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Home My WebLink About2014 1st Qtr First Quarter 2014 Ground Water-Monitoring Report Town of Southold Landfall, Cutchoque, NY • TABLE OF CONTENTS Section Number and Title Page Number 1.0 INTRODUCTION 1 2.0 METHODS AND PROCEDURES 1 3.0 DISCUSSION OF RESULTS 2 3.1 Water-Level Results 2 3.2 Field Parameter Results 3 3.3 Leachate Indicator Parameter Results 3 3.4 Inorganic Parameter Results 5 4.0 CONCLUSIONS AND RECOMMENDATIONS 6 Figure Number and Title Follows Page Number • 1. Site Location Map 1 2. Well Location Map 1 Table Number and Title Follows Page Number 1. Summary of Part 360 Routine Parameter Results for 2 First Quarter 2014 Monitoring Round Appendices A. Sample Data Summary Package • i Lockwood, Kessler& Bartlett, Inc. First Quarter 2014 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY • 1.0 INTRODUCTION The Town of Southold has retained Lockwood, Kessler & Bartlett, Inc. (LKB) to perform post-closure ground-water monitoring and reporting for its closed and capped MSW landfill in Cutchogue, NY (Site). The location of the Site is shown in Figure 1. This report is for the first quarter 2014 monitoring round, conducted on March 27, 2014; and describes the work performed and the results obtained. Section 2.0 (Methods and Procedures) details the project requirements and the specific work performed. Section 3.0 (Discussion of Results) summarizes the key findings from this monitoring round, including comparison of the laboratory results to standards and guidance values. Section 4.0 (Conclusions and Recommendations) provides conclusions based on this quarter's results, and recommendations for upcoming quarters. Each report section is supported by figures and/or tables, as appropriate, which follow the page on which they are first referenced. The laboratory data summary package for this monitoring round is provided in Appendix A. 2.0 METHODS AND PROCEDURES Water-level measurements and ground-water samples were collected from the twelve • monitoring wells listed below. A site plan showing the locations of the wells is provided in Figure 2. • MW-1S • MW-5S • MW-1D • MW-5D • MW-3S • MW-6S • MW-3D • MW-6D • MW-4S • MW-8S • MW4D • MW-8D Prior to sampling, the water-level in each well was measured to the nearest 0.01-feet from the top of the well casing utilizing a decontaminated water-level meter. Ground- water samples were collected utilizing a Grundfos RediFlo2 variable-speed electric submersible pump connected to 200 feet of %-inch diameter polyethylene hose on a Keck Reel. Utilizing the well construction records, the pump was placed at the mid-point of each well's screen. Each well was then purged at a low flow rate until its turbidity was less than 5 Nephelometric Turbidity Units (NTUs) and/or field parameter readings stabilized. The sampling apparatus was decontaminated between wells by rinsing its interior and exterior with distilled water. Field parameters were measured utilizing a calibrated YSI 556 Multi Probe System equipped with a flow-through cell. The ground water purged • during sampling was discharged to the land surface at each well location. I Lockwood, Kessler& Bartlett, Inc. • Duck Pard Pt Y-----^� f v_ O II N D --------_- -'" LA j 11958 +J . SITE Z, OREGON 1193 o� CUT�HOGVE S TA / s.. t EAST TTITUCK t� p s q v�' V' CEM£TEa4 N- l P 5 1 _ { • C UST C H K �► r $Y' 25 a Cas a Seo T v ♦ y NORTH9 FORK/ Ma rsh Pt COUNTRY MATTI arr3ponr CUTCHOGUE , HARBOR R�t pq Old Cove 11 ��P,�O O�C� cN. � 11111 .,. MarratookaPt vQo�otT Y.C. /9�Phr1^7T NEW SUFFOLK FIGURE 1 • SITE LOCATION MAP TOWN OF SOUTHOLD LANDFILL, CUTCHOGUE, NY 7 MW5S / I f MW-50A ( , M1 IM-3 % ft t .. , g,.« fes« •_ .r ! /' ---......111 ,, � ':� � .. •'""-.`'� � 4..- ../ ? 1 �. 1 t 1 r i9 .r 1. MW-81 v'� r 0 v P LEGEND MW-6S GROUNDWATER - j MONITORING WELL Afiw 8`S .n r., .`< s t , 300 ISO 0 300 SCALE IN FEET `NOTE:WELL SYMBOLS NOT TO SCALE T -� ,� J, f+ W-ts Note: Base map provided by Town of Southold FIGURE 2 WELL LOCATION PLAN TOWN OF SOUTHOLD LANDFILL, CUTCHOGUE, NY ��a�v First Quarter 2014 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY The ground-water samples were collected directly from the pump discharge hose into new laboratory-supplied bottles of the type required for each specific analysis. A blind duplicate was collected from Well MW-4S and labeled "MW-7S". Field notes were recorded in a bound field notebook. Each sample was labeled with the well number, time and date, etc., placed in a cooler with ice to keep it at 4°C, and delivered to the laboratory the following day. The samples were analyzed for the 6NYCRR Part 360 Routine Parameters. The field parameters were monitored by LKB. Laboratory analyses were performed by Pace Analytical (formerly H2M Labs, Inc.) in Melville, NY. This laboratory is certified by the New York State Department of Health's Environmental Laboratory Approval Program in all required analytical categories, and employs the required internal QA/QC procedures, including analysis of matrix spikes, matrix spike duplicates, method blanks and continuing calibration samples. They also participate in the required biennial proficiency testing. The field data and laboratory results were reviewed by LKB per QA/QC Plan requirements and determined to be useable. 3.0 DISCUSSION OF RESULTS The field and laboratory results for the first quarter 2014 ground water-monitoring round are summarized and compared to the New York State Department of Environmental • Conservation Ambient Water Quality Standards and Guidance Values for Class GA (Potable) ground water, as applicable, in Table 1. A review of the results for the water- level measurements and each analytical parameter group is provided below. 3.1 Water-Level Results As shown in Table 1, water-table elevations were generally consistent across the Site and ranged from 5.94 feet above mean sea level (MSL) in Well MW-1S, located on the south end of the Site, to 3.82 feet above MSL in Well MW-8S, located on the west side of the Site. The water-level results are consistent with ground-water flow information published by the United States Geological Survey in Scientific Investigations Map 3066, Water Table — Sheet 1 of 4, which indicates a relatively low horizontal hydraulic gradient and a northerly horizontal ground water-flow direction. Based on these results, Well Cluster MW-1 is located upgradient of the Site, and the other wells are located downgradient of various portions of the Site. Except for an anomalously high elevation in Well MW-8D, potentiometric surface elevations in the deeper wells are consistent with the water-table elevations. The results for Well MW-8D are attributed to localized hydrogeologic conditions at this well location and screen depth. • 2 Lockwood, Kessler& Bartlett, Inc. Table 1 Summary of Part 360 Routine Parameter Results for First Quarter 2014 Monitoring Round Town of Southold Landfill, Cutchogue, NY NYSDEC Part 360 Units Class GA Well Number and Result Routine Parameters Standard MW-1S MW-1D MW-3S MW-3D MW-4S MW-4D MW-5S MW-5D MW-6S MW-6D MW-8S MW-8D Water-Level Data: T.O.C. Elevation Feet MSL N/A 44.83 44.88 49.50 49.19 63.03 62.92 68.14 67.64 55.77 55.71 54.16 55.29 Depth to Water Feet N/A 38.89 38.90 44.53 44.24 58.50 58.42 63.65 63.20 50.75 50.70 50.34 49.17 Water-Level Elevation Feet MSL N/A 5.94 5.98 4.97 4.95 4.53 4.50 4.49 4.44 5.02 5.01 3.82 6.12 Field Parameters: Conductivity ms/cm No Standard 0.163 0.376 0.910 1.680 0.650 2.360 0.150 1.940 0.184 0.427 0.650 1.040 Temperature oC No Standard 13.7 12.5 15.3 15.2 15.2 14.8 13.6 14.2 12.5 12.2 15.2 14.8 Floaters or Sinkers N/A None None None None None None None None None None None None None pH Units 6.5-8.5 4.85 6.38 6.30 6.51 6.18 6.76 5.43 6.63 5.48 5.64 6.54 6.63 Eh pHmV No Standard 88.2 3.0 8.4 -3.5 14.8 -17.3 56.6 -10.3 52.6 44.0 -4.8 -10.2 Dissolved Oxygen mg/L No Standard 8.94 4.60 0.68 0.45 0.68 1.03 2.69 0.29 1.70 3.23 1.39 0.35 Field Observations N/A No Standard Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor Turbidity NTU <5 3.09 4.57 1.93 1.65 0.22 4.34 1.76 4.39 4.45 3.58 0.59 3.56 ORP mV No Standard NM NM NM NM NM NM NM NM NM NM NM NM Leachate Indicators: Alkalinity mg/L No Standard 4.45 24.1 185 489 193 678 22.7 721 51.1 10.2 169 288 Ammonia mg/L 2 < 0.10 < 0.10 14.1 65.9 < 0.10 27.2 < 0.10 94.5 < 0.10 < 0.50 21.8 21.5 BOD mg/L No Standard < 2 < 2 5 < 2 < 2 < 2 < 2 < 2 < 2 < 2 < 2 < 2 Bromide mg/L 2GV < 0.50 < 0.50 < 0.50 < 0.50 < 0.50 1.71 < 0.50 0.87 < 0.50 < 0.50 < 0.50 < 0.50 Chloride mg/L 250 24.8 30.4 87.1 138 19.5 177 18.9 202 13.7 43.6 43.6 96.8 COD mg/L No Standard < 10.0 < 10.0 31.8 52.7 21.6 57.8 < 10.0 70.5 26.1 < 10.0 29.9 26.1 Hardness mg/L No Standard 32 120 130 180 240 600 44 360 68 150 88 240 Nitrate mg/L 10 2.84 5.21 < 0.10 < 0.10 17.9 < 0.10 0.82 < 0.10 1.18 6.92 < 0.10 < 0.10 Phenols ug/L 1 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 Sulfate mg/L 250 17.4 86.5 47.9 36.7 40.5 91.4 12.7 40.5 6.69 94.0 55.1 82.4 Total Dissolved Solids mg/L 500 91 229 342 528 450 1,250 54 844 90 256 323 503 TKN mg/L No Standard 0.54 0.46 17.7 75.0 0.40 32.9 0.73 108 1.42 0.43 25.7 27.4 Total Organic Carbon mg/L No Standard < 1.0 < 1.0 7.4 19.5 9.6 22.3 4.5 30.8 11.7 < 1.0 9.1 10.0 Inorganic Parameters: Cadmium ug/L 5 < 0.11 < 0.11 4.9 J 2.0 J 0.30 J < 0.11 0.20 J < 0.11 0.20 J 0.20 J 2.2 J 0.70 J Calcium ug/L No Standard 7,410 31,200 26,700 39,000 79,100 140,000 9,610 79,300 18,200 35,800 48,200 57,600 Iron ug/L 300 56.5 J 101 72,400 29,200 16.9 J 526 27.6 J 130 220 67.6 J 33,300 10,400 Lead ug/L 25 11.9 19.9 < 19.5 5.3 5.0 J 15.5 10.4 < 1.9 10 15.9 < 1.9 17.1 Magnesium ug/L 35,000 4,300 J 14,900 17,000 27,600 18,100 60,400 5,010 31,600 4,990 J 17,200 16,600 27,800 Manganese ug/L 300 24.1 2.3 J 4,480 3,560 5,720 3,740 364 11,800 2,920 1,120 352 1,570 Potassium ug/L No Standard 3,840 J 1,930 J 20,200 68,300 39,300 55,800 4,780 J 110,000 4,470 J 3120 J 43,800 49,400 Sodium ug/L 20,000 12,600 19,500 39,400 103,000 10,700 194,000 8,330 133,000 6,340 16,300 22,000 58,600 Notes: T.O.C. = Top of Casing. COD = Chemical Oxygen Demand. mV = millivolts. J = Estimated result> MDL but< RL. MSL = Mean Sea Level. TKN = Total Kjeldahl Nitrogen. mg/L = milligrams per Liter. mS/cm = milliSiemens per centimeter. °C = Degrees Celsius. ug/L = micrograms per Liter. Results in bold font and highlighted in yellow ORP = Oxygen Reduction Potential. pHmV = pH in millivolts. N/A = Not Applicable. exceed Class GA Standard or Guidance Value. BOD = Biological Oxygen Demand. NTU = Nephelometric Turbidity Units. NM = Not Measured. First Quarter 2014 Ground Water-Monitoring Report Town of Southold Landfall, Cutchogue, NY • 3.2 Field Parameter Results Review of the field parameter results in Table 1 indicates the following key findings: • Ground-water conductivity values are higher relative to the main area of Long Island, and may be at least partly attributed to the Site's North Fork location, where naturally higher ground-water salinities may occur due to the proximity to saline surface-water bodies. Conductivities are highest in the deep wells located directly downgradient of the Site (e.g., Wells MW-3D, MW-4D and MW-5D). These highest values appear to be Site-related. • Ground-water temperatures are slightly higher in the shallow wells located downgradient of, and in close proximity to, the main area of the Site. • No floaters or sinkers were noted during this monitoring round. • Ground-water pH is acidic, and is lower than the minimum standard of 6.5 Standard Units in seven of the 12 wells this quarter. The results are consistent with the naturally low pH of Long Island ground water, and are similar in upgradient and downgradient wells. Ground-water pH is higher in the deep well at each cluster. • Eh is similar in upgradient and downgradient wells. Eh is lower in the deep well every cluster except Well Cluster MW-8. The lowest Eh values occurred in Wells MW-4D, MW-5D and MW-8D. • • Dissolved oxygen concentrations are generally lower in the downgradient wells than in the upgradient wells, but dissolved oxygen is present in all 12 wells. • The ground water in all 12 wells was observed to be clear, and did not have a noticeable odor this quarter. • The turbidity of ground water is low and was less than 5 Nephelometric Turbidity Units in all 12 wells this quarter. Therefore, the collection of filtered samples for dissolved metals analyses was not required. • The ORP (oxidation-reduction potential) of ground water could not be measured this quarter due to a probe malfunction. This is not a significant data gap. Overall, the field parameter results obtained this quarter are consistent with the Site's usage and its North Fork setting. Potential Site-related impacts are relatively minor in magnitude and limited to higher conductivity and temperature, and lower dissolved oxygen levels, in certain downgradient wells. 