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HomeMy WebLinkAbout2011 2nd Qtr Lockwood, Kessler& Bartlett, Inc. One Aerial Way,Syosset,NY 11791 Phone:516.938.0600 Fax:516.931.6344 1 July 28, 2011 LKB #1439-01 Anthony J. Cava, PE ' Regional Solid and Hazardous Materials Engineer NYSDEC Region 1 Headquarters ' Division of Solid and Hazardous Materials SUNY at Stony Brook 50 Circle Road Stony Brook, NY 11790-3409 Re: Town of Southold Landfill, 6155 Cox Lane, Cutchogue, NY 11944 ' Dear Mr. Cava, The Second Quarter 2011 Ground Water-Monitoring Report for the Town of Southold ' Landfill is hereby submitted to the Department per 6NYCRR Part 360 requirements. Sincerely, LOCKWOOD, KESSLER & BARTLETT, INC. '4 'e B. Gerlach, CGWP, LEP Director of Environmental Sciences C.c. J. Bunchuck, Town of Southold Q E � 0� WE ' P. Lappano, Lockwood, Kessler & Bartlett, Inc. AUG - 4 20111 U TOWN OF SOUTHOLD DEPT. OF SOLID WASTE _ CONSULTING ENGINEERS SECOND QUARTER 2011 GROUND WATER-MONITORING REPORT ' FOR THE ' TOWN OF SOUTHOLD LANDFILL 6155 COX LANE ' CUTCHOGUE, NY 11944 Prepared for: Southold Town Solid Waste Management District ' 6155 Cox Lane Cutchogue, NY 11944 ' Prepared by: ' Lockwood, Kessler & Bartlett, Inc. 1 Aerial Way Syosset, NY 11791 Submitted to: ' New York State Department of Environmental Conservation Region 1 Headquarters ' SUNY at Stony Brook 50 Circle Road Stony Brook, NY 11790 July 28, 2011 ' Second Quarter 2011 Ground Water-Monitoring Report Town of Southold Landfill, Cutchoque, NY ' TABLE OF CONTENTS ' Section Number and Title Page Number 1.0 INTRODUCTION 1 ' 2.0 METHODS AND PROCEDURES 1 3.0 DISCUSSION OF RESULTS 2 3.1 Water-Level Results 2 3.2 Field Parameter Results 3 ' 3.3 Leachate Indicator Results 3 3.4 Inorganic Parameter Results 4 ' 4.0 CONCLUSIONS AND RECOMMENDATIONS 5 ' Figure Number and Title Follows Page Number 1. Site Location Map 1 2. Well Location Map 1 Table Number and Title Follows Page Number ' 1. Summary of Results for Second Quarter 2011 Monitoring Round 2 Appendices ' A. Sample Chain-of-Custody Form and Laboratory Results i Lockwood, Kessler& Bartlett, Inc. ' Second Quarter 2011 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY ' 1.0 INTRODUCTION ' The Town of Southold has retained Lockwood, Kessler & Bartlett, Inc. (LKB) to perform post-closure ground-water monitoring and reporting for its closed and capped MSW landfill in Cutchogue, NY (Site). The location of the Site is shown in Figure 1. This report is for the second quarter 2011 monitoring round, conducted on June 16, p q 9 2011; and describes the work performed and the results obtained. Section 2.0 (Methods and Procedures) details the project requirements and the specific work performed. Section 3.0 (Discussion of Results) summarizes the key findings from this monitoring round, including comparison of the laboratory results to standards and guidance values. Section 4.0 (Conclusions and Recommendations) provides conclusions based on this quarter's results, and recommendations for upcoming quarters. Each report section is supported by figures and/or tables, as appropriate, which follow the page on which they are first referenced. The sample chain-of-custody form and the laboratory results for this monitoring round are provided in Appendix A. ' 2.0 METHODS AND PROCEDURES ' Water-level measurements and ground-water samples were collected from the twelve monitoring wells listed below. A site plan showing the locations of the wells is provided in Figure 2. • MW-11S • MW-5S • MW-1 D • MW-5D • MW-3S • MW-6S • MW-3D • MW-6D • MW-4S • MW-8S ' MW4D • MW-8D Prior to sampling, the water-level in each well was measured to the nearest 0.01-feet 1 from the top of the well casing utilizing a decontaminated water-level meter. Ground- water samples were collected utilizing a Grundfos RediFlo2 variable-speed electric submersible pump connected to 200 feet of 3/4-inch diameter polyethylene hose on a ' Keck Reel. Based on well construction records and the water-level measurements, well casing volumes were calculated and a minimum of three well casing volumes was purged from each well prior to sampling. The flow rate was then reduced and field ' parameter readings were allowed to stabilize prior to collecting each sample. Field parameters were measured utilizing a calibrated YSI 556 Multi-parameter System ' equipped with a flow-through cell. The sampling apparatus was decontaminated between wells by rinsing its interior and exterior with distilled water. The ground water purged during sampling was discharged to the land surface at each well location. Lockwood' Kessler& Bartlett, Inc. 1 ' Duck Pond Pt O U N D N 11958 i SITE ' 21 ' ) REG0N y 1193 I � goo ,� CUTCHOGUE STA. "'94 1 EAST TTITUCK p.5 1 N - ! y CE . CEMETERY P.S.� o 1 , cu C H O 'UoE C,lop L .T P a y Ne�k C'I ° L 25 fU pD O rCE OP O 1 H f •! t!: J ' ta� it c R CEDApS RO O - - --- P` o t<� sEIEETWDD 'll ' far � _ � � � sofc�ue - - > c - - OIC f o P �O a • w ' NOR TI{ FORK Marsh pt y COUNTRY s Sr O 11k1 IID r`{• 09k Pi MAIL K. _ OPP = e�G c CLUB est ac<o ` A r AIR� U jw a j CUTCHOG o�1y n� -n aA� Old Cove HARBOR ' n� �DUll�p� MarralookaP1 Spo � Y.C. sr XirrtoQPt.e �4� SON bvON D s zs 0 ' ' l),W711�r 1 ' NEW SUFFOLK ' FIGURE 1 SITE LOCATION MAP =Z. TOWN OF SOUTHOLD LANDFILL, CUTCHOGUE, NY 1M Im = "7 mw ! mwls r ! l L 3 ' �(jt •S� ta_+y�r. ;;t2t,E. t- �i .,Ijr) t:,� ' ;.fill'f' r 4•t i-;ii. l(a .0 4 tillsjt r '- Fq 4 r NW-8 j -L: _ �;w` 3 .. i• 't•: v...e.q`: ♦{ V Y /. .lid� � _ \ ~'•�•��• � �#' ._.