Class GA guidance value. At each well cluster, magnesium
concentrations are higher in the deep well, which suggests that they may be
partly due to saline ground-water conditions.
Manganese was detected in one upgradient well at a low concentration, and in
nine of the 10 downgradient wells at higher concentrations that exceed the 300-
ug/L Class GA ground-water standard. The highest manganese concentrations
occurred in Wells MW-3D and MW-5D. The higher manganese concentrations in
the downgradient wells appear to be Site-related.
Potassium was detected in all 12 Site monitoring wells this quarter. Potassium
concentrations in seven of the 10 downgradient wells are noticeably higher
relative to the upgradient wells and appear to be Site-related. The highest
potassium concentration occurred in Wells MW-3D and MW-5D. There is no
Class GA ground-water standard or guidance value for potassium.
Sodium was also detected in all 12 Site monitoring wells. Sodium concentrations
in five downgradient wells (Wells MW-3D, MW-4D, MW-5D, MW-8S and MW-8D)
are noticeably higher relative to the upgradient wells, and exceed the 20,000-
ug/L Class GA ground-water standard. At each well cluster, the highest sodium
concentration occurs in the deep well, which suggests that the sodium results are
partly due to naturally saline ground-water conditions.
Overall, the inorganic parameter results obtained this quarter are also consistent with
the Sites usage and its North Fork setting. Potential Site-related impacts indicated by
these results include downgradient increases in calcium, iron, magnesium, manganese,
potassium and sodium. However, it is important to note that 1) many of these increases
are relatively minor in magnitude, sporadic, and/or do not exceed Class GA ground-
water standards or guidance values; 2) there are no Class GA ground-water standards
or guidance values for calcium or potassium; 3) the Class GA ground-water standards
for iron and manganese are aesthetics-based; 4) the limit for magnesium is based on a
guidance value rather than an actual standard; and 5) sodium is not considered to be
particularly hazardous. Moreover, since ground water on the North Fork is naturally
saline at depth and ultimately discharges to Long Island Sound, the exceedances for
magnesium and sodium, which occur naturally in saline ground water and seawater, are
not a concern with respect to public health or the environment.
Lockwood, Kessler & Bartlett, Inc.
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Third Quarter 2014 Ground Water-Monitoring Report
Town of Southold Landfill, Cutchogue, NY
4.0 CONCLUSIONS AND RECOMMENDATIONS
Based on the results of the third quarter 2014 monitoring round, LKB concludes the
following:
Water-level elevations, horizontal and vertical hydraulic gradients, and ground
water-flow directions are consistent with local/regional hydrogeologic conditions.
In general, ground water-quality conditions are consistent with the Sites North
Fork setting near saline surface-water bodies.
Comparison of upgradient and downgradient results indicates potential Site-
related impacts consistent with an old MSW landfill, however further assessment
indicates that the impacts are not a significant concern with respect to public
health or the environment.
The monitoring schedule for the Site requires monitoring ground water for 6NYCRR Part
360 routine parameters during three calendar quarters and for Part 360 baseline
parameters during one calendar quarter, in rotating quarters. A baseline monitoring
round was performed last quarter. Therefore, the next baseline monitoring round should
be performed during the third quarter of 2015. Until then, the quarterly monitoring
should be performed for Part 360 routine parameters. LKB recommends that this
monitoring schedule be followed.
Lockwood, Kessler & Bartlett, Inc.
7
APPENDIX A
Sample Results
Report Date:Final Report
31-Oct-14 11:07
Re-Issued Report
Revised Report
Laboratory Report
Lockwood Kessler & Bartlett Inc.Work Order:N1726
One Aerial WayProject :Southhold Landfill Routine Parameters
Syosset, NY 11791Project #:
Attn: John Gerlach
Laboratory IDLaboratory IDClient Sample IDClient Sample IDMatrixMatrixDate SampledDate SampledDate ReceivedDate Received
Laboratory IDLaboratory IDClient Sample IDClient Sample IDMMaattrriixxDate SampledDate SampledDate ReceivedDate Received
N1726-01MW-3DAqueous17-Sep-14 08:5018-Sep-14 13:51
N1726-01MW-3DAqueous17-Sep-14 08:5019-Sep-14 10:05
N1726-02MW-3SAqueous17-Sep-14 09:2018-Sep-14 13:51
N1726-02MW-3SAqueous17-Sep-14 09:2019-Sep-14 10:05
N1726-03MW-5SAqueous17-Sep-14 09:4018-Sep-14 13:51
N1726-03MW-5SAqueous17-Sep-14 09:4019-Sep-14 10:05
N1726-04MW-5DAqueous17-Sep-14 10:0018-Sep-14 13:51
N1726-04MW-5DAqueous17-Sep-14 10:0019-Sep-14 10:05
N1726-05MW-4SAqueous17-Sep-14 10:4018-Sep-14 13:51
N1726-05MW-4SAqueous17-Sep-14 10:4019-Sep-14 10:05
N1726-06MW-4DAqueous17-Sep-14 11:3018-Sep-14 13:51
N1726-06MW-4DAqueous17-Sep-14 11:3019-Sep-14 10:05
N1726-07MW-7SAqueous17-Sep-14 10:5018-Sep-14 13:51
N1726-07MW-7SAqueous17-Sep-14 10:5019-Sep-14 10:05
N1726-08MW-8SAqueous17-Sep-14 12:2018-Sep-14 13:51
N1726-08MW-8SAqueous17-Sep-14 12:2019-Sep-14 10:05
N1726-09MW-8DAqueous17-Sep-14 12:5018-Sep-14 13:51
N1726-09MW-8DAqueous17-Sep-14 12:5019-Sep-14 10:05
N1726-10MW-6SAqueous17-Sep-14 13:2018-Sep-14 13:51
N1726-10MW-6SAqueous17-Sep-14 13:2019-Sep-14 10:05
N1726-11MW-6DAqueous17-Sep-14 13:4018-Sep-14 13:51
N1726-11MW-6DAqueous17-Sep-14 13:4019-Sep-14 10:05
N1726-12MW-1SAqueous17-Sep-14 14:2018-Sep-14 13:51
N1726-12MW-1SAqueous17-Sep-14 14:2019-Sep-14 10:05
N1726-13MW-1DAqueous17-Sep-14 14:5018-Sep-14 13:51
N1726-13MW-1DAqueous17-Sep-14 14:5019-Sep-14 10:05
646 Camp Ave * North Kingstown * RI * 028524008 * 401-732-3400 * 401-732-3499
www.spectrum-analytical.comwww.spectrum-analytical.com
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Report Date:Final Report
31-Oct-14 11:07
Re-Issued Report
Revised Report
Laboratory Report
Lockwood Kessler & Bartlett Inc.Work Order:N1726
One Aerial WayProject :Southhold Landfill Routine Parameters
Syosset, NY 11791Project #:
Attn: John Gerlach
I attest that the information contained within the report has been reviewed for accuracy and checked against the quality control requirements for each method. The results
relate only to the samples(s) as received. This report may not be reproduced, except in full, without written approval from Spectrum Analytical.
All applicable NELAC or USEPA CLP requirments have been meet.
Spectrum Analytical (Rhode Island) is accredited under the National Environmental Laboratory Approval Program (NELAP) and DoD Environmental Laboratory
Accreditation Program (ELAP), holds Organic and Inorganic contracts under the USEPA CLP Program and is certified under several states. The current list of our
laboratory approvals and certifications is available on the Certifications page on our web site at www.spectrum-analytical.com.
Please contact the Laboratory or Technical Director at 401-732-3400 with any questions regarding the data contained in the laboratory report.
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N1726Page 5 of 117
N1726Page 6 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-3DSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0109/17/14 8:50
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SW846 6010C -- Metals by ICPSW6010_W
CadmiumND5.0ug/L109/22/2014 14:5979119
Calcium70000800ug/L109/22/2014 14:5979119
Iron110J200ug/L109/22/2014 14:5979119
LeadND10ug/L109/22/2014 14:5979119
Magnesium30000500ug/L109/22/2014 14:5979119
Manganese920050ug/L109/22/2014 14:5979119
Potassium110000B1000ug/L109/22/2014 14:5979119
Sodium1300001000ug/L109/22/2014 14:5979119
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 7 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-3SSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0209/17/14 9:20
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SW846 6010C -- Metals by ICPSW6010_W
CadmiumND5.0ug/L109/22/2014 15:0379119
Calcium60000800ug/L109/22/2014 15:0379119
IronND200ug/L109/22/2014 15:0379119
LeadND10ug/L109/22/2014 15:0379119
Magnesium16000500ug/L109/22/2014 15:0379119
Manganese390050ug/L109/22/2014 15:0379119
Potassium27000B1000ug/L109/22/2014 15:0379119
Sodium95001000ug/L109/22/2014 15:0379119
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 8 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-5SSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0309/17/14 9:40
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SW846 6010C -- Metals by ICPSW6010_W
CadmiumND5.0ug/L110/30/2014 9:2179751
Calcium8800800ug/L110/30/2014 9:2179751
Iron130J200ug/L110/30/2014 9:2179751
LeadND10ug/L110/30/2014 9:2179751
Magnesium6000500ug/L110/30/2014 9:2179751
Manganese47J50ug/L110/30/2014 9:2179751
Potassium36001000ug/L110/30/2014 9:2179751
Sodium140001000ug/L110/30/2014 9:2179751
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 9 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-5DSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0409/17/14 10:00
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SW846 6010C -- Metals by ICPSW6010_W
CadmiumND5.0ug/L110/30/2014 9:2579751
Calcium75000800ug/L110/30/2014 9:2579751
Iron510200ug/L110/30/2014 9:2579751
LeadND10ug/L110/30/2014 9:2579751
Magnesium32000500ug/L110/30/2014 9:2579751
Manganese960050ug/L110/30/2014 9:2579751
Potassium1100001000ug/L110/30/2014 9:2579751
Sodium1300001000ug/L110/30/2014 9:2579751
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 10 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-4SSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0509/17/14 10:40
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SW846 6010C -- Metals by ICPSW6010_W
CadmiumND5.0ug/L109/22/2014 15:2179119
Calcium59000800ug/L109/22/2014 15:2179119
IronND200ug/L109/22/2014 15:2179119
LeadND10ug/L109/22/2014 15:2179119
Magnesium16000500ug/L109/22/2014 15:2179119
Manganese370050ug/L109/22/2014 15:2179119
Potassium26000B1000ug/L109/22/2014 15:2179119
Sodium92001000ug/L109/22/2014 15:2179119
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 11 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-4DSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0609/17/14 11:30
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SW846 6010C -- Metals by ICPSW6010_W