3.3 Leachate Indicator Parameter Results Review of the leachate parameter results in Table 1 indicates the following key findings: • Ground-water alkalinity is noticeably higher in seven of the ten downgradient wells relative to the upgradient wells, and is highest in Wells MW-3D, MW-413 • and MW-5D. 3 Lockwood, Kessler& Bartlett, Inc. First Quarter 2014 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY • • Ammonia is present in six downgradient wells, at concentrations exceeding the Class GA ground-water standard; and is highest in Wells MW-3D and MW- 5D. The fact that the highest ammonia concentrations occur in deeper wells suggests that they may be partly due to natural saline ground-water conditions. • Biological oxygen demand (BOD) was only detected in one downgradient well (MW-3S) at a very low concentration this quarter. • Bromide was only detected in two deep downgradient wells (MW-4D and MW- 5D) at concentrations below the 2-mg/L guidance value this quarter. • Chloride levels are noticeably higher in five of the downgradient wells (MW-3S, MW-3D, MW-4D, MW-5D and MW-8D) relative to the upgradient wells, but are lower higher than the 250-mg/L Class GA ground-water standard in all wells. The fact that chloride concentrations are highest in certain deeper wells suggests that they may be associated with naturally saline ground-water conditions. • Chemical oxygen demand (COD) was detected in eight of the ten downgradient wells. The highest COD results occurred in Wells MW-3D, MW-4D and MW-5D. • Ground-water hardness values are higher in six of ten downgradient wells relative to the upgradient wells. The highest hardness value occurred in Well MW-4D. There is no Class GA ground-water standard for guidance value or this parameter. • Ground-water nitrate levels are relatively low, and lower than the Class GA • ground-water standard in every well except Well MW-4S. • Phenols were not detected in any of the site monitoring wells this quarter. • Sulfate is present in all 12 wells, and at relatively similar concentrations in the upgradient and downgradient wells. The sulfate concentration is higher in the deeper well at all but one well cluster, which suggests that they are at least partly associated with saline ground-water conditions. • Total dissolved solids (TDS) results are noticeably higher in eight of the ten downgradient wells relative to the upgradient wells, and exceed the 500-mg/L Federal MCL in Wells MW-3D, MW-4D, MW-5D and MW-8D. The fact that the highest TDS concentrations occur in the deeper wells suggests that they may associated with naturally saline ground-water conditions. • Total Kjeldahl nitrogen (TKN) is present in all 12 wells this quarter. TKN concentrations in six of the ten downgradient wells are significantly higher than in the upgradient wells. The highest concentrations occurred in Wells MW-3D and MW-5D. There is no Class GA standard or guidance value for this parameter. • Total organic carbon (TOC) was not detected in the upgradient wells, but is present in nine of the ten downgradient wells. The highest concentrations occurred in Wells MW-3D, MW-4D and MW-5D. There is no Class GA standard or guidance value for this parameter. • 4 Lockwood, Kessler& Bartlett, Inc. First Quarter 2014 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY Overall, the leachate parameter results obtained this quarter are also consistent with the Site's usage and its North Fork setting. Potential Site-related impacts indicated by these results include downgradient increases in most of the detected parameters. However, it is important to note that 1) the there are no ground-water standards for six of the parameters; and 2) the downgradient increases occur in a limited number of wells. Moreover, ground water in this area is naturally saline at depth, and ultimately discharges to a saline surface-water body (Long Island Sound). Therefore, the exceedances for ammonia, nitrate and TDS, which occur naturally in saline ground water and seawater, are not a significant concern with respect to public health or the environment. 3.4 Inorganic Parameter Results Review of the inorganic routine parameter results in Table 1 indicates the following key findings: • Cadmium was detected in eight of the ten downgradient wells, but only at low, estimated concentrations below the 5-ug/L Class GA ground-water standard. • Calcium was detected in all 12 wells, and is noticeable higher in Wells MW-4S, MW-41D, MW-51D, MW-8S and MW-81D relative to the upgradient wells. There is no Class GA ground-water standard for this parameter. • • Iron was detected in all 12 wells this quarter, and the concentrations in five of the downgradient wells exceed the 300-ug/L Class GA ground-water standard. The highest iron concentrations occurred in Well Clusters MW-3 and MW-8. At these two clusters, the highest iron concentrations occurred in the shallow wells, suggesting that the higher iron levels detected at these locations are Site-related. • Lead was detected at low, similar concentrations in both upgradient wells and seven of the ten downgradient wells. All detections are much lower than the 25- ug/L Class GA ground-water standard. • Magnesium was detected in all 12 wells, but only the concentration in Well MW- 4D is higher than the 35,000-ug/L Class GA ground-water guidance value. Magnesium concentrations are higher in the deeper well at each cluster, which suggests that they are primarily due to naturally saline ground-water conditions. • Manganese was detected in all 12 wells, and the concentrations in all ten downgradient wells exceeds the 300-ug/L Class GA ground-water standard. The highest manganese concentration occurred in Well MW-51D. • Potassium was detected in all 12 wells. Potassium concentrations are higher in seven of the ten downgradient wells relative to the upgradient wells, and are highest in Wells MW-31D and MW-51D. There is no Class GA ground-water standard or guidance value for this parameter. 5 Lockwood, Kessler& Bartlett, Inc. First Quarter 2014 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY • Sodium was detected in all 12 wells. Sodium concentrations are noticeably higher in six downgradient wells (MW-3S, MW-3D, MW-4D, MW-5D, MW-8S and MW-8D) relative to the upgradient wells, and exceed the 20,000-ug/L Class GA ground-water standard in these wells. The highest sodium concentrations occur in the deep wells, which suggests that they are primarily due to naturally saline ground-water conditions. Overall, the inorganic parameter results obtained this quarter are also consistent with the Site's usage and its North Fork setting. Potential Site-related impacts indicated by these results include downgradient increases in cadmium, calcium, iron, magnesium, manganese, potassium and sodium. However, it is important to note that 1) many of these increases are relatively minor in magnitude, sporadic, and/or less than the Class GA ground-water standard; 2) there are no ground water-quality standards or guidance values for calcium or potassium; 3) the standards for iron and manganese are aesthetics-based; and 4) sodium is not considered to be particularly hazardous. Moreover, as noted above in Section 3.2, ground water on the North Fork is naturally saline at depth and ultimately discharges to a saline surface-water body (Long Island Sound). Therefore, the exceedances for magnesium and sodium, which occur naturally in saline ground water and seawater, are not a concern with respect to public health or the environment. 4.0 CONCLUSIONS AND RECOMMENDATIONS Based on the results of the first quarter 2014 monitoring round, LKB concludes the following: • Water-level elevations, hydraulic gradients and ground water-flow directions are consistent with local and regional hydrogeologic conditions. • In general, ground water-quality conditions are consistent with the Site's North Fork setting near saline surface-water bodies. • Comparison of upgradient and downgradient results indicates potential Site- related impacts consistent with an old MSW landfill, however further assessment indicates that they are not a significant concern with respect to public health or the environment. The monitoring schedule for the Site requires monitoring ground water for 6NYCRR Part 360 routine parameters during three calendar quarters and for Part 360 baseline parameters during one calendar quarter, in rotating quarters. Annual baseline rounds have been performed in the third quarter of 2011, the fourth quarter of 2012 and the first quarter of 2013. Therefore, the next baseline monitoring round should be performed during the second quarter of 2014. 6 Lockwood, Kessler& Bartlett, Inc. 1!!;a'C6 Long Island • r SAMPLE DATA SUMMARY PACKAGE TABLE OF CONTENTS LOCKWOOD, KESSLER & BARTLETT PROJECT: TOWN OF SOUTHOLD LANDFILL 2014 MONITORING ROUND SAMPLES RECEIVED: 3128/14 SDG NO.: LKB009 1. NYS DEC SUMMARY FORMS 2. CHAIN OF CUSTODY DOCUMENTATION 3. SDG NARRATIVES 4. SAMPLE REPORTS 4.1 METALS 4.2 WET CHEMISTRY 5. DUPLICATE SUMMARY RESULTS • 5.1 METALS 5.2 WET CHEMISTRY 6. SPIKE SAMPLE RESULTS 6.1 METALS 6.2 WET CHEMISTRY 7. BLANK SUMMARY DATA AND RESULTS 7.1 METALS 7.2 WET CHEMISTRY • LKB009 S1 ace Long Island 576 goad Hollow Read :,! 631.694,30,10 Melville.NY 1t74r n;; 63'.420&436 1. NYS DEC SUMMARY FORMS LKB009 S2 NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE IDENTIFICATION AND • ANALYTICAL REQUIREMENT SUMMARY SDG: LK13009 Anal tical Requirements Customer Laboratory Sample Sample ME we Code Code _ MW-1D 1403J57-001 X X MWAS 1403J57-002 X X MW-31) 1403J57-003 X X MW-3S 1403J57-004 X X MW-4D 1403J57-005 X X MW-4S 1403357-006 X X MW-51) 1403J57-007 X X MW-5S 1403J57-008 X X MW-6D 1403J57-009 X - -- IMW-6S 1403J57-010 X X MW-7S 1403J57-011 X X MW-8D 1403J57-012 X X MW-8S 1403J57-013 X X • CLP . on-CLP Please indicate year of protocol) TCLITAL7-RS7Priority Pollutant, AV LKB009 S3 • ! • NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG : LK13009 INORGANIC ANALYSIS Laboratory DateRecd Date Samp ID Client Sample ID Matrix Metals Requested at Lab Analyzed 1403J57-001 MW-1D WATER CA,CD,FE,K,MG,MN,NA,PB, 28-Mar-14 04/14 1403J57-001DUP MW-IDD WATER CA,CD,FE,K,MG,MN,NA,PB, 28-Mar-14 04/14 1403J57-001MS MW-1DS WATER CA,CD,FE,K,MG,MN,NA,PB, 28-Mar-14 04/14 1403J57-002 MW-1S WATER CA,CD,FE,K,MG,MN,NA,PB, 28-Mar-14 04/14 1403J57-003 MW-3D WATER CA,CD,FE,K,MG,MN,NA,PB, 28-Mar-14 04/14 1403J57-004 MW-3S WATER CA,CD,FE,K,MG,MN,NA,PB, 28-Mar-14 04/14 1403J57-005 MW-4D WATER CA,CD,FE,K,MG,MN,NA,PB, 28-Mar-14 04/14 1403J57-006 MW-4S WATER CA,CD,FE,K,MG,MN,NA,PB, 28-Mar-14 04/14 1403J57-007 MW-5D 1i WATER CA,CD,FE,K,MG,MN,NA,PB, 28-Mar-14 04/14 1403J57-008 MW-5S WATER CA,CD,FE,K,MG,MN,NA,PB, 28-Mar-14 04/14 1403J57-009 MW-6D WATER CA,CD,FE,K,MG,MN,NA,PB, 28-Mar-14 04/14 1403J57-010 MW-6S WATER CA,CD,FE,K,MG,MN,NA,PB, 28-Mar-14 04/14 1403J57-011 MW-7S WATER CA,CD,FE,K,MG,MN,NA,PB, 28-Mar-14 04/14 1403J57-012 MW-8D WATER j CA,CD,FE,K,MG,MN,NA,PB, 28-Mar-14 04/14 1403J57-013 MW-8S WATER CA,CD,FE,K,MG,MN,NA,PB, 28-Mar-14 04/14 LKB009 S4 • NEW YORK STATE DEPARTMENT OF ENVIRONMENTAL CONSERVATION SAMPLE PREPARATION AND ANALYSIS SUMMARY SDG : LK13009 INORGANIC ANALYSIS Laboratory DateRecd Date Samp ID Client Sample ID Matrix Tests at Lab Analyzed 1403J57-001 MW-1D Groundwater SELECT WET CHEMISTRY** 03i28/14 03/14-04/14 1403J57-002 MW-1S Groundwater SELECT WET CHEMISTRY** 03/28/14 03/14-04/14 I 1403757-003 MW-31) Groundwater SELECT WET CHEMISTRY** 03/28/14 03/14-04/14 1403.157-004 MW-3S Groundwater SELECT WET CHEMISTRY** 03i28/14 03/14-04/14 1403J57-005 MW4D Groundwater SELECT WET CHEMISTRY** 03/28/14 03/14-04/14 1403757-006 IvRV 4S Groundwater SELECT WET CHEMISTRY** 03/28/14 03/14-04/14 1403J57-007 NNW-5D Groundwater SELECT WET CHEMISTRY** 03/28/14 03/14-04/14 1403J57-008 MW-5S Groundwater SELECT WET CHEMISTRY** 03/28/14 03/14-04114 1403J57-009 MW-61D Groundwater SELECT WET CHEMISTRY** 03/28/14 03/14-04'14 1403J57-010 MW-6S Groundwater SELECT WET CHEMISTRY** 03/28/14 03/14-041114 1403757-011 MW-7S Groundwater SELECT WET CHEMISTRY** 03/28/14 03/14-04,14 • 1403.157-012 MW-8D Groundwater SELECT WET CHEMISTRY** 03/28/14 03/14-04,'14 1403.157-013 MW-8S Groundwater SELECT WET CHEMISTRY** 03/28/14 03/14-04/14 ** Alkalinity,Total(As CaCO3) ; Biochemical Oxygen Demand ; Bromide ;Chemical Oxygen Demand ;Chloride ; Hardness(As CaCO3) ; Nitrate as N ; Nitrite as N ; Nitrogen, Ammonia(As N) ; Nitrogen, Kjeldahl,Total ; Phenolics,Total Recoverable; Sulfate; Total Dissolved Solids ;Total Organic Carbon ; LKB009 S5 lace Long Island 575 Broad Hollow Road 63'.694,3040 Melville,NY 11747 := 631.420.8436 2. CHAIN OF CUSTODY DOCUMENTATION • • LKB009 S6 ti Orth CHAIN OFC STODY RECORD AV Amber VW` ES �..i Encore Salnpinr Gv Clear Vial PPV R.M.—ad vial / aceAnalytical P Plea, art PLC Plasdc wnlairrer AL Amber Ute, PLJ Plastic Jar LAB W.O# Quote: Pae of GL Clear LR to Z ZJwuc bag / www.pacelabs.com AP Amber PWsdc TB Tedla bag Page AG Amber Glans WP WMrlpak SJ Soil Jar G ballon Jug I 1 tither TC Terra—re {A��,y/' (/.l�(f� \�/� 2jj �),p�,.��J�►�yr. (1�J1_^e 'Prepreserved vial ( `uC' ■-"-e .l Y " 1 1+- f 7 PIJ �, 3'•a(s):2o<.4uz,8az,16-,32-ar IL.othe- Jr FaamPb40m1 500m1 plastic,8omz13 J=BoSell Jar Company Name: D +n T_ O# Add,..: QPiA( to A5. City: S GSw! State:IVY ZI : •, .,! sD Sakion waste OL o �`t Lr round Water SL Sludge Attn: V h� GW G C Fax# x.i 1/< EFF Emnenl so Salsemment AFW Analyte Free H2O AQ Aquea+s S. WW Waste Ware, NA Nwaqueous email: Phone: a! 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Pompano Lab 954-582-4300 Revision:F•ALL•C•007-Rev.00 C.O.C.Serial# 67585 - - - ------- ----- - -L__KB009-S7_ .= i CHAIN OF C STODY RECORD f-0,x AV Ambervial Vaal ES Encore Sampler CV Ober Vial PPV Prepreserved vial aceAnalytical® P Plaelc PLC Plaslivur ner AL Amber Liter PI.J Plastic Jar CL Clear Lilar Z ZiUlw:bag www.pacelabs.com LAB W.O#� Quote: Pa e/ of y AP Aa+xrPasu� re Tedarheg P 9 AG Amber Gbas WP Whirl pak SJ Soil Jar G Get..Jug r Other 'TC Tara-core PrePteserve vial oz J 4 U v t t rV V 11't. <4 ,&u,16uz,32oz or IL,other_ O n500m1 .u, Exempe:4—P=4oz Plastic,B_ SJ-BoSoil Jar Company Name:fh,k C Q4/ekLT, P()# q f 1 Address: 1 M ;�ti{ 0 J —t City: S £Er State: Zi 11 /' » OL it}r ?xr 4 IN Solid waste OL Oil ..' 