� t LEGEND i -sQ ;I{` ` r �-- p GROUNDWATER MW-6S MONrTORING WELL Mw € 300 150 0 300 L SCALE INFEET J .fS `NOTE WELL SYMBOLS NOT TO SCALE ~ == -- }'1 ... : " tG. Note: Base map provided by Town of Southold FIGURE 2 WELL LOCATION PLAN = = TOWN OF SOUTHOLD LANDFILL, CUTCHOGUE, NY M—AEkAmv ' Second Quarter 2011 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY ' Thesam round-water les were then collected directly from the pump discharge hose g p into new laboratory-supplied bottles of the type required for each specific analysis. A ' matrix spike/matrix spike duplicate was collected from Well MW-6D. Field notes were recorded in a bound field notebook. ' Each sample was labeled with the well number, time and date, etc., placed in a cooler with ice to keep it at 4°C, and kept in LKB's custody overnight. They were picked up by ' the laboratory's courier on June 17, 2011 and were delivered to the laboratory that day. Copies of the sample chain-of-custody form and the laboratory results are provided in Appendix A. ' The samples were analyzed for the 6NYCRR Part 360 Routine Parameters. The analyses were performed by EcoTest Laboratories, Inc. in North Babylon, NY (EcoTest). EcoTest is certified by the New York State Department of Health's Environmental Laboratory Approval Program in all required analytical categories and employs all required internal QA/QC procedures, including analysis of matrix spikes, ' matrix spike duplicates, method blanks and continuing calibration samples. EcoTest also participates in the required biennial proficiency testing. The field data and laboratory results were reviewed by LKB per QA/QC Plan requirements and determined ' to be useable. 3.0 DISCUSSION OF RESULTS The field and laboratory results for the second quarter 2011 ground water-monitoring round are summarized and compared to the New York State Department of ' Environmental Conservation Ambient Water Quality Standards and Guidance Values for Class GA (Potable) ground water, as applicable, in Table 1. A review of the results for the water-level measurements and each analytical parameter group is provided below. 3.1 Water-Level Results ' As shown in Table 1, water-level elevations were relatively consistent across the Site and ranged from 6.25 feet above mean sea level (MSL) in Well MW-1 D, located on the south end of the Site, to 4.72 feet above MSL in Well MW-5D, located on the north end ' of the Site. These results are consistent with last quarter's water-level measurements, as well as ground-water flow information published by the United States Geological Survey in Scientific Investigations Map 3066, Water Table — Sheet 1 of 4, which tindicates a relatively low horizontal hydraulic gradient and a northerly horizontal ground water-flow direction. Based on this information, Well Cluster MW-1 is located upgradient of the Site, and the other wells are located downgradient of various portions of the Site. 2 Lockwood, Kessler& Bartlett, Inc. ' Second Quarter 2011 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY 3.2 Field Parameter Results Review of the field parameter results in Table 1 indicates the following key findings: • Ground-water conductivity values are higher relative to the main area of Long ' Island, and are attributed to the Site's North Fork location, where naturally higher ground-water salinities may occur due to the proximity to saline surface-water ' bodies. Conductivities are similar in the upgradient and downgradient wells, so the higher values do not appear to be Site-related. • Ground-water temperatures are slightly higher in the wells located downgradient ' of, and in close proximity to, the main area of the Site. • No floaters or sinkers were noted during this monitoring round. • Ground-water pH is generally low, and is less than the minimum standard in six of the 12 wells, but these results are consistent with the naturally low ground- water pH on Long Island. The higher pH values in certain wells may be Site- related, but are not a concern as they are within the standard range. ' • The Eh (redox potential) of ground water is positive in all 12 wells, and is similar in upgradient and downgradient wells. ' • Dissolved oxygen concentrations are lower in the downgradient wells than in the upgradient wells, but dissolved oxygen is present in all 12 wells. • The ground water in all 12 wells was observed to be clear and had no noticeable odors. • The turbidity of ground water is less than the standard in all 12 wells, and ' collection of filtered samples for dissolved metals analyses was not required. • The ORP (oxidation-reduction potential) of ground water is variable and ranges from moderately positive to strongly negative in both upgradient and ' downgradient wells. Overall, the field parameter results obtained this quarter are consistent with the Site's usage and its North Fork setting. Potential Site-related impacts are relatively minor and limited to higher temperature and pH, and lower dissolved oxygen levels, in certain ' downgradient wells. 3.3 Leachate Parameter Results ' Review of the leachate parameter results in Table 1 indicates the following key findings: ' • Ground-water alkalinity is noticeably higher in most of the downgradient wells relative to the upgradient wells, and is highest in Well MW-5D. • Ammonia is present in six downgradient wells at concentrations exceeding the ground-water standard, and is highest in Well MW-3D. • Biological oxygen demand is very low to non-detectable in all 12 wells. 