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HomeMy WebLinkAbout2014 2nd Qtr 1 SECOND QUARTER 2014 GROUND WATER-MONITORING REPORT ' FOR THE TOWN OF SOUTHOLD LANDFILL 6155 COX LANE CUTCHOGUE, NY 11944 ' Prepared for: Southold Town Solid Waste Management District 6155 Cox Lane Cutchogue, NY 11944 ' Prepared by: Lockwood, Kessler & Bartlett, Inc. ' 1 Aerial Way Syosset, NY 11791 - D SEP - 2 2014 ' TOM oFsounjoLD MPT.OF SOLID WASTE ' Submitted to: New York State Department of Environmental Conservation ' Region 1 Headquarters SUNY at Stony Brook 50 Circle Road ' Stony Brook, NY 11790 ' AUGUST 28, 2014 ' Second Quarter 2014 Ground Water-Monitoring Report Town of Southold Landfill, Cutchoque, NY 1 ' TABLE OF CONTENTS Section Number and Title Page Number 1.0 INTRODUCTION 1 ' 2.0 METHODS AND PROCEDURES 1 3.0 DISCUSSION OF RESULTS 2 ' 3.1 Water-Level Results 2 3.2 Field Parameter Results 2 ' 3.3 Routine Leachate Indicator Results 3 3.4 Routine Inorganic Parameter Results 5 ' 3.5 Additional Baseline Parameter Results 6 4.0 CONCLUSIONS AND RECOMMENDATIONS 7 Figure Number and Title Follows Page Number ' 1. Site Location Map 1 2. Well Location Map 1 ' Table Number and Title Follows Page Number 1. Summary of Part 360 Routine Parameter Results for 2 ' Fourth Quarter 2014 Monitoring Round 2. Summary of Part 360 Additional Baseline Parameter Results for 2 Fourth Quarter 2014 Monitoring Round Appendices ' A. Sample Data Summary Package t i Lockwood, Kessler& Bartlett, Inc. Second Quarter 2014 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY ' 1.0 INTRODUCTION ' The Town of Southold has retained Lockwood, Kessler & Bartlett, Inc. (LKB) to perform post-closure ground-water monitoring and reporting for its closed and capped MSW landfill in Cutchogue, NY (Site). The location of the Site is shown in Figure 1. This report is for the second quarter 2014 monitoring round, conducted on June 30, ' 2014; and describes the work performed and the results obtained. Section 2.0 (Methods and Procedures) details the project requirements and the specific work performed. Section 3.0 (Discussion of Results) summarizes the key findings from this monitoring ' round, including comparison of the laboratory results to standards and guidance values. Section 4.0 (Conclusions and Recommendations) provides conclusions based on this quarter's results, and recommendations for upcoming quarters. Each report section is ' supported by figures and/or tables, as appropriate, which follow the page on which they are first referenced. The laboratory data summary package for this monitoring round is provided in Appendix A. 2.0 METHODS AND PROCEDURES Water-level measurements and ground-water samples were collected from 11 of the Site's 12 monitoring wells, as listed below. Well MW-8D could not be monitored this ' quarter due to an active bee nest in the wellhead. A site plan showing the locations of the wells is provided in Figure 2. • MW-1S • MW-5S • MW-1 D • MW-5D • MW-3S • MW-6S ' MW-3D • MW-6D • MW-4S • MW-8S • MW4D Prior to sampling, the water-level in each well was measured to the nearest 0.01-feet from the top of the well casing utilizing a decontaminated water-level meter. Ground- water samples were collected utilizing a Grundfos RediFlo2 variable-speed electric submersible pump connected to 200 feet of %-inch diameter polyethylene hose on a Keck Reel. Utilizing the well construction records, the pump was placed at the mid-point of each well's screen. Each well was then purged at a low flow rate until its turbidity was less than 5 Nephelometric Turbidity Units (NTUs) and/or field parameter readings stabilized. ' The ground-water samples were collected directly from theum discharge hose into P P 9 new laboratory-supplied bottles of the type required for each specific analysis. A blind ' duplicate was collected from Well MW-4S and labeled "MW-7S". Matrix spike and matrix spike duplicate samples were collected from Well MW-8S. A field blank and a trip blank were also collected. Field notes were recorded in a bound field notebook. I Lockwood, Kessler& Bartlett, Inc. Duck Pond Pt 1 a v N v lP G 1 % 11958 1 SITE 2 1 � REG0N 9y. 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""- ___ i 7U7�q 'NOTE:WELL SYMBOLS NOT TO SCALE Note: Base map provided by Town of Southold FIGURE 2 WELL LOCATION PLAN TOWN OF SOUTHOLD LANDFILL, CUTCHOGUE, NY LJaAmML” Second Quarter 2014 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY ' Each sample was labeled with the well number, time and date etc. laced in a cooler p , p with ice to keep it at 4°C, and delivered to the laboratory the following day. The samples ' were analyzed for the 6NYCRR Part 360 Baseline Parameters. The field parameters were monitored by LKB. Laboratory analyses were performed by Pace Analytical ' (formerly H2M Labs, Inc.) in Melville, NY. This laboratory is certified by the New York State Department of Health's Environmental Laboratory Approval Program in all required analytical categories, and employs the required internal QA/QC procedures, including analysis of matrix spikes, matrix spike duplicates, method blanks and continuing calibration samples. They also participate in the required biennial proficiency testing. The field data and laboratory results were reviewed by LKB per QA/QC Plan requirements and determined to be useable. 3.0 DISCUSSION OF RESULTS The field and laboratory results for the second quarter 2014 ground water-monitoring round are summarized and compared to the New York State Department of Environmental Conservation Ambient Water Quality Standards and Guidance Values for Class GA (Potable) ground water, as applicable, in Table 1 and 2. Table 1 summarizes ' the results for the Part 360 routine parameters, which are the parameters typically analyzed for during quarterly monitoring. Table 2 summarizes the results for the additional Part 360 baseline parameters analyzed for during this monitoring round. A ' review of the results for the water-level measurements and each analytical parameter group is provided below. 3.1 Water-Level Results As shown in Table 1, water-table elevations were generally consistent across the Site and ranged from 6.83 feet above mean sea level (MSL) in Well MW-1S, located on the south end of the Site, to 4.74 feet above MSL in Well MW-8S, located on the west side of the Site. The water-level results are consistent with ground-water flow information published by the United States Geological Survey in Scientific Investigations Map 3066, Water Table — Sheet 1 of 4, which indicates a relatively low horizontal hydraulic gradient and a northerly horizontal ground water-flow direction. Based on these results, Well Cluster MW-1 is located upgradient of the Site, and the other wells are located downgradient of various portions of the Site. Potentiometric surface elevations in the deeper wells are consistent with the water-table elevations. 3.2 Field Parameter Results rReview of the field parameter results in Table 1 indicates the following key findings: • Ground-water conductivity values are higher relative to the main area of Long Island, and may be at least partly attributed to the Site's North Fork location, where naturally higher ground-water salinities may occur due to the proximity to 2 Lockwood, Kessler& Bartlett, Inc. 1 Table 1 ' Summary of Part 360 Routine Parameter Results for Second Quarter 2014 Monitoring Round Town of Southold Landfill, Cutchogue, NY NYSDEC Part 360 Units Class GA Well Number and Result Routine Parameters Standard MW-1S MW-1 D MW-3S MW-3D MW-4S MW-4D MW-5S MW-5D MW-6S MW-6D MW-8S MW-8D ' Water-Level Data: T.O.C. Elevation Feet MSL N/A 44.83 44.88 49.50 49.19 63.03 62.92 68.14 67.64 55.77 55.71 54.16 55.29 Depth to Water Feet N/A 38.00 37.92 44.21 43.34 57.64 57.55 63.65 63.20 49.81 49.79 49.42 NS ' Water-Level Elevation Feet MSL N/A 6.83 6.96 5.29 5.85 5.39 5.37 4.49 4.44 5.96 5.92 4.74 NS Field Parameters: ' Conductivity ms/cm No Standard 0.169 0.036 0.442 1.230 0.154 2.230 0.177 2.060 0.160 0.344 0.515 NS Temperature oC No Standard 14.9 22.2 16.5 16.5 16.5 16.0 14.6 15.3 14.4 13.9 16.7 NS Floaters or Sinkers N/A None None None None None None None None None None None None NS ' pH Units 6.5-8.5 5.59 6.56 6.51 6.58 6.64 6.96 5.64 6.77 6.03 6.00 6.72 NS Eh pHmV No Standard 77.7 20.0 25.4 21.3 18.3 2.0 74.7 10.3 52.4 54.2 13.1 NS Dissolved Oxygen mg/L No Standard 8.74 12.26 3.30 2.34 5.64 1.56 4.31 0.70 0.70 2.74 0.44 NS Field Observations N/A No Standard Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, NS ' No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor NS Turbidity NTU <5 2.87 4.44 1.79 3.97 1.53 4.64 4.39 5.21 4.49 4.05 2.63 NS ORP mV No Standard 47.5 5.7 -57.1 -65.4 102 -37.0 132 86.4 16.4 17.2 -129 NS Leachate Indicators: Alkalinity mg/L No Standard 4.60 31.0 177 530 169 761 21.3 691 48.5 11.2 302 NS ' Ammonia mg/L 2 < 0.10 < 0.10 15.2 7.60 < 0.10 24.4 < 0.10 88.2 < 0.10 < 0.10 25.0 NS BOD mg/L No Standard < 2 < 2 < 4 < 4 < 2 < 2 < 2 < 2 < 2 < 2 < 4 NS Bromide mg/L 2GV < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 1.87 < 0.50 0.98 < 0.50 < 0.50 < 0.50 NS ' Chloride mg/L 250 30.8 23.2 72.8 128 16.3 330 27.8 186 6.47 42.6 41.7 NS COD mg/L No Standard < 10.0 < 10.0 29.2 47.0 21.6 57.7 < 10.0 74.4 28.0 < 10.0 38.8 NS Hardness mg/L No Standard 34 76 140 180 210 750 44 400 76 130 220 NS ' Nitrate mg/L 10 2.57 3.37 < 0.10 < 0.10 14.0 < 0.10 1.29 < 0.10 0.89 9.19 < 0.10 NS Phenols ug/L 1 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 NS Sulfate mg/L 250 18.0 63.0 49.7 41.8 37.4 106 15.0 45.4 10.5 101 42.4 NS Total Dissolved Solids mg/L 500 115 196 380 602 400 1,230 130 954 124 348 414 NS ' TKN mg/L No Standard 0.28 0.22 16.5 72.4 0.75 40.3 0.84 102 0.98 0.17 25.8 NS Total Organic Carbon mg/L No Standard < 1.0 < 1.0 10.0 24.2 5.8 23.2 1.5 29.0 8.3 < 1.0 12.7 NS ' Inorganic Parameters: Cadmium ug/L 5 < 0.14 < 0.14 0.30J < 0.14 < 0.14 < 0.14 < 0.14 < 0.14 < 0.14 < 0.14 < 0.14 NS Calcium ug/L No Standard 6,780 22,200 24,600 34,700 58,400 147,000 9,650 75,100 14,800 33,700 57,000 NS ' Iron ug/L 300 24.4 J 21.4 J 72,100 30,600 12.6 J 514 11.1 J 78.5 J 71.9 J 21.9 J 38,200 NS Lead ug/L 25 11.9 17.2 11.6 20.5 9.0 18.9 11.0 9.1 12.0 17.1 16.7 NS Magnesium ug/L 35,000 3,980 J 9,730 15,800 24,800 13,600 60,600 5,740 30,800 4,340 J 16,800 20,200 NS Manganese ug/L 300 8.5 J 2.8 J 4,200 3,300 3,440 3,380 54.7 11,800 2,280 872 882 NS Potassium ug/L No Standard 3,440 J 1,480 J 19,000 64,700 38,100 47,200 4,010 J 111,000 4,190 J 2,740 J 44,800 NS Sodium ug/L 20,000 14,600 18,800 42,200 97,900 8,720 206,000 12,000 132,000 6,680 15,900 25,900 NS Notes: T.O.C. = Top of Casing. COD = Chemical Oxygen Demand. mV = millivolts. J = Estimated result> MDL but< RL. ' MSL = Mean Sea Level. TKN = Total Kjeldahl Nitrogen. mg/L = milligrams per Liter. NS = Not Sampled (Due to bee nest in wellhead). mS/cm = milliSiemens per centimeter. °C = Degrees Celsius. ug/L = micrograms per Liter. ORP = Oxygen Reduction Potential. pHmV = pH in millivolts. N/A = Not Applicable. Results in bold font and highlighted in yellow ' BOD = Biological Oxygen Demand. NTU = Nephelometric Turbidity Units. NM = Not Measured. I exceed Class GA Standard or Guidance Value. Table 2 ' Summary of Part 360 Additonal Baseline Parameter Results for Second Quarter 2014 Monitoring Round Town of Southold Landfill, Cutchogue, NY ' NYSDEC Part 360 Units Class GA Well Number and Result Baseline Parameters Standard MW-1 S MW-1 D MW-3S MW-3D MW-4S MW-4D MW-5S MW-5D MW-6S MW-6D MW-8S MW-8D ' Detected Target VOCs: Chlorobenzene ug/L 5 < 5 < 5 < 5 4 J < 5 3 J < 5 13 < 5 < 5 16 NS 1,4-Dichlorobenzene ug/L 3 < 5 < 5 < 5 < 5 < 5 < 5 < 5 3 J < 5 < 5 < 5 NS ' 1,2-Dichloroethane ug/L 0.6 < 5 < 5 < 5 < 5 < 5 4 J < 5 < 5 < 5 < 5 < 5 NS cis-1,2-Dichloroethene ug/L 5 < 5 < 5 < 5 1 J < 5 < 5 < 5 2 J < 5 < 5 < 5 NS 1,2-Dichloropropane ug/L 1 < 5 < 5 < 5 < 5 < 5 8 < 5 4 J < 5 1 1 < 5 NS ' Trichloroethene ug/L 5 < 5 < 5 < 5 1 1 < 5 < 5 < 5 < 5 < 5 < 5 < 5 NS 1,2,3-Trichloropropane ug/L 0.04 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 2 J < 5 NS Leachate Indicators: ' Boron ug/L 1,000 24.0 J 16.8 J 133 512 119 651 22.5 J 760 34.2 J 33.6 J 218 NS Color Units 5 < 5.00 < 5.00 125 125 < 5.00 30.0 < 5.00 35.0 40.0 < 5.00 500 NS ' Inorganic Parameters: Aluminum ug/L No Std. 42.2 J 67.9 J 32.5 J 71.9 J 31.0 J 53.5 J 36.9 J 48.5 J 81.8 J 35.3 J 26.3 J NS Antimony ug/L 3 < 1.6 < 1.6 < 1.6 < 1.6 < 1.6 < 1.6 < 1.6 < 1.6 < 1.6 < 1.6 < 1.6 NS ' Arsenic ug/L 10 < 1.5 < 1.5 < 1.5 3.9J < 1.5 < 1.5 < 1.5 < 1.5 < 1.5 < 1.5 < 1.5 NS Barium ug/L 1,000 58.7 J 30.5 J 189 J 248 103 J 190 J 55.7 J 197 J 63.2 J 24.3 J 240 NS Beryllium ug/L 3 G 0.10 J < 0.091 < 0.091 < 0.091 < 0.091 < 0.091 0.10 J < 0.091 < 0.091 < 0.091 < 0.091 NS ' Chromium, Total ug/L 50 4.2 J 1.6 J < 0.46 < 0.46 1.4 J 1.1 J 2.5 J 1.5 J 2.0 J 1.1 J < 0.46 NS Cobalt ug/L No Std. < 0.16 < 0.16 30.6 J 46.3 J 0.30 J 14.2 J < 0.16 26.0 J 4.7 J 1.1 J 3.9 J NS Copper ug/L 200 1.0 J 1.4 J 17.4 J 8.9 J 2.2 J 3.5 J 1.4 J 14.7 J 11.5 J 0.90 1 < 11.1 J NS ' Cyanide ug/L 200 < 10.0 < 10.0 < 10.0 < 10.0 < 10.0 < 10.0 < 10.0 < 10.0 < 10.0 < 10.0 < 10.0 NS Mercury ug/L 0.7 < 0.10 < 0.10 < 0.10 < 0.10 < 0.10 < 0.10 < 0.10 < 0.10 < 0.10 < 0.10 < 0.10 NS Nickel ug/L 100 1.7 J 0.30 J 2.9 J 28.5 J 11.2 J 37.6 J 3.1 J 34.7 J 16.3 J 12.7 J < 0.29 NS Selenium ug/L 10 2.4J < 1.4 < 1.4 < 1.4 < 1.4 < 1.4 < 1.4 < 1.4 < 1.4 < 1.4 < 1.4 NS Silver ug/L 50 1.9 J 2.2 J < 3.7 < 3.7 1.0 J 0.41 J 1.7 J 2.5 J < 0.37 1.3 J < 3.7 NS Thallium ug/L 0.5 GV < 3.5 < 3.5 12.9 14.4 14.0 12.9 < 3.5 48.3 8.1 J 4.6 J < 3.5 NS Vanadium ug/L No Std. 0.40 J 0.90 J 1.2 J 1.6 J < 0.22 0.3 J 0.3 J < 0.22 < 0.22 0.5 J 1.3 J NS ' Zinc ug/L 2,000GV 6.6 J 136 9.5 J 6.3 J 6.2 J 11.6 J 22.2 4.3 J 9.0 J 11.1 J 12.4 J NS Notes: ' ug/L = micrograms per Liter. Results in bold font and highlighted in yellow J = estmated concentration. exceed Class GA Standard or Guidance Value. NS = Not Sampled (Due to bee nest in wellhead). ' SecondQ uarter 2014 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY saline surface-water bodies. Conductivities are highest in the deep wells located ' directly downgradient of the Site (e.g., Wells MW-3D, MW-4D and MW-5D). These highest values appear to be Site-related. • Ground-water temperatures are similar in the upgradient and downgradient wells. ' • No floaters or sinkers were noted during this monitoring round. • Ground-water pH is acidic, and is lower than the minimum standard of 6.5 ' Standard Units in one of the upgradient wells and three of the downgradient wells this quarter. The results are consistent with the naturally low pH of Long Island ground water. Ground-water pH is higher in the deep well at four of the clusters. ' • Eh is similar in upgradient and downgradient wells. Eh is lower in the deep well every cluster except Well Cluster MW-6. The lowest Eh values occurred in Wells MW-4D and MW-5D. • Dissolved oxygen concentrations are noticeably lower in the downgradient wells relative to the upgradient wells, but dissolved oxygen is present in all 11 wells. ' • The ground water in all 11 wells was observed to be clear, and did not have a noticeable odor this quarter. • The turbidity of ground water is low, was less than the 5-NTU (Nephelometric ' Turbidity Units) standard in 10 of the 11 wells this quarter, and was only slightly higher (5.21 NTU) in Well MW-5D. Therefore, the collection of filtered samples for dissolved metals analyses was not required. ' • The ORP (oxidation-reduction potential) of ground water is positive in both upgradient wells, Well MW-4S, and Well Clusters MW-5 and MW-6; and negative ' in Well Cluster MW-3 and Wells MW-4D and MW-8S this quarter. The highest ORP readings occurred in Wells MW-4S and MW-5S. The lowest (most negative) ORP readings occurred in Well Cluster MW-3 and Well MW-8S. ' Overall, the field parameter results obtained this quarter are consistent with the Site's usage and its North Fork setting. Potential Site-related impacts are relatively minor in ' magnitude and limited to higher conductivity, and lower dissolved oxygen levels and Eh, in certain downgradient wells. ' 3.3 Routine Leachate Parameter Results Review of the leachate routine parameter results in Table 1 indicates the following key ' findings: • Ground-water alkalinity is noticeably higher in six of the nine downgradient wells ' relative to the upgradient wells, and is highest in Wells MW-3D, MW-4D and MW- 5D. • Ammonia is present in five downgradient wells, at concentrations exceeding the 2-mg/L Class GA ground-water standard; and is highest in Well MW-5D. The highest ammonia concentrations occur in deeper wells; which suggests that they may be partly due to natural saline ground-water conditions. 3 Lockwood, Kessler& Bartlett, Inc. ' Second Quarter 2014 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY • BOD (Biological oxygen demand) was not detected in any wells this quarter. • Bromide was only detected in two deep downgradient wells (MW-4D and MW- 5D), at concentrations below the 2-mg/L Class GA guidance value this quarter. • Chloride levels are noticeably higher in four of the downgradient wells (MW-3S, MW-3D, MW-4D and MW-5D) relative to the upgradient wells, but with the exception of Well MW-4D are lower higher than the 250-mg/L Class GA ground- water standard. The fact that the highest chloride concentrations occur in deep wells suggests that they may be due in part to naturally saline ground-water conditions. ' • COD (Chemical oxygen demand) was detected in seven of the nine downgradient wells. The highest COD results occurred in Wells MW-3D, MW-4D and MW-5D. There is no Class GA standard or guidance value for this ' parameter. • Ground-water hardness values are higher in seven of the nine downgradient wells relative to the upgradient wells. The highest hardness values occurred in Wells MW-3D, MW-4D and MW-5D. There is no Class GA ground-water standard for guidance value or this parameter. • Nitrate is present in both upgradient wells and four of the nine downgradient ' wells this quarter. Concentrations are lower than the 10-ug/L Class GA ground- water standard in every well except Well MW-4S. ' • Phenols were not detected in any of the site monitoring wells this quarter. • Sulfate is present in all 12 wells, at relatively similar concentrations in the upgradient and downgradient wells. All concentrations are lower than the 250- ' ug/L Class GA ground-water standard. Sulfate concentrations are higher in the deep well at all but one well cluster, which suggests that they may be partly associated with saline ground-water conditions. ' • TDS (total dissolved solids) results are noticeably higher in seven of the nine downgradient wells relative to the upgradient wells, and exceed the 500-mg/L ' Federal MCL in Wells MW-3D, MW-4D and MW-5D. The fact that the highest TDS concentrations occur in deep wells suggests that they may be partly associated with naturally saline ground-water conditions. ' • TKN (total Kjeldahl nitrogen) is present in all 12 wells this quarter. TKN concentrations in five of the nine downgradient wells are significantly higher than in the upgradient wells. The highest concentrations occurred in Wells MW-3D ' and MW-5D. There is no Class GA standard or guidance value for this parameter. • TOC (total organic carbon) was not detected in the upgradient wells, but is ' present in eight of the nine downgradient wells. The highest concentrations occurred in Wells MW-3D, MW-4D and MW-5D. There is no Class GA standard or guidance value for this parameter. 4 Lockwood, Kessler& Bartlett, Inc. ' Second Quarter 2014 Ground Water-Monitoring Report ort Town of Southold Landfill, Cutchogue, NY Overall, the routine leachate parameter results obtained this quarter are also consistent with the Site's usage and its North Fork setting. Potential Site-related impacts indicated by these results include downgradient increases in most of the detected parameters, primarily in the deep wells. However, it is important to note that 1) the there are no ground-water standards for six of the parameters; and 2) the downgradient increases occur in a limited number of wells. ' Moreover, ground water in this area is naturally saline at depth, and ultimately discharges to a saline surface-water body (Long Island Sound). Therefore, the exceedances for ammonia, chloride, nitrate and TDS, which occur naturally in saline ' ground water and seawater, are not a significant concern with respect to public health or the environment. ' 3.4 Routine Inorganic Parameter Results Review of the inorganic routine parameter results in Table 1 indicates the following key ' findings: • Cadmium was only detected in one downgradient well, at a low, estimated ' concentration below the 5-ug/L Class GA ground-water standard. • Calcium was detected in all 11 wells this quarter, and concentrations are ' noticeable higher in Wells MW-4S, MW-41D, MW-51D and MW-8S relative to the upgradient wells. There is no Class GA ground-water standard or guidance value for this parameter. • Iron was detected in all 11 wells this quarter, and the concentrations in four of the downgradient wells exceed the 300-ug/L Class GA ground-water standard. The highest iron concentrations occurred in Well Cluster MW-3 and Well MW-8S. At Well Cluster MW-3 the highest iron concentration occurred in the shallow well, suggesting that the higher iron at this location is Site-related. • Lead was detected at low, similar concentrations in all 11 wells this quarter. All ' detections are lower than the 25-ug/L Class GA ground-water standard. • Magnesium was detected in all 11 wells, but only the concentration in Well MW- 4D is higher than the 35,000-ug/L Class GA ground-water guidance value. Magnesium concentrations are higher in the deep well at each cluster, which suggests that they may be partly due to naturally saline ground-water conditions. ' • Manganese was detected in all 11 wells, but concentrations are higher in the downgradient wells. Concentrations in eight of the nine downgradient wells exceed the 300-ug/L Class GA ground-water standard. The highest manganese concentration occurred in Well MW-51D. • Potassium was detected in all 11 wells. Potassium concentrations are higher in six of the nine downgradient wells relative to the upgradient wells, and ' highest in Wells MW-31D and MW-51D. There is no Class GA ground-water standard or guidance value for this parameter. 5 Lockwood, Kessler& Bartlett, Inc. ' Second Quarter 2014 Ground Water-Monitoring Report ort ' Town of Southold Landfall, Cutchogue, NY • Sodium was detected in all 11 wells. Sodium concentrations are noticeably ' higher in five downgradient wells (MW-3S, MW-31D, MW-41D, MW-51D and MW- 8S) relative to the upgradient wells, and exceed the 20,000-ug/L Class GA ground-water standard in these wells. The highest sodium concentrations occur in the deep wells, which suggests that they are partly due to naturally saline ground-water conditions. ' Overall, the routine inorganic parameter results obtained this quarter are also consistent with the Site's usage and its North Fork setting. Potential Site-related impacts indicated by these results include downgradient increases in calcium, iron, magnesium, ' manganese, potassium and sodium. However, it is important to note that 1) many of these increases are relatively minor in magnitude,,sporadic, and/or less than the Class GA ground-water standard; 2) there are no ground water-quality standards or guidance ' values for calcium or potassium; 3) the standards for iron and manganese are aesthetics-based; and 4) sodium is not considered to be particularly hazardous. Moreover, as noted above in Section 3.2, ground water on the North Fork is naturally ' saline at depth and ultimately discharges to a saline surface-water body (Long Island Sound). Therefore, the exceedances for magnesium and sodium, which occur naturally in saline ground water and seawater, are not a concern with respect to public health or ' the environment. 