CadmiumND5.0ug/L110/30/2014 9:2879751
Calcium160000800ug/L110/30/2014 9:2879751
Iron730200ug/L110/30/2014 9:2879751
LeadND10ug/L110/30/2014 9:2879751
Magnesium62000500ug/L110/30/2014 9:2879751
Manganese250050ug/L110/30/2014 9:2879751
Potassium360001000ug/L110/30/2014 9:2879751
Sodium2000001000ug/L110/30/2014 9:2879751
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 12 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-7SSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0709/17/14 10:50
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SW846 6010C -- Metals by ICPSW6010_W
CadmiumND5.0ug/L109/22/2014 15:2879119
Calcium56000800ug/L109/22/2014 15:2879119
IronND200ug/L109/22/2014 15:2879119
LeadND10ug/L109/22/2014 15:2879119
Magnesium15000500ug/L109/22/2014 15:2879119
Manganese360050ug/L109/22/2014 15:2879119
Potassium25000B1000ug/L109/22/2014 15:2879119
Sodium89001000ug/L109/22/2014 15:2879119
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 13 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-8SSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0809/17/14 12:20
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SW846 6010C -- Metals by ICPSW6010_W
CadmiumND5.0ug/L109/22/2014 15:3279119
Calcium61000800ug/L109/22/2014 15:3279119
Iron48000200ug/L109/22/2014 15:3279119
LeadND10ug/L109/22/2014 15:3279119
Magnesium21000500ug/L109/22/2014 15:3279119
Manganese75050ug/L109/22/2014 15:3279119
Potassium47000B1000ug/L109/22/2014 15:3279119
Sodium230001000ug/L109/22/2014 15:3279119
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 14 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-8DSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0909/17/14 12:50
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SW846 6010C -- Metals by ICPSW6010_W
CadmiumND5.0ug/L109/22/2014 15:5779119
Calcium50000800ug/L109/22/2014 15:5779119
Iron10000200ug/L109/22/2014 15:5779119
LeadND10ug/L109/22/2014 15:5779119
Magnesium26000500ug/L109/22/2014 15:5779119
Manganese150050ug/L109/22/2014 15:5779119
Potassium44000B1000ug/L109/22/2014 15:5779119
Sodium550001000ug/L109/22/2014 15:5779119
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 15 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-6SSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-1009/17/14 13:20
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SW846 6010C -- Metals by ICPSW6010_W
CadmiumND5.0ug/L109/22/2014 16:0179119
Calcium14000800ug/L109/22/2014 16:0179119
Iron120J200ug/L109/22/2014 16:0179119
LeadND10ug/L109/22/2014 16:0179119
Magnesium4500500ug/L109/22/2014 16:0179119
Manganese180050ug/L109/22/2014 16:0179119
Potassium4100B1000ug/L109/22/2014 16:0179119
Sodium68001000ug/L109/22/2014 16:0179119
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 16 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-6DSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-1109/17/14 13:40
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SW846 6010C -- Metals by ICPSW6010_W
CadmiumND5.0ug/L109/22/2014 16:0579119
Calcium31000800ug/L109/22/2014 16:0579119
Iron210200ug/L109/22/2014 16:0579119
LeadND10ug/L109/22/2014 16:0579119
Magnesium18000500ug/L109/22/2014 16:0579119
Manganese70050ug/L109/22/2014 16:0579119
Potassium2600B1000ug/L109/22/2014 16:0579119
Sodium150001000ug/L109/22/2014 16:0579119
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 17 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-1SSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-1209/17/14 14:20
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SW846 6010C -- Metals by ICPSW6010_W
CadmiumND5.0ug/L109/22/2014 16:0879119
Calcium6400800ug/L109/22/2014 16:0879119
IronND200ug/L109/22/2014 16:0879119
LeadND10ug/L109/22/2014 16:0879119
Magnesium5100500ug/L109/22/2014 16:0879119
Manganese12J50ug/L109/22/2014 16:0879119
Potassium3400B1000ug/L109/22/2014 16:0879119
Sodium180001000ug/L109/22/2014 16:0879119
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 18 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-1DSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-1309/17/14 14:50
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SW846 6010C -- Metals by ICPSW6010_W
CadmiumND5.0ug/L109/22/2014 16:1279119
Calcium24000800ug/L109/22/2014 16:1279119
Iron270200ug/L109/22/2014 16:1279119
LeadND10ug/L109/22/2014 16:1279119
Magnesium12000500ug/L109/22/2014 16:1279119
ManganeseND50ug/L109/22/2014 16:1279119
Potassium1400B1000ug/L109/22/2014 16:1279119
Sodium190001000ug/L109/22/2014 16:1279119
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 19 of 117
RPDLimitQualRPDLimitQualRPDLimitQualRPDLimitQual
B - Analyte detected in the associated Method Blank
JB
RPD Ref Val%RPDRPD Ref Val%RPDRPD Ref Val%RPDRPD Ref Val%RPD
OPTIMA3_140922COPTIMA3_140922EOPTIMA3_141030AOPTIMA3_140922C
0 0 0 0 0 0
2154392215492021761002154393
ANALYTICAL QC SUMMARY REPORT
SeqNo:SeqNo:SeqNo:SeqNo:
Run ID:Run ID:Run ID:Run ID:
LowLimitHighLimitLowLimitHighLimitLowLimitHighLimitLowLimitHighLimit
101 80 120 106 80 120 102 80 120 103 80 120 103 80 120 103 80 120
09/22/14 10:0009/22/14 14:4109/22/14 10:0009/22/14 14:4110/29/14 13:0009/22/14 10:0009/22/14 14:44
10/30/14 9:10
SPK valueSPK Ref Val%RECSPK valueSPK Ref Val%RECSPK valueSPK Ref Val%RECSPK valueSPK Ref Val%REC
MDL - Method Detection Limit
Analysis Date:Analysis Date:Analysis Date:Analysis Date:
Prep Date:Prep Date:Prep Date:Prep Date:
SW846 6010C -- Metals by ICP
0 0 0 0 0 0
- Reporting Limit
RL
22700 4550 22700 2270 22700 22700
010_W
S - Recovery outside accepted recovery limits
R - RPD outside accepted recovery limits
SW6
800 200 500 50 1000 1000 5.0 10 5.0 800 200 10 500 50 1000 1000 800 200 500 50 1000 1000
SW6010_WSW6010_WSW6010_WSW6010_W
RLRLRLRL
ug/Lug/Lug/Lug/L
TestCode:TestCode:TestCode:TestCode:
Units:Units:Units:Units:
ND110 ND31 ND76 ND10 109.8 76 ND29 ND0.89 ND4.2 ND0.89 ND110 ND31 ND4.2 ND76 ND10 ND76 ND29 22870 110 4838 31
23240 76 2347 10 23310 76 23330 29
Southhold Landfill Routine Parameters
MDLMDLMDLMDL
Lockwood Kessler & Bartlett Inc.
J - Analyte detected below quanititation limits
79119791197975179119
MBLKMBLKMBLK
LCS
ResultResultResultResult
SampType:SampType:SampType:SampType:
Batch ID:Batch ID:Batch ID:Batch ID:
ND - Not Detected at the MDL
N1726
LCS-79119LCS-79119
79119
MB-79119MB-79119MB-79119MB-79751MB-79751
MB-
Work Order:
Qualifiers:
Sample ID:Sample ID:Sample ID:Sample ID:
CLIENT:
ManganeseManganeseManganese
m14.10.24.0936
MagnesiumMagnesiumMagnesium
Client ID:Client ID:Client ID:Client ID:
Project:
PotassiumPotassiumPotassium
CadmiumCadmium
AnalyteCalciumAnalyteAnalyteCalciumAnalyteCalcium
SodiumSodiumSodium
LeadLead
IronIronIron
N1726Page 20 of 117
RPDLimitQualRPDLimitQualRPDLimitQual
B - Analyte detected in the associated Method Blank
20 20 20 20 20 20 20 20
230.5 0.24421120 0.7344535 0.74458.7 0.28522120 0.5972225 0.51222960 0.83123290 0.592
RPD Ref Val%RPDRPD Ref Val%RPDRPD Ref Val%RPD
OPTIMA3_140922EOPTIMA3_141030AOPTIMA3_141030A
0 0 0 0 0 0 0 0 0 0
215492121761012176102
ANALYTICAL QC SUMMARY REPORT
SeqNo:SeqNo:SeqNo:
Run ID:Run ID:Run ID:
LowLimitHighLimitLowLimitHighLimitLowLimitHighLimit
107 80 120 106 80 120 102 80 120 93.0 80 120 99.7 80 120 101 80 120 97.5 80 120 98.0 80 120 101 80 120 103 80 120 101 80 120 92.4 80 120 98.9 80
120 101 80 120 96.9 80 120 97.5 80 120 102 80 120 103 80 120
09/22/14 10:0009/22/14 14:4410/29/14 13:0010/29/14 13:00
10/30/14 9:1410/30/14 9:17
SPK valueSPK Ref Val%RECSPK valueSPK Ref Val%RECSPK valueSPK Ref Val%REC
MDL - Method Detection Limit
Analysis Date:Analysis Date:Analysis Date:
Prep Date:Prep Date:Prep Date:
SW846 6010C -- Metals by ICP
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
- Reporting Limit
RL
227.0 455.0 227.0 22700 4550 455.0 22700 2270 22700 22700 227.0 22700 4550 455.0 22700 2270 22700 22700
010_W
S - Recovery outside accepted recovery limits
R - RPD outside accepted recovery limits
SW6
5.0 10 5.0 800 200 10 500 50 1000 1000 5.0 800 200 10 500 50 1000 1000
SW6010_WSW6010_WSW6010_W
RLRLRL
ug/Lug/Lug/L
TestCode:TestCode:TestCode:
Units:Units:Units:
21120 110 4535 31 22120 76 2225 10 22960 76 23290 29 20970 110 4501 31 21990 76 2214 10 23150 76
23420 29
0.89 4.2 0.89 4.2 0.89 4.2
Southhold Landfill Routine Parameters
MDLMDLMDL
Lockwood Kessler & Bartlett Inc.
J - Analyte detected below quanititation limits
791197975179751
LCSD
LCSLCS
ResultResultResult
243.8 482.6 230.5 458.7 230.0 457.4
SampType:SampType:SampType:
Batch ID:Batch ID:Batch ID:
ND - Not Detected at the MDL
N1726
LCSD-79751LCSD-79751
-79119
LCS-79119LCS-79751LCS-79751
LCS
Work Order:
Qualifiers:
Sample ID:Sample ID:Sample ID:
CLIENT:
ManganeseManganese
m14.10.24.0936
MagnesiumMagnesium
Client ID:Client ID:Client ID:
Project:
PotassiumPotassium
CadmiumCadmiumCadmium
AnalyteAnalyteCalciumAnalyteCalcium
SodiumSodium
LeadLeadLead
IronIron
N1726Page 21 of 117
RPDLimitQualRPDLimitQualRPDLimitQualRPDLimitQual
B - Analyte detected in the associated Method Blank
20 BS
20 20 20
20 20 20 20
61240 2.2348030 1.3921340 1.33749.4 1.4846990 3.3423490 3.840 0 0 0
RPD Ref Val%RPDRPD Ref Val%RPDRPD Ref Val%RPDRPD Ref Val%RPD
OPTIMA3_140922COPTIMA3_140922EOPTIMA3_140922COPTIMA3_140922E
0 0 0 0
2154407215493521544082154936
ANALYTICAL QC SUMMARY REPORT
SeqNo:SeqNo:SeqNo:SeqNo:
Run ID:Run ID:Run ID:Run ID:
LowLimitHighLimitLowLimitHighLimitLowLimitHighLimitLowLimitHighLimit
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 50.0 80 120 102 80 120 105 80 120 102 80 120
0 0 0 0 0 0 0 0
09/22/14 10:0009/22/14 15:3509/22/14 10:0009/22/14 15:3509/22/14 10:0009/22/14 15:3909/22/14 10:0009/22/14 15:39
SPK valueSPK Ref Val%RECSPK valueSPK Ref Val%RECSPK valueSPK Ref Val%RECSPK valueSPK Ref Val%REC
MDL - Method Detection Limit
Analysis Date:Analysis Date:Analysis Date:Analysis Date:
Prep Date:Prep Date:Prep Date:Prep Date:
SW846 6010C -- Metals by ICP
0 0
0 0 0 0 0 0 48030 749.4 0 0
- Reporting Limit
RL
4550 2270 227.0 455.0
0 0 0 0 0 0
010_W
S - Recovery outside accepted recovery limits
R - RPD outside accepted recovery limits
SW6
800 200 500 50 1000 1000 5.0 10 200 50 5.0 10
SW6010_WSW6010_WSW6010_WSW6010_W
RLRLRLRL
ug/Lug/Lug/Lug/L
TestCode:TestCode:TestCode:TestCode:
Units:Units:Units:Units:
59890 110 47370 31 21060 76 738.4 10 45450 76 22600 29 50300 31 3071 10
0.89 4.2 0.89 4.2
Southhold Landfill Routine Parameters
MDLMDLMDLMDL
Lockwood Kessler & Bartlett Inc.