3 Lockwood, Kessler& Bartlett, Inc. Second Quarter 2011 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY ' • Bromide was not detected in any samples of the les collected. p • Chloride levels are noticeably higher in six of the 10 downgradient wells relative to the upgradient wells, and higher than the standard in Well MW-4S. • Chemical oxygen demand is higher in six of the downgradient wells than in the ' upgradient wells, and is highest in Well MW-51D. • Ground-water nitrate is relatively low, and less than the standard, in all 12 wells. • Phenols were not detected in any of the samples collected. • Sulfate is present at relatively low levels, less than the standard, in all 12 wells. • Total dissolved solids results are higher in eight of the ten downgradient wells ' relative to the upgradient wells, and exceed the standard in Wells MW-31D, MW- 4S and MW-51D. ' • Total organic carbon is higher in nine of the ten downgradient wells relative to the upgradient wells. • Total Kjeldahl nitrogen is higher in eight of the ten downgradient wells relative to the upgradient wells. Overall, the leachate parameter results obtained this quarter are also consistent with the ' Site's usage and its North Fork setting. Potential Site-related impacts indicated by these results include downgradient increases in alkalinity, ammonia, chloride, chemical oxygen demand, total dissolved solids, total organic carbon and total Kjeldahl nitrogen. However, it is important to note that the majority of these increases are relatively minor in magnitude, and that there are no ground water-quality standards or guidance values for four of these seven parameters. Moreover, ground water in this area is naturally ' saline at depth and ultimately discharges to a saline surface-water body (Long Island Sound). Therefore, the relatively minor, sporadic exceedances for ammonia, chloride and total dissolved solids, which occur naturally in saline ground water and seawater, ' are not a concern with respect to public health or the environment. ' 3.4 Inorganic Parameter Results Review of the inorganic parameter results in Table 1 indicates the following key ' findings: • Cadmium was not detected in any of the wells sampled. ' • Calcium levels are slightly higher in Wells MW-4S, MW-41D, MW-51D, MW-8S and MW-81D relative to the upgradient wells. • Hardness is noticeably higher in eight of the ten downgradient wells relative to ' the upgradient wells, and is highest in Well MW-4S. • Iron is present at concentrations exceeding the standard in five of the ten downgradient wells, and is highest in Well MW-3S. • Lead was not detected in any of the wells sampled. 4 Lockwood, Kessler&Bartlett, Inc. ' Second Quarter 2011 Ground Water-Monitoring Report Town of Southold Landfill, Cutchogue, NY • p Magnesium is resent at similar concentrations in upgradient and downgradient g wells, and the levels in Wells MW-1 S, MW-4S and MW-5D exceed the standard. ' • Manganese is present in all 10 downgradient wells at concentrations higher than in the upgradient wells, and exceed the ground-water standard in nine wells. ' . Potassium levels are higher in six of the ten downgradient wells relative to the upgradient wells, and are highest in Well MW-5D. • Sodium concentrations are higher in six of the ten downgradient wells relative to ' the upgradient wells, and exceed the standard in Wells MW-1 S, MW-3S, MW-3D, MW-4S, MW-5D, MW-8S and MW-8D. Overall, the inorganic parameter results obtained this quarter are also consistent with the Site's usage and its North Fork setting. Potential Site-related impacts indicated by these results include downgradient increases in calcium, hardness, iron, manganese, ' potassium and sodium. However, it is important to note that many of these increases are relatively minor in magnitude; that there are no ground water-quality standards or guidance values for calcium, hardness and potassium; that the standards for iron and ' magnesium are aesthetics-based; and that sodium is not considered to be particularly hazardous. Moreover, as noted above in Section 3.3, ground water in this area is naturally saline at depth and ultimately discharges to a saline surface-water body (Long Island Sound). Therefore, the exceedances for sodium, which occurs naturally in saline ground water and seawater, are not a concern with respect to public health or the ' environment. 4.0 CONCLUSIONS AND RECOMMENDATIONS ' Based on the results of the second quarter 2011 monitoring round, LKB concludes the following: ' • Water-level elevations, hydraulic gradients and ground water-flow directions are consistent with local and regional hydrogeologic conditions. In general, ground water-quality conditions are consistent with the Site's North Fork setting near saline surface-water bodies. ' • Comparison of upgradient and downgradient results indicates potential Site- related impacts, however further assessment indicates that they are not a concern with respect to public health or the environment. ' The monitoring schedule for the Site requires monitoring ground water for 6NYCRR Part 360 Routine Parameters during three calendar quarters and for Part 360 Baseline ' Parameters (a more extensive list) during one calendar quarter. During the first two calendar quarters of 2011, monitoring was performed for Part 360 Routine Parameters, and the 2010 Part 360 Baseline Parameter monitoring rounds were performed during the first calendar quarter. Therefore, LKB recommends that the 2011 Part 360 Baseline Parameter monitoring round be performed during the third quarter monitoring round. 