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HomeMy WebLinkAboutFI Water Supply/Watershed 1994I I I I I i ! I I I I I I I I I I I I FINAL REPORT FISHERS ISLAND WATER SUPPLY/WATERSHED STUDY FOR THE FISHERS ISLAND CONSERVANCY, THE SUFFOLK COUNTY HEALTH DEPARTMENT AND THE SUFFOLK COUNTY PLANNING DEPARTMENT MARCH 1994 PREPARED BY A.R. LOMBARDI ASSOCIATES, INC. 25 TERRACE DRIVE VERNON, CT 06066 I I I ! ! ! ! ! I LIST OF TABLES LIST OF FIGURES ACKNOWLEDGMENTS REPORT CHAPTER ONE CHAPTER TWO CHAPTER THREE CHAPTER FOUR CHAPTER FIVE - CHAPTER SIX - CHAPTER SEVEN - CHAPTER EIGHT - CHAPTER NINE - TABLE OF CONTENTS EXECUTIVE SUMMARY, CONCLUSIONS AND RECOMMENDATIONS INTRODUCTION PURPOSE SCOPE OF STUDY STUDY AREA WATER BUDGET AND DESCRIPTION OF EXISTING WATER SUPPLY SYSTEM RESERVOIR WATER QUALITY SAMPLING AMD ANALYSES TEST BORINGS AND MONITORING WELL PROGRAM THE BARLOW POND INFILTRATION GALLERY/UNDERDRAIN HYDROGEOLOGIC SECTION DETERMINATION OF POTENTIAL CONTAMINANT SOURCES WET WEATHER SAMPLING AND ANALYSES TABLE OF CONTENTS (Contd.) CHAPTER TEN TOPOGRAPHIC MAPPING AND DRAINAGE BASIN SURVEY CHAPTER ELEVEN - TYPICAL SEPTIC TANK ANALYSES BIBLIOGRAPHY I I I ! I I I I I I I I i ii I FIGURE 2-1 FIGURE 5-1 FIGURE 5-2 FIGURE 6-1 FIGURE 7-1 FIGURE 7-2 FIGURE 7-3 FIGURE 7-4 LIST OF FIGURES MAP SHOWING STUDY AREAS FISHERS ISLAND WATER SUPPLY SYSTEM WATERSHED STUDY AREA SHOWING SURFICIAL GEOLOGY AND MONITORING WELLS A MAP SHOWING THE INFILTRATION GALLERY (UNDERDRAIN) A MAP SHOWING GEOLOGIC UNITS A MAP SHOWING THE STUDY AREA AND SECTION A-A A GENERALIZED HYDROGEOLOGIC CROSS SECTION A-A OF THE STUDY AREA (SEPTEMBER 1992 CONDITIONS) A GENERALIZED HYDROGEOLOGIC CROSS SECTION A-A OF THE STUDY AREA (1960 DROUGHT CONDITIONS) (Back of Report) (Back of Report) i I I I I I I I ! I i ! ! I I I i i I I 3-1 5-1 5-2 5-3 8-1 8-2 8-3 8-4 9-1 9-2 10-1 APPENDIX A APPENDIX B APPENDIX C APPENDIX D LIST OF TABLES AREAS OF RESERVOIRS, WATERSHEDS AMD AQUIFERS SURFACE WATER ELEVATIONS (MSL) WATER ELEVATION AMD GRADIENT DATA GROUNDWATER PARAMETERS AMALYZED POTENTIAL SOURCES OF POLLUTION WITHIN THE BARLOW POND WATERSHED POTENTIAL SOURCES OF POLLUTION WITHIN THE MIDDLE FARMS POND WATERSHED POTENTIAL SOURCES OF POLLUTION WITHIN THE TREASURE POND WATERSHED POTENTIAL SOURCES OF POLLUTION IN THE WELL FIELD AREA STORMWATER OR WET WEATHER SAMPLING PROGRAM RESERVOIR DRY AMD WET SAMPLING 1992 WATER SURFACE ELEVATIONS (MSL) SAMPLE RESULTS - RESERVOIR SAMPLE RESULTS - STORMWATER RUN-OFF BORING LOGS SAMPLE RESULTS - GROUNDWATER m m i ! ! m i ! I I m I I I ! CHAPTER ONE EXECUTIVE SUMMARY, CONCLUSIONS AND RECOMMENDATIONS Executive Summary The purpose of this study and report is to provide, the Fishers Island Conservancy, the Suffolk County Health Department and the Suffolk County Planning Department with technical information and recommendations for development of rules, regulations and policies for the future preservation of water quality in the three surface water reservoirs and the groundwater aquifers of the Fishers Island public water supply. The work includes a watershed sanitary survey to identify existing and future potential pollution sources. In order to definitively evaluate risks presented by the identified potential contamination sources, the Barlow Pond Infiltration Gallery (underdrain) was located and mapped in addition to potential pollution sources within the watersheds and aquifers of the public water supply. Test borings and monitor wells were installed to determine groundwater flow patterns. Surface water quality and quantity were determined in the field. This data was used to determine the water available from existing sources (reservoirs and wells), wells only, and surface supply for a year having an average rainfall and one for a one hundred year frequency drought. System demand for these analyses were then compared to the Year 2015 requirements. Conclusions As a result of the data provided by the Fishers Island Conservancy and Fishers Island Water Works, the Suffolk County Health Department and our analysis of the water quality data developed during this study, we conclude as follows: 1. The two wells currently pumping water for the entire Island's use on a westerly segment of Middle Farms are certainly adequate for the better m 1_1 part of a calendar year. Because of the huge increase in summer demand, however, and because of the twin dangers of salt-water intrusion and ih~ drawing down of nearby wetland level to a dangerous degree, it would be far better and more conserving of a vital natural resource if the surface water ~reafment plant on Bar/ow Pond [that used to serve the ~nt]re Islan]~ remained on standby and in good working condition - all in readiness ]est a severe drought or the dangers mentioned above damage the Middle Farm~ underground aquifer. 2. The reservoir watersheds have low density seasonally occupied development. There are seventeen (17) residences located within the watersheds and four (4) in the aquifer which have the potential -~minat~ the publi~ water supply. These po~ntSal sources contamination are listed in Tables 8-l, 8-2, 8-3, and 8-4. The location of the identified potential contamination sources are shown on Figure 5-1. 3. The present surface and groundwater quality is typical of water sourc~ in areas of low density development. EPA 502.z analysis fo~ limits specified for ali surface and groundwaters sampled. 4. The ]atoratory analysis for Pesticides and Herbicides yielded negative results at the detection limits for the contaminants specified in the scope of study. 5. Water from Bari.ow Pond, Middle Farms Pond and Island Pond flows the groundwater during years with average to above average rainfall. 6. The Barlow Pond infiltration Gallery has a watershed area of One Hundred Twenty-Seven (327) acres. It lies about two 12! feet above mea~. sea level, passes under a number of glacial kettle holes and appears to be well ~ituated to intercept groundwater flowing seaward from tho Isabella Bluffs area. Flow from the gallery can be controlled by a valve id h~nhole Number 2 near ~arlo~ Pond. 1-2 I I I I 1 I I I I I I I I I I i I t Recommendations It is recommended that the following actions be undertaken: 1. Establish a comprehensive and vigorous watershed and aquifer monitoring, protection and spill prevention plan. 2. Prepare an emergency plan for dealing with contamination of the groundwater or surface supplies. 3. Prepare a Drought Management Plan. 4. To guard against pollution, all present and future water wells in public use, as well as the three surface reservoirs on Fishers Island, should be mapped and tested thoroughly and periodically. The testing (for minerals and pollutive chemicals such as pesticides and herbicides) should be don~ twice a year, with at least one test coming in the summer months, after a heavy rainfall. 5. Replace the missing manhole covers on the Barlow Pond Infiltration Gallery with locking frames and covers. 6. In case of property development and attendant pollution that would compromise the water quality of Barlow Pond, emergency pipelines should be refurbished, prepared, and if necessary constructed to tap alternative surface water supplies. These supplies can be found at Middle Farms Pond, Treasure Pond, and possibly Brickyard Pond. The first two named are already classed as Island reservoirs, and both water quality and quantity are good enough to serve the whole Island in a pinch - even in summer. These emergency pipe ines should be run directly to ~ Barlow Pond pumping station an to Barlow Pond. Certainly both Middle Farms Pond and Treasure Pondlshould maintain their status as surface reservoirs. 7. As a final step to insure clean and plentiful water supplies well into the 21st century, a new back-up well drilling program to supplement the current wells on west Middle Farms could be begun and sponsored by the I 1-3 Fishers Island Water Works, using both this study and previous studies of Fishers Island aquifers as a guide in locating possible well locations It should be emphasized that any back-up wells of this nature, ne matter how prolific, will not and should not cancel out the need for maintaining the Island's surface reservoirs as sources of potable water. On an Island where almost all locations are within 1/4 mile of the sea, any and all well locations are candidates for salt water intrusion and/or dangerous g:':w-down of key wetland habitats. Additional Environmental Issues Several issues have been raised regarding environmental investigations on Fishers Island since the scope of this r~-t was defined and established in our contract. These issues include additional evaluations of the following items listed in order of watershed protection/supply impr. rtance: i. Surface area tributary to the wellfield and potential sources 2. Analysis of monthly billed water, metered production, popnlation, leakage, and other factors influencing historic and future monthly and annual water demand. Brickyard Pond as potential source of surface water supply 4. The Farlow Pond Infiltration Gallery yield and fh~ influence, if any, of the pond near the Chip Dupont residence. 5. The potent]a/ pollution of the Barlow Pond Infiltration Ga~,.rf b'~ the Pickett Landfill. well impacts on adjacent wetlands. 1-4 ! ! I i I II 1 I I I I I I I I i I I CHAPTER TWO INTRODUCTION Purpose The purpose of this report is to provide the Fishers Island Conservancy, The Suffolk County Health Department and The Suffolk County Planning Department, technical information and recommendations which can be used for development of rules, regulations and policies regarding future development within the Fishers Island water supply watersheds; and for preservation of ground and surface water quality. Scope of ~tudy Included in the report are the following ~nvestigat~ons: 1. Evaluate previous reports and data. 2. Determine the dependability of the water supply using a water budget analysis. 3. Determine reservoir responses to rainfall events. 4. Conduct a test boring and monitor well program and evaluate groundwater flow patterns. 5. Investigate the existing infiltration gallery and determine its tributary area. 6. Identify existing potential sources of pollution and pathways to surface and groundwater supplies. 7. Conduct wet weather sampling analysis of stormwater runoff. 2-1 ! I I I I ! ! 1 I I ! I i ! ! i ! I 8. Conduct reservoir water quality sampling and analyses· Review and field edit existing Suffolk County Department of Public Works topographic maps. Study Area The study area is shown on the map in Figure 2-1. It includes the infiltration gallery, the three (3) pond watersheds and the Middle Farms Flats well field. 2-2 I I ! 1 I I I I I I i I I I i I I I CHAPTER THREE WATER BUDGET AND DESCRIPTION OF EXISTING WATER SUPPLY SYSTEM Water Supply System The Fishers Island Water Works System was constructed in the early 1900's to provide potable water and fire protection for the Island. The system services approximately 600 customers utilizing 22 miles of water mains, an equalization reservoir, a surface water treatment plant, a groundwater treatment facility, a well field and three surface water reservoirs. There are no dams. The sources of surface water include Barlow Pond, Middle Farms Pond and Treasure Pond. Barlow Pond has been augmented in the past, especially during the 1960's drought by transferring water from Middle Farms Pond ssing temporary pipes and pumps. Water is pumped directly from Barlow Pond into the treatment plant. The one (1) million gallon per day surface water treatment plant was constructed during the 1920's. The treatment process includes aeration, coagulation, sedimentation, filtration, pH adjustment and disinfection. However, it was removed from service during 1990 and is on stand-by. The plant is located adjacent to, and draws its supply from Barlow Pond. The sources of groundwater supply include the "SIMA" well, the "Church" well and the "Hers" well. The well water is of good quality except for its iron content which is relatively high. Iron effects water taste and odor and can clog well screens. Iron also stains laundry and plumbing fixtures. A groundwater treatment facility was recently constructed near the Middle Farms Flats well field area. This facility provides pH 3-1 adjustment, sequestering of iron and manganese, and disinfection. The treated water is pumped directly into the existing 10" main in East End Road. The untreated well water can be pumped to Middle Farms Pond te augment the surface supply, and to dilute the concentrations that the treatment facility, when operating, would treat. The distribution system consists of mostly unlined cast iron mains, small portion of asbestos cement pipe and about 2,800 feet of recently installed PVC pipe. The 500,000 gallon Chocomount Reservoir maintains the system pressure and provides fire storage. The recent demand on the well field system has been reported by the system operator as 75,000 gallons per day average during the winter and 200,000 gallons per day during the summer season. The annual maximum one- day usage ranged from 557,000 gallons in 1984 to 663,000 gallons in 1987, and have been projected to be 858,000 gallons by the year 2010, provided that development continues at ifs present rate. During 1988, Buuk and Bi~k Engineers of gartfor~, CT prepared s report on the water supply system which suggested that without augmentation by water supply wells, the reservoir supply would not provide an adequate quantity of water during drought conditions if they were similar to the 1960's drought (100 yr frequency). They further concluded that if the water supply was augmented by pumping 250,000 GPD into Middle Farms Pond during August, September and October, storage would be marginal. They finally concluded that if the surface supply was fully augmented by the Middle Farms well field, there would be an adequate supply of water during a 1960's type drought. An alternate groundwater supply of 200,000 gallons per day groundwater was recommended and subsequently implemented. The groundwater quality has been good with the exception of high iron concentrations which has ranged from 0.1 to 13.7 mg/1 (Ref. Appendix of Report on Fishers Island Water Works, Buck and Buck Engineers, Hartford, Conn. Jan. 29, 1988). As previously mentioned, chemicals are used to 3-2 I I I I i I I I I I I I I I i I I ! I sequester the Iron In the d~str~but~on system. HoweYer, thls method is suitable only for concentrations up to 1 mg/1. Iron concentrations in excess of 0.3 mg/1 are unsatisfactory. If manganese is present, the allowable total of iron and manganese is 0.5 mg/1. Water Budqet This section of the report addresses the overall water budget for the Fishers Island Water Works Corporation; and the study area. Barlow Pond, Middle Farms Pond, Treasure Pond and the currently active Middle Farms Flats well field are considered potential sources of water supply in the event of drought conditions. Therefore, the overall water balance will consider all of these water supplies. The water budget can be described algebraically as follows: WS = DP + SR + I - E - ET - Consumption Where WS is Water Surplus DP is Direct Precipitation SR is Surface Run-off ! is Infiltration into the Well Field Cone of Depression E = Evaporation from Pond Surfaces ET = Evapotranspirat]on from Grassed, Brushy or Wooded Tributary Areas C = Consumption including Unaccounted for Water Direct precipitation averages 53 inches (4.42 feet) per year on Fishers Island based upon data presented in the Groundwater, Inc. report 3-3 of April, 1990. Surface run-off for the sandy soils and extremely brushy watershed based upon review of the above mentioned report is about 15%. Many rain events were observed during the field work, however run-off was observed only at the low points of the roadways. No rivelets or temporary streams, other than roadway run-off, were observed. Therefore we believe the surface runoff is about ten (10] percent and have used ten (10) percent in the water budget. Infiltration or recharge of the groundwater table within Middle Farms Flats aquifer is estimated to be 90% of the precipitation which does not transpire or evaporate. Evaporation on Fishers Island ranges from ]2 inches to t7 inches per year according to the aforementioned report, and transpiration is about 9 inches per year. The projected annual consumption rate estimated by the Fishers Island Water Works, Inc. is 87 million gallons for the year 2015. This data was taken from "Report on F~sbers Island Water Works", dated ~n.'~ry 29i ~a~, by Buck & Buck Engineers of Hartford, Connecticut. The areas of the reservoirs and watersheds are listed in Table 3-1. 3-4 I I I i I I I I I I I I I ! I I i TABLE 3-1 AREAS OF RESERVOIRS~ WATERSHEDS AND AQUIFERS DESCRIPTION Barlow Pond Middle Farms Pond Treasure Pond TOTAL POND AREA AREA (Acres) 13.5 38.0 10.7 62.2 Barlow Pond Watershed Middle Farms Pond Watershed Treasure Pond TOTAL WATERSHED AREA 17.8 54.0 22.2 94.0 TOTAL POND AND WATERSHED (NORMAL RAINFALL) BARLOW INFILTRATION GALLERY TOTAL WATERSHED SURFACE SUPPLIES (DROUGHT CONDITION) WELL FIELD RECHARGE AREA 156.2 127.0 283.2 Acres 113.2 TOTAL EXISTING AREA REQUIRING REGULATION 396.4 AJ Water Balance Using All Supply Sources (Year 2015) Normal Rainfall The Water Balance for the Year 2015 is as follows: Surface Supplies 1. Direct Precipitation on Ponds = 4.42 ft x 62.2 Acres x 43,560 sg ftx 7.48 gal/cu ft = 89.6 Million Gal., yr acre 3-5 me Groundwater Run-off to Ponds* = 4.42 ft x 10% x 94.0 Acres x 43,560 sq ft/Acre x yr 7.48 gal/cu ft = Recharge = 90% x (53 in./yr - 26 in./yr) x 12 in./ft 113.2 Acres x 43,560 sq ft /Acre x 7.48 gal/cu ft Less Evaporation from Ponds = 17 in./~r x 56.1 Acres x 12 in./ft 43,560 sq ft/Acre x 7.48 gal/cu ft = 5. Less Consumption Year 2015 (Buck & Buck) SURPLUS B. Water Balance Well Field Only (Year 2015) Normal Rainfall A water balance for only the well field yields the following: Recharge of the Well Field (From A-3) Less Consumption Year 2015 (From A-5) DEFICIT 13.5 Million Gal./yr 74.7 Million Gal./yr <28.7 Million Gal./yr> <87.0 Million Gal./yr> 6~., Mill~n Gal..~'z' 74.7 Million Gal./yr <87.0 Million Gal./yr> <12.3 Million Gal./yr> *Assumes no contribution from Barlow Pond Infiltration Gallery. 3-6 I I I I I I I I I I I I I I I I I I I C. Water Balance for the Well Fields Plus Middle Farms Pond (Year 2015) Normal Rainfall Assuming the Well Field induces infiltration from Middle Farms Pond, the year 2015 balance is as follows: Surface Supply Direct Precipitation on Middle Farms Pond - 4.42 f__t x 38.0 Acres x 43,560 sq ftx 7.48 gal/cu ft yr Acres 54.7 Million Gal./yr Run-off = 4.42 ft x 10% x 54 Acres x yr 43,560 sq ft/Acre x 7.48 gal/cu ft 7.8 Million Gal./yr Groundwater 3. Well Field Recharge (From A-3) = 74.7 Million Gal./yr Evaporation ~ 1.42 ft x 38.0 Acres x yr 43,560 sq ft x 7.48 gal/cu ft ~ Acre <17.6 Million Gal./yr> TOTAL 119.6 Million Gal./yr 5. Less Year 2015 Consumption (From A-5) ~ <87.0 Million Gal./yr> SURPLUS 32.6 Million Gal./yr The Well Field requires induced infiltration from Middle Pond Farms Pond to provide for future water consumption. 3-7 D. Water Balance for the 100 yr Drought Condition, for Ail Sources (Year 2015) Drought Conditions The 100 percentile probable drought precipitation is 36.39 inches or 3.03 feet. The water budget for the year 2015 assuming a 100 yr drought occurs and all sources are utilized is as follows: Direct precipitation on the ponds = 3.03 ft x 62.2 acres x 43,560 sq ft/Acre x yr 7.48 gal/cu ft = 61.4 Million Gal./yr me Run-off to ponds = 3.03 ft x 10% x 94.0 Acres x 43,560 sq. ft. x yr Acre 7.48 gal/cu ft = 9.3 Million Gal./yr me Barlow Infiltration Gallery 3.03 f_~t x 10% x 127 Acre x 43,560 sq ft/Acre yr 7.48 gal/cu ft = 12.5 Million Gal./yr t Recharge to Well Field = 90% x (36.4 in./yr - 26 in./yr) x 113.2 Acres x 12 in./ft 43,560 sq ft/Acre x 7.48 gal/cu ft 28.8 Million Gal./yr 5. Less Evaporation from Ponds (From A-4) ~ <28.7 Million Gal./yr> 3-8 ! I I I I I I I I I I I I I I I I I 6. Less Consumption Year 2015 (From A-5) = DEFICIT = E. Water Balance 100 yr Drought Condition Year 2015 <87.0 Million Gal./yr~ <3.7 Million In summary, during a prolonged drought period, the total surface and ground water supplies would be taxed. During a severe drought, the usable pond storage which has been estimated by Buck and Buck, Inc. to be 114 million gallons would be utilized. The water budget during a drought using the Well Field and assuming induced infiltration will occur from Middle Farms Pond would yield the following: 1. Well Field Recharge (From D-4) 28.8 Million Gal./yr Direct Precipitation on Middle Farms Pond = 3.03 ft x 38.0 Acres x 43,560 sg ftx yr acre 7.48 gal/cu ft = 37.5 Million Oal./yr Run-off = 3.03 ft x 10% x 54 Acres x yr 43,560 sg ft x 7.48 gal/cu ft = 5.3 Million Gal./yr 4. Evaporation (From C-4) = <17.6 Million Gal./yr] 5. Less Year 2015 Consumption (From A-5) DEFICIT Drought During Year 2015 Well Field Only <87.0 Million Gal./yr~ <33.0 Million Gal./yr] I 3-9 1. Well Field Recharge (From D-4) 2, Consumption Year 2015 (From A-5) DEFICIT = 28.8 Million Gal,/y~ <87.0 Million Gal./y · ~58.2 Milli~t Gal./y The Well Field alone cannot supply enough water during drought periods even if induced infiltration takes place. The worst case would be without induced infiltration during a drought for the demand of the year 2015, The well field would supply 28.8 million gallons of water and the annual consumption would be 87 million gallons or a deficit of 58.2 million gallons would occur. It can be concluded that the surface water treatment plant must remain on stand-by. 3-10 I I I I I I I I I I I I I I I I I '1 I CHAPTER FOUR RESERVOIR WATER QUALITY SAMPLING AND ANALYSES Introduction Barlow Pond, Middle Farms Pond and Treasure Pond were sampled during September 16, 1992 (after a period without rainfall), and September 24, 1992 (after rainfall). The sample locations are shown on Figure 5-1. The samples were obtained at the centers of the ponds as shown on Figure 5-1 and were taken from mid-depth, based upon the assumption that the ponds are shallow and complete mixing of the water occurs. The depths at the centers of Barlow Pond, Middle Farms Pond and Treasure Pond were found to be 24 feet, 21 feet and 12 feet respectively. (The ponds are deeper than previously assumed.) Samples were obtained at mid-depth utilizing 1/2 gallon sampling equipment and weights. The samples were analyzed for physical constituents temperature, color, odor, pH, turbidity, sediment, conductivity, and total solids. Chemical constituents sampled were nitrogen, chloride, alkalinity, hardness, Free C02, iron, manganese, phosphate, and sodium. Bacteriological analyses included total coliforms, fecal coliform and fecal streptococcus. Description The color of Barlow Pond was six times the allowable limit of 15 units at 90 units, Middle Farms Pond was 20 units and Treasure Pond was 5 units. Total solids were in the range of 70 mg/1 for all three ponds. Nitrogen for all three water bodies was typical for small northeastern reservoirs with low density developed watersheds on both sampling occasions. 