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HomeMy WebLinkAbout2013 4th Quarter Draft DRAFT FOURTH QUARTER 2013 GROUND WATER-MONITORING REPORT FOR THE TOWN OF SOUTHOLD LANDFILL 6155 COX LANE CUTCHOGUE, NY 11944 Prepared for: Southold Town Solid Waste Management District 6155 Cox Lane Cutchogue, NY 11944 "of Fat APR - g 2014 ... OWN OF SOUTHOLD Ci PT.OF SOLID WASTE Prepared by: Lockwood, Kessler & Bartlett, Inc. 1 Aerial Way Syosset, NY 11791 Submitted to: New York State Department of Environmental Conservation Region 1 Headquarters SUNY at Stony Brook 50 Circle Road Stony Brook, NY 11790 MARCH 17, 2014 Fourth Quarter 2013 Ground Water-Monitoring Report Town of Southold Landfill, Cutchoque, NY TABLE OF CONTENTS Section Number and Title Page Number 1.0 INTRODUCTION 1 2.0 METHODS AND PROCEDURES 1 3.0 DISCUSSION OF RESULTS 2 3.1 Water-Level Results 2 3.2 Field Parameter Results 3 3.3 Leachate Indicator Parameter Results 4 3.4 Inorganic Parameter Results 5 4.0 CONCLUSIONS AND RECOMMENDATIONS 6 Figure Number and Title Follows Page Number 1. Site Location Map 1 2. Well Location Map 1 Table Number and Title Follows Page Number 1. Summary of Part 360 Routine Parameter Results for 2 Fourth Quarter 2013 Monitoring Round Appendices A. Sample Data Summary Package • i Lockwood, Kessler& Bartlett, Inc. Fourth Quarter 2013 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY • 1.0 INTRODUCTION The Town of Southold has retained Lockwood, Kessler & Bartlett, Inc. (LKB) to perform post-closure ground-water monitoring and reporting for its closed and capped MSW landfill in Cutchogue, NY (Site). The location of the Site is shown in Figure 1. This report is for the fourth quarter 2013 monitoring round, conducted on November 21, 2013; and describes the work performed and the results obtained. Section 2.0 (Methods and Procedures) details the project requirements and the specific work performed. Section 3.0 (Discussion of Results) summarizes the key findings from this monitoring round, including comparison of the laboratory results to standards and guidance values. Section 4.0 (Conclusions and Recommendations) provides conclusions based on this quarter's results, and recommendations for upcoming quarters. Each report section is supported by figures and/or tables, as appropriate, which follow the page on which they are first referenced. The laboratory data summary package for this monitoring round is provided in Appendix A. 2.0 METHODS AND PROCEDURES Water-level measurements and ground-water samples were collected from the twelve monitoring wells listed below. A site plan showing the locations of the wells is provided in Figure 2. • MW-1 S • MW-5S • MW-1 D • MW-5D • MW-3S • MW-6S • MW-3D • MW-6D • MW-4S • MW-8S • MW4D . MW-8D Prior to sampling, the water-level in each well was measured to the nearest 0.01-feet from the top of the well casing utilizing a decontaminated water-level meter. Ground- water samples were collected utilizing a Grundfos RediFlo2 variable-speed electric submersible pump connected to 250 feet of 3/4-inch diameter polyethylene hose on a Keck Reel. Utilizing the well construction records, the pump was placed at the mid-point of each well's screen. Each well was then purged at a low flow rate until its turbidity was less than 5 Nephelometric Turbidity Units (NTUs) and/or field parameter readings stabilized. The sampling apparatus was decontaminated between wells by rinsing its interior and exterior with distilled water. Field parameters were measured utilizing a calibrated YSI 556 Multi Probe System equipped with a flow-through cell. The ground water purged • during sampling was discharged to the land surface at each well location. I Lockwood, Kessler& Bartlett, Inc. Duck Pond P1 N D 11958 SITE 3REGON lr 1193 CUTCHOCUE STA EAST TTITUCK PAO C U T Cr--H U E p N IL 1K C, 25 v1�"ae Or" v} s R_ ic a tam yk ; °� a) a, °� �i�¢0Y � iS t 4 y_���_.IY T N cYr�� j' � � � K // � � N�f�Ki�E >/ ,R V �.,,_a_. L , NORTH FORK Marsh Pt COUNTRY % MATTITUCK curcHorUE AIRPORT A V 0 Rog AV gi, Old Cove HA 1.RBOP 5r Marrcttooka P1 YC. qv J sr i 10mo et NEW SUFFOLK FIGURE 1 SITE LOCATION MAP TOWN OF SOUTHOLD LANDFILL, CUTCHOGUE, NY EL�EEL-" 7.1 S � EASY 4'�'k LrGEND WN—Es - GPGL-'N0`VVAT=-R M.ON'l-TORING'NELL 300 150 0 SCALE N FEET A4 NOTE:VVELL SYM-qOLS RIOT TO SCALE NVI-1S' Note: Base map provided by Town of Southold FIGURE 2 WELL LOCATION PLAN TOWN OF SOUTHOLD LANDFILL, CUTCHOGUE, NY EEL-.A OWL�MEL-JW Fourth Quarter 2013 Ground Water-Monitoring Report Town of Southold Landfall, Cutchogue, NY • The ground-water samples were collected directly from the pump discharge hose into new laboratory-supplied bottles of the type required for each specific analysis. A blind duplicate was collected from Well MW-6S and labeled "MW-7S". A matrix spike/matrix spike duplicate was collected from Well MW-8S. Field notes were recorded in a bound field notebook. Each sample was labeled with the well number, time and date, etc., placed in a cooler with ice to keep it at 4°C, and delivered to the laboratory the following day. The samples were analyzed for the 6NYCRR Part 360 Routine Parameters. The field parameters were monitored by LKB. Laboratory analyses were performed by EcoTest Laboratories, Inc. a division of H2M Labs, Inc., in Melville, NY. EcoTest is certified by the New York State Department of Health's Environmental Laboratory Approval Program in all required analytical categories and employ the required internal QA/QC procedures, including analysis of matrix spikes, matrix spike duplicates, method blanks and continuing calibration samples. They also participate in the required biennial proficiency testing. The field data and laboratory results were reviewed by LKB per QA/QC Plan requirements and determined to be useable. 3.0 DISCUSSION OF RESULTS The field and laboratory results for the fourth quarter 2013 ground water-monitoring round are summarized and compared to the New York State Department of Environmental Conservation Ambient Water Quality Standards and Guidance Values for Class GA (Potable) ground water, as applicable, in Table 1. A review of the results for the water-level measurements and each analytical parameter group is provided below. 3.1 Water-Level Results As shown in Table 1, water-table elevations were generally consistent across the Site and ranged from 5.62 feet above mean sea level (MSL) in Well MW-1S, located on the south end of the Site, to 3.76 feet above MSL in Well MW-8S, located on the west side of the Site. The water-level results are consistent with ground-water flow information published by the United States Geological Survey in Scientific Investigations Map 3066, Water Table — Sheet 1 of 4, which indicates a relatively low horizontal hydraulic gradient and a northerly horizontal ground water-flow direction. Based on these results, Well Cluster MW-1 is located upgradient of the Site, and the other wells are located downgradient of various portions of the Site. Except for an anomalously high elevation in Well MW-8D, potentiometric surface elevations in the deeper wells are consistent with the water-table elevations. The results for Well MW-8D are attributed to localized hydrogeologic conditions at this well location and screen depth. 2 Lockwood, Kessler& Bartlett, Inc. Table 1 Summary of Part 360 Routine Parameter Results for Fourth Quarter 2013 Monitoring Round • Town of Southold Landfill, Cutchogue, NY NYSDEC Part 360 Units Class GA Well Number and Result Routine Parameters Standard MW-1S MW-1D MW-3S MW-3D MW-4S MW-4D MW-5S MW-5D MW-6S MW-6D MW-8S MW-8D Water-Level Data.- T.O.C. ata:T.O.C. Elevation Feet MSL N/A 44.83 44.88 49.50 49.19 63.03 62.92 68.14 67.64 55.77 55.71 54.16 55.29 Depth to Water Feet N/A 39.21 39.14 44.64 44.32 58.48 58.40 63.58 63.17 50.81 50.79 50.40 49.24 Water-Level Elevation Feet MSL N/A 5.62 5.74 4.86 4.87 4.55 4.52 4.56 4.47 4.96 4.92 3.76 6.05 Field Parameters: Conductivity ms/cm No Standard 0.187 0.323 0.750 1.660 0.640 2.300 0.136 2.090 0.209 0.434 0.940 1.090 Temperature oC No Standard 13.8 12.7 16.0 15.8 16.1 15.3 14.1 14.5 12.9 12.5 15.8 15.0 Floaters or Sinkers N/A None None None None None None None None None None None None None pH Units 6.5-8.5 5.10 6.87 6.44 6.54 6.25 6.85 5.40 6.69 5.67 5.79 6.38 6.72 Eh pHmV No Standard 86.3 -14.1 10.4 5 21.5 -12.6 69.3 -3.7 53.6 46.9 14.2 -5.7 Dissolved Oxygen mg/L No Standard 8.14 2.73 0.52 0.33 1.04 0.31 3.47 0.44 0.61 2.18 0.31 0.39 Field Observations N/A No Standard Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor Turbidity NTU <5 0.77 1.98 0.97 1.05 0.76 1.56 0.68 3.81 0.86 0.77 1.03 0.78 ORP mV No Standard 144 16.3 -62.9 -43.4 65.8 0.7 143 36.3 96.5 87.9 -73.8 -55.9 Leachate Indicators: Alkalinity mg/L No Standard 5.95 28.4 203 476 176 663 20.6 714 48.7 9.95 325 301 • Ammonia mg/L 2 < 0.10 < 0.10 17.0 66.0 < 0.10 26.2 < 0.10 91.0 < 0.10 < 0.10 18.2 24.2 BOD mg/L No Standard < 2 < 2 5 < 2 < 2 < 2 < 2 < 2 < 2 < 2 6 < 2 Bromide mg/L 2Gv < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 Chloride mg/L 250 37.7 23.4 70.0 131 14.0 330 17.9 187 21.0 40.7 26.0 91.5 COD mg/L No Standard < 10 < 10 31.4 51.5 20.3 56.8 < 10 73.7 26.2 < 10 41.1 25.5 Hardness mg/L No Standard 36 108 170 250 260 650 36 360 84 160 248 276 Nitrate mg/L 10 0.69 3.48 < 1.00 < 1.00 16.9 < 0.10 0.30 < 0.10 0.68 7.37 < 1.00 < 0.10 Phenols ug/L 1 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 Sulfate mg/L 250 16.0 58.5 38.9 34.8 39.0 82.0 8.70 36.6 7.70 91.0 35.7 75.0 Total Dissolved Solids mg/L 500 136 228 387 676 453 1,360 101 986 165 317 453 572 TKN mg/L No Standard < 0.10 < 0.10 18.8 70.9 0.44 28.4 0.37 93.6 0.74 < 0.10 19.5 26.5 Total Organic Carbon mg/L No Standard < 1.0 < 1.0 7.7 18.8 9.5 21.9 2.7 27.3 10.9 < 1.0 12.5 10.4 Inorganic Parameters: Cadmium ug/L 5 0.3 J < 0.15 < 0.15 < 0.15 0.30 J < 0.15 < 0.15 < 0.15 0.30 J 0.20 J < 0.15 0.20 J Calcium ug/L No Standard 5,860 22,500 23,200 32,900 64,200 142,000 5,660 75,400 19,400 32,400 62,600 51,400 Iron ug/L 300 < 61.9 < 61.9 64,700 24,400 < 61.9 438 < 61.9 105 < 61.9 < 61.9 51,600 9,140 Lead ug/L 25 8.5 13.7 < 7.2 < 0.72 1.2 J 13.3 8.1 < 0.72 7.5 11.3 < 7.2 11.0 Magnesium ug/L 35,000 4,140 J 10,100 15,500 27,600 15,300 59,200 3,800 J 30,400 5,190 15,700 16,000 25,400 Manganese ug/L 300 12.0 J 7.2 J 3,030 3,160 5,820 3,420 42.0 12,000 2,220 1,100 816 1,470 Potassium _ ug/L No Standard 2,930 J 1,180 J 20,300 68,700 37,400 _ 51,800 3,420 J 109,000 4,300 J 2,730 J 30,900 47,100 Sodium ug/L 20,000 15,300 16,600 34,700 97,600 9,550 202,000 9,110 133,000 4,500 J 13,400 15,500 53,900 Notes: . T.O.C. = Top of Casing. COD = Chemical Oxygen Demand. mV = millivolts. J = Estimated result > MDL but < RL. MSL = Mean Sea Level. TKN = Total Kjeldahl Nitrogen. mg/L = milligrams per Liter. mS/cm = milliSiemens per centimeter. °C = Degrees Celsius. ug/L = micrograms per Liter. Results in bold font and highlighted in yellow ORP = Oxygen Reduction Potential. pHmV = pH in millivolts. N/A = Not Applicable. exceed Class GA Standard or Guidance Value. BOD = Biological Oxygen Demand. NTU = Nephelometric Turbidity Units. NM = Not Measured. Fourth Quarter 2013 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY • 3.2 Field Parameter Results Review of the field parameter results in Table 1 indicates the following key findings: • Ground-water conductivity values are higher relative to the main area of Long Island, and may be at least partly attributed to the Site's North Fork location, where naturally higher ground-water salinities may occur due to the proximity to saline surface-water bodies. Conductivities are highest in the deep wells located directly downgradient of the Site (e.g., Wells MW-3D, MW-4D and MW-5D). These highest values appear to be Site-related. • Ground-water temperatures are slightly higher in the shallow wells located downgradient of, and in close proximity to, the main area of the Site. • No floaters or sinkers were noted during this monitoring round. • Ground-water pH is acidic, and is lower than the minimum standard in seven of the 12 wells this quarter. The results are consistent with the naturally low pH of Long Island ground water, and are similar in upgradient and downgradient wells. Ground-water pH is slightly higher in the deep well at each cluster. • Eh is also similar in upgradient and downgradient wells. Eh is lower in the deep well at each cluster. The lowest Eh values occurred in Wells MW-1 D, MW-4D, MW-5D and MW-8D. • Dissolved oxygen concentrations are generally lower in the downgradient wells than in the upgradient wells, but dissolved oxygen is present in all 12 wells. • The ground water in all 12 wells was observed to be clear, and did not have a noticeable odor this quarter. • The turbidity of ground water is low and was less than 5 Nephelometric Turbidity Units in all 12 wells this quarter. Therefore, the collection of filtered samples for dissolved metals analyses was not required. • The ORP (oxidation-reduction potential) of ground water is positive at four well clusters (MW-1, MW-4, MW-5 and MW-6), and negative at two well clusters (MW-3 and MW-8) this quarter. The highest ORP readings occurred in the upgradient wells and downgradient Well Clusters MW-5 and MW-6. The lowest (most negative) ORP reading occurred in Well Cluster MW-3 and MW-8. Overall, the field parameter results obtained this quarter are consistent with the Site's usage and its North Fork setting. Potential Site-related impacts are relatively minor in magnitude and limited to higher conductivity and temperature, and lower dissolved oxygen levels and ORP readings, in certain downgradient wells. 