5 ' Lockwood Kessler& Bartlett Inc. Table 1 Summary of Ground Water-Monitoring Results for Second Quarter 2011 Monitoring Round Town of Southold Landfill, Cutchogue, NY NYSDEC Part 360 Units Class GA Well Number and Result Routine Parameters Standard MW-1S MW-1D MW-3S MW-3D MW-4S MW-4D MW-5S MW-5D MW-6S MW-6D MW-8S MW-8D Water-Level Data: ' T.O.C. Elevation Feet MSL N/A 44.83 44.88 49.50 49.19 63.03 62.92 68.14 67.64 55.77 55.71 54.16 55.29 Depth to Water Feet N/A 38.70 38.63 44.24 43.90 58.19 58.20 63.33 62.92 50.40 50.37 48.50 50.05 Water-Level Elevation Feet MSL N/A 6.13 6.25 5.26 5.29 4.84 4.72 4.81 4.72 5.37 5.34 5.66 5.24 ' Field Parameters: Conductivity mS/cm No Standard 0.225 5.300 0.944 1.745 2.302 0.511 0.189 2.136 0.153 0.424 0.906 0.966 Temperature oC No Standard 14.33 13.82 17.88 17.47 16.96 16.71 15.45 15.55 12.99 13.64 16.73 17.42 Floaters or Sinkers N/A None None None None None None None None None None None None None pH Units 6.5-8.5 5.34 6.98 6.38 6.67 6.86 6.32 5.53 6.64 5.39 6.15 6.82 6.89 Eh pHmV No Standard 91.7 1.0 30.4 16.0 4.0 34.6 82.3 14.8 90.4 46.2 9.2 18.6 Dissolved Oxygen mg/L No Standard 7.98 2.06 0.24 0.10 0.12 0.37 1.62 0.21 1.07 1.56 0.13 0.13 Field Observations N/A No Standard Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, Clear, ' No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor No Odor Turbidity NTU <5 1.61 4.30 3.14 4.09 3.20 1.96 2.78 1.83 1.39 1.28 2.06 1.27 ORP mV No Standard 76.8 -70.2 -87.4 -60.9 -60.3 30.0 82.9 -2.0 48.1 26.5 -61.2 -128 ' Leachate Imndicators: Alkalinity mg/L No Standard 10 34 280 840 860 180 38 880 48 16 330 300 Ammonia mg/L 2 < 0.2 < 0.2 17 83 21 0.6 < 0.2 72 1.4 0.2 26 24 ' BOD mg/L No Standard < 2 < 2 11 < 3 < 3 < 2 < 2 < 2 < 2 < 2 < 3 < 3 Bromide mg/L 2Gv < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 Chloride mg/L 250 41 22 80 140 500 11 18 220 7 36 78 80 ' COD mg/L No Standard < 40 < 40 70 50 < 40 50 < 40 90 < 40 < 40 60 50 Nitrate mg/L 10 1.5 3.6 < 0.5 < 0.5 < 0.5 7.7 2.3 < 0.5 1.5 8.4 < 0.5 < 0.5 Phenols mg/L 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 < 0.001 Sulfate mg/L 250 26 47 36 29 50 27 29 40 22 21 48 28 Total Dissolved Solids mg/L 500 140 210 370 700 1,300 360 160 990 110 290 490 430 Total Organic Carbon mg/L No Standard 0.6 < 0.5 12 19 21 4.5 1.8 26 1.3 < 0.5 10 13 TKN mg/L No Standard 0.6 0.6 17 88 23 1.4 0.8 75 1.4 0.4 28 26 Inorganic Parameters: ' Cadmium mg/L 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 Calcium mg/L No Standard 8.1 24 28 30 170 59 11 94 16 38 51 61 Hardness mg/L No Standard 38 100 140 200 690 200 68 380 58 160 230 220 Iron mg/L 0.3 0.08 0.24 87 11 0.89 0.03 0.04 0.07 0.03 0.02 7.8 40 Lead mg/L 0.025 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 < 0.005 Magnesium mg/L 35 43 11 18 31 65 13 9.9 36 4.8 17 25 16 Manganese mg/L 0.3 0.01 0.04 2.7 2.8 2.6 9.2 0.17 12 1.6 1.1 1.2 0.33 ' Potassium mg/L No Standard 4.6 1.7 24 110 54 9.3 6.2 130 5.7 3.5 63 34 Sodium mg/L 20 26 19 46 120 230 8.5 10 160 4.7 13 55 42 ' Notes: T.O.C. =Top of Casing. COD = Chemical Oxygen Demand. NTU = Nephelometric Turbidity Units. Results in bold font and highlighted in yellow MSL = Mean Sea Level. TKN =Total Kjeldahl Nitrogen. mV = millivolts. exceed Class GA Standard or Guidance Value. ORP = Oxygen Reduction Potential. °C = Degrees Celsius. mg/L = milligrams per Liter. BOD = Biological Oxygen Demand. pHmV =pH in millivolts. N/A = Not Applicable. ' APPENDIX A Copy of Sample Chain-of-Custody Form and Laboratory Results r i rr rr rr r r ■� � r r r qff"CMAST MOMPORfINCr. • ENVrIRONMrENTAL TESTING CHAIN OF CUSTODY RECORD 377 Sheffield Avenue, North Babylon, New York 11703 (631)1777•FAX(631)422-5770•Email:ecotestlab@aol.com Client: L160, v C• E&NUMBER OF CONTAINERS Address: l (A Id yq �- 0-s.t--e- 11791 Q Phone: ,'-/ ,9V,OdW FAX: `mac Person receiving report: 7o—,V-,j f is J Sampled by: d w Et ;,,,t-C' ? .��' a o- Source: � c� �A m Job No.: P. 6. A,- y MATRIX- COLLECTED J (Soil, ' SAMPLE IDENTIFICATION REMARKS-TESTS REQUfRED Water,etc.) DATETWE Afi 4o Asqq TY10 fflq6l m Am modtA A 101 a S Ob lU&-, "Orb V mw 6S 5 1 l 1 J _ 1/9161 Ian w — IS2. 3 33 . 3 1 -8S / 1 / t w in ish (Si ature) DA�jTE�T,IIME SEAL INTACT? R ved"y:(S* � e ris hesi� (Si nature) DATE(fIME SEAL INTACT? Received by:(Signature) epresenting: 4/4T j/1 , /',/�'� NO NA Re n ,�, ( t/ingW: ✓/ /C/�- YES NO NA Representing: Relinquished by:(Signature) DATE/TIME SEAL INTACT? R eived by:(Signature) Relinquished by:(Signature) DATE/TIME SEAL INTACT? Received by:(Signature) Representing: YES NO NA Representin : Representing: YES NO NA Representing: Ci0 EST LABORATORIES, INC. ENVIRONMENTAL TESTING 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-5777• FAX(631)422-5770 Email: ecotestlab@aol.com Website: www.ecotestlabs.com ' LAB NO.112754.01 07/12111 Lockwood, Kessler & Bartlett 1 Aerial Way Syosset, NY 11791 ATTN: John Gerlach PO#:K-4492 ' SOURCE OF SAMPLE: Town of Southold LF SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:06/16/11 RECEIVED:06/17/11 ' TIME COL'D:1615 MATRIX:Water SAMPLE: MW-1S ' DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Tot. Kjeldahl N. mg/L 0.6 062211 0.2 S204500NORB ' Ammonia as N mg/L < 0.2 062211 0.2 S20450ONH3C Nitrate as N mg/L 1.5 062311 0.5 EPA353.2 COD mg/L < 40 062011 40 EPA410.4 Tot Organic Carbon mg/L 0.6 062211 0.5 S185310C ' Sulfate as SO4 mg/L 26 062111 5 AS D516-02 Alkalinity tot CaCo3 mg/L 10 062211 2 S182320B Phenols as Phenol mg/L < 0.001 062411 0.001 EPA420.1 ' Chloride as C1 mg/L 41 062211 2 S18450OClB Bromide as Br mg/L < 0.5 * 063011 0.5 EPA300.0 Tot Dissolved Solids mg/L 140 062311 10 S182540C ' BOD5 mg/L < 2 061711 1600 2 S185210B Hardness as CaCO3 mg/L 38 062211 0.52 EPA200.7 Cadmium as Cd mg/L < 0.005 062211 0.005 EPA200.7 ' Calcium as Ca mg/L 8.1 062211 0.2 EPA200.7 Iron as Fe mg/L 0.08 062211 0.01 EPA200.7 Lead as Pb mg/L < 0.005 062211 0.005 EPA200.7 ' Magnesium as Mg mg/L 43 062211 0.005 EPA200.7 Manganese as Mn mg/L 0.01 062211 0.01 EPA200.7 Potassium as K mg/L 4.6 062211 1 EPA200.7 Sodium as Na mg/L 26 062211 1 EPA200.7 ' cc: LRL=laboratory Reporting Limit ' REMARKS: * Analysis performed by Summit Labs, NYID#11777. DIRECT ' rn = 16777 NYSDOH ID # 10320 Wage1 of 1 Mdytiul r=fts rchue to Um=Via u received by the hbw&Wy. EMMESTLABORATORIES, INC. ENVIRONMENTAL TESTING ' 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703.