J - Analyte detected below quanititation limits
79119791197911979119
DUPDUP
MSMS
ResultResultResultResult
NDND238.8 465.5
SampType:SampType:SampType:SampType:
Batch ID:Batch ID:Batch ID:Batch ID:
ND - Not Detected at the MDL
26-08EDUP
N1726-08EDUP
N1726
N1726-08EMSN1726-08EMS
MW-8SMW-8SMW-8SMW-8S
N17
Work Order:
Qualifiers:
Sample ID:Sample ID:Sample ID:Sample ID:
CLIENT:
ManganeseManganese
m14.10.24.0936
Magnesium
Client ID:Client ID:Client ID:Client ID:
Project:
Potassium
CadmiumCadmium
AnalyteCalciumAnalyteAnalyteAnalyte
Sodium
LeadLead
IronIron
N1726Page 22 of 117
RPDLimitQualRPDLimitQualRPDLimitQual
B - Analyte detected in the associated Method Blank
10 J 10 B
10 10 10 10 10
10 10 10 10 10 10 10 10 10
0 0 161000 5.67727.1 2.320 0 61790 4.112515 4.1736300 4.22203500 8.7261240 3.7148030 0.82721340 0.49749.4 0.56946990 1.6123490
0.4220 0 0 0
RPD Ref Val%RPDRPD Ref Val%RPDRPD Ref Val%RPD
OPTIMA3_141030AOPTIMA3_140922COPTIMA3_140922E
217610621544092154937
ANALYTICAL QC SUMMARY REPORT
SeqNo:SeqNo:SeqNo:
Run ID:Run ID:Run ID:
LowLimitHighLimitLowLimitHighLimitLowLimitHighLimit
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0 0 0 0 0
10/29/14 13:0009/22/14 10:0009/22/14 15:4309/22/14 10:0009/22/14 15:43
10/30/14 9:32
SPK valueSPK Ref Val%RECSPK valueSPK Ref Val%RECSPK valueSPK Ref Val%REC
MDL - Method Detection Limit
Analysis Date:Analysis Date:Analysis Date:
Prep Date:Prep Date:Prep Date:
SW846 6010C -- Metals by ICP
0 0 0
0 0 0 0 0 0 0 0 0 0 0 0 0
- Reporting Limit
RL
0 0
0 0 0 0 0 0 0 0 0 0 0
010_W
S - Recovery outside accepted recovery limits
R - RPD outside accepted recovery limits
SW6
25 4000 1000 50 2500 250 5000 5000 4000 1000 2500 250 5000 5000 25 50
SW6010_WSW6010_WSW6010_W
RLRLRL
ug/Lug/Lug/L
TestCode:TestCode:TestCode:
Units:Units:Units:
152200 550 744.1 160 ND21 64380 380 2622 50 37860 380 222100 150 59000 550 48430 160 21450 380 753.7 50
47760 380 23590 150 ND21
4.5 4.5
Southhold Landfill Routine Parameters
MDLMDLMDL
Lockwood Kessler & Bartlett Inc.
J - Analyte detected below quanititation limits
797517911979119
SDSDSD
ResultResultResult
NDND
SampType:SampType:SampType:
Batch ID:Batch ID:Batch ID:
ND - Not Detected at the MDL
N1726
26-06ESD
N1726-08ESDN1726-08ESD
MW-4DMW-8SMW-8S
N17
Work Order:
Qualifiers:
Sample ID:Sample ID:Sample ID:
CLIENT:
ManganeseManganese
m14.10.24.0936
MagnesiumMagnesium
Client ID:Client ID:Client ID:
Project:
PotassiumPotassium
CadmiumCadmium
AnalyteCalciumAnalyteCalciumAnalyte
SodiumSodium
LeadLead
IronIron
N1726Page 23 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-3DSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0109/17/14 8:50
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SM 2340B -- HARDNESS by CalculationSM2340_W
Hardness, Ca/Mg (As CaCO3)3004.0mg/L CaCO3109/22/2014 14:5979119
SM 2320B -- Alkalinity (Total)SM2320_W
Alkalinity, Total (As CaCO3)50080mg/L CaCO3409/19/2014 15:0779108
SM 5220D -- COD by Closed Reflux Colorimetric MethodSM5220
Chemical Oxygen Demand55B20mg/L110/01/2014 14:1279310
SM 5310B TOC -- Total Organic Carbon by combustionSM5310B_TOC_W
Organic Carbon, Total1810mg/L109/26/2014 23:2179141
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 24 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-3SSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0209/17/14 9:20
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SM 2340B -- HARDNESS by CalculationSM2340_W
Hardness, Ca/Mg (As CaCO3)2204.0mg/L CaCO3109/22/2014 15:0379119
SM 2320B -- Alkalinity (Total)SM2320_W
Alkalinity, Total (As CaCO3)27040mg/L CaCO3209/19/2014 15:1079108
SM 5220D -- COD by Closed Reflux Colorimetric MethodSM5220
Chemical Oxygen Demand39B20mg/L110/01/2014 14:1579310
SM 5310B TOC -- Total Organic Carbon by combustionSM5310B_TOC_W
Organic Carbon, Total7.2J10mg/L109/26/2014 23:4179141
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 25 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-5SSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0309/17/14 9:40
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SM 2340B -- HARDNESS by CalculationSM2340_W
Hardness, Ca/Mg (As CaCO3)46B4.0mg/L CaCO3110/30/2014 9:2179751
SM 2320B -- Alkalinity (Total)SM2320_W
Alkalinity, Total (As CaCO3)3220mg/L CaCO3109/19/2014 15:1479108
SM 5220D -- COD by Closed Reflux Colorimetric MethodSM5220
Chemical Oxygen DemandND20mg/L110/01/2014 14:1879310
SM 5310B TOC -- Total Organic Carbon by combustionSM5310B_TOC_W
Organic Carbon, TotalND10mg/L109/27/2014 0:0079141
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 26 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-5DSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0409/17/14 10:00
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SM 2340B -- HARDNESS by CalculationSM2340_W
Hardness, Ca/Mg (As CaCO3)320B4.0mg/L CaCO3110/30/2014 9:2579751
SM 2320B -- Alkalinity (Total)SM2320_W
Alkalinity, Total (As CaCO3)77020mg/L CaCO3109/19/2014 15:1779108
SM 5220D -- COD by Closed Reflux Colorimetric MethodSM5220
Chemical Oxygen Demand75B20mg/L110/01/2014 14:2179310
SM 5310B TOC -- Total Organic Carbon by combustionSM5310B_TOC_W
Organic Carbon, Total2810mg/L109/27/2014 0:1879141
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 27 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-4SSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0509/17/14 10:40
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SM 2340B -- HARDNESS by CalculationSM2340_W
Hardness, Ca/Mg (As CaCO3)2104.0mg/L CaCO3109/22/2014 15:2179119
SM 2320B -- Alkalinity (Total)SM2320_W
Alkalinity, Total (As CaCO3)16020mg/L CaCO3109/19/2014 15:2179108
SM 5220D -- COD by Closed Reflux Colorimetric MethodSM5220
Chemical Oxygen Demand23B20mg/L110/01/2014 14:2479310
SM 5310B TOC -- Total Organic Carbon by combustionSM5310B_TOC_W
Organic Carbon, Total6.6J10mg/L109/27/2014 0:3879141
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 28 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-4DSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0609/17/14 11:30
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SM 2340B -- HARDNESS by CalculationSM2340_W
Hardness, Ca/Mg (As CaCO3)660B4.0mg/L CaCO3110/30/2014 9:2879751
SM 2320B -- Alkalinity (Total)SM2320_W
Alkalinity, Total (As CaCO3)78020mg/L CaCO3109/19/2014 15:2479108
SM 5220D -- COD by Closed Reflux Colorimetric MethodSM5220
Chemical Oxygen Demand61B20mg/L110/01/2014 14:2779310
SM 5310B TOC -- Total Organic Carbon by combustionSM5310B_TOC_W
Organic Carbon, Total2010mg/L109/27/2014 0:5779141
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 29 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-7SSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0709/17/14 10:50
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SM 2340B -- HARDNESS by CalculationSM2340_W
Hardness, Ca/Mg (As CaCO3)2004.0mg/L CaCO3109/22/2014 15:2879119
SM 2320B -- Alkalinity (Total)SM2320_W
Alkalinity, Total (As CaCO3)16020mg/L CaCO3109/19/2014 15:2879108
SM 5220D -- COD by Closed Reflux Colorimetric MethodSM5220
Chemical Oxygen Demand24B20mg/L110/01/2014 14:3079310
SM 5310B TOC -- Total Organic Carbon by combustionSM5310B_TOC_W
Organic Carbon, Total6.6J10mg/L109/27/2014 2:4179142
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 30 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-8SSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0809/17/14 12:20
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SM 2340B -- HARDNESS by CalculationSM2340_W
Hardness, Ca/Mg (As CaCO3)2404.0mg/L CaCO3109/22/2014 15:3279119
SM 2320B -- Alkalinity (Total)SM2320_W
Alkalinity, Total (As CaCO3)38040mg/L CaCO3209/19/2014 15:3179108
SM 5220D -- COD by Closed Reflux Colorimetric MethodSM5220
Chemical Oxygen Demand46B20mg/L110/01/2014 14:3379310
SM 5310B TOC -- Total Organic Carbon by combustionSM5310B_TOC_W
Organic Carbon, Total1610mg/L109/27/2014 3:0179142
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 31 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-8DSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-0909/17/14 12:50
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SM 2340B -- HARDNESS by CalculationSM2340_W
Hardness, Ca/Mg (As CaCO3)2304.0mg/L CaCO3109/22/2014 15:5779119
SM 2320B -- Alkalinity (Total)SM2320_W
Alkalinity, Total (As CaCO3)24040mg/L CaCO3209/19/2014 15:4279108
SM 5220D -- COD by Closed Reflux Colorimetric MethodSM5220
Chemical Oxygen Demand31B20mg/L110/01/2014 14:4579310
SM 5310B TOC -- Total Organic Carbon by combustionSM5310B_TOC_W
Organic Carbon, Total9.3J10mg/L109/27/2014 4:0279142
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 32 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-6SSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-1009/17/14 13:20
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SM 2340B -- HARDNESS by CalculationSM2340_W
Hardness, Ca/Mg (As CaCO3)544.0mg/L CaCO3109/22/2014 16:0179119
SM 2320B -- Alkalinity (Total)SM2320_W
Alkalinity, Total (As CaCO3)4920mg/L CaCO3109/19/2014 15:4579108
SM 5220D -- COD by Closed Reflux Colorimetric MethodSM5220
Chemical Oxygen Demand33B20mg/L110/01/2014 14:4879310
SM 5310B TOC -- Total Organic Carbon by combustionSM5310B_TOC_W
Organic Carbon, Total1310mg/L109/27/2014 4:2179142
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 33 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-6DSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-1109/17/14 13:40
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SM 2340B -- HARDNESS by CalculationSM2340_W
Hardness, Ca/Mg (As CaCO3)1504.0mg/L CaCO3109/22/2014 16:0579119
SM 2320B -- Alkalinity (Total)SM2320_W
Alkalinity, Total (As CaCO3)ND20mg/L CaCO3109/19/2014 15:4979108
SM 5220D -- COD by Closed Reflux Colorimetric MethodSM5220
Chemical Oxygen Demand13BJ20mg/L110/01/2014 14:5179310
SM 5310B TOC -- Total Organic Carbon by combustionSM5310B_TOC_W
Organic Carbon, TotalND10mg/L109/27/2014 4:4179142
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 34 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-1SSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-1209/17/14 14:20
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SM 2340B -- HARDNESS by CalculationSM2340_W
Hardness, Ca/Mg (As CaCO3)374.0mg/L CaCO3109/22/2014 16:0879119
SM 2320B -- Alkalinity (Total)SM2320_W
Alkalinity, Total (As CaCO3)ND20mg/L CaCO3109/19/2014 15:5379108
SM 5220D -- COD by Closed Reflux Colorimetric MethodSM5220
Chemical Oxygen DemandND20mg/L110/01/2014 14:5479310
SM 5310B TOC -- Total Organic Carbon by combustionSM5310B_TOC_W
Organic Carbon, TotalND10mg/L109/27/2014 5:4579142
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 35 of 117
Spectrum Analytical Inc. - North Kingstown RI -- Rhode Island Division
10/31/2014
Lockwood Kessler & Bartlett Inc.