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Volal ies Tedd witheut headepace'1 _ 4 Proper Cantalna a used? — Pompano Lab 954-582-4300 RevWlon:F-ALL-C-007-Rev.00 C.O.C.Serial# 67584 LKB009 S8 PACE ANALYTICAL ah O-' ` 575 Broad Hollow Road \ aceAnalytical` Melville,NY]]747 Sample Receipt Checklist TEL:(631)694-3040 FAX:(631)420-8436 Website:www.pacelabs.rmn Client Name LKB Date and Time Received: 3/28/2014 10:40:00 AM Work Order Number: 1403J57 RcptNo: 1 Received by: Joshl-aedke Gi��Li/ 7 Completed by: _G_ . Reviewed by: I Completed Date: 3/28/2014 11:47:55 AM Reviewed Date: 3/30/2014 9:01:44 PM Carrier name: Client Chain of custody present? Yes ,� No❑ I Chain of custody signed when relinquished and received? Yes EV71 No'❑ Chain of custody agrees with sample labels? Yes We No Are matrices correctly identified on Chain of custody? Yes W No Is it clear what analyses were requested? Yes W NoLl Custody seals intact on sample bottles? Yes ❑ No❑ Not Present �J Samples in proper container/bottle? Yes C' No❑ Were correct preservatives used and noted? Yes C No❑ NA ❑ Preservative added to bottles: Sample Condition? Intact Broken❑ Leaking Sufficient sample volume for indicated test? Yes Fe No❑ Were container labels complete(ID,Pres,Date)? Yes C No❑ All samples received within holding time? Yes C No❑ Was an attempt made to cool the samples? Yes C No❑ NA All samples received at a temp.of>0°C to 6.0`C? Yes No ❑ NA _I Response when temperature is outside of range: Sample Temp.taken and recorded upon receipt? Yes No❑ 0.3 To 1.8'- Water-Were bubbles absent in VOC vials? Yes '❑ No❑ No Vials Water-Was there Chlorine Present? Yes J No❑ NA Water-pH acceptable upon receipt? Yes L'VI No ❑ No Water U Are Samples considered acceptable? Yes ❑ No❑ Custody Seals present? Yes ❑ No E Airbill or Sticker? Air Bill ❑ Sticker ❑ Not Present Airbill No: Case Number. SDG: SAS: LK6009 i I I Any No response should be detailed in the comments section below,if applicable. -------------- ------------------------------ — - — — -- Client Contacted? ❑ Yes ❑ No NA Person Contacted: Contact Mode: ❑ Phone: ❑ Fax: ❑ Email: F-1In Person: Client Instructions: Date Contacted: Contacted By: Regarding: Comments: CorrectiveAction: Page 1 of 1 LKB009 S9 i I INTERNAL CHAIN OF CUSTODY CLIENT: 414 ZI Jp DELIVERABLES: `(l} TURNT AROUND TIME: L cl�J 3 " 1 SDG: L�CASE#: MATRIX: pH CHEC Y r N REMARKS: 1 RECEIVED BY: SIGNATURE:. DATE:3bTIME: CLIENT V DATE BOTTLE #OF SAMPLE LAB# TESTS REQUESTED ID COLLECTED TYPE BOTTLES o" f1tv ,. y -2. 3 � J `ctti �c S 6. 7. 10. 12. 14. S I6. 16. 17. 18. 19. 20. L001 r1 METALS 75 LKB009 S10 0.': 7 • CLIENT: SDG: Ah Oa I INTERNAL CHAIN OF CUSTODY _`r I I SAMPLE SAMPLE BOTTLE POSE OF DATE TIME CHANGE OF RELINQUISHED BY RECEIVED BY TYPE CUSTODY h'. lly I� FI I I' I 2, �y f L001_r1 METALS 76 i - ---- -- -- LKB009 S11 r TERNAL CHAINT OF CUSTODY CLIENT: 13 DELIVERABLES: &j 96.0 TURN AROUND TIME:lLpAiS SDG: G—/l U�� CASE#: MATRIX: �'�L✓ pH CHECX6�or N REMARKS: RECEIVED BY:(j!) SIGNATURE: ��ivG (v�/ DATE L" IME: CLIENT DATE BOTTLE OF SAMPLE LAB# COLLECTED TYPE BOTTLES TESTS REQUESTED ID SAIMw 1. W -W 11q- wN jam.�S�t z. -T--o g3 4s 4. 6. 7. Ll � 9. G _ _ 10.11. 12. G U 14. V { 15. _0 �Z 17. _ c l8. 19. 20. L001-r1 WET CHEMISTRY 123 LKB009 S12 tk�CLIENT: INTERNAL CHAIN OF CUSTODY SAMPLE SAMPLE BOTTLE POSE OF DATE TIME CHANGE OF INIT. RELINQUISHED BY RECEIVED BY TYPE CUSTODY 3 1 , s r i i i • L001-r1 WET CHEMISTRY 124 „, r LKB009 S13 ace Long Island i 575 Broad!-Hollow Road i,: 031 694.3040 Melville,(VY 11747 H 631 420,8436 i 3. SDG NARRATIVES i • LK6009 S14 a06 Lo,g/slend I SDG NARRATIVE FOR METALS ANALYSES SAMPLE(S)RECEIVED: 3/28/14 SDG#: LI B009 For Sample(s): MW-1D MW-5S MW-1S MW-6D MW-31) MW-6S MW-3S MW-7S MW-4D 1\4W-8D MW-4S MW-8S MW-5D Sample(s)was/were received by Pace Analytical Services, Inc. for select metals analysis. Samples were prepared and analyzed using EPA method 6010C with a TS ICAP 6000 instrument. Sample MW-1D was utilized for Q.C. analysis and reporting. • The spike analysis did not meet acceptance criteria for cadmium. The sample was post spiked, reanalyzed and recovered at 129%. Cadmium data was reported flagged"N"on forms 1 and 5A. Due to matrix interferences sample MW-3S required a 1:10 dilution for lead. The lead reporting limit was elevated as required. No other issues were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: April 29, 2014 Vincent Stancampiano • LKB009 S16 • Ree Long Island i SDG NARRATIVE FOR WET CHEMISTRY SAMPLE(S)RECEIVED: 3/28/14 SDG#: LKB009 For Sample(s): MW-1D MW-4S MW-7S MW-1S MW-5D MW-8D MW-3D MW-5S MW-8S MW-3S MW-61) MW-4D MW-6S Samples)was/were received by Pace Analytical Services, Inc for select wet chemistry analysis. Samples were prepared and analyzed using the following methods: Alkalinity SM2320B Nitrate EPA 353.2 Anions—Cl, SO4,Br EPA 300.0 Nitrite EPA 353.2 Biochemical Oxygen Demand SM5210B Phenols EPA 420.1 Chemical Oxygen Demand EPA 410.4 Total Dissolved Solids SM2540C Ammonia SM4500-NH3 H Total Kjeldahl Nitrogen EPA 351.2 Hardness SM2340C Total Organic Carbon SM5310B • Samples utilized for Q.C. analysis were listed on the Q.C. summary report.. The BOD oxygen blank depletion was greater than 0.2 mg/1 (0.39 mg/1). This was noted on the final reports. Due to matrix interferences sample MW-61) required a 1:5 dilution for ammonia. The reporting limit was elevated to<0.50 mg/1 as required. Samples were diluted and reanalyzed as required to keep instrument readings within calibration ranges or to minimize matrix interferences. No other issues were noted during the analysis of this sample group. I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or his designee, as verified by the following signature. Date Reported: May 6, 2014 • Vincent Stancampiano LKB009 S16 ace Lang/s/8,7d 575 Broad Hollcvv Road 611,694.3040 Melville NY 11747 631.4201.8436 4. SAMPLE REPORTS 4.1 METALS 4.2 WET CHEMISTRY LKB009 S17 i .0 ace Long Island 575 Broad Hollow Road <cd 631.694.3040 Melville,NY 11747 4, 9-31.420.8436 4.1 METALS LKB009 S18 • aOLang/stand i 575 Broad Hollow Road tel. 631.694.3040 Melville,NY 11747 fax.631.420.8436 QUALIFIERS FOR METALS ANALYSIS Q (Quality Control) Qualifiers E - Serial dilution is not within acceptance criteria or the reported value is estimated because of the presence of interference. An explanatory note is included in the SDG narrative. N - Matrix spike sample recovery not within control limits. * - Duplicate analysis is not within control limits. C (Concentration) Qualifiers B - Entered if the reported value is less than the Contract Required Detection • Limit (CRDL) but greater than the Instrument Detection Limit (IDL). U - Entered if the analyte was analyzed for but not detected, i.e., less than the IDL. M (Method) Qualifiers P - Analyzed by ICP. MS - Analyzed by ICP-MS CV- Analyzed by Manual Cold Vapor techniques. AV - Analyzed by Automated Cold Vapor techniques. C - Analyzed by Manual Spectrophotometric Method. CA- Analyzed by Midi-distillation Spectrophotometric Method. NR - Analyte not Required. • LK6009 S19 • U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET � MW-1D Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LKB009 Matrix (soil/water) : WP:TER Lab Sample ID: 1403J57-001 Level (lew/med) : LOW Date Received: 3/28/2014 % Solids: 0.0 Concentration Units (ug/L or mg/kg dry we_grt) : UG/L CAS No. Analvte Concentration C Q N 7440-43-9 !Cadmium 0.11 U N P 7440-70-2 ,Calcium 31200 P 7439-89-6 Iron 101 P 7439-92-1 Lead 19.9 _ P 7439-95-4 Magnesium 149 0 P i 7439-96-5 Manganese 2.3 3 P 7440-09-7 Potassium __ 1930 3 P 7440-23-5 Sodium 19500 �P I • Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported 4/25/2014 • FORM I - IN ILM04.1 LKB009 S20 • U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET 17'v�-1S Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LKB009 Matrix (soil/water) : WATER Lab Sample ID: 1403J57-002 Level (low/med) : LOW Date Received: 3/28/2014 Sclids: 0.0 Concentration Units (ug/L or mg/kg dry weight) 1-0/L CAS No. Analy-e Concentration Ci Q M 7440-43-9 Cadmium 0.11 U N F 0-70-2 Calcium 7410 F Iron 56.5 B 74140-70-2 P 7439-92-1 Lead 11.9 P ;7439-95-4 Magnesi.lm 4300 B P 7439-96-5 Manganese 24.1 F 744-0-09-7-- Pssium 38401B -------- - ota- 7440-23-3 Sodium 12600] • Color Before_ COLORTFSS C-a-ity Before: CLEAR Texture: Color After: COLORLESS Clarity Atter: CLEAR Artifacts: Comments: Date Reported 4/25/2014 7-0RM I - IN iLM04 .1 LKB009 S21 • U.S. EPA - CL? 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW-3D I, Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LKB009 '_Matrix (soil/water) : WATER Lab Sample ID: 1403J57-003 Level (low/med) : LCW Da:e Received: 3/28/2014 Solids: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/:. ----------- CAS No. Analyte Concentration C ' Q M� 7440-43_-9 l�:�admiun 2.0 B N P 7440-70-2 Calcium 39000 P r--- 7439-89-6 Iron 292002, P 7439-92-1 Lead 5.3, P 17439-95-4 Magnesium 2 7439-96-5 Mangane e -F _ 3560 - P - - - 7440-09-7 Potassium _ _ 68300 P 7440-23-5 — - 30 Scdi�n 1030 � 00 P Color Before: COLORLESS Clarity Before: CTFAR Texture: Color After: YELLOW C-arity After: CLEAR ArtifacLs: Comments: Date Reported 4/25/2014 • FORM I - IN ILM04.1 LKB009 S22 • U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET -3S Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LKB009 Matrix (soil/water) : WATER Lab Samp-e T_D: 1403J57-004 Level (low/med) : LOW Date Received: 3/28/2014 Solids: 0.0 Concentration Units (ug/L or mg/kg dry we-'grt) : UG/L CAS No. i Analyte ( Concentration C Q M 7440-43-9 Cadmium4. 9, B N P 7440-70-2 Calcium 2670C---� _--— P- x7439-89-6 Iron 72400! P 7439-92-1 Lead 19.5 UP 7439-95-4 Magnesium --- 1700 — ----- P 7439-96-5 Manganese 4480 I P 17440-09-7 Potassium 20200 P 7440-23-5 (Sodium 39400 P • Color Before_ COLORI,RSS Clarity Before: CLEAR Texture: Color After: YELLOW Clarity After: CLEAR Artiiac--s: Comments: Date Reported 4/25/2014 FORM I - IN ILM04. LKB009 S23 • U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANAL`_'SIS DATA SHEET --� E:7MW�-4C Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LKB009 Matrix (soil/water) : WATER Lab Sample ID: 1403J57-005 Level (_ow/med) : LOW Date Received.: 3/28/2014 Scli•ds: 0. 0 Concentration Units (ug/L or mg/kg dry weight) : UG/L l I ' AS No. Analyte Concentration C Q M 7440-_4_3 i _-9 Cadmum 0.11; D N P 7440-70-2 Calcium 14000_0 P 7439-89-6 lIron 526 P 7439-92-1 Lead --- -- - - 15.5 - ----P. 7439-95-4 Magnesii-m 60400' P 7439-96-5 Manganese 37401 p 7440-09-7 Potassium 55900 _---- - P 7440-23-5 ,Sodium — 194000 P -- • Color Before: COLCRLESS Clari_y Before: CLEAR Texture: Color After: COLORLESS Clari'Ly AfLer: CLEAR Artifacts: Comments: Date Reported 4/25/2014 FORM I - IN ILM04.1 LKB009 S24 • U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DA"A SHEET MW-4S Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LKB009 Natr--x (soil/water) : WATER Lab Sample ID: 1403J57-006 Level (low/med) : LCW Date Received: 3/28/2014 Solids: O.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L t CAS No. Ana-_ _vte : Concentration C Q M 1- 7440-43-9 Cadmium 0.30 BI N P 17440-70-2 (Calci,—,n 7910_0_ _ P B 17439-89-6 ,Iron 16.9 439-92-1 :Lead 5.0 Bi P 7439-95-4 jMagnesium 18100 1 P 7439-96-5 !Manganese 5720!1 --T___ 7440-09-7 Potassium 393001 P 7440-23-5 'iSodiuir 10700 - P- Color Before: COLORLESS Clarity Before: CLEAR _ Textl.r_e: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported 4/25/20.14 FORM I - IN ILM04. 1 LKB009 S25 • U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW-5D Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SCG No. : LKE009 Matrix (soil/water) : WATER Lab Sample ID: 1403J57-007 Level ;low/med) : LOW Date Received: 3/28/2C14 % Solids: 0.0 Concentration Units (uc/L or mg/kg dry weight) : UG/L CAS Nc. Analyte Cor-centration C Q M 7440-43-9 iCadmiam- - --_— 0.111 U N P 7440-70-2 (,Calcium 793001 P 7439-89-6 Iron 130 P 7439-92-1 Lead 1.9 U P 7439-95-4 Magnesium 31600 P 7439-96-5 Manganese 11800, P 7440-09-7 Potassium -_—— 110000 P 7440-23-5 Sodium 1330001 P Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported 4/25/2014 FORM I - IN ILM04.1 LKB009 S26 U.S. EPA - CLP 1 EPA SAN_PLE NO INORGANIC ANALYSIS DATA SHEET MW-5S Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LKED09 Matrix (soil/water) : WATER Lab Sample ID: 1403J57-008 Level (low/med) : LOW Date Received: 3/28/2014 s Solids: 0.0 Concentration Units (ug;L or mg/kg dry weight) : UG/L CAS No. Analyte Concentra ion C Q M 7440-43-9 'Cadmium 0.20 B N P 7440-70-2 'Calcium 9610 - - ---P 7439-89-6 ;Iron 27.61 BI P 7439-92-i L ad 10.41_ ,- P 7439-95-4 jMagnesium 5Cicl P 7439-96-5 ,Manganese F 364 P 7440-09-7 'Potassium 4780 3 �i, t P 7440-23-5_Sodiam _ 8330 P Color Before_COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported 4/25/2014 -ORM I - IN ILM04. 1 LKB009 S27 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW-6D Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. S'1S No. : SDG No. : LKB009 Matrix (soil/water) : WATER Lab Sample ID: 1403J57-009 Level (low/med) : LOW Date Received: 3/28/2014 % Solids: 0. 0 Ccncentration Units (ug/L or mg/kg dry weight) : UG/L CAS No. Analyte Concentra-_' on C i M 7440-43-9 Cadmium - --- -0.20 B N P 7440-70-2 Calci= 35800 _ P 17439-89-6 Iron 67.61 B P 7439-92-1 -ead 15.91 - - - P 7439-95-4 Maqnesium _ 17200', 7439-96-5 Manganese i _ 1'20 P 7440-09-7 Potassium- 3120 Bj P 7440-23-5 Sodium 16300 — `P • Color Before: COLORT,RSS Clarity Before: CLEAR. Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reported 4/25/2014 , • - ------------------ FORK I - IN ILM04 .1 LKB009 S28 • U.S. EPA - CLP 1 EPA SAN_PLE NO INORGANIC ANALYSIS DATA SHEET Mw-6S i Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LKB009 Matrix (soil/water) : `NATER Lab Sample ID: 1403J57-010 Level (lewimed) LOW Date Received: 3/28/2014 E Solids: 0.0 Concentration Units (ug//L or mg/kg dry :,eight) : UG/L CAS No. Analyte Concentration C Q M I 7440-43-9 ICadmiu-n 0.201 B N P 7440-70-2 Calcium 13200' -- F 7439-89-6 Iron 220 17439-92- Lead 1C P 7439-95-44 Magnesium 499C B �Ph 17439-96-5 Manganese 2920 T P F440-09-7 Potassium 4470 B F 7440-23-5 Sodium 6340 F • Color Before_ COLORI,P;SS Clarity Before: CLEAR Texture: - Color After: COLORLESS Clarity After: CLEAR Artifacts: Commen:s: Date Reported 4/25/2014 FORM I - IN IL1,104.1 LKB009 S29 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET — 7MW-7S Lab Name: PACE -ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LKB009 Matrix (soil/water) : WATER, Lab Sample ID: 1403J57-011 Level (low/ned) : LOW Date Received: 3/28/2014 Sol-ids: 0.0 Concentration snits (ug/L or mg/kg dry weight) : UG/L CAS No. Analyte Concentration Q yI 7440-43-9 Cadmi= 0.30 B N P 17440-70-2 Calcium 73600 17439-89-6 Iron 21.9', B P 7439-92-1 Lead _ 3.44 B , P 7439-95-4 iMagnesium 16700 1 P 7439-9G-5 Manganese 5330 P 7440-09-7 (Potassium 36600 P 7440-23-5 Sodium 10000 P • Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: COLORLESS Clarity After: CLEAR Artifacts: Comments: Date Reperted 4/25/2014 FORM I - 1N ILM04.1 LKB009 S30 U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANA=,YSIS DATA SHEET MW-8D Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LK3009 Matr-x (soil/wa`er) : WATER Lab Sample ID: 1403J57-012 Leve_ (low/med) : LOW Cate Received: 3/28/2014 So-- -'ds: 0.0 Concentration Units (ug/L or mg/kg dry weiaht) : UG/L CAS No. Analyte Concentration C Q M 117440-43-9 Cadmium 0.70 B N P 17440-70-2 ICalcium 5"1 P :7439-89-6 Iron10400 7439-92-1 Lead_ - 1.7.1 P ;7439-95-4 N-agnesium27800 �P -- -- - - 7439-96-5 Ianganese 1570 P- 7440-09-7 Potassium 49400 P 7440-23-5 Sodium 58600 P • Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: YELLOW Clari-y Af-er: CLEAR Artifacts: Comments: Date Reported 4/25/2014 • FORM I - IN ILM04.1 LKB009 S31 • U.S. EPA - CLP 1 EPA SAMPLE NO INORGANIC ANALYSIS DATA SHEET MW-8S Lab Name: PACE ANALYTICAL Lab Code: 10478 Case No. SAS No. : SDG No. : LKB009 Matrix (scil/water) : WATER Lab Sample ID: 14C3J57-013 Level (low/med) : LOW Date Received: 3/28/2014 % Solids: 0. 0 Concentration Units (ug/L or mg/kg dry weigh-) : UG/L CAS No. TAnalyte Concetration C Q M r_ 7440-43_-9 Cadmium - — _ 2.2 B N P 7440-70-2 Calcium 48200 - — P 7439-89-6 1Iror ---- 33300 - P- 7439-92-1 (Lead 1.91 L P 7439-95-4 Magr_esiw-n _ 16600( P 7439-96-5 IMancanese 3521 P 7440-09-7 Potassium 438001 P i 7440-23-5 Sodium 22000 P • Color Before: COLORLESS Clarity Before: CLEAR Texture: Color After: YELLOW Clarity After: CLEAR Ar-ifacts: Comments: Date Reported 4/25/2014 • FORM I - .N ILM04.1 LKB009 S32 i ace long Island 575 Broad Hollow Road i 631.594.3043 [Aelvrle,NY;1741 e3'; 420.84?6 4.2 WET CHEMISTRY • LKB009 S33 • aC16Ana1j&a1� LABORATORY RESULTS Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 The lab is not directly responsible for the integrity of the sample before receipt at TEL:(631)694-3040 FAX:(631)420436 j• the lab and is responsible onlyfor the certified tests requested. NYSDCH 113#10478 wwv.oacelabs.com Lockwood Kessler&Bartlett One Aerial Way Sample Information: Lab No. : 1403J57-001 Type: Groundwater Syosset,NY 11791 Client Sample ID: MW-ID Attn To : John Gerlach Collected :3/27/2014 3:40:00 PM Origin: Received :3128/2014 10:40:00 AM Collected By CLIENT Analytical Method: SM2320B: Analyst: JDLR Parameters) Results Ouglifier D;F. Units Anal Container: Alkalinity,Total(As CaCO3) 24.1 1 mg/L 03/31/2014 1:27 PM Container-01 of 02 Analytical Method: E300.0: Analyst: bka Parameters) Results ualifierD_F. Uni s Analyzed: Container: Bromide <0.50 1 mg/L 04/07/2014 9:12 PM Container-01 of 02 Chloride 30.4 1 mg/L 04/07/2014 9:12 PM Container-01 of 02 Sulfate 86.5 D 5 mg/L 04/07/2014 9:26 PM Container-01 of 02 Analytical Method: SM52106: Prep Method: SM6210B Prep Date:3/28/2014 11:28:13 AM Analyst: VaS Parameters) Results Qualifier D.F. Units Analyzed: Container: Biochemical Oxygen Demand <2 1 mg/L 03/28/2014 2:15 PM Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.39 mg/L Analytical Method: E410.4: Analyst: CN Parameters) Results Qualifier D.F. Units Analyzed: Container: Chemical Oxygen Demand <10.0 1 mg/L 04/07/2014 7:54 AM Container-01 of 01 Analytical Method: SM234OC: Analyst: JA Parameters) Results Qualifier D.F. Units Analyzed: Container: Hardness(As CaCO3) 120 D 10 mg/L 04/07/2014 2:00 PM Container-01 of 01 Analytical Method: SM4500-NH3 H: Analyst bka Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrogen,Ammonia(As N) <0.10 1 mg/L 04/09/2014 2:28 PM Container-01 of 01 Analytical Method: E353.2: Analyst EM Parameters) Results 0 u life r P.F.. Units Analyzed: Container. Nitrite as N <0.10 1 mg/L 03/29/2014 7:27 AM Container-01 of 02 Analytical Method: E353.2: Analyst EM Parameters) Results Qualifier D.F.. Units Analyzed: Container. Nitrate as N 5.21 D 10 mg/L 03/29/2014 8:13 AM Container-01 of 01 Analytical Method: E420.1 : Prep Method: E420.1 Prep Date:4/3/2014 5:00:00 AM Analyst EM Parameters) Results Qualifier D.F.. Units Analyzed: Container. Phenolics,Total Recoverable <5.0 1 pg/L 04/07/2014 9:22 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank # 4n , — D.F.=Dilution Factor D=Results for Dilution H=Receivedlanalyzed outside of analytical holding time Client Services Manager +=ELAP/NE LAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. • S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 1 of 26 LKB009 S34 /!;CIC71 � 1 [ 'p LABORATORY RESULTS / Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 t1 TEL:(631)694-3040 FAX:(631)420.8436 The lab is not directly responsible forthe integrity of the sample before receipt at i NYSDOH ID#10475 w�wv.oacala5s.com the lab and is responsible only for the certified tests requested. i Lockwood Kessler&Bartlett One Aerial Way Sample Information: Syosset,NY 11791 Lab No. : 1403J57-001 Type: Groundwater Attn To John Gerlach Client Sample ID: MW-1D Collected :312712014 3:40:00 PM Origin: Received :3/28/2014 10:40:00 AM Collected By CLIENT Analytical Method: SM254OC:IOC Analyst: CO Parameters) Results ualifierD_F. Units Analyzed: Container: Total Dissolved Solids 229 1 mg/L 03/3012014 10:26 AM Container-01 of 02 Analytical Method: E351.2: Prep Method: E351.2 Prep Date:4/8/2014 5:15:00 AM Analyst: TF Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrogen,Kjeldahl,Total 0.46 1 mg/L 04/06/2014 12:47 PM Container-01 of 01 Analytical Method: SM531OB: Analyst: CO Parameters) Results ualifier D_F. Units Analyzed: Container: Total Organic Carbon <1.0 1 mg/L 04/02,12014 8:22 PM Container-01 of 02 i Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 2 of 26 LKB009 S35 LABORATORY RESULTS Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 The lab is not directly responsible for the integrity of the sample before receipt at TEL:(631)894-3040 FAX:(831)420-8438 j the lab and is responsible only for the certified tests requested. i NYSDOH ID#10478 www.oacelabs.com Lockwood Kessler&Bartlett Sample Information: One Aerial Way Syosset,NY 11791 Lab No. : 1403J57.002 Type: Groundwater Attn To : John Gerlach ClientSamplelD: MW-1S Collected :3/27/2014 3:20:00 PM Origin: Received :3/28/2014 10:40:00 AM Collected By CLIENT Analytical Method: SM2320B: Anal : JOLR Parameterfs) Results Qualifier D.F. Units Analyzed: Container. Alkalinity,Total(As CaCO3) 4.45 1 mg/L 03131/20141:37 PM Container-01 of 02 Analvdcal Method: E300.0: Anal : bka Parameterfs) Results Qualifier D_F. Units Analyzed: Con finer: Bromide <0.50 1 mg/L 04/07/2014 9:39 PM Container-01 of 02 Chloride 24.8 1 mg/L 04/07/2014 9:39 PM Container-01 of 02 Sulfate 17.4 1 mg/L 04/07/2014 9:39 PM Container-01 of 02 Analytical Method: SM5210B: Prep Method: SM5210B Prep Date:3128/2014 11:28:13 AM Analyst: VaS Parameterfs) Results Qualifier D.F. Units Analyzed: Container: Biochemical Oxygen Demand <2 1 mg/L 03/28/2014 2:20 PM Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.39 mg/L Analyllcal Method: E410.4: Analyst: CN Parameterfs) Results Qualifier D.F.. Units Analyzed: Container: • Chemical Oxygen Demand <10.0 1 mg/L 04/07/2014 7:56 AM Container-01 of 01 Analytical Method: SM2340C: Analyst: JA Parameterfs) Results Qualifier D.F.. Units Analyzed: Container: Hardness(As CaCO3) 32 D 2 mg/L 04/07/2014 2:05 PM Container-01 of 01 Analytical Method: SM4500-NH3 H: Analyst: bka Parameterfs) Results Qualifier D.F.. Units Anatyzed: n to r. Nitrogen,Ammonia(As N) <0.10 1 mg/L 04/09/2014 2:29 PM Container-01 of01 Analvbcal Method: E353.2: Analyst: EM Parameterfs) Results Qualifier Q. Units Analyzed: Container: Nitrite as N <0.10 1 mg/L 03/29/2014 7:31 AM Container-01 of 02 Analytical Method: E353.2: Analyst: EM Parameterfs) Results Clualifier D_F. Units Analyzed: Container. Nitrate as N 2.84 D 5 mg/L 03/29/2014 8:17 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date:4/3/2014 5:00:00 AM Analyst: EM Parameterfs) Results Qualifier D.F. Units Analyzed: Container. Phenolics,Total Recoverable <5.0 1 Ng/L 04/0712014 9:23 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank # 4,- D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 3 of 26 LKB009 S36 • C, tj ifd�l LABORATORY RESULTS �+ _ Results for the samples and analytes requested 575 Broad Hollow Road, MelNlle,NY 11747 TEL(631)694-3040 FAX:(631)420.8436 The lab is no:directly responsible for the Integrity of the sample before receipt at the lab and is resaonsibie only for the certified tests equested. i NYSDOH ID#10478 www.r)acelabs.com Lockwood Kessler&Bartlett One Aerial Way Sample Information: Lab No. : 1403J57-002 Type: Groundwater Syosset,NY 11791 MW-1S Attn To John Gerlach Client Sample ID: Collected :3/27/2014 3:20:00 PM Origin: Received :3/28/2014 10:40:00 AM Collected By CLIENT Analytical Method: SM2540C:IOC Analyst: CO Parameters} Results Qualifier D.F. Units Analyzed: Container Total Dissolved Solids 91 1 mg/L 03/30/2014 10:32 AM Container-01 of 02 AnalWcal Method: E351.2: Prep Method: E351.2 Prep Date:4/8/2014 5:15:00 AM Analyst TF Parameters} Results Qualifier D.F. Units Analvzed: Container: Nitrogen,Kjeldahl,Total 0.54 1 mg/L 04/08/2014 12:48 PM Container-01 of 01 Analvtical Method: SM531 OB: Analyst CO Parameters} Results Qualifier Q. Units Analyzed: Container: Total Organic Carbon <1.0 1 mg/L 04/02/2014 8:44 PM Container-01 of 02 • Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. • S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 4 of 26 LKB009 S37 • 1!;aC16Ana1ytjca1 LABORATORY RESULTS Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 TEL(631)694-3040 FAX(631)420-8436 The lab Is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the cerdfed tests requested. NYSDOH ID#10478 www.oacelabs.00m Lockwood Kessler&Bartlett One Aerial Way Sample Information: Lab No. : 1403J57-003 Type: Groundwater Syosset,NY 11791 Client Sample ID: MW-3D Attn To John Gerlach Collected :3/27/2014 8:20:00 AM Origin: Received :3/28/201410:40:00 AM Collected By CLIENT Analytical Method: SM2320B: Anaivst: JDLR Parameters) Results Qualifier D.F.. Units Analyzed: Container: Alkalinity,Total(As CaCO3) 489 D 10 mg/L 03/31/2014 1:42 PM Container-01 of 02 Analytical Method: E300.0: Analyst bka Parameters) Results gualifier D_F. Units Analyzed: Container: Bromide <0.50 1 mg/L 04/07/2014 9:53 PM Container-01 of 02 Chloride 138 D 5 mg/L 04/07/2014 10:06 PM Container-01 of 02 Sulfate 36.7 1 mg/L 04/07/2014 9:53 PM Container-01 of 02 Analytical Method: SM521OB: Preo Method: SM5210B Preo Date:3/28/2014 11:28:13 AM Analyst VaS Parameters) Results Qualifier D.F.. Units Analyzed: Container: Biochemical Oxygen Demand <2 1 mg/L 03/28/2014 2:25 PM Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.39 mg/L Analytical Method: E410.4: Analyst: CN Parameters) Results Qualifier D.F. Units Analyzed: Container: Chemical Oxygen Demand 52.7 1 mg/L 04/07/2014 7:58 AM Container-01 of 01 Analytical Method: SM2340C: Analyst: JA Parameters) Results Qualifier D.F. Units Analyzed: Container: Hardness(As CaCC3) 180 D 10 mg/L 04/07/2014 2:10 PM Container-01 of 01 Analvtical Method: SM4500-NH3 H: Analyst bka Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrogen,Ammonia(As N) 65.9 D 50 mg/L 04/09/2014 2:31 PM Container-01 of 01 Analytical Method: E353.2: Analyst: EM Parameters) Results ualifier Q. Units Analyzed: Container: Nitrite as N <0.10 1 mg/L 03/2912014 7:32 AM Container-01 of 02 Analytical Method: E353.2: Analyst: EM Parameterfs) Results Qualifier D_F. Units Analyzed: Container: Nitrate as N <0.10 1 mg/L 03/29/2014 8:18 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Preo Date:4/3/2014 5:00:00 AM Analyst EM Parameters) Results Qualifier D. Units Analyzed: Container: Phenolics,Total Recoverable <5.0 1 pg/L 04/07/2014 9:24 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. n 8=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 5 of 26 LKB009 S38 • ac6Ana1j4ca1,a LABORATORY RESULTS Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 TEL:1631)6l FAX:(63'I)420-6436 The lab Is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certifed tests requested. NYSDOH ID#10478 www.pacelabs.com Lockwood Kessler&Bartlett Sample Information: One Aerial Way Lab No. : 1403J57-003 Type: Groundwater Syosset,NY 11791 Client Sample ID: MW-30 Attn To John Gerlach Collected :3/27/2014 8:20:00 AM Origin: Received :3/28/2014 10:40:00 AM Collected By CLIENT Analytical Method: SM254OC:IOC Analyst: CO Parameterfs) Results Qualifier D.F. Units Analyzed: Container: Total Dissolved Solids 528 D 2 mg/L 03/30/2014 10:34 AM Container-01 of 02 Analytical Method: E351.2: Prep Method: E351.2 Prep Date:4/8/2014 5:15:00 AM Analyst: TF Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrogen,Kjeldahl,Total 75.0 D 20 mg/L 04108/2014 12:49 PM Container-01 of 01 Analytical Method: SM531OB: Analyst: CO Parameters) Results Qualifier 2.F. Units Analyzed: Container: Total Organic Carbon 19.5 1 mg/L 04/0212014 9:06 PM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. / n B=Found in Blank --- D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Repotted: 5/7/2014 Page 6 of 26 LKB009 S39 • ?C1 f�[jm LABORATORY RESULTS j Results for the samples and analytes requested 575 Broad Hollow Road. Melville,NY 11747 The lab Is