HomeMy WebLinkAbout2015 2nd
SECOND SEMIANNUAL REPORT OF 2015
TOWN OF SOUTHOLD LANDFILL
POST CLOSURE GROUNDWATER MONITORING PROGRAM
Prepared for:
TOWN OF SOUTHOLD
SOLID WASTE MANAGEMENT DISTRICT
CUTCHOGUE, SUFFOLK COUNTY, NEW YORK
Prepared by:
D&B ENGINEERS AND ARCHITECTS, P.C
WOODBURY, NEW YORK
MAY 2016
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SECOND SEMIANNUAL REPORT OF 2015
TOWN OF SOUTHOLD LANDFILL
POST CLOSURE GROUNDWATER MONITORING PROGRAM
TABLE OF CONTENTS
Section Title Page
1.0 INTRODUCTION....................................................................................................... 1-1
2.0 SAMPLING PROCEDURES AND ANALYSES .................................................... 2-1
2.1 Groundwater Level Measurement Procedures .................................................. 2-1
2.2 Groundwater Sampling Procedures .................................................................. 2-1
2.3 Sample Analyses ............................................................................................... 2-3
3.0 GROUNDWATER LEVEL MEASUREMENTS .................................................... 3-1
4.0 DISCUSSION OF RESULTS .................................................................................... 4-1
4.1 Data Validation ................................................................................................. 4-1
4.2 Groundwater Results ......................................................................................... 4-2
4.2.1 Field Parameters ................................................................................... 4-2
4.2.2 Volatile Organic Compounds ............................................................... 4-3
4.2.3 Inorganic Parameters (Metals) .............................................................. 4-4
4.2.4 Leachate Indicators ............................................................................... 4-5
5.0 CONCLUSIONS AND RECOMMENDATIONS ................................................... 5-1
List of Appendices
NYSDEC Approval Letter for Request for Modifications (July 12, 2015) ..................A
Groundwater Analytical Results ...................................................................................B
Groundwater Sampling Logs ........................................................................................C
Chain of Custody Forms ...............................................................................................D
Data Validation Check List ..........................................................................................E
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TABLE OF CONTENTS (continued)
Section Title Page
List of Figures
1-1 Site Location Map .............................................................................................1-2
2-1 Groundwater Monitoring Well Location Map ..................................................2-2
List of Tables
3-1 Groundwater Level Data December 28, 2015 ..............................................3-2
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1.0 INTRODUCTION
The Town of Southold has retained D&B Engineers and Architects, P.C. (D&B) to
perform post-closure groundwater monitoring and reporting for the closed and capped municipal
solid waste (MSW) landfill in Cutchogue, New York (i.e. the Site). The location of the Site is
shown in Figure 1-1. This report is for the Second Semiannual 2015 groundwater monitoring
event, conducted on December 28, 2015 and describes the work performed and the results
obtained. The groundwater monitoring wells were sampled in strict conformance with the
Quality Assurance/Quality Control (QA/QC) Plan, which is part of the Post Closure Monitoring
and Maintenance Manual, dated August 2003.
In the past, groundwater sampling was performed quarterly with three rounds analyzed
for New York Codes, Rules and Regulations (NYCRR) Part 360 Routine Parameters and one
round analyzed for 6NYCRR Part 360 Baseline Parameters on a rotating basis. In the Spring of
2015, on behalf of the Town of Southold, D&B proposed modifications to the New York State
Department of Environmental Conservation (NYSDEC) pertaining to the sampling frequency
and analyses for the Post-Closure Groundwater Monitoring Program for the Site. The request for
these modifications was approved by the NYSDEC in a letter dated July 2, 2015 and is provided
in Appendix A.
Commencing with the Second Semiannual 2015 groundwater monitoring event described
in this report, modifications to the Post-Closure Groundwater Monitoring Program included:
A reduction in sampling frequency from quarterly to semiannually for all well
clusters (MW-1, MW-3, MW-4, MW-5, MW-6 and MW-8); and
Groundwater analysis for 6NYCRR Part 360 Baseline Parameters for both
semiannual sampling events.
