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Home My WebLink About2012 1st Qtr Lockwood, Kessler & Bartlett, Inc. One Aerial Way,Syosset,NY 11791 • Phone:516.938.0600 Fax:516.931.6344 May 15, 2012 LKB #1439-01 Ajay Shah, PE Regional Solid and Hazardous Materials Engineer NYSDEC Region 1 Headquarters Division of Solid and Hazardous Materials SUNY at Stony Brook 50 Circle Road Stony Brook, NY 11790-3409 Re: Town of Southold Landfill, 6155 Cox Lane, Cutchogue, NY 11944 Dear Mr. Shah, The First Quarter 2012 Ground Water-Monitoring Report for the Town of Southold • Landfill is hereby submitted to the Department per 6NYCRR Part 360 requirements. Sincerely, LOCKWOOD, KESSLER & BARTLETT, INC. John B. Gerlach, CGWP, LEP Director of Environmental Sciences C.c. J. Bunchuck, Town of Southold P. Lappano, Lockwood, Kessler & Bartlett, Inc. • CONSULTING ENGINEERS • FIRST QUARTER 2012 GROUND WATER-MONITORING REPORT FOR THE TOWN OF SOUTHOLD LANDFILL 6155 COX LANE CUTCHOGUE, NY 11944 Prepared for: Southold Town Solid Waste Management District 6155 Cox Lane Cutchogue, NY 11944 Prepared by: Lockwood, Kessler & Bartlett, Inc. 1 Aerial Way Syosset, NY 11791 Submitted to: New York State Department of Environmental Conservation Region 1 Headquarters SUNY at Stony Brook 50 Circle Road Stony Brook, NY 11790 0 May 15, 2012 First Quarter 2012 Ground Water-Monitoring Report Town of Southold Landfall, Cutchoque, NY • TABLE OF CONTENTS Section Number and Title Page Number 1.0 INTRODUCTION 1 2.0 METHODS AND PROCEDURES 1 3.0 DISCUSSION OF RESULTS 2 3.1 Water-Level Results 2 3.2 Field Parameter Results 3 3.3 Leachate Indicator Results 4 3.4 Inorganic Parameter Results 5 4.0 CONCLUSIONS AND RECOMMENDATIONS 6 Figure Number and Title Follows Page Number • 1. Site Location Map 1 2. Well Location Map 1 Table Number and Title Follows Page Number 1. Summary of Ground Water-Monitoring Results for 2 First Quarter 2012 Monitoring Round Appendices A. Sample Chain-of-Custody Form and Laboratory Results • i Lockwood, Kessler& Bartlett, Inc. First Quarter 2012 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY • 1.0 INTRODUCTION The Town of Southold has retained Lockwood, Kessler & Bartlett, Inc. (LKB) to perform post-closure ground-water monitoring and reporting for its closed and capped MSW landfill in Cutchogue, NY (Site). The location of the Site is shown in Figure 1. This report is for the first quarter 2012 monitoring round, conducted on March 20, 2012; and describes the work performed and the results obtained. Section 2.0 (Methods and Procedures) details the project requirements and the specific work performed. Section 3.0 (Discussion of Results) summarizes the key findings from this monitoring round, including comparison of the laboratory results to standards and guidance values. Section 4.0 (Conclusions and Recommendations) provides conclusions based on this quarter's results, and recommendations for upcoming quarters. Each report section is supported by figures and/or tables, as appropriate, which follow the page on which they are first referenced. The sample chain-of-custody form and the laboratory results for this monitoring round are provided in Appendix A. 2.0 METHODS AND PROCEDURES Water-level measurements and ground-water samples were collected from the twelve monitoring wells listed below. A site plan showing the locations of the wells is provided in Figure 2. • 0 MW-1 S 0 MW-5S • MW-1 D • MW-5D • MW-3S • MW-6S • MW-3D • MW-6D • MW-4S • MW-8S • MW4D • MW-8D Prior to sampling, the water-level in each well was measured to the nearest 0.01-feet from the top of the well casing utilizing a decontaminated water-level meter. Ground- water samples were collected utilizing a Grundfos RediFlo2 variable-speed electric submersible pump connected to 200 feet of 3/4-inch diameter polyethylene hose on a Keck Reel. Utilizing the well construction records, the pump was placed at the mid-point of each well's screen. Each well was then purged at a low flow rate until its turbidity was less than 5 Nephelometric Turbidity Units (NTUs) and/or field parameter readings stabilized. The sampling apparatus was decontaminated between wells by rinsing its interior and exterior with distilled water. Field parameters were measured utilizing a calibrated YSI 556 Multi-parameter System equipped with a flow-through cell. The ground water purged during sampling was discharged to the land surface at each well location. • 1 Lockwood, Kessler& Bartlett, Inc. • Duck Pond Pt O U N D v N 11958! SITE � REG0N 111 1193 CUTCMOGUE STA. 9 L 1 EAST TTITUCK v s r �r f 4q Cf'N. CEhIETCAY� P CUTCHO 'UE Yax NE o`1 N Cn t0. Rs AD lir. I �y Hfi/ w i n :3 NOR FORK Marsh Pt e a, COONTRY wIC+�' oua MATTITUCK �D W w 3t' CLUB est Cr x s' of i AIRPORT CUTCHOGUE HARBOR o.sr as Cove I _ Marrutooka.Pt �,„6�or � YC. pt. t 1, NEW SUFFOLK FIGURE 1 SITE LOCATION MAP TOWN OF SOUTHOLD LANDFILL, CUTCHOGUE, NY i l i i i L/LAMIML-AF a( \v M p t -3S . 1 - SII r - '- � ± �- ,� S'L;jt•. ' , l � [ r LEGEND y i :/ T1 GROUNDWATER iW-6S MONITORING WELL 300 150 fl 300`+ j � .. — / ( SCALEiNFcET � l j�� ; . . - _ � �•---._-�� >,J`f jt r '�T.