Client:
MW-1DSouthhold Landfill Routine Parameters
Client Sample ID:Project:
N1726-1309/17/14 14:50
Lab ID:Collection Date:
AnalysesResultQualRLUnitsDFDate AnalyzedBatch ID
SM 2340B -- HARDNESS by CalculationSM2340_W
Hardness, Ca/Mg (As CaCO3)1104.0mg/L CaCO3109/22/2014 16:1279119
SM 2320B -- Alkalinity (Total)SM2320_W
Alkalinity, Total (As CaCO3)3320mg/L CaCO3109/19/2014 15:5679108
SM 5220D -- COD by Closed Reflux Colorimetric MethodSM5220
Chemical Oxygen Demand14BJ20mg/L110/01/2014 14:5779310
SM 5310B TOC -- Total Organic Carbon by combustionSM5310B_TOC_W
Organic Carbon, TotalND10mg/L109/27/2014 6:0879142
ND - Not Detected at the Reporting LimitS - Spike Recovery outside accepted recovery limits
Qualifiers:
J - Analyte detected below quanititation limitsR - RPD outside accepted recovery limits
B - Analyte detected in the associated Method BlankE - Value above quantitation range
DF - Dilution FactorRL - Reporting Limit
N1726Page 36 of 117
RPDLimitQualRPDLimitQualRPDLimitQualRPDLimitQual
B - Analyte detected in the associated Method Blank
20
10/31/2014
380.0 0
RPD Ref Val%RPDRPD Ref Val%RPDRPD Ref Val%RPDRPD Ref Val%RPD
MANUAL_140919AMANUAL_140919AMANUAL_140919AMANUAL_140919A
Date:
0 0
2154000215400121540102154011
ANALYTICAL QC SUMMARY REPORT
SeqNo:SeqNo:SeqNo:SeqNo:
Run ID:Run ID:Run ID:Run ID:
LowLimitHighLimitLowLimitHighLimitLowLimitHighLimitLowLimitHighLimit
101 80 120 100 75 125
0 0 0 0
09/19/14 15:0009/19/14 15:0009/19/14 15:0009/19/14 15:0309/19/14 15:0009/19/14 15:3509/19/14 15:0009/19/14 15:38
SPK valueSPK Ref Val%RECSPK valueSPK Ref Val%RECSPK valueSPK Ref Val%RECSPK valueSPK Ref Val%REC
MDL - Method Detection Limit
Analysis Date:Analysis Date:Analysis Date:Analysis Date:
Prep Date:Prep Date:Prep Date:Prep Date:
SM 2320B -- Alkalinity (Total)
0
0 380.0
- Reporting Limit
RL
100.0 100.0
320_W
S - Recovery outside accepted recovery limits
R - RPD outside accepted recovery limits
SM2
mg/L CaCO3mg/L CaCO3mg/L CaCO3mg/L CaCO3
20 20 40 40
SM2320_WSM2320_WSM2320_WSM2320_W
RLRLRLRL
Spectrum Analytical Inc. - North Kingstown RI --
TestCode:TestCode:TestCode:TestCode:
Units:Units:Units:Units:
ND20 101.0 20 380.0 40 480.0 40
Southhold Landfill Routine Parameters
MDLMDLMDLMDL
Lockwood Kessler & Bartlett Inc.
J - Analyte detected below quanititation limits
79108791087910879108
MBLK
DUP
LCS
MS
ResultResultResultResult
SampType:SampType:SampType:SampType:
Batch ID:Batch ID:Batch ID:Batch ID:
ND - Not Detected at the MDL
N1726-08GDUP
N1726
Alkalinity, Total (As CaCO3)Alkalinity, Total (As CaCO3)Alkalinity, Total (As CaCO3)Alkalinity, Total (As CaCO3)
N1726-08GMS
LCS-79108LCS-79108
79108
MB-79108
MW-8SMW-8S
-
Work Order:
B
M
Qualifiers:
Sample ID:Sample ID:Sample ID:Sample ID:
CLIENT:
m14.10.24.0936
Client ID:Client ID:Client ID:Client ID:
Project:
AnalyteAnalyteAnalyteAnalyte
N1726Page 37 of 117
RPDLimitQualRPDLimitQualRPDLimitQualRPDLimitQual
B - Analyte detected in the associated Method Blank
J 20 B
20
240.8 1.9 656.5 1.77
RPD Ref Val%RPDRPD Ref Val%RPDRPD Ref Val%RPDRPD Ref Val%RPD
OPTIMA3_140922FOPTIMA3_141030BOPTIMA3_140922FOPTIMA3_141030B
2155615217610921556272176113
ANALYTICAL QC SUMMARY REPORT
SeqNo:SeqNo:SeqNo:SeqNo:
Run ID:Run ID:Run ID:Run ID:
LowLimitHighLimitLowLimitHighLimitLowLimitHighLimitLowLimitHighLimit
0 0 0 0 0 0 80 120
09/22/14 10:0009/22/14 14:4110/29/14 13:0009/22/14 10:0009/22/14 15:3510/29/14 13:00
10/30/14 9:1010/30/14 9:32
SM 2340B -- HARDNESS by Calculation
SPK valueSPK Ref Val%RECSPK valueSPK Ref Val%RECSPK valueSPK Ref Val%RECSPK valueSPK Ref Val%REC
MDL - Method Detection Limit
Analysis Date:Analysis Date:Analysis Date:Analysis Date:
Prep Date:Prep Date:Prep Date:Prep Date:
0
0
- Reporting Limit
RL
340_W
S - Recovery outside accepted recovery limits
R - RPD outside accepted recovery limits
SM2
mg/L CaCO3mg/L CaCO3mg/L CaCO3mg/L CaCO3
4.0 4.0 4.0 20
SM2340_WSM2340_WSM2340_WSM2340_W
RLRLRLRL
TestCode:TestCode:TestCode:TestCode:
Units:Units:Units:Units:
ND0.30 0.30420.30
0.30 1.5
Southhold Landfill Routine Parameters
MDLMDLMDLMDL
Lockwood Kessler & Bartlett Inc.
J - Analyte detected below quanititation limits
79119797517911979751
MBLKMBLK
DUP
SD
ResultResultResultResult
236.3 645.0
SampType:SampType:SampType:SampType:
Batch ID:Batch ID:Batch ID:Batch ID:
ND - Not Detected at the MDL
N1726-08EDUP
N1726
N1726-06ESD
79119
MB-79119MB-79751MB-79751
Hardness, Ca/Mg (As Hardness, Ca/Mg (As Hardness, Ca/Mg (As Hardness, Ca/Mg (As
MW-8SMW-4D
MB-
Work Order:
Qualifiers:
Sample ID:Sample ID:Sample ID:Sample ID:
CLIENT:
m14.10.24.0936
Client ID:Client ID:Client ID:Client ID:
Project:
CaCO3)CaCO3)CaCO3)CaCO3)
AnalyteAnalyteAnalyteAnalyte
N1726Page 38 of 117
RPDLimitQualRPDLimitQualRPDLimitQualRPDLimitQual
B - Analyte detected in the associated Method Blank
20 B
JBB
45.72 4.43
RPD Ref Val%RPDRPD Ref Val%RPDRPD Ref Val%RPDRPD Ref Val%RPD
SPEC2_141001ASPEC2_141001ASPEC2_141001ASPEC2_141001A
0 0
2159969215997021599802159981
ANALYTICAL QC SUMMARY REPORT
SeqNo:SeqNo:SeqNo:SeqNo:
Run ID:Run ID:Run ID:Run ID:
SM 5220D -- COD by Closed Reflux Colorimetric Method
LowLimitHighLimitLowLimitHighLimitLowLimitHighLimitLowLimitHighLimit
89.50 93.1 80 120 0 0 0 0 60.00 81.3 75 125
10/01/14 10:0010/01/14 14:0610/01/14 10:0010/01/14 14:0910/01/14 10:0010/01/14 14:3910/01/14 10:0010/01/14 14:42
SPK valueSPK Ref Val%RECSPK valueSPK Ref Val%RECSPK valueSPK Ref Val%RECSPK valueSPK Ref Val%REC
MDL - Method Detection Limit
Analysis Date:Analysis Date:Analysis Date:Analysis Date:
Prep Date:Prep Date:Prep Date:Prep Date:
0
20 0 20 45.72
- Reporting Limit
RL
S - Recovery outside accepted recovery limits
220
R - RPD outside accepted recovery limits
SM5
20 20
SM5220SM5220SM5220SM5220
mg/Lmg/Lmg/Lmg/L
RLRLRLRL
TestCode:TestCode:TestCode:TestCode:
Units:Units:Units:Units:
10.69 10 83.34 10 47.79 10 94.50 10
Southhold Landfill Routine Parameters
MDLMDLMDLMDL
Lockwood Kessler & Bartlett Inc.