3 Lockwood, Kessler& Bartlett, Inc. Fourth Quarter 2013 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY • 3.3 Leachate Indicator Parameter Results Review of the leachate parameter results in Table 1 indicates the following key findings: • Ground-water alkalinity is noticeably higher in seven of the ten downgradient wells relative to the upgradient wells, and is highest in Wells MW-3D, MW-4D and MW-5D. • Ammonia is present in six downgradient wells at concentrations exceeding the Class GA ground-water standard, and is highest in Wells MW-3D and MW- 5D. The fact that the highest ammonia concentrations occur in the deeper wells suggests that they may be partly due to natural saline ground-water conditions. • Biological oxygen demand (BOD) was only detected in two downgradient wells (MW-3S and MW-8S) at very concentrations this quarter. • Bromide was not detected in any of the site monitoring wells this quarter. • Chloride levels are noticeably higher in five of the downgradient wells (MW-3S, MW-3D, MW-4D, MW-5D and MW-8D) relative to the upgradient wells, but except for Well MW-3D are lower higher than the Class GA ground-water standard in all wells. The fact that chloride concentrations are highest in certain deeper wells suggests that they may be associated with naturally saline ground- water conditions. • Chemical oxygen demand (COD) was detected in eight of the ten downgradient wells. The highest COD results occurred in Wells MW-3D, MW-4D and MW-5D. • Ground-water hardness values are higher in eight of ten downgradient wells relative to the upgradient wells. The highest hardness value occurred in Well MW-4D. There is no Class GA ground-water standard for this parameter. • Ground-water nitrate levels are relatively low, and lower than the Class GA ground-water standard in every well except Well MW-4S. • Phenols were not detected in any of the site monitoring wells this quarter. • Sulfate is present in all 12 wells, and at relatively similar concentrations in the upgradient and downgradient wells. The sulfate concentration is higher in the deeper well at all but one well cluster, which suggests that they are at least partly associated with saline ground-water conditions. The elevated sulfate concentrations observed last quarter were not present this quarter, which suggests that last quarter's results were a laboratory error. • Total dissolved solids (TDS) results are noticeably higher in eight of the ten downgradient wells relative to the upgradient wells, and exceed the Federal MCL in Wells MW-3D, MW-4D, MW-5D and MW-8D. The fact that the highest TDS concentrations occur in the deeper wells suggests that they may associated with naturally saline ground-water conditions. • 4 Lockwood, Kessler& Bartlett, Inc. Fourth Quarter 2013 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY • • Total Kjeldahl nitrogen (TKN) was not detected in the upgradient wells, but was detected in nine of the ten downgradient wells. The highest concentrations occurred in Wells MW-31D and MW-51D. There is no standard or guidance value for this parameter. • Total organic carbon (TOC) was not detected in the upgradient wells, but was detected in nine of the ten downgradient wells. The highest concentrations occurred in Wells MW-31D, MW-41D and MW-51D. There is no standard or guidance value for this parameter. Overall, the leachate parameter results obtained this quarter are also consistent with the Site's usage and its North Fork setting. Potential Site-related impacts indicated by these results include downgradient increases in most of the detected parameters. However, it is important to note that 1) the there are no ground-water standards for six of the parameters; and 2) the downgradient increases occur in a limited number of wells. Moreover, ground water in this area is naturally saline at depth, and ultimately discharges to a saline surface-water body (Long Island Sound). Therefore, the exceedances for ammonia, chloride, nitrate and TDS, which occur naturally in saline ground water and seawater, are not a significant concern with respect to public health or the environment. 3.4 Inorganic Parameter Results Review of the inorganic routine parameter results in Table 1 indicates the following key findings: • Cadmium was only detected in five wells, including one upgradient well, at similar, very low estimated concentrations. All detected concentrations are much lower than the Class GA ground-water standard. • Calcium was detected in all 12 wells, and is noticeable higher in Wells MW-4S, MW-41D, MW-51D, MW-8S and MW-81D relative to the upgradient wells. There is no Class GA ground-water standard for this parameter. • Iron was detected in six of the downgradient wells, and five of the detected concentrations exceed the Class GA ground-water standard. The highest iron concentrations were detected in Well Clusters MW-3 and MW-8. At these two clusters, the highest iron concentrations occurred in the shallow wells, suggesting that the higher iron levels detected at these locations are Site-related. • Lead was detected at very low, similar concentrations in both upgradient wells and six of the ten downgradient wells. All detections are much lower than the Class GA ground-water standard. • Magnesium was detected in all 12 wells, but only the concentration in Well MW- 4D is higher than the Class GA ground-water guidance value. Magnesium . concentrations are higher in the deeper well at each cluster, which suggests that they are primarily due to naturally saline ground-water conditions. 5 Lockwood, Kessler& Bartlett, Inc. Fourth Quarter 2013 Ground Water-Monitoring Report Town of Southold Landfall, Cutchogue, NY • • Manganese was detected in all 12 wells sampled, exceeds the Class GA ground-water standard in nine of the ten downgradient wells, and is highest in Well MW-5D. • Potassium was detected in all 12 wells. Potassium concentrations are higher in seven of the ten downgradient wells relative to the upgradient wells, and are highest in Wells MW-3D and MW-5D. There is no Class GA ground-water standard for this parameter. • Sodium was detected in all 12 wells. Sodium concentrations are noticeably higher in five downgradient wells (MW-3S, MW-3D, MW-4D, MW-5D and MW- 8D) relative to the upgradient wells, and exceed the Class GA ground-water standard in these wells. The highest sodium concentrations occur in the deep wells, which suggests that they are primarily due to naturally saline ground-water conditions. Overall, the inorganic parameter results obtained this quarter are also consistent with the Site's usage and its North Fork setting. Potential Site-related impacts indicated by these results include downgradient increases in calcium, iron, magnesium, manganese, potassium and sodium. However, it is important to note that 1) many of these increases are relatively minor in magnitude, sporadic, and/or less than the Class GA ground-water standard; 2) there are no ground water-quality standards or guidance values for calcium or potassium; 3) the standards for iron and manganese are aesthetics-based; and 4) sodium is not considered to be particularly hazardous. Moreover, as noted above in Section 3.2, ground water on the North Fork is naturally saline at depth and ultimately discharges to a saline surface-water body (Long Island Sound). Therefore, the exceedances for magnesium and sodium, which occur naturally in saline ground water and seawater, are not a concern with respect to public health or the environment. 4.0 CONCLUSIONS AND RECOMMENDATIONS Based on the results of the fourth quarter 2013 monitoring round, LKB concludes the following: • Water-level elevations, hydraulic gradients and ground water-flow directions are consistent with local and regional hydrogeologic conditions. • In general, ground water-quality conditions are consistent with the Site's North Fork setting near saline surface-water bodies. • Comparison of upgradient and downgradient results indicates potential Site- related impacts consistent with an old MSW landfill, however further assessment indicates that they are not a significant concern with respect to public health or the environment. 6 Lockwood, Kessler & Bartlett, Inc. Fourth Quarter 2013 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY The monitoring schedule for the Site requires monitoring ground water for 6NYCRR Part 360 routine parameters during three calendar quarters and for Part 360 baseline parameters during one calendar quarter, in rotating quarters. Annual baseline rounds have been performed in the third quarter of 2011, the fourth quarter of 2012 and the first quarter of 2013. Therefore, the next baseline monitoring round should be performed during the second quarter of 2014. Accordingly, LKB recommends that the first quarter 2014 monitoring round be performed for Part 360 routine parameters. 7 Lockwood, Kessler& Bartlett, Inc. [a bs 7 ,, 5 _ -:Broad F-iCtilfnv Road i?s vtom. NY 1174736 SAMPLE DATA SUMMARY PACKAGE TABLE OF CONTENTS LOCKWOOD, KESSLER & BARTLETT PROJECT: TOWN OF SOUTHOLD LANDFILL 2013 MONITORING ROUND SAMPLES RECEIVED: 11/22/13 SDG NO.: LK13008 1. NYS DEC SUMMARY FORMS 2. CHAIN OF CUSTODY DOCUMENTATION 3. SDG NARRATIVES 4. SAMPLE REPORTS 4.1 METALS 4.2 WET CHEMISTRY 5. DUPLICATE SUMMARY RESULTS • 5.1 METALS 5.2 WET CHEMISTRY 6. SPIKE SAMPLE RESULTS 6.1 METALS 6.2 WET CHEMISTRY 7. BLANK SUMMARY DATA AND RESULTS 7.1 METALS 7.2 WET CHEMISTRY • LKB008 S1 f z labs, Baxd"ON'w Road 631.694.30,40u INY -1 174 ., 631.420.84'-,CT 1. NYS DEC SUMMARY FORMS LKB008 S2 NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE IDENTIFICATION AND • ANALYTICAL REQUIREMENT SUMMARY SDG: LK13008 Anal ical Requirements Customer Laboratory Sample Sample ME we Code Code MW 1D 1311670-001 X X j MW-1S 1311B70-002 I X X IMW-31) 1311B70-003 X X IMW-3S 1311B70-004 X X MW4D 1311 B70-005 X X MW 4S 1311B70-006 X X [MW-5D 1311670-007 X -_-X_ - i 1311870-008 X X MW-6D 1311 B70-009 X X MW-6S 1311 B70-010 X X 'MW-7S 1311 B70-011 X X MW-81) 1311870-012 X X MW 8S 1311670-013 X X FIELD BLANK 1311B70-014 X X s • CLP�on--HpPlease indicate year of protocol} 9TC , , Priority Pollutant, LKB008 S3 NEW YORK STATE DEPARTMENT OF ENVIAMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG : LK13008 INORGANIC ANALYSIS Laboratory DateRecd Date Samp ID Client Sample ID Matrix Metals Requested at Lab Analyzed 1311B70-001 MW-1D WATER CA,CD,FE,K,MG,MN,NA,PB, 22-Nov-13 12/13 1311B70-002 MW-1S WATER CA,CD,FE,K,MG,MN,NA,PB, 22-Nov-13 12/13 1311B70-003 MW-3D WATER CA,CD,FE,K,MG,MN,NA,PB, 22-Nov-13 12/13 1311B70-004 MW-3S WATER CA,CD,FE,K,MG,MN,NA,PB, 22-Nov-131 12/13 13111370-005 IMW-4D WATER CA,CD,FE,K,MG,MN,NA,PB, 22-Nov-13 12/13 1311B70-006 MW-4S WATER CA,CD,FE,K,MG,MN,NA,PB, 22-Nov-13 12/13 1311B70-007 MW-5D WATER CA,CD,FE,K,MG,MN,NA,PB, 22-Nov-13 12/13 1311070-008 MW-5S WATER CA,CD,FE,K,MG,MN,NA,PB, 22-Nov-13 12/13 1311B70-009 MW-6D WATER CA,CD,FE,K,MG,MN,NA,PB, 22-Nov-13 12/13 1311B70-010 MW-6S WATER CA,CD,FE,K,MG,MN,NA,PB, 22-Nov-13 12/13 CA,CD,FE,K,MG,MN,NA,PB, _ 1311 070-011 MW-7S WATER �PB, 22-Nov 13 12/13 1311B70-012 MW-8D WATER CA,CD,FE,K,MG,MN,NA,PB, 22-Nov-13 12/13 1311B70-013 MW-8S WATER CA,CD,FE,K,MG,MN,NA,PB, 22-Nov-13 12/13 131 IB70-013DUP M W-8SD WATER CA,CD,FE,K,MG,MN,NA,PB, 22-Nov-13 12/13 1311 B70-013MS !MW-8SS WATER CA,CD,FE,K,MG,MN,NA,PB, 22-Nov-13 12/13 1311B70-014 FIELD BLANK WATER CA,CD,FE,K,MG,MN,NA,PB, 22-Nov-13 12/13 LKB008 S4 • NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG : LKB008 INORGANIC ANALYSIS Laboratory DateRecd Date Samp ID j Client Sample ID I Matrix Tests at Lab Analyzed f 1311B70-041 MW-1D Groundwater SELECT WET CHEMISTRY** i 11/22/13 11/13-12/13 i 1311B70-002 i MW-IS Groundwater SELECT WET CHEMISTRY** 11/22/13 j 11/13-12/13 1311B70-003 MW-3D Groundwater SELECT WET CHEMISTRY* 11/22/13 11/13-12/13 1311B70-004 MW-3S Groundwater SELECT WET CHEMISTRY** 11/22/13 11/13- 12/13 1311B70-005 MW-4D Groundwater SELECT WET CHEMISTRY*' 11/22/13 11/13- 12!13 1311B70-006 MW-4S Groundwater SELECT WET CHEMISTRY** 11/22/13 11/13- 12/13 1311B70-007 MW-5D I Groundwater I SELECT WET CHEMISTRY** i 11/22/13 1 11/13-12/13 i 131 IB70-008 I MW-5S Groundwater ' SELECT WET CHEMISTRY** 11/22/13 11/13-12/13 I i I 131 IB70-009 MW-6D Groundwater SELECT WET CHEMISTRY** 11/22/13 I1/13-12/13 1311B70-010 MW-6S Groundwater SELECT WET CHEMISTRY`` 11/22/13 11/13-12/13 I 131 IB70-011 1W'-7S Groundwater SELECT WET CHEMISTRY** 11/22/13 11/13-12/13 1311B70-012 MW-8D Groundwater SELECT WET CHEMISTRY** 11/22/13 1 11/13- 12/1- 3 1311B70-013 MW-8S Groundwater SELECT WET CHEMISTRY** 11/22/13 11/13-12/13 1311B70-014 FIELD BLANK Field Blank SELECT WET CHEMISTRY** l 11/22/13 11/13-12/1 I ** Alkalinity,Total(As CaCO3); Biochemical Oxygen Demand ; Bromide ;Chemical Oxygen Demand;Chloride;Hardness(As CaCO3) ; Nitrate as N ; Nitrite as N ; Nitrogen, Ammonia(As N);Nitrogen, Kjeldahl,Total;Phenolics,Total Recoverable ;Sulfate; Total Dissolved Solids ;Total Organic Carbon ; LKB008 S5 a� [d bS a gr 575-Broad P-oiow Road (331.694,, ri ,x 3a MelvOie, NY 1174 7631.420.84:?6 2. CHAIN OF CUSTODY DOCUMENTATION • LKB008 S6 MR*ab75 road Hollow Rd.,Melville,NY 11747 01 Q e EXTERNAL CHAIN OF CUSTOD)o ("631)694-3040 Fax:(631)420-8436 wCLIENT: H2M SDG NO: PROJECT NAME/NUMBER NOTES: Project Contact. Yc L a Phone Number, OR SAMPLERS:(Signature)/Client �'� -!- ; r t-Ci. L��a,wo1;1 e r � I�rl�r�- �o -� -`-•�� � � ,� � Q � � PIS/Quote# 110 NIA DELIVERABLES: 1 DF ) C�� �( r S TURNAROUND TIME: z ANALYSIS REQUESTED " co DATE TIME MATRIX FIELD I.D. LAB I.D. NO. REMARKS: -7: W M�- ►� 003 -7 a r a , ooL� S 7 ti - il -9\) 11 d1 II'.Go C)W K3 - $ 1 7 -4 II ,fit I G30 (\N' 3 "� • o 2j -4 �►�Sl II aI 11: a Reli�n} jishe by:(Signatu ) Date; Time: Received 1( ature) fDate: / tTime: LABORATORY USE ONLY l'g (l .i�) �I.�1 1112ZI! Il,0ci samples were: Relinquls d by:(Sig ature) Date: Time: Rec . ed :(Sign t ) Date: Time: 1 Shipped or Hand Delivered Airbill# II COC Tape was: � 3 1 n ` I} t i I�b 1.Present on outer package: Q" fished b . Signature) Date: Time: Received by:(Signatu Date: Time: 2.Unbroken on outer package: Y r N Relinquished by:(Signature) Date: Time: Received by. Signature Date: Time: LKB008 S7 WHITE COPY-ORIGINAL YELLOW COPY-CLIENT PINK COPY- LABORATORY N abs o 68, EXTERNAL CHAIN OF CUSTOD *75 Broad Hollow Rd.,Melville,NY 11747 -` (631)694-3040 Fax:(631)420-8436 www,h2m[abs.com CLIENT: LK H2M SDG NO: PROJECT NAME/NUMBER NOTES: Project Contact. L 1 © `, (- Gkf tic `14 3 Phone Number. E V* SAMPLERS.(Signature)/Client L ° �� � PIS1Quote# N N j DELIVERABLES: TURNAROUND TIME: o ANALYSIS REQUESTED Pin}- S(U Pow%xN_ s'�"CXX o I z �oc DATE TIME MATRIX FIELD I.D. LAB I.D. NO. REMARKS: q14\ t300 60 Mw— S a 13rr ,�� -010 It at q'3V CzW fl�dt t�-1•�� W �•►�`� Qj����\ l- 7 d+ � � 1 � `,/ r iii i (Sign.ed b (Si [(Ll: Time. Recelved b re) Date: Time; LABORATO Y USE ONLY 13 V,C)P� 'z7- Samples were: 1.Shipped^or Hand Dellvered'— Airbill# Rellnqul ad by: ignature) Date: Time: Recei d b ig a ) Date: Time: COC Tape was: ((�' Tr: 72-t3 II',o9 1.Present on outer package: 'Y, r N �1',��. Roll ish by:(Signature) Date: Time: Received by:(Signature) 2.Unbroken on outer packager�`C,Date: Time: N 'I Relinquis ed by:(Signature) ate: ime: Received by:(Signature Date: Time: WHITE COPY-ORIGINAL YELLOW COPY-CLIENT PINK COPY- LABOHMAY H2M LABS INC L KD O V 0 labs 575 Broad Hollow Road Melville,NY 11747 Sample Receipt Checklist 18 TEL:(631)694-3040 FAX:(631)420-8436 Website,Knvw.h2mlobs.com Client Name LKB Date and Time Received: 11/22/2013 11:09:00 AM Work Order Number. 1311B70 RcptNo: 1 Received by MelissaWatson Completed by: �1 - Reviewed by: G, Completed Date: 11/22/2013 Reviewed Date: 11/25/2013 10:44:57 AM Carrier name: Client Chain of custody present? Yes I No❑ Chain of custody signed when relinquished and received? Yes [./—j No❑ Chain of custody agrees with sample labels? Yes Evi No❑ Are matrices correctly identified on Chain of custody? Yes 1-/7 No❑ Is it clear what analyses were requested? Yes C No❑ Custody seals intact on sample bottles? Yes ❑ No❑ Not Present Samples in proper container/bottle? Yes W No❑ Were correct preservatives used and noted? Yes F No❑ NA ❑ Preservative added to bottles: Sample Condition? Intact Broken❑ Leaking ❑ Sufficient sample volume for indicated test? Yes No Were container labels complete(ID,Pres, Date)? Yes W No All samples received within holding time? Yes -1/1 No❑ Was an attempt made to cool the samples? Yes IV] No❑ NA ❑ All samples received at a temp.of>0`C to 6.0`C? Yes ❑ No W/1 NA ❑ Response when temperature is outside of range: Samples were collected the same day and chilled. Sample Temp.taken and recorded upon receipt? Yes C No 0 To U Water-Were bubbles absent in VOC vials? Yes ❑ No❑ No Vials Water-Was there Chlorine Present? Yes No❑ NA Water-pH acceptable upon receipt? Yes W7 No No Water n Are Samples considered acceptable? Yes [. No❑ Custody Seals present? Yes W-1 No Airbill or Sticker? Air Bil ❑' Sticker❑ Not Present Airbill No: Case Number: SDG: SAS: LKB008 Any No response should be detailed in the comments section below,if applicable. -------------------------------- Client Contacted? [ Yes EV No Person Contacted: Contact Mode: ,: Phone: ❑ Fax: ❑ Email: ❑ In Person: Client Instructions: Date Contacted: Contacted By: Regarding: Comments: CorrectiveAction: • LKB008 S9 Page I of 1 I U2M LABS, Ili. INTERNAL CHAIN OF CUSTODY CLIENT: DELIVERABLES: foD S-109 TURN AROUND TMM.