not directly responsible for the Integrity of the sample before receipt at TEL:(831)694-3040 FAX(631)420-6436 j' the lab and is responsible only for the certified tests requested. NYSDOH ID#10478 www.pacelabs.com Lockwood Kessler&Bartlett Sample Information: One Aerial Way Syosset,NY 11791 Lab No. : 1403J57-004 Type: Groundwater Attn To John Gerlach Client Sample ID: MW-3S Collected .3/27/2014 9:15:00 AM Or gin: Received :3/28/2014 10:40:00 AM Collected By CLIENT Analytical Method: SM2320B: Analyst: JDLR Parameters) Results Qualifier D.F. Units Analyzed: Container: Alkalinity,Total(As CaCO3) 185 D 10 mg/L 0313l/2014 1:50 PM Container-01 of 02 Analytical Method: E300.0: Ana t• bka Parameters) Res I s gualifier D_F. Units Analyzed: Container: Bromide <0.50 1 mg/L C4/07/2014 10:20 PM Container-01 of02 Chloride 87.1 D 5 mg/L 04/07/2014 10:33 PM Container-01 of 02 Sulfate 47.9 1 mg/L 04/07/2014 10:20 PM Container-01 of 02 Ana"cal Method: SM521OB: Prep Method: SM5210B Prep Date:3/28/2014 11:28:13 AM Analyst: VaS Parameters) Results Qualifier D.F. Units Analyzed: Container: Biochemical Oxygen Demand 5 1 mg/L 03/28/2014 2:30 PM Container-0I of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.39 mg/L Analytical Method: E410.4: Analyst: CN Parameters) Results Qualifier D.F. Units Analyzed: Container: Chemical Oxygen Demand 31.8 1 mg/L 04/07/2014 8:00 AM Container-01 of 01 Analytical Method: SM2340C: Analyst: JA Parameters) Results Qualifier D.F.. Units Analyzed: Container Hardness(As CaCO3) 130 D 10 mg/L 04/07/2014 2:15 PM Container-01 of 01 Anah4cal Method: SM4500-NH3 H: Analyst bka Parameters) Results Qualifier D.F.. Units Analyzed: Container: Nitrogen,Ammonia(As N) 14.1 D 10 mg/L 04/09/2014 2:32 PM Container-01 of 01 Analytical Method: E353.2: Analyst: EM Parameters) Results Qualifier D.F.. Units Analyzed: C n in r. Nitrite as N <0.10 1 mg/L 03/29/2014 7:33 AM Container-01 of 02 Analytical Method: E353.2: Analyst: EM Parameterfs) Results Qualifier D.F. Units Analyzed: Container. Nitrate as N <0.10 1 mg/L 03/29/2014 8:19 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date:4/3/2014 5:00:00 AM Analyst EM Parameters) Results Qualifier D.F. Units Analyzed: Container. Phenolics,Total Recoverable <5.0 1 pg/L 04/07/2014 9:25 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank # 4-- D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. • S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Repotted: 5/7/2014 Page 7 of 26 LKB009 S40 • ,Mnalica � LABORATORY RESULTS Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 � TEL:(631)694-3040 FAX:(631)42C-8436 The lab is not directly responsible for the icey of the sample before receipt at the lab and is responsible only for the certifiedd tests requested. NYSDOH 0910478 www.nacelabs.com Lockwood Kessler 8r Bartlett Way Sample Information: One Aerial11791 Lab No. : 1403J57-004 Type: Groundwater Syosset, Attn To : John Gerlach Client Sample ID: MW-3S Collected :3/2712014 9:15:00 AM Origin: Received :3/2812014 10:40:00 AM Collected By CLIENT Analytical Method: SM2540C:IOC Analyst CO Parameters) Results ualifier D_F. Units Analyzed: Container. Total Dissolved Solids 342 1 mg/L 03/30/2014 10:36 AM Contalner-01 of 02 Analytical Method: E351.2: Prep Method: E351.2 Preo Date:4/8/2014 5:15:00 AM - Analyst: TF Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrogen,Kjeldahl,Total 17.7 D 10 mg/L 04/08/2014 12:50 PM Container-01 of 01 Analvtical Method: SM53106: Analyst: CO Parameters) Results Qualifier D.F. Units Analyzed: Container. Total Organic Carbon 7.4 1 mg/L 04/02/2014 9:28 PM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. • S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 8 of 26 LKB009 S41 • aG,�f-1+r 'j F#ical'. LABORATORY RESULTS j _ `i Results for the samples and analytes requested 575 Broad Hollow Road. Melville,NY 11747 TEL:(631)6943040 FAX:(631)420-8436 The lab is not directly responsible for the integrity of the sample before receipt at � trie lab and is responsible only for the certified tests requested. i NVSDOH IDtF10478 wm^t.oacelabs.com Lockwood Kessler&Bartlett Aerial Way Sample Information: One 11791 Lab No. : 1403J57-005 Type: Groundwater Syosset Attn To : John Gerlach Client Sample ID: MWD Collected :3/2712014 11:30:00 AM Origin: Received :3/2812014 10:40:00 AM Collected By CLIENT Analvdcal Method: SM23208: Analyst JDLR Parameters) Results Qualifier D.F. Units Analyzed: Container. Alkalinity,Total(As CaCO3) 678 D 10 mg/L 03/31/20141:58 PM Container-01 of 02 Analytical Method: E300,0: Analyst, bka Parameters) Results Qualifier D.F. Units Analyzed: Container. Bromide 1.71 1 mg/L 04/07/2014 11;14 PM Container-01 of 02 Chloride 177 D 5 mg/L 04/07/2014 11:27 PM Container-01 of 02 Sulfate 91.4 D 5 mg/L 04/10/2014 12:22 AM Container-01 of 02 Analytical Method: SM521 OB: Preo Method: SM5210B Prep Date:3/28/2014 11:28:13 AM Analyst: VaS Parameters) Results Qualifier D.F. Units Analyzed: Container: Biochemical Oxygen Demand <2 1 mg/L 03/28/2014 2:35 PM Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.39 mg/L Analytical Method: E410.4: Analyst: CN Parameters) Results Qualifier D.F.. Units AnabZQdIll Container: Chemical Oxygen Demand 57.8 1 mg/L 04/07/2014 8:02 AM Container-01 of 01 Analytical Method: SM2340C: Analyst: JA Parameters) Results Qualifier D.F. Units Analyzed: Container: Hardness(As CaCO3) 600 D 50 mg/L 04/07/2014 2:20 PM Container-01 of 01 Analvtical Method: SM4500-N H3 H: Analyst: bka Parameters) Results Qualifier D.F. Units Analyzed: Container. Nitrogen,Ammonia(As N) 27.2 D 25 mg/L 04/0912014 2:33 PM Container-01 of 01 Analytical Method: E353.2: Analyst: EM Parameters) Results Qualifier D.F. Units Analyzed: Container. Nitrite as N <0.10 1 mg/L 03/29/2014 7:35 AM Container-01 of 02 Analytical Method: E353.2: Analyst: EM Parameterst Results Qualifier D_F. Units Analyzed: Container: Nitrate as N <0.10 1 mg/L 03/2912014 8:21 AM Container-01 of 01 Analytical Method: E420.1 : Prep Method: E420.1 Prep Date:4/3/2014 5:00:00 AM Analyst: EM Parameters) Results Qualifier D.F. Units Analyzed: Container: Phenolics,Total Recoverable <5.0 1 pg/L 04/07120149:26 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank # e�-- D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NE LAC J=Estimated value-below calibration range unless otherwise noted. • S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 9 of 26 LKB009 S42 1 �'16,I nalXll��r'a LABORATORY RESULTS .Y i Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 TEL(631)694-3040 FAX:(631)420-8436 The lab is not responsible directly responsible for the inted to of the sample before receipt at � the lab and is responsible only for the certlfed lasts requested. i NYSDOH ID#10478 www.oaGelabs.com Lockwood Kessler&Bartlett One Aerial Way Sample Information: Lab No. : 1403J57-005 Type: Groundwater Syosset,NY 11791 Client Sample ID: MW-4D Attn To John Gerlach Collected :3/27/2014 11.30:00 AM Origin: Received :3/2812014 10:40:00 AM Collected By CLIENT Analytical Method: SM254OC:IOC Analyst: CO Parameter(s) Results Qualifier D.F. Units Analyzed: Container. Total Dissolved Solids 1,250 D 2 mg/L 03/30/2014 10:38 AM Container-01 of 02 Analytical Method: E351.2: Prep Method: E351.2 Prep Date:4/8/2014 5:15:00 AM Analyst TF Parameter(s) Results Qualifier D_F. UnitsnA aly ed: Container, Nitrogen,Kjeldahl,Total 32.9 D 10 mg/L 04108/2014 12:51 PM Container-01 of 01 Analytical Method: SM531OB: Analyst CO Parameter(s) Results Qualifier D.F. Units Acab= Container. Total Organic Carbon 22.3 1 mg/L 04/03/2014 12:46 AM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. • S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 10 of 26 LKB009 S43 !21AnaJ `ical, LABORATORY RESULTS _ .Y; Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 h TEL:(631)694-3040 FAX:(631)420-8436 The lab is not directly responsible for the integrity of the sample before receipt at i the lab and is responsible onlyforthe certifed tests requested. f NYSDOH ID#10478 www.p� Lockwood Kessler&Bartlett Aerial Way Sample Information: One Lab No. : 1403J57-006 Type: Groundwater SyossetNY 11781 : Client Sample ID: MW-4S Attn To John Gerlach Collected :3/27/2014 11:00:00 AM Origin: Received :3/2812014 10:40:00 AM Collected By CLIENT Analytical Method: SM2320B: Analyst: JDLR Parameterfs) Results Qualifier D.F. Units Analyzed: Container: Alkalinity,Total(As CaCO3) 193 D 10 mg/L 03/31/2014 2:07 PM Container-01 of 02 Analytical Method: E300.0: Analyst: bka Parameterfs) Results Qualifier D_F. Units Analyzed: Container: Bromide <0.50 1 mg/L 04/07/2014 11:41 PM Container-01 of 02 Chloride 19.5 1 mg/L 04107/2014 11:41 PM Container-01 of 02 Sulfate 40.5 1 mg/L 04/07/2014 11:41 PM Container-01 of 02 Analvtical Method: SM521OB: Preo Method: SM52106 Prep Date:3/28/2014 11:28:13 AM Analyst: VaS Parameters) Results ualifier D_F. Units Analyzed: n finer: Biochemical Oxygen Demand <2 1 mg/L 03/28/2014 2:40 PM Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.39 mg/L Analytical Method: E4110.4: Analyst: CN Parameters) Results Qualifier D.F. Units Analyzed: Container. Chemical Oxygen Demand 21.6 1 mg/L 04/07/2014 8:04 AM Container-01 of 01 Analytical Method: SM2340C: Analyst: JA Parameters) Results Qualifier D.F. Units Analyzed: Container: Hardness(As CaCO3) 240 D 20 mg/L 04107/2014 2:25 PM Container-01 of 01 Analvbcal Method: SM4500-NH3 H: Analyst: bka Parameters) Results Qualifier D.F. Units Analyzed Container: Nitrogen,Ammonia(As N) <0.10 1 mg/L 04109/2014 2:34 PM Container-01 of 01 Analytical Method: E353.2: Analyst: EM Parameters) Results ualifier D_F. Units Analyzed: Container: Nitrite as N <0.10 1 mg/L 03/29/2014 7:36 AM Container-01 of 02 Analytical Method: E353.2: Analyst: EM Parameters) Results Qualifier F. Units Analyzed: Container Nitrate as N 17.9 D 25 mg/L 03/29/2014 8:22 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date:4/3/2014 5:00:00 AM Analyst: EM Parameters) Results QualifierD.F. Units Analyzed: Container: Phenolics,Total Recoverable <5.0 1 ug/L 04/07/2014 9:27 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank # a-- D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Repotted: 5/7/2014 Page 11 of 26 LKB009 S44 • 1c, al LABORATORY RESULTS Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 The lab Is not directly responsible for the integrity of the sample before receipt of TEL(631)694-3040 FAX:(631)420-8436 � the lab and is responsible only for the certified tests requested. i NYSDOH ID#10478 www.oacelabs.com Lockwood Kessler&Bartlett Sample Information: One Aerial Way Lab No. : 1403J57-006 Type: Groundwater Syosset,NY 11791 Client Sample ID: MW-4S Attn To John Gerlach Collected :3/27/2014 11:00:00 AM Origin: Received :312812014 10:40:00 AM Collected By CLIENT Analytical Method: SM254OC:IOC Analyst: CO Parameters) suits Qualifier F. Units Analyzed: Container: Total Dissolved Solids 450 1 mg/L 03/3012014 10:40 AM Container-01 of 02 Analytical Method: E351.2: Prep Method: E351.2 Prep Date:4/8/2014 5:15:00 AM Analyst TF Parameters) Results Qualifier D.F.. JU nits Analyzed: Container: Nitrogen,Kjeldahl,Total 0.40 1 mg/L 04/08/2014 12:52 PM Container-01 of 01 Analytical Method: SM531OB: Analyst: CO Parameters) Results Qualifier D.F. Units Analyzed: Container. Total Organic Carbon 9.6 1 mg/L 04/03/2014 1:08 AM Container-C1 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. • S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 12 of 26 LKB009 S46 Yt/ CMnalj tial LABORATORY RESULTS Y i Results for the samples and analytes requested 575 Broad Hollow Road. Melville.NY 11747 �• TEL(631)694-3040 FAX: 631 420-8436 The lab Is not directly responsible for the integrity of the sample before receipt at t � t � the lab and is responsible only for the certified tests requested. NYSDOH ID#1 0478 www.oacelabs.com Lockwood Kessler&Bartlett One Aerial Way Sample Information: Lab No. : 1403J57-007 Type: Groundwater Syosset,NY 11791 Client Sample ID: MW-5D Attn To : John Gerlach Collected :3/27/2014 10:00:00 AM Origin: Received :3/28/2014 10:40:00 AM Collected By CLIENT Analytical Method: SM2320B: Analyst JDLR Parameters} Results Qualifier D.F. Units Analyzed: Container. Alkalinity,Total(As CaCO3) 721 D 10 mg/L 03/31/2014 2:29 PM Container-01 of 02 Analytical Method: E300.0: AnalysA bka Parameter s) Results Qualifier D.F. Units Analyzed: n i Bromide 0.87 1 mg/L 04/07/2014 11:54 PM Container-01 of 02 Chloride 202 D 10 mg/L 04/08/2014 12:08 AM Container-01 of 02 Sulfate 40.5 1 mg/L 04/07/2014 11:54 PM Container-01 of 02 Analvbcal Method: SM5210B: Prep Method: SM5210B Preate:3/28/2014 11:28:13 AM Analyst: VaS Parameters} Results QualifierD.F. Units Analyzed: Container: Biochemical Oxygen Demand <2 1 mg/L 03/26/2014 2:45 PM Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.39 mg/L Analytical Method: E410.4: Analyst: CN Parameters) Results Qualifier D.F. Units Analyzed: Container: Chemical Oxygen Demand 70.5 1 mg/L 04/0712014 8:06 AM Container-01 of 01 Analytical Method: SM234OC: Analyst: JA Parameters) Results Qualifier D.F.. Units Analyzed: Container: Hardness(As CaCO3) 360 D 20 mg/L 04/07/2014 2:30 PM Codainer-01 of 01 Analytical Method: SM4500-NH3 H: Analyst: bka Parameters) Results Qualifier D.F.. Units Anal Container. Nitrogen,Ammonia(As N) 94.5 D 100 mg/L 04109/2014 2:35 PM Container-01 of 01 Analytical Method: E353.2: Analyst: EM Parameters) Results Qualifier D.F. Units Analyzed: Container. Nitrite as N <0.10 1 mglL 03/29/2014 7:37 AM Container-01 of 02 Analytical Method: E353.2: Analyst: EM Parameters) Results Qualifier D.F. Units Analvzed: Container. Nitrate as N <0.10 1 mg/L 03/29/2014 8:25 AM Contalner-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date:4/3/2014 5:00:00 AM Analyst: EM Parameters) Results Qualifier D.F. Units Analyzed: Container. Phenolics,Total Recoverable <5.0 1 pg/L 04/07/2014 9:28 