J - Analyte detected below quanititation limits
79310793107931079310
MBLK
DUP
LCS
MS
ResultResultResultResult
SampType:SampType:SampType:SampType:
Batch ID:Batch ID:Batch ID:Batch ID:
ND - Not Detected at the MDL
N1726-08BDUP
N1726
N1726-08BMS
Chemical Oxygen DemandChemical Oxygen DemandChemical Oxygen DemandChemical Oxygen Demand
LCS-79310LCS-79310
79310
MB-79310
MW-8SMW-8S
MB-
Work Order:
Qualifiers:
Sample ID:Sample ID:Sample ID:Sample ID:
CLIENT:
m14.10.24.0936
Client ID:Client ID:Client ID:Client ID:
Project:
AnalyteAnalyteAnalyteAnalyte
N1726Page 39 of 117
RPDLimitQualRPDLimitQualRPDLimitQualRPDLimitQualRPDLimitQualRPDLimitQual
B - Analyte detected in the associated Method Blank
S
20
16.03 2.75
RPD Ref Val%RPDRPD Ref Val%RPDRPD Ref Val%RPDRPD Ref Val%RPDRPD Ref Val%RPDRPD Ref Val%RPD
TOC1_140926ATOC1_140926ATOC1_140926ATOC1_140926ATOC1_140926ATOC1_140926A
0 0 0
215760321576382157605215763921576422157643
ANALYTICAL QC SUMMARY REPORT
SeqNo:SeqNo:SeqNo:SeqNo:SeqNo:SeqNo:
Run ID:Run ID:Run ID:Run ID:Run ID:Run ID:
SM 5310B TOC -- Total Organic Carbon by combustion
LowLimitHighLimitLowLimitHighLimitLowLimitHighLimitLowLimitHighLimitLowLimitHighLimitLowLimitHighLimit
60.00 108 80 120 60.00 100 80 120 0 0 0 0 50.00 70.2 75 125
09/26/14 13:0009/26/14 14:5909/26/14 13:0009/26/14 13:0009/26/14 15:2109/26/14 13:0009/26/14 13:0009/26/14 13:00
09/27/14 2:0009/27/14 2:2209/27/14 3:2009/27/14 3:40
SPK valueSPK Ref Val%RECSPK valueSPK Ref Val%RECSPK valueSPK Ref Val%RECSPK valueSPK Ref Val%RECSPK valueSPK Ref Val%RECSPK valueSPK Ref Val%REC
MDL - Method Detection Limit
Analysis Date:Analysis Date:Analysis Date:Analysis Date:Analysis Date:Analysis Date:
Prep Date:Prep Date:Prep Date:Prep Date:Prep Date:Prep Date:
0
10 0 10 0 10 16.03
- Reporting Limit
310B_TOC_W
RL
S - Recovery outside accepted recovery limits
R - RPD outside accepted recovery limits
SM5
SM5310B_TOC_WSM5310B_TOC_WSM5310B_TOC_WSM5310B_TOC_WSM5310B_TOC_WSM5310B_TOC_W
10 10 10
mg/Lmg/Lmg/Lmg/Lmg/Lmg/L
RLRLRLRLRLRL
TestCode:TestCode:TestCode:TestCode:TestCode:TestCode:
Units:Units:Units:Units:Units:Units:
ND2.0 ND2.0 64.74 2.0 60.19 2.0 2.0 51.13 2.0
Southhold Landfill Routine Parameters
MDLMDLMDLMDLMDLMDL
Lockwood Kessler & Bartlett Inc.
J - Analyte detected below quanititation limits
791417914279141791427914279142
MBLKMBLK
DUP
LCSLCS
MS
ResultResultResultResultResultResult
16.48
SampType:SampType:SampType:SampType:SampType:SampType:
Batch ID:Batch ID:Batch ID:Batch ID:Batch ID:Batch ID:
ND - Not Detected at the MDL
N1726-08CDUP
N1726
N1726-08CMS
LCS-79141LCS-79141LCS-79142LCS-79142
79141
MB-79141MB-79142MB-79142
Organic Carbon, TotalOrganic Carbon, TotalOrganic Carbon, TotalOrganic Carbon, TotalOrganic Carbon, TotalOrganic Carbon, Total
MW-8SMW-8S
MB-
Work Order:
Qualifiers:
Sample ID:Sample ID:Sample ID:Sample ID:Sample ID:Sample ID:
CLIENT:
m14.10.24.0936
Client ID:Client ID:Client ID:Client ID:Client ID:Client ID:
Project:
AnalyteAnalyteAnalyteAnalyteAnalyteAnalyte
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Page 69 of 117N1726
Page 70 of 117N1726
Wednesday, October01,2014
Attn: MsAgnesRHuntley
SpectrumAnalytical
Rhode IslandDivision
646CampAvenue
NorthKingstown,RI02852
Project ID:SOUTHHOLDLANDFILL
Sample ID#s:BH17182- BH17194
This laboratory isincompliancewith theNELACrequirementsofproceduresused
exceptwhere indicated.
Thisreportcontainsresults for theparameterstested,under thesamplingconditions
describedon theChain Of Custody,asreceivedby the laboratory.
AscannedversionoftheCOC formaccompanies theanalyticalreportand isanexact
duplicateof theoriginal.
Ifyouhaveanyquestionsconcerning thistesting,pleasedonothesitate tocontact
PhoenixClientServicesatext.200.
Sincerelyyours,
PhyllisShiller
LaboratoryDirector
NELAC - #NY11301NJLabRegistration#CT-003
CTLabRegistration#PH-0618NYLabRegistration#11301
MALabRegistration#MA-CT-007PALabRegistration#68-03530
MELabRegistration#CT-007RILabRegistration#63
NHLabRegistration#213693-A,BVTLabRegistration#VT11301
587 EastMiddleTurnpike,P.O.Box370,Manchester,CT06040
Telephone(860)645-1102Fax(860)645-0823
N1726Page 71 of 117
Environmental Laboratories, Inc.
587EastMiddleTurnpike, P.O.Box370,Manchester,CT06045
Tel.(860)645-1102Fax(860)645-0823
AnalysisReport
FOR:Attn: MsAgnes R Huntley
SpectrumAnalytical
October01,2014
Rhode Island Division
646 CampAvenue
NorthKingstown, RI 02852
SampleInformationCustody InformationDateTime
Matrix:WATERCollected by:09/17/148:50
Received by:
LocationCode:SPECTRUM-RISW09/22/1415:49
Rush Request:StandardAnalyzed by:
see"By" below
P.O.#:N1726
LaboratoryData
SDGID:GBH17182
Phoenix ID:BH17182
Project ID:SOUTHHOLD LANDFILL
MW-3D
ClientID:
RL/
ParameterResultPQLUnitsDate/TimeByReference
<0.0080.008mg/L09/24/14GDE420.4
Phenolics
Comments:
If thereareanyquestionsregarding thisdata,please call PhoenixClient Servicesatextension200.
Thisreportmustnotbereproducedexceptin fullasdefinedbytheattached chainof custody.
Phyllis Shiller,Laboratory Director
October01,2014
ReviewedandReleasedby: Sarah Bell,ProjectManager
Page1of13Ver 1
N1726Page 72 of 117
Environmental Laboratories, Inc.
587EastMiddleTurnpike, P.O.Box370,Manchester,CT06045
Tel.(860)645-1102Fax(860)645-0823
AnalysisReport
FOR:Attn: MsAgnes R Huntley
SpectrumAnalytical
October01,2014
Rhode Island Division
646 CampAvenue
NorthKingstown, RI 02852
SampleInformationCustody InformationDateTime
Matrix:WATERCollected by:09/17/149:20
Received by:
LocationCode:SPECTRUM-RISW09/22/1415:49
Rush Request:StandardAnalyzed by:
see"By" below
P.O.#:N1726
LaboratoryData
SDGID:GBH17182
Phoenix ID:BH17183
Project ID:SOUTHHOLD LANDFILL
MW-3S
ClientID:
RL/
ParameterResultPQLUnitsDate/TimeByReference
<0.0080.008mg/L09/24/14GDE420.4
Phenolics
Comments:
If thereareanyquestionsregarding thisdata,please call PhoenixClient Servicesatextension200.
Thisreportmustnotbereproducedexceptin fullasdefinedbytheattached chainof custody.
Phyllis Shiller,Laboratory Director
October01,2014
ReviewedandReleasedby: Sarah Bell,ProjectManager
Page2of13Ver 1
N1726Page 73 of 117
Environmental Laboratories, Inc.
587EastMiddleTurnpike, P.O.Box370,Manchester,CT06045
Tel.(860)645-1102Fax(860)645-0823
AnalysisReport
FOR:Attn: MsAgnes R Huntley
SpectrumAnalytical
October01,2014
Rhode Island Division
646 CampAvenue
NorthKingstown, RI 02852
SampleInformationCustody InformationDateTime
Matrix:WATERCollected by:09/17/149:40
Received by:
LocationCode:SPECTRUM-RISW09/22/1415:49
Rush Request:StandardAnalyzed by:
see"By" below
P.O.#:N1726
LaboratoryData
SDGID:GBH17182
Phoenix ID:BH17184
Project ID:SOUTHHOLD LANDFILL
MW-5S
ClientID:
RL/
ParameterResultPQLUnitsDate/TimeByReference
<0.0080.008mg/L09/24/14GDE420.4
Phenolics
Comments:
If thereareanyquestionsregarding thisdata,please call PhoenixClient Servicesatextension200.
Thisreportmustnotbereproducedexceptin fullasdefinedbytheattached chainof custody.
Phyllis Shiller,Laboratory Director
October01,2014
ReviewedandReleasedby: Sarah Bell,ProjectManager
Page3of13Ver 1
N1726Page 74 of 117
Environmental Laboratories, Inc.
587EastMiddleTurnpike, P.O.Box370,Manchester,CT06045
Tel.(860)645-1102Fax(860)645-0823
AnalysisReport
FOR:Attn: MsAgnes R Huntley
SpectrumAnalytical
October01,2014
Rhode Island Division
646 CampAvenue
NorthKingstown, RI 02852
SampleInformationCustody InformationDateTime
Matrix:WATERCollected by:09/17/1410:00
Received by:
LocationCode:SPECTRUM-RISW09/22/1415:49
Rush Request:StandardAnalyzed by:
see"By" below
P.O.#:N1726
LaboratoryData
SDGID:GBH17182
Phoenix ID:BH17185
Project ID:SOUTHHOLD LANDFILL
MW-5D
ClientID:
RL/
ParameterResultPQLUnitsDate/TimeByReference
<0.0080.008mg/L09/24/14GDE420.4
Phenolics
Comments:
If thereareanyquestionsregarding thisdata,please call PhoenixClient Servicesatextension200.
Thisreportmustnotbereproducedexceptin fullasdefinedbytheattached chainof custody.
Phyllis Shiller,Laboratory Director
October01,2014
ReviewedandReleasedby: Sarah Bell,ProjectManager
Page4of13Ver 1
N1726Page 75 of 117
Environmental Laboratories, Inc.
587EastMiddleTurnpike, P.O.Box370,Manchester,CT06045
Tel.(860)645-1102Fax(860)645-0823
AnalysisReport
FOR:Attn: MsAgnes R Huntley
SpectrumAnalytical
October01,2014
Rhode Island Division
646 CampAvenue
NorthKingstown, RI 02852
SampleInformationCustody InformationDateTime
Matrix:WATERCollected by:09/17/1410:40
Received by:
LocationCode:SPECTRUM-RISW09/22/1415:49
Rush Request:StandardAnalyzed by:
see"By" below
P.O.#:N1726
LaboratoryData
SDGID:GBH17182
Phoenix ID:BH17186
Project ID:SOUTHHOLD LANDFILL
MW-4S
ClientID:
RL/
ParameterResultPQLUnitsDate/TimeByReference
<0.0080.008mg/L09/24/14GDE420.4
Phenolics
Comments:
If thereareanyquestionsregarding thisdata,please call PhoenixClient Servicesatextension200.