This report is organized into the following sections: Section 2.0 (Sampling Procedures
and Analyses) describes the water level measurements and groundwater sampling procedures, as
well as the groundwater analyses. Section 3.0 (Groundwater Level Measurements) summarizes
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1-1
Long Island
NN
Sound
Southold
48
25
Great Peconic
Bay
SOUTHOLD LANDFILL
CUTCHOGUE, NEW YORK
SITE LOCATION MAP
Figure 1-1
3753 -Site Location Map.indd (04/29/16 - 2:54 PM)
the groundwater level measurements and groundwater elevations. Section 4.0 (Discussion of
Results) summarizes the key findings from this groundwater monitoring event, including
comparison of the laboratory results to NYSDEC Class GA Groundwater Standards and
Guidance Values. Section 5.0 (Conclusions and Recommendations) provides conclusions and
recommendations based on the second semiannual 2015 results.
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1-3
2.0 SAMPLING PROCEDURES AND ANALYSES
Water level measurements and groundwater samples were collected from the
monitoring wells (MW-1S, MW-1D, MW-3S, MW-3D, MW-4S, MW-4D, MW-5S, MW-5D,
MW-6S, MW-6D, MW-8S and MW-8D) on December 28, 2015 as part of the Second
Semiannual 2015 groundwater monitoring event. A site plan showing the locations of the
monitoring wells is provided in Figure 2-1. The following sections provide a brief discussion of
the procedures used during groundwater level measurements, groundwater sampling and sample
analysis.
2.1 Groundwater Level Measurement Procedures
Prior to sampling, water level measurements were obtained from the 12 monitoring wells
to determine the volume of standing water in the well for purposes of purging, as well as for
determination of groundwater elevations and flow direction. Groundwater level measurements
were obtained from a surveyed measuring point on each well utilizing a decontaminated
electronic water level indicator to an accuracy of 0.01 foot. A discussion regarding groundwater
level measurements and groundwater flow direction is provided in Section 3.0.
2.2 Groundwater Sampling Procedures
Sampling procedures for the collection of the groundwater samples were implemented in
accordance with the protocol described in the Quality Assurance/Quality Control (QA/QC) Plan,
which is part of the Post Closure Monitoring and Maintenance Manual, dated August 2003.
Field decontamination was performed between sampling locations for non-disposable equipment.
Prior to collecting groundwater samples, the 12 monitoring wells were purged to remove
the standing water in the well. Well purging was accomplished by first measuring the static
water level in the well and calculating the volume of standing water. A decontaminated
submersible pump was used to purge the water from the well. Decontamination of the
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2-1
submersible pump used for well purging was performed in accordance with the procedure
described in the QA/QC Plan.
During the purging process, groundwater was monitored and recorded for the following
field parameters: pH, temperature, specific conductance, oxidation reduction potential (ORP),
dissolved oxygen and turbidity. When the values of the field parameters stabilized within 10%
based on the last two readings, the turbidity of the groundwater was less than 50 Nephelometric
Turbidity Units (NTUs) and at least three well volumes had been removed, well purging was
considered complete.
In accordance with the QA/QC Plan, groundwater samples were collected using new,
dedicated, disposable polyethylene bailers and polypropylene rope. Samples for VOC analysis
were collected first, followed by inorganic parameters and leachate indicators. Each sample was
labeled with the well number, time and date, and stored in an ice-filled cooler with the chain of
custody forms and shipped to the laboratory (ALS Environmental) the same day.
Appropriate quality assurance/quality control (QA/QC) samples, which included matrix
spike and matrix spike duplicate (MS/MSD) sets and a trip blank were collected in accordance
with the QA/QC Plan.
Tables summarizing the analytical results are provided in Appendix B and discussed in
Section 4.0. Groundwater sampling logs for the Second Semiannual 2015 groundwater
monitoring event are provided in Appendix C, and the chain of custody forms are provided in
Appendix D.
2.3 Sample Analyses
Groundwater samples collected during the Second Semiannual 2015 groundwater
monitoring event from the 12 monitoring wells were analyzed for 6NYCRR Part 360 Baseline
Parameters. Laboratory analyses were performed by ALS Environmental, located in Rochester,
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New York. This laboratory is approved under the New York State Department of Health
Environmental Laboratory Approval Program (ELAP) for the analyses performed.