•.(631)422-5777• FAX (631)422-5770 Email: ecotestlab@aol.com Website: www.ecotestiabs.com ' LAB NO.112754.02 07/12/11 Lockwood, Kessler $ Bartlett 1 Aerial Way Syosset, NY 11791 ATTN: John Gerlach PO*:K-4492 ' SOURCE OF SAMPLE: Town of Southold LF SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:06/16/11 RECEIVED:06/17/11 ' TINE COUD:1545 MATRIX:Water SAMPLE: MW-11) ' DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Tot. Kjeldahl N. mg/L 0.6 062211 0.2 S204500NORB Ammonia as N mg/L < 0.2 062211 0.2 S20450ONH3C Nitrate as N mg/L 3.6 062311 0.5 EPA353.2 COD mg/L < 40 062011 40 EPA410.4 Tot Organic Carbon mg/L < 0.5 062211 0.5 S185310C Sulfate as SO4 mg/L 47 062111 5 AS D516-02 Alkalinity tot CaCo3 mg/L 34 062211 2 S182320B Phenols as Phenol mg/L < 0.001 062411 0.001 EPA420.1 ' Chloride as Cl mg/L 22 062211 2 S184500018 Bromide as Br mg/L < 0.5 * 063011 0.5 EPA300.0 Tot Dissolved Solids mg/L 210 062311 10 S182540C ' BOD5 mg/L < 2 061711 1600 2 S185210B Hardness as CaCO3 mg/L 100 062211 0.52 EPA200.7 Cadmium as Cd mg/L < 0.005 062211 0.005 EPA200.7 ' Calcium as Ca mg/L 24 062211 0.2 EPA200.7 Iron as Fe mg/L 0.24 062211 0.01 EPA200.7 Lead as Pb mg/L < 0.005 062211 0.005 EPA200.7 Magnesium as Mg mg/L 11 062211 0.005 EPA200.7 Manganese as Mn mg/L 0.04 062211 0.01 EPA200.7 Potassium as K mg/L 1.7 062211 1 EPA200.7 Sodium as Na mg/L 19 062211 1 EPA200.7 ' cc: LRL=Laboratory Reporting Limit ' REMARKS: * Analysis performed by Summit Labs, NYID#11777. ' DIRECTOR ' rn = 16778 NYSDOH ID # 10320 491 1 of 1 AnabftW r min mlrte to the mmpla m reMwd by the Wwamy. EC�EST LABORATORIES, INC. ENVIRONMENTAL TESTING 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703.•.(631)422-57770 FAX(631)422-5770 Email: ecotestlab@aol.com Website: www.ecotestlabs.com LAB NO.112754.03 07/12/11 Lockwood, Kessler & Bartlett 1 Aerial Way ' Syosset, NY 11791 ATTN: John Gerlach P06:K-4492 ' SOURCE OF SAMPLE: Town of Southold LF SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:06/16/11 RECEIVED:06/17/11 ' TIME COL'D:0940 MATRIX:Water SAMPLE: MW-3S DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Tot. Kjeldahl N. mg/L 17 062211 0.2 S204500NORB ' Ammonia as N mg/L 17 062211 0.2 S20450ONH3C Nitrate as N mg/L < 0.5 062311 0.5 EPA353.2 COD mg/L 70 062011 40 EPA410.4 Tot Organic Carbon mg/L 12 062211 0.5 S185310C ' Sulfate as SO4 mg/L 36 062111 5 AS D516-02 Alkalinity tot CaCo3 mg/L 280 062211 2 S182320B Phenols as Phenol mg/L < 0.001 062411 0.001 EPA420.1 ' Chloride as Cl mg/L 80 062211 20 S184500CIB Bromide as Br mg/L < 0.5 * 063011 0.5 EPA300.0 Tot Dissolved Solids mg/L 370 062311 20 S182540C ' BOD5 mg/L 11 061711 1600 2 S185210B Hardness as CaCO3 mg/L 140 062211 0.52 EPA200.7 Cadmium as Cd mg/L < 0.005 062211 0.005 EPA200.7 ' Calcium as Ca mg/L 28 062211 0.2 EPA200.7 Iron as Fe mg/L 87 062211 0.01 EPA200.7 Lead as Pb mg/L < 0.005 062211 0.005 EPA200.7 ' Magnesium as Mg mg/L 18 062211 0.005 EPA200.7 Manganese as Mn mg/L 2.7 062211 0.01- EPA200.7 Potassium as K mg/L 24 062311 10 EPA200.7 Sodium as Na mg/L 46 062211 1 EPA200-3 ' cc: LRL=Laboratory Reporting Limit ' REMARKS: * Analysis performed by Summit Labs, NYID#11777. ' DIRECTOR ' rn = 16779 NYSDOH ID 4 10320 11gi 1 of 1 MdyhcW mmin KWe to the..meta u nmvW by the l bomwy. 7TESTLABORATORIES, INC. ENVIRONMENTAL TESTING ' 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-67770 FAX(631)422-6770 Email: ecotestiab@aol.com Website: www.ecotestlabs.com LAB NO.112754.04 07/12/11 Lockwood, Kessler & Bartlett 1 Aerial Way ' Syosset, NY 11791 ATTN: John Gerlach PO#:K-4492 ' SOURCE OF SAMPLE: Town of Southold LF SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:06/16/11 RECEIVED:06/17/11 TIME COL'D: 1020 ' MATRIX:Water SAMPLE: MW-31) ' DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Tot. Kjeldahl N. mg/L 88 062211 0.2 S204500NORB ' Ammonia as N mg/L 83 062211 0.2 S204500NH3C Nitrate as N mg/L < 0.5 062311 0.5 EPA353.2 COD mg/L 50 062011 40 EPA410.4 Tot Organic Carbon mg/L 19 062211 1 S185310C ' Sulfate as SO4 mg/L 29 062111 5 AS D516-02 Alkalinity tot CaCo3 mg/L 840 062211 20 51823206 Phenols as Phenol mg/L < 0.001 062411 0.001 EPA420.1 Chloride as Cl mg/L 140 062211 2 S184500CIB Bromide as Br mg/L < 0.5 * 063011 0.5 EPA300.0 Tot Dissolved Solids mg/L 700 062311 20 51825400 ' BODS mg/L < 3 061711 1600 3 S185210B Hardness as CaCO3 mg/L 200 062211 0.52 EPA200.7 Cadmium as Cd mg/L < 0.005 062211 0.005 EPA200.7 ' Calcium as Ca mg/L 30 062211 0.2 EPA200.7 Iron as Fe mg/L 11 062211 0.01 EPA200.7 Lead as Pb mg/L < 0.005 062211 0.005 EPA200.7 ' Magnesium as Mg mg/L 31 062211 0.005 EPA200.7 Manganese as Mn mg/L 2.8 062211 0.01 EPA200.7 Potassium as K mg/L 110 062311 10 EPA200.7 Sodium as Na mg/L 120 062311 10 ' EPA200.7 ' cc: LRL=Laboratory Reporting Limit ' REMARKS: * Analysis performed by Summit Labs, NYID#11777. DIRECTOR ' rn = 16780 NYSDOH