3.5 Additional Baseline Parameter Results ' Review of the Part 360 additional baseline parameter results in Table 2 indicates the rN following key findings: • The majority of the VOCs (volatile organic compounds) analyzed for were not detected in any of the wells sampled. VOC detections were limited to relatively low concentrations of seven aromatic hydrocarbons and chlorinated solvents in five of the nine downgradient wells. Low-magnitude exceedances for one or two ' VOCs occurred in Wells MW-41D, MW-51D, MW-61D and MW-8S. Except for the relatively low concentration of chlorobenzene in Well MW-8S, VOCs were not detected in the shallow downgradient wells. VOCs were not detected in the upgradient wells. • Boron was detected in all 11 wells, and concentrations are noticeably higher in six of the downgradient wells (MW-3S, MW-31D, MW-4S, MW-41D, MW-51D and ' MW-8S) relative to the upgradient wells. All boron detections are lower than the 1,000-ug/L Class GA ground-water standard. • Color exceeded the aesthetics-based 5-CU (Color Units) Class GA ground-water ' standard in Wells MW-3S, MW-31D, MW-41D, MW-51D, MW-6S and MW-8S. • Regarding the baseline inorganic parameters, except for exceedances of the 0.5- ug/L Class GA ground-water guidance value for thallium in seven of the nine downgradient wells, the concentrations of these parameters were lower than their Class GA ground-water standard or guidance value in all 11 wells. The 6 Lockwood, Kessler& Bartlett, Inc. Secondater-Monitorin uarter 2014 Ground W Q g Report Town of Southold Landfall, Cutchogue, NY exceedances for thallium are not a significant concern as the limit is a guidance value rather than a standard. Antimony, cyanide and mercury were not detected. Aluminum, arsenic, barium, chromium, selenium, silver, vanadium and zinc were detected at similar concentrations in upgradient and downgradient wells and/or only detected sporadically at low, estimated concentrations. Barium, copper and nickel concentrations, while low in all wells, were noticeably higher in certain downgradient wells relative to the upgradient wells. The above results indicate that the Site is not a significant source of releases of the additional Part 360 baseline parameters to ground water. Moreover, the fact that VOC ' detections are limited to a few compounds at relatively low concentrations, primarily in the deeper wells, suggests that they reflect regional ground water-quality conditions. ' 4.0 CONCLUSIONS AND RECOMMENDATIONS Based on the results of the second quarter 2014 monitoring round, LKB concludes the following: • Water-level elevations, hydraulic gradients and ground water-flow directions are consistent with local and regional hydrogeologic conditions. ' • In general, ground water-quality conditions are consistent with the Site's North Fork setting near saline surface-water bodies. • Comparison of upgradient and downgradient results indicates potential Site- related impacts consistent with an old MSW landfill, however further assessment indicates that they are not a significant concern with respect to public health or the environment. The monitoring schedule for the Site requires monitoring ground water for 6NYCRR Part 360 routine parameters during three calendar quarters and for Part 360 baseline parameters during one calendar quarter, in rotating quarters. The next baseline monitoring round should be performed during the third quarter of 2014. Until then, the quarterly monitoring should be performed for Part 360 routine parameters. LKB recommends that this monitoring schedule be followed. It is also recommended that the wellheads be inspected for active bee nests during the summer monitoring months, and that any nests found be removed. 7 Lockwood, Kessler& Bartlett, Inc. 1 i 1 APPENDIX A Sample Data Summary Package 1 1 1 1 1 1 1 1 1 1 1 111'! c10E Long Island l SAMPLE DATA SUMMARY PAQKAGE TABLE OF CONTENTS LOCKWOOD, KESSLER & BARTLETT PROJECT: TOWN OF SOUTHOLD LANDFILL 2014 MONITORING ROUND SAMPLES RECEIVED: 7/1/14 ' SDG NO.: LKBO10 1. NYS DEC SUMMARY FORMS ' 2. CHAIN OF CUSTODY DOCUMENTATION 3. SDG NARRATIVES I4. SAMPLE REPORTS 4.1 VOLATILES ' 4.2 METALS 4.3 WET CHEMISTRY 5. SURROGATE SPIKE ANALYSIS RESULTS 5.1 VOLATILES 6. MATRIX SPIKE/ MATRIX SPIKE DUPLICATE SUMMARY ' 6.1 VOLATILES 7. DUPLICATE SUMMARY RESULTS 7.1 METALS ' 7.2 WET CHEMISTRY 8. SPIKE SAMPLE RESULTS 8.1 METALS 8.2 WET CHEMISTRY ' 9. BLANK SUMMARY DATA AND RESULTS 9.1 VOLATILES 9.2 METALS 9.3 WET CHEMISTRY ' 10. INTERNAL STANDARD DATA 10.1 VOLATILES ' LKBO10 S1 ace Long JslBnd , i 1 575 Broad Hollow Road 63 i.694.3040 ' Melville, NY 11747 fix 631.C2Q.843& 1. NYS DEC SUMMARY FORMS LKB010 S2 , NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION ' SAMPLE IDENTIFICATION AND ANALYTICAL REQUIREMENT SUMMARY SDG: LK13010_ Analytical Re uirements Customer Laboratory ME MSvoA we Sample — Sample Code Code MW-1 D 1407015-001 X X X MWAS 1407015-002 X X X ' MW-3C— D 1407015-003 X X X ----� !MW-3S 1407015-004 X X X MW-4D 1407015-005 X X X MW-4S 1407015-006 - X X - - X MW-5D 1407015-007 X X x MW-5S 1407015-008 X X X MW-6D 1407015-009 X X X MW-6S 1407015-010 X t X X MW-7S 1407015-011 X X X MW-8S 1407015-012 X X X ' Field Blank 1407015-013 X X X Trip Blank 1407015-014 X Storage Blank 1407015-015 X ' CLP n- Please indicate year of protocol) I+� TCL/TAL, HSL, Priority Pollutant, LK 010 S3 NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY VOLATILE (VOA) SDG: LK13010 ANALYSES Laboratory Analytical Date 1 DateRecd Date Date Extraction Samp ID I Client Sample ID Matrix Protocol Collected i at Lab Extracted Anal zed Method DF Level Aux Cleanup 1407015-OOIG MW-113 Aqueous ASP8260 30-Jun-14 O1-Jul-14 02-Jul-14 I LOW 1407015-002G MW-IS Aqueous ASP8260 30-Jun-14 01-Jul-14 02-Jul-14 1 LOW 1407015-003G MW-31) Aqueous I ASP8260 30-Jun-14 01-Jul-14 02-Jul-14 1 LOW 1407015-004G MW-3S Aqueous ASP8260 30-Jun-14 01-Jul-14 02-Jul--14 1 LOW 1407015-005G MW41J Aqueous AS118260 30-Jun-14 01-Jul-14 02-Jul-14 I LOW 1407015-006G jMW-4S Aqueous ASP8260 30-Jun-14 01-Jul-14 02-Jul-14 1 LOW 1407015-007G MW-51) Aqueous ASP8260 30-Jun-14 01-Jul-14 02-Jul-14 1 LOW 1407015-0086 IMW-5S Aqueous ASP8260 30-Jun-14 01-Jul-14 02-Jul-14 1 LOW 1407015-009G MW-61) Aqueous ASP8260 30-Jun-14 01-Jul-14 02-Jul-14 1 LOW 1407015-0I0G MW-6S Aqueous ASP8260 30-Jun-14 O1-Jul-14 02-Jul-14 1 LOW 1407015-011G MW-7S Aqueous ASP8260 30-Jun-14 01-Jul-14 02-Jul-14 I LOW 1407015-012G MW-8S Aqueous ASP8260 30-Jun-14 01-Jul-14 02-Jul-14 l LOW 1407015-012GMS MW-8SMS Aqueous ASP8260 30-Jun-14 O1-Jul-14 02-Jul-14 1 LOW 1407015-012GMSD MW-8SMSD Aqueous ASP8260 30-Jun 14 Ol-Jul-14 02-Jul-14 1 LOW 1407015-013G Field Blank Aqueous ASP8260 01-Jul-14 01-Jul-14 02-Jul-14 1 LOW 1407015-014A Trip Blank Aqueous ASP8260 30-Jun-14 01-Jul-14 02-Jul-14 1 LOW 1407015-015A Storage Blank Aqueous ASP8260 01-Jul-14 01-Jul-14 02-Jul-14 1 LOW MELKEOS4 i i i i i i l i i i i i i i i l• i i i NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG . LKBO10 INORGANIC ANALYSIS Laboratory DateRecdl Date Samp ID Client Sample ID Matrix Metals Requested at Lab Analyzed 1407015-001 MW-1D WATER AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01-Jul-14 07/14 1407015-002 MW-1S WATER AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01-Jul-14 07/14 1407015-003 MW-3D WATER AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN. 01-Jul-14 07/14 1407015-004 MW-3S WATER AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01-Jul-14 07/14 1407015-005 MW-4D WATER AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01-Jul-14 07/14 1407015-006 MW-4S WATER AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01-Jul-14 07/14 1407015-007 MW-5D WATER AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01-Jul-14 07/14 1407U15-008 MW-5S' WATER AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR.CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01-Jul-14 07/14 1407015-009 'MW-6D WATER AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01-Jul-14 07/14 1407015-010 MW-6S WAT1;R AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01-Jul-14 1 07/14 1407015-011 BMW-7S WATER AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01-Jul-14 07/14 1407015-012 MW-8S WATER AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01-Jul-14 07/14 1407015-012DUP MW-8SD WATER AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01-Jul-14 07/14 1407015-012MS MW-8SS WATER AG AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01-Jul-14 07/14 1407015-013 Field Blank WATER AG,AL,AS,B,BA,BE,CA,CD,CN,CO,CR,CU,FE,HG,K,MG,MN,NA,NI,PB,SB,SE,TL,V,ZN, 01-Jul-14 ! 07/14 LKBO10 S5 NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG : LKBO10 INORGANIC ANALYSIS Laboratory DateRecd Date , Samp ID Client Sample ID Matrix7 Tests at Lab Analyzed 1407015-001 MW-113 Groundwater SELECT WET CHEMISTRY** 07/01/14 07/14 1407015-002 MW-1S Groundwater SELECT WET CHEMISTRY** 07/01/14 07/14 ' 1407015-003 MW-3D Groundwater SELECT WET CHEMISTRY " 07/01/14 07/14 1407015-004 MW-3S Groundwater SELECT WET CHEMISTRY** 07!01/14 07!14 1407015-005 MW-41D Groundwater SELECT WET CHEMISTRY 07/01/14 07/14 1407015-006 MW-4S Groundwater SELECT WET CHEMISTRY"* 07/01/14 07/14 1407015-007 MW-5D Groundwater SELECT WET CHEMISTRY** 07/01/14 07/14 1407015-008 MW-5S Groundwater SELECT WET CHEMISTRY** 07/01/14 07/14 , 1407015-009 MW-6D Groundwater SELECT WET CHEMISTRY 07/01/14 07/14 I 1407015-010 MW-6S Groundwater SELECT WET CHEMISTRY** 07/01/14 07/14 1407015-011 MW-7S Groundwater SELECT WET CHEMISTRY** 07/01/14 07/14 1407015-012 MW-8S Groundwater SELECT WET CHEMISTRY** 07/01/14 07/14 ' 1407015-012DUP MW-8SDUP Groundwater SELECT WET CHEMISTRY** 07/01/14 07/14 1407015-012MS MW-8SMS Groundwater SELECT WET CHEMISTRY** 07/01/14 07/14 i 1407015-013 Field Blank Field Blank SELECT WET CHEMISTRY** 07/01/14 07/14 ** Alkalinity,Total(As CaCO3);Biochemical Oxygen Demand ; Bromide ;Chemical Oxygen Demand ; Chloride;Chromium, Hexavalent;Color; Hardness(As CaCO3); Nitrate as N; Nitrite as N ; Nitrogen,Ammonia(As N) ; Nitrogen, Kjeldahl,Total ; Phenolics,Total Recoverable;Sulfate;Total Dissolved Solids ;Total Organic Carbon ; t LKB010 S6 ' i aci Long Island r i575 Broad Holiow Road eg 631.694.3040 Melville,NY 11747 631 420.8436 i 2. CHAIN OF CUSTODY DOCUMENTATION II I i i 1 ' LKB010 S7 labs Q2664 EXTERNAL CHAIN OF CUSTODY 575 Broad Hollow Rd.,Melville,NY 11747 (631)694-3040 Fax:(631)420-8436 www.h2mlabs.com CLIENT: LAO IH2M SDG NO: Cl PROJECT NAME/NUMBER NOTES: Project Contact. e1 c Z 0 Phone Number. SAMPLERS:(Signature)/Client 05 --t--t �o �. A � � ` L1.(.� W Q PIS/Quote# /S I3 v� ,� V DELIVERABLES: f TURNAROUND TIME: o m ANALYSIS REQUESTED d `� 7 z Vi � � a � � DATE TIME MATRIX FIELD I.D. - LAB I.D.NO. REMARKS: AQ r4W-35 10 a 1 2 a 3o TOO AQ MO-30 1C1 1 1 2 1 22 :30 AQ tw-SS 10 Z 1 2 t 2 Z --Q 3o qV AQ io 1 .91 30 10:�t0 Q �'tJ Z11 1211 2, 6 30 100 AQ MU-9D 10 3o 12W AQ J0 Z 613o 1:00 AQ 10 to 60) : Aa l c a I a I a a —moo Relinqulsheti by:(Signare) Date: Time: Received by:(Signature) e: Time: LABORATORY USE ONLY /' �""""�;:%�"� Samples were: elfin uis (Signature) 7111A me: eceived tf (Signature) Da e: Time: 1.Shipped or Hand Delivered_Airbill# q y;( 9 ) y.( 9 ? COC Tape was: 1.Present on outer package: Y or N Relinquished by:(Signature) Date: Time: Received by:(Signature) Date: Time: 2.Unbroken on outer package: Y or N,7 Z, Relinquished by:(Signature) Date: Time: Received by:(Signature) Date: Time /: 0, 3 L 3 3 CC-- 111 J WHITE COPY-ORIGINAL YELLOW COPY-CLIENT PINK COPY- LABORATORY M = IM = M M = = r = = = = = = M If575 abs EXTERNAL CHAIN OF CUSTODY Broad Hollow Rd.,Melville,NY 11747 02665 31)694-3040 Fax:(631)420-8436 ww.h2m[abs.com CLIENT: kB H2M SDG NO: PROJECT NAME//NUMBER NOTES: Project Contact. n a Phone Number. OR SAMPLERS:(Signature)/Client m Gn LMN g �' J �3 PIS/Quote# DELIVERABLES: J r TURNAROUND TIME: 5 ANALYSIS REQUESTED DATE TIME MATRIX FIELD I.D. LAB I.D.NO. REMARKS: V T1 4130 '2;30 mo_ Is )G) ) 2- I 2 .), ---U 6130 3.617 RQ MQ- 10 10 21. 9 ] la la I 1 0 7t 1 10 Q knk /0 Q ] a , a Relin uishhed y:(Sign ie) WDate: Time: Received by:(Signature) Date: Time: LABORATORY USE ONLY � 1Samples were: Ii uished (Signature)oj Time: ved by:(Signature) Time: 1.Shipped_,or Hand Delivered_Airbill# COC Tape was: 1.Present on outer package: Y or N Relinquished by:(Signature) Date: Time: Received by:(Signature) Date: Time: 2.Unbroken on outer package: Y or N Relinquished by:(Signature) ata me: Received by:(Signature) Date: Time: WHITE COPY-ORIGINAL YELLOW COPY-CLIENT PINK COPY-LABORATORY _-�LKBO10_S9_ PACE AX LYTICAL TSL/ 0 1,D 575 Broad Hollow Road Sample Receipt Checklist aceAnal1/tical� Melville,NY 11747 TEL:(631)694-3040 FAX:(631)420-8436 Website:www.pacelabs.com Client Name LKB Date and Time Received: 7/1/2014 10:40:00 AM d Work Order Number: 1407015 RcptNo: 1 Received by: JoshLaedke Completed by: Reviewed by: �— Completed Date: 7/1/2014 11:04:42 AM Reviewed Date: 7/6/2014 12:34:55 PM Carrier name: Client Chain of custody present? Yes No ❑ Chain of custody signed when relinquished and received? Yes d❑ No ❑ Chain of custody agrees with sample labels? Yes © No ❑ Are matrices correctly identified on Chain of custody? Yes ❑/ No❑ Is it Gear what analyses were requested? Yes © No❑ Custody seals intact on sample bottles? Yes ❑ No❑ Not Present Samples in proper containerlbottle? Yes No❑ Were correct preservatives used and noted? Yes No❑ NA ❑ Preservative added to bottles: Sample Condition? Intact Broken❑ Leaking ❑ Sufficient sample volume for indicated test? Yes ❑ .'No❑ Were container labels complete(ID,Pres,Date)? Yes © No ❑ All samples received within holding time? Yes © No ❑ Was an attempt made to cool the samples? Yes IV] No U NA ❑ ' All samples received at a temp.of>0°C to 6.0°C? Yes k No❑ NA ❑ Response when temperature is outside of range: Sample Temp.taken and recorded upon receipt? Yes No ❑ 0.3 To 3.10 , Water-Were bubbles absent in VOC vials? Yes No C No Vials ❑ Water-Was there Chlorine Present? Yes ❑ No ❑ NA 0 Water-pH acceptable upon receipt? Yes k No❑ No Water ❑ Are Samples considered acceptable? Yes No ❑ I Custody Seals present? Yes G No L-11 Airbili or Sticker? Air Bill ❑ Sticker ❑ Not Present Airbill No: , Case Number: SDG: SAS: LKBO10 Any No response should be detailed in the comments section below,if applicable. , Client Contacted? LlYes ElNo 21 NA Person Contacted_ , Contact Mode: ❑ Phone: ❑ Fax: ❑ Email: ❑ In Person: Client Instructions: Date Contacted: Contacted By: , Regarding: Comments: 11 for ms/msd 8s composited due to different colors of sample bottles mslmsd and tb not noted on COC CorrectiveAction: Page 1 of 1 LK6010 S10 , d li .I ' INTERNAL CHAIN OF CUSTODY 7 f� CLIENT: /I DELIVERABLES: S TURN AROUND TIME: ,l SDG: [ �) ,V CASE#: MATRIX: H CHE 1 /y REMARKS: ' RECEIVED BY: J9 SIGNATURE: DATE: E: CLIENT DATE BOTTLE #OF SAMPLE LAB# COLLECTED TYPE BOTTLES TESTS REOUESTED ID )-o °h6'1,3()Ill i 2. I `0 7- 3.3. 3 4. 5. 6. 7. C/ _0 i 9. o 10. .jIF 13. E Ids A 13 1 141 t IB ju 9 013 Q 15.Sr 6fei 4 16. 17. 18. ' 19. 20. L001-r1 GCMS VOLATILE 99 1 LKB010 S11 CLIENT: /t J SDG: pO } INTERNAL CHAIN OF CUSTODY PURPOSE OF DATE TIIv1E SAMPLE SAMPLE BOTTLE CHANGE OF INIT. RELINQUISHED BY RECEIVED BY TYPE CUSTODY �Ii�JN 377 1 1 . 1 1 r 1 r I L001-r1 GCMS VOLATILE 100 LKB010 S12 d INTERNAL CHAIN OF CUSTODY i� L9 CLIENT: ! DELIVERABLES: ' ,6 -200 TURN AROUND TIME: 21401 ' SDG CASE#: MATRIX: (.�- t`� pH CHECK rN REMARKS: ,�_►-� RECEIVED BY: SIGNATURE:? DATE'; &TPVIE:A-410 CLIENT DATE BOTTLE #OF SAMPLE LAB# COLLECTED TYPE BOTTLES TESTS REQUESTED ID 2. �Cie) 4. I � V 1 g. J 1 � I ' 12. `v z 1 / 0 13 1 1a. 1s, 1e. 17. /Al 18. ' 19. 20. L001 r1 METALS 121 ' LKB010 S13 CLIENT: SDG: .o INTERNAL CHAIN OF CU-STODY PURPOSE OF DATE TIIv1E SAMPLE SAMPLE BOTTLE CHAIvTGE OF IIQTT. RELINQUISHED BY RECEIVED BY TSE CUSTODY i 3w I a 1 1 L001 r1 METALS 122 LKB010 S14 , r INTERNAL, C D CHAIN OF CUSTODY �I 1 CLIENT: �i/C� DELNERABLES:PeS )DQ TURN AROUND TIME: Z/V k f ` r� 1 iSDG: L 61 l` CASE: MATRIX: W pH CHECK60r N REMARKS: 1 RECEIVED BY: _SIGNATURE: DATE&&ATIME:/6 1 CLIENT DATE BOTTLE #OF SAMPLE LAB# COLLECTED TYPE BOTTLES TESTS REQUESTED ID 1. by a�r ���jly5 _ �i��c�sw'�`rr'r�� I 1 w 2. - rs 2Gl 11.7j�fZif � - 6. 1 7. 135 i10. 11. 1 12. s � 13. i i 151 5 16. Vi 17. �`V 1 I V t J •� 18. 1 19. 20. L001 r1 WET CHEMISTRY 191 =� 1 LKB010 S15 I CLIENT: SDG: O ' INTERNAL CHAIN OF CUSTODY SAMPLE SAMPLE BOTTLE POSE OF DATE TIlV]E RELINDISHED BY y TYPE CHANGE OF INIT. Q RECEIVED B CUSTODY c� S/ AJ ?5 � J vi M2, kll I c-l� �i // - o.�o �os•v L !t//� t T•ria ' D 8 _ gAf n For co i L001 r1 WET CHEMISTRY 192 LKB010 S16 ' 25ceLong Island i ' 575 Broad Hollow Road e:: 631 094.3040 Melville,NY 1174 7 031.420.8430 3. SDG NARRATIVES i ' LK13010 S17 _. acetamIs/and 575 Broad Hollow Road tel 631.694.3040 ' Melville.NY 11747 fax 631.420.8436 SDG NARRATIVE FOR VOLATILES ANALYSES SAMPLE(S)RECEIVED: 7/1/14 SDG#: LKBO10 For Sample(s): MW-1D MW-4S MW-7S MW-IS MW-51) MW-8S MW-31) MW-5S Field Blank MW-3S MW-61) Trip Blank MW-4D MW-6S Storage Blank ' MW-12D Trip Blank The above water sample(s) and blank(s) was/were analyzed by EPA method 8260C for a select r list of volatile organic analytes and reported in accordance with NYSDEC ASP 2005 Category B. All Q. C. data and calibrations met the requirements of the method, and no problems were encountered with sample analysis. The following should be noted: Sample MW-8S was analyzed as the matrix spike/matrix spike duplicate. All percent recoveries and RPDs were within Q. C. limits. A lab fortified blank was analyzed, and recoveries indicate good method efficiency. In the initial calibrations, average response factors were employed for all targeted analytes. the variability %D for some compounds In the continuing calibration verification(s) (CCV), ty( ) , was above 20%. These analytes are flagged with a "Z" qualifier in the spiked analyses. (They were not found in the samples.). I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: July 29, 2014 r Ursula Middel Quality Analyst , LKB010 S18 C c Long Island j I SDG NARRATIVE FOR METALS ANALYSES ' SAMPLE(S)RECEIVED: 7/01/14 SDG#: LKBO10 For Sample(s): MW-1D 1\4W-5S MW-IS MW-6D MW-3D MW-6S MW-3S MW-7S MW-4D MW-8S ' MW-4S FIELD BLANK MW-5D t Sainple(s) was/were received by Pace Analytical Services, Inc. for TAL metals plus boron and cyanide analysis. Samples were prepared and analyzed using EPA method 200.7 with a TS ICAP 6000 instrument, ' method 245.1 with a Leeman HYDRA mercury analyzer and method SM450OCN C E for cyanide. ' Sample MW-8S was utilized for Q.C. analysis and reporting. The spike analysis did not meet acceptance criteria for silver. The sample was post spiked, reanalyzed and recovered at 111.4%. Silver data was reported flagged"N" on forms 1 and 5A. ' Due to matrix interferences samples MW-31), MW-3S and MW-8S required a 1:10 dilution for Silver. The silver reporting limit was elevated as required. ' No other issues were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and ' conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory ' Manager or his designee, as verified by the following signature. Date Reported: July 31, 2014 ' Vincent Stancampi o 1 ' LKB010 S19 1 n ace Lnng Island I SDG NARRATIVE FOR WET CHEMISTRY SAMPLE(S)RECEIVED: 7/01/14 ' SDG#: LKB010 For Sample(s): ' MW-1D MW-4S MW-7S MW-1S MW-51) MW-8S MW-3D MW-5S FIELD BLANK MW-3S MW-6D MW-4D MW-6S Sample(s)was/were received by Pace Analytical Services, Inc for select wet chemistry analysis. ' Samples were prepared and analyzed using the following methods: Alkalinity SM2320B Hexavalent Chromium SM3500-Cr D r Anions— Cl, SO4, Br EPA 300.0 Nitrate EPA 353.2 Biochemical Oxygen Demand SM5210B Nitrite EPA 353.2 , Chemical Oxygen Demand EPA 410.4 Phenols EPA 420.1 Color SM2120B Total Dissolved Solids SM2540C Ammonia EPA 350.1 Total Kjeldahl Nitrogen EPA 351.2 Hardness SM2340C Total Organic Carbon EPA 9060 ' Sample MW-8S was utilized for Q.C. analysis and reporting. Due to the dilutions used for BOD analysis, samples MW-31), MW-3S and MW-8S reporting limits ' were elevated to < 4 mg/l. Due to matrix interferences sample MW-8S required a 1:5 dilution for hexavalent chromium. The , reporting limit was elevated to < 0.10 mg/1 as required. Samples were diluted and reanalyzed as required to keep instrument readings within calibration ranges , or to minimize matrix interferences. No other issues were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of ' the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: August 7, 2014 , Vincent Stancam ano LKB010 S20 1 1 /_:.. 5ceLnngIsand 575 Broad Hollow Road 631.694.3040 Melville.NY 11747 531.420.8436 1 1 4. SAMPLE REPORTS ' 4.1 VOLATILES 4.2 METALS 4.3 WET CHEMISTRY 1 1 1 1 1 i 1 i 1 1 LKB010 S21 aoLanglsland 575 Broad Hollows Road fEs. 631.694.3040 Melville,NY 11747 `ax 631.420.8436 1 4.1 VOLATILES 1 1 1 i i i 1 LKB010 S22 ' ' / �,• amanglsland ! 575 Broad Hollow Road tel.631.694.3040 Melville, NY 11747 fax 631.420.8436 ' QUALIFIERS FOR REPORTING ORGANICS DATA Value - If the result is a.value greater than or equal to the quantification limit, report the value. 1 U - Indicates compound was analyzed for but not detected. The sample quantitation limit must be corrected for dilution and for percent moisture. For example, 10U for phenol in water if the sample final volume is the protocol-specified final volume. If a 1 to 10 dilution of extract is necessary, the reported limit is 100 U. For a soil sample, the value must also be adjusted for percent moisture. For example, if the sample had 24%moisture and a 1 to 10 dilution factor, the sample quantitation limit for phenol (330 U)would be corrected to: ' (-J 00 U) 100%moisture D x df where D= 100 and df-dilution factor ' lao—a4 For example,at 24%moisture,D= 100 =0.76 ' (300 U) 76 x 10 -4300 U rounded to the appropriate number of significant figures ' For sennivolatile soil samples, th:, ea-tract must be concentrated to 0.5 mL, and the sensitivity of the analysis is not compromised by the cleanup procedures. Similarly,pesticide samples subjected to GPC are concentrated to 5.0 mL. Therefore,the CRQL values in Exhibit C will apply to all samples,regardless ' of cleanup. However, if a sample extract cannot be concentrated to the protocol-specified volume (see Exhibit C),this fact must be accounted for in reporting the sample quantitation limit. ' J - Indicates an estimated value. This flag is used either when estimating a concentration for tentatively identified compounds where a 1:l response is assumed or when the mass spectral data indicates the presence of a compound that meets the identification criteria but the result is less than the specified quantification limit but greater than zero. (e.g.: If limit of quantification is 10 ugfL, and a ' concentration of 3 ug/i, is calculated, report as 3J) The sample quantitation limit must be adjusted for dilution as discussed for the U flag. ' N - Indicates presumptive evidence of a compound. This flag is only used for tentatively identified compounds, where the identification is based on a mass spectral library search. It is applied to all TIC results. For generic characterization of a TIC, such as chlorinated hydrocarbon, the N code is not used. ' P - This flag is used for a pesticide/Aroclor target analyte when there is greater than 25% difference for detected concentrations between the two GC columns (see Form X). The lower of the two values is reported of Form I with a "P". ' C - This flag applies to pesticide results when the identification has been confirmed by GC/MS.. If GC/MS confirmation was attempted but was unsuccessful, do not apply this flag, instead use a Laboratory defined flag,discussed below. 1 ' LKBO10 S23 ace Long Island ' 575 Broad Hollow Road tel.531,694.3040 Melville, NY 11747 fax 631.420.8436 B - This flag is used when the analyte is found in the associated blank as well as in the sample. It indicates possible probable blank contamination and warns the data user to take appropriate action. This ' flag must be used for a TIC as'well as for a positively identified targ et compound. E - This flag identified compounds whose concentrations exceed the calibration range of the GC/N4S instrument for that specific analysis. If one or more compounds have a response greater than full ' scale, except as noted in Exhibit D,the sample or extract must be diluted and re-analyzed according to the specifications in Exhibit D. All such compounds with a response greater than full scale should have the concentration flagged with an "E" on the Form I for the original analysis. If the dilution of the extract causes any compounds identified in the first analysis to be below the calibration ranges in the second ' analysis, then the results of both analyses shall be reported on separate copies of Form 1. The Form I for the diluted sample shall have the "DL" suffix appended to the sample number. NOTE: For total xylenes, where three isomers are quantified as two peaks, the calibration range of each peak should be considered ' separately, e.g. a diluted analysis is not required for total xylenes unless the concentration of the peak representing the single isomer exceed 200 ug/L or the peak representing the two coeluting isomers on that GC column exceed 400 uglL. Similarly, if the two 1,2-Dichloroethene isomers coelute,a diluted analysis ' is not required unless the concentration exceed 400 ug/L. D - This flag identifies.all compounds identified in an analysis at a secondary dilution factor. If a sample or extract is re-analyzed at a higher dilution factor, as in the "E" flag above, the "DL" suffix is ' appended to the sample number on the Form I for the diluted sample, and all concentration values reported on that Form I are flagged with the "D" flag. This flag alerts data users that any discrepancies between the concentrations reported may be due to dilution of the sample or extract. 