Thisreportmustnotbereproducedexceptin fullasdefinedbytheattached chainof custody.
Phyllis Shiller,Laboratory Director
October01,2014
ReviewedandReleasedby: Sarah Bell,ProjectManager
Page5of13Ver 1
N1726Page 76 of 117
Environmental Laboratories, Inc.
587EastMiddleTurnpike, P.O.Box370,Manchester,CT06045
Tel.(860)645-1102Fax(860)645-0823
AnalysisReport
FOR:Attn: MsAgnes R Huntley
SpectrumAnalytical
October01,2014
Rhode Island Division
646 CampAvenue
NorthKingstown, RI 02852
SampleInformationCustody InformationDateTime
Matrix:WATERCollected by:09/17/1411:30
Received by:
LocationCode:SPECTRUM-RISW09/22/1415:49
Rush Request:StandardAnalyzed by:
see"By" below
P.O.#:N1726
LaboratoryData
SDGID:GBH17182
Phoenix ID:BH17187
Project ID:SOUTHHOLD LANDFILL
MW-4D
ClientID:
RL/
ParameterResultPQLUnitsDate/TimeByReference
<0.0080.008mg/L09/24/14GDE420.4
Phenolics
Comments:
If thereareanyquestionsregarding thisdata,please call PhoenixClient Servicesatextension200.
Thisreportmustnotbereproducedexceptin fullasdefinedbytheattached chainof custody.
Phyllis Shiller,Laboratory Director
October01,2014
ReviewedandReleasedby: Sarah Bell,ProjectManager
Page6of13Ver 1
N1726Page 77 of 117
Environmental Laboratories, Inc.
587EastMiddleTurnpike, P.O.Box370,Manchester,CT06045
Tel.(860)645-1102Fax(860)645-0823
AnalysisReport
FOR:Attn: MsAgnes R Huntley
SpectrumAnalytical
October01,2014
Rhode Island Division
646 CampAvenue
NorthKingstown, RI 02852
SampleInformationCustody InformationDateTime
Matrix:WATERCollected by:09/17/1410:50
Received by:
LocationCode:SPECTRUM-RISW09/22/1415:49
Rush Request:StandardAnalyzed by:
see"By" below
P.O.#:N1726
LaboratoryData
SDGID:GBH17182
Phoenix ID:BH17188
Project ID:SOUTHHOLD LANDFILL
MW-7S
ClientID:
RL/
ParameterResultPQLUnitsDate/TimeByReference
<0.0080.008mg/L09/24/14GDE420.4
Phenolics
Comments:
If thereareanyquestionsregarding thisdata,please call PhoenixClient Servicesatextension200.
Thisreportmustnotbereproducedexceptin fullasdefinedbytheattached chainof custody.
Phyllis Shiller,Laboratory Director
October01,2014
ReviewedandReleasedby: Sarah Bell,ProjectManager
Page7of13Ver 1
N1726Page 78 of 117
Environmental Laboratories, Inc.
587EastMiddleTurnpike, P.O.Box370,Manchester,CT06045
Tel.(860)645-1102Fax(860)645-0823
AnalysisReport
FOR:Attn: MsAgnes R Huntley
SpectrumAnalytical
October01,2014
Rhode Island Division
646 CampAvenue
NorthKingstown, RI 02852
SampleInformationCustody InformationDateTime
Matrix:WATERCollected by:09/17/1412:20
Received by:
LocationCode:SPECTRUM-RISW09/22/1415:49
Rush Request:StandardAnalyzed by:
see"By" below
P.O.#:N1726
LaboratoryData
SDGID:GBH17182
Phoenix ID:BH17189
Project ID:SOUTHHOLD LANDFILL
MW-8S
ClientID:
RL/
ParameterResultPQLUnitsDate/TimeByReference
<0.0080.008mg/L09/24/14GDE420.4
Phenolics
Comments:
If thereareanyquestionsregarding thisdata,please call PhoenixClient Servicesatextension200.
Thisreportmustnotbereproducedexceptin fullasdefinedbytheattached chainof custody.
Phyllis Shiller,Laboratory Director
October01,2014
ReviewedandReleasedby: Sarah Bell,ProjectManager
Page8of13Ver 1
N1726Page 79 of 117
Environmental Laboratories, Inc.
587EastMiddleTurnpike, P.O.Box370,Manchester,CT06045
Tel.(860)645-1102Fax(860)645-0823
AnalysisReport
FOR:Attn: MsAgnes R Huntley
SpectrumAnalytical
October01,2014
Rhode Island Division
646 CampAvenue
NorthKingstown, RI 02852
SampleInformationCustody InformationDateTime
Matrix:WATERCollected by:09/17/1412:50
Received by:
LocationCode:SPECTRUM-RISW09/22/1415:49
Rush Request:StandardAnalyzed by:
see"By" below
P.O.#:N1726
LaboratoryData
SDGID:GBH17182
Phoenix ID:BH17190
Project ID:SOUTHHOLD LANDFILL
MW-8D
ClientID:
RL/
ParameterResultPQLUnitsDate/TimeByReference
<0.0080.008mg/L09/24/14GDE420.4
Phenolics
Comments:
If thereareanyquestionsregarding thisdata,please call PhoenixClient Servicesatextension200.
Thisreportmustnotbereproducedexceptin fullasdefinedbytheattached chainof custody.
Phyllis Shiller,Laboratory Director
October01,2014
ReviewedandReleasedby: Sarah Bell,ProjectManager
Page9of13Ver 1
N1726Page 80 of 117
Environmental Laboratories, Inc.
587EastMiddleTurnpike, P.O.Box370,Manchester,CT06045
Tel.(860)645-1102Fax(860)645-0823
AnalysisReport
FOR:Attn: MsAgnes R Huntley
SpectrumAnalytical
October01,2014
Rhode Island Division
646 CampAvenue
NorthKingstown, RI 02852
SampleInformationCustody InformationDateTime
Matrix:WATERCollected by:09/17/1413:20
Received by:
LocationCode:SPECTRUM-RISW09/22/1415:49
Rush Request:StandardAnalyzed by:
see"By" below
P.O.#:N1726
LaboratoryData
SDGID:GBH17182
Phoenix ID:BH17191
Project ID:SOUTHHOLD LANDFILL
MW-6S
ClientID:
RL/
ParameterResultPQLUnitsDate/TimeByReference
0.0090.008mg/L09/24/14GDE420.4
Phenolics
Comments:
If thereareanyquestionsregarding thisdata,please call PhoenixClient Servicesatextension200.
Thisreportmustnotbereproducedexceptin fullasdefinedbytheattached chainof custody.
Phyllis Shiller,Laboratory Director
October01,2014
ReviewedandReleasedby: Sarah Bell,ProjectManager
Page10of13Ver 1
N1726Page 81 of 117
Environmental Laboratories, Inc.
587EastMiddleTurnpike, P.O.Box370,Manchester,CT06045
Tel.(860)645-1102Fax(860)645-0823
AnalysisReport
FOR:Attn: MsAgnes R Huntley
SpectrumAnalytical
October01,2014
Rhode Island Division
646 CampAvenue
NorthKingstown, RI 02852
SampleInformationCustody InformationDateTime
Matrix:WATERCollected by:09/17/1413:40
Received by:
LocationCode:SPECTRUM-RISW09/22/1415:49
Rush Request:StandardAnalyzed by:
see"By" below
P.O.#:N1726
LaboratoryData
SDGID:GBH17182
Phoenix ID:BH17192
Project ID:SOUTHHOLD LANDFILL
MW-6D
ClientID:
RL/
ParameterResultPQLUnitsDate/TimeByReference
<0.0080.008mg/L09/24/14GDE420.4
Phenolics
Comments:
If thereareanyquestionsregarding thisdata,please call PhoenixClient Servicesatextension200.
Thisreportmustnotbereproducedexceptin fullasdefinedbytheattached chainof custody.
Phyllis Shiller,Laboratory Director
October01,2014
ReviewedandReleasedby: Sarah Bell,ProjectManager
Page11of13Ver 1
N1726Page 82 of 117
Environmental Laboratories, Inc.
587EastMiddleTurnpike, P.O.Box370,Manchester,CT06045
Tel.(860)645-1102Fax(860)645-0823
AnalysisReport
FOR:Attn: MsAgnes R Huntley
SpectrumAnalytical
October01,2014
Rhode Island Division
646 CampAvenue
NorthKingstown, RI 02852
SampleInformationCustody InformationDateTime
Matrix:WATERCollected by:09/17/1414:20
Received by:
LocationCode:SPECTRUM-RISW09/22/1415:49
Rush Request:StandardAnalyzed by:
see"By" below
P.O.#:N1726
LaboratoryData
SDGID:GBH17182
Phoenix ID:BH17193
Project ID:SOUTHHOLD LANDFILL
MW-1S
ClientID:
RL/
ParameterResultPQLUnitsDate/TimeByReference
<0.0080.008mg/L09/24/14GDE420.4
Phenolics
Comments:
If thereareanyquestionsregarding thisdata,please call PhoenixClient Servicesatextension200.
Thisreportmustnotbereproducedexceptin fullasdefinedbytheattached chainof custody.
Phyllis Shiller,Laboratory Director
October01,2014
ReviewedandReleasedby: Sarah Bell,ProjectManager
Page12of13Ver 1
N1726Page 83 of 117
Environmental Laboratories, Inc.
587EastMiddleTurnpike, P.O.Box370,Manchester,CT06045
Tel.(860)645-1102Fax(860)645-0823
AnalysisReport
FOR:Attn: MsAgnes R Huntley
SpectrumAnalytical
October01,2014
Rhode Island Division
646 CampAvenue
NorthKingstown, RI 02852
SampleInformationCustody InformationDateTime
Matrix:WATERCollected by:09/17/1414:50
Received by:
LocationCode:SPECTRUM-RISW09/22/1415:49
Rush Request:StandardAnalyzed by:
see"By" below
P.O.#:N1726
LaboratoryData
SDGID:GBH17182
Phoenix ID:BH17194
Project ID:SOUTHHOLD LANDFILL
MW-1D
ClientID:
RL/
ParameterResultPQLUnitsDate/TimeByReference
<0.0080.008mg/L09/24/14GDE420.4
Phenolics
Comments:
If thereareanyquestionsregarding thisdata,please call PhoenixClient Servicesatextension200.
Thisreportmustnotbereproducedexceptin fullasdefinedbytheattached chainof custody.
Phyllis Shiller,Laboratory Director
October01,2014
ReviewedandReleasedby: Sarah Bell,ProjectManager
Page13of13Ver 1
N1726Page 84 of 117
QA/QC Batch287209,QC Sample No: BH17189 (BH17182, BH17183, BH17184, BH17185, BH17186, BH17187, BH17188,
BH17189, BH17190, BH17191, BH17192, BH17193, BH17194)
Phenolics
85 - 11520
N1726Page 85 of 117
f 1
Page 86 of 117
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Environmental Laboratories, Inc.
587 EastMiddle Turnpike,P.O.Box370,Manchester,CT06045
Tel. (860)645-1102Fax(860)645-0823
NYTemperatureNarration
October 01, 2014
SDGI.D.:GBH17182
Thesamplesinthisdeliverygroupwerereceivedat6°C.