ID # 10320 Pae 1 of 1 Aadyded mobs mbaa to the umpla u mceivW by lbs MM-Y. ECOIEST LABORATORIES, INC. ENVIRONMENTAL TESTING ' 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-5777• FAX(631)422-5770 Email: ecotestlab@aol.com Website: www.ecotestiabs.com LAB NO.112754.05 07/12/11 Lockwood, Kessler 5 Bartlett 1 Aerial Way ' Syosset, NY 11791 ATTN: John Gerlach PO#:K-4492 ' SOURCE OF SAMPLE: Town of Southold LF SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:06/16/11 RECEIVED:06/17/11 TIME COL'D: 1250 ' MATRIX:Water SAMPLE: MW-4S ' DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Tot. Kjeldahl N. mg/L 23 062211 0.2 S204500NORB ' Ammonia as N mg/L 21 062211 0.2 S20450ONH3C Nitrate as N mg/L < 0.5 062311 0.5 EPA353.2 COD mg/L < 40 062011 40 EPA410.4 Tot Organic Carbon mg/L 21 062211 1 S185310C ' Sulfate as SO4 mg/L 50 062111 5 AS D516-02 Alkalinity tot CaCo3 mg/L 860 062211 20 S182320B Phenols as Phenol mg/L < 0.001 062411 0.001 EPA420.1 ' Chloride as Cl mg/L 500 062211 100 S18450OClB Bromide as Br mg/L < 0.5 * 063011 0.5 EPA300.0 Tot Dissolved Solids mg/L 1300 062311 20 S182540C ' BOD5 mg/L < 3 061711 1600 3 S1852108 Hardness as CaCO3 mg/L 690 062311 5.2 EPA200.7 Cadmium as Cd mg/L < 0.005 062211 0.005 EPA200.7 ' Calcium as Ca mg/L 170 062311 2 EPA200.7 Iron as Fe mg/L 0.89 062211 0.01 EPA200.7 Lead as Pb mg/L < 0.005 062211 0.005 EPA200.7 1 Magnesium as Mg mg/L 65 062211 0.005 EPA200.7 Manganese as Mn mg/L 2.6 062211 0.01. EPA200.7 Potassium as K mg/L 54 062311 10 EPA200.7 Sodium as Na mg/L 230 062311 10 - EPA20U.7 ' cc: LRL=Laboratory Reporting Limit REMARKS: * Analysis performed by Summit Labs, NYID#11777. DIRECT ' rn = 16781 NYSDOH ID # 10320 a e 1 of 1 mWytial maw ml.w to the wmphx a m dvW by the bbamwry- MMESTLABORATORIES, INC. ENVIRONMENTAL TESTING 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631) 422-67770 FAX(631)422-6770 Email: ecotestlab@aol.com Website: www.ecotestiabs.com ' LAB NO.112754.06 07/12/11 Lockwood, Kessler & Bartlett 1 Aerial Way ' Syosset, NY 11791 ATTN: John Gerlach PO#:K-4492 ' SOURCE OF SAMPLE: Town of Southold LF SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:06/16/11 RECEIVED:O6/17/11 ' TIME COL'D: 1230 MATRIX:Water SAMPLE: MMI-4D DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Tot. Kjeldahl N. mg/L 1.4 062211 0.2 S204500NORB Ammonia as N mg/L 0.6 062211 0.2 S204500NH3C ' Nitrate as N mg/L 7.7 062311 0.5 EPA353.2 COD mg/L 50 062011 40 EPA410.4 Tot Organic Carbon mg/L 4.5 062211 0.5 S185310C ' Sulfate as SO4 mg/L 27 062111 5 AS D516-02 Alkalinity tot CaCo3 mg/L 180 062211 2 S182320B Phenols as Phenol mg/L < 0.001 062411 0.001 EPA42O.1 ' Chloride as Cl mg/L 11 062211 2 S184500CIB Bromide as Br mg/L < 0.5 * 063011 0.5 EPA300.0 Tot Dissolved Solids mg/L 360 062311 10 S182540C BODS mg/L < 2 061711 1600 2 S185210B ' Hardness as CaCO3 mg/L 200 062211 0.52 EPA200.7 Cadmium as Cd mg/L < 0.005 062211 0.005 EPA200.7 ' Calcium as Ca mg/L 59 062211 0.2 EPA200.7 Iron as Fe mg/L 0.03 062211 0.01 EPA200.7 Lead as Pb mg/L < 0.005 062211 0.005 EPA200.7 ' Magnesium as Mg mg/L 13 062211 0.005 EPA200.7 Manganese as Mn mg/L 9.2 062211 0.01 EPA200.7 Potassium as K mg/L 9.3 062211 1 EPA200.7 Sodium as Na mg/L 8.5 062211 1 EPA200.7 ' cc: LRL=Laboratory Reporting Limit ' REMARKS: * Analysis performed by Summit Labs, NYID#11777. DIRECTOR ' rn = 16782 NYSDOH ID # 10320 �PW 1 of 1 kWylicd Daubs fob&to the wnpk.=rweivW by dw bibontmy. EMMESTLABORATORIES, INC. ENVIRONMENTAL TESTING ' 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-67779 FAX(631)422-6770 Email: ecotestlab@aol.com Website: www.ecotestiabs.com ' LAB NO.112754.07 07/12/11 Lockwood, Kessler & Bartlett 1 Aerial Way ' Syosset, NY 11791 ATTN: John Gerlach PO#:K-4492 ' SOURCE OF SAMPLE: Town of Southold LF SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:06/16/11 RECEIVED:06/17/11 ' TIME COL'D:1115 MATRIX:Water SAMPLE: MW-5S ' DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Tot. K3eldahl N. mg/L 0.8 062211 0.2 S204500NORB Ammonia as N mg/L < 0.2 062211 0.2 S20450ONH3C Nitrate as N mg/L 2.3 062311 0.5 EPA353.2 COD mg/L < 40 062011 40 EPA410.4 Tot Organic Carbon mg/L 1.8 062211 0.5 S185310C ' Sulfate as SO4 mg/L 29 062111 5 AS D516702 Alkalinity tot CaCo3 mg/L 38 062211 2 S182320B Phenols as Phenol mg/L < 0.001 062411 0.001 EPA420.1 ' Chloride as C1 mg/L 18 062211 2 S1845000lB Bromide as Br mg/L < 0.5 * 063011 0.5 EPA300.0 Tot Dissolved Solids mg/L 160 062311 10 S182540C ' BOD5 mg/L < 2 061711 1600 2 S185210B Hardness as CaCO3 mg/L 68 062211 0.52 EPA200.7 Cadmium as Cd mg/L < 0.005 062211 0.005 EPA200.7 ' Calcium as Ca mg/L 11 062211 0.2 EPA200.7 Iron as Fe mg/L 0.04 062211 0.01 EPA200.7 Lead as Pb mg/L < 0.005 062211 0.005 EPA200.7 ' Magnesium as Mg mg/L 9.9 062211 0.005 EPA200.7 Manganese as Mn mg/L 0.17 062211 0.01 EPA200.7 Potassium as K mg/L 6.2 062211 1 EPA200.7 ' Sodium as Na mg/L 10 062211 1 EPA200.7 cc: LRL=Laboratory Reporting Limit ' REMARKS: * Analysis performed by Summit Labs, NYID#11777. DIRECTOR rn = 16783 NYSDOH ID # 10320 e 1 of 1 An.lytiul mwlu mlue to the ample a mxvee by uw ldwmwy. CO EST LABORATORIES, INC. ENVIRONMENTAL TESTING ' 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-6777• FAX(631)422-6770 Email: ecotestiab@aol.com Website: www.ecotestiabs.com LAB NO.112754.08 07/12/11 Lockwood, Kessler & Bartlett 1 Aerial Way ' Syosset, NY 11791 ATTN: John Gerlach PO*:K-4492 ' SOURCE OF SAMPLE: Town of Southold LF SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:06/16/11 RECEIVED:06/17/11 TIME COL'D:1150 MATRIX:Water SAMPLE: MJ-5D ' DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Tot. Kjeldahl N. mg/L 75 062211 0.2 S204500NORB ' Ammonia as N mg/L 72 062211 0.2 S204500NH3C Nitrate as N mg/L < 0.5 062311 0.5 EPA353.2 COD mg/L 90 062011 40 EPA410.4 Tot Organic Carbon mg/L 26 062211 1 S185310C Sulfate as SO4 mg/L 40 062111 5 AS D516-02 Alkalinity tot CaCo3 mg/L 880 062211 2 S182320B Phenols as Phenol mg/L < 0.001 062411 0.001 EPA420.1 ' Chloride as Cl mg/L 220 062211 2 S1845000lB Bromide as Br mg/L < 0.5 * 063011 0.5 EPA300.0 Tot Dissolved Solids mg/L 990 062311 20 S182540C ' BOD5 mg/L < 2 061711 1600 2 S185210B Hardness as CaCO3 mg/L 380 062211 0.52 EPA200.7 Cadmium as Cd mg/L < 0.005 062211 0.005 EPA200.7 ' Calcium as Ca mg/L 94 062211 0.2 EPA200.7 Iron as Fe mg/L 0.07 062211 0.01 EPA200.7 Lead as Pb mg/L < 0.005 062211 0.005 EPA200.7 ' Magnesium as Mg mg/L 36 062211 0.005 EPA200.7 Manganese as Mn mg/L 12 062211 0.01 EPA200.7 Potassium as K mg/L 130 062311 10 EPA200.7 Sodium as Na mg/L 160 062311 10 ' EPA200.7 ' cc: LRL=Laboratory Reporting Limit ' REMARKS: * Analysis performed by Summit Labs, NYID#11777. ' DIRECTOR rn = 16784 NYSDOH ID 4 10320 4e 1 of 1 AMybcW rowlb r6 to to the ampks u receives by the may. MCOIEST LABORATORIES, INC. ENVIRONMENTAL TESTING ' 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-6777• FAX(631)422-6770 Email: ecotestlab@aol.com Website: www.ecotestiabs.com ' LAB NO.112754.09 07/12/11 Lockwood, Kessler $ Bartlett 1 Aerial Way ' Syosset, NY 11791 ATTN: John Gerlach P06:K-4492 ' SOURCE OF SAMPLE: Town of Southold LF SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:06/16/11 RECEIVED:06/17/11 TIME COL'D: 1435 ' MATRIX:Water SAMPLE: MW-6S ' DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Tot. Kjeldahl N. mg/L 1.4 062211 0.2 S204500NORB ' Ammonia as N mg/L 1.4 062211 0.2 S204500NH3C Nitrate as N mg/L 1.5 062311 0.5 EPA353.2 COD mg/L < 40 062011 40 EPA410.4 Tot Organic Carbon mg/L 1.3 062211 0.5 S185310C ' Sulfate as SO4 mg/L 22 062111 5 AS D516-02 Alkalinity tot CaCo3 mg/L 48 062211 2 S182320B Phenols as Phenol mg/L < 0.001 062411 0.001 EPA420.1 ' Chloride as Cl mg/L 7 062211 2 S1845000lB Bromide'as Br mg/L < 0.5 * 063011 0.5 EPA300.0 Tot Dissolved Solids mg/L 110 062311 10 S182546C ' BODS mg/L < 2 061711 1600 2 S1852108 Hardness as CaCO3 mg/L 58 062211 0.52 EPA200.7 Cadmium as Cd mg/L < 0.005 062211 0.005 EPA200.7 ' Calcium as Ca mg/L 16 062211 0.2 EPA200.7 Iron as Fe mg/L 0.03 062211 0.01 EPA200.7 Lead as Pb mg/L < 0.005 062211 0.005 EPA200.7 ' Magnesium as Mg mg/L 4.8 062211 0.005 EPA200.7 Manganese as Mn mg/L 1.6 062211 0.01' EPA200.7 Potassium as K mg/L 5.7 062211 1 EPA200.7 Sodium as Na mg/L 4.7 062211 1 EPA200.7 ' cc: LRL=Laboratory Reporting Limit ' REMARKS: * Analysis performed by Summit Labs, NYID#11777. DIRECTOR ' rn = 16785 NYSDOH ID 4 10320 ge 1 of 1 Mdyhal maw mode to dw=Mks as receives by uw kbomw y. CO FST LABORATORIES, INC. ENVIRONMENTAL TESTING ' 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-57779 FAX(631)422-5770 Email: ecotestiab@aol.com Website: www.ecotestlabs.com ' LAB NO.112754. 10 07/12/11 Lockwood, Kessler & Bartlett 1 AerialWay ' Syosset, NY 11791 ATTN: John Gerlach PO#:K-4492 ' SOURCE OF SAMPLE: Town of Southold LF SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:06/16/11 RECEIVED:06/17/11 ' TIME COL'D:1410 MATRIX:Water SAMPLE: MW-6D ' DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Tot. Kjeldahl N. mg/L 0.4 062211 0.2 S204500NORB ' Ammonia as N mg/L 0.2 062211 0.2 S20450ONH3C Nitrate as N mg/L 8.4 062311 0.5 EPA353.2 COD mg/L < 40 062011 40 EPA410.4 Tot Organic Carbon mg/L < 0.5 062211 0.5 S185310C ' Sulfate as SO4 mg/L 21 062111 25 AS D516-02 Alkalinity tot CaCo3 mg/L 16 062211 2 S182320B Phenols as Phenol mg/L < 0.001 062411 0.001 EPA420.1 ' Chloride as Cl mg/L 36 062211 2 S184500CIB Bromide as Or mg/L < 0.5 * 063011 0.5 EPA300.0 Tot Dissolved Solids mg/L 290 062311 10 S182540C ' BOD5 mg/L < 2 061711 1600 2 S185210B Hardness as CaCO3 mg/L 160 062211 0.52 EPA200.7 Cadmium as Cd mg/L < 0.005 062211 0.005 EPA200.7 ' Calcium as Ca mg/L 38 062211 0.2 EPA200.7 Iron as Fe mg/L 0.02 062211 0.01 EPA200.7 Lead as Pb mg/L < 0.005 062211 0.005 EPA200.7 ' Magnesium as Mg mg/L 17 062211 0.005 EPA200.7 Manganese as Mn mg/L 1.1 062211 0.01 EPA200.7 Potassium as K mg/L 3.5 062211 1 EPA200.7 ' Sodium as Na mg/L 13 062211 1 EPA200.7 ' cc: LRL=Laboratory Reporting Limit ' REMARKS: * Analysis performed by Summit Labs, NYID#11777. ' DIRECTOR _aO rn = 16786 NYSDOH ID # 10320 �aUe 1 of 1 Atwlyecd raulft mb to to uw. Win a mcai"d by the lWxNAtaY. &COIEST LABORATORIES, INC. ENVIRONMENTAL TESTING 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-6777• FAX(631)422-6770 Email: ecotestiab@aol.com Website: www.ecotestiabs.com ' LAB NO.112754. 11 07/12/11 Lockwood, Kessler & Bartlett 1 Aerial Way ' Syosset, NY 11791 ATTN: John Gerlach PO#:K-4492 ' SOURCE OF SAMPLE: Town of Southold LF SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:06/16/11 RECEIVED:06/17/11 ' TIME COL'D:1410 MATRIX:Water SAMPLE: MW-6D MS ' DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Tot. Kjeldahl N. mg/L 7.8 062211 0.2 S204500NORB ' Ammonia as N mg/L 10 062211 0.2 S204500NH3C Nitrate as N mg/L 9.1 062311 0.5 EPA353.2 COD mg/L 190 062011 40 EPA410.4 Tot Organic Carbon mg/L 10 062211 0.5 S185310C ' Sulfate as SO4 mg/L 39 062111 25 AS D516-02 Phenols as Phenol mg/L 0.029 062411 0.001 EPA420.1 ' Chloride as Cl mg/L 86 062211 2 S1845000lB ' Hardness as CaCO3 mg/L 300 062211 0.52 EPA200.7 Cadmium as Cd mg/L 0.39 062211 0.005 EPA200.7 ' Calcium as Ca mg/L 58 062211 0.2 EPA200.7 Iron as Fe mg/L 21 062211 0.01 FPA200.7 Lead as Pb mg/L 0.38 062211 0.005 EPA200.7 ' Magnesium as Mg mg/L 37 062211 0.005 EPA200.7 Manganese as Mn mg/L 1.4 062211 0.01 EPA200.7 Potassium as K mg/L 9.4 062211 1 EPA200.7 Sodium as Na mg/L 17 062211 1 - EPA200.7 ' cc: LRL=laboratory Reporting Limit ' REMARKS: RESULTS REPORTED ON THIS PAGE REPRESENT SAMPLE AFTER SPIKING FOR (MATRIX SPIKE OR MATRIX SPIKE DUPLICATE) AND DO NOT REPRESENT ACTUAL CONCENTRATIONS DETECTED IN SAMPLE. ' DIRECTOR . 