1 A - This flag indicates that a TIC is a suspected aldol -condensation product. X - Other specific flags may be required to properly define the results. If used,they must be fully ' described and such description attached to the Sample Data Summary Package and the SDG narrative. Begin by using "X". If more than one flag is required use "Y" and "Z" as needed. If more than five qualifiers are required for a sample result, used the "X" flag to combine several flags as needed. For , instance, the X flag nught combine "A", "B", and D flags for some samples. The laboratory defined flags limited to the letters "X";"Y" and"Z". The combination of flags "BV or"UB"is expressly prohibited. Blank contaminants are flagged "B" only ' when they are detected in the sample. Y Suspected secondary contamination. ' X Analyte is suspected column bleed Z Analyse had a%D greater then 20%in the daily CCV ' LKB010 S24 ' 1A EPA SAMPLE NO. ' VOLATILE ORGANICS ANALYSIS DATA SHEET MW-1D ' Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKS010 Matrix: (soil/water) WATER Lab Sample ID: 1407015-001G Sample wt/vol: 5 (g/mL) mL Lab File ID: G26233.D Level: (low/med) LOW Date Received: 07/01/14 ' % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (man) Dilution Factor: 1.00 ' Soil Extract Volume: - (,pL) Soil Aliquot Volume (pL) CONCENTRATION UNITS: CAS NO. COMPOUND (pg/L or pg/Kg) pg/L Q 74-87-3 Chloromethane 5 U� 75-01-4 Vinyl chloride 5 U ' 74-83-9 Bromomethane 5 U 75-00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane 5 U ' 75-35-4 1,1 -Dichloroethene 5 U 74--88-4 Iodomethane 5 U 108-05-4 1 Vinyl acetate 5 U ' 67-64-1 Acetone - 5 U 75715-0 t Carbon disulfide 5 U 75-09-2 Methylene chloride _ 5 U 156-60- trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichloroethane 5 U - — - _ 156-59-2 cis-1,2-Dichloroethene I_ 5 U i 78-93-3 2-Butanone 5 U 74-97-5 B omochloromethane 5 U ' 67-66-3 Chloroform 5 U - — ----- ------ ---- 71-55-6 1,1,1-Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U - - - 107-06-G 07-00 66-2 1,2-Dichloroethane 5 U r-- 79-01-6- Trichloroethene _ _ 5 _U ! 78-87-5 1,2-Dichloropropane 5 U 74-95-3 Dibromomethane - --- - 5 U i 75-27-4 Bromedichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene__ 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-88-3 Toluene -__ --_--- _ 5 i U -- 10061-02-6 trans-1,3-Dichloropropene 5 j U 79-00-5 1,1,2-Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U ' 591-78-6 2-Hexanone 5 U 124-48-1 Dibromcchloromethane- 5 U L -- 106-93-4 1,2-Dibromoethane 5 U ' FORM I VOA - 1 OLM04.2 ' LKBO10 S25 lg EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET ' MW-1D Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKB010 Matrix: (soil/water) WATER Lab Sample ID: 1407015-001G ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26233.D , Level: (low/med) LOW Date Received: 07/01/14 % Moisture: not dec. Date Analyzed: 07/02/14 ' GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pL) Soil Aliquot Volume (pL) , CONCENTRATION UNITS: ' CAS NO. COMPOUND (pg/L or pg/Kg) pg/L 4 108-90-7 Chlorobenzene 5 U 110-57-6 trans-1,4-Dichloro-2-butene 5 U r 100-41-4 Ethylbenzene 5 U ' 630-20-6 1,1,1,2-Tetrachloroethane _ 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene 5 U j 75-25-2 Bromoform 5 U r 79-34-5 1,1,2,2-Tetrachloroethane 5 U 96-18-4 1,2,3-Trichlorooropane _ 5 U 106-46-7 1,4-Dichlorobenzene 5 U 95-50-1 1,2-Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane _ 5 U r FORM I VOA - 2 OLM04.2 LKBO10 S26 ' 1F EPA SAMFLE NO. ' VOLATILE ORGANICS ANALYSIS DATA SHEET MW-1D TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LKE SAS No. : SDG No. ; LKB010 Matrix: (soil/water) WATER Lab Sample ID: 1407015-0010 ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26233.D Level: (low/med) LOW Date Received: 07/01/14 Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 ' Soil Extract Volume: (ul) Soil Aliquot Volume: 0 (uL) j CONCENTRATION UNITS: ' Number TICS found: 0 (lag/L or pg/Kg) L CAS NUMBER COMPOUND NAME RT EST.CONC. Q I i I 1 � I i I i ' FORM I VOA-TIC 0LM04.2 LKB010 S27 lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET ' MW-1S Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-002G ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26234.D ' Level: (low/med) LOW Date Received: 07/01/14 % Moisture: not dec. Date Analyzed: 07/02/14 ' GC Column: Rtx-624 ID: .16 (man) Dilution Factor: 1.00 Soil Extract Volume: (pL) Soil Aliquot Volume (pL) ' CONCENTRATION UNITS: CAS NO. COMPOUND (pg/L or pg/Kg) pg/L Q ' 74-87-3 Chloromethane 5 U 75-01-4 Vinyl chloride 5 --J U - -- 74-83-9 Bromomethane 5 U 75-00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U , 74-88-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5 U 67-64-1 Acetone 5 U 75-15-0 Carbon disulfide 5 U ' 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichloroethane 5 U - - - - 1.56-59-2 cis-1,2-Dichloroethene- _ 5 U 78-93-3 2-Butanone _ 5 U 74-97-5 Bromochloromethane 5 U 67-66-3 Chloroform 5 U , 71-55-6 1,1,1-Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U , 107-06-2 1,2-Dichloroethane 5 U 79-01-6 Trichloroethene 5 U 78-87-5 1,2-Dichloropropane 5 U 74-95-3 Dibromomethane 5 U ' 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U --------------- 108-86-3 Toluene 5 U ' 10061-02-6 trans-1,3-Dichloropropene 5 U 79-00-5 1,1,2-Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U 591-78-6 2-Hexanone 5 U ' 124-46-1 Dibromochloromethane 5 U 106-93-4 1,2-Dibromoethane 5 U FORM I VOA - 1 OLM04.2 ' LKB010 S28 ' 1B EPA SAMPLE NO. ' VOLATILE ORGANICS ANALYSIS DATA SHEET MW-1S ' Lab Name: PACE ANALYTICAL, Contract: Lab Code: 10478 Case No. : LIB SAS No. : SDG No. : LKBO10 ' Matrix: (soil/water) WATER Lab Sample ID: 1407015-002G Sample wt/vol: 5 (g/mL) mL Lab File ID: G26234.D ' Level: (low/mod) LOW Date Received: 07/01/14 ' % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 ' Soil Extract Volume: (pL) Soil Aliquot Volume (pL) CONCENTRATION UNITS: ' CAS NO. COMPOUND (pg/L or pg/Kg) pg/L Q 108-90-7 Chlorobenzene 5 U 110-57-6 trans-1,4-Dichloro-2-butene 5 U ' 100-41-4 Ethylbenzene 5 U 630-20-6 1,1,1,2-Tetrachloroethane 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene 5 U - - --- - - 75-25-2 Bromoform 5 U J 79-34-5 1,1,2,2-Tetrachloroethane 5 U 96-18-4 1,2,3-Trichloropropane 5 U -- - - - - - 106-46-7 1,4-Dichlorobenzene 5 U ' 95-50-1 1,2-Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U ' FORM I VOA - 2 OLM04.2 ' LKB010 S29 IF EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET ,• , TENTATIVELY IDENTIFIED COMPOUNDS MW-1S Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LK13010 Matrix: (soil/water) WATER Lab Sample ID: 1407015-002G ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26234.D Level: (low/med) LOW Date Received: 07/01/14 Moisture: not dec. Date Analyzed: 07/02/14 ' GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (ul) Soil Aliquot Volume: 0 (IAL) , CONCENTRATION UNITS: Number TICS found: 0 (pq/L or fag/Kg) CAS NUMBER COMPOUND NAME RT EST,CONC. Q 1 FORM I VOA-TIC OLM04.2 , LKBO10 S30 , lA EPA SAMPLE NO. ' VOLATILE ORGANICS ANALYSIS DATA SHEET MW-3D ' Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKB010 ' Matrix: (soil/water) WATER Lab Sample ID: 1407015-003G ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26235.D Level: (low/med) LOW Date Received: 07/01/14 ' % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 ' Soil Extract Volume: (pL) Soil Aliquot Volume (pL) CONCENTRATION UNITS: ' CAS NO. COMPOUND - - — (µg/L or }ig/Kg) U/L 4 74-87-3 Chloromethane 5 T- U 75-01-4 Vinyl chloride 5 U 74-83-9 Bromomethane 5 U 75-00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane 5 U - -- --- -- i 75-35-4 1,1-Dichloroethene 5 U 74-88-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5 U 67-64-1 Acetone 5 U 75-15-0 Carbon disulfide 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans 1,2-llichloroethene 5 U - ----- ----- ' 75-34-3 1,1-Dichloroethane __ 5 — U 156-59-2 cis-1,2-Dichloroethene 1 J 7B-93-3 2-Butanone 5 U 74-97-5 Bromochloromethane 5 U - - -- 67-66-3 Chloroform 5 U 71-55-6 1,1,1-Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U ' 107-06-2 1,2-Dichloroethane 5 U 79-01-6 Trichloroethene 1 J 78-87-5 1,2-Dichloropropane 5 U ' 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichloromethane 5 L' 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U ----- - - 108-88-3 Toluene 5 U ---- - 10061-02-6 trans-1,3-Dichloropropene 5 U 79-00-5 1,1,2-Trichloroethane 5 U j 127-18-4 Tetrachloroethene 5 U -- -- 591-78-6 2-Hexanone 5 -U 124-48-1 Dibromochloromethane _ 5 U 106-93-4 1,2-Dibromoethane 5 U FORM I VOA - 1 OLM04.2 ' LKB010 S31 1B EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET ' MW-3D Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-003G ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26235.D ' Level: (low/med) LOW Date Received: 07/01/14 % Moisture: not dec. Date Analyzed: 07/02/14 ' GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: — (pL) Soil Aliquot Volume CONCENTRATION UNITS: ' CAS NO. COMPOUND (pg/L or pg/Kg) pg/L 4 108-90-7 Chlorobenzene 4 J _ 110-57-6 trans-1,4-Dichloro-2-butene 5 U- 100-41-4 Ethylbenzene 5 U , 630-20-6 1,1,1,2-Tetrachloroethane 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene 5 U ' 75-25-2 Bromoform 5 U 79-34-5 1,1,2,2-Tetrachloroethane 5 U 96-18-4 1,2,3-Trichloropropane 5 _ U 106-46-7 1 1,4-Dichlorobenzene 5 U 1 ' 95-50-1 1,2-Dichlorobenzene 5 U 96-12-8 , 1,2-Dibromc-3-chloropropane 5 U FORM I VOA - 2 OLM04.2 ' LKBO10 S32 , 1F EPA SAMPLE N0. ' VOLATILE ORGANICS ANALYSIS DATA SHEET MW-3D TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: PACE ANALYTICAL Contract: _ ' Lab Code: 10478 Case No. : LKS SAS No. : SDG No. : LKB010 Matrix: (soil/water) WATER Lab Sample ID: 1407015-003G ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26235.D Level: (low/med) LOW Date Received: 07/01/14 ' % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pl) Soil Aliquot Volume: 0 (�iL) CONCENTRATION UNITS: ' NumberrTICs found: r 0 (jzg/L or ug/Kg) 119/L CAS NUMBER COMPOUND NAME RT EST.CONC. Q FORM I VOA-TIC OLM04.2 ' LKBO10 S33 lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET , MW-3S Lab Name: PACE ANALYTICAL Contract: , Lab Code: 10478 Case No. : LIB SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-004G Sample wt/vol: 5 (g/mL) mL Lab File ID: G26236.D ' Level: (low/med) LOW Date Received: 07/01/14 % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pL) Soil Aliquot Volume (pL) ' CONCENTRATION UNITS: ' CAS NO. COMPOUND (pg/L or pg/Kg) pg/L Q 74-87-3 Chloromethane 5 U 75-01-4 Vinyl chloride 5 U 74-83-9 Bromomethane 5 U 75-00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane_ 5 U , 75-35-4 1,1-Dichloroethene 5 U 74-88-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5 U 67-64-1 Acetone 5 U 75-15-0 Carbon disulfide 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichl.oro_ethane 5 U ' 156-59-2 cis-1,2-Dichloroethene 5 U 78-93-3 2-Butanone 5 U 74-97-5 Bromochloromethane 5 U 67-66-3 Chloroform 5 U , 71-55-6 1,1,1-Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U 107-06-2 1,2-Dichloroethane 5 U ' 79-01-6 Trichloroethene 5 U 78-87-5 1,2-Dichloropropane 5 U 74-95-3 Dibromomethane 5 U ' 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-88-3 Toluene 5 U , 10061-02-6 trans-1,3-Dichloropropene 5 U 79-00-5 1,1,2-Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U 591-78-6 2-Hexanone 5 U 124-48-1 Dibromochlo_romethane 5 U 106-93-4 1,2-Dibromoethane 5 U FORM I VOA - 1 OLM04.2 ' LKBO10 S34 ' 1B EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MW-3S Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 ' Matrix: (soil/water) WATER Lab Sample ID: 1407015-004G Sample wt/vol: 5 (g/mL) mL Lab File ID: G26236.D Level: (low/med) LOW Date Received: 07/01/14 % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 ' Soil Extract Volume: (pL) Soil Aliquot Volume _ (pL) CONCENTRATION UNITS: CAS NO. COMPOUND (pg/L or pg/Kg) µg/L Q 108-90-7 Chlorobenzene 5 U 110-57-6 trans-1,4-Dichloro-2-butene 5 U ---- - — __ 100-41-4 Ethylbenzene 5 U 630-20-6 1,1,1,2-Tetrachloroethane 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene 5 U 75-25-2 Bromoform 5 _ U 79-34-5 1,1,2,2-Tetrachloroethane _ 5 U 96-18-4 1,2,3-Trichloropropane 5 U 106-46-7 1,4-Dichlorobenzene 5 U ---- 95-50-1 1,2-Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U ' FORM I VOA - 2 OLM04.2 ' LKBO1O S35 IF EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS MW-3S Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-004G Sample wt/vol: 5 (g/mL) mL Lab File ID: G26236.D Level: (low/med) LOW Date Received: 07/01/14 % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: Soil Aliquot Volume: 0 (PL) CONCENTRATION UNITS: Number TLCs found: 0 (}zg/L or ug/Kg) Pg/L CAS NUMBER COMPOUND NAME RT EST.CONC. FORM I VOA-TIC 0LM04.2 LKB010 S36 , lA EPA SAMPLE NO. ' VOLATILE ORGANICS ANALYSIS DATA SHEET MW-4D ' Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No.: SDG No. : LKB010 ' Matrix: (soil/water) WATER Lab Sample ID: 1407015-005G Sample wt/vol: 5 (g/mL) mL Lab File ID: G26237.D Level: (low/med) LOW Date Received: 07/01/14 % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 ' Soil Extract Volume: (pL) Soil Aliquot Volume (}iL) CONCENTRATION UNITS: CAS NO. COMPOUND (pg/L or pg/Kg) H/L Q 74-87-3 Chloromethane 5 U 75-01-4 Vinyl chloride 5 U 74-83-9 Bromomethane ' 5 U 75-00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane 5 U -- - 75-35-4 1,1-Dichloroethene 5 U 74-88-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5 U 67--64-1 Acetone 5 U 75-15-0 Carbon disulfide 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene--------4--------- 5 U ' 75-34-3 1,1-Dichloroethane 5 U 156-59-2 cis-1,2-Dichloroethene 5 U 78-93-3 2-Butanone 5 U 74-97-5 Bromochloromethane 5 j U ' 67-66-3 Chloroform - - 5 — U 71-55-6 1,1,1-Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U r 107-06-2 1,2-Dichlorcethane 4 J 79-01-6 Trichloroethene 5 U 78-87-5 1,2-Dichloropropane 8 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U ' 108-8883 Toluene _ _5 10061-02-6 trans-1,3-Dichloropropene 5 U 79-00-5 1,1,2-Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U ' 591-78-6 2-Hexanone 5 U I 124-48-1 Dibromochloromethane 5 U 106-93-4 1,2-Dibromoethane 5 U ' FORM I VOA - 1 OLM04.2 LKB010 S37 1 1B EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET , MW-4D Lab Name: PACE ANALYTICAL, Contract: Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-005G ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26237.D Level: (low/mad) LOW Date Received: 07/01/14 % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pL) Soil Aliquot Volume (pL) ' CONCENTRATION UNITS: CAS NO. COMPOUND (}ig/L or pg/Kg) pg/L Q 108-90-7 Chlorobenzene 3 J 110-57-6 trans-1,4-Dichloro-2-butene 5 U 100-41-4 Ethylbenzene 5 U U ' 630-20-6 1,1,1,2-Tetrachloroethane 5 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene 5 U 75-25-2 Bromoform 5 U 79-34-5 1,1,2,2-Tetrachloroethane 5 U 96-18-4 1 1,2,3-Trich1oropropane 5 U 106-46-7 1,4-Dichlorobenzene 5 U 95-50-1 1,2-Dichlorobenzene5 U ' ~ 96-12-8 j 1,2-Dibromo-3-chloropropane 5 U FORM I VOA - 2 OLM04.2 LKBO10 S38 1F EPA SAMPLE NO. ' VOLATILE ORGANICS ANALYSIS DATA SHEET MW-4D TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LKS SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015 005G ' Sample wt/vol: 5 (g/mL) mL Lab File ID: C26237.D Level: (low/med) LOW Date Received: 07/01/14 ' % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (ill) Soil Aliquot Vo=ume: 0 (uL) CONCENTRATION UNITS: Number TICS found: 0 (pg/L or pg/Kg) Pg/L CAS NUMBER COMPOUND NAME RT EST.CCNC. i Q ' FORM I VOA-TIC OLM04.2 ' LKB010 S39 IA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET ' MW-4S Lab Name: PACE ANALYTICAL Contract: , Lab Code: 10478 Casa No. : LRB SAS No. : SDG No. : LIBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-006G i Sample wt/vol: 5 (g/mL) mL Lab File ID: G26238.D ' Level: (low/med) LOW Date Received: 07/01/14 % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pL) Soil Aliquot Volume (pL) - CONCENTRATION UNITS: ' CAS NO. COMPOUND (pg/L or pg/Rg) pg/L Q 74-87-3 Chloromethane A5 U 75-01-4 Vinyl chloride 5 U �- - - 74-83-9 i Bromomethane ' S U 75-00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U 74-88-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5 U 67-64-1 Acetone 5 U ' 75-15-0 Carbon disulfide 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichloroethane 5 U ' 156-59-2 cis-1,2-Dichloroethene 5 U 78-93-3 2-Butanone _ 5 U 74-97-5 Bromochloromethane 5 U 67-66-3 Chloroform 5 U ' 71-55-6 1,1,1-Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U ' 107-06-2 1,2-Dichloroethane 5 U 79-01-6 Trichloroethene 5 U 78-87-5 1,2-Dichloropropane 5 U 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-88-3 Toluene 5 U 10061-02-6 trans-1,3-Dichloropropene 5 U- 79-00-5 1,1,2-Trichloroethane S. U 127-18-4 Tetrachloroethene 5 U 591-78-6 2-Hexanone 5 U ' 124-48-1 Dibromochloromethane 5 1 U 106-93-4 1,2-Dibromoethane 5 U FORM I VOA - 1 OLM04.2 ' LKB010 S40 ' 1B EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MW-4S ' Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 ' Matrix: (soil/water) WATER Lab Sample ID: 1407015-006G Sample wt/vol: 5 (g/mL) mL Lab File ID: G26238.D Level: (low/med) LOW Date Received: 07/01/14 ' % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 ' Soil Extract Volume: (pL) Soil Aliquot Volume (pL) CONCENTRATION UNITS: ' CAS NO. COMPOUND -- (pg/L or pg/Kg) pg/L Q 108-90-7 Chlorober_zene 5 U 110-57-6 trans-1,4-Dichloro-2-butene 5 U ' 100-41-4 Ethylbenzene 5 U 630-20-6 1,1,1,2-Tetrachloroethane 5 U 1330-20-7 Xylene (total) 5 U 100-42--5 Styrene 5 U 75-25-2 Bromoform 5 U - - 79-34-5 1,1,2,2-Tetrachloroethane 5 U 96-18-4 ! 1,2,3-Trichloropropane 5 U 106-46-7 1,4-Dichlorobenzene — - - 5 U 95-50-1 1,2-Dichlorobenzene _ - - 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U ' FORM I VOA - 2 OLM04.2 ' LKB010 S41 1F EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET ' MW-4S TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 ' Matrix: (soil/water) WATER Lab Sample ID: 1407015-006G , Sample wt/vol: 5 (g/mL) mL Lab File ID: G26238.D Level: (low/med) LOW Date Received: 07/01/14 g Moisture: not dec. Date Analyzed: 07/02_/14 ' GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pl) Soil Aliquot Volume: 0 (pL) ' CONCENTRATION LNITS: Number TICS found: 0 (ug/L or ' uJ/K9) 119/L --- CAS NUMBER COMPOUND NAME RT EST.CONC. ! Q FORM I VOA-TIC OLM04.2 ' LKBO1O S42 ' lA EPA SAMPLE NO. ' VOLATILE ORGANICS ANALYSIS DATA SHEET MW-5D ' Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LIB SAS No. : SDG No. : LKBO10 ' Matrix: (soil/water) WATER Lab Sample ID: 1407015-007G Sample wt/vol: 5 (g/mL) mL Lab File ID: G26239.D Level: (low/med) LOW Date Received: 07/01/14 ' % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 ' Soil Extract Volume: (pL) Soil Aliquot Volume (gL) CONCENTRATION UNITS: ' —CAS NO. COMPOUND (pg/L or pg/Kg) 11g/L 4 74-87-3 Chloromethane 5 U 75-01-4 1 Vinyl chloride 5 U 74-83-9 Bromomethane 5 U '75-00-3 Chloroethane 5 U r 107-13-1 Acrylonitrile 5 U - 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U 74-88-4 Iodomethane 5 U 108-03-4 Vinyl acetate 5 U -- 67-64-1 Acetone _ 5 U 75-15-0 Carbon-di ulfide 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U -----' ------ — 75-34-3 1,1-Dichloroethane 5 U 156-59-2 cis-1,2-Dichloroethene 2 J 7878-93-3-3 2-Butanone 5 U 74-97-5 Bromochloromethane 5 U 67-66-3 Chloroform — 5 -- U 71-55-6 1,1,1-Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U -- - 107-06-2 1,2-Dichloroethanehane 5 U r 79-01-6 Trichloroethene 5 U 78-87-5 1,2-Dichloropropane 4 J 74-95-3 Dibromomethane - 5 U 75-2.7-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-88-3 Toluene 5 U ' 10061-02-6 trans-1,3-Dichloropropene 5 U 79-00-5 1,1,2-Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U - --- 591-76-6 2-Hexanone 5 U 1.24-48-1 Dibromochloromethane 5 U 106-93-4 122-Dibromoethane 5 U ' FORM I VOA - 1 OLM04.2 ' LKB010 S43 1B EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MW-5D Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-007G ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26239.D Level: (low/med) LOW Date Received: 07/01/14 ' % Moisture: not dec. Date Analyzed: 07/02/14 , GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pL) Soil Aliquot Volume (}iL) ' CONCENTRATION UNITS:- , CAS NO. COMPOUND (pg/L or pg/Kg) pg/L Q 108-90-7 Chlorobenzene 13 110-57-6 trans-1,4-Dichloro-2-butene 5 U 100-41-4 Ethylbenzene 5 U ' 630-20-6 1,1,1,2-Tetrachloroethane 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene 5 U -- � 75-25-2 Bromoform 5 U 79-34-5 1,1,2,2-Tetrachloroethane 5 U 96-1B-4 1,2,3-Trichloropropane 5 U 106-46-7 1,4-Dichlorobenzene 3 J 95-50-1 1,2-Dichlorobenzene 5 U ' 96-12-8 1,2-Dibromo-3-chloropropane 5 U FORM I VOA - 2 OLM04.2 LKB010 S44 ' 1F EPA SAMPLE NO. ' VOLATILE ORGANICS ANALYSIS DATA SHEET MW-5D TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. ; LKE SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-007G ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26239.D Level: (low/med) LOWDate Received: 07/01/14 ' % Moisture: not dec. T Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 ' Soil Extract Volume: (ill) Soil Aliquot Volume; 0 (jiL) CONCENTRATION UNITS: ' Number TICs found: 1 (ug/L or pg/Kg) etc/L CAS NUMBER COMPOUND NAME RT EST.CONC. Q 1. 1634-04-4 Propane,2-methoxy-2-methyl- -- _ 2.77 6 A 1 ' FORM I VOA-TIC OLM04.2 LKB010 S45 lA EPA SAMPLE NO, VOLATILE ORGANICS ANALYSIS DATA SHEET , MW-5S Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-008G ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26240.D Level: (low/mad) LOW Date Received: 07/01/14 , % Moisture: not dec. Date Analyzed: 07/02/14 ' GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pL) Soil Aliquot Volume (pL) ' CONCENTRATION UNITS: , CAS NO. COMPOUND (pg/L or pg/Kg) pg/L Q 74-87-3 Chloromethane 5 U 75-01-4 Vinyl chloride 5 U 74-83-9 Bromomethane 5 U 75-00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane 5 U ' 75-35-4 1,1-Dichloroethene 5 U 74-88-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5 U -- 67-64-1 Acetone 5 U ' 75-15-0 Carbon disulfide 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Di.chl.oroethane 5 U , 156-59-2 cis-1,2-Dichloroethene 5 U 78-93-3 2-Butanone 5 U 74-97-5 Bromochloromethane 5 U 67-66-3 Chloroform 5 U , 71-55-6 1,1,1-Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 i U 71-43-2 Benzene 5 U -- _ 107-06-2 1,2-Dichloroethane 5 U 79-01-6 Trichloroethene 5 U 78-67-5 1,2-Dichloropropane 5 U 74-93-3 i Dibromomethane 5 U ' 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 106-10-1 4-Methyl-2-pentanone 5 U 108-88-3 Toluene 5 U ' 10061-02-6 trans-1,3-Dichloropropene 5 U 79-00-5 1,1,2-Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U - _ 591-78-6 2-Hexanone 5 U 124-46-1 Dibromochloromethane 5 U 106-93-4 1,2-Dibromoethane 5 U FORM I VOA - 1 OLM04.2 LKB010 S46 ' IB EPA SAMPLE NO. ' VOLATILE ORGANICS ANALYSIS DATA SHEET MW-5S ' Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 ' Matrix: (soil/water) WATER Lab Sample ID: 1407015-008G Sample wt/vol: 5 (g/mL) mL Lab File ID: G26240.D ' Level: (low/med) LOW Date Received: 07/01/14 ' % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 ' Soil Extract Volume: (}iL) Soil Aliquot Volume (pL) CONCENTRATION UNITS: CAS NO. COMPOUND ------- (pg/L or pg/Kg) pq/L --Q- - 108-90-7 Chlorobenzene 5 U 110-57-6 trans-l,4-Dichloro-2-butene 5 U - - 100-41-4 Ethylbenzene 5 U 630-20-6 1,1,1,2-Tetrachloroethane 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene 5 U --- 75-25-2 ! Bromoform 5 U 79-34-5 1,1,2,2-Tetrachloroethane - 5 U 96-18-4 1,2,3-Trichloropropane 5 U 106-46-7 1,4-Dichlorobenzene 5 U 95-50-1 1,2-Dichlorobenzene 5 U �— 96-12-8 1,2-Dibromo-3-chloropropane 5 U ' FORM I VOA - 2 OLM04.2 ' LKBO10 S47 r 1F EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET r MW-5S TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKB010 r Matrix: (soil/water) WATER Lab Sample ID: 1407015-008G , Sample wt/vol: 5 (g/mL) mL Lab File ID: G26240.D Level: (low/med) LOW Date Received: 07./01/14 a Moisture: not dec. Date Analyzed: 07/02/14 r GC Column: Rtx-624 ID: _18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pl) Soil Aliquot Volume: 0 (pL) ' CONCENTRATION UNITS: Number TICs found: 0 (pg/L or pg/Kg) L , CAS NUMBER COMPOUND NAME —RT EST.CONC. Q r r r r r r r r r r FORM I VOA-TIC OLM04.2 r LKB010 S48 , 1A EPA SAMPLE NO. ' VOLATILE ORGANICS ANALYSIS DATA SHEET MW-6D ' Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 ' Matrix: (soil/water) WATER Lab Sample ID: 1407015-009G ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26241.D Level: (low/mad) LOW Date Received: 07/01/14 ' % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (IaL) Soil Aliquot Volume CONCENTRATION UNITS: ' CAS NO. COMPOUND (pg/L or pg/Kg) Kg/L 4 74-87-3 Chiorome`_hane 5 U 75-01-4 Vinyl chloride 5 U --j --- - - I 74-83-9 Bromomethane 5 U 75-00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U �- - 75-69-4 Trichlorofluoromethane 5 _ U ' r 75-35-4 1,1-Dichloroethene _ 5 U 74-88-4 Iodomethane 5 -- U 108-05-4 Vinyl acetate 5 U 67-64-1 Acetone 5 U 75-15-0 Carbon disulfide 5 U 75-09-2 Methylene chloride 5 T U 156-60-5 trans-1,2-Dichloroethene 5 U ' 75-34-3 1,1-Diehloroethane 5 U 