- 21 1S SDG#: CASE#: MATRIX: Vim' PH CHECK 9 N REMARKS: RECEFVED BY: M r SIGNATURE: DATE: I 1"1'2'kVDAE:I V:Dl H2M LAB DATE BOTTLE 0 OF TESTS CLIENT ID 0 COLLECTED TYPE BOTTLES REQUESTED V lE . r toot o_�.►.xy-QICS��) udti �3S i '5 D 4�OJI u l�S Ott „ „ E METALS 0229 LKB008 S10 CLIENT: L-Y-5 SDG INTERNAL CHAIN OF CUSTODY SAMPLB PURPOSB OF RELINQUISHED SAMPLE BOTTLB CHANGE OF DATE TIME BY RECEIVED By CUSTODY INIT shit A. slow" Blow 3I alcW 9200 slow Slow aI QI slow a2GH SIGN BIGY SIGN aim# SIGN SIGN SIGN slow SIGH SIGN SIGH SIGN SIGN SIGH SIGN SIGH SIGN SIGs S N 3I ON SIGH SIGN �w SIGN BION t SIGN SIGN I SIGN SIGN SIGN SIGN s I GN 3 ON SIGN 3IOH SIGN 9Z 027 SIGN ' 9I GH SSGN — SIGN SIGN } • METALS LKB008 SII U2AA UAIA, INC. INTERNAL CHAIN OF CUSTODY CLIENT: L E4 DELIVERABLES: �0 5'7 OD TURN AROUND TAME: 1 D ��✓ SDG#1: L�- DO_ CASE#: MATRIX: yy pH CHECK Y�N REMARKS: RECEIVED BY: �(.V" SIGNATURE: ✓ V DATE: 112M LAB DATE BOTTLE X OF TESTS CLIENT ID COLLECTED TYPE BOTTLES REQUESTED ^^AA .'Y`W V 19� l'�f�t� J�LK W�Snn CDSr��SM, NCL'MY1 _ t y� �O P"^�;•V 4i�j-w-SM�111J3-wl MIAa�LA-0 1sE��t .►E ���`�G 3S �4D �S D an L)L- ` o n • 'VET CHEMISTRY p� LKB008 S12 00 70 i� f U2A UAUS., INC• CLIENT- L-kc INTERNAL CHAIN OF CUSTODY '. SAMPLE PURPOSE OF RELINQUISHED SAMPLE BOTTLE CHANGE OF f DATE TIME BY RECEIVED BY TYPE CUSTODY INIT ' 3Icui 9I ON elan Sfc✓- SIGN sI 1 I 3 ' ))-2-143 it10 _� cc�nc�. h�1 f00 A fKJs s s SZON Sion I 4 3 Blow _.. szGN SIG 11,330 13 r/_ s I j�3o /1 A.4 - IOL„'_ S � c Gx SIGN SIGN SIGN 9IGN SIGs 9Iox SIGN sIGN SIGN SIon IO siox s/CN SIGN BION - v SIGN 31” Sion sIOn IGN SIGN SION SIGN SIGH SIGN STM N SIGN 1 - -- lI l • WET CHEMISTRY LKB008 S13 0071. a bs 5755 Broad�40,ow Road 531.094.3(?�t :?VI'i .:�lti,•4 3. SDG NARRATIVES LKB008 S14 la bs- • 575 Broad Hollow Road tel 631.694.3040 Melville.NY 11747 fax 631.420,8436 SDG NARRATIVE FOR METALS ANALYSES SAMPLE(S) RECEIVED: 11/22/13 SDG#: LKB008 For Sample(s): MWAD MW-41) MW-613 MW-8S MW-1S MW-4S MW-6S FIELD BLANK MW-31) MW-51) MW-7S MW-3S MW-5S MW-81) r Sample(s) was/were received by H2M Labs, Inc. for select metals analysis. Samples were prepared and analyzed using EPA method 6010C with a TS ICAP 6000 Instrument. Sample MW-8S was utilized for Q.C. analysis and reporting. Spike analysis did not meet acceptance criteria for lead. The sample was post spiked,reanalyzed and recovered at 111.3%. Lead data was reported flagged"N"on fon-ns 1 and 5A. Spike analysis did not recover within 75-125% for iron. Since the sample value was greater than four times the spike concentration,post spikes and data qualifiers were not required. No other issues were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and- conditions of the contract, both technically and for completeness, for other.than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. - Date Reported: December 12, 2013 All Vincent Stancampiano Vice President • LK13008 S15 [abs 575 Broad Hollow Road tel 631.694.3040 Melville,NY 11747 fax 631.420.8436 SDG NARRATIVE FOR WET CHEMISTRY SAMPLE(S)RECEIVED: 11/22/13 SDG#: LKB008 For Sample(s): MW-1D MW-4S MW-7S MW-IS MW-51) MW-8D MW-3D MW-5S MW-8S MW-3S MW-61) Field Blank MW-413 MW-6S Sample(s) was/were received by EcoTest, a division of H2M Labs, Inc for select wet chemistry analysis. Samples were prepared and analyzed using the following methods: Alkalinity SM2320B Nitrate EPA 353.2 Anions—Cl, SO4, Br EPA 300.0 Nitrite EPA 353.2 Biochemical Oxygen Demand SM5210B Phenols EPA 420.1 Chemical Oxygen Demand EPA 410.4 Total Dissolved Solids SM2540C Ammonia EPA 350.1 Total Kjeldahl Nitrogen EPA 351.2 • Hardness SM2340C Total Organic Carbon SM5310B Sample MW-8S was utilized for Q.C. analysis and reporting. The BOD oxygen blank depletion was greater than 0.2 mg/1 (0.27 mg/1). This was noted on the final reports. The BOD duplicate analysis slightly exceeded acceptance criteria. Batch acceptance was based on LCS recovery. Due to matrix interferences samples MW-313,MW-3S, and MW-8S required a 1:10 dilution for nitrate. The reporting limit was elevated as required. The initial spike analysis did not meet acceptance criteria for nitrate. The sample was reanalyzed with the spike recovering acceptably. Samples were diluted and reanalyzed as required to keep instrument readings within calibration ranges or to minimize matrix interferences. No other issues were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: December 12, 2013 Vincent Stancampiano Vice President �KBoos s1s u4 [abs 175 1:>mad`loiiow llo«l 631.c94.3140 • Meivi€e, NY 11747 631,420.84- 36 4. SAMPLE REPORTS 4.1 METALS 4.2 WET CHEMISTRY • LKB008 S17 4 i [abs I.,mal 575,Broad�oilowRoa! ?vte;vit€8. NY'.1717 631.42-0.8436 4.1 METALS • i LKB008 S18 U2M "US, INC. • QUALIFIERS FOR METALS ANALYSIS Q (Quality Control) Qualifiers E - Serial dilution is not within acceptance criteria or the reported value is estimated because of the presence of interference. An explanatory note is included in the SDG narrative. N - Matrix spike sample recovery not within control limits. * - Duplicate analysis is not within control limits. C (Concentration) Qualifiers 6 - Entered if the reported value is less than the Contract Required Detection In Limit (CRDL) but greater than the Instrument Detection Limit (IDL). U - Entered if the analyte was analyzed for but not detected, i.e., less tl arif�10' IDL. ltd.Method) Qualifiers P - Analyzed by ICP. MS - Analyzed by ICP-MS CV- Analyzed by Manual Cold Vapor techniques. AV- Analyzed by Automated Cold Vapor techniques: C - Analyzed by Manual Spectrophotometric Method. CA- Analyzed by Midi-distillation Spectrophotometric Method. NR - Analyte not Required. .tYr LKB008 S19 U.S. EPA - CLP 1 EPA SAMPLE NO Lab Name: H2M LABS INC INORGANIC ANALYSIS DATA SHEET MW-1D Lab Code: 10478 Case No. SAS No. : SDG No.. : LKB008 Matrix (soil/water) : WATER Lab Sample ID: 1311B70-001 Level (low/med) : LOW Date Received: 11/22/2013 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. I Analyte ' Concentration C 7440-43-9 Cadmium 0 1, - P 7440-70-2 Calcium 225001 -- - P 7439-89-6 Iron -- 61.9! L - -- itt P 7439-92-1 -Lead! 13.7 h I P 7439-95-4 Magnesium 10_00 i P_ 17439-96-5 Manganese 7.2; B P 17440-09-7 Potassium_ 1180 B P 7440-23-5 Sodium 16600 P • Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Rencrted 12/9/2013 FORM I - IN LKEPAQ 1§240,1 • U.S. EPA - CLP 1 EPA SAMPLE NO Lab Name: H2M LABS INC .LNORGP.NIC ANALYSIS DATA SHEET MW-1S Lab Code: 10478 Case-'.No. SAS No. : SDG No. : LKB08 Matrix (soil/water) : WATER' Lab Sample ID: 1311B70-002 Level (low/med) : LOW Cate Received: 11/22/2013 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. Analyte Concentration , C Q M 7440-43-9 Cadmium 0.30 3 F 7440-70-2 {Calcium 5860 F j 7439-89-6 (Iron 61.9 U p 7439-92-1 Lead f 8.5 N p J 7439-95-4 Magnesium 4140T B p 7439-96-5 Manganese -- 12.0 B ;--- P 7440-09-7 Potassium 29330 B _ p 17440-23-5 Sodium_ 15.40 t --- p • Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported 12/9/2013 FORM I - IN LKBJ)gp, 1 z • U.S. EPA - CLF 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET Mw-3D i Lab Name: H2M LABS INC Lab Code:;`- 10478 Case 'No. SAS No. SDG No. ; LK3008 Matrix (s'.oil WATER Lab Sample ID: 1311B70-003 Level (low/med) : LOW Date Received: 11/22/2013 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. Analyte Concentration � Cli Q M - 7440-43-9 Cadmium 0.15101 P 7440-70-2 calcium 329001 F j 7439-89-6Iron -- 24400 P 7439-92-1 Lead - C.72jU N P 7439-95-4 Magnesium 27600 P 7439-96-5 Manganese 3160 P 7440-09-7 Potassium L 69700 P 7440-23-5 jsodium 97600 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: YELLOW Clarity After: CLEAR Artifacts: i� 4 Y: Comments Date. Reported 12/9/2013 - ORN I - IN LKB4O{J §§i _ . U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW-3S Lab Name: H2M LABS INC � Lab Coder 10478 Case No. SAS No. : SDG No. : LKB008 Matrix (soil/water) : WATER Lab Sample ID: 1311370-004 Level (low/med) : LOW Date Received: 11/22/2013 Solids: 0.0 Concentration Units (ug/L or mg/kc dry weight) : UG/L CAS �- CAS No. 1 Analyte Concentration C — --� M -i 7440_43-9 Cadmium 0.75 U P 7440-70-2 Calcium 2320�01 p 7439-89-6 Iron 6470 — ^— p - ---- ---- _— 7li 439-92-1 Lead 7.2'! II N 1,:�7439-95-4 Magnesium _ 15500 _7439-96-5 Manganese 3036 X7440-09-7 Potassium 20300' P - - 7440-23-5 ;Sodium 34700 p Color Before: COLORLESS Clarity Before: CLEAR - Texture: Color After: YELLOW Clarity After: CLErR Artifacts: Comments; Data- Reperzed 72/9/2013 --.. - - - ------------------- FORM I - IN LKEXW-,823. 1 . U.S. EPA - CLF 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET -- -- MW-4D Lab Name: H2M LABS INC Lab Coder: 10478 Case No. SAS No. : SDG No. : LKB008 Matrix (soil/water) : WATER Lab Sample ID: '_311B70-005 -evel (low/med) : LOW Date Received: 11/22/2013 Sclids: 0.0 Concentration Units (ug/L or mg/kg dry weig -) : L'G/L ; � i -M CAS No. Analyte . oncentration C 7440-43-9 Cadmium 0.15 TJ - - P 7440-70-2 ,Calcium 142000 P 7439-89-6 Iron 438, _--p 7439-92-1 Lead 13.3 N P -� 7939-95-4 [Magnesium _592001 p 7439-96-5 [Manaanese 0' 7440-09-7 Potassia_m 51800 r� 7440-23-5 Sodiun t 202000 a Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported 12/4/2013 FORAM i - IN LKB"§,S§�4 • U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW-4� Lab Name: H2M LABS INC Lab Code:: 10478 Case No. SAS No. : SDG No. : LKB008 Matrix (soil/water) : WATER Lab Sample iD: 1311B70-006 Level (low/med) : LOW Date Received: 11/22/2013 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L AS Nc. Analyte ( Concentration Ci Q M � Ij 7440-43-9 Cadmium 0.301B PJ 7440-70-2 Calcium 64200' P 7 7439-89-6 Iron 61.91 F i7439-92-1 Lead 1-21 B 144 P 7439-95-4 Magnesia-n 15300 r 7439-96-5 Manganese 5820 P 7440-09-7 Potassium 374001 P_ 44 23-5 Sodium 9550; i P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Repor-ed 12/9/2013 FORM 1 - IN LKBgq§,M.1 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET Mw-5D Lab Name: H2M LABS INC Lab Code:: 10478 'Case -No. SAS No. : SDG No. : LKB008 Matrix (soil/water) : WATER Lab Sample ID: 1311B70-007 Level (lcw/med) : LOW Date Received: 11/22/2013 Solids: 0.0 Concentration Units (ug/L or mg/kq dry weight) : UG/L ! CAS No. Analyte Concentration C Q I M ;7440-43-9 Cadmium 0.151U P X7440 70 2 Calcium 75400 P -! L7439-89-6 Iron 105 P 7439-92-1 !Lead 0.72, U ! _N P 7439-95-4 Magnesium 304001 _ P 7439-96-5 Manganese 12000 P 7440-09-7 'Potassium _ 109000, P 7440-23-5 Sodium _133000 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments Date'- Reported 12/9/2013 _ FORM 7 - IN LKBRIi. 1 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW-5S Lab Name: H2M LABS INC Lab Code:' 10478 Case No. SAS No. : SDG No. : LKB008 Matrix (soil/water) : MATER Lab Sample ID: 1311B70-008 Level (low/med) : LOVA Date Received: 1-1/22/2013 Solids: O.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L - CAS No. jAralyte ! Concentration C ` Q 7440-43-9 Cadmium 0.15 U P 7440-70-2 ICaicium 5660 PP 7439-89-6 11ron 61. 9 U ~' P 7439-92-1 Lead 8.1 --- N 7439-95-4 'Macrnesium 1 _ 3800 B , I 7439-96-5 Manganese42.0 7440-09-7 Potassium- 3420 B P 744C-23-5 Sodium 9110! P Color Before: COLORLESS Clarity Befcre: CLEAR Texture: Color Atter: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date- Reported 12/9/2013 FORM I - IN . U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET Mw-6D Lab Name: H2M LABS INC Lab Code: 10478 Case No. SAS No. : SDG No. : LKB008 Matrix (soil/water) : WATER Lab Sarp.,z) e ID: 1311B70-009 Level (-ow/med) : LOW Date Received: 11/22/2013 Solids: 0.0 Concentration Units (ug/L or mg/ka dry weight) : uG/L CAS No. Analyte Concentration Q M j _ III 1 7440-43-9 Cadmium 0.20 B P 7440-70-2 Calcium _ 32400 _ P 7439-59-6 Iron 61.9 U P 7439-92-1 Lead - 11.31 N P 7439-95-4 Magnesium i 15700i P 7439-96-5 Manganese 1100 P 17440-09-7 Potassium_ 2730 B P 17440-23-5 Soditun13400 PI • Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reperted 12/9/2013 FORM I - I N LKBQQ#j§748. 1 } • U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET r MW-6S Lab Name: H2M LABS INC Lab Code:- 10478 Case No. SAS No. : SDG No. : LKB008 Matrix (s:oil/water) :. •.WATER Lab Sample TD: 1311970-010 Level (low/med) : LOW Date Received: 11/22/2013 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : U1-/L T i CAS No. Analyte Concentration C Q ; M 7440-43-9 Cadmium 0.30 B P 7440-70-2 Calcium 19400 l p 7439-89-6 Iron - 61. 9 U P ^! 7439-92-1 Lead 7.5 i N P 7439-95-4 Magnesium 5190 P 7439-96-5 Manganese 2220, P 7440-09-7 Potassium 4300' B P 7440-23-5 Sodium 4500 B P . Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments Date Reported 12/9/2013 FORM I - IN LKBDDW899. 1 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSTS DATA SHEET �M[�-7S Lab Name: H2M LABS INC L _ Lab Code:; 10478 Case; No. SAS No. : SDG No. : LKB008 Matrix (s-oil/water) : WATER Lab Sample T-D: 13.11B70-011 Level (low/med) : LOW Date Received: 11/22/24013 % Solids: 0. 0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. I Analyte ConcentraticnQ M I � 7440-43-9 (Cadmium 0.201 B :7440-70-2 Calcium - _ 18500 P 7439-89-6 'Iron 61.9 1 j p 7439-92-1 Lead 5.9! N P 7439-95-4 Magnesium 490pjB P 739-96-5 Manganese 2090; i P 940-0 -7 Potassium 413013 P -23-540 Sodium 41301 B F i I Color Before: COLORLESS Clarity Before: CLEAR Texture: ` Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported 12/9/2013 FORM I - IN LKBPQ§4�p.1 • U.S. EPA - CLP I EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET Lab Name: H2M LABS INC MW-8D Lab Code:" 10478 Case No. SAS No. : SDG No. : LKB008 Matrix (soil/water) : WATER Lab Sample ID: 1311B70-012 Level (low/med) : LOW Date Received: 11/22/2013 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/T CAS No. _f .Analyte Concentratio7 C Q M 7440-43-9 Cadmium 0.20 B P 7440-70-2 Calcium 51400 F� ,7439-89-6 Iron 9140 F� X7439-92-i ,Lead 1i.0 1 N P ,7439-95-4 jMagnesium 25400 j 7439-96-5 Manganese 147G P 7440-09-7 Potassium — 47100 _ 1p7440-23-5 Sodium 53900 • Color Before: COLORLESS Clarity Before: CLEAR _ Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date_ Reported 12/9/2013 ORM I - IN LKBq? 1 • U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET —� MW-8S Lab Name: H2M LABS INC Lab Code:; 10478 Case No. SAS No. : SDG No. : LKB008 Matrix (soil/water) : WATER Lab. Sample ID: 1311B70-013 Leel (low/med) : LOW Date Received: 11/22/2013 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. Analyte Concentration C Q M 7440-43-9 Cadmium 0.15 U P 7440-70-2 Calcium 62E00 P +7439-89-6 Iron 51600 _ P 7439-92-1 Lead 7.2 Uj N P 7439-95-4 Magnesium 1_6000 P 7439-96-5 Manganese 816 P ` 7440-09-7 Potassium 30900 P 7440-23-5 aSodium 15500 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: YELLOW Clarity After: CLEAR Artifacts: Comments: Date Reported 12/9/2013 FORM 1 - IN LKBD . 