-IfF,L _ /-'' / 'NOTE. !VELE SYMBOLS NOT TO PAW tS SCALE / + �1 Note: Base map provided by Town of Southold FIGURE 2 WELL LOCATION PLAN TOWN OF SOUTHOLD LANDFILL, CUTCHOGUE, NY LJ a A&ML-" First Quarter 2012 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY • The ground-water samples were collected directly from the pump discharge hose into new laboratory-supplied bottles of the type required for each specific analysis. A matrix spike/matrix spike duplicate was collected from Well MW-8D. Field notes were recorded in a bound field notebook. Each sample was labeled with the well number, time and date, etc., placed in a cooler with ice to keep it at 4°C, and picked up by the laboratory the next day. Copies of the sample chain-of-custody form and the laboratory results are provided in Appendix A. The samples were analyzed for the 6NYCRR Part 360 Routine Parameters. The field parameters were monitored by LKB. Laboratory analyses were performed by EcoTest Laboratories, Inc. in North Babylon, NY (EcoTest). EcoTest is certified by the New York State Department of Health's Environmental Laboratory Approval Program in all required analytical categories and employs all required internal QA/QC procedures, including analysis of matrix spikes, matrix spike duplicates, method blanks and continuing calibration samples. EcoTest also participates in the required biennial proficiency testing. The field data and laboratory results were reviewed by LKB per QA/QC Plan requirements and determined to be useable. 3.0 DISCUSSION OF RESULTS The field and laboratory results for the first quarter 2012 ground water-monitoring round • are summarized and compared to the New York State Department of Environmental Conservation Ambient Water Quality Standards and Guidance Values for Class GA (Potable) ground water, as applicable, in Table 1. A review of the results for the water- level measurements and each analytical parameter group is provided below. 3.1 Water-Level Results As shown in Table 1, water-table elevations were generally consistent across the Site and ranged from 7.14 feet above mean sea level (MSL) in Well MW-1S, located on the south end of the Site, to 5.02 feet above MSL in Well MW-8S, located on the west side of the Site. These results are consistent with previous water-level measurements, as well as ground-water flow information published by the United States Geological Survey in Scientific Investigations Map 3066, Water Table — Sheet 1 of 4, which indicates a relatively low horizontal hydraulic gradient and a northerly horizontal ground water-flow direction. Based on this information, Well Cluster MW-1 is located upgradient of the Site, and the other wells are located downgradient of various portions of the Site. Except for an anomalously high elevation in Well MW-8D, potentiometric surface elevations in the deeper wells are consistent with the water-table elevations. The results for Well MW-8D are attributed to localized hydrogeologic conditions at this well location and screen depth. • 2 Lockwood, Kessler& Bartlett, Inc. Table 1 Summary of Ground Water-Monitoring Results for First Quarter 2012 Monitoring Round Town of Southold Landfill, Cutchogue, NY NYSDEC Part 360 Units Class GA Well Number and Result Routine Parameters Standard MW-IS MW-1D MW-3S MW-3D MW-4S MW-4D MW-5S MW-5D MW-6S MW-6D MW-8S MW-8D Water-Level Data: T.O.C. Elevation Feet MSL N/A 44.83 44.88 49.50 49.19 63.03 62.92 68.14 67.64 55.77 55.71 54.16 55.29 Depth to Water Feet N/A 37.69 37.62 43.39 43.08 57.39 57.31 _62.58 62.03 49.51 49.46 49.14 47.99 Water-Level Elevation Feet MSL N/A 7.14 7.26 6.11 6.11 5.64 5.61 5.56 5.61 6.26 6.25 5.02 7.30 Field Parameters: Conductivity mS/cm No Standard 0.257 0.298 0.862 1.704 0.649 2.338 0.205 2.242 0.228 0.428 0.903 1.125 Temperature oC No Standard 14.39 13.28 16.48 16.01 16.45 15.42 14.35 14.83 12.68 13.08 16.72 15.55 Floaters or Sinkers N/A None None None None None None None None None None None None None pH Units 6.5-8.5 5.34 6.97 6.34 6.50 6.25 6.74 5.45 6.56 5.70 5.58 6.56 6.38 Eh pHmV No Standard 86.1 -3.3 31.6 23.1 36.7 9.4 80.4 19.1 66.1 72.8 18.0 28.8 Dissolved Oxygen mg/L No Standard 6.26 1.82 0.28 0.34 0.43 0.27 2.75 0.25 0.96 1.80 0.31 0.25 Field Observations N/A No Standard Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor Turbidity NTU <5 1.01 0.81 1.40 0.64 0.28 2.61 2.96 2.21 0.81 0.65 1.61 0.63 ORP mV No Standard 251 10.1 -53.5 -63.2 161 11.3 240 84.9 208 191 -103 -50.5 Leachate Imndicators: Alkalinity mg/L No Standard 14 34 220 560 200 730 32 780 58 14 300 320 • Ammonia mg/L 2 < 0.2 0.2 16 67 0.6 23 1.4 74 5.2 0.6 20 22 BOD mg/L No Standard < 2 < 2 7.4 2.5 < 2 < 2 < 2 < 2 < 2 < 2 3.9 < 2 Bromide mg/L 2Gv < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 Chloride_ _ mg/L 250 32 22 68 130 18 300 18 220 12 34 40 90 COD _ mg/L No Standard < 40 50 < 40 60 50 70 < 40 110 < 40 < 40 50 < 40 Nitrate mg/L 10 7.6 3 < 0.5 < 0.5 15 < 0.5 1.2 < 0.5 4.3 9 < 0.5 < 0.5 Phenols mg/L 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 Sulfate mg/L 250 29 50 35 33 43 55 24 42 14 55 49 55 Total Dissolved Solids mg/L 500 120 150 360 630 370 1,200 73 870 96 260 350 490 Total Organic Carbon mg/L No Standard < 0.5 < 0.5 6.1 16 10 27 < 0.5 27 2.1 < 0.5 9.1 9.3 TKN mg/L No Standard 0.4 1 17 69 1.6 24 2 76 6 1 21 23 Inorganic Parameters: Cadmium mg/L 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 Calcium mg/L No Standard 9.3 22 26 28 70 150 9.2 90 19 36 56 57 Hardness mg/L No Standard 42 94 140 200 230 660 51 370 74 160 220 260 Iron mg/L 0.3 0.04 0.28 67 15 1 0.56 0.08 0.13 0.03 0.02 35 9.8 Lead mg/L 0.025 < 0.005 < 0.005 0.006 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 Magnesium mg/L 35 4.7 10 17 33 13 68 6.8 35 6.3 17 20 29 Manganese mg/L 0.3 0.01 0.01 2.7 2.9 7.4 3.2 0.11 13 2 1.3 0.9 1.6 Potassium mg/L No Standard 4.9 1.5 22 94 29 59 5.8 130 5.4 3.4 40 56 Sodium mg/L 20 25 18 36 97 12 220 11 180 3.9 14 25 58 Notes: • T.O.C. = Top of Casing. COD = Chemical Oxygen Demand. NTU = Nephelometric Turbidity Units. Results in bold font and highlighted in yellow MSL = Mean Sea Level. TKN = Total Kjeldahl Nitrogen. mV = millivolts. exceed Class GA Standard or Guidance Value. ORP = Oxygen Reduction Potential. °C = Degrees Celsius. mg/L = milligrams per Liter. BOD = Biological Oxygen Demand. pHmV = pH in millivolts. N/A = Not Applicable. First Quarter 2012 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY • 3.2 Field Parameter Results Review of the field parameter results in Table 1 indicates the following key findings: • Ground-water conductivity values are higher relative to the main area of Long Island, and may be at least partly attributed to the Site's North Fork location, where naturally higher ground-water salinities may occur due to the proximity to saline surface-water bodies. Conductivities are highest in the deep wells located directly downgradient of the Site. These highest values appear to be Site-related. • Ground-water temperatures are slightly higher in the wells located downgradient of, and in close proximity to, the main area of the Site. • No floaters or sinkers were noted during this monitoring round. • Ground-water pH is generally low, and is less than the minimum standard in seven of the 12 wells. The results are consistent with the naturally low pH of Long Island ground water, and are similar in upgradient and downgradient wells. • The Eh (redox potential) of ground water is positive in 11 of the 12 wells, and the only negative value occurred in the deep well located upgradient of the Site. Therefore, this quarter ground-water Eh does not appear to be significantly influenced by the Site. • Dissolved oxygen concentrations are lower in the downgradient wells than in the upgradient wells, but dissolved oxygen is present in all 12 wells. • The ground water in all 12 wells was observed to be clear, and did not have a noticeable odor this quarter. • The turbidity of ground water is low and was less than 5 Nephelometric Turbidity Units in all 12 wells this quarter. Therefore, the collection of filtered samples for dissolved metals analyses was not required. • The ORP (oxidation-reduction potential) of ground water is slightly positive to strongly positive in eight of the 12 wells; and moderately negative in Well Clusters MW-3 and MW-8, which are located directly downgradient of the main area of the Site. These negative ORP readings appear to be Site-related. Overall, the field parameter results obtained this quarter are consistent with the Site's usage and its North Fork setting. Potential Site-related impacts are relatively minor in magnitude and limited to higher conductivity and temperature, and lower dissolved oxygen levels, and Eh and ORP readings, in certain downgradient wells. • 3 Lockwood, Kessler& Bartlett, Inc. First Quarter 2012 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY 3.3 Leachate Parameter Results Review of the leachate parameter results in Table 1 indicates the following key findings: • Ground-water alkalinity is noticeably higher in most of the downgradient wells relative to the upgradient wells, and is highest in Wells MW-4D and MW-5D. • Ammonia is present in seven downgradient wells at concentrations exceeding the Class GA ground-water standard, and is highest in Wells MW-3D and MW- 5D. • Biological oxygen demand (BOD) is very low to non-detectable in all 12 wells. • Bromide was not detected in any of the wells sampled. • Chloride levels are noticeably higher in five of the downgradient wells relative to the upgradient wells, and higher than the Class GA ground-water standard in Well MW-4D. • Chemical oxygen demand (COD) is slightly higher in three of the downgradient wells relative to the upgradient wells, and is highest in Well MW-5D. • Ground-water nitrate levels are relatively low, and less than the Class GA ground-water standard in every well except Well MW-4S. • Phenols were not detected in any of the wells sampled. • • Sulfate is present at relatively low levels, much lower than the Class GA ground- water standard, in all 12 wells. • Total dissolved solids (TDS) results are noticeably higher in eight of the ten downgradient wells relative to the upgradient wells, and exceed the Class GA ground-water standard in Wells MW-3D, MW-4D and MW-5D. • Total organic carbon (TOC) was detected in eight of the ten downgradient wells. • Total Kjeldahl nitrogen (TKN) is noticeably higher in six of the ten downgradient wells relative to the upgradient wells. Overall, the leachate parameter results obtained this quarter are also consistent with the Site's usage and its North Fork setting. Potential Site-related impacts indicated by these results include downgradient increases in most of the detected parameters. However, it is important to note that 1) the there are no ground-water standards for five of these parameters; 2) most of the downgradient increases occur in a limited number of wells; and 4) approximately one-half of the standard exceedances are relatively minor in magnitude. Moreover, ground water in this area is naturally saline at depth, and ultimately discharges to a saline surface-water body (Long Island Sound). Therefore, the standard exceedances for ammonia, chloride and TDS, which occur naturally in saline ground water and seawater, are not a significant concern with respect to public health or the • environment. 