156-59-2 cis-1,2-Dichloroethene 5 U 78-93-3 2-Butanone 5 U 74-97-5 Bromochloromethane 5 U - - - � 67-66-3 Chloroform 5 U 71-55-6 1,1,1-Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene _ 5 U 107-06-2 1,2-Dichloroethane -- - 5 _ U 79-01-6 Trichloroethene 5 U ------------- ------ -- -- 78-87-5 1,2-Dichloropropane 1 S ' 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U ' 108-88-3 Toluene 5-- — U 10061-02-6 trans-1,3-Dichloropropene 5 U 79-00-51,1,2-Trichloroethane 5 �— U 127-18-4 I Tetrachloroethene 5 U 591-78-6 2-Hexanone 5 U 124-48-1 Dibromochloromethane 5 U 106-93-4 1,2-Dibromoethane 5 U ' FORM I VOA - 1 OLM04.2 ' LKBO1O S49 1B EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET , MW-6D Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-009G ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26241.D ' Level: (low/med) LOW Date Received: 07/01/14 % Moisture: not dec. Date Analyzed: 07/02/14 ' GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pL) Soil Aliquot Volume (pL) , CONCENTRATION UNITS: ' CAS NO. COMPOUND (pg/L or pg/Kg) Hg/L Q j 108-90-7 Chlorobenzene 5 U r 110-57-6 trans-1,4-Dichloro-2-butene 5 U -- --- �— 100-41-4 Ethylbenzene 5 U 630-20-6 1,1,1,2-Tetrachloroethane 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 styrene 5 U 75-25-2 Bromoform 5 U 79-34-5 1,1,2,2-Tetrachloroethane 5 U 96-18-4 1,2,3-Trichloropropane 2 J 106-46-7 1,4-Dichlorobenzene 5 U , 95-50-1 j 1,2-Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U FORM I VOA - 2 OLMO4.2 LKB010 S50 , 1F EPA SAMPLE NO. ' VOLATILE ORGANICS ANALYSIS DATA SHEET MW-6D TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LKS SAS No. : SDG No. : LKB010 Matrix: (soil/water) WATER Lab Sample ID: 1407015-003G Sample wt/vol: 5 (g/mL) mL Lab File ID: G26241.D Level: (low/med) LOW Date Received: 07/01/14 ' % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 ' Soil Extract Volume: (pl) Soil Aliquot Volume: 0 (jiL) CONCENTRATION UNITS: ' NumberrTICs found: 0 (ug/L or pg/Kg) �g/L CAS NUMBER COMPOUND NAME RT - - II EST.CONC. Q ' FORM I VOA-TIC OLM04:2 ' LKB010 S51 1A EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET ' MW-6S Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LIB SAS No. : SDG No. : LIBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-01OG ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26242.D Level: (low/mod) LOW Date Received: 07/01/14 , % Moisture: not dec. Date Analyzed: 07/02/14 ' GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pL) Soil Aliquot Volume (pl,) ' CONCENTRATION UNITS: ' CAS NO. COMPOUND (pg/L or pg/Rg) pg/L Q 74-87-3 Chloromethane 5 U 75-01-4 Vinyl chloride 5 U 74-83-9 Bromomethane 5 U , 75-00-3 Chloroethane 5 U — - --- 107-13-1 Acrylonitrile 5 U 7 _ 5 U 5-35-4 1,1-Dichloroethene 5 U - - ' 75-69-4 Trichlorofluoromethane i 74-88-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5 U--- 67-64-1 Acetone 5 U ' 75-15-0 Carbon disulfide 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichloroethane 5 U ' 156-59-2 cis-1,2-Dichloroethene 5 U 78-93-3 2-Butanone 5 U 74-97-5 Bromochloromethane 5 U 67-66-3 Chloroform 5 U ' 71-55-6 1,1,1-Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U j 71-43-2 Benzene 5 U 107-06-2 1,2-Dichloroethane 5 U , 79-01-6 Trichloroethene 5 U 78-87-5 1,2-Dichloropropane 5 U 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichloromethane 5 U ' 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-88-3 Toluene 5 U ' 10061-02-6 trans-1,3-Dichloropropene 5 U 79-00-5 1,1,2-Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U 591-78-6 1 2-Hexanone 5 U ' 124-48-1 Dibrcmochlcromethane 5 U 106-93-4 1,2-Dibromoethane 5 U FORM I VOA - 1 OLM04.2 LKBO10 S52 , 1B EPA SAMPLE NO. ' VOLATILE ORGANICS ANALYSIS DATA SHEET MW-6S Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-01OG Sample wt/vol: 5 (g/mL) mL Lab File ID: G26242.D Level: (low/med) LOW Date Received: 07/01/14 ' % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract volume: (}il,) Soil Aliquot Volume (pL) CONCENTRATION UNITS: CAS NO. COMPOUND (pg/L or Pg/Kg) pg/L Q 108-90-7Chlorobenzene 5 U 110-57-6 trans-1,4-Dichloro-2-butene 5 U 100-41-4 Ethylbenzene 5 U - 630-20-6 1,1,1,2-Tetrachloroethane 5 U 1330-20-7 Xylene (total) _— - 5 U 100-42-5 Styrene -- _ 5 U - 75-25-2 2 Bromoform 5 U 79-34-5 1,1,2,2-Tetrachloroethane 5 U 96-18-4 1,2,3-Trichloropropane 5 U ' 106-46-7 1,4-Dichlorobenzene 5 U 95-50-1 1,2-Dichlorobenzene 5 U 96-12-8 L1,2-Dibromo-3-chloropropane 5 U FORM I VOA - 2 OLM04.2 LKB010 S53 IF EPA SAMPLE NO, VOLATILE ORGANICS ANALYSIS DATA SHEET MW-6S TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No. ; SDG No. : LK3010 Matrix: (soil/water) WATER Lab Sample ID: 1407015-01OG Sample wt/vol: 5 (g/mL) mL Lab File ID: G26242.D Level: (low/med) LOW Date Received: 07/01/14 % Moisture: not dec. Date Analyzed: 07/02/14 i GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pl) Soil Aliquot Volume: 0 (pL) ' CONCENTRATION UNITS! Number TICS found: 0 (pg/L or pg/Kg) CAS NUMBER COMPOUND NAME RT EST.CONC. Q FORM I VOA-'PIC OLM04.2 LKBO1O S54 LA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET Mw-7S ' Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-011G Sample wt/vol: 5 (q/mL) mL Lab File ID: G26243.D Level: (low/med) LOW Date Received: 07/01/14 % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pL) Soil Aliquot Volume (pL) CONCENTRATION UNITS: CAS NO. COMPOUND (}ig/L or pg/Kg) pl/L Q 74-87-3 Chloromethane 5 , U 75-01-4 Vinyl chloride 5 U 74-83-9 f Bromomethane 5 U 75-00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5 U 74-88-4 rIodomethane 5 U 108-05-4 Vinyl acetate -5 U ' 67-64-1 i Acetone 5 U 75-15-0;Carbon disulfide 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U ' 75-34-3 1 1-Dichloroethane 5 U 156-59-2 cis-1,2-Dichloroethene 5 U 78-93-3 2-Butanone 5 U 74-97-5 Bromochloromethane 5 U ' 67-66-3 Chloroform 5 U 71-55-6 1,1,1-Trichloroethane 5 _ U 56-23-5 Carbon tetrachloride 5 U ' - - 71-43-2 Benzene - -- _-- — 5 -- --U ---_ 107-06-2 1,2-Dichloroethane 5 U 79-01-6 Trichloroethene -5 U 78-87-5 1,2-Dichloropropane 5 U ' 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U j - 1,1,2-Trichloroethane 5 100611-02-6 trarsn1,3-Dichloro ro ene 5 fi U 9-00 5 U 127-18-4 Tetrachloroethene 5 U 591-78-6 2-Hexanone _ 5 U 124-48-1 Dibromochloromethane 5 U 106-93-4 1,2-Dibromoethane 5 U ' FORM I VOA - 1 OLM04.2 ' LKBO10 S55 1B EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET ' MW-7S Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LIB SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-011G ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26243.D Level: (low/mod) LOW Date Received: 07/01/14 % Moisture: not dec. Date Analyzed: 07/02/14 , GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pL) Soil Aliquot Volume (}aL) CONCENTRATION UNITS: CAS NO. COMPOUND (pg/L or fag/Kg) pg/L Q 108-90-7 Chlorobenzene 5 U 110-57-6 trans-1,4-Dichloro-2-butene 5 U 100-41-4 i Ethylbenzene 5 U ' 630--20-6 1,1,1,2-Tetrachloroethane 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene 5 U 75-25-2 Bromoform 5 U 79-34-5 1,1,2,2-Tetrachloroethane 5 U 96-18-4 1,2,3-Trichloropropane 5 U 106-46-7 1,4-Dichlorobenzene 5 U ' 95-50-1 1,2-Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U 1 i FORM I VOA - 2 OLM04.2 LKB010 S56 ' 1F EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MW-7S TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-011G Sample wt/vol: 5 (g/mL) mL Lab File ID: G26243.D Level: (low/med) LOW Date Received: 07/01/14 ' % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 ' Soil Extract Volume: (pl) Soil Aliquot Volume: 0 (liL) CONCENTRATION UNITS: ' Number TICS found: 0 (ug/L or jig/Kg) g/L CAS NUMBER COMPOUND NAME RT T EST.CONC. Q ' FORM I VOA-TIC OLM04.2 tLKB010 S57 lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MW-8S Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-012G ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26244.D Level: (low/mad) LOW Date Received: 07/01/14 , % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pL) Soil Aliquot Volume _(}iL) , CONCENTRATION UNITS: CAS NO. COMPOUND (pg/L or pg/Kg) pg/L Q 74-87-3 Chloromethane 5 Tu 75-01-4 Vinyl chloride 5 U -- -- - 74-83-9 Bromomethane 5 U 75-00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene _ 5 U 74-88-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5 U - _ -..__ 67-64-1 Acetone 5 U - ---- 75-15-0 Carbon disulfide 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichloroethane 5 U ' 156-59-2 cis-1,2-Dichloroethene 5 U 78-93-3 2-Butanone 5 U 74-97-5 Bromochloromethane 5 U 67-66-3 Chloroform _ 5 U 71-55-6 1,1,1-Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U ' 107-06-2 1,2-Dichloroethane 5 U 79 01 6 Trichloroethene 5 U 78-87-5 1,2-Dichloropropane 5 U 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichloromethane _ 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-88-3 Toluene 5 U 10061-02-6 trans-1,3-Dichloroprcpene 5 U 79-00-5 1,1,2-Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U 591-78-6 2-Hexanone 5 U ' 124-48-1 Dibromochloromethane 5 U 106-93-4 1,2-Dibromoethane 5 U FORM I VOA - 1 OLM04.2 LKBO10 S58 , 1 1B EPA SAMPLE NO. ' VOLATILE ORGANICS ANALYSIS DATA SHEET MDP-8S ' Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-012G ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26244.D Level: (low/med) LOW Date Received: 07/01/14 ' % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 ' Soil Extract Volume: (pL) Soil Aliquot Volume (pL) CONCENTRATION UNITS: CAS NO. COMPOUND (pg/L or pg/Kg) pg/L Q 108-90-7 -Chlorobenzene 16 110-57-6 trans-1,4-Dichloro-2-butene 5 U 100-41-4 Ethylbenzene 5 U 630-20-6 1,1,1,2-Tetrachloroethane 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 + Styrene 5 U � 75-25-2 _Bromoform 5 U 79-34-5 1,1,2,2-Tetrachloroethane 5 U 96-18-4 1,2,3-Trichloropropane _5 U 106-46-7 1,4-Dichlorobenzene f 5 U r 95-50-1 1,2-Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U ' FORM I VOA - 2 OLM04.2 ' LKBO1O S59 1F EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET MW-8S TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: PACE ANALYTICAL Contract: , Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKB010 Matrix: (soil/water) WATER Lab Sample ID: 1407015-012- ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26244.D Level: (low/med) LOW Date Received: 07/01/14 % Moisture: not dec. Date Analyzed: 07/02/14 ' GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (Pl.) Soil Aliquot Volume: 0 (pL) ' CONCENTRATION UNITS: Number TICS found: 0 (ug/L or pg/Kg) /L , CAS NUMBER COMPOUND NAMERT EST.CONC. Q FORM I VOA-TIC OLM04.2 ' LKBO10 S60 , IA EPA SAMPLE NO. ' VOLATILE ORGANICS ANALYSIS DATA SHEET Field Blank Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 ' Matrix: (soil/water) WATER Lab Sample ID: 1407015-013G ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26247.D Level: (low/med) LOW Date Received: 07/01/14 ' % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 ' Soil Extract Volume: (pL) Soil Aliquot Volume — (pL) ' CONCENTRATION UNITS: CAS NO. COMPOUND (pg/L or jig/Kg) p( /L Q 74-87-3 Chloromethane 5 U 75-01-4 Vinyl chloride 5 U 74-63-9 Bromomethane 5 U 75-00-3 Chloroethane + 5 U------ 10 7-13-1 107-13-1 Acrylonitrile 5 U ' 75-69-4 Trichlorofluoromethane 5 U 75-35-4 1,1-Dichloroethene 5- 74-88_4 74-88-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5 U ' 67-64-1 Acetone 5 U 75-15-0 Carbon disulfide 5 U _ 75-09-2 Methylene chloride 5 _ U 156-60-5 trans-1,2-Dichloroethene 5 U ' 75-34-3 1,1-Dic oroet ane 5 U 156-59-2 cis-1,2-Dichloroethene 5 U 78-93-3 2-Butanone 5 U 74-97-5 Bromochloromethane 5 U 67-66-3 Chloroform 5 U 71-55-6 1,1,1-Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U ' 71-43-2 Benzene 5 U 107-06-2 ! 1,2-Dichloroethane 5 U 79-01 6 Trichloroethene 5 U 78-87-5 1,2-Dichloropropane 5 U ' 74-95-3 Dibromomethane 5 U 75-27-4 Bromodichlorcmethane 5 U 10061-01-5 cis-1,3-Dichloro ro ere 5 108-10-1 4-Methyl-2-pentanone 5 U ' 108-88-3 Toluene 5 U 10061-02-6 trans 1,3-Dichloropropene5 U 79-00-5 1,1,2-Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U 2— - - — 591-78-6 2-Hexanone 5 U 124-48-1 Dibromoch-oromethane 5 U 106-93-4 1,2-Dibromoethane 5 U ' FORM I VOA - 1 OLM04.2 ' LKB010 S61 1B EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET ' Field Blank Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LIB SAS No. : SDG No. : LIBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-013G Sample wt/vol: 5 (g/mL) mL Lab File ID: G26247.D , Level: (low/mad) LOW Date Received: 07/01/14 % Moisture: not dec. Date Analyzed: 07/02/14 , GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pL) Soil Aliquot Volume (pL) , CONCENTRATION UNITS: ' CAS NO. COMPOUND (pg/L or pg/Rg) pg/L Q 108-90-7 Chlorobenzene 5 U 110-57-6 trans-1,4-Dichloro-2-butene 5 U 100-41-4 Ethylbenzene 5 U , 630-20-6 1,1,1,2-Tetrachloroethane 5 U 1330-20-7 1 Xylene (total.) 5 U 100-42-5 Styrene 5 U 75-25-2 Bromoform 5 U ' 79-34-5 1,1,2,2-Tetrachloroethane 5 U 96-18-4 1,2,3-Trichloropropane 5 U 106-46-7 1,4-Dichlorobenzene t 5 U ' 95-50-1 1,2-Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U J FORM I VOA - 2 OLM04.2 LKBO10 S62 , IF EPA SAMPLE NO. ' VOLATILE ORGANICS ANALYSIS DATA SHEET TENTATIVELY IDENTIFIED COMPOUNDS Field Blank Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample 10: 1407015-013G Sample wt/vol: 5 (g/mL) mL Lab File ID: G26247.D Level: (low/med) LOW Date Received: 07/01/14 ' % Moisture: not dec. Date Analyzed: 07/02/1.4 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 ' Soil Extract Volume: (ul) Soil Aliquot Volume:'! 0 (yL) CONCENTRATION UNITS: ' Number TICs found: 0 (ug/L or µg/Kg) 119/L CAS NUMBER COMPOUND NAME RT EST.Cw. Q it ' FORM I VOA-TIC OLM04.2 ' LKBO10 S63 IA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET ' Trip Blank Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LIB SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-014A ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26248.D ' Level: (low/med) LOW Date Received: 07/01/14 % Moisture: not dec. Date Analyzed: 07/02/14 , GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pL) Soil Aliquot Volume (pL) ' ___-_ -------- CONCENTRATION UNITS: - -- ' CAS NO. COMPOUND (}ig/L or pg/Kg) pg/L Q 74-87-3 j Chloromethane 5 U 75-01-4 Vinyl chloride 5 U 74-83-9 Bromomethane 5 U , 75-00-3 ! Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane 5 U ! 75-35-4 1,1-Dichloroethene 5 U ' 74-BB-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5 U 67-64-1 Acetone 5 U- 75-15-0 75-15-0 Carbon disulfide 5 U 75-09-2 Methylene chloride _ 5 U 156-60-5 trans-1,2-Dichloroethene 5 U -- — — 75-34-3 1,1-Dichloroethane 5 U 156-59-2 cis-1,2-Dichloroethene 5 U 78-93-3 2-Butanone 5 U 74-97-5 Bromochloromethane 5 U 67-66-3 Chloroform 5 U , 71-55-6 1,1,1-Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U 107-06-2i 1,2-Dichloroethane 5 U 79-01-6 Trichloroethene 5 U 7B-87-5 1,2-Dichloropropane 5 U 74-95-3 Dibromcmethane 5 U , 75-27-4 Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U 108-88-3 Toluene 5 U ' 10061-02-6 trans-1,3-Dichloroprcpene 5 U 79-00-5 1,1,2-Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U -- - ---- 591-78-6 2-Hexanone 5 U 124-48-1 Dibromochloromethane 5 U 106-93-4 1,2-Dibromoethane 5 U FORM I VOA - 1 OLM04.2 LKB010 S64 ' ' 1B EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SKEET Ep ank ' Lab Name: PACE ANALYTICAL Contract: I� Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 ' Matrix: (soil/water) WATER Lab Sample ID: 1407015-014A l ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26248.D - — I Level: (low/med) LOW Date Received: 07/01/14 6 Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 ' Soil Extract Volume: (pL) Soil Aliquot Volume (pL) CONCENTRATION UNITS: CAS NO. COMPOUND (pg/L or pg/Kg) pg/L Q --- - - -- 108-90-7 Chlorobenzene I 5 U 110-57-6 trans-1,4-Dichloro 2-butene _ 5 U ' 100-41-4 Ethylbenzene - - - - 5 ------ -- 630-20-6 1,1,1,2-Tetrachloroethane 5 U 1330-20-7 Xylene (total) 5 __ U 100-42-5 Styrene 5 U 75-25-2 Bromoform 5 U 79-34-5 1,1,2 2-Tetrachloroethane 5 U 96-18-4 1,2,3-Trichloropropane 5 U ' 106-46-7 1,4-Dichlorobenzene 5 U 95-50 1 1,2-Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropar_e 5 U ' FORM I VOA - 2 OLM04.2 ' LKBO1O S65 lA EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET ' Storage Blank Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-015A ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26249.D Level: (low/med) LOW Date Received: 07/01/14 , % Moisture: not dec. Date Analyzed: 07/02/14 , GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (}1L) Soil Aliquot Volume (pL) , -- - CONCENTRATION UNITS: , CAS NO. COMPOUND (pg/L or pg/Kg) Hg/L Q 74-87-3 Chloromethane 5 U 75-01-4-Vinyl chloride_ 5 U 74-83-9 Bromomethane _ 5 U ' 75-00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane 5 U ' 75-35-4 1,1-Dichloroethene 5 U 74-88-4 Iodomethane _ _ 5 U 108-05-4 Vinyl acetate 5 fu 67-64-1 Acetone 5 ' 75-15-0 Carbon disulfide 5 --- - - - -- 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U 75-34-3 1,1-Dichloroethane 5 U 156-59-2 cis-1,2-Dichloroethene 5 _ U , 78-93-3 2-Butanone _ 5 U 74-97-5 Bromochloromethane _ 5 U 67-66-3 Chloroform 5 U ' 71-55-6 1,1,1-Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U 107-06-2 1,2-Dichloroethane 5 U , 79-01-6 Trichloroethene 5 U 78-87-5 1,2-Dichloropropane 5 U 74-95-3 Dibromomethane 5 U ' 75-27-4 Bromodichloromethane _ 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U _ -- — 108-88-3 Toluene 5 U 10061-02-6 trans-1,3-Dichloropropene _ 5 U 79-00-5 1,1,2-Trichloroethane 5 U 127-18-4 Tetrachloroethene 5 U 591-76-6 2-Hexanone 5 U , 124-48-1 Dibromochloromethane 5 U 106-93-4 1,2-Dibromoethane 5 U FORM I VOA - 1 OLM04.2 LKBO10 S66 , IB EPA SAMPLE NO. ' VOLATILE ORGANICS ANALYSIS DATA SHEET Storage Blank ' Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKE SAS No. : SDG No. : LIBO10 Matrix: (soil/water) WATER Lab Sample ID: 1407015-015A ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26249.D Level: (low/med) LOW Date Received: 07/01/14 ' % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 ' Soil Extract Volume: (pL) Soil Aliquot Volume (pL) ' -- ----- — - - ----CONCENTRATION UNITS: CA NO. COMPOUND (µg/L or ug/Kg) pg/L Q 108-90-7 Chlorobenzene 5 U 110-57-6 ! trans-1,4-Dichloro-2-butene 5 U 100-41-4 Ethylbenzene 5 U -7 630-20-6 1,1,1,2-Tetrachloroethane 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene 5 U 75-25-2-1 Bromoform 5 U 79-34-5 1,1,2,2-Tetrachloroethane 5 U 96-18-4 1,2,3-Trichloropropane 5 U ' 106-46-7 1,4-Dichlorobenzene 5 U 95-50-1 1,2-Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U 1 FORM I VOA - 2 OLM04.2 ' LKBO10 S67 i aceLong Island ' 575 Broad Hollow Road ke,: 631.694.3040 ' Melville,NY 11747 631.420.8436 4.2 METALS 1 LKB010 S68 r ' ace long Island 575 Broad Hollow Road tel.631.694.3040 Melville, NY 11747 fax 631.420.8436 QUALIFIERS FOR METALS ANALYSIS Q (Quality Control) Qualifiers E - Serial dilution is not within acceptance criteria or the reported value is estimated because of the presence of interference. An explanatory note is included ' in the SDG narrative. N - Matrix spike sample recovery not within control limits. ' * - Duplicate analysis is not within control limits. ' C (Concentration) Qualifiers B - Entered if the reported value is less than the Contract Required Detection Limit (CRDL) but greater than the Instrument Detection Limit (IDL). U - Entered if the analyte was analyzed for but not detected, i.e., less than the IDL. M (Method) Qualifiers ' P - Analyzed by ICP. MS - Analyzed by ICP-MS CV- Analyzed by Manual Cold Vapor techniques. AV- Analyzed by Automated Cold Vapor techniques. C - Analyzed by Manual Spectrophotometric Method. CA- Analyzed by Midi-distillation Spectrophotometric Method. ' NR - Analyte not Required. ' LKB010 S69 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW-1D Lab Name: PACE ANALYTICAL ' Lab Code: 10478 Case No. SAS No. : SDG No. : LKBO10 Matrix (soil/water) : WATER Lab Sample ID: 1407015-001 Level (1cw/med) : LOW Date Received: 7/1/2014 Solids: 0_0 Concentration Units (ug/L or mg/kg dry weight) : UG/L ;, CAS No. Analyte Concentration C Q M ' 7429-90-5 Aluminum 67.9 B P '7440-36-0 lAntimony _ 1.6 U P 17440-38-2 jArsenic _ 1.5�U P , 7440-39-3 jBarium 30.51 B P 7440-41-7 Beryllium, 0.0911 U P 7440-42-8 Boron 16.81 B - P 7440-43-9 Cadmium 0.14 U P ' 7440-70-2 Calcium 22200 P 7440-47-3 -Chromium 1.61 B P 7440-48-4 Cobalt 0.16 U ! P 7440-50-8 Copper 1.4 B F 57-12--5 Cyanide 1o.0 U CA 7439-89-6 lIron 21.4 BP 7439-92-1 Lead 17.2 P 7439-95-4 Magnesium _ 9730 P 7439-96-5 Manganese _ 2.8 BT P 7439-97-6 Mercury 0.10 U CV 7440-02-0 Nickel 0.30 B P , 7440-09-7 Potassium 1480 Bi F 7782-49-2 i,Selenium 1.4 U P 7440-22-4 ISilver 2.2 B ! N F 7440-23-5 7Sodium 18800 F ' 7440-28-0 Thallium 3.5 U ' P 7440-62-2 lVanadium 0.90 S F 7440-66-6 jZinc 136 F Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: ' Date Reported 7/20/2014 FORM I - IN ILM04.1 LKBO10 S70 , U.S. EPA - CLP 1 EPA SAMPLE NO Lab Name: PACE ANALYTICAL INORGANIC ANALYSIS DATA SHEET - MW-ls ' Lab Code: 10478 Case No. SAS No. : SDG No. : LKBO10 Matrix (so_1/water) : WATER Lab Sample ID: 140-7015-002 Level (low/med) : LOW Date Received: 7/1/2014 a Solids: 0_0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS Nc. anaIyte TConcentration C Q M - - - —7-- --- B 2. 7429-50-5 Aluminum 42P 7440-36-0 Antimony-----! 1.6 U ', P ' 7440-38-2 Arsenic 1.5 L P 7440-39-3 Barium 58.7 B , P _ x940-41-7 Beryllium -- ---_ 0.101 B P 7440-92-8 Boron 24.0, B F - 7440-43-9 Cadmium 0.14 r_7 7440-70-2 Calcium 6780 ^-P P 7440-47-3 Chromium 4.2 B P 744C-48-4 Cobalt 0.16 U P -- -- - - - - 744C-50-8 Copper 1.0 B P -57-12-5 Cyanide 10._0 U CA ;7439-89-6 Iron 24.4 B P 7439-92-1 Lead 11.9 P - -- 7939-95-4 Magnesium 3980 B _ P 7439-96-5 Manganese 8. B P 5 743 o9-97-6 MCV f--- -- ----�_ -Mercury r 0._0 U 7440-G2-0 Nickel 1.7 B_ � P 7440-09-7 Potassium 3440 B — P 7782-49-2 Selenium 2.4 B P 7440-22-4 Silver 1.9 B N P 7440-23-5 Sodium 4600'1 P - --- 7440-28-0 Thallium 3.51 U P 7440-62-2 Vanadium 0.40; B P 7440-66-6 Zinc 6.61B P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: ' Comments: Date Reported 7/20/2014 FORK_ I - IN ILM04.1 ' LKB010 S71 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MWW=3D Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LKBO10 Matrix (soil/water) : WATER Lab Sample ID: 1407015-003 Level (low/med) : LOW Date Received: 7/1/2014 % Solids: 0_0 ' Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. Analyte Concentration C Q M 7429-90-5 Aluminum 71.9 B P 7440-36-0 Antimony 1.6 U P __ _ 7440-38-2 _Arsenic 3.9 B P 7440-39-3 Barium 248 _ P 7440-41-7 Beryllium 0.091 U P 7440-42-8 Boron 512 P 7440-43-9 Cadmium _ 0.14 U P 7440-70-2 Calcium 34700 P 7440-47-3 Chromium 0.46 U P 7440-48-4 Cobalt 46.3 B P 7440-50-8 Copper 8.9 B P 57-12-5 Cyanide 10.0 U CA 7439-89-6 Iron 30600 P 7439-92-1 Lead 20.5 P 7439-95-4 Magnesium 24800 P 7439-96-5 Manganese 3300 P 7439-97-6 Mercury 0.10 U CV 7440-02-0 Nickel 28.5 B P 17440-09-7 Potassium 64700 P 7782-49-2 Selenium 1.4 U P 7440-22-4 Silver 3.7 U N P 7440-23-5 Sodium 97900 P ' 7440-28-0 Thallium _ 14.4 P 7440-62-2 Vanadium _ 1.6 B P .7440-66-6 Zinc 6.31 B I P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: YELLOW Clarity After: CLEAR Artifacts: Comments: Date Reported 7/20/2014 FORM I - IN ILM04 .1 ' LKB010 S72 , 1 U.S. EPA - C_,P 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW-3S t Lab Name: PACE ANALYTICAL _- —_ Lab Code: 10478 Case No. SAS No. : SDG No. : LKBO10 1 Matrix (soil/water) : WATER Lab Sample ID: 1407015-004 Level (low/med) : LOW Date Received: 7/1/2014 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : JG/L CASNo. Analyte Concentration C Q M 74290- 90-5 Aluminum 32.5 B P 7440-36-0 lAntimony 1.6 U P 7440-38-2 Arsenic - 1.5 U — P 7440-_3_9-3 Barium 189 B P 7440-41-7 Ber llium 0.091 U P 7440-42-8 Boron 133 P 7440-43-9 Cadmium 0.3CI B P ' 7440-70-2-,--.Calcium 24600 -- P 7440-47-3 Chromium 0.4611 U P 7440-48-4 Cobalt 30.6 B P 7440-50-8—copper 17.4, B P 57-12-5 Cyanide 10.0; U CA 7439-89-6 Iron 72100, P 17439-92-1 Lead 11.61 P 1 7439-95-4 Magnesium 15800 - _ _ 17439-96-5 Manganese 4200 P_ 7439-97-6 Mercury 0.10 U -- CV-� 17440-02-0 Nickel --2.9 _B --_---_ -- P 17440-09-7 Potassium 19000 -P 17782-49-2 Selenium 1.4', U P ;7440-22-4 (Silver 3.-,, U N 2 7440-23-5 ISodium. 