4-1 Chlorides were in a similar range for all three ponds. The chloride content of about 30 mq/1 is relatively high for surface waters in rural areas as was the specific conductance. However, the proximity of the pond to the ocean and the associated aerosol transportation of chlorides most probably accounts for the anomaly. The alkalinity of the three pond~ w~s low and the waters may be classified as soft or very soft. The iron content of Barlow Pond is high at 0.84 ppm (the maximum for potable water is 0.3 Ag/l) whereas Middle Farms Pond was lower at 0.16 ppm and Treasure Pond was very low at less than 0.01 mg/1. The existence of high iron concentrations in Barlow Pond are, according to the Suffolk County Department of Health Services, Bureau of Drinking Water, relatively well understood. The iron is thought to result from the long practice of disposing of waste backwash water from the filters at the surface water filtration plant directly into the pond. There originally were provisions for clarificafion of ~he backwash water which would allow iron to setti~ out. The Bureau of Drinkin§ Water believes the backwash water c]arifier h~ not beer ,~=~ }n many y~ars due to a broken line. £=~.=.=~ samples rev=~d b~t~zi~i c~nt~nt The Barlow [~o~d ~ample indicated 5, 2 and 3 per 100 A1 for total coliforms, fecal coliforms and fecal streptococcus respectively during the 9/17/92 sample and 20, 18 and 2 per 100 ml for the 9/24 sample. The first set of Middle Farms Pond samples revealed concentrations of 23, 0 and 0 per 100 RI for the total, fecal, and streptococcus and 260, 680 and 0 per 100 ml respectively for the second set of samples. Middle Farms Pond should be resampled for bacteria, especially near residences to verify the results. The results of the reservoir raw water quality sampling and analyses indicate that the raw water quality is typical of small northeastern surface supplies with low density developed watersheds. The sampling program confirmed the need for filtration of the surface waters. Laboratory data is included in Appendix A at the end of this report. 4-2 I I I I I I I I I I I I I I I I I I I CHAPTER FIVE TEST BORINGS AND MONITORING WELL PROGRAM A. Introduction A test well and monitoring well program was conducted within the study area during September 1992, by ARL, Inc. Clarence Welti Associates, Inc. provided subcontract services including the actual borings and monitoring well installations, soil sampling and boring log preparation. The soil samples obtained are split spoon samples which were obtained at 10 foot intervals. Samples were observed, logged and placed in sample jars. The eleven monitoring wells and a single boring is shown on Figure 5-1 at the back of this report and the Boring Logs are in Appendix C. The purpose of the monitoring well program was to determine 1) the character of the soils, 2) the groundwater surface elevations and gradients and 3) analyze the groundwater quality. The selection of the monitoring well locations was based upon sections and data in the island-wide hydrogeolo~ic report published April 1990, by Ground Water, Inc., and existing and potential future sources of pollution as discussed in Chapter 8. B. Soils Characteristics The general surficial geology within the study area is shown in Figure 5-2. Based upon this U.S.G.S. surficial geology mapping, end- moraine deposits ring Barlow Pond, Middle Farms Pond and Treasure Pond. End-moraine deposits are defined as a complex assemblage of well-sorted sand, gravel and till. It includes small glacial kettle fillings of silt and fine sand, which occurs only on Fishers Island. The area immediately southwest of Barlow Pond and in Middle Farms flats is defined as Qsg which is described by U.S.G.S. as "sand plain deposits" which are sand and minor 5-1 I I I I I I I I I I I I I I I I I I l gravel underlying "sand plains" lO to 20 feet above sea level on Fishers Island. Based upon the boring logs for monitoring well I1 and monitoring well #2, at least a 21 feet thick light brown fine to medium sand surficial deposit exists in the area southwest of Barlow Pond. The extent of this sand in the direction of Barlow Pond is greater than shown by the U.S.G.S., see Figure 5-2. The depth of this sandy material is greater than previously estimated, based upon the borings and visual observation of a large abandoned well field which is in the area southwest of Barlow Pond and north of Brickyard Pond. The boring logs and observations of soils for monitoring well 13 northwest of the pond reveal some silt from 20.0' to 21.5'. The estimated permeability of this soil is less than 2 ft/day. This soil forms a dike which contains the water in Barlow Pond. The soil is consistent with the Figure 5-2, and the U.S.G.S. description, i.e., it appears to be an end- moraine deposit. The boring logs for monitoring well #4 which is located north of Barlow Pond near Mrs. Gordon Murphy's residence, indicate that a light brown coarse to fine sand, some fine to coarse gravel, a few cobbles and boulders exist. Some of the cuttings contained more silt than the boring logs indicate. Therefore, it is our opinion that the logs are consistent with the Qem, end-moraine deposits shown on Figure 5-2 and the permeability is relatively low. The boring logs and soils observations for monitoring well 15 near the water treatment plant indicate that the soils are light brown fine to medium sand, with a trace of silt. The appearance, grain size and gradation is consistent with the Qsg or sand plain deposits, not the end- moraine deposits which were identified by the U.S.G.S. and are shown in Figure 5-2. The permeability of the soil found in monitoring well )5 is estimated to be about 10 to 25 feet per day. It can be concluded that the 5-3 relatively narrow soil berm between Barlow Pond and Island Pond which iE about 4 feet lower, offers little resistance to flow from Barlow Pond to Island Pond. It is likely that sediment at the bottom of Barlow Pond provides the most significant barrier to groundwater flow from Bar]ow Pond to Island Pond. During the reservoir sampling program, it was noted that Barlow Pond, Middle Farms Pond and Treasure Pond have significant deposits of muck on their bottoms. Monitoring well #6 was placed near the driveway entrance to Bagley Reed's residence at the south end of Barlow Pond. Thp soil to a ?~Sf]~ >f i' L~et is light brow~ fine t, mediu~ sand, with a trace cl silt. The so]Is between 18 feet and 25 feet is coarse to medium sand which indicated that the boring was within the sand plain deposit. The material at the bottom of the boring appeared to be excellent water yielding material and the location with respect to the water d~ve]~ped and connected to the existing water distribution system~ After discussions with Mr. Robert Wall and evaluation of the monitoring well ~6 boring logs, it was decided to be worthwhile to bore hole (B-l) about 12 feet from the monitoring well ~ and explore the Sn~slbility of a new water supply well. The boring log and observations ~od]cate that the soil is not sufficiently permeable for a h~gh yield water supply well. Monitoring well #7 located south of Middle Farms Pond near the Miller residence remulted in light b~nwn fin~ to medium san,~ with a trace cf silt which indicates it is part of the sand plain deposits. The water table was relatively shallow. The permeability is estimated to be 10 to 50 fee~ per day. Monitoring well #8 boring and soils observations were conducted to a d~pth of 1[1.5 feet. This boring and well were installed deep to 5-4 I I I I I ! I I I I I I I I I I I I I determine the characteristics of deep underlying soils and to sample selected contaminants such as sodium and chlorides because the fresh water aquifer is near and possibly over brackish to saline water. The upper 18.0 foot layer of soil was light brown fine to medium sand. The 18.0 foot to 35 foot layer is light brown fine to medium sand with a trace of coarse sand. The soil from 35 feet to 45 feet was similar. A thin sand, silt and clay lense exists between 45.0 feet and 55 feet. Fine to coarse sand exists to 96 feet. The soil from 96.0 feet to 151.5 feet consists of compact grey silt, fine sand and clay. In sumn~ry, the m~terial down to 96 feet is relatively permeable. Below that elevation, the soils are impermeable. Based on the monitoring well #8 log, it can be concluded that the aquifer is much deeper near Middle Farms Pond than previously thought and reported, and the aquifer top and end are not confined near the Middle Farms Pond. It is probable that Middle Farms Pond is within the cone of depression and supplies water to the well field via induced infiltration. The monitoring well #9 is located near the main road north of the Laughlin residence driveway and Middle Farms Pond. The boring revealed a silty soil which most likely can be characterized by low permeabilities near the surface and at the ground water surface elevation, and higher permeabilities at deeper (13.0-21.5') depths. This soil is relatively consistent with the end-moraine deposit description. It can be concluded that floating pollutants would most likely travel slowly in this soil. The monitoring well #10 is located adjacent to the main road north of the Bafferty residence and Middle Farms Pond. The soils characteristics based upon the field observations, samples and boring logs can be characterized as light brown fine sand, little silt~ cobbles and boulders. This soil has relatively low permeahilities and fits the description of end-moraine deposits. The boring and monitoring well Ill are located west of Middle Farms Pond and the Templeton residence. These soils, based upon the field 5-5 observations and boring logs are light brown fine to medium sand underlain by light brown fine to coarse sand, and little fine to coarse gravel. The soils at monitoring well #11 are relatively permeable near the groundwater surface. The estimated permeability of the upper 96 feet generally is in the 50 ft/day to 100 ft/day range. Some layers of less permeable soils are within this upper layer. However, the aquifer is not confined. Therefore, it is possible that surface pollutants including any oil, gasoline, nitrates, fertilizers, pesticides or herbicides could mow downward and be captured by the water supply system cone of depression. C. Hydraulic Gradients One purpose of the monitoring well program was determination of hydraulic gradients around Barlow, Middle Farms and Treasure Ponds. Th~ dir n and j'~di~nt of the grnundwater surfaces around the ponds determines the destination and velocities of pollutants within the oquifer. 5-6 I I I I I I I I I I I I I I I I I I I In order to determine the gradients of the water surfaces around the three ponds, the elevations of the ponds were surveyed utilizing verifiable benchmarks and determined to be as follows: TABLE 5-1 SURFACE WATER ELEVATIONS (MSL) WATER BODY Barlow Pond Middle Farms Pond Treasure Pond Island Pond Beach Pond Fishers Island Sound WATER SURFACE ELEVATION* 6.0+_ 7.9+_ 7.9+_ 3.9+-- 2.5+_ (Estimate) 0.0 The water elevations within the monitoring wells and the estimated distances from the monitoring wells were scaled from the map. were then determined to the water bodies The resulting data is shown in Table 5-2. It can be concluded that the flow of groundwater was away from the ponds in all cases, and the surface gradients vary from 0.0010 ft/ft to 0.0454 feet/feet. D. Groundwater Samnlina and Analyses This section describes the purposes, procedures and results of the groundwater sampling program. *It should be noted that actual water elevations vary significantly from the values shown on the Fishers Island topographic mapping that was utilized as part of this study. 5-7 The monitoring wells are located based upon soils evaluations, water level evaluations and water quality evaluations. All of the monitoring wells are shown on Figure 5-1. Certain wells were selected for sampling based upon the premise that they were located where potential plumes from residential sites exist. Monitoring wells 4, 5, 6, 7, 9, 10 and 11 were placed down gradient from residences and the water treatment plant and were tested for volatile organic compounds (502.2], pesticides and selected sanitary contaminants. Monitoring well #8 which is 150 feet deep was sampled for selected constituents such as chlor]des to dete:mine if salt water intrusion has occurred. A summary of the monitoring wells which were sampled and the contaminants sampled are shown in Table 5-3 and the results of the analyses are shown in Appendix D. 5-8 I I I I I ! I I I I I I I I I I I I TABLE 5-2 WATER ELEVATION AND GRADIENT DATA LOCATION TOP OF PIPE DEPTH WATER ELEV. ELEV. TOP TO WS* SURFACE EL. DISTANCE GRADIENT (MSL) (MSL) FEET (MSL) FEET FT/FT MW #1 17.24 11.83 5.41 - 0.0025 Barlow Pond 6.0 240 MW #2 14.66 10.92 3.74 Barlow Pond 6.0 280 - 0.0081 MW #3 15.13 10.0 5.13 Bnrlow Pond 6.0 90 - 0.0051 MW #4 43.37 40.00 3.37 Barlow Pond 6.0 340 - 0.0077 MW #5 29.42 24.75 4.67 Barlow Pond 6.0 200 - 0.0067 Island Pond 3.9 200 + 0.0039 MW #6 Barlow Pond 6.0 23.84 18.33 5.51 500 - 0.0010 MW#7 Middle Farms Pond 16.37 12.66 3.71 7.9 300 - O.0140 MW #7 Beach Pond 2.5+_ 16.37 12.66 3.71 300 + 0.0040 * TOP means top of the 2" diameter PVC pipe - WS means surface of the groundwater table 5-9 TABLE 5-2, (Contd.) WATER ELEVATION AND GRADIENT DATA TOP OF PIPE DEPTH WATER LOCATION ELEV. ELEV. TOP TO TOW* SURFACE EL. DISTANCE GRADIENT (MSL) (MSL) FEET (MSL) FEET FT/FT MW #8 13.11 9.75 3.36 Middle Farms Pond 7.9 100 - 0.0454 MW #9 Middle Farms Pond 13.52 6.50 7.02 7.9 750 - 0.0012 MW #9 Fishers Island Sound 0.0 13.52 6.50 7.02 320 + 0.0219 MW #10 Middle Farms Pond 29.08 22.67 6.41 7.9 300 - 0.0050 MW #10 Fishers Island Sound 0.0 29.08 22.67 6.41 900 + 0.0071 MW #11 Middle Farms Pond 15.08 12.25 7.9 2.83 200 - 0.0254 * TOP means top of the 2" diameter PVC pipe - WS means surface of the groundwater table NOTE: (-) means away from surface waters and (+) means toward surface waters 5-10 I I I I I ! I I I I I I I I I I I I I ~H ~Oq~S ~C M~-i 5.7 0.SXlO0 13 M~-2 5.2 6.2X10 12 M4-3 -- M~4 5.7 1.2XlO0 9.5 M~-5 6.5 1.9XlO0 12 M4-6 6.0 7XlO ~ I~-7 6.0 7XlO ~ M4-8 6.5 1.6XlO0 12 M4-9 5.1 14 C~du~tivity level Cobh ~tivity 5-11 TA~ 5-3 (Contd.) (~[H~3WATER PAR~I~I{S ANALY2~D pH MIO~S mla~S C 7.1 2.2~[10D 12 ~-11 6.5 12 X 10 13 Conductivity * US~A 502.2 Organic Cc~pounds for Safe Drinking Wate~ Act Herbicides,~esticides per the Safe Drirddng %~ter Act 5-12 I I I I I ! I I I I I I I i I I I I I · ' is located near the road southwest of Barlow Pond. The screen is set to recover constituents near the groundwater surface. No VOC's were found to be in the water. Iron and manganese were found to be elevated but not excessive at 0.41 mg/1 and 0.17 mg/1 respectively. The field pH was low at 5.7 Monitorin~ Well ~2 is located southwest of Barlow Pond near three (3) residences. The hydraulic gradient was sloped downward from Barlow Pond toward the residences during the sampling program. Therefore, it is unlikely that residential sources of pollution impacted this well at the time. A reversal of the gradient toward Barlow Pond during dry weather could result in future elevated parameters in this well from the residences and nearby abandoned well field equipment. The well screen is set to obtain samples near the groundwater surface. No VOC's, herbicides or pesticides were found. The albuminoid nitrogen was at 0.48 mg/1 indicating most likely decaying vegetation. All other constituents were low, indicating good quality water. The field pM was low at 5.2. Monitoring Well ~3 was not sampled because it was installed to determine soils and groundwater characteristics only. Monitoring Well #4 was located north of Barlow Pond near the road and near three (3) residences. Evaluation of the groundwater surface gradient indicates that the groundwater most likely was flowing away from Barlow Pond at the time the samples were obtained. The screen is set to obtain samples near the surface of the groundwater table. VOC's, herbicides and pesticides were not found. Manganese was elevated at 0.63 mg/1 and nitrates were above background levels indicating some probable human impact on the groundwater quality. The field pH was Iow at 5.7. Monitoring Well #5 is located near the water treatment plant. The screen was set to obtain samples from near the groundwater surface. The 5-13 gradient was from Barlow Pond toward Island Pond. No VOC's were found to be present in this groundwater. The albuminoid nitrogen was 0.48 mg/1 which may be from decayed matter at the bottom of Barlow Pond. The conductivity at 190 indicated elevated mineral content compared with other samples. Nitrate nitrogen was elevated at 2.06 mg/1. This elevated nitrate cannot be explained at this time. The pH was 6.5 which most likely indicates the influence of Barlow Pond water. Monitoring Well ~6 was located southwest of Barlow Pond near the Bagley Reid residence. The gradient of the groundwater surface indicates that the flow was southwest from Barlow Pond under the residence. No VOC's, herbicides or pesticides were found. Only manganese was found to be elevated at 0.36 mg/1. Monitoring Well #7 was located south of Middle Farms Pond and several residences. The gradient of the groundwater indicates that the flow was most likely from und~ at least one residence. It i~ possib]~ ba~ed upon review of the topography, that groundwater flows from under several of these £e-~d~I,,es. No VOC's, pesticides or herticides we~= [~ ".d. Albuminoid nitrogen content was high at 0.96 mg/1 which may be the result of human activities or natural decay of vegetation. Nitrate nitrogen was elevated above background levels at 1.18 mg/1 indicating possible fertilizer or septic system influence. Monitoring Well #8 is a 150 feet deep well west of Middle Farms Pond. The purpose of this well was the determination of soils characteristics and potential chloride intrusion at deep depths. The chloride content was elevated at 30 mg/1 which is not extremely high for this area. Monitoring well 2D which was installed about 600 feet south of MW 8 had 91 mg/1 chlorides during the 11/14/88 sample period which indicates potential southern saltwater intrusions from Block Island Sound. Chlorides can also be transported from sea water onto land as aerosols. Therefore, 30 mg/1 of chloride concentration does not seem excessive. However, in view of the relatively low chloride concentration at 150 feet deep in MW #8, the concentration of 91 mg/1 in MW 2D which is about 80 feet deep does seem excessive and should be monitored very carefully and frequently. 5-14 I I I I I I I I I I I I I I I I I I I Monitorin~ Well 19 is located near the main road, north-northwesterly of Middle Farms Pond. The groundwater gradient indicates that water flows from Middle Farms Pond toward Fishers Island Sound through the Laughlin property. Monitoring Well ~10 is located near the main road north of Middle Farms Pond. The groundwater gradient indicates that water flows from Middle Farms Pond toward Fishers Island Sound and most likely flows under a residence. The conductivity at 220 micromhos, the manganese at 1.3 mg/1, the nitrate nitrogen at 12.4 mg/1, the pH at 7.1 and the sodium at 26.0 mg/1 all indicate that a source or sources of groundwater pollution are nearby. The nitrate level exceeds the allowable limit for drinking water. VOC's were not found. Monitoring We]] ~11 is located west of Middle Farms Pond. Based upon the gradient of the groundwater surface, the groundwater flows from Middle Farms Pond toward the wel! field. The groundwater most likely flows from under one residence. The screen is set at a level which will capture pollutants on or near the surface of the groundwater. This well is an important indicator of potential pollution of the well field. It should be monitored in addition to MW 18 in the future. No VOC's, herbicides or pesticides were found. Albuminoid nitrogen and manganese were elevated. However, no sources of pollution were indicated to be present. 