4 Lockwood, Kessler& Bartlett, Inc. First Quarter 2012 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY 3.4 Inorganic Parameter Results Review of the inorganic parameter results in Table 1 indicates the following key findings: • Cadmium was not detected in any of the wells sampled. • Calcium was detected in all 12 wells, and is slightly higher in Wells MW-4S, MW- 4D, MW-51D, MW-8S and MW-81D relative to the upgradient wells. There is no Class GA ground-water standard for this parameter. • Ground-water hardness values are higher in eight of ten downgradient wells relative to the upgradient wells. There is no Class GA ground-water standard for this parameter. • Iron is present in all 12 wells, was detected at concentrations exceeding the Class GA ground-water standard in six downgradient wells, and is highest in Well Clusters MW-3 and MW-8. • Lead was not detected in any of the wells sampled. • Magnesium was detected in all 12 wells, and the level in Well MW-41D is higher than the Class GA ground-water standard. • Manganese was detected in every downgradient well, exceeds the Class GA • ground-water standard in nine of the ten downgradient wells, and is highest in Well MW-51D. • Potassium was detected in all 12 wells. Potassium concentrations are higher in seven of the ten downgradient wells relative to the upgradient wells, and are highest in Wells MW-31D and MW-51D. There is no Class GA ground-water standard for this parameter. • Sodium concentrations are noticeably higher in four of the ten downgradient wells relative to the upgradient wells, and exceed the Class GA ground-water standard in Wells MW-1S, MW-3S, MW-31D, MW-41D, MW-51D, MW-8S and MW- 8D. Overall, the inorganic parameter results obtained this quarter are also consistent with the Site's usage and its North Fork setting. Potential Site-related impacts indicated by these results include downgradient increases in calcium, hardness, iron, magnesium, manganese, potassium and sodium. However, it is important to note that 1) many of these increases are relatively minor in magnitude, sporadic, or less than the Class GA ground-water standard; 2) there are no ground water-quality standards or guidance values for calcium, hardness or potassium; 3) the standards for iron and magnesium are aesthetics-based; and 4) sodium is not considered to be particularly hazardous. Moreover, as noted above in Section 3.2, ground water in this area is naturally saline at depth and ultimately discharges to a saline surface-water body (Long Island Sound). Therefore, the exceedances for sodium, which occurs naturally in saline ground water • and seawater, are not a concern with respect to public health or the environment. 5 Lockwood, Kessler& Bartlett, Inc. First Quarter 2012 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY 4.0 CONCLUSIONS AND RECOMMENDATIONS Based on the results of the first quarter 2012 monitoring round, LKB concludes the following: • Water-level elevations, hydraulic gradients and ground water-flow directions are consistent with local and regional hydrogeologic conditions. • In general, ground water-quality conditions are consistent with the Site's North Fork setting near saline surface-water bodies. • Comparison of upgradient and downgradient results indicates potential Site- related impacts consistent with an old MSW landfill, however further assessment indicates that they are not a significant concern with respect to public health or the environment. The monitoring schedule for the Site requires monitoring ground water for 6NYCRR Part 360 Routine Parameters during three calendar quarters and for Part 360 Baseline Parameters (a more extensive list) during one calendar quarter, in rotating quarters. The most recent round of monitoring for Baseline Parameters was performed during the third quarter of 2011. Therefore, LKB recommends monitoring for Routine Parameters during the first three quarters of 2012, and monitoring for Baseline Parameters during the • fourth quarter of 2012. • 6 Lockwood, Kessler& Bartlett, Inc. C.O EST LABORATORIES, INC. ENVIRONMENTAL TESTING 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422.5777• FAX(631)422-5770 Email: ecotestlab@aol.com Website: www.ecotestiabs.com LAB NO.121019. 14 04/19/12 Lockwood, Kessler & Bartlett 1 Aerial Way Syosset, NY 11791 ATTN: John Gerlach PO#: SOURCE OF SAMPLE: Town of Southold Landfill, #1439-01 SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:03/20/12 RECEIVED:03/21/12 TIME COL'D:1430 MATRIX:Water SAMPLE: MW-1S DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Cadmium as Cd mg/L < 0.005 032712 0.005 EPA200.7 Calcium as Ca mg/L 9.3 032712 0.2 EPA200.7 Iron as Fe mg/L 0.04 032712 0.01 EPA200.7 Lead as Pb mg/L < 0.005 032712 0.005 EPA200.7 Magnesium as Mg mg/L 4.7 032712 0.005 EPA200.7 Manganese as Mn mg/L 0.01 032712 0.01 EPA200.7 Potassium as K mg/L 4.9 032712 1 EPA200.7 • Sodium as Na mg/L 25 032712 1 EPA200.7 Hardness as CaCO3 mg/L 42 032712 0.52 EPA200.7 Tot. Kjeldahl N. mg/L 0.4 032212 0.2 S204500NORB Nitrate as N mg/L 7.6 032212 0.5 EPA353.2 Ammonia as N mg/L < 0.2 032212 0.2 S20450ONH3C Tot Organic Carbon mg/L < 0.5 032312 0.5 S185310C Chloride as Cl mg/L 32 032612 2 S18450OClB Phenols as Phenol mg/L < 0.001 032312 0.001 EPA420. 1 Bromide as Br mg/L < 0.5 * 033012 0.5 EPA300.0 Sulfate as SO4 mg/L 29 032212 5 AS D516 02 COD mg/L < 40 032212 40 EPA410.4 BOD5 mg/L < 2 032112 1500 2 S185210B Tot Dissolved Solids mg/L 120 032212 10 S182540C Alkalinity tot CaCo3 mg/L 14 032612 2 S182320B cc: LRL=Laboratory Reporting Limit REMARKS: * Analysis performed by Summit Labs, NYID#11777. Thomas Powell DIRECTOR_.. rn = 5143 NYSDOH ID # 10320 Page 1 of 1 Analytical malts ml to to the umpla u meeived by dw lebomrory. C0 EST LABORATORIES, INC. ENVIRONMENTAL TESTING 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-5777• FAX(631)422-5770 Email: ecotestlab@aol.com Website: www.ecotestlabs.com LAB NO.121019.13 04/19/12 Lockwood, Kessler & Bartlett 1 Aerial Way Syosset, NY 11791 ATTN: John Gerlach PO#: SOURCE OF SAMPLE: Town of Southold Landfill , #1439-01 SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:03/20/12 RECEIVED:03/21/12 TIME COL'D: 1410 MATRIX:Water SAMPLE: MW-1D DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Cadmium as Cd mg/L < 0.005 032712 0.005 EPA200.7 Calcium as Ca mg/L 22 032712 0.2 EPA200.7 Iron as Fe mg/L 0.28 032712 0.01 EPA200.7 Lead as Pb mg/L < 0.005 032712 0.005 EPA200.7 Magnesium as Mg mg/L 10 032712 0.005 EPA200.7 Manganese as Mn mg/L 0.01 032712 0.01 EPA200.7 Potassium as K mg/L 1.5 032712 1 EPA200.7 • Sodium as Na mg/L 18 032712 1 EPA200.7 Hardness as CaCO3 mg/L 94 032712 0.52 EPA200.7 Tot. Kjeldahl N. mg/L 1 032212 0.2 S204500NORB Nitrate as N mg/L 3 032212 0.5 EPA353.2 Ammonia as N mg/L 0.2 032212 0.2 S204500NH3C Tot Organic Carbon mg/L < 0.5 032312 0.5 S185310C Chloride as Cl mg/L 22 032612 2 S184500CIB Phenols as Phenol mg/L < 0.001 032312 0.001 EPA420. 