4220C, P 7440-28-0 IThallium 12.9 P 7440-62-2 Vanadium 1.2 B P 7440-66-6 IZinc 9.5 B P Color Before: COLORLESS Clarity Befcre: CLEAR - Texture: Color After: YELLOW Clarity After: CLEAR Artifacts: Comments: Date Reported 7/20/2014 - - -- - ------- — ._ ------------------ FORM -----FORM I - IN ILM04 .1 ' LKB010 S73 1 1 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANA!YSIS DATA SHEET N_W-4D Lab Name: PACE ANALYTICAL ' Lab Code: 10478 Case No. SAS No. : SDG No. : LKB010 Matrix (soil/water) : WATER Lab Sample ID: 1407015-005 Level (low/med) : LOW Date Received: 7/1/2014 Solids: 00 Concentration Units (ug/L or mg/kg dry weight) : UG/L rCAS No. Analyte Concentration CT Q M 7429-90-5 jAluminum 1 53.5 B , P 17440-36-0 Antimony 1.6 U P 7440-38-2 Arsenic 1.5 U P 744C-39-3 Barium 190 B P - 7440-41-7 Beryllium 0.091 U P 7440-42-8 Boron 651 - 7440-43-9 Cadmium 1 0.14 UP 7440-70-2 Calcium 147000 P 7440-47-3 Chromium 1.1 B P 7440-48-4 Cobalt 14.2 B P 7440-50-8 Copper 3.5 B P , 57-12-5 Cyanide 10.0 U CA 7439-89-6 Iron 514 P 7439-92-1 Lead 18.9 _ P 7439-95-9 Magnesium 60600 P 7439-96-5 IManganese 3380 P 7439-97-6 IMercury 0.10 U Cv 7440C2_ B -__ P , 7440-C9-'-7 Potassium 47200_ P 7782-49-2 Selenium 1.41 U P 7440-22-4 Silver 0.41 B N P 7440-23-5 Sodium 20600C; P 7440-28-0 Thallium 12.91 P 7440-62-2 vanadium 0.301B P 7440-66-6 Zinc 11.61B P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color Af-er: COLORLESS Clarity After: CLEAR Artifacts: Comments: , Date Reported 7/20/2014 FORM I - IN ILM04.1 LKB010 S74 ' 1 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET Lab Name: PACE ANALYTICAL Lab Code: .0478 Case No. SAS No. : SDG No. : LKB010 Matrix (soil/water) : WATER Lab Sample ID: 1407015-006 Level (low/med) : LOW Date Received: 7/1/2014 ' % Solids: 0_0 Concentration Units (ug/L or mg/kg dry weight) : OG/L - ---�--- ---- CAS No. Analyte ConcentrationlIC — Q M 7429-90-5 Aluminum 31.OtB P 7440-36-0 AA ntimon - 1 61 U P 17440-38-2 Arsenic 1.5 U P !7440-39-3 Barium 10_3 B P 7440-41-7 Beryllium 0.091' U P 7440-42-8 Boron 119, P ,7440-43-9 Cadmium 0.14; U P '7440-70-2 Calcium 58400 P 7440-47-3 Chromium 1.4' 13 P 74-50-_8 Cobalt I - 0230'B P _ .Copper — - 5712-5 Cyanide 0 0� B P 7439-92-1 !Lead ----- - -- - --- - 9.0' --- - � U CA , 7439-69-6 (Iron---- — - -- 12.6i B --- P _ -. -- - - P 7439-95 4 Magresium 13600 P .7439-96-5 Manganese 3440�i P 7439-97-6 Mercury 0.10' U Cv 7440-02-0 Nickel 11.2 B 7440-09-7--Potassium 38100 i P 7782-49-2 Selen_um_ 1.4 U P 7440-22-4 Silver 1.0; BN P ` 7440-23-5 Sodium 8720'. P 7440-28-0 Thallium 14.Oi P 7440-62-2 Vanadium 0.22 U P 7440-66-6 Zinc 6.2 B P ' Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported 7/20/2014 ' FORM I - IN ILM04.1 ' LKB010 S75 U.S. EPA - CIP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW-5D Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LKBO10 Matrix (soil/water) : WATER Lab Sample ID: 1407015-OC7 ' Level (low/med) : LOW Date Received: 7/1/2014 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : JG/L CAS No. Analyte Ccncentration C Q - M 7429-90-5 Aluminum 48.5 B P 7440-36-0 Antimony1.6 U P 7440-38-2 Arsenic 1,5 U _ P 7440-39-3 Barium 197 B P 7440-41-7 Beryllium 0.091 U P 7440-42-8 Boron 760 P 7440-43-9 Cadmium - 0.14U P 7440-70-2 Calcium T 75100 P 7440-47-3 Chromium 7— 1.5 B P 7440-48-4 Cobalt - 26.0 B P 7440-50-8 Copper 14.7 B P 57-12-5Cyanide 10.0 U CA 7439-89-6 Iron 78.5 B P 7439-92-1 Lead 9.1 P 7439-95-4 Magnesium 30800 P 7439-96-5 Manganese 11800 P 7439-97-6—Mercury 0.10 U CV 7440-02-0 Nickel 34.7 B P , 7440-09-7 Potassium 111000 P 7782-49-2 Selenium 1.4 U P '7440-22-4 Silver 2.5 B_ N P 7440-23-5 Sodium 132000 P 7440-28-0 Thallium 46.3 _ P 7440-62-2 Vanadium _ 0.22 U P 7440-66-6 jZinc 4.31 B P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported 7/20/2014 FORM I - IN ILM04 .1 ' LKBO10 S76 ' U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET Mie'-5S Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LKBO10 Matrix (soil/water) : WATER Lab Sample ID: 1407015-008 Level (low/med) : LOW Date Received: 7/1/2014 o Solids: 0_0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. Analyte ConcentrationIC Q T M� 7429-90-5 Aluminum _ 36.9' B P 7440-36-0 Antimony 1.61U P —------ — , 7440-38-2 Arsenic 1.51U P 7440-39-3 Barium 55.7' 7' B P 744C-91-7 lBerylliun 0..-'OB P 744C-42-8 Boron — - —22.51 B - P 650 7440-70-2 Calcium 9 7940-43-9 Cadmium 0. 4,1 U P 7440-47-3 Chromium 2.5', B __ P 7440_-48-4 Cobalt 0.16, U ! P 7440-50-8 Copper 1.4 B _ P 57-12-5 Cvanide 10.0U CA 7439-69-6 Iron 11.11 B P 7439-92=1 Le --T— --- 5740 -- P 1 7439-95-4 Magnesium - - - P 7439-96-5 !Manganese 54.7 P 7439-97-6 IMercury 0.10 U CV 7440-02-0 Nickel _ 3.1 B P 1 7440-09-7 Potassium 4010 B P 17782-49-2 Selenium _ 1.4' U P 7440-22-4 Silver 1.7 B N P 7440-23-5 Sodium 120001 P 7440-28-0 Thallium 3.51 U P 7440-62-2 iVanadium 0.30 B P 7440-66-6 Zinc 22.2 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: ' Comments: Date Reported 7/20/2014 FORM I - IN ILM04 . 1 ' LKBO10 S77 1 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW-6D Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LKBO10 Matrix (soil/water) : WATER Lab Sample ID: 1407015-009 Level (low/med) : LOW Date Received: 7/1/20"_4 % Solids: 0_0 ' Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. Analyte Concentration C Q M 7429-90-5 Aluminum 35.3 B P 7440-36-0 Antimony 1.6 U P ---_.. _ 7440-38-2 Arsenic 1.5 U P � 7440-39-3 Barium 24.3 B P 7440-41-7 Beryllium 0.091 U P 7440-42-8 Boron _ 33.61 B P 7440-43-9 Cadmium 0.14 TJ P 7440-70-2 Calcium 33700 P !7440-47-3 Chromium 1.1 Bi P 7440-48-4 Cobalt 1.1 BT P 7440-50-8 Copper 0.90 BP 57-12-5 Cyanide 10.0 U CA 7439-89-6 Iron 21.9 BI _ P ;7439-92-1 Lead 17.1 �— P 7439-95-4 Magnesium 16800 P 7439-96-5 Manganese 872 P 7439-97-6 Mercury 0.10 U I CV 7440-02-0 Nickel 12.7 B P 7440-09-7 Potassium _ 2740_B _ P 7782-49-2 Selenium 1.4 U P 7440-22-4 Silver 1.3 B N P 7440-23-5 Sodium 15900 P 7440-28-0 Thallium 4.6 B _ P 7440-62-2 Vanadium 0.50 B P 7440-66-6 IZinc 11.1 B P Color Before: COLORLESS Clarity Before: 'CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported 7/20/2014 FORM I - IN ILM04 .1 LKBO10 S78 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET NPT-6 S Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LKBO10 Matrix (soil/water) : WATER Lab Sample ID: 1407015-010 Level (low/med) : LOW Date Received: 7/1/2014 % Solids: 0_0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. Analyse ! Concentrationlc Q M ' 7429-90-5 Aluminum 81 81 B P 7440-36-0 Antimony 1.6'U P 7440-38-2 Arsenic 1.51 U P ' 7440-39-3 Barium 63.21 B P 7440-41-7 Beryllium 0.091 Ui P 7440-42-9 lBoron 34.2' B ', P '7440-43-9 Cadmium 0.14 U - — P 7440-70-2 Calcium 14800 P 7940-97-3 Chromium 2.0 B P 7440-48-4 Cobalt4.7B P _ Cyanide - _ 7440-50-8 Copper _ 11 5 B P 57-12-5 C yanode 10.0, U CA 7439-89-6 Iron 71.91 B P 7439-92-1 Lead 12.01 P ' 17439-95-4 Maggesium — — _43�_I P 7439-96-5 Man anese 2280 P ---_�-- 16. B�--_ 7439-97-6 Mercury 0.101U CV 7440-02-0 Nickel 3 P 7440-09-7 Potassium 4190 B P 7782-49-2 Selenium 1.4 U P 7440-22-4 Silver 0.37 U N P 7440-23-5 Sodium 6680 P 7440-28-0 Thallium 8.1 B I P 7440-62-2 Vanadium 0.22 U P 7440-66-6 Izinc 9.0 B P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported 7/20/2014 - 1 - FORM I - IN ILM04 .1 ' LKB010 S79 U.S. EPA - CLP 1 EPA SAMPLE NO , INORGANIC ANALYSIS DATA SHEET MW-7S Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LK3010 Matrix (soil/water) : WATER Lab Sample ID: 1407015-011 Level (low/med) : LOW Date Received: 7/1/2014 % Solids: 0_0 ' Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. Analyte Concentration C ' Q M , 7429-90-5 Aluminum ^25.2 B P 7440-36-0 Antimony 1.6 U P 7440-38-2 Arsenic _ 1.5 U P 7440-39-3 Barium 105 Bj j P 7440-41-7 Beryllium 0.091 U 7440-42-8 Boron 122 j P 7440-43-9 Cadmium 0.14 U _ P 7440-70-2 Calcium 60000 P 7440-47-3 Chromium_ 1.5 B P 7440-48-4 Cobalt 0._40_B P 7440-50-8 Copper -_ 1.9 B P ' 57-12-5 Cyanide 10.0 U CA 7439-89-6 Iron 8.4 B P 7439-92-1 Lead------ - 9.2 P 7439-95-9 Magnesium _ 14000 7439-96-5 Manganese 3450 P 7439-97-6 Mercury 0.10 U CV 7440-02-0 Nickel — 11.6 B P 7440-09-7 Potassium 38800 P 7782-49-2 Selenium 1.4 U P 7440-22-4 Silver 1.9 B N P 7440-23-5 Sodium B930 P ' 7440-28-0 Thallium 13.9 P 7440-62-2 Vanadium 0.22 U P 74.40-66-6 Zinc 6.1 B P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported 7/20/2014 FORM I - IN ILM04.1 LKBO10 S80 , 1 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET —— MW-8S Lab Name: PACE ANALYTICAL ' Lab Code: 10478 Case No. SAS No. : SDG No. : LKB010 Matrix (soil/water) : WATER Lab Sample IC: =407015-012 Level (low/med) : LOW Date Received: 7/1/2014 ' % Solids: 0_0 Concentration Units (ug/L or rr.g/kg dry we' ght) : UG/L ' CAS No Analyte Concentration CI Q — M 7429-90-5 'A1 dnum 26.3: B ! _ P 7440-36-0 I-Antimony 1.6_U P 7440-38-2 Arsenic U P 740393 Barium — _- 240 — P J 5 ;7440-41-7 ,Beryllium_ 0.09E U P 7440-42-8 ;Bcron - _ 216 P 7440-43-9 Cadmium 0.14 U P 117 440-70-2 Calcium 57000 P ------- ---- ----- ;7440-47-3 Chrom-um C.46 U P 7440-48-4 Cobalt 3.9 B P r 7440-50-8 Copper 11.1 8 � P 57-12-5 Cyanide 10.0 U ! CA_ 7439-89-6 Iron 38200 P 7439-92-1 (Lead 16.7 P 17439-95-4 N_agnesium 2C2C0 P 7439-96-5 Manganese 882 P 7939-97-6 Mercury - ------ — - .10 U CV ' 7440-02-0 Nickel C.29 U P 7440-09-7 Potassium 448CO P 7782-49-2 ,Selenium 1,4 J P 7440-22-4 Silve_ 3.7 U - � ~' N P 7440-23-5 ''Sodium 259CO --- P 1 - _- 7440-28-0 Thallium 3.5_U_ P '7440-62-2 Vanadium 1.3 BLL P 7440-66-6 IZinc __12.4 B P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: YELLOW Clarity After: CLEAR Artifacts: Comments: Date Reported 7/20/2014 FORM I - IN ILM04. 1 ' LKBO10 S81 U.S. EPA - CLP 1 EPA SAMPLE NO ' INORGANIC ANALYSIS DATA SHEET Field Blank Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LKBO10 ' Matrix (soil/water) : WATER Lab Sample ID: 1407015-013 Level (low/med) : LOW Date Received: 7/1/2014 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. Analyte Concentration C Q M ' 7429-90-5 Aluminum 21.8 B _ P 7440-36-0 Antimony 1.6 U P J 7440-38-2 Arsenic __ 1.5U P 7440-39-3 Barium 0.5CIB P 7440-41-7 Beryllium 0.0911U P 17440-42-8 Boron 3.91 B 7440-43-9—Cadmium 0.14{ U ! P 7440-70-2 Calcium ! 31.7 BP 17440-47-3 'Chromium _ 2.2 B P 7440-48-4 Cobalt _ 0.16 U P 17440-50-8 Copper T ` - 0.80 B P 57-12-5 Cyanide 10.0 U CA ,7439-89-6 Iron 55.2 B P 17439-92-1 Lead 1.0 UI P 7439-95-4 Magnesium 18.3 U P 7439-96-5 Manganese _0.50 B P 7439-97-6 Mercury 0.10 U CV 1 7440-02-0 Nickel _ _ 0.29 U P 1 7440-09-7 Potassium 211 B _ P 7782-49-2 Selenium 1.4 U P- 7440-22-4 Silver 0.95 B N T P 7440-23-5 Sodium 86.6 B P 7440-28-0 Thallium3.5 U P ' 7440-62-2 Vanadium T 0.40 B P 7440-66-6 Zinc 1 3.5 B P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported. 7/20/2014 FORM I - IN ILM04.1 LKBO10 S82 , 1 aceLoflg Island 575 Broad Flolbw Road =et 631.694.3040 Melville,NY 11747 >, 631 420.8436 4.3 WET CHEMISTRY 1 1 LKBO10 S83 /ry�7 / LABORATORY RESULTS ' r - a'C6 -i a1Xica-/ Results for the samples and analytes requested 575 Broad Hollow Road, Melville,W11747 TEL:(631)894-3040 FAX:(631)420A438 The lab is not directly responsible for the integrity of the sample before receipt at the lab and Is responsible only for the certified tests requested. WSDOHIDft10478 wwwpacelabs.rom Lockwood Kessler&Bartlett Sample Information: One Aerial Way Syosset,NY 11791 Lab No. : 1407015-001 Type: Groundwater ' Client Sample ID: MW-1D Attn To : John Gerlach Collected :6/30/2014 3:00:00 PM Origin: Received :7/1/2014 10:40:00 AM Collected By LKB99 Analytical Method: SM23208: Analyst: JDLR ParameteKsl Results Qualifier D. Units Analyzed: Container Alkalinity,Total(As CaCO3) 31.0 1 mg/L 07/08/2014 12:44 PM Container-01 of 02 , Analytical Method: E300.0: Analyst: bka Parameter(sl Results Qualifier D.F. Units Ana lyzed Container. Bromide <0.50 1 mg/L 07/10/2014 9:17 PM Container-01 of 02 ' Chloride 23.2 1 mg/L 07/10/2014 9:17 PM Container-01 of 02 Sulfate 63.0 D 5 mg/L 07/10/2014 9:31 PM Container-01 of 02 AnaMtical Method: SM5210B: Prep Method: SM5210B Prep Date:7/212014 7:32:55 AM Analyst VaS , Parametef(sl Results Oualifier 2.F. Units Analyzed: Container. Biochemical Oxygen Demand <2 1 mg/L 07/0212014 9:45 AM Container-01 of 02 Analytical Method: E410.4: Analvst: VaS Parameter(sl Results Qualifier D. Units Analyzed: Container: Chemical Oxygen Demand <10.0 1 mg/L 07/14/2014 9:36 AM Container-01 of 01 Analytical Method: SM212OB:IOC Analyst: EM Parametertsl Results Qualifier D. Units Analyzed: Container. , Color <5.00 1 units 07/02/2014 5:02 AM Container-01 of 02 Color pH 6.00 + 1 units 07/02/2014 5:02 AM Container-01 of 02 Analytical Method: M3500-Cr D: Analyst: EM ' Parameter(sl Results Qualifier D.F. Units Analyzed: Container. Chromium,Hexavalent <0.02 1 mg/L 07/02/2014 5:47 AM Container-01 of 02 Analytical Method: SM2340C: Analyst: JA Parameter(sl Results Quarifier D_F. Units Analyzed: Container: Hardness(As CaCO3) 76 D 4 mg/L 07/10/2014 12:10 PM Container-01 of 01 Analytical Method: E350.1: Analyst: bka Parameters) Results Qualifier D_F. Units Analyzed: Container. Nitrogen,Ammonia(As N) <0.10 1 mg/L 07/07/2014 12:03 PM Container-01 of 01 Analytical Method: E353.2: Analyst: TF Parameters) Results Qualifier D_F. Units Analyzed: Container. ' Nitrite as N <0.10 1 mg/L 07/02/2014 7:36 AM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte I matrix I method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC , J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 8/11/2014 Pagel of 26 , LKB010 S84 , ' f LABORATORY RESULTS i 7,IaXAnalyiticaf 575 Broatl�ollow Road. Melvlla,NY 11747 Results for the samples and analytes requested ' ' TEL:(631)694-3040 FAX:(631)420-6x36 The lab is not directly respo ffpr the integrity of the sample before receipt at the 18b and is responsib:e onlyly foror the certified tens requested. � NYSDOH 0#10478 sv8^N.pacelabs.mm Lockwood Kessler&Bartlett Sample Information: One Aerial Way Lab No. : 1407015-001 Syosset,NY 11791 Type: Groundwater Attn To John Gerlach Client Sample ID: MWA D Collected :6/30/2014 3:00:00 PM Origin: ' Received :7/1/2014 10:40:00 AM Collected By LKB99 Analytical Method: E353.2: Analyst: TF Parameterfsl Results Qualifier D.F.. Units na ed: Container., ' Nitrate as N 3.37 D 5 mg/L 07/02/2014 6:37 AM Container-01 of 01 Analytical Method: E420.1: Prop Method: E420.1 Prep Date:7/10/2014 7:30:00 AM Analyst: EM Parameterfsl Results Qualifier D.F. Units Analyzed: Lontaine. ' Phenolics,Total Recoverable <5.0 1 pg/L 07/14/2014 12:02 PM Container-01 of 01 AnaNtical Method: SM2540C:IOC Analyst: SH2 Parameterfsl Results Qualifier D.F. Units Ana zed: Container. ' Total Dissolved Solids 196 1 mg/L 07/02/2014 11:03 AM Container-01 of 02 Analytical Method: E351.2: Prep Method: 351.2 Prep Date:7110/2014 5:30:00 AM Analyst: TF Parameterfsl Results Qualifier D.F.. Units Analyzed: container: Nitrogen,Kjeldahl,Total 0.22 1 mg/L 07/10/2014 11:36 AM Container-01 of 01 Analytical Method: SW9060: Analyst: CN Parameterfsl Results Qualifier D.F.. Units Analyzed: Container. Total Organic Carbon <1.0 1 mg/L 07/12/2014 4:30 AM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H-Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte I matrix I method c=Calibration acceptability criteria exceeded for this analyte ' r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. ' Date Reported. 111];2014 Page 2 of 26 LKB010 S85 r' r f LABORATORY RESULTS ' - r?GB/ nyf ca" Results for the samples and analytes requested 575 Broad follow Road, Melville,NY 11747 r T'EL:(631)894-3040 FAX:(631)420-8436 The lab is not directly responslble'of the Integrity of the sample before receipt at , NYSCOH IDi110478 wwwoacelabs cpm the lab and is responsible only for the certified tests requested. Lockwood Kessler&Bartlett One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1407015-002 Type: Groundwater ' Attn To : John Gerlach Client Sample ID: MW-1S Collected :6/30/2014 2:30:00 PM Origin: Received :7/112014 10:40:00 AM ' Collected By LKB99 Analytical Method. SM2320B: Analyst: JDLR Parameterfs) Results Qualifier D_F. Units Analyzed: Container. Alkalinity,Total(As CaCO3) 4.60 1 mg/L 07/0812014 12:52 PM Container-01 of 02 Analytical Method: E300.0: Analyst: bka Parameterfs) Results ualifierD_F. Units Analyzed: Container. Bromide <0.50 1 mg/L 07/1012014 9:44 PM Container-01 of 02 , Chloride 30.8 1 mg/L 07/10/2014 9:44 PM Container-01 of 02 Sulfate 18.0 1 mg/L 0711012014 9:44 PM Container-01 of 02 Analytical Method: SM5210B: Prep Method: SM5210B Preto Date:712/2014 7:32:55 AM Analyst: VaS Parameterfs) Results Qualifier D.F.. Units Analyzed: Container: Biochemical Oxygen Demand <2 1 mg/L 07/0212014 9:50 AM Container-01 of 02 Analytical Method: E410.4: Analyst VaS Parameterfs) Results Qualifier D.F.. Units Analyzed: Container: ' Chemical Oxygen Demand <10.0 1 mg/L 07/14/2014 9:38 AM Container-01 of 01 Analytical Method: SM212OB:IOC AnalM, EM Parameterfs) Results Qualifier D.F.. Units Analyzed: Container: , Color <5.00 1 units 07/02/2014 5:03 AM Container-01 of 02 Color pH 5.50 + 1 units 07/0212014 5:03 AM Container-01 of 02 Analytical Method: M3500-Cr D: Analyst: EM ' Parameterfs) Results Qualifier D. Units Anatvzed7 Container7 Chromium,Hexavalent <0.02 1 mg/L 07/02/2014 5:48 AM Container-tot of 02 Analytical Method: SM2340C: Analyst: JA ' Parameterfs) Results Qualifier D. Units Ana ed: Container: Hardness(As CaCO3) 34 D 2 mg/L 07/10/2014 12:15 PM Container-01 of 01 Analytical Method: E350.1: Analyst bka Parameterfs) Results Qualifier D. Units Ana ed: Container: ' Nitrogen,Ammonia(As N) <0.10 1 mg/L 07/07/2014 12:04 PM Container-01 of 01 Analytical Method: E353-2: Analyst: TF Parameterfs) Results Qualifier D_F. Units Analyzed: Container: ' Nitrite as N <0.10 1 mg/L 07/02/2014 7:37 AM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. , B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte!matrix)method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. ' S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported. 8/11/2014 Page 3 of 26 LKB010 S86 , ' LABORATORY RESULTS �� � �� � Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 ' TEL:(631)694-3040 FAX'(631)420-6436 The lab is not directly responsible for the integnty of the sample before receipt at the lab and is responsible only for the certified tests requested. NYSDOH 1/3910478 www.oacelabs.w Lockwood Kessler&Bartlett Sample Information: One Aerial Way Lab No. : 1407016-002 Type: Groundwater Syosset,NY 11791 Client Sample ID: MW-1S Attn To John Gerlach Collected :6130/2014 2:30:00 PM Origin: ' Received :7/112014 10:40:00 AM Collected By LKB99 Analytical Method: E353.2: AnatVst TF Parameterfs) Results Qualifier D.F. Units Analyzed: Container. ' Nitrate as N 2.57 D 5 mg/L 07/02/2014 8:38 AM Container-01 of 01 Analytical Method: E420.1 : Prep Method: E420.1 Prep Date:7110/2014 7:30:00 AM Ana st: EM Parameterfs) Results Qualifier D. Units Analyzed: Container. ' Phenolics,Total Recoverable <5.0 1 vg/L 07/14/2014 12:03 PM Container-01 of 01 Analytical Method: SM2540C:IOC Analyst: SH2 Parameterfs) sults QuAlifier D_F. Units Analyzed: Container ' Total Dissolved Solids 115 1 mg/L 07102/2014 11:04 AM Container-01 of 02 Analytical Method: E351.2: Prep Method: 351.2 Prep Date:7110/2014 5:30:DO AM Analyst: TF Parameterfs) Results Qualifier D.F. Units Analyzed: Container. Nitrogen,Kjeldahl,Total 0.28 1 mg/L 07/10/2014 11:39 AM Container-01 of 01 ' Analytical Method: SW9060: Ana st: CN Parameterfs) Results Qualifier D.F. Units Analyzed: Container. Total Organic Carbon <1.0 1 mg/L 07124/2014 11:00 PM container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank ' D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte/matrix!method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC ' J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 8/11/2014 Page 4 of 26 1 LKB010 S87 ;a7ceAnalyfical" LABORATORY RESULTS ' Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 TEL:(631)694-3040 FAX:(631)420.8435 The lab is tot directly responsible for the integrityto tithe requested. before receipt at the lab and is responsible only for the certified tests requested. NYSDOH Oft 10478 www.tacelabs.com Lockwood Kessler&Bartlett One Aerial Way Sample Information: Lab No. : 1407015-003 Type: Groundwater , Syosset,NY 11791 Client Sample ID: MW-3D Attn To : John Gerlach Collected :6/30/2014 9:00:00 AM Origin: Received :7/1/2014 10:40:00 AM , Collected By LKB99 Analytical Method: SM23208: Analyst: JDLR ParamMff sl Results Qualifier D.F, Units Analyzed: Container. Alkalinity,Total(As CaCO3) 530 D 10 mg/L 07/08/2014 12:56 PM Condainer-01 of 02 , Analytical Method: E300.10: Analyst: bka Parameter(sl Results Qualifier D.F. Units Analyzed: Container. Bromide <0.50 1 mg/L 07/10/2014 9:58 PM Container-01 of 02 , Chloride 128 D 5 mg/L 07/10/2014 10:11 PM Container-01 of 02 Sulfate 41.8 1 mg/L 07/10/2014 9:58 PM Container-01 of 02 Analytical Method: SM521OB: Prep Method: SM5210B Prep Date:712/2014 7:32:55 AM Analyst: VaS , Parameter(sl Results Qualifier Q. Units Analyzed: Container Biochemical Oxygen Demand <4 1 mg/L 07102/20114 9:55 AM Container-01 of 02 Analytical Method: E410.4: Analyst VaS ' Parameter(sl Results ualifier D_F. Units nal Container: Chemical Oxygen Demand 47.0 1 mg/L 07/14/2014 9:40 AM Container-01 of 01 Analytical Method: SM212OB:IOC Analyst: EM Parameter(sl Results QualifierD_F. Units Analyzed: Container. Color 125 D 5 units 07102/2014 5:04 AM Container-01 of 02 Color pH 7.5 D + 5 units 07/02/2014 5:04 AM Container-01 of 02 Analytical Method: M3500-Cr D: Analyst: EM I Parameter(sl Results Qualifier D.F. Units Analyzed p t Chromium,Hexavalent <0.02 1 mg/L 07/02/2014 5:49 AM Container-01 of 02 Analytical Method: SM2340C: Analyst: JA , Parameter(sl Results Qualifier D. Units Analyzed: Container: Hardness(As CaCO3) 180 D 10 mg/L 07/10/2014 12:20 PM Container-01 of 01 Analytical Method: E350.1 Anafvstbka Parameter(s1 Results Q011fier D_F. Qnits Ana ed: Container. , Nitrogen,Ammonia(As N) 7.60 D 50 mg/L 07/0712014 12:05 PM Container-01 of 01 Analytical Method: E353.2: Analyst: TF Parameter(s) Results Qualifier Q. Units Anal Container: Nitrite as N <0.10 1 mg/L 07102/2014 7:39 AM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution , H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte I matrix I method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC ' J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 8/11/2014 Page 5 of 26 ' LKBO10 S88 , LABORATORY RESULTS aceAnalyf+cal Results for the samples and analytes requested 575 Broad Hallow Road, Melville,NY 11747 TEL:(831)8943040 FAX:(63?)420-8438 The lab is not directly responsible for the integrity of the sample before receipt at ` the NYSDOH ID#10478 www.oacelabs atm lab and is responsible only for the certified tests requested r Lockwood Kessler&Bartlett One Aerial Way Sample Information: ' Lab No. : 1407015-003 Type: Groundwater Syosset,NY 11791 ID: Attn To : John Gerlach Client Sample MW-3D Collected :6/30/2014 9:00:00 AM Origin: ' Received :7/l/2014 10:40:00 AM Collected By LKB99 Analytical Method: E353.2: Analyst: TF Parameterfs) Results Qualifier D.F. Units AnaContamner- Nitrate as N <0.10 1 mg/L 07/02/2014 8:39 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date:7/1Oi2014 7:30:00 AM Analyst: EM Parameterfsl Results Qualifier D. Units Analyzed: Container: ' Phenolics,Total Recoverable <5.0 1 pg/L 07114/2014 12:04 PM Container-01 of 01 Analytical Method: SM2540C:IOC Analyst SH2 Parameterfsl Results ualifierD_F. Units Analyzed: Container ' Total Dissolved Solids 602 1 mg/L 07/02/2014 11:04 AM Container-01 of 02 Analytical Method: E351.2: Prep Method: 351.2 Prep Date:7/10/2014 5:30:00 AM Analyst: TF Parameterfs) Resul s Qualifier D_F. Uni s AnalyzedContainer: ' Nitrogen,Kjeldahl,Total 72.4 D 20 mg/L 07/10/2014 11:40 AM Container-01 of 01 Analytical Method_ SW9060: Analyst: CN Parameter(sl Results Quaiifier D.F. Units Analyzed; Container: Total Organic Carbon 24.2 D 10 mg/L 0711212014 5:53 AM Container-01 of 02 1 ' Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank ' D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte!matrix/method c=Calibration acceptability criteria exceeded for this analyte ' r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 1111/2114 Page 6 of 26 ' LKBO10 S89 a LABORATORY RESULTS , ° "y aC6APa1 dca" Results for the samples and analytes requested / 575 Broad Hollow Road, Melville,NY 11747 TEL:(631)694-3040 FAX:(631)420-6436 The lab is not directly responsible for the integrity tof the sample before receipt at the lab and is responsible only for the certified tests requested. NYSCOH IDg10476 www.pacNabs.corn Lockwood Kessler&Bartlett One Aerial Way Sample Information: Syossetl 11791 Lab No. : 1407015-004 Type: Groundwater ' Client Sample ID: MW-3S Attn To : John Gerlach Collected :6/30/2014 8:30:00 AM Origin: Received :7/112014 10:40:00 AM , Collected By LKB99 Analytical Method: SM2320B: Analyst: JDLR Parameters) Results Qualifier D.F. Units Analyzed: Container Alkalinity,Total(As CaCO3) 177 D 2 mg/L 07108!2014 1:03 PM Container-01 of 02 , Analvtical Method: E300.0: Analyst: bka Parameters) R ults guarifier D_F. Units Analyzed: Container: Bromide <0.50 1 mg/L 07110/2014 10:25 PM Container-01 of 02 , Chloride 72.8 D 5 mg/L 07/10/2014 10:38 PM Container-01 of 02 Sulfate 49.7 1 mg/L 07/10/2014 10:25 PM Container-01 of 02 Analytical Method: SM5210B: Prep Method: SM5210B Prep Date:7/212014 7:32:55 AM Analyst: VaS Parameter(sl Results ualifier D.F. Units Analyzed: ontainer. Biochemical Oxygen Demand <4 1 mg/L 07/02/2014 10:00 AM Container-01 of 02 Analytical Method: E410.4: Analyst: VaS ' Parameter(sl Results Qualifier D_F. Units Analyzedm Container: Chemical Oxygen Demand 29.2 1 mg/L 07/14/2014 9:42 AM Container-011 of 01 Analytical Method: SM212OB:IOC Analyst: EM Parameter(st Results Qualifier D. Units Analyzed: Container: ' Color 125 D 5 units 071C212014 5:05 AM Container-01 of 02 Color pH 7 D + 5 units 07/02/2014 5:05 AM Container-01 of 02 Analytical Method: M3500-Cr D: Analyst: EM , Parameters) Results Qualifier D. Units Analyzed: Container: Chromium,Hexavalent <0.02 1 mg/L 07/02/2014 5:50 AM Container-01 of 02 Analytical Method: SM234OC: Analyst: JA , Parameters) Results Qualifier D.F.. Units Analyzed: Container: Hardness(As CaCO3) 140 D 10 mg/L 07/10/2014 12:25 PM Container-07 of 01 Analytical Method: E350.1: Analyst: bka Parameter(s1 Results Qualifier D.F.. UnitsaAn lyzed Container: , Nitrogen,Ammonia(As N) 15.2 D 10 mg/L 0710712014 12:07 PM Container-011 of 01 Analytical Method: E353.2: Analyst: TF Parameters) Results Qualifier Q.F.. Units Analyzed: Container. ' Nitrite as N <0.10 1 mg/L 07/02/2014 7:40 AM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank GN D.F.