5-15 I I I I I ! I I I I I I I I I I I I I CHAPTER SIX THE BARLOW POND INFILTRATION GALLERY/UNDERDRAIN A. Introduction This section of the report addresses the location of the underdrain which extends from the main road at a point about 3,000 feet southwest of Barlow Pond to the pond. The physical description of the drain, the tributary area, the history, flow evaluations, and potential pollution are discussed in the following narrative. B. Description The underdrain or "Infiltration Gallery" was evaluated initially by ARL, Inc. utilizing the old 1931 plans by W. Brown, Inc. which were supplied to us by Mr. Robert Wall, Superintendent of the Fishers Island Water Works, Inc. The horizontal alignment of the infiltration gallery is clearl~ shown on this plan. Our reproduction of this conduit alignment is shown on the map identified as Figure 6-1 (at the back of the report). The total length is 3,800 feet. The upstream end of the gallery system begins with a series of ditches which collect run-off from the Isabella Bluff area. Based on the old plans, these drainage ditches were very extensive. Substantial flows were observed in these ditches by ARL staff during April, 1992. The overland flow enters head walls and a closed conduit south of the main road 150 feet west of Pole ~773. It then flows south within what is thought to be a 12" diameter tile conduit to the edge of the swamp behind Chip Dupont's house. It should be noted that no swamp existed in 1931. Two major drainage ditches crossed this land which is now a swamp and exited at the two drainage culverts shown on Figure 6-1. The drain turns northward at this point and parallels the swamp under a man-made berm. At about 200 feet along the way, a 12" diameter outfall juts out toward the swamp at an elevation of 3 feet above the swamp water level. This outfall was dry when it was observed during the Spring of 1992, but was submerged during an inspection in March of 1993. 6-1 The drain zig-zag~ about 500 feet northeast across the DuPont land to an un-named road. It then turns about 20 degrees in an easterly directb~ and extends about 400 feet to Grey Gull Lane. It then turns northward and extends about 1,700 feet to the intersection of the Bar]ow Pond Roadway From this point, it e×tends about 300 feet to a point that extends approximately 25 feet into Barlow Pond. The pipe is tile, based upon the field observations, discussions Mr. cavanaugh Iwho bas indicated that he worked on the construct]on of it/ and the physical tracing of the pipe into Barlow Pond. The outfall pipe was buried and could not be seen. However, the tile pipe bells could be felt through the bottoms of the waders. The outfall pipe size in 6~rlow ?ond is mnst /i~ly 15 inches diame*er. Manholes l, 2, 5 on the map shown in Figure 6-1, and two more near the swamp behind the 5uPont house were found and inspected. They are 5 foet diameter brick and mortar manholes. was seeping into it at a rapid rate of flow during early spring. In general, the manholes appear to be in good condition with the e×ceptior~ cf manhole ~5, whioh she, uld be repaired. Manhole #2 probably has a valve in it just below the water level because the top square turning bar was only visible. The pipe and manhole bottoms were impossible to inspect because the waters are murky. Turbidity, and color from lignins and tannins appear to be present in the water and visibility is extremely limited. It is therefore recommended that the inlets and outlets be temporarily plugged, and the manholes sbnuld be pumped an~ examined. C. Tributar~ Area The total infiltration gallery tributary surface area is about !27 acre5 as compared with Barlow Pond's 31 acre tributary area. The surface tributary area extends southwesterly to within 300 fe~t of the Pb?ket: I I I I I I I I I I I I I I I I I I I Landfill. About 92 acres of land between the main road and the Isabella Bluffs contribute surface water to the drainage ditches near Pole ~773 and the culvert near Grey Gull Lane. The subsurface tributary area is extremely difficult to estimate. The majority of the drain lies in sandy soils. The pipe invert or bottom is about 4 feet below the groundwater table and about 10 feet below grade in the manholes which were inspected. The Manholes 1, 2 and 5 which were found and inspected are near Barlow Pond and Grey Gull Lane. The width of the zone of influence of this drain, in the event it was flowing toward Barlow Pond, would be substantial (Barlow Pond must be drained down for this to occur.). Assuming the zone of influence of the drain averages 300 feet wide when Barlow Pond is drained and water flows through the drain towards it, the total groundwater tributary area to the drain is about 26 acres. The width of groundwater influence most likely varies greatly depending upon the depth of the drain and the types of soils (sands, tills and muck). History The 1931 plans by W. C. Brown, Inc. describe the drain as an "Infiltration Gallery". Based upon this description and the drain configuration (see Figure 6-1), it is probable that the drain has been used to supplement Barlow Pond water during drought periods. Our investigations show that various means including pumping water from Middle Farms Pond have been used to augment the Barlow Pond water supply during droughts and/or high summer usage periods. It has been suggested that during the early 1920's, the upper reaches of this drain were constructed for the purposes of dewatering the abandoned clay pits for clay mining and brick making. This line could have extended to and terminated at the outfall into the DuPont swamp because early maps show a drainage ditch from the 12-inch outfall directly to Fishers Island Sound, and another drainage ditch is located on the east side of Dupont's land and drains to Fishers Island Sound. 6-3 A~other key piece of evidence that the drab', was extended to augment the Bar]ow Pond water supply ia the fact that an abandoned well field lies immediately southwesterly of the pond. The well f]~]d bad numerous we]] points, an ~laborate suction manifold, a huge gasoline driven pump and a raw water main extending toward Bar]ow Pond. It was most likely used to supplement the Barlow Pond water supply. Therefore, we conclude the need for Barlow Pond augmentation e×ist~d d',ring early years. Flow Evaluations No movement of the existing water was noted during numerous inspections of m~i~noles 1, 2 and 5. Substantial overland fi.~ f~om th~ northwes~ s]npes cf the isabella Bluffs has been observed enterlng the head wails of the conduit near the main road and Pole ~773, and substantial flows have been seen entering the cracked mortar of Manhole u~a: Gre~ Gull L~ne. This manhol~ i~ within the drainag~ ditch which e×tend~ to th~ main road and a 10" diameter culvert under th~ ma~n road Also the land depressions during the less rainy periods. bu?ont swamp outf~l]. on both sides of Grey Gull Lan~ No outflow has be~n observed at +he !2" Dye tracing of flow between Manhole ~1 and Manhole ~? near Bar]ow Pond ha? substantiated that after rainfall evenes water flows from Bariow Pond toward Grey Gu]] Lane. It can be hypothesized that during rainstorms, the Barlow Pond water elevation rises quickly, reflecting the amount of precipitation (Bo~ Wall, the Fishers ts]~nd Water Works Supervisor, ind]=oted that when i+ rain= !", the Pond raises 1"). The sandy aquifer which surrounds the drain. rises more slowly and therefore forms a sink to accept flow, and results in flow away from Barlnw Pond. During drought conditions, the flow would be reversed toward Pond, and the infiltration gallery would provide added water · [.~ I I I I I I I I I I I I I I I I I I I to Barlow Pond. The drain and surrounding aquifer provide additional water sturage. The reversal of flow would result in transport of pollutants from the drain tributary to the pond. F. Potential Pollution The sources of pollution within the tributary area are relatively well defined but dispersed. They are non-point sources from four residences, roadway run-off from the main road and some potential fertilized areas. Non-point sources of pollution also include water fowl and animal wastes. The possibility of an oil tank leak, an oil spill on the main road or gasoline leakage into the surface water or aquifer exists. Any and all chemicals applied to the ground within the tributary area could eventually end up in Barlow Pond. A possible but not probable source of pollution is the Pickett Landfill because the sand plain soils extend from the area of the landfill to Barlow Pond. However, the pollutant would have to move 1,900 feet in the groundwater table. The most likely source of pollutants with potential impact on Barlow Pond are the potential sources identified at the three residences adjacent to the infiltration gallery and the Pond. In the event that any homes are proposed near Barlow Pond, potential pollutant sources, direct pathways (overland and through the groundwater) and indirect pathways (through the drain) will have to be evaluated. The next most direct pathway for pollutants to enter the Barlow Pond via the drain is overland drainage from the abandoned clay pit to the main road, under the main road via the 10" diameter culvert and into Manhole ~8 near Grey Gull Lane or via septic systems constructed near the nnderdrain. Finally, it has been indicated that the potential for hydrocarbon contamination of the abandoned well field exists because gasoline, grease and other materials were used within the aquifer area. The destination of these pollutants could be Barlow Pond via the drain. 6-5 In summary, the underdrain is 3,800 feet long and drains an area that extends an additional 1,400 feet further from Barlow Pond. The surface tributary area of the underdrain is 3.5 times as large as the Bar/ow Pond watershed area or 127 acres. The groundwater tributary area to the drain is estimated to be 26 acres which is 2/3's the size of Barlow Pond's tributary area. The history of the construction of the drain dates to before 1929 and, most likely, the post World I era. Flow character- istics in the drain have not been completely defined, and the risk of pollution of the drain is low to moderate except from septic systems in the vicinity of Barlow Pond. The risk of pollution of Barlow Pond via the underdra]n would increase substantially during drought conditions when the pond must be drawn down or excessive evaporation occurs. A drought or drawdown of Barlow Pond would greatly increase the likelihood of pollution of the pond via the infiltration gallery. 6-6 I I I I I I I I I I I I I i I I I I I CHAPTER SEVEN HYDROGEOLOGIC SECTION A. Introduction The purpose of plotting a hydrogeologic cross section in the study area, which includes the three (3) ponds and the Middle Farms aquifer, is to assess the potential of surface and groundwater pollution by contaminants which enter the aquifer. B. Description During September 1992, ARL, Inc. determined the groundwater and surface water elevations of eleven (11) monitoring wells and three (3) ponds. Based upon the results, we conclude the groundwater normally flows away from Barlow Pond in all directions, and away from Middle Farms Pond in the southerly, westerly and northerly directions. Based upon previously published data, Treasure Pond groundwater most probably flow~ south and west. Middle Farms Pond and Treasure Pond may recharge from the east and north respectively, again based upon the April 1990 Groundwater, Inc. report. Specifically, the normal groundwater direction of flow moves existing pollutants away from the surface waters. Two phenomena can reverse these flow directions at Barlow Pond. The first is a drought similar to those occurring during July 1929 through December 1932, September 1940 through April 1945 and August 1961 through November 1971 which lower the levels of the ponds and reverse the groundwater flow. It is possible, but has not been substantiated herein, that other periods of drawdown of Barlow Pond have occurred in the past. The second phenomena is reversal of pathways of groundwater flow and pollutants caused by dense, fine grained layers of soils in some areas near the ponds. 7-1 Soils logs from test holes for a septic system which were excavated in the southeast portion of the Barlow Pond watershed revealed a sandy till soil with mottling at 10 feet below grade. Grade is at elevation 25 feet msl. The mottling indicates the seasonal water table elevation and that a restrictive layer of soil exists at about elevation 15 feet ms l. This test hole was about 210 feet from Barlow Pond which has a surface elevation of about 6.0 msl. The hydraulic gradient could be 0.0429 ft/ft during the high groundwater period. The water table based upon the test hole mottling was much higher than Barlow Pond and groundwater most l~kely drains toward the pond. It is unlikely but possible that bacteria could reach the pond from this septic system. Nutrients and trace organics most likely presently flow to the pond within the groundwater flow. Direct pollution of the Middle Farm Flats groundwater is possible because the aquifer is unconfined and the cones of depression of the water supply wells are large. In addition to direct pollution, it is possible th=t polluted run-off f-om th~ roa north of t]~e well field cou]~ flow overland to the well field and infiltrate into the aquifer. The geologic units of the area are shown in Figure 7-1. Large areas of proximal or fine to medium sand, Qsq, are present southwest of Barlow Pond and within Middle Farms Flats. The depth of this sand is greater than 22 feet in the area of MW ~2 and greater than 38 feet at MW Interestingly, MW G5 previously installed indicated the sand layer to be about 13 feet thick at a location just 200 feet from MW #2. The thickness of the proximal outwash varies greatly in the Middle Farms Flats area. At MW ~8, it is about 100 feet deep and at MW 2D it is shown as 8 feet deep in the GWI report. The cross section west to east across the SIMA, Church and "Hers" production wells is shown as a 70 foot to 30 foot thick band of sand and gravel overlain by silt and fine sand. The sand and gravel bows down to 70 feet below grade. ARL, Inc. found that, based upon MW ~8 logs, the sand extends from the surface to 96 feet below grade at the eastern edge of the aquifer near Middle Farms Pond. Therefore, according to the buring data, it Pay be concluded that the aquifer thickens as it extends from the 7-2 I I I I I I I I I I I I I I I I I I I well field area to Middle Farms Pond and it is not confined. It is probable that water flows from Middle Farms Pond into the well field. Figure 7-2 shows the cross-section line on a topographic map. Monitoring wells 12, 5, MW2D and 8 are shown on this map because they were used to determine cross section characteristics. In order to illustrate the effect of droughts or drawdown on the pathways of pollutants, and to illustrate general water table characteristics of the study area Figures 7-3 and 7-4 are presented. Figure 7-3 shows the cross section of conditions which existed during September 1992 when the ARL survey crew measured the water surface elevations. The cone of depression for the well field is generalized based upon published information and data. The pathways of pollutants within the groundwater are away from Barlow Pond and the west end of Middle Farms Pond. Figure 7-4 shows a condition which cuuld exist during a drought. Barlow Pond's water elevation was 1.5 feet msl during the 1960 drought. During the drought period the gradient reverses. This condition would be worse in the southwest and northern edges of Barlow Pond. As previously mentioned, the result would be travel of pollutants from the surrounding areas toward the ponds. The infiltration gallery flow would also reverse. 7-3 LEGEND ,0 A MAP SHOWING GEOLOGIC SCALE: I"=1000' UNITS ,/~ Lombard~ FIGURE 7-I I I I I I I I I I I I I I I ! I I I I CHAPTER EIGHT DETERMINATION OF POTENTIAL CONTAMINANT SOURCES A. Introduction This Chapter describes the methods used to identify, assess and map the potential sources of ground and surface water pollution within the water supply watershed area. The potential sources include residential development, roadways, the water treatment plant, the golf range and salt water bodies. Sources can be categorized as point and non-point (dispersed sources). Identified potential sources are shown on the map, Figure 5-1 at the back of this report. B. Description of Contaminant Types The potential sources of pollution identified within the study area include the following point sources: Residential septic systems O]1 storage tanks Swimming pool discharges Non-point sources include: Herbicides and pesticides used for lawns, shrubs and gardens Fertilizers used for lawns and shrubbery Roadway runoff Salt water intrusion of ground and surface waters Construction erosion and sedimentation Animal manure Water fowl 8-1 1. Point Sources a. Residential On Site Disposal Systems Many of the existin~ on site wastewat~r di=~a] Sybte~L= the planning area are old and most likely substandard. Some maybe leaching cesspools and lack septic tanks. All on site disposal systems are sources of bacteria, viruses, nitrogen, phosphorous, trace organics, and other pollutants. Bacteria including fecal colifor~ and fecal streptococcus from human waste discharges can travel long distances in saturated, porous soils. The inclusion of clay lenses in the soils which occurs on Fishers Island within the study area can restrict downward movement of septic system effluent and result in horizontal movement cf septic system effluent toward surface waters. Bacteria survive in aqueous solutions for extended periods of time. Some authors have cited a survival time in the groundwaters of New England of three (3) to six (6) weeks as a reasonable figure. (2) Virus tend to conform with the same principals applied to bacterial for survival in on site disposal systems, with one distinct and important difference. Viral organisms can survive for extended periods of lime D saturated soils and will therefore travel grea[ d~t~nces (Jr +~v sur~["c' to reach the ~r _.~ ~. level. The critical safeguard is maintenance of a_Sn adequate depth of unsaturated soil between a leaching system with a viable biological growth layer and the groundwater table. Most research in the laboratory and field indicates sixty [60) cm (2 feet] of unsaturated porous soil can remove viruses very effectively. 8-2 I I I I I I I I I I I I I ! I I I I i Overland flow of wastewater from failed septic systems that are underlain with marginal soil conditions could result in direct pollution of the receiving waters with both bacteria and viruses. Nitrogen~ N in the form of nitrate ion (NO3 ) is considered a pollutant if it exceeds the concentration of greater than 10 mg/1 as N according to the U.S. Public Health Service. The nitrate has been known to cause an infant disease known as Methemoqlobinemia. The sources of nitrogen in the study area include septic systems, lawn fertilizers, and animal wastes. Nitrogen discharges to surface waters promotes aquatic weed growth, "duck" weeds, algae, and macrophytes. Nitrogen is a necessary element for aquatic weed growth, but may not be the limiting nutrient for the Island ponds. It is most likely that phosphorus is the limiting nutrient. During the reservoir sampling program, abundant growths of aquatic plants, especially macrophytes, were observed in all reservoirs, especially Treasure Pond. (4) Phosphorus Septic systems discharge relatively large amounts of phosphorus. The phosphorus is bound to the underlying soils depending upon the cation exchange capacity of the soil. In general, sandy soils absorb less phosphorus than silts and clays. In general, the larger the soil particle size, the lower the capacity of the soil to absorb phosphorus. The sandy soils adjacent to the ponds and in the aquifer are most likely relatively poor absorbers of phosphorus. 8-3 (5) Trace Organic Chemicals are sometime present in household wastewater. The sources of trace organics can be cleaners, solvents~ degreasers, paint products, antifreeze, motor oils, furniture strippers, photograp~~ chemicals and other ho,~=e~o!d Some septic system additives contain organic chemicale which enter and pollute groundwaters. In addition to groundwater pollution, failed septic systems within the watershed could result in overland flow and water po?