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3.0 GROUNDWATER LEVEL MEASUREMENTS
Groundwater level measurements were collected by D&B on December 28, 2015, from
the 12 groundwater monitoring wells as part of the Second Semiannual 2015 groundwater
monitoring event. The groundwater level measurements from the monitoring wells are
summarized in Table 3-1.
As shown in Table 3-1, water
ranged from 5.50 feet above mean sea level (MSL) in well MW-1S, located on the south end of
the Site, to 3.66 feet above MSL in well MW-8S, located on the west side of the Site. Well
MW-8S exhibits a lower water table elevation in comparison to the closest shallow wells
MW-4S and MW-6S. The lower water table elevation at well MW-8S may be due to reduced
groundwater recharge in close proximity to the capped landfill. Based upon the December 28,
2015 groundwater level measurements and calculated water table elevations, groundwater flow
direction was determined to be in a north-northwesterly direction. Therefore, well cluster MW-1
is located upgradient of the Site, and the other wells are located along the downgradient
boundary of the Site.
Site are consistent with
the shallow well water table elevations, except for well MW-8D, and indicate virtually no
vertical hydraulic gradient throughout the landfill site. An upward vertical hydraulic gradient is
indicated at well cluster MW-8, due to the lower water table elevation.
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Table 3-1
SOUTHOLD LANDFILL
SECOND SEMIANNUAL 2015 GROUNDWATER MONITORING EVENT
MONITORING WELL GROUNDWATER ELEVATION MEASUREMENTS
DECEMBER 28, 2015
Measuring Point
Elevation Depth to Water from Groundwater Elevation
Well Designation (feet above msl) Measuring Point (feet) (feet above msl)
MW-1S 44.83 39.33 5.50
MW-1D
44.88 39.30 5.58
MW-3S
49.50 44.73 4.77
MW-3D
49.19 44.41 4.78
MW-4S
63.03 58.64 4.39
MW-4D
62.92 58.53 4.39
MW-5S
68.14 63.80 4.34
MW-5D
67.64 63.33 4.31
MW-6S
55.77 50.91 4.86
MW-6D 55.71 50.85 4.86
MW-8S 54.16 50.50 3.66
MW-8D 55.29 50.31 4.98
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3-2
4.0 DISCUSSION OF RESULTS
4.1 Data Validation
Twelve groundwater samples and one trip blank were collected on December 28, 2015 as
part of the Second Semiannual 2015 groundwater monitoring event performed at the Town of
Southold Landfill. All samples were analyzed for the 6NYCRR Part 360 Baseline Parameters,
including volatile organic compounds (VOCs), inorganic parameters (metals) and leachate
indicators. Sample analysis was performed in accordance with SW-846 methods. The
laboratory analyses were performed by ALS Environmental, located in Rochester, New York and
reported in data package R1511241.
The data package submitted by the analytical laboratory was validated in accordance with
NYSDEC quality assurance/quality control (QA/QC) requirements, the contract requirements
and Part 360. All samples were analyzed within the method specified holding times except where
noted below. The following requirements were outside limits and required qualification of the
data:
The percent recovery (%R) was above the QC limit for mercury in the spike sample.
As a result, mercury was qualified as an estimated detection limit (UJ) in all
groundwater samples.
The hexavalent chromium results were analyzed outside the holding time for
groundwater samples MW-3D and MW-4S. Hexavalent chromium was qualified as
estimated (UJ) in groundwater samples MW-3D and MW-4S.
The %Rs for COD, chloride, TKN and hexavalent chromium were below QC limits
in the matrix spike (MS) and/or MS duplicate. COD, chloride, TKN and hexavalent
chromium were qualified as estimated (J/UJ) in all groundwater samples.
No other issues were found with the sample results and all results are deemed valid and
usable for environmental assessment purposes as qualified above. Data validation checklists
completed for the Second Semiannual 2015 groundwater monitoring event conducted on
December 28, 2015 are provided in Appendix E.
