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HomeMy WebLinkAboutCorazzini Property Phase II Environmental Site Assessment Limited Phase II Environmental Site Assessment Corazzini Property Cutchogue, New York N&P Project No. 01327 November 6, 2002 Corazzini Property,Cutchogue Limited Phase 11 ESA Limited Phase H Environmental Site Assessment Corazzini Property THIS DOCUMENT CONTAINS 9 PAGES OF TEXT COPIES AND CIRCULATION OF THIS REPORT ARE AS FOLLOWS: Two(2)copies to client One(1)copy retained in NP&V files Prepared For: Mr. Gregory F.Yakaboski Town of Southold Office of the Town Attorney Town Hall, 53095 Main Road P.O. Box 1179 Southold,New York 11971 Prepared By: Mr.Charles J.Voorhis, CEP,AICP Nelson,Pope&Voorhis,LLC 572 Walt Whitman Road Melville,New York 11747 (631)472-5665 Long Island Analytical Laboratories 101-4 Colin Avenue Holbrook,New York 11741 Copyright©2002 by Nelson,Pope&Voorhis,LLC K PAIF NELSON, POPE 6 VOORHIS. LLC ENVIRONMENTAL • PLANNING • CONSULTING Limited Phase H Environmental Site Assessment Corazzini Property CONTENTS 1.0 INTRODUCTION Page 1 of 9 2.0 SAMPLING AND ANALYSIS PROGRAM (SAP) Page 2 of 9 2.1 HAND AUGER SOIL SAMPLING Page 2 of 9 2.2 SOIL SAMPLE FOR LABORATORY ANALYSIS Page 2 of 9 3.0 LABORATORY ANALYSIS Page 4 of 9 3.1 ANALYTICAL TEST METHODS Page 4 of 9 3.2 ANALYTICAL RESULTS Page 4 of 9 4.0 QUALITY ASSURANCE/QUALITY CONTROL PROCEDURES(QA/QC) Page 5 of 9 5.0 SUMMARY AND CONCLUSION Page 7 of 9 6.0 REFERENCES Page 8 of 9 APPENDICES Page 9 of 9 %PWY NELSON, POPE 6 VOORHIS, LLC ENVIRONMENTAL • PLANNING • CONSULTING Corazzini Property,Cutchogue Limited Phase II ESA Limited Phase II Environmental Site Assessment Corazzini Property 1.0 INTRODUCTION AND PURPOSE Nelson, Pope & Voorhis, LLC (NP&V) has been contracted to prepare a Limited Phase H Environmental Site Assessment for the subject property. This report is intended to address recognized environmental conditions that were identified in a Phase I Environmental Site Assessment report prepared by Nelson, Pope & Voorhis, LLC dated October 31, 2001. The Phase I ESA was performed in accordance with the standards detailed by the American Society of Testing and Materials (ASTM) for the Performance of a Phase I Environmental Site Assessment (E 1527). This Phase H ESA was designed to determine what, if any, impact on-site activities have had upon the environmental quality of the subject property. The subject property lies in the Hamlet of Cutchogue, Town of Southold, County of Suffolk, New York. The subject property is part of a 6.5 acre parcel of land. The property is located on the west side of Cox Lane, approximately 425 feet north of North Road (CR 48). The property is more particularly described as Suffolk County Tax Map # 1000-084-01-26.2. The subject property consists of a 75 foot wide strip of land located on the south side of the 6.5 acre tax parcel. This portion of the property contains several pieces of abandoned equipment and two (2) large piles of dirt or crushed asphalt. Based on these findings the Phase I Environmental Site Assessment identified recognized environmental conditions that prompted the performance of this Phase 11 Environmental Site Assessment. These conditions included: the presence of large piles of dirt and asphalt of unknown origin and storage of equipment that may have caused surface staining. This assessment has been designed and performed by NP&V to address the potential impacts to the on-site soils. The laboratory analysis was provided by Long Island Analytical Laboratories. The protocol used to direct this investigation is based upon the following documents: 1) New ' York State Department of Environmental Conservation (NYSDEC) Technical Administrative Guidance Memorandum (TAGM) 4046 Determination of Soil Cleanup Objectives and Cleanup Levels and 2) the Suffolk County Department of Health Services (SCDHS) SOP 9-95 Pumpout and Soil Cleanup Criteria. The following sections detail the subject property and surrounding area characteristics, sampling program, quality assurance protocol, laboratory analysis methodology and laboratory results. NELSON, POPE 6 VOORHIS, LLC ENVIRONMENTAL . PLANNING • CONSULTING Corazzini Property,Cutchogue Limited Phase II ESA 2.0 SAMPLING AND ANALYSIS PROGRAM (SAP) 2.1 HAND AUGER SOIL SAMPLING The large pile of soil located along the southern property boundary was sampled using a stainless steel hand auger. The soil samples (ES-1, MS-1 & WS-1) were collected from various locations throughout each third of the large pile of dirt. These samples were collected from various depths within the pile of dirt. These samples were analyzed for the presence of volatile and semi- volatile organic compounds and metals due to the unknown origin of the dirt. Figure 1 provides a location of the samples collected. 