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. G� B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. • S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 13 of 26 LKB009 S46 LABORATORY RESULTS ;.acmnalyfical Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 4, TEL:(631)694-3040 FAX:(631)420-8436 The lab is not directly responsible for the integ•ity of the sample before receipt at the lab and is responsible only for the certified tests requested. i NYSDOH 10#10478 vmn.oacelahs.com Lockwood Kessler&Bartlett Aerial Way Sample Information: One Syosset11791 Lab No. : 1403J57-007 Type: Groundwater : Client Sample ID: MW-5D Attn To John Gerlach Collected :3127/20114 10:00:00 AM Origin: Received :3/28/2014 10:40:00 AM Collected By CLIENT Analytical Method: SM254OC:IOC Analyst: CO Parameter(sl Results Qualifier D.F. Units Analyzed: Container: Total Dissolved Solids 844 D 2 mg/L 03/30/201410:42 AM Container-01 of 02 Analytical Method: E351.2: Prep Method: E351.2 Prep Date:4/8/2014 5:15:00 AM Analyst: TF Parameters) Results QualifierD_F. Units Analyzed: Container: Nitrogen,Neldahl,Total 108 D 50 mg/L 04/08/2014 1:32 PM Container-01 of 01 Analytical Method: SM5310B: Analyst CO Parameters) Results ualifier D_F. Units Analyzed: Container: Total Organic Carbon 30.8 1 mg/L 04/03/2014 1:30 AM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 14 of 26 LKB009 S47 )/!; M j&al ' LABORATORY RESULTS ClcResults for the samples and analytes requested 575 Broad Hollow Road. Melville,NY 11747 The lab Is not o responsible for the integrity of sample before receipt at TEL:;631)694-3040 FAX:(631)420-8436 res I" the lab and is responsible only for the certified tests requested. NYSDOH113#1D478 wyrwmacelabs.com Lockwood Kessler&Bartlett Sample Information: One Aerial Way Lab No. : 1403J57-008 Type: Groundwater Syosset,NY 11791 Attn To : John Gerlach Client Sample ID: MW-5S Collected :3/27/2014 10:30:00 AM Origin: Received :3/2812014 10:40:00 AM Collected By CLIENT Analytical Method: SM2320B: Analyst JDLR Parameterfs) Results Qualifier D.F. Units Analyzed: Container. Alkalinity,Total(As CaCO3) 22.7 1 mg/L 03131/2014 2:37 PM Container-01 of 02 Analytical Method: E300.0: Analyst: bka Parameterfs) Results ualifierD_F. nits Analyzed: Container Bromide <0.50 1 mg/L 04/08/2014 12:21 AM Container-01 of 02 Chloride 18.9 1 mg/L 04/08/2014 12:21 AM Container-01 of 02 Sulfate 12.7 1 mg/L 04/08/2014 12:21 AM Container-01 of 02 Analytical Method: SM521OB: Prep Method: SM5210B Prep Date:3/28/2014 11:28:13 AM Analyst VaS Parameters) Results Qualifier D.F. Units Analyzed: Container. Biochemical Oxygen Demand <2 1 mg/L 03/28/2014 2:50 PM Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.39 mg/L Analvtical Method: E410.4: Analyst: CN Parameters) Results Qualifier D.F. Units Analyzed: Container: Chemical Oxygen Demand <10.0 1 mg/L 04/07/2014 8:08 AM Container-01 of 01 Analytical Method: SM234OC: Analyst: JA Parameters) Results Qualifier D.F. UnitsAnalyzed: Container. Hardness(As CaCO3) 44 D 2 mg/L 04/07/2014 2:45 PM Container-01 of 01 Analytical Method: SM4500-NH3 H: Analyst bka Parameters) Results Qualifier D.F. Units Analyzed: Containerr, Nitrogen,Ammonia(As N) <0.10 1 mg/L 04/09/2014 2:36 PM Container-01 of 01 Analytical Method: E353.2: Analyst: EM Parameters) Results Qualifier D.F. Units Analyzed: Container. Nitrite as N <0.10 1 mg/L 03/29/2014 7:38 AM Container-01 of 02 Analytical Method: E353.2: Analyst: EM Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrate as N 0.82 1 mg/L 03/29/2014 8:26 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date:4/3/2014 5:00:00 AM Analyst: EM Parameters) Results Qualifier D.F. Units Analyzed: Container. Phenolics,Total Recoverable <5.0 1 pg/L 04/07/2014 9:29 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank # 4-- D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 15 of 26 LKB009 S48 !;a?ci17 � 1fCt ,.� LABORATORY RESULTS Results for the samples and analytes requested 575 Broad Hollow Road, frlelville,NY 11747 TEL:(631)694-3040 FAX(631)420-8436 The lab Is not dlrwly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. i NYSDOH ID#10478 www.oacelabs.com Lockwood Kessler 8r Bartlett One Aerial Way Sample Information: Syosset, l 11791 Lab No. : 1403J57-008 Type: Groundwater : Client Sample ID: MW-5S Attn To John Gerlach Collected :3/27/2014 10:30:00 AM Origin: Received :3/28/201410:40:00 AM Collected By CLIENT Analytical Method: SM254OC:IOC Analyst CO Parameterts) Results Qualifier D.F. Units Analyzed: Container. Total Dissolved Solids 54 1 mg/L 03/30/2014 10:44 AM Container-01 of 02 Analytical Method: E351.2: Prep Method: E351.2 Prep Date:4/8/2014 5:15:00 AM Analyst TF Parameters) Results Qualifi@r D_F. ni Analyzed: Container. Nitrogen,Kjeldahl,Total 0.73 1 mg/L 04/08/2014 12:53 PM Container-01 of 01 Analytical Method: SM531 OB: Analyst CO Parameter's) Results Qualifier D.F. Units Analyzed: Container: Total Organic Carbon 4.5 1 mg/L 04/03/2014 1:52 AM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated.B=Found in Blank /'�D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 16 of 26 LKB009 S49 ;ac, }yr# q LABORATORY RESULTS • r - j i Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 t, TEL:(631)694-3040 FAX:(631)420-8436 The lab is not directly responsible for the integrity of the sample before receipt at � the lab and is responsible only for the certified tests requested. i NYSDOH 10#10478 www.t)acelabs.com Lockwood Kessler 8r Bartlett Sample Information: One Aerial Way Syosset,NY 11791 Lab No. ; 1403J57-009 Type: Groundwater Client Sample ID: MW-6D Attn To John Gerlach Collected :3/27/2014 2:40:00 PM Origin: Received :3/28/2014 10:40:00 AM Collected By CLIENT Analytical Method: SM2320B: Analyst: JDLR Parameters) Results ualifier D.F. Units Analyzed: Container. Alkalinity,Total(As CaCO3) 10.2 1 mg/L 03/31/2014 2:43 PM Container-01 of 02 Analytical Method: E300.0: Anal : bka Parameters) Results Qualifier F. Units Ana ed: Container: Bromide <0.50 1 mg/L 04/08/2014 12:35 AM Container-01 of 02 Chloride 43.6 1 mg/L 04/08/2014 12:35 AM Container-01 of 02 Sulfate 94.0 D 5 mg/L 04/08/2014 12:48 AM Container-01 of 02 Analytical Method: SM521 OB: Preo Method: SM5210B Prep Date:3/28/2014 11:28:13 AM Analyst: VaS Parameters) Results Qualifier D.F. Units Analyzed: Container Biochemical Oxygen Demand <2 1 mg/L 03128/2014 2:55 PM Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.39 mg/L Analytical Method: E410.4: Analyst: CN Parameters) Results Qualifier D.F. Units Analyzed: Container: Chemical Oxygen Demand <10.0 1 mg/L 04/07/2014 8:10 AM Container-01 of 01 Analytical Method: SM234OC: Analyst: JA Parameters) Results ualifier D_F. Units Analyzed: Container: Hardness(As CaCO3) 150 D 10 mg/L 04/07/2014 2:50 PM Container-01 of 01 Analvdcal Method: SM4500-NH3 H: Analyst bka Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrogen,Ammonia(As N) <0.50 D 5 mg/L 04/09/2014 3:34 PM Container-01 of 01 Analytical Method: E353.2: Analyst EM Parameters) Results ualifierD_F. Units Anal Container: Nitrite as N <0.10 1 mg/L 03/29/2014 7:42 AM Container-01 of 02 Analytical Method: E353.2: Analyst EM Parameters) Results Qualifier D_F. Units Analyzed: Container, Nitrate as N 6.92 D 10 mg/L 03/29/2014 8:28 AM Container-01 of 01 Anali Method: E420.1: Preo Method: E420.1 Preo Date:4/312014 5:00:00 AM Analyst EM Parameters) Results Qualifier D.F. Units Analyzed: Container Phenolics,Total Recoverable <5.0 1 pg/L 04/07/2014 9:30 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. L�a/ / B=Found in Blank (�,�,�/��, D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 17 of 26 LKB009 S50 CMnally}ica � LABORATORY RESULTS Y i Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 TEL(831)694-3040 FAX:(631)4211-8436 The lab is not directly responsible for the integrity of the sample before receipt at the lab and Is responsible only for the certified tests requested. NYSDOH ID#10478 wywy.oacelabs.com Lockwood Kessler&Bartlett Way Sample Information: One Aerial Syosset, 11791 Lab No. : 1403J57-009 Type: Groundwater Client Sample ID: MW-6D Attn To John Gerlach Collected :3/27/2014 2:40:00 PM Origin: Received :3/28/2014 10:40:00 AM Collected By CLIENT Analytical Method: SM2540C:IOC Analyst: CO Parametegsl Results Qualifier D.F. Units Analyzed: Container: Total Dissolved Solids 256 1 mg/L 03130/2014 10:46 AM Container-01 of 02 Analytical Method: E351.2: Prev Method: E351.2 Preo Date:4/8/2014 5:15:00 AM Analyst: TF Parameterfs) Results Qualifier D.F. Units Analyzed: Container: Nitrogen,Kjeldahl,Total 0.43 1 mg/L 04/08/2014 12:54 PM Container-01 of 01 Analytical Method: SM531OB: Analyst: CO Parameters) Results Qualifier D.F. Units Analyzed: Container: Total Organic Carbon <1.0 1 mg/L 04/08/2014 3:11 PM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 18 of 26 LKB009 S51 • fL° 1 .Y iiftC�r n. LABORATORY RESULTS Results for the samples and analytes requested 575 Broad Hollow Road, Melvllle,NY 11747 TEL:1631)6943040 FAX-(631)420-8436 The lab Is not directly responsible for the integrity of the sample before receipt at i NYSDOH ID#10478 w.yx.oacelabs.com the lab and is responsible only for the certified tests requested. � Lockwood Kessler&Bartlett One Aerial Way Sample Information: Lab No. : 1403J57-010 Type: Groundwater Syosset,NY 11791 Client Sample ID: MW-6S Attn To : John Gerlach Collected :3/2712014 2:20:00 PM Origin: Received :312a/2014 10:40:00 AM Collected By CLIENT Analytical Method: SM2320B: Analyst: JDLR Parameterfsl Results Qualifier 2.F. Units Analyzed. Container: Alkalinity,Total(As CaCO3) 51.1 D 2 ri 03/31/2014 2:48 PM Container-01 of 02 Analytical Method: E300.0: Analyst bka Parameteris) Eglultj Qualifier D FUnits Analyzed: Container: Bromide <0.50 1 mg/L 04/08/2014 1:56 AM Container-01 of 02 Chloride 13.7 1 mg/L 04/08/2014 1:56 AM Container-01 of 02 Sulfate 6.69 1 mg/L 04/08/2014 1:56 AM Container-01 of 02 Analytical Method: SM5210B: Prep Method: SM5210B Prep Date:3/28/2014 11:28:13 AM Analyst VaS Parameters) Results ualifier D_F. Units Analyzed: Container: Biochemical Oxygen Demand <2 1 mg/L 03/28/2014 3:00 PM Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.39 mg/L Analvtical Method: E410.4: Analyst CN Parameters) Results Qualifier D. Units nal Container: Chemical Oxygen Demand 26.1 1 mg/L 04/07/2014 8:12 AM Container-01 of 01 Analvticai Method: SM2340C: Analyst: JA Parameters) Results Qualifier D.F. Units Analyzed: Container. Hardness(As CaCO3) 68 D 4 mg/L 04/07/2014 2:55 PM Container-01 of 01 AnaWcal Method: SM4500-NH3 H: Analyst: bka Parameters) Results Oualifier D_F. Units Analyzed: Container Nitrogen,Ammonia(As N) <0.10 1 mg/L 04/09/2014 2:41 PM Container-01 of 01 Analytical Method:_ E353.2: Analyst: EM Parameters) Results Qualifier D.F. Units Analyzed: Container. Nitrite as N <0.10 1 ni 03/29/2014 7:43 AM Container-01 of 02 AnaWcal Method: E353.2: Analyst: EM Parameterts) Results Qualifier F. Units Analyzed; container. Nitrate as N 1.18 D 2 mg/L 03129/2014 8:29 AM Container-01 of 01 Anaivtcal Method: E420.1: Prep Method: E420.1 Prep Date:4/3/2014 5:00:00 AM Analyst: EM Parameters) Results Qualifier D.F. Units Analyzed: Container: Phenolics,Total Recoverable <5.0 1 pg/L 04/07/2014 9:31 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 19 of 26 LKB009 S62 ri� l � c ,n LABORATORY RESULTS Results for the samples and analytes requested 575 Broad Hollow Road. Melville,NY 11747 � TEL:(631)694-3040 FAX(631)420-8436 The lab is not directly responsible for the integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. NYSDOH ID010478 www.oacelabs.com Lockwood Kessler&Bartlett Sample Information: One Aerial Way Lab No. : 1403J57-010 Type: Groundwater Syosset,NY 11791 Client Sample ID: MW-6S Attn To : John Gerlach Collected :3/27/2014 2:20:00 PM Origin: Received :3/28/2014 10:40:00 AM Collected By CLIENT Analytical Method: SM2540C:IOC Analyst: CO Parameterts) Results Qualifier D.F. Units Analyzed: Container. Total Dissolved Solids 90 1 mg/L 03/30/2014 10:48 AM Container-01 of 02 Analytical Method: E351.2: Preo Method: E351.2 Prec Date:4/8/2014 5:15:00 AM Analyst: TF Parameters) Results Qualifier D. nits Analyzed: Container Nitrogen,Kjeldahl,Total 1.42 1 mg/L 04/08/201412:55 PM Container-01 of 01 Analytical Method: SM531 OB: Analyst: CO Parameters) Results Qualifier D.F. Units Analyzed: Container. Total Organic Carbon 11.7 1 mg/L 04/08/2014 3:33 PM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. • S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 20 of 26 LKB009 S53 c� n LABORATORY RESULTS r MnalyficalResults for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 The lab is not y responsible the Integrity of the sample before receipt at TEL:(631)6943040 FAX:(631)420-8436 responsible th � the lab and is responsible only for the certified tests requested. NYSDOH 0#10476 w .oacelabs.com Lockwood Kessler&Bartlett Sample Information: One Aerial Way Syosset,NY 17791 Lab No. : 1403157-011 Type: Groundwater Attn To : John Gerlach Client Sample ID: MW-7S Collected :3/2712014 11:10:00 AM Origin: Received :3/2812014 10:40:00 AM Collected By CLIENT Analytical Method: SM23208: Analyst JDLR Parameters) Results CLualifier D_F. Units Analyzed: Container. Alkalinity,Total(As CaCO3) 196 D 10 mg/L 03/31/2014 2:55 PM container-01 of 02 Analytical Method: E300.0: Analyst bka Parameters) Results Ovarifler D_F. ni Analyzed: Container. Bromide <0.50 1 mg/L 04/08/2014 2:09 AM Chloride 19.4 1 mg/L 04/08/2014 2:09 AM Sulfate 40.0 1 mg/L 04/08/2014 2:09 AM Analytical Method: SM521OB: Prep Method: SM5210B Prep Date:3/28/2014 11:28:13 AM Analyst VaS Parameters) Results Qualifier D.F. Units Analyzed; Container Biochemical Oxygen Demand <2 1 mg/L 03/28/2014 3:05 PM Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.39 ri Analytical Method: E410.4: Analyst: CN Parameters) Results