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4.2 Groundwater Results
The laboratory results for the Second Semiannual 2015 groundwater monitoring event are
summarized on Table B-1 through Table B-3 in Appendix B and compared to the New York
State Department of Environmental Conservation Ambient Water Quality Standards and
Guidance Values for Class GA groundwater (herein referred to as the Class GA groundwater
standards and guidance values). Table B-1 provides the volatile organic compound (VOC)
results, Table B-2 the inorganic parameters (metals) results and Table B-3 the leachate indicator
results. Field parameters measured during the groundwater purging process are presented on the
groundwater sampling logs in Appendix C. A discussion of the field parameters and each
analytical parameter group is provided below.
4.2.1 Field Parameters
A review of the field parameters for the groundwater samples collected from each well,
provided on the groundwater sampling logs in Appendix C, indicates the following key findings:
Conductivity values were highest in deep wells located downgradient of the Site,
including wells MW-3D, MW-4D, MW-5D and MW-8D. The high conductivity
values appear to be Site-related. There is no Class GA standard or guidance value for
conductivity.
Groundwater temperatures were approximately 1 to 2 degrees Celsius higher in 8 of
the 10 downgradient wells relative to the upgradient wells. The highest temperatures
were recorded in well clusters MW-3, MW-4 and MW-8. There is no Class GA
standard or guidance value for temperature.
pH was lower than the minimum Class GA groundwater standard of 6.5 in upgradient
well MW-1S and in 9 of the 10 downgradient wells. The results are consistent with
the naturally low pH of Long Island groundwater. Groundwater pH was typically
higher in the deep well at each well cluster, including the upgradient deep well.
Dissolved Oxygen (DO) concentrations were lower in all 10 downgradient wells
measured relative to upgradient wells. DO concentrations in the downgradient wells
ranged between 0.47 mg/l at MW-5D to 3.35 mg/l at MW-5S. The concentrations in
upgradient wells MW-1S and MW-1D were 6.65 mg/l and 3.62 mg/l, respectively.
There is no Class GA standard or guidance value for DO.
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The Oxidation-Reduction Potential(ORP)of groundwater waspositive in both
upgradient wells, and in well clusters MW-4, MW-5 and MW-6 indicating oxidizing
conditions; and negative in well clusters MW-3 and MW-8 indicating reducing
conditions. There is no Class GA standard or guidance value for ORP.
In general, the groundwater samples collected from the 12 Site monitoring wells were
observed to be clear, and did not have a noticeable odor.
Light non-aqueous phase liquid (LNAPL) or dense non-aqueous phase liquid
(DNAPL) was not noted in any of the groundwater samples collected from the 12 Site
monitoring wells.
Overall, the field parameter results obtained during the Second Semiannual 2015
groundwater monitoring event are consistent with previous sampling events indicating some
leachate impacts typical of a closed municipal solid waste (MSW) landfill. The leachate-related
impacts are relatively minor in magnitude and limited to higher conductivity and temperature,
and lower DO and ORP in certain downgradient wells.
4.2.2 Volatile Organic Compounds
Review of the VOC results provided on Table B-1 in Appendix B indicates the
following key findings:
Except for 1,2-dichloropropane detected in well MW-1D at a concentration below the
Class GA groundwater standard, VOCs were not detected in upgradient well cluster
MW-1.
Three out of the ten downgradient monitoring wells (deep wells MW-4D, MW-5D
and MW-8D) exhibited several VOCs at concentrations marginally above Class GA
groundwater standards, including 1,2-dichloroethane (1,2-DCA) and 1,2-
dichloropropane in MW-4D and MW-8D, and 1,2-dichloropropane and
chlorobenzene in MW-5D.
The highest detected VOC concentration was chlorobenzene in MW-5D at a
concentration of 10 ug/l, above the Class GA groundwater standard of 5 ug/l.
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4-3
In general, the VOC results for the Second Semiannual 2015 groundwater monitoring
event are consistent with previous sampling events. Based on these results, the Site is not a
significant source of VOC contaminants to the groundwater.
4.2.3 Inorganic Parameters (Metals)
Review of the inorganic parameter (metals) results provided on Table B-2 in Appendix
B indicates the following key findings:
Iron, magnesium, manganese and sodium were detected above Class GA groundwater
standards/guidance values in one or more downgradient wells. Inorganic parameters
were not detected above Class GA groundwater standards/guidance values in
upgradient wells.