2.2 LABORATORY SAMPLE LOCATION AND FREQUENCY The soil samples collected from the site were containerized and labeled for identification purposes. The labels were coded to correspond to the location from which the samples were secured. Table 1 provides an index of how the samples were coded during labeling. TABLE 1 SAMPLE IDENTIFICATION SAMPLE LOCATION SAMPLE ID CODE Sample collected from the eastern portion of the pile. ES-1 Sample collected from the middle of the pile. MS-1 Sample collected from the western portion of the pile. WS-1 ail NELSON. POPE 6 VOORHIS, LLC ENVIRONMENTAL • PLANNING . CONSULTING Page 2 of 9 Corazzini Property,Cutchogue Limited Phase I1 ESA FIGURE 1 SAMPLE LOCATION MAP Coxs Lase o ES-1 MS-1 0 WS-1 NORTH Page 3 of 9 ALLAMC Up LSON POPE S V- IS LLC IROIWIENTAL PLANNING�CONSULTING Corazzini Property,Cutchogue Limited Phase II ESA 3.0 LABORATORY ANALYSIS 3.1 ANALYTICAL TEST METHODS The soil samples were transported to a New York State Certified Commercial Laboratory for analysis. Selection of the analytical test methods were based on USEPA Test Method 8260 for volatile organic compounds, USEPA Test Method 8270 for semi-volatile organic compounds and metals. 3.2 ANALYTICAL RESULTS The laboratory analysis performed on the soil samples revealed that several of the analyzed constituents exhibited elevated concentrations. Table 2 provides a comparison of those constituents with elevated concentrations and the regulatory standards. The laboratory analysis sheets (NYS ASPA) as prepared by Long Island Analytical Laboratories are presented in Appendix A of this document. As depicted in Table 2, several of the analyzed constituents exceeded the regulatory guidance values set forth in the NYSDEC TAGM 4046, but did not exceed the SCDHS SOP 9-95 parameters. TABLE 2 COMPARISON ANALYSIS Constituents ES-1 MS-1 WS-1 NYSDEC SCDHS TAGM 4046 SOP 9-95 Semi-Volatiles ppb ppb ppb ppb ppb Phenanthrene ND ND 415 50,000 50,000 Di-n-Butylphthalate ill ND ND 8,100 NA Fluoranthene ND 455 883 50,000 50,000 Pyrene ND 542 714 50,000 50,000 Benzo-a-anthracene ND 258 304 224 6,000 Chyrsene ND 321 423 400 800 Bis(2-Ethylexyl)Phtalate 61 ND ND 50,000 NA Benzo-b-flouroanthene ND 261 337 1,100 2,200 Benzo-k-flouroanthene ND 213 262 1,100 2,200 Benzo-a- yrene ND 218 291 61 22,000 Indeno(1,2,3-c,d)pyrene ND 142 187 3,200 6,400 Benzo-g,h,i- erylene ND 153 171 50,000 50,000 Metals PPM PPM PPM PPM PPM Arsenic 7.4 4.1 3.4 7.5 25.0 Barium 21.8 18.8 15.2 300 NA Chromium 9.2 5.6 4.4 50 100 Mercury 0.020 1 ND I ND 1 0.1 2.0 Lead 8.3 1 31.6 19.4 SB 400 ND-Not Detected NA-Not Applicable Bold indicates the constituent exceeds the NYSDEC regulatory standards NELSON, POPE 6 VOORHIS. LLC ENVIRONMENTAL . PLANNING . CONSULTING Page 4 of 9 Corazzini Property,Cutchogue Limited Phase II ESA 4_0 QUALITY ASSURANCE/QUALITY CONTROL PROCEDURES (QA/QQ This sampling protocol was conducted in accordance with USEPA accepted sampling procedures for hazardous waste streams (Municipal Research Laboratory, 1980, Sampling and Sampling Procedures for Hazardous Material Waste Streams, USEPA, Cincinnati, Ohio EPA- 600\280- 018) and ASTM Material Sampling Procedures. All samples were collected by or under the auspices of USEPA trained personnel having completed the course Sampling of Hazardous Materials, offered by the Office of Emergency and Remedial Response. Separate QA/QC measures were implemented for each of the instruments used in soil-gas and soil sampling. Separate QA/QC measures were implemented for each of the instruments used in the Sampling and Analysis Program. Sampling instruments included a stainless steel hand auger and sample vessels. Prior to arrival on the site and between sample locations, the probes sections were decontaminated by washing with a detergent (alconox/liquinox) and potable water solution with distilled water rinse. The organic vapor analyzer was calibrated