1 Bromide as Br mg/L < 0.5 * 033012 0.5 EPA300.0 Sulfate as SO4 mg/L 50 032212 5 AS D516 02 COD mg/L 50 032212 40 EPA410.4 BOD5 mg/L < 2 032112 1500 2 S185210B Tot Dissolved Solids mg/L 150 032212 10 S182540C Alkalinity tot CaCo3 mg/L 34 032612 2 S182320B cc: LRL=Laboratory Reporting Limit REMARKS: * Analysis performed by Summit Labs, NYID#11777. • Thomas Powell DIRECTOR_ rn = 5142 NYSDOH ID # 10320 Page 1 of 1 Mdytiul mum relate to the simples as received by the Isbontory. (;OEST LABORATORIES, INC. ENVIRONMENTAL TESTING • 377 SHEFFIELD AVE. a N. BABYLON, N.Y. 11703•.(631)422-6777•FAX(631)422-6770 Email: ecotestlab@aol.com Website: www.ecotestiabs.com LAB NO.121019.02 04/19/12 Lockwood, Kessler & Bartlett 1 Aerial Way Syosset, NY 11791 ATTN: John Gerlach PO#: SOURCE OF SAMPLE: Town of Southold Landfill , #1439-01 SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:03/20/12 RECEIVED:03/21/12 TIME COL'D:0910 MATRIX:Water SAMPLE: MW-3S DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Cadmium as Cd mg/L < 0.005 032712 0.005 EPA200.7 Calcium as Ca mg/L 26 032712 0.2 EPA200.7 Iron as Fe mg/L 67 032712 0.01 EPA200.7 Lead as Pb mg/L 0.006 032712 0.005 EPA200.7 Magnesium as Mg mg/L 17 032712 0.005 EPA200.7 Manganese as Mn mg/L 2.7 032712 0.01 EPA200.7 Potassium as K mg/L 22 032812 10 EPA200.7 Sodium as Na mg/L 36 032712 1 EPA200.7 Hardness as CaCO3 mg/L 140 032712 0.52 EPA200.7 Tot. Kjeldahl N. mg/L 17 032212 0.2 S204500NORB Nitrate as N mg/L < 0.5 032212 0.5 EPA353.2 Ammonia as N mg/L 16 032212 0.2 5204500NH3C Tot Organic Carbon mg/L 6.1 032312 0.5 S185310C Chloride as Cl mg/L 68 032612 4 S184500CIB Phenols as Phenol mg/L < 0.001 032312 0.001 EPA420.1 Bromide as Br mg/L < 0.5 * 033012 0.5 EPA300.0 Sulfate as SO4 mg/L 35 032212 5 AS D516 02 COD mg/L < 40 032212 40 EPA410.4 BODS mg/L 7.4 032112 1500 2 S185210B Tot Dissolved Solids mg/L 360 032212 20 S182540C Alkalinity tot CaCo3 mg/L 220 032612 5 S182320B cc: LRL=Laboratory Reporting Limit REMARKS: * Analysis performed by Summit Labs, NYID#11777. Thomas Powell DIRECTORNlever-- rn = 5131 NYSDOH ID # 10320 Page 1 of 1 Analytical mutts relate to the aatttples as received by the laboratory. COEST LABORATORIES, INC. ENVIRONMENTAL TESTING . 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-67779 FAX(631)422-6770 Email: ecotestlab@aol.com Website: www.ecotestiabs.com LAB NO. 121019.01 04/19/12 Lockwood, Kessler & Bartlett 1 Aerial Way Syosset, NY 11791 ATTN: John Gerlach PO#: SOURCE OF SAMPLE: Town of Southold Landfill, #1439-01 SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:03/20/12 RECEIVED:03/21/12 TIME COL'D:0840 MATRIX:Water SAMPLE: MW-3D DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Cadmium as Cd mg/L < 0.005 032712 0.005 EPA200.7 Calcium as Ca mg/L 28 032712 0.2 EPA200.7 Iron as Fe mg/L 15 032712 0.01 EPA200.7 Lead as Pb mg/L < 0.005 032712 0.005 EPA200.7 Magnesium as Mg mg/L 33 032712 0.005 EPA200.7 Manganese as Mn mg/L 2.9 032712 0.01 EPA200.7 Potassium as K mg/L 94 032812 10 EPA200.7 Sodium as Na Mg/L 97 032712 1 EPA200.7 Hardness as CaCO3 mg/L 200 032712 0.52 EPA200.7 Tot. Kjeldahl N. mg/L 69 032212 0.2 S204500NORB Nitrate as N mg/L < 0.5 032212 0.5 EPA353.2 Ammonia as N mg/L 67 032212 0.2 5204500NH3C Tot Organic Carbon mg/L 16 032312 1 S185310C Chloride as Cl mg/L 130 032612 4 S184500ClB Phenols as Phenol mg/L < 0.001 032312 0.001 EPA420. 1 Bromide as Br mg/L < 0.5 * 033012 0.5 EPA300.0 Sulfate as SO4 mg/L 33 032212 5 AS D516 02 COD mg/L 60 032212 40 EPA410.4 BODS mg/L 2.5 032112 1500 2 S185210B Tot Dissolved Solids mg/L 630 032212 20 S182540C Alkalinity tot CaCo3 mg/L 560 032612 4 S182320B CC'. LRL=Laboratory Reporting Limit REMARKS: * Analysis performed by Summit Labs, NYID#11777. • Thomas Powell DIRECTOR rn = 5130 NYSDOH ID # 10320 Page 1 of 1 Analytical raulu relate to the samples u received by the laboratory. CO EST LABORATORIES, INC. ENVIRONMENTAL TESTING • 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-6777• FAX(631)422-6770 Email: ecotestiab@aol.com Website: www.ecotestlab,s.com LAB NO.121019.06 04/19/12 Lockwood, Kessler & Bartlett 1 Aerial Way Syosset, NY 11791 ATTN: John Gerlach PO#: SOURCE OF SAMPLE: Town of Southold Landfill , #1439-01 SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:03/20/12 REC_EIVED:03/21/12 TIME COL'D: 1115 MATRIX:Water SAMPLE: MW-4S DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Cadmium as Cd mg/L < 0.005 032712 0.005 EPA200.7 Calcium as Ca mg/L 70 032712 0.2 EPA200.7 Iron as Fe mg/L 1.0 032712 0.01 EPA200.7 Lead as Pb mg/L < 0.005 032712 0.005 EPA200.7 Magnesium as Mg mg/L 13 032712 0.005 EPA200.7 Manganese as Mn mg/L 7.4 032712 0.01 EPA200.7 Potassium as K mg/L 29 032812 10 EPA200.7 • Sodium as Na mg/L 12 032712 1 EPA200.7 Hardness as CaCO3 mg/L 230 032712 0.52 EPA200.7 Tot. KJeldahl N. mg/L 1.6 032212 0.2 S204500NORB Nitrate as N mg/L 15 032212 2.5 EPA353.2 Ammonia as N mg/L 0.6 032212 0.2 S20450ONH3C Tot Organic Carbon mg/L 10 032312 0.5 S185310C Chloride as Cl mg/L 18 032612 4 S18450OClB Phenols as Phenol mg/L < 0.001 032312 0.001 EPA420. 