=Dilution Factor D=Results for Dilution , H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte!matrix 1 method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC , J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported 8/11/2014 Page 7 of 26 , LKB010 S90 ' ' LABORATORY RESULTS l � Analytfcal Results for the samples and analytes requested ' 575 Broad Hollow Road, McMlle,NY 11747 TEL:(631)694-3046 FAX:(631)420-8436 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested NYSDOH IDf.'10478 www.oacelabs.com Lockwood Kessler&Bartlett Sample Information: One Aerlal Way ' Syosset,NY 11791 Lab No. : 1407015-004 Type: Groundwater Attn To : John Gerlach Client Sample ID: MW-3S Collected :613012014 8:30:00 AM Origin: Received :71112014 10:40:00 AM Collected By LKB99 AnaMical Method: E353.2: Analyst: TF Parameterls) Results Qualifier D.F. Units Analyzed: Container: ' Nitrate as N <0.10 1 mg/L 07/02/2014 8:40 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date:7/10/2014 7:30:00 AM Analyst EM Param igy.Q Results Qualifier D. Units Analyzed, Container: ' Phenolics,Total Recoverable <5.0 1 pg/L 07114/2014 12:05 PM Container-01 of 01 Analytical Method: SM254CC:IOC Analyst: SH2 Parameterls) Results ualifierD_F. Units Analyzed: Container: ' Total Dissolved Solids 380 1 mg/L 07/02/2014 11:06 AM Container-01 of 02 Analytical Method: E351 2: Prep Method: 351.2 Prep Date: 7/10/2014 5:30:00 AM Analyst: TF Parameterls) Results Qualifier D.F. Units Analyzed: Container: ' Nitrogen,Kjeldahl,Total 16.5 D 10 mg/L 07/10/2014 11:43 AM Contalner-o1 of 01 Analytical Method: SW9060: Analyst: CN Parameterls) Results Qualifier D.F. Units Analyzed: Container: Total Organic Carbon 10.0 D 10 mg/L 07112/2014 6:34 AM Container-01 or 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank ' D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte/matrix 1 method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC ' J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: $11112014 Page 8 of 26 ' LKB010 S91 LABORATORY RESULTS , �� � � �� � Results for the sam les and analytes requested r 575 Broad Hollow Road, Melville,NY 11747 p � q TEL:(531)694-3040 FAX(631)420-8435 The lab is not directly responsible for the integrity of the sample before receipt at ' the lab and is responsible only for the certified tests reWested, NYSDOH 10#10478 wwwpaacelahs.mm Lockwood Kessler&Bartlett One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1407015-005 Type: Groundwater ' Client Sample ID: MW-4D Attn To : John Gerlach Collected :6/30/2014 11:00:00 AM Origin: Received :7/1/2014 10:40:00 AM ' Collected By LKB99 Analytical Method: SM23208: Analyst: JDLR Parameters) Results Qualifier D.F. Units Analyzed: Container: Alkalinity,Total(As CaCO3) 761 D 10 mg/L 07/08/2014 1:10 PM Container-01 or02 , Analytical Method: E300.0: Analyst: bka Parameter(s1 Results Qualifier D.F. Units Analyzed: Container: Bromide 1.87 1 mg/L 07110/2014 10:52 PM Container-01 of 02 , Chloride 330 D 10 mg/L 07115/2014 11:56 PM Container-01 of 02 Sulfate 106 D 5 mg/L 07110/2014 11:32 PM Container-01 of 02 Analytical Method: SM5210B: Prep Method: SM5210B Prep Date:7/2/2014 7:32:55 AM Anal : VaS , Parameter(s1 Results ualifier D_F. Units Analyzed: Container. Biochemical Oxygen Demand <2 1 mg/L 07102/2014 10:05 AM Container-01 of 02 Analytical Method: E410.4: Analyst: VaS Parameter(sl Results Qualifier Q.F.. Units Analyzed: Container ' Chemical Oxygen Demand 57.7 1 mg/L 07114/2014 9:44 AM Container-01 of 01 Analytical Method: SM21208:IOC Anal : EM Parameter(s1 Results Qualifier D. Units Analyzed: Container: ' Color 30.0 1 units 07/02/2014 5:06 AM Container-01 of 02 Color pH 7.50 + 1 units 07/02/2014 5:06 AM Container-01 of 02 Analytical Method: M3500-Cr D: nal EM I Parameterts) Results ualifier F. Units Analyzed: Container: Chromium,Hexavalent <0.02 1 mg/L 07/02/2014 5:51 AM Container-01 of 02 Analytical Method: SM2340C: Analyst: JA I Parameteral�er s) Results uF. Units Ana ed: o tainer: Hardness(As CaCO3) 750 D 50 mg/L 07/10/2014 12.30 PM Container-01 of 01 AnaMical Method: E350.1: analyst; bka Parameters) Results C ualifier D_F. Units Anal Container: ' Nitrogen,Ammonia(As N) 24.4 D 10 mg/L 07/07/2014 12:08 PM Container-01 of 01 Analytical Method: E353.2: Analyst: TF Parameterfsl Results Qualifier D.F.. Units Analyzed: Container. , Nitrite as N <0.10 1 mg/L 07/02/2014 7:41 AM Container-01 of o2 Qualifiers: E=Value above quantitation range,Value estimated. ' B=Found in Blank D.F.=Dilution Factor D=Results for Dilution ' H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte I matrix!method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. ' S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 8/11/2014 Page 9 of 26 ' LKBO10 S92 , ' LABORATORY RESULTS '11!;ac nalWaf Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 TEL.;631;694-3040 FAX(631)420-8436 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. NYSDOH:D#10478 wwwoaoelabs.com Lockwood Kessler&Bartlett ' One Aerial Way Sample Information:Lab No. : 1407015-005 Type: Groundwater Syosset,NY 11791 Client Sample ID: MW-4D All To : John Gerlach Collected :6/30/2014 11:00:00 AM Origin: ' Received :7/1/2014 10:40:00 AM Collected By LKB99 Analytical Method: E353.2: Analyst: TF Parameters) Results Qualifier D.F. Units Analyzed: Container. ' Nitrate as N <0.10 1 mg/L 07/02/2014 8:41 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date: 7/10/2014 7:30:00 AM Ana st: EM Parameter(Q Results Qualifier D.F. Units Analyzed: Container. ' Phenolics,Total Recoverable <5.0 1 pg/L 07/14/2014 12:06 PM Container-01 of 01 Analytical Method: SM254OC:IOC Analyst: SH2 Parameter(s) Results Qualifier D.F.. Units nal � Container: ' Total Dissolved Solids 1,230 1 mg/L 07!02/2014 11:06 AM Container-01 of 02 Analytical Method: E351.2: Prep Method: 351.2 Preo Date: 7/1012014 5:30:00 AM Analyst: TF Parameters) Results Qualifier D.F. Units Ana ed: Container: ' Nitrogen,Kjeldahl,Total 40.3 D 10 mg/L 07/1012014 11:44 AM Container-Ot of 01 Analytical Method: SW9060: Analyst: CN Parameters) Results Qualifier D.F.. Units Ana ed: Container: Total Organic Carbon 23.2 1 mg/L 07/12/2014 7:16 AM Container-01 of 02 DualKfers: E=Value above quantitation range,Value estimated. B=Found in Blank __— ' D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte/matrix/method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC ' J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 8/11/2014 Page 10 of 26 ' LKBO10 S93 �} /� LABORATORY RESULTS , G � �� Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 ' TEL:(631)694-3040 FAX(S31)420 436 The let)is not d;recty responsible for the integrity of the sample before receipt at the lab and Is responsible only for the cenfied tests requested. i NYSDOHID010478 www.oamlabs.com Lockwood Kessler&Bartlett Sample Information: One Aerial Way Lab No. : 1407015-006 Type: Groundwater ' Syosset,NY 11791 Client Sample ID: MW-4S Attn To : John Gerlach Collected :6/30/2014 10:30:00 AM Origin: Received :7/1!201410:40:00 AM Collected By LKB99 Analytical Method: SM2320B: Analyst: JDLR Parameters) Results ualifier Q.F. Units al e : Container: Alkalinity,Total(As CaCO3) 169 D 2 mg[L 07/08/2014 1:20 PM Container-01 of 02 ' Analytical Method: E300.0: Analyst: bka Parameters]! Results ualifier 2.F. Units Analyzed: Container. Bromide <0.50 1 mg/L 07/10/2014 11:46 PM Container-01 of 02 , Chloride 16.3 1 mg/L 07/10/2014 11:46 PM Container-01 of 02 Sulfate 37.4 1 mg/L 07/10/2014 11:46 PM Container-01 of 02 AnaMical Method: SM5210B: Prep Method: SM5210B Prep Date:7/2/2014 7:32:55 AM Ana st: VaS ' Parameters) Results Qualifier D.F. Units Ana ed: Container. Biochemical Oxygen Demand <2 1 mg/L 07/02/2014 10:10 AM Container-01 of 02 Anehrtical Method: E410.4: Analyst: VaS ' Parameters) Results Qualifier D. Units Analyzed: Containerm Chemical Oxygen Demand 21.6 1 mg/L 07/14/2014 9:46 AM Container-01 of 01 Analytical Method: SM21208:IOC Analyst: EM Parameters) Results Qualifier D_F. Units Analyzed: Container: ' Color <5.00 1 units 07102/2014 5:07 AM Container-01 of 02 Color pH 7.00 + 1 units 07102/2014 5:07 AM Container-01 of 02 Analytical Method: M3500-Cr D: Analyst: EM , Parameters) Results Oualifier D_F. Units Analyzed: Container: Chromium,Hexavalent <0.02 1 mg/L 07/02/2014 5:52 AM Container-01 of 02 Analytical Method: SM234OC: Analyst JA ' Parameters) Results Qualifier Q.F.. Units Analyzed: Container: Hardness(As CaCO3) 210 D 10 mg/L 07/10/2014 12:35 PM Container-01 of 01 Analytical Method: E350.1 : Analyst: bka Parameters) Results ualifierD_F. Units Analvzed: o ta' e ' Nitrogen,Ammonia(As N) <0.10 1 mg/L 07107/2014 12:09 PM Container-01 of 01 Analytical Method: E353.2: Analyst: TF Pafameter(S) Results Qualifier D.F.. Units Analyzed Container ' Nitrite as N <0.10 1 mg/L 07/0212014 7:42 AM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. �1 , B=Found in Blank D.F.=Dilution Factor D=Results for Dilution , H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSOCH ELAP does not offer certification for this analyte/matrix/method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC ' J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 8/11/2014 Page 11 of26 ' LKBO10 S94 ' LABORATORY RESULTS f _- a1C6Ana1ydca1 Results for the samples and analytes requested 575 Bread Hollow Road, Melville,NY 11747 ' TEL;631)694-3040 FAX:(631)420-8435 The lab is responsible not directly responsible for the integrity of the sample before receipt at the lab and is responsible only forthe certifed tests requestetl. NYSDOH 10#10478 www.oacelabs com Lockwood Kessler&Bartlett Sample Information: One Aerial Way ' Syosset,NY 71791 Lab No. : 1407015-006 Type: Groundwater Client Sample ID: MW-4S Attn To John Gerlach Collected :6/3012014 10:30:00 AM Origin: Received :71112014 10:40:00 AM Collected By LKB99 Analytical Method: E353.2: Analyst: TF Parameterfs) Results ualifier D_F. Units Analyzed: Container. Nitrate as N 14.0 D 20 mg/L 0710212014 8:45 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date:7/10/2014 7:30:00 AM Analyst: EM Parameterfs) Results Qualifier D.F. Units Analyzed: Container. Phenolics,Total Recoverable <5.0 1 pg/L 07/14/2014 12:07 PM Container-01 of 01 Analytical Method: SM2540C:IOC Analyst: SH2 Parameterfs) Results Qualifier D. UnitsnA alvzed: Container. ' Total Dissolved Solids 400 1 mg/L 07/02/2014 11:07 AM Container-01 of 02 Analytical Method: E351.2: Prep Method: 351.2 Prep Date:7/10/2014 5:30:00 AM Analyst: TF Parameterfs) Results Qualifier D.F. Units Analyzed: Container. Nitrogen,Kjeldahl,Total 0.75 1 mg/L 07/10/2014 11:44 AM Container-01 of 01 ' Analytical Method: SW9060: Analyst: CN Parameterfs) Results Qualifier D.F. Units Analyzed: Container. Total Organic Carbon 5.8 1 mg/L 07/24/2014 11:00 PM Container-01 of 02 ' Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte/matrix/method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC ' J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 8/11/2014 Page 12 of 26 1 ' LKB010 S95 saCl { [�1,. LABORATORY RESULTS / Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 ' TEL(631)694-3040 FAX:(631)420-8436 The lab is not cirectly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. 1' NYSCOH 113#1047B wwwpacelabs cpm Lockwood Kessler&Bartlett Sample Information: One Aerial Way Lab No. : 1407015-007 Type: Groundwater , Syosset,NY 11791 Client Sample ID: MW-6D Attn To : John Gerlach Collected :6/30/2014 9:50:00 AM Origin: Received :7/1/2014 10:40:00 AM ' Collected By LKB99 Analytical Method: SM2320B: Analyst: JDLR Parameterlsl Results ualifierD_F. Units Analyzed: Container. Alkalinity,Total(As CaCO3) 691 D 10 mg/L 07/08/2014 1:27 PM Container-01 of 02 ' Analytical Method: E300.0: Analyst: bka Parameterlsl Results Qualifier D.F. Units Analyzed: Container. Bromide 0.98 1 mg/L 07/10/2014 11:59 PM Container-01 of 02 ' Chloride 186 D 10 mg/L 07/11/2014 12:13 AM Container-01 of 02 Sulfate 45.4 1 mg/L 07/10/2014 11:59 PM Container-01 of 02 Analytical Method: SM52108: Prep Method: SM5210B Prep Date:7/2/2014 7:32:55 AM Analyst VaS , Pframeter(s) Results C.Luarifier D.F. Units Analyzed: Container. Biochemical Oxygen Demand <2 1 mg/L 0710212014 10:15 AM Container-01 of 02 Analytical Method: E410.4: Analyst: VaS ' Parameterlsl Results Qualifier Q.F.. Units Analyzed: Container, Chemical Oxygen Demand 74.4 1 mg/L 07/14/2014 9:48 AM Container-01 of 01 Analytical Method: SM21206 IOC Analyst: EM Parameterlsl Results Qualifier D. Units Analyzed: Container: Color 35.0 1 units 07/02/2014 5:08 AM Container-Ot of 02 Color pH 8.00 + 1 units 07/02/2014 5:08 AM Container-01 of 02 Anal)dical Method: M3500-Cr D. Analyst EM , Parameters) Results Qualifier D.F. Units Analyzed;. Container. Chromium,Hexavalent <0.02 1 mg/L 07102/2014 5:53 AM Container-01 of 02 Analytical Method: SM2340C: Analyst: JA , Parameterlsl Results ualifier D_F. Units Analyzed: Container Hardness(As CaCO3) 400 D 20 mg/L 07/10/2014 12:40 PM Container-01 of 01 Analytical Method: E350.1: Analyst: bka Parameters) Results Qualifier D.F.. Units Anal Contalner. ' Nitrogen,Ammonia(As N) 88.2 D 25 mg/L 07/07/2014 12:10 PM Container-01 of 01 Analytical Method: E353.2: Analyst: TF Parameterlsl Results gualifier D_F. nits Analyzed: Container. ' Nitrite as N <0.10 1 mg/L 07/02/2014 7:46 AM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution , H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte/matrix/method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. ' S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 8/11/2014 Page 13 of 26 ' LKBO10 S96 , ' ,• LABORATORY RESULTS ceAnall ' Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY'1747 ' TEL:(631)694-3040 FAX:i631)420-8436 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. NYSDOH10#10478 wwwoacelabs.com Lockwood Kessler&Bartlett Sample Information: One Aerial Way' Syosset,NY 11791 Lab No. : 1407015-007 Type: Groundwater Attn To John Gerlach Client Sample ID: MW-5D Collected :6130/2014 9:50:00 AM Origin: Received :711/2014 10:40:00 AM Collected By LKB99 Analytical Method. E353.2: Analyst: TF Parameters) Results Qualifier D. Units Analyzed ntainer; Nitrate as N <0.10 1 mg/L 07/02/2014 8:46 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date:7/10/2014 7:30:00 AM Analyst: EM Parameters) Results Qualifier D. Units Analyzed: Container: ' Phenolics,Total Recoverable <5.0 1 Ng/L 07/14/2014 12:08 PM Container-01 of 01 Analytical Method: SM254OC:IOC Analyst7 SH2 Parameters) Results ualifierD_F. Units Analyzed: Container: Total Dissolved Solids 954 1 mg/L 07/02/2014 11:07 AM Container-01 of 02 Analytical Method: E351.2: Prep Method: 351.2 Prep Date: 7/10/2014 5:30:00 AM Analyst: TF Parameters) Results Qualifier D. Units Analyzed: Container Nitrogen, Kjeldahl,Total 102 D 50 mg/L 07110/201411:45 AM Container-01 of 01 ' Analytical Method: SW9060: Analyst: CN Parameters) Results Qualifier D.F. Units Analyzed: Container: Total Organic Carbon 29.0 D 10 mg/L 07/24/2014 11:00 PM Container-01 of 02 ' Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank ' D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte/matrix/method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC ' J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 8,111/2014 Page 14 of 26 ' LKB010 S97 LABORATORY RESULTS/,/�7 ' 46Anal, ",,}ical Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 1 TEL(631)594-3040 FAX:(631)420-8436 The lab Is not directly responsible for the integdly of tie sample before receipt at ' the lab and is responsible only for the certified tests requested. NYSDOH ID410478 mmoacelabs.com Lockwood Kessler&Bartlett One Aerial Way Samole Information: Syosset,NY 11791 Lab No. : 1407015-008 Type: Groundwater , Attn To John Gerlach Client Sample ID: MW-6S Collected :5/3012014 9:30:00 AM Origin: Received :7/112014 10:40:00 AM Collected By LKB99 Analytical Method: SM2320B: Analyst: JDLR Parameterfsl Results Qualifier D.F.- Units Al Container Alkalinity,Total(As CaCO3) 21.3 1 mg/L 07/06/2014 1:35 PM Container-01 of 02 ' Analytical Method: E300-0: Analyst: bka Parameterls/ Results ualifier D.F. Units Analyzed: Container: Bromide <0.50 1 mg/L 07/11/2014 12:26 AM Container-01 of 02 ' Chloride 27.8 1 mg/L 07/11/2014 12:26 AM Container-01 of 02 Sulfate 15.0 1 mg/L 07/11/2014 12:26 AM Container-01 of 02 Analytical Method: SM5210B: Prep Method: SM5210B Prep Date:7/2/2014 7:32:55 AM Analyst: VeS Parameterls) Results Qualifier D. Units Ana ed: Container: Biochemical Oxygen Demand <2 1 mg/L 07/02/2014 10:20 AM Container-01 of 02 Analytical Method: E4104: Analyst: VaS Parameterfsl ResultS Qualifier D_F. Units Analyzed: Container. ' Chemical Oxygen Demand <10.0 1 mg/L 07/14/2014 9:50 AM Container-01 of 01 Analytical Method: SM212OB:IOC Analyst: EM Parameterls) Results -Qualifier D.F.. Units Analyzed: Container: ' Color 15.00 1 units 07/02/2014 5:09 AM Container-01 of 02 Color pH 5.50 + 1 units 07/02/2014 5:09 AM Container-01 of 02 Analytical Method: M3500-Cr D: Analyst: EM ' Parameterls) Results ualifier D_F. Units Analyzed: Container. Chromium,Hexavalent <0.02 1 mg/L 07/02/2014 5:54 AM Container-01 of 02 Analytical Method: SM2340C: Analyst: JA Parameterfsl Results Qualifier D.F.. Units Analvzed: Container. Hardness(As CaCO3) 44 D 4 mg/L 07/1012014 12:45 PM Container-01 of 01 Analytical Method: E350.1: Anatysti bka Parameterfsl Results Qualifier D.F.. Units Analyzed: Container. ' Nitrogen,Ammonia(As N) <0.10 1 mg/L 07107/2014 12:11 PM Container-Ot of 01 Analytical Method: E353.2: Analyst: TF Parameterfsl Results aualifier D. Units Analyzed Container, ' Nitrite as N <0.10 1 mg/L 07/02/2014 7:47 AM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found iBlank D.F.=Dilutioo n Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte/matrix/method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. ' S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 8/11/2014 Page 15 of 26 LKBO10 S98 ' LABORATORY RESULTS ` � � Results for the samples and analytes requested 575 Broad Hollow Road Melville,NY 11747 TEL.(631)594-3040 FAX:(631)420-8436 The lab is not directly responsible for the integrity of:he sample before receipt at the lab and is responsible only for the certified tests requested. NYSOOH ID#10478 www.pacelws.com Lockwood Kessler&Bartlett Sample Information: One Aerial Way Lab No. : 1407015-008 Type: Groundwater ' Syosset,NY 11791 : Client Sample ID: MW-5S Attn To John Gerlach Collected :6130/2014 9:30:00 AM Origin. ' Received :7/1/2014 10:40:00 AM Collected By LKB99 Analytical Method: E353.2: Analyst: TF Parameterfs) Results Qualifier D.F. Units Analyzed: Container ' Nitrate as N 1.29 1 mg/L 07/0212014 8:47 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date:7/10/2014 7:30:00 AM Analyst: EM Parameters) Results Qualifier D.F. Units Ana ed: Container: Phenolics,Total Recoverable <5.0 1 pg/L 07/14/2014 12:09 PM Container-01 of 01 Analytical Method: SM2540C:IOC Analyst: SH2 Parameters) Results Qualifter D.F. Units Analyzed: Container. Total Dissolved Solids 130 1 mg/L 0710212014 11:08 AM Container-01 of 02 Analytical Method: E351.2: Prep Method: 351,2 Prep Date:7110/2014 5:30:00 AM Analyst: TF Parameters) Results Qualifier D_F. Units Ana ed: Container. Nitrogen,Kjeldahl,Total 0.84 1 mg/L 07/10/2014 11:46 AM Container-01 or01 &nWylicaill Method: SW9060: Analyst: CN Parameterfsl Results Qualifier D.F. Units Analyzed: Container: Total Organic Carbon 1.5 1 mg/L 07/2412014 11:00 PM Container-01 of02 1 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank ' D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte/matrix/method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 8/11/2014 Page 16 of 26 ' LKB010 S99 ��i�i}J� LABORATORY RESULTS G t1ly1C1 Results for the samples and analytes requested 575 Broad Hollow Road Melville,ray 11747 TEL(631)694-3040 FAX(631)420-6436 The lab is not directly responsible for the integrity o`the sample before receipt at NYSDOH IDk10478 www.paC8labs, the lab and is responsible only for the certified tests requested. � com Lockwood Kessler&Bartlett Sample Information: One Aerial Way Lab No. : 1407015-009 Type: Groundwater Syosset,NY 11791 Client Sample ID: MW-6D , Attn To John Gerlach Collected :6130/2014 2:00:00 PM Origin: Received :7/1/2014 10:40:00 AM ' Collected By LKB99 Analytical Method: SM2320B: Analyst: JDLR Parameters) Results Qualifier D.F. Units Analyzed7 Container. Alkalinity,Total(As CaCO3) 11.2 1 mg/L 0710812014 1:41 PM Container-01 of 02 ' Analytical Method: E300.0: AnalySt7 bka Parameters) Results Qualifier D. Units Ana Container: Bromide <0.50 1 mg/L 07/11/2014 12:40 AM Container-01 of 02 ' Chloride 42.6 1 mg/L 07/11/2014 12:40 AM Container-01 of 02 Sulfate 101 D 5 mg/L 07111/2014 12:53 AM Container-01 of 02 Analytical Mathod: SM52108: Prep Method: SM5210B Prep Date:712/2014 7:32:55 AM Analyst: VeS Parameters) Results ualifier D.F.. Units Analyzed: Container: Biochemical Oxygen Demand <2 1 mg/L 07102/2014 10:25 AM Container-01 of 02 Analytical Method: E410.4: Analyst: VaS Parameters) Results Quarifler P.F.. Units Ana ed: Container. Chemical Oxygen Demand <10.0 1 mg/L 07114/2014 9:52 AM Container-01 of 01 Analytical Method: SM212OB:IOC AnalW: EM Parameters) Results Qualifier D.F.. Units Analyzed: Container. ' Color <5.00 1 units 07/02/2014 5:10 AM Container-01 of 02 Color pH 5-50 + 1 units 07/02/2014 5:10 AM Container-01 of 02 Analytical Method: M3500-Cr D: Analyst: EM , Parameters) Results ualifierD_F. Units Analyzed: Container. Chromium,Hexavalent <0.02 1 mg/L 07/02/2014 5:55 AM Container-01 of 02 Analytical Method: SM2340C: Analyst: JA Parameters) Results Qualifier D_F. Units Analyzed: Container. Hardness(As CaCO3) 130 D 10 mg/L 07/10/2014 12:50 PM Container-01 of 01 Analytical Method: E350.1: Analyst: bka Parameters) Results Qualifier D_F_ Units Analyzed: Container. Nitrogen,Ammonia(As N) <0.10 1 mg/L 07107/2014 12:12 PM Container-01 of 01 Analytical Method: E353.2: Anallyat TF Parameters) Results Qualifier D.F.. Units Analyzed: Container. Nitrite as N <0.10 1 mg/L 07/02/2014 7:48 AM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. ' B=Found in Blank D.F.