prior to sampling using a span gas of known concentration. All sample vessels were "level A" certified decontaminated containers. Samples were placed into vessels consistent with the analytical parameters. After acquisition, samples were preserved in the field. All containerized samples were refrigerated to 40 C during transport. A sample represents physical evidence, therefore, an essential part of liability reduction is the proper control of gathered evidence. To establish proper control, the following sample identification and chain-of-custody procedures were followed. Sample Identification Sample identification was executed by use of a sample tag, logbook and manifest. Documentation provides the following: 1. Project Code 2. Sample Laboratory Number 3. Sample Preservation 4. Instrument Used for Source Soil Grabs 5. Composite Medium Used for Source Soil Grabs 6. Date Sample was Secured from Source Soil 7. Time Sample was Secured from Source Soil 8. Person Who Secured Sample from Source Soil Chain-of-Custody Procedures Due to the evidential nature of samples, possession was traceable from the time the samples were collected until they were received by the testing laboratory. A sample was considered under custody if: �,1 NELSON, POPE 6 VOORHIS, LLC ENVIRONMENTAL • PLANNING • CONSULTING Page 5 of 9 Corazzini Property,Cutchogue Limited Phase II ESA It was in a person's possession, or It was in a person's view, after being in possession, or It was in a person's possession and they were to lock it up, or It is in a designated secure area. When transferring custody, the individuals relinquishing and receiving signed, dated and noted the time on the Chain-of-Custody Form. Laboratoryy Custody Procedures A designated sample custodian accepted custody of the shipped samples and verified that the information on the sample tags matched that on the Chain-of-Custody records. Pertinent information as to shipment, pick-up, courier, etc. was entered in the "remarks" section. The custodian then entered the sample tag data into a bound logbook which was arranged by project code and station number. The laboratory custodian used the sample tag number or assigned an unique laboratory number to each sample tag and assured that all samples were transferred to the proper analyst or stored in the appropriate source area. The custodian distributed samples to the appropriate analysts. Laboratory personnel were responsible for the care and custody of samples from the time they were received until the sample was exhausted or returned to the custodian. All identifying data sheets and laboratory records were retained as part of the permanent site record. Samples received by the laboratory were retained until after analysis and quality assurance checks were completed. w NELSON. POPE 6 VOORHIS, LLC ENVIRONMENTAL • PLANNING • CONSULTING Page 6 of 9 Corazzini Property,Cutchogue Limited Phase II ESA 5.0 SUMMARY AND CONCLUSION This investigation was completed to address issues raised in a prior Phase I ESA prepared by Nelson, Pope & Voorhis, LLC. A sampling and analysis program was designed to determine if the large pile of dirt contained elevated concentrations of volatile and semi-volatile organic compounds and metals and if the equipment stored on-site had caused any surface staining. The sampling and analysis plan consisted of soil/sediment quality testing using analytical test methods consistent with expected parameters and agency soil cleanup objectives. The following presents an evaluation of the results of this investigation. 1. Three (3) soil samples were collected from the large pile of dirt located along the southern property boundary. These soil samples were analyzed for the presence of volatile and semi-volatile organic compound and metals. The analytical results revealed that several of the analyzed constituents exhibited elevated concentrations. Several of the elevated concentrations exceeded the NYSDEC TAGM 4046 standards but, did not exceed the SCDHS standards set forth in SOP 9-95. As a result, it is recommended the laboratory results be reviewed by a regulatory agency to determine if any remedial action is required. 2. The soil beneath the stored equipment was inspected to determine if any visible surface staining was observed. This inspection revealed no surface staining was present, therefore,no soil samples were collected or analyzed. The subject property has been evaluated consistent with the findings of a Phase I ESA, and in accordance with standard practice for the industry. This Phase II ESA addresses only the specific areas of the site warranting further analysis and can only provide conclusions regarding the soil quality in those specific areas tested. The Phase lI ESA report is limited to the evaluation of on- site conditions at the time of completion of the field sampling program. d e'�•see . I I C�`� :• (0 LO Date of Completion Charle . Voorhis, CEP, AICP Project Manager NELSON, POPE 6 VOORHIS, LLC ENVIRONMENTAL • PLANNING • CONSULTING Page 7 of 9 Corazzini Property,Cutchogue Limited Phase II ESA 6_0 REFERENCES New York State Department of Environmental Conservation (NYSDEC), 1992, Sampling Guidelines and Protocols Technology Background and Quality Control/Quality Assurance for NYSDEC Spill Response Program,NYSDEC, Albany, New York. Suffolk County Department of Health Services (SCDHS), 1998, Standard Operating Procedure for the Administration of Article 12 of the Suffolk County Sanitary Code Article 12 — SOP 9-95 Pumpout and Soil Cleanup Criteria,Yaphank,New York NYSDEC, 1994, Technical Administrative Guidance Memorandum, HWR-94-4046, Determination of soil cleanup objectives and cleanup levels, Division of Hazardous Waste Remediation, Albany,New York. �NELSON, POPE POPE & VOORHIS, LLC ENVIRONMENTAL • PLANNING • CONSULTING Page 8 of 9 Corazzini Property,Cutchogue Limited Phase II ESA APPENDICES ft �► NELSON, POPE & VOORHIS, LLC ENVIRONMENTAL . PLANNING• CONSULTING Page 9 of 9 Corazzini Property,Cutchogue Limited Phase II ESA APPENDIX A LABORATORY DATA SHEETS ho"I'T NELSON, POPE 6 VOORHIS, LLC ENVIRONMENTAL . PLANNING.CONSULTING LONG ISLAND ANALYTICAL NYSDOH ELAN#11273 LABORATORIES INC. CTDOH# PH-0284 "TOMORROMli ANALY77CAL SOLUTIONS T=v.m Page 1 of 16 October 30, 2002 Steven McGinn Nelson, Pope &Voorhis 572 Walt Whitman Road Melville, New York 11747 Re: Corrazihi Property, Cutchogue Dear Mr. McGinn: Enclosed please find the Laboratory Analysis Report(s) for sample(s) received on October 29, 2002. Long Island Analytical Laboratories analyzed the samples on October 30, 2002 for the following: CLIENT ID ANALYSIS ES-1 EPA 8260, EPA 8270, 8 RCRA Metals MS-1 EPA 8260, EPA 8270, 8 RCRA Metals WS-1 EPA 8260, EPA 8270, 8 RCRA Metals If you have any questions or require further information, please call at your convenience. Long Island Analytical Laboratories would like to thank you for the opportunity to be of service to you. Best Regards, Lano-ISla I&A n,atyrL�ca,L Laboratarte,, Inc/ 101-4 Colin Drive • Holbrook, New York 11741 Phone (631 ) 472-3400 • Fax (631) 472-8505 • Email: LIAL@Iialinc.com Page 2 of 16 Client: Nelson, Pope, & Voorhis Client ID: Corrazihi Property ES-1 Date received: 10/29/02 Laboratory ID: 0227680 Date extracted: 10/29/02 Matrix: Soil Date analyzed: 10/29/02 ELAP #: 11693 EPA METHOD 8260 Parameter CAS No. Results u /k BENZENE 71-43-2 <5 BROMOBENZENE 108-86-1 <5 BROMOCHLOROMETHANE 74-97-5 <5 BROMODICHLOROMETHANE 75-27-4 <5 BROMOFORM 75-25-2 <5 BROMOMETHANE 74-83-9 <5 n-BUTYLBENZENE 104-51-8 <5 sec-BUTYLBENZENE 135-98-8 <5 tert-BUTYLBENZENE 98-06-6 <5 CARBON TETRACHLORIDE 56-23-5 <5 CHLOROBENZENE 108-90-7 <5 CHLORODIBROMOMETHANE 124-48-1 <5 CHLOROETHANE 75-00-3 <5 CHLOROFORM 67-66-3 <5 CHLOROMETHANE 74-87-3 <5 2-CHLOROTOLUENE 95-49-8 <5 4-CHLOROTOLUENE 106-43-4 <5 1,2-DIBROMO-3-CHLOROPROPANE 96-12-8 <5 1,2-DI BROMOETHANE 106-93-4 <5 DIBROMOMETHANE 74-95-3 <5 1,2-DICHLOROBENZENE 95-50-1 <5 1,3-DICHLOROBENZENE 541-73-1 <5 1,4-DICHLOROBENZENE 106-46-7 <5 DICHLORODIFLUOROMETHANE 75-71-8 <5 1,1-DICHLOROETHANE 75-34-3 <5 1,2-DICHLOROETHANE 107-06-2 <5 1,1-DICHLOROETHENE 75-35-4 <5 cis-1,2-DICHLOROETHENE 156-59-2 <5 trans-1,2-DICHLOROETHENE 156-60-5 <5 LONG ISLAND ANALYTICAL LABORATORIES INC. 101-4 Colin Drive • Holbrook, New York 11741 'TOMORROWS ANAcrnCALfaLMONSTOWN Phone (631) 472-3400 • Fax (631) 472-8505 • Email: LIAL@Iialinc.com Page 3 of 16 Client: Nelson, Pope, & Voorhis Client ID: Corrazihi Property ES-1 Date received: 10/29/02 Laboratory ID: 0227680 Date extracted: 10/29/02 Matrix: Soil Date analyzed: 10/29/02 ELAP #: 11693 EPA METHOD 8260 Parameter CAS No. Results u /k 1,2-DICHLOROPROPANE 78-87-5 <5 1,3-DICHLOROPROPANE 142-28-9 <5 2,2-DICHLOROPROPANE 594-20-7 <5 1,1-DICHLOROPROPENE 563-58-6 <5 ETHYLBENZENE 100-41-4 <5 HEXACHLOROBUTADIENE 87-68-3 <5 ISOPROPYLBENZENE 98-82-8 <5 p-ISOPROPYLTOLUENE 99-87-6 <5 METHYLENE CHLORIDE 75-09-2 <5 NAPHTHALENE 91-20-3 <5 n-PROPYLBENZENE 103-65-1 <5 STYRENE 100-42-5 <5 1,1,1,2-TETRACHLOROETHANE 630-20-6 <5 1,1,2,2-TETRACHLOROETHANE 79-34-5 <5 TETRACHLOROETHENE 127-18-4 <5 TOLUENE 108-88-3 <5 1,2.3-TRICHLOROBENZENE 87-61-6 <5 1,2,4-TRICHLOROBENZENE 120-82-1 <5 1,1,1-TRICHLOROETHANE 71-55-6 <5 1,1,2-TRICHLOROETHANE 79-00-5 <5 TRICHLOROETHENE 79-01-6 <5 TRICHLOROFLUOROMETHANE 75-69-4 <5 1,2,3-TRICHLOROPROPANE 96-18-4 <5 1,3,5-TRIMETHYLBENZENE 108-67-8 <5 1,2,4-TRIMETHYLBENZENE 95-63-6 <5 VINYL CHLORIDE 75-01-4 <5 ACETONE 67-64-1 <50 CARBON DISULFIDE 75-15-0 <5 2-BUTANONE MEK) 78-93-3 <10 VINYL ACETATE 108-05-4 <5 2-HEXANONE 591-78-6 <5 p & m-XYLENE 1330-20-7 <10 o-XYLENE 1330-20-7 <5 MTBE 1634-04-4 <5 LONG Laboratory Director ISLAND ANALYTICAL LABORATORIES INC. 101-4 Colin Drive • Holbrook, New York 11741 rOMORROWsANALrnCALfaUTIONSTiMYN Phone (631) 472-3400 • Fax (631) 472-8505 • Email: LIAL@lialinc.com Page 4 of 16 Client: Nelson, Pope, & Voorhis Client ID: Corrazihi Property ES-1 Date received: 10/29/02 Laboratory ID: 0227680 Date extracted: 10/29/02 Matrix: Soil Date analyzed: 10/29/02 ELAP #: 11693 EPA METHOD 8270 Parameter CAS No. Results u /k Bis(2-CHLOROETHYL)ETHER 111-44-4 <40 PHENOL 108-95-1 <40 2-CHLOROPHENOL 95-57-8 <40 1,3-DICHLOROBENZENE 541-73-1 <40 1,4-DICHLOROBENZENE 106-46-7 <40 1,2-DICHLOROBENZENE 95-50-1 <40 Bis(2-CHLOROISOPROPYL)ETHER 108-60-1 <40 2-METHYLPHENOL 95-48-7 <40 HEXACHLOROETHANE 67-72-1 <40 N-NITROSODI-n-PROPYL AMINE 621-64-7 <40 4-METHYLPHENOL 106-44-5 <40 NITROBENZENE 98-95-3 <40 ISOPHORONE 78-59-1 <40 2-NITROPHENOL 88-75-5 <40 2,4-DIMETHYLPHENOL 105-67-9 <40 Bis 2-CHLOROETHOXY METHANE 111-91-1 <40 2,4-DICHLOROPHENOL 102-83-2 <40 1,2,4-TRICHLOROBENZENE 120-82-1 <40 NAPHTHALENE 91-20-3 <40 4-CHLOROANILINE 106-47-8 <40 HEXACHLOROBUTADIENE 87-68-3 <40 4-CHLORO-3-METHYLPHENOL 59-50-7 <40 2-METHYLNAPHTHALENE 91-57-6 <40 HEXACHLOROCYCLOPENTADIENE 77-47-4 <66 2,4,6-TRICHLOROPHENOL 88-06-2 <40 2,4,5-TRICHLOROPHENOL 95-95-4 <40 2-CHLORONAPHTHALENE 91-58-7 <40 2-NITROANILINE 88-74-4 <40 ACENAPHTHYLENE 208-96-8 <40 DIMETHYLPHTHALATE 131-11-3 <40 2,6-DINITROTOLUENE 606-20-2 <40 ACENAPHTHENE 1 83-32-9 <40 LONG ISLAND ANALYTICAL LABORATORIES INC. 101-4 Colin Drive - Holbrook, New York 11741 "70MORRpwsANALr17cALSMUIIONsflMYN Phone (631) 472-3400 - Fax (631) 472-8505 - Email: LIAL@lialinc.com Page 5 of 16 Client: Nelson, Pope, & Voorhis Client ID: Corrazihi Property ES-1 Date received: 10/29/02 Laboratory ID: 0227680 Date extracted: 10/29/02 Matrix: Soil Date analyzed: 10/29/02 ELAP #: 11693 EPA METHOD 8270 Parameter CAS No. Results u /k 3-NITROANILINE 99-09-2 <40 2,4-DINITROPHENOL 51-28-5 <40 DIBENZOFURAN 132-64-9 <40 2,4-DINTROTOLUENE 121-14-2 <40 4-NITROPHENOL 100-02-7 <40 FLUORENE 86-73-7 <40 4-CHLOROPHENYL PHENYL ETHER 7005-72-3 <40 DIETHYLPHTHALATE 84-66-2 <40 4-NITROANILINE 100-01-6 <40 4,6-DINITRO-2-METHYLPHENOL 534-52-1 <40 N-NITROSODIPHENYLAMINE 86-30-6 <40 4-BROMOPHENYL-PHENYL ETHER 101-55-3 <40 HEXACHLOROBENZENE 118-74-1 <40 PENTACHLORPHENOL 87-86-5 <40 PHENANTHRENE 85-01-8 <40 ANTHRACENE 120-12-7 <40 Di-n-BUTYLPHTHALATE 84-74-2 111 FLUORANTHENE 206-44-0 <40 PYRENE 129-00-0 <40 BUTYLBENZYLPHTHALATE 85-68-7 <40 3,3-DI CHLOROBENZIDINE 91-94-1 <40 BENZO-a-ANTH RACE NE 56-55-3 <40 CHRYSENE 218-01-9 <40 Bis(2-ETHYLEXYL)PHTALATE 117-81-7 61 DI-n-OCTYLPHTHALATE 117-84-0 <40 BENZO-b-FLUOROANTHENE 205-99-2 <40 BENZO-k- FLUOROANTHENE 207-08-9 <40 BENZO-a-PYRENE 50-32-8 <40 INDENO(1,2,3-c,d)PYRENE 193-39-5 <40 DIBENZO-a,h-ANTHRACENE 53-70-3 <40 BENZO- ,h,i-PERYLENE 191-24-2 <40 Laboratory Director LONG ISLAND ANALYTICAL LABORATORIES INC. 101-4 Colin Drive - Holbrook, New York 11741 'MMORROWSANalrncALSMUTIONSTODAYN Phone (631) 472-3400 - Fax (631) 472-8505 - Email: LIAL@Iialinc.com Page 6 of 16 Client: Nelson, Pope, & Voorhis Client ID: Corrazihi Property ES-1 Date received: 10/29/02 Laboratory ID: 0227680 Date extracted: 10/30/02 Matrix: Soil Date analyzed: 10/30/02 ELAP #: 11693 METALS ANALYSIS 8 RCRA Parameter MDL Results mg/kg SILVER, Ag 1.65 m /k <1.65 ARSENIC, As 1.65 mg/kg mg/kg 7.4 BARIUM, Ba 3.33 mg/kg mg/kg 21 .8 CADMIUM, Cd 1.00 mg/kg <1.00 CHROMIUM, Cr 1.65 mg/kg mg/kg 9•2 MERCURY, H 0.020 m /k 0.020 LEAD, Pb 1.65 m /k 8.3 SELENIUM, Se 1.65 mg/kg <1.65 Performed by SW-846 Method 6010 Laboratory Director LONG ISLAND ANALYTICAL LABORATORIES INC. 101-4 Colin Drive • Holbrook, New York 11741 '"MORROwsaNAlrncaLSaUTIONSMUy- Phone (631) 472-3400 • Fax (631) 472-8505 • Email: LIAL@lialinc.com Page 7 of 16 Client: Nelson, Pope, & Voorhis Client ID: Corrazihi Property MS-1 Date received: 10/29/02 Laboratory ID: 0227681 Date extracted: 10/29/02 Matrix: Soil Date analyzed: 10/29/02 ELAP #: 11693 EPA METHOD 8260 Parameter CAS No. Results u /k BENZENE 71-43-2 <5 BROMOBENZENE 108-86-1 <5 BROMOCHLOROMETHANE 74-97-5 <5 BROMODICHLOROMETHANE 75-27-4 <5 BROMOFORM 75-25-2 <5 BROMOMETHANE 74-83-9 <5 n-BUTYLBENZENE 104-51-8 <5 sec-BUTYLBENZENE 135-98-8 <5 tert-BUTYLBENZENE 98-06-6 <5 CARBON TETRACHLORIDE 56-23-5 <5 CHLOROBENZENE 108-90-7 <5 CHLORODIBROMOMETHANE 124-48-1 <5 CHLOROETHANE 75-00-3 <5 CHLOROFORM 67-66-3 <5 CHLOROMETHANE 74-87-3 <5 2-CHLOROTOLUENE 95-49-8 <5 4-CH LO ROTO LU EN E 106-43-4 <5 1,2-DIBROMO-3-CHLOROPROPANE 96-12-8 <5 1,2-DIBROMOETHANE 106-93-4 <5 DIBROMOMETHANE 74-95-3 <5 1,2-DICHLOROBENZENE 95-50-1 <5 1,3-DICHLOROBENZENE 541-73-1 <5 1,4-DICHLOROBENZENE 106-46-7 <5 DICHLORODIFLUOROMETHANE 75-71-8 <5 1,1-DICHLOROETHANE 75-34-3 <5 1,2-DICHLOROETHANE 107-06-2 <5 1,1-DICHLOROETHENE 75-35-4 <5 cis-1,2-DICHLOROETHENE 156-59-2 <5 trans-1,2-DICHLOROETHENE 156-60-5 <5 LONG ISLAND ANALYTICAL LABORATORIES INC. 101-4 Colin Drive - Holbrook, New York 11741 "TONORROWSANALrflCALSaUTIONSTWAY' Phone (631) 472-3400 - Fax (631) 472-8505 - Email: LIALClialinc.com Page 8 of 16 Client: Nelson, Pope, & Voorhis Client ID: Corrazihi Property MS-1 Date received: 10/29/02 Laborato ID: 0227681 Date extracted: 10/29/02 Matrix: Soil Date analyzed: 10/29/02 ELAP #: 11693 EPA METHOD 8260 Parameter CAS No. Results u /k 1,2-DICHLOROPROPANE 78-87-5 <5 1,3-DICHLOROPROPANE 142-28-9 <5 2,2-DICHLOROPROPANE 594-20-7 <5 1,1-DICHLOROPROPENE 563-58-6 <5 ETHYLBENZENE 100-41-4 <5 HEXACHLOROBUTADIENE 87-68-3 <5 ISOPROPYLBENZENE 98-82-8 <5 -ISOPROPYLTOLUENE 99-87-6 <5 METHYLENE CHLORIDE 75-09-2 <5 NAPHTHALENE 91-20-3 <5 n-PROPYLBENZENE 103-65-1 <5 STYRENE 100-42-5 <5 1,1,1,2-TETRACHLOROETHANE 630-20-6 <5 1,1,2,2-TETRACHLOROETHANE 79-34-5 <5 TETRACHLOROETHENE 127-18-4 <5 TOLUENE 108-88-3 <5 1,2,3-TRICHLOROBENZENE 87-61-6 <5 1,2,4-TRICHLOROBENZENE 120-82-1 <5 1,1,1-TRICHLOROETHANE 71-55-6 <5 1,1,2-TRICHLOROETHANE 79-00-5 <5 TRICHLOROETHENE 79-01-6 <5 TRICHLOROFLUOROMETHANE 75-69-4 <5 1,2,3-TRICHLOROPROPANE 96-18-4 <5 1,3,5-TRIMETHYLBENZENE 108-67-8 <5 1,2,4-TRIMETHYLBENZENE 95-63-6 <5 VINYL CHLORIDE 75-01-4 <5 ACETONE 67-64-1 <50 CARBON DISULFIDE 75-15-0 <5 2-BUTANONE (MEK) 78-93-3 <10 VINYL ACETATE 108-05-4 <5 2-HEXANONE 591-78-6 <5 & m-XYLENE 1330-20-7 <10 o-XYLEN E 1330-20-7 <5 MTBE 1634-04-4 <5 LONG Laboratory Director ISLAND ANALYTICAL LABORATORIES INC. 101-4 Colin Drive - Holbrook, New York 11741 "MMeeQewseNAMCAi SOLUTIONS TODAY" Phone (631) 472-3400 - Fax (631) 472-8505 - Email: LIAL@lialinc.com Page 9 of 16 Client: Nelson, Pope, & Voorhis Client ID: Corrazihi Property MS-1 Date received: 10/29/02 Laboratory ID: 0227681 Date extracted: 10/29/02 Matrix: Soil Date analyzed: 10/29/02 ELAP #: 11693 EPA METHOD 8270 Parameter CAS No. Results u /k Bis(2-CHLOROETHYL)ETHER 111-44-4 <100 PHENOL 108-95-1 <100 2-CHLOROPHENOL 95-57-8 <100 1,3-DICHLOROBENZENE 541-73-1 <100 1,4-DICHLOROBENZENE 106-46-7 <100 1,2-DICHLOROBENZENE 95-50-1 <100 Bis(2-CHLOROISOPROPYL)ETHER 108-60-1 <100 2-METHYLPHENOL 95-48-7 <100 HEXACHLOROETHANE 67-72-1 <100 N-NITROSODI-n-PROPYL AMINE 621-64-7 <100 4-METHYLPHENOL 106-44-5 <100 NITROBENZENE 98-95-3 <100 ISOPHORONE 78-59-1 <100 2-NITROPHENOL 88-75-5 <100 2,4-DIMETHYLPHENOL 105-67-9 <100 Bis 2-CHLOROETHOXY METHANE 111-91-1 <100 2,4-DICHLOROPHENOL 102-83-2 <100 1,2,4-TRICHLOROBENZENE 120-82-1 <100 NAPHTHALENE 91-20-3 <100 4-CHLOROANILINE 106-47-8 <100 HEXACHLOROBUTADIENE 87-68-3 <100 4-CHLORO-3-METHYLPHENOL 59-50-7 <100 2-METHYLNAPHTHALENE 91-57-6 <100 HEXACHLOROCYCLOPENTADIENE 77-47-4 <100 2,4,6-TRICHLOROPHENOL 88-06-2 <100 2,4,5-TRICHLOROPHENOL 95-95-4 <100 2-CHLORONAPHTHALENE 91-58-7 <100 2-NITROANILINE 88-74-4 <100 ACENAPHTHYLENE 208-96-8 <100 D IMETHYLPHTHALATE 131-11-3 <100 2,6-DINITROTOLUENE 606-20-2 <100 ACENAPHTHENE 83-32-9 1 <100 LONG ISLAND ANALYTICAL LABORATORIES INC. 101-4 Colin Drive - Holbrook, New York 11741 "TOMORROWS ANALrncALtotUrloNSTCDAY' Phone (631) 472-3400 - Fax (631) 472-8505 - Email: LIAL@lialinc.com Page 10 of 16 Client: Nelson, Pope, & Voorhis Client ID: Corrazihi Property MS-1 Date received: 10/29/02 Laborato ID: 0227681 Date extracted: 10/29/02 Matrix: Soil Date analyzed: 10/29/02 ELAP #: 11693 EPA METHOD 8270 Parameter CAS No. Results u /k 3-NITROANILINE 99-09-2 <100 2,4-DINITROPHENOL 51-28-5 <100 DIBENZOFURAN 132-64-9 <100 2,4-DINTROTOLUENE 121-14-2 <100 4-NITROPHENOL 100-02-7 <100 FLUOR ENE 86-73-7 <100 R4-IBROMOPHENYL OPHENYL PHENYL ETHER 7005-72-3 <100 ETHYLPHTHALATE 84-66-2 <100 4-NITROANILINE 100-01-6 <100 ITRO-2-METHYLPHENOL 534-52-1 <100 ROSODIPHENYLAMINE 86-30-6 <100 -PHENYL ETHER 101-55-3 <100 HEXACHLOROBENZENE 118-74-1 <100 PENTACHLORPHENOL 87-86-5 <100 PHENANTHRENE 85-01-8 189 ANTHRACENE 120-12-7 <100 Di-n-BUTYLPHTHALATE 84-74-2 <100 FLUORANTHENE 206-44-0 455 PYREN E 129-00-0 542 FEBUTYLBENZYLPHTHALATE 85-68-7 <100 ICHLOROBENZIDINE 91-94-1 <100 NZO-a-ANTHRACENE 56-55-3 258 CHRYSENE 218-01-9 321 Bis(2-ETHYLEXYL PHTALATE 117-81-7 <100 DI-n-OCTYLPHTHALATE 117-84-0 <100 BENZO-b-FLUOROANTHENE 205-99-2 261 BENZO-k- FLUOROANTHENE 207-08-9 213 BENZO-a-PYRENE 50-32-8 218 INDENO(1,2,3-c,d)PYRENE 193-39-5 142 DIBENZO-a,h-ANTHRACENE 53-70-3 <100 BENZO- ,h,i-PERYLENE 191-24-2 153 MDL's are raised due to matrix interference. Laboratory Director LONG ISLAND ANALYTICAL LABORATORIES INC. 101-4 Colin Drive - Holbrook, New York 11741 WMUMDMwseNALY"CALtaurlONSTOWN Phone (631) 472-3400 - Fax (631) 472-8505 - Email: LIAL@lialinc.com Page 11 of 16 Client: Nelson, Pope, & Voorhis Client ID: Corrazihi Property MS-1 Date received: 10/29/02 Laboratory ID: 0227681 Date extracted: 10/30/02 Matrix: Soil Date analyzed: 10/30/02 ELAP #: 11693 METALS ANALYSIS 8 RCRA Parameter MDL Results mg/kg SILVER, Ag <1 .65 ARSENIC, As 1.65 mg/kg mg/kg 4.1 BARIUM, Ba 3.33 mg/kg mg/kg 18.8 CADMIUM, Cd 1.00 m /k <1 .00 CHROMIUM, Cr 1.65 mg/kg mg/kg 5.6 MERCURY, Hg 0.020 mg/kg <0.020 LEAD, Pb 1.65 mg/kg mg/kg 31.6 SELENIUM, Se 1.65 mg/kg <1 .65 Performed by SW-846 Method 6010 Laboratory Director LONG ISLAND ANALYTICAL LABORATORIES INC. 101-4 Colin Drive • Holbrook, New York 11741 "TOMORROWS ANALY77CAL SMUrIONS TOWN Phone (631) 472-3400 • Fax (631) 472-8505 • Email: LIALCIialinc.com Page 12 of 16 Client: Nelson, Pope, & Voorhis Client ID: Corrazihi Property WS-1 Date received: 10/29/02 Laboratory ID: 0227682 Date extracted: 10/29/02 Matrix: Soil Date analyzed: 10/29/02 ELAP #: 11693 EPA METHOD 8260 Parameter CAS No. Results u /k BENZENE 71-43-2 <5 BROMOBENZENE 108-86-1 <5 BROMOCHLOROMETHANE 74-97-5 <5 BROMODICHLOROMETHANE 75-27-4 <5 BROMOFORM 75-25-2 <5 BROMOMETHANE 74-83-9 <5 n-BUTYLBENZENE 104-51-8 <5 sec-BUTYLBENZENE 135-98-8 <5 tert-BUTYLBENZENE 98-06-6 <5 CARBON TETRACHLORIDE 56-23-5 <5 CHLOROBENZENE 108-90-7 <5 CHLORODIBROMOMETHANE 124-48-1 <5 CHLOROETHANE 75-00-3 <5 CHLOROFORM 67-66-3 <5 CHLOROMETHANE 74-87-3 <5 2-CHLOROTOLUENE 95-49-8 <5 4-CHLOROTOLUENE 106-43-4 <5 1,2-DIBROMO-3-CHLOROPROPANE 96-12-8 <5 1,2-DIBROMOETHANE 106-93-4 <5 DIBROMOMETHANE 74-95-3 <5 1,2-DICHLOROBENZENE 95-50-1 <5 1,3-DICHLOROBENZENE 541-73-1 <5 1,4-DICHLOROBENZENE 106-46-7 <5 DICHLORODIFLUOROMETHANE 75-71-8 <5 1,1-DICHLOROETHANE 75-34-3 <5 1,2-DICHLOROETHANE 107-06-2 <5 1,1-DICHLOROETHENE 75-35-4 <5 cis-1,2-DICHLOROETHENE 156-59-2 <5 trans-1,2-DICHLOROETHENE 156-60-5 <5 LONG ISLAND ANALYTICAL LABORATORIES INC. 101-4 Colin Drive - Holbrook, New York 11741 -TOMORROWS ANALY77CAL SOLUTIONS 1MY" Phone (631) 472-3400 - Fax (631) 472-8505 - Email: LIAL@lialinc.com Page 13 of 16 Client: Nelson, Pope, & Voorhis Client ID: Corrazihi Property WS-1 Date received: 10/29/02 Laboratory ID: 0227682 Date extracted: 10/29/02 Matrix: Soil Date analyzed: 10/29/02 ELAP #: 11693 EPA METHOD 8260 Parameter CAS No. Results u /k 1,2-DICHLOROPROPANE 78-87-5 <5 1,3-DICHLOROPROPANE 142-28-9 <5 2,2-DICHLOROPROPANE 594-20-7 <5 1,1-DICHLOROPROPENE 563-58-6 <5 ETHYLBENZENE 100-41-4 <5 HEXACHLOROBUTADIENE 87-68-3 <5 ISOPROPYLBENZENE 98-82-8 <5 -ISOPROPYLTOLUENE 99-87-6 <5 METHYLENE CHLORIDE 75-09-2 <5 NAPHTHALENE 91-20-3 <5 n-PROPYLBENZENE 103-65-1 <5 STYRENE 100-42-5 <5 1,1,1,2-TETRACHLOROETHANE 630-20-6 <5 1,1,2,2-TETRACHLOROETHANE 79-34-5 <5 -- TETRACHLOROETHENE 127-18-4 <5 TOLUENE 108-88-3 <5 1,2,3-TRICHLOROBENZENE 87-61-6 <5 1,2,4-TRICHLOROBENZENE 120-82-1 <5 1,1,1-TRICHLOROETHANE 71-55-6 <5 1,1,2-TRICHLOROETHANE 79-00-5 <5 TRICHLOROETHENE 79-01-6 <5 TRICHLOROFLUOROMETHANE 75-69-4 <5 1,2,3-TRICHLOROPROPANE 96-18-4 <5 1,3,5-TRIMETHYLBENZENE 108-67-8 <5 1,2,4-TRIMETHYLBENZENE 95-63-6 1 <5 VINYL CHLORIDE 75-01-4 <5 ACETONE 67-64-1 <50 CARBON DISULFIDE 75-15-0 <5 2-13UTANONE (MEK 78-93-3 <10 VINYL ACETATE 108-05-4 <5 2-HEXANONE 591-78-6 <5 p & m-XYLENE 1330-20-7 <10 o-XYLENE 1330-20-7 <5 MTBE 1634-04-4 <5 LONG Laboratory Director ISLAND ANALYTICAL LABORATORIES INC. 101-4 Colin Drive - Holbrook, New York 11741 "TOMORROW$ANAirncAL SOLUTIONS rMYN Phone (631) 472-3400 - Fax (631) 472-8505 - Email: LIAL@Iialinc.com Page 14 of 16 ;CIie;nt: Nelson, Pope, & Voorhis ;Laborent ID: Corrazihi Property ;;IWS-1 eceived: 10/29/02 ato ID: 0227682 Date extracted: 10/29/02 Matrix: Soil Date analyzed: 10/29/02 ELAP #: 11693 EPA METHOD 8270 Parameter CAS No. Results u /k Bis(2-CHLOROETHYL ETHER 111-44-4 <200 PHENOL 108-95-1 <200 2-CHLOROPHENOL 95-57-8 <200 1,3-DICHLOROBENZENE 541-73-1 <200 1,4-DICHLOROBENZENE 106-46-7 <200 1,2-DICHLOROBENZENE 95-50-1 <200 Bis(2-CHLOROISOPROPYL)ETHER 108-60-1 <200 2-METHYLPHENOL 95-48-7 <200 HEXACHLOROETHANE 67-72-1 <200 N-NITROSODI-n-PROPYL AMINE 621-64-7 <200 4-METHYLPHENOL 106-44-5 <200 NITROBENZENE 98-95-3 <200 ISOPHORONE 78-59-1 <200 2-NITROPHENOL 88-75-5 <200 2,4-DIMETHYLPHENOL 19 <200 mi Bis 2-CHLOROETHOXY METHANE 111--91--1 <200 2,4-DICHLOROPHENOL 102-83-2 <200 1,2,4-TRICHLOROBENZENE 120-82-1 <200 NAPHTHALENE 91-20-3 <200 4-CHLOROANILINE 106-47-8 <200 HEXACHLOROBUTADIENE 87-68-3 <200 4-CHLORO-3-METHYLPHENOL 59-50-7Ef� <200 2-METHYLNAPHTHALENE 91-57-6 <200 HEXACHLOROCYCLOPENTADI ENE 77-47-4 <200 2,4,6-TRICHLOROPHENOL 88-06-2 <200 2,4,5-TRICHLOROPHENOL 95-95-4 <200 2-CHLORONAPHTHALENE 91-58-7 <200 2-N ITROAN I LI N E 88-74-4 <200 ACE NAPHTHYLENE 208-96-8 <200 DIMETHYLPHTHALATE 131-11-3 <21 2,6-DINITROTOLUENE 606-20-2 <200 ACENAPHTHENE 83-32-9 <200 LONG ISLAND ANALYTICAL LABORATORIES INC. 101-4 Colin Drive - Holbrook, New York 11741 "TOMORROWS ANALY17CAL SOLLMONS TODAYN Phone (631) 472-3400 - Fax (631) 472-8505 - Email: LIAL@lialinc.com Page 15 of 16 Client: Nelson, Pope, & Voorhis Client ID: Corrazihi Property W S-1 Date received: 10/29/02 Laboratory ID: 0227682 Date extracted: 10/29/02 Matrix: Soil Date anal zed: 10/29/02 ELAP #: 11693 EPA METHOD 8270 Parameter CAS No. Results u /k 3-NITROANILINE 99-09-2 <200 2,4-DINITROPHENOL 51-28-5 <200 DIBENZOFURAN 132-64-9 <200 2,4-DINTROTOLUENE 121-14-2 <200 4-NITROPHENOL 100-02-7 <200 FLUORENE 86-73-7 <200 4-CHLOROPHENYL PHENYL ETHER 7005-72-3 <200 DIETHYLPHTHALATE 84-66-2 <200 4-NITROANILINE 100-01-6 <200 4,6-DINITRO-2-METHYLPHENOL 534-52-1 <200 N-NITROSODIPHENYLAMINE 86-30-6 <200 4-BROMOPHENYL-PHENYL ETHER 101-55-3 <200 HEXACHLOROBENZENE 118-74-1 <200 PENTACHLORPHENOL 87-86-5 <200 PHENANTHRENE 85-01-8 415 ANTHRACENE 120-12-7 <200 Di-n-BUTYLPHTHALATE 84-74-2 <200 _ FLUORANTHENE 206-44-0 883 PYRENE 129-00-0 714 BUTYLBENZYLPHTHALATE 85-68-7 <200 3,3-DICHLOROBENZIDINE 91- BENZO-a-ANTHRACENE 56-55-3 304 04 -1 CHRYSENE 218-01-9 423 Bis(2-ETHYLEXYL)PHTALATE 117-81-7 <200 DI-n-OCTYLPHTHALATE 117-84-0 <200 BEN ZO-b-FLUOROANTHENE 205-99-2 337 BENZO-k- FLUOROANTHENE 207-08-9 1i 262 BENZO-a-PYRENE 50-32-8 291 INDENO(1,2,3-c,d)PYRENE 193-39-5 187 DIBENZO-a,h-ANTHRACENE 53-70-3 <200 BENZO- ,h,i-PERYLENE 191-24-2 171 MDL's are raised due to matrix interference. � o,t Laboratory Director LONG ISLAND ANALYTICAL LABORATORIES INC. 101-4 Colin Drive - Holbrook, New York 11741 "TOMORROWS ANALvnCALEMMONSTODAY' Phone (631) 472-3400 - Fax (631) 472-8505 - Email: LIAL@lialinc.com Page 16 of 16 rD;ate t: Nelson, Pope, & Voorhis Client ID: Corrazihi Property W S-1 received: 10/29/02 Laborato ID: 0227682 ate extracted: 10/30/02 Matrix: Soil Date analyzed: 10/30/02 ELAP #: 11693 METALS ANALYSIS 8 RCRA Parameter MDL Results mg/kg SILVER, A 1.65 W/k <1.65 ARSENIC, As 1.65 3.4 BARIUM, Ba 3.33 15.2 CADMIUM, Cd 1.00 <1.00 CHROMIUM, Cr 1 .65 4.4 MERCURY, H 0.020 <0.020 LEAD, Pb 1 .65 19.4 SELENIUM, Se 1.65 <1.65 Performed by SW-846 Method 6010 Laboratory Director LONG ISLAND ANALYTICAL LABORATORIES INC. 101-4 Colin Drive • Holbrook, New York 11741 ,mueoQew5ANALY77CALSMVTIONfTODAY• Phone (631) 472-3400 • Fax (631) 472-8505 • Email: LIAL@lialinc.com