~ut~on w!th trace organics. Normally, some trace organics will be removed in the soils by volatilization, chemical reactions, and absorption. b. Heating Oil Storage Tanks Heating oil storage tanks, especially underground tanks can rust and leak causing contamination of s~.ii_ and the ~[oundw~t=~. Mu=~ ~, the residences and the water treatment plant have oil storage tanks on their sites. The primary constituent of concern is the carcinogen benzene. Residences which have oil storage tanks on their premises are shown on Tables 8-1 through 8-4 on the following pages. c. Swimminq Pool Wastes The potential pollutants associated with swimming pool backwash include bacteria such as fecal coliforms and fecal streptococcus, chlorine (RTH), stabilizing acids such ae cyanatic acid, algae, alkalinit3 additives and diatomaceous earth. In some cases, pool water is held for long periods of time, which can result in pollutant concentration. 8-4 I i i I I ! I I i I I i I I I I ! I i 2. Non-Point Sources a. Pesticides and Herbicides Pesticides and herbicides that are used for lawns, orchards and shrubs can be dangerous to human health if consumed in drinking water. Extensive pesticide and herbicide constituents are now required for monitoring under the Safe Drinking Water Act. The current EPA Phase II and Phase V requirements and the New York Sanitary Code monitoring requirements are more stringent that the sampling regime defined in the scope of this study. However, the lack of pesticides and herbicides in the samples analyzed for this study is most probably indicative of presence or absence of other contaminants. b. Fertilizers Fertilizers contain nitrogen and phosphorus which nourish aquatic plant life. The plants flourish, die, settle to the bottoms of the reservoirs and decay causing oxygen uptake, and taste and odor in the drinking water. The proximity of some lawns, and shrubs to the surface water reservoirs most likely results in increased nutrient loadings. During rainstorms, the fertilizers are washed into the three (3) ponds, and eventually seep into the Middle Farms Flats Aquifer. c. Roadway Run-Off Roadway run-off can include BUD, nitrogen, sodium, chlorides, phosphorus, grease, petroleum, chromium, lead, zinc and copper. Fuel oil and gasoline spills are probable. The benzene content of the fuel, and the pathways that these pollutants follow, are the most critical concerns. 8-5 The loading of pollutants on a receiving water from roadway run-off depends upon the volume of traffic and miles of roadway in the area. Both the volume of traffic and the miles of roads in the study area are low. However, the relative volume of construction vehicles is high and fuel oil does have to b= transported to the east end of the Is]~n~ on the main road adjacent to Barlow Pond and the Middle Farm flats. The parameters of greatest concern which would be associated with fuel spills are benzene, toluene, xylenes, and other hydrocarbons. The roadways in some cases such as the one leading from the Isabella Bluff area to the four corners intersection at the southwest corner of Barlow Pond (near Bagley Reid's), concentrate and transmit pollutants. The stormwater run-off turns and flows northward at the four corners intersection and enters the Barlow Pond via a swamp near Bagley Reid's house. Oil, ~rease, i~,w i~vel lead, salt, sand and other constituents are transported by stormwater toward the reservoirs. Of course, oil or gasoline could also be transmitted into the ponds or aquifer in the event of a spill or spills. d. Salt Water Intrusion Salt water pollution occurs in groundwaters as a result of over pumping of aquifers near and open to the ocean. Another type of salt water contamination of surface and groundwaters is aerosol migration of wind blown salt water and sprays from wave action. The Suffolk County Department of Health Services, Bureau of Drinking Water has required the Fishers Island Water Works to implement a monitoring program to detect salt water intrusion as a condition of its approval of the recently installed public water supply wells. 8-6 I i I I I ! I t i I I I I I ! i i I e. Construction Construction activities can promote erosion of soils which could result in solids, nitrogen, solids, phosphorus and other contaminants being transmitted to the reservoirs. In addition, construction activities could result in overland flow to the surface supplies or leaching into the groundwater of gasoline, oil, solvents, paint, paint thinners, adhesive materials and other pollutants. f. Animal Manure Animal manure can result in pollutant loads on ground and surface waters. The fecal matter contains HOD, nitrogen, phosphorous and pathogenic organisms. The result can be increased coliform concentrations and over nourishment of aquatic plant life. Although, few horses or other domestic animals are within the public water supply tributary areas at this time, more can be anticipated in the future. The existing wild animal population, such as muskrats, squirrels, deer, etc. is not readily known. It is suggested that the March 1993 Fishers Island Water Supply and Watershed Study Ecological Component Report be referred to for additional information. However these creatures can contribute significant pollution loads. g. Water Fowl Water fowl have been reported to be abundant on the reservoirs. Water fowl discharge large quantities of nitrogen and phosphorus in relationship to their body weights. Flocks of water fowl can increase coliform concentrations in reservoir water beyond allowable limits. These nutrients over nourish waterbodies resulting in aquatic growths. During the reservoir sampling program, no water fowl were sited. It is suggested that the Watershed Study Ecological Component of this Report be consulted for a more definitive discussion of indigenous water fowl. However, it has been reported that many water fowl have been observed on ail three reservoirs. 8-7 The potential sources of pollution from existing residences within the study area are shown in Tables 8-1 through 8-4. 8-8 ! ,! ! ! I1. Reid, Bagley X X X B 55O X B 5_50 - N - B X B X N X A X A X X X X 3. Corbier~o, Adrieune ** X X X 4. Ham-As, David ** X X X 5. Rafferty, Bernard X X X ! 6. C~lhoun, Robert X X X ! 7. Mm~v, Mrs. Ox~m x x x 8. Water 2¥e~Lu~ Pl~nt - X - 9. Hotch~, Winchester X X X i0. C.,~,,,~ud, Mark and A.no X X *A Me~ns above ground or b~9~,~ ~ B Mmms below ground t~nk N M~ans no tm~ ! ROAI~AY TA~ 8-2 ~:~I'iC~DES/ OIL * CAPA~£t ~ ~Sl~ /?mO'. ,~y~S ~RBIC~ TA~ (C~) ROADWAY 1. Templeton, John M. X X X A 2. Imughlin, James B. X X X B 3. Bernard and Ano ~mmtees X X X A (Mrs. W. G. Rafferty) 4. Foster, John H. and W.F. X X X 2B 5. Geniesse, Robert J. X X X B 6. M~er, Robert X X X B 7. Rentschl~ .'~. - - -- (3 Unit~) 550 X X X *A Memm above ground B M~ms below ground N Me~ns no tank **On ~tershed boundary with Tr~msu~e P~ - see Tre~ure P~md Table 8-3 for this pote~lti~l source. 8-10 I ! I I I. I. 1. I I I I I I I i I I I Re~er~ (3 m~i.~.s) X X X N,N,B -- X Gemie~se, Robert J. X X X B 5.~ X Foster, JohnH. andW. F. X (3 Bu:~.~) X X 2B B Mesns be_lo~ ~.nd ~tershed boundary of Middle Farm Po~d 8-11 X TAN ~ 8-4 [~AY X X X X .Means above grotmd Means below ground 8-12 I I I I t I I I I I I I I I I I i I I Mapping Potential Sources of Pollutfon In order to identify potential sources of water pollution within the Fishers Island water supply watersheds, the 1974 base map furnished by the Suffolk County Planning Department was reviewed and updated using 1988 aerial photos and field editing. The photos revealed current residences~ roads~ driveways~ lawns~ drainage swales and other pertinent information. The mapping review and photographic editinG was followed by field edits of potential sources of pollution and coordination with Mr. Robert Wall, the Water Works Superintendent, and coordination with Mr. Rarold Cook of Gada~ Inc., which supplies fuel oil and pumps septage from the septic systems. The field review included assessment of the residential areas and facilities, edit of the watershed tributary area topography and extent, identification of pollution pathways and review of the drainage patterns. It was assumed that all residences are served by septic systems, are utilized at least from Memorial Day through Labor Day and some are used for greater lengths of time. The water treatment plant is not served by a septic system. Most residences are utilizing large fuel tanks, and most have lawns and landscaped areas. The main road and several driveways are paved. The remaining roads are combinations of sand and gravel. Sources of pollution within the water supply watersheds are shown in Figure 5-1 at the back of the report. The residences, paved roads, cleared areas and driveways are shown on the map. The septic systems and fuel tanks are assumed to be near the buildings. 8-13 I I I I I I I I i I I i 1 I i I I I ! CHAPTER NINE WET WEATHER SAMPLING AND ANALYSES A. Introduction This Chapter describes the wet weather sampling and analyses of stormwater run-off entering Barlow Pond, Middle Farms Pond and Treasure Pond. Description The initial approach to sampling and analyses of run-off included flow measurements in swales leading to the ponds during storm events and composite sampling of the run-off. However, after field observation during storm events, it became obvious that the stormwater only concentrated on paved roadways. The rainwater soaks into underlying sandy soils rather than accumulating in swales. None of the drainage swales are well defined except for a few leakoffs from roadways. The major leakoff of roadway surface run-off is located near the southwest end of Barlow Pond where the roadway dips to a low point. Stormwater run-off from the Isabella Bluff area drains down to the intersection of the bluff road and the main road and then flows to the aforementioned leakoff into a wetland near the Bagley Reid residence. Several other small roadway leakoffs are located northwest of Middle Farms Pond. An alternative stormwater sampling program was developed after observation of the storm events and the response of staff gauges at the reservoirs. This alternative program included sampling and analyses of selected near shore locations at each pond. The locations were selected based upon the locations of residences, i.e., the sample points were located down slope from the residences near the edges of the ponds. The stormwater sampling points are shown on Figure 5-1. 9-1 C. Sam~lin$ Samples were collected prior to a storm event and immediately after one. The initial set of alternative runoff samples were collected on Octut~< 13, 1992, after a relatively prolonged dry period. The second set of samples were collected on October 26, 1992, after a storm event on October 25, 1992. The premise or theory is that the initial set of samples during the dry weather period indicates the water quality prior to a storm or base line quality information. The second set of samples indicates the water quality after a storm event. The sample points, descriptions of the sample points and the types of samples obtained are shown below in Table 9-1. TABLE 9-1 STORMWATER OR WET WEATHER SAMPLING PROGRAM SAMPLE POINT B-1 DESCRIPTION Barlow Pond near Bagley Reid's Residence CONTAMINANTS 502.2 (VOC's), Pesticides Selected Constituents B-2 Barlow Pond near the Water Treatment Plant 502.2 (VOC's) Pesticides, Herbicides, Selected Constituents Barlow Pond near the Murphy Residence 502.2 (VOC's), Selected Constituents B-4 Barlow Pond in the Swamp near Bagley Reid's 502.2 (VOC's), Pesticides, Herbicides, Selected Constituents M-1 Middle Farms Pond South Shore near Several Residences 502.2 (VOC'$), Pesticides, Herbicides, Selected Constituents 9-2 I I I I I I I I i I I I 1 I I t i ! ! TABLE 9-1 (Contd.) STORMWATER OR WET-WEATHER SAMPLING PROGRAM SAMPLE POINT M-2 DESCRIPTION Middle Farms Pond near the Rafferty Residence CONTAMINANTS 502.2 (VOC's), Selected Constituents N-3 Middle Farms Pond near the Foster Residence 502.2 (VOC's), Pesticides, Herbicides, Selected Constituents T-1 Treasure Pond near the Foster Residence 502.2 (VOC's), Pesticides, Herbicides, Selected Constituents The VOC's, pesticides and herbicides were not detected at the specified limits in all cases for both the dry and wet samples or background water quality. See Appendix B. 9-3 Date Total Colifecnn c~/1oo m~ Fecal Coliform C~J/100 ml Fecal Strep 5 2 3 Wet 9/24 20 18 Wet 10/27 25 4 Dry 10/13 ~8 60 2 Wet lO/27 18 5 B-3 Dry 10/13 16 6 Wet 10/27 14 12 18 10 Wet 1~ 420 10 I I I I I I I I I I I I t I I I i I ! F~V~ Center Mid Depth Dry 9/16 Wet 9/24 ~ ~ Dr~ ~0/13 ~et 10/27 ~ ~ D~ ~0/~3 Wet ~o/26 ~ 3 Dr~ ~0/13 Wet 10/26 9-5 ~ - 1992 (Ca~.) ~d/100 ml 23 ~60 18 14 45 16 14 ~'U/iO0 ml 0 68O 12 3 8O 8 10 3 F-,~] Strep C~/iO0 ml 0 0 0 0 1 0 3 0 9--2 l~te Total Colifom C~U/100 ml cFU/lOO ml Fecal Strep TR~ASDRE POND Center Mid Depth 9/16 9/2a 10/13 18 Wet I I I I I I I I I I I i I I I I I I I In order to effectively evaluate the impact of existing on-site wastewater disposal systems on the public water supply in the study area, the following factors must be appreciated: 1. The seasonal nature of the inhabitants of the watershed areas. The travel time for pollutants from on-site disposal systems to the surface waterbodies. The permeability and voids in the profiles of the soils present in the study area. The above factors present a unique situation in the evaluation of bacteriologic analyses of the waters from the study area. The population is at its greatest on Fishers Island from late June to early September. In the remainder of the year, the number of inhabitants dwindles to almost nil particularly in the study area. Once established in a properly designed and maintained on-site system, the "bio-crust" and qeo chemical reactions remove bacteria, virus, phosphorus, nitrogen, etc. provided there is adequate distance between the groundwater table, the "bio-crust" and any receiving waterbody. Highly permeable soils, particularly those known to have voids in the soil profile can allow rapid movement of wastewater through the ground. Septic tank effluent requires three to six weeks of residence in groundwaters to insure bacterial dieoff.' Viruses passing through the "bio-crust" and entering the groundwater can survive for much longer periods than bacteria. The soils in the study area are of the Riverhead and Plymouth series. They are noted as possible pollution hazards and are known to have voids which facilitate "pipinp" of groundwater through the soil profile. Samples of reservoir water taken in September from the Centers of Barlow, Middle Farms and Treasure Ponds indicate low levels of bacteriologic pollution in mid September under dry conditions. The wet 9-7 weather samples at the end of September rose slightly for Barlow and Treasure Ponds. The Middle Farms Pond wet sample was substantially higher (Total Coliform 260, Fecal Coliform 680, Fecal Strep 0) than the dry (TC 23 CFU~ FC 0 CFU). The water samples were taken at the reservoirs to evaluate runoff impacts in mid to late October 1992. The dry samples were taken in mid October, the wet weather at the end. The dry weather alternative runofi samples for all three reservoirs had more bacteriologic pollution than the later wet weather samples. The prime exception to this tend were the samples from the wetland near the Bagley Reed residence (sample point B-4] where the dry samples (TC 200, FC 18 and FS 10 rose to TC 420, FC 400 and FS 10]. The data are inconclusive. In order to properly evaluate the impacts of the existing on-site disposal systems, a sampling program beginning in early May should be undertaken to determine water quality with most on-site disposal systems dormant. The sampling should progress through the summer tn determine if there is a slug of pollution entering the reservoir due to septic tank "start up" and if there is any short circuit flow to the waterbodies due to "piping" or heavy weekend use. Finally, the program should run through the end of September which will provide at least six weeks of groundwater residence after a period for re- establishment of on site disposal system use. Samples taken in the October to April period, may be inconclusive due to dormant on-site disposal systems and surface water temperatures which limit coliform organism "viability". Establishment of solid baseline data on the surface supplies would be a prudent action prior to further development in the study area. 9-8 I I I I I I I I I I I I 1 I I I I I I CHAPTER TEN TOPOGRAPHIC MAPPING AND DRAINAGE BASIN SURVEY A. Introduction The base mapping for the topographic survey was the Suffolk County DPW 1" = 200' scale mapping. As previously discussed in Chapter 8, this mapping was updated using aerial photos dated 1988 and field surveys were conducted to check pond elevations, monitoring well elevations and grade at the monitoring wells. Rouses which had been constructed during the interim period were scaled and plotted approximately on the base map. The ARL survey crew field surveyed the major waterbodies and the monitoring wells. Basic differences based on published benchmark information were determined to exist, regarding the surface elevations of Barlow Pond, Middle Farms Pond, Treasure Pond and Island Pond as shown in the following table (10-1). TABLE 10-1 WATER SURFACE ELEVATIONS (MSL) WATERBODY ARL ELEVATIONS MAP ELEVATIONS Barlow Pond 6.0+ 10.5 Middle Farms Pond 7.9A 12.5 Treasure Pond 7.9~ 12.5 Island Pond 3.9~ 3.0 In addition, the survey crew obtained grades and tops of well casings at the 11 monitoring wells and 1 boring, and set benchmarks and staff gages at all three reservoirs for rainfall response testing. The elevations on the map were compared with our surveyed elevations. Some differences were apparent. 10-1 Field edits of the reservoir watersheds and the infiltration gallery areas were conducted during the early stages of the project to identify the extent and configuration of the watersheds and to inYestigate the locations of roadway leakoffs~ culverts~ drainage ways~ manholes on the infiltration gallery and other items. It was concluded, based upon the old plan showing a pipe interconnec- tion between Treasure Pond and Middle Farms Pond, the topographic mapping and the survey, that the gate is open and the ponds are hydraulically interconnected via the pipe. 10-2 I I I ! I I I I I I I I I I I I I I I CHAPTER ELEVEN TYPICAL SEPTIC TANK ANALYSES A. Introduction Septic systems discharge bacteria, viruses, nitrogen, phosphates and metals trace organics to the groundwater. Bacteria survive for 3 to 6 weeks in soil. It is assumed that coliform bacteria in septic systems originate in the human intestine. The presence of the coliform indicator organisms infers the possible presence of pathogenic organisms. In sensitive areas such as water supply watersheds, analyses of the time of travel of bacteria should be done prior to construction of a septic system. B. Method of Analysis Time of travel analyses utilizes the soil permeability, porosity and hydraulic gradient to arrive at the velocity of groundwater movement. V = Ki N Where V = Velocity (ft/day) K = Permeability (ft/day i = The Hydraulic Gradient N = Porosity of the Soil 11-1 The estimated values for areas around the Barlow Pond Water~he.