Iron was detected above the Class GA groundwater standard of 300 ug/l in 5
downgradient wells (MW-3S, MW-3D, MW-4D, MW-8S and MW-8D). These iron
concentrations ranged from 310 ug/l at MW-4D to 109,000 ug/l detected in shallow
well MW-3S.
Magnesium was detected above the Class GA guidance value of 35,000 ug/l in
downgradient deep well MW-4D at a concentration of 57,600 ug/l. At each well
cluster, higher magnesium concentrations occurred in the deep well, which suggests
that the detected magnesium concentrations may be partly associated with naturally
saline groundwater conditions at depth.
Manganese was detected above the Class GA groundwater standard of 300 ug/l in 8
downgradient wells (MW-3S, MW-3D, MW-4S, MW-4D, MW-5D, MW-6S,
MW-6D and MW-8D). Manganese concentrations in these wells ranged between 873
ug/l at MW-6D to 11,300 ug/l at deep well MW-5D.
Sodium was detected above the Class GA groundwater standard of 20,000 ug/l in 6
downgradient wells (MW-3S, MW-3D, MW-4D, MW-5D, MW-8S and MW-8D).
Sodium concentrations in these wells ranged between 21,300 ug/l at MW-8S to
196,000 ug/l at deep well MW-4D. At each well cluster, higher sodium
concentrations occurred in the deep well, which suggests that the detected sodium
concentrations may be partly associated with naturally saline groundwater conditions
at depth.
In general, the inorganic parameter results for the Second Semiannual 2015 groundwater
monitoring event are consistent with previous sampling events indicating some leachate impacts
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typical of a closed MSW landfill. In addition, higher concentrations of some inorganic
parameters in deep wells may be related in part to naturally saline groundwater conditions at
depth.
4.2.4 Leachate Indicators
Review of the leachate indicator results provided on Table B-3 in Appendix B indicates
the following key findings:
Ammonia, chloride, nitrate and phenols were detected above Class GA groundwater
standards in one or more downgradient wells. Leachate indicators were not detected
above Class GA groundwater standards/guidance values in upgradient wells.
Ammonia was detected above the Class GA groundwater standard of 2 mg/l in 6
downgradient monitoring wells (MW-3S, MW-3D, MW-4D, MW-5D, MW-8S and
MW-8D). Ammonia concentrations in these wells ranged between 9.23 mg/l at
MW-3S to 74.7 mg/l at deep well MW-5D.
Chloride was detected above the Class GA groundwater standard of 250 mg/l in deep
well MW-4D at a concentration of 292 mg/l. The higher chloride concentrations in
the deep wells may be due in part to naturally saline groundwater conditions at depth.
Nitrate was detected above the Class GA groundwater standard of 10 mg/l in
downgradient shallow well MW-4S at a concentration of 19.5 mg/l and deep well
MW-6D at a concentration of 10.8 mg/l.
Phenols were detected above the Class GA groundwater standard of 0.001 mg/l in
downgradient deep wells MW-3D (0.0094 mg/l), MW-4D (0.0075 mg/l) and MW-5D
(0.0085 mg/l).
In general, the leachate indicator results for the Second Semiannual 2015 groundwater
monitoring event are consistent with previous sampling events indicating some leachate impacts
typical of a closed MSW landfill. In addition, higher concentrations of some leachate indicators
in deep wells may be related in part to naturally saline groundwater conditions at depth.
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4-5
5.0 CONCLUSIONS AND RECOMMENDATIONS
Based on the results of the Second Semiannual 2015 groundwater monitoring event,
D&B concludes the following:
Water level elevations, horizontal and vertical hydraulic gradients, and groundwater
flow directions are consistent with previous results and local/regional hydrogeologic
conditions.
In general, groundwater quality is consistent with previous results indicating some
downgradient leachate impacts typical of a closed MSW landfill.
Some of the elevated concentrations detected in downgradient deep wells may be
related in part to naturally saline groundwater conditions at depth.