1 U.S. EPA - CLP • I EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET -o FIELD BLANK Lab Name: H2M LABS INC Lab Coder 10478 . Case .No. SAS No. : SDG No. : LKBOOB Matrix (soil/water) : WATER Lab Sample ID: 1311B70-014 Level (low/med) : LOW !Date Received: 11/22/2013 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L ' CAS o. Analyte Concentration lC Q M t 7490-43_9 Cadmium 0.15! u --t—d P 7440-70-2 Calcium 60.9! B P 7439-89-6 Iron — 61.9iu _ I P ;7439-92-1 jLead 0.72 U N P 17439-95-4 IMagnesium 29.9 B ! -- P 7439-96-5 ;Manganese 3.2 B P 744G-G9-7 Potassium 681 B ' P 7440-23-5 Sodium 1980 U P • Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported 12/12/2013 • FORM I - IN [a bs ' 575 Broad Hollow Roar ; 410831.E94.; • Wwi<'e,NY '747 531.=20.8436 4.2 WET CHEMISTRY • LKB008 S34 __ LrO_.. EST LABORATONES A division of H2M Labs, Inc. LABORATORY RESULTS • 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL-(631)694-3040 FAX:(631)420-8436 The lab is not directly responsible for the integrity of the sample before receipt at NYSDOH 10..10478 the lab and is responsible only for the certified tests requested. LVCKWOCC i ESSiGr J 6S;-UaV, One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1311 B70-001 Type: Groundwater Attn To : John Gerlach Client Sample ID: MW-1D Collected :11/21/2013 1:45:00 PM Origin: Received :11/22/2013 11:09:00 AM Collected By CLIENT Analytical Method: SM2320B: Analvst: HT Parameters) Results Qualifier D.F. Units Analyzed: Container. Alkalinity,Total(As CaCO3) 28.4 1 mg/L 11/27/2013 11:49 AM Container-91 of 02 Analytical Method: E300.0: Analyst: bka Parameters) Results Qualifier D.F. Units Analyzed: Container: Bromide <0.50 1 mg/L 12/06/2013 1:49 AM Container-01 of 02 Chloride 23.4 1 mg/L 12;06!2013 1:49 AM Container-01 of 02 Sulfate 58.5 D 5 mg/L 12/06.;2013 2:29 AM Container-01 of 02 Analytical Method: SM5210B: Prep Method: SM5210B Prep Date: 11/22/2013 9:34:26 AM Analyst: CN Parameters) Results Qualifier D.F. Units Analyzed: Container. Biochemical Oxygen Demand <2 1 mg/L 11/22/2013 Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.27 mg/L Analytical Method: E410.4: Analyst: CN Parameter(s) Results Qualifier D. Units Analyzed: Container: • Chemical Oxygen Demand <10 1 mg/L 12103/2013 8:21 AM Container-01 of 01 Analytical Method: SM234OC: Analyst HT Parameters) Results Qualifier D.F. Units Analyzed: Container. Hardness(As CaCO3) 108 D 4 mg/L 12103!2013 11:20 PM Container-01 of 01 Analytical Method: SM4500-NH3 H: Analyst: JA Parameter(s) Results Qualifier D.F.. Units Analyzed: Container. Nitrogen,Ammonia(As N) <0.10 1 mg/L 12/05x2013 3:09 PM Container-01 of 01 Analytical Method: E353.2: Analyst EM Parameterls) Results Qualifier D.F. Units Analyzed: Container. Nitrite as N <0.10 1 mg/L 11123/2013 7:45 AM Container-01 of 02 Analytical Method: E353.2: Analyst: EM Parameterls) Results Qualifier D.F. Units Analyzed: Container: Nitrate as N 3.48 D 10 mg/L 11/2312013 8:40 AM Container-01 of 01 Analytical Method: E420.1: Preo Method: E420.1 Prep Date: 12/4/2013 8:00:00 AM Analyst: EM Parameterls) Results Qualifier D. Units Analyzed: Container: Phenolics,Total Recoverable <5.0 1 P91L 12/05/2013 7:22 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. Clew B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Laboratory Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte • r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 1 of 28 LKB008 S35 Ec'oTEST LABORATOR' IES. A division of H2M Labs,Inc. LABORATORY RESULTS 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)654-3040 FAX:(631)420-8436 NYSDOH IDM10478 The lab is not directly responsible for the integrity of the sample be`ore receipt at the lab and is responsible onlyfor the certified test requested. One Aerial Way M Sample Information: Lab No. : 1311 B70-001 Type: Groundwater Syosset,NY 11791 Client Sample ID: MW-1D Attn To : John Gerlach Collected :11/21/2013 1:45:00 PM Origin: Received :11122/2013 11:09:00 AM Collected By CLIENT Analytical Method: SM254OC:IOC Analyst MLM Parameteris) Results Qualifier D.F. Units Analyzed: Container. Total Dissolved Solids 228 1 mg/L 11,26/2013 2:06 PM Container-01 of 02 Analytical Method: E351.2: Preo Method: E351.2 Prep Date: 12/4!2013 5:00:00 AM Analyst: TF Parameters) Results Qualifier D.F. Units Analyzed: Container. Nitrogen,Kjeldahl,Total <0.10 1 mg/L 12!04/2013 12:56 PM Container-01 of 01 Analytical Method: SM5310B: Analyst CO Parameters) Results Qualifier D.F. Units Analyzed: Container. Total Organic Carbon <1.0 1 mg/L 12/06/2013 1:55 PM Container-01 of 02 • Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Receivedlanalyzed outside of analytical holding time Laboratory Manager +=ELAP i NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 2 of 28 LKB008 S36 Ec7rgsT LA86R'AT-ORIES A division of H2A4 Labs,Inc. LABORATORY RESULTS 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL:(631)694-3040 FAX-(631)420-8438 NYSDOH 10#10478 The lab isnot directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. LOCKWO00 AOSSior a Ma7zi@7k One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1311 B70-002 Type: Groundwater Attn To John Gerlach Client Sample ID: MW-1S Collected 1:11/21/2013 2:30:00 PM Origin: Received `'11/22/2013 11:09:00 AM Collected By CLIENT Analytical Method: SM23208: Analyst HT Parameter(s) Results Qualifier D. Units Analyzed: Container. Alkalinity,Total(As CaCO3) 5.95 1 mg/L 11/27/2013 11:59 AM Container-01 of 02 Analytical Method: E300.0: Analyst bka Parameters) Results Qualifier D.F. Units Analyzed: Container: Bromide <0.50 1 mg/L 12/0612013 2:43 AM Container-01 of 02 Chloride 37.7 1 mg1L 12106!2013 2:43 AM Container-01 of 02 Sulfate 16.0 1 mg/L 12/0Er2013 2:43 AM Container-01 of 02 Analytical Method: SM521OB: Prep Method: SM5210B Prep Date: 1/2212013 9:34:26 AM Analyst; CN Parameters) Results Qualifier D.F. Units AnaNzed: Container: Biochemical Oxygen Demand <2 1 mg/L 1112212013 Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.27 mg/L Analytical Method: E410.4: Analyst CN Parameter(s) Results Qualifier D. Units Analyzed: Container: Chemical Oxygen Demand <10 1 mg/L 12/03/2013 8:23 AM Container-01 of 01 Analytical Method: SM234OC: Analyst: HT Parameters) Results ualifier D. Units Analyzed: Container: Hardness(At CaCO3) 36 D 2 mg/L 12/03/2013 11:20 PM Container-01 of 01 Analytical Method: SM4500-NW H: Analys JA Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrogen,Ammonia(As N) <0.10 1 mg/L 12/05/2013 3:10 PM Container-01 of 01 Analytical Method: E353.2: Analyst; EM Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrite as N E` <0.10 1 mg/L 11/23/2013 7:46 AM Container-01 of 02 Anaf t cal Method: E353.2: Analyst: EM Parameters') Results Qualifier D.F. Units Analyzed: Container. Nitrate as Wz. 0.60 1 mg/L 11/2312013 8:41 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date: 1214/20',3 8:00:00 AM Anal EM Parameter() Results Qualifier D.F.. Units Analyzed: Container: Phenolics,T`Ptal Recoverable z 5.0. 1 Ng/L 12/05/2013 7:23 AM Container-01 of 01 Qualifiers: E-Value above quantitation range,Value estimated. B;";:Found in Blank D.F.=Dilution Factor D=Results for Dilution H:-Received/analyzed outside of analytical holding time Laboratory Manager +=ELAP I NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte • r ,Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-.below calibration range unless otherwise noted. S r Recovery exceeded control limits for this analyte This report steall not be reproduced except in full, N Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 3 of 28 LKB008 S37 "CO EST L480RA TORIES A division of H2M Labs,Inc. LABORATORY RESULTS . 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL:(681)694-3040 FAX:(631)420-8436 NYSDOH ID#10478 The tab Is not directly responsible for the integrity of the sample before receipt at the lab and is responsible onfy for the certified tests requested. One Aerial Way Vu Sample Information: Syosset,NY 11791 Lab No. : 1311 B70-002 Type: Groundwater Attn To John Gerlach Client Sample ID: MW-JS Collected 11/21/2013 2:30:00 PM, Origin: Received r 11/22/201311:09:00 AM Collected By CLIENT Anahbcal Method• SM254OC:10C Analvst: MLM Parameters} Results Qualifier D_FUnits Analyzed: Corsi:Ir. Total Dissolved Solids 136 1 mg/L 11126/2013 2:09 PM Container-01 of 02 Analytical Method: E351.2: Preo Method: E351.2 Prep Date: 12/4,2013 5:00:00 AM Analyst: TF Parameterls} Results QualifierD_F. Units Anal vied: Container: Nitrogen,Kjeldahl,Total <0.10 1 mg/L 12/04/2013 12:56 PM Container-01 of 01 AnaH4ical Method, SM531OB: Analyst: CO Parameterls} Results Qualifier D.F. Units Analyzed: Container. Total Organic Carbon <1.0 1 mg/L 12/06/2013 2:17 PM Container-01 of 02 • Qualifiers: E t Value above quantitation range,Value estimated. B=Found in Blank Qixir. 11I D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time +=ELAP/NELAC does not offer certification for this analyte Laboratory Manager c=Calibration acceptability criteria exceeded for this analyte • r=`Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted_ S=Recovery exceeded control limits for this analyte� This report shall not be reproduced except in foil, N Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013: Page 4 of 28 LKB008 S38 Ec'oTEST LA60RATORIES A division of H2M Labs,Inc. LABORATORY RESULTS 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX(631)420-8436 NYSDOH 10#10478 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. One Aerial Way Sample Information: Lab No. : 1311 B70-003 Syosset,NY 11791 Type: Groundwater Attn To John Gerlach Client Sample ID: MW-3D Collected 11/21/2013 7:30:00 AM_ Origin: Received 11/22/2013 11:09:00 AM Collected By CLIENT Analytical Method: SM2320B: Analyst: HT Parameters} Results Qualifier D. Units Analyzed: Container: Alkalinity,Total(As CaCO3) 476 D 10 mg/L I Ii27f2013 12:04 PM Container-01 of 02 Analytical Method: E300.0: Analyst: bka Parameters} Results Qualifier D_F. Units Analyzed: Container. Bromide <0.50 1 mg/L 12/0612013 2:56 AM Container-01 of 02 Chloride 131 D 5 mg/L 12/06/2013 3:10 AM Container-01 of 02 Sulfate 34.8 1 mg/L 12/06/2013 2:56 AM Container-01 of 02 Analytical Method: SM521OB: Prep Method: SM5210B Prep Date: 11/22/2013 9:34:26 AM Analyst: CN Parameters} Results Qualifier D_F. Units Anarvzed: Container: Biochemical Oxygen Demand <2 1 mg/L 11/22,*2013 Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.27 mg/L Analytical Method: E410.4: Anal CN • Parameters} Results Qualifier D. Units Analyzed: Container: Chemical Oxygen Demand 51.5 1 mg/L 12/03/2013 8:25 AM Container-01 of Ot Analytic al h4ethod: SM234OC: Analyst: HT Parameters) Results Qualifier D_F. Units Analyzed' Cor>tain H Hardness(As.CaCO3) 250 D 10 mg/L 12/03/2013 11:20 PM Container-01 of 01 Analytical Method: 'SM450D-NH3 H Analyst JA Parameters} Results Qualifier D. Units Analwed: Container: Nitrogen,Ammonia(As N).. 66.0 D 50 mg/L 12/05/2013 3:11 PM Container 01 of 01 Analytical Method:. E353.2: Analyst EM Parameters} Results Qualifier D. Units Anafy2ed: Container: Nitrite as N <0.10 1 mg/L 1112312013 7:47 AM Container-01 of 02 Analytical Method: E353.2: Analyst: EM Parameters} Results Qualifier D_F. Units Anal : Container, Nitrate as N <1.00 D 10 mgR 11/23/2013 8:46 AM Cordainer-0t of 01 Analytical Method: E420.1: Preo Method: E420.1 Prep Date 12/412013 8:00:00 AM Analyst: EM Parameters} Results Qualifier D_F. Units Analyzed: Container Phenolics,Total Recoverable <5.0 1 pg/L 12105;2013 7:24 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. yy B=Found in Blank a ,. D.F.=Dilution Factor D=Results for Dilution H Received/analyzed outside of analytical holding time +=ELAP/NELAC does not offer certification for this analyte Laboratory Manager c=Calibration acceptability criteria exceeded for this analyte . r Reporting limit>MDCand<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory- Date Reported: 12/27/2013 Page 5 of 28 LKB008 S39 + A" EST LABORATORIES A division of H2M Labs,Inc- LABORATORY RESULTS 575 Broad Hollow Road, Melville.NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX:(631)420-8436 NYSDOH 1091,0478 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1311 B70-003 Type: Groundwater Attn To John Gerlach Client Sample ID: MW-3D Collected z 11/21/2013 7:30:00 AM Origin: Received :11/22/2013 11:09:00 AM Collected By"CLIENT AnatOcal Method: SM2540C:IOC Analyst: MLM Parameterls) Results QualifierD_F. Units Analyzed: Container Total Dissolved Solids 676 D 2 mg/L 11/26/2013 2:12 PM Container-01 of 02 Analytical Method: E351.2: Prep Method: E351.2 Prep Date:1214120135:00:00 AM Analyst: TF Parameterfsi Results Qualifier D. Units Analyzed: Container: Nitrogen,Kjeldahl,Total 70.9 D 20 mg/L 12/04/2013 12:57 PM Container-01 of 01 Analytical Method: SM531OB: Analyst CO Parameter(s) ResultsQualifier L. Units Ana!yzed: Container: Total Organic Carbon 18.8 1 mg/L 12/06,12013 2:39 PM Container-01 of 02 • Qualifiers: E=Value above quantitation range,Value estimated. y B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H Received/analyzed outside of analytical holding time Laboratory Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 6 of 28 LK6008 S40 00" EST 86 A T0R1E A division of N2M Labs,Inc. LABORATORY RESULTS 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX(631)420-8436 NYSDOH ID#10478 The tab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. LOCK-1,ro03 One Aerial Way Sample Information: Lab No. : 1311 B70-004 Syosset,NY 11791 Type: Groundwater Attn To : . John Gerlach Client Sample ID: MW-3S Collected >11/21/2013 8:15:00 AM Origin: Received ':11122/2013 11.09:00 AM Collected By CLIENT Analytical Method: SN12320B: Analyst HT Parameterfs) Results Qualifier D. Units Analyzed: Container Alkalinity,Total(As CaCO3) 203 D 10 mgfL 11/27/2013 12:11 PM Container-01 of 02 Analytical Method: E300.0: Analyst: bka Parameterfs) Results Qualifier D. Units Analyzed: Container. Bromide <0.50 1 mg/L 12/06,2013 3:23 AM Container-01 of 02 Chloride 70.0 D 5 mg/L 12/06/2013 3:37 AM Container-01 of D2 Sulfate 38.9 1 mg/L 12/06/2013 3:23 AM Container-01 of 02 Analytical Method: SM521OB: Preo Method: SM5210B Preo Date:11/22/2013 9:34:26 AM Analyst: CN Parameterfs) Results Qualifier D.F. Units Analyzed: Container: Biochemical Oxygen Demand 5 1 mg/L 11/22/2013 Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.27 mg/L Analytical tvlethod: E410.4: Analyst: CN • Parameterfs) Results Qualifier D. Units Analyzed: Container. Chemical Oxygen Demand 31.4 1 mg/L 12/03/2013 8:27 AM Container-01 of 01 Analytical Method: SM2340C: Analyst: HT Parameterfs) Results Qualifier D_F. Units Analyzed: Container. Hardness(As CaCO3) 170 D 10 mg/L 12/03/2013 11:20 PM Container-01 of 01 Analytical Method, SM4500-NH3 H: Analyst: JA Parameterfs) Results Qualifier D. Units Analyzed: Container. Nitrogen,Ammonia(As N) 17.0 D 10 mg/L 12/05/2013 3:12 PM Container-01 of 01 Analytical Method: E3532: Analyst: EM Parameterfs) Results Qualifier D.F.. Units Analyzed: Container: Nitrite as N <0.10 1 mg/L 1/23/2013 7:48 AM Container-01 of 02 Analytical Method: E353.2: Analyst: EM Parameterfs) 'Results Qualifier D_F. Units Analyzed: Container: Nitrate as N:. <1.00 D 10 mg/L 11/23/2013 8:47 AM Container-01 of 01 Anelvtical Method: E-420.1: Preo Method: E420.1 Preo Date: '214/2013 8:00:OD AM Anal EM Parameter(s) Results Qualifier D. Units Artalvzed: Oontainer Phenolics,Total Recoverable <5.0 1 pg/L 12105/2013 7:25 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. B Found in Blank D.F.