~ are as follows: 50 ft/day for fine to medium sand 2..343 [perched w~tcr table] 0.35 estimate V = K__i = 50 ft/day x 0.043 = 6 ft/day N 0.35 6 ft/day x 71 days 1~6 foot set back required. It should be noted that the K values or permeabilities vary greatly. The range could be 25 ft/day to 150 ft/day. The Suffolk County, New York USDA Soil Survey classifications for the upper soil layers in the watershed area indicate that the permeabilities (K) are greater than 12.6 ft/day and range up to 150 ft/day. Based upon ARL visual observations, boring logs and grain sizes of the soils near Barlow Pond, the estimated permeabilities (K) range up to 150 ft/day. The permeabilities of the soils south of the pond and between Barlow and Island Ponds particularly appear to be of moderately high (5 to 25 ft/day) permeability. However, in order to properly evaluate a specific site, particularly in this very sensitive area, in-situ or laboratory permeabilities should be determined at several points and elevations within the proposed septic system location. Viruses have been found to travel long distances in saturated sandy soils. However, if an unsaturated distance of about 2 feet exists below an established biological growth layer of a leaching system, the viruses are removed. Domestic sewage contains organic, ammonia and nitrate nitrogen. Septic tank effluent leaves the tank in the organic or ammonia condition. The stone-soil interface on a leaching system normally creates an aerobic condition. The ammonia is oxidized to nitrite - nitrate 11-2 I I I I I I I I I I I I I I I I I I I nitrogen. Nitrate moves readily in the groundwater table. A typical requirement is that the nitrate concentrations remain below 10 mg/L as N for health purposes. A major concern in reservoir watersheds is excessive nitrogen concentrations in the ponds which causes over nourishment of aquatic plants. This can result in reservoir infilling and taste/odor problems. Although septic tanks contribute to the nitrogen concentrations in surface and groundwaters on Fishers Island, it is the opinion of the Suffolk County Health Department that nitrogen concentrations in these waters due to turf management practices is more significant. The zoning of low density housing, the brief seasonal occupancy which predominates on Fishers Island and the absence of housing on the majority of the watershed appears to support this conclusion. Procedure for nitrogen computations: Assume 3 bedroom house with two people per bedroom 3 bedrooms x 2 people x 75 gpcd = 450 gpd, 450 gal/day x 3.8 liter/gal bedroom = 1710 L/day 2. Typical concentrations 40 mg/L, 40% removed by pretreatment, therefore 1710 L/day x 40 mg/L (1.0 - 0.4) = 41,040 mg/day Rainfall for dilution, 250 ftx 250 ft = 62,500 sg ft average daily precipitation 0.01 ft, 60% infiltrates, therefore 375 cu ft/day or 2805 gallons or 10,659 L. 4, Delivery to site, 1710 L/day at 24 mg/L = 41040 mg/day Dilution, 10,659 L/day + 1710 L/day = 12,369 L/day 5. Final concentration 41,040 mg/day/12,369 L/day = 3.3 mg/L 6. Drinking water standard 10 mg/L therefore the discharge is ok. 11-3 The nitrogen computation of 3.3 mg/1 for a 250 ft ky 250 ft appears tn compare well with modelling ('Protection and Restoration of Ground Water in Southhold, N.Y.," Trautman et al, Cornell University, 1983) and actual sampling ('Suffolk County Comprehensive Water Resources Management Plan" [CWRMP], SCDHS, Dvirka and ~artilucci, and Mal-o]m Pirnie, Inc., 1987) performed for other Suffolk County and Cornell studies, which indicate an average nitrogen concentration of approximately 3.8 to 3.9 mg/1 in areas with one dwelling unit per acre. Article 6 of the Suffolk County Sanitary Code limits development in n~n-=ewered areas to 40,000 square feet per single family home [or its equivalent in terms of 300 gpd of sanitary flow) in Hydrogeologic Zones 3,5, and 6, and 20,000 square feet per unit (medium-density) with average groundwater nitrogen concentrations of 4 ppm and 6 ppm, respectively (comparing well with the CWRMP and Cornell reports). The goal of the Article 6 regulations is to ensure that nitrogen doe5 not exceed the 10mg/1 drinking water limit. Phosphate can tzi.~ge: ~:.~rophi£at[ of surface waters if .t .£ the limiting nutrient. Phosphate generally has a concentration of 20 mg/L in domestic sewage. Some researchers such as Shawney and Hill subscribe to the theor}' that soils absorbs phosphorous. As the groundwater fluctuates, a soil section that has been absorbing phosphate is left with no recharge. Over a 6 month period, phosphate will combine with Iron (Fe), Aluminum (Al), or Calcium (Ca) to form less soluble precipitates. The original absorption sites are then regenerated. This theory results in the following computation: Normal domestic waste concentration is 20 mg/L 40% removal by biocrust & septic tank: 20 mg/L x 60% = 12 mg/L Absorption rate by soil: 22 mg/lb, of soil Daily flow to septic system (600 gal/day) (3.8 L/gal) = 2271 L/day PO = 12 mg/L x 2271 L/day = 27,252 mg/day Calculate absorption in one foot section of soil: 1 ft (width) x 1 ft (height) x 120 ft (length of system) = 120 cf 11-4 I I I I I I I I I I I I I I I I I I I Soil weight: 120 cf x 120 lb/cf = 14,400 lb/cf Absorption per foot: 14,400 lb/cf x 22 mg/lb = 316,800 mg/ft Distance traveled per day: 27,252 mg/day - 316,000 mg/ft = 0.087 it/day Distance traveled in 6 months: 0.087 it/day x 30 days x 6 months = 15.6 ft Distance available: + 120 ft Other prominent investigators such as Vollenwilder and Dillon of the Ontario Institute in Canada subscribe to the theory that a phosphate wedge continues toward the surface water at a continuous steady state rate. Trace organics ranging from household cleaners to paints and solvents can be found in some septic systems. Sometimes septic tank additives which contain organic pollutants are used on septic systems. Some trace organics can move readily in the groundwater. It can be concluded that drought conditions result in groundwater flows toward the ponds and aquifer and possible pollution of them. The pathways of pollutants from septic systems to the three ponds and the Middle Farms Flat aquifer should be carefully evaluated prior to any additional construction of residences. 11-5 I I I I I I I I I I I I I I I I I I BIBLIOGRAPHY In order to evaluate the study area, the following data was collected and analyzed. Existing surface water quality data The U.S.G.S. topographical mapping The U.S.G.S. surficial and bedrock geological informtion The Department of Agriculture SCS soil survey of Suffolk County, NY Mapping dated 1929 of the Infiltration Gallery by W. Brown, Inc. The Suffolk County DPW 1" = 200 it. scale topographical mapping of the study area Test pit logs for selected recently installed septic systems near the reservoirs Report "Pleistocene Stratigraphy of Long Island New York", Les Sirkin, Department of Earth Sciences, Adelphi University, 1982 Report "Hydrogeologic Report conducted on Fishers Island, New York, for Fishers Island Conservancy", Groundwater, Inc., April 1990 Report "Fishers Island Production Wells for the Fishers Island Water Works Corporation, Fishers Island, New York", Groundwater, Inc., May 1989 Precipitation recorded by the Fishers Island Water Works Corporation, Mike Conroy, Assistant Supervisor. Ground, reservoir and stormwater quality data collected and analyzed by Henry Souther Laboratories, Inc. Field surveys by ARL, Inc. of water surfaces Field measurements of reservoir responses to rainfall events Town of Southold Assessor's mapping Zoning map for building after 1989 Field edits of the Barlow Pond, Middle Farms Pond, Treasure Pond, the Infiltration Gallery and Aquifer tributary areas Dye tracing flow in manholes il and 12 of the infiltration gallery Connecticut DEP Guidelines for Discharge of Swimming Pool Wastewaters Consultation with Mr. Kevin Walsh, Manager, Water Quality, Connecticut Water Co,any "Water Resources Engineering", Linsley and Franzini, 1972 Report on Fishers Island Water Works, January 29, 1988, Buck and Buck Engineers, Hartford, CT Protecting Connecticut's Water-Supply Watersheds: A Guide for Local Officials, May 1990, James M. Doenges Source Protection and the Small Utility, AWWA Journal, August 1988, William D. Gollmitz Safeguarding Groundwater AWWA Journal, September 1986, W. R. Dobratz, et al. I I I I I I I I I I I I I I I I I I I APPENDIX A SAMPLE RESULTS - RESERVOIR I I I I I I I I THE NEWLANDS SANITARY LABORATORY TEL. (203) 242..6201 FAX (203) 286..0634 ARL Job #91-2040 REPORT ON EXAMINATION OF WATER Sample No. 745J2 Date Received 9/17/92 . Hour . Tcmp ........ Clicm A. R. Lomb. ard.i.Assoc.., 25 Te~Fa~...Dri.ve., Vernpn,..Conn. 06066 Attn:....M.~.ke Horn Collected By Mik~ Hor~ .............. Date 9/!7/.92... Rcportcd ...9/.24/92... Source Fischers .IslAnd..~..Bar]ow Po~td..H.i.d,. Depth...Temperature 22°C ................ Color (tn~) (apparent) 70 .. Odor...Di.stinct..Gr.assy .................... pH ..... 6..1.. Turbidity 1.1 Sediment .Slight (Saqd-!ike). I. Solids, VolatiJc ........................ 9." 2. Fixed ............... I O. 3. Total . ..7.2 ....... 11. 4. Effcct on hcating ............. 12. 5. Ammonia Nitrogen .... ~).,.000 ..... 13. 6. Albuminoid Nitrogen - - - . .................. 14. ?. Nitrite Nitrogen ........ 9.:.909 ..... IS. 8. Nitrate Nitrogen ......... 17. Bacteria per mL at :)S°C. 18. Tolal Coliform Or~s ..... Foaming ..... Cbloridc ........... ~.~ .......... AIk,'dinity ............. ~.(~ ...... Total Hardocss ....... ~'.[. · · Frcc C'O= (Calculated) - - . ...... !3.5_ . 0.66 Mangancsc .1 e~ [~p...Q, Q.]~ ..... Detergents .... . ...................... ..... Co~d.uct iyi.t2~..@..25.~ ~ ...... 90..mi. cx'.o~hos/cm I (All chemical da~ given in parts per million.) Fecal Coliforms (@ 44.5°C) 2 Fecal Streptococcus (@ 35°C) 3 m Phosphate (PO4) 0.05 Sodium (Na) 11.4 m GENERAL CONCLUSIONS: m m m m i IM6A ........................................... ..~. Labor o y Director ' , '5£ J?;O0 HEHF'~ SOUTHER LABS THE NEWLANDS SANITARY LABORATORY RI~ORT ON EXAMINATION OF WATER · ~npk No.' 1076,~E .Dato Rec, civod ..g/.Z4/92 ........ Hour .............. Tcmp ....... Client ...A,...R,...I,C~.!:~.t~.~..s.p.¢, ,..A.t,.trL~.....~:1.~..Hqf'B.e .................. Co~zd By ........................................................... mt,..91~.~Z~ ........ P,c~o~(l ..... 10l:119.2. So~,~...,.Et~h.e..~..!~!.a.~....-...!~.r. Lo.~ .~.o.p..d.....~L~....~. p.~h ....................................................... Co~ (m~) ............ (apparent) ... 9.0 ....... Odor ....... F.a.~J~t..~egetab. l.e ..................... pH ...... .~,..4. Turbidity ...L.6.... Sedin~nt . ~,~S:id.e.r~.b.].e..Re.d-!h:'0~!~ ............. Foaming .... !, ~ Voh~ . . . ....................... 9:'. Chloride .............. ZS. ...... 2. FGed ....................... 10. Alknlinity ............ ~.... 3. Tolal ..... ~ .............. II. Total Hardne~ - . ......... ~.Z.. 4. 'Effort on he, tins ..................... 12. Freo CO~ (Calculated) - . ..... 4.,.0 s.' An~no~ ~it~-~ ..... ..0.:.0.,0...6. ..... ~. ~o~. -- . ............. 0.....~. 6. AIl~miaoidNitmlea ....................... 14.Mangan~o .............. ~.;,Q~. 7. ~'=i~i~o~n. .........O.,..Q.O...q ..... Js.De~r~nt~ ..................... S. N'~ab~ N'm~:)l~ - ........0.,.7,.~ ........ ~6...Rht~P.h~,.1;~...(~..P..I~4). .................. 0.,.~8.... 17. Bacl~ia per mL at :~oC. 18. TeUlCol~mm O_l~s ...... ~.Q .... Fecal Colifom Fecal Streptococcus Conductivity e 25°C Sodtu~ (Na) (All chemicaldm~vcnMpimpcrn~lllon.) 2 90 mtcromhos/cm 1D.8 G~,N~.M~. CONCLt~IONS: ...................................................... La~oratory Director THE NEWLANDS SANITARY LABORATORY HENRY SOUTHER LABORATORIES. PROPRIETOR TEL. (203) 242-6291 FAX (203) 21~0634 ARL Job #91-2040 REPORT ON EXAMINATION O1: WATER Sample No. 746J2 Date Received 9/16/92 . Hour .... Tcmp ..... Client A.. R. Lombardi. Assoc., 25 Terrac. e Drive.,.Vernon, Conn. 06066 Attn.;...Mike Horn Collected By .. Mike Horn ................. Date ....9/.1.~/92 ..... Reported ..... 9_/.24/92.. Source Fishers Island, Middle Farm Pond - Mid Depth - Temperature 22°C ,. ...... ............................................. . .......... on he "~'~ Co'o, ( ,[.~ ) ( ~pp~[c"' ) · 3 2 .... Odor Very..f!! n.t..~o.1 d, ~C~n~ .......... ~ ........... Turbidity 4.5 Sediment 1. I 3. 4. 5. ?. 8. I I'L 18. I ! I I .. Moderate GFeen Solids, VolatUc .... . .................. Fixed ............. Total ....... ~.07 .... Effect on heating - - . .... Ammonia Nitrogen ......... 0,000... Albumin@id Nitrogen ............... ' Nitrite Nitrogen ............... 0..000... Nitrate Nitrogen ............... 0,.Q3 ..... Bacteria per ml. at 35°C. Total Coliform Organisms ........... Foaming 9." Chi@ride ............... 28 ........ 10. AIknlinity ............ ~.'. · · Il. Total Hurdncss .......... ~9. 12. Frcc CO. (Calculated) ......... 28. ~ .... 0.11 13. Iron ............................. 14. Manganese .... . ........... 15. D~terg~nts ......................... 16 .... Cl01~ du.c.t J Y j.~yl..@..2 ~.°.C ...... 9 5.,i. m J. cIz0lllho s / cm (All chemical data given in parts per million.) Fecal Coliforms (@44.5°C) Fecal Streptococcus (@ 35°C) Phosphate (PO4) Sodium (Na) 0 0 0.10 11.4 (~ENERAL CONCLUSIONS: I I I I I FORM6.A /'~~/~ ~ Laboratory Director DEC 17 '92 12:59 HEHRY SOUTHER LABS 'THE NEWLANDS SANITARY LABORATORY REPORT ON ~XAMINATION OF WATER staple No. 2077,]2 .. Datc Rcc~i~l 9/2(/9Z Hour .... Tcmp ....... Oi~t ...A~,R...Lp.m..b.~rd.!..A~.~.~,..~..Att~:.....IU.ke. I~orne .................................... ~tcd By ........................................................ Da~c ....9l.~.4. l~2 ..... R,'-po~d ...... ].0/.7./~2... Smm:e. _F:[shex::LZ:s.'J.~,nd....-....Hlddle..Ea~ms...P. onA Z/Z..dep.~ ....................................... ¢dot (true) ........... '. (apparent). _20 ......... Odor ....... F.~..~.fl~;..~bbag.~ ........................ pH .....5.,.7.... .'....Hoderate J~d,flr, own ................... Foamin8 ......... ........................ ~ Chlorldc - - 32 .................... ~" 11. Total Hatdncss ........... .4.! ..... ................... 12. Frec CO=- (Calculated) -. ......... ~O.. ............. .0..;~0..0 13. Iron - . ............. ~0.,].~. ...................... 14. Mang~csg .............. 0...03. .............. .O,,.O,.O.O ~. ~r~-.~ ...................... ............. 0.,.0.7.. ~ ..... P. hosph~t.~..LP.O~.)* - .......................... 0...09. Feca1,Collfoms Fecal Streptococcus Conductivtt~ ~ 25°C Sodium (Na) (A3ld~:mie~dam~ven~lml, spermallon.) 680 0 100 mic~omhos/cm THE NEWLANDS SANITARY LABORATORY HENRY SOUTHER LABORATORIES, PROPRIETOR BLOOMFIELD, CONNECTICUT O&O02 TEL. (203) 242-6291 FAX (203) 2Ba-0634 ARL Job #91-2040 I I I I I I I I REPORT ON EXAMINATION OF WATER Sample No. 747j2 Datc Received .9/16/92 Hour ........ Tcmp ......... Client A. g. I:ombar~di..As~0c.,, 25.TeFra.~e..Dr!ve,Vernon, ~;onn,. 06066 -.At.tn:....l~ike Collectcd By N.i ke Horn ..................... Date ..... ~[~/.9.~... Rcponcfl ...9~/.~/.~ ..... Source Fisher~..[s.~.a. od..:...~[~e~.~re..Po~d...~J~jd Depth,. -...Tempeca~ure 22°C .............. Color (true) (apparent) ~ .. Odor ..Very...faint ............................ pH ....... 5.3. Turbidity 1. 2. 3. 4. 5. 6. 7. 8. 17. 0.44 S~dimcnt . Very. slight. Solids, Volatile ...................... Fixed ............. Total ......... 74 ........ Effect on hcating ............ Ammonia Nitrogen - - - . 0..000. ..... .......... Foaming 97 Chloride - 10. I1. 12. 13. Albuminoid Nitrogen - - - . ................ 14. Nitrite Nitrogen .... . .... 0,.000 ..... 15. 18. Nitrate Nitrogen ........... ..0.,.Q~0 ......16. Bacteria per mL at 35~C, Total Collfotm OI~nn~xmx Fecal Colifoms (@ 44.5°C) Alkalinity .............. .6. ..... Total Hardness - - - ........ 31 Frcc CO= (Calculated) - . ....... 60 ..... Manganese .... . ............. Detergents ..................... m Fecal Streptococcus (~ 35°C) Phosphate (PO4) Sodium {Na) m Horn I Conductiy.i,t~..~..£SSC ......llO..micro~nhos/cm GENERAL CONCLUSIONS: (All chemical data given in parts per million.) 0 0 0.02 15.5 I 1 I I I FORM 6.A Director DEC 17 'gE 1~:58 NENPY SOUTHE~ L~, THE NEWLANDS SANITARY LABORATORY IEPOKT ON EXAMINATION OF WATER S3mplc No. 107~J2 .. Date R~,ai~d 9/2~/9,2 ...... Hour ............. Tcmp ..... Oient .A..g, ,Lombatd.i..),ssoc,,..Atlm:....~ke .l~ne ...................... Con~c~d By ............................................................ ~t~ .,.9/.2.~/...9..~ ....... ~o~d ..1,0../.21.~;~ ....... So,~ .K~.b.e..,..s....[~.T~.n..d....-....T..re~ure..Po.~d..~l.Z, I~pth .................................................... ~ (true) .............(a~) .... 5 .......Odor ...... .F. ~3..n..t,...v..~.ge~b Te ....................... pH ....... . .. Yery .,sT:ight. ............................ Foaming ................. ..................... !0, All~Unlty - . .......... ~ ...... ...... 7.0 ............. I I. Total Hatdne~.~ , 35 .................. 12, F~ CO~ (Ca]curtal) - - 39 ....... ~r~g'~.~ ..... t3. Itoh. les~...th~n,..O.,.OL ...................... 14. Man~,ancs~ .............. 0,.0Z ........ .o.,..o..o...o. ..... ~s. ~t~-nta , . .................. ........ I~,.pg.O. ..... 16, ._1~ hg.s~ha~..J, Rg.4.! .......................... n..03.., (Ail ~ data ~iven in psis per million.) Fecal Collfo~s Fec&l Streptococcus Conductivity (~ 25°C) Sodium (Na) 0 0 105 micromho$/cm 14.8 GF.N f~.Al, COHCI, UIIOflS: Laboratory Director I I I I I I I I I I I I I ! I I I I I APPENDIX B SAMPLE RESULTS - S?ORMWATER RUN-OFF I [~[~ HENRY SOUTHER LABORATORIES ~ INC. N®wllnd~ Sanitary Lab Division I I I A. PICHARD LOf.~i~ARDI, P.E. RICHARD J. I.OMBARDI ViCe Pres~t THOMAS D. LEE 24 Tobey Road · Bloomfield, CT · 06002 ENVIRONMENTAL AND METALLURGICAL ANALYSIS Established 1898 203-242-6291 FAX 203-286-0634 October 29, 1992 m A. R. Lombardi Assoc. 25 Terrace Drive Vernon, Conn. 06066 m Attn: Mr. Mike Horne Gentlemen: ARL Job #91-2040 Fishers Island The attached report covers the analysis of samples submitted to this laboratory on October 13, 1992. Newlands Sanitary Laboratory sample numbers 478K2 thru 485K2. I I ! I TDL/cas Very truly yours, THE NE~ANITARY/_////~/x(~,,i/~LABORATORY~ Thomas D. Lee Laboratory Director I I RECEIVED NOV 2 1992 I I CZ) 0 o o I [~[~ HENRY SOUTHER LABORATORIES ~ INC, I Newlindl Sinlblry Lllb Division 24 Tobey Road · Bloomfield, CT · 06002 ENVIRONMENTAL AND METALLURGICAL ANALYSIS Established 1898 v~.~o~..., November 25, 1992 I THOMAS O. LEE m A. R. Lombardi Assoc., Inc. 25 Terrace Drive Vernon, Conn. 06066 m Attn: Galen Semprebon I I ARL Job #91-2040 Fisher Island Gentlemen: The attached report covers the analysis of samples submitted to this laboratory on October 27, 1992. Newlands Sanitary Laboratory sample numbers 1188K2 thru 1195K2. I ! I I I Very truly yours, THE~g~.~~NEWLAND ANITARY LABORATOR I I TDL/cas Thomas D. Lee Laboratory Director I I I I RECEIVED rife. ~. 1992 d J 0 CD '7- 'r' 0 0 0 o~ I I I I I I I I I I I I I I I i I I I A. RICHARD LOMBARDt, P.E. President RICHARD J. LOMBARDI Vice President THOMAS D. LEE HENRY SOUTHER LABORATORIES INC Newlands Sanitary Lab Division 24 Tobey Road · Bloomfield, CT · 06002 ENVIRONMENTAL AND METALLURGICAL ANALYSIS Established 1898 203-242-6291 FAX 203-286.0634 November 5, 1992 A. R. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 An'N: Mr. Jim Sommers Gentlemen: The attached report covers the analysis of lfle samples submitted to this laboratory on October 27, 1992. Newlands Sanitary Laboratory Request No. 880, samples 1 through 10. RJL/pb Very ffuly yours, THE NEWLANDS SANITARY LABORATORY Richard J. Lombardi Vice President ! ! Send Results To: Mr. Jim Sommers A.R. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 Analyzed By: Henry Souther Labs Inc. 24 Tobey Road Bloomfield, CT 06002 I Request # 880 I IReport Date 11/05/92 I 10 water samples submitted by A. R. Lombardi Assoc., Inc./Fishers Island on 10/27/92 for VOC 63. I(EPA 502.2) Sample Number I B-l, water sample collected 10126192. 1,1,1,2-Tetrachloroethane Less than 0.5 ug/L 1,1,1-Trichloroethane Less than 0.5 ug/L 1,1,2,2-Tetrachloroethane Less than 0.5 ug/L 1,1,2-Trichloroethane Less than 0.5 ug/L 1,1,2-Trichlorotrifiuoroethane Less than 0.5 ug/L 1,1-Dichloroethane Less than 0.5 ug/L 1,1-Dichloroethene Less than 0.5 ug/L 1,1-Dichloropropene Less than 0.5 ug/L 1,2,3-Trichlorobenzene Less than 0.5 ug/L 1,2,3-Trichloropropane Less than 0.5 ug/L 1,2,4-Trichlorobenzene Less than 0.5 ug/L 1,2,4-Trimethylbenzene Less than 0.5 ug/L 1,2-Dibromo-3-chloropropane (DBCP) Less than 0.02 ug/L 1,2-Dibromoethane (EDB) Less than 0.02 ug/L 1,2-Dichlorobenzene Less than 0.5 ug/L 1,2-Dichloroethane Less than 0.5 ug/L 1,2-Dichloropropane Less than 0.5 ug/L 1,3,5-Trimethylbenzene Less than 0.5 ug/L 1,3-Dichlorobenzene Less than 0.5 ug/L 1,3-Dichloropropane Less than 0.5 ug/L 1,4-Dichlorobenzene Less than 0.5 ug/L 2,2-Dichloropropane Less than 0.5 ug/L 2-Chloroethylvinylether Less than 0.5 ug/L 2-Chtorotoluene Less than 0.5 ug/L 4-Chlorotoluene Less than 0.5 ug/L Benzene Less than 0.5 ug/L Bromobenzene Less than 0.5 ug/L Bromochloromethane Less than 0.5 ucj/L Bromodichloromethane Less than 0.5 ug/L Bromoform Less than 0.5 ug/L Bromomethane Less than 0.5 ug/L c-l,2-Dichloroethylene Less than 0.5 ug/L c-l,3-Dichloropropene Less than 0.5 ug/L Carbon tetrachloride Less than 0.5 ug/L Chlorobenzene Less than 0.5 ug/L Chloroethane ] Less than 0.5 ug/L Send Results To: Mr. Jim Sommem A.R. Lombardi Associates, Inc. Analyzed By: Henry Souther Labs Inc. 25 Terrace Drive Vernon, CT 06066 Request # 880 I Rel.~..~ Date 11/05/92 J 10 water samples submitted by A. R. Lombardi Assoc., Inc./Fishers Island on 10/27/92 for VOC 63. (EPA 502.2) Chloroform Less than 0.5 ucj/L Chloromethane Less than 0.5 ug/L Dibromochloromethane Less than 0.5 ug/L Dibromomethane Less than 0.5 ug/L Dichlorodifluoromethane Less than 0.5 ug/L Ethylbenzene Less than 0.5 ug/L Hexachlorobutadiene Less than 0.5 ug/L Isopropy~benzene Less than 0.5 ucj/L m-Xylene Less than 0.5 ug/L Methyl t-butyl ether (MTBE) Less than 0,5 ug/L Methylene chloride Less than 0.5 ug/L n-I]utylbenzene Less than 0.5 ugJL n-Propylbenzene Less than 0.5 ug/L Naphthalene Less than 0.5 ug/L o-Xylene Less than 0.5 ug/L p-tsopropyltoluene Less than 0.5 ug/L p-Xylene Less than 0.5 ug/L sec-Butylbenzene Less than 0.5 ug/L Styrene Less than 0.5 ug/L t-l,2*Dichloroethylene Less than 0.5 ug/L t-l,3-Dichloropropene Less than 0.5 ug/L tert-Butylbenzene Less than 0.5 ucj/L Tetrachloroethylene Less than 0.5 ug/L Toluene Less than 0.5 ug/L Trichloroethylene Less than 0.5 ug/L Trichlorofluormethane Less than 0.5 ug/L Trimethybenzene Less than 0.5 ug/L Vinyl chloride Less than 0.5 ug/L Sample Number 2 B-2, water sample collected 10/26/92. 24 Tobey Road Bloomfield, CT 06002 1,1,1,2-Tetrachloroethane 1,1,1 -Trichloroethane 1,1,2,2-Tetrachloroethane 1.1,2-Trichloroethane 1.1,2-Trichlorot rifluoroethane 1,1 -Dichloroethane 1.1 -Dichloroethene 1.1-Dichloropropene Less than 0mS ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0m 5 ug/L Less than 0.5 ugJL Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ugJL ! ! Send Results To: Mr. Jim Sommers AR. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 Analyzed By: Henry Souther Labs Inc. 24 Tobey Road Bloomfield, CT 06002 IRequest # 880 I I I I I I I I I I I I I I I J ~ Date 11/05/92 10 water samples submitted by A. R. Lombardi Assoc., Inc./Fishers Island on 10/27/92 for VOC 63. (EPA 502.2) 1,2,3-Trichlorobenzene 1,2,3-Trichloropropane 1,2,4-Trichlorobenzene 1,2,4-Trimethylbenzene 1,2-Dibromo-3-chloropropane (DBCP) 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3,5-Trimet hylbenzene 1,3-Dichlorobenzene 1,3-Dichloropropane 1,4-Dichlorobenzene 2,2-Dichloropropane 2-Chlo roethylvinylether 2-Chlorotoluene 4-Chlorotoluene Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane c-1,2-Dichloroethylene c-1,3-Dichloropropene Carbon tetrachloride Chlorohenzene Chloroethane Chloroform Chloromethane Dibromochloromethane Dibromomethane Dichlorodifluoromet hane Ethylbenzene Hexachlorobutadiene Isopropylbenzene m-Xylene Methyl t-butyl ether (MTBE) Methylene chloride Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.5 ucj/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug,/L Less than 0.5 ug,/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ucj/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ucj/L Less than 0.5 ucj/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Send Results To: Mr. Jim Sommers A.R. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 Analyzed By: Henry Soulher Labs Inc. 24 Tobey Road Bloomfield, CT 06002 Re(:{uest#,880 I Re~ate 11/05/92 J 10 water samples submitted by A. R. Lombardi Assoc., Inc./Fishem Island on 10/27/92 for VOC 63. (EPA 502.2) n-Butylbenzene Less than 0.5 ugJL n-Propylbenzene Less than 0.5 ug/L Naphthalene Less than 0 5 ugJL o-Xylene Less than 0.5 ug/L p-lsopropyltoluene Less than 0,5 ug/L p-Xylene Less than 0.5 ug/L sec-Butylbenzene Less than 0.5 ug/L Styrene Less than 0.5 ug/L t-l,2-Dichloroethylene Less than 0.5 ug/L t-l,3-Dichloropropene Less than 0.5 ug/L tert-Butylbenzene Less than 0.5 ug/L Tetrachloroethylene Less than 0.5 ug/L Toluene Less than 0.5 ug/L Trichloroethylene Less than 0.5 ug/L Trichlorofluormethane Less than 0.5 ug/L Trimethybenzene Less than 0.5 ug/L V~nyi chloride Less than 0.5 ug~L Sample Number 3 B-3, water sample collected 10/26/92. ,1,1,2-Tetrachlo roethane 1,1,1 -Trichloroetha ne ,1,2,2-Tet fac hloroethane ,1,2-Trichloroethane ,1,2-Trichlorotrifluoroethane 1,1 -Dichloroethane 1,1 -Dichloroethene 1,1 -Dichloropropene ,2,3-Trichlorobenzene ,2,3-Trichloropropane ,2,4-Trichlorobenzene ,2,4-Trimethylbenzene 1,2-Dibromo-3-chtoropropane (DBCP) 1,2-Dibromoethane (EDB) ,2-Dichlorobenzene ,2-Dichloroethane ,2-Dichloropropane ,3, 5-Trimethylbenzene ,3-Dichiorobenzene 4 Less than 0.5 ug/L Less than 0.5 ucJ/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ucj/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 u~/L Less than 0.5 ug/L Less than 0.02 ug/L Less than 0 02 ug// Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L ! ! Send Results To: Mr. Jim Sommers A.R. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 Analyzed By: Henri Souther Labs Inc. 24 Tobey Road Bloomfield, CT 06002 IRequest # 880 I Rel.~.,Dort Date I 1/05/92 ] 10 water samples submitted by A. R. Lombardi Assoc., Inc./Fishers Island on 10/27/92 for VOC 63. (EPA 502.2) 1,3-Dichloropropane Less than 0.5 ug/L 1,4-Dichlorobenzene Less than 0.5 ug/L 2,2-Dichloropropane Less than 0.5 ug/L 2-Chloroethylvinylether Less than 0.5 ug/L 2-Chlorotoluene Less than 0.5 ug/L 4-Chlorotoluene Less than 0.5 ug/L Benzene Less than 0.5 ug/L Bromobenzene Less than 0.5 ug/L Bromochloromethane Less than 0.5 ug/L Bromodichloromethane Less than 0.5 ug/L Bromoform Less than 0.5 ~Kj/L Bromomethane Less than 0.5 ugJL c-l,2-Dichloroethylene Less than 0.5 ug/L c-l,3-Dichloropropene Less than 0.5 ug/L Carbon tetrachloride Less than 0.5 ug/L Chlorobenzene Less than 0.5 ug/L Chloroethane Less than 0.5 ug/L Chloroform Less than 0.5 ug/L Chloromethane Less than 0.5 ug/L Dibromochloromethane Less than 0.5 ug/L Dibromomethane Less than 0,5 ug/L Dichlorodifluoromethane Less than 0.5 ug/L Ethylbenzene Less than 0.5 ug/L Hexachlorobutadiene Less than 0,5 ug/L Isopropylbenzene Less than 0.5 ug/L m-Xylene Less than 0.5 ug/L Methyl t-butyl ether (MTBE) Less than 0.5 ug/L Methylene chloride Less than 0.5 ug/L n-Butylbenzene Less than 0.5 ug/L n-Propylbenzene Less than 0.5 ug/L Naphthalene Less than 0,5 ug/L o-Xylene Less than 0.5 ug/L p-lsopropyltoluene Less than 0.5 ug/L p-Xylene Less than 0.5 ug/L sec-Butyibenzene Less than 0.5 ug/L Styrene Less than 0.5 ug/L t-l,2-Dichloroethylene Less than 0,5 ug/L t-l,3-Dichloropropene Less than 0.5 ug/L tert-Butylbenzene 5 Less than 0.5 ug/L Send Results To: Mr. Jim Sommers A.R. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 Analyzed By: Hen~ Sou~erLabslnc. 24T obey Road Bloomfield, CT 06002 Rec{uest# 880 ] ReL~.~_..~Date 11/05/92 ] 10 water samples submitted by A. R. Lombardi Assoc., tnc./Fishers Island on 10/27/92 for VOC 63. (EPA 502.2) Tetrachloroethylene Less than 0.5 ug/L Toluene Less than 0.5 ug/L Trichloroethylene Less than 0.5 ucj/L Trichlorofluormethane Less than 0.5 ug/L Trimethybenzene Less than 0.5 ug/L Vinyl chloride Less than 0.5 ucjJL Sample Number 4 Middle Farm M-1 water sample collected 10/26/92 1,1,1,2-Tetrachloroethane 1,1,1 -Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1,2-Trichlorotrifl uoroethane 1,1 -Dichloroethane 1,1 -Dichloroethene 1,1 -Dichloropropene 1,2,3-Trichlorobenzene 1,2,3-Trichloropropa ne 1,2,4-Trichlorobenzene 1,2,4-Trimethylbenzene 1,2-Dibromo-3-chloropropane (DBCP) 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3, 5-Trimethylbenzene 1,3-Dichlorobenzene 1,3-Dichloropropane 1,4-Dichlorobenzene 2,2-Dichloropropane 2-Chloroet hylvinylether 2-Chlorotoluene 4*Chlorotoluene Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.6 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ugJL I I I I I I I I I I I I I I I I I I I Send Results To: Mr. Jim Sommers A.R. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 Recluest # 880 1 IRep°rt Date 1 1/05/92 10 water samples submitted by A. R. Lombardi Assoc., Inc./Fishers Island on 10/27/92 for VOC 63. (EPA 502.2) Bromomethane c-1,2-Dichloroethylene c-1,3-Dichloropropene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane Dibromomethane Dichlorodifluoromet hane Ethylbenzene Hexachlorobutadiene Isopropylbenzene m-Xylene Methyl t-butyl ether (MTBE) Methylene chloride n-Butylbenzene n-Propylbenzene Naphthalene o-Xylene p-lsopropyltoluene p-Xylene sec-Butylbenzene Styrene t-1,2-Dichloroethylene t-1,3-Dichloropropene tert-Butylbenzene Tetrechloroethylene Toluene Trichloroethylene Trichlorofluormethane Trimethybenzene Vinyl chloride Sampla Number 5 Analyzed By: Henry Souther Labs Inc. 24 Tobey Road Bloomfield, CT 06002 Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ugJL Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug,/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Middle Farm M-2, water sample collected 10/26/92. 1,1,1,2-Tetrachloroethane 1,1,1 -Trichloroetha ne Less than 0.5 ug/L Less than 0.5 ug/L Send Results To: Mr. Jim Sommers A.R. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 Analyzed By: Request # 880 10 water samples submitted by A. R. Lombardi Assoc., Inc./Fishers island on 10/27/92 for VOC 63. (EPA 502.2) 1,1,2,2-Tetrachloroethane Less than 0.5 ug/L 1,1,2-Trich~oroethane Less than 0.5 ug/L 1,1,2-Trichlorotrifluoroethane Less than 0.5 ug/L 1,1-Dichloroethane Less than 0.5 ug/L 1,1-Dichloroethene Less than 0.5 ug/L 1,1-Dichloropropene Less than 0.5 ug/L 1,2,3-Trichlorobenzene Less than 0.5 ug/L 1,2,3-Tr~chloropropane Less than 0.5 ugJL 1,2,4-Trichlorobenzene Less than 0.5 ugJL 1,2,4-Trimethylbenzene Less than 0.5 ug/L 1,2-Dibromo-3-chloropropane (DBCP) Less than 0 02 ug/L 1,2-Dibromoethane (EDB) Less than 0.02 ucj/L 1,2-Dichlorobenzene Less than 0.5 ug/L 1,2-Dichloroethane Less than 0.5 ucj/L 1,2-Dichloropropane Less than 0.5 ug/L 1,3,5-Trimethylbenzene Less than 0.5 ug/L i,5 ~ch[orobenzene Less than 0.5 ugJL 1,3-Dichloropropane Less than 0.5 ug/L 1,4-Dichlorobenzene Less than 0.5 ucj/L 2,2-Dichloropropane Less than 0.5 ugJL 2-Chloroethylvinylether Less than 0.5 ug/L 2-Chlorotoluene Less than 0.5 ug/L 4-Chlorotoluene Less than 0.5 ugJ'L Benzene Less than 0.5 ug/L Bromohenzene Less than 0.5 ug/L Bromochloromethane Less than 0.5 ugJL Bromodichloromethane Less than 0.5 ug/L Bromoform Less than 0.5 ug/L Bromomethane Less than 0.5 ug/L c-l,2-Dichloroethylene Less than 0.5 ug/L c-l,3-Dichloropropene Less than 0.5 ug/L Carbon tetrachloride Less than 0.5 ug/L Chlorobenzene Less than 0.5 ug/L Chloroethane Less than 0.5 ug/L Chloroform Less than 0.5 ug/L Chloromethane Less than 0.5 ug/L Dibromochioromethane Less than 0.5 ug/L Dibromomethane Less than 0.5 ug/L Dichlorodifluoromethane 8 Less than 0.5 ug/L Henry Souther Labs Inc. 24 Tobey Road Bloomfield, CT 06002 I I I I I I I ! I I I I I t I I ! i / Send Results To: Mr. Jim Sommers A.R. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 Analyzed By: Henry Souther Labs Inc. 24 Tobey Road Bloomfield, CT 06002 Sample Number 6 Recluest # 880 I Re[.~.~..~Date I 1/05/92 J 10 water samples submitted by A. R. Lombardi Assoc., Inc./Fishers Island on 10/27/92 for VOC 63. (EPA 502.2) Ethylbenzene Less than 0.5 ug/L Hexachlorobutadiene Less than 0.5 ug/L Isopropylbenzene Less than 0.5 ug/L m-Xylene Less than 0.5 ug/L Methyl t-butyl ether (MTBE) Less than 0.5 ug/L Methylene chloride Less than 0.5 ug/L n-Butylbenzene Less than 0.5 ug/L n-Propylbenzene Less than 0.5 ug./L Naphthalene Less than 0.5 ug/L o-Xylene Less than 0.5 ug/L pqsopropyltoluene Less than 0.5 ug/L p-Xylene Less than 0.5 ug/L sec-Butylbenzene Less than 0.5 ug/L Styrene Less than 0.5 ug/L t-l,2-Dichloroethy[ene Less than 0.5 ug/L t-l,3-Dichloropropene Less than 0.5 ug/L tert-Butylbenzene Less than 0.5 ug/L Tetrachloroethyiene Less than 0.5 ug/L Toluene Less than 0.5 ug/L Trichloroethylene Less than 0.5 ug/L Trichlorofluormethane Less than 0.5 ug/L Trimethybenzene Less than 0.5 ug/L Vinyl chloride Less than 0.5 ug/L Middle Farm M-3, water sample collected 10/26/92. 1,1,1,2-Tetrachloroethane 1,1,1 -Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1,2-Trichlorot rifluoroethane 1,1 -Dichloroethane 1,1 -Dichloroethene 1,1 -Dichloropropene 1,2, 3-Trichlorobenzene 1,2,3-Trichloropropane 1,2,4-Trichlorobenzene 1,2,4-Trimethylbenze ne 1,2-Dibromo-3-chloropropane {DBCP) Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 u§/L Less than 0.02 ug/L Send Results To: Mr. Jim Sommers A.R. Lombardi Associates, inc. 25 Terrace Drive Vernon, CT 06066 Analyzed By: Hen~ Sou~erLabslnc. 24 Tobey Road Bloomfield, CT 06002 1,2-Dibromoethane (EDB) Less than 0.02 ug/L 1,2-Dichlorobenzene Less than 0.5 ug/L 1,2-Dichloroethane Less than 0.5 ug/L 1,2-Dichloropropane Less than 0.5 ug/L 1,3,5-Trimethylbenzene Less than 0.5 ug/L 1,3-Dichlorobenzene Less than 0.5 ug/L 1 ~3-Dichloropropane Less than 0 5 ug/L 1,4-Dichlorobenzene Less than 0.5 ug/L 2,2-Oichloropropane Less than 0 5 ug/L 2-Chloroethylvinylether Less than 0.5 ug/L 2-Chlorotoluene Less than 0.5 ug/L 4-Chlorotoluene Less than 0.5 ug/L Benzene Less than 0.5 ug/L Bromobenzene Less than 0.5 ug/L Bromochloromethane Less than 0.5 ug/L Bromodichloromethane Less than 0.5 ug/L Bromoform Less than 0.5 ug/L Bromomethane Less than 0.5 ug/L c-l,2-Dichloroethylene Less than 0.5 ug/L c-l,3-Dichloropropene Less than 0.5 ug/L Carbon tetrachloride Less than 0.5 ug/L Chlorobenzene Less than 0.5 ug/L Chloroethane Less than 0.5 ug/L Chloroform Less than 0.5 ug/L Chloromethane Less than 0.5 ug/L Dibromochloromethane Less than 0.5 ug/L Dibromometnane Less than 0.5 ug/L Dichlorodifluoromethane Less than 0.5 ug/L Ethylbenzene Less than 05 ug/L Hexachlorobutadiene Less than 0.5 ug/L Isopropylbenzene Less than 0.5 ug/L m-Xylene Less than 0.5 ug/L Methyl t-butyl ether (MTBE) Less than 0.5 ug/L Mett~ylene chloride Less tnan u.5 ug/L n-Butylbenzene Less than 0.5 ug/L n-Propylbenzene Less than 0.5 ug/L Naphthalene Less than 0.5 ug/L o-Xylene Less than 0.5 ug/L p-lsopropyltoluene ] 0 Less than 0.5 u§/L Request#880 I ReL~.~_.~.Date 11/05/92 J 10 water samples submitted by A. R. Lombardi Assoc., Inc./Fishers Island on 10/27/92 for VOC 63. (EPA 502.2) I I I I 1 I I I I i I I I I I I ! i Send Results To: Mr. Jim Sommers A.R. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 Analyzed By: Hen~Sou~erLabslnc. 24 Tobey Road Bloomfield, CT 06002 I IRep°rt Date 11/05/92 J Recluest # 880 10 water samples submitted by A. R. Lombardi Assoc., Inc./Fishers Island on 10/27/92 for VOC 63. (EPA 502.2) p-Xylene Less than 0.5 ug/L sec-Butylbenzene Less than 0.5 ug/L Styrene Less than 0.5 ug/L t-l,2-Dichloroethylene Less than 0.5 ug/L t-l,3-Dichloropropene Less than 0.5 ug/L tert-Butylbenzene Less than 0.5 ug/L Tetrachloroethylene Less than 0.5 ug/L ToJuene Less than 0.5 ug/L Trichloroethylene Less than 0.5 ug/L Trichlorofluormethane Less than 0.5 ug/L Trimethybenzene Less than 0.5 ug/L Vinyl chloride Sample Number 7 Less than 0.5 ug/L Treasure T-l, water sample collected 10/26/92. 1,1,1,2-Tetrachloroethane 1,1,1 -Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-TrJchloroethane 1,1,2-Trichlorotrifluoroethane 1,1-Dichloroethane 1,1 -Dichloroethene 1,1 -DichJoropropene 1,2,3-Trichlorobenzene 1,2,3-Trichloropropane 1,2,4-Trichlorobenzene 1,2,4-Trimet hylbenzene 1,2-Dibromo-3-chloropropane (DBCP) 1,2-Dibromoethane 1,2.Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3, 5-Trimethylbenzene 1,3-Dichlorobenzene 1,3-Dichloropropane 1,4-Dichlorobenzene 2,2-Dichloropropane 2~Chloroet hylvinylether 2-Chlorotoluene Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ugJL Less than 0.5 ucj/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0,5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ugJL Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L ]_ ] Less than 0.5 ug/L Send Results To: Mr. Jim Sommers A.R. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 Analyzed By: Hen~ Sou~erLabslnc. 24 Tobey Road Bloomfield, CT 06002 ReQuest# 880 I ReL~.~portDate 11/05/92 J 10 water samples submitted by A. R, Lombardi Assoc., Inc./Fishers Island on 10/27/92 for VOC 63. (E,PA 502.2) 4-Chlorotoluene Less than 0.5 ug/L Benzene Less than 0,5 ug,/L Bromobenzene Less than 0.5 ug/L Bromochloromethane Less than 0.5 ug/L Bromodichloromethane Less than 0.5 ug/L Bromoform Less than 0.5 ug/L Bromomethane Less than 0.5 ug/L c-l,2-Dichloroethylene Less than 0.5 ug/L c-l,3-Dichloropropene Less than 0.5 ug/L Carbon tetrachloride Less than 0.5 ug/L Chlorobenzene Less than 0.5 ug/L Chloroethane Less than 0.5 ug/L Chloroform Less than 0.5 ug/L Chloromethane Less than 0.5 ug/L Dibromochloromethane Less than 0.5 ug/L Dibromomethane Less than 0.5 ug/L Dichlorodifluoromethane Less than 0.5 ug/L Ethylbenzene Less than 0.5 ug/L Hexachlorobutadiene Less than 0.5 ug/L Isopropylbenzene Less than 0.5 ug/L m-Xylene Less than 0.5 ug/L Methyl t-butyl ether (MTBE) Less than 0.5 ug/L Methylene chloride Less than 0.5 ug/L n-Butylbenzene Less than 0.5 ug/L n-Propylbenzene Less than 0.5 ug/L Naphthalene Less than 0.5 ug/L o-Xylene Less than 0 5 ug/L p-lsopropyltoluene Less than 0.5 ug/L p-Xylene Less than 0.5 ug/L sec-Butylbenzene Less than 0.5 ug/L Styrene Less than 0.5 ug/L t-l,2-Dichloroethylene Less than 0.5 ug/L t-l,3-Dichloropropene Less than 0.5 ug/L tert-Butylbenzene Less than 0.5 ug/L Tetrachloroethylene Less than 0.5 ug/L Toluene Less than 0.5 ug/L Trichloroethylene Less than 0.5 ug/L Trichlorofluormethane Less than 0.5 ug/L Trimethybenzene ] ~, Less than 0.5 ug/L Send Results To: Mr. Jim Sommers A.R. Lombardi Associates, Inc. Analyzed By: Henry Souther Labs inc. 25 Terrace Drive 24 Tobey Road Vernon, CT 06066 Bloomfield, CT 06002 Request # 880 J JReport Date 11/05/92 I 10 water samples submitted by A. R. Lombardi Assoc., Inc./Fishers Island on 10/27/92 for VOC 63. i (EPA 502.2) Vinyl chloride Less than 0.5 ugJL i Sample Number 8 Swamp S-1, water sample collected 10/26/92. 1,1,1,2-Tetrachloroethane Less than 0.5 ug/L 1,1,1-Trichloroethane Less than 0.5 ug/L 1,1,2,2-Tetrachloroethane Less than 0.5 ug/L 1,1,2-Trichloroethane Less than 0.5 ug/L 1,1,2-Trichlorotrifluoroethane Less than 0.5 ug/L 1,1-Dichloroethane Less than 0.5 ug/L 1,1-Dichloroethene Less than 0.5 ug/L 1,1-Dichloropropene Less than 0.5 ug/L 1,2,3-Trichlorobenzene Less than 0.5 ucJ/L 1,2,3-Trichloropropane Less than 0.5 ucj/L 1,2,4-Trichlorobenzene Less than 0.5 ug/L 1,2,4-Trimethylbenzene Less than 0.5 ug/L 1,2-Dibromo-3-chloropropane (DBCP) Less than 0.02 ug/L 1,2-Dibromoethane (EDB) Less than 0.02 ug/L 1,2-Dichlorobenzene Less than 0.5 ug/L 1,2-Dichloroethane Less than 0.5 ug/L 1,2-Dichloropropane Less than 0.5 ug/L 1,3, 5-Trimet hylbenzene Less than 0.5 ug/L 1,3-Dichlorobenzene Less than 0.5 ucj/L 1,3-Dichloropropane Less than 0.5 ug/L 1,4t-Dichlorobenzene Less than 0.5 ug/L 2,2-Dichloropropane Less than 0.5 ug,/L 2-Chloroethylvinylether Less than 0.5 ug/L 2-ChJorotoluene Less than 0.5 ug/L 4-Chlorotoluene Less than 0.5 ug/L Benzene Less than 0.5 ug/L Bromobenzene Less than 0.5 ug/L Bromochloromethane Less than 0.5 ug/L Bromodichloromethane Less than 0.5 ug/L Bromoforrn Less than 0.5 ug/L Bromomethane Less than 0.5 ug/L c-l,2-Dichloroethylene Less than 0.5 ug/L c-l,3-Dichloropropene Less than 0.5 ug/L Carbon tetrachloride Less than 0.5 ug/L Chlorobenzene ]_ ..3 Less than 0.5 ug/L Send Results To: Mr. Jim Sommers A.R. Lombardi Associates, Inc. Analyzed By: Henry Souther Labs Inc. 25 Terrace Drive Vernon, CT 06066 Sample Number 9 24 Tobey Road Bloomfield, CT 06002 Request # 880 ] ~05/92 J 10 water samples submitted by A. R. Lombardi Assoc., Inc./Fishers Island on 10/27/92 for VOC 63. (EPA 502.2) Chloroethane Less than 0.5 ug/L Chloroform Less than 0.5 ug/L Chloromethane Less than 0.5 ug/L Dibromochloromethane Less than 0.5 ugJL Dibromomethane Less than 0.5 ug/L Dichlorodifluoromethane Less than 0.5 ug/L Ethylbenzene Less than 0.5 ug/L Hexachlorobutadiene Less than 0.5 ug/L Isopropylbenzene Less than 0 5 ug/L m-Xylene Less than 0 5 ug/L Methyl t-butyl ether (MTBE) Less than 0.5 ug/L Methylene chloride Less than 0.5 ug/L n-Butylbenzene Less than 0.5 ug/L n-Propylbenzene Less than 0.5 ug/L Naphthalene Less than 0.5 ug/L o-Xylene Less than 0.5 ug/L p-lsopropyltoluene Less than 0.5 ug/L p-Xylene Less than 0.5 ug/L sec-Butylbenzene Less than 0.5 ug/L Styrene Less than 0.5 ug/L t-l,2-Dichloroethylene Less than 0.5 ug/L t-l,3-Dichloropropene Less than 0.5 ug/L tert-Butylbenzene Less than 0.5 ug/L Tetrachloroethylene Less than 0.5 ug/L Toluene Less than 0.5 ug/L Trichloroethylene Less than 0.5 ug/L T.,,:? ;..:rofluormethane Less than 0.5 ug/L Trimethybenzene Less than 0.5 ug/L Vinyl chloride Less than 0.5 ug/L Field Blank, water sample collected 10/26/92. 1,1,1,2-Tetrac hloroethane 1 1,1-Trichloroethane 1,1,2,2-Tet fac hlo roetha ne 1,1,2-Trichloroethane 1,1,2-Trichlorotrifluoroethane 1,1 -Dichloroethane 1,1 -Dicnloroethene Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Send Results To: Mr. Jim Sommers A.R. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 I Request# 880 I ReL~.~_..~Date 11/05/92 I 10 water samples submitted by A. R. Lombardi Assoc., inc./Fishers island on 10/27/92 for VOC 63. (EPA 502.2) 1,1-Dichloropropene Less than 0.5 ug/L 1,2,3-Trichlorobenzene Less than 0.5 ug/L 1,2,3-Trichloropropane Less than 0.5 ug/L 1,2,4-Trichlorobenzene Less than 0.5 ug/L 1,2,4-Trimethylbenzene Less than 0.5 ug/L 1,2-Dibromo-3-chloropropane (DBCP) Less than 0.02 ug/L 1,2-Dibromoethane (EDB) Less than 0.02 ug,/L 1,2-Dichlorobenzene Less than 0.5 ug/L 1,2-Dichloroethane Less than 0.5 ug/L 1,2-Dichloropropane Less than 0.5 ug/L 1,3,5-Trimethylbenzene Less than 0.5 ug/L 1,3-Dichlorobenzene Less than 0.5 ug/L 1,3-Dichloropropane Less than 0.5 ug/L 1,4-Dichlorobenzene Less than 0.5 ug/L 2,2-Dichloropropane Less than 0.5 ug/L 2-Chloroethylvinylether Less than 0.5 ug/L 2-Chlorotoluene Less than 0.5 ug/L 4-Chlorotoluene Less than 0.5 ug/L Benzene Less than 0.5 ug/L Bromobenzene Less than 0.5 ug/L Bromochloromethane Less than 0.5 ug/L Bromodichloromethane Less than 0.5 ug/L Bromoform Less than 0.5 ug/L Sromomethane Less than 0.5 ug/L c-l,2-Dichloroethylene Less than 0.5 ucj/L c-l,3-Dichloropropene Less than 0.5 ug/L Carbon tetrachloride Less than 0.5 ug/L Chlorobenzene Less than 0.5 ug/L Chloroethane Less than 0.5 ug/L Chloroform Less than 0.5 ug/L Chloromethane Less than 0.5 ug/L Dibromochloromethane Less than 0.5 ug/L Dibromomethane Less than 0.5 ug/L Dichlorodifluoromethane Less than 0.5 ug/L Ethylbenzene Less than 0.5 ug/L Hexachlorobutadiene Less than 0.5 ug/L Isopropylbenzene Less than 0.5 ug/L m-Xylene Less than 0.5 ug/L Methyl t-butyl ether (MTBE) 'J .~ Less than 0.5 ug/L Analyzed By: Hen~Sou~erLabslnc. 24 Tobey Road Bloomfield, CT 06002 Send Results To: Mr. Jim Sommers A.R. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 Recluest # 880 10 water samples submitted by A. R. Lombardi Assoc., Inc./Fishers Island on 10/27/92 for VOC (EPA 5O2.2) Methylene chloride n-Butylbenzene n-Propylbenzene Naphtha~ne o-Xylene p-lsopropyltoluene p-Xylene sec-Butylbenzene Styrene t- 1,2- Dichloroethytene t-1,3-Dichloropropene tert-Butylbenzene Tetrachloroethylene Toluene Trichloroethylene Trichlorofluormethane Trimethybenzene Vinyl chloride Analyzed By: Hen~ Sou~erLabslnc. 