(Noteacceptancecriteriaisabovefreezingupto6°C)
Page1of 1
N1726Page 87 of 117
N1726Page 88 of 117
N1726Page 89 of 117
N1726Page 90 of 117
N1726Page 91 of 117
Creator :GregDanielewski
CreationDate :9/29/20149:21:05PM
LastModified :9/29/201410:07:48PM
Description :Phenol
CupSample IDMDFWeightSampleTypeComments
S1CalStd ACalibrationStandard
S2CalStd BCalibrationStandard
S3CalStd CCalibrationStandard
S4CalStd DCalibrationStandard
S5CalStd ECalibrationStandard
S6CalStd FCalibrationStandard
S7CalStd GCalibrationStandard
S8CalStd HCalibrationStandard
S9CALSTDCheckStandard
S8BLANKCheckStandard
S70.005ppmCheckStandard
180LCSRAW0.262mg/LCheckStandard
76xUnknown
1BH17189PBUnknown
2BH17189LCSUnknown
3BH17189DUPUnknown
4BH17189SPKUnknown
5BH17182Unknown
6BH17183Unknown
7BH17184Unknown
S9CALSTDCheckStandard
S8BLANKCheckStandard
8BH17185Unknown
9BH17186Unknown
10BH17187Unknown
11BH17188Unknown
12BH17189Unknown
13BH17190Unknown
14BH17191Unknown
15BH17192Unknown
5BH17182Unknown
16BH17193Unknown
S9CALSTDCheckStandard
S8BLANKCheckStandard
17BH17194Unknown
18SPECIALUnknown
19BH18297PBUnknown
20BH18297LCSUnknown
21BH18297DUPUnknown
22BH18297SPKUnknown
Page 1
N1726Page 92 of 117
23BH18295500Unknown
24BH18296500Unknown
25BH18297Unknown
26SPECIALUnknown
S9CALSTDCheckStandard
S8BLANKCheckStandard
14BH17191Unknown
S9CALSTDCheckStandard
S8BLANKCheckStandard
AnalyteTable
Phenol
(mg/L)
CalStd A0.500
CalStd B0.250
CalStd C0.100
CalStd D0.0500
CalStd E
0.0250
CalStd F0.0100
CalStd G5.00e-3
CalStd H
0.00
Page 2
N1726Page 93 of 117
Author:GregDanielewskiPhoenixLabsDate:9/29/2014
OriginalRunFilename:OM_9-29-2014_09-21-05PM.OMNCreated:9/29/20149:21:05PM
OriginalRunAuthor'sSignature: \[GregDanielewski\]
CurrentRunFilename:OM_9-29-2014_09-21-05PM.OMNLastModified: 9/29/2014 10:07:48PM
CurrentRunAuthor'sSignature: \[GregDanielewski\]
Description:Phenol
Channel 1
Phenol
SampleRep.CupNo.ADFMDF
Conc.(mg/L)Area
(V.s)
CalStd A1S10.5002.00
CalStd B1S20.2500.958
CalStd C1S30.1000.392
CalStd D1S40.05000.214
CalStd E1S50.02500.104
CalStd F1S60.01000.0463
CalStd G1S75.00e-30.0277
CalStd H1S80.00-4.68e-3
CALSTD1S90.09690.385
KnownConc:0.100
DQMTest:>+ ConcentrationLimit
Result:0.0969< 0.110
MessagePass
Action
DQMTest:<-ConcentrationLimit
Result:0.0969> 0.0900
MessagePass
Action
Calibration:Table/Fig.: 1
BLANK1S8-4.37e-4-2.10e-4
KnownConc:0.00
DQMTest:>+ ConcentrationLimit
Result:-4.37e-4<4.99e-3
MessagePass
Action
0.005ppm1S76.69e-30.0280
KnownConc:5.00e-3
LCSRAW0.262mg/L11800.2861.13
KnownConc:0.262
DQMTest:>+ ConcentrationLimit
Result:0.286<0.288
MessagePass
Action
DQMTest:<-ConcentrationLimit
Result:0.286>0.236
MessagePass
Action
x1766.66e-30.0279
BH17189PB113.18e-30.0141
BH17189LCS120.2711.08
BH17189DUP137.40e-30.0308
BH17189SPK140.1860.738
BH17182157.84e-30.0326
BH17183164.00e-30.0174
BH17184173.19e-30.0142
CALSTD1S90.09670.384
KnownConc:0.100
DQMTest:>+ ConcentrationLimit
Result:0.0967< 0.110
MessagePass
Action
DQMTest:<-ConcentrationLimit
Result:0.0967> 0.0900
MessagePass
Action
BLANK1S82.10e-39.85e-3
KnownConc:0.00
-1 -
N1726Page 94 of 117
Author:GregDanielewskiPhoenixLabsDate:9/29/2014
DQMTest:>+ ConcentrationLimit
Result:2.10e-3<4.99e-3
MessagePass
Action
BH17185184.38e-30.0189
BH17186192.08e-39.77e-3
BH171871105.32e-30.0226
BH171881112.61e-30.0119
BH171891125.45e-30.0231
BH171901133.80e-30.0166
BH171911149.33e-30.0385
BH171921153.16e-42.77e-3
BH17182155.05e-30.0215
BH171931163.33e-30.0147
CALSTD1S90.09630.383
KnownConc:0.100
DQMTest:>+ ConcentrationLimit
Result:0.0963< 0.110
MessagePass
Action
DQMTest:<-ConcentrationLimit
Result:0.0963> 0.0900
MessagePass
Action
BLANK1S8-1.61e-3-4.87e-3
KnownConc:0.00
DQMTest:>+ ConcentrationLimit
Result:-1.61e-3<4.99e-3
MessagePass
Action
BH171941173.15e-30.0140
SPECIAL1180.1850.734
BH18297PB1191.97e-39.33e-3
BH18297LCS1200.2691.07
BH18297DUP1218.53e-30.0353
BH18297SPK1220.1900.754
BH182951231220.966500.00
BH182961241351.07500.00
BH182971258.44e-30.0350
SPECIAL1260.1850.734
CALSTD1S90.09840.391
KnownConc:0.100
DQMTest:>+ ConcentrationLimit
Result:0.0984< 0.110
MessagePass
Action
DQMTest:<-ConcentrationLimit
Result:0.0984> 0.0900
MessagePass
Action
BLANK1S83.63e-42.96e-3
KnownConc:0.00
DQMTest:>+ ConcentrationLimit
Result:3.63e-4<4.99e-3
MessagePass
Action
BH171911149.69e-30.0399
CALSTD1S90.09590.381
KnownConc:0.100
DQMTest:>+ ConcentrationLimit
Result:0.0959< 0.110
MessagePass
Action
DQMTest:<-ConcentrationLimit
Result:0.0959> 0.0900
MessagePass
Action
BLANK1S89.89e-45.44e-3
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N1726Page 95 of 117
Author:GregDanielewskiPhoenixLabsDate:9/29/2014
KnownConc:0.00
DQMTest:>+ ConcentrationLimit
Result:9.89e-4<4.99e-3
MessagePass
Action
Channel1-Set:1 / 7
2.35
0.500mg/L
2.28
0.250mg/L
0.100mg/L
0.0500mg/L
0.0250mg/L
0.0100mg/L
5.00e-3mg/L
0.00mg/L
2.09
56.5Time:(s)486.2
Channel1-Set:2 / 7
2.35
2.28
0.286mg/L
0.271mg/L
0.0969mg/L
6.69e-3mg/L6.66e-3mg/L7.40e-3mg/L
3.18e-3mg/L
-4.37e-4mg/L
2.09
486.2Time:(s)926.6
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N1726Page 96 of 117
Author:GregDanielewskiPhoenixLabsDate:9/29/2014
Channel1-Set:3 / 7
2.35
2.28
0.186mg/L
0.0967mg/L
7.84e-3mg/L
4.00e-3mg/L4.38e-3mg/L
3.19e-3mg/L2.10e-3mg/L2.08e-3mg/L
2.09
926.2Time:(s)1.4e+3
Channel1-Set:4 / 7
2.35
2.28
9.33e-3mg/L
5.45e-3mg/L
5.32e-3mg/L3.16e-4mg/L5.05e-3mg/L
2.61e-3mg/L3.80e-3mg/L
3.33e-3
2.09
1.4e+3Time:(s)1.8e+3
Channel1-Set:5 / 7
2.35
2.28
0.269mg/L
0.190mg/L
0.185mg/L
0.0963mg/L
8.53e-3mg/L
-1.61e-3m3.15g/Le-3mg/L1.97e-3mg/L
2.09
1.8e+3Time:(s)2.2e+3
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Author:GregDanielewskiPhoenixLabsDate:9/29/2014
Channel1-Set:6 / 7
2.35
2.28
0.270mg/L
0.243mg/L
0.185mg/L
0.0984mg/L
0.0959mg/L
9.69e-3mg/L
8.44e-3mg/L
3.63e-4mg/L
2.09
2.2e+3Time:(s)2.7e+3
Channel1-Set:7 / 7
2.35
2.28
9.89e-4mg/L
2.09
2.7e+3Time:(s)5.5e+3
Table:1(Phenol)
KnownConc.PeakAreaPeakHeightDet.Conc
Rep.%RSD%ResidualDetectionDateDetectionTime
(mg/L)(V.s)(V)(mg/L)
10.50012.000.1730.0-0.80.5049/29/20149:22:05PM
20.25010.9580.08230.03.40.2419/29/20149:22:57PM
30.10010.3920.03340.01.30.09879/29/20149:23:49PM
40.050010.2140.01830.0-7.20.05379/29/20149:24:42PM
50.025010.1049.33e-30.0-3.60.02609/29/20149:25:36PM
60.010010.04633.80e-30.0-12.00.01139/29/20149:26:30PM
75.00e-310.02772.13e-30.0-28.46.60e-39/29/20149:27:27PM
80.001-4.68e-3-4.59e-4-1.57e-39/29/20149:28:23PM
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N1726Page 98 of 117
Author:GregDanielewskiPhoenixLabsDate:9/29/2014
Figure:1(Phenol)
2.00
Area=3.96*Conc+ 1.76e-3
Conc= 0.253*Area-3.84e-4
CorrelationCoefficient(r)= 0.99974
Weighting:None
0.00Concentrationmg/L0.500
-6 -
N1726Page 99 of 117
SampleID,ReplicateNumber,DetectionDate,DetectionTime,CupNumber,RepeatNumber,Description,SampleType,ManualDilutionFactor,AnalyteName,Anal
CalStdA,1,9/29/2014,9:22:05PM,S1,1,,CalibrationStandard,1,Phenol,0.5,mg/L
CalStdB,1,9/29/2014,9:22:57PM,S2,1,,CalibrationStandard,1,Phenol,0.25,mg/L
CalStdC,1,9/29/2014,9:23:49PM,S3,1,,CalibrationStandard,1,Phenol,0.1,mg/L