=Dilution Factor D=Results for Dilution , H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte I matrixmethod c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. , S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 8/11/2014 Page 17 of 26 LKB010 S100 ' LABORATORY RESULTS " lytic Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 ' TEL:(631;694.3040 FAX:(631)420-8435 the lab Is not directly responsiole for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. i NYSDOH ID010479 www.oacelabs.com Lockwood Kessler&Bartlett One Aerial Way Sample Information: ' Syosset,NY 11791 Lab No. : 1407015-009 Type: Groundwater Client Sample ID: MW-613 Attn To John Gerlach Collected :6/30/2014 2:00:00 PM Origin: ' Received :7/1/2014 10:40:00 AM Collected By LKB99 Analytical Method: E353.2: Analyst: TF ParametgLW Results ualifier D_F. Units Analyzed: Container: ' Nitrate as N 9.19 D 10 mg/L 07/02/2014 9:49 AM Container-01 of 01 AnaMical Method: E420.1: Prep Method: E420.1 Prep Date:7/10/2014 7:30:00 AM Analyst: EM Parameteris) Results Qualifier D.F. Units Analyzed: Container: ' Phenolics,Total Recoverable <5.0 1 pg/L 07/1412014 12:10 PM Container-01 of 01 Analytical Method: SM254OC:IOC Analyst: SH2 Parameters) Results Qualifier D.F. Units Analyzed: Container, ' Total Dissolved Solids 348 1 mg/L 07/02/2014 11:09 AM Container-01 of 02 Analytical Method: E351.2: Prep Method: 351.2 Prep Date:7/10/2014 5:30:00 AM Analyst: TF Parameteris) Results Ouafifier D_F. Units Analyzed: Container: Nitrogen,Kjeldahl,Total 0.17 1 mg/L 07/10/2014 11:47 AM Container-01 of 01 ' Analytical Method: SW9060: Analyst: CN Parameters) Resultsualifier D.F. Units Analyzed: Container: Total Organic Carbon <1.0 1 mg/L 07/24/2014 11:00 PM Container-01 of 02 nualifers: E=Value above quantitation range.Value estimated. B=Found in Blank ' D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte/matrix!method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC ' J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 111112114 Page 18 of 26 1 ' LKBO10 S101 }f f,n r+�� LABORATORY RESULTS ' - � nalXf cal Results for the samples and analytes requested 575 Broad=oliow Road, Melville.NY 11747 TEL(631)694-3040 FAX:(631)420-8436 The lab is not directly responsible for the integrity of the sample before receipt at NYSDOH ID#10476 wwwoacelabs.com the lab and is responsible only for the certified tests requested. Lockwood Kessler&Bartlett One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1407015-010 Type: Groundwater , Attn To : John Gerlach Client Sample ID: MW-6S Collected :6/30/2014 1:00:00 PM Origin: Received :711/2014 10:40:00 AM Collected By LKB99 Analytical Method: SM2320B: Anal : JOLR Parameterfsl Results uaiifirD_F. Units Analyzed: Container: Alkalinity,Total(As CaCO3) 48.5 1 mg/L 07/0812014 1:47 PM container-01 of 02 Analytical Method: E300.0: Analyst: bka Parameterfsl Results Oualifier F. Analyzed: Container: Bromide <0.50 1 mg/L 07/11/2014 1:07 AM Container-01 of 02 ' Chloride 6.47 1 mg/L 07/11/20141:07 AM Container-01 of 02 Sulfate 10.5 1 mg/L 07/11/2014 1:07 AM Container-01 of 02 Analytical Method: SM5210B: Prep Method: SM5210B Prep Date:71212 01 4 7:32:55 AM Analyst: VaS ' Parameterfsl Results Qualifier D.F.. Units Analyzed: Container: Biochemical Oxygen Demand <2 1 mg/L 07/02/2014 10:30 AM Container-01 of 02 AnaMical Method: E410.4: Analyst: VaS ' P9l2mete1(s1 Results Qualifier D.F.. Units Analyzed7 Container: Chemical Oxygen Demand 28.0 1 mg/L 07114/2014 9:54 AM Container-01 of 01 Analytical Method: SM212OB:IOC Analyst: EM Parameter(sl Results ualifierD_F. Units Analyzed: Container. ' Color 40.0 1 units 07/02/2014 5:11 AM Container-01 of 02 Color pH 6.00 + 1 units 07/02/2014 5:11 AM Container-01 of 02 Analytical Method: M3500-CrD: Parameterfsl Results Qualifier D. Units Ana Analyst: EM ' _lyz_e1c: Container. Chromium,Hexavalent <0.02 1 mg/L 07/02/2014 5:56 AM Container-01 of 02 Analytical Method: SM234OC: Analyst: JA , Parameterfsl Results Qualifier D. Units Analyzed: Container: Hardness(As CaCO3) 76 D 4 mg/L 07/10/2014 12:55 PM Container-01 of o1 Analytical Method: E350.1: Analyst: bka Parameterfsl Results Q alifier D_F. Units Analyzed: Container. ' Nitrogen,Ammonia(As N) <0.10 1 mg/L 07/07/2014 12:14 PM Container-01 of 01 Analytical Method: E353.2: Analyst: TF Parameterfsl Results Qualifier D.F.. Units Ana ed: Container ' Nitrite as N <0.10 1 mg/L 07/02/2014 7:49 AM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank 64v- D.F.=Dilution Factor D=Results for Dilution , H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte/matrix/method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 8/11/2014 Page 19 of 26 ' LKB010 S102 , Anal I+Caf LABORATORY RESULTS Results for the samples and analytes requested 575 Broad Hollow Roed, Melville,NY 11747 TEL:(631)694-3040 FAX:(631)420-8436 The lab Is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested- r NYSDOH 0010478 wwwoacelatrs.com Lockwood Kessler S Bartlett One Aerial Way Sample Information: ' Syosset NY 11791 Lab No. : 1407015-010 Type: Groundwater Client Sample ID: MW-6S Attn To John Gerlach Collected :6/30/2014 1:00:00 PM Origin: ' Received :7/1/2014 10:40:00 AM Collected By LKB99 Analytical Method: E353.2: Analyst: TF Parameterfs) Results Qualifier D. Units Analyzed Container Nitrate as N 0.89 1 mg/L 07/02/2014 8:50 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date:7111731 AM Analyst: EM Paremeter(s1 Results ualifierD_F. Units Analyzed: Container: ' Phenolics,Total Recoverable <5.0 1 pg/L 07/14/2014 12:11 PM Container-01 of 01 Analytical Method: SM2540C:IOC Anal s' SH2 Parameter(s) Results Qualifier D.F. Units Analyzed: Container: ' Total Dissolved Solids 124 1 ri 07/02/2014 11:08 AM Container-01 of 02 Analytical Method: E351.2: Preo Method: 351.2 Prep Date:7/10/2014 5:30:00 AM Analyst: TF Parameterfs) Results Cualifier D.F. Units Analyzed: Container: Nitrogen,Kjeldahl,Total 0.98 1 mg/L 07/10/2014 11:48 AM Container-01 of 01 ' Analytical Method: SW9060: Analyst: CN Parameterfs) Results Qualifier D.F. Units Analyzed: Container: Total Organic Carbon 8.3 1 ni 07/24/2014 11:00 PM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank ' D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte/matrix/method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC ' J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported. 8/11/2014 Page 20 11 ' LKB010 S103 rLABORATORY RESULTS , Analytical Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 TEL(631)694-3040 FAX:(631)420-8436 The lab is not directly responsible for the integrity,of he sample before receipt at the lab and is responsible only for the certified tests requested. NYSDOH 10#1G478 www.oacelabs.com Lockwood Kessler&Bartlett One Aerial Way Sample Information: Lab No. : 1407015-011 Type: Groundwater ' Syosset,NY 11791 Client Sample ID: MW-7S Attn To : John Gerlach Collected :6/30/2014 10:40:00 AM Origin: Received :711/2014 10:40:00 AM , Collected By LKB99 Analytical Method: SM2320B: Analyst: JDLR Parameters) Results Qualifier D. Units Analyzed: Container: Alkalinity,Total(As CaCO3) 170 D 2 mg/L 07108/2014 2:09 PM Container-01 of 02 ' Analytical Method: E300.0: Analyst: bka Parameter(sl Results Qualifier D.F. Units Analyzed: Container: Bromide <0.50 1 mg/L 07111/2014 1:20 AM Container-01 of 02 ' Chloride 16.1 1 mg/L 07111/2014 1:20 AM Container-01 of 02 Sulfate 37.5 1 mg/L 07111/2014 1:20 AM Container-01 of 02 Analytical Method: SM52105: Prep Method: SM5210B Prep Date:7122014 7:32:55 AM Analyst: VaS , Parameter(sl Results Qualifier D.F. Units Analyzed: Container. Biochemical Oxygen Demand <2 1 mg/L 07/02/2014 10:35 AM Container-01 of 02 Analytical Method: E410.4: Analyst: Va$ , Parameter(sl Results Oualifier D_F. Units Analyzed: Container Chemical Oxygen Demand 17.8 1 mg/L 07114/2014 9:56 AM Container-01 of 01 Analytical Method: SM212OB:IOC Analyst: EM Parameter(sl Results Qualifier D. Units Analyzed: Container ' Color <5.00 1 units 07102/2014 5:12 AM Container-01 of 02 Color pH 7.00 + 1 units 07/02/2014 5:12 AM Container-01 of 02 Analytical Mathod: M3500-Cr D: Analyst: EM ' Parameters) Results ualifier D_F. Units Analyzed: Container: Chromium,Hexavalent <0.02 1 mg/L 07102/2014 5:57 AM Container-01 of 02 Analytical Method: SM234OC: Analyst: JA ' Parameters) Results ualifier D_F. Units Analyzed: Container. Hardness(As CaCO3) 190 D 10 mg/L 07110/20141:00 PM Container-01 of 01 Analytical Method: E350.1: Analyst: bka , Parameter(sl Results Qualifier D_F. Units Analyzed: Container: Nitrogen.Ammonia(As N) <0.10 1 mg/L 07/072014 12:17 PM Container-01 of 01 Analytical Method: E353.2: Anel : TF Parameter(sl Results Qualifier D. Units Analyzed: Container: ' Nitrite as N <0.10 1 mg/L 07/02/2014 7:50 AM Container-01 of 02 - - ------ i Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution ' H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte/matrix/method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC ' J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 9/11/2014 Page 21 of 26 ' LKBO10 S104 ' 1 ac�//��{� �/ti"a f LABORATORY RESULTS ` '"`��J '� Results for the samples and analytes requested 575 Broad Hollow Road, Melville.NY 11747 TEL.(631)6943040 FAX:(631)420-8436 The:ab is not directly responsible for the integrity of the sample before receipt at NYSDOH ID#10476 wwwpacelabe.com the lab and is responsibe only for the certified tests requested. Lockwood Kessler&Bartlett One Aerial Way Sample Information: Lab No. : 1407015-011 Type: Groundwater Syosset,NY 11791 Client Sample ID: MW-7S Attn To John Gerlach Collected :6/30/201410:40:00 AM Origin: ' Received :71112014 10:40:00 AM Collected By LKB99 Analytical Method: E353,2: Analyst: TF Parameter(§/ Results Qualifier D.F. Units Analyzed: ontainer ' Nitrate as N 9.14 D 20 mg/L 07/02/2014 8:51 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date:7/10!2014 7:30:00 AM Analyst: EM Parameter(§) Results Oualifter Q.F.. Units Ana ed: Container. ' Phenolics,Total Recoverable <5.0 1 pg/L 07114/2014 12:12 PM Container-01 o(01 Analytical Method: SM2540C:IOC Anal : SH2 Parameter(s1 ResuRs Qualifier Q.F.. Units Analyzed: Container. ' Total Dissolved Solids 383 1 mg/L 07/0212014 11:09 AM Container-01 of 02 Analytical Method: E351.2: Prep Method: 351.2 Prep Date:7/10/2014 5:30:00 AM Analyst: TF Parameter(§) Results Qualifier DD=F. Units Analyzed: Container: Nitrogen,Kjeldahl,Total 0.48 1 mg/L 07/10/2014 11:49 AM Container-01 of 01 ' Analytical Method: SW9060: Analyst: CN Parameter(§/ Results Qualifier D.F. Units Analyzed: Container. Total Organic Carbon 5.9 1 mg/L 07/24/2014 11:00 PM Container-01 of 02 1 ' Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank ' D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte/matrix!method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC ' J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported 8/11/2014 Page 22 of 26 ' LKB010 S105 I , LABORATORY RESULTS 575 Broatl Hollow Road Melville,NY 11747 ���` a"J '��� Results for the samples and analytes requested ' ' TEL:(831)694-3040 FAX:(631)420.8435 The lab is not esy responsible for the integrity of the Semple before receipt at the lab and is responsible only for:he certified tests requested. NYSDOH 0ff10478 wwwoacelabs.com Lockwood Kessler&Bartlett One Aerial Way Sample Information: Lab No. : 1407015-012 Type: Groundwater Syosset,NY 11791 Client Sample ID: MW-8S Attn To : John Gerlach Collected :6/3012014 12:00:00 PM Origin: Received :7/1/2014 10:40:00 AM ' Collected By LKB99 Analytical Method: SM2320B: Analyst: JDLR Parameters) Results Qualifier D.F.. Units Anal Container: Alkalinity,Total(As CaCO3) 302 D 10 mg/L 07/08/2014 2:18 PM Container-01 of 06 ' Analytical Method: E300.0: Analyst: bka Parameters) Results Qualifier D.F. Units Analyzed: Container: Bromide <0.50 1 mg/L 07/11/2014 1:34 AM Container-01 of D6 ' Chloride 41.7 D 5 mg/L 07/11/2014 2:42 AM Container-01 of D6 Sulfate 42.4 D 5 mg/L 07/11/2014 2:42 AM Container-01 of D6 Analytical Method: SM5210B: Prep Method: SM5210B Prep Date:7/2/2014 7:32:55 AM AnaW: VaS IfArameteris Results Qualifier D.F. Units Analyzed: Container: Biochemical Oxygen Demand <4 1 mg/L 07/02/2014 10:40 AM Container-01 of 06 Analytical Method: E410.4: Analyst7 VaS Parameterfs) Results Qualifier D_F. Units Analyzed: Container Chemical Oxygen Demand 38.8 1 mg/L 07/14/2014 9:58 AM Container-01 of 03 Analytical Method: SM212OB:IOC Analyst: EM Parameteris) Results Qualifier D.F.. Units Analyzed: Container: Color 500 D 25 units 07102/2014 5:13 AM Container-01 of D6 Color pH 7.5 D + 25 units 07102/20145:13 AM Container-01 of Analvtical Method: M3500-Cr D: Analyst EM Parameters) Resufts Qualifier D_F. Units Analyzed: Container: Chromium,Hexavalent <0.10 D 5 mg/L 07/02/2014 6:04 AM Container-01 of 06 Analytical Method: SM234OC: Analyst: JA , Parameter(sl Results Qualifier D.F. Units Analyzed: Container: Hardness(As CaCO3) 220 D 10 mg/L 07/1012014 1:05 PM Container-01 of 03 Analytical Method: E350.1: na bka ' Parameter(sl Results Qualifier D.F.. Units Anal Container: Nitrogen,Ammonia(As N) 25.0 D 10 mg/L 07/07/2014 12:18 PM Container-01 of 03 Analytical Method: E363.2: Analyst: TF Parameter(sl Results Qualifier D.F.. Units Analyzed: Container ' Nitrite as N <0.10 1 mg/L 07/0212014 8:00 AM Container-01 of 06 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution , H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte/matrix/method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC ' J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 8/11/2014 Page 23 of 26 ' LKB010 S106 ' ' LABORATORY RESULTS f ., 6Ana1 dcaf Results for the samples and analytes requested 575 Broad Hollow Road, McWille,NY 11 747 TEL:(631)6943040 FAX:(631)420-8436 The lab is not directly responsible toa integrity of the sample before receipt at the lab and is respcnsible only for:hehe Cenifietl tests requested. NYS00HI0010476 wwwpacelabs.com Lockwood Kessler&Bartlett One Aerial Way Sample Information: ' Syosset,NY 11791 Lab No. : 1407015-012 Type: Groundwater Client Sample ID: MW-8S Attn To John Gerlach Collected :6/30/2014 12:00:00 PM Origin: ' Received :7111201410:40:00 AM Collected By LK699 Analytical Method: E353.2: Analyst: TF Parameter(sl Results Qualifier D.F. Units Analyzed: Container: ' Nitrate as N <0.10 1 mg/L 07/02/2014 8:52 AM Container-01 of 03 Analytical Me:hod: E420.1: Prep Method: E420.1 Prep Date:7/10/2014 7:30:00 AM Analyst: EM ParametegM Results ualifierD_F. Units Analyzed: Container: Phenolics,Total Recoverable <5.0 1 pg/L 07/14/2014 12:13 PM Container-01 of 03 Analytical Method: SM264OC:IOC Anal : SH2 Parameter(s1 Results Qualifier D.F.. Units Analyzed7Container: ' Total Dissolved Solids 414 1 mg/L 07/02/2014 11:09 AM Container-01 of 06 Analytical Method: E351.2: Prep Method: 351.2 Prep Date:7/10/2014 5:30:00 AM Analyst: TF Parameter(sl Results ualifier D_F. Units AnalyzedI7 Container. Nitrogen,Kjeldahl,Total 25.8 D 10 mg/L 07/10/201411:50 AM Container-01 of 03 ' Analytical Method: SW9060: Analyst: CN Parameters) Results QualifierD_F. Units Analyzed: Container: Total Organic Carbon 12.7 D 10 mg/L 07/2412014 11:00 PM Container-01 of 06 1 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank G?� ------ ' D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte!matrix!method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 8/11/2014 Page 24 of 26 ' LKB010 S107 f LABORATORY RESULTS ' r aCEAna1y ca Results for the samples and analytes requested / 575 Broad Hollow Road, McMlie,NY 11747 p q TEL:(631)fi94-3040 FAX (631)420-8435 fhe:ab is not directly responsibe for the integrity of ttie sample before receipt at ' the lab and is responsible only for the certified tests requested. NYSDOH ID410478 wwwoacelabs.com Lockwood Kessler&Bartlett One Aerial Way Sample Information: Syosset NY 11791 Lab No. : 1407015-013 Type: Field Blank ' Client Sample ID: Field Blank Attn To John Gerlach Collected :7/1/201410:00:00 AM Origin: Received :7/1/2014 10:40:00 AM ' Collected By LKB99 Analytical Method: SM2320B: Analyst: JDLR Parameters) Results Qualifier D.F.. Units Ana ed: Container: Alkalinity,Total(As CaCO3) <1.00 1 mg/L 07/0812014 2:41 PM Container-01 of 02 ' Analytical Method: E300.0: Analyst: bite Parameters) Results Qualifier D.F.. Units Analyzed: Container7 Bromide <0.50 1 mg/L 07/11/2014 3:22 AM Container-01 of 02 ' Chloride <2.00 1 mg/L 07111/2014 3:22 AM Container-01 of 02 Sulfate <5.00 1 mg/L 07111/2014 3:22 AM Container-01 of 02 Analytical Method: SM5210B: Prep Method: SM52108 Prep Date:7/212014 7:32:55 AM Analyst: VaS ' Parameters) Results Qualifier D.F. Units Analyzed: Container: Biochemical Oxygen Demand <2 1 mg/L 07/02/2014 10:50 AM Container-01 of 02 Analytical Method: E410.4: Analyst: VaS ' Parameters) Results ualifier D_F. Units Analyzed: Container: Chemical Oxygen Demand <10.0 1 mg/L 07/14/2014 10:04 AM Container-01 of 01 Analytical Method: SM212OB:IOC Analyst: EM Parameters) Results Qualifier D. Units Analyzed: Container: , Color <5.00 1 units 07/02/2014 5:15 AM Container-01 of 02 Color pH 5.00 + 1 units 07/02/2014 5:15 AM Container-01 of 02 Analytical Method: M3500-Cr D: Analyst: EM , Parameters) Results QualifierD_F. Units Analyzed: Container: Chromium,Hexavalent <0.02 1 mg/L 07/02/2014 6:01 AM Container-01 of 02 Analytical Method: SM2340C: Analyst: JA , Parameters) Results ualifier PF. Units Analyzed: Container. Hardness(As CaCO3) <5 1 mg/L 07/10/2014 1:20 PM Container-01 of 01 Analytical Method: E350.1: Analyst: bka Parameters) Results ualifierD_F. Units Analyzed: Container. ' Nitrogen,Ammonia(As N) <0.10 1 mg/L 07/07/2014 12:22 PM Container-01 of 01 Analytical Method: E353.2: Analyst: TF Parameters) Results Qualifier D_F. Units al e : ontai e , Nitrite as N <0.10 1 mg/L 07/02/2014 7:55 AM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution , H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte!matrix/method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC ' J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 8/11/2014 Page 25 of 26 ' LKB010 S108 ' lac' t',} LABORATORY RESULTS _ r M `all "ica Results for the samples and analytes requested 575 Broad Hollow Road, Melville.NY 11747 ' The lab is not d,rectly responsible for the integrity of the sample before receipt at TEL:(631)694-3Ca0 FAX:(631)a20•Ba36 � the lab and is responsible only for the certified tests requested. NYSDOH 0tf10478 mwwpacslabs.com Lockwood Kessler&Bartlett One Aerial Way Sample Information: ' Lab No. : 1407015-013 Type: Field Blank Syosset,NY 11791 Client Sample ID: Field Blank Attn To John Gerlach Collected :7/1/2014 10:00:00 AM Origin: ' Received :7/1/2014 10:40:00 AM Collected By LKB99 Analytical Method: E353.2: Ana st• TF Parameters) Results Qualifier D.F. Units Analyzed- Container: ' Nitrate as N <0.10 1 mg/L 07/02/2014 8:56 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date: 7/10/2014 7:30:00 AM Analyst: EM Parameter(§) Results Qualifier D.F. Units Analyzed: Container: ' Phenolics,Total Recoverable <5.0 1 pg/L 07/14/2014 12:16 PM Container-01 of 01 Analytical Method* SM2540C IOC Analyst: SH2 Parameter(§) Results Oualifier Q. Units Analyzed: ontaine: ' Total Dissolved Solids <10 1 mg/L 07/07/2014 10:11 AM Container-01 of 02 Analytical Method: E361.2: Prep Method: 351.2 Prev Date:7/10/2014 5:30:00 AM Analyst: TF Parameter(§) Resultsualifier D.F. Units Analyzed: Container: Nitrogen,Kjeldahl,Total <0.10 1 mg/L 07/10/2014 11:54 AM Container-01 of 01 ' Analytical Method: SW9060: Analyst: CN Parameter(s) Results Qualifier D.F. Units Analyzed: Container: Total Organic Carbon <1.0 1 mg/L 07/24/2014 11:00 PM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank ' D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=NYSDOH ELAP does not offer certification for this analyte/matrix/method c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC ' J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 8/11/2014 Page 26 of 26 ' LKBO10 S109 ace Long Island , i 575 Broad follow Road 63 1.694.3044 t Melville, NY 11747 lax 631.420,8436 5. SURROGATE SPIKE ANALYSIS RESULTS 5.1 VOLATILES , 1 LKB010 S110 ' 2A ' WATER VOLATILE SYSTEM MONITORING COMPOUND RECOVERY Lab Name: PACE ANALYTICAL, Contract: ' Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 ..._. ------- - ------ EPA SMC1 SMC2 SMC3 OTHER TOT SAMPLE NO. DCA# TOL# BFB # OUT 01VBLK070214 85 96 108 0.. ' 02 LFB070214 --- 82 97 104 0 03 MW-1D 85 97 108 0 -- - -- _ 09 -1S 84 97 106 0 05 -3D 84 96 107 0 06 -3S 85 96 108 0 07 MW-4D 84 96 107 0 ' MW-4S 84 97 106 0 09 MW-5D 85 97 107 0 10 MW-5S 85 97 108 0 11' 13� 7D 85 97 107 0 96 107 0 12 65 89 i S 84 i 95 107 t --- p -- ---- --- 19MW-8S 85 96 108 0 ' 15 -8SMS 83 97 103 -- 0 -T,- 16MW-8SMS D 82 97 104 0 17 Field Blank 85 97 109 0 18 Trip Blank 85 96 107 0 193torage Blank 84 96 108 0 ' QC Limits SMC1 DCA = 1,2-Dichlorcethane-d4 (53-183) SMC2 TOL = Toluene-d8 (60-135) SMC3 BFB = 4-Bromofluorobenzene (63-140) ' # Column to be used to flag recovery values * Values outside of contract required QC limits ' page 1 of 1 FORM II VCA-1 OLM04.2 ' LKB010 S111 1 ace tong is/and , 575 Broad Hollow Road 1�^i 631.694.3040 ' Melville,NY 1,1747 631.420,8436 r r r 6. MATRIX SPIKE / MATRIX SPIKE DUPLICATE SUMMARY ' 6.1 VOLATILES 1 1 1 r 1 r r i 1 r r LK13010 S112 ' 3A WATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY ' Lab Name: PACE ANALYTICAL Contract: - Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 Matrix Spike - EPA Sample No. : MW-8S — - - - SPIKE SAMPLE MS - MS - QC. ADDED CONCENTRATION CONCENTRATION % LIMITS COMPOUND g/L) (Ng/L) (Ng/L) REC# REC. 11-Dichloroethene 50 0 50 101 45-146 - - - - - Benzene 50 0 47 94 t 73-119- Trichloroethene 50 0 49 98 69-117 Toluene 50 0 49 t 99 72-119 Chlorobenzene 50 _ 16 67 103 75-113 SPIKE MSD MSD ADDED CONCENTRATION % % QC LIMITS COMPOUND (Ng/L) I (Ng/L) REC# RPD# RPD REC. - 1 j-Dichloroethene 50 48 95 6 30 45-146 1 Benzene 50 4589 5 30 73-119 Trichloroethene 50 47 94 4 30 69-117 Toluene 50 46 -93 6 30 72-119 Chlorobenzene 50 64 96 7 30 75-113 # Column to be used to flag recovery and RPD values with an asterisk ' * Values outside of QC limits RPD: 0 out of 5 outside limits ' Spike Recovery: 0 out of 10 outside limits COMMENTS: FORM III VOA-1 oznro 4.2 iLKB010 S113 3A SYSTEM MONITORING SPIKE RECOVERY Lab Name: PACE_ANALYTICAL _ Contract: — Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKBO10 Sample ID LFE070214 Level: (low/med) LOW Column ID Rtx-624 Column Diam 18 Inst. ID HP5972-2 Init. Calib. Date(s) : 06/26/14 19:33 , Analysis Date: 07/02/14 12:15 06/26/14 23:28 SPIKESAMPLE SPIKE SPIKE ( QC- ADDED CONCENTRATION CONCENTRATION % LIMITS , COMPOUND (pg/L) (pg/L) (pg/L) REC# REC. Chloromethane 50 0 25 49 f 46-144 Vinyl chloride 50 0 41 82 43-143 romomethane 50 0 34 68 52-147 --- ------..- -----l Chloroethane 50 0 45 91 r 49-151 ,Acrylonitrile 50 0 40 80 59-148 Tnchlorofluoromethane 50 047 94 27-173 i 1 1-Dichloroethene 50 0 47 93 45-146 lodomethane 50 0 37 75 61-144 Vinyl acetate Carbon disulfide — 50 0� 40 -----I - 811-1-20-1-58 Acetone 50 0 47 94 23-188 I 50 0 42 83 48-132 Methylene chloride 50 0 45 90 61-142 trans-1,2-Dichloroethene 50 0 46 92 56-142 1,1-Dichloroethane 50 0 42 83 83-151 cis-1,2-Dichloroethene 50 0 46 92 72-121 2-Butanone 50 0 44 87 44-162 -_ -..-- - --- --- — _- Bromochloromethane 50 0 49 97 t 81-116 Chloroform 50 0 44 89 72-122 1,1,1-Trichloroethane 50 0 45 90 t 65-118 on 50 49 Bernbzeneetrachloride----- - 50 -- 0 _--_ 46 92 73-119 1 1,2-Dichloroethane 50 0 f 46 91 74-129 Trichloroethene 50 0 47 94 69-117 - -- -- + 1,2-Dichloropropane 50 0 46 922 75-117 Dibromomethane 50 0 49 99 75-125 Bromodichloromethane 50 0 48 97 I, 78-117 cis-1,3-Dichloropropene 50 0 49 98 78-116 4-Methyl-2-pentanone 50 0 41 81 69-132 Toluene 50 0 48 96 72-119 trans-1,3-Dichloropropene 50 0 49 97 1 79-116 # Column to be used to flag recovery and RPD values with an asterisk * Values outside of QC limits Spike Recovery: 0 out of 47 outside limits COMMENTS: FORM III SW8260 LKB010 S114 , i ' 3A SYSTEM MONITORING SPIKE RECOVERY ' Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No. : SDG No. : LKB010 iSample ID LFB070214 Level: (low/med) LOW Column ID Rtx-624 Column Diam .18 Inst. ID HP5972-2 Init. Calib. Date(s) : 06/26/14 19:33 Analysis Date: 07/02/14 12:15 06/26/14 23:28 1,1,2-Trichloroethane 50 0 49 98 80-117 Tetrachloroethene 50 0 57 113 60-128 2-Hexanone 50 0 46 93 83-115 Dibromochloromethane 50 0 55 111 70120 3 11 tCrans-b4-D ch oao-2-butene enzene 50 - 0 - - -50- - 106 875-1-13 i — 50 0 39 _ -- 77 71-121 Ethylbenzene 50 0 54 108 70-113 1,1,1,2-Tetrachloroethane 50 D 54- -- 109 74-113 rt -Xylene(total) 150 0 160 103 71 109 Styrene 50 0 53 -- t 72-118, liromoform 50 - 0 57 113 65-122 11,2 Tetrachloroethane 50 0 48 96 74---121'-1 1,2,3-Tnchloropropane 50 0 50 99 71-123 - -- 4-Dichlorobenzene 50 0 52 104 71-113 53 1,2-Dichlorobenzene 50 0 107 t 74-113 1 2-Dibromo-3-chloropropane 50 0 48 95 74-119 1 i 1 i # Column to be used to flag recovery and RPD values with an asterisk * Values outside of QC limits Spike Recovery: 0 out of 47 outside limits ' COMMENTS: ' FORM III SW826C LKB010 S115 i 2ane Long Island ' 575 Broad Hollow road let 631.694 3040 , Melville,NY 11747 6,, 1531.420.8436 7. DUPLICATE SUMMARY RESULTS 7.1 METALS 7.2 WET CHEMISTRY LKB010 S116 i U.S. EPA - CLF 6 EPA SAMPLE NO DUPLICATES MW-8S ' Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. SAS No. : SDG No. : LKBO10 Matrix (soil/water) : WATER Level (low/med) : LOW % Solids for Sample: 0.0 % Solids for Duplicate: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L Control - -- - --- -- Analyte Limit Samp�e (S) C Duplicate (D) C RPD Q M Aluminum 200.0000 26.3000 B 23.--0001 B 13.0 P Antimony_ 1.6189 U 1. 6189' U P Arsenic 1.4989 U - 1.4989 U t- P Barium 200.0000}_ 240.5000 242.`_000 0.7' P Beryllium_ fi - - - - -- 0.0912 UI 0.0912 U ! IP , ' Boron 100.0000 217.7000 218. 6000 _ _ _ - - _-. _ 0.4, ! P ', !Cadmium 0.1447 U 0.1447' U P Calcium 57030.0000 _ _ 57840.0000 l.4 P Chromium 0.4638 U 0. 4638 U P Cobalt _ 50.0000 3.9000 B 3.8000 B 2.6 P --- --- Copper _ 2.5.0000 11.1000 Bl _ _ 11.2000 B 0. 9 i P Cyanide 10.0000 U ! 10.0000U I I CA ' Iron _ 38190.0000 - 38600.0000 1.1 P Lead 16.6800 18 .3000 9.3 P Ma nesi.um_1500_0_00001 20220.0000 __ 20500.0000, 1.4 P Macanese _ 882.3000 _ 882.5000 0.0 P Mercury _ C.1000 U 0.1000 U CV Nickel 1 0.2851 U _ _ 0.2851 U P Potassium _ 44770.00001 0.0 P Selenium 5.0000 1.4464 4_______ 44780.0000 1.7420 B 200.0 P - ' Silver 3.6694 U 3. 6694 U 0.0 P Sodium 25890.0000 29280.0000 12.31 P Thallium T 3.5091 U 3.5091 U P Vanadium 50.0000 1.3000 B 1.3000 B 0.0__ P Zinc 20.0000 12.4000 B 6. 9000 B _ 57.0 P FORM VI - IN ILM04. 