1 Bromide as Br mg/L < 0.5 * 033012 0.5 EPA300.0 Sulfate as SO4 mg/L 43 032212 5 AS D516 02 COD mg/L 50 032212 40 EPA410.4 BODS mg/L < 2 032112 1500 2 S185210B Tot Dissolved Solids mg/L 370 032212 10 S182540C Alkalinity tot CaCo3 mg/L 200 032612 2 S182320B cc: LRL=Laboratory Reporting Limit REMARKS: * Analysis performed by Summit Labs, NYID#11777. . Thomas Powell DIRECTOR � � rn = 5135 NYSDOH ID # 10320 Page 1 of 1 Analytical multa ralate to the samples as received by the laboratory. COEST LABORATORIES, INC. ENVIRONMENTAL TESTING 377 SHEFFIELD AVE. - N. BABYLON, N.Y. 11703-.(631)422-6777- FAX(631)422-6770 Email: ecotestlab@aol.com Website: www.ecotestiabs.com LAB NO.121019.05 04/19/12 Lockwood, Kessler & Bartlett 1 Aerial Way Syosset, NY 11791 ATTN: John Gerlach PO#: SOURCE OF SAMPLE: Town of Southold Landfill , #1439-01 SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:03/20/12 RECEIVED:03/21/12 TIME COL'D: 1045 MATRIX:Water SAMPLE: MW-4D DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Cadmium as Cd mg/L < 0.005 032712 0.005 EPA200.7 Calcium as Ca mg/L 150 032712 0.2 EPA200.7 Iron as Fe mg/L 0.56 032712 0.01 EPA200.7 Lead as Pb mg/L < 0.005 032712 0.005 EPA200.7 Magnesium as Mg mg/L 68 032712 0.005 EPA200.7 Manganese as Mn mg/L 3.2 032712 0.01 EPA200.7 Potassium as K mg/L 59 032812 10 EPA200.7 • Sodium as Na mg/L 220 032812 10 EPA200.7 Hardness as CaCO3 mg/L 660 032712 0.52 EPA200.7 Tot. KJeldahl N. mg/L 24 032212 0.2 S204500NORB Nitrate as N mg/L < 0.5 032212 0.5 EPA353.2 Ammonia as N mg/L 23 032212 0.2 S204500NH3C Tot Organic Carbon mg/L 27 032312 2.5 S185310C Chloride as Cl mg/L 300 032612 4 S184500CIB Phenols as Phenol mg/L < 0.001 032312 0.001 EPA420. 1 Bromide as Br mg/L < 0.5 * 033012 0.5 EPA300.0 Sulfate as SO4 mg/L 55 032212 5 AS D516 02 COD mg/L 70 032212 40 EPA410.4 BODS mg/L < 2 032112 1500 2 S185210B Tot Dissolved Solids mg/L 1200 032212 20 S182540C Alkalinity tot CaCo3 mg/L 730 032612 10 S182320B cc: LRL=Laboratory Reporting Limit REMARKS: * Analysis performed by Summit Labs, NYID#11777. • Thomas Powell DIRECTORj�w`Y/ rn = 5134 NYSDOH ID # 10320 Page 1 of 1 Analytical rml4 relate to the umples a rw6ived by the lebommy. CD EST LABORATORIES, INC. ENVIRONMENTAL TESTING • 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-6777• FAX(631)422-6770 Email: ecotestlab@aol.com Website: www.ecotestiabs.com LAB NO.121019.04 04/19/12 Lockwood, Kessler & Bartlett 1 Aerial Way Syosset, NY 11791 ATTN: John Gerlach PO#: SOURCE OF SAMPLE: Town of Southold Landfill , #1439-01 SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:03/20/12 RECEIVED:03/21/12 TIME COL'D: 1020 MATRIX-Water SAMPLE: MW-5S DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Cadmium as Cd mg/L < 0.005 032712 0.005 EPA200.7 Calcium as Ca mg/L 9.2 032712 0.2 EPA200.7 Iron as Fe mg/L 0.08 032712 0.01 EPA200.7 Lead as Pb mg/L < 0.005 032712 0.005 EPA200.7 Magnesium as Mg mg/L 6.8 032712 0.005 EPA200.7 Manganese as Mn mg/L 0.11 032712 0.01 EPA200.7 Potassium as K mg/L 5.8 032712 1 EPA200.7 • Sodium as Na mg/L 11 032712 1 EPA200.7 Hardness as CaCO3 mg/L 51 032712 0.52 EPA200.7 Tot. Kjeldahl N. mg/L 2.0 032212 0.2 S204500NORB Nitrate as N mg/L 1.2 032212 0.5 EPA353.2 Ammonia as N mg/L 1.4 032212 0.2 S204500NH3C Tot Organic Carbon mg/L < 0.5 032312 0.5 S185310C Chloride as Cl mg/L 18 032612 4 S18450OClB Phenols as Phenol mg/L < 0.001 032312 0.001 EPA420.1 Bromide as Br mg/L < 0.5 * 033012 0.5 EPA300.0 Sulfate as SO4 mg/L 24 032212 5 AS D516 02 COD mg/L < 40 032212 40 EPA410.4 BOD5 mg/L < 2 032112 1500 2 S185210B Tot Dissolved Solids mg/L 73 032212 10 S182540C Alkalinity tot CaCo3 mg/L 32 032612 2 S182320B cc: LRL=Laboratory Reporting Limit REMARKS: * Analysis performed by Summit Labs, NYID#11777. ThomasPowell DIRECTOR �"-. rn = 5133 NYSDOH ID # 10320 Page 1 of 1 Analytical rdulte relate to the aamphs as received by Uro laboratory. CO EST LABORATORIES, INC. ENVIRONMENTAL TESTING • 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631) 422-67779 FAX(631)422-5770 Email: ecotestlab@aol.com Website: www.ecotestiabs.com LAB NO.121019.03 04/19/12 Lockwood, Kessler & Bartlett 1 Aerial Way Syosset, NY 11791 ATTN: John Gerlach PO#: SOURCE OF SAMPLE: Town of Southold Landfill , #1439-01 SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:03/20/12 RECEIVED:03/21/12 TIME COL'D:0950 MATRIX:Water SAMPLE: MW-5D DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Cadmium as Cd mg/L < 0.005 032712 0.005 EPA200.7 Calcium as Ca mg/L 90 032712 0.2 EPA200.7 Iron as Fe mg/L 0.13 032712 0.01 EPA200.7 Lead as Pb mg/L < 0.005 032712 0.005 EPA200.7 Magnesium as Mg mg/L 35 032712 0.005 EPA200.7 Manganese as Mn mg/L 13 032712 0.01 EPA200.7 Potassium as K mg/L 130 032812 50 EPA200.7 • Sodium as Na mg/L 180 032812 50 EPA200.7 Hardness as CaCO3 mg/L 370 032712 0.52 EPA200.7 Tot. Kjeldahl N. mg/L 76 032212 0.2 S204500NORB Nitrate as N mg/L < 0.5 032212 0.5 EPA353.2 Ammonia as N mg/L 74 032212 0.2 S20450ONH3C Tot Organic Carbon mg/L 27 032312 1 S185310C Chloride as Cl mg/L 220 032612 2 S184500CIB Phenols as Phenol mg/L < 0.001 032312 0.001 EPA420.1 Bromide as Br mg/L < 0.5 * 033012 0.5 . EPA300.0 Sulfate as SO4 mg/L 42 032212 5 AS D516 02 COD mg/L 110 032212 40 EPA410.4 BOD5 mg/L < 2 032112 1500 2 S185210B Tot Dissolved Solids mg/L 870 032212 25 S182540C Alkalinity tot CaCo3 mg/L 780 032612 4 5182320/3 cc: LRL=Laboratory Reporting Limit REMARKS: * Analysis performed by Summit Labs, NYID#11777. • Thomas Powell DIRECTOR_ _ rn = 5132 NYSDOH ID # 10320 Page 1 of 1 Analytical rewlb relate to the samples as received by the laboratory. CO EST LABORATORIES, INC. ENVIRONMENTAL TESTING 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703.