4) ' rn = 16787 NYSDOH ID # 10320 like 1 of 1 AWyticd raWts rekk to the anvke a receives by the bbmtm- E77ESTLABORATORIES, INC. ENVIRONMENTAL TESTING 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-6777• FAX(631)422-6770 Email: ecotestiab@aol.com Website: www.ecotestiabs.com ' LAB NO.112754.12 07/12/11 Lockwood, Kessler & Bartlett 1 Aerial Way Syosset, NY 11791 ATTN: John Gerlach PO#:K-4492 ' SOURCE OF SAMPLE: Town of Southold LF SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:06/16/11 RECEIVED:06/17/11 ' TIME COL'D: 1410 MATRIX:Water SAMPLE: MW-61) MSD ' DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Tot. Kjeldahl N. mg/L 8.0 062211 0.2 S204500NORB ' Ammonia as N mg/L 10 062211 0.2 S204500NI13C Nitrate as N mg/L 9.3 062311 0.5 EPA353.2 COD mg/L 190 062011 40 EPA410.4 Tot Organic Carbon mg/L it 062211 0.5 S185310C ' Sulfate as SO4 mg/L 38 062111 25 AS D516-02 Phenols as Phenol mg/L 0.029 062411 0.001 EPA420.1 ' Chloride as Cl mg/L 84 062211 2 S184500CIB ' Hardness as CaCO3 mg/L 300 062211 0.52 EPA200.7 Cadmium as Cd mg/L 0.39 062211 0.005 EPA200.7 ' Calcium as Ca mg/L 60 062211 0.2 EPA200.7 Iron as Fe mg/L 21 062211 0.01 EPA200.7 Lead as Pb mg/L 0.38 062211 0.005 EPA200.7 ' Magnesium as Mg mg/L 38 062211 0.005 EPA200.7 Manganese as Mn mg/L 1.5 062211 0.011 EPA200.7 Potassium as K mg/L 9.7 062211 1 EPA200.7 Sodium as Na mg/L 17 062211 1 EPA200.7 ' cc: LRL=Laboratory Reporting Limit ' REMARKS: RESULTS REPORTED ON THIS PAGE REPRESENT SAMPLE AFTER SPIKING FOR (MATRIX SPIKE OR MATRIX SPIKE DUPLICATE) AND DO NOT REPRESENT ACTUAL CONCENTRATIONS DETECTED IN SAMPLE. ' DIRECT ' rn = 16788 NYSDOH ID # 10320 age 1 of 1 Atulytle.l sults mWe to the ample a received by We hibo awy. CO EST LABORATORIES, INC. ENVIRONMENTAL TESTING ' 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-67770 FAX(631)422-5770 Email: ecotestiab@aol.com Website: www.ecotestiabs.com ' LAB NO.112754. 13 07/12/11 Lockwood, Kessler & Bartlett 1 Aerial Way ' Syosset, NY 11791 ATTN: John Gerlach PO#:K-4492 ' SOURCE OF SAMPLE: Town of Southold LF SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:06/16/11 RECEIVED:06/17/11 TIME COL'D: 1500 ' MATRIX:Water SAMPLE: MW-8S ' DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Tot. Kjeldahl N. mg/L 28 062211 0.2 S204500NORB Ammonia as N mg/L 26 062211 0.2 S2045OONH3C ' Nitrate as N mg/L < 0.5 062311 0.5 EPA353.2 COD mg/L 60 062011 40 EPA410.4 Tot Organic Carbon mg/L 10 062211 0.5 S185310C ' Sulfate as SO4 mg/L 48 062111 5 AS D516-02 Alkalinity tot CaCo3 mg/L 330 062211 10 51823206 Phenols as Phenol mg/L < 0.001 062411 O.00r EPA420.1 ' Chloride as Cl mg/L 78 062211 2 S184500ClB Bromide as Br mg/L < 0.5 * 062911 0.5 EPA300.0 Tot Dissolved Solids mg/L 490 062311 20 S182540C BODS mg/L < 3 061711 1600 3 S185210B Hardness as CaCO3 mg/L 230 062211 0.52 EPA200.7 Cadmium as Cd mg/L < 0.005 062211 0.005 EPA200.7 ' Calcium as Ca mg/L 51 062211 0.2 EPA200.7 Iron as Fe mg/L 7.8 062211 0.01 EPA200.7 Lead as Pb mg/L < 0.005 062211 0.005 EPA200.7 ' Magnesium as Mg mg/L 25 062211 0.005 EPA200.7 Manganese as Mn mg/L 1.2 062211 0.01 EPA200.7 Potassium as K mg/L 63 062311 10 EPA200.7 Sodium as Na mg/L 55 062211 1 EPA200.7 ' cc: LRL=Laboratory Reporting Limit REMARKS: * Analysis performed by Summit Labs, NYID#11777. ' rn = 16789 NYSDOH ID # 10320 DIRECTOR e 1 of 1 A Wow mwns mWe w the amplea w receives by the W mwy. CO EST LABORATORIES, INC. ENVIRONMENTAL TESTING ' 377 SHEFFIELD AVE. • N. BABYLON, N.Y. 11703•.(631)422-67779 FAX(631)422-6770 Email: ecotestlab@aol.com Website: www.ecotestlabs.com LAB NO.112754.14 07/12/11 Lockwood, Kessler & Bartlett 1 Aerial Way ' Syosset, NY 11791 ATTN: John Gerlach PO#:K-4492 SOURCE OF SAMPLE: Town of Southold LF SOURCE OF SAMPLE: COLLECTED BY: Client DATE COL'D:06/16/11 RECEIVED:06/17/11 ' TIME COL'D:1450 MATRIX:Water SAMPLE: MW-81) ' DATE TIME ANALYTICAL ANALYTICAL PARAMETERS UNITS RESULT FLAG OF ANALYSIS LRL METHOD Tot. Kjeldahl N. mg/L 26 062211 0.2 S204500NORB ' Ammonia as N mg/L 24 062211 0.2 S204500NH3C Nitrate as N mg/L < 0.5 062311 0.5 EPA353.2 COD mg/L 50 062011 40 EPA41O.4 Tot Organic Carbon mg/L 13 062211 0.5 S185310C ' Sulfate as SO4 mg/L 28 062111 5 AS D516-02 Alkalinity tot CaCo3 mg/L 300 062211 2 51823208 Phenols as Phenol mg/L < 0.001 062411 0.001 EPA42O.1 ' Chloride as Cl mg/L 80 062211 4 S18450OClB Bromide as Br mg/L < 0.5 * 062911 0.5 EPA300.0 Tot Dissolved Solids mg/L 430 062311 20 S182540C ' BODS mg/L < 3 061711 1600 3 51852108 Hardness as CaCO3 mg/L 220 062211 0.52 EPA200.7 Cadmium as Cd mg/L < 0.005 062211 0.005 EPA200.7 ' Calcium as Ca mg/L 61 062211 0.2 EPA2O0.7 Iron as Fe mg/L 40 062211 0.01 EPA200.7 Lead as Pb mg/L < 0.005 062211 0.005 EPA2O0.7 ' Magnesium as Mg mg/L 16 062211 0.005 EPA200.7 Manganese as Mn mg/L 0.33 062211 0.01 EPA200.7 Potassium as K mg/L 34 062311 10 EPA200.7 Sodium as Na mg/L 42 062211 1 EPA200.7 ' cc: LRL=Laboratory Reporting Limit ' REMARKS: * Analysis performed by Summit Labs, NYID#11777. ' DIRECT ' rn = 16790 NYSDOH ID # 10320 P Ige 1 of 1 Andydat molts rotate to ft smryks u mcetved by the Lbomimy.