Qualifier D.F. Units Analyzed: Container: Chemical Oxygen Demand 22.2 1 mg/L 04/07/2014 8:14 AM Container-01 of 01 Analytical Method: SM2340C: Analyst: JA Parameters) Results Qualifier D.F. UnitsnA alyzed: Container: Hardness(As CaCO3) 250 D 10 mg/L 0410712014 3:00 PM Container-01 of 01 Analytical Method: SM4500-NH3 H: Analyst: bka Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrogen,Ammonia(As N) <0.10 1 mg/L 04/09/2014 2:42 PM Container-01 of o1 Analytical Method: E353.2: Analyst EM Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrite as N <0.10 1 mg/L 03/29/2014 7:44 AM Container-01 of 02 Analytical Method: E353.2: Analyst: EM Parameters) Results Qualifier D.F. Units AuabzegL Container: Nitrate as N 17.3 D 100 mg/L 03/29/2014 8:30 AM Container-01 of 01 Analytical Method: E420.1: Preo Method: E420.1 Prep,Date:4/3/2014 5:00:00 AM Analyst: EM Parameters) Results Qualifier D.F. Units Analyzed: Container: Phenolics,Total Recoverable <5.0 1 pg/L 04/0712014 9:32 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank -^ D.F. =Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. • S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 21 of 26 LKB009 S64 (�1!;,,a16Ana1j4ica1 LABORATORY RESULTS " Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 P' TEL:(631)694-3040 FAX:(631)420.8436 The lab net directly responsible for the Integrity of the sample before receipt at � the lab and d is responsible only for the certified tests requested. i NYSDOH ID#10478 www.uacelabs.com Lockwood Kessler&Bartlett Sample Information: One Aerial Way Lab No. : 1403J57-011 Type: Groundwater Syosset,NY 11791 : Client Sample ID: MW-7S Attn To John Gerlach Collected :312712014 11:10:00 AM Origin: Received :3/28/2014 10:40:00 AM Collected By CLIENT Analytical Method: SM254OC:IOC Analyst: CO Parameterfs) Results Qualifier D.F. Units Analyzed: Container: Total Dissolved Solids 448 1 mg/L 03/30/2014 10:50 AM Container-01 of 02 Analytical Method: E351.2: Prep Method: E351.2 Prep Date:4/8/2014 5:15:00 AM Analyst TF Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrogen,Kjeldahl,Total 0.48 1 mg/L 04/08/2014 12:58 PM Container-01 of 01 Analytical Method: SM531 OB: Analyst: CO Parameters) Results Qualifier D.F. Units Analyzed: Con finer: Total Organic Carbon 9.2 1 mg/L 04/08/2014 3:55 PM Container-01 of 02 Qualifiers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. • S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 22 of 26 LKB009 S55 LABORATORY RESULTS Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 TEL:(837)894-3040 FAX:(631)420-8436 The lab is not directly respcnsiblefor the Integlty,of the sample before receipt at the lab and is responsible only for the certified tests requested. NYSDOH ID#10478 www.nacelabs.com Lockwood Kessler&Bartlett Sample Information: One Aerial Way Lab No. : 1403J57-012 Type: Groundwater Syosset,NY 11791 : Client Sample ID: MW-8D Attn To John Gerlach Collected :3/27/2014 12:40:00 PM Origin: Received :3/2812014 10:40:00 AM Collected By CLIENT Analytical Method: SM2320B: Analyst: JDLR Parameters) Results Qualifier D_F. Units Analyzed Container: Alkalinity,Total(As CaCO3) 288 D 10 mg/L 03/31/2014 3:04 PM Container-01 of 02 Analvtical Method: E300.0: Analyst: bka Parameters) Results Qualifier D.F. Units Analyzed: Container: Bromide <0.50 1 ri 04/08/2014 2:23 AM Chloride 96.8 D 5 mg/L 04/08/2014 2:36 AM Container-01 of 02 Sulfate 82.4 D 5 mg/L 04/08/2014 2:36 AM Container-01 of 02 Analytical Method: SM521OB: Prep Method: SM5210B Prep Date:3/28/2014 11:28:13 AM Analyst VaS Parameters) Results Qualifier D.F. Units Analyzed: Container: Biochemical Oxygen Demand <2 1 mg/L 03/2812014 3:10 PM Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.39 mg/L Analytical Method: E410.4: Analyst: CN Parameters) Results Qualifier Q.F. Units Analyzed: Container: Chemical Oxygen Demand 26.1 1 mg/L 04/07/2014 8:16 AM Container-01 of 01 Analytical Method: SM2340C: Analyst: JA Parameterfs) Results ualifierD_F. Units Analyzed: Container. Hardness(As CaCO3) 240 D 10 mg/L 04107/2014 3:05 PM Container-01 of 01 Analytical Method: SM4500-NH3 H: Analyst: bka Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrogen,Ammonia(As N) 21.5 D 10 mg/L 04/09/2014 2:44 PM Container-01 of 01 Analytical Method: E353.2: Analyst: EM Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrite as N <0.10 1 mg/L 03/29/2014 7:45 AM Container-01 of 02 Analytical Method: E353.2: Analyst: EM Parameters) Results ualifier DD^F. Units Analyzed: Container: Nitrate as N <0.10 1 mg/L 03129/2014 8:31 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date:4/3/2014 5:00:00 AM Analyst: EM Parameters) Results Qualifier D.F. Units Analyzed: Container. Phenolics,Total Recoverable <5.0 1 pg/L 04/07/2014 9:33 AM Container-01 of01 Qualifiers: E=Value above quantitation range,Value estimated. G� B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. • S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Repotted: 5/712014 Page 23 of 26 LKB009 S56 2.. 6Ana1j&a1 LABORATORY RESULTS r Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 The lab is not directly responsible for the Irteg-Iry of the sample before receipt at TEL(fi31)694.3040 FAX:(631)420-8436 f the lab and is responsible cr ly for the certified tests requested. i NYSDOH 0410478 www.oacelabs.cori Lockwood Kessler&Bartlett Sample Information: One Aerial Way Lab No. : 1403J57-012 Type: Groundwater Syosset,NY 11791 : Client Sample ID: MW-8D Attn To John Gerlach Collected :3127/201412:40:00 PM Origin: Received :3128/201410:40:00 AM Collected By CLIENT Analytical Method: SM2540C:IOC Analyst CO Parameter(s) Results Qualifier D.F.. Units Analyzed: Container. Total Dissolved Solids 503 1 ni 03/30/2014 10:52 AM Container-01 of 02 Analytical Method: E351.2: Prep Method: E351.2 Prep Date:4/8/2014 5:15:00 AM Analyst: TF Parameter(s) Results Qualifier D_F. Units Lnelyzed Container: Nitrogen,Kjeldahl,Total 27.4 D 20 mg/L 04/08/2014 12:58 PM Container-01 of 01 Analytical Method: SM531 OB: Analyst: CO ParameteKsl Results Qualifier D_F. Units Analyzed: Container: Total Organic Carbon 10.0 1 mg/L 04/08/2014 4:17 PM Container-01 of 02 • Quallflers: E=Value above quantitation range,Value estimated. B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. • S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5n12014 Page 24 of 26 LKB009 S67 it � ,I-� LABORATORY RESULTS r - '�"1 ! Results for the samples and analytes requested 575 Broad Hollow Road, MBlvlle,NY 11747 TEL:(831)694-3040 FAX:(631)420-8438 The lab is not directly responsible for the integrity of the sample before receipt at i, the lab and is responsible only for the certified tests requested. NYSDOH ID910478 www.oaGelabs.com Lockwood Kessler&Bartlett Sample Information: One Aerial Way Lab No. : 1403J57-013 Type: Groundwater Syosset,NY 11791 : Client Sample{D: MW-8S Attn To John Gerlach Collected :3/27/20141:00:00 PM Origin: Received :3128/2014 10:40:00 AM Collected By CLIENT Analytical Method: SM2320B: Analyst, JDLR Parameterfsl Results Qualifier D.F. Units Analyzed: Container: Alkalinity,Total(As CaCO3) 169 D 10 mg/L 03/31/2014 3:13 PM Container-01 of 02 Analytical Method: E300.0: Analyst bka Parameterls) Results Qualifier D.F. Units Analyzed: Container: Bromide <0.50 1 mg/L 04/08/2014 2:50 AM Container-01 of 02 Chloride 43.6 D 5 mg/L 04/08/2014 3:03 AM Container-01 of 02 Sulfate 55.1 D 5 mg/L 04/08/2014 3:03 AM Container-01 of 02 Analytical Method: SM5210B: Prep Method: SM5210B Preo Date:3/28/2014 11:28:13 AM Analyst VaS Parameters) Results ualifierD_FUnits Analyzed: Container: Biochemical Oxygen Demand <2 1 mg/L 03/28/2014 3:15 PM Container-01 of 02 NOTES: Blank depletion exceeds 0.2 mg/L-average depletion of 0.39 mg/L Analvbcal Method: E410.4: Analyst: CN Parameters) Results Qualifier D.F. Units Analyzed: Container: Chemical Oxygen Demand 29.9 1 mg/L 04/07/2014 8:18 AM Container-01 of 01 Analytical Method: SM2340C: Analyst: JA Parameters) Results Qualifier D.F. Units Ana ed: Container: Hardness(As CaCO3) 88 D 4 mg/L 04/07/2014 3:10 PM Container-01 of 01 Analytical Method: SM4500-NH3 H: Analyst: bka Parameters) Results Qualifier D.F. Units Analyzed: Container: Nitrogen,Ammonia(As N) 21.8 D 10 mg/L 04/08/2014 2:45 PM Container-01 of 01 Analytical Method: E353.2: Analyst: EM Parameters) Results Qualifier D.F.. Units Analyzed: Container: Nitrite as N <0.10 1 mg/L 03/29/2014 7:47 AM Container-01 of 02 Analytical Method: E353.2: Analyst EM Parameters) Resul Qualifier D_F. Units Analyzed: Container: Nitrate as N <0.10 1 mg/L 03/29/2014 8:32 AM Container-01 of 01 Analytical Method: E420.1: Prep Method: E420.1 Prep Date:4/3/2014 5:00:00 AM Analyst EM Parameters) Results Qualifier D.F. Units Analyzed: Container. Phenolics,Total Recoverable <5.0 1 Ng/L 04/07/2014 9:34 AM Container-01 of 01 Qualifiers: E=Value above quantitation range,Value estimated; B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless otherwise noted. • S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in Full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 25 of 26 LKB009 S68 l? LABORATORY RESULTS t'I f ��N�p Results for the samples and analytes requested 575 Broad Hollow Road, Melville,NY 11747 t, TEL:(631)694-3040 FAX:(631)420-8436 The lab Is not dlredly responsible for the Integrity of the sample before receipt at the lab and is responsible only for the certified tests requested. i NYSDOH/0#10478 www.oacelabs.com Lockwood Kessler&Bartlett Sammie Information: One Aerial Way Syosset,NY 11791 Lab No. : 1403J57-013 Type: Groundwater : Client Sample ID: MW-8S Attn To John Gerlach Collected :3/27/2014 1:00:00 PM Origin: Received :3/28/2014 10:40:00 AM Collected By CLIENT Analytical Method: SM2540C:IOC Anaivsk CO Parameters) Results Qualifier D.F. Units Ana ed: Container: Total Dissolved Solids 323 1 mg/L 03!3012014 10:54 AM Container-01 of 02 Analvical Method: E351.2: Prep Method: E351.2 Preo Date:4/8/2014 5:15:00 AM Analyst: TF Parameters) Res I s Qualifier D.F., Mnits Analyzed: Container: Nitrogen,Kjeldahl,Total 25.7 D 10 mg/L 04/08/2014 12:59 PM Container-01 of 01 Analytical Method: SM5310B: Analyst: CO Parameters) Results Qualifier D.F. Units Analyzed: Container: Total Organic Carbon 9.1 1 mg/L 04/08/2014 4:39 PM Container-M of 02 Qualifiers: E=Value above quantitation range,Value estimated. G� B=Found in Blank D.F.=Dilution Factor D=Results for Dilution H=Received/analyzed outside of analytical holding time Client Services Manager +=ELAP/NELAC does not offer certification for this analyte c=Calibration acceptability criteria exceeded for this analyte r=Reporting limit>MDL and<LOQ,Value estimated. Test results meet the requirements of NELAC J=Estimated value-below calibration range unless othervvise noted. S=Recovery exceeded control limits for this analyte This report shall not be reproduced except in full, N=Indicates presumptive evidence of compound without the written approval of the laboratory. Date Reported: 5/7/2014 Page 26 of 26 LKB009 S69 ace Long lsl8fld 5`5 Broad Holiow Road 631.694,3040 Melville, NY 11747 631.420,8436 5. DUPLICATE SUMMARY RESULTS 5.1 METALS 5.2 WET CHEMISTRY • LKB009 S60 • U.S. EPA - CLP 6 EPA SAMPLE NO DUPLICATES MW-1D Lab Name: PACE ANALYTICAL Contract: I Lab Code: 1C478 Case No. SAS No. : SDG No. : LK13009 Matrix (scil/water) : WATER Level (low/med) LOW s Solids for Sample: 0.0 Solids for Duplicate: 0.0 Concentration Units (ug/L or mg/kg dry weight) : UG/L i Control Analyte Limit Sample (S) C Duplicate (D) C RPD IQ M Cadmium 0.1134 U 0.1134IU ! P Calcium T 31160.0000 ii30790.0000 1.2 P Iron 100.0000 101.4300 76.7000, B _ 27.7 P Lead 5.0000 - -9.8300 19.0900' 4.1 P Magnesium 5000.0000 14870.0000 14660. 0000 1 1.4 P Manganese 7 15.0000 ' 2.3000 IR 2.2000 B ' 4 .4 P Potassium 5000.0_000 1930.0000 R 1875.000013 ' 2.9 P Sodium 5000.0000 19480.0000 19210.00001 _.4 P , FORM VI - IN ILM04.1 LKB009 S61 0 ! ! PACE ANALYTICAL Date: 25-Apr-14 QC SUMMARY REPORT SDG: LKB009 Spike Sample Recovery RPDRef %RPD Sample ID: Cllcnt Sample ID__ Analyte Result Units Amount Result %REC Limits Value %RPD UCL — MB-033114 MB-033114 -Alkalinity,Total(As CaCO3) <1 MG/L -- -- - LCS-033114 LCS-033114 Alkalinity,Total(As CaCO3) 24.7 MG/L 25 <1 99 80 120 14031<13-001BMS 14031<13-001BMS -i Alkalinity,Total(As CaCO3) 50.3 MG/L 25 25.2 101 75 125 1403K13-001BDUP 1403K13-001BDUP (Alkalinity,Total(As CaCO3) 25.0 MG/L 1 25.2 0.80 20 MB-43872 MB-43872 Biochemical Oxygen Demand I <2 MG/L LCS-43872 ILCS-43872 Biochemical Oxygen Demand , 228 MG/L 198 <2 115 85 116 1403.122-001ADUP 1403.122-001ADUP Biochemical Oxygen Demand 159 MG/L 160 0.94 20 -- - - -- - - - --- - —---- 1-- MB-040713 MB-040713 Bromide <0.5 MG/L LCS-040713 ILCS-040713 Bromide 2.52 MG/L 2.5 <0.5 101 90 110 1404145-001AMS 11404145-001AMS Bromide 0.99 MG/L 1 <0.5 99 80 120 1404145-001ADUP 1404145-001ADUP Bromide <0.5 MG/L <0.5 20 MB-040714 MB-040714 Chemical Oxygen Demand <10- MG/L LCS-040714 ILCS-040714 Chemical Oxygen Demand 102 MG/L 100 <10 102 1 90 110 1 1403J57-0138MS MW-85MS Chemical Oxygen Demand 130 1 MG/L 100 29.9 100 90 110 1403J57-013BDUP MW-8SDUP Chemical Oxygen Demand 30.5 MG/L 29.9 2.1 20 MB-040713 MB-040713 Chloride <2 MGfL LCS-040713 LCS-040713 Chloride 9.70 r MG/L 10 <2 97 90 110 1404145-001AMS 1404145-001AMS Chloride 16.0 MGIL 10 5.18 108 80 120 — ---- - I - --- --- - ---- -- --- 1404145-001ADUP 1404145-001ADUP Chloride 5.19 -1 MG/L 5.18 0.21 20� MB-040714 MB-040714 iHardness(As CaCO3) <5 MGL LCS-040714 LCS-040714 Hardness(As CaCO3) 1000 MGL 1000 <5 100 80 120 1403J57-007DMS MW-5DMS Hardness(As CaCO3) 2320 MG/L 2DD0 360 98 75 125 1403.157-0071C)DUP MW-5DDUP Hardness(As CaCO3) 360 MGIL 360 20 1 LKB009 S62 QC SUMMARY REPORT SDG: LKB009 Spike Sample Recovery RPDRef %RPD Sa{nple ID: Cllctll Saw We ID: A11111Nle Result Units Amount Result %REC Limits Value %RPD UCL IMB-032914 MB-032914 Nitrate as N <0.1 MGIL ,LCS 032914 LCS-032914 Nitrate as N 1.14 MG/L 1.13 <0.1 101 90 110 1403J57-001 BMS MW-IDMS Nitrate as N 9.79 MGIL 5 5.21 92 90 110 j 1403J57-001 BD-UP MW-1DDUP Nitrate as N 5.06 MG/L 5.21 2.9 20 MB-032914 MB-032914 !Nitrite as IN <0.1 MGIL iLCS-032914 LCS-032914 Nitrite as N 1.01 MG/L 1 <0.1 101 90 110 1403J57-001AMS MW-1DMS Nitrite as N 0.52 MG/L 0.5 <0.1 104 90 110 1403J57-001ADUP - MW-lDDUP ,Nitrite as N <0.1 MG/L -<0.1 20 MB-040914 MB-040914 Nitrogen,Ammonia(As N) <0.1 MGIL LCS-040914 LCS-040914 Nitrogen,Ammonia(As N) 1.10 MG/L 1 <0.1 110 90 110 1404524-001 BMS 1404524-001BMS Nitrogen,Ammonia(As N) 0-47 MG/L 0.5 <0.1 94 75 125 1404524-001 BDUP 1404524-001 BDUP Nitrogen,Ammonia(As N) <0.1 MG/L <0.1 20 MB-43994 MB-43994 (Nitrogen,Kjeldahl,Total <0.1 MG/L LCS-43994 LCS-43994Nitrogen Kjeldahl,Total 4.33 MG/L 4 <0.1 108 90 110 43994-LFBD 43994-LFBD INitrogen,Kjeldahl,Total 4.42 MGIL 4 <0.1 111 75 125 4.38 0.91 20 43994-LFB 3994 LFB INitrogen,Kjeldahl,Total 4.38 MGIL 4 <0.1 110 75 125 MB-43933 MB-43933 Phenolics,Total Recoverable <5 UGlL ,LCS-43933 LCS-43933 Phenolics,Total Recoverable- --31.7 UGlL 30 <5 106 80 120 - -- 1404189-006AMS 1404189-006AMS Phenolics,Total Recoverable 18.1UG/L 20 <5 91 75 125 1404189-006ADUP 1404189-006ADUP Phenolics,Total Recoverable <5 UGIL <5 20 MB-040713 MB-040713 Sulfate T<5 MGIL LCS-040713 LCS-040713 Sulfate 9.10 MG/L 10 <5 91 90 110 1403J57-009AMS MW-6DMS Sulfate 147 MGIL 50 94_0 107 80 120 1403J57-009ADUP MW-6DDUP Sulfate 94.1 MG/L 94.0 0.1 20 - 2 LKB009 S63 QC SUMMARY REPORT .SDG: LK 3009 Spike Sample Recovery RPDRef %RPD au l)le ID: (iitll iaiUl)le�l): «;,,ti)t� Result �'c:. Am-. t Res.lt %REC Limiis Val.;e %RPD JGL MB-040913 MB-040913 Sulfate 15 MGIL �LCS-040913 �LCS-040913 Sulfate 9.10 MGIL 10 <5 91 90 1110 14 Total Dissolved Solids < 10 CS 033014 CS 0330014 - Total Dissolved Solids 280 MGIL 300 <10 93 80 120 1403J57-001AMS MW 1 DMS Total Dissolved Solids 536 MG/L 300 229 102 75 125 1403J57-001ADUP MW-1Dl Total Dissolved Solids 230 MGIL j 229 0.44 20 MB-040814 ITotal Organic Carbon < 1 MGIL LCS-040814 LCS-040814 (Total Organic Carbon 27.6MGIL 25 <1 110 80120 MB-040214 MB-040214 Total Organic Carbon <1 MGIL LCS-040214 LCS-040214 Total Organic Carbon26.5 MGIL 25 ; <1 106 80 120 1404012-003AMS 1404012-003AMS Total Organic Carbon 13.3 MGIL 10 3.2 101 75 125 1404012-003ADUP 1404012-003ADUP ITotal Organic Carbon 2.9 MGIL - 3.2 11.1 20 _ _ 3 LKB009 S64 / ace long is/and r 575 Broad Ho'iow Road f:; 613!.634.3040 Meivii=e, NY 11747 631.430.8436 6. SPIKE SAMPLE RESULTS 6.1 METALS 6.2 WET CHEMISTRY LKB009 S65 U.S. EPA - CLP 5A EPA SAMPLE NO SPIKE SAMPLE RECOVERY - —� MW-1D5 Lab Name: PACE ANALYTICAL Ccrtrac-: Lab Code: 10478 Case No. SAS No. : SDG No. : LKB009 Matrix (soil/water) : WATER Level (low/med) : LOW % Solids for Sample: 0.0 Concentration Units (ug/L or mg/kg dry weight) : OG/L Control Limit ( Spiked Sample Sample Spike Analyte %R Result (SSR) C Result (SR; C ' Added (SA) %R Q M Cadmium 1 75-125 62. 90001 _ 0.1"_34 Jj -7).001 125.8 N P Iron ' 75-125 1302. 0000 101.4000 1000 00. 120.1 P Lead ! 75-125 (3. 9100 19.8800 20.00-! 120.21 P Mancfanese 75-125 627.2000 2.3000 B , 500.00 12,9- n1 P 7- 4 Comments: FORM V (Part 1) - IN ILM04._ LKB009 S66 U.S. EPA - CLP 5B EPA SAMPLE NO POST DIGEST SPIKE SAMPLE RECOVE-RY M'R-1 DA Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. SAS No. : SDG No. : LKB009 Matrix (soil/wa-er) : WATER. Level (low/med) : LOW Concentration_ Units: ug/L Control Limit Spiked Sample Sample Spike Analyte %R Result ;SSR) C Result (SR) CI' Added (SA) %R. Q M �Cadm_um 12.90 0. 11 U 10. 0 Comments: • FORM V (Part 2) - IN ILM04 .1 LKB009 S67 PACE ANALYTICAL Date: 25-Apr-14 QC SUMMARY RL4 PORT SDG: LKB009 Spike Sample Recovery RPDRef %RPD Sample ID: Client Sample ID: _ Analyte Result units Amount Result %REC Limits Value %RPD UCL MB-033114 MB-033114 Alkalinity,Total(As CaCO3) <1 MG/L LCS-033114 LCS-033114 Alkalinity,Total(As CaCO3) 24.7 MG/L 25 <1 99 80 1201 1 1403K13-001BMS 14031<13-001BMS Alkalinity,Total(As CaCO3) 50.3 MG/L 25 25.2 101 75 125 1403K13-001BDUP 14031<13-001BDUP Alkalinity,Total(As CaCO3) 25.0 MG/L 25.2 0.80 20 MB-43872 MB-43872 Biochemical Oxygen Demand <2 MG/L LCS-43872 LCS-43872 Biochemical Oxygen Demand 228 MG/L 198 <2 115 85 116 �d - — — 1403J22-001ADUP 1403J22-001ADUP Biochemical Oxygen Demand j 159 MG/L _-�160 0.94 20 MB-040713 11VIB 040713 Bromide I <0.5 MG/L LCS-040713 LCS-040713 Bromide 2.52 MG/L 2.5 <0.5 101 90 110 1404145-001AMS 1404145-001AMS Bromide 0.99 MG/L 1 <0.5 99 80 120 1404145-001ADUP 1404145-001ADUP Bromide <0.5 MG/L <0.5 20 MB-040714 MB-040714 Chemical Oxygen Demand <10 MG/L LCS-040714 LCS-040714 Chemical Oxygen Demand 102 MG/L 100 <10 102 90 110 1403J57-013BMS MW-8SMS Chemical Oxygen Demand 130 MG/L 100 29.9 100 90 110 1403J57-013BDUP MW-8SDUP Chemical Oxygen Demand 30.5 MG/L 29.9 2.1 20 MB-040713 MB-040713 Chloride <�TMGIL LCS-040713 LCS-040713 Chloride 9. MG/L 10 <2 97 90 1101 1 1404145-001AMS 1404145-001AMS Chloride 16.0 MG/L 10 5.18 108 80 120 1404145_001ADUP 1404145-001ADUP Chloride 5.19 MG/L 5.18 0.21 20 MB-040714 MB-040714 Hardness(As CaCO3) <5 MG/L LCS-040714 LCS-040714 Hardness(As CaCO3) 1000 MG/L 1000 <5 10080 120 1403J57-007DMS MW-5DMS Hardness(As CaCO3) 2320 MG/L 2000 360 98 75 1251 1403J57-007DDUP MW-5DDUP Hardness(As CaCO3) 360 MG/L 360 20 1 LKB009 S68 QC SUMMARY REPORT SDG: LKB009 Spike Sample Recovery RPDRef %RPD S:uuple ID: Clicut Sautple ID: �lualytL - Result _Units Amount Resu?t %REC Limits Value %RPD UCL MB-032914 MB-032914 Nitrate as N <0.1 MGIL LCS-032914 LCS 032914 Nitrate as N 1.14 MG/L 1.13 <0.1 101 90 110 1403J57-001BMS MW 1DMS Nitrate as N 9.79 MG/L 5 5.21 92 90 110 1403J57-001BDUP MW-1DDUP Nitrate as N 5.06 MGIL 5.21 2.9 20 M6-032914 MB-032914 Nitrite as N <0.1 MG/L LCS-032914 LCS-032914 Nitrite as N 1.1 MG/L 1 <0.1 101 90 110 1403J57-001ADUP MW-1DDUP Nitrite as N O 0 1 MG/L 0.5 <0.1 104 90 110 <0 1 20] MB-040914 MB-040914 Nitrogen,Ammonia(As N) <0.1 MG/L LCS-040914 LCS-040914 Nitrogen,Ammonia(As N) 1.10 MGIL 1 <0.1 110 90 110 1404524-001 BMS 1404524-001 BMS Nitrogen,Ammonia(As N) 0.47 ^MG/L 0.5 <0.1 94 75 125 1404524-0016DUP 1404524-001 BDUP Nitrogen,Ammonia(As N) <0.1 MG/L <0_1 �20 FMB-43994 MB-43994 Nitrogen,Kjeldahl,Total <0.1 MG/L LCS-43994 LCS-43994 Nitrogen,Kjeldahl,Total 4.33 MGIL 4 <0.1 108 90 110 143994-LFBD 43994-LFBD Nitrogen Kjeldahl,Total 4.42 1 MG/L 4 <0.1 111 75 125 4.38 0.91 20 43994-LFB 43994-LFB Nitrogen Kjeldahl,Tota-I- 4.38 MGIL 4 <0.1 110 75 125 1 MB-43933 MB-43933 Phenolics,Total Recoverable 1 <5 UG/L LCS-43933 LCS-43933 Phenolics,Total Recoverable 31.7UGIL 30 <5 106 80 120 1404189-006AMS 1404189-006AMS Phenolics,Total Recoverable 18.1 UG/L 20 <5 91 75 125 1404189-006ADUP 1404189-006ADUP IPhenolics,Total Recoverable <5 UG/L <5 20 MB-040713 MB-040713 Sulfate I <5 ---MG/L - LCS-040713 LCS-040713 Sulfate9.10 MG/L 10 <5 91 90 110 1403J57-009AMS MW-6DMS Sulfate 1 147 MG/L 50 94.0 107 80 120 1403J57-009ADUP MW-6DDUP Sulfate 94.1 MG/L 94.0 0.1 20 _ - 2 LKB009 S69 � � O QC SUMMARY REPORT SDG: LKB009 Spike Sample Recovery RPDRef %RPD i,, i';i)le 1i): iiCu[ JaR1p1C 11): 11;, 'tc Result Ain.—.it Rcs,At %REC Limits Valve %:RPD UCL -----] MB-040913 MB-040913 Sulfate <5 MGIC CCS-040913 CCS-040913 Sulfate 9.10 MG/L 10 <5 91 90 110 -- - - MB-033014 MB-033014 Total Dissolved Solids < 10 MG/L LCS-033014 LCS-033014 Total Dissolved Solids 280 MG/L 300 < 10 93 80 1120 1403J57-001AMS MW-1DMS Total Dissolved Solids i 536 MG/L 300 229 102 75 1251 1403.157-001ADUP MW-1DDUP Total Dissolved Solids - -_ 230 - MG/L 229 0.44 20 1 MB-040814 MB-040814 Total Organic Carbon <1 MG/� LCS-040814 — ILCS-040814 (Total Organic Carbon 27.6 MG/L 25 <1 110 80 120 MB-040214 MB-040214 Total Organic Carbon <1 MGIC LCS-040214 LCS-040214 Total Organic Carbon 26.5 MG/L 25 < 1 106L1480 120 04012-003AMS 1404012-003AMS Total Organic Carbon 13.3 MG/1. 10 3.2 101 75 125 '1404012-003ADUP 1404012-003ADUP Total Organic Carbon 2.9 MG/L 3.2 11.1 20 3 LKB009 S70 aceLong Island 575 Broad Hollow Road 631.694 3()40 Melville-NY 11747 631.42-3,8436 7. BLANK SUMMARY DATA AND RESULTS 7.1 METALS 7.2 WET CHEMISTRY • • LKB009 S71 • U.S. EPA - CLP 3 BLANKS Lab Name: PACE ANALY--ICAL Contrac::: Lab Code: 10470 Case No. SAS No. : SDG No. : LKB009 Preparation Blank Matrix (soil/water) : WATER Preparation Blank Concentration Units (ug/L or :ng/kg) : UG/L Initial - - - Ca-ib. Continuing Calibration Prepa- Blank Blank (ug/L) ration Analvte (uq/L) C 1 C 2 C 3 C Blank C M Cadmium _ 0.11 U 0.1 U 0.1 U 0.1 U 0.1101 U I P Calcium 25.8 U 25.8 U 25.3, U 25.8 U 25.800 U P Iron 3.9 U 5.0 B 4.4 B 5.2 B 3.900' U P bead ..9 U 1.9 ' U 1.9 U 1.9 U 1.9.00 U P • Magnesium 22-01 U 2_2.0 j U 22.Oj ii 22.0 -1 T 22.000 U P IManganese 0.3 U1 0.Potassium 81.04 U 81.0 j U -98.01 B 81.0 I U 11 C.320j U P - -- - 81.000; U Sodium 146.8j TJ 146.8 U 146.8 U 14 6.8 U 146.860 U P • FORM III - IN ILM04.1 LKB009 S72 U.S. EPA - CLP 3 BL.UdKS Lab Name: PACE ANALYTICAL Contract: Lab Code: 10478 Case No. SAS No. : SCG No. : LKB009 Preparation Blank Matrix (scil/water) : WATER Preparation Blank Concentration Units (ug/L or mg/kg) : UG/L Initial Calib. Continuing Calibration Prepa- Blank Blank (ug/L) ration Analyte (ug/L) C , 1 C 2 C 3 CII Blank C M Cadmium 0.1 I U — - P i Calcium 25.8 I UP +--- Iron 3.9 ' U -- --_ --- P Lead 1.9 U 1.9 U 1. -TU P • Mag nesium - 31 .2 B -- - � P Fla n —an. e _ j 0.3 1 U P -- T jPotassium 81C. U 1 I P Sodium — i 146.8 JU iFORM III - IN ILM04.1 LKB009 S73 PACE ANALYTICAL Date: 25-Apr-14 QC SUMMARY REPORT SDG: LKBO09 Spike Sample Recovery RPDRef %RPD Sample ID: CUM Sample ID: Analyte Result Units Amount Result %REC Limits Value %RPD UCL MB-033114 MB-033114 Alkalinity,Total(As CaCO3) <1 MG/L LCS-033114 LCS-033114 !Alkalinity,Total(As CaCO3) 24.7 MG/L 25 <1 99 80 1201 1403K13-001BMS 14031<13-001BMS Alkalinity,Total(As CaCO3) 50.3 MG& 25 j 25.2 101 75 125 1403K13-0016DUP 1403K13-001BDUP jAlkalinity,Total(As CaCO3) 25.0 MGIL 25.2 0.80 20 MB-43872 IMB-43872 Biochemical Oxygen Demand <2 MGIL -- — --_ — 160 0.94 20 LCS-43872 LCS-43872 Biochemical Oxygen Demand 228 MG/L 198 <2 115 85 116 1403J22-001ADUP j1403J22-001ADUP Biochemical Oxygen Demand 159 MG/L MB-040713 MB-040713 Bromide <0.5 MGIL LCS-040713 ILCS-040713 Bromide2.52 MGIL 2.5 <0.5 101 90 110 1404145-001AMS 14�04145-001AMS Bromide 0.99 MG/L 1 <0.5 99 80 120 1404145-001ADUP 11404145-001ADUP Bromide <0.5 MG/L <0.5 20 MB-040714 IMB-040714 Chemical Oxygen Demand <10 MG/L LCS-040714 LCS-040714 Chemical Oxygen Demand 102 MGIL 100 <10 102 90 110 1403J57-013BMS MW-8SMS Chemical Oxygen Demand 130 MG/L 100 29.9 100 90 110 1403J57-013BDUP [MW-8SDUP Chemical Oxygen Demand 1 30.5 MG/L 29.9 2.1 20 MB-040713 MB-040713 Chloride <2 MG/L LCS-040713 ILCS-040713 Chloride 9.70 MG/L 10 <2 97 90 110 1404145-001AMS 11404145-001AMS Chloride 16.0 MG/L 10 5.18 108 80 120 1404145-001ADUP 1404145-001ADUP Chloridei 5.19 MGIL _ 5.18 0.21 20 MB-040714 MB-040714 Hardness(As CaCO3) <5 MG/L LCS-040714 LCS-040714 Hardness(As CaCO3) 1000 MG/L 1000 <5 100 80 120 f403J57-007DMS MW-5DMS Hardness(As CaCO3) 2320 MG/L 2000 360 98 75 125 1403J57-007DDUP MW-5DDUP Hardness(As CaCO3) 360 MGIL 360 20 1 LKB009 S74 QC SUMMARY REPORT SDG: LKB009 Spike Sample Recovery RPDRef %RPD __SNI pje ID: Clicnt Saitlpje]D: Alla)yte- Resuli Units Amount ResUlt %REC Limits Value %RPD UCL MB-032914 MB-032914 Nitrate as N <0.1 !MjG/L LCS-032914 LCS-032914 Nitrate as N 1.14 1.13 <0.1 101 90 110 1403J57-001BMS MW-1DMS Nitrate as N 9.79 5 5.21 92 90 110 1403J57-001BDUP MW-1DDUP Nitrate as N 5.06 5.21 2.9 20 MB-032914 MB-032914 Nitrite as N -/L --�- LCS-032914 LCS-032914 Nitrite as N 1.01 1 MGIL 1 <0.1 101 90 110 1403J57-001AMS MW-1DM5 Nitrite as N - 0.52 MGIL 0.5 <0.1 104 ! 90 110 1403J57-001ADUP MW-1 DDUP Nitrite as N 1<<0.1 MG/L <0.1 20 MB-040914 M13-040914 Nitrogen,Ammonia(As N) <0.1 MGIL LCS-040914 LCS-040914 Nitrogen,Ammonia(As N) FF, MGIL 1 <0.1 110 90 110 1404524-001BMS 1404524-001BMS Nitrogen,Ammonia(As N) , 0.47 MGlL 0.5 <0.1 94 75 125 1404524-001BDUP 1404524-001BDUP Nitrogen,Ammonia(As N) <0.1 MGlL <0.1 20 MB-43994 MB-43994 Nitrogen,Kjeldahl,Total <0.1 MG/L_____ iLCS-43994 LCS-43994 Nitrogen,Kjeldahl,Total 4.33 MGIL 4 <0.1 108 90 110 143994-LFBD 43994-LFBD Nitrogen,Kjeldahl,Total 4.42 MGIL 4 <0.1 111 75 125 4.38 0.91 20 43994-LFB 43994-LFB _ _ Nitrogen,Kjeldahl,Total 4.38 MGJL 4 j <0.1 110 75 125 -- - MB-43933 MB-43933 FPhenolics,Total Recoverable <5 UGIL LCS-43933 LCS-43933 Phenolics,Total Recoverable 31.7 UGIL 30 <5 106 80 120 1404189-006AMS 1404189-006AMS Phenolics,Total Recoverable 18.1 UGIL 20 <5 91 75 125 1404189-006ADUP 1404189-006ADUP Phenolics,Total Recoverable <5 UGIL <5 20 MB-040713 MB-040713 'Sulfate <5 MGIL LCS-040713 LCS-040713 Sulfate 9.10 MGIL 10 <5 j 91 90 110 1403J57-009AMS MW-6DMS Sulfate 147 MGIL 50 94.0 107 80 120 1403J57-009ADUP MW-6DDUP ISulfate 94.1 MGIL 94.0 0.1 20 LKB009 S76 QC SUMMARY REPORT SDG: LKB009 Spike Sample Recovery RPDRef °%RPD So n IC Ill; IiCtll Sample ll); ic Resilt L'r:..: Ani—it Resit %REC Limits Value %-RPO UCL MB-040913 M3 040913 SulfateE <5 MG/L ILCS-040913 LCS-040913 Sulfate 9.10 MG/L 10 <5 91 90 l 110 - MB-033014 MB-033014 Total Dissolved Solids < 10 MG/L LCS-033014 LCS-033014 Total Dissolved Solids 280 MG/L 300 <10 93 X80 120 1403,157-001AMS MW-1DMS Total Dissolved Solids 536 MG/L 300 229 102 75 125 1403J57-001ADUP MW-1DDUP Total Dissolved Solids 230 MG/L 229 l 0.44 20 MB-040814 --�MB-040814 Total Organic Carbon <1 MG/L Fmc-sLCS-040814 LCS-040814 Total Organic Carbon 27.6 MG/L ' 25 <1 110 80 120 -- MB-040214 MB-040214 mal Organic Carbon < 1 MGIL LCS-040214 LCS-040214 !Total Organic Carbon t 26.5 MGIL 25 < 1 106 80 120 1404012-003AMS 1404012-003AMS !Total Organic Carbon 13.3 MG/L 10 ! 3.2 101 75 125 1404012-003ADUP 1404012-003ADUP (Total Organic Carbon ! 2.9 MG/L 3.2 11.1 20 LKB009 S76