The NYSDEC has previously approved the Town o
scope and frequency of post-closure monitoring to semiannually for Part 360 Baseline
Parameters. The Second Semiannual 2015 results discussed in this report are generally
consistent with previous sampling events and do not indicate any significant changes or
deterioration in groundwater quality that would warrant a change in the scope of the monitoring
program. Therefore, the monitoring reduction approved by NYSDEC should be continued.
The next monitoring round (First Semiannual 2016 groundwater monitoring event) is
scheduled to be conducted in May 2016 for Part 360 Baseline Parameters.
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5-1
APPENDIX A
NYSDEC APPROVAL LETTER FOR REQUEST FOR MODIFICATIONS
(JULY 12, 2015)
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APPENDIX B
GROUNDWATER ANALYTICAL RESULTS
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5.Nfuizm.3.Qfoubopof...
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J:\\_HazWaste\\3753 (Southold Landfill)\\Groundwater 2015 - 4Q Data\\4qtr2015
Ubcmf!C.2
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2-2-3.Usjdimpspfuibof 2!TU1/45!V1/45!V1/45!V1/45!V
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3.Ifybopof 61!HW2/8!V2/8!V2/8!V2/8!V
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Cspnpejdimpspnfuibof 61!HW1/43!V1/43!V1/43!V1/43!V
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Cspnpnfuibof 6!TU1/3:!V1/3:!V1/3:!V1/3:!V
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Dbscpo!Ufusbdimpsjef 6!TU1/56!V1/56!V1/56!V1/56!V
Dimpspcfo{fof 6!TU1/3:!V1/3:!V3/7!K4/8!K
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Dimpspgpsn 8!TU1/36!V1/36!V1/36!V1/36!V
Dimpspnfuibof 6!TU1/32!V1/32!V1/32!V1/32!V
Djt.2-3.Ejdimpspfuizmfof 6!TU1/41!V1/41!V1/41!V1/41!V
Djt.2-4.Ejdimpspqspqfof 1/5!TU1/35!V1/35!V1/35!V1/35!V
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p.Yzmfof 6!TU,1/31!V1/31!V1/31!V1/31!V
Tuzsfof 6!TU1/31!V1/31!V1/31!V1/31!V
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Upmvfof 6!TU1/31!V1/31!V1/31!V1/31!V
Usbot.2-3.Ejdimpspfuifof 6!TU1/44!V1/44!V1/44!V1/44!V
Usbot.2-4.Ejdimpspqspqfof 1/5!TU1/31!V1/31!V1/31!V1/31!V
Usbot.2-5.Ejdimpsp.3.Cvufof 6!TU1/81!V1/81!V1/81!V1/81!V
Usjdimpspfuizmfof!)UDF*6!TU1/33!V1/33!V1/33!V1/33!V
Usjdimpspgmvpspnfuibof 6!TU1/31!V1/31!V1/31!V1/31!V
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Wjozm!Dimpsjef 3!TU1/43!V1/43!V1/43!V1/43!V
Upubm!Wpmbujmf!Pshbojd!Dpnqpvoet...11/646:/23
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vh0m!!Njdsphsbnt!qfs!mjufs
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TU!!!Tuboebse
J:\\_HazWaste\\3753 (Southold Landfill)\\Groundwater 2015 - 4Q Data\\4qtr2015
Ubcmf!C.3
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Hspvoexbufs!Npojupsjoh!Qsphsbn
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2111!TU
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J:\\_HazWaste\\3753 (Southold Landfill)\\Groundwater 2015 - 4Q Data\\4qtr2015
Ubcmf!C.4
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Upxo!pg!Tpvuipme!Mboegjmm!
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Upubm!Ejttpmwfe!Tpmjet
2/:2/1!V:/435/77/:31/45/637/25/32/1!V22/623/4
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J:\\_HazWaste\\3753 (Southold Landfill)\\Groundwater 2015 - 4Q Data\\4qtr2015
APPENDIX C
GROUNDWATER SAMPLING LOGS
3753\\NN04081601_SoutholdT rpt(R02)
APPENDIX D
CHAIN OF CUSTODY FORMS
3753\\NN04081601_SoutholdT rpt(R02)
APPENDIX E
DATA VALIDATION CHECK LIST
3753\\NN04081601_SoutholdT rpt(R02)
EBUB!WBMJEBUJPO!DIFDLMJTU
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