=Dilution Factor D=Results for Dilution H Received/analyzed outside of analytical holding time Laboratory Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J Estimated value-below,calibration range unless otherwise noted. S r Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 7 of 28 LKB008 S41 _ c0 .EST .iLM6T0; RIES A division of H2M tabs,inc. LABORATORY RESULTS 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX(631)420-8436 NYSDOH IDg10478 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. LOC"VOCu One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1311 B70-004 Type: Groundwater Attn To John Gerlach Client Sample ID: MW-3S Collected ,_:11/2112013 8:15:00 AM Origin: Received :11/22/2013 11:09:00 AM Collected By CLIENT Analytical Method: SM254OC:IOC Analyst: MLWI Parameterfs) Results Qualifier D.F.. Units Analyzed: Container: Total Dissolved Solids 387 1 mg/L 11/26/2013 2:15 PM Container-01 of 02 Analytical Method: E351.2: Prep Method: E351.2 Prep Date: 12/4/2013 5:00:00 AM Analyst TF Parameterfs) Results Qualifier D.F.. Units Analyzed: Container. Nitrogen,Kjeldahl,Total 18.8 D 10 mg/L 12/04/20131:40 PM Container-01 of01 Analytical Method: SM5310B: Analyst: CO Parameterfs) Results Qualifier D.F.. Units Analyzed: Container. Total Organic Carbon 7.7 1 mg/L 12/06/2013 3:01 PM Container-01 of 02 i Qualifiers: E'=Value above quantitation range,Value estimated. B:=Found in Blank all, Ott D:F. =Dilution Factor D=Results for Dilution H'=Received/analyzed outside of analytical holding time Laboratory Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S.=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 8 of 28 LKI3008 S42 CCOIEST LABORATORIES Adivision ofH2MLabs,Inc. LABORATORY RESULTS 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX-(631)420-8436 NYSDOH iD#10478 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. LOCKWOOu r\GSSiGr&Gar.i&:a One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1311 B70-005 Type: Groundwater Attn To John Gerlach Client Sample ID: MW-4D Collected :11/2112013 10:00:00 AM Origin: Received `:11/22/201311:0900 AM Collected By CLIENT Analytical Method: SM2320B: Analyst: HT Parameters) Results Qualifier D. Units Analyzed: Container: Alkalinity,Total(As CaCO3) 663 D 10 mg/L 11/2712013 12:19 PM Container-01 of 02 Analytical Method: E300.0: Analyst: bka Parameters) Results Qualifier D. Units Anahzed: Container. Bromide <0.50 1 mg/L 12/06/2013 3:50 AM Container-01 of 02 Chloride 330 D 10 mg/L 12106.x2013 4:04 AM Container-01 of 02 Sulfate 62.0 D 10 mg/L 12106/2013 4:04 AM Container-01 of 02 Analvtical Method: SM521OB: Prep Method: SM5210B Prep Date:11/22/2013 9:34:26 AM Analyst: CN Parameters) Results Qualifier D_F. Units Analyzed: Container: Biochemical Oxygen Demand <2 1 mg/L 11/22/2013 Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.27 mg/L Analytical Method: E410.4: Analyst: CN Parameters) Results Qualifier D.F. Units Analyzed: Container: Chemical Oxygen Demand 56.8 1 mg/L '003/2013 8:29 AM Container-01 of 01 AnalAical Method: SM234OC: Analyst HT Parameters) Results Qualifier D.F.. Units Analvzed: Container: Hardness(As CaCO3) 650 D 10 mg/L 12/03/2013 1120 PM Container-01 of 01 Analytical Method: SM4500-NH3 H: Analyst: JA Parameters) Results Qualifier D.F.. Units Analyzed: Container Nitrogen,Ammonia(As N) 26.2 D 20 mg/L 12x05!2013 3:13 PM Container-01 of 01 Adalvtical Method: E3532: Analyst EM Parameters) Results Qualifier D.F.. Units AraWed: Container. Nitrite as N. <0.10 1 mg/L 11/23!2013 7:49 AM Container-01 of 02 Analytical Method: E353.2: Analyst: EM Parameters) Results Qualifier D.F.. Units Analyzed: Container: Nitrate as tit; <0,10 1 mg/L 11/23/2013 8:48 AM Container-01 of 01 Analytical Method: E420..1: . Preo P4ethod: E420.1 Prep Date: 12/4.x2013 8:00:00 AM Analyst: EM Parameters) Results Qualifier D_F. Units Analyzed: Container. Phenolics,Total Recoverable <5.0 1 pg/L 12,05/2013 7:26 AM Cont2iner-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. y B.=Found in Blank t2�x�► fii[ 'w'"-� D,F.=Dilution Factor D=Results for Dilution H Receivedlanalyzed outside of analytical holding time Laboratory Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S'=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 4 of 28 LKB008 S43 EFT k-i-A TORI A division of H2M Labs,Inc. LABORATORY RESULTS 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL:(631)694-3040 FAX:(631)420-8436 NYSDOH 1D*10478 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1311 B70-005 Type: Groundwater Attn To :: John Gerlach Client Sample ID: MW-4D Collected :11/21/201310:00:00AM _ Origin: Received :11/22/2013 11:09:00 AM _ Collected By CLIENT Analytical Method: SM2540C:IOC Analyst. MLM Parameters) Results Qualifier D_F. Units Analyzed: Container. Total Dissolved Solids 1,360 D 2 mg/L 11/2612013 2:18 PM Container-01 of 02 Analytical Method: E351.2: Prep Method: E351.2 Preo Date: 1 214/201 3 5:00:00 AM Analyst TF Parameters) Results Qualifier D.F.. Units Analyzed: Container Nitrogen,Kjeldahl,Total 28.4 D 10 mg/L 12104,2013 12:59 PM Container-01 of 01 Analytical Method: SM5310B: Analyst CO Parameters) Results Qualifier D.F.. Units Ana ed: Container: Total Organic Carbon 21.9 1 mg/L 12/06/2013 3:23 PM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. y B=Found in Blank . . a,-,, !1[ AU-11-- D.F.=Dilution Factor D=Results for Dilution H'=Received/analyzed outside of analytical holding time Laboratory Manager +=ELAP I NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit -MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S.=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N-Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 10 of 28 LKB008 S44 65 m LABORATORIES, A division of H21vf Labs,Inc. LABORATORY RESULTS 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX-(631)420-8436 NYSDOH ID#10478 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. LOCwwoou r assi'cr&tsarrziazz Sample Information: One Aerial Way Lab No. . 1311 B70-006 Syosset,NY 11791 Type: Groundwater Attn To : Jahn Gerlach Client Sample ID: MW-4S Collected ,11/21/2013 10:30;00 AM Origin: Received :11/2212013.11:09:00 AM Collected By CLIENT Analvtical Method: SM2320B: Analyst: HT Parameters) Results Qualifier D. Units Analyzed: Container: Alkalinity,Total(As CaCO3) 176 D 4 mg/L 11/27/2013 12:28 PM Container-01 of 02 Analytical Method: E300.0: Anal bka Parameterfs) Results Qualifier D.F.. Units Ana ed: Container. Bromide <0.50 1 mg/L '2/0612013 4:17 AM Container-01 of 02 Chloride 14.0 1 mg/L 12/06/2013 4:17 AM Container-01 of 02 Sulfate 39.0 1 mg/L 12/06/2013 4:17 AM Container-01 of 02 Analytical Method: SM521OB: Prep Method: SM5210B Prep Date:11/22/2013 9:34:26 AM Analyst: CN Parameters) Results Qualifier D-F. Units Analyzed: Container, Biochemical Oxygen Demand <2 1 mglL 11/22/2013 Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.27 mg/L Analytical Method: E410.4: Analyst; CN • Parameter(s) Results Qualifier D. Units Analyzed: Container. Chemical Oxygen Demand 20.3 1 mg/L 12/03/2013 8:31 AM Container-01 of 01 Analytical Method: SM234OC: Analyst: HT Parametetis) Results Qualifier D.F. Units Analyzed: Container: Hardness{A CaCO3) 260 D 10 mg/L 12/03/2013 11:20 PM Container-01 of 01 Analytical Method: SM4500-NH3 H: Analyst: JA Parameter(s) Results Qualifier D.F. Units Analyzed: Container: Nitrogen,Arrimonia(As N) <0.10 1 mg/L 12/05/2013 3:15 PM Container-01 of 01 Analytical Method: E353.2: Analyst: EM Parameters) Results Qualifier D.F.. Units Analyzed: Container. Nitrite as N '- <0.10 1 mg/L 11/23/2013 7:51 AM Container-01 of 02 Analytical Method: E353.2: Analyst. EM Parameter(s) Results Qualifier D.F. Units Analyzed: Container. Nitrate as N'° 16.9 D 50 mg/L 11/23/2013 8:50 AM Container-01 of 01 Analytical Method: E420.1: : Prep Method: E420.1 Preo Date:12/4120138:00:00 AM Anal EM Parameters.) Results Qualifier D.F. Units Analyzed: Container: Phenolics,Total Recoverable -5.0 1 pg/L 12/05/2013 7:27 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank all" A D.F.=Dilution Factor D=Results for Dilution H=Receivedlanalyzed outside of analytical holding time Laboratory Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NE LAC J=Estimated value.-below calibration range unless otherv,se noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 11 of 28 LK6008 S45 EST LABORATORIES Adivision ofH2MLabs,Inc. LABORATORY RESULTS 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL:(631)694-3040 FAx:(631)420-8436 NYSDOH ID910478 The lab Is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. LOCK &OG noSSIar&Uaiiicic Sample Information: One Aerial Way Lab No. : 1311 B70-006 Syosset,NY 11791 Type: Groundwater Attn To John Gerlach Client Sample ID: MW4S Collected 11/21/2013 10:30:06 AM Origin: Received :.11/22/201311:09:00AM Collected By CLIENT Analytical Method: SM254OC:IOC Analyst: MLM Parameters) Results Qualifier D. Units Analyzed: Container: Total Dissolved Solids 453 1 mg/L 11/26/2013 2:21 PM Container-01 of 02 Analvticaf Method: E351.2: Prep Method: E351.2 Prep Date: 12/4/2013 5:00:00 AM Analyst TF Parameters) Results Qualifier D. Units Analyzed: Container. Nitrogen,Kjeldahl,Total 0.44 1 mg/L 12/04/2013 1:00 PM Container-01 of 01 Analytical Method: SM531OB: Analyst CO Parameters) Results Qualifier D. Units Analyzed: Container. Total Organic Carbon 9.5 1 mg/L 12/0612013 3:45 PM Container-01 of 02 • Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H'=Received/analyzed outside of analytical holding time Laboratory Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 12 of 28 LKB008 S46 EWEsT LABOR' AT'Wims A division of H2M tabs,Inc. LABORATORY RESULTS 575 Broad Hollow Road, Wvitle,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX:(631)420.8436 NYSDOH ID#10476 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. LOGi WOOD KcSaicr Q L161�iCll One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1311B70-007 Type: Groundwater Attn To : ;:, John Gerlach;: Client Sample ID: MW-5D Collected ;11/21/2013 9:00:00 AM Origin: Received :11/22/2013 11:09:00 AM Collected By`CLIENT Analytical Method: SM2320B: Analyst HT Parameters) Results Qualifier D.F. Units Analyzed: Container. Alkalinity,Total(As CaCO3) 714 D 10 mg/L 11/27/2013 12:36 PM Container-01 of 02 Analytical Method: E300.0: Ana!yst bka Parameters) Results Qualifier D.F.. Units Analyzed: Container. Bromide <0.50 1 mg/L 12/06/2013 4:31 AM Container-01 of 02 Chloride 187 D 10 mg/L 12106/2013 5:11 AM Container-01 of 02 Sulfate 36.6 1 mg/L 12/0612013 4:31 AM Corrtainer-01 of 02 Analvtical Method: SM5210B: Prep Method: SM52106 Prep Date:1112212C139:34:26 AM Analyst CN Parameters) Results Qualifier D.F.. Units Analyzed: Container: Biochemical Oxygen Demand <2 1 mglL 11/22/2013 Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.27 mg/L Analytical Method: E410.4: Analyst: CN • Parameter(s) Results Qualifier D_F. Units Analyzed: Container. Chemical Oxygen Demand 73.7 1 mg/L 12/03/2013 8:33 AM Container-01 of 01 Analytical Method: SM2340C: Analyst: HT Parameters) Results Qualifier D_F. Units Analyzed: Container: Hardness(A�CaCO3) 360 . D 10 mg/L 12/03/2013 11:20 PM Container-01 of 01 Analytical Method: SM4500-NH3 H: Analyst JA Parameters) Results Qualifier D. Units Analyzed: Container Nitrogen,Ammonia(As N) 91.0 D 100 mg/L 12/05/2013 3:16 PM Container-01 of 01 Ana)ytical Method: E353.2:' Analyst: EM Parameter(s) Results Qualifier D. Units AnaA¢ed: Container: Nitrite as N <0.10 1 mg/L 11123/2013 7:52 AM Container-01 of 02 Analytical Method: E353.2: Analyst EM Parameter(s:) Results Qualifier D.F. Units Analyzed: Container. Nitrate as N <0.10 1 mg/L 11/2312013 8:51 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date: 12/412013 8:00:00 AM Analyst EM Parameters) Results Qualifier D.F.. Units Analyzed: Container. Phenolics,Tota)Recoverable <5.0 1 Ng/L 1205/2013 7:28 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. B Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time. Laboratory Manager +=ELAP I NELAC does not offer certification for this analyte c_Calibration acceptability criteria exceeded for this analyte • r Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=.Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 13 of 28 LKB008 S47 COEST LABORATORIES A division of 1-f2M Labs, Inc. LABORATORY RESULTS 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX:(631)420-8436 The lab is not directly responsible for the integrity of the sample before receipt at NYSDOH IDk10478 the lab and is responsible only for the certified tests requested. LOCKWOvu F%OSSie u caiaicia One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1311 B70-007 Type: Groundwater Attn To : ;, John Gerlach Client Sample ID: MW-5D Collected 11/21/2013 9:00:00 AM Origin: Received :11/22/2013 11:09:00 AM Collected By"CLIENT Analytical Method: SM2540C:IOC Analyst: MLM Parameters) Results Qualifier D.F.. Units Analyzed: Container: Total Dissolved Solids 986 D 2 mg/L 11/26/2013 2:24 PM Container-01 of 02 Analytical Method: E351.2: Prep Method: E351.2 Prep Date:12'412013 5:00:00 AM Analyst: TF Parameters) Results Qualifier D. Units Analvzed: Container. Nitrogen,Kjeldahl,Total 93.6- D 20 mg/L 12/04/20131:01 PM Container-01 of01 Analytical Method: SM531OB: Analyst: CO Parameters) Results Qualifier D. Units Analyzed: Container. Total Organic Carbon 27.3 1 mg/L 12/06/2013 4:07 PM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. x B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Laboratory Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 14 of 28 LKB008 S48 - 0 EST LABORATORIES A division o1H2M Labs,Inc. LABORATORY RESULTS • 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX(631)420-8436 NYSDOH ID#10478 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. L0C;C o0 i t-,G5SiGr C.uat[laic One Aerial Way Sample Information: Syosset,NY 11791 Lab No. Type: 1311 B70-008 T Groundwater Attn To :p, John Gerlach Client Sample ID: MW-5S Collected :.1112112013 9:30:00 AM Origin: Received :1112212013 11:09: 0 AM Collected By CLIENT Analytical Method: SM2320B: Analyst HT Parameters) Results Qualifier D. Units Ana Zed: Container. Alkalinity,Total(As CaCO3) 20.6 1 mg/L 11/27/2013 1:01 PM Container-01 of 02 Analytical Method: E300.0: Analyst: bka Parameterfs) Results Qualifier D. Units Analyzed: Container Bromide <0.50 1 mg/L 12/06/2013 5:25 AM Container-OI of 02 Chloride 17.9 1 mg/L 12/06/2013 5:25 AM Container-01 of 02 Sulfate 8.70 1 mg/L 12(06,2013 5:25 AM Container-01 of 02 Analytical Method: SM5210B: Prep Method: SM5210B Prep Date: 11/2212013 9:34:26 AM Analyst CN Paremeter(s) Results Qualifier D.F.. Units Analyzed: Container-, Biochemical Oxygen Demand <2 1 mg/L 11/22/2013 Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.27 mg/L Analytical Method: E410.4: Analyst: CN Parameter(s) Results Qualifier D. Units Analyzed: Container: Chemical Oxygen Demand <10 1 mg/L 12/03/2013 8:35 AM Container-01 of 01 Analytical Method: SM2340C: Analyst: HT Parameters) Results Qualifier D.F.. Units Analyzed: Container. Hardness(As CaCO3) 36 _ D 2 mg/L 12/03,12013 11:20 PM Container-01 of 01 Analv5cal Method: SM4500-NH3 H: Analyst JA Parameters) Results Qualifier D.F.. Units Analyzed: Container: Nitrogen,Ammonia(As N). <0.10 1 mg/L 2/0512013 3:17 PM Container-01 of 01 Analytical Method`. E353.2: Analyst EM Parameters) Results Qualifier D.F.. Units Analyzed: Container. Nitrite as N c 0.10 1 mg/L 11/23/2013 7:53 AM Container-01 of 02 Analytical Method: E353.2: Analyst EM Parameters) Results Qualifier D. Units Analyzed: Container. Nitrate as N. 0.30 1 mg/L 11/2312013 8:52 AM Container-01 of 01 Arralytical Method. E420.1: Prep Method: E420.1 Prep Date: 12/412013 8:00:00 AM Analyst: EM Parameters) Results Qualifier D.F.. Units Analyzed. Container: Phenolics,Total Recoverable <5.0 1 pg/L 12/05/2013 7:29 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. Crgiwri `'t.l B Found in Blank' !�[ D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Laboratory Manager +`ELAP 1 NELAC does not offer certification for this analyte c=.Calibration acceptability criteria exceeded for this analyte • r-Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value below calibration range unless otherwise noted. S Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N17 Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 15 of 28 LKB008 S49 Ec""MsT LABORATORIES A division of H2M Labs,Inc. LABORATORY RESULTS 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX(631)420-8436 NYSDOH ID�10478 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. r_OW OOQ naSSic a uBiluaZ, Sample Information: One Aerial way Lab No. : 1311 B70-008 Syosset,NY 11791 Type: Groundwater Attn To : , John Gerlach Client Sample ID: MW-5S Collected : 11/21/2013 0:30:00 AM Origin: Received :11/22/201311:09:00AM Collected By CLIENT Analytical Method: SM254OC:IOC Analyst: MLM PaM eterls) Results Qualifier D.F. Units Analyzed: Container Total Dissolved Solids 101 1 mg/L 1112612013 2:27 PM Container-01 of 02 Analytical Method: E351.2: Prep Method: E351.2 Prep Date: 12/4/2013 5:00:00 AM Analyst: TF Parameterfs) Results Qualifier D.F. Units Analyzed: Container. Nitrogen,Kjeldahl,Total 0.37 1 mg/L 12/04/2013 1:02 PM Container-01 of 01 Analytical Method: SM531OB: Analvst CO Parameters} Results Qualifier D.F. Units Analyzed: Container: Total Organic Carbon 2.7 1 mg/L 12/06/2013 4:29 PM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank. D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Laboratory Manager +�ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value.-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N Indicates presumptive evidence of compound without the written approval of the laboratory. nate Reported: 12/27/2013 Page 16 of 28 LK13008 S50 CO ESQ' LABORATORIES A division ofH2M Labs,Inc. LABORATORY RESULTS • 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL:(631)694-3040 FAX:(631)420-8436 NYSDOH 01110478 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. LOC wOW iiesSiOr a�cliti�ic One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1311 B70-009 Type: Groundwater Attn To : ::. John Gerlach Client Sample ID: MW-6D Collected _11/21/201312:30:00 PM Origin: Received :11/2212013 11:09:00 AM Collected By CLIENT Analytical Method: SM232OB: Analyst: HT Parameterfs) Results Qualifier D_F. Units Analyzed: Container: Alkalinity,Total(As CaCO3) 9.95 1 mg/L 11127/2013 1:07 PM Container-01 of 02 Analytical Method: E300.0: Analyst bka Parameterfs) Results Qualifier D_F. Units Analyzed: Container: Bromide <0.50 1 mg/L 12/06/2013 5:38 AM Container-01 of 02 Chloride 40.7 1 mg/L 12106/2013 5:38 AM Container-01 of 02 Sulfate 91.0 D 10 mg/L 12/D6/2013 5:52 AM Container-01 of 02 Analytical Method: SM521OB: Prep Method: SM5210B PrevDate 11/22,!2013 9:34:26 AM Analyst. CN Parameterfs) Results Qualifier D_F. Units Analyzed: Container Biochemical Oxygen Demand 12 1 mg/L 11/22/2013 Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.27 mg/L Analytical Method: E410.4: Analyst: CN Parameter(s) Results Qualifier D. Units Analyzed: Container. Chemical Oxygen Demand <10 1 mg/L 12/03/2013 8:37 AM Container-01 of 01 Analytical Method: SM234OC: Analyst HTParameterfs} Results Qualifier D_F. Units Analyzed: Container. Hardness(A5 CaCO3) 160 D 10mg/L 12/03/2013 11:20 PM Container-01 of 01 Analytical Method: SM4500-NH3 H: PaAnalyst JA rameterfs) Results Qualifier D.F. Units AnaN2ed: Container. Nitrogen,Ammonia(As N)- <0.10 1 mg/L 12/05/2013 3:18 PM Container-01 of 01 Analytical Method: E353,2: Analyst: EM Parameterfs} Results Qualifier D_F. Units Analyzed: Container. Nitrile as N <0,10 1 mg/L 11/23/2013 7:54 AM Container-01 of 02 Analytical Method• E353.2: Analyst: EM Parameterfs) Results Qualifier D_F. Units Analyzed: Container: Nitrate as N_ 7 37 D 10 mg/L 11/23/2013 8:53 AM Container-01 of 01 Analytical Method, E420.1 Prep Method: E420.1 Prep Date: 1214/2013 8:00:00 AM Analysti EM Parameterfs) Results Qualifier D. Units Anal Container. Phenolics,Total Recoverable <5.0 1 pg/L 12/05/2013 7:30 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. y B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time +=ELAP I NELAC does not offer certification for this analyte Laboratory Manager c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12./27/2013 Page 17 of 28 LKB008 S51 EFOTEST LABORATORIES. A division of H2M Labs,Inc. LABORATORY RESULTS • 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX:(631)420-8436 NYSDOH ID#10478 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. LOCKWOo—ui i�eaSi@r ix ua.riiEu One Aerial Way Sample Information: Lab No. : 1311 B70-009 Syosset,NY 11791 Type: Groundwater Attn To John Gerlach Client Sample ID: MW-6D Collected .11/21/2013.12:30:00 PM Origin: Received :_11/22/2013 11:09:00 AM Collected By 'CLIENT Analytical Method: SM254OC:IOC Analyst: MLM Parameters) Results Qualifier D.F.. Units Analyzed- Container: Total Dissolved Solids 317 1 mg/L 11126/2013 2:30 PM Container-01 of 02 Analytical Method: E351.2: Prep Method: E351.2 Prep Date: 12/4/2013 5:00:00 AM Analyst: TF Parameters} Results Qualifier P.F.. Units Analvzed: Container: Nitrogen,Kjeldahl,Total <0.10 1 mg/L 12/04/2013 1:02 PM Container-01 of 01 Analytical Method: SM531OB: Analyst: CO Parameters} Results Qualifier D.F.. Units Analyzed: Container. Total Organic Carbon <1.0 1 mg/L 12/06/2013 4:51 PM Container-01 of 02 • Qualifiers: E=Value above quantitation range,Value estimated. y, B=Found in Blank /k a,", - D.F=Dilution Factor .D=Results for Dilution H=Received/analyzed outside of analytical holding time Laboratory Manager +=ELAP/NELAC does not offer certification for this analyte c--:.Calibration acceptability criteria exceeded for this analyte • r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J-Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 18 of 28 LK6008 S52 A division ofH2M Labs,Inc. LABORATORY RESULTS • 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX:(631)420.8436 NYSDOH 113#10478 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. Lo4R11rVOG l%esSiar a L.ar-LieiY One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1311 B70-010 Type: Groundwater Attn To John Gerlach Client Sample ID: MW-6S Collected :11/21/2013.1:00:00 PM Origin: Received :11/22/201311:09:00 AM Collected By CLIENT Analytical Method: SM232OB: Analyst HT Parameters) Results Qualifier D. Units Analyzed: Container. Alkalinity,Total(As CaCO3) 48.7 1 mg/L 11/27/2013 1:13 PM Container-01 of 02 Analytical Method: E300.0: Analyst: bka Parameter(s) Results Qualifier D_F. Units Analyzed7 Container: Bromide <0.50 1 mg/L 12/0612013 6:05 AM Container-01 of 02 Chloride 21.0 1 mg/L 12/06/2013 6:05 AM Container-01 of 02 Sulfate 7.70 1 mg/L 12106/2013 6:05 AM Container-01 of 02 Analytical Method: SM5210B: Prep Method: SM5210B Preo Date;1112212013 9:34:26 AM Analyst: CN Parameters) Results Qualifier D_F. UnitsAnalyzed: Container: Biochemical Oxygen Demand <2 1 mg/L 11/22/2013 Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.27 mg/L Analytical Method: E410.4: Analyst CN • Parameters) Results Qualifier D.F. Units Analyzed: Container. Chemical Oxygen Demand 26.2 1 mg/L 1210312013 8:39 AM Container-01 of 01 Analytical Method: SM2340C: Analyst: HT Parameters) Results Qualifier D. Units Analyzed: Container: Hardness(As CaCO3) 84 D 4 mg/L 12/03/2013 11:20 PM Container-01 of 01 Analytical Method: SM4500-NH3 H: Analyst" JA Parameters) Results Qualifier D. Units Analyzed: Container: Nitrogen,Ammonia(As N) <0.10 1 mg/L 12/05,12013 3:19 PM Container-01 of 01 Analytical Method: E353.2: _ Analyst: EM Parameters) Results Qualifier D_F. Units Analyzed: Container: Nitrite as N <0.10 1 mg/L 11/23!2013 7:55 AM Container-01 of 02 AnalOcal Method, E353.2: Analyst: EM Parameters) Results Qualifier D. Units Analyzed: Container Nitrate as N.-.- 0.68 1 mg/L 11/23/2013 9:06 AM Container-01 of 01 Analytica!Method: E420.1: Prep Method: E420.1 Prep Date: 12/4/2013 8:00:00 AM Analyst EM Parameters) Results Qualifier D. Units Analyzed: Container. Phenolics,Total Recoverable <5.0 1 pg/L 12/05/2013 7:31 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H Received/analyzed outside of analytical holding time Laboratory Manager +=ELAP I NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte . r Reporting limit>MDL and<LOQ.Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 19 of 28 LK13008 S53 Ec""OTEST LABOR' ATORIES- A division of H2M tabs,Inc. LABORATORY RESULTS . 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3640 FAX:(631)420-8436 NYSDOH ID#10478 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. L0C;iC 0C-Q f\Gb.JIG[iic oar lieu One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1311 B70-010 Type: Groundwater Attn To : John Gerlach Client Sample ID: MW-6S Collected :11/21/2013 1:00:00 PM Origin: Received :11/22/201311:09:00AM Collected By CLIENT Analytical Method: SM254OC:IOC Analyst: MLM Parameters) Results Qualifier D_F. Units Analyzed: Container. Total Dissolved Solids 165 1 mg/L 11126/2013 2:33 PM Container-01 of 02 Analytical Method: E351.2: Preo Method: E351.2 Prep Date: 12/4/2013 5:00:00 AM Analyst TF Parameters) Results Qualifier R.F.. Units Analyzed: Container Nitrogen,Kjeldahl,Total 0.74 1 mg/L 12/04/2013 1:05 PM Container-01 of 01 Analytical Method: SM531OB: Analyst CO Parameters) Results Qualifier D.F.. Units Analyzed: Container. Total Organic Carbon 10.9 1 mg/L 12/06.2013 5:57 PM Container-01 of 02 • Qualifiers: E=Value above quantitation range,Value estimated. yl B Found in Blank D.F.=Dilution Factor D=Results for Dilution H Received/analyzed outside of analytical holding time Laboratory Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte • r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 20 of 28 LKB008 S54 SUEST L480RA RIi A division of H2M Labs,Inc. LABORATORY RESULTS 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX:(631)420-8436 NYSDOH 113#10478 The lab is not directly responsible for the integrity of the sample before receipt at the lab and Is responsible only for the certified tests requested. Lockwood Kessler a BartielA One Aerial Way Sample Information: Lab No. : 1311 B70-011 Syosset,NY 11791 Type: Groundwater Attn To John Gerlach Client Sample ID: MW-7S Collected :11/2112013 12:00:00 PM Origin: Received .11/22/2013 1109:00 AM Collected By CLIENT Analytical Method: SM2320B: Analyst HT Parameteris) Results Qualifier D.F.. Units Analyzed: Container. Alkalinity,Total(As CaCO3) 49.4 1 mg1L 11/27/2013 1:21 PM Container-01 of 02 Analytical Method: E300.D: Analyst: bka Parameters) Results Qualifier D.F.. Units Analyzed: Container. Bromide <0.50 1 mg/L 12/06/2013 6:19 AM Container-01 of 02 Chloride 21.0 1 mg/L 12/06/2013 6:19 AM Container-01 of 02 Sulfate 7.70 1 mg/L 12/06!2013 6:19 AM Container-01 of 02 Analytical Method: SM521OB: Prep Method: SM5210B Prep Date: 11/22/2013 9:34:26 AM Analyst: CN Parameters) Results Qualifier D.F.. Units Analyzed: Container: Biochemical Oxygen Demand <2 1 mg/L 11/22/2013 Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.27 mg/L Analytical Method: E410.4: Analyst: CN • Parameter(s) Results Qualifier D.F.. Units Analyzed: Container: Chemical Oxygen Demand 24.9 1 mg/L 12/03/2013 8:41 AM Container-01 of 01 Analytical Method: SM2340C: Analyst FFr Parameters) Results Qualifier D.E.. Units Analyzed: Container. Hardness(As CaCO3) 80 D 2 mg/L 12/03.2013 11:20 PM Container 01 of 01 Arialytical Method: SM4500-NH3 H: Analyst: JA Parameters) Results Qualifier D.F.. Units Analyzed: Container. Nitrogen,Ammonia(As N) <0.10 1 mg/L 12/0512013 3:23 PM Container-01 of 01 Analytical Method: E353.2: Analyst: EM Parameters) Results Qualifier R.F.. Units Analyzed: Container: Nitrite as N <0.10 1 mg/L 11/23/2013 7:59 AM Container-01 of 02 Ariaivlical Method: E353.2: Analyst EM Parameter(`s) Results Qualifier D_F- Units Analyzed: Container: Nitrate as N 0.67 1 mg/L 11/23/2013 9:08 AM Container-01 of 01 An Method: E420.1: Prep Method: E420.1 Prep Date:12/4/2013 8:00:00 AM Analyst EM Parameters) Results Qualifier D.F.. Units Analyzed: Container- Phenolics, ontainerPhenolics,Total Recoverable <5.0 1 pg/L 12/05/2013 7:32 AM Container-01 of 01 Qualifiers: E.`=Value above quantitation range,Value estimated. B:=Found in Blank D.F.=Dilution Factor D=Results for Dilution H.=Receivedianalyzed outside of analytical holding time Laboratory Manager + ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte • r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value below calibration range unless otherwise noted. 5'=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N`=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 21 of 28 LKB008 S55 cO EST LAHORA TORIES A division of H2M Labs,Inc. LABORATORY RESULTS • 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX(631)420-8436 NYSDOH ID#10478 The lab isnot directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. Lockwood Kessler&BariieH One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1311 B70-011 Type: Groundwater Attn To :' John Gerlach Client Sample ID: MW-7S Collected ;:11/21/2013 12:00:00 PM Origin: Received ^1 1/22/201 3 1 1:09:00 AM _ Collected By CLIENT Analytical Method: SM254OC:IOC Analyst MLM Parameters) Results Qualifier D.F. Units Analyzed: Container: Total Dissolved Solids 177 1 mg/L 11/26/20132:36 PM Container-01 of 02 Anal4cal Method: E351.2: Preo Method: E351.2 Prep Date: 12/4/2013 5:00:00 AM Analyst- TF Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrogen,Kjeldahl,Total 0.85 1 mg/L 12/04120131:06 PM Container-01 of 01 Analytical Method: SM5310B: Analyst: CO Parameters} Results Qualifier D.F. Units Analyzed: Container. Total Organic Carbon 11.1 1 mg/L 12106/2013 6:19 PM Container-01 of 02 • Qualifiers: E Value above quantitation range,Value estimated. � p�,w,,,1 B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H F Received/analyzed outside of analytical holding time Laboratory Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte • r_Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value_below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N,=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 22 of 28 LKB008 S56 NO ESTLABORATOR. IES A division of H2M Labs,Inc. LABORATORY RESULTS 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL:(631)694-3040 FAY(631)420-8436 NYSDOH 0X10478 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only far the certified tests requested. Lockwood Kessler&Sartilett Sample Information: One Aerial Way Syosset,NY 11791 Lab No. : 1311B70-012 Type: Groundwater Attn To > John Gedach Client Sample ID: MW-81D Collected r 11/21/2013 11:00:00 AM . Origin: Received . 11/2212013 11:09:00 AM Collected By CLIENT Analytical Method: SM23203: Analyst: HT Parameters) Results Qualifier D. Units Analyzed: Container: Alkafinity,Total(As CaCO3) 301 D 10 mg/L 11/27/2013 1:28 PM Container-01 of 02 Analytical Method: E300.0: Analyst: bka Parameters) Results Qualifier D.F. Units Analyzed: Container: Bromide <0.50 1 mg/L 12/06/2013 6:32 AM Container-01 of 02 Chloride 91.5 D 5 mg/L 12/06/2013 6:46 AM Container-01 of 02 Sulfate 75.0 D 5 mg/L 12/06/2013 6:46 AM Container-01 of 02 Analytical Method: SM521OB: Prep Method: SM5210B Prep,Date:11!22/2013 9:34:26 AM Analyst: ON Parameters) Results Qualifier D.F. Units Analyzed: Container: Biochemical Oxygen Demand <2 1 mg/L 11/22/2013 Cont2iner-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.27 mg/L Analytical Method: E410.4: Analyst: ON • Parameter(s) Results Qualifier D. Units Analyzed: Container. Chemical Oxygen Demand 25.5 1 mg/L 12/03/2013 8:43 AM Container-01 of 01 Analytical Method: SM234OC: Analyst HT Parameter(s) Results Qualifier D.F. Units Analyzed: Container. Hardness(As CaCO3) 276 D 4 mg/L 12/03/2013 11:20 PM Container-01 of 01 Analytical Method: SM4500-NH3 H: Analyst JA Parameters) Results Qualifier D.F.. Units nal Contalner. Nitrogen,Arrimonia(As N) 24.2 D 20 mg/L 12/05/2013 3:24 PM Container-01 of 01 Analytical Method: E353.2: Analyst: EM Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrite as N <0.10 1 mg/L 11!23;2013 8:00 AM Container-01 of 02 Analytical Method: E353.2: Analyst EM Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrate as N ' <0.10 1 mg/L 11;2312013 9:09 AM Container-01 of 01 Analytical Method: E420.1-: Preo Method: E420.1 Prep,Date: 1214/2013 8:00:00 AM Analyst: EM Parameters) Results Qualifier D.F. Units Analyzed: Container: Phenolics,Total Recoverable <5.0 1 pg/L 12/05/2013 7:33 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. Q f B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Laboratory Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte • r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 23 of 28 LKB008 S57 EC"OMST LABORI .A. -TORIES' A division of H2M Labs,Inc. LABORATORY RESULTS 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX:(631)420-8436 NYSDOH 10#10478 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certlfied tests requested. Lock-WOW Ressier &bartiett Sample Information_: One Aerial Way Lab No. : 1311 B70-012 Type: Groundwater Syosset,NY 11791 Client Sample ID: MW-8D Attn To John Gerlach Collected ;11/21/2013 11:00:00 AM Origin: Received 11/22/2013 11:09:00 AM, Collected By CLIENT Analytical Method: SM254OC:IOC Anat s: MLM Parameters) Results Qualifier D.F. Units Analyzed: Container: Total Dissolved Solids 572 D 2 mg/L 11/26!2013 2:39 PM Container-01 of 02 Analytical Method: E351.2: Prep Method: E351.2 Preo Date: 12/4,2013 5:00:00 AM Analyst TF Parameterls) Results Qualifier D.F. Units Analvzed: Container Nitrogen,Kjeldahl,Total 26.5 D 20 mg/L 12104/2013 1:07 PM Container-01 of 01 Analytical Method: Stv15310B: Analyst: CO Parameterts) Results Qualifier D.F. Units Ana rzed: Container: Total Organic Carbon 10.4 1 mg/L 12106/2013 6:41 PM Container-01 of 02 • Qualifiers: E=Value above quantitation range,Value estimated. Qww ,�,,,�1 B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H.=Received/analyzed outside of analytical holding time Laboratory Manager +=FLAP/NELAC does not offer,certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value :below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=' Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12127/2013. Page 24 of 28 LKB008 S58 A division of H2M Labs,Inc. LABORATORY RESULTS • 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX(631)420-8436 NYSDOH ID#10478 The lab is not directly responsible for the ntegrity of the sample before receipt at the lab and is responsible only for the certified tests requested. LVVFWVVU I�CfDJiCi Ot GGI L5161t One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1311B70-013 Type: Groundwater Attn To John Gerlach Client Sample ID: MW-8S Collected ;11/21/201311:30:00 AM Origin. Received 211/22/2013 i 1:09:00 AM Collected By CLIENT Analytical Method: SM2320B: Analyst: HT Parameters) Results Qualifier D. Units Analyzed: Container. Alkalinity,Total(As CaCO3) 325 D 10 mg/L 11127/2013 2:09 PM Container-01 of 06 Analv4ical Method: E300.0: Analyst EM Parameters) Results Qualifier D. Units Analyzed: Container. Bromide <-0.50 1 mg/L 12/1012013 2:49 PM Container-01 of 06 Chloride 26.0 1 mg/L 12/1012013 2:49 PM Container-01 of 06 Sulfate 35.7 1 mg/L 12/10/2013 2:49 PM Container-01 of 06 Analytical Method SM521OB: Prep Method: SM5210B Prep Date:11/2212013 9:34:26 AM Analyst: CN Parameters) Results Qualifier D.F.. Units Analyzed: Container. Biochemical Oxygen Demand 6 1 mg/L 1112212013 Container-01 of 06 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.27 mg/L Analytical Mettwd: E410.4: Analyst: CN • Parameters) Results Qualifier D. Units Analvzed: Container: Chemical Oxygen Demand 41.1 1 mg/L 12/03/2013 8:45 AM Container-01 of 03 Analytical Method: SM234OC: Analvst HT Parameters) ResultsQualifier D.F.. Units Ana ed: Container. Hardness(As CaCO3) 248 D 4 mg/L 12/03/2013 11:20 PM Container-01 of 03 Analytical Method: SM4500-NH3 H: Anal JA Pafamete[(s - Results Qualifier D.F. Units - Analyzed: Container: Nitrogen,Ammonia(As N) 18.2 D 20 mg/L 12/0512013 3:25 PM Container-01 of 03 AnAWcal Method: E353.2: Analyst: EM Parameters) Results Qualifier D.F.. Units Analyzed: Container. Nitrite as N - <0.10 1 mg/L 11!23/2013 8:01 AM Container-01 of 06 Analytical Method: E353.2: Analyst EM Parameters) Results Qualifier D_F. Units Analyzed: Container. Nitrate as N <1.00 D 10 mg/L 11.,23/2013 9:37 AM Container-01 of 03 Analv4ical Method: -E420.1:: Preo Method, E420.1 Prep Date: 12/4/2013 8:00:00 AM Analyst EM Parameterfs) Results Qualifier D. Units Anahzed: Container: Phenolics,Total Recoverable <5.0 1 ug/L 12/05/2013 7:34 AM Container-01 of 03 Qualifiers: E=Value above quantitation range,Value estimated- B=Found in Blank Ili D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Laboratory Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte • r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12127/2013 Page 25 of 28 LKB008 S59 EST LABORATORIES A division of H2M Labs,Inc. LABORATORY RESULTS 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX-(631)420-8436 NYSDOH ID#10478 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. t_tOCKWOOa F Ea'sicr ut tip[{Cil One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1311 B70-013 Type: Groundwater Attn To John Gerlach Client Sample ID: MW-8S Collected 11/21/201311:30:00AM' Origin: Received _:11/22/201311:09:00AM Collected By CLIENT Analytical Method: SM2540C:IOC Analyst MLM Parameters) Results Qualifier D.F.. Units Analyzed: Container. Total Dissolved Solids 453 1 mg/L 11/2612013 2:42 PM Container-01 of 06 Analytical Method: E351.2: Prep Method: E351.2 Prep Date: 12/4/2013 5:00:00 AM Analyst TF Parameters) Results Qualifier DD=F. Units Analyzed: Container: Nitrogen,Kjeldahl,Total 19.5 D 10 mg/L 12/04/2013 108 PM Container-01 of 03 Analytical Method: SM531OB: Analyst CO Parameters) Results Qualifier D.F.. Units Analyzed: Container: Total Organic Carbon 12.5 1 mg/L 12/06/2013 7:03 PM Container-01 of 06 i Qualifiers: E=_Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution !! H'=Received/analyzed outside of analytical holding time Laboratory Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 26 of 28 LKB008 S60 00 EST LABORATORIES' A division ofH2M Labs, Inc. LABORATORY RESULTS . 575 Broad Hollow Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX:(631)420.8436 NYSDOH ID#10476 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. &uarjejl One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1311B70-014 Type: Field Blank Attn To John Gerlach Client Sample ID: FIELD BLANK Collected :11/21/2013 2:45:00 PM Origin: Received .:11/22/2013 11:09:00 AM Collected By CLIENT Analytical Method: SM2320B: Analyst: HT Parameterfs) Results Qualifier D.F.. Units Analyzed: Container. Alkalinity,Total(As CaCO3) <1.00 1 mg/L 11,27/2013 2:33 PM Container-01 of 02 Analytical Method: E300.0: Analyst: EM Parameters) Results Qualifier D.F.. Units Analyzed: Container: Bromide <0.50 1 mg/L 12/10/2013 3:29 PM Container-01 of 02 Chloride <2.00 1 mg/L 12/10/2013 3:29 PM Container-01 of 02 Sulfate <5.00 1 mg/L 12/10/2013 3:29 PM Container-01 of 02 Analytical Method: SM521OB: Prep Method: SM5210B Prep Date: 11/22/2013 9:34:26 AM Analyst: CN Parameters) Results Qualifier D. Units Analyzed: Container. Biochemical Oxygen Demand <2 1 mg1L 11/22/2013 Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.27 mg/L Anal+tical Method: E410.4: Analyst: CN Parameterfs) Results Qualifier D.F.. Units Analyzed- Container: • Chemical Oxygen Demand <10 1 mg/L 12/03/2013 8:51 AM Container-01 of 01 Analytical Method: SM234OC: Analyst: HT Parameterfs) Results Qualifier D.F.. Units Analyzed: Container: Hardness(As CaCO3) F 5 1 mg/L 12/03/2013 1 1:20 PM Container-01 of 01 Anslvtical Method: SM4500-NH3 H: Analyst: JA Parameters) Results Qualifier D. Units An I ze : Cordainer Nitrogen,Ammonia(As N) <0.10 1 mg/L i 2/05/2013 3:29 PM Container-01 of 01 Analvtical Method: E353.2: Analyst EM Parameter(s) Results Qualifier D.F.. Units Analyzed: Container: Nitrite as N <0.10 1 mg/L 11123/2013 8:05 AM Container-01 of 02 Analytical Method: E353.2: Arialyat EM Parameter(§) Results Qualifier D_F. Units Analyzed: Container. Nitrate as N(: <0.10 1 mg/L 11/23/2013 9:04 AM Container-01 of 01 Analvtical Method: E420:1: Prep Method: E420.1 Prep Date: 12/4/2013 8:00:00 AM Analyst: EM Parameters) Results Qualifier D. Units Analyzed: Container. Phenolics,Total Recoverable <5.0 1 pg/L 12/05/2013 7:37 AM Container-01 of 01 Qualifiers: E 'Value above quantitation range,Value estimated. B=Found in Blank !Ji D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Laboratory Manager +=ELAP/NELAC does not offer certification for this analyte G=Calibration acceptability criteria exceeded for this analyte • r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. 5=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 12/27/2013 Page 27 of 28 LKB008 S61 I MOTE T BORAT WE A division of H2M Labs,Inc. LABORATORY RESULTS • 575 Broad Ho!low Road, Melville,NY 11747 Results for the samples and analytes requested TEL(631)694-3040 FAX:(631)420.5436 NYSDOH 0#10478 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. One Aerial Way .-uu y ` Sample Information: Syosset,NY 11791 Lab No. : 1311137D-014 Type: Field Blank Attn To John Gerlach Client Sample ID: FIELD BLANK Collected :11/2112013 2:45:00 PM Origin: Received :11/22/2013 11:0.9:00 AM Collected By. CLIENT Analytical Method: SM2540C:IOC Analyst MLM Parameters) Results Qualifier D.F. Units Analvzed: Container: Total Dissolved Solids 13 1 mg/L 11/26/2013 2:51 PWA Container-01 of 02 Analytical Method: E351.2: Prep Method: E351.2 Prep Date: 1214/2013 5:00:00 AM Analyst: TF Parameters) Results Qualifier D.F.. Units Analyzed: Container: Nitrogen,Kjeldahl,Total <0.10 1 mg/L 12/04/2013 1:10 PM Container-01 of 01 AnAlvtical Method: SM531OB: Analyst: CO Parameters) Results Qualifier D.F.. Units Analyzed: Container. Total Organic Carbon <1.0 1 mg1L 12/06/2013 8:09 PM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank ""' D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Laboratory Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte • r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=_Estimated value-below calibration range unless otherwise noted. S Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory_ Date Reported: 12/27/2013 Page 28 of 28 LKB008 S62 labs 575 Broad"oilow Road 531.E�J4. C?4C) • h",esviEe. NY 1174' 03'1.420.3436 5. DUPLICATE SUMMARY RESULTS 5.1 METALS 5.2 WET CHEMISTRY • • LKB008 S63 F r- • U.S. EPA - CLP 6 EPA SAMPLE NO DUPLICATES MW-8S Lab Name: H2M LABS INC Contract: Lab Coder_ 10478 - Case_ No. SAS No. : SDG No. : LKB008 Matrix (soil/water) :' 'WATER Level (low/med) : LOW Solids for Sample: 0.0Solids for Duplicate: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L ---� -- -- _ Control FQi Analyte Limit Sample (S) C Duplicate (D) C RPD Cadmium 0. 1510 U 0.1510 U_ p Calcium _ 62630.0000 64540.0000 3.0 P iron I 51590.0000 53490.0000 3.6 P Lead 7.1838 U 7. 1838 U P Maonesi 00.0000 1 16010.0000 16570.0000 3.4 P Manganese 816.4000 _ 840.5000 2. 9 P Potassium 30940.0000 31160.0000 0.7 P Sodium ;5000. 00001 15470. 00001 16080. 0000 3. 9 P � i c FORM VI - IN ILM04 . 1 LKB008 S64 H2M LABS :INC nate: 11- -13 QC SUMMARY REPO I tT SDG: LKB008 Spike Sample Recovery RPDRef.., %RPD Sample ID: -Analyte Result Units Amount Result %REC Limits Value %RPD UCL -_ Client Sample Ip• _-_- _ - ---_ _--____-- MB-1 1271.3 ------ Alkalinity,Total(As CaCO3) < 1 MG/L LCS-112713 LCS-112713 Alkalinity,Total(As CaCO3) 23.1 MG/L 25 <1 92 80 120 1311B70-013AMS. MW=8SMS Alkalinity,Total(As CaCO3) -- 548 MG/L 250 325 89 75 125 1311B70-013ADUP MW-8SDUP Alkalinity,Total(As CaCO3) 320 MG/L 325 1.6 20 MB-42288 !MB-42288 Biochemical Oxygen xygen Demand <2 MG/L LCS-4_2288 �LCS-42288 _ — Biochemical Oxygen Demand 203 MG/L 198 <2 103 85 116 1311B70-013ADUP !MW-8SDUP- T Biochemical Oxygen Demand 3 MG/L 6 59.8 20 MB-121013 SMB-121013 Bromide <0.5 MG/L LCS-121013 LCS-121013 Bromide 2.48 MG/L 2.5 <0.5 99 90 110 1311 B70-013AMS MW-8SMS Bromide 1.03 MG/L 1 <0.5 I 98 80 120 �1311B70-013ADUP _LW-8SDUP -_^ Bromide <0.5 MG/L <0.5 20 MB-120513__ _MB-120513 Bromide <0.5 MG/L ILCS-120513 � LCS-120513 TBromide _ 2.60 MG/L 2.5+e.—0,5 104 90 110 — MB-120313 MB-120313 Chemical Oxygen Demand < 10 MG/L LCS-120313 LCS-120313 Chemical Oxygen Demand — 101 MG/L 100 <10 101 90 110 11311B70-013BMS MW-8SMS Chemical Oxygen Demand 150 MG/L 100 41.1 109 90 110 1311B70-0138DUP MW-8SDUP Chemical Oxygen Demand 41.1 MG/L 41.1 20 MB-120513 M12 B- 0513 Chloride <2 MG/L LCS-120513 L. 120513 Chloride 90 11101 LKB008 S65 1 QC SUMMARY REPOIff SDG: LKB008 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB 1211713 MB-121013, •. Chloride 2 MG/L- -- __^ --- L' CS 121013 LCS-121013 Chloride 9.12 MG/L 10 <2 91 90 110 - --- - 11311B70-013AMS MW-88MS Chloride 35.7 MG/L 10 T 26.0 97 80 120 .113 11370-013ADUP MW-8SDUP Chloride 25.9 MG/L 26.0 0.39 20 MB-120313 MB-120313 Hardness(As CaCO3) <5 MG/L LCS-120313 LCS-120313 Hardness(As CaCO3) 990 MG/L 1000 <5 99 80 120 1311 B70-013DMS MW-8SMS Hardness(As CaCO3) 664 MG/L 400 248 104 75 125 1311 B70-013DDUP MW-8SDUP Hardness(As CaCO3) 248 MG/L 248 20 (MBa-112313 jMBa-112313 Nitrate as N <0.1 MG/L ILCSa-112313 ILCSa-112313 Nitrate as N 1.09 MG/L 1.13 <0.1 96 90 110 13� 11B70-013BMS 1311B70-013BMS Nitrate as N 4.84 MG/L 5 <1 97 90 110 L1311870-013BDUP 11311B70-013BDUP Nitrate as N <1 MG/L < 1 20 MB 112313 MB-112313 Nitrate as N <0.1 MG/L LCS 112313 LCS-112313 INitrate as N 1.10 MG/L 1.13 <0.1 97 j 901101 MB-112313 MB-112313 Nitrite as N <0.1 MG/L LCS-112313 LCS-112313 Nitrite as N 1.02 MG/L 1 <0.1 102 90 110 1311B70-013AMS MW-8SMS Nitrite as N 0.45 MG/L 0.5 1 <0.1 90 90 110 1311670-013ADUP MW-8SDUP Nitrite as N <0.1 MG/L <0.1 20 MB1-120513 MB1-120513 Nitrogen,Ammonia(As N) <0.1 MG/L LCS1-120513 LCS1-120513 Nitrogen,Ammonia(As N) 1.09 MG/L 1 <0.1 109 90 110 1311B70-0136MS MW-8SMS Nitrogen,Ammonia(As N) 28.2 MG/L 10 18.2 100 75 125 1311B70-013BDUP MW-8SDUP Nitrogen,Ammonia(As N) 18.0 MG/L 18.2 1.1 20 LKB008 S66 2 QC SUMMARY REPOJ:IT SDG: LKB008 Spike Sample Recovery RPDRef,,. ',',RPD Sample IDc Client Sample IDT Analyte Result Units Amount Result'%REC Limits Value %oRPD UCL MB42394 MB-42394 Nit rogen,.Kjeldahl,Total <0.1 MG/L LCS-42394 LCS-42394 Nitrogen, Kjeldahl,Total 4.38 MG/L 4 <0.1. 110 90 110 F1311B70-013BMS MW-8SMS Nifrogen_, Kjeldahl,Total 22.8 MG/L 4 19.5 83 75 125 X1311 670-013BDUP MW-BSDUP Nitrogen, Kjeldahl,Total 19.9 MG/L 19.5 2.2 20 W13-42397 MB-42397 Phenolics,Total Recoverable <5 UG/L — LCS-42397 LCS-42397 Phenolics,Total Recoverable 26.8 UG/L 30 <5 89 80 120 11311 B70-0136MS MW-8SMS Phenolics,Total Recoverable 20.5 UG/L 20 <5 103 75 125 1311870-0136DUP MW-BSDUP Phenolics,Total Recoverable <5 UG/L <5 20 MB-120513 MB-120513 Sulfate <5 MG/L LCS-120513 ILCS-120513 Sulfate 9.80 MG/L 10 <5 98 90 11101 MB-121013 MB-121013 _ Sulfate <5 MG/L — LCS-121013 LCS-121013 Sulfate 9.51 MG/L 10 <5 95 90 110 1311B70-013AMS MW-8SMS Sulfate 46.4 MG/L 10 35.7 107 80 120 1311B70-013ADUP MW-BSDUP _Sulfate — 35.4 MG/L _� 35.7 0.84 20 MB-112613 MB-112613 Total Dissolved Solids < 10 MG/L LCS-112613 LCS-112613 Total Dissolved Solids_ 298 MG/L 300 <1D 1 99 80 120 1311B70-013AMS W 8SMS — Total Dissolved Solids 727 MG/L 300 453 91 75 125 1311B70-013ADUP IMW-BSDUP Total Dissolved Solids 442 MG/L 453 2.5 20 MB-120613 MB-120613 Total Organic Carbon <1 MG/L LCS-120613 LCS-120613 Total Organic Carbon 27.4 MG/L 25 <1 110 80 120 1311670-013CMS __ MW-8SMS Total Organic Carbon 21.5 MG/L 10 12.5 90 75 125 1311 B70-013CDUP MW-8SDUP Total Organic Carbon 12.7 MG/L 12.5 1.5 20 LKB008 S67 3 rrs �M :ASF labs 3 575 Broad HcOow Ro�-,:3 631.E?4.3)uC NY 1174-, 63i A20.8436 43u 6 SPIKE SAMPLE RESULTS 6.1 METALS 6.2 WET CHEMISTRY LKB008 S68 U.S. EPA - CLP 5A EPA SAMPLE NO SPIKE SAMPLE RECOVERY Lab Name: H2M LABS INC Contract: MW-8SS Lab Code: 10478 Case No. SAS No. : SDG No. : LKB008 Matrix (soil/water) : WATER Level (low/med) : LOW Solids for Sample: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L Control Limit Spiked Sample Sample Spike Analyte %R Result (SSR) C Result (SR) C Added (SA) oR Q M Cadmium 75-125 4;. 40000._1510 U 50. 00 94.8 P Iron 53120.0000 51590.0000 1000.00 153.0 P Lead _75-125 14 .250U B 7. 1838 U 20. 00 71.2 N P Man anese 75-125 -296.0000 816.4000 500.00 95. 9 P • Comments: FORM V (Pa=t 1) - IN ILM04.1 LKB008 S69 U.S. EPA - CLP 5B EPA SAMPLE NO POST DIGEST SPIKE SAMPLE RECOVERY MW-8SA Lab Name: H2M LABS INC Contract: Lab Code: 10478 Case. No. SAS No. : SDG No. : LKB008 Matrix (soil/water) : WATER Level (low/med) LOW Concentration Units: ug/L Control Limit Spiked Sample Sample Spike [Analyte %R Result (SSR) C Result (SR) C Added (SA) %R Q M Lead 111.30 7.20 1 U ' 100.0 111.3 P • Comments: FORM V (Part 2) - IN ILM04 . 1 LKB008 S70 • i • H2M LABS INC Date: 11-,)ec-13 QC SUMMARY REPO'fff SDG: LKB008 Spike Sample Recovery RPDRef %RPD Sam.ple ID: Client Sample ID. Analyte _ Result Units Amount Result %REC Limits Value %RPD UCL MB-112713 MB-112713 Alkalinity,Total(As CaC 03) < 1 MGIL �--- i LCS 112713_ LCS-112713 Alkalinity,Total(As CaCO3) _ 23_1 MG/L 25 < 1 92. 80 120 1311B70-013AMS MW-8SMS Alkalinity,Total(As CaCO3)_ 548 MGIL 250 325 89 75 125 1311B70-013ADUP MW-8SDUP Alkalinity,Total(As CaCO3) 320 MGIL 325 1.6 20 rMB-42288 MB-42288 Biochemical Oxygen Demand I <2 1 MGIL LCS-42288 LCS-42288 Biochemical Oxygen Demand 203 MGIL 198 <2 1 103 85 1116 1311870 013ADUP MW-8SDUP Biochemical Oxygen Demand 3 MGIL 6 59.8 20 MB-121013 MB-121013 Bromide <0,5 MGIL LCS-121013 LCS-121013 Bromide 2.48 MGIL 2.5 <0.5 99 190 110 1311B70-013AMS MW-8SMS Bromide 1.03 MGIL 1 <0.5 98 80 120 1311B70-013ADUP MW-8SDUP Bromide <0.5 MGIL <0.5 C 20 MB-120513 MB-120513 lBromide <0.5 MG/L LCS-120513 LCS-120513 Bromide 2.60 MGIL 2.5 <0.5 104 90+ MB-120313 MB-120313 lChernical Oxygen Demand <10 MG/L LCS-120313 LCS-120313 Chemical Oxygen Demand 101 MGIL 100 <10 101 90 110 1311670-013BMS MW-8SMS Chemical Oxygen Demand 150 MGIL 100 41.1 109 90 110 1311B70-013BDUP MW-8SDUP Chemical Oxygen Demand 41.1 MGIL 41.1 20 MB 120513 MB-120513 Chloride <2 MGIL LCS 120513— LCS-120513 hloride 9.60 MGIL 10 <2 96 90 110 LKB008 S71 1 • i � QC SUMMARY REPOIIT SDG: LKB008 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB-121013 MB 121013 Chloride 1 <2 MG/L J - LCS-121013 - LCS 121013 _ Chloride 9.12 MG/L 10 <2: 91 90 110 1311 B70__ MW-8SMS Chloride 35.7 MGIL 10 26.0 97 80 120 1311870-013ADUP. MW-8SDUP _ -- - -- - - -.--- _----_- 26.0 0.39 20 Chloride 25.9 MG/L MB-120313 - IMB-120313 _ Hardness(As CaCO3) - - <5 MG/L LCS-120313 LCS-120313 Hardness(As CaCO3) 990 MG/L 1000 <5 99 80 120 1311 B70-013DMS MW-8SMS Hardness(As CaCO3) 664 MG/L 400 248 104 75 125 '1311870-013DDUP MW-8SDUP Hardness(As CaCO3) 248 MG/L 248 20 !MBa-112313 -MBa-112313 Nitrate as N <0.1 MG/L LCSa-112313 �LCSa-112313 Nitrate as N 1.09 MG/L 1,13 <0.1 96 90 110 1311670-013BMS 1311B70-013BMS Nitrate as N 4.84 MGIL 5 < 1 97 90 110 1311B70-013BDUP �1311B70-013BDUP Nitrate as N <1 MG/L < 1 X20 MB-112313 MB-112313 Nitrate as N <0.1 ��G/L L LCS•112313 LCS-112313 Nitrate as N 1.10 1.13 <0.1 97 90 110 MB-112313 MB-112313 Nitrite as N <0.1 MG/L LCS-112313 LCS-112313 Nitrite as N x1.02 MG/L 1 <0.1 102 90 110 1311B70-013AMS MW-8SMS _ _ Nitrite as N 0.45 MG/L 0.5 <0.1 90 90 110 1311B70-013ADUP MW-8SDUP Nitrite as N <0.1 MG/L <0.1 20 MB1-120513 _ MB1-120513 Nitrogen,Ammonia(As N) <0.1 MG/L LC81-120513 LCS1-120513 Nitrogen,Ammonia(As N) 1.09 MG/L 1 <0.1 109 90 11101 1311B70-013BMS MW-8SMS Nitrogen,Ammonia(As N) 28.2 MG/L 10 18.2 100 75 11251 1311870-013BDUP MW-8S6UP Nitrogen,Ammonia(As N) 18.0 MG/L 18.2 1.1 20 LKB008 S72 2 QC SUMMARY,R.EP011T SDG: LKB008 Spike Sample Recovery RPDRef %RPD' Sample 1D_ _ Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL !MB-42394 MB-42394 Nitrogen, Kjeldahl,Total <0.1 MG/L LCS-42394 LCS-42394. Nitrogen;Kjeldahl,Total 4.38 MG/L 4 <0.1 110 90 110 --- --- g _ ------ MGIC 4 19.5 83 75 125 1311B70-013BMS MW-8SMS Nitrogen, Kjeldahl,Total 22 8 -- �1311B70-01313DUP MW78SDUP Nitrogen, Kjeldahl,-Tota l 19.9 MG/L 19.5 2.2 20 MB 42397 MB-42397 !Phenolics,Total Recoverable <5 UG/L LCS-42397 LCS-42397 'Phenolics,Total Recoverable 26.8 UG/L 30 <5 89 8061120 1311B70-013BMS MW-8SMS Phenolics,Total Recoverable 20.5 UG/L 20 <5 103 75 125 1311870-013BDUP MW-8SDUP Phenolics,Total Recoverable <5 UG/L <5 20 M13-120513 T M3-120513 Sulfate <5 MG/L LCS-120513 LCS-120513 Sulfate g.80 MG/L 10 �<5–_98 1-90+110 J MB-121013 MB-121013 Sulfate <5 MG/L LCS-121013 LCS-121013 Sulfate 9.51 MG/L 10 <5 95 90 1-16T- 1311 B70 013AMS 101311B70-013AMS MW-8SMS Sulfate 46.4 MG/L 10 35.7 107 80 120 1311870-013ADUP MW-8SDUP Sulfate 35.4 MG/L 35.7 0.84 20 fMB-112613 MB-112613 Total Dissolved Solids <10 MG/L LCS-112613 _— LCS-112613 Total Dissolved Solids 298 MG/L 300 <10 99 80 120 – 1311 B70-013AMS MW-8SMS Total Dissolved Solids 727 MG/L 300 453 91 75 125 L131 B71 0 013ADUP MW-8SDUP Total Dissolved Solids 442 —MGIC 453 2.5 20 M13-120613 MB-120613 Total Organic Carbon < 1 MG/L LCS-120613 LCS-120613 Total Organic Carbon 27.4 MG/L 25 <1 110 80 120 F1311B70-013CMS MW-8SMS Total Organic Carbon 21.5 MG/L 10 12.5 90 75 125 1311B70-013CDUP MW-8SDUP Total Organic Carbon 12.7 MG/L 12.5 1.5 20 LK6008 S73 3 labs 575 Brod (,'![ow Fac_: 639.6 X4.30=t', Me?YI'€ ,€VY''s747 (,35.420'- -136 7. BLANK SUMMARY DATA AND RESULTS 7.1 METALS 7.2 WET CHEMISTRY • • LKB008 S74 • U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS INC Contract: Lab Code: 10478 Case No. SAS No. : SDG No. : LKB008 Preparation Blank Matrix (soil/water) : WATER Preparation Blank Concentration Units (ug/L or mg/kg) : L'G/L —r - - -— Initial Calib. Continuing Calibration Prepa- Blank Blank (ug/L) ration Analyte (ug/L) Ci 1 C 2 C 3 C Blank C M Cadmium 0.2 U 0.2. L' 0.3 B 0.2 U 0.150 U P Calcium -11.0 B1 7.4 U ?.4 J 7.4 U 7.400 U P Iron 61.9 U�— 61. 9 U 6i.9 'J 61.9 U ' 61.900 U P 0Lead 0.7 U 0.7 U -- Q.7, U -1.4 B 0.720 U P —Magnesium 10.5 U 10.5 1 U -14.0; B ! 10.5 U 10.500 U P Manganese C.1 U 0.1 U _ 0.21B 0.1 U 0.700 B P Potassium 105.9lu -160.Q B -500.0 B ', -630.0 B 106.000 U P Sodium 1976. U 1976.3 U j 1976.3; U 1976.3 U I980.000 U P • ECRM III - IN ILM04 .1 LKB008 S75 • U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS INC Contract: Lab Code: 10478 Case, No. SAS No. : SDG No. : LKB008 Preparation Blank Matrix (soil/water) : WATER Preparation Blank Concentration Units (UC/7 or ma/kg) : UG/L Initial Calib. Continuing CalibrationPrepa- Blank Blank (uc/L) ration Analyte (ug/L) CI 1 C 2 C 3 C Blank C M � Cadmium 0.2 U1 D.2 U1 C.2 f B i I p (Calcium 7.4 U 7 - 7.9 U p Iron 61.9 U 6i.9, U 61.9 ` U0 P Lead -1.1 3 — -1.q — a.7 U p Magnesium 1C.5 U 10.51 U ! 10.5 U p Manganese B _ 0.1 t 0.2 B p Potassium -290.0 B _-360.01 B 300.6 B p 1976.3 U °76_3-L 976.3 U P • FORM III - IN ILM04 .1 LKB008 S76 • U.S. EPA - CLP 3 BLANKS Lab Name: H2M LABS INC Contract: Lab Code:= 10478 Case No. SAS No. : SDG No. : LKB008 5: Preparatibn Blank Matrix (soil/water) : WATER Preparation Blank Concentraticn Units (ug/L or mg/kg) : UG/L -- Initial i Calib. Ccntinuing Calibration M Prepa- Blank i i Blank (ug/L) i ration Analyte (ug/L) CI 1 C 2 C 3 Ci Blank C M I , Cadmium0.2 U1 p Calcium I18.2 I B i _L_1— 4 P Iron - 61.4 F t P Lead B P ',Magnesium -- 31.3_-B -- _ P Manganese - _--- 0,1 j U P 'Potassium - -500.0 B — � i Sodium 1976.3 J p — -- �� FORM III - IN ILM04 .1 LKB008 S77 • U.S. EFA - CLP 3 BLANKS Lab Name: H2M LABS INC Contract: Lab Coder 10478 Case No. SAS No. : SDG No. : LK3008 Preparation Blank Matrix (soil/water) : WATER Preparation Blank Concentration Units (ug/L or mg/kg) : UG/L Initial i Calib. Continuing Calibration Prepa- Blank Blank (ug/L) ration Analyte (ug/L) C1 P P 1 C 2 C 3 C Blank C M !Cadmium 0.2 U 0.2--II U 0.2. 30.2 U 0.150 U Calcium 17.51B 7.4 IU 26.0 B t 7.4 U 7.400 U -- - — Iron ! 61.9_2 _ 61.9 U 61.9 U 61. 9 U 61.900, U P Lead _ C.7 U 0.7 U 0.7 � C.7 U ; 0.720 U P • Magnesium 21.8 B _10.5 U 20.1 B ' 10.5 'UU 10.500 U P Manganese 0.1 U _0.1 U 0.1 U l 0.1 U 0.100 U P Potassium 105.9 U -170.0 BI -160.0, 3 -150.0 B ' 106.000 U P Sodium 1976.3 U 1976.3 U ; 1976.3! 1 1976.3 ' 1 1980.000 U P `. • FORM III - IN ILM04 . 1 LKB008 S78 • U.S. EPA - CLF 3 BLANKS Lab Name: H2M LABS INC Contract: Lab Coder 10478- Case No. SAS No. : SDG No. : LKB008 Preparation_ Blank Matrix (soil/water) : WATER Preparation Blank Concentration Units (ug/L or mg/ka) : UG/L -- r Initial Calib. Continuing Calibration Prepa- Blank Blank (ug/L) ration Analyte (ug/L) C 1 C 2 C 3 C Blank C M Cadmium --I III 0.2 U 0 .4 B 0.2 U 1 F Calcium U 16.8 BIron ' P Lead - _ 00.9 U 6 C.7 0 U —61 .9 U P • ------ - L L 0.9 B Magnesium 13.2 B 10.8, B 13.8 B I j I � P Manganese 0.1 U 0.2: B j 0.1tU P I -1-- Potassium 105.9 U 105. U -190.0 B I P � Sodium i f 1976.3 U 9-76.6.31 U 11976.3 U ; P • FORM T_-I I- ILM04 . 1 1 'J LKB008 S79 112M LABS INC Date: 11-,:)ec-13 QC SUMMARY REPO=RT SDG: LKB0O8 Spike Sample Recovery RPDRef %RPD _ Sample ID:_ Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %oRPD UCL MB-112713 MB-112713 Alkalinity,Total(As CaCO3) <1 MG/L LCS 112713 LCS-112713 Alkalinity,Total(As CaCO3) 23.1 MG/L 25 <1 92 80 120 ' ------- 1311B70-013AMS MW-8SMS _ _ Alkalinity,Total(As CaCO3) i-548 1 MG/L 250 325 89 75 125 1311B70-013ADUP MW-8SDUP Alkalinity,Total(As CaCO3) 320 MG/L 325 1.6 20 MB-42288 MB-42288 Biochemical Oxygen Demand <2 MG/L LCS-42288 ILCS-42288 Biochemical Oxygen Demand 203 MG/L 198 <_2 103 85 116 1311B70-013ADUP MW-8SDUP Biochemical Oxygen Demand 3 MG/L 6 59.8 20 MB-121013 MB-121013 Bromide <0.5 MG/L LCS-121013 LCS-121013 Bromide 2.48 MG/L 2.5 <0.5 99 90 110 1311B70413AMS MW-8SMS Bromide 1.03 MG/L 1 <0.5 98 80 120 1311B70-013ADUP MW-8SDUP Bromide <0.5 MG/L - <0.5 20 MB 120513 IMB-120513 Bromide <0.5 -I---MG/L r —j----- LCS120513 ILCS-120513 Bromide 2.6D MGIL 2.5 1 <0.5 104 90 110 MB 120313 MB 120313 Chemical Oxygen Demand <10 MG/L LCS 120313 LCS 120313 Chemical Oxygen Demand_ 101 MG/L 100 < 1090 90 110 1311B70-013BMS MW-8SMS Chemical Oxygen Demand 150 MG/L 100 41.1 109 90 110 _ -I-- -- 1311B70-013BDUP MW-8SDUP — Chemical Oxygen Demand 41.1 MG/L 41.1 20 MB-120513 MB-120513 Chloride <2 MG/L i _ -- --- ---- ---- --- � � LCS-120513 LCS-120513 _- Chloride 9.60 MGIL 10 <2 96 90 110 --�_---_- LK6008 S80 1 QC SUMMARY REPOTtT SDG: LKB008 Spike Sample Recovery RPDRef %RPD _ SamWe ID: Client Sample ID: Anaiyte -- Result Units Amount Result %REC Limits Value %RPD UCL --- ---- IMB-121013 — MB-121013 Chloride <2 MG/L ;LCS-121013 LCS-121013 Chloride 9.12 MG/L 10 <2 91 90 110 11311B70-013AMS LMW-8SMS- Chloride 35.7 MG/L 10 26.0 97 80 120 1311670-013ADUP MW-8SDUP Ch[pride.• 25.9 MG/L 26.0 - 0.39 20 MB-120313 IMB-120313 Hardness(As CaCO3) <5 MG/L T LCS-120313 LCS-120313 Hardness(As CaCO3) 990 MG/L 1000 <5 99 80 120 1311670-013DMS MW-8SMS _ Hardness(As CaCO3) 664 MG/L 400 248 104 75 125 1311870-013DDUP MW-8SDUP Hardness(As CaCO3) 248 MG/L -r 248 20 MBa-112313 MBa-112313 Nitrate as N -<0.1 MG/L -- - ---- -- MG/L 90 110 LCSa-112313 LCSa-112313 Nitrate as N 1.09 MG/L 1.13 <0.1 96 11 -- 1311670-013BMS 1311 B70-013BMS Nitrate as N 4.84 MG/L 5 < 1 97 90 110 1311B70-013BDUP 1311870-013BDUP Nitrate as N - - <1 MGlL _ �_ _ <1 20 'Nit MG/L 12313 tate��N LCS11123 3 -- -- ---LCS11123 3- - - -Nitrate as N - -i 1.100 -MG/l. 1.13 ; <0.1 97 90 110 — -- MB 112313 MB-112313 Nitrite as N <0.1 MG/L LCS 112313 LCS-112313 Nitrite as N 1.02 MG/L 1 <0.1 102 90 110 1311 B70-013AMS MW-8SMS Nitrite as N 0.45 MG/L 0.5_ <0.1 90 90 : 110 1311 B70-013ADUP A W )M -8SDUP Nitrite as N <0.1 MG/L T <0.1 20 MB1-120513 �M61-120513 Nitrogen,Ammonia(As N) <0.1 MG/L �LCS1-120513 — ILCS1-120513 Nitrogen,Ammonia(As N) 1.09 MG/L 1 <0.1 109 +90 110 1311870-013BMS MW-8SMS Nitrogen,Ammonia(As N) 28.2 MG/L 10 18.2 100 T75 125 1311B70-013BDUP MW-8SDUP Nitrogen,Ammonia(As N) 18.0 MG/L �, 18.2 1 1,1 �2O LK8008 S81 2 : :. QC SUMMARY REPORT SDG: LKB008 _ Spike Sample Recovery RPDRef %RPD Sample ID:_ _ Client Sample ID.: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB-42354 --µ MB-42394.. ----- Nitrogen, Kjeldahl,Total <0.1 MG/L LCS-42394 LCS-42394 Nitrogen, Kjeldahl,Total 4.38 MG/L 4 <0.1 110 90 110 _ _ 1311 B70-013BMS MW-8SMS Nitrogen,Kjeldahl,.Total T 22.8 MG/L 4 19.5 83 75 125 1311870-013BDUP MVV-88DUP Nitrogen, Kjeldahl,Total 19.9 MG/L 19.5 2.2 20 MB-42397 MB-02397 Phenolics,Total Recoverable <5 UG/L LCS-42397 LCS-42397 Phenolics,Total Recoverable 26.8 UGIL 30 <5 89 80 1120 1311B70-013BIVIS MW-8SMS Phenolics,Total Recoverable 20.5 UG/L 20 <5 103 75 1125 1311 870-0136DUP MW-8SDUP Phenolics,Total Recoverable <5 UGIL <5 20 -- ----------- - -- 1 -- -- MB-120513 �MB-120513 Sulfate <5 MG/L - — - - �� --- -- — --- - -- - ------ LCS-120513 LCS-120513 Sulfate 9.80 MG/L 10 <5 98 90 110 - -_j-- -- - -- -— - -- - -- �--- MB 121013 SMB-121013 Sulfate <5 MG/L LCS 121013 LCS-121013_ -- Sulfate _ 9.51 MG/L 10 <5 95 90 110 1311 B70-013AMS MW-8SMS Sulfate 46.4 MG/L 10 35.7 107 80 120 ---- - ------- - ---- - ---- -- -. 1_ 1311870-013ADUP MW-BSDUP Sulfate 35.4 MG/L 1 35.7 0.84 20 MB-1 12613 MB-112613 Total Dissolved Solids < 10 MG/L LCS 112613 LCS-112613 Total Dissolved Solids 298 MG/L 300 <10 99 80 120 1311B70-013AMS MW-8SMS ---JTotal Dissolved Solids 727 MG/L 300 453 91 75 125 1311B70-013ADUP MW-8SDUP Total Dissolved Solids 442 MG/L 453 2.5 20 -M--6-1-20613 MB 120613 Total Organic Carbon <1 MG/L I LC5 120613 LC5 120613 Total Organic Carbon 27.4 MG/L 25 < 1 110 80 120 1311870-013CMS MW 8SMS Total Organic Carbon 21.5 MG/L 10 112.5 90 75 125 1311670-013CDUP MW-8SDUP Total Organic Carbon 12.7 MG/L __ 12.5 1.5 20 I LKB008 S82 3