24 Tobey Road Bloomfield, CT 06002 Sample Number 10 Trip Blank, Less than 0.5 ug/L Less than 0.5 ug/L Less than 0 5 ug/L Less than 0.5 ug/L Less than 0 5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 05 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0 5 ug/L Less than 0.5 ug/L Less than 0 5 ug/L Less than 0.5 ug/L Less than 0.5 Less than 0.5 ug/L water sample collected 10/26/92. 1,1,1,2-Tetrach]oroethane 1,1,1 -Trichloroet hane 1,1,2,2-Tetrac bio roethane 1,1,2-Trichloroethane 1,1,2-Trichlorotrifluoroethane 1 ~ -Dichloroethane 1,1 -Dichloroethene 1,1-Dichloropropene 1,2, 3-Trichlorobenzene 1,2,3-Trichloropropane 1,2,4-Trichloro ~enzene 1,2,4-Trimethylbenzene 1,2-Dibromo-3-chloropropane (DBCP) 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3, 5-Tr, methylbenzene 16 Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than (3 5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ugJL Send Results To: Mr. Jim Sommers AR. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 Recluest # 880 ] Re~.~port Date 11/05/92 10 water samples submitted by A. R. Lombardi Assoc., Inc./Fishers island on 10/27/92 for VOC 63. (EPA 502.2) 1,3-Dichlorobenzene Less than 0.5 ug/L 1,3-Dichloropropane Less than 0.5 ug/L 1,4-Dichlorobenzene Less than 0.5 ug/L 2,2-Dichloropropane Less than 0.5 ug/L 2-Chloroethylvinylether Less than 0.5 ug/L 2-Chlorotoluene Less than 0.5 ug/L 4-Chlorotoluene Less than 0.5 ug/L Benzene Less than 0.5 ug/L Bromobenzene Less than 0.5 ug/L Bromochloromethane Less than 0.5 ug/L Bromodichloromethane Less than 0.5 ug/L Bromoform Less than 0.5 ug/L Bromomethane Less than 0.5 ug,/L c-l,2-Dichloroethylene Less than 0.5 ug/L c-l,3-Dichloropropene Less than 0.5 ug/L Carbon tetrachloride Less than 0.5 ug/L Chlorobenzene Less than 0.5 ug/L Chloroethane Less than 0.5 ug/L Chloroform Less than 0.5 ug/L Chloromethane Less than 0.5 ug/L Dibromochloromethane Less than 0.5 ug/L Dibromomethane Less than 0.5 ug/L Dichlorodifluoromethane Less than 0.5 ug/L Ethylbenzene Less than 0.5 ug/L Hexachlorobutadiene Less than 0.5 ug/L Isopropylbenzene Less than 0.5 ug/L m-Xylene Less than 0.5 ug/L Methyl t-butyl ether (MTBE) Less than 0.5 ug/L Methylene chloride Less than 0.5 ug/L n-Butylbenzene Less than 0.5 ug/L n-Propylbenzene Less than 0.5 ug/L Naphthalene Less than 0.5 ug/L o-Xylene Less than 0.5 ug/L p-lsopropyltoluene Less than 0.5 ug/L p-Xylene Less than 0.5 ug/L sec-Butylbenzene Less than 0.5 ug/L Styrene Less than 0.5 ug/L t-l,2-Dichloroethylene Less than 0.5 ug/L t-l,3-Dichloropropene ] '7 Less than 0.5 ug/L Analyzed By: Hen~Sou~erLabslnc. 24 Tobey Road Bloomfield, CT 06002 Send Results To: Mr. Jim Sommers A.R. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 Analyzed By: Request # 880 ~ IRepor[ Date 11/05/92 10 water samples submitted by A. R. Lombardi Assoc., Inc./Fishers Island on 10/27/92 for VOC 63. (EPA 502.2) tert-Butylbenzene Tetrachloroethylene Toluene Trichloroethylene Trichlorofluormethane Trimethybenzene Vinyl chloride Less than 0.5 ug/L Less than 0.5 ugJL Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Hen~ Sou~erLabslnc: 24 Tobey Roae Bloomfield, CT 06002 I I I ! A. RICHARD LOMBARDI, P.E. Pcesident RICHARD J. LOMBARDI vice President THOMAS D. LEE HENRY SOUTHER LABORATORIES INC Newlands Sanitary Lab Diviaion 24 Tobey Road · Bloomfield, CT · 06002 ENVIRONMENTAL AND METALLURGICAL ANALYSIS Established 1898 203.242-6291 FAX 203.286-0634 m ! November 12, 1992 .=,, A.R. Lombardi Assoc., Inc. I 25 Terrace Drive Vernon, CT 06066 i A 'I-FN: Mr. Jim Somers Gentlemen: i The attached report covers the analysis of the samples submitted to this laboratory on October 27, 1992. Newlands Sanitary Laboratory Request No. 887, samples 1 through 6. ! m TDL/pb I Very buly yours, THE N~ANITARY/U...c,~.~.t o.~., /'-'~ ~ ~,~z~LABORATORY Thomas D. Lee Laboratory Director RECEIVED NOV 1 3 1992 X. I. LOMIARBI ASSOCIAES, I ! I I I I 1 I I I I I i 1 I I I i I Send Results To: Mr. Jim Sommers AR. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 Analyzed By: Hen~ Sou~erLabslnc. 24 Tobey Road Bloomfield, CT 06002 Request# 887 I IRep°rt Date ,11/12/92 I 6 water samples submitted by A. R. Lombardi Assoc,, Inc./Fisher Island on 10/27/92 for Pesticide &Herbicide. ARL Job~91-2040-1. Sample Number I B-l, water sample collected 10/26/92. 2,4,5-TP Sitvex 2,4-D Endrin Lindane Methoxychlor Toxaphene Sample Number 2 2,4,5-TP Silvex 2,4-D Endrin Lindane Methoxychlor Toxaphene Sample Number 3 2,4,5-TP Silvex 2,4-D Endrin Lindane Methoxychlor Toxaphene Sample Number 4 2,4,5-TP Silvex 2,4-D Endrin Lindane Methoxychlor Toxaphene Sample Number 5 B-2, water Less than 1 ug/L Less than 1 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.5 ug/L sample collected 10/26/92, Less than I ug/L Less than 1 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0,5 ug/L Bagley Reids, water sample collected 10/26/92. T-l, water Less than 1 ug/L Less than I ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.02 ucj/L Less than 0.5 ug/L sample collected 10/26/92, Less than 1 ug/L Less than I ug/L Less than 0.02 u<j/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.5 ug/L Middle Farm M-l, water sample collected 10/26/92. Send Results To: Mr. Jim Sommers A.R. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 Analyzed By: Hen~ Sou~erLabslnc. 24 Tobey Road Bloomfield, CT 06002 ReQuest# 887 I ~Re~Date 11/12/92 J 6 water samples submitted by A. R. Lombardi Assoc., Inc./Fisher Island on 10/27/92 for Pesticide &Herbicide. ARL Job~91-2040-1 2,4,5-TP Silvex 2,4-D Endrin Lindane Methoxychlor Toxaphene Sample Number 6 Less than 1 ug/L Less than 1 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.5 ug/L Middle Farm M-3, water sample collected 10/26/92. 2,4,5-TP Silvex 2,4-D Endrin Lindane Methoxychlor Toxaphene Less than I ug/L Less than 1 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.5 ug/L 2 I I I I I I I I I I I ! i I I I I I I APPENDIX C BORING LOGS I : PROJECT NAME CLARENCE WELTI ASSOC.. INC. CLIENTA.R.LONgARO] WATER SUPPLY STUDY P.O. BOX 397 GLASTONBUR¥ CONN 06033 I LOCATION ~ FISHERS ]SLANDol NE~ YORK Elevation I DATE 9/10 ' i 10 1 12-16-20 10.0'-11.5' I 17,0' I BOTTON O~ BORING 17,0' 20 10.0" (.010) SCREEN' BENTONITE SEAL 5,0~-3.0~ 30 7" DIA. ROADgAY BOX COVER I I CLARENCE WELTI ASSOC., INC. P.O BOX 397 GLASTONBURY CONN 06033 DRILLING PROCEDORES 1 t HOLLOW STEM AUC;E~ O~ameter ICLIENT A.R.LONBARDI /,. 25" SAMPLE BLOWSI6 DEPT,~ LEGEND: Co~ ~ STRATUM DESCRIPTION LIGHT/SR.FINE-HED.SAND,TR.SILT BOTTO~ OF BORING 21.5' 10.0' (.010) SCREEN 7.0' RISER 10 30 Mea Dense 4-B M/Sldi 30-50 Dense 8 15 StlU PROJECT NAME WATER SUPPLY STUDY LOCATION FISHERS ISLAND. NEW YORK HOLE NO HW'2 I Sud~ Elevauor, I 21.5' Sheel 1 et 1 I CLIENT PROJECT NAME CLARENCE WELTI ASSOC., INC. P.O. I~OX 397 A.R.LOHSARD! ~ATER SUPPLY STUDy GLASTONBURY. CONN 06033 LOCATION I FISHERS ISLAND. NEt~ YORK I 10 1 16-14-13 10,0'-11.5~ LIGHT/SR.F INE*CRS. SAND, SOHE SILT, LITTLE FINE-HED.GRAVEL,TR.CORSLE$ & I BOU~.DERS i 2 30-28-28 20.0~-21.5, 20 ~ CLARENCE WELTI ASSOC., INC. CLIENT PROJECT NAME A.R.LO~,BARDI gATER SUPPLY $TUOY P.O BOX 397 GLASTONBURY. CONN 06033 LOCATION  FISHERS ISLANO,, #El,/ YORK I I 2 IDRIVEN CASING D~emeter GROUND WATER OBSERVATIONS START DATE 9/8/ I LI~T/BR.CRS-FINE SAND,SOHE FINE-CR$. I 18.0" I 20 2 18-25-30 20.0'-21.5' ! 25 I 30 3 16-18-28 30.0'-31.5' FI#E-ORS.GRAVEL,TR.COBBLES & BOULDERS CLARENCE WELTI ASSOC., INC. P.O BOX 397 GLASTONDURY CONN 06033 DRrLLiNG PROCEDURES 1 1 HOLLOW STEM AUGER. 25" CLIENT LEGEND. Co~ A · 3. 4 . (S~tecl Gee o~ more) p ROdE C~T N~eJ~4 E WATER SUPPLY STUDY LO~TION FISHERS ISLAND, NEW YORK WATER OBSERVATIONS START ~5.0' LIGHT/BR.FINE-CRS.SANDoSOME SILT & FINE-CRS.GRAVEL,TR.CO~SLES & SOULDERS LIGHT/BR.CRS-MED.SAflDoSONE FINE-CRS. Ca~AVEL,TR.COBBLES,BOULDERS & SILT 53.0' 2" I~LL POINT a 48.0' 10.0' (.010) SCREEN 45,0' RISER 2.0~ STICKUP BENTONITE SEAL 31,0'-~.0' CONCRETE 1.0'-0.0' &"DIA, X 5' PROTECTIVE STEEL CASING WITH LOCKING ALUflINUH CAP REMARKS CLARENCE WELTI ASSOC., INC. CLIENT PROJECT AoR.LOHBARD! UATI~R SUPPLY STUDY P.O. BOX 397 GLASTON~URY. CONN 06033 LOCATION FISHERS [~, #E~ YORK GROUND START DATE I0 1 8-9-12 10.0~.11.5, 35 35.0' **TOPSOIL LEGEND: Co~ A CLARENCE WELTI ASSOC., INC. P O BOX 397 GLASTONBURY CONN 06033 DRILLING PROCEDURES 1 HOLLOW STEM AUGER LEGEND: CG~ A 4.25" ICLIENT A.R .LOI4BARDI STRATUM DESCRIPTION 2" WELL POINT @ 32.0' 10.0' (.010) SCREEN 12.0' RISER SAND 32.0'-20.0' BENTONITE SEAL 20.0' - 18.0' BAD, FILLED 18.0~-1.0~ CONCRETE 1.0'-0.0' ?" DIA. ROADWAY BOX COVER PROJECT NAME WATER ~OPPLY STUDY FISHERS ISLAND, NEW YORK CLIENT PROJECT NAME CLARENCE WELTI ASSOC.. INC. A.R.LOMSARDI ~ATER ~J~PLY STI~¥ P.O BOX 397 GLASTONBURY. CONh 0~O33 LOCATION FISHERS ISLAND, NEt4 yORK S~lace t DRIVEN CASING D,ameter GROUND WATER O~3SERVAT!ON$ ~----~OD~A~T~ET LI~T/BR.F I NE-NED.SAND, TR. SI LT 1 5-8-10 18,0l_ CLARENCE WELTI ASSOC., INC. P.O BOX 397 GLASTONBUR¥ CONN 06033 DRILLING PROCEDURE S I 4.25" 1',,- 18-Z1 10.0'-11.5' LEGEND: Co~ A PROJECT NAME WATER SUPPLy STUpY LOCATION FISHERS ISLAND, NEW YORK GROUND WATER OBSERVAT)ONS ISTART STRATUM DESCRIPTION LIGHT/BR.FINE-HED.SANDoTR.SILT WELL POINT ~ 17.0" 10.0' (.010) SCREEN Z.0 STICKUP SAND 17.0' - 5.0' CONCRETE 1.0'-0.0' 0-10 Loose 0-4 Soft 10.30 Med Dense 4 8 M/Shf/ 30-50 Dense 8 15 St~H 18.0' REMARKS I! CLIENT PROJECT NAME CLARENCE WELTI ASSOC.. INC. A.R.LOHSARD[ ~ATER SUPPLY STUDy P.O. BOX 3g? GLASTONBURY CONN 06033 LOCATION I I Ii D=Dr'~ C=Core0 t.',=:'Vas~,eo trace 0tol0O,o 0-10Loose 0.4 Sol1 II CLIENT PROJECT NAME CLARENCE WELTI ASSOC., INC. A.R.LO~BARDI WATER SUPPLY STUDY P.O. BOX 397 GLASTONBUFIY. (~ONN 06033 LOCATION FISHERS iSLAND, NEW YORK -I I CLIENT PROJECT NAME CLARENCE WELTI ASSOC., INC. A.R.LONSARDI I,/ATER SUPPLY STUOY PO. BOX ~97 i GLASTONBURY. CONN 06033 LOCATION FISHERS ISLAND, NEt~ YO~K 04qlLLING PROCEOURES ~ I . 2 3 4 . (S~,eCI o~e or mo~e) HOLE NO. ~o8 I ! II ! ! ! ! ! I CLARENCE WELTI ASSOC., INC. ~ O BOX 397 GLASTONBURY. CONN 06033 DRILLING PROCEDURES ~[ HOLLOW STEM AUGER D~amet~ DRIVEN CASING I~ameler LEGEND C,O~ A I~L OWS/6 DEPTH PROJECT NAME WATER SUPPLY STUDY FISHERS ISLAND, NEW YORK m STRATUM DESCRIPTION + ~EPTH GR.FINE SAND,LITTLE SILT & CLAY LAYERS 151.5' BOTTON OF BORING 151.5' 2" WELL POINT @ 150.0' 10.0' (.010) SCREEN; 142.0' RISER BENTONITE SEAL 137'-1351;BACKFILLED 135'-1' CO~ICRETE 1.0'-0.0'; 4" DIA. X 5' PROTECTIVE STEEL CASING WITH LOCKZNG ALUfllNUH CAP REMARKS I CLIENT PROJECT NAME CLARENCE WELTI ASSOC., INC. P.O BOX 397 A.R.LOHBARD! ~ATER SUPPLY STUOY GLASTONBURY. CONN 06033 LOCATION I FISHERS ISLAND, #E~ YORK I · 8.0' ! ! i 21.5' ! II ! ! CLARENCE WELTI ASSOC., INC. P O BOX 397 GLASTONBURY. CON~'~ 06033 ORILLING PROCE DLIRES I 34-38-69 10.0' - 1 ! .5' ~.0 -60 20.0'-21.0' 40-60 30.0'-31.0' LEGEND: Co~ A PROJECT NAME ~ATER SUPPLY STUDY LOCATION FISHERS ISLAND, NEW YO~K STRATUM DESCRIPTION REMARKS + DEPTH LZGHT/BE.FINE-NED.SAND,TR.SILT LIGNT/BR.F[NE SAND~LITTLE SILT, COBBLES & BOULDERS 7,0' LIGHT/BR.FINE-CRS.SAND,L]TTLE SILT, FINE-NED.GRAVEL~CO~BLES & BOUDLERS 18.0' 2" ~LL POINT g 30.0~ 10.0~ (.010) SCREEN 22.0' RZSER; 2.0' STICKUP SAND 30.0'-18.0~; BENTONITE SEAL 18.0'-16.0' BACKFILLED 16.0'-1.0'; CONCRETE 1.0'-0.0~ 7" DIA. ROADWAY BOX COVER Dr,lief CHRISTIANA 31.0' I CLIENT PROJECT NAME CLARENCE WELTI ASSOC., INC. A.R.LOHBARDI WATER ~UPPLY STUDY P.O BOX 397 GLASTONBURY. CONN 06033 LOCATION I I 10 1 32-25-30 10,0'-11.5' I ~3o ! ! CLIENT PROJECT NAME CLARENCE WELTI ASSOC., INC. FISHERS ISLAND WATEr t~ORKS P O BOX 397 GLASTONBURY CONN 06033 LOCATION FISHERS ISLAND, NEI~ YORK I PROJECT NAME CLARENCE WEL'TI ASSOC., INC. P O I~OX 397 GLASTONBURY CONN 060~3 DRILLING I>ROCEDURES 1 HOLLOW STEM AUGER Dlarr, eler 2 DRrVEN CASING O,8mele~ LEGEND Co~ A ICLIENT FISHERS ISLAND WAVER ~KS &ty~e LOCATION FISHERS ISLAND, NEd YO~K GRO,,NO W&,ER O.SE.V&TIO. S J%~,~, SR.FINE-CRS.SAND~LITTLE SILT, FINE-MED.GRAVEL~C0~BLES & BOULDERS BOTTO~ OF BORING 70.0' REMARKS 70.0' **TOPSOIL I I I I I I I I I I I I I I I I I I I APPENDIX D SAMPLE RESULTS - GROUNDWATER HENRY SOUTHER LABORATORIES! INC. Newl~nd~ Sanitary L~b Oivl~lo~ I I I A. R r.:,~,~RO LOMD~kRDI. P.E. RIP,lARD J. LOMBAROI THOMAS O. LEE 24 Tobey Road · Bloomfield, CT * 06002 ENVIRONMENTAL AND METALLURGICAL ANALYSIS Estalflished 1898 203-242-6291 FAX 203-286-0634 October 19, 1992 I A. R. Lombardi Assoc., Inc. 25 Terrace Drive Vernon, Conn. 06066 m Attn: Mr. Mike Horne m Gentlemen: m ARL Job #91-2040-1 Fishers Island The attached report covers the analysis of samples submitted to this laboratory on October 1, lg92. Newlands Sanitary Laboratory sample numbers 46K2 thru 55K2. m m Very truly yours, m ! m TDL/cas THE NEWLANDS SANITARY LABORATORY Thomas D. Lee Laboratory Director m m m RECEIVED OCT Iq 1992 I. L~IIUII)I ASil)O~l~, IRC- m m m I I I I I I I I I I I I I I I I I I I A. RICHARD LC)MBARDI, P.E. President RICHARD J. LOMBARDI Vice Presidenl THOMAS D. LEE HENRY SOUTHER LABORATORIES INC Newlands Sanitary Lab Division 24 Tobey Road * Bloomfield, CT · 06002 ENVIRONMENTAL AND METALLURGICAL ANALYSIS Established 1898 203-242-6291 FAX 203-286-0634 October6,1992 A. R. Lombardi Assoc., Inc. 25 Terrace Drive Vernon, CT 060~6 ATTN: Mr. Mike Horn Gentlemen: The attached report covers the analysis of the samples submitted to this laboratory on October 1, 1992. Newlands Sanitary Laboratory Request No. 838, samples I through 10. TD~pb Very truly yours, THE NEW~NI~ SANITARY LABORATORY Thomas D. Lee Laboratory Director RECEIVED OCT 2t 1992 it. LOMB~BI ASSQCIAT~S, I1~ Send Results To: Analyzed By: Henry Souther Labs Inc. A.R. Lombardi Associates, Inc. 24 Tobey Road 25 Terrace Dr. Bloomfield, CT Vernon, CT 06066 06002 I IRaport Date 10/06/92 I 10 water eamplee submitted by A.R. Lombardi Associates, Inco/ Fishers Island on 10/01/92 for VOC 63. (EPA 502.2) Sample Number I MW-l, water sample collected 09/30/92. 1,1,1,2-Tatrachloroethane Less than 0.5 ug/L 1,1,1-Trichloroethane Less than 0.5 ug/L 1,1,2,2-Tetrachl6roethane Less than 0.5 ug/L 1,1,2-Trichloroethane Less than 0.5 ug/L 1,1,2-Trichlorotrifluoroethane Less than 0.5 ug/L l,l-Dichloroethene Less than 0.5 ug/L 1,1-Dichloroethene Less than 0.5 ug/L 1,1-Dichloropropene Less than 0.5 ug/L 1,2,3-Trichlorobenzene Less than 0.5 ug/L 1,2,3-Trichloropropane Less than 0.5 ug/L 1 Less than 0.5 ,2,4-mrichlorobenzene 1,2,4-Trimethylbenzene Less than 0.5 ug/L 1,2-Dibromo-3-chloropropane (DBCP) Less than 0.02 ug/L 1,2-Dibromoethane (EDB) Less than 0.02 ug/L 1,2-Dichlorobenzene Less than 0.5 ug/L 1,2-Dichloroethane Less than 0.5 ug/L 1,2-Dichloropropane Less than 0.5 ug/L 1,3,5-Trimethylbenzene Less than 0.5 ug/L 1,3-Dichlorobenzene Less than 0.5 ug/L 1,3-Dichloropropane Less than 0.5 ug/L 1,4-Dichlorobenzene Less than 0.5 ug/L 2,2-Dichloropropane Less than 0.5 ug/L 2-Chloroethylvinylether Less than 0.5 ug/L 2-Chlorotoluene Less than 0.5 ug/L 4-Chiorotoluene Less than 0.5 ug/L Benzene Less than 0.5 ug/L Bromobenzene Less than 0.5 ug/L Bromochloromethane Less than 0.5 ug/L Bromodichloromethene Less than 0.5 ug/L Bromoform Less than 0.5 ug/l_ Bromomethane Less than 0.5 ug/L c-l,2-Dichloroethylene Less than 0.5 ug/L c-l,3-Dichloropropene Less than 0.5 ug/t. Carbon tetrachloride Less than 0.5 ug/L Chlorobenzene Less than 0.5 ug/L Chloroethane ]. Less than 0.5 ug/L Send Results to: A.R. Lombardi Associates, Inc. 25 Terrace Dr. Vernon, CT 06066 Analyzed By: IReciuest # 8-38 I IR; ort Date 10/05/92 I 10 water samples submitled by A.R. Lombardi Associates, Inc. / Fishers Island on (EPA 502.2) Henry Souther Labs Inc. 24 Tobey Road Bloomfield, CT 06002 10/01/92 for VOC 63 Sample Chloroform Less than 0.5 ugJL Chloromethane Less than 0.5 ug/L Dibromochloromethane Less than 0.5 ug/L Dibromomethane Less than 0.5 ug/L Dichlorodifluoromethane Less then 0.5 ug/L Ethylbenzene Less than 0.5 ug/L Hexachlorobutadiene Less than 0.5 ug/L Isopropylbenzene Less than 0.5 ug/L m-Xylene Less than 0.5 ug/L Methyl-t-butyl ether Less than 0.5 ug/L Methylene chloride Less then 0.5 ug/L n-Butylbenzene Less than 0.5 ug/L n-Propylbenzene Less than 0.5 ug/L Naphthalene Less than 0.5 ug/L o-Xylene Less than 0.5 ug/L D-fsopropyltoluene Less than 0.5 ug/L p-Xylene Less than 0.5 ug/L sec-Butylbenzene Less than 0.5 ug/L Styrene Less than 0.5 ug/L t-l,2-Dichloroethylene Less than 0.5 ug/L t-l,3-Dichloropropene Less than 0.5 ug/L tert-Butylbenzene Less than 0.5 ug/L Tetrachloroethylene Less than 0.5 ug/L Toluene Less than 0.5 ug/L Trichloroethylene Less than 0.5 ug/L Trichlorofluormethane Less than 0.5 ug/L Trimethybenzene Less than 0.5 ug/L Vinyl chloride Less then 0.5 ug/L Number 2 MW-2, water sample collected 09/30/92. 1,1,1,2-Tetrachloroethene 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1,2-Trichlorotrifluoroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,1-Dichloropropene Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L I I Send Results To: A.R. Lombardi Associates, Inc. 25 Terrace Dr. Vernon, CT 06066 Analyzed By: Henry Souther Labs Inc. 24 Tobey Road Bloomfield, CT 06002 I I I I I I I I I I I I I I I I IRacluest# 636 I ~92 J 10 water samples submitted by A.R. Lombardi Associates, Inc, / Fishers Island on (EPA 502.2) 10/01/92 for VOC 63. 1,2,3-Trichlorobenzene 1,2,3-Trichloropropane 1,2,4-Trichlorobenzene 1,2,4-Trimethylbenzene 1,2-Dibromo-3-chloropropane (DBCP) 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3,5-Trimethylbenzene 1,3-Dichlorobenzene 1,3-Dichloropropane 1,4-Dichlorobenzene 2,2-Dichloropropane 2-Chloroethylvinylsther 2-Chlorotoluene 4-Chlorotoluene Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane c-1,2-Dichloroethylene c-1,3-Dichloropropene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethene Dibromochloromethane Dibromomethane Dichlorodifluoromethane Ethylbenzene Hexachlorobutadiene Isopropylbenzene m-Xylene Methyl-t-butyl ether Methylene chloride 3 Less than 0.5 ug/L Less than 0.5 ug/L. Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.02 ug/L Lass than 0.02 ug/L Less than 0.5 ug/L Less than 0.5 ug/L. Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less then 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Send Results To: A.R. Lombardi Associates, Inc. 25 Terrace Dr. Vernon, CT 06066 Analyzed By: Henry Souther Labs Inc. 24 Tobey Road Bloomfield, CT 06002 ~Request # 838 J ~92 J 10 water samples submitled by A.R. Lombardi Associates, Inc. / Fishers Island on (EPA 502.2) 10/01/92 for VOC 63. n-Butylbenzene Less than n-Propylbenzene Less than Naphthalene Less than o-Xylene Less than p-lsopropyltoluene Less than p-Xylene Less than sec-Butylbenzene Less than Styrer,~ Less than t-1,2-Dichloroethytene Less than t-l,3-Dichloropropene Less than tert-Butylbenzene Less than Tetrachloroethylene Less than Toluene Less than Trichloroethylene Less than Trichlorofluorrnethane Less than Trimethybenzene Less than Vinyl chloride Less than Sample Number 3 MW-4, water sample 0.5 ug/L 0.5 ug/L 0.5 ug/L 0.5 ug/L 0.5 ug/L 0.5 ug/L 0.5 ug/L 0.5 ug/L 0.5 ug/L 0.5 ug/L 0.5 ug/L 0.5 ug/L 0.5 ug/L 0.5 ug/L 0.5 ug,'L 0.5 ug/L 0.5 ug/L collected 09/30/92, 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroetha ne 1,1,2-Trichloroethane 1,1,2-TricMorotrifluoroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,1-Dichloropropene 1,2,3-Trichlorobe nzene 1,2,3-Trichloropropane 1,2,4-Trichlorobenzene 1,2,4-Trimethylbenzene 1,2-Dibromo-3-chloropropane (DBCP) 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichtoroethane 1,2-Dichloropropane 1,3,5-Trimethylbenzene 1,3-Dichlorobenzene Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less then 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L 4 Less Ihan 0.5 ug/L I I Send Results To: A.R. Lombardi Associates, Inc. 25 Terrace Dr. Vernon, CT 06066 Analyzed By: Henry Soulher Labs Inc. 24 Tobey Road Bloomfield, CT 06002 I I I ! I I I I I I I I I I I I RL~.q.uest # 838 J IRepo, Date 10/06/92 I 10 water samples submitted by A.R. Lombardi Associates, Inc. / Fishers Island on (EPA 502.2) 10/01/92 for VOC 63. 1,3-Dichloropropane 1,4-Dichlorobenzene 2,2-Dichloropropane 2-Chloroethylvinylether 2-Chlorotoluene 4-Chlorotoluene Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane c-1,2-Dichloroethylene c-l,3-Dichloropropene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane Dibromomethane Dichlorodifluoromethane Ethylbenzene Hexachlorobutadiene Isopropylbenzene m-Xylene Methyl-t-butyl ether Methylene chloride n-Butylbenzene n-Propylbenzene Naphthalene o-Xylene p-Isopropylloluene p-Xylene sec-Butylbenzene Styrene t-1,2-Dichloroethylene t-l,3-Dichloropropene tert-Butylbenzene 5 Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/l_ Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less then 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/l_ Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less then 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Send Results To: A.R. Lombardi Associates, Inc. 25 Terrace Dr. Vernon, CT 06066 Analyzed By: Henry Souther Labs Inc. 24 Tobey Road Bloomfield, CT 06002 IRequsst # e3S J IReport Date 10/06/92 I 10 water samples submitted by A.R. Lombardi Associates, Inc. / Fishers Island on 10/01/92 for VOC 63. (EPA 502.2) Tetrachloroethylene Toluene Trichloroethylene Trichlorofluormethane Trimelhybenzene Vinyl chloride Sample Number 4 Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L MW-5, water sample collected 09/30/92. 