CalStdD,1,9/29/2014,9:24:42PM,S4,1,,CalibrationStandard,1,Phenol,0.05,mg/L
CalStdE,1,9/29/2014,9:25:36PM,S5,1,,CalibrationStandard,1,Phenol,0.025,mg/L
CalStdF,1,9/29/2014,9:26:30PM,S6,1,,CalibrationStandard,1,Phenol,0.01,mg/L
CalStdG,1,9/29/2014,9:27:27PM,S7,1,,CalibrationStandard,1,Phenol,0.005,mg/L
CalStdH,1,9/29/2014,9:28:23PM,S8,1,,CalibrationStandard,1,Phenol,0,mg/L
CALSTD,1,9/29/2014,9:29:17PM,S9,1,,CheckStandard,1,Phenol,0.0969,mg/L
BLANK,1,9/29/2014,9:30:12PM,S8,1,,CheckStandard,1,Phenol,-0.000437,mg/L
0.005ppm,1,9/29/2014,9:31:08PM,S7,1,,CheckStandard,1,Phenol,0.00669,mg/L
LCSRAW0.262mg/L,1,9/29/2014,9:32:03PM,180,1,,CheckStandard,1,Phenol,0.286,mg/L
x,1,9/29/2014,9:32:59PM,76,1,,Unknown,1,Phenol,0.00666,mg/L
BH17189PB,1,9/29/2014,9:33:55PM,1,1,,Unknown,1,Phenol,0.00318,mg/L
BH17189LCS,1,9/29/2014,9:34:50PM,2,1,,Unknown,1,Phenol,0.271,mg/L
BH17189DUP,1,9/29/2014,9:35:44PM,3,1,,Unknown,1,Phenol,0.0074,mg/L
BH17189SPK,1,9/29/2014,9:36:38PM,4,1,,Unknown,1,Phenol,0.186,mg/L
BH17182,1,9/29/2014,9:37:32PM,5,1,,Unknown,1,Phenol,0.00784,mg/L
BH17183,1,9/29/2014,9:38:26PM,6,1,,Unknown,1,Phenol,0.004,mg/L
BH17184,1,9/29/2014,9:39:19PM,7,1,,Unknown,1,Phenol,0.00319,mg/L
CALSTD,1,9/29/2014,9:40:11PM,S9,2,,CheckStandard,1,Phenol,0.0967,mg/L
BLANK,1,9/29/2014,9:41:06PM,S8,2,,CheckStandard,1,Phenol,0.0021,mg/L
BH17185,1,9/29/2014,9:42:01PM,8,1,,Unknown,1,Phenol,0.00438,mg/L
BH17186,1,9/29/2014,9:42:54PM,9,1,,Unknown,1,Phenol,0.00208,mg/L
BH17187,1,9/29/2014,9:43:46PM,10,1,,Unknown,1,Phenol,0.00532,mg/L
BH17188,1,9/29/2014,9:44:39PM,11,1,,Unknown,1,Phenol,0.00261,mg/L
BH17189,1,9/29/2014,9:45:30PM,12,1,,Unknown,1,Phenol,0.00545,mg/L
BH17190,1,9/29/2014,9:46:23PM,13,1,,Unknown,1,Phenol,0.0038,mg/L
BH17191,1,9/29/2014,9:47:14PM,14,1,,Unknown,1,Phenol,0.00933,mg/L
BH17192,1,9/29/2014,9:48:05PM,15,1,,Unknown,1,Phenol,0.000316,mg/L
BH17182,1,9/29/2014,9:48:57PM,5,2,,Unknown,1,Phenol,0.00505,mg/L
BH17193,1,9/29/2014,9:49:52PM,16,1,,Unknown,1,Phenol,0.00333,mg/L
CALSTD,1,9/29/2014,9:50:45PM,S9,3,,CheckStandard,1,Phenol,0.0963,mg/L
BLANK,1,9/29/2014,9:51:39PM,S8,3,,CheckStandard,1,Phenol,-0.00161,mg/L
BH17194,1,9/29/2014,9:52:35PM,17,1,,Unknown,1,Phenol,0.00315,mg/L
SPECIAL,1,9/29/2014,9:53:30PM,18,1,,Unknown,1,Phenol,0.185,mg/L
BH18297PB,1,9/29/2014,9:54:25PM,19,1,,Unknown,1,Phenol,0.00197,mg/L
BH18297LCS,1,9/29/2014,9:55:19PM,20,1,,Unknown,1,Phenol,0.269,mg/L
BH18297DUP,1,9/29/2014,9:56:13PM,21,1,,Unknown,1,Phenol,0.00853,mg/L
BH18297SPK,1,9/29/2014,9:57:07PM,22,1,,Unknown,1,Phenol,0.19,mg/L
BH18295,1,9/29/2014,9:58:01PM,23,1,,Unknown,500,Phenol,0.243,mg/L
BH18296,1,9/29/2014,9:58:54PM,24,1,,Unknown,500,Phenol,0.27,mg/L
BH18297,1,9/29/2014,9:59:47PM,25,1,,Unknown,1,Phenol,0.00844,mg/L
SPECIAL,1,9/29/2014,10:00:39PM,26,2,,Unknown,1,Phenol,0.185,mg/L
CALSTD,1,9/29/2014,10:01:32PM,S9,4,,CheckStandard,1,Phenol,0.0984,mg/L
BLANK,1,9/29/2014,10:02:26PM,S8,4,,CheckStandard,1,Phenol,0.000363,mg/L
BH17191,1,9/29/2014,10:03:20PM,14,2,,Unknown,1,Phenol,0.00969,mg/L
CALSTD,1,9/29/2014,10:05:32PM,S9,5,,CheckStandard,1,Phenol,0.0959,mg/L
BLANK,1,9/29/2014,10:06:26PM,S8,5,,CheckStandard,1,Phenol,0.000989,mg/L
N1726Page 100 of 117
9/29/201410:10:45PMPage1of 1
LACHATDataTransferLog
C:\\ProgramFiles\\Lachat\\Omnion\\Data\\2014\\OM_9-29-2014_09-21-05PM.csvNotTransferred
FileName:TransferDate:
RunDateSampleAcodeAnalyteResultMDLDilICRaw%SolidSMessage
09/29/149:37PMBH17182PHEN-LDLPhenolicsBRL0.0081.00.00784100
09/29/149:48PMBH17182PHEN-LDLPhenolicsBRL0.0081.00.00505100
09/29/149:38PMBH17183PHEN-LDLPhenolicsBRL0.0081.00.004100
09/29/149:39PMBH17184PHEN-LDLPhenolicsBRL0.0081.00.00319100
09/29/149:42PMBH17185PHEN-LDLPhenolicsBRL0.0081.00.00438100
09/29/149:42PMBH17186PHEN-LDLPhenolicsBRL0.0081.00.00208100
09/29/149:43PMBH17187PHEN-LDLPhenolicsBRL0.0081.00.00532100
09/29/149:44PMBH17188PHEN-LDLPhenolicsBRL0.0081.00.00261100
09/29/149:45PMBH17189PHEN-LDLPhenolicsBRL0.0081.00.00545100
09/29/149:33PMBH17189B_PHEN-WLabBlank forPhenBRL0.0151.00.00318
09/29/149:35PMBH17189D_PHEN-WSampleDuplicate fBRL0.0151.00.0074100
09/29/149:34PMBH17189L_PHEN-WLabControlforPhe1031.00.271
09/29/149:36PMBH17189R_PHEN-WMtxSpkRecovery f93.01.00.186100
09/29/149:46PMBH17190PHEN-LDLPhenolicsBRL0.0081.00.0038100
09/29/149:47PMBH17191PHEN-LDLPhenolics0.0090.0081.00.00933100
09/29/1410:03PMBH17191PHEN-LDLPhenolics0.0100.0081.00.00969100
09/29/149:48PMBH17192PHEN-LDLPhenolicsBRL0.0081.00.000316100
09/29/149:49PMBH17193PHEN-LDLPhenolicsBRL0.0081.00.00333100
09/29/149:52PMBH17194PHEN-LDLPhenolicsBRL0.0081.00.00315100
09/29/149:58PMBH18295PHEN-WMPhenolics1227.5500.0121.5100
09/29/149:58PMBH18296PHEN-WMPhenolics1357.5500.0135100
09/29/149:59PMBH18297PHEN-WMPhenolicsBRL0.0151.00.00844100
09/29/149:54PMBH18297B_PHEN-WLabBlank forPhenBRL0.0151.00.00197
09/29/149:56PMBH18297D_PHEN-WSampleDuplicate fBRL0.0151.00.00853100
09/29/149:55PMBH18297L_PHEN-WLabControlforPhe1031.00.269
09/29/149:57PMBH18297R_PHEN-WMtxSpkRecovery f95.01.00.19100
N1726Page 101 of 117
PHEN-WM
PHEN-WM-287209
QAQCCode#QPHEN-WMQAQCSample #BH17189
SampleAcodeAnalysisSampleSurrogateFinalpH<2CommentsStartFinishInitials
Wgt(g)Vol(ml)Vol(ml)DateDate
</= 2GD
BH17189BLK505009/2409/24
</= 2GD
BH17189LCS505009/2409/24
</= 2GD
BH17189DUP505009/2409/24
</= 2GD
BH17189MS505009/2409/24
</= 2GD
BH17182PHEN-LDL505009/2409/24
</= 2GD
BH17183PHEN-LDL505009/2409/24
</= 2GD
BH17184PHEN-LDL505009/2409/24
</= 2GD
BH17185PHEN-LDL505009/2409/24
</= 2GD
BH17186PHEN-LDL505009/2409/24
</= 2GD
BH17187PHEN-LDL505009/2409/24
</= 2GD
BH17188PHEN-LDL505009/2409/24
</= 2GD
BH17189PHEN-LDL505009/2409/24
</= 2GD
BH17190PHEN-LDL505009/2409/24
</= 2GD
BH17191PHEN-LDL505009/2409/24
</= 2GD
BH17192PHEN-LDL505009/2409/24
</= 2GD
BH17193PHEN-LDL505009/2409/24
</= 2GD
BH17194PHEN-LDL505009/2409/24
</= 2GD
SPECIAL505009/2409/24
QCRptCmnt
CuSO4=5-81-18.Spikesolution=Phenol-0011-spkT.V.=10.0mg/L.Spikedsample1mL:50mL.
PrepComment
T.V.=0.20mg/L.LCS=(04-10-14)ERAP203-515tv=0.262mg/Lasmade0.1mL to1L.Special=
BLKSPK=0.20mg/L.
PostComment
Surrogate Id #Tracking #TimeIn
Spike #
Tracking #TimeOut
LCSID #
Tracking #Temp
TimeBasic
ameh R
!!!SDay*Rus24**ush
9/29/201410:11:13PM
N1726Page 102 of 117
PHEN-WM
PHEN-WM-287215
QAQCCode#QPHEN-WMQAQCSample #BH18297
SampleAcodeAnalysisSampleSurrogateFinalpH<2CommentsStartFinishInitials
Wgt(g)Vol(ml)Vol(ml)DateDate
</= 2GD
BH18297BLK505009/2409/24
</= 2GD
BH18297LCS505009/2409/24
</= 2GD
BH18297DUP505009/2409/24
</= 2GD
BH18297MS505009/2409/24
4GD
BH18295PHEN-WM505009/2409/24
4GD
BH18296PHEN-WM505009/2409/24
</= 2GD
BH18297PHEN-WM505009/2409/24
</= 2GD
SPECIAL505009/2409/24
QCRptCmnt
PrepCommentCuSO4=5-81-18.Spikesolution=Phenol-0011-spkT.V.=10.0mg/L.Spikedsample1mL:50mL.
T.V.=0.20mg/L.LCS=(04-10-14)ERAP203-515tv=0.262mg/Lasmade0.1mL to1L.Special=
BLKSPK=0.20mg/L.
PostComment
Surrogate Id #Tracking #TimeIn
Spike #
Tracking #TimeOut
LCSID #Tracking #Temp
TimeBasic
ameh R
!!!SDay*Rus24**ush
9/29/201410:11:22PM
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Last Page of Data Report
N1726Page 117 of 117