1 t ' LKB010 S117 PACE ANALYTICAL Date: 01-Aug-14 QC SUMMARY REPORT SDG: LKB010 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: _ Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB-070814 MB-070814 Alkalinity,Total(As CaCO3) <1.00 j MG/L I LCS-070814 — LCS-070814 Alkalinity,Total(As CaCO3) 24.1 - MG/L 25 <1.00 96 80 120 1407015-012EMS ;MW-8SMS Alkalinity,Total(As CaCO3) 542 MGIL 250 302 96 75 125 1407015-012EDUP !MW-8SDUP Alkalinity,Total(As CaCO3) 291 MG/L 302 3.7 20 MB-45263 MB-45263 Biochemical Oxygen Demand <2.00 MG/L LCS-45263 LCS-45263 Biochemical Oxygen Demand 219 MG/L 198 <2.00 111 85 11161 1407015-012EDUP MW-8SDUP Biochemical Oxygen Demand <4.00 MG/L <4 20 MB-071014 MB-071014 Bromide <0.500 MG/L LCS-071014 LCS-071014 Bromide 2.56 MG/L 2.5 <0.500 102 90 110 1407015-012EMS MW-8SMS Bromide 1.19 MGL 1 <0.500 99 80 120 1407015-012EDUP MW-8SDUP Bromide <0.500 MG/L <0.5 20 MB-071414 MB-071414 Chemical Oxygen Demand <10.0 MG/L LCS-071414 LCS-071414 Chemical Oxygen Demand 97.9 MG/L 100 <10.0 98 90 110 1407015-012BMS MW-8SMS Chemical Oxygen Demand 130 MG/L 100 38.8 91 90 110 1407015-012BDUP MW-8SDUP Chemical Oxygen Demand 40.0 MG/L 38.8 3.2 20 --- ��2.00 MG/L MB-071514 Chloride!LCS-071514 LCS-071514 Chloride MG/L 10 <2.00 105 90 11C --- - MB-071014 MB-071014 Chloride <2.00 MG/L LCS-071014 LCS-071014 Chloride 10.5 MG/L 10 <2.00 1 105 90 1101 1407015-012EMS MW-8SMS Chloride 98.9 MG/L 50 41.7 114 80 11201 1407015-012EDUP MW Chloride 42.1 MG/L 41.7 0.84 20 BO 18 QC SUMMARY REPORT SDG: LKBOIO Spike Sample Recovery RPDRef %RPD Sample_ID, Client SamWe ID: _ _ AItalyte Result Units Amount Result %REC Limits Value %RPD UCL MB-070214_ MB 070214 `Chromium,Hexavalent <0.020 MG/L LCS-070214 LCS-070214 Chromium,Hexavalent 0.212 i MG/L 0.2 <0.020C 106 80 120 1407015-012EMS - _ _-IMW-8SMS - � Chromium,Hexavalent-- - 0.985 j MGIL -1- <_0.100 99 175�125 --�— - - 1407015-012EDUP MW BSDUP Chromium,Hexavalent <0.100 MGlL <0-1 20 MB-070214 �MB-070214Color <5.00 Units 14I- 0 5 012EDUP BMW-SDUP Color 500 Units 40 <5.00 100 80 1z� 500 20 � MB-071014 MB-071014 Hardness(As CaCO3) <5.00 MG/L ILCS-071014 LCS 071014 Hardness(As CaCO3) 1000 MG/L 1000 <5.00 100 80 120 1407015-012DMS MW-8SMS Hardness(As CaCO3j 1210 GlL 1000 220 99 75 125 -9_5 1407015-012DDUP MW-BSDUP Hardness As CaCO3 220 200 MG/L 20 —21 -- - - j----__� - MB-070214 MB-070214 Nitrate as N <0.100 MGIL -1 ' I LCS-070214 LCS-070214 Nitrate as N 1.16 MG/L 1.13 j<0.1001, 103 90 110, W- D P ---— Nitrate as N -- i' <0.100 MGI� - - 110 1407015-012BMS 'MW-8SMS Nitrate as N 0.490 MGlL 0.5 �<-0.100� 98 90 1407015-012BDUP ;M 8S U L <0.1 20 MB 070214 MB-070214 INitrite as N <0.100 MGlL LCS-070214 LCS-070214 Nitrite as N 1.05 ML 1 <0.100 105 90 1101 0-5 <0.100 91 1407015-012EDUP MW-BSDUP Nitrite as N <0.100 MG/L - 90 110 1-0.1 20 M8-070314 MB-070314 Nitrogen,Ammonia(As N) <0.100 MG/L !LCS-070314 LCS-070314 Nitrogen,Ammonia(As N) 1.07 MG/L 1 <13.100 107 90 110 1407015-012BMS MW-8SMS Nitrogen,Ammonia(As N) 30.2 MG/L 5 25.0 104 90 110 1407015-012BDUP MW-BSDUP Nitrogen,Ammonia(As N) 25.0 MG/L 25.0 0.040 20 2 LKB010 S119 QC SUMMARY REPORT SDG: LKBO 10 Spike Sample Recovery RPDRef °/RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB-45371 MB-45371 Nitrogen,Kjeldahl,Total <0.100 MG/L LCS-45371 LCS-45371 Nitrogen,Kjeldahl,Total 4,14 MG/L 4 1<0.100� 1-04 go --1-101 1407015-012BMS MW-8SMS Nitrogen,Kjeldahl,Total 33.2 MG/L 8 25.8 1 93 1 75 112 !1407015-012BDUP MW-8SDUP Nitrogen,Kjeldahl,Total 27.7 MG/L 25.8 7.1 20 MB-45373 MB-45373 Phenolics,Total Recoverable <5.00 UG/L LCS-45373 LCS-45373 Phenolics,Total Recoverable 26.5 UG/L 30 <5.00 88 80 120 1407015-012BMS Mw-8SMS Phenolics,Total Recoverable 15.5 UG/L 20 <5.00 78 75 125 1407015-012BDUP MW-8SDUP Phenolics,Total Recoverable <5.00 UG/L <5 20 MB-071014 MB-071014 Sulfate <5.00 MGIL LCS-071014 LCS-071014 Sulfate 9.78 MG/L 10 <5.00 98 90 110 1407015-012EMS MW-8SMS Sulfate 97.5 MG/L 50 42.4 110 80 120--. 1407015-012EDUP MW-8SDUP -------Sulfate- 42.8 MGIL- 42.4 11.1 20 MB-070214 AMB-070214 Total Dissolved Solids <10.0 MG/L LCS-070214 ILCS-070214 Total Dissolved Solids 296 MG/L 300 <10.0 99J80 120 1407015-012EMS MW-8SMS Total Dissolved Solids 732 MG/L 300 414 106 75 125 14070 Total Dissolved Solids j 409 MG/L 414 1.2 20 jMB-070714 -------IMB-070714 Total Dissolved Solids 10.0 MG/L ILCS-070714 ILCS-070714 --iTotal Dissolved Solids 273 MGIL 300 <10.0 91 MB-072414 MB-072414 Total Organic Carbon <1.00 MG/L LCS-072414 LCS-072414 Total Organic Carbon 21.2 MG/L 25 <1.00 85 80 1120 1407015-012CMS Mw-8SMS Total Organic Carbon 105 MG/L 100 12.7 92 75 125 1407015-012CDUP MW-8SDUP Total Organic Carbon 12.8 MG/L 12.7 0.70 20 III MB-071114 IMB-071114 Total Organic Carbon <1.00 F_�-- - [25 F120[7�j S-�71114 ILCS-071114 Total Organic Carbon 27.8 MG/L < 3 IIMBOIW20 M ' aceCong Island i ' 575 Broad Hollow Road :-;1 631.694,3040 MelvOle NY 11747 631.420,8436 8. SPIKE SAMPLE RESULTS ' 8.1 METALS 8.2 WET CHEMISTRY 1 LKBO10 S121 U.S. EPA - CLP 5A EPA SAMPLE NO ' SPIKE SAMPLE RECOVERY - MR'-8SS Lab Name: PACE ANALYTICAL Contract: L Lab Code: 10478 Case No. SAS No. : SDG No. : LKS010 Matrix (soil/water) : WATER Level (low/med) : LOW % Solids for Sample: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L f Control Lim_t Spiked Sample Sample Spike Analyte %R Result (SSR) C � Result (SR) C Added (SA) %R Q M - - --- Aluminum 75-125 2252.0000 26.3000 B 2000. 00 111.3 iP Antimon 75-125 557.8000 1.6189 U1 500. 00 111. 6 P Arsenic 75-125 46.2700 1.4989 U 40. 00 115.7 P Barium 75-125 _ 2444.0000 240.5000 2000.00 110.2 P Beryllium 75-125 53.6000 0.0912 Uj 50. 00 107.2 P Boron 75-125 1320.0000 217.7000 1000. 00 110.2 P Cadmium 75-125 55.6000 0.1447 U 50.00 111.2 P Chromium 75-125 215.1000 0.4638 U 200.00 107. 6 P Cobalt 75-125 559.4000 3. 9000 B 500.00 111.1 P ' 'Copper 75-125 286. 1000 11.1000 B 250.00 110.0 P Cyanide 75-125 90.5595 10.0000 U 100.00 90. 6 CA Iron _ 38990.0000 _ 38190.0000 1000.00 80.0 P ' Lead 75-125 36.7700 16.6800 20.00 100.5 P Manganese 75-125 1434 .0000 882.3000 500.00 110.3 P Mercur 75-125 0. 9706 0.1000 U 1.00 97. 1 CV Nickel 75-125 552.4000 0.2851 U 500.00 110.5 P ' Selenium 75-125 12.0400 1_4464 U 10. 00 120.4 P Silver 75-125 26.3600 B _3.6694 U 50.00 52.7 N P Thallium 75-125 56.1500 3.5091 U 50. 00 112.3 P Vanadium 75-125 534.7000 1 .3000 B 500.00 106.7 P , Zinc 75-125 546. 6000 12.4000 B 500.00 106.8 P Comments: FORM V (Part 1) - IN ILM04 .1 LKB010 S122 U.S. EPA - CLP ' 5B EPA SAMPLE NO POST DIGEST SPIKE SAMPLE RECOVERY MW-8SA Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. SAS No. : SDG No. : LKBO10 Matrix (Soi_/water) : WATER Level (low/med) : LOW ' Concentration Units: ug/L Control Limit Spiked Sample Sample Spike Analyte %R Result (SSR) C Result (SR) C Added (SA) j $R Q M Silver 334.30 3.70 �U 1 300.0 111. 4 P � r Comments: FORM V (Part 2) - IN ILM04.1 ' LKBO10 S123 PACE ANALYTICAL Date: 01-Aug-14 QC SUMMARY REPORT SDG: LKB010 Spike Sample Recovery RPDRef °/RPD Sam le ID• Client Sample 1D: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB-070814 MB-070814 Alkalinity,Total(As CaCO3) <1.00 MGIL <1.00 96 8 LCS-070814 LCS-070814 Alkalinity,Total(As CaCO3) 24.1 MG/L 25 0 120 - - 0 - - 1407015-012EMS MW-8SMS Alkalinity,Total(As CaCO3) 542 MGIL 250 302 96 75 11125 1407015-012EDUP MW-8SDUP Alkalinity,Total(As CaCO3) 291 MGIL 302 3.7 20 -- - - - M645263 MB-45263 Biochemical Oxygen Demand <2.00 , MGIL LCS-45263 — ILCS-45263 Biochemical Oxygen Demand 219 MGIL 198 <2.00 111 85 116 ---— --- -- ------ -- 1407015-012EDUP !MW-8SDUP Biochemical Oxygen Demand <4.00 MGIL <4 20 MB-071014 MB-071014 Bromide <0.500 MGIL LCS-071014 LCS-071014 Bromide 2.56 MGIL 2.5 <0.500 102 90 110 1407015-012EMS MW-8SMS Bromide 1.19 1 MGIL 1 <0.500 99 80 120 1407015 012EDUP MW 8SDUP Bromide <0.500 MGIL -<0.5 20 MB-071414 MB-071414 Chemical Oxygen Demand <10.0 MG/L LCS-071414 LCS-071414 Chemical Oxygen Demand 97.9 MG/L 100 <10.0 98 90 110 11407015-012BMS MW-8SMS Chemical Oxygen Demand 130 MGIL 100 1 38.8 91 90 110 i -- -- - -- 11407015-012BDUP MW-8SDUP Chemical Oxygen Demand 40.0 MGIL X38.8 3.2 20 MB-071514 MB-071514 Chloride <2.00 MGIL i LCS-071514 LCS-071514 Chloride 10.5 MG/L 10 <2.00 105 i 90 110 MB-071014 MB-071014 Chloride <2.00 MG/L LCS-071014 LCS-071014 Chloride 10.5 MG/L 10 <2.00 105 90 110 1407015-012EMS MW-8SMS Chloride 98.9 MG/L 50 41.7 1 114 80 120 1407015-012EDUP MW-8SDUP Chloride 42—.1 MG/L 41.7 0.84 ' 20 r M"BO'jW24 QC SUMMARY REPORT SDI : LKBO10 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB-070214 MB-070214 ;Chromium,Hexavalent <0.020 MGIL ' 1407015-012EMS MW-8SMS Chromium,Hexavalent _ 0.985 MG/L 1 <0.100 99 75 LCS-070214 -_ LCS-070214 {Chromium,Hexavalent 0.2 12 MGIL 0.2 0.020106 80 120 1 I 125 1407015-012EDUP MW-8SDUP Chromium Hexavalent <0.100 . MGIL <0.1 20 --- __-- I -- —40 FMB-070214 MB-070214 Color <5.00 Units � LCS-070214 LCS-070214 Color 40.0 Units <5.00 100 80 120 -- - 1407015-012EDUP MW-8SDUP _Color 500 Units 500 20 MB-071014 Hardness(As CaCO3) < 0 IVIGIL LCS-071014 LCS-071014 Hardness(As CaCO3) 1000MG/L 1000�<5.00 r 100 80 120 1407015-012DMS MW-8SMS Hardness(As CaCO3) 1210 MG/L 1000 220 75 125 1407015-012DDUP MW-8SDUP Hardness(As CaCO3) 200 MG/L - 220 9.5 2� ----- -- —{ ----- --I MB-070214 iM6-070214 Nitrate as N <0.100 MGIL LCS-070214 :LCS-070214 Nitrate as N 1.16 MGIL 1.13 <0.1001 103 90 1101 0 IVIGIL 1407015-012BDUP MW 8SDUP Nitrate as N O 01 00 IVIG/L <0.100 98 90 I,I 1101 <0.1 20 _ _ _ _ — - I S-070214 LCS-070214 i - Nitrite as N 1.05 MGIL -1 <0.100 105 90 1101 - MB-070214 MB-070214 Nitrite as N <0.100 MGIL 1407015-012EMS MW-8SMS Nitrite as N 0.455 WIG/L 0.5 <0.100 91 �90 110 ,1407015-012EDUP MW-8SDUP Nitrite as N <0.100 MG/L <0.1 20� SMB-070314 MB-070314 Nitrogen,Ammonia(As N) <0.100 MGIL rLCS-070314 LCS-070314 Nitrogen,Ammonia(As N) 1.07 MGIL 1 <0.100 107 90 110 14070 5 01 12BMS MW-8SMS INitrogen,Ammonia(As N) 30.2 MG/L 5 25.0 104 90 110 041 7015-012BDUP MW-8SDUP Nitrogen,Ammonia(As N) 25.0 1 MGIL 25.0 0.040 20 2 LKB010 S126 QC SUMMARY REPORT SDG: LKBO10 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB-45371 MB-45371 Nitrogen,Kjeldahl,Total <0.100 MG/L LCS-45371 LCS 45371 Nitrogen,Kjeldahl,Total 4.14 MG/L----4---<-0.-100-1D4 90 110 1407015-012BMS MW-8SMS jNitrogen,Kjeldahl,Total 33.2 MG/L. 8 25.8 93 75 125 07015-012BDUP MW-8SDUP INitrogen,Kjeldahl,Total 27.7 MG/L 25.8 7.1 20 MB45373 MB-45373 Phenolics,Total Recoverable <5.00 UGIL LCS-45373 LCS-45373 Phenolics,Total Recoverable 26.5 UGIL 30 <5.00 88 80 120 1407015-012BMS MW 8SMS Phenolics,Total Recoverable 15.5 UGIL 20 <5.00 78 75 125 -- - - - 1407015-012BDUP MW-8SDUP Phenolics,Total Recoverable <5.00 UGIL <5 20 MB-071014 MB-071014 Sulfate <5.00 MG/L LCS-071014 LCS-071014 Sulfate 9.78 MG/L 10 <5.00 98 90 4110 =4 1407015-012EMS MW-8SMS Sulfate 97.5 MG/L 50 42.4 110 80 120 1407015-012EDUP MW-8SDUP Sulfate 42.8 MG/L 42.4 j 1.1 20 - MB-070214 MB-070214 Total Dissolved Solids <10.0 MG/L F T LCS-070214 LCS-070214 Total Dissolved Solids 296 MG/L 300 < 10.0 99 80 1201 1407015-012EMS MW-8SMS Total Dissolved Solids 732 MG/L 300 414 106 75 125 - - - 1407015-012EDUP MW-8SDUP Total Dissolved Solids 409 MG/L ! 414 1.2 20 - -- -- - - -1_- MB-070714 TMB-070714 Total Dissolved SolidsLCS-070714 S-070714 Total Dissolved Solids 273 MGIL 300 <10.69�80 20 MB-072414 MB-072414 Total Organic Carbon <1.00 MG/L LCS-072414 LCS-072414 Total Organic Carbon 21.2 SMG/L 25 <1.00 85 80 120 140701 MS MW-8SMS Total Organic Carbon 105 MG/L 100 12.7 92 75 125 1407015-012CDUP MW-8SDUP Total Organic Carbon 12.8 MG/L 12.7 0.70 �2O MB-071114 MB-071114 Total Organic Carbon I <1.00 MG/L LCS-071114 LCS-071114 Total Organic Carbon 27.8 MGIL } 25 <1.00 111 80_1120 3 BO 2 ace Long Island i 575 Broad Hollow Read k-,! 531.694.3040 Melville,NY 11747 631.420.8436 1 9. BLANK SUMMARY DATA AND RESULTS ' 9.1 VOLATILES 9.2 METALS 9.3 WET CHEMISTRY r ' LKB010 S127 4A EPA SAMPLE NO. VOLATILE METHOD BLANK SUMMARY VBLK070214 ' Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No.: LKB SAS No. : SDG No. ; LKB010 , Lab File ID: G26231.D Lab Sample ID: VBLK070214 Date Analyzed: 07/02/14 Time Analyzed: 11:46 GC Column: Rtx-624 ID: .18 (mm) Heated Purge: (YIN) N Instrument ID: HP5972-2 , THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES, MS, AND MSA: EPA LAB LAB TIME SAMPLE NO. SAMPLE ID FILE ID ANALYZED , 01 LFB070214 LFB070214 nG26235.D 12:15 02 MW-1D 1407015-001G 12:44 03 Mw-1S 1407015-002G 13:13 04 MW-3D 1407015-003G 13:43 05 MW-3S 1407015-004G 14:12 06 MW-41) 1407015-005G G26237.D 14:41 , 07 MW4S 1407015-006G G26238.D 15:10 08 MW-5D 1407015-007G G26239.D 15:40 09 MW-5S 1407015-008G G26240.D 16:09 10 MW-6D 1407015-009G G26241.D 16:38 , 11 MW-6S 1407015-01 OG G26242.D 17:08 12 anw-7S 1407015-011G G26243,D 17:37 131 MW-8S 1407015-012G G26244.D 18:06 14 Mw sans 1407015-012GMS G26245.D 18:36 15 MW-8SMSD 1407015-012GMSD G26246.D 19:05 16 Field Blank 1407015-0136 G26247.D 19:34 17 Trip Blank 1407015-014A G26248.D 20:03 18 Storage Blank 1407015-015A G26249.D 20:32 ' COMMENTS: page 1 of 1 FORM IV VOA OLM04.2 , LKB010 S128 ' IA EPA SAMPLE NO. ' VOLATILE ORGANICS ANALYSIS DATA SHEET VELK070214 ' Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LP03 SAS No. : SDG No. : LKBO10 ' Matrix: (soil/water) WATER Lab Sample ID: VBLK070214 Sample wt/vol: 5 (g/mL) mL Lab File ID: G26231.D Level: (low/med) LOW T Date Received: ' % Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: _ --(pL) Soil Aliquot Volume (pL) CONCENTRATION UNITS: ' CAS NO. COMPOUND (pg/L or pg/Kg) pg/L Q - -- ---- EE 74-87-3-----Chloromethane 5 75-01-4 Vinyl chloride 5 ' 74-83-9 Bromomethane 5 U 75-00-3 Chloroethane 5 U 107-13-1 Acrylonitrile 5 U 75-69-4 Trichlorofluoromethane 5 U - -- - 75-35-4 1,1-Dichloroethene 5 U 74-88-4 Iodomethane 5 U 108-05-4 Vinyl acetate 5 U 67-64-1 Acetone 5 U - 75-15--0 Carbon disulfide 5 U 75-09-2 Methylene chloride 5 U 156-60-5 trans-1,2-Dichloroethene 5 U ' 75-34-3 1,1-Dichloroethane 5 U 156-59-2 cis-1,2-Dichloroethene 5 U 78-93-3 2-Butanone 5 I U 74-97-5 Bromochloromethane 5 U 67-66-3 Chloroform 5 U 71-55-6 1,1,1-Trichloroethane 5 U 56-23-5 Carbon tetrachloride 5 U 71-43-2 Benzene 5 U 107-06-2 1,2-Dichloroethane 5 U- 79-01-6 Trichloroethene 5 U 76-87-5 1,2-Dichloropropane 5 U �- 74-95-3 Dibromomethane 5 U 75-27-4 ! Bromodichloromethane 5 U 10061-01-5 cis-1,3-Dichloropropene 5 U 108-10-1 4-Methyl-2-pentanone 5 U ' 108-88-3 Toluene 5 _U 10061-02-6 trans-1,3-Dichloroprcpene 5 U 79-00-5 1,1,2-Trichloroethane 5 U 127-18-4 Tetrachloroethene _ 5 U ' 591-78-6 2-Hexanone 5 U 124-48-1 Dibromochloromethane - 5 U 106-93-4 1,2-Dibromoethane 5 _ 1 U ' FORM I VOA - 1 OLM04.2 ' LKB010 S129 1B EPA SAMPLE NO. VOLATILE ORGANICS ANALYSIS DATA SHEET ' VBLK070214 Lab Name: PACE ANALYTICAL Contract: ' Lab Code: 10478 Case No. : LKS SAS No. : SDG No. : LKS010 Matrix: (soil/water) WATER Lab Sample ID: VBLK070214 ' Sample wt/vol: 5 (g/mL) mL Lab File ID: G26231.D Level: (low/med) LOW Date Received: % Moisture: not dec. Date Analyzed: 07/02/14 ' GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 Soil Extract Volume: (pL) Soil Aliquot Volume (PL) CONCENTRATION UNITS: CAS NO. COMPOUND (pg/L or pg/Kg) µg/L Q 108-90-7 Chlorobenzene 5 U 110-57-6 trans-1,4-Dichloro-2-butene 5 U 100-41-4 Ethylbenzene 5 U 630-20-6 1,1,1,2-Tetrachloroethane 5 U 1330-20-7 Xylene (total) 5 U 100-42-5 Styrene _ 5 U 75-25-2 Bromoform 5 U , 79-34-5 1,1,2,2-Tetrachloroethane 5 U 96-18-4 1,2,3-Trichloropropane 5 U 106-46-7 1,4-Dichlorobenzene 5 U , _ 95-50-1 1,2-Dichlorobenzene 5 U 96-12-8 1,2-Dibromo-3-chloropropane 5 U FORM I VOA - 2 OLMO4.2 ' LKB010 S130 ' 1F EPA SAMPLE NO._ VOLATILE ORGANICS ANALYSIS DATA SHEET ' VBLK070214 TENTATIVELY IDENTIFIED COMPOUNDS Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. : LKB SAS No. : _ SDG No. : LK13010 Matrix: (soil/water) WATER Lab Sample ID: VBLK070214 ' Sample wt/vol: 5 (g/mL) mL Lab F--le ID: G26231.D Level: (low/med) LOW Date Received: o Moisture: not dec. Date Analyzed: 07/02/14 GC Column: Rtx-624 ID: .18 (mm) Dilution Factor: 1.00 ' Soil Extract Volume: Soil Aliquot Volume; 0 (uL) CONCENTRATION LNITS: Number TICS found: 0 (ug/L or pg/Kg) pg/L CAS NUMBER i COMPOUND NAME RT EST—CONC. Q i ' FORM I VOA-TIC OLM04.2 ' LKBO10 S131 U.S. EPA - CLP ' 3 'BLANKS Lab Name: PACE ANALYTICAL Contract: , Lab Code: 1047E Case No. SAS No. : SDG No. : LKBO10 Preparation Blank Matrix (soil/water) : WATER ' Preparation Blank Concentration Units (ug/L or mg/kg) : UG/ I FI-11 itiaalib. Continuing Calibration Prepa- Blank Blank (ug/L) ration , Analyte (ug/L) C ; 1 C 2 C 3 C Blank C ' M Aluminum 10.6 U 13.7 IBI 11.2 B ' 10.6 U1 10.600 U P , Antimony -2.6 B -2.5 B -3.2 B -2.7 B 1.600 U P jArsenic 1.5 U 1.5 U 1.5 U 1.5 U 1.500 U P ;Barium 0.3 B 0.4 B __0.4' B 0.4 B 0.300 U P Peryllium 0.1 U 0.1 B _ 0.1 B 0.1 B 0.091u P ' Boron 3.3 B 2.7 B _6B 2.1 B 1.300 U P ICadmium 0.1 U 0.1 U 0.2 B 0.2 B 0.140 U P !Calcium 12.1 U 12.1 U 12.1 U 12.1 U 12.100 U P Chromium 0.5 U 0.5 U 0.5 U 0.5 U 0.460 UP !Cobalt 0.2 U 0.2 U _ 0.2 U 0.2 U 0.160 U P !Copper _ 0.4, U 0.4 U 0.4 B_ 0.4 U 0.400 B P Iron 3.2' U 3.2 U 3.2 U -4.8 B 3.200 U P !Lead 1.0' U 1.0 U 1.0 U 1.0 U 1.000 U P ' Magnesium 18.3 U 1.8_.3 U 18.3 U 18.3 U 18.300 U _ P ',Manganese 0.1, U 0.1 ! U 0.1 U 0.2 B 00 U P -0.1_ Nickel 0.3 U 0.3 U 0.3 U 0.3 U 0.290 U P - _ 'Potassium 81.4 B 71.0 J 71.0 U 71.0 U IF 71.000 U P Selenium 1.6 B 1.4 U 1.4 U 1.4 U 1.400 U P Silver 1.5 B 0.4 _U 0.4 U 0.7 B ' 1.480 B P 'Sodium 27.3 B 40.7 B 22.7 B 27.6 B 23.500 B P Thallium 3.5 U 3.5 ! U 3.5 U 3.5 U 3.500 U P ' Vanadium 0.4 3 0.2 ' U 0.2 U 0.2 U 0.220 U P Zinc 0.8 U 0.8t U 0.8 U 0.8 U 0.820 U P i FORM III - IN ILM04.1 LKB010 S132 ' 1 U.S. EPA - CLP ' 3 BLANKS 'Jame: PACE ANALYTICAL Contract: :ode: 10478 Case No. SAS No. : SDG No. : LKB010 11 ration Blank Matrix (soil/water) : WATER 3ration Blank Concentration Units (ug/L or mg/kg) : UG/L - Initial Calib. Continuing Calibration Prepa- Blank Blank (ug/L) raticn j lyte (ug/L) C 1 C 2 C 3 C Blank C M Mn-am 10.6 U i�.-- --- P ony -2.5 B - p i s T— 1.5 U p m - -- 0.4 B --- -- P lium 0.1 U L p 2.8 B P 0.1 U _ P Um _ 12.1j U - p ium 0.5 I U T p 0 2 U p - - - — r _ - 0.4 i U - I - -- P -- 3.2 U -- ; IP 1 1.0 U p ium 18.3+Up I nese T -- 0.1 U --- - - p 1 -t— - 0.3 U ( P ium _ 71.0 U - ---- p ---------- um _ !- 1.4 U p r ; 0.4 U - -- -- -- --� P i m 26.6 ' B I p Um 3.5 U P um - 0.2 U ------- --- ---r— --- --0.8 U p r FORM III - IN ILM04. 1 ' LKB010 S133 PACE ANALYTICAL Date: 01-Aug-14 QC SUMMARY REPORT SDG: LKB010 Spike Sample Recovery RPDRef %RPD Sample ID• Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL ——------------------------ MB-070814 MB-070814 Alkalinity,Total(As CaCO3) <1.00 MG/L UdS--67-0814 LCS-070-8-1-4---- Alkalinity,Total(As CaCO3) 24.1 MG/L 25 <1.00 96 ! 80 120 1407015-012EMS MW-8SMS--­----- --Alkalinity,Total(As CaCO3) 542 MG/L 250 302 96 175 125 1407015-012EDUPMW-8SDUP Alkalinity,Total(As CaCO3) 291 MG/L 1 302 —3.7 20 MB-45263 —TMB-45263 Biochemical Oxygen Demand <2 0 MG/L LCS-45263 ILCS-45263 Biochemical Oxygen Demand 219 MG/L 198 <2.00 111 85 116 11407015-012EDUP IMW-8SDUP Biochemical Oxygen Demand <4-00 MG/L <4 20 MB-071014 MB-071014 Bromide <0.500 MG/L MG/L 2.5 <0.500 102 90 110 �:::0::::F,"v LCS-071014 LCS-071014 Bromide 2.56 1407015-012EMS mw-8sms Bromide 1.19 MG/L 1 <0.500 99 80 120 Mw--B-SDUP (6,Z6 F-- < 1407015-012EDUP Bromide <0.500 MG/L 0.51 20 —nMrly—V5 MB-071414 MB-071414 Chemical Oxygen Demand <10-0 M'L LCS-071414 LCS-071414 Chemical Oxygen Demand 97.9 MG/L 100 <10.0 98 90 1110 1407015-012BMS MW-BSMS Chemical Oxygen Demand 130 MG/L 100 38.8 91 i 90 110 207015-012BDUP MW-8SDUP Chemical Oxygen Demand 40,0 MG/L 38.8 3.2 20 MPB-071-51-4 14 ride LCS_l3- 5-- Chloride - 5 LCS- 71 14 LCS-071514 2.O�Ll O� -1 10 , I < MB-071014 71 14 Chloride <2.00 MG/L LCS-071014 ILCS-071014 Chloride 10.5 MG/L 10 <2.00 105 90 11101 1407015-012EMS lmw-asms Chloride 98.9 MG/L 50 41.7 -.1-14-- 80 11201 1407015-012EDUP !MW-8SDUP Chloride 42.1 MGIL --F-- 41.7 0.84 20 M EWBOJM34 w w■ w w w w■ w� aw w� ww w� ■� w w ww w w w w QC SUMMARY REPORT SDG: LKBO10 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB-070214 MB 070214 Chromium Hexavalent <D 020_L_ MGIL LCS-070214 LCS-070214 .Chromium Hexavalent 0.212 !- MG/L 0.2 0.020 106 80 1120 1407015-012EMS MW-8SM5 1Chromium Hexavalent 0.985 MG/L 1 <0.100 99 75 125 !� 1407015-012EDUP IMW-8SDUP -- (Chromium,Hexavalent <0.100 MG/L20 *B-070214 MB-070214 (Color I <5.00 Units (LCS-070214 LCS-070214 Colo r 40.0 Units 40 <5.00 100 80 120 1407015-012EDUP MW-8SDUP Color 500 Units 500 i 20 - �- - -- --------- MB-071014 MB-071014 Hardness(As CaCO3) <5.00 MG/L li LCS-071014 LCS-071014 Hardness(As CaCO3) 1000 MG/L 1000 <5.00 ! 100 80 120 1407015-012DMS MW-8SMS Hardness(As CaCO3) 1210 MG/L 1000 220 99 75 125 -- _ - - - --- 220 -- 9 1407015 012DD-UP rMW-8SDUP Hardness(As CaCO3)3) 200 MG/L �— 1 20 -- --- - - <0.100,--MG/L - MB-070214 MB-070214 Nitrate as N � LCS-070214 LCS-070214 Nitrate as N 1.16 MG/L 1.13 <0_100 103 90 1101 0 MG/L 1407015-012BDUP - MW 8SDUP -_- Nitrate as N— - 0 0100 MG/L 0.5 <-0.100 98 190 110x0.1 20 MB-070214 MB-070214 Nitrite as N <0.100 MG/L iLCS-070214 LCS-070214 i Nitrite as N 1.05 MGIL 1 <0.100 105 90 110 1407015 012EMS MW 8SMS te as N 0.455 MG/L Nitri0.5 <0.100 91 90 110 1407015-012EDUP MW 8SDUP INitrite as N �<0.100 1 MG/L <0.1 20 MB 070314 MB-070314 Nitrogen,Ammonia(As N) <0.100 MGIL LCS-070314 LCS-070314 Nitrogen,Ammonia(As N) 1.07 MGIL 1 <0.100, 107 90 110 1407015-012BMS MW-8SMS Nitrogen,Ammonia(As N) 30.2 MG/L 5 25.0 104 90 110— 1407015-012BDUP MW-8SDUP Nitrogen,Ammonia(As N) 25.0 MG/L j 25.0 0.040 20 2 LKB010 S135 QC SUMMARY REPORT SDG: LKBO10 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: Analyte -_ -_ Result Units Amount Result %REC- Limits Value %RPD UCL _^ MB-45371 MB-45371 Nitrogen,Kjeldahl,Total <0.100 MGIL LCS-45371 LCS-45371 Nitrogen,Kjeldahl,Total 4.14 MG/L 4 <0.100 104 90 110 1407015 012BMS MW-8SMS Nitrogen,Kjeldahl,Total 33.2 MG/L 825.8 93 75 125_ 1407015-012BDUP_ MW-BSDUP - Nitrogen,Kjeldahl,Total 27.7 MG/L - - 25.8 7.1 j 20 MB-45373 MB-45373 Phenolics,Total Recoverable <5.00 UG/L LCS-45373 LCS-45373 Phenolics,Total Recoverable 26.5 UG/L 30 <5.00 88 80 120 1407015-012BMS MW-8SMS Phenolics,Total Recoverable 15.5 UG/L 20 <5.00 78 75 125 T 1407015-012BDUP MW-BSDUP Phenolics,Total Recoverable <5.00 UG/L <5 2D MB-071014 MB-071014 Sulfate <5.00 MG/L LCS-071014 LCS-071014 ISulfate 9.78 MG/L 10 <5.00 98 90 110 1407015-012EMS MW-8SMS Sulfate 97.5 MG/L 50 42.4 110 80 120 1407015-012EDUP MW-BSDUP Sulfate 42.8 MG/L 42.4 1.1 20 MB-070214 IMB-070214 Total Dissolved Solids <10.0 MG/L LC_S-070214 LC -070214 Total Dissolved Solids 296 MG/L 300 <10.0 99 80 120 1407015-012EMS MW-8SMS Total Dissolved Solids 732 MG/L 300 414 106 75 125 --- - - -- �1407015-012EDUP MW-BSDUP Total Dissolved Solids 409 MG/L 414 1.2 20 MB-070714 MB-070714 -Total Dissolved Solids __L271,'13 10.0 IV _ �� LCS-070714_ LCS-070714 iTotal Dissolved Solids 273 MGIL � 300 <10.0 91 i 80 120 MB-072414 MB-072414 Total Organic Carbon <1.00 MG/L LCS-072414 LCS-072414 Total Organic Carbon 21.2 MG/L 25 <1.00 85 80 120 1407015-012CMS MW-8SMS Total Organic Carbon 105 MGIL 100 12.7 92 75 125 1407015-012CDUP MW-BSDUP Total Organic Carbon _ 12.8 MGIL 12.7 0.70 20 MB-071114 MB-071114 Total Organic Carbon <1 M__ -7�R MGIL - LCS 071114 LC5-071114 Total Or amc Carbon 27.8 MGIL 25 <1.00 111 80 120 3 i ace Lang Island i 575 Broad Hollow Road 531.694.3040 Melville; NY t X747 -zO G31.420.8436 10. INTERNAL STANDARD DATA 10.1 VOLATILES 1 ' LKB010 S137 8 INTERNAL STANDARD AREA AND RT SUMMARY , Lab Name: PACE ANALYTICAL SDG No.: LKB01 Lab Code: 10478 ' Lab File ID(Standard): G26230.D Date Analyzed: 7/2/2014 Instrument ID: HP5972-2 Time Analyzed: 11_16 ' GC Column: Rtx-624 ID: .18 (mm) Heated Purge: (YIN) N IS1 IS2 IS3(CBZ) IS4 14DCB AREA# RT # AREA# RT # AREA# RT # AREA# RT # 12 HOUR STD 215111 3.840 388778 4.370 1701636.530 137094 8.050 ' UPPER LIMIT 430222 4,340 777556 4.870 340326 7.030 274188 8.550 LOWER LIMIT 107556 3.340 194389 3.870 85082 6.030 68547 7.550 SAMPLE NO, -T 01 VBLK070214 230870 3.84 407511 4.37 178466 1 6.53 155457 8.05 02 LFB070214 212800 3.84 381207 4.37 166752 6.53 136012 8.05 03 MW-1D 227204 3.84 401535 4.37 177099 6.53 154115 8.05 04 MW-1 S 231813 I 3.84 410411 4,36 178677 6.53 154969 8.05 , 05 MW-31D 225916 3.84 405573 4.37 177332 j 6.53 153436 8.05 06 MW-3S 226362 3.84 404504 4.37 175639 6.53 153169 8.05 07 MW-4D 226371 3.84 405675 4,37 180036 6.53 154403 8.05 ' 08 MW-4S 230373 3.84 408893 4.37 178760 6.53 153034 8.05 09 MW-5D 226291 3.84 401494 4.37175883 6.53 150739 8.05 10 MW-5S 225621 3.84 401672 4.37 175322 f 6.53 153501 8.05 11iMW-61) 224127 3.84 397907 4.37 174301 6.53 152347 8.05 12 MW 6S 222664 3.84 399586 4,37 174097 6.53 152081 8.05 13 MW-7S 225541 3.84 402588 4.37 176097 6.53 153387 8.04 14 I MW-8S 221195 3.84 393931 4.36 171720 I 6,53 150913 8.05 ISiMW-6SMS 203978 j 3.84 371462 I 4.37 162565 I 6.53 131070 8.05 16iMW-8SMSD 202163 3.84 369271 I 4.36 162031 I 6.53 130450 8,05 17 Field Blank 221436 3.83 390146 4.36 172450 6.53 149678 8.05 ' 18,Tdp Blank 220296 3.84 392488 4.37 172566 6.53 152055 8.05 4Storage Blank j 220436 3.84 398187 I 4.37 175349 6,53 151564 8.05 IS1 =Pentafluoro benzene I33(CBZ)=Chlorobenzene-d5 ' IS2 = 1,4-Difluorobenzene IS4 14DCB=1,4-Dichlorobenzene-d4 AREA UPPER LIMIT=+100%of internal standard area AREA LOWER LIMIT=-50%of internal standard area ' RT UPPER LIMIT=+0.50 minutes of internal standard RT RT LOWER LIMIT=-0.50 minutes of internal standard RT #Column used to flag values outside QC limits with an asterisk. , Values outside of QC limits. 07W/1414:28 FORM VIII SW8260 LKB010 S138 '