1,1,1,2-Tetrachloroethene 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1,2-Trichlorotrifluoroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,1-Dichloropropene 1,2,3-Trichlorobenzene 1,2,3-Trichloropropane 1,2,4-Trichlorobenzene 1,2,4-Trimethylbenzene 1,2-Dibromo-3-chloropropane (DBCP) 1,2-Dibromoethane (EOB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3,5-Trimethylbenzene 1,3-Dichlorobenzene 1,3-Dichloropropane 1,4-Dichlorobenzene 2,2-Dichloropropane 2-Chloroethylvinylet her 2-Chlorotoluene 4-Chlorotoluene Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Lees than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug,'L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L I I I I I I I I I I I I I I I I I I I Send Results To: Analyzed By: A.R. Lombardi Associates, Inc. 25 Terrace Dr. Vernon, CT 06066 ~6~6 ] ~/o~/92 I 10 water samples submitled by A.R. Lombardi Associates, Inc./ Fishers Island (EPA 502.2) Henry Souther Labs Inc. 24 Tobey Road Bloomfield, CT 06002 on 10/01/92 for VOC 63. Bromomethane Less than 0.5 ug/L c-1,2-DJchloroethylene Less than 0.5 ug/L c-l,3-Dichloropropene Less than 0.5 ug/L Carbon tetrachloride Less than 0.5 ug/L Chlorobenzene Less than 0.5 ug/L Chloroethane Less than 0.5 ug/L Chloroform Less than 0.5 ug/L Chloromethane Less than 0.5 ug/L Dibromochloromethane Less than 0.5 ug/L Dibromomethane Less than 0.5 ug/L Dichlorodifluoromethane Less than 0.5 ug/L Ethylbenzene Less than 0.5 ug/L Hexachlorobutadiene Less than 0.5 ug/L Isopropylbenzene Less than 0.5 ug/L m-Xylene Less than 0.5 ug/L Methyl-t-butyl ether Less than 0.5 ug/L Methylene chloride Less than 0.5 ug/L n-Butylbenzene Less than 0.5 ug/L n-Propylbenzene Less than 0.5 ug/L Naphthalene Less than 0.5 ug/L o-Xylene Less than 0.5 ug/L p-lsopropyltoluene Less than 0.5 ug/L p-Xylene Less than 0.5 ug/L sec-Butylbenzene Less than 0.5 ug/L Styrene Less than 0.5 ug/L t-l,2-Dichloroethylene Less than 0.5 ug/L t-l,3-Dichloropropene Less than 0.5 ug/L tert-Butylbenzene Less than 0.5 ug/t. Tetrachloroethylene Less than 0.5 ug/L Toluene Less than 0.5 ug/L Trichloroethylene Less than 0.5 ug/L Trichlorofluormethane Less than 0.5 ug/L Trimethybenzene Less than 0.5 ug/L Vinyl chloride Less than 0.5 ug/L Sample Number 5 MW-6, water sample collected Less than 0.5 ug/L 7 Less than 0.5 ug/L 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 09/30/92. Send Results To: A.R. Lombardi Associates, Inc. 25 Terrace Dr. Vernon, CT 06066 Analyzed By: Hen~ SoutherLabslnc. 24 Tobey Road Bloomfield, CT 06002 IRecluest # 838 I I...Repo, Oate 10/06/92 I 10 water samples submitted by A.R. Lombardi Associates, Inc. / Fishers Island on (EPA 502.2) 10/01/92 for VOC 63. 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1,2-Trichlorotrifiuoroethane 1 ,l~Dichloroethane 1,1-Dichloroethene 1,1-Dichloropropene 1,2,3-Trichlorobenzene 1,2,3-Trichloropropane 1,2,4-Trichlorobe nzene 1,2,4-Trimethylbenzene 1,2-Dibromo-3-chloropropane (DBCP) 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-D[chloroethane 1,2-Dichloropropane 1,3,5-Trimethylbenzene 1,3-Dichlorobenzene 1,3-Dichloropropane 1,4~Dichlorobenzene 2,2-Dichloropropane 2-Chloroethylvinylet her 2-Chlorotoluene 4-Chlorotoluene Benzene Bmmobenzene Bromochloromethane Bromodichloromethane Bromotorm Bro_momethane c-1,2-Dichloroethylene c-1,3-Dichloropropene Carbon tetrachloride Chlombenzene Chloroethane Chloroform Chloromethane Dibromochloromethane Dibromomethane Dichlorodifluoromethane Less than 0.5 ,,g/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Lees than 0.5 ug/L Less than 0.5 ug/l_ Lees than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/l_ Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/!._ Less than 0.5 ug/L I I I I I I I I I I I I I I I I I I Send Results To: Analyzed By: Henry Souther Labs Inc, A.R. Lombardi Associates, Inc. 25 Terrace Dr. Vernon, CT 06066 ~838 J IRePortDate 10/06/92 J 10 water samples submitted by A.R. Lombardi Associates, Inc. I Fishers Island (EPA 502.2) 24 Tobey Road Bloomfield, CT 06002 on 10/01/92 for VOC 63. Ethylbenzene Less than 0.5 ug/L Hexachlorobutadiene Less than 0.5 ug/L Isopropylbenzene Less than 0.5 ug/L m-Xylene Less than 0.5 ug/L Methyl-t-butyl ether Less than 0.5 ug/L Methylene chloride Less than 0.5 ug/L n-Butylbenzene Less than 0.5 ug/L n~Propylbenzene Less than 0.5 ug/L Naphthalene Less than 0.5 ug/L o-Xylene Less than 0.5 ug/L I>-Isopropyltoluene Less than 0.5 ug/L p~Xylene Less than 0.5 ug/L sec-Butylbenzene Less than 0.5 ug/L Styrene Less than 0.5 ug/L t-l,2-Dichloroethylene Less than 0.5 ug/L t-l,3-Dichloropropene Less than 0.5 ug/L tert-Butylbenzene Less than 0.5 ug/L Tetrschloroethylene Less than 0.5 ug/L Toluene Less than 0.5 ug/L Trichloroethylene Less than 0.5 ug/L Trichlorofluormethane Less than 0.5 ug/L Trimethybenzene ' Less than 0.5 ug/L Vinyl chloride Less than 0.5 ug/L Sample Number 6 MW-7, water sample collected 09130/92. 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1,2-Trichlorotrifluoroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,1-Dichloropropene 1,2,3-Trichlorobenzane 1,2,3-Trichloropropsne 1,2,4-Trichlorobenzene 1,2,4-Trimethylbenzene 1,2-Dibromo-3-chloropropane (DBCP) Less than 0.5 ug/l_ Less than 0.5 ug/L Less than 0.5 ug/!.. Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.02 ug/L Send Resu~s To: A.R. Lombardi Associates, Inc. 25 Terrace Dr. Vernon, CT 06066 Analyzed By: Hen~ Sou~erLabslnc 24 Tobey Road Bloomfield, CT 06002 LRecluest#838 I R[. portDate t0/06/92 J 10 water samples submitted by A.R. Lombardi Associates, Inc. / Fishers Island on 10/01/92 lot VOC 63. (EPA 502.2) 1,2-Dibromoethane (EDB) Less than 0.02 ug/L 1,2-Dichlorobenzene Less than 0.5 ug/L 1,2-Dichloroethane Less than 0.5 ug/L 1,2-Dichloropropane Less than 0.5 ug/L 1,3,5-Trimethylbenzene Less than 0.5 ug/L 1,3-Dichlorobenzene Less than 0.5 ug/L 1,3-Dichloropropane Less than 0.5 ug/L 1,4-Dichlorobenzene Less than 0.5 ug// 2,2-Dichloropropane Less than 0.5 ug/L 2-Chloroethylvinylether Less than 0.5 ug/L 2-Chlorotoluene Less than 0.5 ug/L 4-Chlorotoluene Less than 0.5 ug/L Benzene Less than 0.5 ug/L Bromobenzene Less than 0,5 ug/L Bromochloromethane Less than 0.5 ug/L Bromodichloromethane Less than 0.5 ug/L Bromoform Less than 0.5 ug/L Bromomethane Less than 0,5 ug/L c-l,2-Dichloroethylene Less than 0.5 ug/L c-l,3-Dichloropropene Less than 0.5 ug/L Carbon tetrachloride Less than 0.5 ag/L Chlorobenzene Less than 0,5 ug/L Chloroethane Less than 0.5 ug/L Chloroform Less than 0.5 ug/L Chloromethane Less than 0.5 ug/L Dibromochloromethane Less than 0.5 ug/L Dibromomethane Less than 0.5 ug/L Dichlorodifluoromethane Less than 0.5 ug/L Ethylbenzene Less than 0,5 ug/L Hexachlorobutadiene Less than 0.5 ug/L Isopropylbenzene Less than 0.5 ug/L m-Xylene Less than 0.5 ug/L Methyl-t-butyl ether Less than 0.5 ug/L Methylene chloride Less than 0.5 ug/L n-Butylbenzene Less than 0.5 ug/L n-Propylbenzene Less than 0.5 ug/L Naphthalene Less than 0.5 ug/L o-Xylene Less than 0.5 ug/L p-lsopropyltoluene 1~ 0 Less than 0.5 ug/L ! ! Send Results To: A.R. Lombardi Associates, Inc. 25 Terrace Dr. Vernon, CT 06066 Analyzed By: Henry Souther Labs Inc. 24 Tobey Road Bloomfield, CT 06002 · IR .usst# 836 I 0/05/92 J ! 10 water samples submitted by A.R. Lombardi Associates, Inc. / Fishers Island (EPA 502.2) on 10/01/92 for VOC 63. p-Xylene Less than 0.5 ug/L sec-Butylbenzene Less than 0.5 ug/L Styrene Less than 0.5 ug/L t-l,2-Dichloroethylene Less than 0.5 ug/L t-l,3-Dichloropropene Less than 0.5 ug/L tert-Butylbenzene Less than 0.5 ug/L Tetrachloroethylene Less than 0.5 ug/L Toluene Less than 0.5 ug/L Trichloroethylene Less than 0.5 ug/L Trichlorofluormethane Less than 0.5 ug/L Trimethybenzene Less than 0.5 ug/L Vinyl chloride Less than 0.5 ug/L Sample Number 7 MW-10, water sample collected 09/30/92. 1,1,1,2-Tetrachloroethane Less than 0.5 ug/L 1,1,1-Trichloroethane Less than 0.5 ug/L 1,1,2,2-Tetrachloroethane Less than 0.5 ug/L 1,1,2-Trichloroethane Less than 0.5 ug/L 1,1,2-Trichlorotrifluoroethane Less than 0.5 ug/L 1,1-Dichloroethane Less than 0.5 ug/L 1,1-Dichloroethene Less than 0.5 ug/L 1,1-Dichloropropene Less than 0.5 ug/L 1,2,3-Trichlorobenzene Less than 0.5 ug/L 1,2,3-Trichloropropane Less than 0.5 ug/L 1,2,4-Trichlorobenzene Less than 0.5 ug/L 1,2,4-Trimethylbenzene Less than 0.5 ug/L 1,2-Dibromo-3-chloropropane (DBCP) Less than 0.02 ug/L 1,2-Dibromoethane (EDB) Less than 0.02 ug/L 1,2-Dichlorobenzene Less than 0.5 ug/L 1,2-Dichloroethane Less than 0.5 ug/L 1,2-Dichloropropane Less than 0.5 ug/L 1,3,5-Trimethylbenzene Less than 0.5 ug/L 1,3-Dichlorobenzene Less than 0.5 ug/!.. 1,3-Dichloropropane Less than 0.5 ug/L 1,4-Dichlorobenzene Less than 0.5 ug/L 2,2-Dichloropropane Less than 0.5 ug/L 2-Chloroethylvinylether Less than 0.5 ug/L 2-Chlorotoluene ] ]- Less than 0.5 ug/L Send Results To: A.R. Lombardi Associates, Inc. 25 Terrace Dr. Vernon, CT 06066 Analyzed By: Hen~ Sou~erLabslnc. 24 Tobey Road Bloomfield, CT 06002 ~Request#838 J Re[~..~EortDate 10/06/92 J 10 water samples submitted by A.R. Lombardi Associates, Inc. / Fishers Island (EPA 502.2) on 10/01/92 for VOC 63. 4-Chlorotoluene Less than 0.5 ug/L Benzene Less than 0.5 ug/L Bmmobenzene Less than 0.5 ug/L Bromochloromethane Less than 0.5 ug/L Bromodichloromethane Less than 0.5 ug/L Bromoform Less than 0.5 ug/L Bromomethane Less than 0.5 ug/L c-l,2-Dichloroethylene Less than 0.5 ug/L c-l,3-Dichloropropene Less than 0.5 ug/L Carbon tetrachloride Less than 0.5 ug/L Chlorobenzene Less than 0.5 ug/L Chlorosthane Less than 0.5 ug/L Chloroform Less than 0.5 ug/L Chloromethane Less than 0.5 ug/L Dibromoch[oromethane Less than 0.5 ug/L Dibromomethane Less than 0.5 ug/L Dichlorodifluoromethane Less than 0.6 ug/L Ethylbenzene Less than 0.5 ug/L Hexachlorobutadiene Less than 0.5 ug/L Isopropylbenzene Less than 0.5 ug/L m-Xylene Less than 0.5 ug/L Methyl-t-butyl ether Less than 0.5 ug/L Methylene chloride Less than 0.5 ug/L n-Butylbenzene Less than 0.5 ug/L n-Propylbenzene Less than 0.5 ug/L Naphthalene Less than 0.5 ug/L o-Xylene Less than 0.5 ug/L p-lsopropyltoluene Less than 0.5 ug/L p-Xylene Less than 0.5. ug/L sec-Butylbenzene Less than 0.5 ug/L Styrene Less than 0.5 ug/L t-l,2-Dichloroethylene Less than 0.5 ug/L t-l,3-Dichloropropene Less than 0.5 ug/L tert-Butylbenzene Less than 0.5 ug/L Tetrachloroethylene Less than 0.5 ug/L Toluene Less than 0.5 ug/L Trichloroethylene Less than 0.5 ug/L Trichlorofluormethane Less than 0.5 ug/L Trimethybenzene ] ') Less than 0.5 ug/L I I Send Results To: A.R. Lombardi Associates, Inc. 25 Terrace Dr. Vernon, CT 06066 Analyzed By: Henry Souther Labs Inc. 24 Tobey Road Bloomfield, CT 06002 I I IRequest# 838 I ~e 10/06/92 10 water samples submitted by A.R. Lombardi Associates, Inc. / Fishers Island on 10/01/92 for VOC 63. (EPA 502.2) Vinyl chloride Less than 0.5 ug/L i Sample Number 8 MW-l l, water sample collected 09/30/92. I I I I I I I I I I I I I 1,1,1,2-Tetrachloroethane Less than 0.5 ug/[. 1,1,1-Trichloroethane Less than 0.5 ug/L 1,1,2,2-Tetrachloroethane Less than 0.5 ug/L 1,1,2-Trichloroethane Less than 0.5 ug/L l,l,2-Trichlorotriflueroethane Less than 0.5 ug/L 1,1-Dichloroethane Less than 0.5 ug/L l,l-Dichloroethene Less than 0.5 ug/L l,l-Dichloropropene Less than 0.5 ug/L 1,2,3-Trichlorobenzene Less than 0.5 ug/L 1,2,3-Trichloropropane Less than 0.5 ug/L 1,2,4-Trichlorobenzene Less than 0.5 ug/L 1,2,4-Trimethylbenzene Less than 0.5 ug/L 1,2-Dibromo-3-chloropropane (DBCP) · Less than 0.02 ug/L 1,2-Dibromoethane (EDB) Less than 0.02 ug/L 1,2-Dichlorobenzene Less than 0.5 ug/L 1,2-Dichloroethsne Less than 0.5 ug/L 1,2-Dichloropropane Less than 0.5 ug/L 1,3,5-Trimethylbenzene Less than 0.5 ug/L 1,3-Dichlorobenzene Less than 0.5 ug/L 1,3-Dichloropropane Less than 0.5 ug/L 1,4-Dichlorobenzene Less than 0.5 ug/L 2,2-Dichloropropane Less than 0.5 ug/L 2-Chloroethylvinylether Less than 0.5 ug/L 2-Chlorotoluene Less than 0.5 ug/L 4-Chlorotoluene Less than 0.5 ug/L Benzene Less than 0.5 ug/L Bromobenzene Less than 0.5 ug/L Bromochloromethana Less than 0.5 ug/L Bromodichloromethane Less than 0.5 ug/L Bromoform Less than 0.5 ug/L Bromomethane Less than 0.5 ug/L c-l,2-Dichloroethylene Less than 0.5 ug/l_ c-l,3-Dichloropropene Less than 0.5 ug/L Carbon tetrachloride Less than 0.5 ug/L Chlorobenzene ]. 3 Less than 0.5 ug/L Send Results To: A.R. Lombardi Associates, Inc. 25 Terrace Dr. Vernon, CT 06066 Analyzed By: Henry SoutherLabslnc. 24 Tobey Road Bloomfield, CT 06002 ~Request # 838 I ~ 10 water samples submitted by A.R. Lombardi Associates, Inc. / Fishers Island on 10/01/92 for VOC 63. (EPA 502.2) Chloroethane Less than 0.5 ug/L Chloroform Less than 0.5 ug/L Chloromethane Less than 0.5 ug/L Dibromochloromethane Less than 0.5 ug/L Dibromomethane Less Ihan 0.5 ug/L Dichlorodifiuoromethane Less than 0.5 ug/L Ethylbenzene Less than 0.5 ug/L Hexachlorobutadiene Less than 0.5 ug/L Isopropylbenzene Less than 0.5 ug/L m-Xylene Less than 0.5 ug/L Methyl-t-butyl ether Less than 0.5 ug/L Methylene chloride Less than 0.5 ug/L n-Butylbenzene Less than 0.5 ug/L n-Propylbenzene Less than 0.5 ug/L Naphthalene Less than 0.5 ug/L o-Xylene Less than 0.5 ug/L p-lsopropyltoluene Less than 0.5 ug/L p-Xylene Less than 0.5 ug/L sec-Butylbenzene Less than 0,5 ug/L Styrene Less than 0.5 ug/L t-l,2-Dichloroethylene Less than 0.5 ug/L t-l,3-Dichloropropene Less than 0.5 ug/L tert-Butylbenzene Less than 0.5 ug/L Tetrachloroethylene Less than 0.5 ug/L Toluene Less than 0.5 ug/L Trichloroethylene Less than 0.5 ug/L Trichlorofluormethane Less than 0.5 ug/L Trimethybenzene Less than 0.5 ug/L Vinyl chloride Less than 0.5 ug/L Sample Number 9 Field Blank, water sample collected 09/30/92. 1,1,1,2-Tetrachloroetha ne 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1,2-Trichlorotrifluoroethane 1,1-Dichloroethane 1,1 -Dichloroethene Less than 0.5 ug/L Less than 0.5 ug/L Less than 0,5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L I I Send Results To: A.R. Lombardi Associates, Inc. 25 Terrace Dr. Vernon, CT 06066 Analyzed By: Henry Souther Labs Inc. 24 Tobey Road Bloomfield, CT 06002 I I I I I I I I I I I I I I I I ~Requast # 636 J ~ 10 water samples submitted by A.R. Lombardi Associates, Inc. / Fishers Island on 10/01/92 for VOC 63. (EPA 502.2) 1,1-Dichloropropene 1,2,3-Trichlorobenzene 1,2,3-Trichloropropane 1,2,4-Trichlorobenzene 1,2,4-Trimethylbenzene 1,2- Dibromo-3-chloropropane (DBCP) 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3,5-Trimethylbenzene 1,3-Dichlorobenzene 1,3-Dichloropropane 1,4-Dichlorobenzene 2,2-Dichloropropane 2-Chloroethylvinylether 2-Chlorotoluene 4-Chlorotoluene Benzene Bromobenzene Bromochloromethane Bromodichloromethene Bromoform Bromomethane c-1,2-Dichloroethylene c-1,3-Dichloropropene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane Dibromomethane Dichlorodifluoromethane Ethylbenzene Hexachlorobutadiene Isopropylbenzene m-Xylene Methyl-t-butyl ether Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/I. Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Lass than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/I. Less than 0.5 ug/I. Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/I. Less than 0.5 ug/L Less than 0.5 ug/[. Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/l_ Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/l_ Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L. Less than 0.5 ug/L Send Results To: A.R. Lombardi Associates, Inc. 25 Terrace Dr. Vernon, CT 06066 Analyzed By: Henry Souther Labs Inc. 24 Tobey Road Bloomfield, CT 06002 ~ ] IReportDate t0/06/92 ] 10 water samples submitted by A.R. Lombardi Associates, Inc. / Fishers Island on 10/01/92 for VOC 63. (EPA 502.2) Methylene chloride Less than 0.5 ug/L n-Butylbenzene Less than 0.5 ug/L n-Prop¥1benzene Less than 0.5 ucj/L Naphthalene Less than 0.5 ug/L o-Xylene Less than 0.5 ug/L p-lsopropyltoluene Less than 0.5 ug/L p-Xylene Less than 0.5 ug/L sec-Sutylbenzene Less than 0.5 ug/L Styrene Less than 0.5 ug/L t-l,2-Dichloroethyiene Less than 0.5 ug/L t*l,3-Dichloropropene Less than 0.5 ug/L tert-Butylbenzene Less than 0.5 ug/L Tetrachloroethylene Less than 0.5 ug/L Toluene Less than 0.5 ug/L Trichloroethylene Less than 0.5 ug/L Trichlorofluormethane Less than 0.5 ug/L Trimethybenzene Less than 0.5 ug/L Vinyl chloride Less than 0.5 ug/L Sample Number I 0 Trip Blank, water sample collected 09/30/92. 1,1,1,2oTetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroet bane 1,1,2-Trichloroethane 1,1,2-Trichlorotrifluoroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,1-Dichioropropene 1,2,3-Trichlorobenzene 1,2,3-Trichloropropane 1,2,4-Trichlorobenzene 1,2,4-Trimethylbenzene 1,2-Dibromo-3-chloropropane (DBCP) 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,3,5-Trimethylbenzene Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L I I I Send Results To: A.R. Lombardi Associates, Inc. 25 Terrace Dr. Vernon, CT 06066 Analyzed By: IRequest # e3e I R[.~port Date 10/06/92 J 10 water samples submitted by A.R. Lombardi Associates, Inc./ Fishers Island (EPA 502.2) Henry Souther Labs Inc. 24 Tobey Road Bloomfield, CT 06002 on 10/01/92 Ior VOC 63. I I I I I I I I I I I I I I I 1,3-Dichlorobenzene Less than 0.5 ug/L 1,3-Dichloropropane Less than 0.5 ug/L 1,4-Dichlorobenzene Less than 0.5 ug/L 2,2-Dichloropropane Less than 0.5 ug/L 2-Chloroethylvinylether Less than 0.5 ug/L 2-Chlorotoluene Less than 0.5 ug/L 4-Chlorotoluene Less than 0.5 ug/L Benzene Less than 0.5 ug/L Bromobenzene Less than 0.5 ug/L' Bromochloromethane Less than 0.5 ug/L Bromodichloromethane Less than 0.5 ug/L Bromoform Less than 0.5 ug/L Bromornethane Less than 0.5 ug/L c-l,2-Dichloroethylene Less than 0.5 ug/L c-l,3-Dichloropropene Less than 0.5 ug/L Carbon tetrachloride Less than 0.5 ug/L Chlorobenzene Less than 0.5 ug/L Chloroethane Less than 0.5 ug/L Chloroform Less than 0.5 ug/L Chloromethane Less than 0.5 ug/L Dibromochloromethane Less than 0.5 ug/L Dibromomethane Less than 0.5 ug/L Dichlorodifiuoromethane Less than 0.5 ug/L Ethylbenzene Less than 0.5 ug/L Hexachlorobutadiene Less than 0.5 ug/L Isopropylbenzene Less than 0.5 ug/L m-Xylene Less than 0.5 ug/l_ Methyl-t-butyl ether Less than 0.5 ug/L Methylene chloride Less than 0.5 ug/L n-Butylbenzene Less than 0.5 ug/L n-Propylbenzene Less than 0.5 ug/L Naphthalene Less than 0.5 ug/L o-Xylene Less than 0.5 ug/L p-lsopropyltoluene Less than 0.5 ug/L p-Xylene Less than 0.5 ug/L sec-Butylbenzene Less than 0.5 ug/L Styrene Less than 0.5 ug/L t-1,2-Dichloroethylene Less than 0.5 ug/L t-l,3-Dichloropropene I 7 Less than 0.5 ug/L Send Results To: - A.R. Lombardi Associates, Inc. 25 Terrace Dr. Vernon, CT 06066 Analyzed By: Hen~ Sou~erLabslnc. 24 Tobey Road Bloomfield, CT 06002 10 water samples submitted by A.R. Lombardi Associates, Inc. / Fishers Island on 10/01/92 for VOC 63. (EPA 502.2) tert-Butylbenzene Tetrachloroethylene Toluene Trichloroethylene Trichlorofluormethane Trimethybenzene Vinyl chloride Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L Less than 0.5 ug/L 18 I I' I I I I I I I I I I I I I I I I I A. RICHARD LOM~ARDI, P.E. President RICHARD J. LOMBARDI Vice President THOMAS D. LEE HENRY SOUTHER LABORATORIES INC Newlands Sanitary Lab Division 24 Tobey Road · Bloomfield, CT * 06002 ENVIRONMENTAL AND METALLURGICAL ANALYS{S Established 1898 203-242-6291 FAX 203-286-0634 October 6, 1992 A. R. Lorobardi, Assoc., inc. 25 Terrace Drive Vernon, CT 06066 ATTN: Mr. Mike Horn Gentlemen: The attached report covers the analysis of the samples submitted to this laboratonJ on October 1, 1992. Newlands Sanitary Laboratory Request No. 839, sarople I through 6. TDL/pb Very truly yours, THE NEWLANDS SANITARY LABORATORY Thomas D. Lee Laboratory Director I I I I I I I I I I I I I I I I I I I Send Results To: A.R. Lombardi Associates, Inc. 25 Terrace Drive Vernon, CT 06066 Analyzed By: Henry Souther Labs Inc. 24 Tobey Road Bloomfield, CT 06002 ~Request# 839 J ~Report Date 10/06/92 J 6 water samples submitted by A.R. Lombardi Associates, Inc./ Fishers Island on 10/01/92 for Pesticides & Herbicides. Sample Number I MW-2, water sample collected 09/30/92. Sample 2,4,5-TP Silvex Less than 1 ug/L 2,4-D Less than I ug/L Endrin Less than 0.02 ug/L Lindane Less than 0.02 ug/L Methoxychlor Less than 0.02 ug/L Toxsphene Less than 0.5 ug/L Number 2 MW-4, water sample collected 09/30/92. Sample 2,4,5-TP Silvex Less than 1 ug/L 2,4-D Less than 1 ug/L Endrin Less than 0.02 ug/L Lindane Less than 0.02 ug/L Methoxychler Less than 0.02 ug/L Toxsphene Less than 0.5 ug/L Number 3 MW-6, water sample collected 09/30/92. Sample 2,4,5-TP Silvex Less than 1 ug/L 2,4-D Less than I ug/L Endrin Less than 0.02 ug/L Lindane Less than 0.02 ug/L Methoxychlor Less than 0.02 ug/L Toxaphene Less than 0.5 ug/L Number 4 MW-7, water sample collected 09/30/92. 2,4,5~TP Silvex 2,4-D Endrin Lindane Methoxychlor Toxaphene Sample Number 5 Less than 1 ug/L Less than 1 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.5 ug/L MW-11, water sample collected 09/30/92. Send Results To: A.R. Lombardi Associates, Inc, 25 Terrace Drive Vernon, CT 06066 Analyzed By: Hen~Sou~erLabslnc. 24 Tobey Road Bloomfield, CT 06002 IRecluest # 839 I ~/06/92 ~ 6 water samples submitted by A.R. Lombardi Associates, Inc. / Fishers Island on 10/01/92 for Pesticides & Herbicides. 2,4,5-TP Silvex 2,4-D Endrin Lindane Methoxychlor Toxaphene Less than 1 ug/L Less than 1 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.02 ug/L Less than 0.5 ug/L