•.(631)422-6777• FAX(631)422-5770 Email: ecotestlab@aol.com Website: www.ecotestlabs.com LAB NO. 121019. 12 04/19/12 Lockwood, Kessler & Bartlett 1 Aerial Way Syosset, NY 11791 ATTN: John Gerlach PO#: SOURCE OF SAMPLE: Town of Southold Landfill, #1439-01 SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:03/20/12 RECEIVED:03/21/12 TIME COL'D: 1330 MATRIX:Water SAMPLE: MW-6S DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Cadmium as Cd mg/L < 0.005 032712 0.005 EPA200.7 Calcium as Ca mg/L 19 032712 0.2 EPA200.7 Iron as Fe mg/L 0.03 032712 0.01 EPA200.7 Lead as Pb mg/L < 0.005 032712 0.005 EPA200.7 Magnesium as Mg mg/L 6.3 032712 0.005 EPA200.7 Manganese as Mn mg/L 2.0 032712 0.01 EPA200.7 Potassium as K mg/L 5.4 032712 1 EPA200.7 Sodium as Na mg/L 3.9 032712 1 EPA200.7 • Hardness as CaCO3 mg/L 74 032712 0.52 EPA200.7 Tot. Kjeldahl N. mg/L 6.0 032212 0.2 S204500NORB Nitrate as N mg/L 4.3 032212 0.5 EPA353.2 Ammonia as N mg/L 5.2 032212 0.2 520450014113C Tot Organic Carbon mg/L 2. 1 032312 0.5 S185310C Chloride as Cl mg/L 12 032612 2 S184500ClB Phenols as Phenol mg/L < 0.001 032312 0.001 EPA420. 1 Bromide as Br mg/L < 0.5 * 033012 0.5 EPA300.0 Sulfate as SO4 mg/L 14 032212 5 AS D516 02 COD mg/L < 40 032212 40 EPA410.4 BODS mg/L < 2 032112 1500 2 S185210B Tot Dissolved Solids mg/L 96 032212 10 S182540C Alkalinity tot CaCo3 mg/L 58 032612 2 51823206 cc: LRL=Laboratory Reporting Limit REMARKS: * Analysis performed by Summit Labs, NYID#11777. • Thomas Powell DIRECTOR_ rn = 5141 NYSDOH ID # 10320 Page 1 of 1 Analytical resuhs relate to the samples as received by the I.bontory. CO EST LABORATORIES, INC. ENVIRONMENTAL TESTING • 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703.•.(631)422-67779 FAX(631)422-6770 Email: ecotestiab@aol.com Website: www.ecotestiabs.com LAB NO.121019.11 04/19/12 Lockwood, Kessler & Bartlett 1 Aerial Way Syosset, NY 11791 ATTN: John Gerlach PO#: SOURCE OF SAMPLE: Town of Southold Landfill , #1439-01 SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:03/20/12 RECEIVED:03/21/12 TIME COL'D: 1300 MATRIX:Water SAMPLE: MW-6D DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Cadmium as Cd mg/L < 0.005 032712 0.005 EPA200.7 Calcium as Ca mg/L 36 032712 0.2 EPA200.7 Iron as Fe mg/L 0.02 032712 0.01 EPA200.7 Lead as Pb mg/L < 0.005 032712 0.005 EPA200.7 Magnesium as Mg mg/L 17 032712 0.005 EPA200.7 Manganese as Mn mg/L 1.3 032712 0.01 EPA200.7 Potassium as K mg/L 3.4 032712 1 EPA200.7 • Sodium as Na mg/L 14 032712 1 EPA200.7 Hardness as CaCO3 mg/L 160 032712 0.52 EPA200.7 Tot. Kjeldahl N. mg/L 1 032212 0.2 S204500NORB Nitrate as N mg/L 9.0 032212 0.5 EPA353.2 Ammonia as N mg/L 0.6 032212 0.2 S204500NH3C Tot Organic Carbon mg/L < 0.5 032312 0.5 S185310C Chloride as Cl mg/L 34 032612 4 S184500CIB Phenols as Phenol mg/L < 0.001 032312 0.001 EPA420.1 Bromide as Br mg/L < 0.5 * 033012 0.5 EPA300.0 Sulfate as SO4 mg/L 55 032212 5 AS D516 02 COD mg/L < 40 032212 40 EPA410.4 BODS mg/L < 2 032112 1500 2 S185210B Tot Dissolved Solids mg/L 260 032212 10 S182540C Alkalinity tot CaCo3 mg/L 14 032612 2 S182320B cc: LRL=Laboratory Reporting Limit REMARKS: * Analysis performed by Summit Labs, NYID#11777. • Thomas Powell DIRECTOR rn = 5140 NYSDOH ID # 10320 Page 1 of 1 AmlylicA exults rotate to dK samples as roaived by the laboratory. a_ CO EST LABORATORIES, INC. ENVIRONMENTAL TESTING is 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-57779 FAX(631)422-5770 Email: ecotestlab@aol.com Website: www.ecotestiabs.com LAB NO.121019.08 04/19/12 Lockwood, Kessler & Bartlett 1 Aerial Way Syosset, NY 11791 ATTN: John Gerlach PO#: SOURCE OF SAMPLE: Town of Southold Landfill, #1439-01 SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:03/20/12 RECEIVED:03/21/12 TIME COL'D: 1220 MATRIX:Water SAMPLE: MW-8S DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Cadmium as Cd mg/L < 0.005 032712 0.005 EPA200.7 Calcium as Ca mg/L 56 032712 0.2 EPA200.7 Iron as Fe mg/L 35 032712 0.01 EPA200.7 Lead as Pb mg/L < 0.005 032712 0.005 EPA200.7 Magnesium as Mg mg/L 20 032712 0.005 EPA200.7 Manganese as Mn mg/L 0.9 032712 0.01 EPA200.7 Potassium as K mg/L 40 032812 10 EPA200.7 • Sodium as Na mg/L 25 032712 1 EPA200.7 Hardness as CaCO3 mg/L 220 032712 0.52 EPA200.7 Tot. Kjeldahl N. mg/L 21 032212 0.2 S204500NORB Nitrate as N mg/L < 0.5 032212 0.5 EPA353.2 Ammonia as N mg/L 20 032212 0.2 S204500NH3C Tot Organic Carbon mg/L 9.1 032312 0.5 S185310C Chloride as C1 mg/L 40 032612 4 S184500CIB Phenols as Phenol mg/L < 0.001 032312 0.001 EPA420. 1 Bromide as Br mg/L < 0.5 * 033012 0.5 EPA300.0 Sulfate as SO4 mg/L 49 032212 10 AS D516 02 COD mg/L 50 032212 40 EPA410.4 BOD5 mg/L 3.9 032112 1500 2 S185210B Tot Dissolved Solids mg/L 350 032212 20 S182540C Alkalinity tot CaCo3 mg/L 300 032612 4 S182320B cc: LRL=Laboratory Reporting Limit REMARKS: * Analysis performed by Summit Labs, NYID#11777. • Thomas Powell DIRECTOR rn = 5137 NYSDOH ID # 10320 Page 1 of 1 Analytical rewlts relate to the samples as received by Ow labmtory. (;OEST LABORATORIES, INC. ENVIRONMENTAL TESTING . 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-6777• FAX(631)422-6770 Email: ecotestlab@aol.com Website: www.ecotestiabs.com LAB NO.121019.09 04/19/12 Lockwood, Kessler & Bartlett 1 Aerial Way Syosset, NY 11791 ATTN: John Gerlach PO#: SOURCE OF SAMPLE: Town of Southold Landfill, #1439-01 SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:03/20/12 RECEIVED:03/21/12 TIME COL'D: 1220 MATRIX:Water SAMPLE: MW-8S MS DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Cadmium as Cd mg/L 0.38 032712 0.005 EPA200.7 Calcium as Ca mg/L 76 032712 0.2 EPA200.7 Iron as Fe mg/L 52 032712 0.01 EPA200.7 Lead as Pb mg/L 0.38 032712 0.005 EPA200.7 Magnesium as Mg mg/L 40 032712 0.005 EPA200.7 Manganese as Mn mg/L 1.3 032712 0.01 EPA200.7 Potassium as K mg/L 45 032812 10 EPA200.7 • Sodium as Na mg/L 30 032712 1 EPA200.7 Hardness as CaCO3 mg/L 360 032712 0.52 EPA200.7 Tot. Kjeldahl N. mg/L 40 032212 0.2 S204500NORB Nitrate as N mg/L 1.3 032212 0.5 EPA353.2 Ammonia as N mg/L 30 032212 0.2 S20450014113C Tot Organic Carbon mg/L 20 032312 1 S185310C Chloride as Cl mg/L 140 032612 4 S184500ClB Phenols as Phenol mg/L 0.029 032312 0.001 EPA420. 1 Bromide as Br mg/L 11 * 033012 0.5 EPA300.0 Sulfate as SO4 mg/L 88 032212 10 AS D516 02 COD mg/L 230 032212 40 EPA410.4 cc: LRL=Laboratory Reporting Limit REMARKS: RESULTS REPORTED ON THIS PAGE REPRESENT SAMPLE AFTER SPIKING (FOR MATRIX SPIKE OR MATRIX SPIKE DUPLICATE) AND DO NOT REPRESENT ACTUAL CONCENTRATIONS DETECTED IN SAMPLE. * Analysis performed by Summit Labs, NYID#11777. iThomas Powell DIRECTOR _ rn = 5138 NYSDOH ID # 10320 Page 1 of 1 Am1)4icd multi rel.te to the umples u received by Um I.bmtmy. CO EST LABORATORIES, INC. ENVIRONMENTAL TESTING • 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703.•.(631)422-5777• FAX(611)422-6770 Email: ecotestlab@aol.com Website: www.ecotestiabs.com LAB NO.121019.10 04/19/12 Lockwood, Kessler & Bartlett 1 Aerial Way Syosset, NY 11791 ATTN: John Gerlach PO#: SOURCE OF SAMPLE: Town of Southold Landfill, #1439-01 SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:03/20/12 RECEIVED:03/21/12 TIME COL'D: 1220 MATRIX:Water SAMPLE: MW-8S MSD DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Cadmium as Cd mg/L 0.38 032712 0.005 EPA200.7 Calcium as Ca mg/L 78 032712 0.2 EPA200.7 Iron as Fe mg/L 53 032712 0.01 EPA200.7 Lead as Pb mg/L 0.39 032712 0.005 EPA200.7 Magnesium as Mg mg/L 41 032712 0.005 EPA200.7 Manganese as Mn mg/L 1.3 032712 0.01 EPA200.7 Potassium as K mg/L 45 032812 10 EPA200.7 Sodium as Na mg/L 30 032712 1 EPA200.7 • Hardness as CaCO3 mg/L 360 032712 0.52 EPA200.7 Tot. Kjeldahl N. mg/L 41 032212 0.2 S204500NORB Nitrate as N mg/L 1.3 032212 0.5 EPA353.2 Ammonia as N mg/L 31 032212 0.2 5204500NH3C Tot Organic Carbon mg/L 21 032312 1 S185310C Chloride as Cl mg/L 140 032612 4 S184500CIB Phenols as Phenol mg/L 0.03 032312 0.001 EPA420.1 Bromide as Br mg/L 10 * 033012 0.5 EPA300.0 Sulfate as SO4 mg/L 84 032212 10 AS D516 02 COD mg/L 220 032212 40 EPA410.4 cc: LRL=Laboratory Reporting Limit REMARKS: RESULTS REPORTED ON THIS PAGE REPRESENT SAMPLE AFTER SPIKING (FOR MATRIX SPIKE OR MATRIX SPIKE DUPLICATE) AND DO NOT REPRESENT ACTUAL CONCENTRATIONS DETECTED IN SAMPLE. * Analysis performed by Summit Labs, NYID#11777. Thomas Powell DIRECTOR rn = 5139 NYSDOH ID # 10320 Page 1 of 1 Analytical reeulu relate to the urnplea u received by the laboratory. CO EST LABORATORIES, INC. ENVIRONMENTAL TESTING 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-57770 FAX(631)422-5770 Email: ecotestlab@aol.com Website: www.ecotestiabs.com LAB NO.121019.07 04/19/12 Lockwood, Kessler & Bartlett 1 Aerial Way Syosset, NY 11791 ATTN: John Gerlach PO#: SOURCE OF SAMPLE: Town of Southold Landfill, #1439-01 SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:03/20/12 RECEIVED:03/21/12 TIME COL'D: 1150 MATRIX:Water SAMPLE: MW-8D DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Cadmium as Cd mg/L < 0.005 032712 0.005 EPA200.7 Calcium as Ca mg/L 57 032712 0.2 EPA200.7 Iron as Fe mg/L 9.8 032712 0.01 EPA200.7 Lead as Pb mg/L < 0.005 032712 0.005 EPA200.7 Magnesium as Mg mg/L 29 032712 0.005 EPA200.7 Manganese as Mn mg/L 1.6 032712 0.01 EPA200.7 Potassium as K mg/L 56 032812 10 EPA200.7 • Sodium as Na mg/L 58 032712 1 EPA200.7 Hardness as CaCO3 mg/L 260 032712 0.52 EPA200.7 Tot. Kjeldahl N. mg/L 23 032212 0.2 S204500NORB Nitrate as N mg/L < 0.5 032212 0.5 EPA353.2 Ammonia as N mg/L 22 032212 0.2 S204500NH3C Tot Organic Carbon mg/L 9.3 032312 0.5 S185310C Chloride as Cl mg/L 90 032612 4 S184500CIB Phenols as Phenol mg/L < 0.001 032312 0.001 EPA420. 1 Bromide as Br mg/L < 0.5 * 033012 0.5 EPA300.0 Sulfate as SO4 mg/L 55 032212 5 AS D516 02 COD mg/L < 40 032212 40 EPA410.4 BOD5 mg/L < 2 032112 1500 2 S185210B Tot Dissolved Solids mg/L 490 032212 20 S182540C Alkalinity tot CaCo3 mg/L 320 032612 4 S182320B cc: LRL=Laboratory Reporting Limit REMARKS: * Analysis performed by Summit Labs, NYID#11777. Thomas Powell DIRECTOR „� io rn = 5136 NYSDOH ID # 10320 Page 1 of 1 Analytical multi relate to the samples as roeeivod by the laboratory. 7At ABORATORIES, INC. - ENVIRONMENTAL TESTIN� Cf�AIN OF CUSTODY RE D 377 Sheffvenue, North Babylon, New York 11703 (631)422-5777-FAX(631)422-5770-Email:ecotestlab@aol.com Client: Lo�K oZ k� r «:�1�� +�� TYP,E&NUMbE—A PCONTAINERS/ 2 (� Address: �CO Phone:5lb-`139-0 Loo FAx:5I1 -A3\-(,344 0 �� y� Person receiving report: -5 AZa� yc`a Sampled by: Source:',,,,,, A- J,�'� � - Job N � 1 o.. 4 MATRIX COLLECTED p (Soil, SAMPLE IIDENTIFICATI,0� '1z v �! -./ ,.r AEM4RKS-TESTS R EM IRE0 . Water,etc.) OATS TIME 3 7o i IU t•1LJ-3S t, s ji 11 i*D-A M.�J- 5 l t t S � 3 lt.j5 I''titil —yS > > 1 � l V\ 4) 1�'�6 s K l�• ;� �J - S r1s t r -A h-3 raw- to S S \ 8 0 M W Relinquished by:(Signature) DATE/TIME SEAL INTACT? Received b :((Signature) Relinquished by:(Signature) DATE/TI SEAL INTACT ZReived by:(Signature) YES NO NA " � e YES NO NARepresenting: Reesenti Representing esenting: rR elnquished by:(Signature) DATE/TIME SEALINTACT? Received by:(Signature) Relinquished by:(Signature) DATE/TIME SEAL INTACT eceived by:(Signature) e resentin YES NO NA p g: p g. YES NO NARepresenting: P g Re Representing: Representing: